Method for lightening or dyeing human keratinous fiber by using anhydrous composition comprising monoethanolamine/basic amino acid mixture, and device therefor

The present invention comprises an anhydrous composition (A) containing one or more aliphatic substances, one or more surfactants, monoethanolamine, and one or more basic amino acids, and optionally 1 A composition (C1) containing a seed or multiple oxidant dyes and / or a direct dye, and a composition (B) containing one or more oxidants are used to lighten or lighten human keratin fibers. Regarding the method for dyeing.

The present invention relates to a multi-partition device containing the compositions (A) and (B) and optionally (C1) described above.

In the method for lightening human keratin fibers, an aqueous composition containing at least one oxidizing agent is often used under alkaline pH conditions. The role of this oxidant is to break down the melanin in the hair, which, to varying degrees, leads to significant lightening of the fibers, depending on the nature of the oxidant present. Therefore, for relatively weak lightening, the oxidant is generally hydrogen peroxide. When stronger lightening is desired, a peroxide salt, such as a persulfate, is usually used in the presence of hydrogen peroxide.

Among the methods for dyeing human keratin fibers, for example, hair, oxidative dyeing or permanent dyeing can be mentioned. More specifically, the dyeing method uses one or more oxidation dye precursors, usually one or more oxidation bases which may be combined with one or more coupling agents.

Generally, the oxidation base is selected from ortho- or para-phenylenediamine, ortho- or para-aminophenol and heterocyclic compounds. These oxidation bases are colorless or slightly colored compounds that, when mixed with an oxidizing substance, allow the formation of colored chemicals via an oxidative condensation step.

The tones obtained using these oxidation bases often change when used in combination with one or more coupling agents, and the coupling agents are particularly aromatic meta-diamines, meta-aminophenols, meta-di. It is selected from phenol and certain heterocyclic compounds, such as indole compounds.

Due to the variety of molecules used as oxidation bases and coupling agents, it is possible to obtain a wide range of colors.

Direct or semi-permanent staining is also known. In the method conventionally used for direct dyeing, a direct dye, which is a colored and coloring molecule having an affinity for the fiber, is applied to the keratin fiber, and the molecule is diffused by leaving it on for a certain period of time. After infiltrating the fibers, rinse off.

Commonly used direct dyes are selected from nitrobenzene, anthraquinone, nitropyridine, azo, methine, azomethine, xanthene, acridine, azine and triallylmethane direct dyes.

This type of method does not require the use of oxidants to develop color. However, the use of oxidizing agents is not excluded for the purpose of obtaining not only coloring but also lightening effect. Such a method is called direct staining or semi-permanent staining under lightening conditions.

In the method of permanent or semi-permanent dyeing under lightening conditions, in most cases, an aqueous composition containing at least one oxidizing agent is used at the same time as the dye composition under alkaline pH conditions. The role of this oxidant is to break down the melanin in the hair, which, to varying degrees, leads to significant lightening of the fibers, depending on the nature of the oxidant present. Therefore, for relatively weak lightening, the oxidant is generally hydrogen peroxide. When stronger lightening is desired, a peroxygenated salt, such as a persulfate, is usually used in the presence of hydrogen peroxide.

One of the problems is that the method for lightening or the method of oxidative staining or direct dyeing under lightening conditions is carried out under alkaline conditions, and the most commonly used alkaline agent is aqueous ammonia. Due to that. Ammonia water is particularly advantageous in this type of method. This is because the pH of the composition can be adjusted to an alkaline pH to decompose the oxidizing agent. However, this agent also causes swelling of keratin fibers with opening of the scales, which promotes the penetration of oxidants and dyes, essentially oxidative dyes, into the fibers, resulting in a reaction effect. Is enhanced.

However, this basicizing agent is extremely volatile and is disliked by users due to the release of the characteristic, strong, and rather unpleasant odor of ammonia during this method.

In addition, higher content than necessary must be used to compensate for the evaporation of ammonia. This is not unaffected by the user, who may face not only discomfort due to odor, but also an increased risk of hypersensitivity, such as increased scalp irritation (stinging).

With respect to the option of simply substituting all or part of the aqueous ammonia with one or more other standard basing agents, the aqueous ammonia-based basing agents lead to the production of more effective compositions. No, but it is especially because these basicizing agents do not result in sufficient lightening of the colored fibers in the presence of oxidants.

<p><patcit num="1"><text>GB1026978</text></patcit><patcit num="2"><text>GB1153196</text></patcit><patcit num="3"><text>FR2801308</text></patcit><patcit num="4"><text>DE2359399</text></patcit><patcit num="5"><text>JP88-169571</text></patcit><patcit num="6"><text>JP05-63124</text></patcit><patcit num="7"><text>EP0770375</text></patcit><patcit num="8"><text>WO 96/15765</text></patcit><patcit num="9"><text>DE3843892</text></patcit><patcit num="10"><text>DE4133957</text></patcit><patcit num="11"><text>WO94 / 08969</text></patcit><patcit num="12"><text>WO94 / 08970</text></patcit><patcit num="13"><text>FR-A-2733749</text></patcit><patcit num="14"><text>DE19543988</text></patcit><patcit num="15"><text>FR-A-2886136</text></patcit><patcit num="16"><text>WO95 / 15144</text></patcit><patcit num="17"><text>WO95 / 01772</text></patcit><patcit num="18"><text>EP714954</text></patcit><patcit num="19"><text>FR2189006</text></patcit><patcit num="20"><text>FR2285851</text></patcit><patcit num="21"><text>FR2140205</text></patcit><patcit num="22"><text>EP1378544</text></patcit><patcit num="23"><text>EP1674073</text></patcit><patcit num="24"><text>EP1637566</text></patcit><patcit num="25"><text>EP1619221</text></patcit><patcit num="26"><text>EP1634926</text></patcit><patcit num="27"><text>EP1619220</text></patcit><patcit num="28"><text>EP1672033</text></patcit><patcit num="29"><text>EP1671954</text></patcit><patcit num="30"><text>EP1671955</text></patcit><patcit num="31"><text>EP1679312</text></patcit><patcit num="32"><text>EP1671951</text></patcit><patcit num="33"><text>EP167952</text></patcit><patcit num="34"><text>EP167971</text></patcit><patcit num="35"><text>WO06 / 063866</text></patcit><patcit num="36"><text>WO06 / 063867</text></patcit><patcit num="37"><text>WO06 / 063868</text></patcit><patcit num="38"><text>WO06 / 063869</text></patcit><patcit num="39"><text>EP1408919</text></patcit><patcit num="40"><text>EP1377264</text></patcit><patcit num="41"><text>EP1377262</text></patcit><patcit num="42"><text>EP1377261</text></patcit><patcit num="43"><text>EP1377263</text></patcit><patcit num="44"><text>EP1399425</text></patcit><patcit num="45"><text>EP1399117</text></patcit><patcit num="46"><text>EP1416909</text></patcit><patcit num="47"><text>EP1399116</text></patcit><patcit num="48"><text>EP1671560</text></patcit><patcit num="49"><text>EP1006153</text></patcit><patcit num="50"><text>EP1433472</text></patcit><patcit num="51"><text>EP1433474</text></patcit><patcit num="52"><text>EP1433471</text></patcit><patcit num="53"><text>EP1433473</text></patcit><patcit num="54"><text>EP6291333</text></patcit></p>

<p><nplcit num="1"><text>Walter Noll, "Chemistry and Technology of Silicones" (1968), Academic Press</text></nplcit><nplcit num="2"><text>"Cosmetics and Toiletries", Vol. 91, January, 76, 27-32</text></nplcit><nplcit num="3"><text>Todd and Byers, "Volatile Silicone Fluids for Cosmetics"</text></nplcit><nplcit num="4"><text>CTFA (6th edition, 1995)</text></nplcit><nplcit num="5"><text>"Color Index International" 3rd Edition</text></nplcit></p>

<p> One of the objects of the present invention is that the methods carried out using existing compositions have drawbacks caused by the presence of large amounts of ammonia, but without such drawbacks, lightening and this lightening. It is to propose a method for lightening human keratin fibers, which retains at least equivalent effectiveness in terms of colorization uniformity.</p><p> One of the objects of the present invention is also that the methods performed using existing compositions have drawbacks caused by the presence of large amounts of ammonia, but without such drawbacks, the resulting coloration. It is to propose a method for dyeing human keratin fibers, which is carried out in the presence of an oxidizing agent, which retains at least the same effectiveness in terms of strength, chromaticity and uniformity of dyeing along the fibers. ..</p>

