Compositions and methods for improving performance of long-wearing comsetic products

Composition and method for improving the performance of durable cosmetics

Technical field

The present invention relates to a type of composition and a method for using the composition to improve the performance of durable cosmetics. Such compositions and methods of using such compositions enable users to significantly enhance the performance of durable cosmetics without compromising their main advantages.

Background technique

Compositions for improving cosmetics are known in the art. Such compositions include those that are applied to a composition such as lipstick to provide gloss, smoothness, and transfer resistance to the applied composition. These improved products use a variety of polymer fluids and film-forming technologies. For example, an acrylic film-forming agent introduced into the top coat of a lipstick, such as "Sealed with a Kiss" from CSI, is delivered in a volatile carrier alcohol, and it is applied to the surface of the lipstick.

The above-mentioned other side coating product is the Japanese application flat 5

Those disclosed in [1993]-221829 (filed on August 31, 1993). The top coat is believed to exhibit a long-lasting cosmetic effect, control color transfer, and have improved applicability. The top coating contains 0.2 to 25% silica powder and/or alumina powder and 75% to 99.8% perfluoropolyether of the following formula.

Wherein R1 to R5 are independent fluorine atoms, perfluoroalkyl groups or oxyperfluoroalkyl groups; the values of p, q and r are at least zero; wherein the molecular weight of perfluoropolyether is from about 500 to about 10,000, where p, q and r can be equal, but not zero. The preferred perfluoropolyethers disclosed herein are the commercially available products Fomblin HC-04, HC-25 and HC-R, purchased from Montefluosu Company in Milan, Italy.

Although such compositions can produce certain benefits, they have been found to often interfere with the main advantages of the cosmetics on which they are applied. For example, in order to improve the durability performance produced by the composition applied to the cosmetic, the gloss and sensory properties of the cosmetic product may be lost. In addition, in order to improve the gloss or sensory properties provided by such compositions, the durability of cosmetics may be lost.

SUMMARY OF THE INVENTION The present invention relates to a type of composition and a method of using the composition with cosmetics whose solubility parameter is less than or equal to 8.5 (cal/cm3) 1/2 to improve overall cosmetic-related properties. These compositions contain oils with a C log P value greater than or equal to 13.

In addition, the present invention relates to a method for improving transfer resistant flexible film-forming cosmetics, the method comprising: a. Applying a transfer-resistant flexible film-forming cosmetic, wherein the solubility parameter of the cosmetic is less than or equal to 8.5 (cal/cm3) 1/2; b. Let the cosmetics dry; and c. A second composition is applied to the cosmetic, wherein the Clog P value of the second composition is greater than or equal to 13.

BACKGROUND OF THE INVENTION When supplementing the advantages of cosmetics, the supplemental or second composition should minimize the loss of other properties of the cosmetic. The composition of the present application can be used with all types of cosmetics to provide the required additional properties. As far as lipstick products are concerned, these properties include brightness, luster, and lubricity.

Specifically in film-forming cosmetics, the second composition should be incompatible with cosmetics. Incompatibility means that the composition of the present invention contains special components that will not rupture the film formed after applying cosmetics. This is especially true for anti-transfer agents, flexible film-forming cosmetics such as lipsticks.

Lip cosmetics are well known in the art and include many different formulations to provide skin beauty and care effects. One of the advantages consumers most often look for, especially in lip cosmetics, is increased or "long-term" durability.

Some people believe that durable cosmetics are cosmetics that resist smearing to another object in contact with them; for example, to prevent the transfer of lip compositions to tableware such as cups and napkins. However, other factors found to be critical in predicting durability are the flexibility of cosmetics and their ability to resist the transfer of solvents applied to the skin, such as edible oils. This cosmetic is the subject of co-pending patent applications USSN08/732,946 and USSN08/732,948, which are titled "Metastatic Cosmetic Compositions", both of which were filed on October 17, 1996 by Drechsler and others, and are incorporated herein by reference. . This composition contains an organosiloxane resin, a liquid diorganosiloxane polymer and a volatile carrier. The film formed after the application of the cosmetic is basically transfer-resistant and flexible, and the cosmetic has surprisingly Improved durability.

The solubility parameter of the cosmetic used with the composition of the present invention is less than or equal to about 8.5 (cal/cm3) 1/2 (according to the Hildebrand scale). Generally, the solubility parameter is a function of the cohesive energy of a substance or cosmetics containing the substance. Simply put, cohesive energy is an attractive force, which depends on the electronegativity of the atoms constituting the molecule, and serves as the basis for some properties such as viscosity, adhesion, blending and even boiling point. Some substances, such as water, have high cohesive energy, and some substances, such as oil, have low cohesive energy. Highly cohesive components are "polar", while less cohesive components are oily or "non-polar". Hildeband developed a method for estimating solubility parameters based on the boiling point, molecular weight and specific gravity of substances; see JHHidebrand, JMPrausnitz and RLScotts Regular and Related Solutions, New York; Van Nostrand Reinholdt (1950), hereby incorporated by reference. The Hildebrand solubility parameters of many cosmetics and pharmaceutical substances have been published, see Cosmetic BenchReference, Carol Stream IL, Allured Publishing (1992), and AFBartons Handbook of Solubility Parameters and Other Cohesion Parameters, 2nd edition, Boca Raton; CRC Press (1992); both documents are incorporated by reference.

The C log P value of the oil in the composition determines whether the composition of the present invention is sufficiently incompatible with cosmetics to improve the performance of the cosmetics. The P value is the octanol/water partition coefficient of the oil constituting the composition. The coefficient is the ratio of the equilibrium concentration of the composition in octanol and water. Due to the high value of the octanol/water partition coefficient, for more convenience, the form of log value with base 10 as the number is adopted, namely logP.

The above logp value is calculated using the "ClogP" program of Daylight CIS. The calculated logP is based on the fragment method of Hansch and Leo (see A. Leo's Comprehensive Medicinal Chemistry, Volume 4, edited by C. Hansch, PGSammens, JBTaylor and CARansden, page 295, Pergamon Press, 1990); For reference. The fragment method is based on the chemical structure of each oil component, and considers the number and type of atoms, atomic conductivity, and chemical bonding. The ClogP value is the most reliable and widely used method to evaluate the physicochemical properties.

