Epoxytriazine-capped polyphenylene ethers and method for their preparation.

0001This invention relates to the preparation of polyphenylene ethers containing epoxy groups, and to the use of such polyphenylene ethers in copolymer preparation.

0002The polyphenylene ethers are a widely used class of thermoplastic engineering resins characterized by excel­lent hydrolytic stability, dimensional stability, toughness, heat resistance and dielectric properties. However, they are deficient in certain other properties such as workabil­ity and solvent resistance. Therefore, there is a continu­ing search for means for modifying polyphenylene ethers to improve these other properties.

0003Among the means being studied are blending of polyphenylene ethers with certain other resinous materials such as polyesters, polyamides or olefin polymers. Blends of these other materials with polyphenylene ethers are, however, usually incompatible. Molded parts fabricated from such blends are generally brittle and may undergo catas­trophic delamination upon impact.

0004Numerous methods for compatibilizing blends of polyphenylene ethers with such other materials have been developed. For example, PCT published application 87/850 describes polyphenylene ethers-polyester blends compatibil­ized by the addition of an aromatic polycarbonate. Said blends are extremely versatile in numerous critical appli­cations such as the fabrication of automobile body parts. However, the presence of polycarbonate may result in degra­dation of certain other properties such as heat distortion temperature.

0005In addition, a problem sometimes arises by virtue of the presence of aminoalkyl-substituted end groups on certain commercially available polyphenylene ethers, as described in more detail hereinafter. For optimum impact strength, it is frequently necessary to remove said amino­alkyl-substituted end groups and other amine constituents frequently present as impurities in the polyphenylene ether. Such expedients as the use of amine quenchers and/or vacuum venting of the polyphenylene ether are effective in decreas­ing amino nitrogen content, but add a step to the processing operation which may be undesirable under certain circum­stances.

0006Various methods are also known for preparing copolymers of polyphenylene ethers with the aforementioned other materials. Such copolymers are effective as compat­ibilizers for blends of the same resins. To facilitate copolymer formation, it is frequently advisable to employ a polyphenylene ether containing functional groups. For example, epoxy groups can react with such nucleophilic groups in polyesters and polyamides as amino, hydroxy and carboxy groups, leading to copolymer formation.

0007Several methods of preparing epoxy-functionalized polyphenylene ethers are disclosed in various patents and publications. For example, U.S. Patent 4,460,743 describes the reaction of a polyphenylene ether with epichlorohydrin, to produce an epoxy-functionalized polymer which forms copolymers with carboxy-functionalized polyolefins. How­ever, this method requires dissolution of the polyphenylene ether in a large excess of epichlorohydrin, a relatively expensive reagent which is also a strong skin irritant and can cause kidney injury.

0008PCT published application 87/7279 describes the reaction of polyphenylene ethers with terephthaloyl chloride and glycidol to form an epoxy-functionalized polyphenylene ether useful, for example, for the preparation of copolymers with polyesters and polyamides, but copolymer formation with weakly nucleophilic polymers such as polyesters by this method requires a solution reaction in relatively expensive and high boiling solvents such as trichlorobenzene and is very slow.

0009In the same application are described reactions of various epoxy-functionalized ethylenic monomers such as glycidyl acrylate, glycidyl methacrylate and allyl glycidyl ether with polyphenylene ethers in the presence of free radical initiators. The resulting epoxy-functionalized materials are useful as intermediates for the preparation of copolymers by melt reaction with both polyesters and poly­amides. However, functionalization of the polyphenylene ether by this method requires large quantities of the monomer, and certain of such monomers, including glycidyl methacrylate, are toxic. Moreover, the reaction is gener­ally accompanied by homopolymerization of the epoxy-func­tionalized monomers, and it is then necessary to remove the homopolymer by such complicated operations as dissolution of the crude polymeric product following by formation and decomposition of a polyphenylene ether-methylene chloride complex. Thus, these materials are not readily adaptable to copolymer preparation on an industrial scale.

0010The present invention provides a simple method for introducing epoxy functionality into a polyphenylene ether, employing simple solution or interfacial conditions and relatively inexpensive reagents. The products are highly reactive and readily convertible under both solution and melt conditions to copolymers or polyphenylene ethers with a wide variety of strongly and weakly nucleophilic polymers, notably polyesters and polyamides. Such copolymers have excellent physical properties, particularly when blended with conventional impact modifiers for polyphenylene ethers. They also find potential use as compatibilizers for blends containing unfunctionalized polyphenylene ethers.

0011In one of its aspects, the invention includes epoxytriazine-capped polyphenylene ether compositions comprising polymer molecules having end groups of the formula <chemistry id="chem0001" num="0001"><img file="EP0347539A2_D0001.tif" /></chemistry> wherein: each Q¹ is independently halogen, primary or secondary lower alkyl (i.e., alkyl containing up to 7 carbon atoms), phenyl, haloalkyl, hydrocarbonoxy, or halohydrocarbonoxy wherein at least two carbon atoms sepa­rate the halogen and oxygen atoms; each Q² is independently hydrogen, halogen, primary or secondary lower alkyl, phenyl, haloalkyl, hydro­carbonoxy or halohydrocarbonoxy as defined for Q¹; X is an alkyl, cycloalkyl or aromatic radical or <chemistry id="chem0002" num="0002"><img file="EP0347539A2_D0002.tif" /></chemistry> R¹ is a divalent aliphatic alicyclic, hetero­cyclic or unsubstituted or substituted aromatic hydrocarbon radical.

0012The epoxytriazine-capped polyphenylene ethers of this invention may be prepared as described hereinafter from the polyphenylene ethers known in the art. The latter encompass numerous variations and modifications all of which are applicable to the present invention, including but not limited to those described hereinafter.

0013The polyphenylene ethers comprise a plurality of structural units having the formula <chemistry id="chem0003" num="0003"><img file="EP0347539A2_D0003.tif" /></chemistry> and in each of said units independently, each Q¹ and Q² is as previously defined. Examples of primary lower alkyl groups suitable as Q¹ and Q² are methyl, ethyl, n-propyl, n-butyl, isobutyl, n-amyl, isoamyl, 2-methylbutyl, n-hexyl, 2,3-dimethylbutyl, 2-, 3- or 4-methylpentyl and the corres­ponding heptyl groups. Examples of secondary lower alkyl groups are isopropyl, sec-butyl and 3-pentyl. Preferably, any alkyl radicals are straight chain rather than branched. More often, each Q¹ is alkyl or phenyl, especially C₁₋₄ alkyl, and each Q² is hydrogen. Suitable polyphenylene ethers are disclosed in a large number of patents.

0014Both homopolymer and copolymer polyphenylene ethers are included. Suitable homopolymers are those con­taining, for example, 2,6-dimethyl-1,4-phenylene ether units. Suitable copolymers include random copolymers con­taining such units in combination with (for example) 2,3,6-­trimethyl-1,4-phenylene ether units. Many suitable random copolymers, as well as homopolymers, are disclosed in the patent literature.

0015Also included are polyphenylene ethers containing moieties which modify properties such as molecular weight, melt viscosity and/or impact strength. Such polymers are described in the patent literature and may be prepared by grafting onto the polyphenylene ether in known manner such vinyl monomers as acrylonitrile and vinylaromatic compounds (e. g., styrene), or such polymers as polystyrenes and elastomers. The product typically contains both grafted and ungrafted moieties. Other suitable polymers are the coupled polyphenylene ethers in which the coupling agent is reacted in known manner with the hydroxy groups of two polyphenylene ether chains to produce a higher molecular weight polymer containing the reaction product of the hydroxy groups and the coupling agent, provided a substantial proportion of free hydroxy groups remain present. Illustrative coupling agents are low molecular weight polycarbonates, quinones, heterocycles and formals.

0016The polyphenylene ether generally has a number average molecular weight within the range of about 3,000-­40,000 and a weight average molecular weight within the range of about 20,000-80,000, as determined by gel permea­tion chromatography. Its intrinsic viscosity is most often in the range of about 0.35-0.6 dl./g., as measured in chloroform at 25°C.

0017The polyphenylene ethers are typically prepared by the oxidative coupling of at least one corresponding mono­hydroxyaromatic compound. Particularly useful and readily available monohydroxyaromatic compounds are 2,6-xylenol (wherein each Q¹ is methyl and each Q² is hydrogen), where­upon the polymer may be characterized as a poly(2,6-di­methyl-1,4-phenylene ether), and 2,3,6-trimethylphenol (wherein each Q¹ and one Q² is methyl and the other Q² is hydrogen).

0018A variety of catalyst systems are known for the preparation of polyphenylene ethers by oxidative coupling. There is no particular limitation as to catalyst choice and any of the known catalysts can be used. For the most part, they contain at least one heavy metal compound such as a copper, manganese or cobalt compound, usually in combination with various other materials.

0019A first class of preferred catalyst systems con­sists of those containing a copper compound. Such catalysts are disclosed, for example, in U.S. Patents 3,306,874, 3,306,875, 3,914,266 and 4,028,341. They are usually com­binations of cuprous or cupric ions, halide (i.e., chloride, bromide or iodide) ions and at least one amine.

0020Catalyst systems containing manganese compounds constitute a second preferred class. They are generally alkaline systems in which divalent manganese is combined with such anions as halide, alkoxide or phenoxide. Most often, the manganese is present as a complex with one or more complexing and/or chelating agents such as dialkyl­amines, alkanolamines, alkylenediamines, o-hydroxyaromatic aldehydes, o-hydroxyazo compounds, ω-hydroxyoximes (mono­meric and polymeric), o-hydroxyaryl oximes and β-diketones. Also useful are known cobalt-containing catalyst systems. Suitable manganese and cobalt-containing catalyst systems for polyphenylene ether preparation are known in the art by reason of disclosure in numerous patents and publications.

0021Particularly useful polyphenylene ethers for the purposes of this invention are those which comprise mole­cules having at least one of the end groups of the fomulas <chemistry id="chem0004" num="0004"><img file="EP0347539A2_D0004.tif" /></chemistry> wherein Q¹ and Q² are as previously defined; each R² is independently hydrogen or alkyl, with the proviso that the total number of carbon atoms in both R² radicals is 6 or less; and each R³ is independently hydrogen or a C₁₋₆ pri­mary aklyl radical. Preferably, each R² is hydrogen and each R³ is alkyl, especially methyl or n-butyl.

0022Polymers containing the aminoalkyl-substituted end groups of formula IV may be obtained by incorporating an appropriate primary or secondary monoamine as one of the constituents of the oxidative coupling reaction mixture, especially when a copper- or maganese-containing catalyst is used. Such amines, especially the dialkylamines and preferably di-n-butylamine and dimethylamine, frequently become chemically bound to the polyphenylene ether, most often by replacing one of the α-hydrogen atoms on one or more Q¹ radicals. The principal site of reaction is the Q¹ radical adjacent to the hydroxy group on the terminal unit of the polymer chain. During further processing and/or blending, the aminoalkyl-substituted end groups may undergo various reactions, probably involving a quinone methide-type intermediate of the formula <chemistry id="chem0005" num="0005"><img file="EP0347539A2_D0005.tif" /></chemistry> with numerous beneficial effects often including an increase in impact strength and compatibilization with other blend components. Reference is made to U.S. Patents 4,054,553, 4,092,294, 4,477,649, 4,477,651 and 4,517,341, the disclo­sures of which are incorporated by reference herein.

0023Polymers with 4-hydroxybiphenyl end groups of formula V are typically obtained from reaction mixtures in which a by-product diphenoquinone of the formula <chemistry id="chem0006" num="0006"><img file="EP0347539A2_D0006.tif" /></chemistry> is present, especially in a copper-halide-secondary or tertiary amine system. In this regard, the disclosure of U.S. Patent 4,477,649 is again pertinent as are those of U.S. 4,234,706 and 4,482,697, which are also incorporated by reference herein. In mixtures of this type, the dipheno­quinone is ultimately incorporated into the polymer in substantial proportions, largely as an end group.

0024In many polyphenylene ethers obtained under the above-described conditions, a substantial proportion of the polymer molecules, typically constituting as much as about 90% by weight of the polymer, contain end groups having one or frequently both of formulas IV and V. It should be understood, however, that other end groups may be present and that the invention in its broadest sense may not be dependent on the molecular structures of the polyphenylene ether end groups, provided a substantial proportion of free hydroxy groups is present.

0025The use of polyphenylene ethers containing sub­stantial amounts of unneutralized amino nitrogen generally affords compositions with undesirably low impact strengths. The possible reasons for this are explained hereinafter. The amino compounds include, in addition to the aforemen­tioned aminoalkyl end groups, traces of amine (particularly secondary amine) in the catalyst used to form the polypheny­lene ether.

0026The present invention therefore includes the use of polyphenylene ethers in which a substantial proportion of amino compounds has been removed or inactivated. Polymers so treated contain unneutralized amino nitrogen, if any, in amounts no greater than 800 ppm and more preferably in the range of about 100-800 ppm.

