Synergistic insecticidal mixtures.

(54) Title: SYNERGIC INSECTICIDE MIXTURES. (54) Titie: SYNERGISTIC INSECTICIDAL MIXTURES.

(57) Summary

The invention relates to insecticidal mixtures, which contain Thiodicarb and at least one other known active product from the chloronicotinyl series, as well as to the use of these mixtures for the fight against animal pests.

(57) Abstract

The invention relates to insecticidal mixtures, comprising thiodicarb and at least one other known active ingredient from the chloronicotinyl series and to the use of said mixtures in order to combat animal pests.

(12) NACH DEM VERTRAG ÜBER DIB INTERNATIONALE ZUSAMMENAKBE1T AUE DEM GEBIET DES PATONTWESENS (PCT) VEROEFENTLICHTE INTERNATIONALE ANMELDUNG ®g | Ι · Ι · Ι ···· Β1 · ΙΪ · 1ΒΒ1Ι1Ι ·· (43) Internationales Yeroffentlichungsdatnm (10) Internationale Yerofl'enüidiungsnummer

30. Jdbí 2005 (06/30/2005) PCT WO 2005/058039 Al (51) Internationale Patentklassifikation ': A01N 47/24 // (A01N 47/24, 51: 00,47: 40,43: 40) (21) Internationales Aklenzeichen: PCT7EP2004 / 0134-70 (22) · Internatíonales Anmeldedatum:.

27. November 2004 (27.11.2004) (25) Einrddiungsspradie: Deutsch (26) VcroffentlichuDgssprache: Deutsch (30) 'Angaben zurPrioritát:

• 10358181.2 12. Dezember 2003 (12.12.2003) DE

- • - • 102004028995.6 · 16. Juni 2004 (16.06.2004) DE (71) Anmelder^;(7tir alie Bestimmungsslaaien thousand Ausnahme. Von US): BAYER CRÓPSCIENCE AKTIENGE · ···. . SELLSCHAET [DE / DE]; Alfred-Nobel-Str. '50, 40789

Monheim (DE).

(72) -Erilnder; und (75) Erfinder / Aiundder (nur / go US) ·. ANDERSCH, Wol fram [DE / DE]; SchlodderdicherWeg 77.51468 Bergisch Gladbach '(DB). HÜNGENBERG, Heike [DE / D E]; Lou 'veciennesstr. 2A, 40764 Langenfeld (DE). THIELERT, Wóllgang [DE / DE]; Bnschweg 69,51519 Odenthal (DE).

(74) Gemeinsamer Vertreter: BAYER CROPSCIENCE AKTTENGESELLSCHAET; Law and Patents, Patents and Licensing, 51368 Leverkusen (DE).

(81) Bestimmungsstaatcn (soweii niela anden angegeben, jur jede verfiigbare nationale Schutzrechlsart) '. AE, AG, AL,

AM, AT, AU, AZ, BA, BB, BG, BR, BW.BY.BZ, CA, CH, CN, CO, CR, CU, CZ, DE, DK, DM, DZ, EC, EE, EG, ES, H, GB, GD, GE, GH, GM, HR, HU, ID, IL, IN, IS, JP, KE, KG, KP, KR, KZ, LC, LK, LR, LS, LT, LU, LY, MA MD, MG, MK, MN, MW, MX, MZ, NA, NI, NO, NZ, OM, PG, PH, PL, PT, RO, RU, SC, SD, SE, SG, SK, SL , SY, TJ, TM, 'TN, TR, TT, TZ, UA, UG, US, UZ, VC, YN, YU, ZA, ZM,

ZW.

(84) Bcstimmungsstaaten isaweil niela anden angegeben, fiir jede verfiigbare regionale Schutzrechtsart): ARIPO (BW, GH, GM, KE, LS, MW, MZ. NA, SD, SL, SZ, TZ, UG, ZM, ZW), eurasisches (AM, AZ, BY, KG, KZ, MD, RU, '· TJ, TM), EuropáiEches (AT, BE, BG, CH, C, Y, CZ, DB, DK, EE, ES, FI, HR, GB, GR, HU, 'IE, IS, ΓΓ, LÚ, MC, NL, PL, PT, RO, SE SI, SK, TR), OAPI (BR BI, CR CG, CI, CM, GA, GN, GQ , GW, ML, MR, NE, SN, TD, TG). „

YerBffentlicht:

-. mit imemarionalem Recherchenberidn - vor Abiaupdsr für An'derungen der Ansprüche gehenden Frist; Veroffenilichung wird wiederhoh, rfalls Andenutgen eimreffen

Zur Erklarung der Zweibudtslaben-Codes und der anderen Abkiirzungen wird aurf die Erkldrungen (Guidance Notes an Codes and Abbreviations) am Anrfang jeder regularen Ausgdbe der PCT-Gazette verwiesen.

WO 2005/058039 Al

<img file="MXPA06006367A_D0001.tif" />

(54) Title: SYNERGISTICINSECTTCIDAL MIXTURES (54) Bezeidmung: SYNERGISTISCHEINSEKTIZIDB MISCHUNGEN (57) Abstract: The invention relates ío insecticidal mixtures, comprising thiodicarb and at least one other known active ingredient from the chloronicotinyl series and to Üie use of said mixtures to combat animal pests.

(57) Zusammenlassung: Die ErfinduDg betrifft insektizide Mischungen, entbaltend Thiodicarb und mindestens einen weiteren bekannlen Wirkstoff aus der Reihe der Chlomicotinyle sowie die Yerwendung dieser Mischungen zur Bekampfung lierischer Schádlin.

SYNERGIC INSECTICIDE MIXTURES

Field of the Invention

The present invention relates to new combinations of active ingredients, which contain, as active ingredients, Thiodicarb and another active ingredient from the chloronicotinyl series and which have very good insecticidal properties.

Background of the Invention

It is already known that Thiodicarb can be used to fight animal pests, especially insects. Furthermore, they are known to be suitable for the fight against animal pests, especially against insects, for example Imidacloprid, Thiacloprid, Clothianidin,

<td>he</td><td>Thi ame thoxam,</td><td>he</td><td>Acetamiprid,</td><td>he</td><td>Nitenpyram</td><td>and the</td>

<td colspan="2">Dinotefuran.</td><td></td><td></td><td></td><td></td><td></td>

<td></td><td>Activity</td><td>of</td><td>these products</td><td>it is</td><td>good without</td><td>embargo</td>

<td>let</td><td>be desired</td><td>in</td><td>some cases</td><td>with</td><td>occasion of</td><td>low</td>

application amounts or against individual pests.

Detailed description of the invention

It has now been found that mixtures containing

Thiodicarb and, respectively, a compound from the chloronicotinyl series, have a synergistic activity and are suitable for fighting animal pests. Due to this synergism, smaller amounts of the

REF.:173320 active products', that is, the effect is greater than the effect of the individual components.

The compounds mentioned are known, for example, from the publication The Pestici-de Manual, ll^th Edition, 1997, published by British Crop Protection Council, see page 119 for Thiocarb, page 706 for Imidacloprid, page 9 for Acetamiprid and page 880 for

Nitenpyram.

Thiamethoxam has the formula

CI

<img file="MXPA06006367A_D0002.tif" />

NO₂

N.

and is known from publication EP 0 580 553.

Clothianidin has the formula

H

CI

<img file="MXPA06006367A_D0003.tif" />

NO₂

N and is known from publication EP 0 376 279.

Thiacloprid has the formula ci

<img file="MXPA06006367A_D0004.tif" />

'CN and is known from publication EP 0 235 725.

Dinotefuran has the formula H

CL 2— CH — Γ-k, NHCH_OR

ΛΛ i *

0 ^^ 2-CH — N

NO „and is known from publication EP 0 649 845.

The proportion between the two active products used, as well as the total amount to be used of the mixture depends on the type and origin of the insects. Optimal proportions and total application amounts can be determined for each application respectively by means of test series.

A particularly preferred mixture according to the invention contains the active ingredients Thiodicarb and Imidacloprid. In the mixture is the proportion by weight, between both active products, preferably comprised between 100 on 1 and 1 on 50 and especially preferably, between 25 on 1 and 1 on 5, being mentioned in this case, as well as below , the Thiodicarb first in the corresponding proportions ..

Another particularly preferred mixture according to the invention contains the active ingredients Thiodicarb and

Acetamiprid. In the mixture there is the proportion by weight, between both active products, preferably comprised between 100 on 1 and 1 on 50 and particularly preferably, between 25 on 1 and 1 on 5.

Another particularly preferred mixture according to the invention contains the active ingredients Thiodicarb and Nitenpyram. In the mixture there is the proportion by weight, between both active products, preferably comprised between 100 on 1 and 1 on 50 and particularly preferably, between 25 on 1 and 1 on 5.

Another particularly preferred mixture according to the invention contains the active ingredients Thiodicarb and Dinotefuran. In the mixture there is the proportion by weight, between both active products, preferably comprised between 100 on 1 and 1 on 50 and particularly preferably, between 25 on 1 and 1 on 5.

Another particularly preferred mixture, according to the • invention, contains the active ingredients Thiodicarb and

Thiamothoxam. In the mixture is the proportion by weight, between both active products, preferably comprised between 100 on 1 and 1 on 50 and in a particularly preferred way, between 25 on 1 and 1 on 5.

