Untitled record
Abstract
Polyolefin compositions useful for construction articles for outdoor use, for instance house siding, cladding, soffit or roofing. The compositions comprise a polyolefin substrate which has incorporated therein one or more additives selected from the group consisting of a) one or more ultraviolet light absorbers, b) one or more hindered amine light stabilizers and c) one or more antioxidants. Advantageously, the polyolefin substrate also has incorporated therein d) one or more colorants, e) one or more fillers, f) one or more flame retardants and optionally g) one or more antimicrobial compounds. The compositions exhibit certain performance levels according to standard tests, for example impact strength of > 35 in-lb per ASTM D4226, coefficient of linear thermal expansion of < 4.5 x 10E-05 in/in/ft per ASTM D696 and optionally acceptable color uniformity in finished siding parts per ASTM D6864 and/or acceptable low delta E color for the intended application per ASTM D2244 and/or a UL
Term
No projected expiry on record.
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14 claims: 14 independent, 0 dependent
- 11- An extruded product of an extruded article in the form of a word, letter, word, letter, word, letter, word, letter, word, letter, letter, letter, letter, letter, letter, or letter 1- منتج مقذوف extruded article في صورة اوط ج نوط لي زلنوكسا ، وططا ،لأو تا يو ، وق ا ا و You're sooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooo'''''s soooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooo or 0.178 or يكوووورم زجلنووووتج زلقووووذوف extruded article سوووول 0.076 سوووو 0.030 برصوووولى زوووو 0.178 سوووو 0.070 in Egypt 8.62 in Egypt 0.18 in Egypt2Yes, 14.84 pounds, 0.31 pounds 0.070 برصوولى وو م مووت 8.62 بطسووكطس 0.18 ةطوو ق موو 2ى زوو 14.84 بطسووكطس 0.31 ةطوو ق M, Wishtl, Aj م ى ويشتل عج 5 Polyolefin substrate 5 ،ر، لل برزي يوزف ت polyolefin composition ،تضلت ة، ك برزي يوزف ت polyolefin substrate م مج Baht zlar d zltfl zlkhttt mt zlrl zlkr l mt بهط زلر د زلضطفل زلختطة مت زلجلرعل زلكر ل مت Ultraviolet light absorbers يى مر د متصطص زضرط فرق زلنف جي ultraviolet light absorbersا I am stuck in a car, hindered by amine light stabilizers and بى مثلتطت ضرط ذ ت يم ت معطمل hindered amine light stabilizers و Antioxidants جى مضطد ت ألك antioxidantsا 10 A,L TZTR,L 10 ا ،ل ت زتر، لل Moore, hit with a force of 3.95 pounds, 35 meters long, with a straight and narrow fold, made for the American Wall of Talouta. موور ،صووطد بلقوو ة 3.95 وور،تتمتر 35 برصوول-ةطوو ى مقطسوول وفقووط زوووججلع ل ألمريك وول تلووطة ED 4226 ASTM American Society for Testing and Materials ZLR D ى دي 4226اASTM American Society for Testing and Materials زلر د Maatmu, if there is a lot of linear thermal expansion in Balqoa 8.1 معطمو ،لو د او رةي أوي linear thermal expansion بلقوو ة 8.1 × 10-05 سوو ق سو ق دةنول مئريل 4.5 05-10 x برصلقبرصلقم ى مقطسل وفقط زوججلع ل ألمريك ول تلوطة زلور د American D 696 and ttat Society for Testing and Materials 15 دي 696و ت طةيط Society for Testing and Materials 15 , Jut Zurm is inverted, and it is not American. ،جوط زورم مقلورس فوي ألنو كط زجط ل ول زلشوألل وفقوط زووججلع ل ألمريك ول تلوطة زلور د American DE 6864 and Q Society for Testing and Materials دي 6864 وقيو Society for Testing and Materials Zorm Dztot E Monkhfm Maqlorus Zakhsutkh Zalajorb and the fall of Zoujjala for American and Taluta Zlor D American زورم دزتوط E مونخفم مقلورس زخسوتخ زلأجورب وفقوط زووججلع ل ألمريك ول تلوطة زلور د American De 2244 and Qo Society for Testing and Materials دي 2244وقيو Society for Testing and Materials 20 Maintenance of 1-UL-94 V, 0-V, and flame spread index with a power of 200 mm. 20 ،صون 1-UL-94 V يو 0-V وقيو مؤشور تشوطة زهو flame spread index بلقو ة 200 مقطسول J-84 T American Society for Testing and Materials and only a pair of American Society for Testing and Materials D ي-84ت American Society for Testing and Materials وفقط زوججلع ل ألمريك ل تلطة زلر د
- 22- Use the polyolefin substrate for a long time. 2- زلنوووتج وفقوووطر زعنصووور ز لطيووول 1ا ا ووو وووت ،ضووول ت د ووو ة، وووك زلووورزي يوز فووو ت polyolefin substrate مر د ضطفل ضطف ل ،شتل عج :25 De mr d ztgret colorants a 25 دى مر د زتجريت colorantsا ٦٣٧٤ ٦٣٧٤ -١١٠- -١١٠- She is a teacher and filler هى مر د زل ط fillersا We are talking about flame retardants and وى مر د ،أ ر زجه flame retardants و Yesterday, I found antimicrobial compounds ى مر،لطت مضطد زجل كروبطت antimicrobial compoundsت
- 35 3- Polyolefin substrate Alwata Awat 5 3- زلنتج وفقط زعنصر ز لطيل 1ا ا ،كرم ة، وك زلورزي يوزفو ت polyolefin substrate علوطة عوت Polyethylene copolymer, polypropylene, polypropylene and polypropylene copolymer Wooooooooooooooooooooooow polyethylene ya u jj mt yi mnhtt بوووووورزي ث جوووووو ت polyethyleneا بوووووورزي بووووووروب ج ت polypropyleneا بوووووورز لر مشووووووترو ث ج تقبووووووروب ج ت ethylene/propylene copolymerا جوووووو ج مووووووت بوووووورزي بوووووروب ج ت polypropylene وبوووووورزي ث جوووووو ت polyethyleneا يو ج ج مت يي منهطت
- 410 4- Zlntg and only Zlntl 1A A:10 4- زلنتج وفقط زعنصر ز لطيل 1ا ا : Ultraviolet light absorbers -aryl-s-triazines 2-hydroxybenzophenones and cyanoacrylates ت ت طة مر د متصطص زضرط فرق زلنف جي ultraviolet light absorbers موت زلجلرعول زلكر ول مووت مر،لووطت و ةو، ووي ف ن وو بنووكو ،وو ري ي وس hydroxyphenylbenzotriazolesا مر،لووطت ،ووري -يةي -s-، ري ي يت tris-aryl-s-triazinesا مر،لطت و ةو، ي بنكو ت hydroxybenzoatesا مر،لوطت 2-و ةو، ي بنكو ف نرم 2-hydroxybenzophenones ومر،لطت س ط ر يكريخت cyanoacrylatesا 15 Diakylhydroxylamine stabilizer, rice, towel stabilizer, organic phosphorus. phosphorus Such as dialkylhydroxylamine. 15 وووت ت وووطة مضوووطد ت ألك ووو antioxidants موووت زلجلرعووول زلكر ووول موووت ،رز فوووطت مثلووو stabilizer فرسوفرةي عضوري organic phosphorusقمضوطد يك و ف نورزي phenolic antioxidant معوطقا مثلتوطت د ي يزك و و ةو، و يمو ت dialkylhydroxylamine stabilizersا ،رز فوطت مثلو فرسوفرةي عضوري organic phosphorus stabilizerقمثلووو د ي يزك ووو و ةو، ووو يمووو ت dialkylhydroxylamine I am like amine oxide stabilizers, and I am like organic persimmons. stabilizerا مثلتوووطت يو، ووو يمووو ت amine oxide stabilizers و،رز فوووطت مثلووو فرسوووفرةي عضوووري 20 organic phosphorus stabilizer such as amine oxide stabilizer 20 organic phosphorus stabilizerقمثل يو، يم ت amine oxide stabilizerا Woooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooot وووت ت وووطة مووور د زتجوووريت colorants موووت زلجلرعووول زلكر ووول موووت صووولطعطت عضوووريل وع ووور عضوووريل Organic and inorganic pigments اorganic and inorganic pigments And tata mor d zlo t fillers death zaljalarul zalkar and death yaz wataf talal natural fibers and mor d mot وت ت وطة مور د زلو ط fillers موت زلجلرعول زلكر ول موت يز وطف طل ع ول natural fibers ومور د مو ط And inorganic fillers are common و inorganic fillers ع ر عضريل 25 brominated flame retardants 25 ت ت طة مور د ،وأ ر زجهو flame retardants موت زلجلرعول زلكر ول موت مور د ،وأ ر زهو معطزجول بووطزكجرة chlorinated flame retardantsا موور د ،ووأ ر زهوو معطزجوول بووطزلرو brominated flame ٦٣٧٤ ٦٣٧٤ -١١١- -١١١- phosphorus based flame retardants. Lots of borate compounds, and again, you see, there are many metal containing flame retardants. retardantsا مور د ،ووأ ر زهوو مط لوول عجوو يسووط فرسووفرة phosphorus based flame retardantsا مر،لووطت و ةو، وو مع وول metal hydroxide compoundsا مر،لووطت مط لوول عجوو يسووط م خموو ت melamine based compoundsا مر،لوطت ي ت لورم antimony compoundsا مر،لوطت بورةت borate compounds ومر د ،أ ر زه ي رى ، تري عج معطدم metal containing flame retardantsت 5 5
- 55- Zlntg and only Zlntgl 1A A:5- زلنتج وفقط زعنصر ز لطيل 1ا ا : T-t-t-t-t-t-t-t-t-t-t-t-r-t-t-t-t-t-t-t-t-t-r,-t-t-b-r,-t-t-t-b-r,-t-2-t-t-t-t-t-t-t-t-t-t-t-t-tt H2-BnO,RY and S-5-chloro ت ت طة مر د متصطص زضرط فرق زلنف جي ultraviolet light absorbers موت زلجلرعول زلكر ول مت 5-كجورةو-2- 3-t-ب ر، و -2-و ةو، وي -5-م ث و ف ن و ى-H2-بنوكو ،و ري ي وس -5-chloro -2- K-Rm-α-3)-2A2-5A3-BOOO-t-butyl-2-hydroxy-5-methylphenyl)-2H-benzotriazole -2- ك رم وووووو-α- 3)-2ا 2- 5ا3-بوووووو-t-butyl-2-hydroxy-5-methylphenyl)-2H-benzotriazole 10 E-2-(3,5-bis-α-cumyl-2-hydroxyphenyl)-2H benzotriazole 6-D-E-2 -4- 4,6-diphenyl-2-(4-hexyloxy-2-hydroxyphenyl)-s-triazine 6a4-buuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuu-4a2 -D Y M Th Woooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooo -4-4-you-4,6-bis-(2) ,4-dimethyl phenyl)-2-(2-hydroxy-4-octyloxyphenyl)-s-triazine 5a3-d-y-,wort-pr,woo - 10 و ةو، وووووووووووووووي ف ن ووووووووووووووو ى-H2-بنوووووووووووووووكو ،ووووووووووووووو ري ي وس -2-(3,5-bis-α-cumyl-2-hydroxyphenyl)-2H benzotriazoleا 6ا4-د ي ف ن ووو -2- 4- وك ووو يو، وووي -2-و ةو، وووي ف ن ووو ى-s-،ووو ري ي يوووت 4,6-diphenyl-2-(4-hexyloxy-2-hydroxyphenyl)-s-triazineا 6ا4-بوووووووووووووووو - 4ا2-د ي م ث وووووووووووووووو ف ن ووووو ى-2- 2-و ةو، وووووي -4-يو،ت ووووو يو، وووووي ف ن ووووو ى-s-،ووووو ري ي يوووووت -4,6-bis-(2,4-dimethyl phenyl)-2-(2-hydroxy-4-octyloxyphenyl)-s-triazineا وك ووووط دي وووو 5ا3-د ي -،وووورت-ب ر، وووو - 15 4-Hydroxybenzoate 4-di-tert-butyl-4-hydroxybenzoate 15 4-و ةو، ووووي بنووووكو ت hexadecyl 3,5-di-tert-butyl-4-hydroxybenzoateا 4ا2-د ي -،وووورت- Br,Fn 5a3-dj-,rt-bt,-4-fw,jbnco-t-2,4-di-tert-butylphenyl 3,5-di-tert butyl-4-hydroxybenzoate f4-u 2-4-octyloxy 2-4-octyloxy ب ر، ف ن 5ا3-د ي -،رت-ب ر، -4-و ةو، ي بنكو ت -2,4-di-tert-butylphenyl 3,5-di-tert butyl-4-hydroxybenzoate و4-يو،ت وووووووو يو، ووووووووي -2-و ةو، ووووووووي بنووووووووكو ف نوووووووورم -2-4-octyloxy and hydroxybenzophenone و hydroxybenzophenone And it's like this وت ت وطة مثلتوطت ضورط ذ ت يمو ت معوطق hindered amine light stabilizers موت زلجلرعول زلكر ول 20 died: 20 مت: 1y 1-Soooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooo 1-1 1ى 1-سووووو كجر وك وووووو يو، وووووي -6ا6ا2ا2-،تووووو ر م ث ووووو -4-يو،توووووط دي وووووو يم نوووووور ب ل ريووووو ت -1 Acyclohexyloxy-2,2,6,6-tetramethyl-4-octadecylaminopiperidine اcyclohexyloxy-2,2,6,6-tetramethyl-4-octadecylaminopiperidine 2Y B6A6A2A2-,T R M T B L R T-4-Y S Latkt (bis(2,2,6,6-tetramethylpiperidin-4-yl) 2ى ب 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى س لطكطت (bis(2,2,6,6-tetramethylpiperidin-4-yl sebacate اsebacate 25 3H PO 1-IS TR,WY-6A6A2A2-,TUR MTH W B L REO T-4-WY SO LATKT-2,2,6,6-bis(1-acetoxy 25 3ىبو 1-يس تر، وي -6ا6ا2ا2-،تو ر م ث و ب ل ريو ت-4- و ى سو لطكطت -2,2,6,6-bis(1-acetoxy tetramethylpiperidin-4-yl) sebacate اtetramethylpiperidin-4-yl) sebacate ٦٣٧٤ ٦٣٧٤ -١١٢- -١١٢- 4-Booooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooossssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssss These Ooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooo) bis 4ى بوووووووووووووووووو 6ا6ا2ا2ا1-بنتووووووووووووووووووط م ث وووووووووووووووووو ب ل ريوووووووووووووووووو ت-4- وووووووووووووووووو ى سوووووووووووووووووو لطكطت -1,2,2,6,6)bis pentamethylpiperidin-4-yl) sebacate اpentamethylpiperidin-4-yl) sebacate 5 EBOOO 1-Sooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooove with it - 1)bis 5ىبوووو 1-سوووو كجر وك وووو يو، ووووي -6ا6ا2ا2-،توووو ر م ث وووو ب ل ريوووو ت-4- وووو ى سوووو لطكطت -1)bis Acyclohexyloxy-2,2,6,6-tetramethylpiperidin-4-yl) sebacate اcyclohexyloxy-2,2,6,6-tetramethylpiperidin-4-yl) sebacate 5 6EBOOO 1-YU, TWUU, WY-6A6A2A2-, TOOO R M T W O B L R O T-4- W O Y SOOO LATKT -bis(1-octyloxy) 5 6ىبووو 1-يو،ت ووو يو، وووي -6ا6ا2ا2-،تووو ر م ث ووو ب ل ريووو ت-4- ووو ى سووو لطكطت -bis(1-octyloxy 2,2,6,6;-tetramethylpiperidin-4-yl) sebacate 2,2,6,6؛-tetramethylpiperidin-4-yl) sebacate 7YBOOO 1-YSOOO-6A6A2A2-,TOOO R MTH WOO B L REOOO T-4-OOOO YY SOOOOO LKTKT -bis(1-acyl-2,2,6,6-tetra 7ىبووو 1-يسووو -6ا6ا2ا2-،تووو ر م ث ووو ب ل ريووو ت-4- ووو ى سوووو لطكطت -bis(1-acyl-2,2,6,6-tetra Amethylpiperidin-4-yl) sebacate اmethylpiperidin-4-yl) sebacate 8YBOOOOO 6A6A2A2A1-Pentoooot M Th WOO-4-B L REOOO Y N-BR, WOO-5-A3-DD Y -, WURT-BR, WOO-4 8ىبووووو 6ا6ا2ا2ا1-بنتوووووط م ث ووووو -4-ب ل ريووووو ى N-ب ر، ووووو -5ا3-د ي -،ووووورت-ب ر، ووووو -4 10 And, uh, we're going to buy it and put it -4-bis(1,2,2,6,6-pentamethyl-4-piperidyl) n-butyl-3,5-di-tert-butyl 10 و ةو، وي بنكيو مطزر ووطت -4-bis(1,2,2,6,6-pentamethyl-4-piperidyl) n-butyl-3,5-di-tert-butyl hydroxybenzylmalonate hydroxybenzylmalonate 9Y4A2-B] 1-S KJR K Y W, J-6A6A2A2-, T R M T B L R E T-4- B R, YM NER[-6- 9ى4ا2-ب ] 1-س كجر وك ي و، ي -6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ىب ر، يم نر[-6- 2-ww,jw 2-و ةو، ي ث Yum Noooooooooooooooooooooooooooooooooooooooooooooooooooooow -2,4-bis[(1-cyclohexyloxy-2,2,6,6-tetramethylpiperidin-4-yl)butyl يم نووووووووووور -s-،ووووووووووو ري ي يووووووووووووت -2,4-bis[(1-cyclohexyloxy-2,2,6,6-tetramethylpiperidin-4-yl)butyl Amino]-6-(2-hydroxyethyl amino-s-triazine 15 اamino]-6-(2-hydroxyethyl amino-s-triazine 15 10 EBOOO 1-Soooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooo 1-1)bis 10ىبوووو 1-سوووو كجر وك وووو يو، ووووي -6ا6ا2ا2-،توووو ر م ث وووو ب ل ريوووو ت-4- وووو ى يد لووووطت -1)bis Acyclohexyloxy-2,2,6,6-tetramethylpiperidin-4-yl) adipate اcyclohexyloxy-2,2,6,6-tetramethylpiperidin-4-yl) adipate ( 1-cyclohexyloxy-2,2,6,6-piperidin-4-yl)butylamino]-6-chloro-s 11ى4ا2-ب ] 1-س كجر وك يو، ي -6ا6ا2ا2-ب ل ريو ت-4- و ىب ر، و يم نور[-6-كجورةو-s-،ووووووووووووووووو ري ي يوووووووووووووووووت -2,4-bis[(1-cyclohexyloxy-2,2,6,6-piperidin-4-yl)butylamino]-6-chloro-s atriazine 20 اtriazine 20 12J1-2-WW, J-2-MTH Proper, J-4-WH, J-6A6A2A2-,T R M T B L R T -1 12ى 1- 2-و ةو، ي -2-م ث بروبر، يى-4-و ةو، ي -6ا6ا2ا2-،ت ر م ث ب ل ري ت -1 2)a-hydroxy-2-methylpropoxy)-4-hydroxy-2,2,6,6-tetramethylpiperidine 2)ا-hydroxy-2-methylpropoxy)-4-hydroxy-2,2,6,6-tetramethylpiperidine 13Y1-2-WWW,WY-2-MTHW PROPER,WWY-4-U,WOR-6A6A2A2-,TW R M T W B L REO T-2)-1 13ى1- 2-و ةو، ووي -2-م ث وو بروبر، وويى-4-يو، وور-6ا6ا2ا2-،توو ر م ث وو ب ل ريوو ت -2)-1 Hydroxy-2-methylpropoxy)-4-oxo-2,2,6,6-tetramethylpiperidine اhydroxy-2-methylpropoxy)-4-oxo-2,2,6,6-tetramethylpiperidine ٦٣٧٤ ٦٣٧٤ -١١٣- -١١٣- 14Y1-2-WW, J-2-MTHW Proper, YY-4-U, tot Dikt Rio Yu, Y-6A6A2A2-,TU R MTHW 14ى1- 2-و ةو، ي -2-م ث و بروبر، ويى-4-يو،توط ديكط ريو يو، وي -6ا6ا2ا2-،تو ر م ث و B L REOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOO T-1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethyl ب ل ريووووووووووووووووووووووووووووووووووووووووووووووووووو ت -1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethyl piperidine اpiperidine 15YBOOOOO 1- 2-WOW, WOW-2-MTH WOW PROPER, WOWY-6A6A2A2-, TOOO R M W WOO B L REOOO T-4- WOO Y 15ىبوووو 1- 2-و ةو، ووووي -2-م ث وووو بروبر، وووويى-6ا6ا2ا2-،توووو ر م ث وووو ب ل ريوووو ت-4- وووو ى bis(1-(2-hydroxy-2-methylpropoxy)-2,2,6,6-tetramethylpiperidin-4-yl)sebacate 5 ml اbis(1-(2-hydroxy-2-methylpropoxy)-2,2,6,6-tetramethylpiperidin-4-yl) sebacate 5 س لطكطت 16B 1- 2-WW, J-2-M Th Proper, Yi-6A6A2A2-,T R M Th B L R T-4-Y Yd Lat 16ىب 1- 2-و ةو، ي -2-م ث بروبر، يى-6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى يد لطت bis(1-(2-hydroxy-2-methylpropoxy)-2,2,6,6-tetramethylpiperidin-4-yl)adipate اbis(1-(2-hydroxy-2-methylpropoxy)-2,2,6,6-tetramethylpiperidin-4-yl) adipate 17J4A2-B {2 -1[-N-WW, J-2-MTH Proper, J-6A6A2A2-,T R M Th B L R E T-4- 17ى4ا2-ب }2 -1[-N-و ةو، ي -2-م ث بروبر، يى-6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- f[-N-b-r, y-ym-nor-6-2-oh, w-th-ym-n-s-,w-2,4-bis{N-[1-(2-hydroxy) و [-N-ب ر، و يم نور -6- 2-و ةو، وي ث و يم نورى-s-،و ري ي يوت -2,4-bis{N-[1-(2-hydroxy 2-methylpropoxy)-2,2,6,6-tetramethylpiperidin-4-yl]-N-butylamino}-6-(2-hydroxyethyl- 10 2-methylpropoxy)-2,2,6,6-tetramethylpiperidin-4-yl]-N-butylamino}-6-(2-hydroxyethyl- 10 amino)-s-triazine اamino)-s-triazine 18A4-Benco-6A6A2A2-,T R M T B L R T 4-benzoyl-2,2,6,6-tetramethylpiperidine 18ى4-بنكوي -6ا6ا2ا2-،ت ر م ث ب ل ري ت 4-benzoyl-2,2,6,6-tetramethylpiperidineا 19 D D - 6 A6 A2 A2 A1-Pentoooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooo with it to it - di 19ى د ي- 6ا6ا2ا2ا1-بنتوووووووط م ث ووووووو ب ل ريووووووو ت-4- ووووووو ى p-م ثر، وووووووي بنكيج ووووووو ت مطزر وووووووطت -di 1,2,2,6,6)a-pentamethylpiperidin-4-yl)p-methoxybenzylidenemalonate 1,2,2,6,6)ا-pentamethylpiperidin-4-yl) p-methoxybenzylidenemalonate 15 20 y 6 a 6 a 2 a2-, to r m th w p l r i o t-4- and u, tout dicot t 2,2,6,6-tetramethylpiperidin-4-yl 15 20ى 6ا6ا2ا2-،تو ر م ث وو ب ل ريوو ت-4- و يو،تووط ديكووط ر ت 2,2,6,6-tetramethylpiperidin-4-yl octadecanoate اoctadecanoate 21YB1-U,TU,J-6A6A2A2-,T R M T B L R O E S C W NNT-2,2,6,6-bis(1-octyloxy) 21ى ب 1-يو،ت يو، ي -6ا6ا2ا2-،ت ر م ث ب ل ريو ى سك و نطت -2,2,6,6-bis(1-octyloxy tetramethylpiperidyl)succinate اtetramethylpiperidyl) succinate 22H 6A6A2A2A1-PENTA MTH-4-IM NR B L RE T 1,2,2,6,6-pentamethyl-4-aminopiperidineA 22ى 6ا6ا2ا2ا1-بنتط م ث -4-يم نر ب ل ري ت 1,2,2,6,6-pentamethyl-4-aminopiperidineا 20 23y 2-yu j -9a9a7a7-,t rm w-1-yu,t-8a3-d i a-4-yu,r-sol ru[5a4]dicotm 20 23ى 2-يو ي -9ا9ا7ا7-،ت ر م ث و -1-يو، وط-8ا3-د ي آ -4-يو، ور-سول رو]5ا4[ديكوطم 2a-undecyl-7,7,9,9-tetramethyl-1-oxa-3,8-diaza-4-oxo-spiro[4,5]decane 2ا-undecyl-7,7,9,9-tetramethyl-1-oxa-3,8-diaza-4-oxo-spiro[4,5]decane 24I,RI6A6A2A2-,T-R-M-TH-4-B-L-RI-TREGOR,and Ri-IsO-4-tris(2,2,6,6-tetramethyl) 24ى ،ري 6ا6ا2ا2-،ت ر م ث -4-ب ل ري ى تريجور ،و ري يسو تطت -4-tris(2,2,6,6-tetramethyl piperidyl)nitrilotriacetate اpiperidyl) nitrilotriacetate 25ى ،ووري 2-و ةو، ووي -3- يم نوور - 6ا6ا2ا2-،توو ر م ث وو ب ل ريوو ت-4- ىبروب وو ى تريجوور 26 25 Wow, it's sooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooo (tris(2-hydroxy-3-(amino-(2,2,6,6-tetramethylpiperidin-4-yl)propyl) 25 ،ووووووووووو ري يسوووووووووووو تطت (tris(2-hydroxy-3-(amino-(2,2,6,6-tetramethylpiperidin-4-yl)propyl nitrilotriacetate اnitrilotriacetate ٦٣٧٤ ٦٣٧٤ -١١٤- -١١٤- 26i,tr,6a6a2a2-,t-r-m-th-4-b-l-ri-4-a3a2a1-b-t-t-t-r,r-r, and kht-tetrakis 26ى ،تر ، 6ا6ا2ا2-،ت ر م ث -4-ب ل ري ى-4ا3ا2ا1-ب ر،طم-،ت ر ،ربر، و خت -tetrakis 2,2,6,6)a-tetramethyl-4-piperidyl)-1,2,3,4-butane-tetracarboxylate 2,2,6,6)ا-tetramethyl-4-piperidyl)-1,2,3,4-butane-tetracarboxylate 26 27ى ،توووو ر ،وووو 6ا6ا2ا2ا1-بنتوووووط م ث وووو -4-ب ل ريوووو ى-4ا3ا2ا1-ب ر،ووووطم-،توووو ر ،ربر، وووو خت tetrakis(1,2,2,6,6-pentamethyl-4-piperidyl)-1,2,3,4-butane-tetracarboxylate اtetrakis(1,2,2,6,6-pentamethyl-4-piperidyl)-1,2,3,4-butane-tetracarboxylate 5 28i 1a1'- 2a1- thootm d y wo y-boo 5a5a3a3-,tu r m th wo p l r y nw r m -(1,1'-(1,2-ethanediyl) 5 28ى 1ا1'- 2ا1- ثووطم د ي وو ى-بوو 5ا5ا3ا3-،توو ر م ث وو ب ل ر ينوورمى -(1,1'-(1,2-ethanediyl bis(3,3,5,5-tetramethylpiperazinone) اbis(3,3,5,5-tetramethylpiperazinone) 29Y3-N-U,T F-9A9A7A7-,TU-R-M-TH-8A3A1-,WRI A SOL RO]4.5[DICOTEM-4A2-DYWM-3 29ى 3-N-يو،ت و -9ا9ا7ا7-،تو ر م ث و -8ا3ا1-،و ري آ سول رو]4.5[ديكوطم-4ا2-د ي وم -3 n-octyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro[4.5]decan-2,4-dione اn-octyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro[4.5]decan-2,4-dione 30-8-iso-t-3-dode f-9a9a7a7-, to r m s f -8a3a1-, and ri a sol rho]4.5[dicotm-4a2- 30ى 8-يسو ت -3-دودي و -9ا9ا7ا7-،تو ر م ث و -8ا3ا1-،و ري آ سول رو]4.5[ديكوطم-4ا2- 8a-acetyl-3-dodecyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione 10 dwm 8ا-acetyl-3-dodecyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione 10 د ي وم 31H3-Dodecyl W-1-6A62A2-,Two-R-M-TH-4-B-L-R-E-B-R-O-T-5A2-DYM-3-dodecyl 31ى 3-دودي وو -1- 6ا6ا2ا2-،توو ر م ث و -4-ب ل ري ىب روز وو ت-5ا2-د ي وم -3-dodecyl 2,2,6,6)-1a-tetramethyl-4-piperidyl)pyrrolidin-2,5-dione 2,2,6,6)-1ا-tetramethyl-4-piperidyl)pyrrolidin-2,5-dione -3 32ى 3-دودي ووووووووو -1- 6ا6ا2ا2ا1-بنتوووووووووط م ث ووووووووو -4-ب ل ري ىب روز ووووووووو ت-5ا2-د ي وم -3 Dodecyl-1-(1,2,2,6,6-pentamethyl-4-piperidyl)pyrrolidine-2,5-dione اdodecyl-1-(1,2,2,6,6-pentamethyl-4-piperidyl)pyrrolidine-2,5-dione 15 33i N'N-B -FRAM -NA'N-B 6A6A2A2-,T R M T -4-B L R E H U T M T T D E Y M U T 15 33ى Nا'N-ب -فرةم -Nا'N-ب 6ا6ا2ا2-،ت ر م ث -4-ب ل ري ىوك ط م ث ج ت د ي يمو ت N,N'-bis-formyl-N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine اN,N'-bis-formyl-N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine 33 YIBOOOOO 1-YU WUU YKKTAM WUUU, WUWWY -6A6A2A2-, TOOOOO R MTH WOOOO B L REOOOOO T-4- Ykrber Wooooooooooot -1)bis 33يىبووووو 1-يو ووووو يكطم ووووو يو، وووووي -6ا6ا2ا2-،تووووو ر م ث ووووو ب ل ريووووو ت-4- ىكربر وووووطت -1)bis Undecanyloxy-2,2,6,6-tetramethylpiperidin-4-yl)carbonate اundecanyloxy-2,2,6,6-tetramethylpiperidin-4-yl)carbonate 34 Y and Wawat, c, so-and-to-wow. 34ى ووووط،ج ،فطعوووو 4ا2-بوووو ] 1-سوووو كجر وك وووو يو، ووووي -6ا6ا2ا2-ب ل ريوووو ت-4- وووو ىب ر، وووو 20 yum noor[-6-kjwuraw-s-,wu ri yūt muw na'n-boo 3-ym nour prob wu y th goo t d y ymww t-1)]2,4-bis 20 يم نوور[-6-كجوورةو-s-،وو ري ي يووت موو Nا'N-بوو 3-يم نوور بروب وو ى ث جوو ت د ي يموو تى -1)]2,4-bis cyclohexyloxy-2,2,6,6-piperidin-4-yl)butylamino]-6-chloro-s-triazine with N,N'-bis(3- cyclohexyloxy-2,2,6,6-piperidin-4-yl)butylamino]-6-chloro-s-triazine with N,N'-bis(3- Aminopropyl)ethylenediamine اaminopropyl)ethylenediamine) 35 J and Watt, J, Kth and Wu 2-1 condensate-Wu, Wu, Wu, Wu-6A6A2A2-,TUU R M Th, Wu-4-W, Wu. 35ى وووط،ج ،كث ووو 2 -1 condensate-و ةو، وووي ث ووو ى-6ا6ا2ا2-،تووو ر م ث ووو -4-و ةو، وووي B L REOOOOOOOOOO