Untitled record

HIGH EFFICIENCY PERFUME CAPSULES

FIELD OF THE INVENTION

The present application relates to encapsulated and high-efficiency compositions, such as consumer products, which comprise encapsulated high-efficiency, as well as the processes for manufacturing and using encapsulated high-efficiency and compositions comprising encapsulated high-efficiency.

BACKGROUND OF THE INVENTION

Beneficial agents, such as perfumes, silicones, waxes, flavorings, vitamins and fabric softening agents, are expensive or generally less effective when used in high concentrations in consumer products, for example personal care compositions, cleaning compositions and fabric care compositions. Consequently, there is a desire to optimize the effectiveness of such beneficial agents. A method to achieve said objective is to improve the efficiency of supply of said beneficial agents. Unfortunately, it is difficult to improve the effectiveness of the delivery of the beneficial agents since such agents may be lost due to their physical or chemical characteristics, or because they may be incompatible with other components of the composition or with the treated site.

One method to improve the effectiveness in the delivery of a beneficial agent is to encapsulate the beneficial agent. While such efforts can improve the efficiency in the supply of the beneficial agent, further improvements in the efficiency in the delivery are desired, since encapsulated beneficial agents may be lost before or after being applied to the site of interest, due to factors such as interactions. mechanical or chemical, for example, the action of wash or rinse liquors, and / or load interactions. In certain applications the deposit of the encapsulated beneficial agents is improved by coating the encapsulated beneficial agent with polymers. Generally, such a polymeric coating improves the deposit of the encapsulates. However, when multiple surfaces are treated simultaneously, for example, a laundry load containing a variety of fabrics, each surface is typically treated to a different degree (larger or smaller amounts of beneficial agent are supplied). For cases where the beneficial agent is a perfume, the different levels of treatment in the different fabrics of a wash load can lead to an odor too strong in some fabrics and an odor too weak in other fabrics. The applicants acknowledged that the source of the unequal treatment problem was mainly due to the preferential encapsulation deposit that was driven by the polymeric deposit assistant. Thus, what is needed are encapsulated beneficial agents that have a uniform and high deposit profile across multiple different surfaces.

In the present application the applicants describe encapsulated beneficial agents and specific classes of polymers containing amines that, when combined, provide a uniform and high deposition profile across multiple different surfaces, for example, hair, skin and multiple fabrics, taies cotton horn, high surface cotton, polycotton and polyester.

SUMMARY OF THE INVENTION

The present application relates to encapsulated and high-efficiency compositions, such as consumer products, which comprise encapsulated high-efficiency, as well as to processes for manufacturing and using encapsulated high-efficiency and compositions comprising encapsulated high-efficiency.

DETAILED DESCRIPTION OF THE INVENTION

Definitions

As used herein, "consumer product" means products or devices for baby care, for beauty care, fabric and home care, family care, female care, health care. , snacks and / or drinks intended, generally, to be used or consumed in the form in which they are sold. These products include, but are not limited to, pafiales, bibs, cleaning wipes; products for, and / or methods related to, the treatment of hair (human hair, dog or cat hair), which include bleaching agents, colorants, dyes, conditioners, shampoos, hair modeling products; deodorants and antiperspirants; personal hygiene products; cosmetics; skin care products, which includes the application of creams, lotions, and other products that are typically applied for domestic use, including fine fragrances; and shaving products; products for, or methods related to, treatment of fabrics, hard surfaces and other surfaces related to fabric and household care, including: environmental care, which includes environmental modifiers and scent supply systems, car care, dishwashing, fabric conditioning (including softening and / or cooling), laundry detergents, additive and / or laundry and rinse care, cleaning and / or treatment of hard surfaces that include floor and toilet cleaners, and other types of cleaning for domestic or institutional use; products or methods related to toilet paper, facial wipes, paper tissues or paper towels; tampons, female towels; related products or methods

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<img file="AR080330A1_D0002.tif" />

with bucai care, which include toothpastes, dental gels, mouthwashes, denture adhesives, teeth whiteners; Over-the-counter pharmaceutical products for health care, including cough and cold remedies, pain relievers, for RX, pet health and nutrition; Processed food products intended primarily to be consumed between regular meals or as accompanying meals (some non-limiting examples include fried potato chips, tortillas, popcorn, salami donuts, fried corn flakes, cereal bars, fried vegetable flakes , snack mixes, canapés, fried multi-grain flakes, crackers, cheese snacks, roasted pork skin, corn snacks, small sandwiches, extruded sandwiches and donuts); and coffee.

As used herein, the term "composition for cleaning and / or treatment" is a subset of consumer products that includes, unless otherwise indicated, beauty care, care products. &amp; of fabrics and home. Such products include, but are not limited to, products for the treatment of hair (human, dogs and / or cats), including discoloration, coloration, had, conditioning, shampooing, stylized; deodorants and antiperspirants; personal hygiene products; cosmetics; skin care, including the application of creams, lotions and other products that are applied in a typical way, for domestic use, even fine fragrances; and shaving products, fabric treatment products, hard surfaces and any other surfaces related to fabric and household care, including: environmental care, including environmental modifiers and scent supply systems, car care, dishwashing, fabric conditioning (even softening and / or cooling), laundry detergents, additive and / or laundry and rinse care, cleanser and / or treatment for hard surfaces, including floor and toilet cleaners, “high performance” washing agents or for all purposes, in the form of granules or dust, especially cleaning agents; liquid cleaning agents, in gel, or in the form of multipurpose paste, especially so-called high performance liquids; liquid detergents for fine fabrics; agents for manual dishwashing, or low performance agents for dishwashing, especially those of large foam; dishwashing agents, including various types of tablets, granules, liquids and aids and rinses, for domestic and institutional use; disinfectants and liquid cleaners, including those of the antibacterial type for hand washing, cleaning bars, mouthwashes, denture cleaners, dentifrices, carpet or car shampoos, bath cleaners, including toilet cleaners;

<img file="AR080330A1_D0003.tif" />

shampoos and hair rinses; shower gels, fine fragrances, barium foams and metal cleaners; as well as cleaning aids, as well as bleaching additives and those of the "bar stain remover" type or for pretreatment; products with substrates, such as the sheets that are added in the dryer of clothes, pads and dry and moistened buns, substrates of non-woven fabric and sponges; thus as sprinklers and vaporizers, all for domestic and / or institutional use; and / or methods related to bucai care, including toothpastes, dental gels, dental rinses, dentures adhesives, teeth whiteners.

As used herein, the term "composition for cleaning and / or treatment of fabrics and / or hard surfaces" is a subset of the compositions for cleaning and treatment which includes, unless otherwise indicated, agents. "high performance" wash or for all purposes in the form of granules or powder, especially cleaning detergents; liquid, gel, or multi-purpose paste cleaning agents, especially so-called high performance liquids; liquid detergents for fine fabrics; agents for manual dishwashing, or low performance agents for dishwashing, especially those of large foam; dishwashing agents, including various types of tablets, granules, helpers and rinsing liquids, for domestic and institutional use; disinfectant agents and liquid cleaners, including those of the antibacterial type for hand washing, cleaning bars, shampoos for carpets or automobiles, bathroom cleaners, even toilet cleaners; and metal cleaners, fabric conditioning products, including softening and / or cooling, which may be in liquid, solid and / or dryer sheet form; thus, as cleaning assistants, such as bleaching additives and types of "stain removers in sticks" or for pretreatment, products loaded with substrates, taies such as sheets affixed to the dryer, pads and dry and moistened buns, nonwoven fabric substrates and sponges; and also sprinklers and vaporizers. All products that are applicable may be in a standard, concentrated or even highly concentrated form, even to the point where such products may, in certain aspects, be non-aqueous.

As used in the present description, the articles such as "a" and "ones", for example, used in a claim, mean one or more of what is claimed or described.

As used in the present description, the terms "include", "includes" and "which includes" are not limiting.

As used in the present description, the term "solid" includes the

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<img file="AR080330A1_D0005.tif" />

Product forms in tablets, granular, powder and stick.

As used herein, the term "fluid" includes liquid, gel, paste and gas product forms.

As used herein, the term "site" includes paper products, fabrics, clothing, hard surfaces, hair and skin.

Unless stated otherwise, all levels of the ο component of the composition refer to the active portion of that component or composition and exclude impurities, for example, residual solvents or by-products, which may be present in the commercially available sources of such components or compositions.

All percentages and proportions are calculated by weight, unless otherwise indicated. All percentages and proportions are calculated based on the total composition, unless otherwise specified.

It will be understood that any maximum numerical limit given in this specification shall include all lower numerical limits, as if the lower numerical limits had been explicitly noted in this description. Any minimum numerical limit given in this specification shall include any greater numerical limit, as if the greater numerical limits had been explicitly noted in this description. Any numerical interval given in this specification shall include any minor numerical interval that falls within the greater numerical interval, as if all minor numerical intervals had been explicitly noted in this description.

High efficiency encapsulates and suspension / agglomerates that comprise them

An encapsulation that can comprise a core, a wall with an external surface and a coating, the wall encapsulates the core, the coating covers the outer surface of the wall, the coating can comprise one or more polymeric efficiency having the following formula:

NR₂

Ri where:

<img file="AR080330A1_D0006.tif" />

a) where a and b can be integers or averages (real numbers) of approximately 50 to 100,000;

b) each R1 can be independently selected from H, CH₃, (C = O) H, alkylene, alkylene with unsaturated CC bonds, CH₂-CROH, (C = O) -NH-R, (C = O) - (CH₂)_n-OH, (C = O) -R, (CH₂)_n-E, - (CH₂-CH (C = O))_n-XR, - (CH₂)_n-COOH, (CH₂)_n-NH₂, -CH₂)_n- (C = O) NH₂, the index n can be an integer from about 0 to about 24, E can be an electrophilic group; R may be a saturated or unsaturated alkane, dialkylsiloxy, dialkyloxy, aryl, alkylated aryl, which may also contain an entity selected from the group consisting of cyano, OH, COOH, NH₂, NHR, sulphonate, sulfate, -NH₂, quaternized amines, thiols, aldehydes, alkoxy, pyrrolidone, pyridine, imidazole, imidazolinium halides, guanidine, phosphate, monosaccharide, oligo or polysaccharide;

c) R2 or R3 may be absent or present:

(i) when R3 is present, each R2 can be independently selected from the group consisting of -NH₂, -COO-, - (C = O) -, -O-, -S-, -NH- (C = O) -, -NRr, dialkylsiloxy, dialkyloxy, phenylene, naphthalene, alkyleneoxy; and each R3 can be independently selected from the same group as R1;

(ii) when R3 is absent, each R2 can be independently selected from the group consisting of -NH₂, -COO-, - (C = O) -, -O-, -S-, -NH- (C = O) -, -NRv, dialkylsiloxy, dialkyloxy, phenylene, naphthalene, alkyleneoxy; and each R3 can be independently selected from the same group as R1; and (iii) when R2 is absent, each R3 can be independently selected from the same group as R1;

d) the efficiency polymer (s) having an average molecular mass of from about 1000 Da to about 50,000,000 Da, from about 5000 Da, to about 25,000,000 Da, from about 10,000 Da to about 10,000,000 Da, or even from about 340,000 Da to about 1,500,000 Da; a degree of hydrolysis, for polyvinyl formamides, from about 5% to about 95%, from about 7% to about 60%, or even from about 10% to about 40%; and / or a charge density of about 1 meq / g of polymer of efficiency at about 23 meq / g

<img file="AR080330A1_D0007.tif" />

of efficiency polymer, about 1.2 meq / g of efficiency polymer and meq / g of efficiency polymer, about 2 meq / g of efficiency polymer to about 10 meq / g of efficiency polymer, or even about 1 meq / g of polymer of efficiency to about 4 meq / g of polymer of efficiency

In one aspect of the encapsulation, one or more efficiency polymers is selected from the group consisting of polyvinyl amines, polyvinyl formamides, and polyallyl amines and the copolymers thereof, the efficacy polymer (s) may have:

<td>to)</td><td colspan="3">an average molecular mass</td><td>from</td><td>approximately</td><td> 1000</td><td>Gives</td><td>to</td>

<td></td><td>approximately</td><td> 50.000.000</td><td>Gives,</td><td>from</td><td>approximately</td><td> 5000</td><td>Gives,</td><td>to</td>

<td></td><td>approximately</td><td> 25.000.000</td><td>Gives,</td><td>from</td><td>approximately</td><td> 10.000</td><td>Gives</td><td>to</td>

approximately 10,000,000 Da, or even from approximately 340,000 Da to approximately 1,500,000 Da;

b) a degree of hydrolysis, for polyvinyl formamides, from about 5% to about 95%, from about 7% to about 60%, or even from about 10% to about 40%; I

c) a loading density of about 1 meq / g of polymer of efficiency to about 23 meq / g of polymer of efficiency, of about 1.2 meq / g of polymer of efficiency and 16 meq / g of polymer of efficiency, of about 2 meq / g of polymer of efficacy to about 10 meq / g of polymer of efficiency, or even about 1 meq / g of polymer of efficiency to about 4 meq / g of polymer of efficiency.

In one aspect of the encapsulation, the coating may comprise one or more polyvinyl formamides, the polyvinyl formamides may have:

<td>to)</td><td>an average molecular mass</td><td>from</td><td>approximately</td><td>1000 Gives</td>

<td></td><td>approximately 50,000,000 Da,</td><td>from</td><td>approximately</td><td>5000 days</td>

<td></td><td>approximately 25,000,000 Da,</td><td>from</td><td>approximately</td><td>10,000 gives</td>

about 10,000,000 Da, or even about 340,000 Da to about 1,500,000 Da;

b) a degree of hydrolysis, for polyvinyl formamides, from about 5% to about 95%, from about 7% to about 60%, or even from about 10% to about 40%; Y

c) a loading density of about 1 meq / g of polymer of efficiency to about 23 meq / g of polymer of efficiency, of about 1.2 meq / g of polymer of efficiency and 16 meq / g of polymer of efficiency, of

<img file="AR080330A1_D0008.tif" />

'At about 2 meq / g of polymer of efficacy to about 10 meq / g of polymer of efficiency, or even about 1 meq / g of polymer of efficiency to about 4 meq / g of polymer of efficiency. In the aspect mentioned above, polymer efficiency is synonymous with polyvinyl formamide.

In one aspect of the encapsulation, the encapsulation may have a wall-to-wall ratio of about 1: 200 to about 1: 2, about 1: 100 to about 1: 4, or even about 1:80 to about 1:10 .

In an aspect of the encapsulation;

a) the core may comprise a material selected from the group consisting of perfumes; brighteners; dyes; insect repellents; silicones; waxes; flavorings; vitamins; fabric softening agents; skin care agents, in one aspect, paraffins; enzymes; antibacterial agents; bleachers; sensation agents; and mixtures thereof;

b) the wall may comprise a material selected from the group consisting of polyethylenes; polyamides; polystyrenes; poly brakes; polycarbonates; polyesters; polyacrylates; aminoplasts, in one aspect the aminoplast may comprise a polyurea, polyurethane and / or polyureaurethane, in one aspect the polyurea may comprise polyoxymethyleneourea and / or melamine formaldehyde; polyolefins; polysaccharides, in an alginate and / or chitosan aspect; jelly; shellac; epoxide resins; vinyl polymers; water insoluble inorganic; silicone; and mixtures of these.

In one aspect of the encapsulation the core may comprise perfume and the wall may comprise melamine formaldehyde and / or crosslinked melamine formaldehyde.