<p> These and other objectives are achieved by the present invention, and one subject of the present invention is therefore a method for lightening human keratin fibers using: a) An anhydrous composition containing one or more fatty substances, one or more surfactants, monoethanolamine, and one or more basic amino acids, b) Composition containing one or more oxidizing agents (B).</p><p> Another subject of the invention relates to a method of dyeing human keratin fibers using: a) An anhydrous composition containing one or more fatty substances, one or more surfactants, monoethanolamine, and one or more basic amino acids, b) Compositions (C1) containing one or more oxidative dyes and / or direct dyes, c) Aqueous composition containing one or more oxidizing agents (B).</p><p> The present invention also relates to a multi-segment device containing the aforementioned compositions (A) and (B) and optionally (C1).</p><p> Other features and advantages of the present invention will become clearer as you read the descriptions and examples below.</p><p> In the text below, the upper and lower limits of a range of values are included in that range unless otherwise noted.</p><p> The human keratin fibers treated by the method according to the present invention are preferably hair.</p><p> The cosmetic anhydrous composition (A) has a water content of 0% by weight or more, less than 5% by weight, more preferably less than 2% by weight, and more specifically less than 1% with respect to the weight of the composition. Have. It should be noted that the water may be in the form of bound water, such as water of crystallization of salts, or trace amounts of water absorbed by the starting material used in the preparation of the compositions according to the invention.</p><p> Furthermore, when the method of the present invention is a lightening method, a composition free of precursors (bases and coupling agents) of direct dyes or oxidative dyes commonly used for dyeing or other purposes of human keratin fibers. This method is carried out in the presence of, but if any of these are contained, their total content is 0.005 relative to the weight of the anhydrous composition and the weight of the aqueous composition containing the oxidant. Does not exceed% by weight. Strictly speaking, at such a content, perhaps only the composition could be stained, so no staining effect would be observed on the keratin fibers.</p><p> Preferably, this method is carried out without the use of oxidation bases, coupling agents and direct dyes.</p><p> As mentioned above, the cosmetic anhydrous composition (A) contains one or more fatty substances.</p><p> The term "fatty substance" is an organic compound that is insoluble in water (solubility is less than 5%, preferably less than 1%, more preferably 0.1%) at room temperature (25 ° C) and under atmospheric pressure (760 mmHg). Means. The aliphatic substance contains at least one hydrocarbon-based chain having at least 6 carbon atoms or at least 2 contiguous siloxane groups in its structure. In addition, fatty substances are generally soluble in organic solvents such as chloroform, ethanol, benzene, liquid petrolatum or decamethylcyclopentasiloxane under the same temperature and pressure conditions.</p><p> According to the present invention, the fatty substance is selected from compounds that are liquid or pasty at room temperature and atmospheric pressure.</p><p> More specifically, fatty substances are C₆~ C₁₆Selected from lower alkanes, non-silicone oils of animal, plant, mineral or synthetic origin, fatty alcohols, fatty acids, fatty acids and / or esters of fatty alcohols, non-silicone waxes and silicones.</p><p> For the purposes of the present invention, fatty alcohols, fatty esters and fatty acids, more specifically, contain at least linear or branched, saturated or unsaturated hydrocarbon-based groups containing 6 to 30 carbon atoms. It is recalled that it contains one and its groups are optionally substituted by one or more hydroxyl groups (particularly 1 to 4). These compounds, when unsaturated, can contain 1 to 3 conjugated or unconjugated carbon-carbon double bonds.</p><p> C₆~ C₁₆Lower alkanes are linear or branched, and in some cases cyclic. Examples include hexane, undecane, dodecane, tridecane, and isoparaffins such as isohexadecane and isodecan.</p><p> Animal oils, vegetable oils, mineral oils or synthetically derived oils that can be used in the compositions of the present invention include: --Animal-derived hydrocarbon-based oils, such as perhydrosqualene, --Plant or synthetic triglyceride oils, eg liquid fatty acid triglycerides containing 6 to 30 carbon atoms, eg heptanic acid or octanoic acid triglycerides, or eg sunflower oil, corn oil, soybean oil, mallow oil, grapes Seed oil, sesame oil, hazelnut oil, apricot oil, macadamia oil, arara oil, castor oil, avocado oil, capricyl / capric acid triglyceride, for example, products sold by Stearineries Dubois or Miglyol from Dynamit Nobel. ) Products sold under the names 810, 812 and 818 (registered trademarks), jojoba oil and shea butter oil, --- Linear or branched hydrocarbons derived from minerals or synthetics containing more than 16 carbon atoms, such as volatile or non-volatile liquid paraffin, and derivatives thereof, petrolatum, liquid petrolatum, polydecene, eg, Hydrocarbon polyisobutenes such as Parleam®, preferably liquid paraffin, petrolatum, liquid petrolatum, polydecene and hydrogenated polyisobutene, such as Parleam, --Fluoro oil, eg BNFL Perfluoromethylcyclopentane and perfluoro 1,3-dimethylcyclohexane; perfluoro 1,2-dimethylcyclobutane; 3M to PF5050 (registered) sold under the names Flutec® PC1 and Flutec® PC3 by Fluorochemicals. Perfluoroalkanes such as dodecafluoropentane and tetradecafluorohexane sold under the names of Trademark) and PF5060®, or bromoperfluorooctanoic acid sold under the name Foralkyl® from Atochem; nonafluoro Methoxybutane and nonafluoroethoxyisobutane; perfluoromorpholin derivatives such as 4-trifluoromethylperfluoromorpholin sold by 3M under the name PF5052®.</p><p> Fatty alcohols suitable for use in the present invention are more specifically selected from saturated or unsaturated, linear or branched alcohols containing 8 to 30 carbon atoms. Examples may include cetyl alcohol, stearyl alcohol and mixtures thereof (cetylstearyl alcohol), octyldodecanol, 2-butyloctanol, 2-hexyldecanol, 2-undecylpentadecanol, oleyl alcohol or linolyl alcohol. is there.</p><p> Fatty acids that can be used with respect to the present invention are more specifically selected from saturated or unsaturated carboxylic acids containing 6 to 30, especially 9 to 30 carbon atoms. It is advantageous that the carboxylic acid is selected from myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid and isostearic acid.</p><p> Esters of fatty acids and / or esters of fatty alcohols are advantageous when different from the triglycerides described above, especially saturated or unsaturated, linear or branched C.₁~ C₂₆Aliphatic monoacids or polyacids and saturated or unsaturated, linear or branched C₁~ C₂₆Aliphatic monoalcohols or polyalcohols can be mentioned, and the total number of carbon atoms in the ester is 10 or more.</p><p> As monoesters, dihydroabiethylbehenate, octyldodecylbehenate, isosetylbehenate, cetyl lactate, lactate C₁₂~ C₁₅Alkyl, isostearyl lactate, lauryl lactate, linolyl lactate, oleyl lactate, stearyl (iso) octanate, isosetyl octanate, octyl octanate, cetyl octanate, decyl oleate, isosetyl isostearate, isosetyl laurate, isosetyl stearate, Isodecyl octanoate, isodecil oleate, isononyl isononanoate, isostearyl palmitate, methyl acetylricinolenate, myristyl stearate, octyl isononanoate, 2-ethylhexyl isononanoate, octyl palmitate, octyl pelargone, octyl stearate Octyldodecyl acid, oleyl erucate, ethyl and isopropyl palmitate, 2-ethylhexyl palmitate, 2-octyldecyl palmitate, alkyl myristate, such as isopropyl myristearate, butyl myristerate, cetyl myritearate, myristearic acid Examples thereof include hexyl stearate, butyl stearate, isobutyl stearate, dioctyl malate, hexyl laurate, and 2-hexyl decyl laurate, such as 2-octyldodecyl, myristyl millistearate, and stearyl millistearate.</p><p> In addition, in this embodiment, C₄~ C₂₂Dicarboxylic acid or tricarboxylic acid ester and C₁~ C₂₂Alcohol esters, as well as mono-, di- or tricarboxylic acid esters, and C₂~ C₂₆Di-, tri-, tetra- or pentahydroxy alcohol esters can also be used.</p><p> In particular, the following esters can be mentioned: diethyl sebacate, diisopropyl sebatate, diisopropyl adipate, di-n-propyl adipate, dioctyl adipate, diisostearyl adipate, dioctyl maleate, glyceryl undecylate, stearoyl stearate. Octyldodecyl acid, pentaerythritol monoricinoleate, pentaerythritol tetraisononanoate, pentaerythritol tetrapelargonate, pentaerythritol tetraisostearate, pentaerythritol tetraoctanoate, propylene glycol dicaprylate, propylene glycol dicaprate, elca Tridecyl acid, triisopropyl citrate, triisostearyl citrate, glyceryl trilactic acid, glyceryl trioctate, trioctyldodecyl citrate, trioleyl citrate, propylene glycol dioctanoate, neopentyl glycol diheptate, diethylene glycol diisononanoate, and distearate Polyethylene glycol acid acid.</p><p> Among the esters described above, ethyl palmitate, isopropyl palmitate, myristyl palmitate, cetyl palmitate or stearyl palmitate, 2-ethylhexyl palmitate, 2-octyldecyl palmitate, alkyl myristate, such as isopropyl myristate, myristic acid Uses hexyl stearate, butyl stearate, isobutyl stearate, dioctyl malate, hexyl laurate, 2-hexyldecyl laurate, isononyl isononanoate or cetyl octanoate, such as butyl, cetyl myristate or 2-octyldodecyl myristate. It is preferable to do so.</p><p> The composition further comprises C as a fatty ester.₆~ C_30、Preferably C₁₂~ C₂₂It can also contain sugar esters and diesters of fatty acids. Recall that the term "sugar" means an oxygen-bearing hydrocarbon-based compound containing multiple alcohol groups, with or without aldehyde or ketone groups, and containing at least 4 carbon atoms. Will be done. Such sugars can be monosaccharides, oligosaccharides or polysaccharides.</p><p> Examples of suitable sugars that can be mentioned include sucrose (sucrose), glucose, galactose, ribose, fructose, maltose, mannose, arabinose, xylose and lactose, and derivatives thereof, in particular alkyl derivatives such as methyl derivatives. For example, there is methyl glucose.</p><p> Fatty acid sugar esters are linear or branched, saturated or unsaturated C with the above-mentioned sugar esters or mixtures of esters.₆~ C₃₀, Preferably C₁₂~ C₂₂May be specifically selected from the group comprising esters of the fatty acids of the above or mixtures thereof. If unsaturated, these compounds may contain 1 to 3 conjugated or unconjugated carbon-carbon double bonds.</p><p> Esters according to this embodiment can also be selected from mono-, di-, tri-, tetraesters and polyesters, and mixtures thereof.</p><p> These esters are, for example, esters of oleic acid, lauric acid, palmitic acid, mistylic acid, bechenic acid, coconut fatty acid, stearic acid, linoleic acid, linolenic acid, capric acid and arachidonic acid or mixtures thereof, for example, especially oleo. It can be selected from an ester in which palmitic acid, oleic stearic acid and palmitostearic acid are mixed.</p><p> Even more particularly preferred is the use of monoesters and diesters, especially mono-or dioleic acid, stearic acid, bechenic acid, oleopalmitic acid, linoleic acid, linolenic acid and oleostearic acid sucrose, glucose or methyl glucose. Is preferable.</p><p> An example that can be mentioned is a product sold by Amerchol under the name Glucate® DO, which is methyl glucose dioleate.</p><p> Examples of esters or esters of sugars and fatty acids that can be mentioned include: --Products sold by Crodesta under the names F160, F140, F110, F90, F70 and SL40, which are 73% monoester and 27% di and triester, 61% monoester and di, respectively. Formed from tri and tetraester 39%, monoester 52% and di, tri and tetraester 48%, monoester 45% and di, tri and tetraester 55%, monoester 39% and di, tri and tetraester 61% Corresponds to sucrose palmitostearate, and sucrose monolaurate. --Products sold under the name Ryoto Sugar Esters, for example B370, corresponding to sucrose behenate formed from 20% monoester and 80% di-triester-polyester. --Sucrose monodipalmitostearate sold by Goldschmidt under the name Tegosoft® PSE.</p><p> Non-silicone waxes include carnauba wax, candelilla wax, esparto grass wax, paraffin wax, ozokerite, vegetable waxes such as olive wax, rice wax, hydrogenated jojoba wax or pure flower wax ( Absolute wax), for example, animal waxes such as the essence wax of the flower of Kurofusasuri sold by Bertin (France), for example beeswax or modified beeswax (Ceraberina) are particularly selected. Other waxes or waxy starting materials that can be used in accordance with the present invention are, in particular, marine waxes, such as products sold by Sophim under the reference number M82, and polyethylene waxes or polyolefin waxes in general. Is.