T 1-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-hydroxypiperidine and the woooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooo 1-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-hydroxypiperidines ب ل ريوووووووووو ت 1-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-hydroxypiperidine والووووووووووم سك وووووووووو ن succinic acid 25 اsuccinic acid 25 ٦٣٧٤ ٦٣٧٤ -١١٥- -١١٥- 36i i,j,th condensate Na'N-b 6a6a2a2-,t t t d -4-b l ri i-wk t m th jo t d d 36ى ط،ج ،كث condensate Nا'N-ب 6ا6ا2ا2-،ت ر م ث -4-ب ل ري ى-وك ط م ث جو ت د ي Yenoow n, n'-bis (2,2,6,6-tetramethyl-4-piperidyl) -Hexamethylenediadine 4-, wooowowowe-woo, and wooow wooooo nir-6 a 2-d, jaro-5 A3 A1-, Revy Y 4-tert-octylamino-2,6-dichloro-1,3,5-triazine يمووووووووو ت N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylenediamine و4-،ووووووووورت-يو،ت ووووووووو يم نر -6ا2-د ي ،جرةو-5ا3ا1-، ري ي يت 4-tert-octylamino-2,6-dichloro-1,3,5-triazineا 37i i,j,th condensate Na'N-b 6a6a2a2-,t t t d -4-b l ri i-wk t m th jo t d y 37ى ط،ج ،كث condensate Nا'N-ب 6ا6ا2ا2-،ت ر م ث -4-ب ل ري ى-وك ط م ث جو ت د ي And 4-suuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuu N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylenediamine 5 و4-سووووووو كجر وك وووووو N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylenediamine 5 يموووووو ت YM NER-6A2-DY,GRO-5A3A1-,RIYT 4-cyclohexylamino-2,6-dichloro-1,3,5-triazine يم نر -6ا2-د ي ،جرةو-5ا3ا1-، ري ي يت 4-cyclohexylamino-2,6-dichloro-1,3,5-triazineا 38i i,j,th condensate Na'N-b - 6a6a2a2-,t t t t -4-b l ri yuk t m th jo t d y 38ى ط،ج ،كث condensate Nا'N-ب - 6ا6ا2ا2-،ت ر م ث -4-ب ل ري ىوك ط م ث جو ت د ي -2 and 4-times Farz Nour-6A N,N'-bis-(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine YMW T -2و4-مرةفرز نوور-6ا N,N'-bis-(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine يموو ت DD,GRRO-5A3A1-,RIYT 4-morpholino-2,6-dichloro-1,3,5-triazine د ي ،جرةو-5ا3ا1-، ري ي يت 4-morpholino-2,6-dichloro-1,3,5-triazineا 10 39y,t,j,kth and condensate Na'N-po - 6a6a2a2a1-pentot m th and -4-b l ryu yuk and m th th go t 10 39ى وط،ج ،كث و condensate Nا'N-بو - 6ا6ا2ا2ا1-بنتوط م ث و -4-ب ل ريو ىوك وط م ث جو ت N,N'-bis-(1,2,2,6,6-pentamethyl-4-piperidyl)hexamethylenediamine and 4-merferase Nr-6a2-di,jr-5a3a1-, 4-morpholino -2,6-dichloro-1,3,5-triazine د ي يمووووووووووووووووووووووووووووووووووووووووووووو ت N,N'-bis-(1,2,2,6,6-pentamethyl-4-piperidyl)hexamethylenediamine و4-مرةفرز نر-6ا2-د ي ،جرةو-5ا3ا1-، ري ي يت 4-morpholino-2,6-dichloro-1,3,5-triazineا 40i wt,j,kth wu 2 condensate-kjwuraw-6a4-boo 4-n-br,w ym noor -6a6a2a2-,tow r m ww 40ى ووط،ج ،كث وو 2 condensate-كجوورةو-6ا4-بوو 4-N-ب ر، وو يم نوور -6ا6ا2ا2-،توو ر م ث وو BlRiO-5A3A1-,F-(2-chloro-4,6-bis(4-n-butylamino-2,2,6,6-tetramethylpiperidyl) ب ل ريو ى-5ا3ا1-،و ري ي يوت -(2-chloro-4,6-bis(4-n-butylamino-2,2,6,6-tetramethylpiperidyl 1,2a-bis(3-aminopropylamino)ethane 1,3,5 and 2a1-b3-im ner prop im see th-triazine 15 1,2ا-bis(3-aminopropylamino)ethane 1,3,5 و2ا1-ب 3-يم نر بروب يم نرى ثطم-triazine 15 41 ywwwt,j,kthwww 2 condensate-kjwww-6a4-ddy - 4-N-br, ww ym now-6a6a2a2a1-bntwwt 41ى ووووط،ج ،كث وووو 2 condensate-كجوووورةو-6ا4-د ي - 4-N-ب ر، وووو يم نوووور -6ا6ا2ا2ا1-بنتووووط M, woooowoowoowoowo, for Rioowoowoowoowoow م ث ووووووووووووووووووو ب ل ريووووووووووووووووووو ى-5ا3ا1-،ووووووووووووووووووو ري ي يوووووووووووووووووووت -1,2,2,6,6-2-chloro-4,6-di-(4-n-butylamino pentamethylpiperidyl)-1,3,5-triazine and 2a1-boooooo - 3-yum Noooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooot-3)-1,2-bis pentamethylpiperidyl)-1,3,5-triazine و2ا1-بوووووو - 3-يم نوووووور بروب وووووو يم نرى ثووووووطم -3)-1,2-bis Aminopropylamino)ethane اaminopropylamino)ethane 20 42 y and wooout, c, so, 9 A 9 A 7 A 7-, Toooooo, R 20 42ى وووووط،ج ،فطعووووو 9ا9ا7ا7-،تووووو ر م ث ووووو -2-سووووو كجر يو ي ووووو -1-يو، وووووط-8ا3-د ي آ -4- U,RSO[5A4]DECOUTUM LOUI,GOROWWET-3,8-7,7,9,9-tetramethyl-2-cycloundecyl-1-oxa يو، رسووول رو ]5ا4[ديكوووطم وي لوووي ،جووورةو و ووو ةيت -3,8-7,7,9,9-tetramethyl-2-cycloundecyl-1-oxa diaza-4-oxospiro diaza-4-oxospiro 4,5]decane and epichlorohydrin 4,5]ا]decane and epichlorohydrin 42 43ى بووووورزي ]م ث ووووو ا 3-يو، وووووي - 6ا6ا2ا2-،تووووو ر م ث ووووو ب ل ريووووو ت-4- ىبروب ووووو ى[ س جر، وووووطم Apoly[methyl,(3-oxy-(2,2,6,6-tetramethylpiperidin-4-yl)propyl)]siloxane 25 اpoly[methyl,(3-oxy-(2,2,6,6-tetramethylpiperidin-4-yl)propyl)] siloxane 25 CAS#182635-99-0 اCAS#182635-99-0 ٦٣٧٤ ٦٣٧٤ -١١٦- -١١٦- 42 4-YM NOOR B L REO T-2,2,6,6 44ى ووط،ج ،فطعوو الووم مطز وو آ ه ةيوو -C18-C22-α-يوزفوو ت-بوورز لر مشووترو -maleic acid an hydride-C18-C22-α-olefin-copolymer مووو 6ا6ا2ا2-،تووو ر م ث ووو -4-يم نووور ب ل ريووو ت -2,2,6,6 tetramethyl-4-aminopiperidine اtetramethyl-4-aminopiperidine - 45ى وووط،ج ،كث ووو يوز جووورمري oligomeric condensate موووت 4ا4'-وك وووط م ث جووو ت ب يم نووور - 5 6A6A2A2-,TOOO R M T W O B L R O T (4,4'-hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine) 5 6ا6ا2ا2-،تووو ر م ث ووو ب ل ريووو تى (4,4'-hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine And 4a2-d y, gora-6-] 6a6a2a2-, tu r m th and b l rio t-4- br, y y m nur [-s-, w r y u t m o و4ا2-د ي ،جورةو-6-] 6ا6ا2ا2-،تو ر م ث و ب ل ريو ت-4- ىب ر، و يم نور[-s-،و ري ي يوت م أو 2,4-dichloro-6-[(2,2,6,6-tetramethylpiperidin-4-yl)butylamino]-s-triazine end-capped 2,4-dichloro-6-[(2,2,6,6-tetramethylpiperidin-4-yl)butylamino]-s-triazine end-capped طرف وط Buuuuuuuuuuuuuuuuuuuuuuuu-2-chloro-4,6-bis(dibutylamino)-s-2-chloro-4,6-bis(dibutylamino)-s بووووو 2-كجوووورةو-6ا4-بوووو د ي ب ر، وووو يم نوووورى-s-،وووو ري ي يووووت -2-chloro-4,6-bis(dibutylamino)-s atriazine اtriazine 10 45 10 46ى وووط،ج ،كث ووو يوز جووورمري oligomeric condensate موووت 4ا4'-وك وووط م ث جووو ت ب يم نووور - 6a6a2a2a1-pentaamethyl piperidine and 4a2-di,gwo-6-] 6a62a2a1-pentaamethyl piperidine L R E O T-4- E B R, W Y M N O R [-s-, W O R Y Y U T M O T F -[2,4-dichloro-6-[(1,2,2,6,6-pentaamethylpiperidin-4) -yl)butylamino s-triazine end-capped poo-2-kjwo-6a4-poo-d-y-pr-r,w-ym-no-s-,wo-riyut-4,6-2-chloro 6ا6ا2ا2ا1-بنتوووووووووط م ث ووووووووو ب ل ريووووووووو تى -4,4'-hexamethylenebis(amino-1,2,2,6,6-pentaamethyl piperidine) و4ا2-د ي ،جوورةو-6-] 6ا6ا2ا2ا1-بنتووط م ث ووو ب ل ريووو ت-4- ىب ر، ووو يم نووور[-s-،ووو ري ي يووت م أووو طرف ووط -[2,4-dichloro-6-[(1,2,2,6,6-pentaamethylpiperidin-4-yl)butylamino s-triazine end-capped بووو 2-كجوورةو-6ا4-بوو د ي ب ر، وو يم نوورى-s-،وو ري ي يووت -4,6-2-chloro bis(dibutylamino)-s-triazine 15 اbis(dibutylamino)-s-triazine 15 47i wt,j,kth wu yuz gourmri oligomeric condensate mut 4a4'-wk wt m th goo t b ym noor -1-proper, w -6a6a2a2-,tu r m th w b l rio t -2,2,6, 6-4,4'-hexamethylenebis(amino-1-propoxy tetramethylpiperidine) and 4a2-dj,gura-6-]1-propr,w-6a2a2-,to r m th w p l r i o t-4- b r, ym nr[-s-,ri yt m a tip t-2,4-dichloro-6-[(1-propoxy-2,2,6,6-tetramethyl) 47ى ووط،ج ،كث وو يوز جوورمري oligomeric condensate مووت 4ا4'-وك ووط م ث جوو ت ب يم نوور -1-بروبر، وي -6ا6ا2ا2-،تو ر م ث و ب ل ريو تى -2,2,6,6-4,4'-hexamethylenebis(amino-1-propoxy tetramethylpiperidine) و4ا2-د ي ،جورةو-6-] 1-بروبر، وي -6ا6ا2ا2-،توو ر م ث و ب ل ريو ت-4- ىب ر، يم نر[-s-، ري ي يت م أ طرف ط -2,4-dichloro-6-[(1-propoxy-2,2,6,6-tetramethyl 20 piperidin-4-yl)butylamino]-striazine end-capped po-2-cgr-6a4-b d y b t, ym see-s- 20 piperidin-4-yl)butylamino]-striazine end-capped بو 2-كجرةو-6ا4-ب د ي ب ر، يم نرى-s- 2-chloro-4,6-bis(dibutylamino)-s-triazine ،ري ي يت 2-chloro-4,6-bis(dibutylamino)-s-triazineا 48 i wt,j,kth wuuz gourmri oligomeric condensate moot 4a4'-wk wt m th goo t b ym noor -1-ysooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooood -4,4'- hexamethylenebis(amino-1-acyloxy 2,2,6,6-tetramethylpiperidine and 4a2-dj,gw-6-]1-isuuu,wi-6a6a2a2-,tow r m wu 48ى ووط،ج ،كث وو يوز جوورمري oligomeric condensate مووت 4ا4'-وك ووط م ث جوو ت ب يم نوور -1-يسووووووو يو، وووووووي -6ا6ا2ا2-،تووووووو ر م ث ووووووو ب ل ريووووووو تى -4,4'-hexamethylenebis(amino-1-acyloxy 2,2,6,6-tetramethylpiperidine و4ا2-د ي ،جوورةو-6-] 1-يسوو يو، ووي -6ا6ا2ا2-،توو ر م ث وو 25 B L R E O T-4- E B R, W Y M N O R [-s-, W O R Y E U T M O T R O T -2,2,6,6-2,4-dichloro-6-[(1-acyloxy) 25 ب ل ريوو ت-4- ىب ر، وو يم نوور[-s-،وو ري ي يووت م أوو طرف ووط -2,2,6,6-2,4-dichloro-6-[(1-acyloxy ٦٣٧٤ ٦٣٧٤ -١١٧- -١١٧- Buuuuuuuuuuuuuuuuuuuuuuu-6a4-iuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuu box بووووو 2-كجوووورةو-6ا4-بوووو د ي tetramethylpiperidin-4-yl)butylamino]-s-triazine end-capped br,im see-s-,ri yt 2-chloro-4,6-bis(dibutylamino)-s-triazine and ب ر، يم نرى-s-، ري ي يت 2-chloro-4,6-bis(dibutylamino)-s-triazine و 49 Y T, J, Z Sars, Aj, H, Bur, asked, Fata’, Y M B, Ay Aluta, Awat, J, Z, Surs, Aj, H, Bur, Ask, Fata’ 2 A1-Boo 3-Yum Nour Probe and Yum Na’r Thawtum 1,2-bis (3-aminopropylamino)ethane mo 49ى ط،ج ، ز صرس عج ه بر سأل ،فطع يى م بى ا يى علوطة عوت وط،ج ،و ز صورس عج وه بر سوأل ،فطعو 2ا1-بوو 3-يم نور بروب و يم نرى ثووطم 1,2-bis(3-aminopropylamino)ethane موو 5 As a result of cyanuric chloride, and in the case of 6A6A2A2-, T R M T B L R E T-4- B R, and 5 كجرةي س ط رةي cyanuric chloride و بى علطة عت 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ىب ر، و 2,2,6,6)t-tetramethylpiperidin-4-yl)butylamine 2,2,6,6)ت-tetramethylpiperidin-4-yl)butylamine يم ت
- 66- You slipped and lost your fingernails. 1 A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, a, a, a, a, a, a, a, a, a, a, a 6- زلنووووتج وفقووووط زعنصوووور ز لطيوووول 1ا ا وووو ووووت ت ووووطة موووور د ،ثل وووو زضوووورط ذ ت ألموووو ت زلعووووطق hindered amine light stabilizers مت زلجلرعل زتي ،تكرم مت:10 2Y B6A6A2A2-,T R M T B L R T-4-Y S Latkt (bis(2,2,6,6-tetramethylpiperidin-4-yl) 10 2ى ب 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى س لطكطت (bis(2,2,6,6-tetramethylpiperidin-4-yl sebacate اsebacate 20 y 6 a 6 a 2 a2-, to r m th w p l r i o t-4- and u, tout dicot t 2,2,6,6-tetramethylpiperidin-4-yl 20ى 6ا6ا2ا2-،تو ر م ث وو ب ل ريوو ت-4- و يو،تووط ديكووط ر ت 2,2,6,6-tetramethylpiperidin-4-yl octadecanoate اoctadecanoate 14y 1- 2-ww, j-2-mw prober, yy-4-u,t dikt riu, j-6a6a2a2-,tw r mw 14ى 1- 2-و ةو، ي -2-م ث بروبر، يى-4-يو،تط ديكط ري يو، ي -6ا6ا2ا2-،تو ر م ث و 15 B L REOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOO T-1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethyl 15 ب ل ريووووووووووووووووووووووووووووووووووووووووووووووووووو ت -1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethyl piperidine اpiperidine 33i N'N-B -FRAM -NA'N-B 6A6A2A2-,T R M T -4-B L R E H U T M T T D E Y M U T 33ى Nا'N-ب -فرةم -Nا'N-ب 6ا6ا2ا2-،ت ر م ث -4-ب ل ري ىوك ط م ث ج ت د ي يمو ت N,N'-bis-formyl-N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine اN,N'-bis-formyl-N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine 36i i,j,th condensate Na'N-b 6a6a2a2-,t t t d -4-b l ri i-wk t m th jo t d d 36ى ط،ج ،كث condensate Nا'N-ب 6ا6ا2ا2-،ت ر م ث -4-ب ل ري ى-وك ط م ث جو ت د ي 20 N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylenediamine and 4-,ووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووو pic 20 يمووووووووو ت N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylenediamine و4-،ووووووووورت-يو،ت ووووووووو YM NER-6A2-DY,GRO-5A3O1-,REYET 4-tert-octylamino-2,6-dichloro-1,3,5-triazine يم نر -6ا2-د ي ،جرةو-5ا3ا1-، ري ي يت 4-tert-octylamino-2,6-dichloro-1,3,5-triazineا 38i i,j,th condensate Na'N-b - 6a6a2a2-,t t t t -4-b l ri yuk t m th jo t d y 38ى ط،ج ،كث condensate Nا'N-ب - 6ا6ا2ا2-،ت ر م ث -4-ب ل ري ىوك ط م ث جو ت د ي -2 and 4-times Farz Nour-6A N,N'-bis-(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine YMW T -2و4-مرةفرز نوور-6ا N,N'-bis-(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine يموو ت DD,GRRO-5A3A1-,RIYT 4-morpholino-2,6-dichloro-1,3,5-triazine د ي ،جرةو-5ا3ا1-، ري ي يت 4-morpholino-2,6-dichloro-1,3,5-triazineا ٦٣٧٤ ٦٣٧٤ -١١٨- -١١٨- 39y,t,j,kth and condensate Na'N-po - 6a6a2a2a1-pentot m th and -4-b l ryu yuk and m th th go t 39ى وط،ج ،كث و condensate Nا'N-بو - 6ا6ا2ا2ا1-بنتوط م ث و -4-ب ل ريو ىوك وط م ث جو ت N,N'-bis-(1,2,2,6,6-pentamethyl-4-piperidyl)hexamethylenediamine and 4-merferase Nr-6a2-di,jr-5a3a1-, 4-morpholino -2,6-dichloro-1,3,5-triazine د ي يمووووووووووووووووووووووووووووووووووووووووووووو ت N,N'-bis-(1,2,2,6,6-pentamethyl-4-piperidyl)hexamethylenediamine و4-مرةفرز نر-6ا2-د ي ،جرةو-5ا3ا1-، ري ي يت 4-morpholino-2,6-dichloro-1,3,5-triazineا 44-YWAT, J-Fta`oum, Matz, and Ah-Yo -C18-C22-α-Yuzfu T--Bors-Lar-Mashutru -maleic acid an 44ى وط،ج ،فطعو الوم مطز و آ ه ةيو -C18-C22-α-يوزفو ت--بورز لر مشوترو -maleic acid an 5 hydride-C18-C22-α-olefin-copolymer Moo 6a6a2a2-,too t-t-2,2,6,6 5 hydride-C18-C22-α-olefin-copolymer مووو 6ا6ا2ا2-،تووو ر م ث ووو -4-يم نووور ب ل ريووو ت -2,2,6,6 tetramethyl-4-aminopiperidine اtetramethyl-4-aminopiperidine 45 ml 45ى مر،وو يوز جوورمري ووط،ج ،كث وو 4 oligomeric compound condensateا4'-وك ووط م ث جوو ت B E M N R -6A6A2A2-,T R M T P L R T -4,4'-hexamethylenebis(amino-2,2,6,6-tetramethyl) ب يم نر -6ا6ا2ا2-،ت ر م ث ب ل ري تى -4,4'-hexamethylenebis(amino-2,2,6,6-tetramethyl (piperidine 4a2-dj,grw-6-]6a6a2a2-,tur rm th and b l rio t-4- br,ym nur[-s-,r (piperidine و4ا2-د ي ،جورةو-6-] 6ا6ا2ا2-،تو ر م ث و ب ل ريو ت-4- ىب ر، و يم نور[-s-،و ري 2,4-dichloro-6-[(2,2,6,6-tetramethylpiperidin-4-yl)butylamino]-s-triazine 10 y ut m or tip and end 2,4-dichloro-6-[(2,2,6,6-tetramethylpiperidin-4-yl)butylamino]-s-triazine 10 ي يوت م أو طرف وط end-capped po-2-cgwo-6a4-poo-d-y-br,w-y-m-n-s-,w-ri-yut-2-chloro-4,6-bis(dibutyl) end-capped بووو 2-كجوورةو-6ا4-بوو د ي ب ر، وو يم نوورى-s-،وو ري ي يووت -2-chloro-4,6-bis(dibutyl amino)-s-triazine اamino)-s-triazine 47 47ى مر،وو يوز جوورمري ووط،ج ،كث وو 4 oligomeric compound condensateا4'-وك ووط م ث جوو ت B y m noor -1-propr,www-6a6a2a2-,tow r m th ww b l riooo t-1-4,4'-hexamethylenebis(amino 15 (propoxy-2,2,6,6-tetramethylpiperidine and 4a2-di) Gooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooo -6-] 1-Proper, Woooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooow-6-a6a2a2- ب يم نووور -1-بروبر، وووي -6ا6ا2ا2-،تووو ر م ث ووو ب ل ريووو تى -1-4,4'-hexamethylenebis(amino 15 (propoxy-2,2,6,6-tetramethylpiperidine و4ا2-د ي ،جوووووووورةو-6-] 1-بروبر، وووووووووي -6ا6ا2ا2- ,tr m th b l ri t-4- ep r,im nr[-s-,ri ut m or tip and t-2,4-dichloro-6-[(1-propoxy) ،تر م ث ب ل ري ت-4- ىب ر، يم نر[-s-، ري ي يوت م أو طرف وط -2,4-dichloro-6-[(1-propoxy -42,2,6,6 BUOOOOOO 2-KJU-6A-tetramethylpiperidin-4-yl)butylamino]-s-triazine end-capped -42,2,6,6 بوووووو 2-كجووووورةو-6ا-tetramethylpiperidin-4-yl)butylamino]-s-triazine end-capped b d y b t, y m nr-s-, ri yt 2-chloro-4,6-bis(dibutylamino)-s-triazine ب د ي ب ر، يم نرى-s-، ري ي يت 2-chloro-4,6-bis(dibutylamino)-s-triazine And, rice, fatt, thant, and thathth, manhat و،رز فطت ثنط ل وثخث ل منهت 20 20
- 77- زلنوتج وفقوط زعنصور ز لطيول 1ا ا و ،كورم مور د ،ثل و ألمو ت زلعوطق hindered amine light stabilizers علطة عت ،رز فل ثنط ل يو ثخث ل منتقط مت زلجلرعل زتي ،تكرم مت:7. 2B6A6A2A2-,T-R-M-TH-B-L-R-T-4-Y-S-O-LtkT (bis(2,2,6,6-tetramethylpiperidin-4-yl) 2ىب 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى سو لطكطت (bis(2,2,6,6-tetramethylpiperidin-4-yl sebacate f 36i i,c,th and condensate Na'N-po 6a6a2a2-,tur rm th and -4-b l rio j-wk and t sebacate و 36ى ط،ج ،كث و condensate Nا'N-بو 6ا6ا2ا2-،تو ر م ث و -4-ب ل ريو ى-وك وط -4And N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylenediamine 25 m s goooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooow -4و N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylenediamine 25 م ث جوووووووووووو ت د ي يموووووووووووو ت ٦٣٧٤ ٦٣٧٤ -١١٩- -١١٩- ,rt-u,t-ym-nor-6a2-di,gura-5a3a1-,riyut-1,3,5-4-tert-octylamino-2,6-dichloro ،رت-يو،ت يم نور -6ا2-د ي ،جورةو-5ا3ا1-،و ري ي يوت -1,3,5-4-tert-octylamino-2,6-dichloro atriazine اtriazine 2B6A6A2A2-,T-R-M-TH-B-L-R-T-4-Y-S-O-LtkT (bis(2,2,6,6-tetramethylpiperidin-4-yl) 2ىب 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى سو لطكطت (bis(2,2,6,6-tetramethylpiperidin-4-yl sebacate f 38i i,c,th and condensate Na'N-po - 6a6a2a2-,tur rm th f -4-b l ryu yuk t sebacate و 38ى ط،ج ،كث و condensate Nا'N-بو - 6ا6ا2ا2-،تو ر م ث و -4-ب ل ريو ىوك وط -4And N,N'-bis-(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine 5 m s gooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooow -4و N,N'-bis-(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine 5 م ث جوووووووووووو ت د ي يموووووووووووو ت MRFR-6A2-DY,GRO-5A3A1-,RIYT 4-morpholino-2,6-dichloro-1,3,5-triazine مرةفرز نر-6ا2-د ي ،جرةو-5ا3ا1-، ري ي يت 4-morpholino-2,6-dichloro-1,3,5-triazineا 2B6A6A2A2-,T-R-M-TH-B-L-R-T-4-Y-S-O-LtkT (bis(2,2,6,6-tetramethylpiperidin-4-yl) 2ىب 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى سو لطكطت (bis(2,2,6,6-tetramethylpiperidin-4-yl sebacate f 39i wt,j,kth wo condensate Na'N-boo - 6a6a2a2a1-pentot m ww -4-b l riou j sebacate و 39ى ووط،ج ،كث وو condensate Nا'N-بوو - 6ا6ا2ا2ا1-بنتووط م ث وو -4-ب ل ريوو ى N,N'-bis-(1,2,2,6,6-pentamethyl-4-piperidyl)hexamethylenediamine wk wwt m wwwwwwwwwwwwwwwwwwwtwt N,N'-bis-(1,2,2,6,6-pentamethyl-4-piperidyl)hexamethylenediamine وك وووط م ث جووو ت د ي يمووو ت 10 And 4-timefrase Nr-6A2-DY,GRO-5A3A1-,RIYT 4-morpholino-2,6-dichloro-1,3,5-triazine 10 و4-مرةفرز نر-6ا2-د ي ،جرةو-5ا3ا1-، ري ي يت 4-morpholino-2,6-dichloro-1,3,5-triazineا 2B6A6A2A2-,T-R-M-TH-B-L-R-T-4-Y-S-O-LtkT (bis(2,2,6,6-tetramethylpiperidin-4-yl) 2ىب 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى سو لطكطت (bis(2,2,6,6-tetramethylpiperidin-4-yl sebacate and 45 mer, yo s gour mri t, c, ch 4 oligomeric compound condensate a4'-wk t m th c t b y m nr -6 a6 a2 a2-,t t r m th b l ri t -4,4'-hexamethylenebis(amino- 2,2,6,6-tetra methylpiperidine) and 4a2-dj,gw-6-]6a62a2-,to r m th and b l rio t-4- y p r,ym nur[-15 s-,w ri YUUTE M O TARWAT WAT-2,4-dichloro-6-[(2,2,6,6-tetramethylpiperidin-4-yl)butylamino]-s sebacate و 45ى مر، يوز جورمري وط،ج ،كث و 4 oligomeric compound condensateا4'-وك وط م ث ج ت ب يم نر -6ا6ا2ا2-،ت ر م ث ب ل ري تى -4,4'-hexamethylenebis(amino-2,2,6,6-tetra methylpiperidine) و4ا2-د ي ،جورةو-6-] 6ا6ا2ا2-،تو ر م ث و ب ل ريو ت-4- ىب ر، و يم نور[-15 s-،وو ري ي يووت م أوو طرف ووط -2,4-dichloro-6-[(2,2,6,6-tetramethylpiperidin-4-yl)butylamino]-s triazine end-capped pooo 2-kjwooro-6a4-boo d y br, wu yum noori-s-,wu ri y uot -4,6-2-chloro triazine end-capped بوووو 2-كجووورةو-6ا4-بووو د ي ب ر، ووو يم نووورى-s-،ووو ري ي يوووت -4,6-2-chloro bis(dibutylamino)-s-triazine 20-6-6-2-2-2-tetramethylpiperidin-4-yl octadecanoate and 45-tetramethylpiperidin-4-yl octadecanoate. ,Kth Wu Uses Gourmet Oligomeric Compound Condensate Mt 4A4'-WK T M T T B YM NR -6 A6 A2 A2-, T R M T B L R T -'4,4 20 (hexamethylenebis(amino-2,2,6, 6-tetramethylpiperidine and 4a2-dd, goooooooooo-6-]6a2a2- bis(dibutylamino)-s-triazineا 20ى 6ا6ا2ا2-،توووووو ر م ث وووووو ب ل ريوووووو ت-4- وووووو يو،تووووووط ديكووووووط ر ت 2,2,6,6-tetramethylpiperidin-4-yl octadecanoate و 45ى ووط،ج ،كث وو يوز جوورمري oligomeric compound condensate مت 4ا4'-وك ط م ث ج ت ب يم نر -6ا6ا2ا2-،ت ر م ث ب ل ري تى -'4,4 20 (hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine و4ا2-د ي ،جووووووورةو-6-] 6ا6ا2ا2- ,tr m th b l ri t-4- ep t,em nr[-s-,ri yt m a tip t-2,4-dichloro-6-[(2,2,6,6-tetra methylpiperidin- 4-yl)butylamino]-s-triazine end-capped poo-2-cgw-6a4-poo-d-y-b-r,w-ym-n-s-,ri-yt 2-chloro-4,6-bis(dibutylamino)-s -triazine ،تر م ث ب ل ري ت-4- ىب ر، يم نر[-s-، ري ي يت م أ طرف ط -2,4-dichloro-6-[(2,2,6,6-tetra methylpiperidin-4-yl)butylamino]-s-triazine end-capped بووو 2-كجوورةو-6ا4-بوو د ي ب ر، وو يم نرى-s-، ري ي يت 2-chloro-4,6-bis(dibutylamino)-s-triazineا 2Y B6A6A2A2-,T R M T B L R T-4-Y S Latkt (bis(2,2,6,6-tetramethylpiperidin-4-yl) 2ى ب 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى س لطكطت (bis(2,2,6,6-tetramethylpiperidin-4-yl 25 sebacate and 20 to 6a6a2a2-, t-4-4-2-2 ,2,6,6 25 sebacate و 20ى 6ا6ا2ا2-،تووووووووووووووو ر م ث ووووووووووووووو ب ل ريووووووووووووووو ت-4- ووووووووووووووو يو،توووووووووووووووط ديكوووووووووووووووط ر ت -2,2,6,6 Tetramethylpiperidin-4-yl octadecanoate اtetramethylpiperidin-4-yl octadecanoate ٦٣٧٤ ٦٣٧٤ -١٢٠- -١٢٠- 2B6A6A2A2-,T-R-M-TH-B-L-R-T-4-Y-S-O-LtkT (bis(2,2,6,6-tetramethylpiperidin-4-yl) 2ىب 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى سو لطكطت (bis(2,2,6,6-tetramethylpiperidin-4-yl sebacate 14 y 1- 2-o y, y-2-m th prober, yy-4-yo,t dikt rio u, y -6a6a2a2-,tr m th b l ri t -1-(2-hydroxy-2- methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetra sebacateا 14ى 1- 2-و ةو، ي -2-م ث بروبر، يى-4-يو،تط ديكط ريو يو، وي -6ا6ا2ا2-،تر م ث ب ل ري ت -1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetra methylpiperidine and 45% methylpiperidine و 45ى ووووط،ج ،كث وووو يوز جوووورمري oligomeric condensate مووووت 4ا4'-وك ووووط 5 m th c t b y m nr -6a6a2a2-,t r m th b l ri t -4,4'-hexamethylenebis(amino-2,2,6,6-tetra methylpiperidine) and 4a2-di,gura-6-] 6a6a2a2-,tur r m th and b l rio t-4- br, y y m nur[-s-,w ri y y ut m o tar wat -2,4-dichloro-6-[(2,2,6) ,6-tetramethylpiperidin-4-yl)butylamino]-s triazine end-capped pooooo 2kgwooro-6a4-booooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooo -4,6-2chloro 5 م ث ج ت ب يم نر -6ا6ا2ا2-،ت ر م ث ب ل ري تى -4,4'-hexamethylenebis(amino-2,2,6,6-tetra methylpiperidine) و4ا2-د ي ،جورةو-6-] 6ا6ا2ا2-،تو ر م ث و ب ل ريو ت-4- ىب ر، و يم نور[-s-،وو ري ي يووت م أوو طرف ووط -2,4-dichloro-6-[(2,2,6,6-tetramethylpiperidin-4-yl)butylamino]-s triazine end-capped بووووو 2كجوووورةو-6ا4-بوووو د ي ب ر، وووو يم نوووورى-s-،وووو ري ي يووووت -4,6-2chloro bis(dibutylamino)-s-triazine اbis(dibutylamino)-s-triazine 10 14y 1- 2-ww, j-2-mw prober, yy-4-u,t dikt riu, j-6a6a2a2-,tw r mw 10 14ى 1- 2-و ةو، ي -2-م ث بروبر، يى-4-يو،تط ديكط ري يو، ي -6ا6ا2ا2-،تو ر م ث و 1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethyl- PLRI T 1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethyl- ب ل ري ت piperidine 20 to 6a6a2a2-, toooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooot-2,2,6,6 tetramethylpiperidin-4-yl octadecanoate and 45 '-wk wwt m th c t b ym nr -6a6a2a2-,t r m th b l ri t -4,4'-hexamethylenebis(amino-2,2,6,6-tetra 15 (methylpiperidine and 4a2-di, Go-6-] 6a6a2a2-, tu r m th and b l rio t-4- bb r, yum nur[- piperidineا 20ى 6ا6ا2ا2-،توووووووووووووو ر م ث وووووووووووووو ب ل ريوووووووووووووو ت-4- وووووووووووووو يو،تووووووووووووووط ديكووووووووووووووط ر ت -2,2,6,6 tetramethylpiperidin-4-yl octadecanoate و 45ى ووووط،ج ،كث وووو يوز جوووورمري مووووت 4ا4'-وك ووووط م ث ج ت ب يم نر -6ا6ا2ا2-،ت ر م ث ب ل ري تى -4,4'-hexamethylenebis(amino-2,2,6,6-tetra 15 (methylpiperidine و4ا2-د ي ،جورةو-6-] 6ا6ا2ا2-،تو ر م ث و ب ل ريو ت-4- ىب ر، و يم نور[- s-,wo ri yot m oo end-2,4-dichloro-6-[(2,2,6,6-tetramethylpiperidin-4-yl)butylamino]-s triazine end-capped pooo 2-kgwo-6a4 -Boo d y br,wu yum noori-s-,wu ri yoooot -4,6-2chloro s-،وو ري ي يووت م أوو طرف ووط -2,4-dichloro-6-[(2,2,6,6-tetramethylpiperidin-4-yl)butylamino]-s triazine end-capped بوووو 2-كجووورةو-6ا4-بووو د ي ب ر، ووو يم نووورى-s-،ووو ري ي يووووت -4,6-2chloro bis(dibutylamino)-s-triazine اbis(dibutylamino)-s-triazine 2B6A6A2A2-,T-R-M-TH-B-L-R-T-4-Y-S-O-LtkT (bis(2,2,6,6-tetramethylpiperidin-4-yl) 2ىب 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى سو لطكطت (bis(2,2,6,6-tetramethylpiperidin-4-yl 20 separate 20 sebacateا 14ى 1- 2-و ةو، ي -2-م ث بروبر، يى-4-يو،تط ديكط ري يو، ي -6ا6ا2ا2- ,T,R,M,T,B,L,Rio,T-1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethyl piperidine and 36I,W,C,C,W condensate Na'N- BUU 6A6A2A2-,TOO R M T WOO -4-B L REO Y- ،تو ر م ث و ب ل ريو ت -1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethyl piperidine و 36ى ووط،ج ،كث ووو condensate Nا'N-بووو 6ا6ا2ا2-،توو ر م ث ووو -4-ب ل ريوو ى- N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylenediamine N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylenediamine وك ووووووووط م ث جوووووووو ت د ي يموووووووو ت 4-,wort-u,tw yum noor-6a2-di,goura-5a3a1-,wo riyut-4-tert-octylamino-2,6-dichloro و4-،وورت-يو،ت وو يم نوور -6ا2-د ي ،جوورةو-5ا3ا1-،وو ري ي يووت -4-tert-octylamino-2,6-dichloro 1,3,5a-triazine 25 1,3,5ا-triazine 25 ٦٣٧٤ ٦٣٧٤ -١٢١- -١٢١- 2B6A6A2A2-,T-R-M-TH-B-L-R-T-4-Y-S-O-LtkT (bis(2,2,6,6-tetramethylpiperidin-4-yl) 2ىب 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى سو لطكطت (bis(2,2,6,6-tetramethylpiperidin-4-yl sebacate 14y 1- 2-o,j-2-mth prober,yy-4-yo,t dikt ri u,j-6a6a2a2-,tur m th and b lrio t-1-(2-hydroxy- 2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethyl piperidine f-38i-t-c-th-na'N-b-6a6a2a2-,t-t-r-m-4-b-l-ri-h-ok-t-m-th-c T D Y sebacateا 14ى 1- 2-و ةو، ي -2-م ث بروبر، يى-4-يو،تط ديكط ري يو، ي -6ا6ا2ا2-،تو ر م ث و ب ل ريو ت -1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethyl piperidine و 38ى ط،ج ،كث Nا'N-ب - 6ا6ا2ا2-،ت ر م ث -4-ب ل ري ىوك ط م ث ج ت د ي -2 and 4-times Farz Nour-6A N,N'-bis-(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine 5 mm -2و4-مرةفرز نوور-6ا N,N'-bis-(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine 5 يموو ت DD,GRRO-5A3A1-,REEET 4-morpholino-2,6-dichloro-1,3,5-triazine and د ي ،جرةو-5ا3ا1-، ري ي يت 4-morpholino-2,6-dichloro-1,3,5-triazine و 2B6A6A2A2-,T-R-M-TH-B-L-R-T-4-Y-S-O-LtkT (bis(2,2,6,6-tetramethylpiperidin-4-yl) 2ىب 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى سو لطكطت (bis(2,2,6,6-tetramethylpiperidin-4-yl sebacate 14y 1- 2-o,j-2-mth prober,yy-4-yo,t dikt ri u,j-6a6a2a2-,tur m th and b lrio t-1-(2-hydroxy- 2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethyl 10 piperidine f-4-b-l-ri-w sebacateا 14ى 1- 2-و ةو، ي -2-م ث بروبر، يى-4-يو،تط ديكط ري يو، ي -6ا6ا2ا2-،تو ر م ث و ب ل ريو ت -1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethyl 10 piperidine و 39ى وط،ج ،كث و condensate Nا'N-بو - 6ا6ا2ا2ا1-بنتوط م ث و -4-ب ل ريو ى N,N'-bis-(1,2,2,6,6-pentamethyl-4-piperidyl)hexamethylenediamine wk wwt m wwwwwwwwwwwwwwwwwwwtwt N,N'-bis-(1,2,2,6,6-pentamethyl-4-piperidyl)hexamethylenediamine وك وووط م ث جووو ت د ي يمووو ت And 4-timefrase NR-6A2-DDY,GRO-5A3A1-,RIYT 4-morpholino-2,6-dichloro-1,3,5-triazinet و4-مرةفرز نر-6ا2-د ي ،جرةو-5ا3ا1-، ري ي يت 4-morpholino-2,6-dichloro-1,3,5-triazineت
- 88- Polyolefin substrate, mixed with 15 liters of water, 15 oz. 8- زلنتج وفقط زعنصر ز لطيل 1 ،شتل عج ة، ك برزي يوز فو ت polyolefin substrate مضولت بهوط 15 ييضط:Tris(2,4-di-tert-butylphenyl) ،رز فووووووول ،وووووووري 4ا2-د ي -،ووووووورت-ب ر، ووووووو ف ن ووووووو ى فرسوووووووف (tris(2,4-di-tert-butylphenyl phosphite, hindered phenolic antioxidants, hindered phenolic antioxidants Whooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooo Y and woooooooowowoooowoowoowoowoowo phosphiteقمضووطد يك وو ف نوورزي معووطق hindered phenolic antioxidant ا وو مضووطد ت ألك وو زف نرز ول زلعطمول hindered phenolic antioxidants مختوطة موت زلجلرعول زلكر ول موت ،وري 5ا3-د ي -،ووووووووووووورت-ب ر، ووووووووووووو -4-و ةو، وووووووووووووي بنكيووووووووووووو ى ي وووووووووووووكو سووووووووووووو ط رةت -4-tris(3,5-di-tert-butyl 20 hydroxybenzyl) isocyanurateا 5ا3ا1-،وووووري - 5ا3-د ي -،ووووورت-ب ر، ووووو -4-و ةو، وووووي Benzyl-2,4,6-(1,3,5-tris-(3,5-di-tert-butyl-4-hydroxybenzyl) بنكيووووووووووو ى-6ا4ا2-،وووووووووو ري م ث وووووووووو بنوووووووووووكيت -2,4,6-(1,3,5-tris-(3,5-di-tert-butyl-4-hydroxybenzyl Monoethyl ester, calcium salt, and trimethylbenzene موت الوم monoethyl ester مت مر ر ث ستر calcium salt ا مجح زكطز رtrimethylbenzene 5- D 5ا3-د ي -،ووووووووووووووووووورت-ب ر، ووووووووووووووووووو -4-و ةو، وووووووووووووووووووي بنكيووووووووووووووووووو فرسوووووووووووووووووووفر -4-3,5-di-tert-butyl hydroxybenzylphosphonic acid pentaerythritol tetrakis [3-5a3-di-di -tert-butyl-4-hydroxyphenyl hydroxybenzylphosphonic acidا بنتووط ريثريتوورس ،توو ر ،وو ]3- 5ا3-د ي -،وورت-ب ر، وو -425 و ةو، وي ف ن و ى بروب ر وطت[ (pentaerythritol tetrakis [3-(3,5-di-tert-butyl-4-hydroxyphenyl ٦٣٧٤ ٦٣٧٤ -١٢٢- -١٢٢- [propionate and you, tooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooove [propionate ويو،تووووووط دي وووووو 3- 5ا3-د ي -،وووووورت-ب ر، ووووووو -4-و ةو، ووووووي ف ن وووووو ى بروب ر ووووووطت Octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate اoctadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate N,N-di(C16-C18alkyl)hydroxylamine NاN-د ي C16-C18 يزك ىو ةو، يم ت N,N-di(C16-C18alkyl)hydroxylamineا Rice Foul, Wuori 4A2-DDY -, Wurt-BR, Wu Fn Wu Y Farsoof QN N-D Y C16-C18 Yazik Hu, Wu ،رز فووول ،وووري 4ا2-د ي -،ووورت-ب ر، ووو ف ن ووو ى فرسوووف قNاN-د ي C16-C18 يزك ىو ةو، ووو Tris(2,4-di-tert-butylphenyl) phosphite/N,N-di(C16-C18alkyl)hydroxylamine 5 mm t اtris(2,4-di-tert-butylphenyl) phosphite/N,N-di(C16-C18alkyl)hydroxylamine 5 يم ت Di(C16-C18)alkyl methyl amine oxide Yu د ي C16-C18ى يزك م ث يو، يم ت di(C16-C18)alkyl methyl amine oxide يو ,Rice Bean ,Wori 4A2-DD-Y-,WART-BR,W-F-N-W-Y-Frsoof May C16-C18 YZK W M T W YU, YUMU T ،رز فول ،ووري 4ا2-د ي -،ورت-ب ر، وو ف ن وو ى فرسووف قد ي C16-C18ى يزك وو م ث و يو، و يموو ت tris(2,4-di-tert-butylphenyl) phoshphite/di(C16-C18)alkyl methyl amine oxide تtris(2,4-di-tert-butylphenyl) phoshphite/di(C16-C18)alkyl methyl amine oxide
- 910 9- Polyolefin substrate, mixed with a drop 10 9- زلنتج وفقط زعنصر ز لطيل 1 يشتل عج ة، ك برزي يوز فو ت polyolefin substrate مضولت بهوط He controls:ييضط: Tris(2,4-di-tert-butylphenyl) ،رز فووووووول ،وووووووري 4ا2-د ي -،ووووووورت-ب ر، ووووووو ف ن ووووووو ى فرسوووووووف (tris(2,4-di-tert-butylphenyl phosphate phosphiteقبنتووووووط ريثريتوووووورس ،توووووو ر ،وووووو ]3- 5ا3-د ي -،وووووورت-ب ر، وووووو -4-و ةو، ووووووي ف ن وووووو ى Pentaerythritol tetrakis [3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate]]propionate اpentaerythritol tetrakis [3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate] ]بروب ر طت 15 Tris(2,4-di-tert-butylphenyl) 15 ،رز فووووووول ،وووووووري 4ا2-د ي -،ووووووورت-ب ر، ووووووو ف ن ووووووو ى فرسوووووووف (tris(2,4-di-tert-butylphenyl phosphate phosphiteقيو،تط دي 3- 5ا3-د ي -،رت-ب ر، -4-و ةو، ي ف ن و ى بروب ر وطت octadecyl 3,5)-3a-di-tert-butyl-4-hydroxyphenyl) propionate 3,5)-3ا-di-tert-butyl-4-hydroxyphenyl) propionate N,N-di(C16-C18alkyl)hydroxylamine NاN-د ي C16-C18 يزك ىو ةو، يم ت N,N-di(C16-C18alkyl)hydroxylamineا Tris(2,4-di-tert-butylphenyl) ،رز فووووووول ،وووووووري 4ا2-د ي -،ووووووورت-ب ر، ووووووو ف ن ووووووو ى فرسوووووووف (tris(2,4-di-tert-butylphenyl 20 Phosphite N-D C16-C18 Oooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooat with it -N,N-di(C16) 20 phosphiteقNاN-د ي C16-C18 يزك ىو ةو، وووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووو يموووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووو ت -N,N-di(C16 C18alkyl)hydroxylamine اC18alkyl)hydroxylamine Di(C16-C18)alkyl methyl amine oxide Yu د ي C16-C18ى يزك م ث يو، يم ت di(C16-C18)alkyl methyl amine oxide يو Tris(2,4-di-tert-butylphenyl) ،رز فووووووول ،وووووووري 4ا2-د ي -،ووووووورت-ب ر، ووووووو ف ن ووووووو ى فرسوووووووف (tris(2,4-di-tert-butylphenyl Phosphite may be C16-C18, YZK MTHYO, YM T di(C16-C18)alkyl methyl amine oxide 25 phosphiteقد ي C16-C18ى يزك م ث يو، يم ت di(C16-C18)alkyl methyl amine oxideت 25 ٦٣٧٤ ٦٣٧٤ -١٢٣- -١٢٣-
- 1010- Polyolefin 10- زلنووتج وفقووطر زعنصوور ز لطيوول 1ا ا وو ووت ،ضوول ت د وو ة، ووك زلوورزي يوز فوو ت polyolefin substrate substrate مطد ضطفل ضطف ل ،شتل عج :Mawtid Mot Mkhttt Mot Zaljl Raoul Zilkar Wal Moot, Rubber Watt, Taz Woor Calcium Carbonate And He, And He مووطد موو ط مختووطة مووت زلجلرعوول زلكر وول مووت ،ربر ووطت ،طز وو ر calcium carbonateا و ةو، وو magnesium hydroxide, talc, wollastonite and fly ash;5 yo م ن و ر magnesium hydroxideا ،جو talcا و سوتر ط wollastonite و زرموطد زلتأوط ر fly ash؛ 5 يو The flame retardants are broken, the flame retardants are broken, and the flame retardants are broken Woo t melamine and antimony compounds;Yo مور د ،ووأ ر زجهوو flame retardants زلختووطة مووت زلجلرعوول زلكر ول مووت موور د ،ووأ ر زهوو معطزجوول بوطزلرو brominated flame retardantsا مور د ،وأ ر زهو مط لول عجو يسوط فرسوفرة phosphorus based flame retardantsا مر،لووووطت مط لوووول عجوووو يسووووط م خموووو ت melamine ومر،لووووطت ي ت لوووورم antimony compounds؛ يو 10 M, m, m, t, melamine compound, i, c, kth, rs, polyol condensate;10 مر، م خم ت melamine compoundق ط،ج ،كث برز رس polyol condensate؛ melamine polyphosphate passes through ammonium م خمووووو ت بووووورزي فرسوووووفطت melamine polyphosphateا يمر ووووور بووووورزي فرسوووووفطت ammonium pentaerythritol-di-methylphosphonate a pentaerythritol-di-methylphosphonate polyphosphate pentaerythritol-di-methylphosphonate ا بنتوووط ريثريتوورس-د ي -م ث ووو فرسوووفر طتpolyphosphate You pass, and you eat the melamine compound. يو مر،و م خمو ت melamine compoundق وط،ج ،كث و برز ورس polyol condensate ا و زلرز ورس polyol علووطة عووت ، وورس alchol أووي يو متفوورح يو اجقووي ،وو ري و وو ةي trihydric يو ،توو ر و وو ةي 15 tetrahydric, pentahydric, hexahydric, C4-C6, C4, C6aldose, C4-C6, C4-C6ketose, and melamine compound. Melamine pyrophosphate, melamine polyphosphate, melamine polyphosphate, melamine polyphosphate, chloride, antimony trioxide, decabromodiphenyl ether, and decabromodiphenyl ether. 15 tetrahydric يو بنتووووط و وووو ةي pentahydric يو وك ووووط و وووو ةي hexahydric يو يزوووو و -C4-C6 C4 C6aldose أووي يو اجقووي يو ، توور C4-C6 C4-C6ketose وا وو مر،وو زل خموو ت melamine compound علطة عت م خمو ت فرسوفطت melamine phosphateا م خمو ت ب ورو فرسوفطت melamine pyrophosphate يو م خمو ت بورزي فرسوفطت melamine polyphosphate يو ،رز فول موت ي ت لورم ،و ري يو، و antimony trioxide مو ديكووط برومور د ي ف ن و ثور decabromodiphenyl ether يو ،وري 20 [3-bromo-2a2-b bromo-2,2-bis(bromomethyl propyl] phosphate;20 ]3-بروموووووور -2ا2-ب بروموووووور م ث وووووو ىبروب وووووو [ فرسووووووفطت -(tris[3-bromo-2,2-bis(bromomethyl propyl] phosphate؛ يو I'm curious, I'm curious. زلر،لوووطت زلضوووطد زجل كروبوووطت antimicrobial compounds زلختوووطة موووت زلجلرعووول زلكر ووول موووت يو، وو وو zinc oxideا ووط copperا مر،لووطت وووط copper compoundsا مر،لووطت فضوول -3ا 5اsupported silver ا فضول م عرمولsilver dispersions ا مشوتتطت فضولsilver compounds 3-5 supported silver silver dispersions silver compounds 25 D E M Th -,T R F O-5A3O1-H2-TH R D E E T-2-TH O-3,5-dimethyl-tetrahydro-1,3,5-2H 25 د ي م ث -،ت ر و ةو-5ا3ا1-H2-ث ر د ي ي يت-2-ث ورم -3,5-dimethyl-tetrahydro-1,3,5-2H thiodiazin-2-thione po-,wo-ri-br,wo-nr,wo bis-tributyltinoxide 5a4-di-joura-2-N- thiodiazin-2-thioneا بوو -،وو ري ب ر، وو ، نر، وو bis-tributyltinoxideا 5ا4-د ي ،جوورة-2-N- ٦٣٧٤ ٦٣٧٤ -١٢٤- -١٢٤- U,tw-4-jwkwwwtw-3-m 4,5-dichlor-2-n-octyl-4-isothiazolin-3-one O N-b t,w-bnw يو،ت وو -4-ي ووكو ث ووط وز ت-3-وم 4,5-dichlor-2-n-octyl-4-isothiazolin-3-oneا N-ب ر، وو -بنووك zinc-2-oxybisphenoxyarsine, zinc-2- pyridinthiol-1-oxide2-mthwthwur-4-soo-kjr-prop-w-ym-nor-6-αß-d-y-m-th-w-prop-wim-no-s-,woo-riyut-4-2-methylthio ي ووووكو ث ووووط وز ت N-butyl-benzisothiazolineا 10ا10’-يو، ووووي بوووو ف نر، ووووي يةسوووو تا وووو -2-ب ري ت ث ورس -1-يو، و 10,10’-oxybisphenoxyarsine, zinc-2-pyridinthiol-1-oxideا 2-م ث و ث ور-4-سوو كجر بروب وو يم نوور -6- αاß-د ي م ث وو بروب وو يم نوورى-s-،وو ري ي يووت -4-2-methylthio A 2-M Th Woo Th Wooor-4-Soooo Kjr Prop Woo cyclopropylamino-6-(α,β-dimethylpropylamino)-s-triazine 5 ا 2-م ث وووو ث وووور-4-سوووو كجر بروب ووووcyclopropylamino-6-(α,β-dimethylpropylamino)-s-triazine 5 yum nooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooo -2-methylthio-4-cyclopropylamino-6-tert butylamino-s-triazine 2-ms-s-2-methylthio-4-cyclopropylamino-6-tert butylamino-s-triazine WO YUM NOOR -6- αAß-D Y M T W PROP WOO YUM NOOR-6-,RI YET 2-methylthio-4-ethylamino-6-(α,β-dimethylpropylamino)-s-triazine 4A4A2'-,and Ri kgrw-2'-fw,widfnfthor 2,4,4'-trichloro-2'-hydroxydiphenyl ether 3- ord t-2- يم نوووووووور -6-،وووووووورت-ب ر، وووووووو يم نوووووووور -s-،وووووووو ري ي يووووووووت -2-methylthio-4-cyclopropylamino-6-tert butylamino-s-triazineا 2-م ث ووو ث وور-4- ث وو يم نووور -6- αاß-د ي م ث وو بروب ووو يم نووورى-s-،ري ي يت 2-methylthio-4-ethylamino-6-(α,β-dimethylpropylamino)-s-triazineا 4ا4ا2'-،و ري كجورةو-2'-و ةو، وي د ي ف ن و ثور 2,4,4'-trichloro-2'-hydroxydiphenyl etherا 3- ورد ت-2- 10 Prop n andoooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooo 2-propenylbutylcarbamate carbendazim carbendazim 10 بروب ن وووووووووو -ب ر، ووووووووو ،ربطمووووووووووطت 3-iodine-2-propenyl-butylcarbamateا ،رب نوووووووووو ي carbendazim Thiabendazole and Tabn and S تthiabendazole وث طبن وس
- 1111- Polyolefin 11- زلنووتج وفقووط زعنصوور ز لطيوول 1ا ا وو ووت ،ضوول ت د وو ة، ووك زلوورزي يوز فوو ت polyolefin substrate substrate مطد ضطفل ضطف ل ،شتل عج :15 Okay, I've made a lot of noises, I've made a mistake, I've made a mistake, I've made a mistake, I've made a mistake, I've lost my heart 15 زلر،لطت زلضطد زجل كروبطت زلختطة مت زلجلرعل زلكر ل موت فضول silver م عرمول عجو يرز و zeoliteا فضوووول silver م عرموووول عجووو نووووطجا عنصوووور زفضوووول elemental silverا عنصوووور زفضوووول elemental silver elemental silver ب جووو زنوووط ر يو زل كوووروا عنصووور زفضووول elemental silver مشوووت فوووي يووو Silicone oil, silver chloride, silver nitrate, silver nitrate, silver chloride سو ج كرم silicone oilا ،جرةيوو فضوول silver chlorideا توو رت فضوول silver nitrateا سووجفطت فضوول silver sulfate, silver phosphate, and silver zirconate silver sulfateا فرسوفطت فضول silver phosphateا ة،ر وطت فضول silver zirconate ويبط، و فضول silver apatite 20 تsilver apatite 20
- 1212- Polyolefin 12- زلنووتج وفقووطر زعنصوور ز لطيوول 1ا ا وو ووت ،ضوول ت د وو ة، ووك زلوورزي يوز فوو ت polyolefin :substrate :substrate Ultraviolet light absorbers, up to 0.10, 2.5, 25 times more مور د متصووطص زضوورط فوورق زلنف ووجي ultraviolet light absorbersا نلووط ا مووت 0.10 زوو 2.5 25 لل بطزر ما 0.10 g 1.9 g amine light stabilizers مثلتطت ضرط ذ ت يم ت amine light stabilizers معطملا نلط ا مت 0.10 ز 1.9 لل بطزر ما ٦٣٧٤ ٦٣٧٤ -١٢٥- -١٢٥- Anti-alkaline antioxidants 0.05 g 1.0 per ounce مضطد ت ألك antioxidantsا نلط ا مت 0.05 ز 1.0 لل بطزر ما More colorants 0.10 g 3.0 for more مر د زتجريت colorantsا نلط ا مت 0.10 ز 3.0 لل بطزر ما 100% fillers, 5%, 70%, etc مر د زل ط fillersا نلط ا مت 5 ز 70 لل بطزر ما 1 g, a sticky flame retardants, 1 gm 70 g, etc. مر د ،أ ر زجه flame retardantsا نلط ا مت 1 ز 70 لل بطزر ما و 5 Antimicrobial compounds Antimicrobial compounds 0.001 zo 5.0 5 ت طةيوط زلر،لوطت زلضوطد زجل كروبوطت antimicrobial compoundsا نلوط ا موت 0.001 زو 5.0 % for what's wrong ٪ لل بطزر ما Polyolefin substrate ،عتل زن لل زلئريل بطزر م عج يسط عج و م ة، ك زلرزي يوزف ت polyolefin substrateت
- 1313- An extruded product, extruded article, in the form of a piece of paper, a piece of paper, a piece of paper, a piece of paper, a piece of paper, and a piece of paper 13- منتج مقوذوف extruded article فوي صورة اوط ج نوط لي زلنوكس وفقوط زعنصور ز لطيول 1ا ، وططا 10 , nooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooo'''s extruded article 0.076 0.030 10 ،لأووو تا يو ، وووق ا ا ووو يكووورم زجلنوووتج زلقوووذوف extruded article سووول 0.076 سووو 0.030 Barsali g 0.1782ZZO 14.84 ct 0.31 ct2He will grow old برصلى ز 0.178 س 0.070 برصلى وو م مت 8.62 بطسوكطس 0.18 ةطو ق مو 2ى زو 14.84 بطسكطس 0.31 ةط ق م 2ى يشتل عج Wow, the polyolefin substrate is so hot, it's too hot to eat, and the polyethylene is gone WARS LAR MSHOOOOOOOOTRTH GOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOORP JT ة، وووك بوووورزي يوز فووو ت polyolefin substrate منتقووووط مووووت زلجلرعووول زتووووي ،تكووورم مووووت بووورزي ث جوووو ت polyethyleneا بوووووووووووووووورزي بووووووووووووووووروب ج ت polypropyleneا بوووووووووووووووورز لر مشووووووووووووووووترو ث جوووووووووووووووو تق بووووووووووووووووروب ج ت 15 ethylene/propylene copolymer... p Zlnf and ultraviolet light absorbers O-5-chloro-2-(3-t-butyl-2-hydroxy-5-methylphenyl)-2H 15 ethylene/propylene copolymerا جوووووو ج مووووووت بوووووورزي بوووووروب ج ت polypropylene وبوووووورزي ث جوووووو ت polyethyleneا و ج ج مت يي منهطا ة، ك زلرزي يوز ف ت polyolefin substrate مضلت بهط:يى 0.10 زو 0.95 وولل بووطزر ما نلوط ا موت مور د متصووطص زضوورط فورق زلنف وجي ultraviolet light absorbers زلختطة موت زلجلرعول زلكر ول موت 5-كجورةو-2- 3-t-ب ر، و -2-و ةو، وي -5-م ث وو ف ن وو ى-H2-بنووكو ،وو ري ي وس -5-chloro-2-(3-t-butyl-2-hydroxy-5-methylphenyl)-2H 20 benzotriazole 2- 5a3-boo-α-krm woo-2-wo-wo-wo-fe-n-wo-H2-bno-ko-wo-ri-s-3,5-2 20 benzotriazoleا 2- 5ا3-بوو -α-ك رم ووو -2-و ةو، وووي ف ن ووو ى-H2-بنوووكو ،ووو ري ي وس -3,5)-2 bis-α-cumyl-2-hydroxyphenyl)-2H-benzotriazole 6a4-d-y-f-n-w-2-4-kw-2-ww-2-ww-f-n-s-,wuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuu -4,6-diphenyl-2-(4-hexyloxy-2-hydroxyphenyl)-s triazine 6a4-bu-4a2-d y m w f n w y-2- 2-fw, w-4-u, t wu yu, wu f n wu y-s- bis-α-cumyl-2-hydroxyphenyl)-2H-benzotriazoleا 6ا4-د ي ف ن وووو -2- 4- وك وووو يو، ووووي -2-و ةو، ووووووووووي ف ن وووووووووو ى-s-،وووووووووو ري ي يووووووووووت -4,6-diphenyl-2-(4-hexyloxy-2-hydroxyphenyl)-s triazineا 6ا4-بو - 4ا2-د ي م ث و ف ن وو ى-2- 2-و ةو، وي -4-يو،ت وو يو، ووي ف ن وو ى-s- 4,6-bis-(2,4-dimethylphenyl)-2-(2-hydroxy-4-octyloxyphenyl)-s-triazine. ،ووووو ري ي يوووووت 4,6-bis-(2,4-dimethylphenyl)-2-(2-hydroxy-4-octyloxyphenyl)-s-triazineا وك ووووووط 25 DI-TERT-BUTY-4-HEXADECYL 3,5-DI-TERT-BUTYL 25 دي وووووو 5ا3-د ي -،وووووورت-ب ر، وووووو -4-و ةو، ووووووي بنووووووكو ت -4-hexadecyl 3,5-di-tert-butyl hydroxybenzoate 4a2-dj -,woort-br,woow fn,woow 5a3-ddy -,woort-br,woort-br,woof,ooooooooooooooooooooooooooooooooooow hydroxybenzoateا 4ا2-د ي -،ووووورت-ب ر، وووووو ف ن ووووو 5ا3-د ي -،ووووورت-ب ر، ووووو -4-و ةو، ووووووي ٦٣٧٤ ٦٣٧٤ -١٢٦- -١٢٦- 2,4-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate and 4-U,T,U,Y-2-OH,J,NRM 4-octyloxy-2-hydroxybenzophenone. بنوكو ت 2,4-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate و4-يو،ت و يو، وي -2-و ةو، ي بنكو ف نرم 4-octyloxy-2-hydroxybenzophenoneا B 0.15 g 1.5 per liter بى 0.15 ز 1.5 لل بطزر م مت ،رز فل ،ثل ضورط ذ ت يمو ت معوطق ثنط ول يو ثخث ول binary or Mixed material for externally obstructed amine light stabilizer مختطة مت زلجلرعل زلكر ل مت ternary hindered amine light stabilizer 5 2B6A6A2A2-,T-R-M-TH-B-L-R-T-4-Y-S-O-LtkT (bis(2,2,6,6-tetramethylpiperidin-4-yl) 5 2ىب 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى سو لطكطت (bis(2,2,6,6-tetramethylpiperidin-4-yl sebacate f 36i i,c,th and Na'N-bo 6a6a2a2-,tur t m th and -4-b l rio j-wk and t m th jo t d j sebacate و 36ى ط،ج ،كث و Nا'N-بو 6ا6ا2ا2-،تو ر م ث