The composition of the present invention contains oils that can exist in solid to liquid forms. Regardless of its form, the composition of the present invention contains at least one oil in which the total ClogP value of all non-solid molecules is approximately the same as the value of the oil. The ClogP value of the oil in the composition is greater than or equal to 13, preferably greater than or equal to 17, and most preferably greater than or equal to 20. The oil used in the present invention is selected from polyol fatty acid polyesters, triglycerides, liquid synthetic polymers and mixtures thereof.

Polyol fatty acid polyester Polyol fatty acid polyester is a fatty acid polyester derived from any aliphatic or aromatic polyol, the polyol has at least 4 free hydroxyl groups, and at least 80% of these hydroxyl groups have 8 22 carbon atoms One or more fatty acids are esterified.

The polyol from which the polyol fatty acid polyester is derived is preferably from sugar polyols, including mono-, di- and polysaccharides. Preferred examples of monosaccharide sugar polyols are: pentose polyols such as D-ribose, D-arabinose, D-xylose, D-lyxose, D-ribulose and D-xylulose; hexose Polyols, such as D-allose, D-altrose, D-glucose, D-mannose, D-gulose, D-idose, D-galactose, D-talose, D- Fructose, D-sorbose and D-tagatose; heptose polyols, such as D-mannoheptulose and D-sedum heptulose; polyols derived from polyol fatty acid polyesters can also be selected from disaccharides , Such as maltose, lactose, cellobiose, sucrose, trehalose, gentiobiose, melibiose and primrose.

The polyol derived from the polyol fatty acid polyester may also be selected from trisaccharides such as gentiotriose and raffinose.

The polyol from which the polyol fatty acid polyester is derived can also be selected from sugar alcohols such as D-mannitol, D-sorbitol, D-ribitol, D-erithritol, D-lactitol and D-xylitol.

The polyol from which the polyol fatty acid polyester is derived can also be selected from sugars such as methyl glycosides and inositol. The preferred sugar polyol is sucrose. Sucrose polyol fatty acid esters or SPES are disclosed in the priority documents cited in the specification and are derived from sucrose and vegetable oils. This has been widely disclosed in patent documents related to non-digestible oils, such as but not limited to US3600186 issued on August 17, 1971, 4005195 issued on January 25, 1977, and 4005196 issued on January 25, 1977. , These patents have been assigned to Procter & Gamble and are hereby incorporated for reference.

The fatty acid used to form the polyol fatty acid polyester may be a single C8-C24, preferably C16-C22 free fatty acid. These fatty acids can be saturated or unsaturated, linear or branched.

Fats and oils The fats and oils used in the present invention are triacylglycerides or triglycerides formed by the esterification reaction of fatty acids with glycerol and glycerol. Although the difference between fat and oil is uncertain, fat is generally considered to be solid or plastic at room temperature, while oil is liquid under the same conditions. The fatty acids that are subsequently esterified to form triglyceride fats or oils are most commonly derived from marine, animal, and plant sources. For more details on triglyceride oil, its source and processing, please refer to Bailey's "Industrial Oil and Fat Products", published by Interscience Publications, which is incorporated by reference.

At least 90% of the ester substituents on the triglyceride backbone have a carbon chain length of at least 12. Usually the oil is hydrogenated to a certain degree to suppress odors. Such triglycerides include oils of vegetable origin, such as soybean oil, castor oil, olive oil, sunflower oil, almond oil, peanut oil, canola oil, corn oil, other similar vegetable oils and mixtures thereof. Synthetic polymer oil Synthetic polymer oil is useful in the present invention. The synthetic polymer oil is liquid at room temperature and includes glycerol/diethylene glycol/adipate crosspolymer, which is Lexorez 100 purchased from Inolex Chemical Company.

Optional components There are many other ingredients that can be used in cosmetics that can be used in the composition of the present invention. These ingredients are allowed to be used in cosmetics and can be found in reference books, such as "CTFA Cosmetic Ingredients Manual", 2nd edition, Association of Cosmetics, Toiletries and Fragrances, Inc, 1998, 1992. The substances can be used as long as their addition does not significantly damage the composition, and once the composition is applied, it becomes thin. The ingredients include waxes, fragrances, seasoning oils, skin care ingredients, such as sunscreens, emulsifiers and the like. The composition of the present invention can also be made into a hypoallergenic composition, wherein the composition does not contain fragrance, flavor oil, lanolin, sunscreen, especially PABA, or other sensitizers and irritants. The addition of other components should not reduce the overall CLogP value of the oil in the composition to less than 13.