</p><p> The silicones that can be used in the cosmetic compositions of the present invention are volatile or non-volatile, cyclic, linear or branched silicones that are unmodified or modified with organic groups and at 25 ° C. 5 × 10^-6From 2.5m²/ s, preferably 1x10^-5From 1m²Has a viscosity of / s.</p><p> Silicones that can be used in accordance with the present invention may be in the form of oils, waxes, resins or gums.</p><p> Preferably, the silicone is selected from polydialkylsiloxanes, particularly organically modified polysiloxanes containing at least one functional group selected from polydimethylsiloxane (PDMS) and poly (oxyalkylene) groups, amino groups and alkoxy groups. To.</p><p> Organopolysiloxane is defined in detail by Walter Noll, "Chemistry and Technology of Silicones" (1968), Academic Press. The organopolysiloxane may be volatile or non-volatile.</p><p> In the case of volatile, silicone is selected from those having a boiling point between 60 ° C and 260 ° C, more specifically, and more specifically from:</p><p> (i) Cyclic polydialkylsiloxane having 3 to 7 silicon atoms, preferably 4 to 5 silicon atoms. These are, for example, octamethylcyclotetrasiloxane sold by Union Carbide under the name Volatile Silicone® 7207 and by Rhodia under the name Silbione® 70045 V2, from Union Carbide. Decamethylcyclopentasiloxane sold under the name Volatile Silicone® 7158 and from Rhodia under the name Silbione® 70045 V5, and mixtures thereof.</p><p> Also, dimethylsiloxane / methylalkylsiloxane type cyclopolymers, such as the following chemical structures:</p><p><chemistry num="1"><img file="JP2010143920A_D0001.tif" /></chemistry></p><p> Volatile Silicone® FZ3109 sold by Union Carbide can also be mentioned.</p><p> Also, a mixture of cyclic polydialkylsiloxane with an organosilicon compound, such as a mixture of octamethylcyclotetrasiloxane and tetratrimethylsilylpentaerythritol (50/50), and octamethylcyclotetrasiloxane and oxy-1,1'-bis (50/50). A mixture of 2,2,2', 2', 3,3'-hexatrimethylsilyloxy) neopentane can be mentioned.</p><p> (ii) It has 2 to 9 silicon atoms and is 5 × 10 at 25 ° C.^-6m²A linear volatile polydialkylsiloxane with a viscosity of / s or less. An example is decamethyltetrasiloxane, which is sold under the name SH200 by Toray Silicone. Silicones in this category are also found in Cosmetics and Toiletries, Vol. 91, January, 76, pp. 27-32, Todd and Byers, Volatile Silicone Fluids for Cosmetics. Has been described.</p><p> Preferably, non-volatile polydialkylsiloxanes, polydialkylsiloxane gums and resins, polyorganosiloxanes modified with the above-mentioned organofunctional groups, and mixtures thereof are used.</p><p> These silicones are particularly selected from polydialkylsiloxanes and can mainly include polydimethylsiloxanes containing a trimethylsilyl terminal group. Silicone viscosities are measured at 25 ° C, for example, according to ASTM Standard 445 Annex C.</p><p> Among these polyalkylsiloxanes, the following commercial products can be mentioned, but not limited to: --Silbione® or Mirasil® oils of the 47 and 70047 series sold by Rhodia, eg Oil 70047V500000, --Mirasil® series oils sold by Rhodia, --Dow Corning 200 Series Oils, For example 60000mm²DC200 with viscosity of / s, etc. --General Electric's Viscasil® oils and certain oils from General Electric's SF series (SF96, SF18).</p><p> Also mentioned are polydimethylsiloxanes containing dimethylsilanol end groups, known by the name dimethiconol (CTFA), such as Rhodia's 48 series oils.</p><p> Polyalkylsiloxanes in this category can also include products sold by Goldschmidt under the names Abil Wax® 9800 and 9801, which are poly (C).₁~ C₂₀) Dialkylsiloxane.</p><p> Silicone gums that can be used in accordance with the present invention are particularly preferably polydialkylsiloxanes, preferably polydimethylsiloxanes, with a large number average molecular weight of 200,000 to 1000000, which are used alone or as a mixture in a solvent. The solvent can be selected from volatile silicone, polydimethylsiloxane (PDMS) oil, polyphenylmethylsiloxane (PPMS) oil, isoparaffin, polyisobutylene, methylene chloride, pentane, dodecane and tridecane, or mixtures thereof.</p><p> Products that can be used in accordance with the present invention are, more specifically, mixtures such as: A mixture formed from polydimethylsiloxane with hydroxylated chain ends, dimethiconol (CTFA), and cyclic polydimethylsiloxane, also known as cyclomethicone (CTFA), sold by Dow Corning, for example. Product Q2 1401. --A mixture formed from cyclic silicone and polydimethylsiloxane gum, such as General Electric's product, SF1214 Silicone Fluid. This product is obtained by dissolving SF30 gum corresponding to dimethicone having a number average molecular weight of 500000 in SF1202 Silicone Fluid oil corresponding to decamethylcyclopentasiloxane. --Two PDMS with different viscosities, especially a mixture of PDMS gum and PDMS oil, eg SF1236, a product of General Electric. Product SF1236 is 20m²The above-mentioned gum SE30 with a viscosity of / s and 5 × 10^-6m²It is a mixture with oil SF96 having a viscosity of / s. This product preferably contains 15% SE30 gum and 85% SF96 oil.</p><p> Organopolysiloxane resins that can be used in accordance with the present invention have the following units, R, where R represents an alkyl containing 1 to 16 carbon atoms.₂SiO_2/2, R₃SiO_1/2, RSiO_3/2And SiO_4/2It is a crosslinked siloxane system containing. Of these products, R is C, which is particularly preferred.₁~ C₄It represents a lower alkyl group, more specifically methyl.</p><p> Among these resins are products sold under the name Dow Corning 593 or products sold by General Electric under the names Silicone Fluid SS4230 and SS4267, which have a dimethyl / trimethylsiloxane structure. It is silicone.</p><p> In particular, trimethylsiloxysilicate type resins sold by Shin-Etsu Chemical Co., Ltd. under the names of X22-4914, X21-5034 and X21-5037 can be mentioned.</p><p> The organically modified silicone that can be used in accordance with the present invention is the silicone described above that contains one or more organic functional groups attached to its structure via a hydrocarbon base group.</p><p> In addition to the above-mentioned silicones, the organically modified silicones can also be polydiarylsiloxanes functionalized with the above-mentioned organically modifying groups, particularly polydiphenylsiloxanes and polyalkylarylsiloxanes.</p><p> Polyalkylarylsiloxanes are, in particular, 1 × 10 at 25 ° C.^-5From 5x10^-2m²It is selected from linear and / or branched polydimethylsiloxane / methylphenylsiloxane and polydimethylsiloxane / diphenylsiloxane with a viscosity of / s.</p><p> Among these polyalkylarylsiloxanes, examples that can be mentioned are products sold under the following names: --Rhodia 70641 Series Silbone® Oil, --Rhodia Rhodorsil® 70633 and 763 series oils, --Dow Corning 556 Cosmetic Grade Fluid Oil, --Bayer PK series silicones, such as product PK20, --Bayer PN and PH series silicones, such as products PN1000 and PH1000, --Some oils from General Electric's SF series, such as SF1023, SF1154, SF1250 and SF1265.</p><p> Among the organically modified silicones, the following polydiorganosiloxanes can be mentioned: --C₆~ C₂₄Silwet from Union Carbide, an optional product with an alkyl group, having a polyethylene oxy and / or a polypropylene oxy group, eg, a product known as dimethicone copolyol sold by Dow Corning under the name DC1248. (Registered Trademarks) L 722, L7500, L77 and L11 oils, and sold by Dow Corning under the name Q2 5200, (C₁₂) Alkylmethicone copolyol, --Products with substituted or unsubstituted amine groups, such as products sold by Genesee under the names GP4 Silicone Fluid and GP7100, or sold by Dow Corning under the names Q2 8220 and Dow Corning 929 or 939. The product you have. Substituted amine groups are especially C₁~ C₄It is an aminoalkyl group. --Products containing an alkoxylated group, such as products sold by SWS Silicones under the name Silicone Copolymer F-755, and Goldschmidt's Abil Wax® 2428, 2434 and 2440.</p><p> Preferably, the fatty substance is C₂~ C₃Contains neither oxyalkylene units nor glycerol units.</p><p> More specifically, the fatty substance is selected from liquid or pasty compounds at room temperature and atmospheric pressure.</p><p> Preferably, the fatty substance is a compound that is liquid at a temperature of 25 ° C. under atmospheric pressure.</p><p> More specifically, fatty substances are other than fatty acids.</p><p> The fatty substance is preferably C₆~ C₁₆Lower Alcans, non-silicone oils derived from plants, minerals or synthetics, fatty alcohols, esters of fatty acids and / or fatty alcohols, and silicones, or mixtures thereof; and preferably C.₆~ C₁₆It is selected from lower alkanes, non-silicone oils derived from plants, minerals or synthetics, fatty alcohols, esters of fatty acids and / or fatty alcohols, or mixtures thereof.</p><p> Preferably, the fatty material is selected from liquid petrolatum, polydecene and liquid esters of fatty acids and / or fatty alcohols, or mixtures thereof.</p><p> Anhydrous cosmetic compositions are advantageously 10% to 99% by weight, preferably 20% to 90% by weight, and more preferably 25% to 80% by weight, based on the weight of the anhydrous composition. Has a fatty substance content of.</p><p> The cosmetic anhydrous composition (A) also contains one or more surfactants.</p><p> Preferably, the surfactant is selected from nonionic and anionic surfactants.</p><p> Anionic surfactants are, more specifically, from salts of the following compounds (particularly alkali metal salts, especially sodium salts, ammonium salts, amine salts, amino alcohol salts or alkaline earth metal salts, such as magnesium salts). Selected: --Alkyl sulphate, alkyl ether sulphate, alkyl amide ether sulphate, alkylaryl polyether sulphate, monoglyceride sulphate, --Alkyl sulfonate, alkyl amide sulfonate, alkylaryl sulfonate, α-olefin sulfonate, paraffin sulfonate, --Alkyl phosphate, Alkyl phosphate ether, --Alkyl sulfosuccinate, alkyl ether sulfosuccinate, alkylamide sulfosuccinate, --Alkyl sulfoacetate, --Acyl sarcosinate, acylisethionate and N-acyl taurate, Fatty acids such as oleic acid, ricinoleic acid, palmitic acid or stearic acid, coconut oil acid or hydrogenated coconut oil acid salt, --Alkyl-D-galactodosideuronate, --Acyllactilate, --- Salts of polyoxyalkyleneized alkyl ether carboxylic acids, polyoxyalkyleneized alkylaryl ether carboxylic acids or polyoxyalkyleneed alkylamide ether carboxylic acids, especially those containing 2 to 50 ethylene oxide groups. -And their mixture.</p><p> Note that the alkyl or acyl groups of these various compounds advantageously contain 6 to 24, preferably 8 to 24 carbon atoms, and the acyl group preferably represents a phenyl or benzyl group. Should.</p><p> The nonionic surfactant is selected from, more specifically, monooxyalkyleneed or polyoxyalkyleneed, monoglycerolized or polyglycerolized, nonionic surfactants. More specifically, the oxyalkylene unit is oxyethylene or oxypropylene unit, or a combination thereof, and is preferably an oxyethylene unit.</p><p> Examples of oxyalkyleneized nonionic surfactants that can be mentioned include, among others, alone or as a mixture: Oxyalkyleneization (C₈~ C₂₄) Alkylphenol, Saturated or unsaturated, linear or branched oxyalkyleneized C₈~ C₃₀alcohol, Saturated or unsaturated, linear or branched oxyalkyleneized C₈~ C₃₀Amide, Saturated or unsaturated, linear or branched C₈~ C₃₀Acid and polyethylene glycol ester, Saturated or unsaturated, linear or branched C₈~ C₃₀Acid and sorbitol polyoxyethylene ester, Saturated or unsaturated oxyethylene vegetable oil, -Ethylene oxide and / or propylene oxide condensate.</p><p> Surfactants contain ethylene oxide and / or propylene oxide in a constant molar number between 1 and 100, preferably between 2 and 50. It is advantageous that the ionic surfactant does not contain oxypropylene units.</p><p> In one preferred embodiment of the invention, the oxyalkyleneized nonionic surfactant contains 1 to 100 moles of ethylene oxide, oxyethyleneated C.₈~ C₃₀Saturated or unsaturated, linear or branched C containing alcohol, as well as 1 to 100 moles of ethylene oxide₈~ C₃₀It is selected from polyoxyethyleneated esters of acid and sorbitol.</p><p> Monoglycerolization or polyglycerolization Examples of nonionic surfactants are monoglycerolization or polyglycerolation C.₈~ C₄₀Alcohol is preferably used.</p><p> In particular, monoglycerol or polyglycerolized C₈~ C₄₀Alcohol corresponds to the following formula: RO- [CH₂-CH (CH)₂OH) -O]_m-H However, R is a linear or branched C.