و -4-ب ل ريو ى-وك وط م ث جو ت د ي Yenoow n, n'-bis (2,2,6,6-tetramethyl-4-piperidyl) -Hexamethylenediadine 4-, wooowowowe-woo, and wooow wooooo nir-6 a 2-d, jaro-5 A3 A1-, Revy Y 4-tert-octylamino-2,6-dichloro-1,3,5-triazine يمووووووووو ت N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylenediamine و4-،ووووووووورت-يو،ت ووووووووو يم نر -6ا2-د ي ،جرةو-5ا3ا1-، ري ي يت 4-tert-octylamino-2,6-dichloro-1,3,5-triazineا 2B6A6A2A2-,T-R-M-TH-B-L-R-T-4-Y-S-O-LtkT (bis(2,2,6,6-tetramethylpiperidin-4-yl) 2ىب 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى سو لطكطت (bis(2,2,6,6-tetramethylpiperidin-4-yl 10 sebacate f 38i i,c,th and condensate Na'N-po - 6a6a2a2-,tur rm th f -4-b l ryu yuk t 10 sebacate و 38ى ط،ج ،كث و condensate Nا'N-بو - 6ا6ا2ا2-،تو ر م ث و -4-ب ل ريو ىوك وط -4And N,N'-bis-(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine -4و N,N'-bis-(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine م ث جوووووووووووو ت د ي يموووووووووووو ت MRFR-6A2-DY,GRO-5A3A1-,RIYT 4-morpholino-2,6-dichloro-1,3,5-triazine مرةفرز نر-6ا2-د ي ،جرةو-5ا3ا1-، ري ي يت 4-morpholino-2,6-dichloro-1,3,5-triazineا 2B6A6A2A2-,T-R-M-TH-B-L-R-T-4-Y-S-O-LtkT (bis(2,2,6,6-tetramethylpiperidin-4-yl) 2ىب 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى سو لطكطت (bis(2,2,6,6-tetramethylpiperidin-4-yl sebacate f 39i wt,j,kth wo condensate Na'N-boo - 6a6a2a2a1-pentot m ww -4-b l riou j sebacate و 39ى ووط،ج ،كث وو condensate Nا'N-بوو - 6ا6ا2ا2ا1-بنتووط م ث وو -4-ب ل ريوو ى N,N'-bis-(1,2,2,6,6-pentamethyl-4-piperidyl)hexamethylenediamine 15 kw m wt gww t d y mww t N,N'-bis-(1,2,2,6,6-pentamethyl-4-piperidyl)hexamethylenediamine 15 وك وووط م ث جووو ت د ي يمووو ت And 4-timefrz NR-6A2-DY,GRO-5A3A1-, REIT 4-morpholino-2,6-dichloro-1,3,5-triazine O2B6A6A2A2-,T R M T B L R E T-4- Yes, it's broken (bis(2,2,6,6-tetramethylpiperidin-4-yl) و4-مرةفرز نر-6ا2-د ي ،جرةو-5ا3ا1-، ري ي يت 4-morpholino-2,6-dichloro-1,3,5-triazineا 2ىب 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى سو لطكطت (bis(2,2,6,6-tetramethylpiperidin-4-yl sebacate and 45 mer, yo s gour mri t, c, ch 4 oligomeric compound condensate a4'-wk t m th c t b y m nr -6 a6 a2 a2-,t t r m th b l ri t -4,4'-hexamethylenebis(amino- 2,2,6,6-tetra sebacate و 45ى مر، يوز جورمري وط،ج ،كث و 4 oligomeric compound condensateا4'-وك وط م ث ج ت ب يم نر -6ا6ا2ا2-،ت ر م ث ب ل ري تى -4,4'-hexamethylenebis(amino-2,2,6,6-tetra 20 (methylpiperidine and 4a2-dj,gora-6-]6a6a2a2-,tur r m th and b l rio t-4- br,ym nur[-s-,wo r y yot m oo tarf wat-2,4 -dichloro-6-[(2,2,6,6-tetramethylpiperidin-4-yl)butylamino]-s triazine end-capped pooo 2-kjwooro-6a4-boo d y br,wu yum noori-s-,uuu Rey Yoot -4,6-2-chloro bis(dibutylamino)-s-triazine 20a6a6a2a2-,toooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooot-bis(2,2,6) 6-tetramethylpiperidin-4-yl) sebacate and 45% of the oligomeric acid 20 (methylpiperidine و4ا2-د ي ،جورةو-6-] 6ا6ا2ا2-،تو ر م ث و ب ل ريو ت-4- ىب ر، و يم نور[-s-،وو ري ي يووت م أوو طرف ووط -2,4-dichloro-6-[(2,2,6,6-tetramethylpiperidin-4-yl)butylamino]-s triazine end-capped بوووو 2-كجووورةو-6ا4-بووو د ي ب ر، ووو يم نووورى-s-،ووو ري ي يوووت -4,6-2-chloro bis(dibutylamino)-s-triazineا 20ى 6ا6ا2ا2-،توووووو ر م ث وووووو ب ل ريوووووو ت-4- وووووو يو،تووووووط ديكووووووط ر ت bis(2,2,6,6-tetramethylpiperidin-4-yl) sebacate و 45ى ووط،ج ،كث وو يوز جوورمري oligomeric 25 Compound condensate mt 4a4'-wkt mth c tb ym nr -6a6a2a2-,t r m th b l ri t -'4,4 (hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine and 4a2-di) Goooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooo - 6-] 6a6a2a2- 25 compound condensate مت 4ا4'-وك ط م ث ج ت ب يم نر -6ا6ا2ا2-،ت ر م ث ب ل ري تى -'4,4 (hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine و4ا2-د ي ،جووووووورةو-6-] 6ا6ا2ا2- ٦٣٧٤ ٦٣٧٤ -١٢٧- -١٢٧- ,tr m th b l ri t-4- y br,em nr[-s-,ri yt m a tip t-2,4-dichloro-6-[(2,2,6,6-tetra) ،تر م ث ب ل ري ت-4- ىب ر، يم نر[-s-، ري ي يت م أ طرف ط -2,4-dichloro-6-[(2,2,6,6-tetra methylpiperidin-4-yl)butylamino]-s-triazine end-capped bu-2-cgw-6a4-bu-d-y-b-r,w-ym-n-s-,ri-yt 2-chloro-4,6-bis(dibutylamino) -s-triazine methylpiperidin-4-yl)butylamino]-s-triazine end-capped بووو 2-كجوورةو-6ا4-بوو د ي ب ر، وو يم نرى-s-، ري ي يت 2-chloro-4,6-bis(dibutylamino)-s-triazineا 2B6A6A2A2-,T R M T B L R T-4-Y S Latkt 2,2,6,6-tetramethylpiperidin-4-yl 2ىب 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى س لطكطت 2,2,6,6-tetramethylpiperidin-4-yl 5 octadecanoate and 20 to 6a6a2a2-, toooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooot-4-2,2,6,6 5 octadecanoate و 20ى 6ا6ا2ا2-،توووووووووو ر م ث وووووووووو ب ل ريوووووووووو ت-4- وووووووووو يو،تووووووووووط ديكووووووووووط ر ت -2,2,6,6 Tetramethylpiperidin-4-yl octadecanoate اtetramethylpiperidin-4-yl octadecanoate 2B6A6A2A2-,T-R-M-TH-B-L-R-T-4-Y-S-O-LtkT (bis(2,2,6,6-tetramethylpiperidin-4-yl) 2ىب 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى سو لطكطت (bis(2,2,6,6-tetramethylpiperidin-4-yl sebacate 14y 1- 2-o,j-2-mth prober,yy-4-yo,t dikt ri u,j-6a6a2a2-,tr m th b lri t -1-(2-hydroxy-2- methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetra sebacateا 14ى 1- 2-و ةو، ي -2-م ث بروبر، يى-4-يو،تط ديكط ري يو، ي -6ا6ا2ا2-،تر م ث ب ل ري ت -1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetra 10 methylpiperidine and 45 te, c, kth yuz gourmet oligomeric compound condensate mot 4a4'-ok wooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooow -4,4'-hexamethylenebis(amino 2, 2,6,6-tetramethylpiperidine) and 4a2-dj, goooooooor-6-] 6a6a2a2-, tooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooo End-4-2,4-dichloro-6-[(2,2,6,6-tetramethylpiperidin yl)butylamino]-s-triazine end-capped po-2-cgr-6a4-po-d-y-p-r-ym nuri-s-, and ri-yut 10 methylpiperidine و 45ى ط،ج ،كث يوز جورمري oligomeric compound condensate موت 4ا4'-وك ووووووط م ث جوووووو ت ب يم نوووووور -6ا6ا2ا2-،توووووو ر م ث وووووو ب ل ريوووووو تى -4,4'-hexamethylenebis(amino 2,2,6,6-tetramethylpiperidine) و4ا2-د ي ،جووووووورةو-6-] 6ا6ا2ا2-،تووووووو ر م ث ووووووو ب ل ريووووووو ت-4-ىب ر، وو يم نووور[-s-،وو ري ي يوووت م أووو طرف وووط -4-2,4-dichloro-6-[(2,2,6,6-tetramethylpiperidin yl)butylamino]-s-triazine end-capped بوو 2-كجورةو-6ا4-بو د ي ب ر، و يم نورى-s-،و ري ي يوت 15 2-chloro-4,6-bis(dibutylamino)-s-triazine 14H 1- 2-OH,WH-2-MTH,WH-Proper,WH-4-U,Twt Dict RUU,WH-6A2A2-,TW t-4-(1-(2-hydroxy-2-methylpropoxy octadecanoyloxy-2,2,6,6-tetramethylpiperidine 20-6a6a2a2-), t-4-(1-(2-hydroxy-2-methylpropoxy octadecanoyloxy-2,2,6,6-tetramethylpiperidine) U,Tot Dicot Rt 2,2,6,6-tetramethylpiperidin-4-yl octadecanoate and 45i T,C,Kth and Yuz Gurmari oligomeric compound condensate Mot 4A4'-KT MTH Jo T B YM Nur -6A6A2A2-, Tu r m w 15 2-chloro-4,6-bis(dibutylamino)-s-triazineا 14ى 1- 2-و ةو، ووووي -2-م ث وووو بروبر، ووووويى-4-يو،تووط ديكط ريوو يو، ووي -6ا6ا2ا2-،توو ر م ث وو ب ل ريوو ت -4-(1-(2-hydroxy-2-methylpropoxy octadecanoyloxy-2,2,6,6-tetramethylpiperidineا 20ى 6ا6ا2ا2-،تووو ر م ث ووو ب ل ريووو ت-4- ووو يو،توط ديكوط ر ت 2,2,6,6-tetramethylpiperidin-4-yl octadecanoate و 45ى وط،ج ،كث و يوز جورمري oligomeric compound condensate موت 4ا4'-وك وط م ث جو ت ب يم نور -6ا6ا2ا2-،تو ر م ث و 20 B L R E O T (4,4'-hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine and 4A2-DDY,GOOOOOORO-6-]6A6A2A2-,T R M T B L R T-4- B R, y m nr[-s-, ri yt m a taraf and t-2,4-dichloro 20 ب ل ريوووووو تى (4,4'-hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine و4ا2-د ي ،جووووووورةو-6-] 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ىب ر، يم نر[-s-، ري ي يت م أ طرف وط -2,4-dichloro -42,2,6,6)]-6 بوو 2-كجورةو-6ا-tetramethylpiperidin-4-yl)butylamino]-s-triazine end-capped -42,2,6,6)]-6-Bu-2-Cg-6a-tetramethylpiperidin-4-yl)butylamino]-s-triazine end-capped B D E B R, YM NRE-S-, R E Y T 2-chloro-4,6-bis(dibutylamino)-S-triazine ب د ي ب ر، يم نرى-s-، ري ي يت 2-chloro-4,6-bis(dibutylamino)-s-triazineا 2B6A6A2A2-,T-R-M-TH-B-L-R-T-4-Y-S-O-LtkT (bis(2,2,6,6-tetramethylpiperidin-4-yl) 2ىب 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى سو لطكطت (bis(2,2,6,6-tetramethylpiperidin-4-yl 25 sebacate 14y 1- 2-o,j-2-mth prober,yy-4-yo,t dikt ri u,j-6a6a2a2-,tr m th b lri t -1-(2-hydroxy-2- methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetra 25 sebacateا 14ى 1- 2-و ةو، ي -2-م ث بروبر، يى-4-يو،تط ديكط ري يو، ي -6ا6ا2ا2-،تر م ث ب ل ري ت -1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetra ٦٣٧٤ ٦٣٧٤ -١٢٨- -١٢٨- methylpiperidine and 36 y oooot, c, kth woooo condensate Na'N-booooo 6a6a2a2-,tooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooo -4- methylpiperidine و 36ى وووووط،ج ،كث ووووو condensate Nا'N-بووووو 6ا6ا2ا2-،تووووو ر م ث ووووو -4- -(N,N'-bis(2,2,6,6-tetramethyl-) 4-piperidyl hexamethylenediamine and 4-,wort-you,twu-yum-noor - 6a2-d-y, juwo-war-5a3-1-, wow ri yoot -4-tert ب ل ريوووووووووووووووووووووو ى-وك ووووووووووووووووووووووط م ث جوووووووووووووووووووووو ت د ي يموووووووووووووووووووووو ت -(N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl hexamethylenediamine و4-،ووورت-يو،ت ووو يم نووور -6ا2-د ي ،جووورةو-5ا3ا1-،ووو ري ي يوووت -4-tert Octylamino-2,6-dichloro-1,3,5-triazine اoctylamino-2,6-dichloro-1,3,5-triazine 5 2B6A6A2A2-,T-R-M-TH-B-L-R-T-4-Y-S-O-LtkT (bis(2,2,6,6-tetramethylpiperidin-4-yl) 5 2ىب 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى سو لطكطت (bis(2,2,6,6-tetramethylpiperidin-4-yl sebacate 14y 1- 2-o,j-2-mth prober,yy-4-yo,t dikt ri u,j-6a6a2a2-,tur m th and b lrio t-1-(2-hydroxy- 2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethyl piperidine and 38y watt,c,th and condensate Na'N-boo-6a6a2a2-,to rm th and woo-4-b l rio y sebacateا 14ى 1- 2-و ةو، ي -2-م ث بروبر، يى-4-يو،تط ديكط ري يو، ي -6ا6ا2ا2-،تو ر م ث و ب ل ريو ت -1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethyl piperidine و 38ى ووط،ج ،كث ووو condensate Nا'N-بووو - 6ا6ا2ا2-،توو ر م ث ووو -4-ب ل ريوو ى N,N'-bis-(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine N,N'-bis-(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine وك ووووووووط م ث جوووووووو ت د ي يموووووووو ت 10 And 4-timefarz nor-6a2-dj, gura-5a3a1-, and riyut 4-morpholino-2,6-dichloro-1,3,5-triazine and 10 و4-مرةفرز نور-6ا2-د ي ،جورةو-5ا3ا1-،و ري ي يوت 4-morpholino-2,6-dichloro-1,3,5-triazineا و 2B6A6A2A2-,T-R-M-TH-B-L-R-T-4-Y-S-O-LtkT (bis(2,2,6,6-tetramethylpiperidin-4-yl) 2ىب 6ا6ا2ا2-،ت ر م ث ب ل ري ت-4- ى سو لطكطت (bis(2,2,6,6-tetramethylpiperidin-4-yl sebacate 14y 1- 2-o,j-2-mth prober,yy-4-yo,t dikt ri u,j-6a6a2a2-,tur m th and b lrio t-1-(2-hydroxy- 2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethyl sebacateا 14ى 1- 2-و ةو، ي -2-م ث بروبر، يى-4-يو،تط ديكط ري يو، ي -6ا6ا2ا2-،تو ر م ث و ب ل ريو ت -1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethyl 15 piperidine f 39i t,c,th condensate Na'N-po-6a6a2a2a1-pento-m-th-4-b-l-ri-j 15 piperidine و 39ى وط،ج ،كث و condensate Nا'N-بو - 6ا6ا2ا2ا1-بنتوط م ث و -4-ب ل ريو ى N,N'-bis-(1,2,2,6,6-pentamethyl-4-piperidyl)hexamethylenediamine wk wwt m wwwwwwwwwwwwwwwwwwwtwt N,N'-bis-(1,2,2,6,6-pentamethyl-4-piperidyl)hexamethylenediamine وك وووط م ث جووو ت د ي يمووو ت And 4-times FR-6A2-DDY, GROW-5A3A1-, REIT 4-morpholino-2,6-dichloro-1,3,5-triazine AG 0.10 ZOOOO 0.75 WOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOZ MOOOOOOOOOOOOOOOOOOOOOOOOOOOO rice, soooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooot rice 4a2- dj -,wort-br,wo fn,woow y fersoof tris(2,4-di-tert-butylphenyl) phosphite,contretris,tor,f]3- 5a3-dj -,wort-br,w - و4-مرةفرز نر-6ا2-د ي ،جرةو-5ا3ا1-، ري ي يت 4-morpholino-2,6-dichloro-1,3,5-triazineا جى 0.10 زوووو 0.75 وووولل بووووطزر م مووووت ،رز فوووول ،ووووري 4ا2-د ي -،وووورت-ب ر، وووو ف ن وووو ى فرسووووف tris(2,4-di-tert-butylphenyl) phosphiteقبنتط ريثريترس ،تو ر ،و ]3- 5ا3-د ي -،ورت-ب ر، و - 20 4-Pentaerythritol tetrakis [3-(3,5-di-tert-butyl) 20 4-و ةو، ووووووووي ف ن وووووووو ى بروب ر ووووووووطت[ -4-pentaerythritol tetrakis [3-(3,5-di-tert-butyl hydroxyphenyl) propionate]A,RZ FL,RI 4A2-DY -,WORT-BR,WF N WY FRSOUF QU,TD W3-5A3-DY -,WORT-BR,WO-4-W (tris(2,4-di-tert-butylphenyl) hydroxyphenyl) propionate]ا ،رز فل ،ري 4ا2-د ي -،ورت-ب ر، و ف ن و ى فرسوف قيو،تط دي و 3- 5ا3-د ي -،ووورت-ب ر، ووو -4-و ةو، وووي ف ن ووو ى بروب ر وووطت (tris(2,4-di-tert-butylphenyl C16- د ي-NاN اphosphite/octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate C16-D-Naphosphite/octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate C18 is deceased and dies C18 يزك ىو ةو، و يمو ت N,N-di(C16-C18alkyl)hydroxylamineا ،رز فوول ،وري 4ا2-د ي - 25 Tris(2,4-di-tert-butylphenyl) phosphite C16-C18 25 ،وووورت-ب ر، وووو ف ن وووو ى فرسووووف tris(2,4-di-tert-butylphenyl) phosphiteقNاN-د ي C16-C18 N,N-di(C16-C18alkyl)hydroxylamine is C16-C18. يزك ىو ةو، ووووو يموووو ت N,N-di(C16-C18alkyl)hydroxylamineا د ي C16-C18ى يزك ووووو م ث ووووو ٦٣٧٤ ٦٣٧٤ -١٢٩- -١٢٩- U, and di(C16-C18)alkyl methyl amine oxide, u, rice bean, ri 4a2-di-tert-butylphenyl, fn, wu, and tris(2,4-di-tert-butylphenyl) phosphate يو، و يمو ت di(C16-C18)alkyl methyl amine oxide يو ،رز فول ،وري 4ا2-د ي -،ورت-ب ر، و ف ن ووو ى فرسوووف tris(2,4-di-tert-butylphenyl) phosphiteقد ي C16-C18ى يزك ووو م ث ووو يو، ووو Di(C16-C18)alkyl methyl amine oxide اdi(C16-C18)alkyl methyl amine oxide يم ت D 0.1 g 3.0 دى 0.1 ز 3.0 لل بطزر ما نلط ا مت مر د زتجريت زلختطة مت زلجلرعل زلكر ل موت صولطعطت Organic and inorganic pigments 5 organs and inorganic pigments اorganic and inorganic pigments 5 عضريل وع ر عضريل It is 15 and 40, but we can't get enough of it. هى 15 زوو 40 وولل بووطزر ما نلووط ا مووت موور د زلوو ط fillers زلختووطة مووت زلجلرعوول زلكر وول مووت Carbonate, calcium carbonate, magnesium hydroxide, talc, wollastonite, and fly ash. كربر وطت ،طز وو ر calcium carbonateا و ةو، و م ن و ر magnesium hydroxideا ،جوو talcا و ستر ط wollastonite و زرمطد زلتأط ر fly ashا We 1 g 40 for the last time we went to death again, a r zgho flame retardants zalkhtouta death zjalarul وى 1 ز 40 لل بطزر ما نلط ا مت مر د ،أ ر زجهو flame retardants زلختوطة موت زلجلرعول 10 melamine polyphosphate ammonium polyphosphate 10 زلكر ل مت م خم ت برزي فرسفطت melamine polyphosphateا يمر ر بورزي فرسوفطت ammonium pentaerythritol-di-methylphosphonate a pentaerythritol-di-methylphosphonate polyphosphate اpentaerythritol-di-methylphosphonate ا بنتوط ريثريتورس-د ي -م ث وو فرسوفر طتpolyphosphate Marwa مرو BM, melamine compound, PP, PP, PP, polyol condensates, rice, bean, etc., and wormwood, and antimony trioxide, and the decabromodiphenyl ether. ب م خمو ت melamine compoundق وط،ج ،كث و برز وورس polyol condensates و،رز فول موت ي ت لوورم ،وو ري يو، وو antimony trioxide موو ديكووط بروموور د ي ف ن وو ثوور decabromodiphenyl ether يو 15 RI]3-bromer-2a2-bbromer mthiprop[phosphate-(tris[3-bromo-2,2-bis(bromomethyl) 15 ،ري ]3-برومر -2ا2-ب برومر م ث ىبروب [ فرسفطت -(tris[3-bromo-2,2-bis(bromomethyl And propyl]phosphate و ت طةيط propyl] phosphate Yes, 0.02, 2.0. ى 0.02 زوووو 2.0 وووولل بووووطزر ما نلووووط ا مووووت زلر،لووووطت زلضووووطد زجل كروبووووطت antimicrobial compounds زلختوطة موت زلجلرعول زلكر ول موت يو، و و zinc oxideا وط copperا مر،لوطت I was very interested in copper compounds, silver compounds, and I was very curious about silver dispersions ط copper compoundsا مر،لطت فضل silver compoundsا مشتتطت فضول silver dispersionsا 20 3,5-dimethyl-tetrahydro-1,3,5-2H 3- N-butyl-benzisothiazoline 10-10'-U YSO T 10,10'-oxybisphenoxyarsine O W-2-B REO T Th wrs-1 20 فضول م عرمول supported silverا 5ا3-د ي م ث و -،توو ر و وو ةو-5ا3ا1-H2-ث وور د ي ي يووت-2-ث وورم 3,5-dimethyl-tetrahydro-1,3,5-2H-thiodiazin-2-thioneا بوو -،وو ري ب ر، وو ، نر، وو -bis tributyltinoxideا 5ا4-د ي ،جوووووورة-2-N-ي و،ت وووووو -4-ي ووووووكو ث ووووووط وز ت-3-وم -4,5-dichlor-2-n octyl-4-isothiazolin-3-oneا N-ب ر، ووووووووووو -بنوووووووووووك ي وووووووووووكو ث وووووووووووط وز ت N-butyl-benzisothiazolineا 10ا10’-يو، وي ب ف نر، ووي يةسوو ت 10,10’-oxybisphenoxyarsineا وو -2-ب ريوو ت ث وورس -1 25 U, zinc-2-pyridinthiol-1-oxide 2-MTHTHR-4-S KgrPropWYMNur-6-αAß-DYMTHWProPWYMNor-s-,WRIYUT -( 2-methylthio-4-cyclopropylamino-6-(α,β-dimethylpropylamino) 25 يو، zinc-2-pyridinthiol-1-oxideا 2-م ث ث ر-4-س كجر بروب و يم نور -6- αاß-د ي م ث و بروب و يم نورى-s-،و ري ي يوت -(2-methylthio-4-cyclopropylamino-6-(α,β-dimethylpropylamino ٦٣٧٤ ٦٣٧٤ -١٣٠- -١٣٠- -2 s-triazineا 2-م ث وووو ث وووور-4-سوووو كجر بروب وووو يم نوووور -6-،وووورت-ب ر، وووو يم نوووور -s-،وووو ري ي يووووت -2 A2-MTHWWWWW-4-THWYM Noormethylthio-4-cyclopropylamino-6-tert-butylamino-s-triazine ا 2-م ث ووو ث ووور-4- ث ووو يم نووورmethylthio-4-cyclopropylamino-6-tert-butylamino-s-triazine -6- αß-D Y M Th Woooooo Prop Woooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooo -2-methylthio-4-ethylamino-6-(α,β dimethylpropylamino)-s-triazine 4a4a2'-,wooo ri, Goooooor-2'-ooooooooooooooooooooooooooooooooooooooooooooooooooooooooooooow-'2,4,4 -6- αاß-د ي م ث وووووووووو بروب وووووووووو يم نوووووووووورى-s-،وووووووووو ري ي يووووووووووت -2-methylthio-4-ethylamino-6-(α,β dimethylpropylamino)-s-triazineا 4ا4ا2'-،ووو ري ،جووورةو-2'-و ةو، وووي د ي ف ن ووو ثووور -'2,4,4 5 trichloro-2'-hydroxydiphenyl ether 3- and t-2-prop n and oo-b t-2-3-iodine 5 trichloro-2'-hydroxydiphenyl etherا 3- ووووورد ت-2-بروب ن ووووو -ب ر، ووووو ،ربطموووووطت -2-3-iodine Propenyl-butylcarbamate, carbendazim, thiabendazole, etc. propenyl-butylcarbamateا ،رب ن ي carbendazim وث طبن وس thiabendazoleا ا ،ل ت زتر، لل Moore, hit with a force of 3.95 pounds, 35 meters long, with a straight and narrow fold, made for the American Wall of Talouta. موور ،صووطد بلقوو ة 3.95 وور،تتمتر 35 برصوول-ةطوو ى مقطسوول وفقووط زوووججلع ل ألمريك وول تلووطة 4226AD American Society for Testing and Materials Zler D 4226اD American Society for Testing and Materials زلر د 10 Wait, if you want to see a lot of linear thermal expansion, please, 8.1 × 10-05. 10 معطمو ،لو د او رةي أوي linear thermal expansion بلقوو ة 8.1 × 10-05 سوو ق سو ق دةنول Ariel 4.5 05-10 مئريل 4.5 05-10 x برصلقبرصلقم ى مقطسل وفقط زوججلع ل ألمريك ول تلوطة زلور د American 696 Society for Testing and Materials 696 و ت طةيطD Society for Testing and Materials , Jut Zurm is inverted, and it is not American. ،جوط زورم مقلورس فوي ألنو كط زجط ل ول زلشوألل وفقوط زووججلع ل ألمريك ول تلوطة زلور د American 6864 Society for Testing and Materials 6864 وقيوD Society for Testing and Materials 15 The price of the delta 15 زووورم دزتوووط delta E مووونخفم مقلووورس زخسوووتخ زلأجووورب وفقوووط زووووججلع ل ألمريك ووول تلوووطة زلووور د 2244 and restrictionsD American Society for Testing and Materials 2244 وقيوD American Society for Testing and Materials Sun 1-UL-94 V and 0-V, and the size of the activity indicator is a 200-pin cable, only a pair, made for America and only. ،صن 1-UL-94 V يو 0-V وقيو مؤشر تشطة زه بلق ة 200 مقطسل وفقط زوججلع ل ألمريك ول 84T-E American Society for Testing and Materials Talta Zler Dr 84ت-E American Society for Testing and Materials تلطة زلر د
- 1420 14- Polyolefin substrate 20 14- زلنتج وفقط زعنصر ز لطيل 1ا ا ،شتل ة، ك زلرزي يوز ف ت polyolefin substrate ييضط Neryl nucleating agent, Neryl nucleating agent, Fillers, Zinneryl nucleating agent, Sodium benzoate 2A 2'- MTH G T - B 4 A 6 - D D - , Rt عج عطم ،نريل nucleating agent يو مطد م ط fillersا ا يشتل عطم زتنريل nucleating agentعج صرد ر بنكو ت sodium benzoateا 2ا 2’- م ث ج ت - ب 4ا 6- د ي-، رت BR, FNI, PHOSPHATE 2,2'-methylene-bis(4,6-di-tert-butylphenyl)phosphate A NG RO T zinc glycerolate A MJH, TZ R Calcium salt m 1 A 2- D E, R, KT S kajar and k tam ب ر، ف ن ى فرسفطت 2,2’-methylene-bis(4,6-di-tert-butylphenyl)phosphate ا نج رو ت zinc glycerolateا مجح ،طز ر calcium salt مت الم 1ا 2- د ي ،ربر، خت س كجر وك طم 25 1,2-dicarboxylic acid cyclohexane 25 1,2-dicarboxylic acid cyclohexaneا مر،لطت ،ري طم trisamide compoundsا مجح الم س - و- بطي س كجر- ]2.2.2[-ولتطم -2ا 3- د ي ،ربر، خت د ي صرد ر -cis-endo ٦٣٧٤ ٦٣٧٤ -١٣١- -١٣١- bicyclo-[2.2.1]-heptane-2,3-dicarboxylic acid disodium salt aluminum hydroxy-bis[4-(tert) -butyl)benzoate 1a 3:2a 4- b -3a 4- d y m t h bankig t sirp gear 1a 3:2a 4- b 4- m t h bankig t sirp gear,[ bicyclo-[2.2.1]-heptane-2,3-dicarboxylic acid disodium saltا يزرم ن ر و ةو، ي -ب ]4-، رت- ب ر، ى بنكو ت[ [aluminum hydroxy-bis[4-(tert-butyl)benzoateا 1ا 3:2ا 4- ب -3ا 4- د ي م ث بنكيج تى سرةب ترس 1ا 3:2ا 4- ب 4- م ث بنكيج تى سرةب ترس ,[ 1,3:2,4a U-bis-(3,4-dimethylbenzylidene)sorbitol 1,3:2,4-bis(4-methylbenzylidene)sorbitol 1,3:2,4ا يو-bis-(3,4-dimethylbenzylidene)sorbitol 1,3:2,4-bis(4-methylbenzylidene)sorbitol 5 1A 3:2A 4- B 3A 4- D E M Th Bankage T Serb Gear -3,4)1,3:2,4-bis 5 1ا 3:2ا 4- ب 3ا 4- د ي م ث بنكيج تى سرةب ترس -3,4)1,3:2,4-bis dimethylbenzylidene)sorbitol ا وبطزت مر، ،ري طم عأري aromatic trisamide dimethylbenzylidene)sorbitol, bitter, aromatic trisamide compound تcompound ٦٣٧٤ ٦٣٧٤
Independent claims14
1,653 paragraphs in 29 sections, as filed
Full description
Background of the invention
Completely formulated polyolefin compositions useful for long-term outdoor applications are disclosed. Fittings are useful for building materials such as house siding panels, house base, panels, roofing and the like. Specifically, fixtures such as wall panels are useful.