Another particularly preferred mixture according to the invention contains the active ingredients Thiodicarb and

Clothianidin. In the mixture there is the proportion by weight, between both active products, preferably comprised between 100 on 1 and 1 on 50 and particularly preferably, between 25 on 1 and 1 on 5.

Another particularly preferred mixture according to the invention contains the active ingredients Thiodicarb and Thiacloprid. In the mixture there is the proportion by weight, between both active products, preferably comprised between 100 on 1 and 1 on 50 and particularly preferably, between 25 on 1 and 1 on 5.

The combinations of the active products are suitable, with good compatibility with plants and with favorable toxicity for warm-blooded animals, for the fight against animal pests, preferably against insects, arachnids and nematodes, which occur in agriculture, in forestry, for the protection of stored products and materials as well as in the hygiene sector. Preferably, they can be used as agents for the protection of plants. They are active against normally sensitive and resistant species as well as against all or some of the stages of development. To the aforementioned pests belong:

from the order of the Isopoda, for example Oniscus asellus, Armadillidium vulgare, Porcellio scaber.

From the order of the Diplopoda, for example, Blaniulus guttulatus.

From the order of the Chilopoda, for example, Geophilus carpophagus, Scutigera spp.

From the order of the Symphyla, for example, Scutigerella immaculata.

From the order of the Thysanura, for example, Lepisma saccharina.

From the order of the Collembola, for example, Onychiurus armatus.

From the order of the Orthoptera, for example, Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria.

From the order of the Blattaria, for example, Blatta orientalis, Periplaneta americana, Leucophaea maderae,

Germanic blattella.

From the order of the Dermaptera, for example, Forfícula auricularia.

From the order of the Isoptera, for example, Reticulos termes spp.

From the order of the Phthiraptera, for example, Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp.

From the order of the Thysanoptera, for example, Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella occidentalis.

From the order of the Heteroptera, for example, Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp.

From the order of the Homoptera, for example, Aleurodes 25 brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fabae, Aphis pomi, Eriosoma lanigeripus, Hyalopterus arundinis, Phylloxera s. ., Phorodon humuli, Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp., Psylla spp.

From the order of the Lepidoptera, for example, Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta enferlla, Plutella xylostella, Malacosoma neustria, Euproctis chrysoris, Lymantria spp., Bucculatrix thurberiel. spp., Earias insulana, Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis. Galleria mellonella, Tineola pellionella, Hofmannophila podana, Capua reticulana, Clysia ambiguella, Homona magnánima, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae.

From the order of the Coleoptera, for example, Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus,

Ephestia. kuehniella, bisselliella, Tinea pseudospretella, Cacoecia

Choristoneura fumiferana,

Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa ​​decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachna varivestis, Atomaria spp., Oryzaephilus sina. postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligeth.es aeneus, Ptinus spp. ·, Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica, Lissorhoptrus oryzophilus.

From the order of the Hymenoptera, for example, Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.

From the order of the Diptera, for example Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, -Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Typula paludosa, Hylemy Liriomyza spp.

From the order of the Siphonaptera, for example, Xenopsylla cheopis, Ceratophyllus spp.

From the class of the Arachnida for example Scorpio maurus, Latrodectus mactans, Acarus siró, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp.,

Hyalomma spp., Ixodes spp., Psoroptes spp., Chorioptes spp.,

Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa,

Panonychus spp., Tetranychus spp., Hemitarsonemus spp.,

Brevipalpus spp.

The parasitic nematodes of plants include, for example, Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xympropp. Trichodorus spp.,

Bursaphelenchus spp.

According to the invention, all plants and plant parts can be treated. Plants in this case are understood to be all plants and plant populations, such as desired and unwanted wild plants or crop plants (including naturally occurring crop plants). Crop plants can be plants that can be obtained by conventional cultivation and optimization methods or by means of biotechnological and genetic engineering methods or by combinations of these methods, including transgenic planets and including plant varieties that can be protected by the right to protection of plant or non-protectable varieties. Plant parts are understood to mean all the parts and organs of aerial and underground plants, such as shoots, leaves, flowers and roots, with examples of leaves, needles, stems, branches, flowers, fruit bodies, fruits. and seeds as well as roots, bulbs and rhizomes. The plant parts also include the crops as well as the vegetative and generative reproductive material, for example seedlings, bulbs, rhizomes, layers and seeds.

In this case, the especially advantageous effect of the agent according to the invention should be noted with regard to the application in cereal plants, such as for example wheat, oats, barley, common spelled, triticale and rye, as well as well as corn, millet, rice, sugar cane, soybeans, sunflowers, potatoes, cotton, rape, cane, tobacco, sugar beets, fodder beets, asparagus, hops, as well as fruit orchards (comprising pome fruits such as, for example, apples and pears, stone fruits such as, for example, peach, nectarines, cherries, plums and apricots, citrus fruits, such as, for example, oranges, grapefruits, limes, lemons, kumquats, tangerines and satsumas, nuts such as for example pistachios, almonds, drupes and pecans, tropical fruits such as for example mango, papaya, pineapple, dates and bananas, and vines) and vegetables (including green leafy vegetables such as endi via, lamb's lettuce, fennel, sprouted lettuce and cut lettuce, Swiss chard, spinach and Brussels chicory, collards such as cauliflower, broccoli, cabbage from China, green cabbage (winter cabbage or kale), kohlrabi, Brussels sprouts, red cabbage, cabbage and curly leaf cabbage, meaty vegetables such as for example eggplants, cucumbers, peppers, curcubitaceae for consumption, tomatoes, zucchini and sugar corn, root vegetables such as celery radish, turnip, carrot, yellow turnip, radish, radish, red turnip, escorzonera and root celery, pod fruits such as chickpeas and beans as well as bulb vegetables such as leeks and onions for consumption).

The treatment, in accordance with the invention, of plants and plant parts with the combination of active products is carried out directly or through action on the environment, the living room or the storage room in accordance with the usual treatment methods, for example by immersion, spraying, evaporation, misting, spreading, brushing and in the case of reproductive material, especially in the case of seeds, also by coating with one or more layers.

Especially the mixtures according to the invention are suitable for seed treatment. In this way, a large part of the damage caused by pests on crop plants is already generated by the attack of the seed during storage and after the introduction of the seed into the soil as well as during and immediately after the germination of the plants. This phase is especially critical since the roots and shoots of growing plants are especially sensitive and a slight deterioration can lead to the death of the entire plant. Therefore, there is an especially great interest that the seed and the germinating plant are protected by the use of suitable agents.

The fight against pests by treating the seed of plants has been known for a long time and is the object of permanent improvements. However, during seed treatment a series of problems arise that cannot always be satisfactorily resolved. In this way, the development of procedures for the protection of the seed and the germinating plant should be sought that make the additional contribution of plant protection agents unnecessary after sowing or after the sprouting of the plants. Furthermore, efforts should be made to optimize the amount of the active product used in such a way that the seed and the germinating plant are protected in the best possible way against attack due to pests without, however, the plant itself being damaged by the active product used . Especially the procedures for the treatment of plants must also include the intrinsically insecticidal properties of transgenic plants to achieve optimal protection of the seed and the germinating plant with minimal cost in plant protection agents.

The present invention therefore relates especially also to a method for the protection of seeds and germinating plants before attack by pests, by treating the seed with an agent according to the invention . The invention also relates to the use of the agent according to the invention for the treatment of seeds for the protection of the seed and the germinating plant against pests. Furthermore, the invention relates to seeds, which have been treated with an agent, in accordance with the invention, for their protection against pests.

One of the advantages of the present invention is that, as a consequence of the especially systemic properties of the agent according to the invention, the treatment of the seed with these agents not only protects the seeds themselves against pests, but also the plants that grow from them after the outbreak. In this way the direct treatment of the crops can be eliminated at the time of sowing or soon after.

Another advantage consists in the synergistic increase of the insecticidal activity of the agents, according to the invention, in comparison with the corresponding individual products, which goes beyond the sum of the activity of the individual active ingredients arrived at. In this way an optimization of the quantity of the active product used is made possible.

In the same way, it can be considered as advantageous that the mixtures, according to the invention, can be used especially also in the case of transgenic seeds, the plants, which come from these seeds, being capable of expressing a protein directed against pests. By treating such seeds with the agents, according to the invention, certain pests can already be controlled by the expression of the protein, for example insecticide and surprisingly furthermore produces a synergistic complement of activity with the agents according to the invention, which further enhances the effectiveness of protection with pest attack.

The agents according to the invention are suitable for the protection of seeds of any plant variety, as mentioned above, which is used in agriculture, in the greenhouse, in forestry, in gardening or in vineyards. In this case, it is especially concerned with corn, peanut, cane, rapeseed, poppy, olive, coconut, cocoa, soybean, cotton, and beet seeds (for example, sugar beets and fodder beets), rice, millet, wheat, barley, oats, rye, sunflower, sugar cane or tobacco. The agents according to the invention are also suitable for the treatment of seeds of fruit plants and vegetables as already mentioned above. The treatment of corn, soybean, cotton, wheat and cane or rapeseed has special significance.