As mentioned above, oil is an important ingredient of the present invention. In addition to oil, it can also contain other raw materials to give the product the form required by consumers. These forms are liquid, paste and solid. In terms of solid form, the composition of the present invention contains a sufficient amount of raw material to form a stable rod. These raw materials here refer to solid molding agents. The use content of the solid forming agent is preferably from about 0.5% to about 35.0% of the composition, more preferably from about 7.0% to about 25.0%, most preferably from about 8% to about 20. 0%. The solid forming agent is selected from solid polyol fatty acid polyesters, waxes, solid oils and mixtures thereof. a. Solid polyol polyesters The solid polyol polyesters used in the present invention are polyol esters or polyesters, in which the fatty acid ester groups of the polyesters contain the following combinations: (a) Long-chain unsaturated fatty acid structural parts or long-chain unsaturated fatty acids The mixture of saturated fatty acid moieties and short-chain saturated fatty acid moieties, and (b) long-chain saturated fatty acid moieties, the ratio of (a) to (b) is from about 1:15 to about 2:1. At least about 15%, preferably at least about 30%, more preferably at least about 50%, and most preferably at least about 60% of the total fatty acid moiety of the polyester are saturated fatty acid moieties of C20 or higher. The long chain unsaturated fatty acid moiety is typically straight chain and contains at least about 12, preferably about 12 to about 22, more preferably about 18 to about 22 carbon atoms. The best unsaturated fatty acids are C18 mono- and/or di-unsaturated fatty acids. Short chain saturated fatty acids are typically unbranched and contain about 2 to about 12, preferably about 6 to about 12, and most preferably about 8 to about 12 carbon atoms. Long chain saturated fatty acids are typically straight chain and contain at least about 20, preferably about 20 to about 22, and most preferably about 22 carbon atoms. The molar ratio of the (a) group fatty acid moiety to the (b) group fatty acid moiety in the polyester molecule is from about 1:15 to about 2:1, preferably from about 1:7 to about 5:3, more preferably From about 1:7 to about 3:5. These fatty acid esters have an average degree of esterification of at least about 60% of the hydroxyl groups of the polyols are esterified. For sucrose polyesters, preferably about 7 to about 8 polyol hydroxyl groups are esterified. Generally, substantially all, such as at least about 85%, preferably at least about 95%, of the polyol hydroxyl groups are esterified. The preferred polyols of solid polyol fatty acid esters are sugars. The sugars are selected from monosaccharides, disaccharides and trisaccharides, containing from about 4 to about 11, preferably from about 4 to about 8, and most preferably from about 6 To about 8 hydroxyl groups. Examples of four hydroxyl groups are the monosaccharides xylose, arabinose and combinations thereof. Suitable polyols containing five hydroxyl groups are monosaccharides galactose, fructose, mannose, glucose and combinations thereof. Examples of disaccharide polyols that can be used include maltose, lactose, sucrose, and combinations thereof, all of which contain eight hydroxyl groups. The preferred polyol is sucrose.

Examples of long-chain unsaturated fatty acid moieties include, but are not limited to, lauric acid ester, myristyl acid ester, palmitoleic acid ester, oleic acid ester, elaidic acid ester, erucic acid ester, linoleic acid ester, and linolenic acid Esters, arachidonic acid esters, eicosapentaenoic acid esters and docosahexaenoic acid esters. For oxidative stability, mono- or di-unsaturated fatty acid moieties are the best.

Examples of suitable short-chain saturated fatty acid moieties include, but are not limited to, acetate, caproate, caprylate, caprate, and laurate.

Examples of suitable long-chain saturated fatty acid moieties include, but are not limited to, arachidic acid, behenic acid, tetracosanoic acid, and wax acid esters.

Of course, the long-chain unsaturated fatty acid moieties can be used alone or mixed with each other or mixed with the short-chain saturated fatty acid moieties in any ratio. Likewise, the long-chain saturated fatty acid moieties can be used in combination with each other in any ratio. A mixed fatty acid moiety derived from a source oil containing a large amount of the desired unsaturated or saturated acid can be used as the acid moiety to prepare the mixture used herein. The mixed fatty acid from the source oil should contain at least about 30%, preferably at least about 50%, and most preferably at least about 80% of the desired unsaturated or saturated acid. For example, rapeseed oil fatty acids or soybean oil fatty acids can be used instead of pure C12-C16 unsaturated fatty acids. Hardened ie hydrogenated high erucic acid rapeseed oil fatty acids can be used instead of pure C20-C22 saturated acids, preferably C20 and higher acids, or derivatives thereof, such as methyl or other lower alkyl esters, which are concentrated by distillation and the like. The fatty acids of palm kernel oil or coconut oil can be used as a source of C8 to C12 acids. Examples of using the source oil to prepare the solid polyol polyesters used in the compositions herein are the use of high oleic sunflower oil and substantially fully hydrogenated The fatty acid of high erucic acid rapeseed oil is used to prepare solid sucrose polyester. After sucrose is substantially completely esterified with a mixture of fatty acid methyl esters of these two oils in a weight ratio of 1:3, the molar ratio of unsaturated C18 acid radicals to C20 and higher saturated acid radicals in the resulting sucrose polyester is about 1:1, and about 28.6% of the total fatty acid weight in the polyester is C22 fatty acid.

The higher the ratio of unsaturated and saturated acids required in the fatty acid raw material used to prepare the solid polyol polyester, the stronger the binding ability of the ester with the liquid oil described below.

Examples of solid polyol fatty acid polyesters used in the composition include, but are not limited to, raffinose octaester, in which the fatty acid moiety for esterification is linoleate and behenate in a molar ratio of 1:3 ; Maltose heptaester, wherein the fatty acid portion for esterification is sunflower oil fatty acid and tetracosanoate with a molar ratio of 3:4; sucrose octaester, wherein the fatty acid structure portion for esterification is an oil with a molar ratio of 2:6 Ester and behenate; and octaester of sucrose, wherein the fatty acid moiety for esterification is laurate, linoleate and behenate in a molar ratio of 1:3:4. The preferred raw material is sucrose polyester, wherein the degree of esterification is 7-8, the fatty acid structure part is C18 mono- and/or di-unsaturated acid and behenic acid, and the molar ratio of unsaturated acid:behenic acid is 1:7 to 3:5. A particularly preferred polyol ester is octaester of sucrose, in which there are about 7 parts of behenic fatty acid moieties and about 1 part of oleic acid moieties in the molecule.

The solid fatty acid polyesters can be prepared according to the methods for preparing polyol polyesters well known in the current state of the art. See U.S. Patent No. 5,306,516 issued to Letton et al. on April 26, 1994; U.S. Patent No. 5,306,515 issued to Letton et al. on April 26, 1994; U.S. Patent No. 5,305,514 issued to Letton et al. on April 26, 1994; 1989 U.S. Patent No. 4,797,300 issued to Jandacek et al. on January 10, 1976; U.S. Patent No. 3,963,699 issued to Rizzi et al. on June 15, 1976; U.S. Patent No. 4,518,772 issued to Volpenhein on May 21, 1985; May 21, 1985 US Patent No. 4,517,360 issued to Volpenhein in Japan; all of these are hereby incorporated by reference in their entirety. b. Wax Wax useful for the present invention is defined herein as a solid, high molecular weight organic mixture or compound at room temperature. Generally, except that wax does not contain glycerides, its composition is similar to fats and oils. Waxes include high molecular weight hydrocarbons, fatty acids, fatty acid esters, fatty alcohols and mixtures thereof. The waxes useful in the present invention are generally known waxes used in cosmetic technology. These waxes include the waxes described in U.S. Patent No. 5,599,547 issued to Bartholomey et al. on February 4, 1997, which is incorporated herein by reference.

