Agent combinations
Abstract
Die vorliegende Erfindung betrifft neue Wirkstoffkombinationen, die einerseits ein bekanntes Herbizid ausgewählt aus Glyphosate, Glufosinate oder Glufosinate-ammonium, und andererseits mindestens einen bekannten fungiziden Wirkstoff enthält und sehr gut zur Bekämpfung von unerwünschten phytopathogenen Pilzen, insbesondere Sojabohnen-Rost, geeignet sind. Besonders bevorzugt ist die Anwendung dieser Mischungen auf transgenen Pflanzen, die gegen die genannten Herbizide resistent sind.
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15 claims: 1 independent, 14 dependent
- 1Wirkstoffkombinationen, enthaltend Gruppe (1) ein Herbizid ausgewählt aus (1-2) Glufosinate (1-3) Glufosinate-ammonium und mindestens einen Wirkstoff, der aus der folgenden Gruppe (16) ausgewählt ist:Gruppe (16): Pyrrole ausgewählt aus (16-1) Fenpiclonil, (16-2) Fludioxonil, (16-3) Pyrrolnitrine.
- 2Wirkstoffkombinationen gemäß Anspruch 1, enthaltend (1-2) Glufosinate und mindestens einen fungiziden Wirkstoff der Gruppe (16).
- 3Wirkstoffkombinationen gemäß Anspruch 1, enthaltend (1-3) Glufosinate-ammonium und mindestens einen fungiziden Wirkstoff der Gruppe (16).
- 4Verwendung von Wirkstoffkombinationen gemäß Anspruch 1, 2 oder 3 zur Bekämpfung von unerwünschten phytopathogenen Pilzen.
- 5Verwendung von Wirkstoffkombinationen gemäß Anspruch 1, 2 oder 3 zur Behandlung von transgenen Pflanzen.
- 6Verwendung gemäß Anspruch 5, dadurch gekennzeichnet, dass die behandelten transgenen Pflanzen gegen Glyphosate, Glufosinate oder Glufosinate-ammonium resistent sind.
- 7Verfahren zum Bekämpfen von unerwünschten phytopathogenen Pilzen, dadurch gekennzeichnet, dass man Wirkstoffkombinationen gemäß Anspruch 1, 2 oder 3 auf die unerwünschten phytopathogenen Pilze und/oder deren Lebensraum und/oder Saatgut ausbringt.
- 8Verwendung von Wirkstoffkombinationen gemäß Anspruch 1, 2 oder 3 zur Bekämpfung von Rost-Krankheiten an Soja-Pflanzen.
- 9Verwendung von Wirkstoffkombinationen gemäß Anspruch 1, 2 oder 3 zur Behandlung von transgenen Soja-Pflanzen.
- 10Verwendung gemäß Anspruch 9, dadurch gekennzeichnet, dass die behandelten transgenen Soja-Pflanzen gegen Glyphosate, Glufosinate oder Glufosinate-ammonium, bevorzugt Glyphosate, resistent sind.
- 11Verfahren zum Bekämpfen von unerwünschten phytopathogenen Pilzen, dadurch gekennzeichnet, dass man Wirkstoffkombinationen gemäß Anspruch 1, 2 oder 3 auf die Rost-Pilze und/oder deren Lebensraum und/oder Saatgut ausbringt.
- 12Beizmittel enthaltend eine Wirkstoffkombination gemäß Anspruch 1, 2 oder 3.
- 13Verwendung von Wirkstoffkombinationen gemäß Anspruch 1, 2 oder 3 zur Behandlung von Saatgut und/oder zur Behandlung von Saatgut transgener Pflanzen.
- 14Verfahren zum Beizen von Saatgut, dadurch gekennzeichnet, dass man eine Wirkstoffkombination gemäß Anspruch 1, 2 oder 3 auf das Saatgut oder das Saatgut transgener Pflanzen aufbringt.
- 15Verwendung von Wirkstoffkombinationen gemäß Anspruch 1, 2 oder 3 zur Behandlung von herbizid-resistenten oder herbizid-sensitiven Pflanzen.
Independent claims15
605 paragraphs in 67 sections, as filed
0001The present invention relates to new combinations of active ingredients which on the one hand contain a known herbicide selected from glyphosate, glufosinate or glufosinate-ammonium, and on the other hand contain at least one known fungicidal active ingredient and are very suitable for controlling unwanted phytopathogenic fungi, in particular soybean rust. The use of these mixtures on transgenic plants which are resistant to the herbicides mentioned is particularly preferred.
0002It is already known that glyphosate, glufosinate and glufosinate-ammonium have herbicidal properties (cf. <patcit id="pcit0001" dnum="DE2152826A"><text>DE-A 21 52 826</text></patcit>, <patcit id="pcit0002" dnum="DE2717440A"><text>DE-A 27 17 440</text></patcit>). It is also known that numerous carboxamides, triazole derivatives, aniline derivatives, dicarboximides and other heterocycles can be used to combat fungi (cf.<patcit id="pcit0003" dnum="WO03010149A"><text>WO 03/010149</text></patcit>, <patcit id="pcit0004" dnum="DE10303589A"><text>DE-A 103 03 589</text></patcit>, <patcit id="pcit0005" dnum="EP0040345A"><text>EP-A 0 040 345</text></patcit>, <patcit id="pcit0006" dnum="DE2201063A"><text>DE-A 22 01 063</text></patcit>, <patcit id="pcit0007" dnum="DE2324010A"><text>DE-A 23 24 010</text></patcit>, Pesticide Manual, 9th. Edition (1991), pages 249 and 827,<patcit id="pcit0008" dnum="EP0382375A"><text>EP-A 0 382 375</text></patcit> and <patcit id="pcit0009" dnum="EP0515901A"><text>EP-A 0 515 901</text></patcit>). The effect of these substances is not always sufficient at low application rates. Furthermore, it is already known that 1- (3,5-dimethyl-isoxazole-4-sulfonyl) -2-chloro-6,6-difluoro- [1,3] dioxolo- [4,5f] -benzimidazole has fungicidal properties (see.<patcit id="pcit0010" dnum="WO9706171A"><text>WO 97/06171</text></patcit>). Finally, it is also known that substituted halopyrimidines have fungicidal properties (cf.<patcit id="pcit0011" dnum="DE19646407A"><text>DE-A 196 46 407</text></patcit>, <patcit id="pcit0012" dnum="EP712396B"><text>EP-B-712 396</text></patcit>).
0003There have now been found new combinations of active ingredients with very good fungicidal properties <u>Group (1) a herbicide selected from</u>
(1-1) Glyphosate (known from DE-A 21 52 826) of the formula
0004<chemistry id="chem0001" num="0001"><img file="EP2255646A2_D0001.tif" /></chemistry>
(1-2) Glufosinate (known from DE-A 27 17 440) of the formula
0005<chemistry id="chem0002" num="0002"><img file="EP2255646A2_D0002.tif" /></chemistry>
(1-3) Glufosinate-ammonium (known from Pesticide Manual, 13th edition, British Crop Protection Council, 2003, page 511-512) of the formula
0006<chemistry id="chem0003" num="0003"><img file="EP2255646A2_D0003.tif" /></chemistry>and at least one active ingredient selected from the following groups (2) to (23):
Group (2) strobilurins selected from
(2-1) Azoxystrobin (known from EP-A 0 382 375) of the formula
0007<chemistry id="chem0004" num="0004"><img file="EP2255646A2_D0004.tif" /></chemistry>
(2-2) Fluoxastrobin (known from DE-A 196 02 095) of the formula
0008<chemistry id="chem0005" num="0005"><img file="EP2255646A2_D0005.tif" /></chemistry>
(2-3) (2
E
) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl] oxy} phenyl) -2- (methoxyimino) -N-methylethanamide (known from DE-A 196 46 407) of the formula
0009<chemistry id="chem0006" num="0006"><img file="EP2255646A2_D0006.tif" /></chemistry>
(2-4) Trifloxystrobin (known from EP-A 0 460 575) of the formula
0010<chemistry id="chem0007" num="0007"><img file="EP2255646A2_D0007.tif" /></chemistry>
(2-5) (2
E
) -2- (methoxyimino) -
N
-methyl-2- (2 - {[({(1
E
) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) -oxy] methyl} phenyl) ethanamide (known from EP-A 0 569 384) of the formula
0011<chemistry id="chem0008" num="0008"><img file="EP2255646A2_D0008.tif" /></chemistry>
(2-6) (2
E
) -2- (methoxyimino) -
N
-methyl-2- {2 - [(
E
) - ({1- [3- (trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} ethanamide (known from EP-A 0 596 254) of the formula
0012<chemistry id="chem0009" num="0009"><img file="EP2255646A2_D0009.tif" /></chemistry>
(2-7) Orysastrobin (known from DE-A 195 39 324) of the formula
0013<chemistry id="chem0010" num="0010"><img file="EP2255646A2_D0010.tif" /></chemistry>
(2-8) 5-methoxy-2-methyl-4- (2 - {[({(1
E
) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) -2,4-dihydro-3
H
-1,2,4-triazol-3-one (known from WO 98/23155) of the formula
0014<chemistry id="chem0011" num="0011"><img file="EP2255646A2_D0011.tif" /></chemistry>
(2-9) Kresoxim-methyl (known from EP-A 0 253 213) of the formula
0015<chemistry id="chem0012" num="0012"><img file="EP2255646A2_D0012.tif" /></chemistry>
(2-10) Dimoxystrobin (known from EP-A 0 398 692) of the formula
0016<chemistry id="chem0013" num="0013"><img file="EP2255646A2_D0013.tif" /></chemistry>
(2-11) Picoxystrobin (known from EP-A 0 278 595) of the formula
0017<chemistry id="chem0014" num="0014"><img file="EP2255646A2_D0014.tif" /></chemistry>
(2-12) pyraclostrobin (known from DE-A 44 23 612) of the formula
0018<chemistry id="chem0015" num="0015"><img file="EP2255646A2_D0015.tif" /></chemistry>
(2-13) Metominostrobin (known from EP-A 0 398 692) of the formula
0019<chemistry id="chem0016" num="0016"><img file="EP2255646A2_D0016.tif" /></chemistry>
(2-14) (2E) -2- {2 - [({[(1E) -1- (3 - {[(E) -1-fluoro-2-phenylvinyl] oxy} phenyl) ethylidene] amino} oxy ) methyl] -phenyl} -2- (methoxyimino) -N-methylacetamide (known from WO 01/12585) of the formula
0020<chemistry id="chem0017" num="0017"><img file="EP2255646A2_D0017.tif" /></chemistry>
(2-15) Enestrobin (known from EP-A 0 936 213) of the formula
0021<chemistry id="chem0018" num="0018"><img file="EP2255646A2_D0018.tif" /></chemistry>
Group (3) triazoles selected from
(3-1) Azaconazoles (known from DE-A 25 51 560) of the formula
0022<chemistry id="chem0019" num="0019"><img file="EP2255646A2_D0019.tif" /></chemistry>
(3-2) Etaconazole (known from DE-A 25 51 560) of the formula
0023<chemistry id="chem0020" num="0020"><img file="EP2255646A2_D0020.tif" /></chemistry>
(3-3) Propiconazole (known from DE-A 25 51 560) of the formula
0024<chemistry id="chem0021" num="0021"><img file="EP2255646A2_D0021.tif" /></chemistry>
(3-4) difenoconazoles (known from EP-A 0 112 284) of the formula
0025<chemistry id="chem0022" num="0022"><img file="EP2255646A2_D0022.tif" /></chemistry>
(3-5) Bromuconazole (known from EP-A 0 258 161) of the formula
0026<chemistry id="chem0023" num="0023"><img file="EP2255646A2_D0023.tif" /></chemistry>
(3-6) Cyproconazole (known from DE-A 34 06 993) of the formula
0027<chemistry id="chem0024" num="0024"><img file="EP2255646A2_D0024.tif" /></chemistry>
(3-7) Hexaconazoles (known from DE-A 30 42 303) of the formula
0028<chemistry id="chem0025" num="0025"><img file="EP2255646A2_D0025.tif" /></chemistry>
(3-8) Penconazole (known from DE-A 27 35 872) of the formula
0029<chemistry id="chem0026" num="0026"><img file="EP2255646A2_D0026.tif" /></chemistry>
(3-9) Myclobutanil (known from EP-A 0 145 294) of the formula
0030<chemistry id="chem0027" num="0027"><img file="EP2255646A2_D0027.tif" /></chemistry>
(3-10) tetraconazoles (known from EP-A 0 234 242) of the formula
0031<chemistry id="chem0028" num="0028"><img file="EP2255646A2_D0028.tif" /></chemistry>
(3-11) Flutriafol (known from EP-A 0 015 756) of the formula
0032<chemistry id="chem0029" num="0029"><img file="EP2255646A2_D0029.tif" /></chemistry>
(3-12) Epoxiconazole (known from EP-A 0 196 038) of the formula
0033<chemistry id="chem0030" num="0030"><img file="EP2255646A2_D0030.tif" /></chemistry>
(3-13) Flusilazoles (known from EP-A 0 068 813) of the formula
0034<chemistry id="chem0031" num="0031"><img file="EP2255646A2_D0031.tif" /></chemistry>
(3-14) Simeconazole (known from EP-A 0 537 957) of the formula
0035<chemistry id="chem0032" num="0032"><img file="EP2255646A2_D0032.tif" /></chemistry>
(3-15) prothioconazoles (known from WO 96/16048) of the formula
0036<chemistry id="chem0033" num="0033"><img file="EP2255646A2_D0033.tif" /></chemistry>
(3-16) Fenbuconazole (known from DE-A 37 21 786) of the formula
0037<chemistry id="chem0034" num="0034"><img file="EP2255646A2_D0034.tif" /></chemistry>
(3-17) Tebuconazole (known from EP-A 0 040 345) of the formula
0038<chemistry id="chem0035" num="0035"><img file="EP2255646A2_D0035.tif" /></chemistry>
(3-18) Ipconazole (known from EP-A 0 329 397) of the formula
0039<chemistry id="chem0036" num="0036"><img file="EP2255646A2_D0036.tif" /></chemistry>
(3-19) Metconazole (known from EP-A 0 329 397) of the formula
0040<chemistry id="chem0037" num="0037"><img file="EP2255646A2_D0037.tif" /></chemistry>
(3-20) Triticonazole (known from EP-A 0 378 953) of the formula
0041<chemistry id="chem0038" num="0038"><img file="EP2255646A2_D0038.tif" /></chemistry>
(3-21) Bitertanol (known from DE-A 23 24 010) of the formula
0042<chemistry id="chem0039" num="0039"><img file="EP2255646A2_D0039.tif" /></chemistry>
(3-22) triadimenol (known from DE-A 23 24 010) of the formula
0043<chemistry id="chem0040" num="0040"><img file="EP2255646A2_D0040.tif" /></chemistry>
(3-23) Triadimefon (known from DE-A 22 01 063) of the formula
0044<chemistry id="chem0041" num="0041"><img file="EP2255646A2_D0041.tif" /></chemistry>
(3-24) Fluquinconazole (known from EP-A 0 183 458) of the formula
0045<chemistry id="chem0042" num="0042"><img file="EP2255646A2_D0042.tif" /></chemistry>
(3-25) Quinconazole (known from EP-A 0 183 458) of the formula
0046<chemistry id="chem0043" num="0043"><img file="EP2255646A2_D0043.tif" /></chemistry>
(3-26) Amisulbrom (known from JP-A 2001-187786) of the formula
0047<chemistry id="chem0044" num="0044"><img file="EP2255646A2_D0044.tif" /></chemistry>
Group (4) sulfenamides / sulfonamides selected from
(4-1) Dichlofluanid (known from DE-A 11 93 498) of the formula
0048<chemistry id="chem0045" num="0045"><img file="EP2255646A2_D0045.tif" /></chemistry>
(4-2) Tolylfluanid (known from DE-A 11 93 498) of the formula
0049<chemistry id="chem0046" num="0046"><img file="EP2255646A2_D0046.tif" /></chemistry>
(4-3) N- (4-chloro-2-nitrophenyl) N-ethyl-4-methyl-benzenesulfonamide (known from WO 00/659513) of the formula
0050<chemistry id="chem0047" num="0047"><img file="EP2255646A2_D0047.tif" /></chemistry>
Group (5) valinamides selected from
(5-1) Iprovalicarb (known from DE-A 40 26 966) of the formula
0051<chemistry id="chem0048" num="0048"><img file="EP2255646A2_D0048.tif" /></chemistry>
(5-2)
N
1
- [2- (4 - {[3- (4-chlorophenyl) -2-propynyl] oxy} -3-methoxyphenyl) ethyl] -
N
2
- (methylsulfonyl) -L-valinamide
(5-3) Benthiavalicarb (known from WO 96/04252) of the formula
0052<chemistry id="chem0049" num="0049"><img file="EP2255646A2_D0049.tif" /></chemistry>
Group (6) carboxamides selected from
(6-1)
N
- [2- (1,3-dimethylbutyl) phenyl] -1,3-dimethyl-1
H
-pyrazole-4-carboxamide (known from JP-A 10-251240) of the formula
0053<chemistry id="chem0050" num="0050"><img file="EP2255646A2_D0050.tif" /></chemistry>
(6-2)
N
- [2- (1,3-Dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1
H
-pyrazole-4-carboxamide (known from WO 03/010149) of the formula
0054<chemistry id="chem0051" num="0051"><img file="EP2255646A2_D0051.tif" /></chemistry>
(6-3)
N
- [2- (1,3-Dimethylbutyl) phenyl] -5-chloro-1,3-dimethyl-1
H
-pyrazole-4-carboxamide (known from JP-A 10-251240) of the formula
0055<chemistry id="chem0052" num="0052"><img file="EP2255646A2_D0052.tif" /></chemistry>
(6-4) 3- (difluoromethyl) -
N
- [2- (1,3-dimethylbutyl) phenyl] -1-methyl-1
H
-pyrazole-4-carboxamide of the formula
0056<chemistry id="chem0053" num="0053"><img file="EP2255646A2_D0053.tif" /></chemistry>
(6-5) 3- (trifluoromethyl) -
N
- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1-methyl-1
H
-pyrazole-4-carboxamide (known from WO 2004/067515) of the formula
0057<chemistry id="chem0054" num="0054"><img file="EP2255646A2_D0054.tif" /></chemistry>
(6-6) 3- (trifluoromethyl) -
N
- [2- (1,3-dimethylbutyl) phenyl] -5-chloro-1-methyl-1
H
-pyrazole-4-carboxamide (known from JP-A 10-251240) of the formula
0058<chemistry id="chem0055" num="0055"><img file="EP2255646A2_D0055.tif" /></chemistry>
(6-7) 1,3-dimethyl
N
- [2- (1,3,3-trimethylbutyl) phenyl] -1
H
-pyrazole-4-carboxamide of the formula
0059<chemistry id="chem0056" num="0056"><img file="EP2255646A2_D0056.tif" /></chemistry>
(6-8) 5-fluoro-1,3-dimethyl
N
- [2- (1,3,3-trimethylbutyl) phenyl] -1
H
-pyrazole-4-carboxamide (known from WO 03/010149) of the formula
0060<chemistry id="chem0057" num="0057"><img file="EP2255646A2_D0057.tif" /></chemistry>
(6-9) 3- (difluoromethyl) -1-methyl-
N
- [2- (1,3,3-trimethylbutyl) phenyl] -1
H
-pyrazole-4-carboxamide of the formula
0061<chemistry id="chem0058" num="0058"><img file="EP2255646A2_D0058.tif" /></chemistry>
(6-10) 3- (trifluoromethyl) -1-methyl-
N
- [2- (1,3,3-trimethylbutyl) phenyl] -1
H
-pyrazole-4-carboxamide of the formula
0062<chemistry id="chem0059" num="0059"><img file="EP2255646A2_D0059.tif" /></chemistry>
(6-11) 3- (trifluoromethyl) -5-fluoro-1-methyl-
N
- [2- (1,3,3-trimethylbutyl) phenyl] -1
H
-pyrazole-4-carboxamide (known from WO 2004/067515) of the formula
0063<chemistry id="chem0060" num="0060"><img file="EP2255646A2_D0060.tif" /></chemistry>
(6-12) 3- (trifluoromethyl) -5-chloro-1-methyl-
N
- [2- (1,3,3-trimethylbutyl) phenyl] -1
H
-pyrazole-4-carboxamide of the formula
0064<chemistry id="chem0061" num="0061"><img file="EP2255646A2_D0061.tif" /></chemistry>
(6-13)
N
- [2- (1,3-Dimethylbutyl) phenyl] -2-iodobenzamide (known from WO 2004/005242) of the formula
0065<chemistry id="chem0062" num="0062"><img file="EP2255646A2_D0062.tif" /></chemistry>
(6-14) 2-iodine
N
- [2- (1,3,3-trimethylbutyl) phenyl] benzamide (known from WO 2004/005242) of the formula
0066<chemistry id="chem0063" num="0063"><img file="EP2255646A2_D0063.tif" /></chemistry>
(6-15)
N
- [2- (1,3-Dimethylbutyl) phenyl] -2- (trifluoromethyl) benzamide (known from WO 2004/005242) of the formula
0067<chemistry id="chem0064" num="0064"><img file="EP2255646A2_D0064.tif" /></chemistry>
(6-16) 2- (trifluoromethyl) -
N
- [2- (1,3,3-trimethylbutyl) phenyl] benzamide (known from WO 2004/005242) of the formula
0068<chemistry id="chem0065" num="0065"><img file="EP2255646A2_D0065.tif" /></chemistry>
(6-17) 2-chloro-N- (1,1,3-trimethyl-indan-4-yl) nicotinamide (known from EP-A 0 256 503) of the formula
0069<chemistry id="chem0066" num="0066"><img file="EP2255646A2_D0066.tif" /></chemistry>
(6-18) Boscalid (known from DE-A 195 31 813) of the formula
0070<chemistry id="chem0067" num="0067"><img file="EP2255646A2_D0067.tif" /></chemistry>
(6-19) Furametpyr (known from EP-A 0 315 502) of the formula
0071<chemistry id="chem0068" num="0068"><img file="EP2255646A2_D0068.tif" /></chemistry>
(6-20) 1-methyl-3-trifluoromethyl-1H-pyrazol-4-carboxylic acid- (3-p-tolylthiophene-2-yl) -amide (known from EP-A 0 737 682) of the formula
0072<chemistry id="chem0069" num="0069"><img file="EP2255646A2_D0069.tif" /></chemistry>
(6-21) Penthiopyrad (known from EP-A 0 737 682) of the formula
0073<chemistry id="chem0070" num="0070"><img file="EP2255646A2_D0070.tif" /></chemistry>
(6-22)
N
- [2- (1,3-Dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1
H
-pyrrole-3-carboxamide (known from WO 02/38542) of the formula
0074<chemistry id="chem0071" num="0071"><img file="EP2255646A2_D0071.tif" /></chemistry>
(6-23)
N
- (3 ', 4'-Dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1
H
-pyrazole-4-carboxamide (known from WO 03/070705) of the formula
0075<chemistry id="chem0072" num="0072"><img file="EP2255646A2_D0072.tif" /></chemistry>
(6-24) 3- (difluoromethyl) -
N