In one aspect of the encapsulation the core may comprise perfume and the wall may comprise melamine formaldehyde and / or crosslinked melamine formaldehyde, poly (acrylic acid) and poly (acrylic acid-butyl co-acrylate).

In one aspect of the encapsulation the encapsulation may comprise a perfume that may comprise one or more perfume raw materials that provide an improved perfume performance under conditions of high dirt and in cold water. Suitable perfume materials can be found in published US patent applications no. 2008 / 0031961A1 and 2008 / 0994454A1. A non-limiting list of such raw materials for perfume is described in Table 1 below.

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Table 1. Useful raw materials for perfume

<td>Element</td><td>Common Designation</td><td>IUPAC name</td>

<td> 1</td><td>Methyl 2-methyl butyrate</td><td>Methyl 2-methylbutanoate</td>

<td> 2</td><td>Isopropyl 2-Methyl Butyrate</td><td>Propan-2-yl 2-methylbutanoate</td>

<td> 3</td><td>Ethyl-2-Methyl Butyrate</td><td>Ethyl 2-methylbutanoate</td>

<td> 4</td><td>2 ethyl methylpentanoate</td><td>2 ethyl methylpentanoate</td>

<td> 5</td><td>Ethyl heptanoate</td><td>Ethyl heptanoate</td>

<td> 6</td><td>Ethyl octanoate</td><td>Ethyl octanoate</td>

<td> 7</td><td>Bsobutyl hexanoate</td><td>2-methylpropyl hexanoate</td>

<td> 8</td><td>Amyl Butyrate</td><td>Phenyl Butanoate</td>

<td> 9</td><td>Amyl Heptanoate</td><td>Pentyl Heptanoate</td>

<td> 10</td><td>Isoamyl isobutyrate</td><td>3-methylbutyl 2-methylpropanoate</td>

<td> 11</td><td>Hexyl acetate</td><td>Hexyl acetate</td>

<td> 12</td><td>Hexyl butyrate</td><td>Hexyl butanoate</td>

<td> 13</td><td>Hexyl isobutyrate</td><td>Hexyl 2-methylpropanoate</td>

<td> 14</td><td>Hexyl isovalerate</td><td>Hexyl 3-methylbutanoate</td>

<td> 15</td><td>Hexyl propionate</td><td>Hexyl Propanoate</td>

<td> 16</td><td>Ethyl 2-cyclohexyl propanoate</td><td>Ethyl 2-cyclohexyl propanoate</td>

<td> 17</td><td>Ethyl 3,5,5-trimethyl hexanoate</td><td>Ethyl 3,5,5-trimethyl hexanoate</td>

<td> 18</td><td>Glyceryl 5-hydroxidecanoate</td><td>2,3-dihydroxypropyl 5-hydroxidecanoate</td>

<td> 19</td><td>Pile Acetate</td><td>3-methyl 2-butenyl acetate</td>

<td> 20</td><td>3-methyl 2-butenyl acetate</td><td>3-methyl 2-butenyl acetate</td>

<td> 21</td><td>Methyl 3-nonenoate</td><td>Methyl Non-3-enoate</td>

<td> 22</td><td>(E) -dec-4-ethyl enoate</td><td>(E) -dec-4-ethyl enoate</td>

<td> 23</td><td>(E) -oct-2-ethyl enoate</td><td>(E) -oct-2-ethyl enoate</td>

<td> 24</td><td>Ethyl 2,4-decadienoate</td><td>(2E, 4Z) -deca-2,4-ethyl dienoate</td>

<td> 25</td><td>Ethyl 3-octenoate</td><td>(E) -oct-3-ethyl enoate</td>

<td> 26</td><td>Citronelil Acetate</td><td>3,7-dimethyloct-6-enyl acetate</td>

<td> 27</td><td>Ethyl Trans-2-Decanoate</td><td>(E) -dec-2-ethyl enoate</td>

<td> 28</td><td>2-hexen-1-yl isovalerate</td><td>[(E) -hex-2-enil acetate</td>

<td> 29</td><td>2-hexen-1-yl propionate</td><td>[(E) -hex-2-enyl Propanoate</td>

<td> 30</td><td>2-hexen-1-yl valerate</td><td>[(E) -hex-2-enyl] pentanoate]</td>

<td> 31</td><td>(E) 3-Hexen-1-yl -2-hexenoate</td><td>(E) -hex-2-enoate of [(Z) -hex-3-enil]</td>

<td> 32</td><td>3-Hexen-1-yl 2-methylbutyrate</td><td>[(Z) -hex-3-enyl] 2-methylbutanoate]</td>

<td> 33</td><td>3-hexen-1-yl acetate</td><td>[(Z) -hex-3-enil] acetate</td>

<td> 34</td><td>3-hexen-1-yl benzoate</td><td>[(Z) -hex-3-enyl] benzoate]</td>

<td> 35</td><td>3-hexen-1-yl format</td><td>Format of [(Z) -hex-3-enil]</td>

<img file="AR080330A1_D0010.tif" />

<td>Common Designation</td><td>IUPAC name</td>

<td>3-hexen-1-yl tiglate</td><td>((Z) -2-methylbut-2-enoate of [(Z) -hex-3-enyl]</td>

<td>2-methylbutyl 2-methylbutyrate</td><td>2-methylbutyl 2-methylbutanoate</td>

<td>Butyl Isovalerate</td><td>Butyl 3-methylbutanoate</td>

<td>Geranyl acetate</td><td>[(2E) -3,7-dimethylocta-2,6-dienyl] acetate</td>

<td>Geranyl Butyrate</td><td>[(2E) -3,7-dimethylocta-2,6-dienyl] butanoate]</td>

<td>Geranyl Isovalerate</td><td>[(3E) -3,7-dimethylocta-3,6dienyl] 3-methylbutanoate]</td>

<td>Geranyl propionate</td><td>Propanoate of [(2E) -3,7-dimethylocta-2,6-dienyl]</td>

<td>Allylcyclohexane Acetate</td><td>Prop-2-enyl 2-cyclohexylacetate</td>

<td>Allylcyclohexyl Propionate</td><td>Prop-2-enyl 3-cyclohexylpropanoate</td>

<td>Allylcyclohexyl Valerate</td><td>Prop-2-enyl 5-cyclohexylpentanoate</td>

<td>Benzyl Octanoate</td><td>Benzyl Octanoate</td>

<td>Cocolactone</td><td>6-pentyl-5,6-dihydropyran-2-one</td>

<td>Coconut Decanone</td><td>8-methyl-1-oxaspiro (4.5) decan-2-one</td>

<td>Gamma undecalactone</td><td>5-heptyloxolan-2-one</td>

<td>Gamma-decalactone</td><td>5-hexiloxolan-2-one</td>

<td>Gamma-dodecalactone</td><td>5-octiloxolan-2-one</td>

<td>Jasmin lactone</td><td>6 - [(E) -pent-2-enil] oxan-2-one</td>

<td>Jasmolactone</td><td>5 - [(Z) -hex-3-enyl] oxolan-2-one</td>

<td>Nonalactone</td><td>6-butyloxan-2-one</td>

<td>6-acetoxydihydroteaspiran</td><td>Acetate of [2a, 5a (S *)] - 2,6,10,10-tetramethyl-1oxaspiro [4.5] decan-6-il</td>

<td>Phenoxyethyl Isobutyrate</td><td>2- (phenoxy) ethyl 2-methylpropanoate</td>

<td>Pivacycline</td><td></td>

<td>Verdox</td><td>(2-tert-butylcyclohexyl) acetate</td>

<td>Cyclobutane</td><td>Butyrate 3a, 4,5,6,7,7a-hexahydro-4,7methane-1g-inden-5 (ô 6) -yl</td>

<td>Dimethyl anthranilate</td><td>Methyl 2-methylaminobenzoate</td>

<td>Methyl anthranilate</td><td>Methyl 2-aminobenzoate</td>

<td>Octyl aldehyde</td><td>Octane</td>

<td>Nonanal</td><td>Nonanal</td>

<td>Decylic aldehyde</td><td>Channel</td>

<td>Lauric aldehyde</td><td>Dodecanal</td>

<td>Methylnonyl acetaldehyde</td><td>Undecanal of 2-methyl</td>

<td>Methyloctylacetaldehyde</td><td>2-methyl decane</td>

<td>2,4-hexadienal</td><td>(2E, 4E) -hexa-2,4-dienal</td>

<td>Intreleven aldehyde</td><td>Undec-10-enal</td>

<img file="AR080330A1_D0011.tif" />

<td>Common designation</td><td>IUPAC name</td>

<td>Decen-1-al</td><td>(E) -dec-2-enal</td>

<td>Nonen-1-al</td><td>(E) -2-nonen-1-al</td>

<td>Adoxal</td><td>2,6,10-trimethylundec-9-enal</td>

<td>Geraldehyde</td><td>(4Z) -5,9-dimethyldeca-4,8-dienal</td>

<td>Iso citral cycle</td><td>2,4,6-trimethylcyclohex-3-ene-1-carbaldehyde</td>

<td>Mainly d-Limonene</td><td>1-methyl-4-prop-1 -en-2-yl-cyclohexene</td>

<td>Ligustral</td><td>2,4-dimethylcyclohex-3-ene-1 -carbaldeh (do</td>

<td>Aldehyde Myrac</td><td>4- (4-methylpent-3-enyl) cyclohex-3-eno-1- carbaldehyde</td>

<td>Three-year</td><td>Tridec-2-enal</td>

<td>Triplai</td><td>2,4-dimethyl-3-cyclohexen-1-carboxaldehyde</td>

<td>Vertoliff</td><td>1,2-dimethylcyclohex-3-ene-1-carbaldeh Ido</td>

<td>Ciclal C</td><td>2,4-dimethylcyclohex-3-ene-1-carbaldehyde</td>

<td>Anisic aldehyde</td><td>4-methoxybenzaldehyde</td>

<td>Helional</td><td>3- (1,3-benzodioxol-5-yl) -2-methylpropanal</td>

<td>Heliotropin Neocaspirene</td><td>1,3-benzodioxole-5-carbaldehyde</td>

<td>Beta naphthol ethyl ether</td><td>2-ethoxynaphthalene</td>

<td>Beta Naphthol Methyl Ether</td><td>2-methoxynaphthalene</td>

<td>Hyacinth ether</td><td>2-cyclohexyloxyethylbenzene</td>

<td>2-Heptyl cyclopentanone (fleuramona)</td><td>2-heptylcyclopentan-1 -one</td>

<td>Mentone-8-Thioacetate</td><td>O- [2 - [(1S) -4-methyl-2-cyclohexyl] propan-2-yl ethanethioate]</td>

<td>Nectaryl</td><td>2- [2- (4-methyl-1-cyclohex-3enyl) propyl] cyclopentan-1 -one</td>

<td>Phenyl Naphthyl Ketone</td><td>Naftalen-2-yl-phenylmetanone</td>

<td>Decen-1-il cyclopentanone</td><td>2 - [(2E) -3,7-dimethylocta-2,6-dienyl] cyclopentan-one</td>

<td>Fruity cyclopentanone (veloutona)</td><td>2,2,5-trimethyl-5-pentylcyclopentan-1-one</td>

<td>4-methoxy-2-methylbutane thiol (blackcurrant mercaptan)</td><td>4-methoxy-2-methylbutane-2-thiol</td>

<td>Grapefruit Mercaptano</td><td>2- (4-methyl-1-cyclohex-3-enyl) propane-2-thiol</td>

<td>Bucoxima</td><td>N- (1,5-dimethyl-8- bicyclo [3.2.1] octanylidene) hydroxylamine</td>

<td>Labienoxime</td><td>2,4,4,7-tetramethyl-6,8-nonadiene3-one oxime</td>

<td>Undecavertol</td><td>(E) -4-methyldec-3-en-5-ol</td>

<td>Decane Diethyl Acetal</td><td>1,1-dietxidecano</td>

<td>Element</td><td>Common Designation</td><td>IUPAC name</td>

<td> 101</td><td>Diethyl maleate</td><td>Diethyl But-2-Enedioate</td>

<td> 102</td><td>Ethyl acetoacetate</td><td>Ethyl 3-oxobutanoate</td>

<td> 103</td><td>Frutonile</td><td>2-Metildecanonitrile</td>

<td> 104</td><td>Methyl dioxolan</td><td>2- (2-methyl-1,3-dioxolan-2-yl) ethyl acetate</td>

<td> 105</td><td>Cetalox</td><td>3a, 6,6,9a-tetramethyl-2,4,5,5a, 7,8,9,9boctahydro-1H-benzo [e] [1] benzofuran</td>

<td> 106</td><td>Cyclopentol</td><td></td>

<td> 107</td><td>Delta- damascona</td><td>(E) -1- (2,6,6-Trimethyl-1-cyclohex-3-enyl) but-2-en- 1-one</td>

<td> 108</td><td>Eucalyptol</td><td>1,3,3-trimethyl-2-oxabicyclo [2,2,2] octane</td>

<td> 109</td><td>Acetate fluoride</td><td></td>

<td> 110</td><td>Gamma-methyl-ionone</td><td>(E) -3-methyl-4- (2,6,6-trimethyl-1-cyclohex-2- enil) but-3-en-2-one</td>

<td> 111</td><td>Laevo trisandol</td><td></td>

<td> 112</td><td>Linaloi</td><td>3,7-dimethylocta-1,6-dien-3-ol</td>

<td> 113</td><td>Violiff</td><td>[(4Z) -1-cyclooct-4-enyl] methyl carbonate</td>

<td> 114</td><td>Cimai</td><td>3- (4-propan-2-ylphenyl) butanal</td>

<td> 115</td><td>Bourgeonal</td><td>3- (4-tert-butylphenyl) propanal</td>

Perfume microcapsules may be contained in a suspension of perfume microcapsules.

In the context of the present invention, a suspension of perfume microcapsules is defined as a watery dispersion, containing from 10% to 50% by weight of the suspension of perfume microcapsules. The suspension of perfume microcapsules may comprise at least 20%, more preferably, at least 40%, by weight of the suspension of perfume microcapsules of encapsulated perfume ingredients.

The perfume microcapsule suspension of the present invention may comprise a water soluble sai, which is present as a residual impurity of the perfume microcapsule suspension. This residual impurity can come from other ingredients in the suspension of perfume microcapsules, which are acquired from various suppliers. In one aspect, the suspension of perfume microcapsules is purchased from a supplier. The supplier can add additional water soluble sai to the perfume microcapsule suspension to adjust the rheological profiles of the perfume microcapsule suspensions, to improve the stability of the suspension during long-term transport and storage.

<img file="AR080330A1_D0012.tif" />

In the context of the present invention, the water soluble salts of the present invention mean water soluble ionic compounds, positively charged cation compounds and negatively dissociated charged anions. In the context of the present invention, "water soluble" can be defined as a solubility in demineralized water at room temperature and atmospheric pressure. The perfume microcapsule suspension may comprise from 1 mmol / kg to 750 mmol / kg of water soluble sai. In another embodiment, the perfume microcapsule suspension may comprise from 10 mmol / kg to 750 mmol / kg of water soluble sai. Still in another embodiment the suspension of perfume microcapsules may comprise from 1 to 265 mmol / kg of water soluble sai.

In one aspect the water soluble salts present in the suspension of perfume microcapsules are formed of polyvalent cations selected from the group comprising alkaline earth metals, transition metals or metals, together with monoatomic or polyatomic anions. In another embodiment, the water soluble sai comprises cations, the cations are selected from the group comprising berillo, magnesium, calcium, strontium, barium, scandium, titanium, iron, copper, aluminum, zinc, germanium, serium. In another embodiment, the water-soluble sai comprises anions, the anions are selected from the group comprising fluorine, chlorine, bromine, iodine, acetate, carbonate, citrate, hydroxide, nitrate, phosphite, phosphate and sulfate. In one embodiment the anions are the monoatomic anions of the halogens.