₈~ C₄₀, Preferably C₈~ C₃₀Represents an alkyl or alkenyl group of, m represents a number from 1 to 30, preferably a number from 1 to 10.</p><p> Examples of compounds suitable for use in the present invention are lauryl alcohol containing 4 mol of glycerol (INCI name: polyglyceryl-4 lauryl ether), lauryl alcohol containing 1.5 mol of glycerol, and oleyl alcohol containing 4 mol of glycerol. (INCI name: polyglyceryl-4 oleyl ether), oleyl alcohol containing 2 mol of glycerol (INCI name: polyglyceryl-2 oleyl ether), cetearyl alcohol containing 2 mol of glycerol, cetearyl alcohol containing 6 mol of glycerol, Examples include oleocetyl alcohol containing 6 mol of glycerol and octadecanol containing 6 mol of glycerol.</p><p> Alcohol represents a mixture of alcohols, just as the value of m represents a statistic. This means that in commercial products, multiple types of polyglycerolated fatty alcohols can be present simultaneously in the form of a mixture.</p><p> Among monoglycerolized or polyglycerolated alcohols, C containing 1 mol of glycerol₈/ C₁₀C containing 1 mol of alcohol and glycerol₁₀/ C₁₂C containing 1.5 mol of alcohol and glycerol₁₂It is even more preferred to use alcohol.</p><p> Preferably, the surfactant present in the anhydrous composition is a nonionic surfactant.</p><p> More specifically, the surfactant content contained in the anhydrous composition occupies 0.1% by weight to 50% by weight, preferably 0.5% by weight to 30% by weight, based on the weight of the anhydrous composition.</p><p> The composition (A) further contains monoethanolamine and one or more basic amino acids.</p><p> Basic amino acids that can be used in the context of the present invention are selected, more specifically, from those in which the ring or ureido functional group contains an additional amine functional group optionally contained.</p><p> Such basic amino acids are preferably selected from those corresponding to formula (I) below:</p><p><chemistry num="2"><img file="JP2010143920A_D0002.tif" /></chemistry></p><p> However, R represents a group selected from:</p><p><chemistry num="3"><img file="JP2010143920A_D0003.tif" /></chemistry></p><p> The compounds corresponding to formula (I) are histidine, lysine, arginine, ornithine and citrulline, preferably arginine, lysine and histidine, or mixtures thereof.</p><p> It is advantageous that the composition (A) has a monoethanolamine content in the range of 0.1% by weight to 40% by weight, preferably 0.5% by weight to 20% by weight, based on the weight of the composition.</p><p> With respect to the content of basic amino acids, this is more particularly in the range of 0.1% to 40% by weight, preferably 0.5% to 20% by weight, based on the weight of the composition.</p><p> Note that in one particularly advantageous embodiment, the weight ratio of monoethanolamine / basic amino acid is preferably in the range of 0.1 to 10, more preferably 0.3 to 10, and even more preferably 1 to 5. Should be.</p><p> Cosmetic compositions (A) are anionic, cationic, nonionic, amphoteric or zwitterionic polymers or mixtures thereof, inorganic thickeners, and especially fillers, such as clays, talc, etc., especially anions. Organic thickeners, antioxidants, penetrants, sequestrants, fragrances, dispersants, film-forming agents, ceramides, containing sex, cationic, nonionic and zwitterionic polymer binding thickeners, Various auxiliary agents conventionally used in hair dye compositions such as conditioners, preservatives and opalescents can also be included.</p><p> The above-mentioned auxiliaries are generally present in an amount of 0.01 to 20% by weight, respectively, based on the weight of the composition (A).</p><p> The composition can also contain one or more inorganic thickeners selected from organic affinity clay, fumed silica, or mixtures thereof.</p><p> The organic affinity clay can be selected from montmorillonite, bentonite, hectorite, attapargite, sepiolite, and mixtures thereof. The clay is preferably bentonite or hectorite.</p><p> These clays are modified with quaternary amines, tertiary amines, amine acetates, imidazolines, amine soaps, fatty sulfates, alkylaryl sulfonates and amine oxides, and chemical compounds selected from mixtures thereof. Can be quality.</p><p> Organic affinity clays that can be mentioned include quaternium-18 bentonite, such as those sold by Rheox under the names Bentone 3, Bentone 38 and Bentone 38V, United Catalyst's Tixogel VP, Southern Clay. Steer such as those sold by Claytone 34, Claytone 40 and Claytone XL, Bentonite 27 from Rheox, Tixogel LG from United Catalyst, and Claytone AF and Claytone APA from Southern Clay. Larconium Bentonite, Quarternium-18 / Benzarconium Bentonite, such as those sold by Southern Clay under the names Claytone HT and Claytone PS, Bentone Gel ODA, Bentone Gel ECO5, Bentone Gel EUG, Bentone Gel from Rheox IPP, Bentonite Gel ISD, Bentonite Includes quarternium-18 hectorite, such as those sold by Biophil under the names Simagel M and Simagel SI 345 under the names Gel SS71, Bentone Gel VS8 and Bentone Gel VS38.</p><p> Humed silica can be obtained by high temperature hydrolysis of a volatile silicon compound in an oxyhydrogen flame to produce finely dispersed silica. This method makes it possible to obtain hydrophilic silica with a large number of silanol groups, especially on this surface. Such hydrophilic silicas are available, for example, from Degussa, Aerosil 130®, Aerosil 200®, Aerosil 255®, Aerosil 300® and Aerosil 380®, and Cabot. Depending on the company, Cab-O-Sil HS-5 (registered trademark), Cab-O-Sil EH-5 (registered trademark), Cab-O-Sil LM-130 (registered trademark), Cab-O-Sil MS-55 ( It is sold under the names of (registered trademark) and Cab-O-Sil M-5 (registered trademark).</p><p> The surface of silica can be chemically modified by a chemical reaction that reduces the number of silanol groups. It is particularly possible to replace the silanol group with a hydrophobic group, then hydrophobic silica is obtained.</p><p> Hydrophobic groups can be: A trimethylsiloxyl group, which is obtained by treating fumed silica, in particular in the presence of hexamethyldisilazane. Silica treated in this way is known by CTFA (6th edition, 1955) as "silica sililate". They are sold, for example, by Degussa under the reference code Aerosil R812® and Cabot under the reference code Cab-O-Sil TS-530®. --Dimethylsilyloxyl or polydimethylsiloxane group, which is obtained by treating fumed silica, in particular in the presence of polydimethylsiloxane or dimethyldichlorosilane. The silica treated in this way is known by CTFA (6th edition, 1995) as "silica dimethyl silylate". These are, for example, reference codes for Aerosil R972® and Aerosil R974® from Degussa and Cab-O-Sil TS-610® and Cab-O-Sil TS-720 from Cabot. Sold under a (registered trademark) reference code.</p><p> Humed silica preferably has a particle size that may range from nanometers to micrometers, eg, about 5 to 200 nm.</p><p> Preferably, the composition contains hectorite, organically modified bentonite or optionally modified fumed silica.</p><p> Inorganic thickeners, if present, account for 1% to 30% by weight of the weight of the composition.</p><p> The composition may also contain one or more organic thickeners.</p><p> These thickeners include fatty acid amides (coconut monoethanolamide or diethanolamide, oxyethylated alkyl ether carboxylic acid monoethanolamide), polymeric thickeners, such as cellulose-based thickeners (hydroxyethyl cellulose, hydroxypropyl). Cellulose or Carboxymethyl Cellulose), Guar Gum and Derivatives thereof (Hydroxypropyl Guar), Microbial Derived Gum (Xanthan Gum, Sclerogulcan Gum), Acrylic Acid or acrylamide Propanosulfonic Acid Crosslinked Homopolymers and Associated Polymers (in Aqueous Medium) Can be selected from polymers with hydrophilic regions and hydrophobic regions of the fatty chain (alkyl or alkenyl having at least 10 carbon atoms) that can reversibly bind to each other or to other molecules. ..</p><p> In one particular embodiment, the organic thickener is a cellulose-based thickener (hydroxyethyl cellulose, hydroxypropyl cellulose or carboxymethyl cellulose), guar gum and derivatives thereof (hydroxypropyl guar), gums derived from microorganisms. (Xanthan gum, screlogulcan gum) and acrylic acid or acrylamide propanesulfonic acid crosslinked homopolymers, preferably those containing cellulose-based thickeners, especially hydroxyethyl cellulose.</p><p> If an organic thickener is present, its content is typically in the range of 0.01% to 20% by weight, preferably 0.1% by weight to 5% by weight, based on the weight of the composition. ..</p><p> The composition (A) is preferably in the form of a gel or cream.</p><p> If the method according to the invention is a dyeing method, this is done in the presence of a composition (C1) containing one or more oxidative dyes and / or direct dyes.</p><p> Oxidation dyes are generally selected from one or more oxidation bases, which may be combined with one or more coupling agents.</p><p> For example, the oxidation base is selected from para-phenylenediamine, bis (phenyl) alkylenediamine, para-aminophenol, ortho-aminophenol and heterocyclic bases, and their addition salts.</p><p> Para-phenylenediamines that can be mentioned include, for example, para-phenylenediamine, para-toluenediamine, 2-chloro-para-phenylenediamine, 2,3-dimethyl-para-phenylenediamine, 2,6-dimethyl-para. -Phenylenediamine, 2,6-diethyl-para-phenylenediamine, 2,5-dimethyl-para-phenylenediamine, N, N-dimethyl-para-phenylenediamine, N, N-diethyl-para-phenylenediamine, N, N-dipropyl-para-phenylenediamine, 4-amino-N, N-diethyl-3-methylaniline, N, N-bis (β-hydroxyethyl) -para-phenylenediamine, 4-N, N-bis (β) -Hydroxyethyl) Amino-2-methylaniline, 4-N, N-bis (β-hydroxyethyl) amino-2-chloroaniline, 2-β-hydroxyethyl-para-phenylenediamine, 2-fluoro-para-phenylene Diamine, 2-isopropyl-para-phenylenediamine, N- (β-hydroxypropyl) -para-phenylenediamine, 2-hydroxymethyl-para-phenylenediamine, N, N-dimethyl-3-methyl-para-phenylenediamine, N, N- (β-Hydroxyethyl) -para-phenylenediamine, N- (β, γ-dihydroxypropyl) -para-phenylenediamine, N- (4'-aminophenyl) -para-phenylenediamine, N-phenyl -Para-Phenylenediamine, 2-β-Hydroxyethyloxy-Para-Phenylenediamine, 2-β-Acetylaminoethyloxy-Para-Phenylenediamine, N- (β-methoxyethyl) -Para-Phenylenediamine, 4-Amino There are phenylpyrrolidine, 2-thienyl-para-phenylenediamine, 2-β-hydroxyethylamino-5-aminotoluene and 3-hydroxy-1- (4'-aminophenyl) pyrrolidine, and their acid addition salts.</p><p> Among the above-mentioned para-phenylenediamines, para-phenylenediamine, para-toluylenediamine, 2-isopropyl-para-phenylenediamine, 2-β-hydroxyethyl-para-phenylenediamine, 2-β-hydroxyethyloxy-para -Phenylene-diamine, 2,6-dimethyl-para-phenylenediamine, 2,6-diethyl-para-phenylenediamine, 2,3-dimethyl-para-phenylenediamine, N, N-bis (β-hydroxyethyl)- Para-phenylenediamine, 2-chloro-para-phenylenediamine and 2-β-acetylaminoethyloxy-para-phenylenediamine, and acid-added salts thereof are particularly preferred.</p><p> Examples of bis (phenyl) alkylenediamines that can be mentioned include N, N'-bis (β-hydroxyethyl) -N, N'-bis (4'-aminophenyl) -1,3-diamino-propanol. N, N'-bis (β-hydroxyethyl) -N, N'-bis (4'-aminophenyl) ethylenediamine, N, N'-bis (4-aminophenyl) tetramethylenediamine, N, N'-bis (β-Hydroxyethyl) -N, N'-bis (4-aminophenyl) tetramethylenediamine, N, N'-bis (4-methylaminophenyl) tetra-methylenediamine, N, N'-bis (ethyl) -N, N'-bis (4'-amino-3'-methylphenyl) ethylene-diamine and 1,8-bis (2,5-diaminophenoxy) -3,6-dioxaoctane, and their addition salts is there.</p><p> Para-aminophenols that can be mentioned include, for example, para-aminophenol, 4-amino-3-methylphenol, 4-amino-3-fluorophenol, 4-amino-3-hydroxymethylphenol, 4-amino-. 2-Methylphenol, 4-amino-2-hydroxymethylphenol, 4-amino-2-methoxymethylphenol, 4-amino-2-aminomethylphenol, 4-amino-2- (β-hydroxyethylaminomethyl) phenol And 4-amino-2-fluorophenol, as well as acid addition salts thereof.</p><p> Ortho-aminophenols that can be mentioned include, for example, 2-aminophenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol and 5-acetamido-2-aminophenol, and their addition salts. There is.</p><p> Heterocyclic bases that can be mentioned include, for example, pyridine derivatives, pyrimidine derivatives and pyrazole derivatives.</p><p> Pyridine derivatives that can be mentioned include, for example, the compounds described in patents GB1026978 and GB1153196, such as 2,5-diaminopyridine, 2- (4-methoxyphenyl) amino-3-aminopyridine and 3,4-. There are diaminopyridines, as well as their addition salts.