- {3'-fluoro-4 '- [(E) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1
H-
pyrazole-4-carboxamide (known from WO 02/08197) of the formula
0076<chemistry id="chem0073" num="0073"><img file="EP2255646A2_D0073.tif" /></chemistry>
(6-25) 3- (trifluonomethyl) -
N
- {3'-fluoro-4 '- [(
E
) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1
H-
pyrazole-4-carboxamide (known from WO 02/08197) of the formula
0077<chemistry id="chem0074" num="0074"><img file="EP2255646A2_D0074.tif" /></chemistry>
(6-26)
N
- (3 ', 4'-Dichloro-1,1'-biphenyl-2-yl) -5-fluoro-1,3-dimethyl-1
H
-pyrazole-4-carboxamide (known from WO 00/14701) of the formula
0078<chemistry id="chem0075" num="0075"><img file="EP2255646A2_D0075.tif" /></chemistry>
(6-27)
N
- (4'-Chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4- (trifluoromethyl) -1,3-thiazole-5-carboxamide (known from WO 03/066609 ) of the formula
0079<chemistry id="chem0076" num="0076"><img file="EP2255646A2_D0076.tif" /></chemistry>
(6-28)
N
- (4'-Chloro-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide (known from WO 03/066610) of the formula
0080<chemistry id="chem0077" num="0077"><img file="EP2255646A2_D0077.tif" /></chemistry>
(6-29)
N
- (4'-Bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide (known from WO 03/066610) of the formula
0081<chemistry id="chem0078" num="0078"><img file="EP2255646A2_D0078.tif" /></chemistry>
(6-30) 4- (difluoromethyl) -2-methyl-
N
- [4 '- (trifluoromethyl) -1,1'-biphenyl-2-yl] -1,3-thiazole-5-carboxamide (known from WO 03/066610) of the formula
0082<chemistry id="chem0079" num="0079"><img file="EP2255646A2_D0079.tif" /></chemistry>
(6-31)
N
- (4'-Iodo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide (known from WO 03/066610) of the formula
0083<chemistry id="chem0080" num="0080"><img file="EP2255646A2_D0080.tif" /></chemistry>
(6-32)
N
- (4'-Chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4- (difluoromethyl) -1,3-thiazole-5-carboxamide (known from WO 03/066610 ) of the formula
0084<chemistry id="chem0081" num="0081"><img file="EP2255646A2_D0081.tif" /></chemistry>
(6-33) Ethaboxam (known from EP-A 0 639 574) of the formula
0085<chemistry id="chem0082" num="0082"><img file="EP2255646A2_D0082.tif" /></chemistry>
(6-34) fenhexamide (known from EP-A 0 339 418) of the formula
0086<chemistry id="chem0083" num="0083"><img file="EP2255646A2_D0083.tif" /></chemistry>
(6-35) Carpropamide (known from EP-A 0 341 475) of the formula
0087<chemistry id="chem0084" num="0084"><img file="EP2255646A2_D0084.tif" /></chemistry>
(6-36) 2-chloro-4- (2-fluoro-2-methyl-propionylamino) -N, N-dimethyl-benzamide (known from EP-A 0 600 629) of the formula
0088<chemistry id="chem0085" num="0085"><img file="EP2255646A2_D0085.tif" /></chemistry>
(6-37) Fluopicolide (known from WO 99/42447) of the formula
0089<chemistry id="chem0086" num="0086"><img file="EP2255646A2_D0086.tif" /></chemistry>
(6-38) Zoxamides (known from EP-A 0 604 019) of the formula
0090<chemistry id="chem0087" num="0087"><img file="EP2255646A2_D0087.tif" /></chemistry>
(6-39) 3,4-dichloro-N- (2-cyanophenyl) isothiazole-5-carboxamide (known from WO 99/24413) of the formula
0091<chemistry id="chem0088" num="0088"><img file="EP2255646A2_D0088.tif" /></chemistry>
(6-40) carboxin (known from US 3,249,499) of the formula
0092<chemistry id="chem0089" num="0089"><img file="EP2255646A2_D0089.tif" /></chemistry>
(6-41) Tiadinil (known from US 6,616,054) of the formula
0093<chemistry id="chem0090" num="0090"><img file="EP2255646A2_D0090.tif" /></chemistry>
(6-42) Silthiofam (known from WO 96/18631) of the formula
0094<chemistry id="chem0091" num="0091"><img file="EP2255646A2_D0091.tif" /></chemistry>
(6-43)
N
- [2- (1,3-Dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1
H
-pyrrole-3-carboxamide (known from WO 02/38542) of the formula
0095<chemistry id="chem0092" num="0092"><img file="EP2255646A2_D0092.tif" /></chemistry>
(6-44)
N
- {2- [3-chloro-5- (trifluoromethyl) pyridin-2-yl] ethyl} -2- (trifluoromethyl) benzamide (known from WO 2004/016088) of the formula
0096<chemistry id="chem0093" num="0093"><img file="EP2255646A2_D0093.tif" /></chemistry>
(6-45) 1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxylic acid (2-bicyclopropyl-2-yl-phenyl) -amide (known from WO 2006/015865) of the formula
0097<chemistry id="chem0094" num="0094"><img file="EP2255646A2_D0094.tif" /></chemistry>
(6-46) 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxylic acid (2-bicyclopropyl-2-yl-phenyl) -amide (known from WO 2006/015865) of the formula
0098<chemistry id="chem0095" num="0095"><img file="EP2255646A2_D0095.tif" /></chemistry>
(6-47) 1-Methyl-3-trifluoromethyl-1H-pyrazol-4-carboxylic acid [2- (1'-methyl-bicyclopropyl-2-yl) phenyl] amide (known from WO 2006/015865) formula
0099<chemistry id="chem0096" num="0096"><img file="EP2255646A2_D0096.tif" /></chemistry>
(6-48) 1-Methyl-3-difluoromethyl-1H-pyrazole-4-carboxylic acid [2- (1'-methyl-bicyclopropyl-2-yl) phenyl] amide (known from WO 2006/015865) formula
0100<chemistry id="chem0097" num="0097"><img file="EP2255646A2_D0097.tif" /></chemistry>
(6-49) N- [1- (5-bromo-3-chloropyridin-2-yl) ethyl] -2,4-dichloronicotinamide of the formula
0101<chemistry id="chem0098" num="0098"><img file="EP2255646A2_D0098.tif" /></chemistry>
(6-50) N- (5-bromo-3-chloropyridin-2-yl) methyl-2,4-dichloronicotinamide of the formula
0102<chemistry id="chem0099" num="0099"><img file="EP2255646A2_D0099.tif" /></chemistry>
(6-51)
N
- (3 ', 4'-Dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1
H
-pyrazole-4-carboxamide (known from WO 2005/123690) of the formula
0103<chemistry id="chem0100" num="0100"><img file="EP2255646A2_D0100.tif" /></chemistry>
(6-52)
N
- (3 ', 4'-Dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1
H
-pyrazole-4-carboxamide (known from WO 2005/123689) of the formula
0104<chemistry id="chem0101" num="0101"><img file="EP2255646A2_D0101.tif" /></chemistry>
(6-53) 3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid [2- (3,3-dimethylbutyl) phenyl] amide of the formula
0105<chemistry id="chem0102" num="0102"><img file="EP2255646A2_D0102.tif" /></chemistry>
Group (7) dithiocarbamates selected from
(7-1) Mancozeb (known from DE-A 12 34 704) with the IUPAC name Manganese ethylenebis (dithiocarbamate) (polymeric) complex with zinc salt
(7-2) Maneb (known from US 2,504,404) of the formula
0106<chemistry id="chem0103" num="0103"><img file="EP2255646A2_D0103.tif" /></chemistry>
(7-3) Metiram (known from DE-A 10 76 434) with the IUPAC name Zinc ammoniate ethylenebis (dithiocarbamate) - poly (ethylenethiuram disulfide)
(7-4) Propineb (known from GB 935 981) of the formula
0107<chemistry id="chem0104" num="0104"><img file="EP2255646A2_D0104.tif" /></chemistry>
(7-5) Thiram (known from US 1,972,961) of the formula
0108<chemistry id="chem0105" num="0105"><img file="EP2255646A2_D0105.tif" /></chemistry>
(7-6) Zineb (known from DE-A 10 81446) of the formula
0109<chemistry id="chem0106" num="0106"><img file="EP2255646A2_D0106.tif" /></chemistry>
(7-7) Ziram (known from US 2,588,428) of the formula
0110<chemistry id="chem0107" num="0107"><img file="EP2255646A2_D0107.tif" /></chemistry>
Group (8) acylalanines selected from
(8-1) Benalaxyl (known from DE-A 29 03 612) of the formula
0111<chemistry id="chem0108" num="0108"><img file="EP2255646A2_D0108.tif" /></chemistry>
(8-2) Furalaxyl (known from DE-A 25 13 732) of the formula
0112<chemistry id="chem0109" num="0109"><img file="EP2255646A2_D0109.tif" /></chemistry>
(8-3) Metalaxyl (known from DE-A 25 15 091) of the formula
0113<chemistry id="chem0110" num="0110"><img file="EP2255646A2_D0110.tif" /></chemistry>
(8-4) Metalaxyl-M (known from WO 96/01559) of the formula
0114<chemistry id="chem0111" num="0111"><img file="EP2255646A2_D0111.tif" /></chemistry>
(8-5) Benalaxyl-M of the formula
0115<chemistry id="chem0112" num="0112"><img file="EP2255646A2_D0112.tif" /></chemistry>
Group (9): anilino-pyrimidines selected from
(9-1) Cyprodinil (known from EP-A 0 310 550) of the formula
0116<chemistry id="chem0113" num="0113"><img file="EP2255646A2_D0113.tif" /></chemistry>
(9-2) Mepanipyrim (known from EP-A 0 270 111) of the formula
0117<chemistry id="chem0114" num="0114"><img file="EP2255646A2_D0114.tif" /></chemistry>
(9-3) Pyrimethanil (known from DD 151 404) of the formula
0118<chemistry id="chem0115" num="0115"><img file="EP2255646A2_D0115.tif" /></chemistry>
Group (10): benzimidazoles selected from
(10-1) 6-Chloro-5 - [(3,5-dimethylisoxazol-4-yl) sulfonyl] -2,2-difluoro-5H- [1,3] dioxolo [4,5-f] benzimidazole (known from WO 97/06171) of the formula
0119<chemistry id="chem0116" num="0116"><img file="EP2255646A2_D0116.tif" /></chemistry>
(10-2) Benomyl (known from US 3,631,176) of the formula
0120<chemistry id="chem0117" num="0117"><img file="EP2255646A2_D0117.tif" /></chemistry>
(10-3) Carbendazim (known from US 3,010,968) of the formula
0121<chemistry id="chem0118" num="0118"><img file="EP2255646A2_D0118.tif" /></chemistry>
(10-4) Chlorfenazoles of the formula
0122<chemistry id="chem0119" num="0119"><img file="EP2255646A2_D0119.tif" /></chemistry>
(10-5) Fuberidazoles (known from DE-A 12 09 799) of the formula
0123<chemistry id="chem0120" num="0120"><img file="EP2255646A2_D0120.tif" /></chemistry>
(10-6) Thiabendazole (known from US 3,206,468) of the formula
0124<chemistry id="chem0121" num="0121"><img file="EP2255646A2_D0121.tif" /></chemistry>
Group (11): carbamates selected from
(11-1) Diethofencarb (known from EP-A 0 078 663) of the formula
0125<chemistry id="chem0122" num="0122"><img file="EP2255646A2_D0122.tif" /></chemistry>
(11-2) Propamocarb (known from US 3,513,241) of the formula
0126<chemistry id="chem0123" num="0123"><img file="EP2255646A2_D0123.tif" /></chemistry>
(11-3) Propamocarb hydrochloride (known from US 3,513,241) of the formula
0127<chemistry id="chem0124" num="0124"><img file="EP2255646A2_D0124.tif" /></chemistry>
(11-4) Propamocarb-fosetyl of the formula
0128<chemistry id="chem0125" num="0125"><img file="EP2255646A2_D0125.tif" /></chemistry>
Group (12): dicarboximides selected from
(12-1) Captafol (known from US 3,178,447) of the formula
0129<chemistry id="chem0126" num="0126"><img file="EP2255646A2_D0126.tif" /></chemistry>
(12-2) Captan (known from US 2,553,770) of the formula
0130<chemistry id="chem0127" num="0127"><img file="EP2255646A2_D0127.tif" /></chemistry>
(12-3) Folpet (known from US 2,553,770) of the formula
0131<chemistry id="chem0128" num="0128"><img file="EP2255646A2_D0128.tif" /></chemistry>
(12-4) Iprodione (known from DE-A 21 49 923) of the formula
0132<chemistry id="chem0129" num="0129"><img file="EP2255646A2_D0129.tif" /></chemistry>
(12-5) Procymidones (known from DE-A 20 12 656) of the formula
0133<chemistry id="chem0130" num="0130"><img file="EP2255646A2_D0130.tif" /></chemistry>
(12-6) Vinclozolin (known from DE-A 22 07 576) of the formula
0134<chemistry id="chem0131" num="0131"><img file="EP2255646A2_D0131.tif" /></chemistry>
Group (13): Guanidines selected from
(13-1) Dodine (known from GB 11 03 989) of the formula
0135<chemistry id="chem0132" num="0132"><img file="EP2255646A2_D0132.tif" /></chemistry>
(13-2) Guazatine (known from GB 11 14 155)
(13-3) Iminoctadine triacetate (known from EP-A 0 155 509) of the formula
0136<chemistry id="chem0133" num="0133"><img file="EP2255646A2_D0133.tif" /></chemistry>
(13-4) Iminoctadine tris (albesilate)
Group (14): Imidazole selected from
(14-1) Cyazofamide (known from EP-A 0 298 196) of the formula
0137<chemistry id="chem0134" num="0134"><img file="EP2255646A2_D0134.tif" /></chemistry>
(14-2) Prochloraz (known from DE-A 24 29 523) of the formula
0138<chemistry id="chem0135" num="0135"><img file="EP2255646A2_D0135.tif" /></chemistry>
(14-3) Triazoxides (known from DE-A 28 02 488) of the formula
0139<chemistry id="chem0136" num="0136"><img file="EP2255646A2_D0136.tif" /></chemistry>
(14-4) Pefurazoate (known from EP-A 0 248 086) of the formula
0140<chemistry id="chem0137" num="0137"><img file="EP2255646A2_D0137.tif" /></chemistry>
Group (15): morpholines selected from
(15-1) Aldimorph (known from DD 140 041) of the formula
0141<chemistry id="chem0138" num="0138"><img file="EP2255646A2_D0138.tif" /></chemistry>
(15-2) Tridemorph (known from GB 988 630) of the formula
0142<chemistry id="chem0139" num="0139"><img file="EP2255646A2_D0139.tif" /></chemistry>
(15-3) Dodemorph (known from DE-A 25 432 79) of the formula
0143<chemistry id="chem0140" num="0140"><img file="EP2255646A2_D0140.tif" /></chemistry>
(15-4) Fenpropimorph (known from DE-A 26 56 747) of the formula
0144<chemistry id="chem0141" num="0141"><img file="EP2255646A2_D0141.tif" /></chemistry>
(15-5) Dimethomorph (known from EP-A 0 219 756) of the formula
0145<chemistry id="chem0142" num="0142"><img file="EP2255646A2_D0142.tif" /></chemistry>
(15-6) Flumorph (known from EP-A 0 086 438) of the formula
0146<chemistry id="chem0143" num="0143"><img file="EP2255646A2_D0143.tif" /></chemistry>
Group (16): pyrroles selected from
(16-1) Fenpiclonil (known from EP-A 0 236 272) of the formula
0147<chemistry id="chem0144" num="0144"><img file="EP2255646A2_D0144.tif" /></chemistry>
(16-2) Fludioxonil (known from EP-A 0 206 999) of the formula
0148<chemistry id="chem0145" num="0145"><img file="EP2255646A2_D0145.tif" /></chemistry>
(16-3) Pyrrole nitrines (known from JP-A 65-25876) of the formula
0149<chemistry id="chem0146" num="0146"><img file="EP2255646A2_D0146.tif" /></chemistry>
Group (17): phosphonates selected from
(17-1) Fosetyl-Al (known from DE-A 24 56 627) of the formula
0150<chemistry id="chem0147" num="0147"><img file="EP2255646A2_D0147.tif" /></chemistry>
(17-2) Phosphonic acid (known chemical) of the formula
0151<chemistry id="chem0148" num="0148"><img file="EP2255646A2_D0148.tif" /></chemistry>
Group (18): phenylethanamides (known from WO 96/23793, E or Z isomer, preferably E isomer) selected from
(18-1) 2- (2,3-Dihydro-1H-inden-5-yl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide of the formula
0152<chemistry id="chem0149" num="0149"><img file="EP2255646A2_D0149.tif" /></chemistry>
(18-2) N- [2- (3,4-Dimethoxyphenyl) ethyl] -2- (methoxyimino) -2- (5,6,7,8-tetrahydronaphthalene-2-yl) acetamide of the formula
0153<chemistry id="chem0150" num="0150"><img file="EP2255646A2_D0150.tif" /></chemistry>
(18-3) 2- (4-chlorophenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide of the formula
0154<chemistry id="chem0151" num="0151"><img file="EP2255646A2_D0151.tif" /></chemistry>
(18-4) 2- (4-bromophenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide of the formula
0155<chemistry id="chem0152" num="0152"><img file="EP2255646A2_D0152.tif" /></chemistry>
(18-5) 2- (4-methylphenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide of the formula
0156<chemistry id="chem0153" num="0153"><img file="EP2255646A2_D0153.tif" /></chemistry>
(18-6) 2- (4-ethylphenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide of the formula
0157<chemistry id="chem0154" num="0154"><img file="EP2255646A2_D0154.tif" /></chemistry>
Group (19): fungicides selected from
(19-1) Acibenzolar-S-methyl (known from EP-A 0 313 512) of the formula
0158<chemistry id="chem0155" num="0155"><img file="EP2255646A2_D0155.tif" /></chemistry>
(19-2) Chlorothalonil (known from US 3,290,353) of the formula
0159<chemistry id="chem0156" num="0156"><img file="EP2255646A2_D0156.tif" /></chemistry>
(19-3) Cymoxanil (known from DE-A 23 12 956) of the formula
0160<chemistry id="chem0157" num="0157"><img file="EP2255646A2_D0157.tif" /></chemistry>
(19-4) Edifenphos (known from DE-A 14 93 736) of the formula
0161<chemistry id="chem0158" num="0158"><img file="EP2255646A2_D0158.tif" /></chemistry>
(19-5) Famoxadone (known from EP-A 0 393 911) of the formula
0162<chemistry id="chem0159" num="0159"><img file="EP2255646A2_D0159.tif" /></chemistry>
(19-6) Fluazinam (known from EP-A 0 031 257) of the formula
0163<chemistry id="chem0160" num="0160"><img file="EP2255646A2_D0160.tif" /></chemistry>
(19-7) copper oxychloride
(19-9) Oxadixyl (known from DE-A 30 30 026) of the formula
0164<chemistry id="chem0161" num="0161"><img file="EP2255646A2_D0161.tif" /></chemistry>
(19-10) Spiroxamines (known from DE-A 37 35 555) of the formula
0165<chemistry id="chem0162" num="0162"><img file="EP2255646A2_D0162.tif" /></chemistry>
(19-11) Dithianon (known from JP-A 44-29464) of the formula
0166<chemistry id="chem0163" num="0163"><img file="EP2255646A2_D0163.tif" /></chemistry>
(19-12) Metrafenone (known from EP-A 0 897 904) of the formula
0167<chemistry id="chem0164" num="0164"><img file="EP2255646A2_D0164.tif" /></chemistry>
(19-13) fenamidones (known from EP-A 0 629 616) of the formula
0168<chemistry id="chem0165" num="0165"><img file="EP2255646A2_D0165.tif" /></chemistry>
(19-14) 2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidin-4 (3H) one (known from WO 99/14202) of the formula
0169<chemistry id="chem0166" num="0166"><img file="EP2255646A2_D0166.tif" /></chemistry>
(19-15) probenazole (known from US 3,629,428) of the formula
0170<chemistry id="chem0167" num="0167"><img file="EP2255646A2_D0167.tif" /></chemistry>
(19-16) Isoprothiolane (known from US 3,856,814) of the formula
0171<chemistry id="chem0168" num="0168"><img file="EP2255646A2_D0168.tif" /></chemistry>
(19-17) Kasugamycin (known from GB 1 094 567) of the formula
0172<chemistry id="chem0169" num="0169"><img file="EP2255646A2_D0169.tif" /></chemistry>
(19-18) Phthalides (known from JP-A 57-55844) of the formula
0173<chemistry id="chem0170" num="0170"><img file="EP2255646A2_D0170.tif" /></chemistry>
(19-19) Ferimzone (known from EP-A 0 019 450) of the formula
0174<chemistry id="chem0171" num="0171"><img file="EP2255646A2_D0171.tif" /></chemistry>
(19-20) Tricyclazole (known from DE-A 22 50 077) of the formula
0175<chemistry id="chem0172" num="0172"><img file="EP2255646A2_D0172.tif" /></chemistry>
(19-21) N - ({4 - [(Cyclopropylamino) carbonyl] phenyl} sulfonyl) -2-methoxybenzamide of the formula
0176<chemistry id="chem0173" num="0173"><img file="EP2255646A2_D0173.tif" /></chemistry>
(19-22) 2- (4-chlorophenyl) -N- {2- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] ethyl} -2- (prop-2-yn 1-yloxy) acetamide (known from WO 01/87822) of the formula
0177<chemistry id="chem0174" num="0174"><img file="EP2255646A2_D0174.tif" /></chemistry>
(19-23) Proquinazide (known from WO 09426722) of the formula
0178<chemistry id="chem0175" num="0175"><img file="EP2255646A2_D0175.tif" /></chemistry>
(19-24) Quinoxyfen (known from EP-A 0 326 330) of the formula
0179<chemistry id="chem0176" num="0176"><img file="EP2255646A2_D0176.tif" /></chemistry>
(19-25) Cyflufenamid (known from WO 96/19442) of the formula
0180<chemistry id="chem0177" num="0177"><img file="EP2255646A2_D0177.tif" /></chemistry>
(19-26) Pyribencarb (known from WO 01/10825) of the formula