In addition to the encapsulates described in the present description, a suspension is described which may comprise a polymer-coated encapsulation of efficacy, wherein the suspension can have a zeta potential of about 10 meV to about +50 meV, preferably, about +2 meV to about +40 meV, more preferably, from about +5 meV to about +25 meV or from about -40 meV to about +35 meV, preferably, from about -38 meV to about +25 meV, more preferably, from about -35 meV to about +10 meV. In one aspect the suspension can obtain the appropriate level of efficiency polymer, as a result, the efficiency polymer that is part of the encapsulation and / or the encapsulation comprising the efficiency polymer can be made by combining a suspension comprising encapsulation with one or more efficiency polymers

In addition to the encapsulates described in the present description, a suspension which may comprise, based on a total suspension weight, a sufficient amount of polymer coated capsules of efficacy

<img file="AR080330A1_D0013.tif" />

they provide the suspension from about 0.05% to about 10%, from about 0.1% to about 5%, from about 0.125% to about 2% of an efficiency polymer.

In one aspect a suspension is described which may comprise, based on the total weight of the suspension, from about 0.01% to about 5%, from about 0.05% to about 2% or even from about 0.1% to about 1% of a polyvinyl formamide, from about 0% to about 5% MgCI₂, from about 0.1 to about 3% MgCI₂from about 0.2% to about 2.5% MgCI₂ from about 0% to about 1% xanthan gum, from about 0.05% to about 0.5%, from about 0.1% to about 0.25% xanthan gum and one or more of the encapsulates coated or not coated.

In one aspect of the suspension, polyvinyl formamide may have:

<td>to)</td><td colspan="3">an average molecular mass</td><td>from</td><td>approximately</td><td> 1000</td><td>Gives</td><td>to</td>

<td></td><td>approximately</td><td> 50.000.000</td><td>Gives,</td><td>from</td><td>approximately</td><td> 5000</td><td>Gives,</td><td>to</td>

<td></td><td>approximately</td><td> 25.000.000</td><td>Gives,</td><td>from</td><td>approximately</td><td> 10.000</td><td>Gives</td><td>to</td>

approximately 10,000,000 Da, or even from approximately 340,000 Da to approximately 1,500,000 Da;

b) a degree of hydrolysis, for polyvinyl formamides, from about 5% to about 95%, from about 7% to about 60%, or even from about 10% to about 40%; Y

c) a loading density of about 1 meq / g of polyvinyl formamide to about 23 meq / g of polyvinyl formamide, of about 1.2 meq / g of polyvinyl formamide and 16 meq / g of polyvinyl formamide, of about 2 meq / g of polyvinyl formamide at about 10 meq / g of polyvinyl formamide, or even about 1 meq / g of polyvinyl formamide at about 4 meq / g of polyvinyl formamide.

In one aspect a process for preparing a suspension is described which comprises combining, in any order, an encapsulation, an efficiency and stabilization system and, optionally, a biocide. In one aspect the efficiency polymer may comprise polyvinyl formamide, the stabilization system may comprise MgCI₂ and xanthan gum.

In one aspect of the process for making an improved suspension, the encapsulation and the efficacy agent are allowed to be in close contact for at least 15 minutes, for at least 1 hour, or for at least 4 hours before

<img file="AR080330A1_D0014.tif" />

that the suspension be used in a product or used to produce a chipboard.

In one aspect, any of the encapsulates and / or suspensions described in the present description can be used to produce an agglomerate.

In one aspect, a process for making the agglomerate, the processor comprises:

a) combine an encapsulation and / or suspension; a plasticizer, in one aspect, a plasticizer comprising water; and, optionally, a binder and / or chelator to form a mixture;

b) combining the mixture with the dusting agent, in one aspect, a dusting agent comprising silica, to form a material; Y

c) removing a sufficient quantity of the plasticizer from the material to render a product comprising, based on the total weight of the product from 1% to 50% plasticizer.

In one aspect, the plasticizer comprises water.

Suitable capsules that can be converted into the high efficiency capsules described herein may be made in accordance with the applicants description, which include, but are not limited to, the applicants' examples, the description of US patents. . UU. no. USPA 2008/0305982 A1 and / or USPA 2009/0247449 A1. Optionally, suitable capsules can be purchased from Appleton Papers Inc. of Appleton, Wisconsin, United States.

Additionally, the materials for preparing the aforementioned encapsulates can be obtained from CP Kelco Corp. of San Diego, California, United States; BASF AG, from Ludwigshafen, Germany; Rhodia Corp. of Cranbury, New Jersey, United States; Hercules Corp. of Wilmington, Delaware, United States; Agrium Ine. from Calgary, Alberta, Canada, ISP from New Jersey United States, Akzo Nobel from Chicago, IL, United States; Stroever Shellac Bremen of Bremen, Germany; Dow Chemical Company of Midland, MI, United States; Bayer AG of Leverkusen, Germany; Sigma-Aldrich Corp., St. Louis, Missouri, United States.

Suitable efficacy polymers, such as polyvinyl amide polyvinyl amine copolymers, can be produced by selective hydrolyzing of the polyvinyl formamide starter polymer.

Suitable efficiency polymers can also be formed by copolymerization of vinyl formamide with acrylamide, acrylic acid, acrylonitrile, ethylene, sodium acrylate, methyl acrylate, maleic anhydride, vinyl acetate, n-vinyl pyrrolidine.

Suitable efficiency polymers or oligomers can also be formed.

VL by cationic polymerization of vinyl formamide with protonic acids, tgibs as methylsulfonic acid, and / or Lewis acids, such as boron trifluoride.

Suitable efficacy polymers can be obtained from BASF AG of Ludwigshafen, Germany and include Lupamin® 9010 and Lupamin® 9030.

Process for making encapsulated with coating

In one aspect a process is described for preparing a coated encapsulation comprising combining an encapsulation and one or more efficiency polymers.

In one aspect, a process for making a coated encapsulation, wherein the encapsulation, when combined with the efficacy polymer (s), is contained in a suspension.

In one aspect a process for making a coated encapsulation is described, in which a sufficient amount of efficiency polymer is combined with the suspension, to provide the suspension of about 0.05% to about 10%, about 0.1% at about 5%, or even about 0.125% to about 2% of the efficiency polymer, based on the total weight of the suspension.

The high efficiency polymers used to make the aforementioned coated encapsulates may be the efficacy polymers described in the high efficiency γ suspension / agglomerated sections comprising them of the present description.

Consumable product

In one aspect a consumer product is described which comprises any of the encapsulates, an agglomerate comprising encapsulated taies and / or suspensions described in this description.

In one aspect of the consumer product, the consumer product may be a cleaning and / or treatment composition.

In one aspect of the consumer product, the consumer product may be a laundry detergent and / or a fabric softener.

In one aspect of the consumer product, the consumer product may be a detergent for fluid laundry. The laundry detergent fluid, in one aspect, may comprise, based on the total weight of laundry detergent fluid, from about 3% to about 80%, from about 3% to * 8 about 70%, from about 5% to about 60%, even about 8% to about 50% water.

In one aspect of the fluid detergent, the fluid detergent may be a liquid laundry detergent.

In one aspect of the consumer product, the consumer product can be a fabric softener. The fluid fabric softener, in one aspect, may comprise, based on the total weight of fabric fabric softener, from about 30% to about 90%, from about 55% to about 90%, from about 65% to about 85 %, or even about 70% to about 85% water.

In one aspect of the fabric fabric softener, the fabric fabric softener can be a liquid fabric softener.

In one aspect of the consumer product, the consumer product may be solid detergent and an additional ingredient.

In one aspect of the consumer product, the consumer product may be a fluid product for beauty care, for example, a shampoo. The fluid beauty care product, in one aspect, comprises, based on the total weight of the fluid beauty care product, from about 30% to about 95%, from about 55% to about 90%, or even about 65% to about 85% water.

In one aspect of the consumer product, the consumer product may be a conditioner.

In one aspect the consumer product may comprise a sufficient amount of suspension and / or encapsulation to provide the consumer product with a level of polymer efficiency, based on the total weight of consumer product, from about 0.0001% to about 0.1%, from about 0.001% to about 0.1%, or even from about 0.001% to about 0.05%.

In one aspect the consumer product may comprise a material selected from the group consisting of an anionic surfactant, cationic surfactant, silicone and mixtures thereof, the consumer product may also have:

a) an ratio of anionic surfactant to polymer of efficacy of about 100,000: 1 to about 1: 1, of about

25,000: 1 to about 10: 1, or even about 10,000: 1 to about 100: 1;

in,

b) a ratio of cationic surfactant to polymer of efficacy of about 100,000: 1 to about 1: 1, of about 25,000: 1 to about 10: 1, or even about 10,000: 1 to about 100: 1; I

c) a silicone to polymer ratio of efficiency of about 100,000: 1 to about 1: 1 of about 25,000: 1 to about 10: 1, or even about 10,000: 1 to about 100: 1.

In one aspect the encapsulates described in the present description are suitable for use in consumer products, cleaning and treatment compositions and compositions, detergents and highly compacted consumer products, for cleaning and / or treatment of fabric and hard surfaces, including compositions. highly compacted for cleaning and / or treatment of fabric and hard surfaces, for example, highly compacted detergents that can be solid or fluid, in levels, based on the total weight of the consumer product, from about 0.001% to about 20%, from about 0.01% to about 10%, from about 0.05% to about 5%, from about 0.1% to about two%.

In one aspect a consumer product is described which comprises an additional ingredient selected from the group consisting of polymers, in one aspect, a cationic polymer, surfactants, structuring agents, chelating agents, optical brighteners, dye transfer activators, dispersants, enzymes, Enzyme stabilizers, catalytic materials, bleach activators, polymeric dispersants, clay removal agents / dirt deposits, brighteners, polymeric dye conjugates; dye clay conjugates, foam suppressants, dyes, bleach catalysts, additional perfume systems and / or perfume supply, structure elasticizing agents, fabric softener, carriers, hydrotropes, processing aids, rheology modifiers, agents structuring, thickeners, pigments, water and mixtures thereof.

In one aspect, a consumer product comprising an additional ingredient comprising a rheology modifier, thickener and / or structuring agent having a higher shear viscosity, at 20 sec-1 shear rate and at 21 ° C, of ​​1 at 7000 cps and a lower shear viscosity (0.5 sec-1 shear rate at 21 ° C) greater than 1000 cps, or even 1000 cps at 200,000 cps. In one aspect, for cleaning and treatment compositions, rheology modifiers "U impart to the aqueous liquid composition a higher shear viscosity, at 20 sec-1 and at 21 ° C, of ​​50 to 3000 cps and a lower shear viscosity (0.5 sec-1 shear rate at 21 ° C) greater than 1000 cps, or even 1000 cps at 200,000 cps. In one aspect, suitable rheology modifiers, thickeners and / or structuring agents, can be selected from the group consisting of polyacrylates, quaternized polyacrylates, polymethacrylates, polyamides, quaternized polymethacrylates, polycarboxylates, polymeric taies corne pectin gums, alginate, arabinogalactan (gum arâbiga), carrageenan, gellan gum, xanthan gum and guar gum, other non-gummy polysaccharides as gellan gum, and combinations of these polymeric materials, hydroxyl-containing fatty acids, fatty esters or fatty waxes, castor oil and its derivatives, derivatives of hydrogenated castor oil, such as hydrogenated castor oil and hydrogenated castor wax; and mixtures of these.

In one aspect a consumer product is described, the consumer product is a fluid detergent and comprises, based on the total weight of fluid detergent, less than about 80% water, less than about 60% to about 2% water , from about 45% to about 7% water, from about 35% to about 9% water.

In addition to the encapsulates described in the present description, certain perfume delivery systems can be used in the compositions and / or consumer products mentioned above. The methods for making such systems and methods of perfume delivery are described in US Pat. UU. no. USPA 2007/0275866 A1. Taies perfume supply systems include: Polymer Assisted Supply (PAD), Molecule Assisted Supply (MAD), Fiber Assisted Supply (FAD), Amine Assisted Supply (AAD) its acronym in English), assisted supply of cyclodextrin (CD), encapsulated starch supply (SEA), inorganic carrier supply system (ZIC), perfume precursor (PP, for its acronym in English). Such perfume delivery systems can be used in any combination in any type of consumer product, cleaning composition and / or for treatment, composition, detergent, and highly compacted cleaning detergent and / or for treatment of fabric and hard surfaces.

Perfume microcapsule

It is convenient to add perfume in the form of encapsulated perfume ingredients to a composition, since the encapsulation of the perfume ingredients allows the controlled, and often directed, release of the perfume ingredients. Perfume ingredients are the individual chemical compounds that are used to make a perfume composition. A perfume composition comprises one or more perfume ingredients, the choice of the type and number of ingredients depends on the desired final essence. The present invention may comprise perfume microcapsules. It is known to those with experience in the field that perfume microcells release perfume ingredients during fabric handling and during the dressing process, which gives the fabrics a freshness that lasts longer, compared to the addition of Only pure perfume. The release of the perfume ingredients is activated by mechanical stress that breaks the capsule wall and allows the diffusion of the encapsulated perfume ingredient.

A perfume microcapsule comprises a capsule that surrounds a core, the core comprises perfume ingredients. The capsule may be made of a series of materials, but the most preferred is crosslinked melamine formaldehyde. The capsule wall material may comprise a suitable resin that includes the reaction product of an aldehyde and an amine, suitable aldehydes include formaldehyde. Suitable amines may include those selected from the group comprising melamine, urea, benzoguanamine, glycoluril, and mixtures thereof. Suitable melamines may include those selected from the group comprising methylol melamine, methylol methylamine, imino melamine and mixtures thereof. Suitable ureas may include those selected from the group comprising dimethylol urea, methylated dimethylol urea, urearesorcinol, and mixtures thereof.

In the context of the present invention any suitable perfume ingredient can be used. Those skilled in the art will recognize compatible ingredients suitable for use in perfume microcapsules, and will know how to select combinations of ingredients to achieve the desired essences.

In one aspect, at least 75%, 85% or even 90% of the perfume microcapsules may have a particle size of about 1 micron to about 80 microns, about 5 microns to 60 microns, about 10 microns to about 50 microns, or even about 15 microns to about 40 microns.

At least 75%, 85% or even 90% of the perfume microcapsules may have a particle wall thickness of about 60 nm to about 250 nm, about 80 nm to about 180 nm, or even about 100 nm at approximately 160 nm.

The liquid fabric softener compositions of the present invention comprise from 0.05% to 0.8% by weight of the liquid fabric softener composition of encapsulated perfume ingredients, present in the form of a perfume microcapsule. This amount is necessary to ensure that enough perfume is deposited on the fabrics. Perfume and perfume microcapsules are removed by washing during the laundry process. Therefore, it is important to have enough perfume in the liquid fabric softener composition to take account of the unavoidable loss and, thus, achieve sufficient deposit on the fabrics.

In one aspect the perfume microcapsule can be spray dried.