5 Currently, PVC (polyvinyl chloride) wall panels are usually used. PVC walls have disadvantages in terms of their environmental impact and overall performance. PVC walls are not widely used in regions with high temperatures. PVC walls exposed to high levels of sun will show excessive sun fading in a short period of time, i.e. 5 to 7 years. Also, PVC is not completely recyclable and many manufacturing controls must be implemented to limit exposure due to the hazardous vinyl chloride monomer.
It would be beneficial to replace existing PVC with polyolefin siding, as polyolefin siding meets or exceeds the required levels of lightfastness, curing stability, flame retardation and mechanical properties.
For polyolefin walls, the current state of the art is injection molding of thick sections. Injection molded thick section polyolefin walls have a thick cross section due to melt strength not suitable for currently available olefin polymer compositions. Injection molding processing can lead to defects such as flow lines, injection gate defects, and “striping” during outdoor weather. Currently, the industry is seeking extrudable olefin polymer formulations capable of replacing existing PVC with suitable processability, reliability, aesthetics and light weight.
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Conventional injection molded siding panels typically have a thickness range of 0.3175-0.254 cm (0.10 to 0.125 in), with width values ranging from 25.4-50.8 cm (10 to 20 in) and length values from 76.2-162.4 cm (30 to 60 inches), depending on specific designs.
5 The dimensions of the extruded wall format can vary from about 30 to about 50 mils, preferably from about 35 to about 45 mils. Current installations allow the extrusion of today's industry standard wall lengths provided into any linear lengths as produced by the siding conversion operation. Ideal side width values would be a minimum of 10.16 cm (4 in) to a maximum of 45.72 cm (18 in) as is common in existing 10 industries.
International Patent 2013026864A1 relates to a new polyolefin composition comprising a heterophasic propylene copolymer (HECO heterophasic propylene copolymer), high density polyethylene HDPE (second PE2 polyethylene) having a density of less than 940 kg/m<sup>3</sup>And an inorganic filler
15 (F). International patent 2013026864A1 also relates to a product containing a polycarbonate composition.
The aforementioned olefin, and a process for preparing the polyolefin composition and its uses. Polypropylene is the material of choice in many applications as it can be tailored for specific purposes.
US Patent 5214084 relates to a stabilized polypropylene resin composition containing an α-olefinic copolymer rubber and an inorganic filler, namely
20 Moreover, its polypropylene resin composition has excellent stability not only against heat and oxidation but also against light.
US Patent 5,203,941 is described in connection with its use in the construction industry to produce flexible, climate-resistant siding panels made of vinyl (polyvinyl chloride). The following description of vinyl siding panels is Example 25 of one use of the invention for the production of roofs. Embossed cosmetics that withstand the outdoor climate on flexible extruded laminates.
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US Patent 20010006990 is filed for a polyolefin-based composite resin composition having a low linear coefficient of thermal expansion that not only possesses excellent mechanical strength, impact resistance, heat resistance, and product flatness, but also exhibits dimensional stability due to its low shrinkage, coefficient of expansion Low linear thermal, low thermal sintering.
5 This invention relates to a polyolefin-based composition having physical and mechanical properties, such as high effective melting strength, for use in extruded structures (e.g., sides, window profiles, floors, fences, etc.). Extruded compositions according to this invention Extruded siding compositions are offered accordingly
10 The invention provides an easier installation process as opposed to the current state of the art PVC.
General description of the inventor
The present invention describes a polyolefin composition that allows a useful profile to be extruded into siding, floors, fences and window profiles.
Hence, a polyolefin composition including an incorporated polyolefin substrate is disclosed
15 It contains one or more additives selected from the group consisting of
a) One or more ultraviolet light absorbers,
b) One or more obstructed amine light stabilizers
c) one or more antioxidants,
Where the composition is shown
20 Impact force of < 35 in.-lbs measured according to ASTM D4226,
A linear thermal expansion coefficient of > 4.5<sup>05-</sup>10 x inches/inch/feet
Measured according to ASTM D696 and optionally
Acceptable color uniformity of finished sides in accordance with ASTM D6864 and/or
Low delta E color is acceptable for the application required in accordance with ASTM D2244 and/or
25 94-UL rating of 1-V or 0-V and/or flame spread index of >
200 Measured according to ASTM E-48.
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Advantageously, one or more colorants are also incorporated into the polyolefin substrate.
Optionally, one or more additives selected from the group consisting of...
5 e) one or more fillers,
(f) One or more flame retardants
g) One or more antimicrobial compounds.
The polyolefin substrate is preferably homopolymers of polyethylene, copolymers of random or block polyethylene,
<p dir="rtl">10 Homogeneous polypropylene (PP), random or lumpy polypropylene copolymers, ethylene/propylene copolymers, mixtures of polypropylene and polyethylene or mixtures of different types of polyethylene. More preferably The polyolefin substrate is polypropylene, preferably polyethylene, with linear low density (LDPE).</p>
<p dir="rtl">15 Medium density MDPE or high density HDPE. The above mixtures are an example of polypropylene/high density polyethylene, polypropylene/low density polyethylene, and high density polyethylene/low density polyethylene. Tertiary mixtures such as polypropylene/high-density polyethylene/low-density polyethylene have also been included. Polyolefin substrates can be formulated with or without cross-linking.</p>
<p dir="rtl">20 Polyolefin composition contains Example ≤ 10 wt % (wt %) polyolefin, Example ≤ 15 wt %, ≤ 20 wt %, ≤ 25 wt %, ≤ 30 wt %, ≤ 35 wt %, ≤ 40 wt % , ≤ 45 wt%, ≤ 50 wt%, ≤ 55 wt%, ≤ 60 wt%, ≤ 65 wt%, ≤ 70 wt%, ≤ 75 wt%, ≤ 80 wt% or ≤ 85 wt% polyolefin, depending on Weight of the composition.</p>
25 Polypropylene can be a homopolymer of polypropylene homopolymer, polypropylene random copolymer,
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An exchanged or cross-linked copolymer or block copolymer containing one or more comonomers selected from the group consisting of ethylene, α-C30-C4-olefins, vinylcyclohexane, vinylcyclohexene, C20-C4 alkandiene compounds, C4-C20alkandienes,
5 C5-C12cycloalkandienes and norbornene derivatives; The total molarity of propylene and its comonomer is 100%.
Polypropylene copolymer also converts long chain branched polypropylene copolymer.
10 Examples of C30α-C4-olefins include C4-C30-olefins-butene-1,1-butene-1,1-hexene-1,1-hexene-1,1-heptene-1,1-octene-1. nonene-1 1, nonene-decene 1, 1-decene-undecene 1, 1-undecene-dodecene 1, 1-dodecene-tetradecene 1, 1-tetradecene-hexadecene 1, 1-hexadecene-octadecene-1, 1-octadecene 1,4-eicosene-methyl-1-pentene 1,-methyl-1-pentene4-eicosene,1-docosene
15 1,1-docosene-tetracosene 1,1-tetracosene-hexacosene 1,1-hexacosene-octa
1-octacosene and 1-triacontene.
Examples of suitable C4-C20alkandienes include hexadiene and octadiene.
Examples of suitable C5-C12cycloalkandienes include cyclopentadiene, cyclohexadiene, and cyclooctadiene.
.cyclooctadiene
Examples of suitable norbornene derivatives include 5-ethylidene-2-norbornene (ENB), dicyclopentadiene (DCP), and methylene-domethylene.
(MEN) hexahydronaphthaline 25
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An example propylene/ethylene copolymer contains 50 to 99.9%, preferably 80 to 99.9%, specifically 90 to 99.9%, by weight of propylene.
A propylene copolymer where the comonomer is a C20α-C9-olefin such as, for example, 1-nonene, 1-nonene-decene, 1-undecene, 1-dodecene, 1-TTR-decene, 1-hexadecene, 1-octa
5 Decene or 1-eicosine; C20-C9alkandiene C9-C20alkandiene, C9-C9alkandiene Cycloalkandiene C9-C12cycloalkandiene or norbornene derivative such as eg 5-ethylidene-2-norbornene or methylene-dimethylene-hexahydronaphthalene preferably containing more than 90 pmol% , specifically 90 to 99.9% mole, or 90 to 99% mole, of propylene.
A propylene copolymer where the comonomer is C8-C4 α-olefin and C4-C8-olefin.
10 Such as 1-butene, 1-pentene, 1-hexene, 1-heptene, 1-octene or 4-methyl-1-pentene; Vinylcyclohexane, vinylcyclohexene, C8-C4, vinylcyclohexene or C8-C5 cycloalkandiene C5-C8cycloalkandiene preferably containing more than 80% pmol, specifically 80 to 99.9% pmol or 80 to 99% pmol, of propylene .
Examples of a polypropylene copolymer also include propylene/isobutylene.
15 copolymer, propylene/butadiene copolymer, propylene/cycloolefin copolymer, terpolymers of propylene with ethylene and diene such as hexadiene, dicyclopentadiene or ethylene- ethylidene-norbornene; Propylene/1-olefin copolymers where 1-olefin is generated in
20 the site; Polymer art propylene/carbon monoxide combined propylene/carbon monoxide
.copolymers
Oligomers with allyl or vinyl terminated ends of ethylene or propylene can be used as branches in polymerization reactions with propylene to prepare branched polypropylenes with high breaking strength, as disclosed in the patent.
25 US Publication No. 8399725 and US Publication No. 0274425/2013, 0274425/2013, 0030135/2013 and 0137829/2013.
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Polypropylene's linear chain structure results in a polymer that exhibits low melt strength and lack of strand hardening. This can lead to processing problems as the polymer's extensibility is needed. Conversely, polypropylene compounds that exhibit high melting strength are valuable compounds in industrial conversion processes such as blow molding and forming.
<p dir="rtl">5 Thermal or foaming of polypropylene sheet. Polypropylene-based compositions</p>
According to this invention, acceptable melting strength, extensibility and strand hardening are demonstrated for the production of extruded profiles and walls.
Advantageously, polyolefin substrates include a homopolymer or copolymer of polypropylene of suitably high melting strength, optionally blended with a polymer.
<p dir="rtl">10 Homogenous or copolymer of polyethylene. The mixture may also contain a suitable tertiary polymer to facilitate compatibility, partial mixing or miscibility of different polyolefins. These materials are referred to as tension reducing agents or compatibilizers.</p>
Ideally suited stabilizers include polymers containing two or more 15 different parts each of which is miscible or compatible with the individual components to be mixed. He doesn't need it
Compatible Polymer Blends Until they are completely mixed and do not satisfy all the thermodynamic properties of the mixture (e.g. resulting in a single phase, or glass transition temperature), the different polymer blend structures will have improved properties versus the individual components. .
<p dir="rtl">20 One type of compatibility stabilizer for blending polypropylene and polyethylene is called olefin block copolymers, or OBC, containing propylene, ethylene and optionally alpha-sequences.</p>
Dow Global Technologies such as those produced by alpha-olefin sequences olefin
Referenced in American publications Nos. 032621/2011, 060103/2011,
298515/2010, 054121/2011 and 015354/2011. Dow products included
25 Which bears the trade name INFUSE and ExxonMobil VISTAMAXX. These block copolymers are produced with a weight distribution
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-٩-
segment molecular weight and overall molecular weight
>1.4 Mw/Mn, with two or more ethylene and alpha-olefin blocks per chain and low molecular weights (molecular weight > 200,000 g/mol). These block copolymers are characterized by a content of crystallizable parts, cohesive solids, and parts Soft, shapeless mass. 5. The solid mass content varies from 12 to 84% by weight in copolymer artolefin, and the total content of 1-octane (i.e., adds long chain branches) varies from 3 to 14% by weight. Polyart Olefin block co-polymers can be compatible with mixtures of polypropylene and high-density polyethylene where increased ductility at break and tensile strength can be achieved compared to an incompatible mixture of high-density polyethylene and polypropylene.
10 The homopolymer or copolymer of polypropylene or its blend with compatible polyethylene can optionally be covalently cross-linked to introduce long chain branches (LCB) away from the main polypropylene chain resulting in higher melt strength, extensibility and lower melt flow as commercially available.
Chemical crosslinking of a homopolymer or copolymer of polypropylene with a homopolymer or copolymer of polypropylene or with polyethylene and/or with a compatible material is advantageous. These crosslinking processes can result from a significant increase in the melting strength of the polyolefin mixture, as the melt's extensibility, mechanical strength and tensile strength are restricted in current extrusion processes. These cross-linking processes can produce long chain branching on the polypropylene main chain and form an improved amount of 20 polymer chain entanglements resulting in a polymer with higher melt strength.
Covalent bonding can be achieved by agents such as organic peroxides or by treatment with a radiation source such as ultraviolet light, electron beam, or gamma irradiation. Radiation 25 can be achieved in a low or zero oxygen environment. Example, polypropylene with high melt strength and melt extensibility is obtained by mixing linear polypropylene with polypropylene.
٦٣٧٤
-١٠-
Branched b-PP (branched polypropylene) in an extruder. Branched polypropylene is prepared by reacting peroxide with unmodified polypropylene and optionally a bifunctional unsaturated monomer capable of grafting onto unmodified polypropylene to produce long chain branches. In another example, US Patent No. 5,508,318.
5731362, 5591785, 5554668 and 4916198 Making a composite of mixtures of radioactive and non-radiative olefin polymer materials suitable for extrusion.
In contrast to post-extrusion or chemical polymer modification to form cross-links or long-chain branches to improve melt strength, long-chain branching can be performed
10 On prepolyolefins during polymer manufacturing. In one example, polyethylene can be modified in a polymerization unit by exposure to low-level oxygen, called “oxygen determination,” resulting in long-chain branching and improved melt strength, as referenced in US Publication No. 100357/2012.
The polyolefin substrate can contain an additive that improves crystallinity above 15 when the molten polymer is converted into formed elements. These additives are indicated
With nucleating agents.
The degree of crystallinity in polypropylene is a raw variable that affects properties such as modulus, yield stress, strength, etc. The perspective of this invention relates to the use of nucleating agents that influence the preferred formation of crystallinity that improves the melt strength of the polymer during the extrusion process and improves the mechanical properties in the end-use item. Suitable nucleating agents, for example, are sodium benzoate
2,2,sodium benzoate'-methylene-bis)4,6-di-tert-butylphenyl(2-'2' phosphate,
methylene-bis(4,6-di-tert-butylphenyl)phosphate, zinc glycerolate, calcium salt of 1,2-dicarboxylic acid cyclohexane, aromatic trisamide compounds 25 cis-endo-bicyclo acid salt
2.2.1]heptane-2,3-dicarboxylic acid disodium salt], aluminum hydroxy-bis]4-
٦٣٧٤
-١١-
And sorbitol compounds aluminum hydroxy-bis[4-(tert-butyl)benzoate] [tert-butyl(benzoate)
sorbitols such as 2,4:1,3-bis)3,4-dimethylbenzylidene (sorbitol-1,3:2,4-bis(3,4-di 2,4:1,3 methylbenzylidene)sorbitol-bis). 4-methylbenzylidene (sorbitol-4)1,3:2,4-bis methylbenzylidene)sorbitol or 2,4:1,3-bis)3,4-dimethylbenzylidene (sorbitol)
5 1,3:2,4-bis(3,4-dimethylbenzylidene)sorbitol, as stated in the patent
American Publications No. 7,423,088, 7,790,793 and 8,183,312 and American Publication No.
0190797/2012.
Nucleation agents can be present, for example, from about 10 ppm (ppm) to about 10,000 ppm, from about 12 ppm to about 1,000 ppm, from about 10 ppm to about 500 ppm, or from about 12 ppm In million to
About 300 ppm or about 400 ppm, by weight depending on the weight of the polyolefin substrate.
The polyolefin substrate usefully contains an inorganic mineral filler to balance melt strength and extensibility or ductility to allow extruded production15 of bodies and sidewalls. Fillers are described in more detail below.
The polyolefin substrate includes a homopolymer or copolymer of polypropylene optionally blended with a homopolymer or copolymer of polyethylene, where the mixture may also contain a compatibility stabilizer demonstrating a suitable high melting strength. The current melting strength of the polyolefin substrate is at least 4 cN at 210 °C. Example, the melting strength of the polyolefin substrate is about 20 4, about 5, about 6, about 7, about 8, about 9, about 10, About 11, about 12,
About 13, about 14, about 15, about 16, about 17, about 18, about 19, about 20, about 21, about 22, about 23 about 24 or about 25 cN at 210 degrees C. Example The melting strength is ≤ 5, ≤ 7, ≤ 9, ≤ 11, ≤ 13, ≤ 15, ≤ 17, ≤ 19, ≤ 21 or ≤ 23 cN at 210°C.
25 Polyolefin compounds can be prepared by the following methods:
a) Fractal polymerization (naturally under high pressure and at high temperatures) or
٦٣٧٤
-١٢-
b) Catalytic polymerization using a catalyst that normally contains one or more of a metal from groups VIb, Vb, IVb or VIII of the periodic table. These metals usually include one or more of a single ligand, typically oxides. halides, alcoholates, esters, ethers, 5-amines, alkyls, alkenyls and/or aryls that can be coordinated at either the π- or õ- positions. These metal complexes can be in free form or immobilized on substrates, ideally doped magnesium chloride, titanium(III) chloride (III), alumina or silicon oxide. These catalysts can be soluble or insoluble 10 in the polymerization medium. The catalysts themselves can be used in polymerization or activators can also be used, ideally metal alkyls, metal hydrides, metal alkyl halides, metal alkyl oxides or metal alkyloxanes. The metals mentioned are elements of groups IIa, Ia and/or IIIa of the 15 periodic table. Doping can also be suitably modified with ester and ether groups
ether, amine or silyl ether. These catalyst systems are often called TNZ (DuPont), Ziegler(-Natta), Standard Oil Indiana, Phillips, metallocene or SSC (single site catalysts).
Polypropylenes are produced by processes as described in
Kissin, YV (2008), Alkene Polymerization Reactions with Transition 20 Comprehensive Metal Catalysts, Elsevier, pp. 207–. ISBN 978-0-444-53215-2; Hoff, Ray and Mathers, Robert T. (2010), Handbook of Transition Metal Polymerization
Catalysts, John Wiley & Sons, pp. 158– ISBN 978-0-470-13798-7; Moore, E.
P. (1996) Polypropylene Handbook, Polymerization, Characterization, Properties,
Processing, Applications, Hanser Publishers: New York, ISBN 1569902089; 25
Benedikt, G. M. and Goodall, B. L. (eds.) (1998) Metallocene Catalyzed
٦٣٧٤
-١٣-
Polymers, ChemTech Publishing: Toronto, ISBN 978-1-884207-59-4; Malpass,
DB, Introduction to Industrial Polyethylene, Properties, Catalysts, Processes, Wiley
Publ., (2010); and Malpass, D. B., Introduction to Industrial Polypropylene,
Properties, Catalysts, Processes, Wiley Publ., (2012)
5 Ultraviolet light absorbers preferably selected from the group consisting of hydroxyphenylbenzotriazole, tris-aryl-s-triazine, 2-hydroxybenzoate, and 2-hydroxybenzophenone. Cyanoacrylate is a material that absorbs ultraviolet light (UVAs).