0181<chemistry id="chem0178" num="0178"><img file="EP2255646A2_D0178.tif" /></chemistry>
(19-27) 3- [5- (4-chlorophenyl) -2,3-dimethyl-3-isoxazolidinyl] pyridine (known from EP-A 1 035 122) of the formula
0182<chemistry id="chem0179" num="0179"><img file="EP2255646A2_D0179.tif" /></chemistry>
Group (20): (Thio) urea derivatives selected from
(20-1) Pencycuron (known from DE-A 27 32 257) of the formula
0183<chemistry id="chem0180" num="0180"><img file="EP2255646A2_D0180.tif" /></chemistry>
(20-2) Thiophanate-methyl (known from DE-A 18 06 123) of the formula
0184<chemistry id="chem0181" num="0181"><img file="EP2255646A2_D0181.tif" /></chemistry>
(20-3) Thiophanate-ethyl (known from DE-A 18 06 123) of the formula
0185<chemistry id="chem0182" num="0182"><img file="EP2255646A2_D0182.tif" /></chemistry>
Group (21): amides selected from
(21-1) Fenoxanil (known from EP-A 0 262 393) of the formula
0186<chemistry id="chem0183" num="0183"><img file="EP2255646A2_D0183.tif" /></chemistry>
(21-2) Diclocymet (known from JP-A 7-206608) of the formula
0187<chemistry id="chem0184" num="0184"><img file="EP2255646A2_D0184.tif" /></chemistry>
Group (22): triazolopyrimidines selected from
(22-1) 5-chlorine
N
-[
(1S)
-2,2,2-trifluoro-1-methylethyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidin-7-amine (known from US 5,986,135 ) of the formula
0188<chemistry id="chem0185" num="0185"><img file="EP2255646A2_D0185.tif" /></chemistry>
(22-2) 5-chlorine
N
-[
(1R)
-1,2-dimethylpropyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidin-7-amine (known from WO 02/38565) of the formula
0189<chemistry id="chem0186" num="0186"><img file="EP2255646A2_D0186.tif" /></chemistry>
(22-3) 5-Chloro-6- (2-chloro-6-fluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine (known from US 5,593,996) of the formula
0190<chemistry id="chem0187" num="0187"><img file="EP2255646A2_D0187.tif" /></chemistry>
(22-4) 5-Chloro-6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine (known from DE-A 101 24 208) of the formula
0191<chemistry id="chem0188" num="0188"><img file="EP2255646A2_D0188.tif" /></chemistry>
Group (23): iodochromones selected from
(23-1) 2-Butoxy-6-iodo-3-propyl-benzopyran-4-one (known from WO 03/014103) of the formula
0192<chemistry id="chem0189" num="0189"><img file="EP2255646A2_D0189.tif" /></chemistry>
(23-2) 2-ethoxy-6-iodo-3-propyl-benzopyran-4-one (known from WO 03/014103) of the formula
0193<chemistry id="chem0190" num="0190"><img file="EP2255646A2_D0190.tif" /></chemistry>
(23-3) 6-iodo-2-propoxy-3-propyl-benzopyran-4-one (known from WO 03/014103) of the formula
0194<chemistry id="chem0191" num="0191"><img file="EP2255646A2_D0191.tif" /></chemistry>
(23-4) 2-But-2-ynyloxy-6-iodo-3-propyl-benzopyran-4-one (known from WO 03/014103) of the formula
0195<chemistry id="chem0192" num="0192"><img file="EP2255646A2_D0192.tif" /></chemistry>
(23-5) 6-iodo-2- (1-methyl-butoxy) -3-propyl-benzopyran-4-one (known from WO 03/014103) of the formula
0196<chemistry id="chem0193" num="0193"><img file="EP2255646A2_D0193.tif" /></chemistry>
(23-6) 2-But-3-enyloxy-6-iodo-benzopyran-4-one (known from WO 03/014103) of the formula
0197<chemistry id="chem0194" num="0194"><img file="EP2255646A2_D0194.tif" /></chemistry>
(23-7) 3-butyl-6-iodo-2-isopropoxy-benzopyran-4-one (known from WO 03/014103) of the formula
0198<chemistry id="chem0195" num="0195"><img file="EP2255646A2_D0195.tif" /></chemistry>Surprisingly, the fungicidal action of the active compound combinations according to the invention is considerably higher than the sum of the actions of the individual active compounds. So there is an unforeseeable, real synergistic effect and not just an addition.
0199The compound (6-35) carpropamide has three asymmetric substituted carbon atoms. The compound (6-35) can therefore be present as a mixture of different isomers or in the form of a single component. The compounds (1<i>S</i>,3<i>R</i>) -2,2-dichloro-<i>N</i>-[(1<i>R</i>) -1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxamide of the formula<chemistry id="chem0196" num="0196"><img file="EP2255646A2_D0196.tif" /></chemistry>and (1<i>R</i>,3<i>S</i>) -2,2-dichloro-<i>N</i>-[(1<i>R</i>) -1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxane and of the formula<chemistry id="chem0197" num="0197"><img file="EP2255646A2_D0197.tif" /></chemistry>
0200Emphasis is given to active ingredient combinations according to the invention which, in addition to (1-1) glyphosate, contain one or more, preferably one, mixture partner of groups (2) to (23).
0201Emphasis is given to active compound combinations according to the invention which, in addition to (1-2) glufosinates, contain one or more, preferably one, mixing partner of groups (2) to (23).
0202Emphasis is given to active ingredient combinations according to the invention which, in addition to (1-3) glufosinate ammonium, contain one or more, preferably one, mixing partner of groups (2) to (23).
0203The following active ingredients are preferred as mixing partners of groups (2) to (23):<ul id="ul0001" list-style="none" compact="compact"><li>(2-1) azoxystrobin, (2-2) fluoxastrobin, (2-3) (2<i>E</i>) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl] oxy} phenyl) -2- (methoxyimino) -<i>N</i>-methylethanamide, (2-4) trifloxystrobin, (2-5) (2<i>E</i>) -2- (methoxyimino) -<i>N</i>-methyl-2- (2 - {[({(1<i>E</i>) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) ethanamide, (2-6) (2nd<i>E</i>) -2- (methoxyimino) -<i>N</i>-methyl-2- {2 - [(<i>E</i>) - ({1- [3- (trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} ethanamide, (2-8) 5-methoxy-2-methyl-4- (2 - {[({(1<i>E</i>) -1- [3- (trifluoromethyl) phenyl] ethylideneamino) oxy] methyl} phenyl) -2,4-dihydro-3<i>H</i>-1,2,4-triazol-3-one, (2-11) picoxystrobin, (2-9) kresoxim-methyl, (2-10) dimoxystrobin, (2-12) pyraclostrobin, (2-13) metominostrobin, (3-3) propiconazole, (3-4) difenoconazole, (3-6) cyproconazole, (3-7) hexaconazole, (3-8) penconazole, (3-9) myclobutanil, (3-10) tetraconazole, ( 3-13) flusilazole, (3-15) prothioconazole, (3-16) fenbuconazole, (3-17) tebuconazole, (3-21) bitertanol, (3-22) triadimenol, (3-23) triadimphone, (3 -12) epoxiconazole, (3-19) metconazole, (3-24) fluquinconazole, (4-1) dichlofluanide, (4-2) tolylfluanid, (5-1) iprovalicarb, (5-3) benthiavalicarb, (6-2) <i>N</i>- [2- (1,3-Dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1<i>H</i>-pyrazole-4-carboxamide, (6-5) 3- (trifluoromethyl) -<i>N</i>- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1-methyl-1<i>H</i>-pyrazo1-4-carboxamide, (6-8) 5-fluoro-1,3-dimethyl-<i>N</i>- [2- (1,3,3-trimethylbutyl) phenyl] -1<i>H</i>-pyrazole-4-carboxamide, (6-13) <i>N</i>- [2- (1,3-dimethylbutyl) phenyl] -2-iodobenzamide, (6-15) <i>N</i>- [2- (1,3-dimethylbutyl) phenyl] -2- (trifluoromethyl) benzamide, (6-18) boscalid, (6-19) furametpyr, (6-21) penthiopyrad, (6-22) <i>N</i>- [2- (1,3-Dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1<i>H</i>-pyrrole-3-carboxamide, (6-23) <i>N</i>- (3 ', 4'-Dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1<i>H</i>-pyrazole-4-carboxamide, (6-24) 3- (difluoromethyl) -<i>N-</i>{3'-fluoro-4 '- [(<i>E</i>) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1<i>H</i>-pyrazole-4-carboxamide, (6-25) 3- (trifluoromethyl) -<i>N</i>-3'-fluoro-4 '- [(<i>E</i>) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1<i>H</i>-pyrazole-4-carboxamide, (6-26) <i>N</i>- (3 ', 4'-Dichloro-1,1'-biphenyl-2-yl) -5-fluoro-1,3-dimethyl-1<i>H</i>-pyrazole-4-carboxamide, (6-29) <i>N-</i>(4'-bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide, (6-31) <i>N</i>- (4'-Iodo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide, (6-32) N- (4'- Chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4- (difluoromethyl) -1,3-thiazole-5-carboxamide, (6-33) ethaboxam, (6-34 ) Fenhexamide, (6-35) carpropamide, (6-36) 2-chloro-4 - [(2-fluoro-2-methylpropanoyl) amino] -<i>N, N</i>-dimethylbenzamide, (6-37) fluopicolide, (6-38) zoxamide, (6-39) 3,4-dichloro-N- (2-cyanophenyl) isothiazole-5-carboxamide, (6-43) <i>N</i>- [2- (1,3-Dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1<i>H</i>-pyrrole-3-carboxamide, (6-44) <i>N</i>- {2- [3-chloro-5- (trifluoromethyl) pyridin-2-yl] ethyl} -2- (trifluoromethyl) benzamide, (6-45) 1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxylic acid - (2-bicyclopropyl-2-yl-phenyl) -amide, (6-46) 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxylic acid- (2-bicyclopropyl-2-yl-phenyl) -amide, (6-47) 1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxylic acid- [2- (1'-methyl-bicyclopropyl-2-yl) phenyl] amide, (6-48) 1-methyl -3-difluoromethyl-1H-pyrazole-4-carboxylic acid- [2- (1'-methyl-bicyclopropyl-2-yl) phenyl] amide, (6-49) N- [1- (5-bromo-3-chloropyridin-2-yl) ethyl] -2,4-dichloronicotinamide, (6-50) N- (5-bromo-3-chloropyridin-2- yl) methyl-2,4-dichlomicotinamide, (6-51) N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1- methyl-1H-pyrazole-4-carboxarnide, (6-52) N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1- methyl-1H-pyrazole-4-carboxamide, (6-53) 3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid [2- (3,3-dimethylbutyl) phenyl] amide, (7th -1) Mancozeb, (7-2) Maneb, (7-4) Propineb, (7-5) Thiram, (7-6) zineb, (8-1) benalaxyl, (8-2) furalaxyl, (8-3) metalaxyl, (8-4) metalaxyl-M, (8-5) benalaxyl-M, (9-1 ) Cyprodinil, (9-2) mepanipyrim, (9-3) pyrimethanil, (10-1) 6-chloro-5 - [(3,5-dimethylisoxazol-4-yl) sulfonyl] -2,2-difluoro-5H - [1,3] dioxolo [4,5-f] benzimidazole, (10-3) carbendazim, (11-1) diethofen carb, (11-2) propamocarb, (11-3) propamocarb hydrochloride, (11-4 ) Propamocarb-Fosetyl, (12-2) Captan, (12-3) Folpet, (12-4) Iprodione, (12-5) Procymidone, (13-1) Dodine, (13-2) Guazatine, (13-3) iminoctadine triacetate, (14-1) cyazofamide, (14-2) prochloraz, (14-3) triazoxide, (15-5) dimethomorph, (15-4) fenpropimorph, (16-2) fludioxonil, (17-1) fosetyl-Al, (17-2) phosphonic acid, (19-1) acibenzolar-S-methyl, (19-2) chlorothalonil, (19-3) cymoxanil, (19-5) famoxadone, ( 19-6) fluazinam, (19-9) oxadixyl, (19-10) spiroxamines, (19-7) copper oxychloride, (19-13) fenamidones, (19-22) 2- (4-chlorophenyl) -N- { 2- [3-methoxy-4- (prop-2-in-1-yloxy) phenyl] ethyl} -2- (prop-2-in-1-yloxy) acetamide, (20-1) pencycuron, (20-2) thiophanate-methyl, (22-1) 5-chloro<i>N</i>-[<i>(1S) -</i>2,2,2-trifluoro-1-methylethyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidin-7-amine, (22-2) 5-chlorine<i>N-</i>[<i>(1R)</i>-1,2-dimethylpropyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidin-7-amine, (22-4) 5-chloro-6 - (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine, (23-1) 2-butoxy-6- iodo-3-propyl-benzopyran-4-one, (23-2) 2-ethoxy-6-iodo-3-propyl-benzopyran-4-one, (23-3) 6-iodo-2-propoxy-3- propyl-benzopyran-4-one.</li></ul>
0204To combat rust diseases on soy plants, the following are particularly preferred:<ul id="ul0002" list-style="none" compact="compact"><li>(2-1) azoxystrobin, (2-2) fluoxastrobin, (2-4) trifloxystrobin, (2-6) (2<i>E</i>) -2- (methoxyimino) -<i>N</i>-methyl-2- {2 - [(<i>E</i>) - ({1- [3- (trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} ethanamide, (2-8) 5-methoxy-2-methyl-4- (2 - {[({(1<i>E</i>) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) -2,4-dihydro-3<i>H</i>-1,2,4-triazol-3-one, (2-11) picoxystrobin, (2-9) kresoxim-methyl, (2-10) dimoxystrobin, (2-12) pyraclostrobin, (2-13) metominostrobin, (3-3) propiconazole, (3-4) difenoconazole, (3-6) cyproconazole, (3-7) hexaconazole, (3-8) penconazole, (3-9) myclobutanil, (3-10) tetraconazole, ( 3-13) flusilazole, (3-15) prothioconazole, (3-16) fenbuconazole, (3-17) tebuconazole, (3-21) bitertanol, (3-22) triadimenol, (3-23) triadimphone, (3 -12) epoxiconazole, (3-19) metconazole, (3-24) fluquinconazole, (4-1) dichlofluanide, (4-2) tolylfluanid, (6-2) <i>N</i>- [2- (1,3-Dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1<i>H</i>-pyrazole-4-carboxamide, (6-8) 5-fluoro-1,3-dimethyl-<i>N</i>- [2- (1,3,3-trimethylbutyl) phenyl] -1<i>H</i>-pyrazole-4-carboxamide, (6-13) <i>N</i>- [2- (1,3-dimethylbutyl) phenyl] -2-iodobenzamide, (6-15) <i>N</i>- [2- (1,3-dimethylbutyl) phenyl] -2- (trifluoromethyl) benzamide, (6-18) boscalid, (6-19) furametpyr, (6-21) penthiopyrad, (6-22) <i>N</i>- [2- (1,3-Dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1<i>H</i>-pyrrole-3-carboxamide, (6-23) <i>N</i>- (3 ', 4'-Dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1<i>H</i>-pyrazole-4-carboxamide, (6-26) <i>N</i>- (3 ', 4'-Dichloro-1,1'-biphenyl-2-yl) -5-fluoro-1,3-dimethyl-1<i>H</i>-pyrazole-4-carboxamide, (6-29) N- (4'-bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazol-5- carboxamide, (6-31) <i>N</i>- (4'-Iodo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide, (6-32) N- (4'- Chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4- (difluoromethyl) -1,3-thiazole-5-carboxamide, (6-39) 3,4-dichloro- N- (2-cyanophenyl) isothiazole-5-carboxamide, (6-43) <i>N</i>- [2- (1,3-Dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1<i>H</i>-pyrrole-3-carboxamide, (6-45) 1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxylic acid- (2-bicyclopropyl-2-yl-phenyl) -amide, (6-46) 1-methyl -3-difluoromethyl-1H-pyrazole-4-carboxylic acid- (2-bicyclopropyl-2-yl-phenyl) -amide, (6-47) 1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxylic acid- [2 - (1'-methyl-bicyclopropyl-2-yl) phenyl] amide, (6-48) 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxylic acid- [2- (1'-methyl-bicyclopropyl -2-yl) phenyl] amide, (6-49) N- [1- (5-bromo-3-chloropyridin-2-yl) ethyl] -2,4-dichlomicotinamide, (6-50) N- (5-bromo-3-chloropyridin-2-yl) methyl-2,4-dichloronicotinamide, (6-51) N- (3 ', 4'-dichloro-5-fluoro-1, 1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (6-52) N- (3 ', 4'-dichloro-5-fluoro-1, 1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (6-53) 3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid [2nd - (3,3-dimethylbutyl) phenyl] amide, (7-1) mancozeb, (7-2) maneb, (7-4) propineb, (7-5) thiram, (7-6) zineb , (9-1) cyprodinil, (9-2) mepanipyrim, (9-3) pyrimethanil, (10-3) Carbendazim, (11-1) Diethofencarb, (12-2) Captan, (12-3) Folpet, (12-4) Iprodione, (12-5) Procymidone, (13-1) Dodine, ( 13-2) Guazatine, (13-3) iminoctadine triacetate, (14-2) prochloraz, (15-4) fenpropimorph, (16-2) fludioxonil, (19-1) acibenzolar-S-methyl, (19-2 ) Chlorothalonil, (19-3) cymoxanil, (19-6) fluazinam, (19-10) spiroxamines, (19-7) copper oxychloride, (20-2) thiophanate-methyl, (22-1) 5-chloro<i>N</i>-[<i>(1S)</i>-2,2,2-trifluoro-1-methylethyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidin-7-amine, (22-2 ) 5-chlorine<i>N</i>-[<i>(1R)</i>-1,2-dimethylpropyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidin-7-amino, (22-4) 5-chloro-6 - (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine.</li></ul>
0205The following active ingredients are particularly preferred as mixing partners of groups (2) to (23):<ul id="ul0003" list-style="none" compact="compact"><li>(2-2) fluoxastrobin, (2-4) trifloxystrobin, (2-3) (2<i>E</i>) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl] oxy} phenyl) -2- (methoxyimino) -<i>N</i>-methylethanamide, (3-15) prothioconazole, (3-17) tebuconazole, (3-21) bitertanol, (3-22) triadimenol, (3-24) fluquinconazole, (4-1) dichlofluanide, (4-2) Tolylfluanid, (5-1) Iprovalicarb, (6-2) <i>N</i>- [2- (1,3-Dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1<i>H</i>-pyrazole-4-carboxamide, (6-8) 5-fluoro-1,3-dimethyl-<i>N</i>- [2- (1,3,3-trimethylbutyl) phenyl] -1<i>H</i>-pyrazole-4-carboxamide, (6-13) <i>N</i>- [2- (1,3-dimethylbutyl) phenyl] -2-iodobenzamide, (6-15) <i>N</i>- [2- (1,3-dimethylbutyl) phenyl] -2- (trifluoromethyl) benzamide, (6-18) boscalid, (6-21) penthiopyrad, (6-22) <i>N</i>- [2- (1,3-Dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1<i>H</i>-pyrrole-3-carboxamide, (6-23) <i>N</i>- (3 ', 4'-Dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1<i>H</i>-pyrazole-4-carboxamide, (6-29) <i>N</i>- (4'-bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide, (6-31) <i>N</i>- (4'-iodo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide, (6-32) <i>N</i>- (4'-Chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4- (difluoromethyl) -1,3-thiazole-5-carboxamide, (6-34) fenhexamide , (6-35) carpropamide, (6-37) fluopicolide, (6-44) <i>N</i>- {2- [3-chloro-5- (trifluoromethyl) pyridin-2-yl] ethyl} -2- (trifluoromethyl) benzamide, (6-53) 3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid [2- (3,3-dimethylbutyl) phenyl] amide, (7-4) propineb, (8-4) metalaxyl-M, (8-5) benalaxyl-M, (9-3) pyrimethanil, (10-3) carbendazim, (11-4) propamocarb-fosetyl, (12-4) iprodione, (14-2) prochloraz, (14-3) triazoxides, (16-2) fludioxonil, (19-10) spiroxamines , (19-22) 2- (4-chlorophenyl) -N- {2- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] ethyl} -2- (prop-2-yn -1-yloxy) acetamide, (22-4) 5-chloro-6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine.</li></ul>
0206To combat rust diseases on soy plants, the following are particularly preferred:<ul id="ul0004" list-style="none" compact="compact"><li>(2-2) fluoxastrobin, (2-4) trifloxystrobin, (3-15) prothioconazole, (3-17) tebuconazole, (3-21) bitertanol, (3-22) triadimenol, (3-24) fluquinconazole, ( 4-1) dichlofluanid, (4-2) tolylfluanid, (6-2) <i>N</i>- [2- (1,3-Dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1<i>H</i>-pyrazole-4-carboxamide, (6-8) 5-fluoro-1,3-dimethyl-<i>N</i>- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide, (6-13) <i>N</i>- [2- (1,3-dimethylbutyl) phenyl] -2-iodobenzamide, (6-15) <i>N</i>- [2- (1,3-dimethylbutyl) phenyl] -2- (trifluoromethyl) benzamide, (6-18) boscalid, (6-21) penthiopyrad, (6-22) <i>N</i>- [2- (1,3-Dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1<i>H</i>-pyrrole-3-carboxamide, (6-23) <i>N</i>- (3 ', 4'-Dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1<i>H</i>-pyrazole-4-carboxamide, (6-29) <i>N</i>- (4'-bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide, (6-31) <i>N</i>- (4'-iodo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide, (6-32) <i>N</i>- (4'-Chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4- (difluoromethyl) -1,3-thiazole-5-carboxamide, (6-53) 3 -Difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid [2- (3,3-dimethylbutyl) phenyl] amide, (7-4) propineb, (9-3) pyrimethanil, (10-3 ) Carbendazim, (12-4) iprodione, (14-2) prochloraz, (16-2) fludioxonil, (19-10) spiroxamines, (22-4) 5-chloro-6- (2,4,6-trifluorophenyl ) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine.</li></ul>
0207Preferred combinations of active ingredients are described below which consist of two groups of active ingredients and each contain at least one herbicide from group (1) and at least one active ingredient from the specified group (2) to (23).
