A manufacturing method of ceramic board coated TiO2 of air clarifier
Abstract
The present invention relates to a titanium dioxide photocatalytic reaction substrate for an air purifier, and more particularly, by using a ceramic substrate to which a magnetic material is added, contamination on the substrate surface that may occur due to an electrostatic reaction is minimized and titanium dioxide is applied to a chemically stable ceramic substrate. It relates to a method of manufacturing a ceramic substrate for an air purifier coated with a titanium dioxide film, which can maximize the processing efficiency of the air purifier by forming a film by coating the sol. An object of the present invention is to add a magnetic material to a high-strength ceramic and coat titanium dioxide, thereby preventing damage and desorption of titanium dioxide due to long-term use, and preventing contaminants from being bonded to the surface to facilitate photocatalysis. An object of the present invention is to provide a method for manufacturing a ceramic substrate for an air purifier coated with a titanium dioxide film capable of maximizing the efficiency of a photocatalyst. The composition of the present invention to achieve the above object is AlO (24 ~ 50W/%), SiO(35 ~ 40W/%), Mg0 (8 ~ 10W/%), FeO (12 ~ 15W/%), MnO( 11 to 12W/%), CuO (3 to 5W/%), etc. are wet-mixed, molded and dried, and then predetermined to prepare a ceramic substrate. It is characterized in that it comprises a titanium dioxide sol manufacturing process to manufacture, and a coating process in which the substrate manufactured by the substrate manufacturing process is supported in the titanium dioxide sol, dried and heat-treated. More preferably, the substrate manufacturing process is AlO (24 to 50W/%), SiO (35 to 40W/%), Mg0 (8 to 10W/%), FeO (12 to 15W/%), MnO (11 to 12W/%), CuO (3 ~ 5W/%), etc. are wet-mixed, and then a dispersant, plasticizer, organic binder, solvent, etc. are added to have an average particle diameter of 1 to 3 micrometers and pulverize to have a viscosity of 4000CPS. The slurry manufacturing process for preparing the slurry, the green sheet manufacturing process for manufacturing the green sheet by molding and drying the slurry prepared by the slurry manufacturing process to a thickness of 2 to 3 mm, and the green sheet manufacturing process It is characterized in that it consists of a predetermined process of manufacturing a porous ceramic substrate by firing a green sheet at 1300 ~ 1400.

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Projected expiry passed 26 December 2021, 4.7 years ago.
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3 claims: 1 independent, 2 dependent
- 1Al₂O₃ (24 ∼ 50W/%), SiO₂(35 ∼ 40W/%), Mg0 (8 ∼ 10W/%), Fe₂O₃(12 ∼ 15W/%), MnO₂(11 ∼ 12W/%), CuO (3 ∼ 5W/%)등을 습식혼합하고 성형 건조후 소정하여 세라믹기판을 제조하는 기판제조과정과, Titanium Tetraisopropoxide 용액을 무수에탄올 중에서 염산을 공침시켜 이산화티타늄졸을 제조하는 이산화티타늄졸 제조과정과, 상기 기판제조과정에 의해 제조된 기판을 상기 이산화티타늄졸에 담지후 건조시키고 열처리하는 코팅과정으로 이루어지는 것을 특징으로 하는 이산화티타늄막이 코팅된 세라믹기판 제조방법.
- 2제 1항에 있어서, 상기 기판제조과정은, Al₂O₃ (24 ∼ 50W/%), SiO₂(35 ∼ 40W/%), Mg0 (8 ∼ 10W/%), Fe₂O₃(12 ∼ 15W/%), MnO₂(11 ∼ 12W/%), CuO (3 ∼ 5W/%)등을 습식 혼합한 다음, 분산제, 가소제, 유기바인더, 용제등을 첨가하여 평균 입자경이 1 ∼ 3 마이크로 미터를 가지며 4000CPS의 점도를 가지도록 분쇄하여 slurry를 제조하는 slurry제조과정과, 상기 slurry제조과정에 의해 제조된 slurry를 2 ∼ 3 mm 의 두께로 성형, 건조시켜 green sheet를 제조하는 green sheet제조과정과, 상기 green sheet제조과정에 의해 제조된 green sheet를 1300 ∼ 1400℃에서 소성하여 다공질의 세라믹기판을 제조하는 소정과정으로 이루어지는 것을 특징으로 하는 이산화티타늄막이 코팅된 세라믹기판 제조방법.
