Composite coextruded polymeric material
Abstract
The present invention relates to laminates comprising a polyvinylidene fluoride resin layer, a thermoplastic resin layer, and an intermediate polyalkyl methacrylate layer and to the method of making such laminates, preferably by coextrusion.
Term
No projected expiry on record.
- Priority
- Filed
- Granted
- Today
15 claims: 8 independent, 7 dependent
- 1PATENTKRAV 1. Kompositmaterial med tre komponenter, kännetecknat av att det är bildat genom sammanbindning av polyalkylmetakrylat-polyvinylidenfluorid och polyalkylmetakrylat-termoplastisk polymer, som inte är kombinerbar med polyvinylidenfluoriden, varvid materialet har minst en ytteryta av polyvinylidenfluorid och en yta av den med polyvinylidenfluoriden icke kombinerbara termoplastiska polymeren, och varvid det är erhållet genom samsträngsprutning av polyvinylidenfluoriden, polyalkylmetakrylatet och den med polyvinylidenfluoriden icke kombinerbara termoplastiska polymeren, varvid polyalkylmetakrylatet fungerar som mellanliggande bindemedel.
- 2Kompositmaterial enligt krav 1, vilket material uppvisar minst en ytteryta av polyvinylidenfluorid och en yta av den med polyvinylidenfluoriden icke kombinerbara termoplastiska polymeren, kännetecknat av att de båda polymererna är förenade med varandra över hela deras yta medelst polyalkylmetakrylatet, som i sig självt är åtminstone partiellt och fast bundet till hela ytan av de båda polymeren, som skall sammanfogas. J. Material enligt krav 1 eller 2, kännetecknat av att polyalkylmetakrylatet är en blandning av minst 30 viktprocent polyalkylmetakrylat och en annan polymer.
- 34. Material enligt något av de föregående kraven, kännetecknat av att den samsträngsprutade polyvinylidenfluoriden ligger inom ett sådant område beträffande den skenbara viskositeten vid 200°C att den för minst två hastighetsgradienter i följande tabell har skenbar viskositet inom de båda angivna gränsvärdena för den skenbara viskositeten:7907864-8
- 45. Kompositmaterial enligt något av de föregående kraven, kännetecknat av att polyalkylmetakrylatet är polymetylmetakrylat.
- 56. Kompositmaterial enligt krav 5, kännetecknat av att polymetylmetakrylatet uppvisar en viskositet, uppmätt vid 200°C, inom de gränser, för en given hastighetsgradient, som anges i följande tabell:
- 67. Kompositmaterial enligt något av de föregående kraven, kännetecknat av att flödena av polyvinylidenfluorid, polyalkylmetakrylat och med polyvinylidenfluoriden icke kombinerbar termoplastisk polymer är förenade allra senast vid munstyckets kanter.
- 78. Kompositmaterial enligt krav 7, kännetecknat av att en flödesfördelare är anordnad mellan strängsprutapparaterna och munstycket.
- 89. Förfarande för framställning av ett kompositmaterial av polyvinylidenfluorid - med polyvinylidenfluoriden icke kombinerbar termoplastisk polymer, kännetecknat av att man samsträngsprutar polyvinylidenfluoriden, ett polyalkylmetakrylat och en med polyvinylidenfluoriden icke kombinerbar termoplastisk polymer, varvid polyalkylmetakrylatet fungerar som mellanliggande bindemedel.
- 910. Förfarande enligt krav 9, kännetecknat av att polyalkylmetakrylatet är en blandning av minst 50 viktprocent polyalkylmetakrylat och en annan monomer.
- 1011. Förfarande enligt något av kraven 9-11, kännetecknat av att den samsträngsprutade polyvinylidenfluoriden har en sådan viskositet vid 200°C att den för minst två hastig7907864-8 hetsgradienter ligger inom de gränsvärden för den skenbara viskositeten som framgår av följande tabell:j ,3 >3 ,3 .3
- 1112. Förfarande enligt något av kraven 9-11, kännetecknat av att polyalkylmetakrylatet är polymetylmetakrylat.
- 1213. Förfarande enligt krav 12, kännetecknat av att polymetylmetakrylatet har en viskositet, uppmätt vid 200°C, liggande mellan de gränsvärden, för en given hastighetsgradient, som anges i följande tabell:
- 1314. Förfarande enligt något av kraven 9-13, kännetecknat av att flödena av polyvinylidenfluorid, polyalkylmetakrylat och med polyvinylidenfluoriden icke kombinerbar termoplastisk polymer vid slutet av strängsprutapparaterna förenas senast' vid munstyckets kanter.