Suitable fatty acids contain from about 10 to about 40 carbon atoms. Examples are 12-hydroxystearic acid, 12-hydroxylauric acid, 16-hydroxyhexadecanoic acid, behenic acid, erucic acid, stearic acid, caprylic acid, lauric acid, isostearic acid and mixtures thereof. Examples of other suitable fatty acids are further described in U.S. Patent No. 5,429,816 issued to Hofrichter et al. on July 4, 1995 and U.S. Patent No. 5,552,136 issued to Motley on September 3, 1996, which description is incorporated herein by reference. .

Suitable fatty alcohol waxes used herein are monohydric alcohols, ethoxylated fatty alcohols and fatty alcohol esters, excluding ethoxylated fatty alcohols and fatty alcohol esters used as emulsifiers. Specific examples of commercially available fatty alcohols include, but are not limited to Unilin550, Unilin700, Unilin425, Unilin400, Unilin350 and Unilin325, all of which are supplied by Petrolite. Suitable ethoxylated fatty alcohols include, but are not limited to Unithox325, Unithox400, Unithox450, Unithox480, Unithox520, Unithox550, Unithox720, Unithox750, all of which are supplied by Petrolite. Non-limiting examples of suitable fatty alcohol esters are triisostearyl citrate, ethylene glycol di-12-hydroxystearate, tristearyl citrate, stearyl caprylate, stearyl enanthate, Trilauryl citrate.

Suitable fatty acid ester waxes used herein include ester waxes, monoglycerides, diglycerides, triglycerides and mixtures thereof. Non-limiting examples of suitable ester waxes are stearyl stearate, stearyl behenate, palmityl stearate, stearyl octyldodecanol, cetyl ester, cetearyl behenate, behenic acid Behenyl ester, ethylene glycol distearate, ethylene glycol dipalmitate and beeswax. Examples of industrial ester waxes are Koster Keunen's Kester wax, Crodamol SS from Croda, and Rhone Poulenc's Demalcare SPS.

Other waxes used in the present invention are selected from various fractions of animal waxes, vegetable waxes, mineral waxes, natural waxes, synthetic waxes, petrolatum waxes, vinyl polymers, hydrocarbons, such as Fischer-Tropsch waxes, polysiloxanes Waxes and mixtures thereof, wherein the melting point of the wax is greater than about 30°C. The waxes used in the present invention are selected from synthetic waxes, ozokerites, cimond wood esters, "Unilins" from Petrolite, "Ganex" from ISP, alkylated polyvinylpyrrole, C22 to C50 fatty alcohols, and mixtures thereof. Synthetic waxes include those disclosed in Warth's Wax Chemistry and Technology, Part 2, Published by Reinhold Publishing Company, 1956, incorporated by reference. The waxes most suitable here have a melting point of about 30°C to about 115°C and are selected from C8 to C50 hydrocarbon waxes. These waxes include long-chain polymers of ethylene oxide combined with glycols, namely polyoxyethylene glycols. Such waxes include carbide and carbon chemical company carbowat. Other synthetic waxes include long-chain polymers of ethylene and OH or other end-capped groups. Such waxes include Fischer-Tropsch waxes, such as those disclosed on pages 465-469 of the aforementioned article, and include Rosswox available from Ross Corporation, and PT-0602 available from Astor Wax Corporation. Other synthetic waxes include alkylated polyvinylpyrrolidone or PVP, which includes tricontanyl PVP (GannexWP-660 available from ISP company) and PVP/eicosene copolymer (available from ISP company).

The specific wax used in the present invention is selected from beeswax, lanolin wax, shellac wax (animal wax), carnauba wax, candelilla wax, laurel resin (vegetable wax); natural ozokerite, pure ozokerite, (Mineral wax); paraffin wax, microcrystalline wax (petroleum wax); polyethylene, (olefin polymer); polyethylene homopolymer (Fisher-Tropsch wax); C24-45 alkyl methicone (silicone Wax); and mixtures thereof. Most preferred are beeswax, lanolin wax, carnauba wax, candelilla wax, ozokerite wax, ozokerite wax, paraffin wax, microcrystalline wax, polyethylene, C24-45 alkyl methicone and mixtures thereof. c. Solid oil The solid oil used herein is an oil having a melting point greater than about 30°C to about 250°C, preferably from about 37°C to about 100°C, more preferably from about 37°C to about 80°C. The term "solid oil" as used herein refers to any oil or oily raw material that is solid or semi-solid in the temperature range of about 20°C to about 25°C, and has a solubility in water at 25°C generally less than 1% by weight. Examples of suitable solid oils include, but are not limited to, petrolatum, polybranched hydrocarbons, fatty alcohols, fatty acid esters, vegetable oils, hydrogenated vegetable oils, polypropylene glycols, α-hydroxy fatty acids, and those containing from about 10 to about 40 carbon atoms Fatty acids, alkyl amides of di- and/or tricarboxylic acids, ortho-amino acid derivatives and mixtures thereof. The solid oil useful in the cosmetic composition of the present invention is further described in US Patent No. 4,919,934 issued to Deckner et al. on April 24, 1990, which is incorporated herein by reference in its entirety.

Suitable multi-branched hydrocarbons for use herein are hydrocarbon mixtures having from about 17 to about 40 carbon atoms. Non-limiting examples of these hydrocarbon mixtures are squalane, cholesterol, lanolin, behenyl (i.e. C22 hydrocarbons) and isoparaffins.