As already indicated above, treatment of transgenic seeds with an agent according to the invention also has special significance. In this case, these are plant seeds that, as a general rule, contain at least one heterologous gene, which controls the expression of a polypeptide with especially insecticidal properties. The heterologous genes in the transgenic seeds can also come from microorganisms such as Bacillus, Rhizobium, Pseudomonas, Serratia, Trichoderma, Clavibacter, Glomus or Gliocladium. The present invention is especially suitable for the treatment of transgenic seeds, which contain at least one heterologous gene that comes from Bacillus sp. and whose genetic product shows activity against the corn pyral and / or the corn blight. Particularly preferably, in this case, it is a heterologous gene that comes from Bacillus thuringiensis.

Within the scope of the present invention, the agent according to the invention will be applied alone or in a suitable formulation on the seeds. The seeds are preferably treated in a state in which they are so stable that no deterioration occurs during treatment. In general, seed treatment can be carried out at any time between harvest and sowing. Usually the seeds that have been separated from the plants and that have been freed from appendages, shells, stems, pods, wool or the flesh of the fruit will be used.

In general, it must be taken into account at the time of seed treatment that the amount of the agent according to the invention, applied to the seed and / or other additives is chosen in such a way that the germination of the seeds is not impaired. seeds or the plants that grow from them are not damaged. This must be taken into account first of all in the case of active products that can present phytotoxic effects with certain application amounts.

The agents according to the invention can be applied directly, that is to say without containing other components and without having been diluted. As a general rule it is preferred to apply the agents in the form of a suitable formulation on the seeds. Suitable formulations and procedures for seed treatment are known to the person skilled in the art and have been described, for example, in the following documents: US 4,272,417 A, US 4,245,432 A, US 4,808,430 A, US 5,876,739 A, US 2003 / 0176428

Al, WO 2002/080675 Al, WO 2002/028186 A2.

The active compound combinations can be transformed into the usual formulations, such as solutions, emulsions, atomizable powders, suspensions, powders, dusting agents, pastes, soluble powders, granules, suspension-emulsion concentrates, natural and synthetic materials impregnated with the product. active, as well as microencapsulated in polymeric materials.

These formulations are prepared in a known manner, for example by mixing the active compounds with extenders, that is, with liquid solvents and / or solid excipients, optionally with the use of surfactants, that is, emulsifiers and / or dispersants and / or or foam generating means.

When water is used as a extender, organic solvents may be used, for example as auxiliary solvents. Suitable liquid solvents are preferably: aromatic hydrocarbons, such as xylene, toluene, or alkylnaphthalene, chlorinated aromatic hydrocarbons, and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes, or methylene chloride, aliphatic hydrocarbons, such as cyclohexane, or paraffins, for example, petroleum fractions , mineral and vegetable oils, alcohols such as butanol or glycol, as well as their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, or strongly polar solvents such as dimethylformamide and dimethyl sulfoxide as well as water.

As solid excipients are considered:

for example ammonium salts and natural ground minerals, such as kaolin, clay, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and ground synthetic minerals, such as highly dispersed silicic acid, aluminum oxide and silicates, As 15 solid excipients for granules are considered: for example broken and fractionated natural minerals, such as calcite, marble, pumice, sepiolite and dolomite, as well as synthetic granules of inorganic and organic flours and granules of organic material, such as sawdust, coconut shells, ear buds corn and tobacco stalks; Suitable emulsifiers and / or foamers include: for example, nonionic and anionic emulsifiers, such as polyoxyethylene esters of fatty acids, polyoxyethylene ethers of fatty alcohols, for example, alkylaryl polyglycol ether, alkylsulfonates, alkylsulfates, arylsulfonates, as well as albumin hydrolyzates; Suitable dispersants include, for example, lignin sulphite lyes and methyl cellulose.

Adhesives such as carboxymethyl cellulose, powdery, granular or latex-based natural and synthetic polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate, as well as natural phospholipids such as cephalin and lecithin, and synthetic phospholipids. Other additives can be mineral and vegetable oils.

Dyes such as inorganic pigments, for example iron oxide, titanium oxide, Prussian blue, and organic dyes such as alizarin, azo and metallic phthalocyanine dyes as well as trace nutrients such as such as iron, manganese, boron, copper, cobalt, molybdenum and zinc salts.

The formulations generally contain between 0.1 and 95% by weight, preferably between 0.5 and 90% of active compound.

The active compound combinations according to the invention can be presented in their usual commercial formulations as well as in the application forms prepared from these formulations, in mixture with other active products, such as insecticides, baits, sterilants, bactericides, acaricides, nematicides, fungicides, growth regulator products or herbicides. Insecticides include, for example, phosphoric acid esters, carbamates, carbonic acid esters, chlorinated hydrocarbons, phenylureas, products prepared by means of microorganisms and the like.

Particularly favorable mixing components are, for example, the following:

Fungicides:

Aldimorph, Ampropylfos, Ampropylfos-potassium, Andoprim, 10 Anilazin, Azaconazole, Azoxystrobin,

Benalaxyl, Benodanil, Benomyl, Benzamacril, Benzamacrylisobutilo, Bialaphos, Binapacryl, Biphenyl, Bitertanol, BlasticidinS, Bromuconazol, Bupirimat, Buthionat, Chin, Carim, Captafol, Captan, Carb,

Chlorfenazol, Chloroneb, Chloropicrin, Chlorothalonil, Chlozolinat, Clozylacon, Cufraneb, Cymoxanil, Cyproconazol, Cyprodinil, Cyprofuram, Debacarb, Dichlorophen, Diclobutrazol, Diclofluanid, Diclomezin,

Dicloran, Diethofencarb, Difenoconazol, Dimethirimol, 20 Dimethomorph, Diniconazol, Diniconazol-M, Dinocap, diphenylamine, Dipyrithione, Ditalimfos, Dithianon, Dodemorph,

Dodine, Drazoxolon,

Ediphenphos, Epoxiconazol, Etaconazol, Ethirimol, Etridiazol,

Famoxadon, Fenapanil, Fenarimol, Fenbuconazol, Fenfuram, 25 Fenitropan, Fenpiclonil, Fenpropidin, Fenpropimorph,

Fenpropidin,

Fentinacetat, Fentinhydroxide, Ferbam, Ferimzon, Fluazinam, Flumetover, Fluoromid, Fluquinconazole, Flurprimidol,

Flusilazol, Flusulfamid, Flutolanil, Flutriafol, Folpet, Fosetyl-aluminum, Fosetyl-sodium, Fthalid, Fuberidazol, Furalaxyl, Furametpyr, Furcarbonil, Furconazol, Furconazolcis, Furmecyclox,

Guazatin, Hexachlorobenzene, Hexaconazole, Hymexazol,

Imazalil, Imibenconazole, Iminoctadin, Iminoctadinealbesilate, Iminoctadinetriacetate, Iodocarb, Ipconazole, Iprobenphos (IBP), Iprodione, Irumamycin, Isoprothiolan, Isovaledione, Kasugamycin, Kresoxim-methyl, copper preparations, such as: copper, copper sulfate, copper oxide, copper oxine and Bordeaux mixture,

Mancopper, Mancozeb, Maneb, Meferimzone, Mepanipyrim, Mepronil, Metalaxyl, Metconazole, Methasulfocarb, Methfuroxam, Metiram, Metomeclam, Metsulfovax, Mildiomycin, Myclobutan.il, Myclozolin, Dimethyldithiocarbamate, Nickel

Nuarimol,

Ofurace, Oxadixyl, Oxamocarb, oxolinic acid, Oxycarboxim, Oxyfenthiin,

Paclobutrazol, Pefurazoat, Penconazole, Pencycuron,

Phosdiphen, Pimaricin, Piperalin, Polyoxin, Polyoxorim,

Probenazol, Prochloraz, Procymidon, Propamocarb, Propanosinesodio, Propiconazol, Propineb, Pyrazophos, Pyrifenox, Pyrimethanil, Pyroquilon, Pyroxyfur,

Quinconazole, Quintozen (PCNB), sulfur and sulfur preparations,

Tebuconazole, Tecloftalam, Tecnazen, Tetcyclacis,

Tetraconazole,

Thiabendazole,

Thicyofen, Thifluzamide,

Thiophanate-methyl, Thiram, Tioxymid, Tolclofos-methyl,

Tolylfluanid,

Triadimefon,

Triadimenol,

Triazbutyl,

Triazoxid, Trichlamid, Tricyclazol, Tridemorph, Triflumizol,

Triforin, Triticonazole,

Uniconazole,

Validamycin A, Vinclozolin, Viniconazole,

Zarilamid, Zineb, Ziram as well as

Dagger G,

OK-8705,

OK-8801, α- (1, l-dimethylethyl) -β- (2-phenoxyethyl) -1H-1,2,4-triazole-ethanol, a- (2,4-dichlorophenyl) -β-fluorine-b- propyl-lH-1,2,4-triazole-ethanol, a- (2,4-dichlorophenyl) -β-methoxy-a-methyl-lH-l, 2,4-triazole-ethanol, a- (5-methyl -l, 3-dioxan-5-yl) -β - [[4- (trifluoro methyl) -phenyl] 23 methylene] -lH-l, 2,4-triazol-l-ethanol, (5RS, 6RS) -6- hydroxy-2,2,7,7-tetramethyl-5- (1H-1,2,4-triazol-l-yl) -3-octanone, (E) -a- (methoxyimino) -N-methyl-2-phenoxy -phenylacetamide, 1-isopropyl {2-methyl-l - [[[1- (4-methylphenyl) -ethyl] -amino] -carbonyl] propyljcarbamate,