</p><p> Other pyridine oxidation bases useful in the present invention are, for example, the 3-aminopyrazolo [1,5-a] pyridine oxidation bases described in patent application FR2801308 or their addition salts. Examples that can be mentioned are pyrazolo [1,5-a] pyrido-3-ylamine, 2-acetylaminopyrazolo [1,5-a] pyrido-3-ylamine, 2-morpholin-4-ylpyrazolo [1]. , 5-a] pyrido-3-ylamine, 3-amino-pyrazolo [1,5-a] pyridin-2-carboxylic acid, 2-methoxypyrazolo [1,5-a] pyrido-3-yl-amine, (3-Aminopyrazolo [1,5-a] Pyridine-7-yl) Methanol, 2- (3-Aminopyrazolo [1,5-a] Pyridine-5-yl) Ethanol, 2- (3-Aminopyrazolo [1,5] -a] pyrido-7-yl) ethanol, (3-amino-pyrazolo [1,5-a] pyrido-2-yl) methanol, 3,6-diaminopyrazolo [1,5-a] pyridine, 3, 4-Diaminopyrazolo [1,5-a] pyridine, pyrazolo [1,5-a] pyridine-3,7-diamine, 7-morpholin-4-ylpyrazolo [1,5-a] pyrido-3-ylamine, Pyrazolo [1,5-a] Pyridine-3,5-diamine, 5-morpholin-4-ylpyrazolo [1,5-a] Pyrido-3-ylamine, 2-[(3-Aminopyrazolo [1,5-a]] Pyridine-5-yl) (2-hydroxyethyl) amino] ethanol, 2-[(3-aminopyrazolo [1,5-a] pyrido-7-yl) (2-hydroxyethyl) amino] ethanol, 3-aminopyrazolo [ 1,5-a] Pyridine-5-ol, 3-aminopyrazolo [1,5-a] Pyridine-4-ol, 3-aminopyrazolo [1,5-a] Pyridine-6-ol and 3-aminopyrazolo [1,5-a] There are 5-a] pyridine-7-ol, as well as its addition salts.</p><p> Examples of pyrimidine derivatives include the compounds described in Patent DE2359399, JP88-169571, JP05-63124, EP0770375 or Patent Application WO 96/15765, such as 2,4,5,6-tetraaminopyrimidine, 4-hydroxy-. 2,5,6-triaminopyrimidine, 2-hydroxy-4,5,6-triaminopyrimidine, 2,4-dihydroxy-5,6-diaminopyrimidine and 2,5,6-triaminopyrimidine, and theirs. It is a reciprocal form when an addition salt and a remutable equilibrium are present.</p><p> Examples of pyrazole derivatives include the compounds described in patents DE3843892 and DE4133957, as well as patent applications WO94 / 08969, WO94 / 08970, FR-A-2733749 and DE19543988, such as 4,5-diamino-1-methylpyrazole. 4,5-diamino-1- (β-hydroxyethyl) pyrazole, 3,4-diaminopyrazole, 4,5-diamino-1- (4'-chlorobenzyl) -pyrazole, 4,5-diamino-1,3 -Dimethylpyrazole, 4,5-diamino-3-methyl-1-phenyl-pyrazole, 4,5-diamino-1-methyl-3-phenylpyrazole, 4-amino-1,3-dimethyl-5-hydradinopyrazole , 1-benzyl-4,5-diamino-3-methylpyrazole, 4,5-diamino-3-tert-butyl-1-methylpyrazole, 4,5-diamino-1-tert-butyl-3-methylpyrazole, 4,5-diamino-1- (β-hydroxyethyl) -3-methylpyrazole, 4,5-diamino-1-ethyl-3-methylpyrazole, 4,5-diamino-1-ethyl-3- (4' -Methoxyphenyl) pyrazole, 4,5-diamino-1-ethyl-3-hydroxymethylpyrazole, 4,5-diamino-3-hydroxymethyl-1-methylpyrazole, 4,5-diamino-3-hydroxymethyl-1 -Isopropylpyrazole, 4,5-diamino-3-methyl-1-isopropylpyrazole, 4-amino-5- (2'-aminoethyl) amino-1,3-dimethylpyrazole, 3,4,5-triaminopyrazole , 1-Methyl-3,4,5-Triaminopyrazole, 3,5-diamino-1-methyl-4-methylaminopyrazole and 3,5-diamino-4- (β-hydroxyethyl) amino-1-methyl There is pyrazole, as well as its additional salts. 4,5-Diamino-1- (β-methoxyethyl) pyrazole can also be used.</p><p> Preferably, 4,5-diaminopyrazole is used, and more preferably 4,5-diamino-1- (β-hydroxyethyl) pyrazole and / or salts thereof are used.</p><p> Further mentioned pyrazole derivatives include diamino-N, N-dihydropyrazolopyrazolone, particularly those described in patent application FR-A-2886136, such as the following compounds and their addition salts: 2 , 3-Diamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazole-1-one, 2-amino-3-ethyl-amino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazole-1-one, 2-amino-3-isopropyl-amino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazole-1-one, 2-amino -3- (Pyrrolidine-1-yl) -6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazole-1-one, 4,5-diamino-1,2-dimethyl-1,2 -Dihydropyrazole-3-one, 4,5-diamino-1,2-diethyl-1,2-dihydropyrazole-3-one, 4,5-diamino-1,2-di- (2-hydroxyethyl)- 1,2-Dihydropyrazole-3-one, 2-amino-3- (2-hydroxy-ethyl) amino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazole-1-one, 2-Amino-3-dimethylamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazole-1-one, 2,3-diamino-5,6,7,8-tetrahydro-1H , 6H-pyridadino [1,2-a] pyrazole-1-one, 4-amino-1,2-diethyl-5- (pyrrolidin-1-yl) -1,2-dihydropyrazole-3-one, 4- Amino-5- (3-dimethylaminopyrrolidin-1-yl) -1,2-diethyl-1,2-dihydropyrazole-3-one, 2,3-diamino-6-hydroxy-6,7-dihydro-1H , 5H-pyrazolo [1,2-a] pyrazole-1-one.</p><p> 2,3-Diamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazole-1-one and / or salts thereof are preferably used.</p><p> Preferred heterocyclic bases include 4,5-diamino-1- (β-hydroxyethyl) pyrazole and / or 2,3-diamino-6,7-dihydro-1H, 5H-pyrazolo [1, 2-a] Pyrazole-1-one and / or salts thereof are included.</p><p> The compositions of the present invention may also include one or more coupling agents selected to be advantageous from those conventionally used for dyeing keratin fibers.</p><p> Among these coupling agents, among others, meta-phenylenediamine, meta-aminophenol, meta-diphenol, naphthalene-based coupling agents and heterocyclic coupling agents, and their addition salts can be mentioned. ..</p><p> For example, 1,3-dihydroxybenzene, 1,3-dihydroxy-2-methylbenzene, 4-chloro-1,3-dihydroxybenzene, 2,4-diamino-1- (β-hydroxyethyloxy) benzene, 2- Amino-4- (β-hydroxyethylamino) -1-methoxybenzene, 1,3-diaminobenzene, 1,3-bis (2,4-diaminophenoxy) propane, 3-ureidaniline, 3-ureido-1- Dimethylaminobenzene, sesamole, 1-β-hydroxyethylamino-3,4-methylenedioxybenzene, a-naphthol, 2-methyl-1-naphthol, 6-hydroxyindole, 4-hydroxyindole, 4-hydroxy-N -Methylindol, 2-amino-3-hydroxypyridine, 6-hydroxybenzomorpholine, 3,5-diamino-2,6-dimethoxypyridine, 1-N- (β-hydroxyethyl) amino-3,4-methylenedi Oxybenzene, 2,6-bis (β-hydroxyethylamino) toluene, 6-hydroxyindolin, 2,6-dihydroxy-4-methylpyridine, 1-H-3-methylpyrazole-5-one, 1-phenyl- 3-Methylpyrazole-5-one, 2,6-dimethylpyrazolo [1,5-b] -1,2,4-triazole, 2,6-dimethyl- [3,2-c] -1,2, Examples thereof include 4-triazole and 6-methylpyrazolo [1,5-a] benzoimidazole, their acid addition salts, and mixtures thereof.</p><p> In general, the oxidation base and coupling addition salts that can be used in the present invention are, among other things, hydrochlorides, hydrobromates, sulfates, citrates, succinates, tartrates, lactates, tosyls. It is selected from acid addition salts such as acid salts, benzene sulfonates, phosphates and acetates.</p><p> Each oxidation base is preferably 0.0001% to 10% by weight, preferably 0.005% to 5% by weight, based on the total weight of the composition.</p><p> If a coupling agent is present, its content is preferably 0.0001% to 10% by weight, respectively, based on the total weight of the composition, and 0.005% by weight, based on the total weight of the composition. It is preferably from% to 5% by weight.</p><p> For direct dyes, these dyes are more specifically selected from ionic and non-ionic species, preferably from cationic or non-ionic species.</p><p> Examples of suitable direct dyes that can be mentioned are the following direct dyes: azo dyes, methine dyes, carbonyl dyes, azine dyes, nitro (hetero) aryl dyes, tri (hetero) arylmethanes, alone or in admixture. Dyes, porphyrin dyes, phthalocyanine dyes and natural direct dyes.</p><p> More specifically, azo dyes contain -N = N-functional groups, in which two nitrogen atoms do not bond to one ring at the same time. However, it is not excluded that one of the two nitrogen atoms in the -N = N- sequence is bound to the ring.</p><p> Methine dyes are, more specifically, compounds having at least one sequence selected from&gt; C = C &lt;and -N = C &lt;, in which two atoms do not bond to one ring at the same time. However, it should be pointed out that one of the nitrogen or carbon atoms in the sequence can be attached to the ring. More specifically, the dyes of this system are methine, azomethine, mono- and diarylmethane, indamine (or diphenylamine), indophenol, indoaniline, carbocyanine, azacarbocyanine and their isomers, diazacarbocyanine. And their isomers, derived from compounds of the type such as tetraazacarbocyanine, and hemicianin.</p><p> For carbonyl dyes, examples of carbonyl dyes include acridone, benzoquinone, anthraquinone, naphthoquinone, benzanthrone, anthraquinone, pyrantron, pyrazole anthrone, pyrimidino anthrone, flavantron, idantron, flavon, (iso) biolantron. , Isoindolinone, benzimidazolone, isoquinolinone, anthrapyridone, pyrazoloquinazolone, perinone, quinacridone, quinophthalone, indigoid, thioindigo, naphthalimide, anthrapyrimidine, diketopyrrolopyrrole and coumarin.</p><p> Examples of cyclic azine dyes include azine, xanthene, thioxanthene, fluorindin, acridine, (di) oxazine, (di) thiazine and pyronin.</p><p> The nitro (hetero) aromatic dye is, more specifically, a nitrobenzene or nitropyridine direct dye.</p><p> For porphyrin or phthalocyanine type dyes, it is possible to use cationic or non-cationic compounds, optionally containing one or more metals or metal ions, such as alkali metals, alkaline earth metals, zinc and silicon. Is.</p><p> Examples of particularly suitable direct dyes that can be mentioned are nitrobenzene dyes, azo direct dyes, azomethine direct dyes, methine direct dyes, azacarbocyanine direct dyes, eg, tetraazacarbocyanine (tetraazapentamethine), either alone or as a mixture. ), Kinones, in particular anthraquinone, naphthoquinone or benzoquinone substantive dyes, azine, xanthene, triallylmethane, indamine, indigoid, phthalocyanine and porphyrin substantive dyes, as well as natural substantive dyes.</p><p> These dyes can be single chromophore dyes (ie containing only one dye) or multiple chromophores, preferably two or three chromophores, even if the chromophores are the same. They may be different, may or may not be derived from the same chromophore. It should be noted that each polychromatic dye contains multiple radicals derived from molecules that absorb in the visible light range of 400 to 800 nm. Moreover, this absorption of the dye does not require prior oxidation or combination with other species.</p><p> In the case of polychromophore dyes, the chromophores are attached to each other via at least one linker, which can be cationic or non-cationic.</p><p> Preferably, the linker is a linear, branched or cyclic C₁~ C₂₀Alkyl chain of, at least one heteroatom (such as nitrogen or oxygen), and / or at least one group containing such an atom (CO, SO)₂) Is inserted in the optional choice, and at least one heterocycle that may or may not be condensed to the phenyl nucleus is inserted in the optional choice, and at least one quaternary nitrogen atom bonded to the above ring and at least one It has one other heteroatom (oxygen, nitrogen, sulfur, etc.) optionally, at least one substituted or unsubstituted phenyl or naphthyl group is optionally inserted, and at least one quaternary ammonium group. C replaced by two optional choices₁~ C₁₅Substituted with an alkyl group, the linker has no nitro, nitroso or peroxy groups.</p><p> If the heterocyclic or aromatic nuclei are substituted, they are, for example, substituted by: hydroxyl, C.₁~ C₂Alkoxy, C₂~ C₄Hydroxyalkoxy, acetylamino or one or two C₁~ C₄One or more Cs substituted with an alkyl group and optionally substituted with an amino group carrying at least one hydroxyl group.₁~ C₈Alkyl groups, or two groups, together with the nitrogen atom to which they are attached, form a 5- or 6-membered heterocycle that optionally has another heteroatom that is the same as or different from nitrogen. Can be one or more Cs₁~ C₈Alkyl group; halogen atom; hydroxyl group; C₁~ C₂Alkoxy group; C₂~ C₄Hydroxyalkoxy groups; amino groups; one or two identical or different Cs that optionally support at least one hydroxyl group₁~ C₄Amino group substituted with an alkyl group.</p><p> Among the benzene-type direct dyes that can be used, the following compounds can be mentioned, but not limited to: - 1,4-Diamino-2-nitrobenzene, - 1-Amino-2-nitro-4-β-hydroxyethylaminobenzene - 1-Amino-2-nitro-4-bis (β-hydroxyethyl) aminobenzene - 1,4-Bis (β-Hydroxyethylamino) -2-nitrobenzene - 1-β-Hydroxyethylamino-2-nitro-4-bis (β-hydroxyethylamino) benzene - 1-β-Hydroxyethylamino-2-nitro-4-aminobenzene - 1-β-Hydroxyethyl Amino-2-nitro-4- (Ethyl) (β-Hydroxyethyl) Aminobenzene - 1-Amino-3-methyl-4-β-hydroxyethylamino-6-nitrobenzene - 1-Amino-2-nitro-4-β-hydroxyethylamino-5-chlorobenzene - 1,2-Diamino-4-nitrobenzene - 1-Amino-2-β-Hydroxyethylamino-5-Nitrobenzene - 1,2-Bis (β-Hydroxyethylamino) -4-nitrobenzene --- 1-Amino-2-tris (Hydroxymethyl) Methylamino-5-Nitrobenzene - 1-Hydroxy-2-amino-5-nitrobenzene - 1-Hydroxy-2-amino-4-nitrobenzene - 1-Hydroxy-3-nitro-4-aminobenzene - 1-Hydroxy-2-amino-4,6-dinitrobenzene - 1-β-Hydroxyethyloxy-2-β-Hydroxyethylamino-5-nitrobenzene - 1-Methoxy-2-β-Hydroxyethylamino-5-nitrobenzene - 1-β-Hydroxyethyloxy-3-methylamino-4-nitrobenzene - 1-β, γ-dihydroxypropyloxy-3-methylamino-4-nitrobenzene - 1-β-Hydroxyethylamino-4-β, γ-dihydroxypropyloxy-2-nitrobenzene - 1-β, γ-dihydroxypropylamino-4-trifluoromethyl-2-nitrobenzene - 1-β-Hydroxyethylamino-4-trifluoromethyl-2-nitrobenzene --- 1-β-Hydroxyethylamino-3-methyl-2-nitrobenzene - 1-β-Aminoethylamino-5-methoxy-2-nitrobenzene - 1-Hydroxy-2-chloro-6-ethylamino-4-nitrobenzene - 1-Hydroxy-2-chloro-6-amino-4-nitrobenzene - 1-Hydroxy-6-bis (β-hydroxyethyl) amino-3-nitrobenzene - 1-β-Hydroxyethylamino-2-nitrobenzene - 1-Hydroxy-4-β-Hydroxyethylamino-3-nitrobenzene.