0208The active substance combinations listed in Table 1 below are highlighted:<tables id="tabl0001" num="0001"><table frame="topbot"><title><b>Table 1:</b></title><tgroup cols="3" colsep="0"><colspec colnum="1" colname="col1" colwidth="11mm" /><colspec colnum="2" colname="col2" colwidth="45mm" /><colspec colnum="3" colname="col3" colwidth="110mm" /><thead><row valign="middle"><entry><b>No.</b></entry><entry><b>herbicide</b></entry><entry><b>Active ingredient in group (2) to (23)</b></entry></row></thead><tbody><row valign="middle"><entry>1</entry><entry>(1-1) Glyphosate</entry><entry>(2-2) Fluoxastrobin</entry></row><row valign="middle"><entry>2</entry><entry>(1-1) Glyphosate</entry><entry>(2-4) trifloxystrobin</entry></row><row valign="middle"><entry>3</entry><entry>(1-1) Glyphosate</entry><entry>(2-3) (2E) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidynyl] oxy} phenyl) -2- (methoxyimino) -N -methylethanamide</entry></row><row valign="middle"><entry>4</entry><entry>(1-1) Glyphosate</entry><entry>(3-15) prothioconazole</entry></row><row valign="middle"><entry>5</entry><entry>(1-1) Glyphosate</entry><entry>(3-17) Tebuconazole</entry></row><row valign="middle"><entry>6</entry><entry>(1-1) Glyphosate</entry><entry>(3-21) Bitertanol</entry></row><row valign="middle"><entry>7</entry><entry>(1-1) Glyphosate</entry><entry>(3-22) triadimenol</entry></row><row valign="middle"><entry>8</entry><entry>(1-1) Glyphosate</entry><entry>(3-24) fluquinconazole</entry></row><row valign="middle"><entry>9</entry><entry>(1-1) Glyphosate</entry><entry>(4-1) dichlofluanide</entry></row><row valign="middle"><entry>10</entry><entry>(1-1) Glyphosate</entry><entry>(4-2) Tolylfluanid</entry></row><row valign="middle"><entry>11</entry><entry>(1-1) Glyphosate</entry><entry>(5-1) Iprovalicarb</entry></row><row valign="middle"><entry>12</entry><entry>(1-1) Glyphosate</entry><entry>(6-2) N- [2- (1,3-Dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide</entry></row><row valign="middle"><entry>13</entry><entry>(1-1) Glyphosate</entry><entry>(6-8) 5-fluoro-1,3-dimethyl-N- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide</entry></row><row valign="middle"><entry>14</entry><entry>(1-1) Glyphosate</entry><entry>(6-13) N- [2- (1,3-dimethylbutyl) phenyl] -2-iodobenzamide</entry></row><row valign="middle"><entry>15</entry><entry>(1-1) Glyphosate</entry><entry>(6-15) N- [2- (1,3-dimethylbutyl) phenyl] -2- (trifluoromethyl) benzamide</entry></row><row valign="middle"><entry>16</entry><entry>(1-1) Glyphosate</entry><entry>(6-18) Boscalid</entry></row><row valign="middle"><entry>17</entry><entry>(1-1) Glyphosate</entry><entry>(6-21) Penthiopyrad</entry></row><row valign="middle"><entry>18</entry><entry>(1-1) Glyphosate</entry><entry>(6-22) N- [2- (1,3-dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1H-pyrrole-3-carboxamide</entry></row><row valign="middle"><entry>19</entry><entry>(1-1) Glyphosate</entry><entry>(6-23) N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide</entry></row><row valign="middle"><entry>20</entry><entry>(1-1) Glyphosate</entry><entry>(6-29) N- (4'-bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide</entry></row><row valign="middle"><entry>21</entry><entry>(1-1) Glyphosate</entry><entry>(6-31) N- (4'-iodo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide</entry></row><row valign="middle"><entry>22</entry><entry>(1-1) Glyphosate</entry><entry>(6-32) N- (4'-chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4- (difluoromethyl) -1,3-thiazole-5-carboxamide</entry></row><row valign="middle"><entry>23</entry><entry>(1-1) Glyphosate</entry><entry>(6-34) fenhexamide</entry></row><row valign="middle"><entry>24</entry><entry>(1-1) Glyphosate</entry><entry>(6-35) carpropamide</entry></row><row valign="middle"><entry>25</entry><entry>(1-1) Glyphosate</entry><entry>(6-37) Fluopicolide</entry></row><row valign="middle"><entry>26</entry><entry>(1-1) Glyphosate</entry><entry>(6-44) N- {2- [3-chloro-5- (trifluoromethyl) pyridin-2-yl] ethyl} -2- (trifluoromethyl) benzamide</entry></row><row valign="middle"><entry>27</entry><entry>(1-1) Glyphosate</entry><entry>(6-53) 3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid [2- (3,3-dimethylbutyl) phenyl] amide</entry></row><row valign="middle"><entry>28</entry><entry>(1-1) Glyphosate</entry><entry>(7-4) Propineb</entry></row><row valign="middle"><entry>29</entry><entry>(1-1) Glyphosate</entry><entry>(8-4) Metalaxyl-M</entry></row><row valign="middle"><entry>30</entry><entry>(1-1) Glyphosate</entry><entry>(8-5) Benalaxyl-M</entry></row><row valign="middle"><entry>31</entry><entry>(1-1) Glyphosate</entry><entry>(9-3) pyrimethanil</entry></row><row valign="middle"><entry>32</entry><entry>(1-1) Glyphosate</entry><entry>(10-3) carbendazim</entry></row><row valign="middle"><entry>33</entry><entry>(1-1) Glyphosate</entry><entry>(11-4) Propamocarb-fosetyl</entry></row><row valign="middle"><entry>34</entry><entry>(1-1) Glyphosate</entry><entry>(12-4) Iprodione</entry></row><row valign="middle"><entry>35</entry><entry>(1-1) Glyphosate</entry><entry>(14-2) Prochloraz</entry></row><row valign="middle"><entry>36</entry><entry>(1-1) Glyphosate</entry><entry>(14-3) triazoxides</entry></row><row valign="middle"><entry>37</entry><entry>(1-1) Glyphosate</entry><entry>(16-2) Fludioxonil</entry></row><row valign="middle"><entry>38</entry><entry>(1-1) Glyphosate</entry><entry>(19-10) Spiroxamines</entry></row><row valign="middle"><entry>39</entry><entry>(1-1) Glyphosate</entry><entry>(19-22) 2- (4-chlorophenyl) -N- {2- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] ethyl} -2- (prop-2-yn 1-yloxy) acetamide</entry></row><row valign="middle"><entry>40</entry><entry>(1-1) Glyphosate</entry><entry colsep="1">(22-4) 5-chloro-6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine</entry></row><row valign="middle"><entry>41</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(2-2) Fluoxastrobin</entry></row><row valign="middle"><entry>42</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(2-4) trifloxystrobin</entry></row><row valign="middle"><entry>43</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(2-3) (2E) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidynyl] oxy} phenyl) -2- (methoxyimino) -N -methylethanamide</entry></row><row valign="middle"><entry>44</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(3-15) prothioconazole</entry></row><row valign="middle"><entry>45</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(3-17) Tebuconazole</entry></row><row valign="middle"><entry>46</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(3-21) Bitertanol</entry></row><row valign="middle"><entry>47</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(3-22) triadimenol</entry></row><row valign="middle"><entry>48</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(3-24) fluquinconazole</entry></row><row valign="middle"><entry>49</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(4-1) dichlofluanide</entry></row><row valign="middle"><entry>50</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(4-2) Tolylfluanid</entry></row><row valign="middle"><entry>51</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(5-1) Iprovalicarb</entry></row><row valign="middle"><entry>52</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(6-2) N- [2- (1,3-Dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide</entry></row><row valign="middle"><entry>53</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(6-8) 5-fluoro-1,3-dimethyl-N- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide</entry></row><row valign="middle"><entry>54</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(6-13) N- [2- (1,3-dimethylbutyl) phenyl] -2-iodobenzamide</entry></row><row valign="middle"><entry>55</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(6-15) N- [2- (1,3-dimethylbutyl) phenyl] -2- (trifluoromethyl) benzamide</entry></row><row valign="middle"><entry>56</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(6-18) Boscalid</entry></row><row valign="middle"><entry>57</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(6-21) Penthiopyrad</entry></row><row valign="middle"><entry>58</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(6-22) N- [2- (1,3-dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) 1H-pyrrole-3-carboxamide</entry></row><row valign="middle"><entry>59</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(6-23) N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide</entry></row><row valign="middle"><entry>60</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(6-29) N- (4'-bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide</entry></row><row valign="middle"><entry>61</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(6-31) N- (4'-iodo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide</entry></row><row valign="middle"><entry>62</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(6-32) N- (4'-chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4- (difluoromethyl) -1,3-thiazole-5-carboxamide</entry></row><row valign="middle"><entry>63</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(6-34) fenhexamide</entry></row><row valign="middle"><entry>64</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(6-35) carpropamide</entry></row><row valign="middle"><entry>65</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(6-37) Fluopicolide</entry></row><row valign="middle"><entry>66</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(6-44) N- {2- [3-chloro-5- (trifluoromethyl) pyridin-2-yl] ethyl} -2- (trifluoromethyl) benzamide</entry></row><row valign="middle"><entry>67</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(6-53) 3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid [2- (3,3-dimethylbutyl) phenyl] amide</entry></row><row valign="middle"><entry>68</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(7-4) Propineb</entry></row><row valign="middle"><entry>69</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(8-4) Metalaxyl-M</entry></row><row valign="middle"><entry>70</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(8-5) Benalaxyl-M</entry></row><row valign="middle"><entry>71</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(9-3) pyrimethanil</entry></row><row valign="middle"><entry>72</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(10-3) carbendazim</entry></row><row valign="middle"><entry>73</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(11-4) Propamocarb-fosetyl</entry></row><row valign="middle"><entry>74</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(12-4) Iprodione</entry></row><row valign="middle"><entry>75</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(14-2) Prochloraz</entry></row><row valign="middle"><entry>76</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(14-3) triazoxides</entry></row><row valign="middle"><entry>77</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(16-2) Fludioxonil</entry></row><row valign="middle"><entry>78</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(19-10) Spiroxamines</entry></row><row valign="middle"><entry>79</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(19-22) 2- (4-chlorophenyl) -N- {2- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] ethyl} -2- (prop-2-yn 1-yloxy) acetamide</entry></row><row valign="middle"><entry>80</entry><entry>(1-2) Glufosinate</entry><entry colsep="1">(22-4) 5-chloro-6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine</entry></row><row valign="middle"><entry>81</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(2-2) Fluoxastrobin</entry></row><row valign="middle"><entry>82</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(2-4) trifloxystrobin</entry></row><row valign="middle"><entry>83</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(2-3) (2E) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidynyl] oxy} phenyl) -2- (methoxyimino) -N -methylethanamide</entry></row><row valign="middle"><entry>84</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(3-15) prothioconazole</entry></row><row valign="middle"><entry>85</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(3-17) Tebuconazole</entry></row><row valign="middle"><entry>86</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(3-21) Bitertanol</entry></row><row valign="middle"><entry>87</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(3-22) triadimenol</entry></row><row valign="middle"><entry>88</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(3-24) fluquinconazole</entry></row><row valign="middle"><entry>89</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(4-1) dichlofluanide</entry></row><row valign="middle"><entry>90</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(4-2) Tolylfluanid</entry></row><row valign="middle"><entry>91</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(5-1) Iprovalicarb</entry></row><row valign="middle"><entry>92</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(6-2) N- [2- (1,3-Dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide</entry></row><row valign="middle"><entry>93</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(6-8) 5-fluoro-1,3-dimethyl-N- [2- (1,3,3-trimethylbutyl) phenyl] -1H-pyrazole-4-carboxamide</entry></row><row valign="middle"><entry>94</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(6-13) N- [2- (1,3-dimethylbutyl) phenyl] -2-iodobenzamide</entry></row><row valign="middle"><entry>95</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(6-15) N- [2- (1,3-dimethylbutyl) phenyl] -2- (trifluoromethyl) benzamide</entry></row><row valign="middle"><entry>96</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(6-18) Boscalid</entry></row><row valign="middle"><entry>97</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(6-21) Penthiopyrad</entry></row><row valign="middle"><entry>98</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(6-22) N- [2- (1,3-dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1H-pyrrole-3-carboxamide</entry></row><row valign="middle"><entry>99</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(6-23) N- (3 ', 4'-dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide</entry></row><row valign="middle"><entry>100</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(6-29) N- (4'-bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide</entry></row><row valign="middle"><entry>101</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(6-31) N- (4'-iodo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide</entry></row><row valign="middle"><entry>102</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(6-32) N- (4'-chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4- (difluoromethyl) -1,3-thiazole-5-carboxamide</entry></row><row valign="middle"><entry>103</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(6-34) fenhexamide</entry></row><row valign="middle"><entry>104</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(6-35) carpropamide</entry></row><row valign="middle"><entry>105</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(6-37) Fluopicolide</entry></row><row valign="middle"><entry>106</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(6-44) N- {2- [3-chloro-5- (trifluoromethyl) pyridin-2-yl] ethyl} -2- (trifluoromethyl) benzamide</entry></row><row valign="middle"><entry>107</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(6-53) 3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid [2- (3,3-dimethylbutyl) phenyl] amide</entry></row><row valign="middle"><entry>108</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(7-4) Propineb</entry></row><row valign="middle"><entry>109</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(8-4) Metalaxyl-M</entry></row><row valign="middle"><entry>110</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(8-5) Benalaxyl-M</entry></row><row valign="middle"><entry>111</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(9-3) pyrimethanil</entry></row><row valign="middle"><entry>112</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(10-3) carbendazim</entry></row><row valign="middle"><entry>113</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(11-4) Propamocarb-fosetyl</entry></row><row valign="middle"><entry>114</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(12-4) Iprodione</entry></row><row valign="middle"><entry>115</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(14-2) Prochloraz</entry></row><row valign="middle"><entry>116</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(14-3) triazoxides</entry></row><row valign="middle"><entry>117</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(16-2) Fludioxonil</entry></row><row valign="middle"><entry>118</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(19-10) Spiroxamines</entry></row><row valign="middle"><entry>119</entry><entry>(1-3) Glufosinate ammonium</entry><entry colsep="1">(19-22) 2- (4-chlorophenyl) -N- {2- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] ethyl} -2- (prop-2-yn 1-yloxy) acetamide</entry></row><row valign="middle"><entry>120</entry><entry>(1-3) Glufosinate ammonium</entry><entry>(22-4) 5-chloro-6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine</entry></row></tbody></tgroup></table></tables>To combat rust diseases on soybean plants, mixtures with the following numbers are particularly preferred: 1-2, 4-10, 12-22, 28, 31-32, 34-35, 37-38, 40-42, 44-50, 52-62, 68, 71-72, 74-75, 77-78, 80-82, 84-90, 92-102, 108, 111-112, 114-115, 117-118 and 120.