0027A preferred method of inactivation is by extrusion of the polyphenylene ether at a temperature within the range of about 230-390°C, with vacuum venting. This may be achieved either in a preliminary extrusion step (which is sometimes preferred) or during extrusion of the composition of this invention, by connecting the vent of the extruder to a vacuum pump capable of creating a pressure of about 200 torr or less.

0028It is believed that this inactivation method aids in the removal by evaporation of any traces of free amines (predominantly secondary amines) in the polymer, including amines generated by conversion of aminoalkyl end groups to quinone methides of one type represented by formula VI.

0029It will be apparent to those skilled in the art from the foregoing that the polyphenylene ethers contem­plated for use in the present invention include all those presently known, irrespective of variations in structural units or ancillary chemical features.

0030The end groups on the epoxytriazine-capped polyphenylene ethers of this invention have formula I, in which Q¹ and Q² are as previously defined. X may be an alkyl or cycloalkyl radical, typically lower alkyl and especially primary or secondary lower alkyl; an aromatic radical, typically monocyclic and containing 6-10 carbon atoms and especially an aromatic hydrocarbon radical; or a radical of formula II. In formulas I and II, R¹ may be aliphatic, alicyclic, aromatic (including aromatic radicals containing art-recognized substituents) or heterocyclic. It is usually lower alkylene and especially methylene.

0031Another aspect of the invention is a method for preparing the above-described epoxytriazine-capped polyphen­ylene ether compositions. Said method comprises contacting under reactive conditions, in the presence of a basic reagent, at least one polyphenylene ether with an epoxy­chlorotriazine of the formula <chemistry id="chem0007" num="0007"><img file="EP0347539A2_D0007.tif" /></chemistry> wherein R¹ and X are as previously defined.

0032Typical epoxychlorotriazines of formula VIII include 2-chloro-4,6-diglycidoxy-1,3,5-triazine, 2-chloro-­4-(n-butoxy)-6-glycidoxy-1,3,5-triazine and 2-chloro-4-­(2,4,6-trimethylphenoxy)-6-glycidoxy-1,3,5-triazine. These compounds may also be named as though derived from cyanuric acid and designated diglycidyl chlorocyanurate, n-butyl gly­cidyl chlorocyanurate and 2,4,6-trimethylphenyl glycidyl chlorocyanurate, respectively. For the sake of brevity they will sometimes be identified hereinafter as "DGCC", "BGCC" and "MGCC", respectively. They may be prepared, for example, by the reaction of 2,4,6-trichlorotriazine (cyan­uric chloride) with glycidol or combinations thereof with n-butanol or mesitol. Cyanuric chloride and n-butyl di­chlorocyanurate are both commercially available.

0033Intermediates such as DGCC, BGCC and MGCC and the method for their preparation are disclosed and claimed in copending, commonly owned application Serial No. 144,901, filed January 19, 1988. Their preparation is illustrated by the following examples.

Example 1

0034To a mechanically stirred solution of 220.8 g. (1.2 moles) cyanuric chloride in 1500 ml. chloroform, cooled to 0-10°C, was added 266.4 g. (3.6 moles) glycidol in one portion. Aqueous sodium hydroxide (50% solution; 192 g.) was added to the mixture dropwise with stirring over about 3 hours maintaining the reaction temperature below 10°C and preferably around 0-5°C. The reaction mixture was allowed to warm slowly to room temperature. The chloroform layer was washed with distilled water until neutral and dried over magnesium sulfate. The reaction product was found by proton nuclear magnetic resonance to be 2-chloro-4,6-diglycidoxy-­1,3,5-triazine (DGCC). Analysis by liquid chromatography showed about 95% (by weight) chlorodiglycidoxytriazine. The reaction mixture also was found to contain small amounts of triglycidoxytriazine and dichloroglycidoxytriazine.

Example 2

0035To a magnetically stirred solution of 250 g. (1.125 moles) n-butyl dichlorocyanurate in 757 ml. chloro­form, cooled to 0-10°C, was added 250 g. (3.375 moles) glycidol in one portion. Aqueous sodium hydroxide (50% solution; 90 g. ) was added to the mixture dropwise with stirring over about 2 hours maintaining the reaction tem­perature below 10°C and preferably around 0-5°C. The reaction mixture was allowed to warm to room temperature over 30 minutes. The chloroform layer was washed with distilled water until neutral and dried over magnesium sulfate. Proton nuclear magnetic resonance analysis indi­cated a 95% yield of 2-chloro-4-(n-butoxy)-6-glycidoxy-­1,3,5-triazine (BGCC).

Example 3

0036To a mechanically stirred solution of 50 g. (0.175 mole) 2,4,6-trimethylphenyl dichlorocyanurate (prepared by the reaction of equimolar amounts of mesitol and cyanuric chloride) in 170 ml. methylene chloride, cooled to 0-10°C, was added 26.38 g. (0.356 mole) glycidol in one portion. Aqueous sodium hydroxide (50% solution; 14.26 g.) was added to the mixture dropwise with stirring over about 25 minutes maintaining the reaction temperature between 0° and 10°C and preferably around 0-5°C. After stirring an additional 30 minutes, the reaction mixture was allowed to warm to room temperature. The methylene chloride layer was washed with distilled water until neutral and dried over magnesium sulfate. The reaction product was found by proton nuclear magnetic resonance to be 2-chloro-4-(2,4,6-trimethyl­phenoxy)-6-glycidoxy-1,3,5-triazine (MGCC).

0037Various options are available for the reaction of the polyphenylene ether with the epoxychlorotriazine. In one embodiment, the reaction is conducted in solution in a non-polar organic liquid, typically at a temperature in the range of about 80-150°C and preferably about 100-125°C. The basic reagent employed in this embodiment should be soluble in the organic liquid and is generally a tertiary amine. Its identity is not otherwise critical, provided it is sufficiently non-volatile to remain in the reaction mixture at the temperatures employed. Pyridine is often preferred.

0038The amount of epoxychlorotriazine employed in this embodiment is generally in the range of about 1-20% by weight, based on polyphenylene ether. The amount of basic reagent is an effective amount to promote the reaction; in general, about 1.0-1.1 equivalent thereof per mole of chloroepoxytriazine is adequate.

0039The epoxytriazine-capped polyphenylene ethers made in solution by the above-described process are generally found to contain rather high proportions (e.g., at least about 0.47% by weight) of chemically combined chlorine, principally covalently bound. It is believed that the covalently bound chlorine is the result of epoxy groups competing with the organic base as a hyrogen chloride acceptor, with the formation of chlorohydrin moieties. This may be followed by condensation of said chlorohydrin moie­ties with additional epoxy groups to produce such molecular species as polyphenylene ether-epoxytriazine block copolymers and homopolymeric epoxytriazine oligomers. By reason of the presence of such species, the compositions of this invention are also advantageously defined in terms of the method for their preparation.

0040Upon molding, compositions containing polypheny­lene ether copolymers prepared from products containing such species form articles which are ductile but have impact strengths somewhat lower than desired under certain con­ditions. This is particularly true of copolymers with polyesters.

0041A second, preferred embodiment of the method of this invention produces epoxytriazine-capped polyphenylene ethers with little or no covalently bound chlorine. In this method, the reaction is conducted interfacially in a medium comprising water and an organic liquid as previously de­scribed. The basic reagent is a water-soluble base, typi­cally an alkali metal hydroxide and preferably sodium hydroxide. There is also employed a phase transfer cata­lyst. Any of such catalysts which are stable and effective under the prevailing reaction conditions may be used; those skilled in the art will readily perceive which ones are suitable. Particularly preferred are the tetraalkylammonium chlorides wherein at least two alkyl groups per molecule, typically 2 or 3, contain about 5-15 carbon atoms.

0042In this embodiment, reaction temperatures in the range of about 20-70°C may be employed. The amount of epoxytriazine is frequently lower than in the previously described embodiment, typically in the range of about 1-5% and preferably about 2-5% by weight based on polyphenylene ether, since the reaction of the epoxychlorotriazine with the polyphenylene ether apparently proceeds more nearly to completion. Most often, the ratio of equivalents of base to moles of epoxychlorotriazine is about 1.0-1.5:1, and the weight ratio of phase transfer catalyst to base is about 0.1-0.3:1.

0043Still another embodiment utilizes an organic liquid and a solid base, typically a solid alkali metal hydroxide or an anion exchange resin in the free base form. Chloride salts may be removed by methods known in the art, including water washing when a hydroxide is employed and filtration when an anion exchange resin is employed.

0044Regardless of which method of preparation is used, the epoxytriazine-capped polyphenylene ether may be isolated by conventional methods, typically by precipitation with a non-solvent. Among the non-solvents which may be employed are methanol, 2-propanol, acetone, acetonitrile and mixtures thereof.

0045When the non-solvent is an alcohol, and especially methanol, it may undergo base-promoted reaction with the epoxytriazine moieties on the capped polyphenylene ether, usually resulting in a loss of epoxide groups. Either or both of two operations may be employed to suppress this reaction. The first is to neutralize the reaction mixture with any convenient acidic compound; carbon dioxide, in gaseous, liquid or solid form, is often preferred. The second is to remove alcohol from contact with the product as rapidly and completely as possible by conventional means, typically including a subsequent drying step.

0046In the following examples which illustrate the preparation of the epoxytriazine-capped polyphenylene ethers of this invention, all parts and percentages are by weight unless otherwise indicated. Proportions of epoxychlorotri­azine are expressed as a percentage of polyphenylene ether. The following polyphenylene ethers were employed: PPE - a poly(2,6-dimethyl-1,4-phenylene ether) having an intrinsic viscosity in chloroform at 25°C of 0.40 dl./g. VV - PPE which has been extruded on a twin screw extruder within the temperature range of about 260-320°C, with vacuum venting to a maximum pressure of about 20 torr. LN - a poly(2,6-dimethyl-1,4-phenylene ether) having an intrinsic viscosity of 0.57 dl./g., having a low proportion of nitrogen as a result of preparation with a catalyst containing no primary or secondary amine. Percentages of epoxytriazine in the capped polymer were determined from the relative areas of peaks in the nuclear magnetic resonance spectrum attributable to hydrogen atoms in the epoxy and aromatic moieties. Chlorine percentages were determined by quantitative X-ray fluorescence.