</p><p> For azo, azomethine, methine and tetraazapentamethine direct dyes that can be used in accordance with the present invention, the cationic dyes described in patent applications WO95 / 15144, WO95 / 01772 and EP714954, FR2189006, FR2285851, FR2140205, EP1378544 and EP1674073. Can be mentioned.</p><p> Thus, in particular, the following dyes of formulas (I) to (IV), preferably compounds of formulas (I) and (III), can be mentioned:</p><p><chemistry num="4"><img file="JP2010143920A_D0004.tif" /></chemistry></p><p> [During the ceremony, D represents a nitrogen atom or -CH group R₁And R₂Can be the same or different, hydrogen atom; -CN, -OH or NH₂It may be substituted with a group, or it may be combined with the carbon atom of the benzene ring to form a heterocycle with an optional oxygen or nitrogen C.₁~ C₄Alkyl group (this heterocycle is one or more Cs₁~ C₄May be substituted with an alkyl group); represents a 4'-aminophenyl group, R₃And R'₃Can be the same or different, hydrogen atoms, or halogen atoms selected from chlorine, bromine, iodine and fluorine, or cyano, C.₁~ C₄Alkyl, C₁~ C₄Represents an alkoxy or acetyloxy group X^-Represents an anion preferably selected from chlorine, methyl sulphate and acetic acid, A represents a group selected from the following structures A1 to A18, with A1, A4, A7, A13 and A18 being more advantageous]</p><p><chemistry num="5"><img file="JP2010143920A_D0005.tif" /></chemistry></p><p> [In the formula, R₄May be substituted with a hydroxyl group C₁~ C₄Represents an alkyl group, R₅Is the following C₁~ C₄Represents an alkoxy group]</p><p><chemistry num="6"><img file="JP2010143920A_D0006.tif" /></chemistry></p><p> [During the ceremony, R₆Is a hydrogen atom or C₁~ C₄Represents an alkyl group R₇Represents a hydrogen atom, an alkyl group optionally substituted with a -CN group or an amino group, a 4'-aminophenyl group, or R₆Along with, optionally containing oxygen and / or nitrogen, C₁~ C₄Forming a heterocycle that may be substituted with an alkyl group, R₈And R₉May be the same or different, such as hydrogen atoms, such as halogen atoms such as bromine, chlorine, iodine or fluorine, C.₁~ C₄Alkyl or C₁~ C₄Represents an alkoxy group or a CN group X^-Represents an anion preferably selected from chlorine, methyl sulphate and acetic acid, B represents a group selected from the following B1 to B6 structures]</p><p><chemistry num="7"><img file="JP2010143920A_D0007.tif" /></chemistry></p><p> [In the formula, R₁₀Is C₁~ C₄Represents an alkyl group, R₁₁And R₁₂Can be the same or different, hydrogen atom or C₁~ C₄Represents an alkyl group]</p><p><chemistry num="8"><img file="JP2010143920A_D0008.tif" /></chemistry></p><p> [During the ceremony, R₁₃Is a hydrogen atom, C₁~ C₄Represents an alkoxy group or a halogen atom such as bromine, chlorine, iodine or fluorine. R₁₄Is a hydrogen atom, C₁~ C₄It represents an alkyl group or, in combination with the carbon atom of the benzene ring, optionally contains oxygen and / or one or more Cs.₁~ C₄Forming a heterocycle that may be substituted with an alkyl group, R₁₅Represents a hydrogen atom or a halogen atom such as bromine, chlorine, iodine or fluorine. R₁₆And R₁₇Can be the same or different, hydrogen atom or C₁~ C₄Represents an alkyl group D₁And D₂Represents a hydrogen atom or -CH group, which may be the same or different m = 0 or 1, preferably 1. R₁₃When represents an unsubstituted amino group, D₁And D₂At the same time represents the -CH group, understood to be m = 0, X^-Represents an anion preferably selected from chlorine, methyl sulphate and acetic acid, E represents a group selected from the structures of E1, E2 and E7 below, more specifically E1, E2 and E7]</p><p><chemistry num="9"><img file="JP2010143920A_D0009.tif" /></chemistry></p><p> [In the formula, R'is C₁~ C₄Represents an alkyl group At m = 0, D₁When is a nitrogen atom, E can also represent a group of structure E9:</p><p><chemistry num="10"><img file="JP2010143920A_D0010.tif" /></chemistry></p><p> [In the formula, R'is C₁~ C₄Represents an alkyl group. ]</p><p><chemistry num="11"><img file="JP2010143920A_D0011.tif" /></chemistry></p><p> [During the ceremony, The symbol G is the following structure G₁From G₃Represents a group selected from]</p><p><chemistry num="12"><img file="JP2010143920A_D0012.tif" /></chemistry></p><p> [In the formula, structural structure G₁From G₃Ha: R₁₈Is C₁~ C₄Alkyl group, C₁~ C₄Represents a phenyl group that may be substituted with an alkyl group, or a halogen atom selected from chlorine, bromine, iodine or fluorine. R₁₉Is C₁~ C₄Represents an alkyl or phenyl group R₂₀And R₂₁Can be the same or different, C₁~ C₄Represents an alkyl group, a phenyl group, or G₁In, one or more C₁~ C₄Alkyl, C₁~ C₄Alkoxy or NO₂Benzene rings substituted with groups are formed together or G₂In, one or more C₁~ C₄Alkyl, C₁~ C₄Alkoxy or NO₂Benzene rings optionally substituted with groups are formed together to form R₂₀May represent a hydrogen atom, Z is an oxygen or sulfur atom, or -NR₁₉Represents a group M is -CH, -CR (R is C₁~ C₄(Representing alkyl) or -NR₂₂(X^-)_rRepresents a group K is -CH, -CR (R is C₁~ C₄(Representing alkyl) or -NR₂₂(X^-)_rRepresents a group P is -CH, -CR (R is C₁~ C₄(Representing alkyl) or -NR₂₂(X^-)_rRepresents a group r represents 0 or 1 R₂₂Is O^-Atom, C₁~ C₄Alkoxy group, or C₁~ C₄Represents an alkyl group R₂₃And R₂₄Can be the same or different, a hydrogen atom or a halogen atom selected from chlorine, bromine, iodine and fluorine, C₁~ C₄Alkyl or C₁~ C₄Alkoxy group, or NO₂Represents a group X^-Represents an anion preferably selected from chlorine, iodine, methyl sulphate, ethyl sulphate, acetic acid and perchloric acid. However, R₂₂But O^-When representing, r represents 0, K or P or M is -N- (C₁~ C₄) Alkyl X^-When representing, R₂₃Or R₂₄Is preferably a non-hydrogen atom, K is -NR₂₂(X^-)_rWhen representing, M = P = -CH, -CR, M is -NR₂₂(X^-)_rWhen representing, K = P = -CH, -CR, P is -NR₂₂(X^-)_rWhen representing, K = M and -CH or -CR, Z represents a sulfur atom, R₂₁But C₁~ C₄When representing alkyl, R₂₀Is other than hydrogen, Z is -NR₂₂Represents R₁₉Is C₁~ C₄When representing alkyl, structure G₂R of the base₁₈, R₂₀Or R₂₁At least one of the bases of₁~ C₄Other than alkyl groups, The symbol J represents: -(a) Structure J below₁Based on]</p><p><chemistry num="13"><img file="JP2010143920A_D0013.tif" /></chemistry></p><p> [In the formula, structure J₁Is: R₂₅Is a halogen atom selected from hydrogen atom, chlorine, bromine, iodine and fluorine, C₁~ C₄Alkyl or C₁~ C₄Alkoxy group, -OH, -NO₂, -NHR₂₈, -NR₂₉R₃₀Or C₁~ C₄-Represents an NHCO alkyl group or R₂₆Together with, they form a 5- or 6-membered ring that optionally contains one or more heteroatoms selected from nitrogen, oxygen and sulfur. R₂₆Is a halogen atom selected from hydrogen atom, chlorine, bromine, iodine and fluorine, C₁~ C₄Alkyl or C₁~ C₄Represents an alkoxy group or R₂₇Or R₂₈Together with, they form a 5- or 6-membered ring that optionally contains one or more heteroatoms selected from nitrogen, oxygen and sulfur. R₂₇Is a hydrogen atom, -OH group, group NHR₂₈Or NR₂₉R₃₀Represents R₂₈Is a hydrogen atom, C₁~ C₄Alkyl group, C₁~ C₄Monohydroxyalkyl, C₂~ C₄Represents a polyhydroxyalkyl group or a phenyl group R₂₉And R₃₀Can be the same or different, C₁~ C₄Alkyl group, C₁~ C₄Monohydroxyalkyl, or C₂~ C₄Represents a polyhydroxyalkyl group -(B) 5- or 6-membered nitrogen-containing heterocyclic group, which may contain other heteroatoms and / or carbonyl groups and may contain one or more Cs.₁~ C₄It may be substituted with an alkyl, amino or phenyl group, in particular the following structure J₂Is the basis of. ]</p><p><chemistry num="14"><img file="JP2010143920A_D0014.tif" /></chemistry></p><p> [In the formula, structure J₂Is: R₃₁And R₃₂Can be the same or different, hydrogen atom, C₁~ C₄Represents an alkyl or phenyl group Y is the -CO- group or</p><p><chemistry num="15"><img file="JP2010143920A_D0015.tif" /></chemistry></p><p> Represents a group When n = 0 or 1, and n represents 1, then U represents the -CO- group. ]</p><p> In the structures (I) to (IV) defined above, C₁~ C₄The alkyl or alkoxy group preferably represents methyl, ethyl, butyl, methoxy or ethoxy.</p><p> Among the compounds of formulas (I) to (III), the following compounds are preferred:</p><p><chemistry num="16"><img file="JP2010143920A_D0016.tif" /></chemistry></p><p> Further azo direct dyes that can be mentioned include the following dyes listed in the 3rd edition of Color Index International: --Dispar thread 17 --Basic Red 22 --Basic Red 76 --Basic Yellow 57 --Basic Brown 16 --Basic Brown 17 --Disperse Black 9.</p><p> Further, 1- (4'-aminodiphenylazo) -2-methyl-4-bis (β-hydroxyethyl) aminobenzene can also be mentioned.</p><p> The quinone substantive dyes that can be mentioned are the following dyes: --Dispar thread 15 --Solvent Violet 13 --Disperse Violet 1 --Disperse Violet 4 --Disperse Blue 1 --Disperse Violet 8 --Disperse Blue 3 --Disperse Red 11 --Disperse Blue 7 --Basic Blue 22 --Disperse Violet 15 --Basic Blue 99 And, in addition, the following compounds: - 1-N-Methylmorpholinium propylamino-4-hydroxyanthraquinone - 1-Aminopropylamino-4-methylaminoanthraquinone - 1-Aminopropylaminoanthraquinone --5-β-Hydroxyethyl-1,4-diaminoanthraquinone --2-Aminoethylaminoanthraquinone - 1,4-Bis (β, γ-dihydroxypropylamino) anthraquinone.</p><p> Adin dyes that can be mentioned include the following compounds: --Basic Blue 17 --Basic Red 2.</p><p> Triarylmethane dyes that can be used in accordance with the present invention include the following compounds: --Basic Green 1 --Basic Violet 3 --Basic Violet 14 --Basic Blue 7 --Basic Blue 26.</p><p> Indoamine dyes that can be used in accordance with the present invention include the following compounds: - 2-β-Hydroxyethylamino-5- [bis (β-4'-hydroxyethyl) amino] anilino-1,4-benzoquinone - 2-β-Hydroxyethylamino-5- (2'-methoxy-4'-amino) anilino-1,4-benzoquinone --3-N-(2'-Chloro-4'-Hydroxy) Phenylacetylamino-6-Methoxy-1,4-benzoquinoneimine --3-N- (3'-Chloro-4'-Methylamino) Phenylureide-6-Methyl-1,4-benzoquinoneimine --3- [4'-N- (ethyl, carbamilmethyl) amino] Phenylureide-6-methyl-1,4-benzoquinoneimine.</p><p> Tetraazapentamethine-type dyes that can be used in accordance with the present invention include the following compounds listed in the table below:</p><p><tables num="1"><img file="JP2010143920A_D0017.tif" /></tables></p><p> X^-Preferred represents an anion selected from chlorine, iodine, methyl sulphate, ethyl sulphate, acetic acid and perchloric acid.</p><p> For polyaromatic staining, more specifically, at least one optionally condensed, further at least one quaternary nitrogen atom attached to a heterocycle and at least one other optionally. Substituted with at least one optional, having a 5- or 6-membered aromatic heterocycle with a heteroatom (nitrogen, sulfur, oxygen, etc.) and optionally having at least one group OR. It has a phenyl or naphthyl group, where this R is a hydrogen atom, optionally substituted C₁~ C₆Alkyl group, optionally substituted phenyl nuclei, or at least one group N (R')₂This R'can be the same or different, hydrogen atom, optionally substituted C₁~ C₆Represents an alkyl group or an optionally substituted phenyl nucleus, the group R', together with the nitrogen atom to which they are bonded, optionally forms a saturated 5- or 6-membered heterocycle. Or, or instead, one and / or both of the groups R', together with the carbon atoms of the aromatic ring located ortho with respect to the nitrogen atom, are 5- or 6-membered saturated. Examples include symmetric or asymmetric azo and / or azomethine (hydrazone) two or three chromophore dyes that may form a heterocycle.</p><p> Preferred aromatic-cationic heterocycles, which may be mentioned, have 1 to 3, preferably 1 or 2 nitrogen atoms, one of which is a quaternary 5- or 6-membered ring, and the like. There is a heterocycle in which the heterocycle is optionally fused to the benzene nucleus. It should also be noted that the heterocycle may optionally have another heteroatom other than nitrogen, such as sulfur or oxygen.</p><p> If the heterocycle or phenyl or naphthyl groups are substituted, they are, for example, substituted by: hydroxyl, C₁~ C₂Alkoxy, C₂~ C₄One or two Cs carrying hydroxyalkoxy, acetylamino or at least one hydroxyl group optionally₁~ C₄One or more Cs optionally substituted with an amino group substituted with an alkyl group₁~ C₈Alkyl groups or two groups can be combined with the nitrogen atom to which they are attached to form a 5- or 6-membered heterocycle, optionally having another heteroatom that is the same as or different from nitrogen 1 One or more Cs₁~ C₈Alkyl group; halogen atom; hydroxyl group; C₁~ C₂Alkoxy group; C₂~ C₄Hydroxyalkoxy groups; amino groups; one or two same or different Cs that optionally support at least one hydroxyl group₁~ C₄Amino group substituted with an alkyl group.