0209In addition to an active ingredient of group (1), the active compound combinations according to the invention contain at least one active ingredient from the compounds of groups (2) to (23). They can also contain other fungicidally active admixing components.
0210For example, each of the active substance combinations listed in Table 1 can contain a third active substance, which is selected from the following list:<ul id="ul0005" list-style="none" compact="compact"><li>(2-1) azoxystrobin, (2-2) fluoxastrobin, (2-3) (2<i>E</i>) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl] oxy} phenyl) -2- (methoxyimino) -<i>N</i>-methylethanamide, (2-4) trifloxystrobin, (2-5) (2<i>E</i>) -2- (methoxyimino) -<i>N</i>-methyl-2- (2 - {[({(1<i>E</i>) -1- [3- (trifluoromethyl) phenyl] ethylidenlamino) oxy] methyl} phenyl) ethanamide, (2-6) (2nd<i>E</i>) -2- (methoxyimino) -<i>N</i>-methyl-2- {2 - [(<i>E</i>) - ({1- [3- (trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} ethanamide, (2-7) orysastrobin, (2-8) 5-methoxy-2-methyl-4- (2- {[({(1<i>E</i>) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) -2,4-dihydro-3<i>H</i>-1,2,4-triazol-3-one, (2-9) kresoxim-methyl, (2-10) dimoxystrobin, (2-11) picoxystrobin, (2-12) pyraclostrobin, (2-13) metominostrobin, (2-14) (2E) -2- {2 - [({[(1E) -1- (3 - {[(E) -1-fluoro-2-phenylvinyl] oxy} phenyl) ethylidene] amino} oxy ) methyl] phenyl} -2- (methoxyimino) -N-methylacetamide, (2-15) enestroburin, (3-1) azaconazole, (3-2) etaconazole, (3-3) propiconazole, (3-4) difenoconazole , (3-5) bromuconazole, (3-6) cyproconazole, (3-7) hexaconazole, (3-8) penconazole, (3-9) myclobutanil, (3-10) tetraconazole, (3-11) flutriafol, (3-12) epoxiconazole, (3-13) flusilazole, (3-14) simeconazole, (3-15) prothioconazole, (3-16) fenbuconazole, ( 3-17) Tebuconazole, (3-18) Ipconazole, (3-19) Metconazole, (3-20) Triticonazole, (3-21) Bitertanol, (3-22) Triadimenol, (3-23) Triadimefon, (3rd -24) fluquinconazole, (3-25) quinconazole, (3-26) amisulbromo, (4-1) dichlofluanid, (4-2) tolylfluanid, (4-3) N- (4-chloro-2-nitrophenyl) N -ethyl-4-methyl-benzenesulfonamide, (5-1) iprovalicarb, (5-2) <i>N</i><sup>1</sup>- [2- (4 - {[3- (4-chlorophenyl) -2-propynyl] oxy} -3-methoxyphenyl) ethyl] -<i>N</i><sup>2</sup>- (methylsulfonyl) -D-valinamide, (5-3) benthiavalicarb, (6-1) N- [2- (1,3-dimethylbutyl) phenyl] -1,3-dimethyl-1<i>H</i>-pyrazole-4-carboxamide, (6-2) <i>N</i>- [2- (1,3-Dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1<i>H</i>-pyrazole-4-carboxamide, (6-3) <i>N</i>- [2- (1,3-Dimethylbutyl) phenyl] -5-chloro-1,3-dimethyl-1<i>H</i>-pyrazole-4-carboxamide, (6-4) 3- (difluoromethyl) -<i>N</i>- [2- (1,3-dimethylbutyl) phenyl] -1-methyl-1<i>H</i>-pyrazole-4-carboxamide, (6-5) 3- (trifluoromethyl) -<i>N</i>- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1-methyl-1<i>H</i>-pyrazole-4-carboxamide, (6-6) 3- (trifluoromethyl) -<i>N</i>- [2- (1,3-dimethylbutyl) phenyl] -5-chloro-1-methyl-1<i>H</i>-pyrazole-4-carboxamide, (6-7) 1,3-dimethyl-<i>N</i>- [2- (1,3,3-trimethylbutyl) phenyl] -1<i>H</i>-pyrazole-4-carboxamide, (6-8) 5-fluoro-1,3-dimethyl-<i>N</i>- [2- (1,3,3-trimethylbutyl) phenyl] -1<i>H</i>-pyrazole-4-carboxanüd, (6-9) 3- (difluoromethyl) -1-methyl-<i>N</i>- [2- (1,3,3-trimethylbutyl) phenyl] -1<i>H</i>-pyrazole-4-carboxamide, (6-10) 3- (trifluoromethyl) -1-methyl-<i>N</i>- [2- (1,3,3-trimethylbutyl) phenyl] -1<i>H</i>-pyrazole-4-carboxamide, (6-11) 3- (trifluoromethyl) -5-fluoro-1-methyl-<i>N</i>- [2- (1,3,3-trimethylbutyl) phenyl] -1<i>H</i>-pyrazole-4-carboxamide, (6-12) 3- (trifluoromethyl) -5-chloro-1-methyl-<i>N</i>- [2- (1,3,3-trimethylbutyl) phenyl] -1<i>H</i>-pyrazole-4-carboxamide, (6-13) <i>N</i>- [2- (1,3-dimethylbutyl) phenyl] -2-iodobenzamide, (6-14) 2-iodine<i>N-</i>[2- (1,3,3-trimethylbutyl) phenyl] benzamide, (6-15) <i>N</i>- [2- (1,3-dimethylbutyl) phenyl] -2- (trifluoromethyl) benzamide, (6-16) 2- (trifluoromethyl) -<i>N</i>- [2- (1,3,3-trimethylbutyl) phenyl] benzamide, (6-17) 2-chloro-N- (1,1,3-trimethyl-indan-4-yl) nicotinamide, (6-18 ) Boscalid, (6-19) furametpyr, (6-20) 1-methyl-3-trifluoromethyl-1H-pyrazol-4-carboxylic acid- (3-p-tolylthiophene-2-yl) -amide, (6- 21) Penthiopyrad, (6-22) <i>N</i>- [2- (1,3-Dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1<i>H</i>-pyrrole-3-carboxamide, (6-23) <i>N</i>- (3 ', 4'-Dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1<i>H</i>-pyrazole-4-carboxamide, (6-24) 3- (difluoromethyl) -<i>N</i>- {3'-fluoro-4 '- [(<i>E</i>) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1<i>H</i>-pyrazole-4-carboxamide, (6-25) 3- (trifluoromethyl) -<i>N</i>- {3'-fluoro-4 '- [(<i>E</i>) - (methoxyimino) methyl] -1,1'-biphenyl-2-yl} -1-methyl-1<i>H</i>-pyrazole-4-carboxamide, (6-26) <i>N</i>- (3 ', 4'-Dichloro-1,1'-biphenyl-2-yl) -5-fluoro-1,3-dimethyl-1<i>H</i>-pyrazole-4-carboxamide, (6-27) <i>N</i>- (4'-chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4- (trifluoromethyl) -1,3-thiazole-5-carboxamide, (6-28) <i>N</i>- (4'-Chloro-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide, (6-29) <i>N</i>- (4'-Bromo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide, (6-30) 4- (difluoromethyl) - 2-methyl<i>N</i>- [4 '- (trifluoromethyl) -1,1'-biphenyl-2-yl] -1,3-thiazole-5-carboxamide, (6-31) <i>N</i>- (4'-iodo-1,1'-biphenyl-2-yl) -4- (difluoromethyl) -2-methyl-1,3-thiazole-5-carboxamide, (6-32) <i>N</i>- (4'-Chloro-3'-fluoro-1,1'-biphenyl-2-yl) -2-methyl-4- (difluoromethyl) -1,3-thiazole-5-carboxamide, (6-33) ethaboxam , (6-34) fenhexamide, (6-35) carpropamide, (6-36) 2-chloro-4- (2-fluoro-2-methyl-propionylamino) -N, N-dimethyl-benzamide, (6-37 ) Fluopicolide, (6-38) zoxamides, (6-39) 3,4-dichloro-N- (2-cyanophenyl) isothiazole-5-carboxamide, (6-40) carboxin, (6-41) tiadinil, (6 -42) silthiofam, (6-43) <i>N</i>- [2- (1,3-Dimethylbutyl) phenyl] -1-methyl-4- (trifluoromethyl) -1<i>H</i>-pyrrole-3-carboxamide, (6-44) <i>N</i>- {2- [3-chloro-5- (trifluoromethyl) pyridin-2-yl] ethyl} -2- (trifluoromethyl) benzamide, (6-45) 1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxylic acid - (2-bicyclopropyl-2-yl-phenyl) -amide, (6-46) 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxylic acid- (2-bicyclopropyl-2-yl-phenyl) -amide, (6-47) 1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxylic acid- [2- (1'-methyl-bicyclopropyl-2-yl) phenyl] amide, (6-48) 1-methyl -3-difluoromethyl-1H-pyrazole-4-carboxylic acid- [2- (1'-methyl-bicyclopropyl-2-yl) phenyl] amide, (6-49) N- [1- (5-bromo-3-chloropyridin-2-yl) ethyl] -2,4-dichloronicotinamide, (6-50) N- (5-bromo-3-chloropyridin-2- yl) methyl-2,4-dichlomicotinanüd, (6-51) <i>N</i>- (3 ', 4'-Dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1<i>H</i>-pyrazole-4-carboxamide, (6-52) <i>N</i>- (3 ', 4'-Dichloro-5-fluoro-1,1'-biphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1<i>H</i>-pyrazole-4-carboxamide, (6-53) 3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid [2- (3,3-dimethylbutyl) phenyl] amide, (7-1) Mancozeb, (7-2) Maneb, (7-3) Metiram, (7-4) Propineb, (7-5) Thiram, (7-6) Zineb, (7-7) Ziram, (8-1) Benalaxyl , (8-2) furalaxyl, (8-3) metalaxyl, (8-4) metalaxyl-M, (8-5) benalaxyl-M, (9-1) cyprodinil, (9-2) mepanipyrim, (9- 3) pyrimethanil, (10-1) 6-chloro-5 - [(3,5-dimethylisoxazol-4-yl) sulfonyl] -2,2-difluoro-5H- [1,3] dioxolo [4,5-f ] benzimidazole, (10-2) benomyl, (10-3) carbendazim, (10-4) chlorfenazole, (10-5) fuberidazole, (10-6) thiabendazole, (11-1) diethofen carb, (11-2) propamocarb, (11-3) propamocarb hydrochloride , (11-4) Propamocarb-Fosetyl, (12-1) Captafol, (12-2) Captan, (12-3) Folpet, (12-4) Iprodione, (12-5) Procymidone, (12-6) Vinclozolin, (13-1) dodine, (13-2) guazatine, (13-3) iminoctadine triacetate, (13-4) iminoctadine tris (albesilate), (14-1) cyazofamide, (14-2) prochloraz, ( 14-3) triazoxides, (14-4) pefurazoates, (15-1) aldimorph, (15-2) tridemorph, (15-3) dodemorph, (15-4) fenpropimorph, (15-5) dimethomorph, (15-6) flumorph, (16-1) fenpiclonil, (16-2) fludioxonil, ( 16-3) pyrrole nitrines, (17-1) fosetyl-Al, (17-2) phosphonic acid, (18-1) 2- (2,3-dihydro-1H-inden-5-yl) -N- [2 - (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide, (18-2) N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) -2- (5.6 , 7,8-tetrahydronaphthalene-2-yl) acetamide, (18-3) 2- (4-chlorophenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide, (18-4) 2- (4-bromophenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide, (18-5) 2- (4-methylphenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide, (18-6) 2- (4-ethylphenyl) -N- [2- (3,4-dimethoxyphenyl) ethyl] -2- (methoxyimino) acetamide, (19-1) acibenzolar-S-methyl, (19-2) chlorothalonil, (19-3) cymoxanil, (19-4) edifenphos, (19-5) famoxadone, (19-6) fluazinam , (19-7) copper oxychloride, (19-9) oxadixyl, (19-10) spiroxamine, (19-11) dithianon, (19-12) metrafenone, (19-13) fenamidone, (19-14) 2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidin-4 (3H) one, (19-15) probenazole, (19-16) isoprothiolane, (19-17) Kasugamycin, (19-18) Phthalide, (19-19) Ferimzone, (19-20) Tricyclazole, (19-21) N - ({4 - [(Cyclopropylamino) carbonyl] phenyl} sulfonyl) -2-methoxybenzamide, ( 19-22) 2- (4-Chlorophenyl) -N- {2- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] ethyl} -2- (prop-2-yn-1) -yloxy) acetamide, (19-23) proquinazide, (19-24) quinoxyfen, (19-25) cyflufenamid, (19-26) pyribencarb, (19-27) 3- [5- (4-chlorophenyl) -2,3-dimethyl-3-isoxazolidinyl] pyridine (20-1) pencycuron, (20-2) thiophanate-methyl, (20-3) thiophanate -ethyl, (21-1) fenoxanil, (21-2) diclocymet, (22-1) 5-chloro<i>N</i>-[<i>(1S)</i>-2,2,2-trifluoro-1-methylethyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidin-7-amine, (22-2 ) 5-chlorine<i>N</i>-[<i>(1R)</i>-1,2-dimethylpropyl] -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidin-7-amine, (22-3) 5-chloro-6 - (2-chloro-6-fluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine, (22-4) 5-chloro-6- (2,4,6-trifluorophenyl) -7- (4-methylpiperidin-1-yl) [1,2,4] triazolo [1,5-a] pyrimidine, (23-1) 2-butoxy-6-iodine -3-propyl-benzopyran-4-one, (23-2) 2-ethoxy-6-iodo-3-propyl-benzopyran-4-one, (23-3) 6-iodo-2-propoxy-3-propyl -benzopyran-4-one, (23-4) 2-but-2-ynyloxy-6-iodo-3-propyl-benzopyran-4-one, (23-5) 6-iodo-2- (1-methyl-butoxy) -3-propyl-benzopyran-4-one, (23-6) 2-but-3-enyloxy-6-iodo-benzopyran-4- on, (23-7) 3-butyl-6-iodo-2-isopropoxy-benzopyran-4-one.</li></ul>
0211If the active ingredients are present in the active ingredient combinations according to the invention in certain weight ratios, the synergistic effect is particularly evident. However, the weight ratios of the active ingredients in the active ingredient combinations can be varied within a relatively wide range. In general, the combinations according to the invention contain active compounds of the formula (I) and a mixing partner from one of groups (2) to (23) in the mixing ratios given by way of example in Table 2 below.
0212The mixing ratios are based on weight ratios. The ratio is to be understood as active ingredient of group (1): mixed partner.<tables id="tabl0002" num="0002"><table frame="all"><title>Table 2: Mixing ratios</title><tgroup cols="4"><colspec colnum="1" colname="col1" colwidth="24mm" /><colspec colnum="2" colname="col2" colwidth="116mm" /><colspec colnum="3" colname="col3" colwidth="51mm" /><colspec colnum="4" colname="col4" colwidth="51mm" /><thead><row><entry namest="col1" nameend="col2" align="left" valign="top">Mixed partner</entry><entry valign="top">preferred Mixing ratio</entry><entry valign="top">particularly preferred Mixing ratio</entry></row></thead><tbody><row><entry colsep="0">Group (2):</entry><entry>Strobilurins</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">Group (3):</entry><entry>Triazoles</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">Group (4):</entry><entry>Sulfenamides / sulfonamides</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 10 to 1: 0.1</entry></row><row><entry colsep="0">Group (5):</entry><entry>Valinamide</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">Group (6):</entry><entry>Carboxamides</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">Group (7):</entry><entry>Dithiocarbamate</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 25 to 1: 0.2</entry></row><row><entry colsep="0">Group (8):</entry><entry>Acylalanine</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 12 to 1: 0.02</entry></row><row><entry colsep="0">Group (9):</entry><entry>Anilino-pyrimidines</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 10 to 1: 0.05</entry></row><row><entry colsep="0">Group (10):</entry><entry>Benzimidazoles</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">Group (11):</entry><entry>Carbamate without (11-1)</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 100 to 1: 0.2</entry></row><row><entry colsep="0">(11-1):</entry><entry>Diethofencarb</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">Group (12):</entry><entry>(12-1)/(12-2)/(12-3)</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 25 to 1: 0.2</entry></row><row><entry colsep="0">Group (12):</entry><entry>(12-4)/(12-5)/(12-6)</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 10 to 1: 0.05</entry></row><row><entry colsep="0">Group (13):</entry><entry>Guanidines</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 10 to 1: 0.01</entry></row><row><entry colsep="0">Group (14):</entry><entry>Imidazole</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">Group (15):</entry><entry>Morpholines</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">Group (16):</entry><entry>Pyrroles</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">Group (17):</entry><entry>Phosphonates</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 25 to 1: 0.2</entry></row><row><entry colsep="0">Group (18):</entry><entry>Phenylethanamide</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">(19-1):</entry><entry>Acibenzolar-S-methyl</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">(19-2):</entry><entry>Chlorothalonil</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 25 to 1: 0.2</entry></row><row><entry colsep="0">(19-3):</entry><entry>Cymoxanil</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">(19-4):</entry><entry>Edifenphos</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">(19-5):</entry><entry>Famoxadone</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">(19-6):</entry><entry>Fluazinam</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">(19-7):</entry><entry>Copper oxychloride</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 100 to 1: 0.2</entry></row><row><entry colsep="0">(19-8):</entry><entry>Copper hydroxide</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 100 to 1: 0.2</entry></row><row><entry colsep="0">(19-9):</entry><entry>Oxadixyl</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 12 to 1: 0.02</entry></row><row><entry colsep="0">(19-10):</entry><entry>Spiroxamine</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">(19-11)</entry><entry>Dithianon</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">(19-12)</entry><entry>Metrafenone</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">(19-13)</entry><entry>Fenamidone</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">(19-14):</entry><entry>2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidin-4 (3H) one</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">(19-15):</entry><entry>Probenazole</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 100 to 1: 0.2</entry></row><row><entry colsep="0">(19-16):</entry><entry>Isoprothiolane</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 100 to 1: 0.2</entry></row><row><entry colsep="0">(19-17):</entry><entry>Kasugamycin</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">(19-18):</entry><entry>Phthalides</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 100 to 1: 0.2</entry></row><row><entry colsep="0">(19-19):</entry><entry>Ferimzone</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">(19-20):</entry><entry>Tricyclazole</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">(19-21):</entry><entry>N - ({4 - [(Cyclopropylamino) carbonyl] phenyl} sulfonyl) -2-methoxybenzamide</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 100 to 1: 0.2</entry></row><row><entry colsep="0">(19-22):</entry><entry>2- (4-chlorophenyl) -N- {2- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] ethyl} -2- (prop-2-yn-1-yloxy) acetamide</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">(19-23):</entry><entry>Proquinazide</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">(19-24):</entry><entry>Quinoxyfen</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">(19-25)</entry><entry>Cyflufenamid</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 100 to 1: 0.2</entry></row><row><entry colsep="0">(19-26)</entry><entry>Pyribencarb</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 100 to 1: 0.2</entry></row><row><entry colsep="0">(19-27)</entry><entry>3- [5- (4-chlorophenyl) -2,3-dimethyl-3-isoxazolidinyl] pyridine</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 100 to 1: 0.2</entry></row><row><entry colsep="0">Group (20):</entry><entry>(Thio) urea derivatives</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">Group (21):</entry><entry>Amides</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">Group (22):</entry><entry>Triazolopyrimidines</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row><row><entry colsep="0">Group (23):</entry><entry>Iodochromones</entry><entry>1 : 100 to 1: 0.01</entry><entry>1 : 5 to 1: 0.01</entry></row></tbody></tgroup></table></tables>
0213In any case, the mixing ratio should be selected so that a synergistic mixture is obtained. The mixing ratios between the compound of formula (I) and a compound from one of groups (2) to (23) can also vary between the individual compounds of a group.
0214The active compound combinations according to the invention have very good fungicidal properties and can be used to control phytopathogenic fungi, such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes, etc.