- 3제 1항의 방법에 의해 제조된 이산화티타늄막이 코팅된 세라믹기판.
Independent claims3
5 paragraphs, as filed
TECHNICAL FIELD [0002] A manufacturing method of ceramic board coated TiO2 of air clarifier
1 is a process diagram showing a method of manufacturing a ceramic substrate of an air purifier coated with a titanium dioxide film.
<background-art><p>The present invention relates to a titanium dioxide photocatalytic reaction substrate for an air purifier, and more particularly, by using a ceramic substrate to which a magnetic material is added, contamination on the substrate surface that may occur due to an electrostatic reaction is minimized and titanium dioxide is applied to a chemically stable ceramic substrate. It relates to a method of manufacturing a ceramic substrate for an air purifier coated with a titanium dioxide film, which can maximize the processing efficiency of the air purifier by forming a film by coating the sol.</p><p>In general, air purifiers use titanium dioxide photocatalysts to purify air and remove pollutants.</p><p>The photocatalyst, titanium dioxide, creates negatively charged electrons and positively charged holes when exposed to light, and the electrons and holes have very strong reducing and oxidizing power, so that hydroxyl groups that are active oxygen from water and oxygen in the atmosphere (OH) and peroxygen ion (O-) are generated, and the generated hydroxyl group and peroxygen ion have strong oxidizing and reducing power, so they act on sterilization and decomposition of organic matter.</p><p>In general, the titanium dioxide photocatalyst reaction plate of the air purifier is fixed to the surface of aluminum, paper, or equivalent using an adhesive, so the role of the photocatalyst is hindered. This occurred, and the electrostatic contaminants were bonded to the surface of the substrate, so that the reaction plate did not perform its functions, and it was easily damaged and the manufacturing cost of the substrate increased, which caused uneconomical problems.</p></background-art><tech><p>The present invention has been devised to solve the above problems, and an object of the present invention is to prevent desorption of titanium dioxide due to damage and long-term use by adding a magnetic material to high-strength ceramics and coating titanium dioxide, and pollutants An object of the present invention is to provide a method for manufacturing a ceramic substrate for an air purifier coated with a titanium dioxide film, which can maximize the efficiency of the photocatalyst by preventing the bonding to the surface and allowing the photocatalyst to be smoothly formed.</p><p>The composition of the present invention to achieve the above object is AlO (24 ~ 50W/%), SiO(35 ~ 40W/%), Mg0 (8 ~ 10W/%), FeO (12 ~ 15W/%), MnO( 11 to 12W/%), CuO (3 to 5W/%), etc. are wet-mixed, molded and dried, and then predetermined to prepare a ceramic substrate. It is characterized in that it comprises a titanium dioxide sol manufacturing process to manufacture, and a coating process in which the substrate manufactured by the substrate manufacturing process is supported in the titanium dioxide sol, dried and heat-treated.</p><p>More preferably, the substrate manufacturing process is AlO (24 to 50W/%), SiO (35 to 40W/%), Mg0 (8 to 10W/%), FeO (12 to 15W/%), MnO (11 to 12W/%), CuO (3 ~ 5W/%), etc. are wet-mixed, and then a dispersant, plasticizer, organic binder, solvent, etc. are added to have an average particle diameter of 1 to 3 micrometers and pulverize to have a viscosity of 4000CPS. The slurry manufacturing process for preparing the slurry, the green sheet manufacturing process for manufacturing the green sheet by molding and drying the slurry prepared by the slurry manufacturing process to a thickness of 2 to 3 mm, and the green sheet manufacturing process It is characterized in that it consists of a predetermined process of manufacturing a porous ceramic substrate by firing a green sheet at 1300 ~ 1400.</p></tech>