- 1415. Förfarande enligt krav 14, kännetecknat av att man anordnar en flödesfördelare mellan strängsprutapparaterna och. munstycket.
- 1516. Förfarande enligt något av kraven 9-15, kännetecknat av att munstyckets temperatur hålles mellan 180 och 280°C.
Independent claims15
95 paragraphs in 2 sections, as filed
(24) Race day (11) Pubhcenngs86-06-09 number 445 jgg
80-03-26 q _ nq _ oiinuj t. In Anggkan come as
79-09-21
PATENT AUTHORITY (62) National application number (86) International filing date (86) Filing date for European patent application (30)
78-09-25 FR 78 27361
S Swedish patent application
O completed international patent application with number
O converted European patent application with number
79-05-22 FR 79 12952 (71) Applicant Products Chimiques Ugine Kuhlmann, Courbevoie FR (72) Inventor A. Strassel, Oullirts (74) Agent Bergling & Sundbergh AB (54) Designation Composite material of polyvinylidene fluoride and a non-combinable thermoplastic and process for preparing this material by co-extrusion (56) Listed audience stations: US 3,524,906 (260-900) (57) Summary:
The present invention relates to a composite material having at least one outer surface of polyvinylidene fluoride and a surface of non-combinable thermoplastic polymer with polyvinylidene fluoride, the characteristic of the composite being that the two polymers are joined to each other over their entire surface by a polyalkyl methacrylate which is in its partially and firmly bonded to the entire surface of the two polymers to be joined.
The invention further relates to a process for the production of a composite material of polyvinylidene fluoride - with the polyvinylidene fluoride non-combinable thermoplastic polymer, the characteristic of the process being the co-extruding of the polyvinylidene fluoride, a polyalkylmethacrylate and a polyvinylacidylidene binder.
DB 603415
7907864-8
The present invention relates to a composite material consisting of polyvinylidene fluoride, which polymer will hereinafter be referred to as PVF<sub>2</sub>, and a thermoplastic polymer which is not compatible with PVFg. This composite material is obtained by co-extrusion.
The technique of co-extrusion of thermoplastics is well known and is particularly described in Polymer Plastics Technology and Engineering, volume 3, pages 49-68: Coextruded films - Process and Properties by John E. Guillotte.
In general, three methods are known for the co-extrusion of thermoplastics using a number of conventional extruders, which number is equal to the number of polymers to be extruded. The first method involves extruding the polymers separately and combining them when leaving the spray nozzle. The second method consists in feeding a single nozzle by means of at least two extruders, the nozzle having as many channels as there are extruders and thus polymers to be extruded. The liquid polymers are combined at the edges of the spray nozzle, ie. essentially immediately before leaving
7907864-8 nozzle. The third method consists in feeding a flow distributor by means of the desired number of extruders. In this distributor, the polymers are combined to form a single flow which is fed into the nozzle. In these processes, the respective feed rates of the extruders generally provide the ability to control the relative thicknesses of the extruded polymers.
While countless polymers can be co-extruded, it has not been possible to combine PVK with other polymers using this technique. The reason for this is that PVFg is not compatible with the other polymers and also the well-known fact that fluorinated resins do not show appreciable adhesion to the majority of the thermoplastic polymers. This difficulty in combining PVFg with other thermoplastics is also known in connection with the technique of lamination, which consists of taking two prefabricated films, one of PVFg and the other of any desired thermoplastic, and trying to get them to adhere to each other under pressure and during application of heat. Laminating attempts have also been made, without success, to combine a prefabricated film of PVFg with films of polyvinyl chloride, polystyrene, polymethylmethacrylate or an acrylonitrile-butadiene-styrene copolymer leaving the extruder, i. in virtually molten state. Even under these conditions, the two polymers are easily separated after they have cooled down.
So far, when one has wanted to combine PVFg with another thermoplastic thus incompatible, one has to resort to a binder. This process shows the disadvantage that it comprises three steps, namely the preparation of the film of PVFg, the preparation of the film of the thermoplastic and the joining of the films by means of adhesives and pressing them.