</p><p> These polychromic groups are saturated or unsaturated and may or may not be optionally attached to an aromatic heterocycle, and at least one linker containing at least one quaternary nitrogen atom optionally. Are combined through.</p><p> Preferably, the linker is at least one heteroatom (such as nitrogen or oxygen) and / or at least one group having such a heteroatom (CO or SO).₂) Is optionally inserted and may or may not be fused to the phenyl nucleus, at least one heterocycle is optionally inserted and at least one quaternary nitrogen atom attached to the ring and Optionally having at least one other heteroatom (oxygen, nitrogen, sulfur, etc.), at least one substituted or unsubstituted phenyl or naphthyl group optionally inserted, and optionally at least one quaternary C in which the ammonium group is substituted with two optional choices₁~ C₁₅Linear, branched or cyclic C substituted with alkyl groups₁~ C₂₀It is an alkyl chain and this linker has no nitro, nitroso or peroxy groups.</p><p> Bonding of the linker to each chromophore is generally done via a heteroatom substituent on the nucleus of phenyl or naphthyl or via the quaternary nitrogen atom of the cationic heterocycle.</p><p> The dye can contain the same or different chromophores.</p><p> Examples of such dyes are, in particular, EP1637566, EP1619221, EP1634926, EP1619220, EP1672033, EP1671954, EP1671955, EP1679312, EP1671951, EP167952, EP167971, WO06 / 063866, WO06 / 063867, WO06 / 063868, WO06 / 063869, EP1408919. , EP1377264, EP1377262, EP1377261, EP1377263, EP1399425, EP1399117, EP1416909, EP1399116 and EP1671560.</p><p> It is also possible to use the cationic direct dyes described in the following patent applications: EP1006153, cationic or which describes dyes with two anthraquinone-type chromophores attached via a cationic linker. It has EP1433472, EP1433474, EP1433471 and EP1433473, which describe the same or different dichromophore dyes attached via a non-cationic linker, and three chromophores, one of which is the anthraquinone chromophore, where EP6291333 specifically describes dyes in which two chromophores of the azo or diazacarbosianin form or their isomers are attached.</p><p> Natural substantive dyes that can be used in accordance with the present invention include lauson, juglone, alizarin, purpurin, carminic acid, kermesic acid, purprogalin, protocatecaldehyde, indigo, isatin, curcumin, spinulosin, apigenidine and orcein. .. Extracts or simmered products containing these natural dyes, especially henna-based paps or extracts, can also be used.</p><p> When present, the direct dye, more specifically, accounts for 0.0001% to 10% by weight, preferably 0.005% to 5% by weight, based on the total weight of the composition.</p><p> The composition (C1) can contain one and / or other dyes. It can also optionally correspond to two dyeing compositions, one containing an oxidative dye and the other a direct dye.</p><p> The composition (C1) can be an aqueous or non-aqueous composition. The term "aqueous composition" means a composition comprising more than 5% by weight, preferably more than 10% by weight, and even more preferably more than 20% by weight.</p><p> Preferably, the composition (C1) is an aqueous composition.</p><p> The composition may optionally contain an organic solvent. Examples of organic solvents that can be mentioned include C such as ethanol and isopropanol.₂~ C₄Linear or branched alkanols, glycerol, polyols and polyol ethers such as 2-butoxyethanol, propylene glycol, dipropylene glycol, propylene glycol monomethyl ether, and diethylene glycol monomethyl ether and monoethyl ether, as well as benzyl alcohol or phenoxyethanol, etc. There are aromatic alcohols, and mixtures thereof.</p><p> In the presence of the solvent, its content is typically in the range of 1% to 40% by weight, preferably 5% to 30% by weight, based on the weight of the composition (C1).</p><p> The cosmetic composition (C1) is further mentioned in the context of the composition (A), in particular anionic, cationic, nonionic, amphoteric or zwitterionic surfactants or theirs. Mixtures, anionic, cationic, nonionic, amphoteric or zwitterionic polymers or mixtures thereof, inorganic thickeners, especially fillers such as clay, talc, especially anionic, cationic, nonionic and Various organic thickeners containing polymer-binding thickeners, antioxidants, penetrants, metal ion blockers, fragrances, dispersants, film-forming agents, conditioners, ceramides, preservatives, opalescent agents, etc. Auxiliary agents can also be included.</p><p> The above-mentioned auxiliary agents are generally present in an amount of 0.01% by weight to 20% by weight, respectively, based on the weight of the composition (C1).</p><p> The composition may also contain one or more organic thickeners, as detailed in the context of composition (A).</p><p> In one particular embodiment, the organic thickener is a cellulose-based thickener (hydroxyethyl cellulose, hydroxypropyl cellulose or carboxymethyl cellulose), guar gum and derivatives thereof (hydroxypropyl guar), gums derived from microorganisms. (Xanthan gum, screlogulcan gum) and acrylic acid or acrylamide propanesulfonic acid crosslinked homopolymers, preferably those containing cellulose-based thickeners, especially hydroxyethyl cellulose.</p><p> If an organic thickener is present, its content is typically in the range of 0.01% to 20% by weight, preferably 0.1% by weight to 5% by weight, based on the weight of the composition. ..</p><p> Finally, the method is carried out using the composition (B) containing one or more oxidizing agents.</p><p> More specifically, the oxidants are hydrogen peroxide, urea peroxide, bromic acid or ferricyanide alkali metal salts and peroxide salts, such as alkali metal or alkaline earth metal persulfates, perboric acid or percarbonates. It is selected from salts, and peracids and their precursors.</p><p> This oxidant is advantageously composed of hydrogen peroxide, especially as an aqueous solution (aqueous hydrogen peroxide solution), the concentration of which is more specifically 0.1% to 50% by weight of the weight of the oxidation composition. More specifically, it can range from 0.5% to 20%, and more preferably from 1% to 15%.</p><p> Depending on the desired degree of lightening, the oxidizing agent may also preferably contain an oxidizing agent selected from the peroxide salts.</p><p> The oxidation composition can be aqueous or non-aqueous. The term "aqueous composition" means a composition comprising more than 5% by weight, preferably more than 10% by weight, and even more preferably more than 20% by weight.</p><p> Preferably, the composition (B) is an aqueous composition.</p><p> The composition may also contain one or more organic solvents.</p><p> Examples of organic solvents that can be mentioned are linear or branched C.₂~ C₄Alkanol, eg ethanol and isopropanol; glycerol; polyol and polyol ether, eg 2-butoxyethanol, propylene glycol, dipropylene glycol, propylene glycol monomethyl ether, diethylene glycol monomethyl ether and monoethyl ether, and even aromatic alcohols, eg, There are benzyl alcohol or phenoxyethanol, as well as mixtures thereof.</p><p> When the solvent is present, its content is typically in the range of 1% to 40% by weight, preferably in the range of 5% to 30% by weight, based on the weight of the oxidized composition (C). ..</p><p> The oxidation composition can also contain one or more acidifying agents.</p><p> Examples of acidifying agents that may be mentioned include inorganic or organic acids such as hydrochloric acid, ortholic acid, sulfuric acid and the like, carboxylic acids such as acetic acid, tartaric acid, citric acid or lactic acid and the like, and sulfonic acids.</p><p> Generally, the pH of the oxidation composition (B) is less than 7 when aqueous.</p><p> The oxidation composition (B) can also contain other components conventionally used in the art, such as those already detailed in the context of anhydrous compositions and dyeing compositions.</p><p> Ultimately, the oxidation composition takes various forms, such as solvents, emulsions or gels.</p><p> In the first aspect of the present invention, the composition obtained by mixing the above-mentioned anhydrous composition (A) and the above-mentioned composition (B) in place at the time of use is moistened or dried. Applies to keratin fibers.</p><p> In a second aspect of the method, the compositions (A) and (B) are continuously applied to moist or dry keratin fibers without rinsing in between.</p><p> Preferably, the composition (A) is applied, and then (B) is applied.</p><p> In these two embodiments, the weight ratio R1 of the amounts of the compositions (A) / (B) is in the range of 0.1 to 10, more particularly in the range of 0.3 to 3, and even more preferably in the range of 0.5 to 1. take.</p><p> In another aspect of the present invention, the composition obtained by mixing the above-mentioned anhydrous composition (A), the above-mentioned composition (C1) and the above-mentioned aqueous oxidation composition (B) on the spot at the time of use. The object is applied to moist or dry keratin fibers.</p><p> In this embodiment, the weight ratio R'1 of the amount of the composition (A) + (C1) / (B) and the weight ratio R'2 of the amount of the composition (A) / (C1) are preferably 0.1 to 10. Takes the range of 0.3 to 3.</p><p> In a second aspect of the method, the compositions (A), (C1) and (B) are applied continuously to moist or dry keratin fibers, without rinsing in between.</p><p> Preferably, the composition (A), then (C1), then (B), or (C1), then (A), and then (B) is applied.</p><p> In a third aspect, the composition (B), and then the mixture obtained from the compositions (A) and (C1), can be applied continuously without rinsing in between.</p><p> In these last two embodiments, the weight ratio R'1 of the amount of composition (A) + (C1) / (B) and the weight ratio R'2 of the amount of composition (A) / (C1) are More particularly, it ranges from 0.1 to 10, preferably from 0.3 to 3.</p><p> Moreover, regardless of the mode used, the fibers (caused by either in-situ mixing of compositions (A), (B) and (C1) if present, or their continuous application). The mixture present above is generally left for about 1 minute to 1 hour, preferably about 5 to 30 minutes.</p><p> The temperature in the method has traditionally been between room temperature (15-25 ° C) and 80 ° C, preferably between room temperature and 60 ° C.</p><p> After treatment, human keratin fibers are optionally rinsed with water, optionally washed with shampoo, then rinsed with water and then dried or left to dry.</p><p> If the composition applied to the hair (containing compositions (A), (B) and (C1) if present) contains aqueous ammonia or a salt thereof, its content is the final composition. For weight, (NH₃It is pointed out that the weight of the final composition (represented as) is 0.03% by weight or less, and more specifically, 0.01% by weight or less. The final composition is obtained from a mixture of compositions (A), (B) and (C1) if present, which mixture is prior to application of the keratin fibers (in-situ preparation) or on the keratin fibers. Is shown to be done directly (continuous application with or without premixing, without rinsing in between). If the composition contains aqueous ammonia or a salt thereof, the amount of basalizing agent is (NH₃It is preferably greater than the amount of ammonia water (represented as).</p><p> However, the compositions (A), (B) and, if present (C1), preferably do not contain aqueous ammonia.</p><p> In one particularly advantageous embodiment, the composition according to the present invention obtained after mixing the above-mentioned compositions (A), (B) and (C1) has an amount of fatty substance exceeding 20% by weight after mixing. As such, preferably above 25% by weight, and even more preferably above 30% by weight.</p><p> Finally, the invention comprises, as described above, one or more aliphatic substances, one or more surfactants, monoethanolamine and one or more basic amino acids in the first compartment. The present invention relates to a multi-compartment device, comprising a cosmetic anhydrous composition (A) and a composition (B) containing one or more oxidizing agents in a second compartment, as described above.</p><p> Another multi-compartment device according to the present invention is a cosmetic cosmetic containing one or more fatty substances, one or more surfactants, monoethanolamine and one or more basic amino acids in a first compartment. Includes anhydrous composition (A), composition containing one or more oxidizing dyes and / or direct dyes (C1) and aqueous composition containing one or more oxidizing agents (B).</p><p> The following examples are for the purpose of explaining the present invention, and are not limited to that.</p>