10 Hydroxyphenylbenzotriazole compounds, such as ultraviolet light absorbing materials, are disclosed in US Patent No. 3004896; 3055896; 3072585; 3074910; 3189615; 3218332; 3230194; 4127586; 4226763; 4275004; 4278589; 4315848; 4347180; 4383863; 4675352; 4681905 4853471; 5268450; 5278314; 5280124; 5319091; 5410071;
15 5436349؛ 5516914؛ 5554760؛ 5563242؛ 5574166؛ 5607987 5977219
and 6166218, as 2-)2-hydroxy-5-methylphenyl(-H2-benzotriazole 2-2-hydroxy)-3,5(-2,5-methylphenyl)-2H-benzotriazole-di-t-butyl- 2-Hydroxyphenyl(-H2-benzotriazole-2(-2,-(3,5-di-t-butyl-2-hydroxyphenyl)-2H-benzotriazole2)
Hydroxy-5-t-butylphenyl(-H2-benzotaryazole 2-(2-hydroxy-5-t-butylphenyl)-
20 2(-2H-benzotriazole-hydroxy-5-t-octylphenyl(-H2-benzotriazole 2-2)5,hydroxy-5-t-octylphenyl)-2H-benzotriazole-chloro-2-)3, 5-Di-t-butyl-2-
Hydroxyphenyl(-H2-benzotaryazole 5-2--chloro-2-(3,5-di-t-butyl)
<p dir="rtl">5 hydroxyphenyl-2H-benzotriazole-chloro-2-)3-t-butyl-2-hydroxy-5-methyl</p>
<p>-chloro-2-(3-t-butyl-2-hydroxy-5-methylphenyl)-5 benzotaryazole-H2-)phenyl</p>
25 sec-3(-2,2H-benzotriazole-butyl-5-t-butyl-2-hydroxyphenyl(-H2-benzotriazole)
Azole 2(-2,-(3-sec-butyl-5-t-butyl-2-hydroxyphenyl)-2H-benzotriazole2-
٦٣٧٤
-١٤-
Hydroxy-4-octyloxyphenyl(-H2-benzotaryazole 2-4-2-hydroxy)-
3,5(-2,octyloxyphenyl)-2H-benzotriazole-di-t-amyl-2-hydroxyphenyl(-H2-benzotriazole)-3,5(-2,-(3,5-di-t-amyl) -2-hydroxyphenyl)-2H-benzotriazole2 bis-α-cumyl-2-hydroxyphenyl(-H2-benzotriazole 2-2-3,5-bis- -cumyl)-
5 t-3(-2,hydroxyphenyl)-2H-benzotriazole-butyl-2-hydroxy-5-)2-)-
Hydroxy-octa-)ethyleneoxy(carbonyl-ethyl(-2-3-t-butyl-2-hydroxy-5-(2-()--(hydroxy-octa-(ethyleneoxy)carbonyl-ethyl, phenyl(- H2-benzotaryazole, 2-)3-
phenyl)-2H-benzotriazole, benzotriazole-H2-)dodecyl-2-hydroxy-5-methylphenyl
t-3(-2,2-(3-dodecyl-2-hydroxy-5-methylphenyl)-2H-benzotriazole-butyl-2-
10 Hydroxy-5-(2-octyloxycarbonyl)ethylphenyl(-H2-benzotriazole 2-(3-t-butyl 2-hydroxy-5-(2-octyloxycarbonyl)ethylphenyl)-2H-benzotriazole, dodecyl 2 ated -)2-Hydroxy-5-methylphenyl(-H2-benzotriazole-5-dodecylated 2-(2-hydroxy t-3(-2,methylphenyl)-2H-benzotriazole-butyl-2-hydroxy-5-) 2-Octyloxy
Ethyl carbonyl(phenyl(-5-chloro-H2-benzotaryazole 2-2)-5--(3-t-butyl-2-hydroxy)
15 3(-2,octyloxycarbonylethyl)phenyl)-5-chloro-2H-benzotriazole-tert-butyl-5-
(2-(2-Ethylhexyloxy)-carbonylethyl(-2-hydroxyphenyl(-5-chloro-H2-benzotary)
-(3-tert-butyl-5-(2-(2-ethylhexyloxy)-carbonylethyl)-2-hydroxyphenyl)-2 azole
t-3(-2,5-chloro-2H-benzotriazole-butyl-2-hydroxy-5-)2-methoxycarbonyl
Ethyl(phenyl(-5-chloro-H2-benzotaryazole 2-2)-5--(3-t-butyl-2-hydroxy)
20 t-3(-2,methoxycarbonylethyl)phenyl)-5-chloro-2H-benzotriazole-butyl-2-
Hydroxy-5-(2-methoxycarbonylethyl)phenyl(-H2-benzotaryazole 2-2-3-t-butyl)-t-3(-2, hydroxy-5-(2-methoxycarbonylethyl)phenyl)-2H -benzotriazole-butyl-5-)2-)2-ethylhexyloxy(carbonylethyl(-2-hydroxyphenyl(-H2-benzotriazole 2-3)-))
t-butyl-5-(2-(2-ethylhexyloxy)carbonylethyl)-2-hydroxyphenyl)-2H-
25 t-3(-2-benzotriazole-butyl-2-hydroxy-5-)2-isooctyloxycarbonylethyl(phenyl-H2-benzotriazole 2-2)-5-3-t-butyl-2-hydroxy) -
٦٣٧٤
-١٥-
2,2,isooctyloxycarbonylethyl)phenyl-2H-benzotriazole'-methylene-bis)4-t-octyl-
(H2-6-benzotaryazol-2-yl(phenol) 2-,2'-methylene-bis(4-t-octyl-(6-2H)
2(-2,benzotriazol-2-yl)phenol)-hydroxy-3-α-cumyl-5-t-octylphenyl(-H2-benzotriazole-2,-(2-hydroxy-3-cumyl-5- t-octylphenyl)-2H-benzotriazole2
5 )2-Hydroxy-3-t-octyl-5-α-coumyphenyl(-H2-benzotaryazole 2-3-2-hydroxy)-
5 ,t-octyl-5- cumylphenyl)-2H-benzotriazole-fluoro-2-)2-hydroxy-3,5-di-
α-Cumylphenyl(-H2-benzotaryazole 5--fluoro-2-(2-hydroxy-3,5-di- -cumyl)
5 phenyl)-2H-benzotriazole-chloro-2-)2-hydroxy-3,5-di-α-quylphenyl(-
-chloro-2-(2-hydroxy-3,5-di- -cumylphenyl)-2H-5 Benzotaryazole-H2
10 5, benzotriazole-chloro-2-)2-hydroxy-3-α-cumyl-5-t-octylphenyl(-H2-benzo)
-chloro-2-(2-hydroxy-3- -cumyl-5-t-octylphenyl)-2H-benzo-5 tarazole
t-3(-2-triazole-butyl-2-hydroxy-5-)2-isooctyloxycarbonylethyl(phenyl(-5-chloro-H2-benzotriazole 2-2)-5--(3-t) -butyl-2-hydroxy
5 isooctyloxycarbonylethyl)phenyl)-5-chloro-2H-benzotriazole-trifluoromethyl-2-
15 5-trifluoromethyl (2-hydroxy-3-α-cubyl-5-octylphenyl)-H2-benzotaryazole
5 2-(2-hydroxy-3- -cumyl-5-t-octylphenyl)-2H-benzotriazole-t-trifluoromethyl-2-)2-hydroxy-5-t-octylphenyl(-5-H2-benzotriazole) 2)-2-trifluoromethyl
5 hydroxy-5-t-octylphenyl)-2H-benzotriazole-t-rifluoromethyl-2-)2-hydroxy-
3,5-Di-t-octylphenyl(-H2-benzotaryazole 5-3,5--trifluoromethyl-2-(2-hydroxy)
20 di-t-octylphenyl)-2H-benzotriazole, methyl-3-)5-t-trifluoromethyl-H2-benzotriazole
Azol-2-yl(-5-t-butyl-4-hydroxyhydrocinnamate-methyl 3-(5-trifluoromethyl-2H5,benzotriazol-2-yl)-5-t-butyl-4-hydroxyhydrocinnamate-butylsulfonyl-2 -)2-Hydroxy-3-α-cumyl-5-t-octylphenyl(-H2-benzotaryazole 5-2)-2--butylsulfonyl 5,hydroxy-3- -cumyl-5-t-octylphenyl)- 2H-benzotriazole-trifluoromethyl-2-)2-
25 Hydroxy-3-α-cumyl-5-t-butylphenyl(-H2-benzotaryazole 5-2-trifluoromethyl)
5 (2-hydroxy-3- cumyl-5-t-butylphenyl)-2H-benzotriazole-trifluoromethyl-2-
٦٣٧٤
-١٦-
)2-Hydroxy-3,5-di-t-butylphenyl(-H2-benzotriazole 5-2)-2-trifluoromethyl-5,hydroxy-3,5-di-t-butylphenyl)-2H-benzotriazole- Trifluoromethyl-2-)2-
Hydroxy-3,5-di-α-cumylphenyl(-H2-benzotriazole-5-2)-2-trifluoromethyl 5,hydroxy-3,5-di-cumylphenyl)-2H-benzotriazole-butylsulfonyl-2 -)2-
<p dir="rtl">5 Hydroxy-3,5-di-t-butylphenyl(-H2-benzotaryazole 5-2)-2-butylsulfonyl</p>
<p>-2(-2-and-5-phenylsulfonyl hydroxy-3,5-di-t-butylphenyl)-2H-benzotriazole</p>
Hydroxy-3,5-di-t-butylphenyl(-H2-benzotaryazole 5-2)-2-phenylsulfonyl-
.hydroxy-3,5-di-t-butylphenyl)-2H-benzotriazole
Tris-aryl-s-triazine compounds 10 Ultraviolet light absorbing materials, for example, are also disclosed in US Patent No. 3,843,371; 4619956;
4740542؛ 5096489؛ 5106891؛ 5298067؛ 5300414؛ 5354794؛ 5461151؛
5476937؛ 5489503؛ 5543518؛ 5556973؛ 5597854؛ 5681955؛ 5726309؛
5736597؛ 5942626؛ 5959008؛ 5998116؛ 6013704؛ 6060543؛ 6242598
and 6255483, example 4,6-bis-)2,4-dimethylphenyl(-2-)2-hydroxy-4-octyloxy
15 Phenyl(-s-taryazine 4-4-6-bis-(2,4-dimethylphenyl)-2-(2-hydroxy,
octyloxyphenyl)-s-triazine, CYASORB 4,6, 1164 CYASORB-bis-)2,4-dimethylphenyl(-2-)2,4-dihydroxyphenyl(-s-triazine) 4-2,4)-,6-bis 2,4-dimethylphenyl)-2-(2,4-dihydroxyphenyl)-s-triazine-bis)2,4-dihydroxyphenyl(-6-)4-chlorophenyl (-s-taryazine 2-4)-6-(,4-bis(2,4-dihydroxyphenyl)
20 2,4-chlorophenyl)-s-triazine-bis]2-hydroxy-4-(2-hydroxyethoxy)phenyl[-
6-(4-Chlorophenyl(-s-triazine) 2-6-[4-bis[2-hydroxy-4-(2-hydroxyethoxy)phenyl, 2,4,(4-chlorophenyl)-s-triazine- bis]2-hydroxy-4-)2-hydroxy-4-)2-
Hydroxyethoxy(phenyl[-6-)2,4-dimethylphenyl(-s-tariazine 2-,4-bis[2-hydroxy)
,4-(2-hydroxy-4-(2-hydroxyethoxy)phenyl]-6-(2,4-dimethylphenyl)-s-triazine
25 2,4-Bis]2-hydroxy-4-(2-hydroxyethoxy)phenyl[-6-(4-bromophenyl)-s-tari
,4-bis[2-hydroxy-4-(2-hydroxyethoxy)phenyl]-6-(4-bromophenyl)-s-2 azine
٦٣٧٤
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2-triazine-bis]2-hydroxy-4-(2-acetoxyethoxy)phenyl[-6-(4-chlorophenyl)-s-triazine 2-(,4-bis[2-hydroxy-4) -(2-acetoxyethoxy)phenyl]-6-(4-chlorophenyl 2,4,s-triazine-bis)2,4-dihydroxyphenyl(-6-)2,4-dimethylphenyl(-s-triazine) Azine 2,4,4-bis(2,4-dihydroxyphenyl)-6-(2,4-dimethylphenyl)-s-triazine2-bis)4-bis
5 Phenylyl(-6-)2-hydroxy-4-octyloxycarbonylethylideneoxyphenyl(-s-tariazine)
,4-bis(4-biphenylyl)-6-(2-hydroxy-4-octyloxycarbonylethylideneoxyphenyl)-s-2
2 Triazine-phenyl-4-]2-hydroxy-4-)3-sec-butyloxy-2-hydroxypropyloxy(phenyl[-6-]2-hydroxy-4-)3-sec-amyloxy-2- hydroxypropyl oxy(
<p>-phenyl-4-[2-hydroxy-4-(3-sec-butyloxy-2-hydroxy-2-triazine-s-]phenyl</p>
propyloxy)phenyl]-6-[2-hydroxy-4-(3-sec-amyloxy-2-hydroxypropyloxy)-10
2,4-phenyl]-s-triazine-bis)2,4-dimethylphenyl(-6-[2-hydroxy-4-)3-benzyloxy-2-hydroxypropyloxy(phenyl[-s-triazine) Azine 2-(,4-bis(2,4-dimethylphenyl
<p>-2,4,6-[2-hydroxy-4-(3-benzyloxy-2-hydroxypropyloxy)phenyl]-s-triazine</p>
bis)2-hydroxy-4-N-butyloxyphenyl(-6-)2,4-di-N-butyloxyphenyl(-s-)
<p dir="rtl">15 Triazine 2-(4-bis(2-hydroxy-4-n-butyloxyphenyl)-6-(2,4-di-n-butyloxyphenyl, 2,4,s-triazine-bis)2,4-dimethylphenyl (-6-[2-hydroxy-4-)3-nonyloxy*-2-hydroxypropyloxy(-5-α-cubylphenyl[-s-taryazine 2-,4-bis(2,4-dimethyl)</p>
phenyl)-6-[2-hydroxy-4-(3-nonyloxy*-2-hydroxypropyloxy)-5- -cumyl-
phenyl]-s-triazine)* Remember a mixture of octyloxy and nonyl oxy groups
20 nonyloxy and decyloxy(,methylenebis-}2,4-bis)2,4-dimethylphenyl(-6-[2-hydroxy-4-)3-butyloxy-2-hydroxypropoxy(phenyl[-s-] I don't see it {
methylenebis-{2,4-bis(2,4-dimethylphenyl)-6-[2-hydroxy-4-(3-butyloxy-2-)
{hydroxypropoxy)phenyl]-s-triazine, a methylene bridged dimer mixture at the 3:5', 5:5' and 3:3' positions in a ratio of 5:4:1, 2,4,6-Tris)2- Hydroxy
<p dir="rtl">25 -4-Isooctyloxycarbonyl -Isopropyldioxyphenyl(-s-triazine 2-2),4,6-tris</p>
<p>-2,4,hydroxy-4-isooctyloxycarbonylisopropylideneoxyphenyl)-s-triazine</p>
٦٣٧٤
-١٨-
Bis)2,4-dimethylphenyl(-6-)2-hydroxy-4-hexyloxy-5-α-cubylphenyl(-s-tariazine) 2-4-bis(2,4-dimethylphenyl)-6 -(2-hydroxy-4-hexyloxy-5- -cumyl, 2,4,6(-2,phenyl)-s-triazine-trimethylphenyl(-4,6-bis]2-hydroxy-4-) 3-Butyloxy-2-hydroxypropyloxy(phenyl[-s-taryazine 2-(-(2,4,6-trimethylphenyl)
4,6-bis[2-hydroxy-4-(3-butyloxy-2-hydroxypropyloxy)phenyl]-s-triazine 5
2,4,6-tris]2-hydroxy-4-)3-sec-butyloxy-2-hydroxypropyloxy(phenyl[-s-taryazine) 2-(4,6-tris[2-hydroxy-4) -(3-sec-butyloxy-2-hydroxypropyloxy, phenyl]-s-triazine, a mixture of 4,6-bis-)2,4-dimethylphenyl(-2-)2-hydroxy-4-
(3-Dodecyloxy-2-hydroxypropoxy)-phenyl(-s-tariazine 4-2,4)-,6-bis
dimethylphenyl)-2-(2-hydroxy-4-(3-dodecyloxy-2-hydroxypropoxy)-phenyl)-s- 10
triazine and 4,6-bis-(2,4-dimethylphenyl(-2-)2-hydroxy-4-)3-tridecyloxy-2-hydroxypropoxy(-phenyl(-s-triazine) 4- 2)-2-(,6-bis-(2,4-dimethylphenyl hydroxy-4-(3-tridecyloxy-2-hydroxypropoxy)-phenyl)-s-triazine, TINUVIN 4,6,400 TINUVIN-bis-(2,4-dimethylphenyl(-2-)2-hydroxy-4-)315 (2-ethylhexyloxy(-2-hydroxypropoxy)-phenyl(-s-taryazine) 2-4 ,4)-6-bis,
dimethylphenyl)-2-(2-hydroxy-4-(3-(2-ethylhexyloxy)-2-hydroxypropoxy)-
phenyl)-s-triazine and 4,6-diphenyl-2-(4-hexyloxy-2-hydroxyphenyl(-s-)
Triazine.,6-diphenyl-2-(4-hexyloxy-2-hydroxyphenyl)-s-triazine4
Hydroxybenzoate, an example of a compound that absorbs ultraviolet light, is hydroxybenzoate
20 Esters of substituted or unsubstituted benzoic acids, e.g. 4-tert-butylphenyl salicylate, phenyl salicylate, octylphenyl salicylate, dibenzoyl resorcinol, bis)4-tert-butyl Benzoyl resorcinol bis(4-tert-butylbenzoyl) resorcinol, benzoyl resorcinol 2,4,benzoyl resorcinol-di-tert-butylphenyl 3,5-di-tert-butyl-4
25 Hydroxybenzoate 4-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate2,,
Hexadecyl 3,5-di-tert-butyl-4-hydroxybenzoate -hexadecyl 3,5-di-tert-butyl
٦٣٧٤
-١٩-
4-hyd oxybenzoate, octadecyl 3,5-di-tert-butyl-4-hydroxybenzoate octadecyl 3,5-di-tert-butyl-4-hyd oxybenzoate, 2-methyl-4,6-di-tert-butyl Phenyl E,3-di-tert-butyl-4-hydroxybenzoate 2-methyl-4,6-di-tert-butylphenyl 3,5-di
tert<sup>-</sup>butyl<sup>-</sup>4<sup>-</sup>hydroxybenzoate
5 Ultraviolet light-absorbing materials of 2-Hydroxybenzophenone<sup>-</sup>For example, it is 4-hydroxy, 4-methoxy<sup>-</sup>, 4-octyloxy, 4-decyloxy;<sup>-</sup>, 4-dodecyloxy;<sup>-</sup>, 4-benzyloxy<sup>-</sup>, 2,4,4-trihydroxy 74a*30l17lthsa-2,4, and 2-hydroxy-4,4-dimethoxy derivatives hydr0xy-4,4'-dimeth0xy derivatives2-'.
10 Ultraviolet light-absorbing materials from Cyanoacrylate, for example, pentaerythritol tetrakis(2-cyano (3,3-diphenylacrylate), L0-cyano-3a acid. ,0-diphenyl acrylic ethyl ester<sup>-</sup>cyano<sup>-</sup>□
And 0-cyano acid isooctyl ester or isoctyl ester □□□<sup>-</sup>diphenylacrylic acid ethyl ester
-3-Methyl-[-methoxycinnamic methyl ester cyano-D-methyl-p-methoxy-cinnamic-□
·butyl ester or butyl ester acid methyl ester E1
Specifically, the materials that absorb ultraviolet light are H-chloro-2<sup>—</sup>(3-1-Butyl-2-hydroxy-5-methylphenyl)-112-benzotriazole 5-chloro-2-(3-t-butyl-2-hydroxy-5-methylphenyl)-2H-benzotriazole, 2- (3,5-bis-n-cumyl-2-hydr0xyphenyl)-112-benzotriazole,-(3,5-bis-n-cumyl-2-hydr0xyphenyl)-2H-benz0triaz01e2 20 4,6-diphenyl -2-(4-hexyloxy-2-hydroxyphenyl)--triazine 4-6-diphenyl, 10A2H11A-5-(1L11A3A1L0]170-2-1357107-4)-2, 4,6-Bis-(2 4-dimethylphenyl)-2-(2-hydroxy-4-octyloxyphenyl)-triazine 4-2-(6-bis-(2,4-dimethylphenyl), 2-hydroxy-4-octyloxyphenyl)-s-triazine), hexadecyl-3,5-di-tertbutyl-4-
or 4-octyloxyhexadecyl 3,5-di-tert-butyl-4-hydroxybenzoate
25-2-Hydroxybenzophenone;octyloxy-2-hydroxybenzophenone-.
٦٣٧٤
-٢٠-
There are many commercially available UV light absorbing materials, e.g. TINUVIN 326,
CYASORB UV 1164, TINUVIN 1600, TINUVIN 1577, TINUVIN 234
UVINUL 3030, CHIMASSORB 81, CYASORB UV 2908, CYASORB THT, etc.
Ultraviolet light absorbing materials are present, in aggregate, from about 0.01 to about 2.5%.
5 By weight, preferably from about 0.10 to about 1.5 wt%, depending on the weight of the polyolefin substrate. More preferably from about 0.10 to about 0.95 wt%. Example, at levels of about 0.20, about 0.25, about 0.30, about 0.35, about 0.40, about 0.45, about 0.50, about 0.55, about 0.60, about 0.65, about 0.70, about 0.75, about 0.80, about 0.85 or about 0.90%. By weight, based on the weight of the polyolefin substrate and levels between them.
10 Obstructed amine light stabilizers (HALS) are disclosed in US Petition No. 379842/14, Publication No. 136285/2013, and US Patents Nos. 5004770, 5204473, 5096950, 5300544, 5112890, 5124378, and 5 145893, 5216156, 5844026 , 5980783, 6046304, 6117995, 6271377, 6297299, 6392041, 6376584 and 6472456.
<p dir="rtl">15 Suitable retractable safety light fixtures, such as:</p>
<p dir="rtl">(1) 1-cyclohexyloxy-2,2,6,6-TTRmethyl-4-octadecylaminopiperidine-1</p>
cyclohexyloxy-2,2,6,6-tetramethyl-4-octadecylaminopiperidine
(2)bis(2,2,6,6-tetramethylpiperidin-4-yl)sebacate -bis(2,2,6,6-tetramethylpiperidin)
,4-yl)sebacate
20 (3(bis)1-acetoxy-2,2,6,6-TTR methylpiperidin-4-yl) sebacate -bis)1-acetoxy
2,2,6,6-tetramethylpiperidin-4-yl) sebacate
(4)bis(1,2,2,6,6-pentamethylpiperidin-4-yl)sebacat-1,2,2,6,6)bis
,pentamethylpiperidin-4-yl) sebacate
(5(Bis)1-Cycyclohexyloxy-2,2,6,6-TTR Methyl Piperidin-4-yl) Sebacat-1)bis
cyclohexyloxy-2,2,6,6-tetramethylpiperidin-4-yl) sebacate 25
٦٣٧٤
-٢١-
(6(bis)1-octyloxy-2,2,6,6-TTR methylpiperidin-4-yl) sebacate -bis(1-octyloxy)
2,2,6,6;-tetramethylpiperidin-4-yl) sebacate
(7(bis)1-acyl-2,2,6,6-tetra methylpiperidin-4-yl) sebacate -bis(1-acyl-2,2,6,6-tetra)
methylpiperidin-4-yl) sebacate
5 (8(bis)1,2,2,6,6-pentamethyl-4-piperidyl) N-butyl-3,5-di-tert-butyl-4-
bis(1,2,2,6,6-pentamethyl-4-piperidyl) n-butyl-3,5-di-hydroxybenzymalonate
tert-butyl-4-hydroxybenzylmalonate
(9(2,4-Bis])1-cyclohexyloxy-2,2,6,6-TTR methylpiperidin-4-yl(butylamino[-6-)2-hydroxyethyl
10 Amino-s-taryazine 2-4-4-bis[(1-cyclohexyloxy-2,2,6,6-tetramethylpiperidin,
,yl)butylamino]-6-(2-hydroxyethylamino-s-triazine
(10(bis)1-cyclohexyloxy-2,2,6,6-ttr-methylpiperidin-4-yl)adipate-1)bis
cyclohexyloxy-2,2,6,6-tetramethylpiperidin-4-yl) adipate
(11(2,4-Bis])1-cyclohexyloxy-2,2,6,6-piperidin-4-yl(butylamino[-6-
15 Chloro-s-taryazine 2-[4-bis[(1-cyclohexyloxy-2,2,6,6-piperidin-4-yl)butylamino,
,6-chloro-s-triazine
(12) 1-(2-Hydroxy-2-methylpropoxy)-4-Hydroxy-2,2,6,6-TTR Methyl Piperidine
1-(2-hydroxy-2-methylpropoxy)-4-hydroxy-2,2,6,6-tetramethylpiperidine
(13(1-)2-Hydroxy-2-methylpropoxy)-4-oxo-2,2,6,6-TTR Methyl Piperidine-1
(2-hydroxy-2-methylpropoxy)-4-oxo-2,2,6,6-tetramethylpiperidine 20
(14(1-)2-Hydroxy-2-methylpropoxy)-4-octadecanoyl oxy-2,2,6,6-TTR
Methylpiperidine-1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetra methylpiperidine,
(15(Bis)1-(2-hydroxy-2-methylpropoxy)-2,2,6,6-TTRmethylpiperidin-4-yl)
bis(1-(2-hydroxy-2-methylpropoxy)-2,2,6,6-tetramethylpiperidin-4-yl) 25 sebacate
sebacate
٦٣٧٤
(16)Bis(1-(2-hydroxy-2-methylpropoxy)-2,2,6,6-tetramethylpiperidin-4-yl)
bis(l-(2-hydi0xy-2-methylprop0xy)-2,2,6,6-tetiamethylpiperidin-4-yl adipate,
(17)2,4-Bisyl]-1 1-(2-Hydroxy-2-methylpropoxy)-2,2,6,6-tetramethylpiperidin-H-4-yl]-E-butylamino}-
6-(2-Hydoxyethylamino)-5-triazine 2-4-bis{N-[l-(2-hydroxy-2-methyl,
prop0xy)-2,2,6,6-tetiamethylpiperidin-4-yl]-N-butylamine0}-6-(2-hydioxyethyl-
,amino)<sup>_</sup>s<sup>_</sup>triazine
(18)4-benzoyl-6,6,2,2-tetramethylpiperidine 4-benzoyl-2,2,6,6-tetramethylpiperidine,
10 (19) DI—(1,2,2,6,6—BNNA Λethylpiperidine—4—IL^Λ—PTHOHDEBZYLYDINMALUTH -di
1) p-methoxybenzylidenemalonate l-4-1a0110•y]ml0ha0p00-1,2,2,6,6),
(20) 2,2,6,6-tetramethylpiperidin-4-yl octadecanoate 2-,2,6, 6tetram ethyl pi peri di η
4-71 octadecanoate
(21) Bis(1-octyloxy-2,2,6,6-tetramethylpiperidyl) succinate -bis(l-octyloxy n 1 succinate (Al0114••1L%1M02M10-2,2,6,6,
(22) 1,2,2,6,6-pentamethyl-4-aminopiperidine-4-l,2,2,6,6-pentamethyl
,aminopiperidine
(23) 2-Undecyl-7,7,9,9-tetramethyl-1-oxa-3,8-diaza-4-oxo-
Spiro4,5decane 2-undecyl-7,7,9,9-tetramethyl-l-oxa-3,8-diaza<sup>_</sup>4-oxo-
spi2o[4,5]decane 20
(24) Tris(2,2,6,6-tetramethyl-4-piperidyl)tris-2,2,6,6-nitriacetate
,tetramethyl-4-piperidyl)nitrilotriacetate
(25) Tris(2-hydroxy-3-(amino-(2,2,6,6-tetramethylpiperidin-4-yl)propyl)nitrilo
Tris(2-hydioxy-3-(amin0-(2,2,6,6-tetiamethylpiperidin-4-yl)propyl 25 nitrilotriacetate;
٦٣٧٤
-٢٣-
(26) Tatar Kiss (2,2,6,6-TTR Methyl-4-Piperidyl)-1,2,3,4-Butane-TTR Carboxylate
tetrakis(2,2,6,6-tetramethyl-4-piperidyl)-1,2,3,4-butane-tetracarboxylate
(27) Tatar Cyst (1,2,2,6,6-Pentamethyl-4-piperidyl)-1,2,3,4-Butane-Ttr Carboxylate
tetrakis(1,2,2,6,6-pentamethyl-4-piperidyl)-1,2,3,4-butane-tetracarboxylate
5 (28) 1,1'-(1,2-ethanediyl(-bis)3,3,5,5-TTRmethylpiarzenone)-1,2)-'1,1
,ethanediyl)-bis(3,3,5,5-tetramethylpiperazinone)
(29) 3-N-octyl-7,7,9,9-TTR methyl-1,3,8-TRI azspiro[4.5]decane-2,4-dione
,-n-octyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro[4.5]decan-2,4-dione3
(30) 8-Acetyl-3-dodecyl-7,7,9,9-Trmethyl-1,3,8-TrAzpyro[4.5]decane-
10 2,4-Dione-8-1,3,8-acetyl-3-dodecyl-7,7,9,9-tetramethyl-
,triazaspiro[4.5]decane-2,4-dione
(31) 3-Dodecyl-1-(2,2,6,6-TTRmethyl-4-piperidyl(pyrrolidine-2,5-dione-3-)
,dodecyl-1-(2,2,6,6-tetramethyl-4-piperidyl)pyrrolidin-2,5-dione
(32) 3-Dodecyl-1-(1,2,2,6,6-pentamethyl-4-piperidyl(pyrrolidine-2,5-dione-3-)
dodecyl-1-(1,2,2,6,6-pentamethyl-4-piperidyl)pyrrolidine-2,5-dione 15
(33) N',N-bis-formyl-N',N-bis)2,2,6,6-TTR-methyl-4-piperidyl(hexamethylenedi)
N,N'-bis-formyl-N,N'-bis(2,2,6,6-tetramethyl-4- amine
piperidyl)hexamethylenediamine
(a33(bis)1-undecanyloxy-2,2,6,6-ttr-methylpiperidin-4-yl(carbonate)
20 (34) Reaction product 2,4-bis](1-cyclohexyloxy-2,2,6,6-piperidin-4-yl(butyl)
Amino[-6-chloro-s-
Triazine 2-4-bis[(1-cyclohexyloxy-2,2,6,6-piperidin-4-yl)butylamino]-6-chloro, s-triazine with N',N-bis)3-aminopropyl( Ethylenediamine(-3)N,N'-bis
,aminopropyl)ethylenediamine)
٦٣٧٤
-٢٤-
(35) Condensation product 1(2-hydroxyethyl condensate)-2,2,6,6-tetramethyl-4-hydroxy
2)-1-hydroxyethyl acid)-2,2,6,6-tetramethyl-4-hydroxypiperidine piperidine
succinic acid,
(36) Condensation product N',N condensate-bis(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylene
<p>-4N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylenediamine 5-diamine</p>
Tert-octylamino-2,6-dichloro-1,3,5-tariazine 4-tert-octylamino-2,6-dichloro-
1,3,5-triazine
(37) Condensation product N',N condensate-bis(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylene
<p>-4N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylenediamine diamine</p>
<p dir="rtl">10 Cyclohexylamino-2,6-dichloro-1,3,5-tariazine 4-2,6-cyclohexylamino-</p>
, dichloro-1,3,5-triazine
(38) Condensation product N',N condensate-bis-(2,2,6,6-tetramethyl-4-piperidyl)hexamethylene
-4N,N'-bis-(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine diamine
Morpholino-2,6-dichloro-1,3,5-tariazine 4-1,3,5-morpholino-2,6-dichloro-
, triazine 15
(39) Condensation product N',N condensate-bis-(1,2,2,6,6-pentamethyl-4-piperidyl)hexa
N,N'-bis-(1,2,2,6,6-pentamethyl-4-piperidyl)-methylenediamine
hexamethylenediamine and 4-morpholino-2,6-dichloro-1,3,5-tariazine 4-morpholino-
,2,6-dichloro-1,3,5-triazine
20 (40) Condensate product 2-chloro-4,6-bis)4-N-butylamino-2,2,6,6-tetramethyl
Piperidyl(-1,3,5-tariazine 2-2,2,6,6-chloro-4,6-bis(4-n-butylamino-)
tetramethylpiperidyl)-1,3,5-triazine and 1,2-bis)3-aminopropylamino(ethane-3)1,2-bis
,aminopropylamino)ethane
(41) Condensation product 2-condensate-chloro-4,6-di-(4-N-butylamino-1,2,2,6,6-penta-25methylpiperidyl)-1,3,5-tariazine 2 -1,2,2,6,6-chloro-4,6-di-(4-n-butylamino-
٦٣٧٤
-٢٥-
pentamethylpiperidyl)-1,3,5-triazine and 1,2-bis-)3-aminopropylamino(ethane-1,2-bis)
,(3-aminopropylamino)ethane
(42) Reaction product 7,7,9,9-tetramethyl-2-cycloundecyl-1-oxa-3,8-diaz-4-oxospyro[4,5]decane 7-4-7,9 ,9-tetramethyl-2-cycloundecyl-1-oxa-3,8-diaza,
5 oxospiro[4,5]decane and epichlorohydrin,
(43) Poly[methyl,(3-oxy-(2,2,6,6-TTR)methylpiperidin-4-yl(propyl)]siloxane
,poly[methyl,(3-oxy-(2,2,6,6-tetramethylpiperidin-4-yl)propyl)] siloxane
,0-99-CAS#182635
<p dir="rtl">(44) Maleic acid reaction product - α-C22-C18-olefin-copolymer - maleic acid anhydride</p>
<p dir="rtl">10 hydride-C18-C22- -olefin-copolymer with 2,2,6,6-tetramethyl-4-aminopiperidine</p>
,,2,6,6-tetramethyl-4aminopiperidine2
<p dir="rtl">(45) Oligomeric condensate product of 4,4'-hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine) 4,4'-hexamethylenebis(amino-2,2,6,6- tetramethyl, piperidine) and 2,4-dichloro-6-])2,2,6,6-tetramethylpiperidine-4-yl(butylamino[-s-</p>
<p dir="rtl">15 Terminally coated tareazine 2-,4-dichloro-6-[(2,2,6,6-tetramethylpiperidin-4-yl)butyl</p>
amino]-s-triazine end-capped with 2-chloro-4,6-bis)dibutylamino(-s-triazine2-
, chloro-4,6-bis(dibutylamino)-s-triazine
<p dir="rtl">(46) Oligomeric condensate of 4,4'-hexamethylenebis(amino-1,2,2,6,6-pentamethylpiperidine) 4,4'-hexamethylenebis(amino-1,2,2,6). ,6-pentaa,</p>
20 (methylpiperidine and 2,4-dichloro-6-])1,2,2,6,6-pentamethylpiperidine-4-yl(butyl)
Amino[-s-triazine end-capped with 2-chloro-6-[(1,2,2,6,6-pentaamethylpiperidin, yl)butylamino]-s-triazine end-capped with 2-chloro- 4,6-bis)dibutylamino(-s-triazine),-chloro-4,6-bis(dibutylamino)-s-triazine2
<p dir="rtl">(47) Oligomeric condensate product of 4,4'-hexamethylenebis(amino-1)</p>
25 Propoxy-2,2,6,6-TTR Methylpiperidine (4-4'-hexamethylenebis(amino-1-propoxy,
2,2,6,6-tetramethyl
٦٣٧٤
-٢٦-
piperidine and 2,4-dichloro-6-])1-propoxy-2,2,6,6-ttr-methylpiperidin-4-yl(butylamino[-s-ttriazine) terminal capped 2-,4-dichloro -6-[(1-propoxy-2,2,6,6-tetra methylpiperidin-4-yl)butylamino]-s-triazine end-capped with 2-chloro-4,6-bis)dibutylamino(-s) -T-triazine, -chloro-4,6-bis(dibutylamino)-s-triazine2
5 (48) Oligomeric condensate product of 4,4'-hexamethylenebis(amino-1-)
Acyloxy-2,2,6,6-TTR methylpiperidine (4-4'-hexamethylenebis(amino-1-acyloxy,
2,2,6,6-tetramethyl
piperidine) and 2,4-dichloro-6-])1-acyloxy-2,2,6,6-tt-trimethylpiperidin-4-yl(butylamino[-s-tt-triazine) terminal capped 2-2, 2,6,6-,4-dichloro-6-[(1-acyloxy
<p dir="rtl">10 tetramethylpiperidin-4-yl)butylamino]-s-triazine end-capped with 2-chloro-4,6-</p>
And -chloro-4,6-bis(dibutylamino)-s-triazine2-triazine-s-)bis)dibutylamino
<p dir="rtl">(49) A product obtained by the reaction of (A) with (B), where (A) is a product obtained by the reaction of 1,2-bis)3-aminopropylamino(ethane-1,2-bis)3- amino propylamino)ethane with cyanuric chloride and (b) is (2,2,6,6-</p>
15 Methyl piperidin-4-yl tartar (2,2,6,6-tetramethylpiperidin-4-yl)butylamine. Also included is a isoformically modified NH, N-methyl, N-methyl-methoxy, N-methoxy. N-hydroxy, N-hydroxy-propoxy, N-propoxy, N-octyloxy, N-cyclohexyloxy, N-acyloxy, and 2(-N-) analogues
Of any N-(2-hydroxy-2-methylpropoxy) analogues )hydroxy-2-methylpropoxy
20 Of the compounds mentioned above. For example, replacing the NH-hindered amine with an N-methyl hindered amine for the N-methyl counterpart at the NH site.
For illustrative purposes, some structures of the above compounds are shown below.