These operations are impractical and slow and generally require the use of solvents based on solvents which are difficult to eliminate, and in addition, it is not possible to use the composite material immediately due to the time required to dry the adhesive. In addition, the resulting composite is not homogeneous or uniform, since the interfaces are still sensitive to all the phenomena that cause delamination. Accordingly, it can be said that by means of gluing, one does not obtain a uniform composite material but only adjacent thermoplastic elements, the final
7907864-8 structure is heterogeneous.
According to the present invention, these disadvantages are eliminated, and according to the invention a new uniform composite material having a homogeneous structure is obtained, wherein the elements are firmly bonded to each other. This new composite material exhibits at least one outer surface of PVF<sub>2</sub> and a surface of a thermoplastic polymer which is not compatible with PVF<sub>2</sub>, is characterized in that the two polymers are joined or joined together over their entire surface by means of a polyalkyl methacrylate, which itself is at least partially fixed to the entire surface of the two polymers to be joined. The interfaces between PVF<sub>2 </sub>and polyalkylmethacrylate as well as between non-combinable thermoplastic polymer and polyalkylmethacrylate are in the form of an alloy which can be represented e.g. of the result of mixing the components in the molten state, whereby this form of bonding between the components allows one to regard the composite material as uniform and with homogeneous structure as opposed to a so-called composite material with heterogeneous structure, such as e.g. can be obtained by bonding, and for which the interfaces have no transition zone but are clearly marked and fragile or weak. The product of the invention can also be defined as a composite material consisting of three components and formed by the combination of polyalkylmethacrylate PVFg and polyalkylmethacrylate - thermoplastic polymer which is not compatible with PVF<sub>2</sub>, said material having at least one outer surface of PVFg and one surface of thermoplastic polymer which is not compatible with. PVF ,,. The outer surface or surfaces of PVF<sub>2</sub> the composite material is usually free (free) of polyalkyl methacrylate which acts as a binder. This is understandable, if you want PVF<sub>2</sub> the surface must retain all its inherent properties.
For mainly economic reasons, the composite material usually exhibits only one outer surface of PVFg, while the other outer surface is represented by the thermoplastic polymer which is not compatible with PVF<sub>2</sub>However, the thermoplastic polymer non-combinable with PVFg may serve as an adhesive surface for another material. Thus, it is possible that both surface surfaces of the composite material of the invention consist of PVF.<sub>2</sub> with the following order between the three elements: PVFβ - polyalkylmethacrylate with PVF, non-combinable thermoplastic polymer - polyalkylmethacrylate | That is why, according to the invention, the term
7907864-8 the surface of it with. The PVFg non-combinable polymer can mean both an outer surface and an inner surface.
Such a product, which may be present in all forms of thermoplastics commonly used, such as e.g. tubes, housings, profiles, films and plates, of which the latter themselves can be given new forms by known methods, e.g. hot forming, is of great value because it has at least one outer surface which is weather resistant and which generally has all the special properties which apply to PWg, and another surface which exhibits the mechanical properties and generally all the special properties which apply to PWg non-combinable thermoplastics, in the form of a structurally uniform and homogeneous material.
Such a material is obtained in a very interesting and advantageous way by co-extrusion, which is quite surprising in view of the known notorious difficulty of having PVFg adhere to a thermoplastic polymer. It has been found that when co-extruding a polyalkyl methacrylate simultaneously with PVF<sup>0Gh</sup>· <sup>it doesn't</sup> combinable thermoplastic material so that the polymethacrylate is positioned between the two polymers, one obtains a composite material which can be used immediately and whose different layers are firmly bonded to each other. Thus, the invention also relates to a process for producing a composite material of PVFg and non-combustible thermoplastic polymer with PVFg, characterized by co-extruding PVFg, a polyalkylmethacrylate and a thermoplastic polymer which is not combinable with PVFg, wherein .
Although all PVFg materials provide satisfactory results, the best results are obtained with a PVEg * <sup>as</sup> Ligs<sup>s></sup> within such a range of apparent viscosity at 200 ° C that, at least for two velocity gradients in the table below, it has an apparent viscosity that lies between the two specified extremes of apparent viscosity.