Examples 4-14

0047To solutions of 400 grams of polyphenylene ether in 2500 ml. of toluene were added, with stirring, various quantities of pyridine followed by various quantities of epoxychlorotriazines, added in portions. The ratio of equivalents of pyridine to moles of epoxychlorotriazine was 1.04:1. The solutions were heated under reflux for various periods of time, after which the products were precipitated with methanol in a blender, filtered, washed with methanol and vacuum dried. The relevant parameters and analytical results are given in Table I. <tables id="tabl0001" num="0001"><table frame="all"><title>TABLE I</title><tgroup cols="7" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="22.50mm" /><colspec colnum="2" colname="col2" colwidth="22.50mm" /><colspec colnum="3" colname="col3" colwidth="22.50mm" /><colspec colnum="4" colname="col4" colwidth="22.50mm" /><colspec colnum="5" colname="col5" colwidth="22.50mm" /><colspec colnum="6" colname="col6" colwidth="22.50mm" /><colspec colnum="7" colname="col7" colwidth="22.50mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" align="center">Example</entry><entry namest="col2" nameend="col2" align="center">Polyphenylene ether</entry><entry namest="col3" nameend="col4" align="center">Epoxychlorotriazine</entry><entry namest="col5" nameend="col5" align="center">Reaction time, hrs.</entry><entry namest="col6" nameend="col6" align="center">% epoxytriazine</entry><entry namest="col7" nameend="col7" align="center">% chlorine</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" align="center">Identity</entry><entry namest="col4" nameend="col4" align="center">%</entry><entry namest="col5" nameend="col5" /><entry namest="col6" nameend="col6" /><entry namest="col7" nameend="col7" /></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="right">4</entry><entry namest="col2" nameend="col2" align="left">PPE</entry><entry namest="col3" nameend="col3" align="left">DGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">5</entry><entry namest="col5" nameend="col5" align="char" char=".">2</entry><entry namest="col6" nameend="col6" align="char" char=".">0.52</entry><entry namest="col7" nameend="col7" align="right">---</entry></row><row><entry namest="col1" nameend="col1" align="right">5</entry><entry namest="col2" nameend="col2" align="left">PPE</entry><entry namest="col3" nameend="col3" align="left">DGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">5</entry><entry namest="col5" nameend="col5" align="char" char=".">3</entry><entry namest="col6" nameend="col6" align="char" char=".">0.62</entry><entry namest="col7" nameend="col7" align="right">---</entry></row><row><entry namest="col1" nameend="col1" align="right">6</entry><entry namest="col2" nameend="col2" align="left">VV</entry><entry namest="col3" nameend="col3" align="left">DGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">5</entry><entry namest="col5" nameend="col5" align="char" char=".">1</entry><entry namest="col6" nameend="col6" align="char" char=".">0.43</entry><entry namest="col7" nameend="col7" align="right">0.42</entry></row><row><entry namest="col1" nameend="col1" align="right">7</entry><entry namest="col2" nameend="col2" align="left">VV</entry><entry namest="col3" nameend="col3" align="left">DGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">5</entry><entry namest="col5" nameend="col5" align="char" char=".">2</entry><entry namest="col6" nameend="col6" align="char" char=".">0.65</entry><entry namest="col7" nameend="col7" align="right">---</entry></row><row><entry namest="col1" nameend="col1" align="right">8</entry><entry namest="col2" nameend="col2" align="left">VV</entry><entry namest="col3" nameend="col3" align="left">DGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">5</entry><entry namest="col5" nameend="col5" align="char" char=".">3</entry><entry namest="col6" nameend="col6" align="char" char=".">0.63</entry><entry namest="col7" nameend="col7" align="right">0.47</entry></row><row><entry namest="col1" nameend="col1" align="right">9</entry><entry namest="col2" nameend="col2" align="left">VV</entry><entry namest="col3" nameend="col3" align="left">DGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">2.5</entry><entry namest="col5" nameend="col5" align="char" char=".">3.5</entry><entry namest="col6" nameend="col6" align="char" char=".">0.24</entry><entry namest="col7" nameend="col7" align="right">---</entry></row><row><entry namest="col1" nameend="col1" align="right">10</entry><entry namest="col2" nameend="col2" align="left">VV</entry><entry namest="col3" nameend="col3" align="left">DGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">15</entry><entry namest="col5" nameend="col5" align="char" char=".">3</entry><entry namest="col6" nameend="col6" align="char" char=".">2.1</entry><entry namest="col7" nameend="col7" align="right">1.8</entry></row><row><entry namest="col1" nameend="col1" align="right">11</entry><entry namest="col2" nameend="col2" align="left">VV</entry><entry namest="col3" nameend="col3" align="left">DGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">15</entry><entry namest="col5" nameend="col5" align="char" char=".">3</entry><entry namest="col6" nameend="col6" align="char" char=".">1.9</entry><entry namest="col7" nameend="col7" align="right">---</entry></row><row><entry namest="col1" nameend="col1" align="right">12</entry><entry namest="col2" nameend="col2" align="left">VV</entry><entry namest="col3" nameend="col3" align="left">BGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">5</entry><entry namest="col5" nameend="col5" align="char" char=".">3</entry><entry namest="col6" nameend="col6" align="char" char=".">0.50</entry><entry namest="col7" nameend="col7" align="right">---</entry></row><row><entry namest="col1" nameend="col1" align="right">13</entry><entry namest="col2" nameend="col2" align="left">VV</entry><entry namest="col3" nameend="col3" align="left">BGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">5</entry><entry namest="col5" nameend="col5" align="char" char=".">3</entry><entry namest="col6" nameend="col6" align="char" char=".">0.40</entry><entry namest="col7" nameend="col7" align="right">---</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="right">14</entry><entry namest="col2" nameend="col2" align="left">VV</entry><entry namest="col3" nameend="col3" align="left">BGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">15</entry><entry namest="col5" nameend="col5" align="char" char=".">3</entry><entry namest="col6" nameend="col6" align="char" char=".">1.79</entry><entry namest="col7" nameend="col7" align="right">---</entry></row></tbody></tgroup></table></tables>

Examples 15-25

0048To solutions of 400 grams of polyphenylene ether in 2500 ml. of toluene were added various quantities of epoxychlorotriazines dissolved in a small amount of methy­lene chloride. There were then added 48 grams of a 10% solution in toluene of a commercially available methyl­trialkylammonium chloride in which the alkyl groups con­tained 8-10 carbon atoms, and 10% aqueous sodium hydroxide solution in the amount of 1.3 equivalents of sodium hydrox­ide per mole of epoxychlorotriazine. The mixtures were stirred vigorously for various periods at 25-40°C, after which the products were precipitated with methanol in a blender and rapidly filtered, washed with methanol and vacuum dried.

0049The results are given in Table II. Chlorine proportions were less than 200 ppm., the minimum detectable by quantitative X-ray fluorescence. <tables id="tabl0002" num="0002"><table frame="all"><title>TABLE II</title><tgroup cols="6" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26.25mm" /><colspec colnum="2" colname="col2" colwidth="26.25mm" /><colspec colnum="3" colname="col3" colwidth="26.25mm" /><colspec colnum="4" colname="col4" colwidth="26.25mm" /><colspec colnum="5" colname="col5" colwidth="26.25mm" /><colspec colnum="6" colname="col6" colwidth="26.25mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" align="center">Example</entry><entry namest="col2" nameend="col2" align="center">Polyphenylene ether</entry><entry namest="col3" nameend="col4" align="center">Epoxychlorotriazine</entry><entry namest="col5" nameend="col5" align="center">Reaction time. min,</entry><entry namest="col6" nameend="col6" align="center">% epoxytriazine</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" align="center">Identity</entry><entry namest="col4" nameend="col4" align="center">%</entry><entry namest="col5" nameend="col5" /><entry namest="col6" nameend="col6" /></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="right">15</entry><entry namest="col2" nameend="col2" align="left">PPE</entry><entry namest="col3" nameend="col3" align="left">DGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">1.5</entry><entry namest="col5" nameend="col5" align="right">30</entry><entry namest="col6" nameend="col6" align="char" char=".">0.52</entry></row><row><entry namest="col1" nameend="col1" align="right">16</entry><entry namest="col2" nameend="col2" align="left">PPE</entry><entry namest="col3" nameend="col3" align="left">DGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">2.0</entry><entry namest="col5" nameend="col5" align="right">30</entry><entry namest="col6" nameend="col6" align="char" char=".">1.03</entry></row><row><entry namest="col1" nameend="col1" align="right">17</entry><entry namest="col2" nameend="col2" align="left">PPE</entry><entry namest="col3" nameend="col3" align="left">DGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">2.5</entry><entry namest="col5" nameend="col5" align="right">30</entry><entry namest="col6" nameend="col6" align="char" char=".">0.95</entry></row><row><entry namest="col1" nameend="col1" align="right">18</entry><entry namest="col2" nameend="col2" align="left">PPE</entry><entry namest="col3" nameend="col3" align="left">DGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">3.0</entry><entry namest="col5" nameend="col5" align="right">30</entry><entry namest="col6" nameend="col6" align="char" char=".">0.96</entry></row><row><entry namest="col1" nameend="col1" align="right">19</entry><entry namest="col2" nameend="col2" align="left">PPE*</entry><entry namest="col3" nameend="col3" align="left">DGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">3.0</entry><entry namest="col5" nameend="col5" align="right">30</entry><entry namest="col6" nameend="col6" align="char" char=".">1.01</entry></row><row><entry namest="col1" nameend="col1" align="right">20**</entry><entry namest="col2" nameend="col2" align="left">PPE</entry><entry namest="col3" nameend="col3" align="left">DGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">3.0</entry><entry namest="col5" nameend="col5" align="right">30</entry><entry namest="col6" nameend="col6" align="char" char=".">1.24</entry></row><row><entry namest="col1" nameend="col1" align="right">21</entry><entry namest="col2" nameend="col2" align="left">LN</entry><entry namest="col3" nameend="col3" align="left">DGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">3.0</entry><entry namest="col5" nameend="col5" align="right">30</entry><entry namest="col6" nameend="col6" align="char" char=".">0.48</entry></row><row><entry namest="col1" nameend="col1" align="right">22</entry><entry namest="col2" nameend="col2" align="left">PPE</entry><entry namest="col3" nameend="col3" align="left">DGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">5.0</entry><entry namest="col5" nameend="col5" align="right">30</entry><entry namest="col6" nameend="col6" align="char" char=".">1.40</entry></row><row><entry namest="col1" nameend="col1" align="right">23</entry><entry namest="col2" nameend="col2" align="left">VV</entry><entry namest="col3" nameend="col3" align="left">DGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">5.0</entry><entry namest="col5" nameend="col5" align="right">10</entry><entry namest="col6" nameend="col6" align="char" char=".">0.68</entry></row><row><entry namest="col1" nameend="col1" align="right">24</entry><entry namest="col2" nameend="col2" align="left">PPE</entry><entry namest="col3" nameend="col3" align="left">BGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">3.0</entry><entry namest="col5" nameend="col5" align="right">30</entry><entry namest="col6" nameend="col6" align="char" char=".">1.25</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="right">25</entry><entry namest="col2" nameend="col2" align="left">PPE</entry><entry namest="col3" nameend="col3" align="left">MGCC</entry><entry namest="col4" nameend="col4" align="char" char=".">3.0</entry><entry namest="col5" nameend="col5" align="right">30</entry><entry namest="col6" nameend="col6" align="char" char=".">1.50***</entry></row></tbody></tgroup><tgroup cols="6" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="26.25mm" /><colspec colnum="2" colname="col2" colwidth="26.25mm" /><colspec colnum="3" colname="col3" colwidth="26.25mm" /><colspec colnum="4" colname="col4" colwidth="26.25mm" /><colspec colnum="5" colname="col5" colwidth="26.25mm" /><colspec colnum="6" colname="col6" colwidth="26.25mm" /><tbody valign="top"><row><entry namest="col1" nameend="col6" align="justify">*16% slurry of crude PPE in toluene.</entry></row><row><entry namest="col1" nameend="col6" align="justify">**Reaction mixture neutralized with gaseous carbon dioxide.</entry></row><row><entry namest="col1" nameend="col6" align="justify">***Average of 3 runs.</entry></row></tbody></tgroup></table></tables>

0050The epoxytriazine-capped polyphenylene ethers of this invention react with other polymers containing nucleo­philic groups, typically amine, isocyanate, hydroxy or thiol groups or carboxy groups or functional derivatives thereof, to form copolymers. Said copolymers may be molded into articles having high impact strengths and other excellent physical properties. They are also useful for compatibil­izing polymer blends to form molding compositions having similar excellent properties. Compositions comprising copolymers of said epoxytriazine-capped polyphenylene ethers with polyesters, polyamides and functionalized polyolefins are disclosed and claimed in copending, commonly owned application Serial No. [RD-18777], Serial No. [RD-18710] and Serial No. [RD-      ], respectively.

0051Polyesters suitable for preparing polyphenylene ether-polyester copolymer compositions include thermoplastic polyesters illustrated by poly(alkylene dicarboxylates), elastomeric polyesters, polyarylates, and polyester co­polymers such as copolyestercarbonates. Because the prin­cipal reaction which occurs with the epoxy groups in the capped polyphenylene ether involves a carboxylic acid group of the polyester, it is highly preferred that said polyester have a relatively high carboxylic end group concentration. Concentrations in the range of about 5-250 microequivalents per gram are generally suitable, with 10-100 microequiva­lents per gram being preferable, 30-100 being more prefer­able and 40-80 being particularly desirable.

0052The polyester typically comprises structural units of the formula <chemistry id="chem0008" num="0008"><img file="EP0347539A2_D0008.tif" /></chemistry> optionally in combination with units of the formula <chemistry id="chem0009" num="0009"><img file="EP0347539A2_D0009.tif" /></chemistry> wherein each R⁴ is independently a divalent aliphatic, alicyclic or aromatic hydrocarbon radical or polyoxyalkylene radical; R⁵ is a polyoxyalkylene radical; A¹ is a divalent aromatic radical; and A² is a trivalent aromatic radical. The A¹ radical is most often p- or m-phenylene or a mixture thereof, and A² is usually derived from trimellitic acid.

0053The R⁴ radical may be, for example, a C₂₋₁₀ alkylene radical, a C₆₋₁₀ alicyclic radical, a C₆₋₂₀ aromat­ic radical or a polyoxyalkylene radical in which the alky­lene groups contain about 2-6 carbon atoms. As previously noted, this class of polyesters includes the poly(alkylene terephthalates) and the polyarylates. Poly(alkylene tere­phthalates) are frequently preferred, with poly(ethylene terephthalate) and poly(butylene terephthalate) being most preferred.

0054The polyester generally has a number average molecular weight in the range of about 20,000-70,000, as determined by intrinsic viscosity (IV) at 30°C in a mixture of 60% (by weight) phenol and 40% 1,1,2,2-tetrachloroethane.

0055Either solution or melt blending procedures may be employed for the preparation of polyphenylene ether-polyes­ter copolymers. Typical reaction temperatures are in the range of about 175-350°C. Thus, relatively high boiling solvents such as o-dichlorobenzene or 1,2,4-trichlorobenzene are preferred for solution reactions.

0056Melt reaction procedures are frequently preferred because of the availability of melt blending equipment in commercial polymer processing facilities. Conventional equipment of this type is suitable, with the use of ex­trusion equipment generally being convenient and therefore often preferred.

0057The principal reaction which takes place between the epoxytriazine-capped polyphenylene ether and the poly­ester generally involves the carboxylic acid end groups of the latter, which open the epoxide rings to form hydroxy ester groups. Thus, the polyphenylene ether-polyester copolymers preferably comprise molecules containing at least one polyphenylene ether-polyester linkage of the formula <chemistry id="chem0010" num="0010"><img file="EP0347539A2_D0010.tif" /></chemistry> wherein Q¹, Q² and R¹ are as previously defined; Z¹ is an alkyl, cycloalkyl or aromatic radical (most often lower alkyl or aromatic hydrocarbon or <chemistry id="chem0011" num="0011"><img file="EP0347539A2_D0011.tif" /></chemistry> and Z² is OH and Z³ is -O-<img file="EP0347539A2_D0012.tif" />-, or Z² is -O-<img file="EP0347539A2_D0013.tif" /> and Z³ is OH.