Suspension of perfume and chipboard microcapsules

Auxiliary materials

For the purpose of the present invention, the non-limiting list of additional ingredients illustrated in the present description below is suitable for use in the compositions of the present invention, and these may be conveniently incorporated into certain embodiments of the invention, for example, to assist or improve performance, to treat the substrate to be cleaned or to modify the aesthetics of the composition as is the case of perfumes, dyes, tinctures or the like. It is understood that such additives are additional to the components that are supplied by the agglomerated packages and / or solutions of the Applicants. The precise nature of these additional components and the levels of incorporation of these will depend on the physical form of the composition and the nature of the operation for which they will be used. Additional materials include, but are not limited to, surfactants, additives, chelating agents, dye transfer inhibiting agents, dispersants, enzymes and enzyme stabilizers, catalytic materials, bleaching activators, polymeric dispersing agents, removal / anti-redeposition agents. clay dirt, brighteners, foam suppressors, dyes, additional perfumes and perfume delivery systems, agents for elasticizing the structure, fabric softeners, carriers, hydrotropes, process assistants and / or pigments. In addition to the following discussion, suitable examples of such additional ingredients and levels of use are found in US Pat. n .ms 5,576,282, 6,306,812 B1 and 6,326,348 B1 incorporated as reference.

<img file="AR080330A1_D0015.tif" />

Each of the additional ingredients is not indispensable for the applicants' compositions. Therefore, certain modalities of the applicants' compositions do not contain one or more of the following additional materials: bleaching activators, surfactants, additives, chelating agents, dye transfer inhibitors, dispersants, enzymes and enzyme stabilizers, catalytic metal complexes, polymeric dispersing agents, clay stain removal / anti-redeposition agents, brighteners, foam suppressors, dyes, additional perfumes and perfume delivery systems, structure elasticizing agents, fabric softeners, carriers, hydrotropes, process auxiliaries and / or pigments. However, when one or more additional ingredients are present, these should be included as specified below:

Surfactants The compositions according to the present invention may comprise a surfactant or surfactant system, wherein the surfactant can be selected from nonionic, and / or anionic, and / or cationic, and / or ampholytic and / or zwitterionic and / or zwitterionic surfactants non-ionic semipolars. Typically, the surfactant is present at a level of about 0.1%, about 1%, or even about 5%, by weight of the cleaning compositions, at about 99.9%, at about 80%, a about 35%, or even about 30% by weight of the cleaning compositions.

Additives The compositions of the present invention may comprise one or more detergent additives or additive systems. When present, the compositions will typically comprise at least about 1% additive, or from about 5% or 10% to about 80%, 50% or even 30% by weight, of the additive. Additives include, but are not limited to, alkali metal, ammonium and alkanolammonium salts of polyphosphates, alkali metal silicates, alkaline earth metal and alkali metal carbonates, aluminosilicate additives, polycarboxylate compounds; hydroxypolycarboxylated ethers, copolymers of maleic anhydride with ethylene or methyl vinyl ether, 1,3,5-trihydroxybenzene-2,4,6-trisulfonic acid and carboxymethyl-oxysuccinic acid; the various alkali metal, ammonium and substituted ammonium salts of polyacetic acids, taies as tetraacetic acid ethylenediamine and nitrilotriacetic acid, as well as polycarboxylates, such as melitic acid, succinic acid, oxydisuccinic acid, polymethyl acid, 1,3,5benzene-tricarboxy acid carboxymethyloxysuccinic acid, and soluble salts thereof.

<img file="AR080330A1_D0016.tif" />

Chelating agents The compositions herein may also optionally comprise one or more chelating agents of copper, iron and / or manganese. If used, the chelating agents will generally comprise from about 0.1%, by weight of the compositions of the present invention, to about 15%, or even from about 3.0% to about 15% by weight of the compositions of the present invention.

Dye transfer inhibiting agents: the compositions of the present invention may also include one or more dye transfer inhibiting agents. Suitable dye transfer polymeric agents include, but are not limited to, polyvinyl pyrrolidone polymers, Ν-oxide polyamine polymers, N-vinyl pyrrolidone and N-vinylimidazole copolymers, polyvinyloxazolidones and polyvinylimidazoles or mixtures thereof. If included in the compositions of the present invention, the dye transfer inhibitors are present at levels of about 0.0001%, about 0.01%, about 0.05%, by weight of the cleaning compositions , at about 10%, about 2%, or even about 1% by weight of the cleaning compositions.

Tonalizing agents. Optical fluorescent brighteners emit at least some visible light. In contrast, fabric dyeing agents can alter the dyeing of a surface by absorbing at least a portion of the visible light spectrum. Tonalizing agents include dyes, dye-clay conjugates. Suitable dyes include small molecule dyes and polymeric dyes. Small molecule dyes include small molecule dyes selected from the group consisting of:

(1) Tri-azo direct grade blue dyes of the formula:

<img file="AR080330A1_D0017.tif" />

wherein at least two of the naphthyl rings A, B and C are substituted with a group 23

<img file="AR080330A1_D0018.tif" />

sulfonate; ring C may be substituted in position 5 with an NH group₂ or NHPh, X is a benzyl or naphthyl ring substituted with up to 2 sulfonate groups and can be substituted in the 2 position with an OH group and can also be substituted with an NH group₂oNHPh.

(2) Direct violet bis-azo dyes with the formula:

<img file="AR080330A1_D0019.tif" />

wherein Z is H or phenyl, ring A is preferably substituted by a methyl and methoxy group at the positions indicated by the fleets, ring A can also be a naphthyl ring, group Y is a benzyl ring or Naphthyl, which is substituted by a sulfate group and can be mono- or disubstituted by methyl groups.

(3) Blue or red acid grade formula dyes

<img file="AR080330A1_D0020.tif" />

where at least one of X and Y must be an aromatic group. In one aspect, both aromatic groups may be a substituted benzyl or naphthyl group, which may be substituted by non-water soluble groups such as alkyl or alkyloxy or aryloxy groups, X and Y cannot be substituted with water soluble groups such as sulphonates or carboxylates . In another aspect, X is a nitro substituted benzyl group and Y is a benzyl group.

(4) Red dyes acid grade structure

<img file="AR080330A1_D0021.tif" />

ίν

<img file="AR080330A1_D0022.tif" />

<img file="AR080330A1_D0023.tif" />

wherein B is a naphthyl or benzyl group that can be substituted with non-water soluble groups such as alkyl or alkyloxy or aryloxy groups, B cannot be substituted with water soluble groups such as sulphonates or carboxylates.

<img file="AR080330A1_D0024.tif" />

&lt;HO₃S)_n

<img file="AR080330A1_D0025.tif" />

SW₃h where X and Y, independently of each other, are each hydrogen, C alkyl_rC₄ or CrC ^ Ra alkoxy is hydrogen or aryl, Z is Ci-C alkyl₄; CrC alkoxy₄; halogen; hydroxyl or carboxyl, n is 1 or 2 and m is 0, 1 or 2, as well as the corresponding salts thereof and mixtures thereof (6) Triphenylmethane dyes of the following structures

<img file="AR080330A1_D0026.tif" />

<img file="AR080330A1_D0027.tif" />

<img file="AR080330A1_D0028.tif" />

<img file="AR080330A1_D0029.tif" />

<img file="AR080330A1_D0030.tif" />

and mixtures of these. In another aspect suitable small molecule dyes include the small molecule dyes listed below, some of these dyes are selected from the group consisting of the Color Index (Society of Dyers and Colourists, Bradford, UK). 1,4-naphthalenedione, 1- [2- [2- [4 - [[4- (acetyloxy) butyl] ethylamino] -2methylphenyl] diazenyl] -5-nitro-3-thienyl] -ethanone, 1-hydroxy acid 2- (1-Naphthalenedylazo) naphthalenedisulfonic acid, ion (2-), 1-hydroxy-2 - [[4- (phenylazo) phenyl] azo] -Naphthalenedisulfonic acid, ion (2-), acid 2 - [(1 E) - [4- [bis (3-methoxy-3-oxopropyl) amino] -2-methylphenyl] azo] -5-nitro-3-thiophenecarboxylic, ethyl ester, 2 - [[4 - [(2-cyanoethyl) ethylamino] phenyl] azo] -5- (phenylazo) -3thiophenecarbonitrile, 2- [2- [4 - [(2-Cyanoethyl) ethylamino] phenyl] diazenyl] -5- [2- (4-nitrophenyl) diazenyl] -3thiophenecarbonitrile, 2-hydroxy-1- (1-naphthalenylazo) -naphthalenedisulfonic acid , ion (2-), 2-hydroxy-1 - [[4- (phenylazo) phenyl] azo] -naphthalenedisulfonic acid, ion (2-), 4,4 '- [[4- (dimethylamino) -2,5cyclohexadien-1 -ylidene] methylene] bis [N, N-dimethyl-benzenamine, 6-hydroxy-5 - [(4-methoxyphenyl) azo] -2-naphthalenesulfonic acid, monosodium sai, 6-hydroxy-5 - [(4-methylphenyl) azo ] 2-Naphthalenesulfonic, monosodium sai, 7-hydroxy-8 - [[4- (phenylazo) phenyl] azo] -1,3naphthalenedisulfonic acid, ion (2-), 7-hydroxy-8- [2- (1-naphthalenyl) diazenyl] -1,3naphthalenedisulfonic acid , ion (2-), 8-hydroxy-7- [2- (1-naphthalenyl) diazenyl] -1,3-naphthalenedisulfonic acid, ion (2-), 8-hydroxy-7- [2- [4- (2 -phenyldiazenil) phenyl] diazenyl] -1,3-naphthalenedisulfonic acid, ion (2-), acid black 1, acid black 24, acid blue 113, acid blue 15, acid blue 17, acid blue 25, acid blue 29, acid blue 3, acid blue 40, acid blue 45, acid blue 62, Acid Blue 7, Acid Blue 75, Acid Blue 80, Acid Blue 83, Acid Blue 9, Acid Blue 90, Acid Green 27, Acid Orange 12, Acid Orange 7, Acid Red 14, Acid Red 150, Acid Red 151, Acid Red 17, acidic red 18, acidic red 266, acidic red 27, acidic red 4, acidic red 51, acidic red 52, acidic red 73, acidic red 87, acidic red 88, acidic red 92, acidic red 94, acidic red 97, acid violet 15, acid violet 17, acid violet 24, acid violet 43, acid violet 49, basic blue 159, Basic Blue 16, Basic Blue 22, Basic Blue 3, Basic Blue 47, Basic Blue 66, Basic Blue 75, Basic Blue 9, Basic Violet 1, Basic Violet 2, Basic Violet 3, Basic Violet 4, Basic Violet 10, Basic Violet 35, Cl acid black 1, Cl acid blue 10, Cl acid blue 113, Cl acid blue 25, Cl acid blue 29, Cl acid blue 290 Cl acid red 103, Cl acid red 150, Cl acid red 52, Cl acid red 73 , Cl acid red 88, Cl acid red 91, Cl violet acid 17, Cl Acid Violet 43, Direct Blue Cl 1, Direct Blue Cl 120, Direct Blue Cl 34, Direct Blue Cl 70, Direct Blue Cl 71, Direct Blue Cl 72, Direct Blue Cl 82, Direct Violet Cl 51, Dispersed Blue Cl 10, Cl dispersed blue 100, dispersed blue Cl 101, dispersed blue Cl 102, dispersed blue Cl 106: 1, dispersed blue Cl 11, dispersed blue Cl 12, dispersed blue Cl 121, dispersed blue Cl 122, dispersed blue Cl 124, dispersed blue Cl , Cl blue dispersed 128, Cl scattered blue 130, Cl blue

<img file="AR080330A1_D0031.tif" />

dispersed 133, dispersed blue Cl 137, dispersed blue Cl 138, dispersed blue Cl 139, dispersed blue Cl 142, dispersed blue Cl 146, dispersed blue Cl 148, dispersed blue Cl 149, dispersed blue Cl 165, dispersed blue Cl 165: 1, Dispersed blue Cl 165: 2, Dispersed blue Cl 165: 3, Dispersed blue Cl 171, Dispersed blue Cl 173, Dispersed blue Cl 174, Dispersed blue Cl 175, Dispersed blue Cl 177, Dispersed blue Cl 183, Dispersed blue Cl 187, Cl scattered blue 189, Cl dispersed blue 193, dispersed blue Cl 194, dispersed blue Cl 200, dispersed blue Cl 201, dispersed blue Cl 202, dispersed blue 205, dispersed blue Cl 206, dispersed blue Cl 207, dispersed blue Cl 209, dispersed blue Cl 21, Cl dispersed blue 210, dispersed blue Cl 211, dispersed blue Cl 212, dispersed blue Cl 219, dispersed blue Cl 220, dispersed blue Cl 222, dispersed blue Cl 224, dispersed blue Cl 225, dispersed blue Cl 248, dispersed blue Cl 252, Cl dispersed blue 253, dispersed blue Cl 254, dispersed blue Cl 255, dispersed blue Cl 256, dispersed blue Cl 257, dispersed blue Cl 258, dispersed blue Cl 259, dispersed blue Cl 260, dispersed blue Cl 264, dispersed blue Cl 265, Cl dispersed blue 266, Dispersed blue Cl 267, Dispersed blue Cl 268, Dispersed blue Cl 269, Dispersed blue Cl 270, Dispersed blue Cl 278, Dispersed blue Cl 279, Dispersed blue Cl 281, Dispersed blue Cl 283, Dispersed blue Cl 284, Cl dispersed blue 285, Dispersed blue Cl 286, Dispersed blue Cl 287, Dispersed blue Cl 290, Dispersed blue Cl 291, Dispersed blue Cl 294, Dispersed blue Cl 295, Dispersed blue Cl 30, Dispersed blue Cl 301, Dispersed blue Cl 303, Cl dispersed blue 304, dispersed blue Cl 305, dispersed blue Cl 313, dispersed blue Cl 315, dispersed blue Cl 316, dispersed blue Cl 317, dispersed blue Cl 321, dispersed blue Cl 322, dispersed blue Cl 324, dispersed blue Cl 328, Cl dispersed blue 33, dispersed blue Cl 330, dispersed blue Cl 333, dispersed blue Cl 335, dispersed blue Cl 336, dispersed blue Cl 337, dispersed blue Cl 338, dispersed blue Cl 339, dispersed blue Cl 340, dispersed blue Cl 341, Cl dispersed blue 342, dispersed blue Cl 343, dispersed blue Cl 344, dispersed blue Cl 345, dispersed blue Cl 346, dispersed blue Cl 351, dispersed blue Cl 352, dispersed blue Cl 353, dispersed blue Cl 355, dispersed blue Cl 356, Cl dispersed blue 357C.I. dispersed blue 358, dispersed blue Cl 36, dispersed blue Cl 360, dispersed blue Cl 366, dispersed blue Cl 368, dispersed blue Cl 369, dispersed blue Cl 371, dispersed blue Cl 373, dispersed blue Cl 374, dispersed blue Cl 375, Cl dispersed blue 376, dispersed blue Cl 378, dispersed blue Cl 38, dispersed blue Cl 42, dispersed blue Cl 43, dispersed blue Cl 44, dispersed blue Cl 47, dispersed blue Cl 79, dispersed blue Cl 79: 1, dispersed blue Cl 79 : 2, Cl blue dispersed 79: 3, Cl dispersed blue 82, dispersed blue Cl 85, dispersed blue Cl 88, dispersed blue Cl 90, dispersed blue Cl 94, dispersed blue Cl 96, dispersed violet Cl 10, dispersed violet Cl 100, dispersed violet Cl 102, dispersed violet Cl 103, Cl scattered violet 104, Cl violet