7907864-8
<td rowspan="2">Speed gradient sec<sup> J</sup>·</td><td colspan="2">Values for apparent viscosity in Poise</td>
<td>minimum</td><td>maximum</td>
<td> 3,54</td><td> 30 10<sup>3</sup></td><td> 200 10<sup>3</sup></td>
<td> 11,81</td><td> 18 10<sup>3</sup></td><td> 93 10<sup>3</sup></td>
<td> 35,4</td><td> 11 10<sup>3</sup></td><td> 47 10<sup>3</sup> '</td>
<td> 118</td><td> 6,5 10<sup>3</sup></td><td> 21 10<sup>3</sup></td>
<td> 354</td><td> 3,9 10<sup>3</sup></td><td> 10 10<sup>3</sup></td>
<td> 1181</td><td> 2,3 10<sup>3</sup></td><td> 4,5 10<sup>3</sup></td>
The apparent apparent viscosities are measured in a known manner using a capillary rheometer, taking into account the Rabinowitch correction applicable to non-Newtonian fluids.
Although the thickness of the PVFg layer is generally not significant, it is preferable for economic reasons to produce a composite material for which the thickness of the PVFg layer is between 10 µm and a few tenths of a millimeter. Furthermore, with PVFg is understood not only the homopolymer but also the copolymers containing at least 70% by weight of PVFg or mixtures of PVFg with other polymers.
The polyalkylmethacrylate is preferably a polymethylmethacrylate, or PMMA, whose viscosity in the molten state can be selected within the range of viscosity applicable to commercially available PMMA materials, the person skilled in the art knowing possible ways to adjust the viscosity to the desired value, e.g. by mixing with small quantities of batches of any other polymer, provided that a value of at least 75% by weight of polyalkylmethacrylate is maintained.
It has further been found that the quality of the polyalkyl methacrylate and possibly of PVFg should be chosen as a function of the viscosity of the non-combinable thermoplastic material in the molten state. Excellent results are obtained with viscosities for polymethylmethacrylate within the specified limits for a rate gradient given below and measured at 200 ° C. However, these values are not limiting, as those skilled in the art can modify the viscosity as a function of extrusion to control the ride.
7907864-8
<td rowspan="2">Speed gradient sec<sup>-1</sup></td><td colspan="2">Values for apparent viscosity in Poise</td>
<td>minimum</td><td>maximum</td>
<td> 3,54</td><td>100 x 10<sup>3</sup></td><td>500 x 10<sup>3</sup></td>
<td> 11,81</td><td>50 x 10<sup>3</sup></td><td>280 x 10<sup>3</sup></td>
<td> 35,4</td><td>25 x 10<sup>3</sup></td><td>150 x 10<sup>3</sup></td>
<td> 118</td><td>1J x 10<sup>3</sup></td><td>80 x 10<sup>3</sup></td>
<td> 354</td><td>7 x 10<sup>3</sup></td><td>50 x 10<sup>3</sup></td>
<td> 1181</td><td>3.5 x 10<sup>3</sup></td><td>JO x 10<sup>3</sup></td>
It is also possible to combine with the polyalkylmethacrylate by mixing at least one other thermoplastic polymer, provided that this mixture contains at least 10% by weight of polyalkylmethacrylate. The polymer blended with the polyalkyl methacrylate can be selected from the following products or groups of products: the fluorinated thermoplastics, the chlorinated vinyl polymers, the styrene polymers, polycarbonate, polyurethanes, poly (ester ether), the graft copolymer of the styrene-acrylonitrile acrylic elastomer, copolymer acrylonitrile-butadiene-styrene, polyacrylic esters such as polymethyl, polyethyl or polybutyl acrylate, or the copolymers of these acrylic esters with e.g. vinyl derivatives or the copolymers of alkyl methacrylate. with e.g. vinyl chloride, vinyl acetate, methyl acrylate, styrene, isobutene, acrylic acid, acrylonitrile and methacrylonitrile.
The thickness of the polyalkyl methacrylate is adjusted according to the particular case between a few µm and 200 µm. It is generally not advisable to work with larger thicknesses because of the part that the polyalkyl methacrylate has in the mechanical properties of the entire structure.
The thermoplastic polymer not compatible with PVF may be a chlorinated vinyl polymer, such as polyvinyl chloride or polyvinylene chloride, a styrene polymer such as polystyrene or a more impact-resistant polystyrene, a polycarbonate, a polyurethane, a graft copolymer of styrene-acrylonitrile-acrylic elastomer or a copolymer of acrylonitrile-butylene. The thickness of the layer of this thermoplastic polymer can be any thickness, usually from a few tenths to a few millimeters. Of course, this thermoplastic polymer may contain chargers, plasticizers, stabilizers, dyes or other conventional additives.