٦٣٧٤
-٢٧-
)6(
O.O
OC(CH)CO
<img file="SA6374B1_D0001.tif" />
<img file="SA6374B1_D0002.tif" />
)8(
<img file="SA6374B1_D0003.tif" />
<img file="SA6374B1_D0004.tif" />
)9(
HN CH CH OH
<img file="SA6374B1_D0005.tif" />
<img file="SA6374B1_D0006.tif" />
٦٣٧٤
-٢٨-
)19(
)23(
<img file="SA6374B1_D0007.tif" />
NH
<img file="SA6374B1_D0008.tif" />
)25(
O
<img file="SA6374B1_D0009.tif" />
NR NR
CH3
<sup>H</sup>3<sup>C</sup>
<img file="SA6374B1_D0010.tif" />
NR O
<img file="SA6374B1_D0011.tif" />
<sup>H</sup>3<sup>C</sup>
)28(
H.N.N<sup>O</sup>N NH
)29(
<img file="SA6374B1_D0012.tif" />
٦٣٧٤
<img file="SA6374B1_D0013.tif" />
-٢٩-
<img file="SA6374B1_D0014.tif" />
)31(
)33(
<img file="SA6374B1_D0015.tif" />
<img file="SA6374B1_D0016.tif" />
)34(
<img file="SA6374B1_D0017.tif" />
<img file="SA6374B1_D0018.tif" />
)35(
<img file="SA6374B1_D0019.tif" />
٦٣٧٤
-٣٠-
N(CH<sub>2</sub>)<sub>6</sub>
)38(
NN<sup>N</sup>
HH<sub>O</sub>
R
<img file="SA6374B1_D0020.tif" />
R
NN
NN<sub>R</sub>
H
)41(
R=N
<img file="SA6374B1_D0021.tif" />
NCH
3
C4H9
<img file="SA6374B1_D0022.tif" />
)42(
<img file="SA6374B1_D0023.tif" />
n
)43(
٦٣٧٤
-٣١-
)44(
<img file="SA6374B1_D0024.tif" />
H
)45(
<img file="SA6374B1_D0025.tif" />
٦٣٧٤
(٤٩)
<img file="SA6374B1_D0026.tif" />
Preferably, hindered amine light stabilizers selected from the group consisting of
5(2)Bis(2,2,6,6-tetramethylpiperidin-4-yl)sebacat,
(20) 2,2,6,6-tetramethylpiperidin-4-yl octadecanoate,
(14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetra
Methylpiperidine-1-(2-hydroxy-2methylprop0xy)-4-0Ctadecan0yl0xy-2,2,6,6-tetra methylpiperidine,
10(33)T!,A1-bis-formyl-l1,l]-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenedi
Amen,
(36) Condensation product of 2e-bis(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylenediamine and 4-trit-octylamino-6,2-dichloro-e,3, 1-Tray Azin,
(38) Condensation product of, “2e-bis-(6,6,2,2-tetramethyl-4-piperidyl)hexamethylenediamine 15 and 4-morgolitho—6,2-dicludo-h,3,1- Have a nice day,
٦٣٧٤
-٣٣-
(39) Condensation product of, “2e-bis-(6,6,2,2,1-pentamethyl-4-piperidyl)hexamethylenediamine and 4-morpholino-6,2-dichloro-H,3,1 -Tray Azin,
(44) The product of the reaction of maleic acid anhydride-8r0-022-00-olefin-copolymer with 6,6,2,2-tetramethyl-4-aminopiperidine,
E (45) Oligomeric compound resulting from the condensation of 4,4-hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine) and 2,4-dichloro-6-[(2,2,6,6-tetra) Methylpiperidin-4-yl)butylamino]-5-triazine is peripherally covered by 2-chloro-4,6-bis(dibutylamino)-5-triazine,
(47) An oligomeric compound resulting from the condensation of 4,4-hexamethylenebis(amino-1-propoxy-2,2,6,6-tetramethylpiperidine) and 4,2-dichloro-6-a(1-propoxy-2, 2,6,6-tetramethyl
10 Piperidine-4-yl)butylamino]-5-triazine is peripherally covered by 2-chloro-4,6-bis(dibutylamino)-5-triazine and di- and tri-azine combinations thereof.
Certain combinations of amine-challenged light stabilizers are useful. The preferred combinations of amine-impaired light stabilizers are binary combinations of
(2)Bis(2,6,6,2-tetramethylpiperidin-4-yl)sebacate and
15 (36) Condensation product of “2e-bis(6,6,2,2-tetramethyl-4-piperidyl)-hexamethylenediamine
and 4-tart-octyl N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylenediamine.
Amino-2,6-dichloro-3,5,1-triazine 4-3,5,teit-octylamino-2,6-dichloo-l-
;(ΒΙΝ1) three times
(2)Bis(2,2,6,6-tetramethylpiperidin-4-yl)sebacat and
20 (45) Oligomeric compound resulting from the condensation of 4,4-hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine), and 4 2-Dichloro-6-[(2,2,6,6-tetramethylpiperidin-4-yl)butylamino]-5-triazine is terminally coated.
,4-dichl0ro-6-[(2,2,6,6-tetramethylpiperidin-4-yl)butylamine0]-s-triazine end,2
capped with 2-chloro-4,6-bis(dibutylamino)-5-triazine 2-chloro-4,6-bis(dibutyl-
(ΒΙΝ2)amino)<sup>_</sup>s<sup>_</sup>triazine 25
(20) 2,2,6,6-tetramethylpiperidin-4-yl octadecanoate and
٦٣٧٤
-٣٤-
(45) Oligomeric condensation product of 4,4-hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine) and 2,4-dichloro-6-[(2,2,6,6-tetra) Methylpiperidin-4-yl)butylamino]-5-triazine is terminally coated with 2-
Chloro-4,6-bis(dibutylamino)-5-triazine 2-chloi-o-4,6-bis(dibutylamino)-s-
Or (ΒΙΝ3) triazine 5
(2)Bis(2,2,6,6-tetramethylpiperidin-4-yl)sebacat and
(20)2,2,6,6-Tetramethylpiperidin-4-yl octadecanoate-2,2,6,6
(ΒΙΝ4)tetramethylpiperidin-4-yl octadecanoate.
Also preferable are light stabilizers with a triple impedance of amine
10(2)Bis(6,6,2,2-tetramethylpiperidin-4-yl)sebacate,
(14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine and
(45) Oligomeric condensation product of 4,4-hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine) and 2,4-dichloro-6-[(2,2,6,6-tetramethyl Piperidine-4-yl)butylamino]-5-tri-15azine is terminally capped with ?-chloro-6,4-bis(dibutylamino)-5-triazine?-4,6-0 chlo-
TERl)bis(dibutylamino)-s-tri azine
(14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine,
(20) 2,2,6,6-tetramethylpiperidin-4-yl octadecanoate and
20 (45) Oligomeric condensation product of 4,4-hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine) and 2,4-dichloro-6-[(2,2,6,6-tetra) Methylpiperidin-4-yl)butylamino]-5-triazine is peripherally covered by 2-chloro-6,4-bis(dibutylamino)-5-triazine 2-4,6-0 chlo-
Or (TER2)bis(dibutylamino)-s-triazine
(2)Bis(2,2,6,6-tetramethylpiperidin-4-yl)sebacat,
25(14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine and
٦٣٧٤
-٣٥-
(36) Condensation product N',N-bis(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylenediamine and 4-tert-octylamino-2,6-dichloro-1,3 5-Taryazine 4-2,6-tert-octylamino-
(TER3) dichloro-1,3,5-triazine
Ambidextrous light fixtures (38) or (39) can be replacements for ambidextrous light fixtures.
5 Disabled (36) in secondary and tertiary combinations.
There are many commercial amine-inhibited stabilizers, for example TINUVIN, 770 CHIMASSORB, 944,
TINUVIN, CYASORB UV 3529, CYASORB UV 3853, CHIMASSORB 2020
371 UVINUL 5050, UVINUL 4050, NOR, etc.
Tertiary combination 1 is particularly effective in terms of polypropylene homopolymer and copolymer,
10 Tertiary combination 3 is particularly effective in terms of polyethylene.
In combinations of binary hindered amine light stabilizers, the weight:weight ratio is from about 19:1 to about 19:1, from about 17:1 to about 17:1, from about 15:1 to about 15:1, from about 1 :13 to about 13:1, from about 1:11 to about 11:1 or from about 1:9 to about 9:1, for example with ratios of about 1:10, about 1:8, about 1:7, about 1 :6, ca
15 1:5, about 1:4, about 1:3, about 1:2, about 1:1, about 2:1, about 3:1, about
<p dir="rtl">4:1, about 5:1, about 6:1, about 7:1, about 8:1 or about 10:1 and ratios between them. In tertiary amine-immobilized light stabilizer combinations, the weight:weight ratios of any two amine-impeded light stabilizers are the same as for binary combinations.</p>
Advantageously, a combination of low molecular weight and high molecular weight amine-blocking light stabilizers.
<p dir="rtl">20 Low molecular weight stabilizers have a molecular weight from about 200 g/mol to about 1000 g/mol. High molecular weight stabilizers have a molecular weight from about 1,200 g/mol to about 10,000 g/mol.</p>
Suitable hindered amines with low molecular weight are (1)-(33a). High molecular weight hindered amines are (34)-(49).
<p dir="rtl">25 Oligomeric or polymeric amine, the repeating unit “n” is a value such that the average molecular weight is from about 1,200 g/mol to about 10,000 g/mol.</p>
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Instructively, a combination of a high- and low-molecular-weight hindered amine compound with a UV absorber is used, such as the UV absorber hydroxybenzoate. Also the subject of the invention is a polyolefin composition that includes a polyolefin substrate embedded in it (a) a substance hydroxybenzoate that absorbs ultraviolet light
and absorber 5
b) A high-molecular-weight hindered amine compound and a low-molecular-weight hindered amine compound.
Light stabilizers with hindered amines are present, in aggregate, in an amount from about 0.10 to about 1.9% by weight, depending on the weight of the polyolefin substrate. Preferably from about 0.15 to about 1.5 wt%. For example, amine light stabilizers are present by about 0.2, about 0.3, about
<p dir="rtl">10 0.4, about 0.5, about 0.6, about 0.7, about 0.8, about 0.9, about 1.0, about 1.1,</p>
About 1.2, about 1.3 or about 1.4 wt%, depending on the weight of the polyolefin substrate and at levels in between.
Antioxidants selected from the group of hindered phenolic antioxidants, organic phosphorus 15 stabilizers, dialkylhydroxylamine stabilizers, stabilizers
amine oxide stabilizers and tocopherols. Antioxidants are preferably a combination of an organic phosphorus stabilizer and a hindered phenolic antioxidant, a dialkylhydroxylamine stabilizer, a combination of an organophosphorus stabilizer and a 20-dialkylhydroxylamine stabilizer, or an amine oxide stabilizer. A combination of an organophosphorus stabilizer and an amine oxide stabilizer.
Existing antioxidants also include vitamin E and vitamin E acetate (tocopherols). Each can be used alone, in combination with each other or in combination with one or more antioxidants selected from the group of 25 phenolic antioxidants that impair phenolic antioxidants. hindered phenolic antioxidants, dialkylhydroxylamine stabilizers
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dialkylhydroxylamine stabilizers, organophosphorus stabilizers and amine oxide stabilizers
.oxide stabilizers
Well-known organophosphorous stabilizer compounds, for example, are phosphite and phosphonite stabilizers, which include triphenyl phosphite, and di-phosphate compounds.
5 Diphenyl alkyl phosphites, phenyl dialkyl phosphites, tris(nonylphenyl) phosphite, trilauryl phosphate, trioctadecyl phosphate, distearyl pentaerythritol diphosphate pentaerythritol diphosphite, Tris(2,4-di-tert-butylphenyl) phosphite, bis(2,4-di-α-cumyl)
10 Phenyl(pentaerythritol diphosphate bis(2,4-di- -cumylphenyl) pentaerythrtitol
diphosphite, diisodecyl pentaerythritol diphosphite, bis(2,4-di-tert-butylphenyl) pentaerythritol diphosphate -bis(2,4-di D( tert-butylphenyl) pentaerythritol diphosphite(, bis) 2,6-Di-tert-butyl-4-methylphenyl pentaerythritol diphosphate (bis(2,6-di-tert-butyl-4-methylphenyl)
15 E(pentaerythritol diphosphite), biisodecyl oxy-pentaerythritol diphosphate
bisodecyloxy-pentaerythritol diphosphite, bis)2,4-di-tert-butyl-6-methyl
bis(2,4-di-tert-butyl-6-methylphenyl) pentaerythritol phenyl(pentaerythritol diphosphate)
diphosphite, bis tri-tert-butylphenyl (2,4,6-bis tri-tert-butylphenyl) pentaerythritol diphosphite, tris-tearyl sorbitol diphosphate
20 tristearyl sorbitol triphosphite, tartar cyst (2,4-di-tart-butylphenyl) 4,4'-bay
tetrakis (2,4-di-tert-butylphenyl) 4,4'-biphenylene-phenylene-diphosphonate
6 (H) diphosphonite-isooctyloxy-2,4,8,10-t-t-t-butyl-dibenzo[1,3,2][f,d]dioxaphosphbene 6--isooctyloxy-2,4, 8,10-tetra-tert-butyl
6 (C) dibenzo[d,f][1,3,2]dioxaphosphepin-fluoro-2,4,8,10-ttr-butyl-12
25 Methyl-dibenzo[1,3,2[]g,d[dioxaphosphosine 6--fluoro-2,4,8,10-tetra-tert-butyl A) 12-methyl-dibenzo[d,g][1 ,3,2]dioxaphosphocin(,bis)2,4-di-tert-butyl-6-
٦٣٧٤
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10
Methylphenyl(methyl phosphate bis(2,4-di-tert-butyl-6-methylphenyl) methyl phosphate, bis)2,4-di-tert-butyl-6-methylphenyl(ethyl phosphate-6-bis(2, 4-di-tert-butyl 2,'2,2,)G(methylphenyl)ethyl phosphite"-nitrilo[t-triethyl tris)3,3'5,5'-tetra-tert-butyl-1,1' -Biphenyl-2,2'-diyl(phosphate[2-"2,'2,
nitrilo[triethyltris(3,3'5,5'-tetra-tert-butyl-1,1'-biphenyl-2,2'-diyl) phosphate]
(B), bis(2,4-di-t-butylphenyl) octyl phosphate (bis(2,4-di-t-butylphenyl)
octylphosphite, poly(4,4'-}2,2'-dimethyl-5,5'-di-t-butylphenylsulfide- {octylphosphate) (, poly(4,4'- {2,2'- dimethyl-5,5'-di-t-butylphenylsulfide- {octylphosphite poly)4,4'}-isopropyldienediphenol{-octylphosphate(-}'4,4)poly
(isopropylidenediphenol}-octylphosphite, poly)4,4'-}isopropylidene bis]2,6-di
poly(4,4'-{isopropylidenebis[2,6-dibromophenol]}-)bromophenol[{-octyl phosphate]
(octylphosphite, poly)4,4'-}2,2'-dimethyl-5,5'-di-t-butylphenylsulfide{-penta
Erythrityl diphosphate (-{poly(4,4'- {2,2'-dimethyl-5,5'-di-t-butylphenylsulfide)
pentaerythrityl diphosphite,
)B(
<img file="SA6374B1_D0027.tif" />
<img file="SA6374B1_D0028.tif" />
15
<img file="SA6374B1_D0029.tif" />
٦٣٧٤
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<img file="SA6374B1_D0030.tif" />
C(CH3)3
<img file="SA6374B1_D0031.tif" />
3
HC
<img file="SA6374B1_D0032.tif" />
)H(
)And the(
<img file="SA6374B1_D0033.tif" />
O
<sup>POC</sup>18<sup>H</sup>37
O
<img file="SA6374B1_D0034.tif" />
(g)
<img file="SA6374B1_D0035.tif" />
(h)
<img file="SA6374B1_D0036.tif" />
<img file="SA6374B1_D0037.tif" />
(k) f
٦٣٧٤
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<img file="SA6374B1_D0038.tif" />
Organic phosphorus stabilizers are also liquid stabilizers as disclosed in US Publication No. 048782/2010 and US Patent No. 7,888,414, for example liquid phosphate compounds P-3, P-2 and P-4. . Done too
5 Disclosure of suitable organophosphorus stabilizers in American publications
0225736/2013 and 0029844/2010 and US Patent Nos. 7468410
And 8,304,477.
Hindered phenolic antioxidants include, for example, tris(3,5-di-tert-butyl-4-hydroxybenzyl) isocyanurate-4-tris(3,5-di-tert-butyl).
10 1,3,5-hydroxybenzyl)isocyanurate-tris-)3,5-di-tert-butyl-4-hydroxy
Benzyl(-2,4,6-t-trimethylbenzene-(1,3,5-tris-(3,5-di-tert-butyl-4-hydroxybenzyl)
2,4,6-trimethylbenzene, the calcium salt of the monoethyl ester of 3,4-,5-di-tert-butyl hydroxybenzylphosphonic acid, pentaerythritol tartar cyst [3-)3,5-di-tart-butyl-4-
pentaerythritol tetrakis [3-(3,5-di-tert-butyl-4-]15 hydroxyphenyl) propionate
hydroxyphenyl) propionate] or octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate. An organophosphorous stabilizer combination. A hindered phenolic antioxidant, specifically tris(2,4-di-tert-butylphenyl) phosphate.
20 butylphenyl) phosphate and pentaerythritol tartar cyst [3-)3,5-di-tart-butyl-4-
pentaerythritol tetrakis [3-(3,5-di-tert-butyl-4- [hydroxyphenyl)propionate]
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[hydroxyphenyl) propionate] or octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate. Rate weight: weight From an organophosphorus stabilizer to a neutralized phenolic antioxidant in an amount from about 9:1 to about 1:9 and ratios between them, for example about 8:1, about 7:1, about 6:1, about 5:1,
5 About 4:1, About 3:1, About 2:1, About 1:1, About 1:2, About 1:3, About 1:4, About 1:5, About 1:6, About 1:7 or About 1:8 and ratios between them.
Hydroxylamine stabilizers are an example of N,N-dibenzylhydroxylamine N,N,N-dibenzylhydroxylamine-diethylhydroxylamine -N,NN,N,diethylhydroxylamine-dioctylhydroxylamine N,N-dioctylhydroxylamine,
10 N,N-dilaurylhydroxylamine N,N,N,N-dilaurylhydroxylamine-didodecyl
Hydroxylamine N,N,N,N-didodecylhydroxylamine-ditetradecylhydroxylamine N,N,N,N-ditetradecylhydroxylamine-dihexadecylhydroxylamine -N,N
N,N,dihexadecylhydroxylamine-dioctadecylhydroxylamine-N,N
N,dioctadecylhydroxylamine-hexadecyl-N-tt-r-decylhydroxylamine-N
15 N,hexadecyl-N-tetradecylhydroxylamine-hexadecyl-N-heptadecylhydroxylamine
N,N-hexadecyl-N-heptadecylhydroxylamine-hexadecyl-N-octadecylhydroxylamine N-hexadecyl-N-octadecylhydroxylamine,N-heptadecyl-N-octadecylhydroxylamine N,N-heptadecyl-N-octadecylhydroxylamine-methyl-N -octadecylhydroxylamine N-methyl-N-octadecylhydroxylamine or preferably N,N-di (C16-)
20 C<sub>1</sub>8 Alkyl(hydroxylamine N,N-di(C).<sub>1</sub>6-C<sub>1</sub>8alkyl)hydroxylamine.
An example of an amine oxide stabilizer is Di(C).<sub>1</sub>8-C<sub>1</sub>6) Alkyl methyl amine oxide CAS# 204933-93-7, di(C)<sub>1</sub>6-C<sub>1</sub>8) alkyl methyl amine oxide.
A combination of an organophosphorus stabilizer and dialkylhydroxylamine, specifically tris(2,4-di-tert-butylphenyl) phosphite.
25 The N,N-day (C<sub>1</sub>8-C<sub>1</sub>6 Alkyl(hydroxylamine N,N-di(C).<sub>1</sub>6-C<sub>1</sub>8alkyl)hydroxylamine.
٦٣٧٤
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A combination of an organophosphorus stabilizer and an amine oxide stabilizer, specifically tris(2,4-di-tert-butylphenyl) phosphate and di(C).<sub>1</sub>8-C<sub>1</sub>6) Alkyl methyl amine di(C).<sub>1</sub>6-C<sub>1</sub>8) alkyl methyl
amine oxide
Weight ratios: The weight of these two combinations is as shown above for the combination of 5 organic phosphorus compounds/impeded phenolic antioxidant.
Antioxidants are present, in aggregate, from about 0.05 to about 1.0% by weight, depending on the weight of the polyolefin substrate. Preferably from about 0.10 to about 0.75 wt%. For example, antioxidants are present in amounts of about 0.20, about 0.30, about 0.40, about 0.50, about 0.60, about 0.70, about 0.80, about 0.90 or about 1.0% by weight, based on the weight of the 10 polyolefin substrate and at levels in between.
Coloring materials preferably selected from the group consisting of organic pigments and non-organic pigments
Pigment Handbook, Organic TC and mixtures thereof. Suitable examples can be found in any of the commercial dyes in use. Patton, Ed., Wiley-Interscience, New York, 1973.
15 in polymer-based products that are used in existing formulations: metallic oxides, such as titanium dioxide, zinc oxide,
Aluminum oxide and iron oxide, metal hydroxide, metal flakes, such as aluminum flake, chromates, such as lead chromate, sulfides, sulfates, carbonates, carbon black black, 20 bismuth vanadate, silica, talc, china clay, blue and green colors
Phthalocyanine, organic red colours, organic brown colours, pearlescent pigments
And other organic pigments. When needed, chromate-free dyes can also be used, such as barium metaborate, zinc phosphate, aluminum triphosphate, and mixtures thereof.
25 Some useful pigments include CI pigments: Black 12, Black 26, Black 28, Black 30, Blue 15.0, Blue 15.3 (G), Blue 15.3 (R), Blue 28, Blue 36, Blue 385, Brown
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24, Brown 29, Brown 33, Brown 10P850, Green 7 (Y), Green 7 (B), Green 17, Green 26, Green 50, Purple 14, Purple 16, Yellow 1, Yellow 3, Yellow 12, Yellow 13, Yellow 14, Yellow 17, Yellow 62, Yellow 74, Yellow 83, Yellow 164, Yellow 53, Red 2, Red 3 (Y), Red 3 (B), Red 4, Red 48.1, Red 48.2, Red 48.3, Red 48.4 ,
5 Red 52.2, Red 49.1, Red 53.1, Red 57.1 (Y), Red 57.1 (B), Red 112, Red 146, Red 170 (F5RK type) Blue, Tint Orange 5.CI, Tint Orange 13, Tint Orange 34, Tint Orange 23 (R), and Orange 23 (B). Some useful organic pigments include: Orange Pigment 151, Pigment Orange 154, Pigment Orange 155, Pigment Red 8, Pigment Red 8, Pigment Red 49.2, Pigment Red Ham 81, pigment Ham 169, blue dye
10 1, violet dye 1, violet dye 3, violet dye 27, red dye 122, dye
Violet 19. Some useful inorganic pigments include Lemon Chrome, Middle Chrome, Scarlet Chrome, Prime-Rose Chrome, Chrome, and Zinc Chromate.
Preferably, current organic dyes are selected from the group consisting of phthalocyanines, perylenes, azo compounds, and
15 Isoindolines, quinophthalones, diketopyrrolopyrroles, qyinacridones, dioxazines and indanthrones. Blue pigments, for example, are indanthrones and copper phthalo-cyanine classes, such as blue 60, blue 15:1, blue 15:3, blue 15:4 and blue 15:6. Example of green pigments from the copper phthalocyanine class.
20 Example green dye 7 and green dye 36. Purple dyes Example from the quinacridone class, example 2,9-dichloroquinacridone2,, red dye 202. Red pigments Example from the quinacridone class, example dimethyl dimethyl quinacridone, 122 perylene dye, for example 149 perylene dye, 178 perylene 178 dye, or 179 diketopyrrole dye.
25 diketopyrrolopyrrole, example of red pigment 254 and red pigment 264. Examples of yellow pigments from the classes pteridine, isoindolinone, and isoindoline.
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Example: Pigment 115, Pigment 110, Pigment 139. Orange pigments are in the iso-indolenon or diketopyrrolopyrrole class. Example are pigment Orange 61, Pigment orange 71, and Pigment orange 73. Violet pigments are an example in the Quena cridone class. Example: violet dye 19 or from the dioxazine class, example violet dye 23 or dye
5 Violet 37. Advantageously, dye mixtures may be used.
Coloring agents are present, in aggregate, from about 0.10 to about 3.0% by weight, depending on the weight of the polyolefin substrate. Preferably from about 0.2 to about 1.0 wt%. For example, coloring agents are present in levels of about 0.3, about 0.4, about 0.5, about 0.6, about 0.7, about 0.8 or about 0.9 wt%, depending on the weight of the polyolefin substrate and at levels in between.
10 Filling materials can be particles, fibres, organic or inorganic.
Specific organic fillers include wood powder, cork, walnut shells, starch, polymers, carbon, and proteins.
Filling materials may include natural or synthetic fibers from wood, lignin-free and semi-lignin-free cellulose, flax, jute, hemp, kennel, rice husk,
15 Abaca, wool, carbon, aramid fibres, nylons, polyesters and/or combinations thereof.
Specific inorganic fillers include glass, calcium carbonate, beryllium oxide, iron oxide, magnesia, magnesium carbonate, titanium dioxide, 20 zinc oxide, zirconia, hydrated alumina. hydrated alumina, antimony oxide
oxide, metal powders, silica, silicates, organo-nanoclays, clays, barium ferrite, silicon carbide and potassium titanate.
Fibrous inorganic fillers include glass, 25 mineral wool, calcium sulphate, potassium titanate, boron, alumina.
And metals.
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Inorganic filling materials also include alkali earth metal alkaloids of carboxylates or stearates sulfates. Preferably, inorganic filling materials include dolomite, silica, calcium carbonate, magnesium hydroxide, zinc borate, talcs (magnesium silcates), vermiculite, diatomite, perlite, Wallastonite, fly ash, kaolin clay, mica or various titanium dioxides, including processed titanium dioxide.
Preferably, the filling materials are calcium carbonate, 10 magnesium hydroxide, talc, and stunite or fly ash.
Filling materials are present, in aggregate, from about 5 to about 60 or about 70% by weight, depending on the weight of the polyolefin substrate. Preferably from about 10 to about 50 or from about 15 to about 40% by weight. Example fillers are present in the amount of about 10, about 20, about 25, about 30, about 35 or about 45% by weight, depending on the weight of the polyolefin substrate and at levels between them.
15 Suitable flame retardants include chlorinated flame retardants, brominated flame retardants, phosphorus-based flame retardants, metal hydroxide compounds, melamine-based compounds, and antimony compounds.
compounds, borate compounds, other flame retardants containing 20 metals and combinations thereof.
Chlorinated flame retardants are disclosed in US Patent Nos. 6,472,456, 5,393,812, 7,230,042, and 7,786,199. Chlorinated flame retardants are, for example, tris(2-chloroethyl) phosphite, bis-(hexachlorocycloentadeno) cyclooctane, tris(1-chloro-2-
25 Propyl(tris(1-chloro-2-propyl)phosphate, tris(2-chloroethyl)phosphate, bis(2-chloroethyl)vinyl phosphate
٦٣٧٤
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phosphate, hexachlorocyclopentadiene, tris(chloropropyl)phosphate, tris(2-chloroethyl(phosphate-2)trischloroethyl)phosphate, tris(chloropropyl)phosphate, biphenyl compounds Treated with polychlorinated biphenyls, mixtures of chloroethyl compounds
5 Monomeric chloroethyl phosphonates and high boiling phosphonates, tris (2,3-dichloropropyl)phosphate, chlorendic acid, tetrachlorophthalic acid, poly-- mixture. Chloroethyltriphosphonate poly--chloroethyl triphosphonate, bis)hexachlorocyclopentadieno(cyclooctane)
10 DECLORANE PLUS( bis(hexachlorocyclopentadieno)cyclooctane), arvin compounds
Treated with chlorinated paraffins and hexachlorocyclopenta-diene derivatives
.hexachlorocyclopentadiene derivatives
Brominated flame retardants include tetrabromobisphenol A (TBBPA) and its derivatives such as esters, ethers, and oligomers.
15 Examples of tetrabromophthalate ester compounds, bis(2,3-dibromopropyl oxy(tetra-dibromopropyloxy)tetrabromobisphenol AA, brominated carbonate oligomers based on bromobisphenol A tartar, OligoArt epoxy treated with brominated epoxy oligomers based on the condensation of bromo-tatar bisphenol A and epichlorohydrin, and co-polymers from Tatar.
20 Bromobisphenol A and 1,2-dibromoethane; Dibromobenzoic acid, dibromostyrene (DBS) and its derivatives; ethylenebromobistetrabromophthalimide, dibromoneopentyl glycol, dibromocyclooctane, trisbromoneopentanol, Tris ari promo vinyl( Tari Azin
25 2,3-tris(tribromophenyl)triazine-dibromopropanol 3-dibromopropanol2,, tris
Tribromoaniline, Tribromophenol, Tribromophenol, Tribromocyclopentane
٦٣٧٤
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tetrabromocyclopentane, tetrabromobiphenyl ether, tetrabromodipentaerythritol, decabromodiphenyl ether, tetrabromophthalic anhydride, pentabromotoluene, pentabromodiphenyl ether modiphenyl ether
<p dir="rtl">5 pentabromodiphenyl oxide, pentabromophenol</p>
pentabromophenol, pentabromophenyl benzoate, pentabromoethylbenzene, hexabromocyclohexane, hexabromocyclooctane, hexabromocyclodecane, hexabromocyclododecane hexabromocyclododecane, hexa
<p dir="rtl">10 Hexabromobenzene, hexabromobiphenyl, octabromobiphenyl, octabromodiphenyl oxide, poly(pentabromobenzyl acrylate), octabromodiphenyl ether, decabromodiphenyl E Second decabromodiphenyl ethane, decabromodiphenyl, brominated trimethylphenyl indane</p>
<p dir="rtl">15 trimethylphenylindan, tetrabromochlorotoluene, bis(tribromophenoxy)ethane, brominated polystyrene, brominated epoxy oligomer, polypentabromobenzyl acrylate, dibromopropylacrylate, dibromopropylacrylate</p>
<p dir="rtl">20 Bromohexachlorocyclopenta dienocyclooctane</p>
N',dibromohexachlorocyclopentadienocyclooctane-ethyl(bis(dibromonorboranedicarboximide) N'-ethyl(bis)dibromononboranedicarboximide, tarbromo bisphenol S
N'N', tetrabrombisphenol S-ethyl bis)dibromononbornene(dicarboximide -'N'N ethylbis(dibromononbornene)dicarboximide, hexachlorocyclopentadiino-bis-
25 (2,3-Dibromo-1-propyl(phthalate-1-hexachlorocyclopentadieno- bis-(2,3-dibromo)
<p dir="rtl">Propyl)phthalate, brominated phosphates such as Bis)2,3-</p>
٦٣٧٤
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Dibromopropyl phosphate bis(2,3-dibromopropyl)phosphate and tris(bis(2,3-dibromopropyl)phosphate)
Tris(tribromoneopentyl)phosphate and tris(dichlorobromopropyl) phosphate, N',N,tris(dichlorobromopropyl) phosphite- ethylene-bis-)tetrabromophthalamide (-'N,N ethylene-bis-(tetrabromophthalimide), acid tetrabromophthalic acid
[diol[2-hydroxypropyl-oxy-2-2-hydroxyethyl-ethyltetrabromophthalate, vinylbromide, polypentabromobenzyl acrylate, brominated polybrominated dibenzo-p-dioxins, Tris-] 2,3-Dibromopropyl(tris-(2,3-dibromopropyl)-isocyanurate, ethylene-10-bis-tetrabromophthalimide and tris)2,3-dibromopropyl
Propyl tris(2,3-dibromopropyl)phosphate.