0058Another possible reaction is between hydroxy end groups of the polyester and the epoxy groups of the capped polyphenylene ether. Thus, the compositions of the inven­tion are not limited to compounds containing linkages of formula XI but may include compounds with linkages of similar structures containing ether moieties replacing the carboxylate moieties of Z² or Z³.

0059The proportions of polyphenylene ether and poly­ester are not critical; they may be widely varied to provide compositions having the desired properties. Most often, each polymer is employed in an amount in the range of about 5-95%, preferably about 30-70%, of the composition by weight.

0060For the most part, the polyphenylene ether-poly­ester compositions contain various proportions of poly­phenylene ether and polyester homopolymers in addition to copolymer. This may be in the result of incorporation of excess polyester or unfunctionalized polyphenylene ether therein, incomplete capping of the polyphenylene ether, or incomplete reaction of capped polyphenylene ether with polyester. In any event, molded parts produced from said compositions are generally ductile and have higher impact strengths than those produced from simple polyphenylene ether-polyester blends, which are incompatible and often exhibit delamination as previously described.

0061Experimental data suggest that certain other factors are of importance in preparing compositions of maximum impact strength. One of these is the proportion of chlorine in the epoxytriazine-capped polyphenylene ether. Compositions prepared from high chlorine capped polypheny­lene ethers, obtained by the solution method previously described, often have lower impact strengths than those prepared from the low chlorine materials obtained by the interfacial method.

0062Another factor is the proportion of unneutralized amino nitrogen in the polyphenylene ether. High proportions may cause side reactions, including opening of epoxide rings, displacement of epoxide groups from the cyanurate moiety and cleavage of ester linkages. Such side reactions can be minimized by vacuum venting the polyphenylene ether as previously described.

0063A third factor is the molecular structure of the polyphenylene ether-polyester copolymer, which may vary with the molecular structure of the capping agent used (BGCC or MGCC as contrasted with DGCC) and its proportion (leading to capping of one or both ends of polyphenylene ether). Thus, the following copolymer gross structures can be envisioned, where PPE and PE represent the polyphenylene ether and polyester, respectively: <chemistry id="chem0012" num="0012"><img file="EP0347539A2_D0014.tif" /></chemistry>

0064The structure represented by formula XV is theoretically obtainable, for example, by capping a polyphenylene ether having hydroxy groups at both ends of the polymer chain with at least the stoichiometrically equivalent amount of (for example) DGCC. Thus, a polyphenylene ether of number average molecular weight about 20,000 containing at least about 1.9% (by weight) epoxytriazine can be expected to yield copolymers of formula XV. They have diminished physical properties in comparison with those represented by structures XII-XIV, perhaps because the PPE portion of the molecule is eclipsed by the PE portion and is therefore less available to compatibilize a polyphenylene ether-polyester blend.

0065It also appears that compositions containing "high chlorine" capped polyphenylene ethers have a greater tenden­cy towards ductility and high impact strength when a poly­phenylene ether containing a low proportion of unneutralized amino nitrogen is employed, while the opposite is true for "low chlorine" materials. The reason for this is not presently understood.

0066The polyphenylene ether-polyester compositions may contain other constituents in addition to the polyphenylene ether, polyester and copolymer. Examples are elastomeric impact modifiers compatible with either or both of the polyphenylene ether and the polyester.

0067Suitable impact modifiers include various elasto­meric copolymers, of which examples are ethylene-propylene-­diene polymers (EPDM's), both unfunctionalized and function­alized with (for example) sulfonate or phosphonate groups; carboxylated ethylene-propylene rubbers; polymerized cyclo­alkenes; block copolymers of alkenylaromatic compounds such as styrene with polymerizable olefins or dienes, including butadiene, isoprene, chloroprene, ethylene, propylene and butylene; and core-shell elastomers, including those con­taining a poly(alkyl acrylate) core attached to a polysty­rene shell via an interpenetrating network and more fully disclosed in U.S. Patent 4,681,915.

0068The preferred impact modifiers are block (typical­ly diblock, triblock or radial teleblock) copolymers of alkenylaromatic compounds and dienes. Most often, at least one block is derived from styrene and at least one other block from at least one of butadiene and isoprene. Espe­cially preferred are the triblock copolymers with polysty­rene end blocks and diene-derived midblocks. It is fre­quently advantageous to remove (preferably) or decrease the aliphatic unsaturation therein by selective hydrogenation. The weight average molecular weights of the impact modifiers are typically in the range of about 50,000-300,000. Block copolymers of this type are commercially available from Shell Chemical Company under the trademark KRATON, and include KRATON D1101, G1650, G1651, G1652, G1657 and G1702.

0069The presence of such polymers as polycarbonates, copolyestercarbonates or polyarylates may have the effect of improving the impact strengths of molded articles under severe molding conditions, such as high molding temperatures and/or prolonged molding cycle times. The same purpose is frequently served by incorporating at least one compound containing a plurality of epoxide moieties (hereinafter "polyepoxide"), generally in the amount of about 0.1-3.0 and preferably about 0.25-3.0% of the composition. Illustrative compounds of this type are homopolymers of such compounds as glycidyl acrylate and glycidyl methacrylate, as well as copolymers thereof, preferred comonomers being lower alkyl acrylates, methyl methacrylate, acrylonitrile and styrene. Also useful are epoxy-substituted cyanurates and isocyanur­ates such as triglycidyl isocyanurate.

0070The polyepoxide may be introduced by blending with the other components in a single operation. However, its effectiveness may be maximized by preblending with the polyester, typically by dry mixing followed by extrusion. Such preblending frequently increases the impact strength of the composition. While the reason for the effectiveness of the polyepoxide is not entirely understood, it is believed to increase molecular weight, melt viscosity and degree of branching of the polyester by reaction with carboxylic acid end groups of a portion of the polyester molecules.

0071Finally, there may be present conventional ingre­dients such as fillers, flame retardants, pigments, dyes, stabilizers, anti-static agents, crystallization aids, mold release agents and the like, as well as resinous components not previously discussed.

0072In the following examples illustrating the pre­paration and properties of polyphenylene ether-polyester copolymer compositions, the polyesters and impact modifiers employed are identified as follows: PET - various poly(ethylene terephthalates). PBT - poly(butylene terephthalate) having a number average molecular weight of about 50,000, as determined by gel permeation chromatography. PATME - a commercially available elastomeric polyterephthalate from a mixture of tetramethylene glycol, hexamethylene glycol and poly(tetramethy­lene ether) glycol. PTME(50,000) and PTME(54,000) - commercially available elastomeric polyterephthalates from mixtures of tetramethylene glycol and poly(tetra­methylene ether) glycol, having the designated number average molecular weights and about 20% and 50% by weight, respectively, of poly(tetramethy­lene ether) glycol units. PIE - a copolyester prepared from 1,4-butanediol and a 0.91:1 (by weight) mixture of dimethyl terephthalate and the diimide-diacid reaction product of trimellitic acid and a polyoxypropyl­enediamine having an average molecular weight of about 2000. SEBS - a commercially available triblock copolymer with polystyrene end blocks having weight average molecular weights of 29,000 and a hydrogenated butadiene midblock having a weight average molec­ular weight of 116,000. CS - a core-shell material containing 75% of a crosslinked poly(butylacrylate) core and 25% of a crosslinked polystyrene shell, prepared in accord­ance with U.S. Patent 4,684,696. PO - a polyoctenylene with a cis-trans ratio of 20:80, having a weight average molecular weight of about 55,000.

0073The resinous blends described were prepared by dry mixing and extruded on a twin-screw extruder at 400 rpm. and 190-255°C. The extrudates were quenched in water, pelle­tized, oven dried and molded at 280°C into test specimens which were tested for notched Izod impact strength and tensile properties (ASTM procedures D256 and D638, respec­tively) and heat distortion temperature at 0.455 MPa. (ASTM procedure D648).

0074All parts and percentages in the following exam­ples are by weight. The proportion of bound polyphenylene ether, where listed, was determined by extracting uncopoly­merized polyphenylene ether with toluene and determining the proportion of polyphenylene ether in the residue by nuclear magnetic resonance spectroscopy; it is a general indication of the amount of copolymer in the composition.