1- (2,4-dichlorophenyl) -2- (1H-1,2,4-triazol-l-yl) -ethanon-O (phenylmethyl) -oxime

1- (2-methyl-l-naphthalenyl) -lH-pyrrole-2,5-dione,

1- (3,5-dichlorophenyl) -3- (2-propenyl) -2,5-pyrrolidinedione,

1 - [(diiodomethyl) -sulfonyl] -4-methyl-benzene,

1 - [[2- (2,4-Dichlorophenyl) -1,3-dioxolan-2-yl] -methyl] -1Himidazole,

1 - [[2- (4-Chlorophenyl) -3-phenyloxyranyl] -methyl] -1H-1,2,415 triazole,

1- [1- [2 - [(2,4-dichlorophenyl) -methoxy] -phenyl] -ethenyl] -1Himidazole, l-methyl-5-nonyl-2- (phenylmethyl) -3-pyrrolidinol,

2 ', 6'-dibromo-2-methy1-4'-trifluoromethoxy-4'-trifluoro-methyl20 l, 3-thiazol-5-carboxanilide

2,2-dichloro-N- [1- (4-chlorophenyl) -ethyl] -l-ethyl-3-methylc i elopropane c arboxami da,

2.6- dichloro-5- (methylthio) -4-pyrimidinyl-thiocyanate,

2.6- dichloro-N- (4-trifluoromethylbenzyl) -benzamide,

2,6-dichloro-N - [[4- (trifluoromethyl) -phenyl] -methyl] -benzamide,

2- (2,3,3-triiodo-2-propenyl) -2H-tetrazole,

2- [(1-methylethyl) -sulfonyl] -5- (trichloromethyl) -1,3, '4-thiadiazole, 2 - [[6-deoxy-4-0- (4-0-methyl-3-D- glycopranosyl) -a-D-glucopyranosyl] -amino] -4-methoxy-lH-pyrrolo [2,3-d] pyrimidin-5carbonitrile,

2-aminobutane,

2-bromo-2- (bromomethyl) -pentanedinitrile,

2-chloro-N- (2,3-dihydro-l, 1,3-trimethyl-lH-inden-4-yl) -3pyridinecarboxamide,

2-chloro-N- (2,6-dimethylphenyl) -N- (isothiocyanatomethyl) acetamide,

2- phenylphenol (OPP),

3.4- dichloro-l- [4- (difluoromethoxy) -phenyl] -lH-pyrrole-2,5-dione,

3.5- dichloro-N- [cyan [(l-methyl-2-propinyl) -oxy] -methyl] benzamide,

3- (1,1-dimethylpropyl) -l-oxo-lH-inden-2-carbonitrile,

3- [2- (4-chlorophenyl) -5-ethoxy-3-isoxazolidinyl] -pyridine,

4- chloro-2-cyan-N, N-dimethyl-5- (4-methylphenyl) -lH-imidazol-1sulfonamide,

4-methyl-tetrazolo [1,5-a] guinazolin-5 (4H) -one,

8- (1,1-dimethylethyl) -N-ethyl-N-propyl-1,4-dioxaspiro [4,5] decan2-methanamine,

8-hydroxyquinoline insulfate,

9H-xanthene-9carboxylic acid 2 - [(phenylamino) -carbonyl] -hydrazide, bis- (1-methylethyl) -3-methyl-4 - [(3-methylbenzoyl) -oxy] -2,5-thiophene dicarboxylate, cis -1- (4-chlorophenyl) -2- (1H-1,2,4-triazol-l-yl) -cycloheptanol, cis-4- [3- [4- (1,1-dimethylpropyl) -phenyl hydrochloride -2-methylpropyl] -2,6-dimethyl-morpholine, [(4-chlorophenyl) -azo] -ethyl-cyanoacetate, potassium bicarbonate,

Methantetrathiól-sodium salt,

Methyl 1- (2,3-dihydro-2,2-dimethyl-lH-inden-l-yl) -lH-imidazol-5-carboxylate,

Methyl N- (2,6-dimethylphenyl) -N- (5-isoxazolylcarbonyl) -DL-alaninate,

Methyl N- (chloroacetyl) -N- (2,6-dimethylphenyl) -DL-alaninate,

N- (2,3-dichloro-4-hydroxyphenyl) -1-methylc i c1ohexanocarboxami da,

N- (2,6-dimethylphenyl) -2-methoxy-N- (tetrahydro-2-oxo-3-furanyl) acetamide,

N- (2,6-dimethylphenyl) -2-methoxy-N- (tetrahydro-2-oxo-3-thienyl) acetamide,

N- (2-chloro-4-nitrophenyl) -4-methyl-3-nitro-benzenesulfonamide,

N- (4-cyclohexylphenyl) -1,4,5,6-tetrahydro-2-pyrimidinamine,

N- (4-hexylphenyl) -1,4,5,6-tetrahydro-2-pyrimidinamine,

N- (5-chloro-2-methylphenyl) -2-methoxy-N- (2-oxo-3-oxazolidinyl) acetamide,

N- (6-methoxy) -3-pyridinyl) -cyclopropanecarboxamide,

Ν- [2,2,2-trichloro-l - [(chloroacetyl) -amino] -ethyl] -benzamide,

N- [3-chloro-4,5-bis- (2-propynyloxy) -phenyl] -Ν'-methoxymethanimidamide,

N-formyl-N-hydroxy-DL-alanine, sodium salt [2- (dipropylamino) -2-oxoethyl] -ethyl-ethyl-phosphoramidothioate, O-methyl-S-phenyl phenylpropyl phosphoramidothioate, l, 2,3-benzothiadiazole- S-methyl 7-carbothioate, spiro [2H] -1-benzopyran-2,1 '(3 Ή) -isobenzofuran] -3'-one.

Bactericides:

Bronopol, Dichlorophen, Nitrapyrin, Nickel Dimethyldithiocarbamate, Kasugamycin, Octhilinon, Furan Carboxylic Acid, Oxytetracyclin, Probenazol, Streptomycin, Tecloftalam, Copper Sulfate and other copper preparations.

Insecticides / acaricides / nematicides:

one. Acetylcholinesterase (AChE) inhibitors

<td>imatos, by</td><td>example</td><td></td><td></td>

<td>Alanycarb,</td><td>Aldicarb,</td><td>Aldoxycarb,</td><td>Allyxycarb</td>

<td>Aminocarb,</td><td>Bendiocarb,</td><td>Benfuracarb,</td><td>Bufencarb</td>

<td>Butacarb,</td><td>Butocarboxim,</td><td>Butoxycarboxim,</td><td>Carbaryl</td>

<td>Carbofuran,</td><td>, Carbosulfan,</td><td>Cloethocarb,</td><td>Dimethylan</td>

Ethiofencarb, Fenobucarb, Fenothiocarb,

<td colspan="2">Formetanate, Furathiocarb,</td><td>Isoprocarb,</td><td>Metam-sodium</td>

<td>Methiocarb,</td><td>Methomyl,</td><td>Metolcarb,</td><td>Oxamyl</td>

<td>Pirimicarb,</td><td>Pr ornee arb,</td><td>Propoxur,</td><td>Thiodicarb</td>

Thiofanox, Trimethacarb, XMC, Xylylcarb

Triazamates

Organophosphates, for example

Accept, Azamethiphos, Azinphos (-methyl, -ethyl),

Bromopho was you,

Butathiofos,

Chlorethoxyfos,

Chlorpyrifos

Diazinon,

Dicrotophos,

Dioxabenzophos,

Ethoprophos,

Fenitrothion,

Dimethylvinphos, EPN, Ethion,

Fenamiphos,

Fenthion,

Bromfenvinphos (-methyl),

Cadusafos, Carbophenothion,

Chlorfenvinphos, Chlormephos, ¡-methyl / -ethyl), Coumaphos,

Cyanofenphos, Cyanophos, Chlorfenvinphos, DemetonS-methyl, Demeton-S-methylsulfone, Dialiphos,

Dichlofenthion, Dichlorvos / DDVP,

Dimethoate,

Disulfoton,

Etrimfos, Famphur,

Fensulfothion,

Flupyrazofos, Fonofos, Formothion, Fosmethilan, Fosthiazate, Heptenophos, Iodofenphos, Iprobenfos, Isazofos, Isofenphos, O-isopropyl salicylate, Isoxathion, Malathion, Mecarbam,

Methamidophos, Methidathion,

Monocrotophos, Naled, Omethoate, Oxydemeton-methyl,

Parathion (-methyl / -ethyl), Phenthoate, Phorate, Phosalone, Phosmet, Phosphamidon, Phosphocarb, Phoxim,

Methacrypha,

Mevinphos,

Pirimiphos (-methyl /

-ethyl),

Profenofos,

Propaphos, Pyraclofos,

Quinalphos,

Tebupirimfos,

Tetrachlorvinphos,

Propetamphos, Prothiofos, Prothoate, Pyridaphenthíon, Pyridathion,

Sebufos, Sulfotep,

Temephos,

Thiorneton,

Sulprofos,

Terbufos,

Triazophos,

Trichlorfon, Vamidothion

two. Sodium channel modulators / sodium channel blockers as a function of stress

2.1 Pyrethroids, for example

Acrinathrin, Allethrin (d-cis-trans, d-trans),

Beta-Cyfluthrin, Bifenthrin, Bioallethrin,

Bioallethrin-S-cyclopentyl-isomer,

Bioethanomethrin, Biopermethrin, Bioresmethrin, Chlovaporthrin, Cis-Cypermethrin, Cis-Resmethrin,

Cis-Permethrin, Clocythrin, Cycloprothrin,

Cyfluthrin, Cyhalothrin, Cypermethrin (alfa-, beta, theta-, zeta-), Cyphenothrin, Deltamethrin, Empenthrin (IR isomer), Esfenvalerate, Etofenprox, Fenfluthrin, Fenpropathrin, Fenpyrithrin,

Fenvalerate, Flubrocythrinate, Flucythrinate,

Flufenprox, Flumethrin, Fluvalinate, Fubfenprox, Gamma-Cyhalothrin, Imiprothrin, Kadethrin, LambdaCyhalothrin, Metofluthrin, Permethrin (cis-, trans), Phenothrin (lR-trans isomer), Prallethrin,

Profluthrin,

Pyresmethrin,

Protrifenbute,

2.2 .