0215Some pathogens of fungal and bacterial diseases that fall under the generic names listed above may be mentioned as examples, but not by way of limitation:<ul id="ul0006" list-style="none" compact="compact"><li>Diseases caused by powdery mildew pathogens such as</li><li>Blumeria species, such as, for example, Blumeria graminis;</li><li>Podosphaera species, such as, for example, Podosphaera leucotricha;</li><li>Sphaerotheca species, such as, for example, Sphaerotheca fuliginea;</li><li>Uncinula species, such as, for example, Uncinula necator;</li><li>Diseases caused by rust pathogens such as</li><li>Gymnosporangium species, such as, for example, Gymnosporangium sabinae</li><li>Hemileia species, such as, for example, Hemileia vastatrix;</li><li>Phakopsora species, such as, for example, Phakopsora pachyrhizi and Phakopsora meibomiae;</li><li>Puccinia species, such as, for example, Puccinia recondita;</li><li>Uromyces species, such as, for example, Uromyces appendiculatus;</li><li>Diseases caused by pathogens from the Oomycetes group, such as, for example, Bremia species, such as, for example, Bremia lactucae;</li><li>Peronospora species, such as, for example, Peronospora pisi or P. brassicae; Phytophthora species, such as, for example, Phytophthora infestans; Plasmopara species, such as, for example, Plasmopara viticola; Pseudoperonospora species, such as, for example, Pseudoperonospora humuli or Pseudoperonospora cubensis;</li><li>Pythium species, such as, for example, Pythium ultimum;</li><li>Leaf blotch diseases and leaf wilting, caused by e.g. Alternaria species, such as, for example, Alternaria solani; Cercospora species, such as, for example, Cercospora beticola; Cladiosporum species, such as, for example, Cladiosporium cucumerinum; Cochliobolus species, such as, for example, Cochliobolus sativus (conidial form: Drechslera, Syn: Helminthosporium); Colletotrichum species, such as, for example, Colletotrichum lindemuthanium; Cycloconium species, such as, for example, Cycloconium oleaginum; Diaporthe species, such as, for example, Diaporthe citri;</li><li>Elsinoe species, such as, for example, Elsinoe fawcettii; Gloeosporium species, such as, for example, Gloeosporium laeticolor; Glomerella species, such as, for example, Glomerella cingulata; Guignardia species, such as, for example, Guignardia bidwelli; Leptosphaeria species, such as, for example, Leptosphaeria maculans; Magnaporthe species, such as, for example, Magnaporthe grisea; Mycosphaerella species, such as, for example, Mycosphaerelle graminicola; Phaeosphaeria species, such as, for example, Phaeosphaeria nodorum; Pyrenophora species, such as, for example, Pyrenophora teres; Ramularia species, such as, for example, Ramularia collo-cygni; Rhynchosporium species, such as, for example, Rhynchosporium secalis; Septoria species, such as, for example, Septoria apii;</li><li>Typhula species, such as, for example, Typhula incarnata;</li><li>Venturia species, such as, for example, Venturia inaequalis;</li><li>Root and stem diseases caused, for example, by Corticium species, such as, for example, Corticium graminearum;</li><li>Fusarium species, such as, for example, Fusarium oxysporum;</li><li>Gaeumannomyces species, such as, for example, Gaeumannomyces graminis;</li><li>Rhizoctonia species, such as, for example, Rhizoctonia solani;</li><li>Tapesia species, such as, for example, Tapesia acuformis;</li><li>Thielaviopsis species, such as, for example, Thielaviopsis basicola;</li><li>Ear and panicle diseases (including maize cobs) caused by, for example, Alternaria species, such as, for example, Alternaria spp .;</li><li>Aspergillus species, such as, for example, Aspergillus flavus;</li><li>Cladosporium species, such as, for example, Cladosporium spp .;</li><li>Claviceps species, such as, for example, Claviceps purpurea;</li><li>Fusarium species, such as, for example, Fusarium culmorum;</li><li>Gibberella species, such as, for example, Gibberella zeae;</li><li>Monographella species, such as, for example, Monographella nivalis;</li><li>Diseases caused by smut such as</li><li>Sphacelotheca species, such as, for example, Sphacelotheca reiliana;</li><li>Tilletia species, such as, for example, Tilletia caries;</li><li>Urocystis species, such as, for example, Urocystis occulta;</li><li>Ustilago species, such as, for example, Ustilago nuda;</li><li>Fruit rot caused by e.g.</li><li>Aspergillus species, such as, for example, Aspergillus flavus;</li><li>Botrytis species, such as, for example, Botrytis cinerea;</li><li>Penicillium species, such as, for example, Penicillium expansum;</li><li>Sclerotinia species, such as, for example, Sclerotinia sclerotiorum;</li><li>Verticilium species, such as, for example, Verticilium alboatrum;</li><li>Seed and soil-borne rot and wilt, as well as seedling diseases caused by, for example, Fusarium species, such as, for example, Fusarium culmorum;</li><li>Phytophthora species, such as, for example, Phytophthora cactorum;</li><li>Pythium species, such as, for example, Pythium ultimum;</li><li>Rhizoctonia species, such as, for example, Rhizoctonia solani;</li><li>Sclerotium species, such as, for example, Sclerotium rolfsii;</li><li>Cancers, galls and witches' broom caused by eg</li><li>Nectria species, such as, for example, Nectria galligena;</li><li>Wilting diseases caused by e.g.</li><li>Monilinia species, such as, for example, Monilinia laxa;</li><li>Deformations of leaves, flowers and fruits caused by e.g.</li><li>Taphrina species, such as, for example, Taphrina deformans;</li><li>Degenerative diseases of woody plants, caused by e.g.</li><li>Esca species, such as, for example, Phaemoniella clamydospora;</li><li>Flower and seed diseases caused by e.g.</li><li>Botrytis species, such as, for example, Botrytis cinerea;</li><li>Diseases of plant tubers caused by e.g.</li><li>Rhizoctonia species, such as, for example, Rhizoctonia solani;</li><li>Diseases caused by bacterial pathogens such as</li><li>Xanthomonas species, such as, for example, Xanthomonas campestris pv. Oryzae;</li><li>Pseudomonas species, such as, for example, Pseudomonas syringae pv. Lachrymans;</li><li>Erwinia species, such as, for example, Erwinia amylovora;</li></ul>
0216The following diseases of soybeans can preferably be combated:<ul id="ul0007" list-style="none" compact="compact"><li>Fungal diseases on leaves, stems, pods and seeds caused by e.g. Alternaria leaf spot (Alternaria spec. Atrans tenuissima), Anthracnose (Colletotrichum gloeosporoides dematium var. truncatum), Brown spot (Septoria glycines), Cercospora leaf spot and blight (Cercospora kikuchii), Choanephora leaf blight (Choanephora infundibulifera trispora (Syn.)), Dactuliophora leaf spot (Dactuliophora glycines), Downy Mildew, Perrechosuraica (Drechslera glycini), Frogeye Leaf spot (Cercospora sojina), Leptosphaerulina Leaf Spot (Leptosphaerulina trifolii), Phyllostica Leaf Spot (Phyllosticta sojaecola), Powdery Mildew (Microsphaera diffusa), Pyrenochaeta Leaf Spot (Pyrenochaeta glycines), Rhizoctonia Aerial, Foliage, and Web Blight (Rhizoctonia solani), Rust (Phakopsora pachyrhizi), Scab (Sphaceloma glycines), Stemphylium Leaf Blight (Stemphylium botryosum), Target Spot (Coryolapora)</li></ul>
0217Fungal diseases on roots and the stem base caused by e.g. Black Root Red (Calonectria crotalariae), Charcoal Red (Macrophomina phaseolina), Fusarium Blight or Wilt, Root Rot, and Pod and Collar Red (Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equis , Mycoleptodiscus Root Rot (Mycoleptodiscus terrestris), Neocosmospora (Neocosmopspora vasinfecta), Pod and Stem Blight (Diaporthe phaseolorum), Stem Canker (Diaporthe phaseolorum var. caulivora), Phytophthora Rot (Phytophthora megasperma), Brown Stem Rot (Phialophora gregata), Pythium Rot (Pythium aphanidermatum, Pythium irregulare, Pythium debaryanum, Pythium myriotylum, Pythium ultimum), Rhizoctonia Root Red, Damping Decay solani), Sclerotinia Stem Decay (Sclerotinia sclerotiorum), Sclerotinia Southern Blight (Sclerotinia rolfsii), Thielaviopsis Root Rot (Thielaviopsis basicola).
0218The active compound combinations according to the invention are particularly suitable for combating diseases which are caused by rust pathogens such as, for example, Phakopsora species, such as, for example, Phakopsora pachyrhizi and Phakopsora meibomiae.
0219The following diseases of soybeans can preferably be combated:<ul id="ul0008" list-style="none" compact="compact"><li>Fungal diseases on leaves, stems, pods and seeds caused by rust (Phakopsora pachyrhizi and Phakopsora meibomiae). The control of Phakopsora pachyrhizi is particularly preferred.</li></ul>
0220The fact that the active ingredient combinations are well tolerated by plants in the concentrations required to combat plant diseases permits the treatment of entire plants (above-ground parts of plants and roots), of propagation stock and seeds, and of the soil. The active compound combinations according to the invention can be used for leaf application or as a mordant.
0221A large part of the damage to crop plants caused by phytopathogenic fungi already arises from the infestation of the seed during storage and after the seed has been introduced into the soil and during and immediately after the plants have germinated. This phase is particularly critical since the roots and shoots of the growing plant are particularly sensitive and even a little damage can lead to the death of the whole plant. There is therefore particularly great interest in protecting the seeds and the germinating plant by using suitable means.
0222Phytopathogenic fungi that damage plants after emergence are primarily combated by treating the soil and the parts of the plants above ground with pesticides. Due to concerns about the potential impact of pesticides on the environment and human and animal health, efforts are being made to reduce the amount of active ingredients applied.
0223The control of phytopathogenic fungi by treating the seeds of plants has been known for a long time and is the subject of constant improvements. Nevertheless, there are a number of problems with the treatment of seeds that cannot always be solved satisfactorily. It is therefore desirable to develop methods for protecting the seed and the germinating plant which make the additional application of crop protection agents after sowing or after emergence of the plants superfluous or at least significantly reduce them. It is furthermore desirable to optimize the amount of the active ingredient used so that the seed and the germinating plant are optimally protected from attack by phytopathogenic fungi without, however, damaging the plant itself through the active ingredient used. In particular, seed treatment processes should also take into account the intrinsic fungicidal properties of transgenic plants in order to achieve optimum protection of the seed and the germinating plant with a minimal expenditure on crop protection agents.
0224The present invention therefore also relates in particular to a method for protecting seed and germinating plants from attack by phytopathogenic fungi by treating the seed with an agent according to the invention.
0225The invention also relates to the use of the agents according to the invention for the treatment of seeds to protect the seeds and the germinating plant from phytopathogenic fungi.
0226Furthermore, the invention relates to seeds which have been treated with an agent according to the invention for protection against phytopathogenic fungi.
0227One of the advantages of the present invention is that, because of the special systemic properties of the agents according to the invention, the treatment of the seeds with these agents not only protects the seeds themselves, but also the plants resulting therefrom from phytopathogenic fungi after emergence. In this way, the immediate treatment of the crop at the time of sowing or shortly thereafter can be omitted.
0228It is also to be regarded as advantageous that the mixtures according to the invention can also be used in particular with transgenic seeds.
0229The compositions according to the invention are suitable for protecting seeds of any plant type which is used in agriculture, in the greenhouse, in forests or in horticulture. In particular, these are seeds of cereals (such as wheat, barley, rye, millet and oats), corn, cotton, soybeans, rice, potatoes, sunflower, beans, coffee, beets (e.g. sugar beet and fodder beet), peanuts, vegetables ( such as tomato, cucumber, onions and lettuce), lawn and ornamental plants. The treatment of the seeds of cereals (such as wheat, barley, rye and oats), corn and rice is of particular importance. The treatment of soybean seeds is also of particular importance.
0230In the context of the present invention, the agent according to the invention is applied to the seed alone or in a suitable formulation. The seed is preferably treated in a state in which it is so stable that no damage occurs during the treatment. In general, the seed can be treated at any time between harvesting and sowing. Usually, seeds are used that have been separated from the plant and freed of pistons, shells, stems, husk, wool or pulp. For example, seeds can be used that have been harvested, cleaned and dried to a moisture content of less than 15% by weight. Alternatively, seeds can be used that have been treated with water after drying, for example, and then dried again.
0231In general, when treating the seed, care must be taken that the amount of the agent and / or other additives according to the invention applied to the seed is selected so that the germination of the seed is not impaired or the plant resulting therefrom is not damaged. This is particularly important for active substances that can show phytotoxic effects at certain application rates.
0232The agents according to the invention can be applied directly, that is to say without containing further components and without having been diluted. As a rule, it is preferable to apply the agents to the seeds in the form of a suitable formulation. Suitable formulations and processes for seed treatment are known to the person skilled in the art and are described, for example, in the following documents:<patcit id="pcit0013" dnum="US4272417A"><text>US 4,272,417 A</text></patcit>, <patcit id="pcit0014" dnum="US4245432A"><text>US 4,245,432 A</text></patcit>, <patcit id="pcit0015" dnum="US4808430A"><text>US 4,808,430 A</text></patcit>, <patcit id="pcit0016" dnum="US5876739A"><text>US 5,876,739 A</text></patcit>, <patcit id="pcit0017" dnum="US20030176428A1"><text>US 2003/0176428 A1</text></patcit>, <patcit id="pcit0018" dnum="WO2002080675A1"><text>WO 2002/080675 A1</text></patcit>, <patcit id="pcit0019" dnum="WO2002028186A2"><text>WO 2002/028186 A2</text></patcit>.
0233The active compound combinations according to the invention are also suitable for increasing the crop yield. They are also less toxic and have good plant tolerance.
0234According to the invention, all plants and parts of plants can be treated. Plants are understood here to mean all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants). Cultivated plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant cultivars which can or cannot be protected by plant breeders' rights. Plant parts are to be understood to mean all above-ground and underground parts and organs of the plants, such as shoots, leaves, flowers and roots, examples being leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds as well as roots, tubers and rhizomes. The plant parts also include crops and vegetative and generative propagation material, for example cuttings, tubers, rhizomes, offshoots and seeds.
0235The treatment of plants and parts of plants (including seeds) according to the invention with the active compound combinations is carried out directly or by acting on their surroundings, living space or storage space according to the customary treatment methods, for example by dipping, spraying, evaporating, atomizing, scattering, spreading and in the case of propagation material, in particular in the case of seeds, still by single or multi-layer coating. The active ingredient combinations can be prepared before the treatment by mixing the individual active ingredients and are therefore used in a mixture. Or the treatment is carried out successively by first using a herbicide from group (1), followed by treatment with an active ingredient from groups (2) to (23). However, it is also possible to treat the plants or parts of plants (including seeds) first with an active ingredient from groups (2) to (23) and then to treat with a herbicide from group (1). In particular, it is also possible to first coat seeds with one or more active ingredients from groups (2) to (23) in one or more layers and to spray the plants obtained therefrom only after an infection has occurred with a herbicide from group (1) (e.g. Soybean or maize seeds are first treated with fluquinconazole or carboxin, followed by foliar application with glyphosate; or rape seed is first treated with fluquinconazole or carboxin, followed by foliar application later with glufosinate).
0236As already mentioned above, all plants and their parts can be treated according to the invention. In a preferred embodiment, plant species and plant varieties and their parts occurring wildly or obtained by conventional organic breeding methods, such as crossbreeding or protoplast fusion, are treated. In a further preferred embodiment, transgenic plants and plant cultivars which have been obtained by genetic engineering methods, if appropriate in combination with conventional methods (genetically modified organisms) and their parts are treated. The term "parts" or "parts of plants" or "plant parts" was explained above.
0237Plants of the plant cultivars which are in each case commercially available or in use are particularly preferably treated according to the invention.
0238Depending on the plant species or plant cultivars, their location and growth conditions (soils, climate, growing season, nutrition), the treatment according to the invention can also cause superadditive ("synergistic") effects. For example, reduced application rates and / or widening the spectrum of action and / or an increase in the action of the substances and agents which can be used according to the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or Soil salinity, increased flowering performance, easier harvesting, acceleration of ripening, higher harvest yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or workability of the harvested products, which go beyond the effects that are actually to be expected.
0239The preferred transgenic (genetically engineered) plants or plant cultivars to be treated according to the invention include all plants which, by virtue of the genetic engineering modification, have received genetic material which gives these plants particularly advantageous, valuable properties (“traits”). Examples of such properties are better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or Soil salt content, increased flowering performance, easier harvesting, acceleration of ripening, higher harvest yields, higher quality and / or higher nutritional value of the harvested products, higher storage life and / or workability of the harvested products. Further and particularly highlighted examples of such properties are an increased defense of the plants against animal and microbial pests, such as against insects, mites, phytopathogenic fungi, bacteria and / or viruses, and an increased tolerance of the plants to certain herbicidal active ingredients. Examples of transgenic plants are the important crop plants, such as cereals (wheat, rice), corn, soybeans, potatoes, cotton, rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soybeans, potatoes and cotton and rapeseed, especially soy. The traits are particularly emphasized as the increased defense of the plants against insects by toxins which arise in the plants, in particular those which are caused by the genetic material from Bacillus thuringiensis (for example by the genes CryIA (a), CryIA (b), CryIA (c), CryIIA, CryIIIA, CryIIIB2, Cry9c, Cry2Ab, Cry3Bb and CryIF as well as their combinations) are produced in the plants (hereinafter "Bt plants"). The properties (“traits”) which are particularly emphasized are the increased tolerance of the plants to certain herbicidal active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (for example “PAT” gene). The genes conferring the desired properties (“traits”) can also occur in combinations with one another in the transgenic plants. Examples of "Bt plants" are corn varieties, cotton varieties, soy varieties and potato varieties which are sold under the trade names YIELD GARD<sup>®</sup> (e.g. corn, cotton, soy), KnockOut<sup>®</sup> (e.g. maize), StarLink<sup>®</sup> (e.g. maize), Bollgard<sup>®</sup> (Cotton), Nucotn<sup>®</sup> (Cotton) and NewLeaf<sup>®</sup> (Potato) are distributed. Examples of herbicide-tolerant plants are corn varieties, cotton varieties and soy varieties which are sold under the trade names Roundup Ready<sup>®</sup> (Tolerance to glyphosate eg corn, cotton, soy), Liberty Link<sup>®</sup> (Tolerance to phosphinotricin, eg rapeseed), IMI<sup>®</sup> (Tolerance to imidazolinones) and STS<sup>®</sup> (Tolerance to sulfonylureas such as corn) are sold. As herbicide-resistant plants (conventionally bred to herbicide tolerance) are also those under the name Clearfield<sup>®</sup> distributed varieties (e.g. maize) mentioned. Of course, these statements also apply to plant varieties developed in the future or coming onto the market in the future with these or future-developed genetic properties ("traits").
0240Depending on their respective physical and / or chemical properties, the active compound combinations according to the invention can be converted into the customary formulations, such as solutions, emulsions, suspensions, powders, dusts, foams, pastes, soluble powders, granules, aerosols, suspension emulsion concentrates, Active ingredient-impregnated natural and synthetic substances as well as very fine encapsulation in polymeric substances and in coating materials for seeds, as well as ULV cold and warm fog formulations.
0241These formulations are prepared in a known manner, for example by mixing the active ingredients or combinations of active ingredients with extenders, that is to say liquid solvents, pressurized liquefied gases and / or solid carriers, optionally using surface-active agents, that is to say emulsifiers and / or dispersants and / or foam-generating agents.
0242If water is used as an extender, organic solvents can, for example, also be used as auxiliary solvents. The following are essentially suitable as liquid solvents: aromatics, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chlorethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, for example Petroleum fractions, mineral and vegetable oils, alcohols, such as butanol or glycol, and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
0243Liquefied gaseous extenders or carriers mean liquids which are gaseous at normal temperature and under normal pressure, for example aerosol propellants such as butane, propane, nitrogen and carbon dioxide.
0244Solid carrier materials are suitable: for example ammonium salts and natural rock powders, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock powders, such as highly disperse silica, aluminum oxide and silicates. The following are suitable as solid carriers for granules: e.g. broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules from inorganic and organic flours as well as granules from organic material such as sawdust, coconut shells, corn cobs and tobacco stems. Suitable emulsifying and / or foam-generating agents are: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example Alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates and protein hydrolyzates. Possible dispersing agents are, for example, lignin sulfite liquor and methyl cellulose.
0245Adhesives such as carboxymethyl cellulose, natural and synthetic polymers in the form of powders, granules or latices, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and also natural phospholipids, such as cephalins and lecithins, and synthetic phospholipids can be used in the formulations. Other additives can be mineral and vegetable oils.
0246Dyes such as inorganic pigments, for example iron oxide, titanium oxide, ferrocyan blue and organic dyes, such as alizarin, azo and metal phthalocyanine dyes and trace nutrients, such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc, can be used.
0247The active substance content of the use forms prepared from the commercially available formulations can vary within wide ranges. The active substance concentration of the use forms for controlling animal pests such as insects and acarids can be from 0.0000001 to 95% by weight of active substance, preferably between 0.0001 and 1% by weight. The application takes place in a customary manner adapted to the application forms.
0248The formulations for controlling undesirable phytopathogenic fungi generally contain between 0.1 and 95% by weight of active compounds, preferably between 0.5 and 90%.