7907864-8
The apparatus used to make the composite material consists of extruders, nozzles and preferably a flow distributor, all of the conventional type currently used in the field of co-extrusion of thermoplastics. The thickness of each layer is controlled by the feed rate of each extruder.
For the purpose of the invention, the temperature of the nozzle is between 180 ° C and 280 ° C, which temperature is dependent on the co-extruded materials. The temperatures of the extruders are those temperatures normally used for simple extrusion of each of the polymers. In order to ensure satisfactory final cohesion between the three polymers, it is advisable to carry out the co-extrusion of these three polymers in such a way that the materials leaving the extruders are joined at the latest at the nozzle edges. In some cases, very good adhesion may be desirable, and in these cases, the flows of PVFg, thermoplastic and polyalkyl methacrylate leave the extruder so that they run into a certain distance before reaching the edges of the nozzle. In the latter case, instead of a multi-channel nozzle, a flow distributor is provided between the outlet of the extruder and a single-channel nozzle.
Using the technique of co-extrusion and this with the help of at least three extruders, the following composite materials can be prepared with three components: PVFg - polyalkylmethacrylate - with PVF ^ non-combinable thermoplastic · polymer - polyalkylmethacrylate - PVFg.
The following examples further illustrate the invention.
The viscosity is measured by means of a capillary rheometer of the manufacturer INSTRON model 3211 with a capillary which is about 50.8 mm long and which has a nozzle diameter of about 1.27 mm.
Example 1
Three SMTP - KAUFMAN extruders are used, the first of which is equipped with a degassing system with a diameter of 120 mm and a screw length 33 times its diameter. It is used to extrude the acrylonitrile-butadiene-styrene (ABS) copolymer, while the second extruder has a diameter of 50 mm (Super - 2 x 50) and is used for the polymethylmethacrylate (PMMA) and the third, which has a
7907864-8 diameter of 40 mm, was used for PVFg.
These three extruders provide a flow cylinder with a flow, which cylinder itself is connected to a conventional flat nozzle intended to produce a film about 4 mm thick, followed by a calender and a conventional film or sheet extruder. .
The ABS material used is UGIKRAL SF 10 456 from Produits Chimiques Ugine Kuhlmann, while the PMMA material is ALTULITE 2 710 manufactured by the company Altulor, and PVFg is the material FORAFLON 1000 HD from Produits Chemiques Ugine Kuhlmann.
The viscosity of ABS measured at 220 ° C is 75 x 10 10 ^ P at a velocity gradient of 5.6 sec and 10 x 10 ^P at a velocity gradient of 2 sec \ The viscosity of PMMA measured at 200 ° C is 110 x 10 · ^ at the gradient 5.6 sec and 14 x 10 6 at the gradient 2 sec \
Finally, the viscosity of PVF<sub>p</sub>, measured at 200 ° C, Z * 2 * - · are 141 x 10- 3 and 8.8 x ΙΟ-, respectively, for the velocity gradients
5.5 sec<sup>-1</sup> respectively 354 sec<sup>-1</sup>.
The temperatures at which the extruders are heated are in the range of 190-210 ° C for ABS, 180-200 ° C for PMMA and 180-220 ° C for PVFg.
Both the flow distributor and the nozzle have a temperature of 210 ° C. The film is obtained between the cylinders in a calender heated to 80 ° C.
The total amount is about 500 kg / hour. Quantities of the three extruders are regulated in such a way as to obtain a final composite material comprising ABS in the thickness of 4 mm, PMMA in the thickness of 50 µm and PVFg in the thickness of 100 µl. These three layers are perfectly fused with each other as soon as they leave the nozzle. After cooling, a composite material having a homogeneous structure is obtained, one surface thereof being PVF g, the other being ABS.