(Example 1) The following compositions were prepared (unless otherwise noted, the unit of quantity is g%).

<tables num="2"><img file="JP2010143920A_D0018.tif" /></tables>

At the time of use, each composition is mixed by weight with an aqueous oxidation composition containing hydrogen peroxide (6 wt% hydrogen peroxide) as a 20 volume solution.

The pH of the resulting mixture is 10.1 ± 0.1.

Each mixture is then applied to a natural maroon lock (tone depth 5). The bath ratio of the "mixture / hair tuft" is 10/1 (g / g).

The leaving time is 30 minutes at room temperature.

After this time, the follicles are rinsed, then washed with Elvive multivitamin shampoo and dried.

<tables num="3"><img file="JP2010143920A_D0019.tif" /></tables>

This method is carried out using this composition for the above-mentioned composition.

It has been found that the compositions C1 and C2 of the present invention do not have a foul odor unlike the control composition, and it is possible to obtain a lightening color comparable to that of the control composition.

(Example 2) The following compositions were prepared (unless otherwise noted, the unit of quantity is g%).

<tables num="4"><img file="JP2010143920A_D0020.tif" /></tables>

<tables num="5"><img file="JP2010143920A_D0021.tif" /></tables>

At the time of use, mix the following: - 10 parts by weight composition A 4 parts by weight composition B1 --15 parts by weight Platinium international 20-volumes oxidizer (Amount of hydrogen peroxide: 6% by weight)

Each mixture is then applied to a natural hair tress (NG) containing 90% gray hair and a permanent-waved hair tress (PWG) containing 90% gray hair. ..

The bath ratio of the "mixture / hair bundle" is 10/1 (g / g), respectively.

The leaving time is 30 minutes at 27 ° C.

After this time, the hair tresses are rinsed, washed with Elvive Multivitamin Shampoo and dried.

The compositions of the present invention produce a strong and sparingly selective matte result.