Examples 26-35

0075Compositions containing various proportions of epoxytriazine-capped polyphenylene ethers prepared as described in Examples 4-14, various polyesters and SEBS were prepared and molded. The relevant parameters and test results are given in Table III. <tables id="tabl0003" num="0003"><table frame="all"><title>TABLE III</title><tgroup cols="11" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="14.31mm" /><colspec colnum="2" colname="col2" colwidth="14.31mm" /><colspec colnum="3" colname="col3" colwidth="14.31mm" /><colspec colnum="4" colname="col4" colwidth="14.31mm" /><colspec colnum="5" colname="col5" colwidth="14.31mm" /><colspec colnum="6" colname="col6" colwidth="14.31mm" /><colspec colnum="7" colname="col7" colwidth="14.31mm" /><colspec colnum="8" colname="col8" colwidth="14.31mm" /><colspec colnum="9" colname="col9" colwidth="14.31mm" /><colspec colnum="10" colname="col10" colwidth="14.31mm" /><colspec colnum="11" colname="col11" colwidth="14.31mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col11" align="center">Example</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" align="center">26</entry><entry namest="col3" nameend="col3" align="center">27</entry><entry namest="col4" nameend="col4" align="center">28</entry><entry namest="col5" nameend="col5" align="center">29</entry><entry namest="col6" nameend="col6" align="center">30</entry><entry namest="col7" nameend="col7" align="center">31</entry><entry namest="col8" nameend="col8" align="center">32</entry><entry namest="col9" nameend="col9" align="center">33</entry><entry namest="col10" nameend="col10" align="center">34</entry><entry namest="col11" nameend="col11" align="center">35</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Capping agent:</entry><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" /><entry namest="col4" nameend="col4" /><entry namest="col5" nameend="col5" /><entry namest="col6" nameend="col6" /><entry namest="col7" nameend="col7" /><entry namest="col8" nameend="col8" /><entry namest="col9" nameend="col9" /><entry namest="col10" nameend="col10" /><entry namest="col11" nameend="col11" /></row><row><entry namest="col1" nameend="col1" align="left">Identity</entry><entry namest="col2" nameend="col2" align="right">DGCC</entry><entry namest="col3" nameend="col3" align="right">DGCC</entry><entry namest="col4" nameend="col4" align="right">DGCC</entry><entry namest="col5" nameend="col5" align="right">DGCC</entry><entry namest="col6" nameend="col6" align="right">DGCC</entry><entry namest="col7" nameend="col7" align="right">DGCC</entry><entry namest="col8" nameend="col8" align="right">DGCC</entry><entry namest="col9" nameend="col9" align="right">BGCC</entry><entry namest="col10" nameend="col10" align="right">BGCC</entry><entry namest="col11" nameend="col11" align="right">BGCC</entry></row><row><entry namest="col1" nameend="col1" align="left">Percent</entry><entry namest="col2" nameend="col2" align="right">5</entry><entry namest="col3" nameend="col3" align="right">5</entry><entry namest="col4" nameend="col4" align="right">5</entry><entry namest="col5" nameend="col5" align="right">5</entry><entry namest="col6" nameend="col6" align="right">5</entry><entry namest="col7" nameend="col7" align="right">5</entry><entry namest="col8" nameend="col8" align="right">5</entry><entry namest="col9" nameend="col9" align="right">5</entry><entry namest="col10" nameend="col10" align="right">5</entry><entry namest="col11" nameend="col11" align="right">15</entry></row><row><entry namest="col1" nameend="col1" align="left">Capped polyphenylene ether:</entry><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" /><entry namest="col4" nameend="col4" /><entry namest="col5" nameend="col5" /><entry namest="col6" nameend="col6" /><entry namest="col7" nameend="col7" /><entry namest="col8" nameend="col8" /><entry namest="col9" nameend="col9" /><entry namest="col10" nameend="col10" /><entry namest="col11" nameend="col11" /></row><row><entry namest="col1" nameend="col1" align="left">Polyphenylene ether reactant</entry><entry namest="col2" nameend="col2" align="right">VV</entry><entry namest="col3" nameend="col3" align="right">VV</entry><entry namest="col4" nameend="col4" align="right">VV</entry><entry namest="col5" nameend="col5" align="right">VV</entry><entry namest="col6" nameend="col6" align="right">VV</entry><entry namest="col7" nameend="col7" align="right">VV</entry><entry namest="col8" nameend="col8" align="right">VV</entry><entry namest="col9" nameend="col9" align="right">VV</entry><entry namest="col10" nameend="col10" align="right">VV</entry><entry namest="col11" nameend="col11" align="right">PPE</entry></row><row><entry namest="col1" nameend="col1" align="left">Percent epoxytriazine</entry><entry namest="col2" nameend="col2" align="right">0.43</entry><entry namest="col3" nameend="col3" align="right">0.67</entry><entry namest="col4" nameend="col4" align="right">0.69</entry><entry namest="col5" nameend="col5" align="right">0.75</entry><entry namest="col6" nameend="col6" align="right">0.84</entry><entry namest="col7" nameend="col7" align="right">0.84</entry><entry namest="col8" nameend="col8" align="right">0.75</entry><entry namest="col9" nameend="col9" align="right">0.50</entry><entry namest="col10" nameend="col10" align="right">0.50</entry><entry namest="col11" nameend="col11" align="right">1.79</entry></row><row><entry namest="col1" nameend="col1" align="left">Parts</entry><entry namest="col2" nameend="col2" align="right">36</entry><entry namest="col3" nameend="col3" align="right">36</entry><entry namest="col4" nameend="col4" align="right">36</entry><entry namest="col5" nameend="col5" align="right">36</entry><entry namest="col6" nameend="col6" align="right">36</entry><entry namest="col7" nameend="col7" align="right">43</entry><entry namest="col8" nameend="col8" align="right">36</entry><entry namest="col9" nameend="col9" align="right">36</entry><entry namest="col10" nameend="col10" align="right">43</entry><entry namest="col11" nameend="col11" align="right">36</entry></row><row><entry namest="col1" nameend="col1" align="left">Polyester:</entry><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" /><entry namest="col4" nameend="col4" /><entry namest="col5" nameend="col5" /><entry namest="col6" nameend="col6" /><entry namest="col7" nameend="col7" /><entry namest="col8" nameend="col8" /><entry namest="col9" nameend="col9" /><entry namest="col10" nameend="col10" /><entry namest="col11" nameend="col11" /></row><row><entry namest="col1" nameend="col1" align="left">Identity</entry><entry namest="col2" nameend="col2" align="right">PBT</entry><entry namest="col3" nameend="col3" align="right">PBT</entry><entry namest="col4" nameend="col4" align="right">PBT</entry><entry namest="col5" nameend="col5" align="right">PBT</entry><entry namest="col6" nameend="col6" align="right">PBT</entry><entry namest="col7" nameend="col7" align="right">PBT</entry><entry namest="col8" nameend="col8" align="right">PTME (50,000)</entry><entry namest="col9" nameend="col9" align="right">PBT</entry><entry namest="col10" nameend="col10" align="right">PBT</entry><entry namest="col11" nameend="col11" align="right">PBT</entry></row><row><entry namest="col1" nameend="col1" align="left">Parts</entry><entry namest="col2" nameend="col2" align="right">54</entry><entry namest="col3" nameend="col3" align="right">54</entry><entry namest="col4" nameend="col4" align="right">54</entry><entry namest="col5" nameend="col5" align="right">54</entry><entry namest="col6" nameend="col6" align="right">54</entry><entry namest="col7" nameend="col7" align="right">43</entry><entry namest="col8" nameend="col8" align="right">54</entry><entry namest="col9" nameend="col9" align="right">54</entry><entry namest="col10" nameend="col10" align="right">43</entry><entry namest="col11" nameend="col11" align="right">54</entry></row><row><entry namest="col1" nameend="col1" align="left">SEBS, parts</entry><entry namest="col2" nameend="col2" align="right">10</entry><entry namest="col3" nameend="col3" align="right">10</entry><entry namest="col4" nameend="col4" align="right">10</entry><entry namest="col5" nameend="col5" align="right">10</entry><entry namest="col6" nameend="col6" align="right">10</entry><entry namest="col7" nameend="col7" align="right">14</entry><entry namest="col8" nameend="col8" align="right">10</entry><entry namest="col9" nameend="col9" align="right">10</entry><entry namest="col10" nameend="col10" align="right">14</entry><entry namest="col11" nameend="col11" align="right">10</entry></row><row><entry namest="col1" nameend="col1" align="left">Percent bound polyphenylene ether</entry><entry namest="col2" nameend="col2" align="right">16</entry><entry namest="col3" nameend="col3" align="right">26</entry><entry namest="col4" nameend="col4" align="right">16</entry><entry namest="col5" nameend="col5" align="right">--</entry><entry namest="col6" nameend="col6" align="right">19</entry><entry namest="col7" nameend="col7" align="right">28</entry><entry namest="col8" nameend="col8" align="right">>20</entry><entry namest="col9" nameend="col9" align="right">21</entry><entry namest="col10" nameend="col10" align="right">21</entry><entry namest="col11" nameend="col11" align="right">17</entry></row><row><entry namest="col1" nameend="col1" align="left">Izod impact strength, joules/m.</entry><entry namest="col2" nameend="col2" align="right">112</entry><entry namest="col3" nameend="col3" align="right">107</entry><entry namest="col4" nameend="col4" align="right">166</entry><entry namest="col5" nameend="col5" align="right">160</entry><entry namest="col6" nameend="col6" align="right">176</entry><entry namest="col7" nameend="col7" align="right">134</entry><entry namest="col8" nameend="col8" align="right">176</entry><entry namest="col9" nameend="col9" align="right">128</entry><entry namest="col10" nameend="col10" align="right">53</entry><entry namest="col11" nameend="col11" align="right">80</entry></row><row><entry namest="col1" nameend="col1" align="left">Tensile strength, MPa.:</entry><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" /><entry namest="col4" nameend="col4" /><entry namest="col5" nameend="col5" /><entry namest="col6" nameend="col6" /><entry namest="col7" nameend="col7" /><entry namest="col8" nameend="col8" /><entry namest="col9" nameend="col9" /><entry namest="col10" nameend="col10" /><entry namest="col11" nameend="col11" /></row><row><entry namest="col1" nameend="col1" align="left">At yield</entry><entry namest="col2" nameend="col2" align="right">--</entry><entry namest="col3" nameend="col3" align="right">40.4</entry><entry namest="col4" nameend="col4" align="right">40.1</entry><entry namest="col5" nameend="col5" align="right">42.1</entry><entry namest="col6" nameend="col6" align="right">--</entry><entry namest="col7" nameend="col7" align="right">--</entry><entry namest="col8" nameend="col8" align="right">27.8</entry><entry namest="col9" nameend="col9" align="right">--</entry><entry namest="col10" nameend="col10" align="right">--</entry><entry namest="col11" nameend="col11" align="right">--</entry></row><row><entry namest="col1" nameend="col1" align="left">At break</entry><entry namest="col2" nameend="col2" align="right">--</entry><entry namest="col3" nameend="col3" align="right">37.5</entry><entry namest="col4" nameend="col4" align="right">37.5</entry><entry namest="col5" nameend="col5" align="right">37.3</entry><entry namest="col6" nameend="col6" align="right">--</entry><entry namest="col7" nameend="col7" align="right">--</entry><entry namest="col8" nameend="col8" align="right">29.7</entry><entry namest="col9" nameend="col9" align="right">--</entry><entry namest="col10" nameend="col10" align="right">--</entry><entry namest="col11" nameend="col11" align="right">--</entry></row><row><entry namest="col1" nameend="col1" align="left">Tensile elongation, %</entry><entry namest="col2" nameend="col2" align="right">--</entry><entry namest="col3" nameend="col3" align="right">76</entry><entry namest="col4" nameend="col4" align="right">115</entry><entry namest="col5" nameend="col5" align="right">109</entry><entry namest="col6" nameend="col6" align="right">--</entry><entry namest="col7" nameend="col7" align="right">--</entry><entry namest="col8" nameend="col8" align="right">151</entry><entry namest="col9" nameend="col9" align="right">--</entry><entry namest="col10" nameend="col10" align="right">--</entry><entry namest="col11" nameend="col11" align="right">--</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Heat distortion temp., °C</entry><entry namest="col2" nameend="col2" align="right">--</entry><entry namest="col3" nameend="col3" align="right">162</entry><entry namest="col4" nameend="col4" align="right">--</entry><entry namest="col5" nameend="col5" align="right">161</entry><entry namest="col6" nameend="col6" align="right">--</entry><entry namest="col7" nameend="col7" align="right">--</entry><entry namest="col8" nameend="col8" align="right">136</entry><entry namest="col9" nameend="col9" align="right">--</entry><entry namest="col10" nameend="col10" align="right">--</entry><entry namest="col11" nameend="col11" align="right">--</entry></row></tbody></tgroup></table></tables>

Examples 36-47

0076Compositions were prepared and molded from the epoxytriazine-capped polyphenylene ethers of Examples 15-25, PBT and SEBS. The relevant parameters and test results are given in Table IV. <tables id="tabl0004" num="0004"><table frame="all"><title>TABLE IV</title><tgroup cols="10" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="15.75mm" /><colspec colnum="2" colname="col2" colwidth="15.75mm" /><colspec colnum="3" colname="col3" colwidth="15.75mm" /><colspec colnum="4" colname="col4" colwidth="15.75mm" /><colspec colnum="5" colname="col5" colwidth="15.75mm" /><colspec colnum="6" colname="col6" colwidth="15.75mm" /><colspec colnum="7" colname="col7" colwidth="15.75mm" /><colspec colnum="8" colname="col8" colwidth="15.75mm" /><colspec colnum="9" colname="col9" colwidth="15.75mm" /><colspec colnum="10" colname="col10" colwidth="15.75mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" align="center">Example</entry><entry namest="col2" nameend="col3" align="center">Capped polyphenylene ether</entry><entry namest="col4" nameend="col4" align="center">Polyester parts</entry><entry namest="col5" nameend="col5" align="center">SEBS, parts</entry><entry namest="col6" nameend="col6" align="center">Izod impact strength, joules/m.</entry><entry namest="col7" nameend="col8" align="center">Tensile strength, MPa.</entry><entry namest="col9" nameend="col9" align="center">Tensile elongation, %</entry><entry namest="col10" nameend="col10" align="center">Heat distortion temp.. °C</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" align="center">Identity</entry><entry namest="col3" nameend="col3" align="center">Parts</entry><entry namest="col4" nameend="col4" /><entry namest="col5" nameend="col5" /><entry namest="col6" nameend="col6" /><entry namest="col7" nameend="col7" align="center">At yield</entry><entry namest="col8" nameend="col8" align="center">At break</entry><entry namest="col9" nameend="col9" /><entry namest="col10" nameend="col10" /></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="right">36</entry><entry namest="col2" nameend="col2" align="left">Ex. 15</entry><entry namest="col3" nameend="col3" align="right">36</entry><entry namest="col4" nameend="col4" align="right">54</entry><entry namest="col5" nameend="col5" align="right">10</entry><entry namest="col6" nameend="col6" align="right">107</entry><entry namest="col7" nameend="col7" align="right">46.4</entry><entry namest="col8" nameend="col8" align="right">39.0</entry><entry namest="col9" nameend="col9" align="right">52</entry><entry namest="col10" nameend="col10" align="right">176</entry></row><row><entry namest="col1" nameend="col1" align="right">37</entry><entry namest="col2" nameend="col2" align="left">Ex. 16</entry><entry namest="col3" nameend="col3" align="right">36</entry><entry namest="col4" nameend="col4" align="right">54</entry><entry namest="col5" nameend="col5" align="right">10</entry><entry namest="col6" nameend="col6" align="right">742</entry><entry namest="col7" nameend="col7" align="right">45.5</entry><entry namest="col8" nameend="col8" align="right">42.7</entry><entry namest="col9" nameend="col9" align="right">187</entry><entry namest="col10" nameend="col10" align="right">---</entry></row><row><entry namest="col1" nameend="col1" align="right">38</entry><entry namest="col2" nameend="col2" align="left">Ex. 17</entry><entry namest="col3" nameend="col3" align="right">36</entry><entry namest="col4" nameend="col4" align="right">54</entry><entry namest="col5" nameend="col5" align="right">10</entry><entry namest="col6" nameend="col6" align="right">689</entry><entry namest="col7" nameend="col7" align="right">47.7</entry><entry namest="col8" nameend="col8" align="right">42.0</entry><entry namest="col9" nameend="col9" align="right">142</entry><entry namest="col10" nameend="col10" align="right">---</entry></row><row><entry namest="col1" nameend="col1" align="right">39</entry><entry namest="col2" nameend="col2" align="left">Ex. 18</entry><entry namest="col3" nameend="col3" align="right">36</entry><entry namest="col4" nameend="col4" align="right">54</entry><entry namest="col5" nameend="col5" align="right">10</entry><entry namest="col6" nameend="col6" align="right">833</entry><entry namest="col7" nameend="col7" align="right">45.3</entry><entry namest="col8" nameend="col8" align="right">45.1</entry><entry namest="col9" nameend="col9" align="right">212</entry><entry namest="col10" nameend="col10" align="right">---</entry></row><row><entry namest="col1" nameend="col1" align="right">40</entry><entry namest="col2" nameend="col2" align="left">Ex. 19</entry><entry namest="col3" nameend="col3" align="right">36</entry><entry namest="col4" nameend="col4" align="right">54</entry><entry namest="col5" nameend="col5" align="right">10</entry><entry namest="col6" nameend="col6" align="right">790</entry><entry namest="col7" nameend="col7" align="right">42.5</entry><entry namest="col8" nameend="col8" align="right">42.6</entry><entry namest="col9" nameend="col9" align="right">160</entry><entry namest="col10" nameend="col10" align="right">170</entry></row><row><entry namest="col1" nameend="col1" align="right">41</entry><entry namest="col2" nameend="col2" align="left">Ex. 20</entry><entry namest="col3" nameend="col3" align="right">36</entry><entry namest="col4" nameend="col4" align="right">54</entry><entry namest="col5" nameend="col5" align="right">10</entry><entry namest="col6" nameend="col6" align="right">1110</entry><entry namest="col7" nameend="col7" align="right">----</entry><entry namest="col8" nameend="col8" align="right">----</entry><entry namest="col9" nameend="col9" align="right">---</entry><entry namest="col10" nameend="col10" align="right">---</entry></row><row><entry namest="col1" nameend="col1" align="right">42</entry><entry namest="col2" nameend="col2" align="left">Ex. 21</entry><entry namest="col3" nameend="col3" align="right">36</entry><entry namest="col4" nameend="col4" align="right">54</entry><entry namest="col5" nameend="col5" align="right">10</entry><entry namest="col6" nameend="col6" align="right">251</entry><entry namest="col7" nameend="col7" align="right">42.0</entry><entry namest="col8" nameend="col8" align="right">39.6</entry><entry namest="col9" nameend="col9" align="right">121</entry><entry namest="col10" nameend="col10" align="right">---</entry></row><row><entry namest="col1" nameend="col1" align="right">43</entry><entry namest="col2" nameend="col2" align="left">Ex. 22</entry><entry namest="col3" nameend="col3" align="right">36</entry><entry namest="col4" nameend="col4" align="right">54</entry><entry namest="col5" nameend="col5" align="right">10</entry><entry namest="col6" nameend="col6" align="right">251</entry><entry namest="col7" nameend="col7" align="right">45.6</entry><entry namest="col8" nameend="col8" align="right">43.1</entry><entry namest="col9" nameend="col9" align="right">127</entry><entry namest="col10" nameend="col10" align="right">167</entry></row><row><entry namest="col1" nameend="col1" align="right">44</entry><entry namest="col2" nameend="col2" align="left">Ex. 23</entry><entry namest="col3" nameend="col3" align="right">36</entry><entry namest="col4" nameend="col4" align="right">54</entry><entry namest="col5" nameend="col5" align="right">10</entry><entry namest="col6" nameend="col6" align="right">107</entry><entry namest="col7" nameend="col7" align="right">41.9</entry><entry namest="col8" nameend="col8" align="right">35.5</entry><entry namest="col9" nameend="col9" align="right">58</entry><entry namest="col10" nameend="col10" align="right">159</entry></row><row><entry namest="col1" nameend="col1" align="right">45</entry><entry namest="col2" nameend="col2" align="left">Ex. 23 `</entry><entry namest="col3" nameend="col3" align="right">42</entry><entry namest="col4" nameend="col4" align="right">42</entry><entry namest="col5" nameend="col5" align="right">16</entry><entry namest="col6" nameend="col6" align="right">139</entry><entry namest="col7" nameend="col7" align="right">33.6</entry><entry namest="col8" nameend="col8" align="right">32.6</entry><entry namest="col9" nameend="col9" align="right">77</entry><entry namest="col10" nameend="col10" align="right">146</entry></row><row><entry namest="col1" nameend="col1" align="right">46</entry><entry namest="col2" nameend="col2" align="left">Ex. 24</entry><entry namest="col3" nameend="col3" align="right">36</entry><entry namest="col4" nameend="col4" align="right">54</entry><entry namest="col5" nameend="col5" align="right">10</entry><entry namest="col6" nameend="col6" align="right">865</entry><entry namest="col7" nameend="col7" align="right">42.0</entry><entry namest="col8" nameend="col8" align="right">42.1</entry><entry namest="col9" nameend="col9" align="right">193</entry><entry namest="col10" nameend="col10" align="right">154</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="right">47</entry><entry namest="col2" nameend="col2" align="left">Ex. 25</entry><entry namest="col3" nameend="col3" align="right">36</entry><entry namest="col4" nameend="col4" align="right">54</entry><entry namest="col5" nameend="col5" align="right">10</entry><entry namest="col6" nameend="col6" align="right">833</entry><entry namest="col7" nameend="col7" align="right">44.4</entry><entry namest="col8" nameend="col8" align="right">42.7</entry><entry namest="col9" nameend="col9" align="right">169</entry><entry namest="col10" nameend="col10" align="right">---</entry></row></tbody></tgroup></table></tables>