<img file="AR080330A1_D0032.tif" />

dispersed 106, Dispersed violet Cl 107, Dispersed violet Cl 12, Dispersed violet Cl 13, Dispersed violet Cl 16, Dispersed violet Cl 2, Dispersed violet Cl 24, Dispersed violet Cl 25, Dispersed violet Cl 3, Dispersed violet Cl 33, Violet Cl scattered 39, Cl dispersed violet 42, Cl dispersed violet 43, Dispersed violet Cl 45, Dispersed violet Cl 48, Dispersed violet Cl 49, Dispersed violet Cl 5, Dispersed violet Cl 50, Dispersed violet Cl 53, Cl scattered violet 54, Cl scattered violet 55, Cl scattered violet 58, Scattered violet Cl 6, Scattered violet Cl 60, Scattered violet Cl 63, Scattered violet Cl 66, Scattered violet Cl 69, Scattered violet Cl 7, Scattered violet Cl 75, Cl scattered violet 76, Cl dispersed violet 77, Cl dispersed violet 82, Cl dispersed violet 86, Dispersed violet Cl 88, Dispersed violet Cl 9, Dispersed violet Cl 91, Dispersed violet Cl 92, Dispersed violet Cl 93, Cl dispersed violet 93: 1, dispersed violet Cl 94, dispersed violet Cl 95, dispersed violet Cl 96, dispersed violet Cl 97, dispersed violet Cl 98, dispersed violet Cl 99, reactive black Cl 5, reactive blue Cl 19, reactive blue Cl 4 , Reactive red Cl 2, Solvent blue Cl 43, Solvent blue Cl 43, Solvent red Cl 14, Acid black Cl 24, Acid blue Cl 113, Acid blue Cl 29, Direct violet Cl 7, Cl food red 14, Dianix CC violet, direct blue 1, direct blue 71, direct blue 75, direct blue 78, direct blue 80, direct blue 279, direct violet 11, direct violet 31, direct violet 35, direct violet 48, direct violet 5, direct violet 51, direct violet 66, direct violet 9, dispersed blue 106, dispersed blue 148, dispersed blue 165, dispersed blue 3, dispersed blue 354, dispersed blue 364, dispersed blue 367, dispersed blue 56, dispersed blue 77, scattered blue 79, scattered blue 79: 1, scattered red 1, scattered red 15, scattered violet 26, scattered violet 27, scattered violet 28, scattered violet 63, scattered violet 77, eosin Y, ethanol, 2.2 '- [[4 [(3 , 5-dinitro-2-thienyl) azo] phenyl] imino] bis-, diacetate (ester), blue 650 Lumogen F, violet 570 Lumogen F, N- [2- [2- (3-acetyl-5-nitro- 2-thienyl) diazenil] -5- (diethylamino) phenyl] acetamide, N- [2- [2- (4-chloro-3-cyano-5-formyl-2-thienyl) diazenyl] -5- (diethylamino) phenyl ] acetamide, N- [5- [bis (2-methoxyethyl) amino] -2- [2- (5-nitro-2,1-benzisothiazol-3-yl) diazenyl] phenyl] acetamide, N- [5- [bis [2 - (acetyloxy) ethyl] amino] -2 - [(2-bromo-4,6-dinitrophenyl) azo] phenyl] acetamide, naphthalimide, derivative, petroleum black 860, Floxin B, pyrazole, Bengal rose, 6-hydroxy -5- (4-Isopropylphenylazo) -2-sodium naphthalenesulfonate, solvent black 3, solvent blue 14, solvent blue 35, solvent blue 58, solvent blue 59, solvent red 24, solvent violet 13, solvent violet 8, Sudan red 380, triphenylmethane, and triphenylmethane, derivatives and mixtures thereof.

Additional suitable tonalizing agents include, but are not limited to, the thiophenes and thiazoliums described below. Suitable thiophenes can be characterized by the following structure:

<img file="AR080330A1_D0033.tif" />

<img file="AR080330A1_D0034.tif" />

<img file="AR080330A1_D0035.tif" />

where and R₂ can be selected independently of:

a) [(CH₂CR'HO)_x(CH₂CRHO)_YH] where R 'is selected from the group consisting of H, CH₃, CH₂O (CH₂CH₂OR)_ZH, and mixtures thereof; where R is selected from the group consisting of H, CH₂O (CH₂CH₂OR)_ZH, and mixtures thereof; where x + y &lt;5; where ys 1; and where z = 0 to 5;

b) Ri = alkyl, aryl or aryl alkyl and R₂ = [(CH2CR'HO)_x(CH₂CRHO)_YH] where R 'is selected from the group consisting of H, CH₃, CH₂O (CH₂CH₂OR)_ZH, and mixtures thereof; wherein R "is selected from the group consisting of H, CH₂O (CH₂CH₂OR)_zH, and mixtures thereof; where x + y &lt;10; where and&gt; 1; and where z = 0 to 5;

c) R! = [CH₂CH₂(OR₃) CH₂OR₄] and R₂ = [CH₂CH₂(OR₃) CH₂OR₄] where R₃ is selected from the group consisting of H, (CH₂CH₂OR)_ZH, and mixtures thereof; and where z = 0 to 10;

where R₄ it is selected from the group consisting of (CvCie) alkyl, aryl groups, and mixtures thereof; Y

d) wherein R1 and R2 may be independently selected from the product of the addition of styrene oxide amino, glycidyl methyl ether, glybutyl ether isobutyl, isopropylglycidyl ether, glycidyl t-butyl ether, 2-ethylhexylidethyl ether, and glycidylhexadecyl ether, followed by the addition of 1 to 10 alkylene oxide units.

In one aspect such thiophenes can be characterized by the following structure:

Ol ·

<img file="AR080330A1_D0036.tif" />

H

<img file="AR080330A1_D0037.tif" />

N [(CH₂CR'HO) x (CH₂CRHO) and H]₂ where R 'is selected from the group consisting of H, CH₃, CH2O (CH₂CH₂OR)_ZH, and mixtures thereof; wherein R "is selected from the group consisting of H, CH₂O (CH₂CH₂OR)_zH, and mixtures thereof; where x + and S5; where and £ 1; and where z = 0 to 5.

Suitable thiazolium dyes include azo colors which may have the following Formula (I):

Ri Qq

R₄

-N — N — X) —R₃

Formula I where:

R₃ and R₄ they can be the same or different and, independently of each other, are hydrogen, an alkyl group of (C_rC₂₂) saturated or unsaturated, an alkyl group of (Ci-C₂₂) replaced by a halogen atom, a hydroxyalkyl group of (C₂-C₂₂) optionally interrupted by oxygen, a polyether group derived from ethylene oxide, propylene oxide or butylene oxide, an amino alkyl group of (CrCæ), a phenyl group or a substituted or unsubstituted benzyl group, an alkyl group of (CrC₂₂) terminated in sulphonate, sulfate, or carboxylate, or radical groups R₃ and R₄together with the remaining molecule, they can form a heterocyclic or carbocyclic ring system, saturated or unsaturated, substituted or unsubstituted,

<img file="AR080330A1_D0038.tif" />

optionally substituted by halogen, sulfate, sulphonate, phosphate, nitrate, and carboxylate;

X may be a radical group of the phenol series or a heterocyclic radical group or it may be a radical group of the phenol series or a heterocyclic radical group or aniline series or m-toluidine series which may have the following Formula II;

<img file="AR080330A1_D0039.tif" />

Formula II where:

R₅ and R₆ they can be the same or different and, independently of each other, are an alkyl group of (CrC₂₂) saturated or unsaturated, linear or branched, an alkyl ether group of (CH-CY), a hydroxy alkyl group of (C₂-C₂₂) optionally interrupted by oxygen, a polyether group derived from ethylene oxide, propylene oxide, butylene oxide, glycidyl or combinations thereof, an amino alkyl group of (Ci-C₂₂), a phenyl group 0 a substituted or unsubstituted benzyl group, an alkyl group of (C_rC₂₂) Linear or branched terminated in an alkyl, hydroxyl, acetate, sulphonate, sulfate, or carboxylate group of (C_rC₂₂) Line or branched 0 R₅ and Re 0 R₅ and R₇ 0 R₆and R_7i together with the nitrogen atom, they form a 5 to 6 member ring system, which may comprise an additional heteroatom; or R₅ and R₆ or R₅ and R₇ or R₆ and R₇, with a carbon atom of the benzene ring, a 5- or 6-membered heterocycle that optionally contains oxygen or nitrogen that can be substituted with one or more alkyl groups of (C)_rC₂₂);

R₇ they can be the same or different and, independently of each other, are hydrogen, a halogen atom, an alkyl group of (Ci-C₂₂) saturated or unsaturated, an alkyl ether group of (C_rC₂₂), a hydroxyl group, a hydroxyalkyl group of (Ο ·, -Ο₂₂), an alkoxy group of (Ci-C₂₂), a cyano group, a nitro group, an amino group, an alkylamino group of (Ci-C₂₂), a group

<img file="AR080330A1_D0040.tif" />

dialkylamino of (CrC ^), a carboxylic acid group, an alkyl group of 0 (0) 0 - ((^ - 022), a substituted or unsubstituted 0 (0) 0 phenyl group;

Q 'can be an anion that balances the total charge of the compound of Formula I, and the index can be Ο or 1. Suitable anions include chlorine, bromine, methosulfate, tetrafluoroborate, and acetate anions.

Ri can be an alkyl of (Ci-C₂₂), an aromatic alkyl or an alkyl sulfonate radical having the following Formula (III);

<img file="AR080330A1_D0041.tif" />

SW₃where

R₂ is hydrogen, a methyl, ethyl, propyl, acetate or hydroxyl group; myp are integers from 0 to (n-1), n ​​is an integer from 1 to 6 and m + p = (n-1);

with the proviso that the heterocycle of Formula (I) comprises at least two and as maximum three heteroatoms, wherein the heterocycle has as maximum a sulfide atom;

In one aspect, a suitable thiazolium dye may have the following Formula IV:

<img file="AR080330A1_D0042.tif" />

where R₈ and Rg can be the same or different and, independently of each other, can be an alkyl group of (C_rC₂₂) saturated or unsaturated, an alkyl group of (Cr C₂₂), a hydroxyalkyl group of (C₂-C₂₂), optionally interrupted by oxygen, a zi »/ lugroup polyether derived from ethylene oxide, propylene oxide or butylene oxide, an amino alkyl group of (Cr-Cn), a phenyl group or a substituted or unsubstituted benzyl group , an alkyl group of (CrC ^) terminated in sulphonate, 0 carboxylate sulfate, 0 R₈and R_g, together with the nitrogen atom, they can form a 5-member to 6-member ring system, which may comprise an additional heteroatom; or R₈ ό R₉it can form, with a carbon atom of the benzene ring, a five or six membered heterocycle that, optionally, contains oxygen or nitrogen which can be substituted with one or more alkyl groups of (C- | -C₂₂), and mixtures of these, and R_1st It is hydrogen or methyl. For Formula IV, Q 'is as described for Formula I above.

In one aspect, suitable thiazolium dyes may have Formula (V);

<img file="AR080330A1_D0043.tif" />

where:

a.) Ri can be selected from an alkyl entity of (Ci-C₂₂) branched or unbranched, an aromatic alkyl entity, a polyalkylene oxide entity or an entity having the following Formula (VI);

<img file="AR080330A1_D0044.tif" />

where (i) R₂ it can be selected from hydrogen, methyl, ethyl, propyl, acetate or a hydroxyl entity; myp can be, independently, integers of 0

<img file="AR080330A1_D0045.tif" />

a (n-1), with the proviso that n is an integer from 1 to 6 and m + p = (n-1) (ii) Y can be selected from a hydroxyl, sulphonate, sulfate, carboxylate or acetate entity;

b. ) R₃yR₄:

i. ) can be independently selected from hydrogen; a saturated or unsaturated (C1-C22) alkyl entity; a hydroxyalkyl entity of (C₂-C₂₂); a hydroxyalkyl entity of (C₂-C₂₂) comprising, in addition to the hydroxyl oxygen, an oxygen atom; a polyether entity; an aminoalkyl entity of (CîC₂₂); a substituted or unsubstituted phenyl entity; a substituted or unsubstituted benzyl entity; an alkyl entity of (CrC ^) terminated in sulphonate, sulfate, acetate, or carboxylate; 0 ii. ) when taken together they can form a saturated or unsaturated carbocyclic heterocyclic or carbocyclic entity; 0 iii. ) when taken together they can form a saturated or unsaturated heterocyclic or carbocyclic entity substituted by sulfate, sulphonate, phosphate, nitrate, and carboxylate;

c. ) X can be an entity that has the following Formula VII;

<img file="AR080330A1_D0046.tif" />

Formula VII where:

go₅ and R₆:

(a) they can be independently selected from hydrogen; an alkyl entity of (Ο ·, -Ο₂2) saturated or unsaturated; an alkyl hydroxy entity of (C₂-C₂₂); a hydroxyalkyl entity of (C₂-C₂₂) comprising, in addition to the hydroxyl oxygen, an oxygen atom; a polyether entity with or without auction; an aminoalkyl entity of (CrC₂two); a substituted or unsubstituted phenyl entity; a substituted or unsubstituted benzyl entity; a (C1-C22) alkyl entity comprising a Ci-C alkyl ether entity₄ terminal, sulphonate, sulfate, acetate, 0 carboxylate; a thiazole entity or (b) when taken together may form a saturated or unsaturated heterocyclic entity; 0 (c) when taken together they form a saturated or unsaturated heterocyclic entity substituted by one or more entities, alkoxylate, sulfate, sulphonate, phosphonate, nitrate, and / or carboxylate;

(d) when taken together with R₇, R₈, or R₇ and R₈they form one or more saturated or unsaturated heterocyclic entities, optionally substituted by one or more alkoxylate, sulfate, sulphonate, phosphonate, nitrate, and / or carboxylate entities; 0 (e) when taken together they form a thiazole entity;

ii.) R₇ and R₈ a saturated or unsaturated alkyl entity can be independently selected from hydrogen or 0;

d.) Q 'may be an anion that balances the total charge of the compound of Formula I, and the index is 0 or 1. Suitable anions include chlorine, bromine, methosulfate, tetrafluoroborate, and acetate anions.

In one aspect, for Formula V:

to. ) Ri can be a methyl entity;

b. ) R₃ and R₄ they can be hydrogen; Y

c. ) X can have the following Formula Vili:

<img file="AR080330A1_D0047.tif" />

Formula Vili where (i) R5 and Re may be such as defined for Formula VII above;

(ii) R₇ it can be hydrogen or a methyl entity; and (iii) R₈ It can be hydrogen.

In one aspect, for Formula VII, each R₅ and R₆ it comprises, independently, from 1 to 20 units of alkylene oxide and, independently, an entity selected from the group consisting of: styrene oxide, glycidyl methyl ether, isobutyl glycidyl ether, isopropylglycidyl ether, t-butyl glycidyl ether, 2-ethylhexylglycidyl ether or glycidylhexadecyl ether.

Suitable polymeric dyes include polymeric dyes selected from the group comprising polymers containing conjugated chromogens (dye and polymer conjugates) and polymers with copolymerized chromogens in the polymer backbone and mixtures thereof.