Vegetable oils and hydrogenated vegetable oils that are solid or semi-solid at ambient temperatures of about 20°C to about 25°C are also useful here. Examples of suitable vegetable oils and hydrogenated vegetable oils are milk fat, chicken fat, goose fat, horse fat, pig (fat tissue) oil, rabbit fat, sardine oil, animal fat oil (tallow), animal fat oil (lamin), Chinese vegetable fat, Baba Suren oil, cocoa butter, coconut oil, palm oil, palm kernel oil, hydrogenated safflower oil, hydrogenated castor oil, hydrogenated coconut oil, hydrogenated cottonseed oil, hydrogenated herring oil, hydrogenated palm kernel oil, hydrogenated palm oil, hydrogenated peanut oil , Hydrogenated soybean oil, hydrogenated rapeseed oil, hydrogenated linseed oil, hydrogenated rice bran oil, hydrogenated sesame oil, hydrogenated sunflower oil, their derivatives and mixtures.

Suitable polypropylene glycols used here include C4-C16 alkyl ethers of polypropylene glycol and C1-C16 carboxylates of polypropylene glycol. Non-limiting examples of these raw materials are PPG-14 butyl ether, PPG-15 stearyl ether, PPG-9, PPG-12, PPG-15, PPG-17, PPG-20, PPG-26, PPG- 30. PPG-34 and its mixtures.

Suitable alkyl amides of di- and/or tricarboxylic acids used herein include di-substituted or branched monoamides, mono-substituted or branched diamides, triamides and mixtures thereof. Some specific examples of the alkyl amides of di- and tricarboxylic acids include, but are not limited to, the alkyl amides of citric acid, glycerin, aconitic acid, nitrilotriacetic acid and itaconic acid, such as 1,2, 3-propane tributyl amide, 2-hydroxy-1,2,3-propane tributyl amide, 1-propylene-1,2,3-trioctyl amide, N,N',N-tris (form Decyl amide) amine, 2-dodecyl-N,N'-dibutyl succinamide and mixtures thereof. Other suitable amides are described in U.S. Patent 5,429,816 issued to Hofrichter et al. on July 4, 1995 The ortho acyl amino acid derivatives.

2. Colorants Although the composition of the present invention is generally transparent, colorants including pigments and particulate matter such as talc and mica can also be added to enhance the desired effect of the cosmetic product. The colorants applicable here are all inorganic and organic colorants/pigments suitable for lip compositions. These are aluminum, barium or calcium salts or lakes. The lake is either a colorant filled or diluted with a solid diluent, or an organic colorant prepared by precipitating a water-soluble dye on an absorbent surface, which is usually aluminum hydrate. Lakes can also be produced from the precipitation of insoluble salts of acid or basic dyes. Calcium and barium lakes can also be used here.

The preferred lakes of the present invention are red 3 aluminum lake, red 21 aluminum lake, red 27 aluminum lake, red 28 aluminum lake, red 33 aluminum lake, yellow 5 aluminum lake, yellow 6 aluminum lake, yellow 10 aluminum lake, orange 5 aluminum lake and blue 1 aluminum lake, red 6 barium lake, red 7 calcium lake.

Other colorants and pigments can also be included in the lip composition, such as dyes and pearlescent materials, titanium dioxide, red 6, red 21, blue 1, orange 5 and green 5 dyes, chalk, talc, iron oxide and titanate mica .

3. Emulsifier The emulsifier can be used as a coupling agent, and it has affinity with the hydrophilic and hydrophobic phases of the lip composition of the present invention. Emulsifiers can also be used to introduce polar fluids, such as water, propylene glycol, certain oils or mixtures thereof. Such emulsifiers include those commonly used in cosmetics and can be found in CTFA. Polar fluids such as water, glycerin, propylene glycol and mixtures thereof can also be added without the need for emulsifiers, this is when amphoteric substances such as polyol fatty acid polyesters are used in the composition.

4. Skin care active ingredients can be added to the lip composition in both water-soluble and water-insoluble forms. The ingredients may include fat-soluble vitamins, sunscreen agents and pharmaceutical active ingredients. These skin care active ingredients include glycerin, zinc oxide; chamomile oil; ginko biloba extract; pyroglutamic acid, salt or ester; sodium hyaluronate; 2-hydroxycaprylic acid; sulfur; salicylic acid; carboxymethylcysteamine Acid; water, propylene glycol and mixtures thereof.

Example Example 1: Component weight (%) SPE Cottonate 89.75 SPE behenate 5.05 Sericite 15.05 Propyl paraben 0.10 Brasilyl ethylene glycol 0.051 Sericite purchased from US Cosmetics Corp. in a container Mix all the ingredients and heat to 90°C while continuously stirring with a paddle mixer. When the SPE behenate is completely melted, the mixture becomes homogeneous, remove the heat and cool to room temperature. The mixture should be constantly stirred during the cooling process. The resulting liquid is transferred to a single package. Example 2: Components Weight (%) SPE Cottonate 90.30 SPE behenate 4.70 Mica 14.65 Propyl paraben 0.15 Methyl paraben 0.15 Ethylene glycolate 0.051 Sericite purchased from US Cosmetics Corp. Mix all components in a container and heat to 90°C while mixing with a paddle The device is constantly stirring. When the SPE behenate is completely melted, the mixture becomes homogeneous, remove the heat and cool to room temperature. The mixture should be constantly stirred during the cooling process. The resulting liquid is transferred to a single package. Example 3: Component weight (%) castor oil 89.75 glycerin/diethylene glycol/hexamethylene diester cross-linked polymer 15.00 ozokerite 5.00 propyl paraben 0.10 methyl paraben 0.10 ethylene brasilate 0.051 Lexorez purchased from Inolex Chemical Company 100 Mix all components in a container and heat to 90°C while continuously stirring with a paddle mixer. After the local wax is completely melted, the mixture becomes homogeneous, remove the heat and cool to room temperature. The mixture should be constantly stirred during the cooling process. The resulting liquid is transferred to a single package. Example 4: Component weight (%) SPE Cottonate 85.85 SPE Behenate 14.00 Propylparaben 0.10 Ethylene Diacetate 0.05 In a container, mix all the components and heat to 90°C while using a paddle Mixer continuously stirs. When the SPE behenate is completely melted, the mixture becomes homogeneous, remove the heating and pour it into the red mold, cool it to about -5°C before demolding, and then place it in a suitable packaging. Example 5: Components Weight (%) Group A: SEFA Cottonate 84.58 SEFA behenate 14.36 Ganex Wax WP-66010.86 Propyl paraben 0.10BHT 0.05 Group B: Ethylene Brasilate 0.051 was purchased from ISP Technologies Inc. Ganex Wax mix the A component, and use a spatula to mix evenly. Heat the A mixture until all the solids are melted (approximately 90°C), stirring occasionally during heating. Add the B components and mix with a paddle mixer for 5 minutes. The temperature control temperature does not exceed 90°C. After the mixture of the A component and the B component is uniformly mixed, the molten material is poured into a dried (seasoned) lipstick mold. Cool the filled mold at 5°C for about 20 minutes. Move the mold to ambient conditions and release the red rod to exit the mold. Put the stick into the red box. Example 6: Components Weight (%) Group A: SEFA Cottonate 70.67 SEFA Behenate 14.13 Talc 15.00 Propyl Paraben 0.10BHT 0.05 Group B: Ethylene Brasilate 0.05