3.1

3.2

4.

4.1

5,

5.1

5.2

6.

6.1

7.

Resmethrin, RU 15525, Silafluofen, Tau-Fluvalinate, Tefluthrin, Terallethrin, Tetramethrin (-isomer

IR), Tralomethrin, Transfluthrin, ZXI 8901,

Pyrethrins. (Pyrethrum)

DDT

Oxadiazines, for example Indoxacarb

Chloronicotinyl acetylcholine receptor agonists / antagonists, eg

Acetamiprid, Clothianidin, Dinotefuran,

Imidacloprid, Nitenpyram, Nithiazine, Thiacloprid,

Thiamethoxam

Nicotine, Bensultap, Cartap

Acetylcholine receptor modulators

Spinosinas, for example Spinosad

GABA controlled chloride channel antagonists Cyclodiene organic chlorides, for example

Camphechlor, Chlordane, Endosulfan, Gamma-HCH, HCH,

Heptachlor, Lindane, Methoxychlor Fiproles, for example

Acetoprole, Ethiprole, Fipronil, Vaniliprole

Chloride channel activators

Mectins, for example

Avermectin, Emamectin, Emamectin-benzoate,

Ivermectin, Milbemycin

Juvenile hormone mimetics, for example

Diofenolan, Epofenonane, Fenoxycarb, Hydroprene,

Kinoprene, Methoprene, Pyriproxifen, Triprene

8. Ecdysone agonists / disruptors

8.1 Diacylhydrazines, for example

Chromafenozide, Halofenozide, Methoxyfenozide,

Tebufenozide

9. Chitin biosynthesis inhibitors

9.1 Benzoylureas, for example

Bistrifluron, Chlofluazuron, Diflubenzuron,

Fluazuron, Flucycloxuron, Flufenoxuron,

Hexaflumuron, Lufenuron, Novaluron, Noviflumuron,

Penfluron, Teflubenzuron, Triflumuron

9.2 Buprofezin

9.3 Cyromazine

10. Oxidation phosphorylation inhibitors, ATP disruptors

10.1 Diafenthiuron

10.2 Organotins, for example Azocyclotin, Cyhexatin,

Fenbutatin-oxide

eleven. Decouplers of oxidation phosphorylation by interruption of the H-protonic gradient

11.1 Pyrroles, for example Chlorfenapyr

11.2 Dinitrophenols, for example Binapacyrl, Dinobuton,

Dinocap, DNOC

12. Electronic transport inhibitors on the I side

12.1 METI's, for example Fenazaquin, Fenpyroxímate, • Pyrimidifen, Pyridaben, Tebufenpyrad, Tolfenpyrad

12.2 Hydramethylnon

12.3 Dicofol

13. Electronic transport inhibitors by side II

Rotenone

14. Electronic transport inhibitors by side III Acequinocyl, Fluacrypyrim

fifteen. Microbial disruptors of the intestinal membrane of insects

Bacillus thuringiensis strains

16. Fat synthesis inhibitors Tetronic acids, for example

Spirodiclofen, Spiromesifen Tetramic acids, for example

3- (2,5-dimethylphenyl) -8-methoxy-2-oxo-lazaspiro [4.5] dec-3-en-4-yl ethyl carbonate (aka:

carbonic acid, 3- (2,5-dimethylphenil) -8-methoxy ~ 2oxo-l-azaspiro [4.5] dec-3-en-4-yl ethyl ester carbonate 3- (2,5-dimethylphenyl) -8- methoxy-2-oxo-lazaspiro [4.5] dec-3-en-4-yl ethyl-, CAS-Reg.-No .:

382608-10-8) and carbonic acid, cis-3- (2,5dimethylphenil) -8-methoxy-2-oxo-l-azaspiro [4.5] dec3-en-4-yl ethyl ester -y cis-3 carbonate - (2,5dimethylphenyl) -8-methoxy-2-oxo-l-azaspiro [4.5] dec-332 en-4-yl ethyl- (CAS-Reg.-No .: 203313-25-1)

17. Carboxamides, for example Flonicamid

18. Octopaminergy agonists, for example'Amitraz

19. Inhibitors of magnesium-stimulated ATPase, eg Propargite

twenty. BDCAs, for example N2- [1, l-dimethyl-2 (methylsulfonyl) ethyl] -3-iodo-Nl- [2-methyl-4- [1,2,2,2tetrafluoro-1- (trifluoromethyl) ethyl] phenyl ] -1,2benzenedicarboxamide (CAS-Reg.-No .: 272451-65-7)

twenty-one. Nereistoxin analogues, eg Thiocyclam hydrogen oxalate, Thiosultap-sodium

22. Biological products, hormones or pheromones, for example

Azadirachtin, Bacillus spec., Beauveria spec., Codlemone, Metarrhizium spec., Paecilomyces spec., Thuringiensin, Verticillium spec.

2. 3. Active products with unknown or non-specific activity mechanisms

23.1 Gassing agents, for example

Aluminum phosphide, methyl bromide, sulfuryl fluoride

23.2 Selective intake inhibitors, for example

Cryolite, Flonicamid, Pymetrozine

23.3 Mite growth inhibitors, for example

Clofentezine, Etoxazole, Hexythiazox

23.4 Amidoflumet, Benclothiaz, Benzoximate, Bifenazate,

Buprofezin, Chinométhionat,

Chlorobenzilate, Chloropicrin,

Cycloprene, Dicyclanil, Fenoxacrim,

Flufenerim, Flutenzin,

Bromopropylate,

Chl or tell me f orín,

Clothiazoben,

Fentrifanil,

Flubenzimine,

Gossyplure, Hydramethylnone, Japonilure, Metoxadiazone,

Petroleum, Piperonyl Butoxide, Potassium Oleate, Pyridalyl, Sulfluramid, Tetradifon, Tetrasul,

Triarathene, Verbutin, plus (lR-cis) - [5- (phenylmethyl) -3furanyl] -methyl-3 - [(dihydro-2-oxo-3 (2H) -furanylidene) -methyl] 2,2-dimethyl cyclopropanecarboxylate (3-Phenoxyphenyl) -methyl-2,2,3,3- cyclopropanecarboxylate.

tetramethyl

1 - [(2-chloro-5-thiazolyl) methyl] tetrahydro-3,5-dimethyl-N-nitro1,3,5-triazin-2 (1H) -imine

2- (2-chloro-6-fluorophenyl) -4- [4- (1,1-dimethylethyl) phenyl] -4,5dihydro-oxazole

2- (acetyloxy) -3-dodecyl-l, 4-naphthalindione

2-chloro-N - [[[4— (1-phenylethoxy) -phenyl] -amino] -carbonyl] benzamide

2-chloro-N - [[[4- (2,2-dichloro-l, 1-difluoroethoxy) -phenyl] -amino] carbonyl] -benzamide 3-methylphenyl propylcarbamate 25 4- [4- (4-ethoxyphenyl) -4-methylpentyl] -l-fluoro-2-phenoxy-benzene

4-chloro-2- (1,1-dimethylethyl) -5 - [[2- (2,6-dimethyl-4phenoxyphenoxy) ethyl] uncle] -3 (2H) -pyridazinone 4-chloro-2- (2-chloro -2-methylpropyl) -5 - [(6-iodo-3pyridinyl) methoxy] -3 (2H) -pyridazinone

4-chloro-5 - [(6-chloro-3-pyridinyl) methoxy] -2- (3,4-dichlorophenyl) 3 (2H) -pyridazinone

Bacillus thuringiensis strain EG-2348 [2,2-dimethyl-3- (2,4-dichlorophenyl) -2-oxo-l10 oxaspiro benzoic acid-2-benzoyl-l- (1,1-dimethyl) -hydrazide 4.5] dec-3-en-4-yl [3 - [(6-chloro-3-pyridinyl) methyl] -2-thiazolidinyliden] -cyanide dihydro-2- (nitromethylene) -2H-1,3-thiazine-3 (4H) -carboxaldehyde [2- [[1,6-dihydro-6-oxo-l- (phenylmethyl) -4pyridazinyl] oxy] ethyl] -ethyl carbamate

W- (3,4,4-trifluoro-l-oxo-3-butenyl) -glycine

N- (4-chlorophenyl) -3- [4- (difluoromethoxy) phenyl] -4,5-dihydro-4phenyl-lH-pyrazole-l-carboxamide

N-methyl-N '- (1-methyl -2-propenyl) -1,2-hydrazindicarbothioamide N-me ti1-N'-2-propeni1-1,2-hydra z indi carbo ti oami da [2- (dipropylamino ) -2-oxoethyl] -ethyl phosphorous amidothioate of 0.0 diethyl.