In another aspect suitable polymeric dyes include polymeric dyes selected from the group consisting of substantial fabric dyes sold under the name of Liquitint® (Milliken, Spartanburg, South Carolina, USA. UU.), Dye and polymer conjugates formed of at least one reactive dye and a polymer selected from the group consisting of polymers comprising an entity selected from the group consisting of a hydroxyl entity, a primary amine entity, a secondary amine entity , a thiol entity and mixtures thereof. In still another aspect, suitable polymeric dyes include polymeric dyes selected from the group consisting of Liquitint® (Milliken, Spartanburg, South Carolina, USA) Violet CT, carboxymethylcellulose (CMC) conjugated with a reactive blue dye, violet dye reagent or reagent red such as CMC conjugated with Cl Reactive blue 19, marketed by Megazyme, Wicklow, Ireland under the product name AZO-CM-CELLULOSE, product code S-ACMC and mixtures thereof.

Suitable dye clay conjugates include dye clay conjugates selected from the group comprising at least one cationic / basic dye and a smectite clay and mixtures thereof. In another aspect, suitable dye clay conjugates include dye clay conjugates selected from the group consisting of

<img file="AR080330A1_D0048.tif" />

from a selected catholic / basic dye group consisting of basic yellow Cl 1 to 108, basic orange Cl 1 to 69, basic red Cl 1 to 118, basic violet Cl 1 to 51, basic blue Cl 1 to 164, basic green Cl 1 to 14, Cl coffee basic 1 to 23, Cl black basic 1 to 11, and a clay selected from the group consisting of Montmorillonite clay, Hectorite clay, Saponite clay and mixtures thereof. In still another aspect, suitable dye and clay conjugates include dye and clay conjugates selected from the group consisting of Montmorillonite Basic Blue Conjugate B7 Cl 42595, Montmorillonite Basic Blue Conjugate B9 Cl 52015, Montmorillonite Basic Violet Basic Conjugate V3 Cl 42555 Basic Conjugate Montmorillonite G1 Cl 42040, basic red conjugate montmorillonite R1 Cl 45160, Cl montmorillonite conjugate. Basic black conjugate 2, basic blue conjugate hectorite B7 Cl 42595, basic blue conjugate hectorite B9 Cl 52015, basic violet conjugate hectorite V3 Cl 42555, basic green conjugate hectorite G1 Cl 42040, basic red conjugate hectorite R1 Cl 4516 Cl. Conjugate basic black 2, conjugate basic blue saponite B7 Cl 42595, conjugate basic blue saponite B9 Cl 52015, conjugate basic violet saponite V3 Cl 42555, conjugate basic saponite green G1 Cl 42040, basic red saponite conjugate R1 Cl 45160, Cl saponite conjugate. Basic black conjugate 2 and mixtures of these.

Suitable pigments include pigments selected from the group consisting of flavantrone, indantrone, chlorinated indantrone that has 1 to 4 chlorine atoms, pyrantrone, dichloropyrantrone, monobromodichloropirantrone, dibromodichloropyrantrone, tetrabromopirantrone, perylene-3,4,9,10-diimide , wherein the imide groups may be unsubstituted or substituted by C1-C3 alkyl or a phenyl or heterocyclic radical, and where the phenyl and heterocyclic radicals can also carry substituents that do not confer water solubility, antrapyrimidinecarboxylic acid amides, violantrone, isoviolantrone, dioxazine pigments, phthalocyanine copper which can contain up to 2 chlorine atoms per molecule, polychlorine or phthalocyanine phthalocyanine Polybromochloro-copper phthalocyanine containing up to 14 bromine atoms per molecule and mixtures of these. In another aspect, suitable pigments include pigments selected from the group consisting of ultramarine blue (Cl pigment blue 29), ultramarine violet (Cl pigment violet 15) and mixtures thereof.

The above-mentioned fabric dyeing agents can be used in combination (any mixture of fabric dyeing agents can be used). Dyeing agents for suitable fabrics can be purchased from Aldrich, Milwaukee, Wisconsin, USA; Ciba Specialty Chemicals, Basel, Switzerland; BASF, Ludwigshafen, Germany; Dayglo Color Corporation, Mumbai, India; Organic Dyestuffs Corp., East

<img file="AR080330A1_D0049.tif" />

Providence, Rhode Island, USA; Dystar, Frankfurt, Germany; Lanxess, Leverkusen, Germany; Megazyme, Wicklow, Ireland; Clariant, Muttenz, Switzerland; Avecia, Manchester, United Kingdom and / or prepared in accordance with the examples contained herein.

Dispersants The compositions of the present invention may further comprise dispersants. Suitable water-soluble organic materials are homo- or copolymeric acids or their salts, in which the polycarboxylic acid may comprise as a minimum two carboxyl radicals separated from one another by no more than two carbon atoms.

Enzymes The compositions may comprise one or more detergent enzymes that provide cleaning performance and / or fabric care benefits. Examples of suitable enzymes include, among others, hemicellulases, peroxidases, proteases, cellulases, xylanases, lipases, phospholipases, esterases, cutinases, pectinases, queratanases, reductases, oxidases, phenoxidases, lipoxygenases, ligninases, pululases, pululases, pululases malanases, β-glucanases, arabinosidases, hyaluronidase, chondroitinase, laccase and amylases, or mixtures thereof. A typical combination is a cocktail of conventional applicable enzymes, as protease, lipase, cutinase and / or cellulase in conjunction with amylase.

Stabilizers of enzymes. Enzymes for use in compositions, for example, detergents, can be stabilized by various techniques. The enzymes employed herein can be stabilized by the presence of water soluble magnesium and / or calcium ion sources in the finished compositions that provide the ions to the enzymes.

Catalytic metal complexes. Applicant compositions may include catalytic metal complexes. One type of metal-containing bleaching catalyst is a catalyst system comprising a transition metal cation of defined bleaching catalyst activity, such as copper, iron, titanium, ruthenium, tungsten, molybdenum or manganese cations, an auxiliary metal cation that it has little or no bleaching catalyst activity, such as zinc or aluminum cations, and a part having defined stability constants for catalytic and auxiliary metal cations, particularly, tetraacetic acid ethylenediamine, ethylenediaminetetra (methylenephosphonic acid) and salts thereof soluble in water. Such catalysts are described in US Pat. UU. no. 4,430,243.

If desired, the compositions herein can be catalyzed by means of a manganese compound. These compounds and levels of use are well known in the industry and include, for example, catalysts based on

<img file="AR080330A1_D0050.tif" />

manganese described in US Pat. no. 5,576,282.

The cobalt bleaching catalysts useful in the present description are known, and are described, for example, in US Pat. UU. no. 5,597,936 and 5,595,967. Such cobalt catalysts are already easily prepared by known methods, as shown, for example, in US Pat. UU. no. 5,597,936 and 5,595,967.

The compositions herein may also conveniently include a transitional complex of a macropolylic rigid ligand (MRL). For practical reasons and not in a limiting manner, the cleaning compositions and processes herein can be regulated to provide at least one part per hundred million of the MRL species of the beneficial agent in the aqueous washing medium, and can provide about 0.005 ppm to about 25 ppm, about 0.05 ppm to about 10 ppm, or even about 0.1 ppm to about 5 ppm of the MRL in the wash liquor.

Suitable transition metals in the transition metal bleach catalyst of the present disclosure include manganese, iron and chromium. Suitable MRLs in the present description are a special type of ultra-rigid ligand that is a cross bridge, such as 5,12-diethyl-1,5,8,12-tetraazabicyclo [6.6.2] hexadecane.

Suitable transition metal MRLs are easily prepared by known procedures, such as those described, for example, in patent no. WO 00/32601 and in US Pat. no. 6,225,464.

IV Rheology Indicator

The liquid compositions of the present invention may comprise a rheology modifier. The rheology modifier can be selected from the group consisting of materials with hydroxyl, crystalline, non-polymeric functional groups, polymeric rheology modifiers that impart pseudoplastic characteristics to the aqueous liquid matrix of the composition. In one aspect, such rheology modifiers impart a high shear viscosity to the aqueous liquid composition in 20 s'¹Shear speed at 21 ° C, from 1 to 7000 cps and a low shear viscosity (0.5 sec '¹ Shear speed at 21 ° C) of greater than 1000 cps, or even 1000 cps at 200,000 cps. In one aspect, for cleaning and treatment compositions, rheology modifiers impart a high shear viscosity to the aqueous liquid composition in 20 sec.¹ and at 21 ° C, from 50 to 3000 cps and a

<img file="AR080330A1_D0051.tif" />

low shear viscosity (0.5 s'¹ Shear speed at 21 ° C) of greater than 1000 cps, or even 1000 cps at 200,000 cps. The viscosity according to the present invention is measured using an AR 2000 rheometer of TA instruments using a steel plate shaft 40 mm in diameter and a separation size of 500 pm. The high shear viscosity at 20 sec '¹ and low shear viscosity in 0.5 sec '¹ can be obtained from a logarithmic scan of shear speeds of 0.1 sec '¹ at 25 sec '¹ in a time of 3 minutes at 21 ° C. Crystalline materials with hydroxyl function are rheological modifiers that form filiform structuring systems throughout the matrix of the composition after "in situ" crystallization. Polymeric rheology modifiers are preferably selected from polyacrylates, polymeric gums, other non-gum polysaccharides, and combinations of these polymeric materials.

Generally, the rheology modifier will comprise from 0.01% to 1% by weight, preferably, from 0.05% to 0.75% by weight, more preferably, from 0.1% to 0.5% by weight. , of the compositions herein.

Structuring agents that are especially useful in the compositions of the present invention may comprise materials with hydroxyl, crystalline, non-polymeric functions (except for conventional alkoxylation), materials with hydroxyl, crystalline functions that can form filiform structuring systems throughout the matrix liquid when crystallized within it in situ. These materials can generally be characterized as fatty acids, fatty esters or fatty waxes, all of them crystalline and with hydroxyl. In one aspect rheology modifiers include rheology modifiers that contain hydroxyl, crystalline, include castor oil and its derivatives. In one aspect the rheology modifiers included can be derived from castor oil taies as hydrogenated castor oil and hydrogenated castor wax. Commercially available rheology modifiers containing hydroxyl, crystalline, based on castor oil include THIXCIN ™ from Rheox, Ine. (now Elementis).

Other types of rheology modifiers, in addition to rheology modifiers containing crystalline, non-polymeric, hydroxyls described above, can be used in the liquid detergent compositions in the present invention. Polymeric materials can also be used that provide pseudoplastic characteristics to the aqueous liquid matrix.

Suitable polymeric rheological modifiers include those of the polyacrylate, polysaccharides or polysaccharide derivatives type. Polysaccharide derivatives

Typically used as rheology modifiers comprise polymeric rubber materials. Those gums include pectin, alginate, arabinogalactan (gum arabic), carrageenan, gellan gum, xanthan gum and guar gum.

If polymeric rheology modifiers are used in the present invention, gellan gum is preferred. Gellan gum is a heteropolysaccharide prepared by fermentation of Pseudomonaselodea ATCC 31461. CP Kelco EE. UU., Inc. commercially distributes gellan gum under the trade name of KELCOGEL.

Another suitable and alternative rheology modifier includes a combination of a solvent and a polycarboxylate polymer. More specifically, the solvent may be an alkylene glycol. In one aspect the solvent may comprise dipropylene glycol. In one aspect the polycarboxylate polymer may comprise a polyacrylate, polymethacrylate or mixtures thereof. In one aspect the solvent may be present, based on the total weight of the composition, at a level of 0.5% to 15%, or 2% to 9% of the composition. In one aspect the polycarboxylate polymer may be present, based on the total weight of the composition, at a level of 0.1% to 10%, or 2% to 5%. In one aspect, the solvent component may comprise a mixture of dipropylene glycol and 1,2-propanediol. In one aspect the ratio of dipropylene glycol to 1,2-propanediol can be from 3: 1 to 1: 3, or even 1: 1. In one aspect the polyacrylate may comprise a copolymer of unsaturated mono- or di-carbonic acid and Ci-Cso alkyl ester of the (meta) acrylic acid. In another aspect the rheology modifier may comprise an unsaturated mono- or di-carbonic acid polyacrylate and Ci-Cso alkyl ester of the (meta) acrylic acid. These copolymers are distributed by Noveon Ine under the trade name Carbopol Aqua 30®.

In the absence of the rheology modifier and for the purpose of imparting the desired pseudoplastic characteristics to the liquid composition, the liquid composition can be internally structured by means of chemical surfactant phases or gel phases.

Silicone emulsion

The compositions of the present invention may comprise a silicone emulsion. An emulsion is a mixture of a liquid (the dispersed phase) dispersed in another (the continuous phase). In the context of the present invention, the silicone emulsion also encompasses macroemulsion and microemulsion.

In one embodiment the silicone emulsion of the present invention is added as an emulsion of silicone oil in water or a solvent containing an aqueous solution in a range of 35 to 65 (w / w%) . In one embodiment the emulsion of

<img file="AR080330A1_D0052.tif" />

Silicone of the present invention can be any silicone emulsion.

In one embodiment, the average particle size of the silicone emulsion is 0.01 to 2 micrometers, more preferably, 0.2 to 0.8 micrometers of average particle size.

Preferably, the emulsified silicone oil is selected from the group comprising non-ionic, nitrogen-free silicone oils, amino functional silicone oils and mixtures thereof.

In one embodiment of the present invention, the silicone emulsion is an amino functional silicone, preferably aminodimethicone.

In a preferred embodiment of the present invention, the silicone emulsion is a nitrogen-free non-ionic silicone emulsion, preferably selected from the group comprising polydialkyl silicone, polydimethyl silicone, alkyloxylated silicone, ethoxylated silicone, propoxylated silicone, ethoxylated propoxylated silicone, Quaternary silicone or derivatives thereof and mixtures thereof. In a more preferred embodiment, the non-ionic, nitrogen-free silicone emulsion is selected from the group comprising polydialkylsilicone, polydimethyl silicone and mixtures thereof. In one embodiment, the silicone emulsion is polydimethyl silicone.

In this preferred embodiment, where the silicone emulsion is polydimethyl silicone, the polydimethyl silicone has a viscosity between 0.0001 m².s'¹ and 0.1 m².s'¹preferably between 0.0003 m².s'¹ and 0.06 m².s'¹, more preferably, between 0.00035 m².s'¹ and 0.012 m².s'¹.

Solvents suitable for use in the solvent-containing aqueous solution may be selected from the group comprising linear, branched, cyclic, saturated and / or unsaturated C1-C20 alcohols with one or more free hydroxyl groups; amines, alkanolamines, and mixtures thereof. Preferred solvents are monoalcohols, diols, monoamine derivatives, glycerols, glycols and mixtures thereof, such as ethanol, propanol, propanediol, monoethanolamine, glycerol, sorbitol, alkylene glycols, polyalkylene glycols, and mixtures thereof. The most preferred solvents are selected from the group comprising 1,2-propanediol, 1,3-propanediol, glycerol, ethylene glycol, diethylene glycol, and mixtures thereof.

The emulsion contains a water soluble emulsifier, selected from the group of commercially available emulsifiers that comprise cationic, anionic, nonionic or zwitterionic emulsifiers. In a preferred embodiment of this invention the emulsifier is a non-unique surfactant.

Alternatively, premixes of silicone emulsions and solvents are used

<img file="AR080330A1_D0053.tif" />

to overcome process problems in terms of dispersion or proper dissolution of all ingredients in the composition.