Mix the components of group A and mix them evenly with a spatula. Heat the group A mixture until all the solids are melted (about 90°C), stirring occasionally during heating. Add the B components and mix with a paddle mixer for 5 minutes. The temperature control temperature does not exceed 90°C. After the mixture of the A component and the B component is uniformly mixed, the molten material is poured into the dry lipstick mold. Cool the filled mold at 5°C for about 20 minutes. Move the mold to ambient conditions and release the red rod to exit the mold. Put the stick into the red box. Example 7: Components Weight (%) Group A: SEFA Cottonate 83.17 SEFA Behenate 16.63 Propyl Paraben 0.10BHT 0.05 Group B: Ethylene Brasilate 0.05 Mix the components of group A and mix them evenly with a spatula. Heat the group A mixture until all the solids are melted (about 90°C), stirring occasionally during heating. Add component B and mix with a paddle mixer for 5 minutes. The temperature control temperature does not exceed 90°C. After the mixture of the A component and the B component is uniformly mixed, the molten material is poured into the dry lipstick mold. Cool the filled mold at 5°C for about 20 minutes. Move the mold to ambient conditions and release the red rod to exit the mold. Put the stick into the red box. Example 8: Component weight (%) Group A: SEFA Cottonate 75.02 SEFA Behenate 13.58 Talc 7.50 Ganex Wax WP-66010.50 Propyl Paraben 0.15BHT 0.05 Group B: Glycerol 3.00 Methyl Paraben Group 0.15C: Ethylene Brasilate 0.051 was purchased from ISP Technologies Inc. Ganex Wax mix the components of group A and mix them evenly with a spatula. Heat the group A mixture until all the solids are melted (about 90°C), stirring occasionally during heating. Mix the components of group B and mix well with a spatula. Heat the Group B mixture to about 90°C. Mix the A and B components and homogenize at 5000 rpm for 5 minutes. Add the components of Group C and mix with a paddle mixer for 5 minutes. When the mixture is uniformly mixed, pour the molten material into the dry lipstick mold. Cool the filled mold at 5°C for about 20 minutes. Move the mold to ambient conditions and release the red rod to exit the mold. Put the stick into the red box. Example 9: Component weight (%) Group A: SEFA Cottonate 59.55 SEFA Behenate 12.50 Talc 7.50 Propylparaben 0.15 Vitamin E Linoleate 0.10 Group B: Water 10.00 Propylene Glycol 5.00 Glycerol 5.00 Parahydroxy Methyl benzoate 0.15C group: ethylene brasyl acid ester 0.05 Mix the components of group A and mix them evenly with a spatula. Heat the group A mixture until all the solids are melted (about 90°C), stirring occasionally during heating. Mix the components of group B and mix well with a spatula. Heat the Group B mixture to about 90°C. Mix the A and B components and homogenize for 2 minutes at 5000 rpm. Add the components of Group C and mix with a paddle mixer for 5 minutes. When the mixture is uniformly mixed, pour the molten material into the dry lipstick mold. Cool the filled mold at 5°C for about 20 minutes. Move the mold to ambient conditions and release the red rod to exit the mold. Put the stick into the red box. Example 10: Component weight (%) Group A: SEFA Cottonate 85.85 SEFA Behenate 14.00 Propylparaben 0.10 Group B: Ethylene Brasilate 0.05 Mix the components of Group A and mix with a spatula Evenly. Heat the group A mixture until all the solids are melted (about 90°C), stirring occasionally during heating. Add component B and mix with a paddle mixer for 5 minutes. The temperature control temperature does not exceed 90°C. After the mixture of the A component and the B component is uniformly mixed, the molten material is poured into the dry lipstick mold. Cool the filled mold at 5°C for about 20 minutes. Move the mold to ambient conditions and release the red rod to exit the mold. Put the stick into the red box. Example 11: Components Weight (%) Group A: SEFA Cottonate 85.21 SEFA Behenate 14.09 Ganex Wax WP-66010.50 Propyl Paraben 0.10BHT 0.05 Group B: Ethylene Brasilate 0.05 Mix the components of Group A, and use a scraper Spoon and mix well. Heat the group A mixture until all the solids are melted (about 90°C), stirring occasionally during heating. Add component B and mix with a paddle mixer for 5 minutes. The temperature control temperature does not exceed 90°C. After the mixture of the A component and the B component is uniformly mixed, the molten material is poured into the dry lipstick mold. Cool the filled mold at 5°C for about 20 minutes. Move the mold to ambient conditions and release the red rod to exit the mold. Put the stick into the red box. Example 12: Components Weight (%) Group A: SEFA Cottonate 89.75 SEFA Behenate 5.05 Mica 5.05 Propyl Paraben 0.10 Group B: Ethylene Dibasic Acid 0.05 Mix the components of group A and mix them evenly with a spatula. Heat the group A mixture until all the solids are melted (about 90°C), stirring occasionally during heating. Add component B and mix with a paddle mixer for 5 minutes. The temperature control temperature does not exceed 90°C. After the mixture of the A component and the B component is uniformly mixed, pour the molten material into a single container. Allow it to cool to ambient conditions. Example 13: Ingredients Weight (%) Group A: SEFA Cottonate 89.00 Candelabra wax 3.00 Ore wax 1.00 Microcrystalline wax 1.50 Beeswax 5.30 Group B: BHT 0.05 Ethylene Brasilate 0.05 Propyl Parahydroxybenzoate 0.10 Mix the components of Group A and mix them evenly with a spatula. Heat the A mixture until all the solids are melted (approximately 90°C), stirring occasionally during heating. Add component B and mix with a paddle mixer for 5 minutes. The temperature control temperature does not exceed 90°C. After the mixture of the A component and the B component is uniformly mixed, the molten material is poured into the dry lipstick mold. Cool the filled mold at 5°C for about 20 minutes. Move the mold to ambient conditions and release the red rod to exit the mold. Put the stick into the red box. Example 14: Components Weight (%) Group A: SEFA Cottonate 88.00 ozokerite 6.00 Beeswax 5.80 Group B: BHT 0.05 Ethylene Brasilate 0.05 Propyl Parahydroxybenzoate 0.10 Mix the components of Group A and mix them evenly with a spatula. Heat the A mixture until all the solids are melted (approximately 90°C), stirring occasionally during heating. Add component B and mix with a paddle mixer for 5 minutes. The temperature control temperature does not exceed 90°C. After the mixture of the A component and the B component is uniformly mixed, the molten material is poured into the dry lipstick mold. Cool the filled mold at 5°C for about 20 minutes. Move the mold to ambient conditions and release the red rod to exit the mold. Put the stick into the red box. Example 15: Component weight (%) Group A: Castor oil 89.80 SEFA behenate 10.00 Group B: BHT 0.05 Ethylene Brasilate 0.05 Propyl p-hydroxybenzoate 0.10 Mix all the components in a container and Heat to 90°C while continuously stirring with a paddle mixer. When the SPE behenate is completely melted, the mixture becomes homogeneous, remove the heat and cool to room temperature. The mixture should be constantly stirred during the cooling process. The resulting liquid is transferred to a single package. Example 16: Components Weight (%) Group A: Castor oil 74.80SEFA behenate 25.00B group: BHT 0.05 ethylene brasyl acid ester 0.05 propyl p-hydroxybenzoate 0.10 Mix all the components in a container and heat to 90°C while continuously stirring with a paddle mixer. When the SPE behenate is completely melted, the mixture becomes homogeneous, remove the heat and cool to room temperature. The mixture should be constantly stirred during the cooling process. The resulting liquid is transferred to a single package.