0249The active compound combinations according to the invention can be used as such, in the form of their formulations or the use forms prepared therefrom, such as ready-to-use solutions, emulsifiable concentrates, emulsions, suspensions, wettable powders, soluble powders, dusts and granules. They are used in the usual way, e.g. by watering (drenching), drip irrigation, spraying, spraying, scattering, dusting, foaming, brushing, spreading, dry pickling, wet pickling, wet pickling, slurry pickling, incrusting, etc.
0250The active compound combinations according to the invention can be present in commercially available formulations and in the use forms prepared from these formulations, in a mixture with other active compounds, such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth-regulating substances or herbicides.
0251When using the active compound combinations according to the invention, the application rates can be varied within a substantial range, depending on the type of application. In the treatment of parts of plants, the application rates of active compound combination are generally between 0.1 and 10,000 g / ha, preferably between 10 and 1,000 g / ha. In the case of seed treatment, the application rates of the active compound combination are generally between 0.001 and 50 g per kg of seed, preferably between 0.01 and 10 g per kg of seed. In the treatment of the soil, the active compound combination application rates are generally between 0.1 and 10,000 g / ha, preferably between 1 and 5,000 g / ha.
0252The active substance combinations can be used as such, in the form of concentrates or generally customary formulations such as powders, granules, solutions, suspensions, emulsions or pastes.
0253The formulations mentioned can be prepared in a manner known per se, for example by mixing the active ingredients with at least one solvent or diluent, emulsifier, dispersant and / or binder or fixative, water repellants, optionally siccatives and UV stabilizers and, if appropriate Dyes and pigments and other processing aids.
0254The good fungicidal activity of the active compound combinations according to the invention can be seen from the examples below. While the individual active ingredients have weaknesses in their fungicidal action, the combinations show an action that goes beyond a simple summation of action.
0255Fungicides always have a synergistic effect if the fungicidal activity of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients.
0256The expected one <u>fungicidal</u> Effect for a given combination of two active substances can be <nplcit id="ncit0001" npl-type="s"><text>SR Colby ("Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 1967, 15, 20-22</text></nplcit>) can be calculated as follows: If X den <i>Efficiency</i> when using the active ingredient A in an application rate of <i><u>m</u> glha</i> means Y den <i>Efficiency</i> when using the active ingredient B in an application rate of <i><u>n</u> glha</i> means on d
0257E den <i>Efficiency</i> when using active ingredients A and B in application rates of <i><u>m</u> and <u>n</u> glha</i> means then <maths id="math0001"><math display="block"><mi mathvariant="normal">E</mi><mo mathvariant="normal">=</mo><mi mathvariant="normal">X</mi><mo mathvariant="normal">+</mo><mi mathvariant="normal">Y</mi><mo mathvariant="normal">-</mo><mfrac><mrow><mi mathvariant="normal">X</mi><mo mathvariant="normal">+</mo><mi mathvariant="normal">Y</mi></mrow><mn mathvariant="normal">100</mn></mfrac></math><img file="EP2255646A2_D0198.tif" /></maths>
0258The efficiency is determined in%. It means 0% an efficiency that corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
0259Is the real one <u>fungicidal</u> If the effect is greater than calculated, the effect of the combination is super-additive, ie there is a synergistic effect. In this case, the actually observed efficiency must be greater than the value for the expected efficiency (E) calculated from the above formula.
0260The invention is illustrated by the following examples. However, the invention is not limited to the examples.
<u>Examples of use</u>
Example A: Phytophthora test (tomato) / protective
0261<tables id="tabl0003" num="0003"><table frame="none"><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26mm" /><colspec colnum="2" colname="col2" colwidth="12mm" /><colspec colnum="3" colname="col3" colwidth="59mm" /><tbody><row><entry>Solvent:</entry><entry align="right">24,5</entry><entry>Parts by weight of acetone</entry></row><row><entry /><entry align="right">24,5</entry><entry>Parts by weight of dimethylacetamide</entry></row><row><entry>Emulsifier:</entry><entry align="right">1</entry><entry>Part by weight of alkyl aryl polyglycol ether</entry></row></tbody></tgroup></table></tables>To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration.
0262To test for protective activity, young plants are sprayed with the active compound preparation in the stated application rate. After the spray coating has dried on, the plants are inoculated with an aqueous spore suspension of Phytophthora infestans. The plants are then placed in an incubation cabin at approx. 20 ° C and 100% relative humidity. Evaluation is carried out 3 days after the inoculation. 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Example B: Plasmopara test (vine) / protective
0263<tables id="tabl0004" num="0004"><table frame="none"><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26mm" /><colspec colnum="2" colname="col2" colwidth="12mm" /><colspec colnum="3" colname="col3" colwidth="59mm" /><tbody><row><entry>Solvent:</entry><entry align="right">24,5</entry><entry>Parts by weight of acetone</entry></row><row><entry /><entry align="right">24,5</entry><entry>Parts by weight of dimethylacetamide</entry></row><row><entry>Emulsifier:</entry><entry align="right">1</entry><entry>Part by weight of alkyl aryl polyglycol ether</entry></row></tbody></tgroup></table></tables>To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration.
0264To test for protective activity, young plants are sprayed with the active compound preparation in the stated application rate. After the spray coating has dried on, the plants are inoculated with an aqueous spore suspension of Plasmopara viticola and then remain in an incubation cabin at about 20 ° C. and 100% relative atmospheric humidity for 1 day. The plants are then placed in a greenhouse for 4 days at approx. 21 ° C and approx. 90% humidity. The plants are then moistened and placed in an incubation cabin for 1 day. Evaluation is carried out 6 days after the inoculation. 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Example C: Podosphaera test (apple) / protective
0265<tables id="tabl0005" num="0005"><table frame="none"><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26mm" /><colspec colnum="2" colname="col2" colwidth="12mm" /><colspec colnum="3" colname="col3" colwidth="59mm" /><tbody><row><entry>Solvent:</entry><entry align="right">24,5</entry><entry>Parts by weight of acetone</entry></row><row><entry /><entry align="right">24,5</entry><entry>Parts by weight of dimethylacetamide</entry></row><row><entry>Emulsifier:</entry><entry align="right">1</entry><entry>Part by weight of alkyl aryl polyglycol ether</entry></row></tbody></tgroup></table></tables>To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration.
0266To test for protective activity, young plants are sprayed with the active compound preparation in the stated application rate. After the spray coating has dried on, the plants are inoculated with an aqueous spore suspension of the pod mildew pathogen Podosphaera leucotricha. The plants are then placed in a greenhouse at approximately 23 ° C. and a relative humidity of approximately 70%. Evaluation is carried out 10 days after the inoculation. 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Example D: Sphaerotheca test (cucumber) / protective
0267<tables id="tabl0006" num="0006"><table frame="none"><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26mm" /><colspec colnum="2" colname="col2" colwidth="12mm" /><colspec colnum="3" colname="col3" colwidth="59mm" /><tbody><row><entry>Solvent:</entry><entry align="right">24,5</entry><entry>Parts by weight of acetone</entry></row><row><entry /><entry align="right">24,5</entry><entry>Parts by weight of dimethylacetamide</entry></row><row><entry>Emulsifier:</entry><entry align="right">1</entry><entry>Part by weight of alkyl aryl polyglycol ether</entry></row></tbody></tgroup></table></tables>To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration.
0268To test for protective activity, young plants are sprayed with the active compound preparation in the stated application rate. After the spray coating has dried on, the plants are inoculated with an aqueous spore suspension of Sphaerotheca fuliginea. The plants are then placed in the greenhouse at about 23 ° C. and a relative atmospheric humidity of about 70%. Evaluation is carried out 7 days after the inoculation. 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Example E: Uncinula test (vine) / protective
0269<tables id="tabl0007" num="0007"><table frame="none"><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26mm" /><colspec colnum="2" colname="col2" colwidth="12mm" /><colspec colnum="3" colname="col3" colwidth="59mm" /><tbody><row><entry>Solvent:</entry><entry align="right">24,5</entry><entry>Parts by weight of acetone</entry></row><row><entry /><entry align="right">24,5</entry><entry>Parts by weight of dimethylacetamide</entry></row><row><entry>Emulsifier:</entry><entry align="right">1</entry><entry>Part by weight of alkyl aryl polyglycol ether</entry></row></tbody></tgroup></table></tables>To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration.
0270To test for protective activity, young plants are sprayed with the active compound preparation in the stated application rate. After the spray coating has dried on, the plants are inoculated with an aqueous spore suspension of Uncinula necator. The plants are then placed in a greenhouse at approximately 23 ° C. and a relative humidity of approximately 70%. Evaluation is carried out 14 days after the inoculation. 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Example F: Uromyces test (bean) / protective
0271<tables id="tabl0008" num="0008"><table frame="none"><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26mm" /><colspec colnum="2" colname="col2" colwidth="12mm" /><colspec colnum="3" colname="col3" colwidth="59mm" /><tbody><row><entry>Solvent:</entry><entry align="right">24,5</entry><entry>Parts by weight of acetone</entry></row><row><entry /><entry align="right">24,5</entry><entry>Parts by weight of dimethylacetamide</entry></row><row><entry>Emulsifier:</entry><entry align="right">1</entry><entry>Part by weight of alkyl aryl polyglycol ether</entry></row></tbody></tgroup></table></tables>To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration.
0272To test for protective activity, young plants are sprayed with the active compound preparation in the stated application rate. After the spray coating has dried on, the plants are inoculated with an aqueous spore suspension of the rooster pathogen Uromyces appendiculatus and then remain in an incubation cabin at about 20 ° C. and 100% relative atmospheric humidity for 1 day. The plants are then placed in a greenhouse at approx. 21 ° C. and a relative humidity of approx. 90%. 10th Evaluation is carried out days after the inoculation. 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Example G: Phakopsora test (soy)
0273Commercial formulations which are diluted to the desired concentration before application, if appropriate, are used as suitable active substance preparations. Soybean plants (cv. Miyagishirome) were cultivated in a 7.5 cm diameter plastic container for 14 days until they reached the 2.3 leaf stage. The active substance preparations were sprayed onto the test plants in the concentration given below (6 ml for 3 test tubes each, test solution contained 0.02% neoesterin as adhesive). 1 day after application of the active compound preparation, the plants were treated with a urediniospore suspension (1 x 10<sup>5</sup> Urediniosporen / ml) of the Rosterogen Phakopsora pachyrhizi sprayed. The plants are then placed in a greenhouse at approx. 25 ° C during the day and approx. 18 ° C at night and a relative humidity of 91.9%. Evaluation is carried out 11 days after the inoculation by comparing the infected areas of untreated and treated plants. 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infection is observed.<tables id="tabl0009" num="0009"><table frame="all"><title>Table G</title><tgroup cols="4"><colspec colnum="1" colname="col1" colwidth="34mm" /><colspec colnum="2" colname="col2" colwidth="54mm" /><colspec colnum="3" colname="col3" colwidth="16mm" /><colspec colnum="4" colname="col4" colwidth="16mm" /><thead><row><entry namest="col1" nameend="col4" align="center" valign="middle"><b>Phakopsora test (soy)</b></entry></row><row rowsep="0"><entry valign="middle">Active ingredients</entry><entry align="center" valign="middle">Application rate of active ingredient in ppm</entry><entry namest="col3" nameend="col4" align="center" valign="middle">Efficiency in%</entry></row><row><entry align="center" valign="middle" /><entry align="center" valign="middle" /><entry align="center" valign="middle">found *</entry><entry align="center" valign="middle">calc. **</entry></row></thead><tbody><row rowsep="0"><entry morerows="1" rowsep="1" valign="middle">(1-1) Glyphosate</entry><entry align="center" valign="middle">0,5</entry><entry align="center" valign="middle">0</entry><entry align="center" valign="middle" /></row><row><entry align="center" valign="middle">5</entry><entry align="center" valign="middle">0</entry><entry align="center" valign="middle" /></row><row><entry valign="middle">(3-17) Tebuconazole</entry><entry align="center" valign="middle">0,5</entry><entry align="center" valign="middle">50</entry><entry align="center" valign="middle" /></row><row><entry valign="middle">(1-1) + (3-17) (1:1)</entry><entry align="center" valign="middle">0,5 + 0,5</entry><entry align="center" valign="middle">96</entry><entry align="center" valign="middle">50</entry></row><row><entry valign="middle">(1-1) + (3-17) (10:1)</entry><entry align="center" valign="middle">5 + 0,5</entry><entry align="center" valign="middle">99</entry><entry align="center" valign="middle">50</entry></row><row rowsep="0"><entry morerows="1" rowsep="1" valign="middle">(1-2) Glufosinate</entry><entry align="center" valign="middle">0,5</entry><entry align="center" valign="middle">0</entry><entry align="center" valign="middle" /></row><row><entry align="center" valign="middle">5</entry><entry align="center" valign="middle">0</entry><entry align="center" valign="middle" /></row><row><entry valign="middle">(3-17) Tebuconazole</entry><entry align="center" valign="middle">0,5</entry><entry align="center" valign="middle">60</entry><entry align="center" valign="middle" /></row><row><entry valign="middle">(1-2)+(3-17) (1:1)</entry><entry align="center" valign="middle">0,5+0,5</entry><entry align="center" valign="middle">94</entry><entry align="center" valign="middle">60</entry></row><row><entry valign="middle">(1-2)+(3-17) (10:1)</entry><entry align="center" valign="middle">5 + 0,5</entry><entry align="center" valign="middle">95</entry><entry align="center" valign="middle">60</entry></row></tbody></tgroup><tgroup cols="4" rowsep="0"><colspec colnum="1" colname="col1" colwidth="34mm" /><colspec colnum="2" colname="col2" colwidth="54mm" /><colspec colnum="3" colname="col3" colwidth="16mm" /><colspec colnum="4" colname="col4" colwidth="16mm" /><tbody><row><entry namest="col1" nameend="col4" align="justify">* found = found effect ** calc. = Effect calculated according to the Colby formula</entry></row></tbody></tgroup></table></tables>
Example H: Venturia test (apple) / protective
0274<tables id="tabl0010" num="0010"><table frame="none"><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26mm" /><colspec colnum="2" colname="col2" colwidth="12mm" /><colspec colnum="3" colname="col3" colwidth="59mm" /><tbody><row><entry>Solvent:</entry><entry align="right">24,5</entry><entry>Parts by weight of acetone</entry></row><row><entry /><entry align="right">24,5</entry><entry>Parts by weight of dimethylacetamide</entry></row><row><entry>Emulsifier:</entry><entry align="right">1</entry><entry>Part by weight of alkyl aryl polyglycol ether</entry></row></tbody></tgroup></table></tables>To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration.
0275To test for protective activity, young plants are sprayed with the active compound preparation in the stated application rate. After the spray coating has dried on, the plants are inoculated with an aqueous conidia suspension of the Venturia inaequalis apple scab pathogen and then remain in an incubation cabin at about 20 ° C. and 100% relative atmospheric humidity for 1 day. The plants are then placed in a greenhouse at approx. 21 ° C. and a relative humidity of approx. 90%. 10th Evaluation is carried out days after the inoculation. 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Example I: Alternaria test (tomato) / protective
0276<tables id="tabl0011" num="0011"><table frame="none"><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26mm" /><colspec colnum="2" colname="col2" colwidth="12mm" /><colspec colnum="3" colname="col3" colwidth="59mm" /><tbody><row><entry>Solvent:</entry><entry align="right">24,5</entry><entry>Parts by weight of acetone</entry></row><row><entry /><entry align="right">24,5</entry><entry>Parts by weight of dimethylacetamide</entry></row><row><entry>Emulsifier:</entry><entry align="right">1</entry><entry>Part by weight of alkyl aryl polyglycol ether</entry></row></tbody></tgroup></table></tables>To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration.
0277To test for protective activity, young plants are sprayed with the active compound preparation in the stated application rate. After the spray coating has dried on, the plants are inoculated with an aqueous spore suspension of Alternaria solani. The plants are then placed in an incubation cabin at approx. 20 ° C and 100% relative humidity. Evaluation is carried out 3 days after the inoculation. 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Example J: Botrytis test (bean) / protective
0278<tables id="tabl0012" num="0012"><table frame="none"><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26mm" /><colspec colnum="2" colname="col2" colwidth="12mm" /><colspec colnum="3" colname="col3" colwidth="59mm" /><tbody><row><entry>Solvent:</entry><entry align="right">24,5</entry><entry>Parts by weight of acetone</entry></row><row><entry /><entry align="right">24,5</entry><entry>Parts by weight of dimethylacetamide</entry></row><row><entry>Emulsifier:</entry><entry align="right">1</entry><entry>Part by weight of alkyl aryl polyglycol ether</entry></row></tbody></tgroup></table></tables>To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration.
0279To test for protective activity, young plants are sprayed with the active compound preparation in the stated application rate. After the spray coating has dried on, 2 small pieces of agar covered with Botrytis cinerea are placed on each leaf. The inoculated plants are placed in a darkened chamber at approx. 20 ° C and 100% relative humidity. 2 days after the inoculation, the size of the infection spots on the leaves is evaluated. 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Example K: Erysiphe test (barley) / protective
0280<tables id="tabl0013" num="0013"><table frame="none"><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26mm" /><colspec colnum="2" colname="col2" colwidth="10mm" /><colspec colnum="3" colname="col3" colwidth="56mm" /><tbody><row><entry>Solvent:</entry><entry align="right">50</entry><entry>Parts by weight of N, N-dimethylacetamide</entry></row><row><entry>Emulsifier:</entry><entry align="right">1</entry><entry>Part by weight of alkylaryl polyglycol ether</entry></row></tbody></tgroup></table></tables>To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration.
0281To test for protective activity, young plants are sprayed with the preparation of active compound in the stated application rate. After the spray coating has dried on, the plants are covered with spores from Erysiphe graminis f.sp. hordei pollinated. The plants are placed in a greenhouse at a temperature of approx. 20 ° C and a relative humidity of approx. 80% in order to promote the development of mildew pustules. Evaluation is carried out 7 days after the inoculation. 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Example L: Erysiphe test (wheat) / protective
0282<tables id="tabl0014" num="0014"><table frame="none"><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26mm" /><colspec colnum="2" colname="col2" colwidth="10mm" /><colspec colnum="3" colname="col3" colwidth="56mm" /><tbody><row><entry>Solvent:</entry><entry align="right">50</entry><entry>Parts by weight of N, N-dimethylacetamide</entry></row><row><entry>Emulsifier:</entry><entry align="right">1</entry><entry>Part by weight of alkylaryl polyglycol ether</entry></row></tbody></tgroup></table></tables>To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration.
0283To test for protective activity, young plants are sprayed with the preparation of active compound in the stated application rate. After the spray coating has dried on, the plants are covered with spores from Erysiphe graminis f.sp. tritici pollinated. The plants are placed in a greenhouse at a temperature of approx. 20 ° C and a relative humidity of approx. 80% in order to promote the development of mildew pustules. Evaluation is carried out 7 days after the inoculation. 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Example M: Fusarium culmorum test (wheat) / protective
0284<tables id="tabl0015" num="0015"><table frame="none"><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26mm" /><colspec colnum="2" colname="col2" colwidth="10mm" /><colspec colnum="3" colname="col3" colwidth="56mm" /><tbody><row><entry>Solvent:</entry><entry align="right">50</entry><entry>Parts by weight of N, N-dimethylacetamide</entry></row><row><entry>Emulsifier:</entry><entry align="right">1</entry><entry>Part by weight of alkylaryl polyglycol ether</entry></row></tbody></tgroup></table></tables>To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration.