<p>Hereinafter, an embodiment of the present invention will be described with reference to a process diagram showing a method of manufacturing a ceramic substrate of an air purifier coated with a titanium dioxide film of FIG. 1 .</p><p><u>Manufacturing method of ceramic substrate coated with titanium dioxide film</u></p><p><b>1st process (substrate manufacturing process)</b></p><p>The substrate manufacturing process is subdivided into slurry manufacturing process, green sheet manufacturing process, and predetermined process.</p><p>The slurry manufacturing process is AlO (24 50W/%), SiO (35 40W/%), Mg0 (8 10W/%), FeO (12 15W/%), MnO (11 12W/%), After wet mixing CuO (3 ~ 5W/%), etc., 1.5% of a general organic dispersant (Sannovco SN5468) is added and milling is performed for about 20 hours.</p><p>Then, it is prepared into granules using a spray dryer, calcined at about 1150° C., and then pulverized using a vibrating grinder.</p><p>The powder pulverized by the above process is mixed with organic binder (PVB) (3 to 7%), plasticizer (DBP) (2 to 4%), dispersant (FISH OIL) (1 to 3%), solvent (ethanol and toluene) (35 ~ 45%) is added, and the average particle diameter is 1-3 micrometers and the slurry is pulverized to have a viscosity of 4000CPS.</p><p>In the green sheet manufacturing process, the slurry prepared by the slurry manufacturing process is molded to a thickness of 2 to 3 mm on a film coated with a release agent on a blade that can be adjusted in height, and then dried in a dry oven at 40 to 60°C for 24 hours. to manufacture a green sheet.</p><p>In the predetermined process, the green sheet manufactured by the green sheet manufacturing process is predetermined at a rate of 2 to 3 °C/min to 1300 to 1400 °C to manufacture a porous ceramic substrate.</p><p><b>2nd process (titanium dioxide sol manufacturing process)</b></p><p>Titanium dioxide sol (TiOsol) is prepared by co-precipitating a solution of Titanium Tetraisopropoxide with hydrochloric acid in absolute ethanol.</p><p>That is, it is prepared under strong stirring by reacting a titanium tetraisopropoxide solution with 1000 g of absolute ethanol to a concentration of 2M and immersing it drop by drop to a concentration of 0.2M using 2N HCL. A stable sol is produced when reacted for about 12 hours do.</p><p><b>3rd process (coating process)</b></p><p>After loading the substrate in the titanium dioxide sol prepared by the second process, drying, repeating the coating operation 2-3 times, and heat-treating at 550° C. to prepare a ceramic substrate coated with a titanium dioxide film.</p>
<p>As described above, the ceramic substrate coated with titanium dioxide produced by the present invention is not easily damaged and has a low degree of contamination on the surface of the substrate. It maximizes the photocatalytic function by preventing the desorption phenomenon and has the effect of long-term use.</p>
2 sheets
Sheet 1 Sheet 2
Every citation, both ways
| Document | Relation | Office | Cited during |
|---|---|---|---|
| KR20210158293A | Cited by | Republic of Korea | Search report |
| KR102237709B1 | Cited by | Republic of Korea | Search report |
| KR20180106332A | Cited by | Republic of Korea | Search report |
| US3892897A | Cites | United States of America | Search report |
| US6037289A | Cites | United States of America | Search report |
| US6103363A | Cites | United States of America | Search report |
| US6455465B1 | Cites | United States of America | Search report |
| JPH1053437A | Cites | Japan | Search report |
1 member in 1 office
Priority claims2
| Document | Office | Kind | Date |
|---|---|---|---|
| 20010084813 | Republic of Korea | A | |
| KR20010084813 | – | – | – |
Members1
| Document | Office | Kind | |
|---|---|---|---|
| KR20030054616AThis record | Republic of Korea | A |
4 legal events, as the office reported them to INPADOC
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| Unpaid initial registration feeNORF | NORF | |
| Decision to grant or registration of patent rightE701 | E701 | |
| Notification of reason for refusalE902 | E902 | |
| Request for examinationA201 | A201 |
Numbers
- Publication
- 1020030054616
- Publication, DOCDB
- 20030054616
- Publication, EPODOC
- KR20030054616
- Application
- 100084813
- Application, DOCDB
- 20010084813
- Application, EPODOC
- KR20010084813
Titles4
- Korean
- 이산화티타늄막이 코팅된 공기정화기의 세라믹기판의제조방법
- English
- Manufacturing method of ceramic substrate of air purifier coated with titanium dioxide film
- Unlabeled
- 이산화티타늄막이 코팅된 공기정화기의 세라믹기판의 제조방법{A manufacturing method of ceramic board coated TiO2 of air clarifier}
- Unlabeled
- TECHNICAL FIELD [0002] A manufacturing method of ceramic board coated TiO2 of air clarifier
Classification
- CPC, 7
- C04B41/85
- B01D53/86
- B01J21/063
- C04B35/10
- C04B2111/00827
- C04B2111/40
- C04B2235/3217
- IPC, 4
- C04B41 85
- B01D53 86
- B01J21 06
- C04B41 81