Example 2
Using a flow distributor by means of which a five-layer material can be obtained when leaving the nozzle, Example 1 is repeated so that using the same polymers and the same extruders heated to the same temperatures, a composite film is obtained, which in turn exhibits a 75 µm thick layer of PVFg, a 50 µm thick layer
7907864-8 of PMMA, a J mm thick layer of ABS, a 50 µm thick layer of PMMA and finally a 75 / W thick layer of PVF<sub>g</sub>. The resulting coin composite has five layers, which are perfectly fused together. After cooling, a composite material having a homogeneous structure and having two surface surfaces of
PVEg, while its core or center is ABS. Example 3
A two-screw extruder manufactured by KESTERMANN K 107 was used for polyvinyl chloride (PVC), namely EKAVYL SL 66 from Produits Chimiques Ugine Kuhlmann, while JO mm diameter SMTP extruder was used for the polymethylmethacrylate (PMMA), namely RESARITE KOX 125 from the company Resarte, and a KAUFMAN extruder with a diameter of 40 mm for PVFg, namely F0RAFL0N 4000 HD from 15 Produits Chimiques Ugine Kuhlmann.
These three extruders supply a flow distributor, which in turn is connected to a hose extruder nozzle. A vacuum forming device and a conventional type drawing system complete the apparatus.
The three polymers are co-extruded at their normal extruder temperatures, i.e. 160-200 ° C for PVC, 180-200 ° C for PMMA and 180-200 ° C for PVFg. The extruder head and flow distributor are maintained at a temperature between 195 and 200 ° C.
A hose having an outer diameter of 5θ mm is obtained, which hose in turn consists of a layer of PVC having a thickness of about J mm, a layer of PMMA having a thickness of about 50 µm and an inner layer of PVFg having a thickness of about 75 µm. The three polymers are in the form of a composite material with homogeneous and uniform structure.
Example 4
The three extruders from Example J were used, the apparatus terminating in a flow distributor and a hose spray nozzle. In addition, the apparatus comprises a known system for slab forming and blowing, by means of which system the three J5 polymers can be co-extruded and blown.
In the first extruder, PVC, namely EKAVYL SK 55B from Produits Chimiques Ugine Kuhlmann, is fed into the second PMMA, namely RESARITE KOX 125 from the company Resarte, and in the third PVFg, namely FORAFLON 1000 HD from
Product Chimiques Ugine Kuhlmann. The temperatures reached are
7907864-8 or respectively: 16O-18O ° C, 180-190 ° C and 190-200 ° C; the flow distributor and feed nozzle have a temperature of 190 ° C.
A co-extruded blank for blowing is obtained, which blank is then blown in a conventional manner to produce a bottle. The three extruders have been coupled to the flow distributor in such a way that the bottle has an inner layer of PVFg which is about 100 µm thick, an intermediate layer of PMMA which is about 80 µm thick and finally an outer layer of PVC which is about 8/10 mm thick .
The three layers of the resulting bottle are perfectly fused to each other as soon as they leave the spray head. After cooling, the bottle is in the form of a composite material with homogeneous and uniform structure.
Example 5
Three SMTP - KAUFMAN extruders are used, the first of which is equipped with a degassing system with a diameter of 120 mm and a screw length equal to 55 times its diameter. It is used to extrude the copolymer of acrylonitrile-butadiene-styrene (ABS), while the other, having a diameter of 5θ mm (Super - 2 x 5 °), is used for a mixture of the following polymers: polymethylmethacrylate (PMMA): 40 parts by weight, PVFg: J0 parts by weight, ABS: 50 parts by weight; while the third, having a diameter of 40 mm, was used for PVFg.
These three extruders supply a distribution cylinder, which in turn is coupled to a conventional flat nozzle intended to produce a plate having a thickness of about 4 mm, followed by a conventional calender and drawing extruder.
The ABS material used is UGIKRAL SF 10 456 from Produits Chimiques Ugine Kuhlmann, while PMMA is ALTULITE 2 710 from the company Altulor, and PVFg is the material FORAFLON 1000 HD from Produits Chimiques Ugine Kuhlmann.
The viscosity of ABS, measured at 220 ° C, is 75 x 10 6 P at the velocity gradient 5.6 sec<sup>-</sup>^ and 10 x 10 · ^ P at the gradient 2 sec ”<sup>1</sup>. The viscosity of PMMA, measured at 200 ° C, is 110 x 10<sup>y</sup> at the gradient 2 sec.
Finally, the viscosity of PVFg, measured at 200 ° C, is 141 x 10 10 and 8.8 x 10 10P at the velocity gradient 3.5 sec, respectively.<sup>-</sup>·<sup>1</sup>· Respectively 554 sec
The temperatures to which the extruders are heated,
7907864-8 is in the range of 190-210 ° C for ABS, 180-200 ° C for the mixture containing PMMA and 180-220 ° C for PVF
The flow distributor has a temperature of 210 ° C, which also applies to the nozzle. The film is obtained between the cylinders to a calender heated to 80 ° C.