The following does not include all examples of cosmetics that can be used with the above-mentioned composition of the present invention. Example 1: Component weight (%) of the lip composition Group A: Silicone pure rubber 112.60 Isododecane 212.60 Group B: Isododecane 243.38 Bentonite 41.00 Propylene carbonate 0.32 Red #6 calcium lake 1.00 red #7 barium lake 3.00 titanium dioxide 1.50 mica 2.20 organosiloxane resin 322.401. Dimethicone pure rubber compound named SE63 (2,500,000 cSt) purchased from General Electric Company 2. Purchased from Permethyl Corp. Permethyl 99A3. MQ resin named 1170-002 (M:Q=0.7:1) purchased from General Electric Company 4. The organic bentonite 38, purchased from Rheox Company, was mixed with the components of Group A in a beaker and stirred evenly with a paddle mixer. The B group components except propylene carbonate were incorporated and manually mixed to roughly incorporate the dry powder. Homogenize the entire formula with a RossME100LC homogenizer at 7500 rpm until the pigment is fully dispersed. Then, while continuing the homogenization process, slowly add propylene carbonate until the mixture thickens. Combine the A and B mixtures in a beaker and mix them with a paddle mixer. Transfer the resulting liquid to a single package. Example 2: Liquid foundation cosmetic component weight (%) Group A: Organosiloxane resin 14.48 Cyclomethicone 211.11 Polysiloxane polyether emulsifier 310.00 Group B: Polysiloxane-treated titanium dioxide 6.50 poly Siloxane-treated iron yellow 0.28 Polysiloxane-treated iron red 0.15 Polysiloxane-treated iron black 0.06 Group C: 2,500,000 cSt Silicone rubber compound 42.52 Cyclomethicone 24.90 Group D: Water 49.50 Glycerin 10.00 Methyl paraben 0.202-phenoxyethanol 0.301. MQ resin named 1170-002 purchased from General Electric Company 2. 2. Cyclomethicone named 245 Fluid purchased from Dow Corning; 3. 3. A polysiloxane polyether emulsifier named DC3225C purchased from Dow Corning Company 4. A dimethylpolysiloxane gum (2,500,000 cSt), purchased from Dow Corning Company, named SE63, mixes the A and B components together, and homogenizes them at 9500 rpm for 15 minutes. Add the C components and homogenize at 2000 rpm for 2 minutes. Mix the components of group D in another container and use a paddle mixer to mix until a transparent solution. Slowly add the solution of group D to the mixture of groups A, B, and C while homogenizing at 2000 rpm. When all the D solutions have been added, homogenize the entire mixture for another 10 minutes at 2000 rpm. Finally, homogenize the entire mixture for 5 minutes at 5000 rpm. Transfer the resulting liquid to a single package. Example 3: Eyelash cosmetic component weight (%) Group A: Organosiloxane resin 19.60 Cyclomethicone 28.82 Polysiloxane polyether emulsifier 310.00 Group B: Polysiloxane-treated iron black 5.00C Group: 2,500,000 cSt silicone rubber pure rubber compound 5.404 cyclomethicone 216.19D group: water 43.50 sodium chloride 1.00 methyl paraben 0.202-phenoxyethanol 0.301. MQ resin named 1170-002 purchased from General Electric Company 2. 2. Cyclomethicone named 245Fluid purchased from Dow Corning; 3. 3. A polysiloxane polyether emulsifier named DC3225C purchased from Dow Corning Company 4. The dimethylpolysiloxane gum (2,500,000 cSt), purchased from General Electric Company, named SE63, mixes the A and B components together, and homogenizes them at 9500 rpm for 15 minutes. Add the C components and homogenize at 2000 rpm for 2 minutes. Mix the components of group D in another container and use a paddle mixer to mix until a transparent solution. Slowly add the solution of group D to the mixture of groups A, B, and C while homogenizing at 2000 rpm. When all the D solutions have been added, homogenize the entire mixture for another 10 minutes at 2000 rpm. Finally, homogenize the entire mixture for 5 minutes at 5000 rpm. Transfer the resulting liquid to a single package. Example 4: Shear Lip Tint Composition) Component weight (%) Group A: Silicone rubber compound 111.88 Isododecane 254.45 Group B: Organosiloxane resin 320.78 Red #6calcium color lake 0.50 red #7 barium color lake 0.50Gemtone Sunstone50.50Timiron MP -115 pearlescent material 60.50 bentonite gel 410.891. Dimethicone pure rubber compound named SE63 (2,500,000 cSt) purchased from General Electric Company 2. Purchased from Permethyl Corp. The Permethyl 99A3. MQ resin named 1170-002 (M:Q=0.7:1) purchased from General Electric Company 4. VS-5PC purchased from Rheox5. Gemtone Sunstone purchased from Mear Company 6. The Timiron MP-115 pearlescent material purchased from Mear Company was mixed with the A-group components in a beaker and mixed evenly with a paddle mixer. Add the B components to the A component mixture and manually stir to roughly incorporate the dry powder. Homogenize the entire formulation until all the pigments are fully dispersed. Move the resulting fluid to a single package. Example 5: Liquid eyeliner cosmetic components Weight (%) Group A: Organosiloxane resin 18.90 Isododecane 214.90 Group B: Iron black 20.00 Propylparaben 0.10 Group C: 100,000 cSt polysiloxane liquid 311.10 Isododecane 233.00 Group D : Isododecane 210.00 Trihydroxystearate 2.001. MQ resin named 1170-002 (M:Q=0.7:1) purchased from General Electric Company 2. Purchased from Permethyl Corp. The Permethyl 99A3. The dimethylpolysiloxane liquid purchased from General Electric Company was mixed with the components of Group A and mixed uniformly with a paddle mixer. Add the B components and homogenize until the colorant is fully scored. In another container, use a paddle mixer to pre-mix the components of Group C until they are uniform, and then combine them into the mixture of Group A and Group B components. Premix component D and heat to about 57-60°C for about 3 minutes. Remove heat and homogenize for about 5 minutes or until gel appears. Finally, add the D component mixture to the remaining materials and heat the entire mixture to 57-60°C for about 7-10 minutes while mixing with a paddle mixer. Remove the heat and cool to room temperature while mixing with a paddle mixer. Transfer the resulting liquid to a single package. Example 6: Eyeshadow cosmetic components Weight (%) Group A: Organosiloxane resin 122.40 Isododecane 214.90 Group B: Flamenco Gold Pearl 0.60 Flamenco Superpearl 0.84 Titanium dioxide 0.94 Gemtone Copper 0.41 Gemtone Sunstone 1.21 Propyl paraben 0.10 Group C: 1,000 cSt poly Silicone Liquid 313.86 Isododecane 233.00 Group D: Isododecane 210.00 Trihydroxystearate 2.001. MQ resin named 1170-002 (M:Q=0.7:1) purchased from General Electric Company 2. Purchased from Permethyl Corp. Permethyl 99A3. The dimethylpolysiloxane liquid purchased from General Electric Company was mixed with the components of Group A and mixed uniformly with a paddle mixer. Add the B components and homogenize until the colorant is fully scored. In another container, use a paddle mixer to pre-mix the components of Group C until they are uniform, and then combine them into the mixture of Group A and Group B components. Premix component D and heat to about 57-60°C for about 3 minutes. Remove heat and homogenize for about 5 minutes or until gel appears. Finally, add the D component mixture to the remaining materials and heat the entire mixture to 57-60°C for about 7-10 minutes while mixing with a paddle mixer. Remove the heat and cool to room temperature while mixing with a paddle mixer. Transfer the resulting liquid to a single package. Methods for improving cosmetics In addition, the present invention relates to methods for improving transfer-resistant flexible film-forming cosmetics, the method comprising: a. Applying a transfer resistant flexible film-forming cosmetic to the skin, wherein the solubility parameter of the cosmetic is less than or equal to 8.5 (cal/cm3) 1/2; b. Let the cosmetics dry; and c. A second composition is applied to the cosmetic, wherein the C log P value of the composition is greater than or equal to 13.