A mixture with other known active compounds, such as herbicides or with fertilizers and growth regulators, is also possible.

The combinations of the active compounds according to the invention can also be presented, when used as insecticides, in their usual commercial formulations as well as in the application forms prepared from these formulations in mixture with synergists. Synergists are compounds by which the effect of the active product is increased, without the added synergist having to be active in itself.

The active ingredient content of the application forms, prepared from the usual commercial formulations, can vary within wide limits. The concentration of the active ingredient in the application forms can be from 0.0000001 to 95% by weight of the active ingredient, preferably between 0.0001 and 1% by weight.

The application is carried out in a usual way adapted to the application forms.

When used against hygiene pests and stored products, the active product is characterized by an excellent residual effect on wood and clay as well as good alkali stability on whitewashed supports.

The combinations of the active ingredients according to the invention are not only active against pests of plants, hygiene and stored products, but also in the field of veterinary medicine against animal parasites (ectoparasites). such as hard ticks, soft ticks, scabies mites, migratory mites, '36 flies (suckers and mincers), parasitic fly larvae, lice, hair nits, nits of feathers and fleas. To these parasites belong:

From the order of the Anoplurida, for example, Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp.,

Solenopotes spp.

From the order of the Mallofagida and the suborders of the Amblycerina as well as the Tschnocerina, for example

<td colspan="4">Trimenopon spp., Menopon spp., Trinoton spp.</td><td colspan="2">. , Bovicola spp.,</td>

<td colspan="2">Werneckiella spp.,</td><td>Lepikentron</td><td>spp.,</td><td>Damalin</td><td>spp.,</td>

<td>Trichodectes spp</td><td colspan="2">., Felicola spp.</td><td></td><td></td><td></td>

<td>Of order</td><td>of</td><td>the Diptera</td><td>and of</td><td colspan="2">the suborders</td>

<td>Nematocerin well</td><td>how</td><td>brachycerins,</td><td colspan="2">for example Aedes</td><td>spp.,</td>

<td>Anopheles spp. ,</td><td>Culex</td><td>spp., Simulium</td><td> spp.,</td><td>Eusimulium</td><td>spp.,</td>

Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp., Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp. ., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp., Melophagus spp.

From the order of the Siphonapterida, for example Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp.

From the order of the Heteropterida, for example Cimex spp.,

Triatoma spp., Rhodnius spp., Panstrongylus spp.

From the order of the Blattarida, for example Blatta orientalis, Periplaneta americana, Blatella germanica,

Supella spp.

From the subclasses of the Acari (Acariña) and the order of the Meta- as well as Mesoestigmata, for example Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp., Amblyomma spp., Boophilus spp., Dermacentor spp., Haemaphysalis spp., Hyalomma spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp., Pneumonyssus spp., Sternostoma spp., Varroa spp.

From the order of the Actinedida (Prostigmata) and Acaridida (Astigmata), for example Acarapis spp., Cheyletiella spp., Ornithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp. ., Tyrophagus spp., Caloglyphus spp., Hypodectes spp.,

Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp.

The combinations of the active compounds according to the invention are also suitable for the fight against arthropods, which attack animals useful in agriculture such as, for example, cows, lambs, goats, horses, pigs, donkeys, camels, buffaloes. , rabbits, chickens, turkeys, ducks, geese, bees, other domestic animals such as, for example, dogs, cats, house birds, aquarium fish as well as so-called test animals, such as, for example, hamster, guinea pigs, rats and mice. By fighting these arthropods, cases of death and performance reductions (in the case of meat, milk, wool, skins, eggs, honey, etc.) will be avoided, so that, by using the active products in accordance with the invention makes possible a more economic and simple maintenance of the animals.

The application of the active compound combinations according to the invention is carried out in the veterinary field in a known manner by enteral administration in the form of, for example, tablets, capsules, beverages, dragees, granules, pastes , pen, by means of the feed-through procedure, of suppositories, by parenteral administration, such as, for example, by injection (intramuscular, subcutaneous, intravenous, intraperitoneal and the like), implants, by nasal application, by application through the skin in the form, for example, of immersion or bath (Dippen), aerosol (Spray), superficial watering (Pour-on and Spot-on), for washing, dusting as well as with the help of molded bodies containing the active product such as collars, ear marks, tail marks, limb bands, halters, marking devices, etc.

When they are used for domestic livestock, poultry, domestic animals etc. The active ingredients can be used as formulations (for example powders, emulsions, spreading agents), containing the active ingredients in amounts of from 1 to 80% by weight, directly or after dilution of 100 to 10,000 times or they can be used by way of chemical bath.

Furthermore, it has been found that the combinations of the active compounds according to the invention show a high insecticidal effect against insects that destroy industrial materials.

By way of example and preference - however without limitation - the following insects may be mentioned: beetles, such as

Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus, Troctus, Lyctus planicollis, Lyctus linearis, Lyctus linearis, Lyctus pubis. spec., Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec.,

Dinoderus minutus.

Hymenoptera, such as

Sirex juvencus, Urocerus gigas, Urocerus gigas taignus,

Urocerus augur.

Termites, such as

Kalotermes flavicollis, Cryptotermes brevis, Heterotermes flavipes, lucifugus, nevadensis,

Crosswords

Reticulitermes

Zootermopsis

Reticulitermes

Mastotermes

Coptotermes indicated it, santonensis, darwini in sis, formosanus.

Thyssuros, such as Lepisma saccharina.

Industrial materials in the present context are understood to be non-living materials, such as preferably synthetic materials, glues, glues, paper and cardboard, leather, wood and woodworking products and paints.

<td>Of a</td><td>way</td><td>very</td><td>special,</td><td>the</td><td>materials</td><td>To be</td>

<td>protected</td><td>against</td><td>he</td><td>attack of</td><td>the</td><td>insects</td><td>is it so</td>

<td>constituted</td><td colspan="2">for wood</td><td>and products</td><td>of</td><td>elaboration</td><td>of the</td>

wood.

For wood and woodworking products, which can be protected by means of the agents according to the invention or of the mixtures containing them, it should be understood, for example:

Construction Timber, Timber Beams, Rail Sleepers, Bridge Parts, Boat Ribs, Timber Vehicles, Boxes, Pallets, Containers, Telephone Poles, Timber Siding, Timber Windows and Doors, Timber Plywood, Plates plywood, carpentry or wood products, which find application, in a very general way, in the home or in the construction industry.

The combinations of the active compounds can be used as such, in the form of concentrates or of formulations usual in general such as powders, granules, solutions, suspensions, emulsions or pastes.

Said formulations can be prepared in a manner known per se, for example by mixing the active ingredients with at least one solvent or diluent, emulsifier, dispersant and / or binder or fixing agent, water repellent, optionally drying agents and stabilizers. against UV and, if necessary, colorants and pigments as well as other processing aids.

The insecticidal agents or concentrates to be used for the protection of wood and wood materials contain the active product according to the invention in a concentration of 0.0001 to 95% by weight, especially 0.001 to 60% in weight.

The amounts of the agents or concentrates used depend on the type and origin of the insects and the environment. The optimum application amounts can be determined respectively by means of pre-application test series. In general, however, it is sufficient to use from 0.0001 to 20% by weight, preferably from 0.001 to 10% by weight of the active compound, based on the material to be protected.

As solvent and / or diluent serves an organochemical solvent or mixture of solvents and / or an organochemical, oleaginous or oleaginous type solvent or mixture of solvents, hardly volatile and / or a polar organochemical solvent or mixture of solvents and / or water and, if appropriate, an emulsifier and / or humectant.

The organochemical solvents used are preferably oleaginous or oleaginous type solvents, with an evaporation index above 35 and a flash point above 30^toC, preferably located above 45 ²C. As such hardly volatile, water-insoluble, oleaginous or oleaginous type solvents, corresponding mineral oils or their aromatic fractions or mixtures of solvents containing mineral oils, preferably test benzene, petroleum and / or alkylbenzene, will be used.

Advantageously mineral oils with a boiling range of 170 to 220 will be used²C, benzine for tests with a boiling range of 170 to 220^toC, screw oil with a boiling range of 250 to 350 ° C, petroleum or aromatic hydrocarbons with a boiling range of 160 to 280 ° C_z. terpentine oil and the like.

In a preferred embodiment, 5 liquid aliphatic hydrocarbons with a boiling range of 180 to 210 will be used^SC or high boiling point mixture of aromatic and aliphatic hydrocarbons with a boiling range of 180 to 220^toC and / or spindle oil and / or monochloronaphthalene, preferably a10 monochloronaphthalene.

Organic solvents, hardly volatile, oleaginous or of an oleaginous type, with an evaporation rate above 35 and with a flash point above 30^andC, preferably above

45 ²C, they can be partially replaced by light organochemical solvents or with medium volatility; provided that the solvent mixture has an evaporation rate above 35 and a flash point above 30^sC, preferably above

45²C, and that the insecticide-fungicide mixture is soluble or emulsifiable in this solvent mixture.

According to a preferred embodiment, a part of the organochemical solvent or solvent mixture or a polar aliphatic organochemical solvent solvent or mixture will be substituted. Aliphatic organochemical solvents containing hydroxyl and / or ester and / or ether groups are preferably used, such as, for example, glycol ether, esters, or the like.