The total quantity is about J00 kg / hour. Quantities of the three extruders are adjusted in such a way as to finally obtain a composite material comprising ABS in the thickness of 4 mm, the mixture containing PMMA in the thickness of JOuµm and PVFg in the thickness of 100 µm. These three layers are perfectly fused together as they leave the nozzle. After cooling, a composite material of homogeneous structure is obtained, for which one of the surfaces is PVF<sub>2</sub> and the other ABS.
Example 6
Using the same conditions as in Example 5 but replacing the PMMA-containing mixture with the following mixture: JO parts by weight PMMA (RESARITE KOX 125), 40 parts by weight of polyacrylic derivatives (ACRYLOID KM J2J B) and JO parts by weight ABS (UGIKRAL SF 10 4j6 from Produits Chimiques Ugine Kuhlmann), you obtain a composite material with a homogeneous structure, in which the layers are perfectly fused to one another already at the outlet from the nozzle and in which one of the surfaces is made of PVF<sub>2</sub><sup>and the other </sup>of ABS.
7907864-8
Contents2
58 members in 35 offices
Priority claims11
| Document | Office | Kind | Date |
|---|---|---|---|
| 7827361 | France | A | |
| 7827361 | France | A | |
| 7912952 | France | A | |
| 7912952 | France | A | |
| 790003305 | Republic of Korea | A | |
| 790003305 | Republic of Korea | A | |
| 7827361 | – | – | – |
| 7912952 | – | – | – |
| FR19780027361 | – | – | – |
| FR19790012952 | – | – | – |
| KR19790003305 | – | – | – |
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| IL58234A | Israel | A | |
| KR830000832B1 | Republic of Korea | B1 | |
| US4415519A | United States of America | A | |
| SU1071216A3 | Soviet Union (until 1991) | A3 | |
| HU182890B | Hungary | B | |
| IN153223B | India | B | |
| ATA628479A | Austria | A | |
| IE48693B1 | Ireland | B1 | |
| FI69007B | Finland | B | |
| YU40233B | Yugoslavia, later Serbia and Montenegro (until 2006) | B | |
| AT379107B | Austria | B | |
| FI69007C | Finland | C | |
| IT1119928B | Italy | B | |
| IT7968738A0 | Italy | A0 | |
| SE445193BThis record | Sweden | B | |
| NO155686B | Norway | B | |
| NO155686C | Norway | C | |
| JPH0313059B2 | Japan | B2 | |
| BG49714A3 | Bulgaria | A3 | |
| SI7912323A8 | Slovenia | A8 |
2 legal events, as the office reported them to INPADOC
Over the term
Point at a mark for the eventEvents
| Event | Code | |
|---|---|---|
| Patent has lapsedLapsedNUG | NUG | |
| Patent in forceNAL | NAL |
Numbers
- Publication, DOCDB
- 445193
- Publication, EPODOC
- SE445193
- Application
- 7907864
- Application, DOCDB
- 7907864
- Application, EPODOC
- SE19790007864
Titles2
- Swedish
- KOMPOSITMATERIAL AV POLYVINYLIDENFLUORID OCH EN DERMED ICKE KOMBINERBAR TERMOPLAST SAMT FORFARANDE FOR FRAMSTELNING AV DETTA MATERIAL GENOM SAMSTRENGSPRUTNING
- English
- COMPOSITION MATERIAL OF POLYVINYLIDEEN FLUORIDE AND THEREFORE NON-COMBINABLE THERMOPLASTY AND PROCEDURE FOR THE PREPARATION OF THIS MATERIAL BY COMPRESSION
Classification
- CPC, 16
- B32B27/08
- B32B37/153
- B29C48/09
- B29C48/21
- B29C48/335
- Y10T428/31544
- Y10T428/31928
- Y10T428/31536
- Y10T428/3154
- Y10T428/31935
- B29C48/08
- B32B37/12
- B32B27/304
- B32B2327/12
- B32B27/308
- B32B2333/12
- IPC, 5
- B29C48 08
- B32B27 08
- B32B27 30
- B32B37 15
- B44F1 12