Examples 48-49

0077Compositions similar to those of Examples 18 and 24 were prepared and molded, substituting 18 parts of PPE for an equal weight of the epoxytriazine-capped polypheny­lene ether. The relevant test results are given in Table V. <tables id="tabl0005" num="0005"><table frame="all"><title>TABLE V</title><tgroup cols="3" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col3" align="center">Example</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" align="center">48</entry><entry namest="col3" nameend="col3" align="center">49</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Capped polyphenylene ether</entry><entry namest="col2" nameend="col2" align="right">Ex. 18</entry><entry namest="col3" nameend="col3" align="right">Ex. 24</entry></row><row><entry namest="col1" nameend="col1" align="left">Izod impact strength, joules/m.</entry><entry namest="col2" nameend="col2" align="right">48</entry><entry namest="col3" nameend="col3" align="right">64</entry></row><row><entry namest="col1" nameend="col1" align="left">Tensile strength, MPa.:</entry><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" /></row><row><entry namest="col1" nameend="col1" align="left">At yield</entry><entry namest="col2" nameend="col2" align="right">44.7</entry><entry namest="col3" nameend="col3" align="right">44.2</entry></row><row><entry namest="col1" nameend="col1" align="left">At break</entry><entry namest="col2" nameend="col2" align="right">35.1</entry><entry namest="col3" nameend="col3" align="right">36.8</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Tensile elongation, %</entry><entry namest="col2" nameend="col2" align="right">39</entry><entry namest="col3" nameend="col3" align="right">61</entry></row></tbody></tgroup></table></tables>

Examples 50-57

0078Compositions containing epoxytriazine-capped polyphenylene ethers, PET and (in Examples 50-55) SEBS were prepared and molded. In certain instances, the PET was first preextruded at 271°C and dried in order to increase the proportion of carboxylic acid end groups. The following PET's were employed: "Kodapak 7352" (Eastman Kodak Co.) "Vituf 1001A" (Goodyear Chemical) "Rohm &amp; Haas 5202A" Recycled bottle scrap, number average molecular weight about 40,000.

0079The relevant parameters and test results are given in Table VI. <tables id="tabl0006" num="0006"><table frame="all"><title>TABLE VI</title><tgroup cols="9" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="17.50mm" /><colspec colnum="2" colname="col2" colwidth="17.50mm" /><colspec colnum="3" colname="col3" colwidth="17.50mm" /><colspec colnum="4" colname="col4" colwidth="17.50mm" /><colspec colnum="5" colname="col5" colwidth="17.50mm" /><colspec colnum="6" colname="col6" colwidth="17.50mm" /><colspec colnum="7" colname="col7" colwidth="17.50mm" /><colspec colnum="8" colname="col8" colwidth="17.50mm" /><colspec colnum="9" colname="col9" colwidth="17.50mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col9" align="center">Example</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" align="center">50</entry><entry namest="col3" nameend="col3" align="center">52</entry><entry namest="col4" nameend="col4" align="center">52</entry><entry namest="col5" nameend="col5" align="center">53</entry><entry namest="col6" nameend="col6" align="center">54</entry><entry namest="col7" nameend="col7" align="center">55</entry><entry namest="col8" nameend="col8" align="center">56</entry><entry namest="col9" nameend="col9" align="center">57</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Capped polyphenylene ether:</entry><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" /><entry namest="col4" nameend="col4" /><entry namest="col5" nameend="col5" /><entry namest="col6" nameend="col6" /><entry namest="col7" nameend="col7" /><entry namest="col8" nameend="col8" /><entry namest="col9" nameend="col9" /></row><row><entry namest="col1" nameend="col1" align="left">Identity</entry><entry namest="col2" nameend="col2" align="right">Ex. 18</entry><entry namest="col3" nameend="col3" align="right">Ex. 18</entry><entry namest="col4" nameend="col4" align="right">Ex. 24</entry><entry namest="col5" nameend="col5" align="right">Ex. 18</entry><entry namest="col6" nameend="col6" align="right">Ex. 18</entry><entry namest="col7" nameend="col7" align="right">Ex. 18</entry><entry namest="col8" nameend="col8" align="right">Ex. 18</entry><entry namest="col9" nameend="col9" align="right">Ex. 18</entry></row><row><entry namest="col1" nameend="col1" align="left">Parts</entry><entry namest="col2" nameend="col2" align="right">36</entry><entry namest="col3" nameend="col3" align="right">36</entry><entry namest="col4" nameend="col4" align="right">36</entry><entry namest="col5" nameend="col5" align="right">36</entry><entry namest="col6" nameend="col6" align="right">36</entry><entry namest="col7" nameend="col7" align="right">36</entry><entry namest="col8" nameend="col8" align="right">40</entry><entry namest="col9" nameend="col9" align="right">40</entry></row><row><entry namest="col1" nameend="col1" align="left">PET:</entry><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" /><entry namest="col4" nameend="col4" /><entry namest="col5" nameend="col5" /><entry namest="col6" nameend="col6" /><entry namest="col7" nameend="col7" /><entry namest="col8" nameend="col8" /><entry namest="col9" nameend="col9" /></row><row><entry namest="col1" nameend="col1" align="left">Identity</entry><entry namest="col2" nameend="col2" align="right">Kodapak</entry><entry namest="col3" nameend="col3" align="right">Kodapak*</entry><entry namest="col4" nameend="col4" align="right">Kodapak*</entry><entry namest="col5" nameend="col5" align="right">Vituf</entry><entry namest="col6" nameend="col6" align="right">Rohm &amp; liaas</entry><entry namest="col7" nameend="col7" align="right">Bottle scrap</entry><entry namest="col8" nameend="col8" align="right">Kodapak*</entry><entry namest="col9" nameend="col9" align="right">Bottle scrap</entry></row><row><entry namest="col1" nameend="col1" align="left">Parts</entry><entry namest="col2" nameend="col2" align="right">54</entry><entry namest="col3" nameend="col3" align="right">54</entry><entry namest="col4" nameend="col4" align="right">54</entry><entry namest="col5" nameend="col5" align="right">54</entry><entry namest="col6" nameend="col6" align="right">54</entry><entry namest="col7" nameend="col7" align="right">54</entry><entry namest="col8" nameend="col8" align="right">60</entry><entry namest="col9" nameend="col9" align="right">60</entry></row><row><entry namest="col1" nameend="col1" align="left">SEBS, parts</entry><entry namest="col2" nameend="col2" align="right">10</entry><entry namest="col3" nameend="col3" align="right">10</entry><entry namest="col4" nameend="col4" align="right">10</entry><entry namest="col5" nameend="col5" align="right">10</entry><entry namest="col6" nameend="col6" align="right">10</entry><entry namest="col7" nameend="col7" align="right">10</entry><entry namest="col8" nameend="col8" align="right">--</entry><entry namest="col9" nameend="col9" align="right">--</entry></row><row><entry namest="col1" nameend="col1" align="left">Izod impact strength, Joules/m.</entry><entry namest="col2" nameend="col2" align="right">32</entry><entry namest="col3" nameend="col3" align="right">107</entry><entry namest="col4" nameend="col4" align="right">150</entry><entry namest="col5" nameend="col5" align="right">64</entry><entry namest="col6" nameend="col6" align="right">43</entry><entry namest="col7" nameend="col7" align="right">48</entry><entry namest="col8" nameend="col8" align="right">--</entry><entry namest="col9" nameend="col9" align="right">--</entry></row><row><entry namest="col1" nameend="col1" align="left">Tensile strength, MPa.:</entry><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" /><entry namest="col4" nameend="col4" /><entry namest="col5" nameend="col5" /><entry namest="col6" nameend="col6" /><entry namest="col7" nameend="col7" /><entry namest="col8" nameend="col8" /><entry namest="col9" nameend="col9" /></row><row><entry namest="col1" nameend="col1" align="left">; At yield</entry><entry namest="col2" nameend="col2" align="right">45.8</entry><entry namest="col3" nameend="col3" align="right">49.1</entry><entry namest="col4" nameend="col4" align="right">46.2</entry><entry namest="col5" nameend="col5" align="right">49.6</entry><entry namest="col6" nameend="col6" align="right">47.2</entry><entry namest="col7" nameend="col7" align="right">46.4</entry><entry namest="col8" nameend="col8" align="right">58.5</entry><entry namest="col9" nameend="col9" align="right">58.4</entry></row><row><entry namest="col1" nameend="col1" align="left">At break</entry><entry namest="col2" nameend="col2" align="right">35.9</entry><entry namest="col3" nameend="col3" align="right">41.9</entry><entry namest="col4" nameend="col4" align="right">45.6</entry><entry namest="col5" nameend="col5" align="right">41.2</entry><entry namest="col6" nameend="col6" align="right">42.4</entry><entry namest="col7" nameend="col7" align="right">40.9</entry><entry namest="col8" nameend="col8" align="right">51.8</entry><entry namest="col9" nameend="col9" align="right">50.4</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Tensile elongation, %</entry><entry namest="col2" nameend="col2" align="right">106</entry><entry namest="col3" nameend="col3" align="right">208</entry><entry namest="col4" nameend="col4" align="right">253</entry><entry namest="col5" nameend="col5" align="right">152</entry><entry namest="col6" nameend="col6" align="right">214</entry><entry namest="col7" nameend="col7" align="right">178</entry><entry namest="col8" nameend="col8" align="right">272</entry><entry namest="col9" nameend="col9" align="right">237</entry></row></tbody></tgroup><tgroup cols="9" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="17.50mm" /><colspec colnum="2" colname="col2" colwidth="17.50mm" /><colspec colnum="3" colname="col3" colwidth="17.50mm" /><colspec colnum="4" colname="col4" colwidth="17.50mm" /><colspec colnum="5" colname="col5" colwidth="17.50mm" /><colspec colnum="6" colname="col6" colwidth="17.50mm" /><colspec colnum="7" colname="col7" colwidth="17.50mm" /><colspec colnum="8" colname="col8" colwidth="17.50mm" /><colspec colnum="9" colname="col9" colwidth="17.50mm" /><tbody valign="top"><row><entry namest="col1" nameend="col9" align="justify">*Reextruded.</entry></row></tbody></tgroup></table></tables>