Silicone emulsion premixes in the context of the present invention include high internal phase emulsion ("HIPE"). This is achieved by premixing a silicone emulsion, such as polydimethyl silicone horn, and an emulsifier to create a HIPE, then this HIPE is mixed in the composition, which results in a good mixture that results in a homogeneous mixture. Such HIPE comprise at least 65%, alternatively, at least 70%, alternatively, at least 74%, alternatively, at least 80%; alternatively, no more than 95%, by weight of an internal phase (dispersed phase), wherein the internal phase may comprise a silicone emulsion. The internal phase can also be other water insoluble beneficial agents for fabric care, which are not yet pre-emulsified. The internal phase is dispersed by the use of an emulsifying agent. Examples of the emulsifying agent include a surfactant or a surface tension reducing polymer. In one embodiment, the range of the emulsifying agent is at least 0.1% to 25%, alternatively, 1% to 10%, and, alternatively, e 2% to 6% by weight of the HIPE. In another embodiment, the emulsifying agent is soluble in water and reduces the surface tension of water, in a concentration less than 0.1% by weight of deionized water, to less than 0.0007 N (70 dynes), alternatively less than 0, 0006 N (60 dynes), alternatively less than 0.0005 N (50 dynes); alternatively, at or greater than 0.0002 N (20 dynes). In another embodiment, the emulsifying agent is at least partially insoluble in water.

The external phase (continuous phase), in one embodiment, is water, alternatively, it may comprise at least some amount of water, alternatively it may comprise very little or no amount of water. In another embodiment, the external water phase may comprise less than 35%, alternatively, less than 30%, alternatively, less than 25%; alternatively, at least 1%, by weight of HIPE. Non-aqueous HIPEs can also be prepared with a solvent as the external phase with little or no amount of water. Typical solvents include glycerin and propylene glycol.

In another embodiment the composition is a non-concentrated composition. In this mode the silicone emulsion is not, at least initially, emulsified and can be emulsified in the fabric care composition itself.

The composition of the present invention may comprise a silicone emulsion that acts to maintain the physical stability of the liquid composition w

fabric softener after a defrost freeze cycle and also after prolonged storage at low temperatures.

The silicone emulsion of the present invention is at a level of 0.5% to 10%. In another embodiment the silicone emulsion of the present invention is at a level of 0.3% to 10%, preferably 0.3% to 5% and, most preferably, 0.5% to 3.0% by weight of the liquid fabric softener composition.

I. Non-ionic silicone emulsions, nitrotene free:

In the context of the present invention, preferably, the silicone emulsion is selected from the group comprising non-ionic, nitrogen-free silicone emulsion having Formulas (I), (II), (III), and mixtures thereof:

<img file="AR080330A1_D0054.tif" />

R¹ (T):

R²- (R¹) 2SiO - [(R¹) 2Yes]_to- [(R¹) (R²) SiO] b-Si (R¹) 2-R² (II);

Ri

R¹

R¹-Yes or yes

R¹

-fcr-yes—

R¹ R 'R¹ (in);

where each R¹ is independently selected from the group consisting of linear, branched or substituted or unsubstituted alkyl groups having 1 to 20 carbon atoms; linear, branched or cyclic substituted or unsubstituted alkenyl groups having 2 to 20 carbon atoms; substituted or unsubstituted aryl groups having 6 to 20 carbon atoms; substituted or unsubstituted alkylaryl groups, substituted or unsubstituted arylalkyl and substituted or unsubstituted arylalkenyl having 7 to 20 carbon atoms and mixtures thereof; every R² is independently selected from the group consisting of linear, branched or substituted or unsubstituted alkyl groups having 1 to 20 carbon atoms; linear, branched or substituted or unsubstituted alkenyl groups having from 2 to 20 carbon atoms; substituted or unsubstituted aryl groups having 6 to 20 carbon atoms; substituted or unsubstituted alkylaryl groups, substituted or unsubstituted arylalkyl and substituted or unsubstituted arylalkenyl having 7 to 20 carbon atoms and a copolymer group of poly (ethylene oxide / propylene oxide) having the general formula;

- (CH₂)_nO (C₂H₄OR)_c(C₃H₆OR)_dR³ (IV) polydialkyl silicone, polydimethyl silicone, alkyloxylated silicone, quaternary silicone with at least one R² which is a copolymer group of poly (ethylene oxide / propylene oxide) (emulsions of ethoxylated silicone, propoxylated silicone, ethoxylated propoxylated silicone), and each R³ it is independently selected from the group consisting of hydrogen, an alkyl having 1 to 4 carbon atoms, an acetyl group, and mixtures thereof, wherein the index has a value such that the viscosity of the nitrogen-free silicone polymer of Formulas (I) and (III) are between 0.0001 m².s¹ (100 centistokes) and 0.1 m².s'¹ (100,000 centistokes); where a is from 1 to 50; b is from 1 to 50; n is from 1 to 50; c total (for all polyalkyleneoxy side groups) has a value of 1 to 100; total d is from 0 to 14; c + d total has a value of 5 to 150

More preferably, the nitrogen-free non-ionic silicone emulsion is selected from the group consisting of nitrogen-free non-ionic silicone emulsions having Formulas (II) through (III) as described above, wherein R¹ it is selected from the group consisting of methyl, phenyl, phenylalkyl, and mixtures thereof; where R² it is selected from the group consisting of methyl, phenyl, phenylalkyl, and mixtures thereof; and of the group having the general Formula (IV), as described above, and mixtures thereof; where R³ defined as described above and wherein the index w has a value such that the viscosity of the nitrogen-free silicone emulsion of Formula (III) is between 0.0001 m².s¹ (100 centistokes) and 0.1 m².s'¹ (100,000 centistokes); a is 1 to 30, b is 1 s 30, n is 3 to 5, c total is 6 to 100, d total is 0 to 3, and c + d total is 7 to 100.

With the highest preference, the nitrogen-free silicone emulsion is selected from the group comprising non-ionic, linear, nitrogen-free silicone emulsions having the formula General (III) as described above, wherein R¹ It is methyl, that is, the silicone emulsion is polydimethyl silicone. In this preferred embodiment, wherein the silicone emulsion is polydimethyl silicone, the

<img file="AR080330A1_D0055.tif" />

index w has a value such that the polydimethyl silicone has a viscosity between 0.0001 m²s'¹ and 0.1 m².s'¹preferably between 0.0003 m².s'¹ and 0.06 m².s'¹, more preferably, between 0.00035 m².s'¹ and 0.012 m².s'¹.

II. Aminofunctional silicone emulsions:

In one embodiment of the present invention, the silicone emulsion is an amino functional silicone. Aminofunctional silicone emulsions are formula materials:

HO [Yes (CH₃)₂-OR]_x{Yes (OH) [(CH₂)₃-NH- (CH₂)₂-NH₂]OR}_YH where x and y are integers that depend on the viscosity of the silicone emulsion. Preferably, the aminofunctional silicone emulsion has a molecular weight such that it has a viscosity of 0.0005 m².s'¹ (500 centistokes) at 0.5 m².s'¹ (500,000 centistokes). This material is also known as "aminodimethicone".

Method of use

Some of the consumer products described in the present invention can be used to clean or treat a site among others a surface or fabric. Typically, at least a portion of the site is contacted with an embodiment of the applicant's composition, pure or diluted in a liquid, for example, a washing liquid and then, optionally, the site can be washed and / or rinse. In one aspect, optionally, a site is washed or rinsed, contacted with a particle according to the present invention or with a composition comprising said particle and then, optionally, washed or rinsed. In one aspect a method is described for cleaning or treating a site that optionally comprises washing and / or rinsing the site, contacting the site with the selected composition of the compositions and mixtures thereof described herein and, optionally, wash and / or rinse the site. For the purposes of the present invention, washing includes, but is not limited to, scrubbing and mechanical agitation. The fabric can comprise almost any type of fiber that can be washed or treated under the normal conditions of the consumption itself. Liquids that may comprise the described compositions may have a pH of about 3 to about 11.5. The compositions are typically employed in concentrations of about 500 ppm to about 15,000 ppm in solution. When the solvent for washing is water, its temperature typically varies between approximately 5 ° C and 90 ° C and, when the site comprises a fabric, • r- »

<img file="AR080330A1_D0056.tif" />

The ratio between water and fabric is typically between 1: 1 and 30: 1.

TEST METHODS

1. ) Average molecular mass. For purposes of the present specification and claims, the average molecular mass of a polymer is determined according to the ASTM method, ASTM D4001-93 (2006).

two. ) Degree of hydrolysis. For purposes of the present specification and claims, the degree of hydrolysis is determined in accordance with the method found in US Pat. UU. no. 6,132,558, column 2, line 36 to column 5, line 25.

3. ) Load density. For purposes of the present specification and claims, the charge density of a polymer is determined with the aid of colloid titration, cf. D. Horn, Progress in Colloid &amp; Polymer Sci. 65 (1978), 251-264.

Four. ) Zeta potential. For purposes of the present specification and claims, the zeta potential is determined as follows:

to. ) Equipment: Malvern Zetasizer 3000

b. ) Procedure for sample preparation:

(i) add 5 drops of suspension containing the encapsulation of interest to 20 ml of 1 mM NaCI solution to dilute the suspension. It may be necessary to adjust the concentration so that the counting speed is in the range of 50 to 300 Kcps.

(ii) the zeta potential is measured in the diluted sample without filtration (iii) the filtered suspension is injected into the Zetasizer cell and the cell is inserted into the equipment. The test temperature is set at 25 ° C.

(iv) when the temperature is stable (usually 3 to 5 minutes), the measurement starts. Five measurements are taken for each sample. Three samples are taken for each suspension of interest. The average of the 15 readings is calculated.

c. ) Device settings for measurements:

Parameter settings for the sample used:

Material: RI 1,680 melamine, 0.10 absorption Dispersant: 1 mM NaCL emperature: 25 ° C

<img file="AR080330A1_D0057.tif" />

Viscosity: 0.8900 cP RI: 1,330

Dielectric constant: 100

Selection of F (ka): Model: Smoluchowski F (ka) 1.5 Use dispersant viscosity as sample viscosity Cell type: DTS1060C: Clear disposable Zeta cells Measurements: 3 measurements

d.) Results: The zeta potential is reported in mV as the average of the 15 readings taken for the suspension of interest.

EXAMPLES

Although particular embodiments of the present invention have been illustrated and described, it will be apparent to persons with experience in the industry that various changes and modifications can be made without departing from the spirit and scope of the invention. It has been intended, therefore, to encompass in the appended claims all changes and modifications within the scope of the invention.

Example 1: 84% by weight of the core 116% by weight of the wall of the melamine formaldehyde capsule (MF)

25 grams of butylacrylate-acrylic acid copolymer emulsifier (Colloid C351, 25% solids, pka 4,5-4,7, (Kemira Chemicals, Inc. Kennesaw, Georgia, USA) are dissolved and mixed in 200 grams of deionized water The pH of the solution is adjusted to a pH of 4.0 with sodium hydroxide solution 8 grams of partially methylated methylol melamine resin (Cymel 385, 80% solids, (Cytec Industries) West Paterson, New Jersey, USA)) to the emulsifier solution. 200 grams of essential oil are added to the previous mixture with mechanical stirring and the temperature is raised to 50 ° C. After mixing at a higher speed until a stable emulsion is obtained, the second solution and 4 grams of sodium sulfate sai are added to the emulsion. This second solution contains 10 grams of the butylacrylate-acrylic acid copolymer emulsifier (Colloid C351, 25% solids, pka 4,5-4,7, Kemira), 120 grams of distilled water, sodium hydroxide solution to regulate the pH at a pH of 4.8, 25 grams of partially methylated methylol melamine resin (Cymel 385, 80% solids, Cytec). This mixture is heated to 70 ° C and kept overnight with continuous stirring to complete the encapsulation process. 23 grams of

5Κ · acetoacetamide (Sigma-Aldrich, St. Louis, Missouri, USA) upon suspension. An average capsule size of 30 pm is obtained as analyzed with an Accusizer particle size analyzer, model 780.

Example 2

Procedure for preparing perfume microcapsules coated with polymer

Polymer coated perfume microcapsules are prepared by weighing 99 g of the reference suspension of melamine formaldehyde perfume microcapsules (99.75%) and 1 g of Lupamin 9030, 16% active (ex BASF, Ludwigshafen, Germany) In a glass jar. The two ingredients are mixed briefly with a spoon. They are further mixed overnight on a shaker.

Example 3

Procedure to include perfume microcapsules coated in a liquid laundry detergent

74.9 g of compact liquid detergent free of perfume microcapsules are weighed and 1.33 g of polymer coated perfume microcapsules are added.

The resulting product is mixed with a mechanical mixer for 1 minute.

Example 4

A 9 kg aliquot of perfume microcapsules suspension from Example 2 is mixed with a Eurostar mixer (IKA) with an R1382 attachment at a constant speed of 200 RPM. Add to the 500g aliquot of carboxymethylcellulose (Kelco CP) while mixing with the Eurostar mixer with the same attachment and speed described above. The suspension is mixed for a total of two hours or until a uniform paste is formed.

Example 5

1.28 kg of Sipernat® 22S precipitated silica (Degussa) is added to an F-20 vane mixer (Forberg). The mixer is initially operated for 5 seconds to distribute the silica evenly at the base of the mixer. The mixer stops and 8.25 kg of pulp, made according to Example 4, is distributed evenly over the powder. Then, the mixer is operated at 120 rpm for a total of 30 seconds. After mixing the wet particles are removed from the mixer and subjected to review with a 2000 micron sieve to

5l · remove excess. The product that passes through the sieve is dried in batches of 500 g in a 0.02 CDT fluid bed dryer (Niro) at a final moisture content of 20% by weight, measured by Karl Fischer. The dryer is operated at an inlet temperature of 140 ° C and an air velocity of 0.68 m / s.

Examples 6-13

Examples of laundry detergent compositions comprising the perfume composition are included below.