Synthetic resins and / or setting drying oils, known per se, water-dilutable and / or soluble or dispersible or emulsifiable in the organo-chemical solvents used, will be used as organochemical binders within the scope of the present invention. , especially binders consisting of or containing acrylic resin, a vinyl resin, for example polyvinyl acetate, polyester resin, polycondensation or polyaddition resin, polyurethane resin, alkyd resin or modified alkyd resin, phenolic resin, hydrocarbon resin such as indeno-coumarone resin, silicone resin, vegetable drying oils and / or drying agents and / or physical drying binders based on a natural and / or synthetic resin.

The synthetic resin used as a binder can be used in the form of an emulsion, dispersion or solution.

Bitumen or bituminous substances of up to 10% by weight can also be used as binders. In addition, colorants, pigments, water repellents, odor correctors, and inhibitors or corrosion protection agents known per se, and the like can be used.

It is preferred to use, in the medium or in the concentrate, according to the invention, as an organochemical binder at least one alkyd resin or a modified alkyd resin and / or a drying vegetable oil.

Alkyd resins with an oil content greater than 45% by weight, preferably from 50 to 68% by weight, are preferably used in accordance with the invention.

The aforementioned binder can be partially or totally replaced by a fixing agent (mixture) or by a plasticizer (mixture). These additives must avoid volatilization of the active products as well as crystallization or precipitation. They preferably substitute 0.01 to 30% of the binder (based on 100% of the binder used).

Plasticizers are of the chemical class of italic acid esters such as dibutyl, dioctyl or benzylbutyl phthalate, phosphoric acid esters such as tributyl phosphate, adipic acid esters, such as di- ( 2-ethylhexyl), stearates such as butyl stearate or amyl stearate, oleates such as butyl oleate, high molecular weight glycerin ethers or glycol ethers, glycerin esters as well as p-toluenesulfonic acid esters.

Fixing agents are chemically based on polyvinyl alkyl ethers such as polyvinyl methyl ether or ketones such as benzophenone, ethylenebenzophenone.

Especially suitable as solvent or diluent are water, optionally in admixture with one or more of the aforementioned solvents or diluents, emulsifiers and organochemical dispersants .

Especially effective protection of wood is achieved by impregnation procedures on an industrial scale, for example vacuum, double vacuum or pressure procedures.

The agents ready for application may additionally contain other insecticides and additionally one or more fungicides.

At the same time the active compound combinations according to the invention can be used for the protection against the proliferation of organisms on objects, especially of the bodies of ships, sieves, nets, constructions, port facilities and signaling facilities, which come into contact with sea ​​water or brackish water.

The proliferation of organisms caused by sessile Oligochaeten, such as calcareous tubulánidos as well as by bivalves and types of the ledamorfos group (limpets), such as various types of Lepas and Scalpellum, or due to types of the balanomorphic groups (acorn), such as Balanus or Pollicipes species, increases the resistance to friction of ships and leads, as a consequence, due to higher energy consumption and, in addition, to frequent stays in dry dock, to a notable increase in operating costs.

In addition to the proliferation caused by algae, for example Ectocarpus sp. and Ceramium sp., has a special meaning, in particular, the proliferation due to sessile groups of entomostráceos, that are grouped under the name of Cirripedia (cirripedos).

It has now surprisingly been found that the active compound combinations according to the invention have an excellent antifouling effect (antiproliferation of organisms).

By using the active compound combinations according to the invention, the use of heavy metals such as, for example, bis (trialkyltin) sulfides, tri-n-butyltin laurate, tri-n-butyltin chloride can be abandoned. , cuprous oxide (I), triethyltin chloride, tri-n-butyl (2-phenyl-4-chlorophenoxy) -tin, tributyltin oxide, molybdenum disulfide, antimony oxide, polymer butyl titanate, phenyl (bispyridin) chloride - bismuth, Tri-n-Butyltin Fluoride, Manganese Ethylene Bistiocarbamate, Zinc Dimethyldithiocarbamate, Zinc Ethylene Bistiocarbamate, Zinc and Copper Salts of 2-Pyridynthiol-l-Oxide, EthyleneBisthiocarbamoylzinc, Zinc Oxide, Ethanol copper, copper naphthenate and tributyltin halides or the concentration of these compounds can be decisively reduced.

The antifouling paints ready for application may, if appropriate, also contain other active products, preferably algaecides, fungicides, herbicides, molluscicides or other antifouling active products.

Suitable components of the combination for the antifouling agents according to the invention are:

algicides such as

2-tert.-butylamino-4-cyclopropylamino-6-methylthio-l, 3,515 triazine, Dichlorophen, Diuron, Endothal, Fentinacetat,

Isopruton, Methabenzthiazuron, Oxyfluorfen, Quinoclamine and

Terbutryn;

fungicides such as cyclohexylamide-S, benzo [b] thiophenecarboxylic acid S-dioxide, Dichlofluanid, Fluorfolpet, 3iodo-2-propinyl-butylcarbamate, Tolylfluanid and azoles such as

Azaconazole, Cyproconazole, Epoxyconazole, Hexaconazole, Metconazole, Propiconazole, and Tebucanazole;

molluscicides such as complex formers with Fe, Fentinacetat, Metaldehyd, Methiocarb, Niclosamid, Thiodicarb and Trimethacarb; or traditional antifouling products, such as

4,5-dichloro ~ 2-octyl-4-isothiazolin-3-one, diiodomethylparatrylsulfone, 2- (N, N-dimethylthiocarbamoylthio) -5nitrothiazyl, potassium, copper, sodium and zinc salts of 2-pyridynthiol-l -oxide, pyridin-triphenylborane, tetrabutyldiestannoxane, 2,3,5,6-tetrachloro-4 (methylsulfonyl) -pyridine, 2,4,5,6-tetrachloroisophthalonitrile, tetramethylthiuram disulfide and 2,4,6trichlorophenylmaleinimide.

The antifouling agents used contain the active compound in a concentration from 0.001 to 50% by weight, especially from 0.01 to 20% by weight.

Antifouling agents further contain customary components such as for example those described in Ungerer, Chem. Ind. 1985, 37, 730-732 and Williams, Antifouling Marine Coatings, Noyes, Park Ridge, 1973.

Antifouling paints contain, in addition to the active ingredients, algaecides, fungicides, molluscicides and insecticides, especially binders.

Examples of recognized binders are polyvinyl chloride in a solvent system, chlorinated rubber in a solvent system, acrylic resins in a solvent system especially in an aqueous system, vinyl chloride / vinyl acetate copolymer system in the form of aqueous dispersions or in form of organic solvent systems, butadiene / styrene / acrylonitrile rubbers, desiccant oils, such as linseed oil ', resin esters or modified hard resins in combination with tar or bitumen, asphalt, as well as epoxy compounds, small amounts of chlorinated rubber, chlorinated polypropylene and vinyl resins.

If appropriate, the paints also contain inorganic pigments, organic pigments or dyes, which are preferably insoluble in sea water. Furthermore, the paints may contain materials such as rosin to enable a controlled release of the active products. The paints may also contain plasticizers, modifying agents that influence rheological properties, as well as traditional components. Also in self-polishing antifouling systems, the active compound combinations according to the invention can be incorporated.

The active compound combinations according to the invention are also suitable for the fight against animal pests, especially against insects, arachnids and mites, which occur in closed areas, such as, for example, houses, factories, offices, cabins of motor vehicles and the like. They can be used to fight these pests alone or in combination with other active and auxiliary products in household insecticide products. They are active against sensitive and resistant types as well as against all stages of development. To these pests belong:

From the order of the Scorpionidea, for example, Buthus occitanus.

From the order of the Acariña, for example, Argas persicus, Argas reflexus, Bryobia ssp._z Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermathophagoides forinae.

From the order of the Araneae, for example, Aviculariidae,

Araneidae.

From the order of the Opiliones, for example, Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium.

From the order of the Isopoda, for example Oniscus asellus,

Porcellio scaber.

From the order of the Diplopoda, for example, Blaniulus guttalatus, Polydesmus spp.

From the order of the Chilopoda, for example, Geophilus spp.

From the order of the Zygentoma, for example, Ctenolepisma spp., Lepisma sacharina, Lepismodes inquilinus.

From the order of the Blattaria for example Blatta orientalies, Germanic Blattella, Blattella asahinai,

Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa.

From the order of the Saltatoria, for example, Acheta domesticus.

From the order of the Dermaptera, for example, Forfícula auricularia.

From the order of the Isoptera, for example, Kalotermes spp.,

Reticitermes spp.

From the order of the Psocoptera, for example, Lipinatus spp.,

Liposcelis spp.

From the order of the Coleptera, for example, Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum.

From the order of the Diptera, for example, Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp.,

Calliphora erythrocephala, Chrysozona pluvialis, Cules quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria, Simulium spp., Stomoxys calcitrans, Typula padosa.

From the order of the Lepidoptera, for example, Achroia grisella, Gallería mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionalla, Tineola bisselliella.

From the order of the Siphonaptera, for example, Ctenocephalides canis, Ctenocephalides felis, Pulex irritans,

Tunga penetrans, Xenopsylla cheopis.

From the order of the Hymenoptera, for example, Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum.

From the order of the Anoplura, for example, Pediculus humanus capitis, pediculus humanus corporis, Phthirus pubis.