Examples 58-61

0080Compositions containing the epoxytriazine-capped polyphenylene ether of Example 18, PBT, bottle scrap PET and (in Examples 58-60) SEBS were prepared and molded. The relevant parameters and test results are given in Table VII. <tables id="tabl0007" num="0007"><table frame="all"><title>TABLE VII</title><tgroup cols="5" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="31.50mm" /><colspec colnum="2" colname="col2" colwidth="31.50mm" /><colspec colnum="3" colname="col3" colwidth="31.50mm" /><colspec colnum="4" colname="col4" colwidth="31.50mm" /><colspec colnum="5" colname="col5" colwidth="31.50mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col5" align="center">Example</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" align="center">58</entry><entry namest="col3" nameend="col3" align="center">59</entry><entry namest="col4" nameend="col4" align="center">60</entry><entry namest="col5" nameend="col5" align="center">61</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Capped polyphenylene ether, parts</entry><entry namest="col2" nameend="col2" align="char" char=".">36</entry><entry namest="col3" nameend="col3" align="char" char=".">36</entry><entry namest="col4" nameend="col4" align="char" char=".">36</entry><entry namest="col5" nameend="col5" align="char" char=".">40</entry></row><row><entry namest="col1" nameend="col1" align="left">Polyester, parts:</entry><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" /><entry namest="col4" nameend="col4" /><entry namest="col5" nameend="col5" /></row><row><entry namest="col1" nameend="col1" align="left">PBT</entry><entry namest="col2" nameend="col2" align="char" char=".">45</entry><entry namest="col3" nameend="col3" align="char" char=".">27</entry><entry namest="col4" nameend="col4" align="char" char=".">9</entry><entry namest="col5" nameend="col5" align="char" char=".">30</entry></row><row><entry namest="col1" nameend="col1" align="left">PET</entry><entry namest="col2" nameend="col2" align="char" char=".">9</entry><entry namest="col3" nameend="col3" align="char" char=".">27</entry><entry namest="col4" nameend="col4" align="char" char=".">45</entry><entry namest="col5" nameend="col5" align="char" char=".">30</entry></row><row><entry namest="col1" nameend="col1" align="left">SEBS, parts</entry><entry namest="col2" nameend="col2" align="char" char=".">10</entry><entry namest="col3" nameend="col3" align="char" char=".">10</entry><entry namest="col4" nameend="col4" align="char" char=".">10</entry><entry namest="col5" nameend="col5" align="char" char=".">--</entry></row><row><entry namest="col1" nameend="col1" align="left">Izod impact strength, joules/m.</entry><entry namest="col2" nameend="col2" align="char" char=".">753</entry><entry namest="col3" nameend="col3" align="char" char=".">198</entry><entry namest="col4" nameend="col4" align="char" char=".">812</entry><entry namest="col5" nameend="col5" align="char" char=".">--</entry></row><row><entry namest="col1" nameend="col1" align="left">Tensile strength, MPa.:</entry><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" /><entry namest="col4" nameend="col4" /><entry namest="col5" nameend="col5" /></row><row><entry namest="col1" nameend="col1" align="left">At yield</entry><entry namest="col2" nameend="col2" align="char" char=".">43.9</entry><entry namest="col3" nameend="col3" align="char" char=".">41.6</entry><entry namest="col4" nameend="col4" align="char" char=".">44.5</entry><entry namest="col5" nameend="col5" align="char" char=".">46.1</entry></row><row><entry namest="col1" nameend="col1" align="left">At break</entry><entry namest="col2" nameend="col2" align="char" char=".">42.3</entry><entry namest="col3" nameend="col3" align="char" char=".">40.8</entry><entry namest="col4" nameend="col4" align="char" char=".">39.6</entry><entry namest="col5" nameend="col5" align="char" char=".">40.6</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Tensile elongation, %</entry><entry namest="col2" nameend="col2" align="char" char=".">151</entry><entry namest="col3" nameend="col3" align="char" char=".">220</entry><entry namest="col4" nameend="col4" align="char" char=".">195</entry><entry namest="col5" nameend="col5" align="char" char=".">178</entry></row></tbody></tgroup></table></tables>

Examples 62-64

0081Compositions containing epoxytriazine-capped polyphenylene ethers similar to that of Example 18 but containing 0.75-0.85% epoxytriazine, PBT and CS or PO were prepared and molded. The relevant parameters and test results are given in Table VIII. <tables id="tabl0008" num="0008"><table frame="all"><title>TABLE VIII</title><tgroup cols="4" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="39.37mm" /><colspec colnum="2" colname="col2" colwidth="39.37mm" /><colspec colnum="3" colname="col3" colwidth="39.37mm" /><colspec colnum="4" colname="col4" colwidth="39.37mm" /><thead valign="top"><row rowsep="1"><entry namest="col1" nameend="col1" rowsep="0" /><entry namest="col2" nameend="col4" align="center">Example</entry></row><row><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" align="center">62</entry><entry namest="col3" nameend="col3" align="center">63</entry><entry namest="col4" nameend="col4" align="center">64</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Capped polyphenylene ether, parts</entry><entry namest="col2" nameend="col2" align="char" char=".">36</entry><entry namest="col3" nameend="col3" align="char" char=".">37</entry><entry namest="col4" nameend="col4" align="char" char=".">36</entry></row><row><entry namest="col1" nameend="col1" align="left">PBT, parts</entry><entry namest="col2" nameend="col2" align="char" char=".">54</entry><entry namest="col3" nameend="col3" align="char" char=".">55</entry><entry namest="col4" nameend="col4" align="char" char=".">54</entry></row><row><entry namest="col1" nameend="col1" align="left">Impact modifier, parts:</entry><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" /><entry namest="col4" nameend="col4" /></row><row><entry namest="col1" nameend="col1" align="left">CS</entry><entry namest="col2" nameend="col2" align="char" char=".">10</entry><entry namest="col3" nameend="col3" align="char" char=".">8</entry><entry namest="col4" nameend="col4" align="char" char=".">--</entry></row><row><entry namest="col1" nameend="col1" align="left">PO</entry><entry namest="col2" nameend="col2" align="char" char=".">--</entry><entry namest="col3" nameend="col3" align="char" char=".">--</entry><entry namest="col4" nameend="col4" align="char" char=".">10</entry></row><row><entry namest="col1" nameend="col1" align="left">Izod impact strength, joules/m.</entry><entry namest="col2" nameend="col2" align="char" char=".">561</entry><entry namest="col3" nameend="col3" align="char" char=".">219</entry><entry namest="col4" nameend="col4" align="char" char=".">155</entry></row><row><entry namest="col1" nameend="col1" align="left">Tensile strength, MPa.:</entry><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" /><entry namest="col4" nameend="col4" /></row><row><entry namest="col1" nameend="col1" align="left">At yield</entry><entry namest="col2" nameend="col2" align="char" char=".">46.7</entry><entry namest="col3" nameend="col3" align="char" char=".">44.7</entry><entry namest="col4" nameend="col4" align="char" char=".">41.9</entry></row><row><entry namest="col1" nameend="col1" align="left">At break</entry><entry namest="col2" nameend="col2" align="char" char=".">40.8</entry><entry namest="col3" nameend="col3" align="char" char=".">41.4</entry><entry namest="col4" nameend="col4" align="char" char=".">34.9</entry></row><row><entry namest="col1" nameend="col1" align="left">Tensile elongation, %</entry><entry namest="col2" nameend="col2" align="char" char=".">134</entry><entry namest="col3" nameend="col3" align="char" char=".">135</entry><entry namest="col4" nameend="col4" align="char" char=".">70</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Heat distortion temp., °C</entry><entry namest="col2" nameend="col2" align="char" char=".">--</entry><entry namest="col3" nameend="col3" align="char" char=".">156</entry><entry namest="col4" nameend="col4" align="char" char=".">162</entry></row></tbody></tgroup></table></tables>