% by weight / weight of detergent compositions

<td rowspan="2">Raw material</td><td colspan="3">for laundry</td><td rowspan="2"> 9</td><td rowspan="2"> 10</td><td rowspan="2"> 11</td><td rowspan="2"> 12</td><td rowspan="2"> 13</td>

<td> 6</td><td colspan="2"> 8</td>

<td>Linear alkylbenzenesulfonate</td><td> 7,1</td><td> 6,7</td><td> 11,0</td><td> 10,6</td><td> 6,9</td><td> 4,5</td><td> 10,1</td><td> 8,9</td>

<td colspan="2">C alkyl sodium ethoxy sulfate₁₂.₁₅ with an average molar grade of ethoxylation of 3.5 3</td><td> 0,0</td><td> 1,5</td><td> 0,0</td><td> 0,0</td><td> 0,0</td><td> 0,0</td><td> 1,9</td>

<td colspan="2">Acrylic acid / maleic acid 3,6 copolymer</td><td> 1,8</td><td> 4,9</td><td> 2,0</td><td> 1,0</td><td> 1,6</td><td> 3,9</td><td> 2,3</td>

<td>Sodium aluminosilicate (zeolite 4A)</td><td> 4,0</td><td> 0,5</td><td> 0,8</td><td> 1,4</td><td> 16,3</td><td> 0,0</td><td> 17,9</td><td> 2,4</td>

<td>Sodium tripolyphosphate</td><td> 0,0</td><td> 17,5</td><td> 0,0</td><td> 15,8</td><td> 0,0</td><td> 23,3</td><td> 0,0</td><td> 0,0</td>

<td>Sodium carbonate</td><td> 23,2</td><td> 16,8</td><td> 30,2</td><td> 17,3</td><td> 18,4</td><td> 9,0</td><td> 20,8</td><td> 30,0</td>

<td>Sodium sulfate</td><td> 31,4</td><td> 29,4</td><td> 35,5</td><td> 7,2</td><td> 26,3</td><td> 42,8</td><td> 33,2</td><td> 28,3</td>

<td>Sodium silicate</td><td> 0,0</td><td> 4,4</td><td> 0,0</td><td> 4,5</td><td> 0,0</td><td> 6,1</td><td> 0,0</td><td> 4,6</td>

<td>C ethoxylated alkyl alcohol₁₄_₁₅ which has an average molar ethoxylation degree of 7</td><td> 0,4</td><td> 2,6</td><td> 0,8</td><td> 2,5</td><td> 3,1</td><td> 0,3</td><td> 3,8</td><td> 0,4</td>

<td>Sodium percarbonate</td><td> 16,0</td><td> 0,0</td><td> 8,4</td><td> 20,4</td><td> 13,1</td><td> 3,6</td><td> 0,0</td><td> 7,0</td>

<td>Sodium perborate</td><td> 0,0</td><td> 9,9</td><td> 0,0</td><td> 0,0</td><td> 0,0</td><td> 0,0</td><td> 0,0</td><td> 0,0</td>

<td>Tetraacetylethylenediamine (TAED)</td><td> 2,2</td><td> 1,7</td><td> 0,0</td><td> 4,7</td><td> 3,6</td><td> 0,0</td><td> 0,0</td><td> 0,8</td>

<td>Calcium bentonite</td><td> 0,0</td><td> 0,0</td><td> 0,0</td><td> 1,8</td><td> 0,0</td><td> 0,0</td><td> 0,0</td><td> 5,6</td>

<td>Citric acid</td><td> 2,0</td><td> 1,5</td><td> 2,0</td><td> 2,0</td><td> 2,5</td><td> 1,0</td><td> 2,5</td><td> 1,0</td>

<td>Protease (84 mg active / g)</td><td> 0,14</td><td> 0,12</td><td> 0,0</td><td> 0,12</td><td> 0,09</td><td> 0,08</td><td> 0,10</td><td> 0,08</td>

<td>Amylase (22 mg active / g)</td><td> 0,10</td><td> 0,11</td><td> 0,0</td><td> 0,10</td><td> 0,10</td><td> 0,0</td><td> 0,14</td><td> 0,08</td>

<td>Lipase (11 mg active / g)</td><td> 0,70</td><td> 0,50</td><td> 0,0</td><td> 0,70</td><td> 0,50</td><td> 0,0</td><td> 0,0</td><td> 0,0</td>

<td>Cellulase (2.3 mg active / g)</td><td> 0,0</td><td> 0,0</td><td> 0,0</td><td> 0,0</td><td> 0,0</td><td> 0,0</td><td> 0,18</td><td> 0,0</td>

<td>Charity agent composition of Example 5</td><td> 1,4</td><td> 0,6</td><td> 0,8</td><td> 1,0</td><td> 0,7</td><td> 0,3</td><td> 0,7</td><td> 1,2</td>

Water &amp; Miscellaneous csp 100%

The equipment and materials described in Examples 1 to 19 can be obtained

<img file="AR080330A1_D0058.tif" />

of the following: IKA Werke GmbH &amp; Co. KG, Staufen, Germany; CP Kelco, Atlanta, United States; Forberg International AS, Larvik, Norway; Degussa GmbH, Düsseldorf, Germany; Niro A / S, Soeberg, Denmark; Baker Perkins Ltd, Peterborough, United Kingdom; Nippon Shokubai, Tokyo, Japan; BASF, Ludwigshafen, Germany; Braun, Kronberg, Germany; Industrial Chemicals Limited, Thurrock, United Kingdom; Primex ehf, Siglufjordur, Iceland; ISP World Headquarters; Polysciences, Inc. of Warrington, Pennsylvania, United States; Cytec Industries Inc., New Jersey, United States; International Specialty Products, Wayne, New Jersey, United States; P&amp;G Chemicals Americas, Cincinnati, Ohio, United States; Sigma-Aldrich Corp., St. Louis, Missouri, United States, Dow Chemical Company of Midland, Ml, USA UU.

Examples 14 to 23. Fabric conditioner

Non-limiting examples of fabric conditioners containing the polymer coated perfume microcapsules described in this specification are summarized in the following table.

EXAMPLES

<td>(% in weigh)</td><td> 14</td><td> 15</td><td> 16</td><td> 17</td><td> 18</td><td> 19</td><td> 20</td><td> 21</td><td> 22</td><td> 23</td>

<td>IFSA^to</td><td> 14</td><td> 16,47</td><td> 14</td><td> 12</td><td> 12</td><td> 16,47</td><td> —</td><td> —</td><td> 5</td><td> 10</td>

<td>FSA^b</td><td></td><td></td><td></td><td></td><td> —</td><td></td><td> 3,00</td><td> —</td><td> —</td><td> —</td>

<td>FSA^C</td><td></td><td></td><td></td><td></td><td> —</td><td></td><td></td><td> 6,5</td><td> —</td><td> ,—</td>

<td>Ethanol</td><td> 2,18</td><td> 2,57</td><td> 2,18</td><td> 1,95</td><td> 1,95</td><td> 2,57</td><td> —</td><td> —</td><td> 0,81</td><td></td>

<td>Isopropyl alcohol</td><td> —</td><td> —</td><td> —</td><td> —</td><td> —</td><td> —</td><td> 0,33</td><td> 1,22</td><td> —</td><td> 1,0-</td>

<td>Starch^d</td><td> 1,25</td><td> 1,47</td><td> 2,00</td><td> 1,25</td><td></td><td> 2,30</td><td> 0,5</td><td> 0,70</td><td> 0,71</td><td> 0,42</td>

<td>Stabilization phase polymer^F</td><td> 0,21</td><td> 0,25</td><td> 0,21</td><td> 0,21</td><td> 0,14</td><td> 0,18</td><td> 0,15</td><td> 0,14</td><td> 0,2</td><td> 0,1</td>

<td>Foam suppressor⁹</td><td> —</td><td> —</td><td> —</td><td> —</td><td> —</td><td> —</td><td> —</td><td> 0,1</td><td> —</td><td></td>

<td rowspan="2">Calcium chloride</td><td> 0,15</td><td> 0,176</td><td> 0,15</td><td> 0,15</td><td> 0,30</td><td> 0,176</td><td> —</td><td> 0,1-</td><td> —</td><td> 0025.</td>

<td></td><td></td><td></td><td></td><td></td><td></td><td></td><td> 0,15</td><td></td><td></td>

<td>DTPA^h</td><td> 0,017</td><td> 0,017</td><td> 0,017</td><td> 0,017</td><td> 0,007</td><td> 0,007</td><td> 0,20</td><td> —</td><td> 0,002</td><td> 0,002</td>

<td>Preservative (ppm)^{l, j}</td><td> 5</td><td> 5</td><td> 5</td><td> 5</td><td> 5</td><td> 5</td><td>b *</td><td>25Ó</td><td> 5</td><td> 5</td>

<td>Antifoam^k</td><td> 0,015</td><td> 0,018</td><td> 0,015</td><td> 0,015</td><td> 0,015</td><td> 0,015</td><td> —</td><td> —</td><td> 0,015</td><td> 0,015</td>

<td>Silicone'</td><td> 1</td><td> —</td><td> —</td><td> 3</td><td> —</td><td> —</td><td> —</td><td> —</td><td> 1</td><td></td>

<td>Dye (ppm)</td><td> 40</td><td> 40</td><td> 40</td><td> 40</td><td> 40</td><td> 40</td><td> 11</td><td colspan="2"> 30-300 30</td><td> 30</td>

<td>Ammonium chloride</td><td> 0,100</td><td> 0,118</td><td> 0,100</td><td> 0,100</td><td> 0,115</td><td> 0,115</td><td> —</td><td> —</td><td></td><td> —</td>

<td>HCl</td><td> 0,012</td><td> 0,014</td><td> 0,012</td><td> 0,012</td><td> 0,028</td><td> 0,028</td><td> 0,016</td><td> 0,025</td><td> 0,011</td><td> 0,011</td>

<td>0.2 microcapsules perfume coated with polymer as described in the Example two</td><td> 0,02</td><td> 0,1</td><td> 0,15 0,12</td><td> 0,13</td><td> 0,3</td><td> 0,4</td><td> 0,24</td><td> 0,1</td>

<td>Additional pure perfume 0.8</td><td> 0,7</td><td> 0,9</td><td> 0,5 1,2</td><td> 0,5</td><td> 1,1</td><td> 0,6</td><td> 1,0</td><td> 0,9</td>

<td>Deionized water t</td><td>t</td><td>t</td><td>ΐ t</td><td>t</td><td>t</td><td>t</td><td>t</td><td>t</td>

<td colspan="5">N, N-di (seboyloxyethyl) -N, N-dimethylammonium chloride.</td><td></td><td></td><td></td><td></td>

<td colspan="6">Methyl bis (seboamidoethyl) 2-hydroxyethyl ammonium methyl sulfate.</td><td></td><td></td><td></td>

<td>Product of the</td><td>reaction</td><td>from</td><td>fatty acid</td><td>with</td><td colspan="3">methyldiethanolamine</td><td>in a</td>

1.5: 1 molar ratio quaternized with methyl chloride, which produces a 1: 1 molar mixture of N, N-bis (stearoyl-oxy-ethyl) Ν, Ν-dimethylammonium chloride and N ^ stearoyl- oxy-ethyl) N, -hydroxyethyl N, N dimethylammonium chloride.

High starch cationic corn starch, available from National Starch under the trade name CATO®. ^F Rheovis CDE ex BASF.

⁹ SE39 from Wacker

Diethylenetriaminepentaacetic acid

KATHON® CG CG available from Rohm and Haas Co. "PPM" is "parts per million".

^J Gluteraldehyde [ς

Antifoam silicone agent available from Dow Corning Corp. under the trade name DC2310.

Silicone emulsion, available under the trade name E3500 distributed by Wacker ^t balance

Examples 24-29. Liquid formulations for laundry (HDL)

<td>Ingredient</td><td> 24</td><td> 25</td><td> 26</td><td> 27</td><td> 28</td><td> 29</td>

<td>Alkyl sulfate</td><td> 0,00</td><td> 0,50</td><td> 12,0</td><td> 12,0</td><td> 6,0</td><td> 7,0</td>

<td>Dodecyl Benzene Sulfonic Acid</td><td> 8,0</td><td> 8,0</td><td> 1,0</td><td> 1,0</td><td> 2,0</td><td> 3,0</td>

<td>Ethoxylated alcohol</td><td> 8,0</td><td> 6,0</td><td> 5,0</td><td> 7,0</td><td> 5,0</td><td> 3,0</td>

<td>Citric acid</td><td> 5,0</td><td> 3,0</td><td> 3,0</td><td> 5,0</td><td> 2,0</td><td> 3,0</td>

<td>Fatty acid</td><td> 3,0</td><td> 5,0</td><td> 5,0</td><td> 3,0</td><td> 6,0</td><td> 5,0</td>

<td>Quaternized hexamethylenediamine ethoxysulfated</td><td> 1,9</td><td> 1,2</td><td> 1,5</td><td> 2,0</td><td> 1,0</td><td> 1,0</td>

<td>Diethylenetriamine pentamethylene phosphonic acid</td><td> 0,3</td><td> 0,2</td><td> 0,2</td><td> 0,3</td><td> 0,1</td><td> 0,2</td>

<td>Enzymes</td><td> 1,20</td><td> 0,80</td><td> 0</td><td> 1,2</td><td> 0</td><td> 0,8</td>

<td>Brightener (FWA with disulfonated stilbene diamine base)</td><td> 0,14</td><td> 0,09</td><td> 0</td><td> 0,14</td><td> 0,01</td><td> 0,09</td>

<td>Cationic hydroxyethyl cellulose</td><td> 0</td><td> 0</td><td> 0,10</td><td> 0</td><td> 0,200</td><td> 0,30</td>

<td>Poly (diallyl dimethyl ammonium acrylamide-co-chloride)</td><td> 0</td><td> 0</td><td> 0</td><td> 0,50</td><td> 0,10</td><td> 0</td>

<td>Structuring hydrogenated castor oil</td><td> 0,50</td><td> 0,44</td><td> 0,2</td><td> 0,2</td><td> 0,3</td><td> 0,3</td>

5G

<td>Boric acid</td><td> 2,4</td><td> 1,5</td><td> 1,0</td><td> 2,4</td><td> 1,0</td><td> 1,5</td>

<td>Ethanol</td><td> 0,50</td><td> 1,0</td><td> 2,0</td><td> 2,0</td><td> 1,0</td><td> 1,0</td>

<td>1,2 propanediol</td><td> 2,0</td><td> 3,0</td><td> 1,0</td><td> 1,0</td><td> 0,01</td><td> 0,01</td>

<td>Glutaraldehyde</td><td> 0</td><td> 0</td><td colspan="2">19 ppm 0</td><td colspan="2">13 ppm 0</td>

<td>Diethylene Glycol (SDR)</td><td> 1,6</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td>

<td>2,3-methyl -1,3-propanediol (M pdiol)</td><td> 1,0</td><td> 1,0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td>

<td>Mono ethanol amine</td><td> 1,0</td><td> 0,5</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td>

<td>Sufficient NaOH to provide the formulation with a pH of:</td><td>pH 8</td><td>pH 8</td><td>pH 8</td><td>pH 8</td><td>pH 8</td><td>pH 8</td>

<td>Cumene Sodium Sulphonate (NaCS)</td><td> 2,00</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td>

<td>Silicone Emulsion (PDMS)</td><td colspan="3"> 0,003 0,003 0,003</td><td> 0,00 3</td><td> 0,003</td><td> 0,003</td>

<td>Pure perfume</td><td> 0,02</td><td> 0,15</td><td> 0,0</td><td> 0,2</td><td> 0,3</td><td> 0,1</td>

<td>Perfume microcapsules coated with polymer as described in Example 2</td><td> 0,2</td><td> 0,02</td><td> 0,1</td><td> 0,15</td><td> 0,12</td><td> 0,13</td>

<td>Water</td><td>csp</td><td>csp</td><td>csp</td><td>csp</td><td>csp</td><td>csp</td>

Example 30. Shampoo formulation

Ingredient

Ammonium Laureth Sulfate (AE₃S) 6.00

Ammonium Lauryl Sulfate (ALS) 10.00

Laureth-4 Alcohol 0.90

Trihydroxystearin⁽⁷⁾ 0,10

Perfume microcapsules coated with polymer as described in 0.60

Example 2

Sodium Chloride 0.40

0.04 citric acid

Sodium Citrate 0.40

Sodium Benzoate 0.25

Ethylene diamine tetraacetic acid 0.10

Dimethicone '⁹'¹⁰'¹¹⁾ 1,00⁽⁹⁾

Water and minor components (QS at 100%) csp

The dimensions and values ​​set forth herein should not be construed as strictly limited to the exact numerical values ​​mentioned. Instead of elio, unless specified in any other way, each of these dimensions will mean both the mentioned value and also a functionally equivalent range that encompasses that value. For example, one dimension

<img file="AR080330A1_D0059.tif" />

described as "40 mm" refer to "approximately 40 mm".

All documents cited in the Detailed Description of the invention are incorporated, in the relevant part, as reference in the present description. Mention of any document should not be construed as an admission that it constitutes a prior art with respect to the present invention. To the extent that any meaning or definition of a term in this document contradicts any meaning or definition of the term in a document incorporated as a reference, the meaning or definition assigned to the term in this document shall prevail.

Although particular embodiments of the present invention have been illustrated and described, it will be apparent to persons with experience in the industry that various changes and modifications can be made without departing from the spirit and scope of the invention. It has been intended, therefore, to encompass in the appended claims all changes and modifications within the scope of the invention.