From the order of the Heteroptera, for example, Cimex hemipterus, Cimex lactularius, Rhodinus prolixus, Triatoma infestans.

Application in the domestic insecticide sector can be carried out in combination with other suitable active products such as phosphoric acid esters, carbamates, pyrethroids, growth regulators or active products from other known classes of insecticides.

The application is carried out in aerosols, spraying agents without pressure, for example pump sprays or sprays, automatic nebulizing devices, mist generators, foams, gels, products for evaporators with evaporation plates of cellulose or synthetic material, evaporators for liquids, gel or membrane evaporators, propeller-driven evaporators, passive or non-energy evaporation systems, mothproofing papers, Anti-moth sachets and anti-moth gels made of granules or powders, in spreadable baits or baited stations.

When the combinations of the active compounds are used, according to the invention, the application amounts can vary within wide limits according to the type of application. When treating parts of plants, the application amounts of the active compounds are generally comprised between 0.1 and 10,000 g / ha, preferably between 10 and 1,000 g / ha.

The good insecticidal effect of the active compound combinations according to the invention is apparent from the following examples. While individually active products fail in their effect, combinations show an effect that goes beyond the simple sum of the effects.

The expected effect for a given combination of two compounds can be calculated as follows (see COLBY, SR: Calculating Synergistic and Antagonistic Response of Herbicide Combinations; Weeds 15, pages 20-22,

1967);

yes

X = the degree of destruction, expressed in% of the untreated controls, when active compound A is used with an application amount of m ppm,

Y = the degree of destruction, expressed in% of the untreated controls, when active agent B is used with an application amount of n ppm,

E = the degree of destruction, expressed in% of the untreated controls, when the active products A and B are used with an application amount of m and n ppm, then

E = X + YXxY

100

If the actual degree of insecticidal destruction is greater than that calculated, then the combination will be super-additive, that is, it will have a synergistic effect. In this case, the degree of destruction actually observed must be greater than the value calculated from the formula previously indicated for the degree of destruction expected (E).

Example A

Myzus persicae trial

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 2 Parts by weight of alkylaryl polyglycol ether

To obtain a suitable preparation of active compound, 1 part by weight of the active compound is mixed with the indicated amounts of solvent and emulsifier and the concentrate is diluted with water, containing emulsifier, to the desired concentration.

Cabbage leaves (Brassica olerácea), which are strongly attacked by the green peach aphid (Myzus persicae), are treated by immersion in the preparation of the active compound of the desired concentration.

After the desired time, the destruction is determined in%. In this case 100% means that all aphids have been destroyed; 0% means that no aphids have been destroyed. The determined destruction values ​​are calculated according to the Colby formula.

In this test it showed the following combination of active ingredients, in accordance with the present invention, a synergistically enhanced activity compared to the individually applied active ingredients:

Table A

Insects harmful to plants

Myzus persicae trial

Active products Concentration Destruction in ppm in% after 6 ^

Thiodicarb

Thiamethoxam

0,8

Thiodicarb + Thiamethoxam (25: 1) according to the invention gef. * ber. ** + 0.8 95 85 * gef. = activity found ** ber. = activity calculated with Colby's formula

Table A

Insects harmful to plants

Myzus persicae trial

Active products · Destruction concentration in ppm in% after 6 ^

<td>Thiodicarb</td><td> 20</td><td> 0</td>

<td>Thiacloprid</td><td> 0,8</td><td> 30</td>

<td>Thiodicarb + Thiacloprid (25</td><td> : 1)</td><td></td>

<td>according to the invention</td><td></td><td>gef. *</td>

<td>ber. **</td><td> 20 + 0,8</td><td> 50 30</td>

<td>* gef. = found activity</td><td></td><td></td>

** ber. = activity calculated with Colby's formula

Example B

Phaedon cochleariae larvae test

Solvent: 7 Parts by weight of dimethylformamide Emulsifier: 2 Parts by weight of alkylaryl polyglycol ether

To obtain a suitable preparation of active compound, 1 part by weight of the active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with water, containing emulsifier, to the desired concentration.

Cabbage leaves (Brassica olerácea) are treated by immersion in the preparation of the active compound of the desired concentration and covered with larvae of the horseradish beetle (Phaedon cochleariae), as long as the leaves are still wet.

After the desired time, the destruction is determined in%. In this case 100% means that all the beetle larvae have been destroyed; 0% means that no beetle larvae have been destroyed. The determined destruction values ​​are calculated according to the Colby formula.

In this test it showed the following combination of active ingredients, in accordance with the present invention, a synergistically enhanced activity compared to the individually applied active ingredients:

Table B

Insects harmful to plants

Phaedon cochleariae larvae test

Active products Concentration Destruction in ppm in% after 6 ^

<td>Thiodicarb</td><td> 100</td><td> 15</td>

<td>Clothianidin</td><td> 4</td><td> 75</td>

<td>Thiodicarb + Clothianidin</td><td>(25 s 1)</td><td></td>

<td>according to the invention</td><td></td><td>gef. *</td>

<td>ber. **</td><td> 100 + 4</td><td> 100 79,75</td>

* gef. = activity found ** ber. = activity calculated with Colby's formula

Table Β

Insects harmful to plants

Phaedon cochleariae larvae test

Active products Concentration Destruction in ppm in% after 6 ^

<td>Thiodicarb</td><td> 100</td><td> 45</td>

<td>Imidacloprid</td><td> 4</td><td> 45</td>

<td>Thiodicarb + Imidacloprid</td><td> (25 : 1)</td><td> -</td>

<td>according to the invention</td><td></td><td>gef. *</td>

<td>ber. **</td><td> 100 + 4</td><td> 80 69,75</td>

* gef. = activity found ** ber. = activity calculated with Colby's formula

Table B

Insects harmful to plants

Phaedon cochleariae larvae test

Active products Concentration Destruction in ppm in% after 6 ^

<td>Thiodicarb</td><td> 100</td><td> 15</td><td></td><td></td>

<td>Thiacloprid</td><td> 4</td><td> 0</td><td></td><td></td>

<td>Thiodicarb + Thiacloprid (25</td><td> : 1)</td><td></td><td></td><td></td>

<td>according to the invention</td><td></td><td></td><td></td><td>gef. *</td>

<td>ber. **</td><td></td><td></td><td></td><td></td>

<td></td><td> 100 + 4</td><td> 65</td><td> 15</td><td></td>

* gef. = activity found ** ber. - activity calculated with Colby's formula

Table B

Insects harmful to plants

Phaedon cochleariae larvae test

Active products Concentration Destruction in ppm in% after 6 ^ ·

<td>Thiodicarb</td><td> 100</td><td> 45</td><td></td>

<td>Thiamethoxam</td><td> 4</td><td> 25</td><td></td>

<td>Thiodicarb + Thiamethoxam</td><td>(25 j 1)</td><td></td><td></td>

<td>according to the invention</td><td></td><td></td><td>gef. *</td>

<td>ber. **</td><td> 100 + 4</td><td> 85</td><td> 58,75</td>

* gef. = activity found ** ber. = activity calculated with Colby's formula

Example C

Assay with Plutella xylostella (resistant strain)

Solvent: 7 Parts by weight of dimethylformamide Emulsifier: 2 Parts by weight of alkylaryl polyglycol ether

To obtain a suitable preparation of active compound, 1 part by weight of the active compound is mixed with the indicated amounts of solvent and emulsifier and the concentrate is diluted with water, containing emulsifier, to the desired concentration.

Cabbage leaves (Brassica olerácea) are treated by immersion in the preparation of active compound of the desired concentration, and covered with caterpillars of the cabbage moth (Plutella xylostella, resistant strain) as long as the leaves are still wet.

After the desired time, the destruction is determined in%. In this case 100% means that all the tracks have been destroyed; 0% means that none of the tracks have been destroyed. The determined destruction values ​​are calculated according to the Colby formula.

In this test it showed the following combination of active ingredients, in accordance with the present invention, a synergistically enhanced activity compared to the individually applied active ingredients:

Table D

Insects harmful to plants

Assay with Plutella xylostella (resistant strain)

Active products Concentration Destruction in ppm in% after 6 ^ ·

<td>Thiodicarb</td><td> 100</td><td> 15</td>

<td>Thiacloprid</td><td> 100</td><td> 45</td>

<td>Thiodicarb + Thiacloprid (1</td><td> : 1)</td><td></td>

<td>according to the invention</td><td></td><td>gef. *</td>

<td>ber. * *</td><td> 100 + 100</td><td> 90 53,25</td>

* gef. = activity found ** ber. = activity calculated with Colby's formula

Table D

Insects harmful to plants

Assay with Plutella xylostella (resistant strain)

Active products Concentration Destruction in ppm in% after 6 ^

<td>Thiodicarb 100</td><td> 5</td><td></td>

<td>Thiamethoxam 100</td><td> 75</td><td></td>

<td>Thiodicarb + Thiamethoxam (1: 1)</td><td></td><td></td>

<td>according to the invention</td><td></td><td>gef. *</td>

<td>ber. **</td><td></td><td></td>

<td> 100 + 100</td><td> 95</td><td> 76,25</td>

* gef. = activity found ** ber. = activity calculated with Colby's formula

It is noted that, in relation to this date, the best method known by the applicant to put the aforementioned invention into practice, is the one that is clear from the present description of the invention.