The user applies the cosmetics and compositions of the present invention in a suitable liquid cosmetic applicator. Applicators for liquid products include the pen-shaped liquid package disclosed in British Patent No. 21198037, which was granted on 5/09/90 and assigned to Mitsubishi Pen Co., Ltd. of Japan.

Another such cosmetic applicator is a unidirectional spiral applicator with increased dose, disclosed in the co-pending Horstman et al. USSN-08/738,129 patent application, filing date 10/25/96, assigned to Procter & Gamble , And its title is "Simple one-way spiral applicator for increased dose." Such a spiral applicator may include a hollow casing, which defines a small chamber with an open application end and a piston located in the small chamber, which is limited to linear movement within the small chamber. The piston preferably has a threaded rod extending therefrom, which rod is connected to a tapped hole in the actuator, so that when the actuator rotates, the advancement of the piston toward the applicator occurs. The rotation of the actuator produces the application of the product from the application end. The applicator is preferably connected to the application end of the casing, which is connected to the cell for liquid delivery, and the product in the cell is applied through the applicator. The applicator may include a coupling and an application part, wherein the coupling is connected to the application end of the casing, and the application part has at least one opening. Several forms of applicator can be used, including, for example, ciliated brushes or felted application surfaces. Felt pads are pads with short, flexible fibers that are substantially perpendicular to the application surface. The bristles of the ciliated brush are preferably sharpened and made of a flexible material. In addition, the supplemental composition can be formed into a solid state and more traditional applicators or tools known in the art can be used.