Examples 65-74

0082Compositions containing epoxytriazine-functional­ized polyphenylene ethers, various elastomeric polyesters and (in Examples 65-71) SEBS as an impact modifier were prepared and molded. The relevant parameters and test results are given in Table IX. <tables id="tabl0009" num="0009"><table frame="all"><title>TABLE IX</title><tgroup cols="11" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="14.31mm" /><colspec colnum="2" colname="col2" colwidth="14.31mm" /><colspec colnum="3" colname="col3" colwidth="14.31mm" /><colspec colnum="4" colname="col4" colwidth="14.31mm" /><colspec colnum="5" colname="col5" colwidth="14.31mm" /><colspec colnum="6" colname="col6" colwidth="14.31mm" /><colspec colnum="7" colname="col7" colwidth="14.31mm" /><colspec colnum="8" colname="col8" colwidth="14.31mm" /><colspec colnum="9" colname="col9" colwidth="14.31mm" /><colspec colnum="10" colname="col10" colwidth="14.31mm" /><colspec colnum="11" colname="col11" colwidth="14.31mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" align="center">Example</entry><entry namest="col2" nameend="col3" align="center">Capped polyphenylene ether</entry><entry namest="col4" nameend="col5" align="center">Polyester</entry><entry namest="col6" nameend="col6" align="center">Impact modifier, parts</entry><entry namest="col7" nameend="col7" align="center">Izod Impact strength, joules/m.</entry><entry namest="col8" nameend="col9" align="center">Tensile strength MPa.</entry><entry namest="col10" nameend="col10" align="center">Tensile Elongation, %</entry><entry namest="col11" nameend="col11" align="center">Heat distortion temp.. °C</entry></row><row><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" align="center">Identity</entry><entry namest="col3" nameend="col3" align="center">Parts</entry><entry namest="col4" nameend="col4" align="center">Identity</entry><entry namest="col5" nameend="col5" align="center">Parts</entry><entry namest="col6" nameend="col6" /><entry namest="col7" nameend="col7" /><entry namest="col8" nameend="col8" align="center">At yield</entry><entry namest="col9" nameend="col9" align="center">At break</entry><entry namest="col10" nameend="col10" /><entry namest="col11" nameend="col11" /></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="right">65</entry><entry namest="col2" nameend="col2" align="left">Ex. 18</entry><entry namest="col3" nameend="col3" align="right">36</entry><entry namest="col4" nameend="col4" align="left">PTME (54,000)</entry><entry namest="col5" nameend="col5" align="right">54</entry><entry namest="col6" nameend="col6" align="right">10</entry><entry namest="col7" nameend="col7" align="right">*</entry><entry namest="col8" nameend="col8" align="char" char=".">--</entry><entry namest="col9" nameend="col9" align="char" char=".">22.2</entry><entry namest="col10" nameend="col10" align="right">457</entry><entry namest="col11" nameend="col11" align="right">--</entry></row><row><entry namest="col1" nameend="col1" align="right">66</entry><entry namest="col2" nameend="col2" align="left">Ex. 18</entry><entry namest="col3" nameend="col3" align="right">36</entry><entry namest="col4" nameend="col4" align="left">PTME (50,000)</entry><entry namest="col5" nameend="col5" align="right">54</entry><entry namest="col6" nameend="col6" align="right">10</entry><entry namest="col7" nameend="col7" align="right">870</entry><entry namest="col8" nameend="col8" align="char" char=".">33.1</entry><entry namest="col9" nameend="col9" align="char" char=".">34.6</entry><entry namest="col10" nameend="col10" align="right">196</entry><entry namest="col11" nameend="col11" align="right">--</entry></row><row><entry namest="col1" nameend="col1" align="right">67</entry><entry namest="col2" nameend="col2" align="left">Ex. 18</entry><entry namest="col3" nameend="col3" align="right">36</entry><entry namest="col4" nameend="col4" align="left">PATME</entry><entry namest="col5" nameend="col5" align="right">54</entry><entry namest="col6" nameend="col6" align="right">10</entry><entry namest="col7" nameend="col7" align="right">*</entry><entry namest="col8" nameend="col8" align="char" char=".">--</entry><entry namest="col9" nameend="col9" align="char" char=".">13.5</entry><entry namest="col10" nameend="col10" align="right">130</entry><entry namest="col11" nameend="col11" align="right">--</entry></row><row><entry namest="col1" nameend="col1" align="right">68</entry><entry namest="col2" nameend="col2" align="left">Ex. 18</entry><entry namest="col3" nameend="col3" align="right">36</entry><entry namest="col4" nameend="col4" align="left">PIE</entry><entry namest="col5" nameend="col5" align="right">54</entry><entry namest="col6" nameend="col6" align="right">10</entry><entry namest="col7" nameend="col7" align="right">160</entry><entry namest="col8" nameend="col8" align="char" char=".">--</entry><entry namest="col9" nameend="col9" align="char" char=".">14.1</entry><entry namest="col10" nameend="col10" align="right">84</entry><entry namest="col11" nameend="col11" align="right">--</entry></row><row><entry namest="col1" nameend="col1" align="right">69</entry><entry namest="col2" nameend="col2" align="left">Ex. 24</entry><entry namest="col3" nameend="col3" align="right">36</entry><entry namest="col4" nameend="col4" align="left">PTME (54,000)</entry><entry namest="col5" nameend="col5" align="right">54</entry><entry namest="col6" nameend="col6" align="right">10</entry><entry namest="col7" nameend="col7" align="right">*</entry><entry namest="col8" nameend="col8" align="char" char=".">8.1</entry><entry namest="col9" nameend="col9" align="char" char=".">44.3</entry><entry namest="col10" nameend="col10" align="right">515</entry><entry namest="col11" nameend="col11" align="right">--</entry></row><row><entry namest="col1" nameend="col1" align="right">70</entry><entry namest="col2" nameend="col2" align="left">Ex. 24</entry><entry namest="col3" nameend="col3" align="right">36</entry><entry namest="col4" nameend="col4" align="left">PTME (50,000)</entry><entry namest="col5" nameend="col5" align="right">54</entry><entry namest="col6" nameend="col6" align="right">10</entry><entry namest="col7" nameend="col7" align="right">844</entry><entry namest="col8" nameend="col8" align="char" char=".">--</entry><entry namest="col9" nameend="col9" align="char" char=".">37.4</entry><entry namest="col10" nameend="col10" align="right">245</entry><entry namest="col11" nameend="col11" align="right">--</entry></row><row><entry namest="col1" nameend="col1" align="right">71</entry><entry namest="col2" nameend="col2" align="left">Ex. 24</entry><entry namest="col3" nameend="col3" align="right">36</entry><entry namest="col4" nameend="col4" align="left">PATME</entry><entry namest="col5" nameend="col5" align="right">54</entry><entry namest="col6" nameend="col6" align="right">10</entry><entry namest="col7" nameend="col7" align="right">*</entry><entry namest="col8" nameend="col8" align="char" char=".">--</entry><entry namest="col9" nameend="col9" align="char" char=".">12.0</entry><entry namest="col10" nameend="col10" align="right">120</entry><entry namest="col11" nameend="col11" align="right">--</entry></row><row><entry namest="col1" nameend="col1" align="right">72</entry><entry namest="col2" nameend="col2" align="left">Ex. 18</entry><entry namest="col3" nameend="col3" align="right">40</entry><entry namest="col4" nameend="col4" align="left">PIE</entry><entry namest="col5" nameend="col5" align="right">60</entry><entry namest="col6" nameend="col6" align="right">--</entry><entry namest="col7" nameend="col7" align="right">--</entry><entry namest="col8" nameend="col8" align="char" char=".">16.1</entry><entry namest="col9" nameend="col9" align="char" char=".">16.3</entry><entry namest="col10" nameend="col10" align="right">30</entry><entry namest="col11" nameend="col11" align="right">--</entry></row><row><entry namest="col1" nameend="col1" align="right">73</entry><entry namest="col2" nameend="col2" align="left">Ex. 18</entry><entry namest="col3" nameend="col3" align="right">40</entry><entry namest="col4" nameend="col4" align="left">PTME (54,000)</entry><entry namest="col5" nameend="col5" align="right">60</entry><entry namest="col6" nameend="col6" align="right">--</entry><entry namest="col7" nameend="col7" align="right">--</entry><entry namest="col8" nameend="col8" align="char" char=".">--</entry><entry namest="col9" nameend="col9" align="char" char=".">26.2</entry><entry namest="col10" nameend="col10" align="right">548</entry><entry namest="col11" nameend="col11" align="right">62</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="right">74</entry><entry namest="col2" nameend="col2" align="left">Ex. 18</entry><entry namest="col3" nameend="col3" align="right">40</entry><entry namest="col4" nameend="col4" align="left">PTME (50,000)</entry><entry namest="col5" nameend="col5" align="right">60</entry><entry namest="col6" nameend="col6" align="right">--</entry><entry namest="col7" nameend="col7" align="right">--</entry><entry namest="col8" nameend="col8" align="char" char=".">36.0</entry><entry namest="col9" nameend="col9" align="char" char=".">40.6</entry><entry namest="col10" nameend="col10" align="right">200</entry><entry namest="col11" nameend="col11" align="right">141</entry></row></tbody></tgroup><tgroup cols="11" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="14.31mm" /><colspec colnum="2" colname="col2" colwidth="14.31mm" /><colspec colnum="3" colname="col3" colwidth="14.31mm" /><colspec colnum="4" colname="col4" colwidth="14.31mm" /><colspec colnum="5" colname="col5" colwidth="14.31mm" /><colspec colnum="6" colname="col6" colwidth="14.31mm" /><colspec colnum="7" colname="col7" colwidth="14.31mm" /><colspec colnum="8" colname="col8" colwidth="14.31mm" /><colspec colnum="9" colname="col9" colwidth="14.31mm" /><colspec colnum="10" colname="col10" colwidth="14.31mm" /><colspec colnum="11" colname="col11" colwidth="14.31mm" /><tbody valign="top"><row><entry namest="col1" nameend="col11" align="justify">*Some or all parts bent but did not break.</entry></row></tbody></tgroup></table></tables>

Examples 75-80

0083Compositions containing the epoxytriazine-capped polyphenylene ether of Example 18, mixtures of PBT with various elastomeric polyesters, and (in Examples 75-79) SEBS as an impact modifier were prepared and molded. The rele­vant parameters and test results are given in Table X. <tables id="tabl0010" num="0010"><table frame="all"><title>TABLE X</title><tgroup cols="7" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="22.50mm" /><colspec colnum="2" colname="col2" colwidth="22.50mm" /><colspec colnum="3" colname="col3" colwidth="22.50mm" /><colspec colnum="4" colname="col4" colwidth="22.50mm" /><colspec colnum="5" colname="col5" colwidth="22.50mm" /><colspec colnum="6" colname="col6" colwidth="22.50mm" /><colspec colnum="7" colname="col7" colwidth="22.50mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col7" align="center">Example</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" align="center">75</entry><entry namest="col3" nameend="col3" align="center">76</entry><entry namest="col4" nameend="col4" align="center">77</entry><entry namest="col5" nameend="col5" align="center">78</entry><entry namest="col6" nameend="col6" align="center">79</entry><entry namest="col7" nameend="col7" align="center">80</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Capped polyphenylene ether, parts</entry><entry namest="col2" nameend="col2" align="char" char=".">36</entry><entry namest="col3" nameend="col3" align="char" char=".">36</entry><entry namest="col4" nameend="col4" align="char" char=".">36</entry><entry namest="col5" nameend="col5" align="char" char=".">36</entry><entry namest="col6" nameend="col6" align="char" char=".">20</entry><entry namest="col7" nameend="col7" align="char" char=".">20</entry></row><row><entry namest="col1" nameend="col1" align="left">PBT, parts</entry><entry namest="col2" nameend="col2" align="char" char=".">27</entry><entry namest="col3" nameend="col3" align="char" char=".">49</entry><entry namest="col4" nameend="col4" align="char" char=".">27</entry><entry namest="col5" nameend="col5" align="char" char=".">5</entry><entry namest="col6" nameend="col6" align="char" char=".">35</entry><entry namest="col7" nameend="col7" align="char" char=".">40</entry></row><row><entry namest="col1" nameend="col1" align="left">Elastomeric polyester, parts:</entry><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" /><entry namest="col4" nameend="col4" /><entry namest="col5" nameend="col5" /><entry namest="col6" nameend="col6" /><entry namest="col7" nameend="col7" /></row><row><entry namest="col1" nameend="col1" align="left">PTME(54,000)</entry><entry namest="col2" nameend="col2" align="char" char=".">27</entry><entry namest="col3" nameend="col3" align="char" char=".">--</entry><entry namest="col4" nameend="col4" align="char" char=".">--</entry><entry namest="col5" nameend="col5" align="char" char=".">--</entry><entry namest="col6" nameend="col6" align="char" char=".">--</entry><entry namest="col7" nameend="col7" align="char" char=".">--</entry></row><row><entry namest="col1" nameend="col1" align="left">PTME(50,000)</entry><entry namest="col2" nameend="col2" align="char" char=".">--</entry><entry namest="col3" nameend="col3" align="char" char=".">5</entry><entry namest="col4" nameend="col4" align="char" char=".">27</entry><entry namest="col5" nameend="col5" align="char" char=".">49</entry><entry namest="col6" nameend="col6" align="char" char=".">--</entry><entry namest="col7" nameend="col7" align="char" char=".">--</entry></row><row><entry namest="col1" nameend="col1" align="left">PIE</entry><entry namest="col2" nameend="col2" align="char" char=".">--</entry><entry namest="col3" nameend="col3" align="char" char=".">--</entry><entry namest="col4" nameend="col4" align="char" char=".">--</entry><entry namest="col5" nameend="col5" align="char" char=".">--</entry><entry namest="col6" nameend="col6" align="char" char=".">35</entry><entry namest="col7" nameend="col7" align="char" char=".">40</entry></row><row><entry namest="col1" nameend="col1" align="left">SEBS, parts</entry><entry namest="col2" nameend="col2" align="char" char=".">10</entry><entry namest="col3" nameend="col3" align="char" char=".">10</entry><entry namest="col4" nameend="col4" align="char" char=".">10</entry><entry namest="col5" nameend="col5" align="char" char=".">10</entry><entry namest="col6" nameend="col6" align="char" char=".">10</entry><entry namest="col7" nameend="col7" align="char" char=".">--</entry></row><row><entry namest="col1" nameend="col1" align="left">Izod impact strength, joules/m.</entry><entry namest="col2" nameend="col2" align="char" char=".">651</entry><entry namest="col3" nameend="col3" align="char" char=".">214</entry><entry namest="col4" nameend="col4" align="char" char=".">790</entry><entry namest="col5" nameend="col5" align="char" char=".">822</entry><entry namest="col6" nameend="col6" align="char" char=".">64</entry><entry namest="col7" nameend="col7" align="char" char=".">--</entry></row><row><entry namest="col1" nameend="col1" align="left">Tensile strength, MPa.:</entry><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" /><entry namest="col4" nameend="col4" /><entry namest="col5" nameend="col5" /><entry namest="col6" nameend="col6" /><entry namest="col7" nameend="col7" /></row><row><entry namest="col1" nameend="col1" align="left">At yield</entry><entry namest="col2" nameend="col2" align="char" char=".">22.8</entry><entry namest="col3" nameend="col3" align="char" char=".">41.9</entry><entry namest="col4" nameend="col4" align="char" char=".">35.0</entry><entry namest="col5" nameend="col5" align="char" char=".">30.2</entry><entry namest="col6" nameend="col6" align="char" char=".">20.7</entry><entry namest="col7" nameend="col7" align="char" char=".">25.1</entry></row><row><entry namest="col1" nameend="col1" align="left">At break</entry><entry namest="col2" nameend="col2" align="char" char=".">25.5</entry><entry namest="col3" nameend="col3" align="char" char=".">38.9</entry><entry namest="col4" nameend="col4" align="char" char=".">36.8</entry><entry namest="col5" nameend="col5" align="char" char=".">36.5</entry><entry namest="col6" nameend="col6" align="char" char=".">19.0</entry><entry namest="col7" nameend="col7" align="char" char=".">19.5</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Tensile elongation, %</entry><entry namest="col2" nameend="col2" align="char" char=".">131</entry><entry namest="col3" nameend="col3" align="char" char=".">118</entry><entry namest="col4" nameend="col4" align="char" char=".">144</entry><entry namest="col5" nameend="col5" align="char" char=".">226</entry><entry namest="col6" nameend="col6" align="char" char=".">39</entry><entry namest="col7" nameend="col7" align="char" char=".">37</entry></row></tbody></tgroup></table></tables>