0285To test for protective activity, young plants are sprayed with the preparation of active compound in the stated application rate. After the spray coating has dried on, the plants are sprayed with a conidia suspension of Fusarium culmorum. The plants are placed in a greenhouse under translucent incubation hoods at a temperature of approx. 20 ° C and a relative humidity of approx. 100%. Evaluation is carried out 4 days after the inoculation. 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Example N: Fusarium nivale (var. Majus) test (wheat) / protective
0286<tables id="tabl0016" num="0016"><table frame="none"><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26mm" /><colspec colnum="2" colname="col2" colwidth="10mm" /><colspec colnum="3" colname="col3" colwidth="56mm" /><tbody><row><entry>Solvent:</entry><entry align="right">50</entry><entry>Parts by weight of N, N-dimethylacetamide</entry></row><row><entry>Emulsifier:</entry><entry align="right">1</entry><entry>Part by weight of alkylaryl polyglycol ether</entry></row></tbody></tgroup></table></tables>To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration. To test for protective activity, young plants are sprayed with the active compound preparation in the stated application rate. After the spray coating has dried on, the plants are sprayed with a conidia suspension of Fusarium nivale (var. Majus). The plants are placed in a greenhouse under translucent incubation hoods at a temperature of approx. 15 ° C and a relative humidity of approx. 100%. Evaluation is carried out 4 days after the inoculation. 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Example O: Fusarium graminearum test (barley) / protective
0287<tables id="tabl0017" num="0017"><table frame="none"><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26mm" /><colspec colnum="2" colname="col2" colwidth="10mm" /><colspec colnum="3" colname="col3" colwidth="56mm" /><tbody><row><entry>Solvent:</entry><entry align="right">50</entry><entry>Parts by weight of N, N-dimethylacetamide</entry></row><row><entry>Emulsifier:</entry><entry align="right">1</entry><entry>Part by weight of alkylaryl polyglycol ether</entry></row></tbody></tgroup></table></tables>To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration. To test for protective activity, young plants are sprayed with the active compound preparation in the stated application rate. After the spray coating has dried on, the plants are sprayed with a conidia suspension of Fusarium graminearum. The plants are placed in a greenhouse under translucent incubation hoods at a temperature of approx. 15 ° C and a relative humidity of 100%. Evaluation is carried out 4 days after the inoculation. 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Example P: Leptosphaeria nodorum test (wheat) / protective
0288<tables id="tabl0018" num="0018"><table frame="none"><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26mm" /><colspec colnum="2" colname="col2" colwidth="10mm" /><colspec colnum="3" colname="col3" colwidth="58mm" /><tbody><row><entry>Solvent:</entry><entry align="right">50</entry><entry>Parts by weight of N, N-dimethylacetamide</entry></row><row><entry>Emulsifier:</entry><entry align="right">1</entry><entry>Parts by weight of alkylaryl polyglycol ether</entry></row></tbody></tgroup></table></tables>To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration. To test for protective activity, young plants are sprayed with the active compound preparation in the stated application rate. After the spray coating has dried on, the plants are sprayed with a spore suspension of Leptosp haeria nodorum. The plants remain in an incubation cabin at 20 ° C. and 100% relative atmospheric humidity for 48 hours. The plants are placed in a greenhouse at a temperature of approx. 15 ° C and a relative humidity of 80%. Evaluation is carried out 10 days after the inoculation. 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Example Q: Pseudocercosporella herpotrichoides test; R strain (wheat) / protective
0289<tables id="tabl0019" num="0019"><table frame="none"><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26mm" /><colspec colnum="2" colname="col2" colwidth="10mm" /><colspec colnum="3" colname="col3" colwidth="58mm" /><tbody><row><entry>Solvent:</entry><entry align="right">50</entry><entry>Parts by weight of N, N-dimethylacetamide</entry></row><row><entry>Emulsifier:</entry><entry align="right">1</entry><entry>Parts by weight of alkylaryl polyglycol ether</entry></row></tbody></tgroup></table></tables>To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration. To test for protective activity, young plants are sprayed with the active compound preparation in the stated application rate. After the spray coating has dried on, the plants at the stem base are inoculated with spores of the R strain of Pseudocercosporella herpotrichoides. The plants are placed in a greenhouse at a temperature of approx. 10 ° C and a relative humidity of 80%. Evaluation is carried out 21 days after the inoculation. 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Example R: Pseudocercosporella herpotrichoides test; W strain (wheat) / protective
0290<tables id="tabl0020" num="0020"><table frame="none"><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26mm" /><colspec colnum="2" colname="col2" colwidth="10mm" /><colspec colnum="3" colname="col3" colwidth="56mm" /><tbody><row><entry>Solvent:</entry><entry align="right">50</entry><entry>Parts by weight of N, N-dimethylacetamide</entry></row><row><entry>Emulsifier:</entry><entry align="right">1</entry><entry>Part by weight of alkylaryl polyglycol ether</entry></row></tbody></tgroup></table></tables>To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration. To test for protective activity, young plants are sprayed with the active compound preparation in the stated application rate. After the spray coating has dried on, the plants at the stem base are inoculated with spores of the W strain of Pseudocercosporella herpotrichoides. The plants are placed in a greenhouse at a temperature of approx. 10 ° C and a relative humidity of 80%. Evaluation is carried out 21 days after the inoculation. 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Example S: Puccinia test (wheat) / protective
0291<tables id="tabl0021" num="0021"><table frame="none"><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26mm" /><colspec colnum="2" colname="col2" colwidth="10mm" /><colspec colnum="3" colname="col3" colwidth="58mm" /><tbody><row><entry>Solvent:</entry><entry align="right">50</entry><entry>Parts by weight of N, N-dimethylacetamide</entry></row><row><entry>Emulsifier:</entry><entry align="right">1</entry><entry>Parts by weight of alkylaryl polyglycol ether</entry></row></tbody></tgroup></table></tables>To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration. To test for protective activity, young plants are sprayed with the active compound preparation in the stated application rate. After the spray coating has dried on, the plants are sprayed with a conidia suspension of Puccinia recondita. The plants remain in an incubation cabin at 20 ° C. and 100% relative atmospheric humidity for 48 hours. The plants are then placed in a greenhouse at a temperature of about 20 ° C. and a relative atmospheric humidity of 80% in order to promote the development of rust pustules. Evaluation is carried out 10 days after the inoculation. 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Example T: Pyrenophora teres test (barley) / protective
0292<tables id="tabl0022" num="0022"><table frame="none"><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26mm" /><colspec colnum="2" colname="col2" colwidth="10mm" /><colspec colnum="3" colname="col3" colwidth="56mm" /><tbody><row><entry>Solvent:</entry><entry align="right">50</entry><entry>Parts by weight of N, N-dimethylacetamide</entry></row><row><entry>Emulsifier:</entry><entry align="right">1</entry><entry>Part by weight of alkylaryl polyglycol ether</entry></row></tbody></tgroup></table></tables>To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with water to the desired concentration. To test for protective efficacy, young plants are sprayed with the active compound preparation in the stated application rate. After the spray coating has dried on, the plants are sprayed with a conidia suspension of Pyrenophora teres. The plants remain in an incubation cabin at 20 ° C. and 100% relative atmospheric humidity for 48 hours. The plants are then placed in a greenhouse at a temperature of approximately 20 ° C. and a relative atmospheric humidity of approximately 80%. Evaluation is carried out 7 days after the inoculation. 0% means an efficiency which corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Contents67
198 sheets
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Every citation, both ways
| Document | Relation | Office | Cited during |
|---|---|---|---|
| WO0014701A1 | Cites | World Intellectual Property Organization (WIPO) | Applicant |
| EP0015756A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0040345A1 | Cites | European Patent Office (EPO) | Applicant |
| WO0065913A1 | Cites | World Intellectual Property Organization (WIPO) | Applicant |
| EP0068813A2 | Cites | European Patent Office (EPO) | Applicant |
| EP0078663A2 | Cites | European Patent Office (EPO) | Applicant |
| EP0086438A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0112284A2 | Cites | European Patent Office (EPO) | Applicant |
| WO0112585A1 | Cites | World Intellectual Property Organization (WIPO) | Applicant |
| EP0145294A2 | Cites | European Patent Office (EPO) | Applicant |
| EP0155509A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0183458A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0196038A2 | Cites | European Patent Office (EPO) | Applicant |
| EP0206999A2 | Cites | European Patent Office (EPO) | Applicant |
| WO0208197A1 | Cites | World Intellectual Property Organization (WIPO) | Applicant |
| EP0219756A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0234242A2 | Cites | European Patent Office (EPO) | Applicant |
| EP0236272A1 | Cites | European Patent Office (EPO) | Applicant |
| WO0238542A1 | Cites | World Intellectual Property Organization (WIPO) | Applicant |
| EP0248086A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0253213A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0256503A2 | Cites | European Patent Office (EPO) | Applicant |
| EP0258161A2 | Cites | European Patent Office (EPO) | Applicant |
| EP0270111A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0278595A2 | Cites | European Patent Office (EPO) | Applicant |
| EP0298196A1 | Cites | European Patent Office (EPO) | Applicant |
| WO03010149A1 | Cites | World Intellectual Property Organization (WIPO) | Applicant |
| WO03066609A1 | Cites | World Intellectual Property Organization (WIPO) | Applicant |
| WO03066610A1 | Cites | World Intellectual Property Organization (WIPO) | Applicant |
| WO03070705A1 | Cites | World Intellectual Property Organization (WIPO) | Applicant |
| EP0310550A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0313512A2 | Cites | European Patent Office (EPO) | Applicant |
| EP0315502A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0329397A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0339418A2 | Cites | European Patent Office (EPO) | Applicant |
| EP0341475A2 | Cites | European Patent Office (EPO) | Applicant |
| EP0378953A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0382375A2 | Cites | European Patent Office (EPO) | Applicant |
| EP0398692A2 | Cites | European Patent Office (EPO) | Applicant |
| EP0431545A2 | Cites | European Patent Office (EPO) | Search report |
| EP0460575A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0515901A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0537957A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0569384A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0596254A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0600629A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0604019A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0639574A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0712396B1 | Cites | European Patent Office (EPO) | Applicant |
| EP0737682A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0936213A1 | Cites | European Patent Office (EPO) | Applicant |
| EP0945065A1 | Cites | European Patent Office (EPO) | Search report |
| DE10303589A1 | Cites | Germany | Applicant |
| DE1076434B | Cites | Germany | Applicant |
| DE1081446B | Cites | Germany | Applicant |
| GB1103989A | Cites | United Kingdom | Applicant |
| GB1114155A | Cites | United Kingdom | Applicant |
| DE1193498B | Cites | Germany | Applicant |
| DE1209799B | Cites | Germany | Applicant |
| DE1234704B | Cites | Germany | Applicant |
| DD140041A1 | Cites | German Democratic Republic (until 1990) | Applicant |
| DD151404A1 | Cites | German Democratic Republic (until 1990) | Applicant |
| DE19531813A1 | Cites | Germany | Applicant |
| DE19539324A1 | Cites | Germany | Applicant |
| DE19602095A1 | Cites | Germany | Applicant |
| DE19646407A1 | Cites | Germany | Applicant |
| US1972961A | Cites | United States of America | Applicant |
| JP2001187786A | Cites | Japan | Applicant |
| WO2004005242A1 | Cites | World Intellectual Property Organization (WIPO) | Applicant |
| WO2004016088A2 | Cites | World Intellectual Property Organization (WIPO) | Applicant |
| WO2004067515A1 | Cites | World Intellectual Property Organization (WIPO) | Applicant |
| WO2005041653A2 | Cites | World Intellectual Property Organization (WIPO) | Search report |
| WO2005123689A1 | Cites | World Intellectual Property Organization (WIPO) | Applicant |
| WO2005123690A1 | Cites | World Intellectual Property Organization (WIPO) | Applicant |
| WO2006015865A1 | Cites | World Intellectual Property Organization (WIPO) | Applicant |
| DE2012656A1 | Cites | Germany | Applicant |
| DE2149923A1 | Cites | Germany | Applicant |
| DE2152826A1 | Cites | Germany | Applicant |
| DE2201063A1 | Cites | Germany | Applicant |
| DE2207576A1 | Cites | Germany | Applicant |
| DE2312956A1 | Cites | Germany | Applicant |
| GB2313595A | Cites | United Kingdom | Search report |
| DE2324010A1 | Cites | Germany | Applicant |
| DE2429523A1 | Cites | Germany | Applicant |
| DE2456627A1 | Cites | Germany | Applicant |
| US2504404A | Cites | United States of America | Applicant |
| DE2513732A1 | Cites | Germany | Applicant |
| DE2515091A1 | Cites | Germany | Applicant |
| DE2543279A1 | Cites | Germany | Applicant |
| DE2551560A1 | Cites | Germany | Applicant |
| US2553770A | Cites | United States of America | Applicant |
| US2588428A | Cites | United States of America | Applicant |
| DE2656747A1 | Cites | Germany | Applicant |
| DE2717440A1 | Cites | Germany | Applicant |
| DE2735872A1 | Cites | Germany | Applicant |
| DE2802488A1 | Cites | Germany | Applicant |
| DE2903612A1 | Cites | Germany | Applicant |
| US3010968A | Cites | United States of America | Applicant |
| DE3042303A1 | Cites | Germany | Applicant |
| US3178447A | Cites | United States of America | Applicant |
98 members in 17 offices
Priority claims3
| Document | Office | Kind | Date |
|---|---|---|---|
| 102005026482 | Germany | – | |
| 102005026482 | Germany | A | |
| 06791516 | European Patent Office (EPO) | A |
Members98
| Document | Office | Kind | |
|---|---|---|---|
| CA2611178A1 | Canada | A1 | |
| CA2916460A1 | Canada | A1 | |
| DE102005026482A1 | Germany | A1 | |
| DE102005026483A1 | Germany | A1 | |
| WO2006131230A2 | World Intellectual Property Organization (WIPO) | A2 | |
| TW200715977A | Taiwan Province of China | A | |
| AR054281A1 | Argentina | A1 | |
| WO2006131230A3 | World Intellectual Property Organization (WIPO) | A3 | |
| MX2007015376A | Mexico | A | |
| KR20080018943A | Republic of Korea | A | |
| EP1893024A2 | European Patent Office (EPO) | A2 | |
| EA200702661A1 | Eurasian Patent Organization (EAPO) | A1 | |
| CN101237777A | China | A | |
| JP2008542409A | Japan | A | |
| ZA200710548B | South Africa | B | |
| EP2132989A2 | European Patent Office (EPO) | A2 | |
| EP2132989A3 | European Patent Office (EPO) | A3 | |
| BRPI0612022A2 | Brazil | A2 | |
| EP1893024B1 | European Patent Office (EPO) | B1 | |
| AT484194T | Austria | T | |
| ATE484194T1 | Austria | T1 | |
| EP2253210A1 | European Patent Office (EPO) | A1 | |
| EP2253211A1 | European Patent Office (EPO) | A1 | |
| EP2253212A1 | European Patent Office (EPO) | A1 | |
| EP2253213A1 | European Patent Office (EPO) | A1 | |
| DE502006008090D1 | Germany | D1 | |
| EP2255644A2 | European Patent Office (EPO) | A2 | |
| EP2255645A2 | European Patent Office (EPO) | A2 | |
| EP2255646A2This record | European Patent Office (EPO) | A2 | |
| EP2255647A2 | European Patent Office (EPO) | A2 | |
| EP2255648A2 | European Patent Office (EPO) | A2 | |
| EP2255649A2 | European Patent Office (EPO) | A2 | |
| EP2255650A2 | European Patent Office (EPO) | A2 | |
| EP2255651A2 | European Patent Office (EPO) | A2 | |
| EP2255652A2 | European Patent Office (EPO) | A2 | |
| EP2255653A2 | European Patent Office (EPO) | A2 | |
| EP2255654A2 | European Patent Office (EPO) | A2 | |
| EP2255655A2 | European Patent Office (EPO) | A2 | |
| EP2255656A2 | European Patent Office (EPO) | A2 | |
| EP2255657A1 | European Patent Office (EPO) | A1 | |
| EP2255658A1 | European Patent Office (EPO) | A1 | |
| EP2255659A2 | European Patent Office (EPO) | A2 | |
| EP2258196A2 | European Patent Office (EPO) | A2 | |
| EP2258197A1 | European Patent Office (EPO) | A1 | |
| EP2258198A1 | European Patent Office (EPO) | A1 | |
| EP2260709A1 | European Patent Office (EPO) | A1 | |
| EP2260710A1 | European Patent Office (EPO) | A1 | |
| EP2260711A2 | European Patent Office (EPO) | A2 | |
| EP2263462A1 | European Patent Office (EPO) | A1 | |
| EP2263463A1 | European Patent Office (EPO) | A1 | |
| EA014410B1 | Eurasian Patent Organization (EAPO) | B1 | |
| EA201001074A1 | Eurasian Patent Organization (EAPO) | A1 | |
| EP2269460A1 | European Patent Office (EPO) | A1 | |
| EP2272368A1 | European Patent Office (EPO) | A1 | |
| EP2272369A1 | European Patent Office (EPO) | A1 | |
| EP2279664A1 | European Patent Office (EPO) | A1 | |
| EP2255648A3 | European Patent Office (EPO) | A3 | |
| EP2255659A3 | European Patent Office (EPO) | A3 | |
| EP2258196A3 | European Patent Office (EPO) | A3 | |
| ES2353974T3 | Spain | T3 | |
| EP2255647A3 | European Patent Office (EPO) | A3 | |
| EP2255645A3 | European Patent Office (EPO) | A3 | |
| EP2255646A3 | European Patent Office (EPO) | A3 | |
| EP2255652A3 | European Patent Office (EPO) | A3 | |
| EP2255653A3 | European Patent Office (EPO) | A3 | |
| EP2255654A3 | European Patent Office (EPO) | A3 | |
| EP2255655A3 | European Patent Office (EPO) | A3 | |
| EP2255656A3 | European Patent Office (EPO) | A3 | |
| EP2260711A3 | European Patent Office (EPO) | A3 | |
| EP2255644A3 | European Patent Office (EPO) | A3 | |
| EP2255649A3 | European Patent Office (EPO) | A3 | |
| EP2255650A3 | European Patent Office (EPO) | A3 | |
| EP2255651A3 | European Patent Office (EPO) | A3 | |
| PL1893024T3 | Poland | T3 | |
| US2011152097A1 | United States of America | A1 | |
| JP2012140441A | Japan | A | |
| TWI369950B | Taiwan Province of China | B | |
| TW201234969A | Taiwan Province of China | A | |
| TW201234970A | Taiwan Province of China | A | |
| JP5101496B2 | Japan | B2 | |
| JP2013006844A | Japan | A | |
| EP2255649B1 | European Patent Office (EPO) | B1 | |
| EA017853B1 | Eurasian Patent Organization (EAPO) | B1 | |
| EP2255657B1 | European Patent Office (EPO) | B1 | |
| EA201270781A1 | Eurasian Patent Organization (EAPO) | A1 | |
| US8754009B2 | United States of America | B2 | |
| US2014213557A1 | United States of America | A1 | |
| CN101237777B | China | B | |
| CN104170838A | China | A | |
| MX336614B | Mexico | B | |
| CA2611178C | Canada | C | |
| CN104170838B | China | B | |
| US9414600B2 | United States of America | B2 | |
| BRPI0612022B1 | Brazil | B1 | |
| AR102997A2 | Argentina | A2 | |
| AR102998A2 | Argentina | A2 | |
| AR102999A2 | Argentina | A2 | |
| CA2916460C | Canada | C |
18 legal events, as the office reported them to INPADOC
Over the term
Point at a mark for the eventEvents
| Event | Code | |
|---|---|---|
| Application deemed to be withdrawnWithdrawn18D | 18D | |
| Information on the status of an ep patent application or granted ep patentGrantedSTATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWNSTAA | STAA | |
| Designated contracting statesAK | AK | |
| Search report despatchedORIGINAL CODE: 0009013PUAL | PUAL | |
| Information on inventor provided before grant (corrected)RIN1 | RIN1 | |
| Information on inventor provided before grant (corrected)RIN1 | RIN1 | |
| Information on inventor provided before grant (corrected)RIN1 | RIN1 | |
| Information on inventor provided before grant (corrected)RIN1 | RIN1 | |
| Information on inventor provided before grant (corrected)RIN1 | RIN1 | |
| Information on inventor provided before grant (corrected)RIN1 | RIN1 | |
| Information on inventor provided before grant (corrected)RIN1 | RIN1 | |
| Information on inventor provided before grant (corrected)RIN1 | RIN1 | |
| Information on inventor provided before grant (corrected)RIN1 | RIN1 | |
| Information on inventor provided before grant (corrected)RIN1 | RIN1 | |
| Information on inventor provided before grant (corrected)RIN1 | RIN1 | |
| Divisional application: reference to earlier applicationAC | AC | |
| Designated contracting statesAK | AK | |
| Public reference made under article 153(3) epc to a published international application that has entered the european phaseORIGINAL CODE: 0009012PUAI | PUAI |
Numbers
- Publication
- 2255646
- Application
- 101691210
Titles3
- German
- Wirkstoffkombinationen
- English
- Agent combinations
- French
- Combinaisons d'agent actif
Classification
- IPC, 3
- A01N57 20
- A01N43 36
- A01P3 00
Designated states31
- Contracting states, 31
- Austria
- Belgium
- Bulgaria
- Switzerland
- Cyprus
- Czechia
- Germany
- Denmark
- Estonia
- Spain
- Finland
- France
- United Kingdom
- Greece
- Hungary
- Ireland
- Iceland
- Italy
- Liechtenstein
- Lithuania
- Luxembourg
- Latvia
- Monaco
- Netherlands (Kingdom of the)
and 7 moreShow fewer
- Poland
- Portugal
- Romania
- Sweden
- Slovenia
- Slovakia
- Türkiye