Suitable commercially available examples of brominated flame retardants include brominated polydiphenyl oxide (DE-60F), deca-bromodiphenyl
decabromodiphenyl oxide (decabromodiphenyl ether)
15 )DBDPO; SAYTEX® 102E), tris[3-bromo-2,2-bis)bromomethyl(propyl[phosphate]
PB 370®, FMC Corp. or FR (tris[3-bromo-2,2-bis(bromomethyl)propyl]phosphate
370, ICL / Ameribrom, tris (2,3-dibromopropyl)phosphate, tetrabromophthalic acid, bis-(N',N-hydroxyethyl(t-r-chlorophenylene) Diamine-'bis-(N,N
20 hydroxyethyl)tetrachlorphenylene diamine, tetrabromobisphenol A bis(2,3-dibromopropyl ether) (PE68), tetrabromobisphenol A bis(2,3-dibromopropyl ether), brominated epoxy resin, ethylene-bis(tetrabromopropyl ether). Phthalamide (ethylene SAYTEX® BT-93) bis(tetrabromophthalimide), octabromodiphenyl ether
<p dir="rtl">1,2-octabromodiphenyl ether-bis)tribromophenoxy(ethane-1,2)</p>
<p dir="rtl">25 FF680(bis(tribromophenoxy)ethane), tetrabromo-bisphenol AA</p>
<p dir="rtl">(SAYTEX® RB100), ethylene bis-(dibromo-norbornene dicarboximide)</p>
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SAYTEX® BN-451( bis-(dibromo-norbornanedicarboximide)(, tris-(2,3-dibromopropyl isocyanurate, hexabromocyclododecane), poly Brominated polystyrene and the EMERALD INNOVATION series from Chemtura, example EMERALD
INNOVATION 1000 5
The organobromine flame retardant is preferably decabromodiphenyl ether or tris[3-bromo-2,2-
Bis)bromomethyl(propyl[phosphate]tris[3-bromo-2,2-bis(bromomethyl)propyl
phosphate.
<p dir="rtl">10 Antimony trioxide (ATO) can be used, especially with existing halogenated flame retardant, i.e. brominated flame retardant. Combinations of antimony trioxide with decabromodiphenyl ether or Tris are preferred [3- Bromo-2,2-bis)bromomethyl(propyl[phosphate).</p>
.tris[3-bromo-2,2-bis(bromomethyl)propyl]phosphate
<p dir="rtl">15 Includes phosphorus-based flame retardants disclosed, for example, in US Publications Nos. 0220422/2003, 0005289/2014, 0257310/2011</p>
0005289/2014 and American struggle with 3966894, 4079035, 4107108, 4108805, 4174343, 4228063, 6265599, 6528559, 6740695, 7786199 and 8349925. Phosphorus-based fire retardants include 20 phosphazene compounds, triphenyl phosphates, phosphate esters, phosphonium derivatives, phosphonates, phosphoric acid esters, and phosphate esters. . Phosphorus-based flame retardants are typically formed from a phosphate core to which alkyl groups (generally 25 straight chain) or an aryl (aromatic ring) are attached. Examples include red phosphorous, non-containing phosphate compounds. Organic inorganic phosphates, non-ammonium phosphate
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insoluble ammonium phosphate, ammonium polyphosphate, ammonium urea polyphosphate, ammonium orthophosphate, ammonium carbonate phosphate, ammonium urea phosphate, diammonium phosphate
<p dir="rtl">5 diammonium phosphate, ammonium melamine phosphate, diethylenediamine polyphosphate, dicyanodiamide polyphosphate, polyphosphate, urea phosphate, melamine pyrophosphate, melamine orthophosphate, salt Melamine salt from dimethyl methylphosphonate</p>
<p dir="rtl">10 dimethyl methyl phosphonate, melamine salt of dimethyl hydrogen phosphate, ammonium salt of boron-polyphosphate, urea salt of dimethyl methyl phosphonate, organophosphates, phosphonates and phosphine oxide oxide. Phosphate esters include, for example, trialkyl derivatives</p>
<p dir="rtl">15 Derivatives, such as triethyl phosphate, tris(2-ethylhexyl)phosphate, trioctyl phosphate, triaryl derivatives, such as triphenyl phosphate, and cresyldiphenyl phosphate.</p>
<p>- Aryl tricresyl phosphate and derivatives of cresyl diphenyl phosphate</p>
Alkyl alkyl compounds, such as 2-ethylhexyl-20 diphenyl phosphate, dimethyl- aryl phosphates, octylphenyl phosphate, and ethylene diamine compounds.
.phosphates
Examples of other phosphorus-based flame retardants include resorcinol-bis-diphenylphosphate, guanidine phenylphosphonate
25 phenylphosphonate, melamine phenylphosphonate, dimethyl
Dimethylaluminium phosphinate, methyl-ethyl aluminum phosphinate
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methyl-ethylaluminiumphosphinate, diethyl aluminum phosphinate
diethylaluminiumphosphinate, poly-[2,4-(piperazine-1,4-yl(-6-morpholine-4-yl(-1,3,5-taryazine)] -poly-[2,4-(piperazine-) 1,4-yl)-6-morpholine-4-yl)-1,3,5-triaz[ine, aluminum polyphosphate, methylaminoboron-phosphate
5 methylamine boron-phosphate, cyanuramide phosphate, magnesium phosphate, ethanolamine dimethyl phosphate, pentaerythritol-di-methylphosphonate, cyclic phosphonate ester, trialkyl phosphonates , potassium ammonium phosphate, cyanwarmide
10 Cyanuramide phosphate, aniline phosphate, tris(1-aziridinyl)phosphine oxide, tris(1-aziridinyl)phosphine
oxide, bis)5,5-dimethyl-2-thiono-1,3,2-dioxaphosphorinamyl)oxide, bis)5,5-dimethyl-2-thiono-1,3,2-dioxaphosphorinamyl)oxide Methylphosphono-N
dimethylphosphono-N-hydroxymethyl-3- hydroxymethyl-3-propionamide
<p dir="rtl">15 Propionamide, tris(2-butoxyethyl)phosphate, tartar salts</p>
tetrakis(hydroxymethyl)phosphonium salts, such as tartar
tetrakis(hydroxymethyl)phosphonium chloride sachet)hydroxymethyl(phosphonium chloride).
Tetrakis(hydroxymethyl)phosphonium sulfate
<p dir="rtl">N,sulfate-hydroxymethyl-3-(dimethylphosphono(-propionamide-3-n-hydroxymethyl)</p>
20 dimethylphosphono-propionamide), a melamine salt of boron-poly
boron-polyphosphate, ammonium salt of boron-polyphosphate, triphenyl phosphate, ammonium dimethyl phosphate, melamine orthophosphate, ammonium urea phosphate, ammonium melamine phosphate, melamine salt from
25 Dimethyl methyl phosphonate, melamine salt of dimethyl hydrogen phosphate and the like.
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Metal hydroxide fire retardants include inorganic hydroxides, such as aluminum hydroxide, magnesium hydroxide, aluminum trihydroxide (ATH), and hydroxycarbonate.
5 Melamine-based flame retardants are a family of non-halogenated flame retardants that include three chemical groups: (a) melamine (2,4,6-triamino-1,3,5-triazine) 4,6-triamino-1,3,5 triazine; (b) Melamine derivatives (including salts of organic or inorganic acids, such as boric acid, cyanuric acid, phosphoric acid, or pyro/poly-acid). Phosphoric(
10 pyro/poly-phosphoric acid; and (c) melamine homologues. Melamine derivatives include, for example, melamine cyanurate (salt of melamine and cyanuric acid), melamine-mono-phosphate (salt of melamine and phosphoric acid), melamine pyrophosphate Melamine polyphosphate analogues include melamine (1,3,5-triazine-2,4,6-triamine-4,6)-N-di.
15 Amino-1,3,5-triazin-2-yl(-4,6)-melam (1,3,5-triazin-2,4,6-triamine-n)
(diamino-1,3,5-triazine--2-yl,myl)2,5,8-tri-amino b1,3,4,6,7,9,9-hepta-azine
<p>-8[Polymelon (2,5,8-triamino 1,3,4,6,7,9,9b-heptaazaphenalene)</p>
Amino-b1,3,4,6,7,9,9-Hepta-Azphenalen-2,5-Diyl(-melon) (poly[8-amino)
1,3,4,6,7,9,9b-heptaazaphenalene-2,5-diyl)
<p dir="rtl">20 Melamine-based flame retardants are also a condensation product of melamine compound/polyol compounds. For example, as disclosed in U.S. Application No. 539097/10 (International Publication No. 055029/2004) and U.S. Publication No.</p>
152376/2010, where the polyol is a linear, branched, or cyclic alcohol, trihydric, tetrahydric, pentahydric, or hexahydric.
<p dir="rtl">25 Or a linear or cyclic C4-C6 aldose, or a C4-C6 ketose, where the melamine compound is melamine phosphate, melamine pyrophosphate, or melamine.</p>
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Polyphosphate. The polyol is preferably pentaerythritol or dipentaerythritol. The melamine compound is preferably melamine phosphate. The molar ratio of melamine to polyol is preferably from about 1:1 to about 4:1. The condensation product can also incorporate a dendrimer polymer substituted by hydroxy groups
<p dir="rtl">5 hydroxy groups, such as dendritic polyester or dendritic polyamide. Preferably denatured polyester is the product of a starting compound selected from the group consisting of trimethyolpropane, pentaerythritol, ethoxylated pentaerythritol, and chain-extending dimethylpropionic acid. Preferably wrinkled polyamide</p>
<p dir="rtl">10 It is a polycondensation product of cyclic carboxylic acid anhydride and diisopropanolamine.</p>
Borate's flame retardant compounds include zinc borate, borax (sodium borate), ammonium borate, and calcium borate. Zinc borate is a boron-based fire retardant with a chemical composition
<p dir="rtl">15 xZnOyB2O3zH2O. Zinc borate can be used alone, or in combination with other chemical compounds, such as alumina trihydrate, magnesium hydroxide, or red phosphorus. It works through zinc halide or zinc oxyhalide, which accelerate the decomposition of halogen sources and promote the formation of char.</p>
<p dir="rtl">20 Examples of other minerals that contain flame retardants, which may be used alone or in combination with other flame retardants, include, but are not limited to, magnesium oxide, magnesium chloride, talcum, and alumina. hydrate, zinc oxide, alumina trihydrate, alumina magnesium, calcium silicate, sodium silicate</p>
<p dir="rtl">25 sodium silicate, zeolite, sodium carbonate, calcium carbonate, ammonium molybdate, iron oxide,</p>
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Copper oxide, zinc phosphate, zinc chloride, malt, sodium dihydrogen phosphate, tin, molybdenum and zinc.
Polytetrafluoroethylene (PTFE) has also been mentioned as an anti-dry agent5 which can provide additional flame retardation to the formulation.
Silicone-based materials are included as linear or branched chain type silicone with or without reactive functional (saturated hydrocarbons).
Suitable flame retardants include those of US Patent Applications No. 10 739842/61 and 835893/61, International Publication No. 099397/2014. Example combination of one or
More bismuth compounds selected from the group consisting of bismuth oxychloride, bismuth oxyfluoride, bismuth oxybromide, bismuth oxyiodide, bismuth oxynitrate and one or more organobromine flame retardants
.organobromine flame retardants 15
Preferably, the flame retardant is melamine polyphosphate, pentaerythritol-di-methylphosphonate, ammonium polyphosphate or melamine phosphate condensate and pentaerythritol.
.pentaerythritol
<p dir="rtl">20 Flame retardants exist, in aggregate, from about 0.5% to about 70% by weight, depending on the weight of the polyolefin substrate, preferably from about 1% to about 50% by weight or more preferably from about 1% to about 40% by weight or from About 15% to about 50% by weight, based on the weight of the polyolefin substrate. Flame retardants are available at levels of about 3, about 5, about 7, about 9, about 11, about 13, about 15, about 17, about 19, about 21, about 23,</p>
<p dir="rtl">25 About 25, about 27, about 29, about 31, about 33, about 35, about 37 or about</p>
39 % by weight, based on the weight of the polyolefin substrate and at levels between them.
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Suitable antimicrobial compounds are disclosed in US Publication No. 0306183/2008.
An example of antimicrobial compounds is o-benzyl-phenol-2, o-benzyl-phenol-benzyl-4-chloro-phenol 2,4,4,-benzyl-4-chloro-phenol2'-trichloro-2'-hydroxy. Dey
5 Phenyl ether 4,4,4,4'-trichloro-2'-hydroxydiphenyl ether2'-dichloro-2-hydroxydiphenyl ether 5,4,4'-dichloro-2-hydroxydiphenyl ether4-chloro-2-hydroxydiphenyl ether Phenyl-methane chloro-2-hydroxy-diphenyl-methane5-, mono-chloro-o-benzyl -phenol
2,2-mono-chloro-o-benzyl-phenol'-methylenebis-(4-chloro-phenol) 2-'2,
(methylenbis-(4-chloro-phenol) or 2,4,6-trichlorophenol.,4,6-trichlorophenol2
10 Suitable inorganic antimicrobial compounds are selected from the group consisting of zinc oxide, copper and copper compounds, colloidal silver, silver nitrate, silver sulphate, silver chloride, and silver complexes. Metal-containing zeolites, metal-containing zeolites.
15 Surface rate.
Mineral-containing zeolite compounds are those described in U.S. Patent Nos. 4,775,585, 4,911,898, 4,911,899, 6,071,542 or 6,585,989.
Preferably, the antimicrobial compounds include a form of silver, e.g. a silver compound, a silver dispersion or supported silver (e.g. silver supported on zeolite or on glass), elemental silver
20 elemental silver, nano- or micro-sized elemental silver, elemental silver dispersed in silicone oil (polymethyldisiloxane), silver chloride, silver nitrate, silver sulfate, silver phosphate, silver zirconate, or silver apatite
.silver apatite
Antimicrobials are also an example, such as 3,5-dimethyl-tetrahydro-1,3,5-25H2-thiodiazin-2-thione and 5-dimethyl-tetrahydro-1,3,5-2H-thiodiazin-2. -thione3,,
Bis-tributyltinoxide-4,5-bis-tributyltinoxide-dichlor-2-N-octyl-4-iso
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Thiazolin-3-one N,,5-dichlor-2-n-octyl-4-isothiazolin-3-one4-butyl-benzisothiazoline 10,10,N-butyl-benzisothiazoline'-oxybisphenoxyarsine -'10,10 oxybisphenoxyarsine, zinc-2-pyridinthiol-1-oxide, zinc-2-pyridinthiol-1-oxide, 2-methylthio-4-cyclopropylamino-6-)ß,α-dimethylpropylamino(-s-tari) Azin 2
5 2,methylthio-4-cyclopropylamino-6- -dimethylpropylamino)-s-triazine-methyl
Thio-4-cyclopropylamino-6-tart-butylamino-s-taryazine 2-4-methylthio-
-6- or 2-methylthio-4-ethylamino cyclopropylamino-6-tert-butylamino-s-triazine
)ß,α-dimethylpropylamino(-s-taryazine 2- -6-methylthio-4-ethylamino-
2,4,4-dimethylpropylamino)-s-triazine'-trichloro-2'-hydroxydiphenyl ether
10 3,,4,4'-trichloro-2'-hydroxydiphenyl ether2-iodidine-2-propenyl-butylcarbamate 3-
Or idodine-2-propenyl-butylcarbamate (IPBC)
iodopropynyl butylcarbamate, carbendazim or thiabendazole.
Antimicrobials are present from about 0.001 wt% to about 5.0 wt%, preferably from about 0.01 to about 4.0 wt%, depending on the weight of the polyolefin substrate.
15 More preferably from about 0.02 to about 2.0 wt%. For example, an antimicrobial exists at weight levels of about 0.05, about 0.10, about 0.20, about 0.30, about 0.40, about 0.50, about 0.60, about 0.70, about 0.80, about 0.90, about 1.0, about 1.1, about 1.2, about 1.3, About 1.4, about 1.5, about 1.6, about 1.7, about 1.8 or about 1.9 wt%, depending on the weight of the polyolefin substrate, and levels in between.
20 Additives can also be present in innovative formulations. Additives can also be from about 0.1 wt% to about 10 wt%, depending on the polyolefin substrate. Preferably from about 0.2 to about 5.0 wt%, based on the weight of the polyolefin substrate.
Additives also include benzofuranone stabilizers, such as those disclosed in US Patent Nos. 4325863, 4338244, 5175312,
25 5216052, 5252643 5369159 5356966 5367008 5428177 or 5428162 or
US Publication No. 0238677/2012 or 3-[4-(2-acetoxyethoxy)phenyl]-5,7-di
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-[4-(2-acetoxyethoxy)phenyl]-5,7-di-tert-butyl-3 tert-butyl-benzofuran-2-one-
5-,7-di-tert-butyl-3-[4-(2-stearoyloxyethoxy)phenyl]benzofuran-2-one-di-tert-butyl-3-[ 4-(2-stearoyloxyethoxy)phenyl]benzofuran 3,3,2-one'-bis]5,7-di-tert-butyl-3-)4-[2-hydroxyethoxy]phenyl(benzo
5 Furan-2-one[3-,3'-bis[5,7-di-tert-butyl-3-(4-[2-hydroxyethoxy]phenyl)benzo
[5,7-furan-2-one-di-tert-butyl-3-)4-ethoxyphenyl(benzofuran-2-one-5-7-di, 4(-3) tert-butyl-3-(4) -ethoxyphenyl)benzofuran-2-one-acetoxy-3,5-dimethylphenyl(-5,7-di-tert-butyl-benzofuran-2-one 3--(4-acetoxy-3,5-dimethylphen 3) 5(-3,yl)-5,7-di-tert-butyl-benzofuran-2-one-dimethyl-4-pivaloyl oxy
10 Phenyl(-5,7-di-tert-butyl-benzopho-arn-2-one-3-(3,5-dimethyl-4-pivaloyloxyphen 3,4(-3,yl)-5,7-di-tert) -butyl-benzofuran-2-one-dimethylphenyl(-5,7-di-tart-
-(3,4-dimethylphenyl)-5,7-di-tert-butyl-benzofuran-2-3 butyl-benzofuran-2-one
2(-3-one-acetyl-5-isooctylphenyl(-5-isooctylbenzofuran-2-one 3-2)-acetyl-5-isooctylphenyl)-5-isooctylbenzofuran-2-one and 3-)2, 3-Dimethylphenyl(-
15 5,7-Di-tert-butyl-benzofuran-2-one-3--(2,3-dimethylphenyl)-5,7-di-tert
butyl-benzofuran-2-one. Benzofuranone stabilizers were also disclosed in US Patent Nos. 8653284, 7601853 and 7390912 and US Publication No.
238677/2012.
Additives also include antistatic agents, antistatic agents
<p dir="rtl">20 Antiscratch agents, slip agents, polymer processing aids and the like. Additives also include mineral salts of fatty acids, such as calcium, magnesium, zinc or aluminum.</p>
stearate. Additives also include thio synergists, such as dilauryl thiodipropionate or distearyl thiodipropionate.
<p dir="rtl">25 Suitable acrylic processing aids include all or partial acrylic processing aids such as Dow 125 PARALOID K. Methods have been mentioned</p>
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Acrylic aids, for example, are in US Publications Nos. 2009111915 and 2012189837 and in US Patent No. 8124664. Acrylic aids, for example, are copolymers made from a mixture of acrylic monomers, or copolymers made from an acrylic monomer, or a mixture of acrylic monomers. Acrylic with one or more monograms
<p dir="rtl">5 also. Copolymers are generally in powder form and have a molecular weight of, from about 500,000 to about 9,000,000.</p>
Monomeric acrylic or methacrylic esters include all monomeric acrylic or methacrylic esters wholly tertiary alkyl alcohols, with alkyl groups having from 1 to 20 carbon atoms or alternatively from 1 to 8 carbon atoms.
<p dir="rtl">10 carbon atoms. Acrylate monomers include, but are not limited to, methyl acrylate, ethyl acrylate, n-butyl acrylate, lauryl acrylate, 2-ethylhexyl acrylate, cyclohexyl acrylate. , iso-octyl acrylate</p>
acrylate, octadecyl acrylate, nonyl acrylate, decyl
<p dir="rtl">15 Decyl acrylate, isobornyl acrylate and dodecyl acrylate. Also useful are aromatic acrylates (e.g. benzyl acrylate). Suitable methacrylate monomers include, but are not limited to, methyl methacrylate, ethyl methacrylate, n-butyl methacrylate, and lauryl methacrylate. lauryl methacrylate</p>
20 2, methacrylate- ethylhexyl methacrylate2-, cyclohexyl
cyclohexyl methacrylate, iso-octyl methacrylate, octadecyl methacrylate, nonyl methacrylate, decyl methacrylate, isobornyl methacrylate, and dodecyl methacrylate. The content of Monom Art Acrylic is in the range of approx
25 60 to 100% by weight and alternatively from about 70 to about 90% by weight of the total monomer
Auxiliary means of acrylic copolymer.
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Examples of copolymerizable monomers include benzyl acrylate and phenyl acrylate; aromatic vinyl compounds such as α-styrene, methylstyren, and vinyltoluene; Vinyl cyanide compounds
Compounds such as acrylonitrile and methacrylonitrile; 5 vinyl esters such as vinyl acetate; And acid anhydrides, such as maleic anhydride. Other copolymerizable monomers can also be used alone or in additive mixtures of two or more. The content of other monomers is in the range of 0 to about 40 wt% and alternatively from about 10 to about 30 wt% of the total monomers.
10 However, multi-functional monomers such as divinylbenzene, 1,3-allyl methacrylate, and 1,3-butanediol can be used.
Dimethacrylate and triallyl cyanurate as components of an acrylic processing aid. The content of these monomers can be in the range of 0.001 to about 2.0 wt% and alternatively from about 0.2 to about 1.0 wt%, depending on the monomer.
15 the college.
The Tg of the acrylic curing aid is eg from about -50°C to about 130°C, eg from about 40°C to about 130°C. An example acrylic curing aid has a molecular weight of from about 500,000 to about 9,000,000, from about 10,000,000 to about 8,000,000 or from about 2,000,000 to about 7,000,000.
20 Examples of acrylic processing aids are used at a weight level of from about 0.5% to about 15%, from about 1% to about 12% or from about 1% to about 10%, depending on the weight of the polyolefin. The acrylic aid can be used at a weight level of about 2%, about 3%, about 4%, about 5%, about 6%, about 7%, about 8% or about 9%, depending on the weight of the polyolefin.
25 Another subject matter of the invention is a polyolefin composition comprising a polyolefin substrate in which an acrylic curing medium is incorporated.
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Additives also include compatibilizers or dispersing aids, such as polyethylene or polypropylene doped with maleic anhydride, ethylene vinyl acetate, ethylene acrylic acid, and the like.
The polymer components of current polyolefin formulations consist primarily of a polyolefin substrate.
5 In general, there are no other polymers, which do not tolerate the presence of additives from polymeric additives such as compatibility stabilizers and the like. Let's say, the polyolefin substrate is ≤ 90 wt%, ≤ 92 wt%, ≤ 94 wt%, ≤ 96 wt% or ≤ 98 wt% polymeric components of the polyolefin formulations.
Current formulations meet or exceed the following industry testing standards.
10 Shows current installations
Impact force of < 35 in.-lbs measured according to ASTM D4226,
Linear thermal expansion coefficient of > 4.5<sup>05-</sup>10 x inches/inches/feet measured according to ASTM D696 and optionally
Acceptable color uniformity of finished sides in accordance with ASTM D6864 and/or
15 Low delta E color is acceptable for the application required in accordance with ASTM D2244 and/or
Flammability of Plastic Materials for UL-94 according to V-0 or V-1 test rate and/or flame spread index Parts in Devices and Appliances, 5<sup>th</sup> Ed., October, 29, 1996
>200 measured according to ASTM E-84.
Example: Existing installations show an impact force of < 60 in-lbs according to ASTM D4226, e.g. 20 < 55 in-lbs, < 50 in-lbs, < 45 in-lbs or < 40 in-lbs.
Example, the application in question is an exterior use such as house panels, house base, panels or roofing. Specifically, the compositions are useful as house siding panels. An acceptable low delta E color is ≥ 8.0, ≥ 7.5, ≥ 7.0, ≥ 6.5, ≥ 6.0, ≥ 5.5, ≥ 5.0, ≥ 4.5, ≥ 4.0, ≥ 3.5. , ≥ 3.0, ≥ 2.5, ≥ 2.0, ≥ 1.5 or ≥ 1.0.
25 The incorporation of the existing components A (-G) and optionally also the additives into the polyolefin substrate is carried out by known methods, for example before or after molding or also by the use of the additive
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Dispersed or dissolved with polyolefin, with or without subsequent evaporation of the solvent. Existing ingredients A (-G) can also optionally be added to polyolefin additives in the form of a master batch that contains the additives at a concentration of, for example, about 2.5% to about 40% by weight, based on the total weight of the master batch. Master Batch The master batch 5 polymer does not need to be the same as the polyolefin substrate.
Molding is carried out by common mixing machines, such as mixers, kneaders or extruders.
.extruders
The existing ingredients A (-G) and optionally the additives can also be mixed initially or added individually.
10 The existing ingredients (a) – g) and optionally also the additives can also be added before or during polymerization or before cross-linking.
Existing ingredients A (-G) and optionally also additives can be incorporated into a polymer which will be made into a flame retardant in pure form or encapsulated in wax, oil or polymer art.
The existing components (a-g) and optionally also the additives can also be atomized onto the poly-15 olefin substrate. It is capable of diluting other additives or solubilities thereof and can also be atomized.
With these additives on polyolefin. Addition by atomization while polymerization catalysts are not activated is particularly useful, as it is possible to perform atomization using, for example, steam used to inhibit activation.
Specifically, the existing additives for components A-G will be incorporated into the thermoplastic polyolefin substrate by melt mixing in an extruder.
The existing formulations are melted and extruded and the final components are prepared by extruding the melt.
Existing additives for components A-G can be added together or separately.
Generally the current process involves measuring the raw materials by weight followed by dry mixing of the raw 25 ingredients. The mixture is fed to a rotating extruder at a constant feed rate to extrude the material into the desired image.
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The product can be raised to provide a desired texture on the surface followed by water cooling or drying and trimming to manufacture the final product.
The benefits of producing polyolefin walls via profile extrusion compared to injection molding of sidewall panels include:
5 Extrusion is a continuous process where the polymer emerges from a pigment forming a linearly formed sheet of any length before being cut into suitable lengths for final assembly. Injection molding is a batch process with a longer "cycle time" and less favorable economic properties considering the volume of polymer converted to the molded item per unit time.
In the case of reverse-rotating twin screw machines used in body 10 extrusion, a uniform ground pressure is created which allows the production of elements of consistent thickness and size.
Twin rotary machines generally allow advantage in terms of flexibility and economy for melting the mixture and mixing various additives, coloring materials, filling materials etc. It directly produces extruded sidewall element. Conversely, the injection molding process
15 Generally for a mixing machine, an additional time step and compound preparation process is necessary to mix the additives and fillers into the base polymer resin before feeding said resin to the injection molding machine. Additional primary components can be added to the injection molding machine, which again requires the initial preparation step of the compound and the use of multiple material feeders at the injection molding machine for many pre-prepared components.
20 different.
Existing installations are particularly used as house panels, cladding, house base or roofing. Existing sidewall panels can be projected as described in US Patent Nos. 5,284,693 and 5,662,977. Alternatively, a process may be used in accordance with US Patent No. 6,823,794 where curable inks are used on an extruded wafer to produce an optical effect.
25 Also a process can be used according to US Publication No. 092701/2007.
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Therefore, a manufacturing element including existing polyolefin compositions is also disclosed. Specifically, the manufacturing item is house panels, cladding, house base or roofing.
Current formulations can be extruded as a monolithic single layer element
.article
5 Alternatively, the present element may be a multi-layer element formed eg via co-extrusion, heat transfer or forging. The existing multi-layer element contains at least one layer of the current polyolefin composition. Preferably, an existing multilayer element containing the existing polyolefin composition as a capstock and/or base layer.
A multilayer article can include a basal layer and an output layer covering 10 basal layers. The multi-layer element can include a base layer and a lining layer covering the base layer. The multi-layer element can include a base layer, an outlet layer and a lining layer.
The base layer consists of a polyolefin composition. There can be additional “tie layers” to avoid adhesion between dissimilar polymer layers in a multilayer element. The outlet layer faces the outside of the house and is exposed to the environment. The lining layer faces the interior of the 15 house.
The cross-linking layers are specifically useful for adhesion of dissimilar polymers or dissimilar polymers with different viscosities or molecular weights, for example such polymers are located in the outlet layer and basal layer, respectively. Examples of tie layer materials include polyolefin, eg polypropylene or polyethylene homopolymer, copolymer etc. and a copolymer or tertiary 20 of a block or graft. Examples of polymers include useful olefin blocks such as the compatibility stabilizers shown above.
The outlet layer can be composed of the same polymer as the base layer or it can be composed of another material such as acrylic, styrenic such as acrylonitrile-styrene-acrylate (acrylonitrile ASA) or polyvinyl chloride. Cover 25 Hardiness against exposure to environmental conditions, such as sunlight, rain, and thermal cycle
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Providing evidence of this hardness by adequately obtaining gloss, surface appearance and color fastness.
The backing layer is useful as an insulation layer, to improve structural rigidity, dimensional stability and/or impact strength. Foamed organic polymer 5 can be formed from the backing material such as polyurethane, or it can be a polyolefin of a similar or different composition of the base layer. A lining layer can be applied to the base layer via co-extrusion, lamination, adhesive or mechanical bonding. Examples of foam backing layers for sidewalls include those referenced in US Patent Nos. 6590004 and 8061097.
10 Detailed description
Examples of multi-layer elements are described in US publications
330272/2010, 092701/2007, 182074/2008 and 0013994/2006 and US Patent No. 8006455.
The length of the stacked side walls according to the present invention is, for example, about 3.658-7.62 m (15 ft. to about 25 ft.) and a width of about 15.24-25.4 cm (6 in. to about 10 ft.).
inch) and thickness from about 0.035 inch to about 0.055 inch (0.0889-0.1397).
The thickness of the existing aligned elements or that of the basal layer of a multilayer element is about 0.0762 cm (0.030), about 0.08128 cm (0.032), about 0.08636 cm (0.034), about 0.09144 cm (0.036), about 0.09652 cm (0.038), about 0.1016 20 cm (0.040), about 0.1067 cm (0.042), about 0.1118 cm (0.044), about 0.1168
cm (0.046), about 0.1219 cm (0.048), about 0.127 cm (0.050), about 0.1321
cm (0.052), approximately 0.1372 cm (0.054), approximately 0.1422 cm (0.056), approximately 1.473
cm (0.58), about 1.524 cm (0.60), about 1.575 cm (0.62), about 1.626 cm (0.64), about 1.676 cm (0.66), about 1.727 cm (0.68) or about 1.778 cm (0.70 25 inches) and Between them.
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The thin sidewall component is moderate in weight and less labor intensive for installation. In the case where the side walls according to this invention include face-back material, it is possible to quantize the front side wall material to a thinner cross-section, have a lower weight, but still have adequate stiffness to permit seamless installation, compared to the larger square area and walls Lateral
5 Heavier polyolefin injection molded.
An inch equals 1000 mils.
The stacked sidewalls according to the present invention, for example the stacked polyolefin sidewalls which include as a substrate a polyolefin homopolymer or a polypropylene copolymer optionally blended with a polyethylene homopolymer or copolymer, where the mixture may include
10 Also a compatibility stabilizer shows a weight of approximately 9.097 Pa (0.19 lb/ft).<sup>2</sup>(This is for the unfilled polymer. For the filled polymer, the sidewalls show a weight of about 9.57606 -
14.36409 Pa (0.20 lb/ft2 to about 0.30 lb/ft2). Show wall elements
The weight of the stack is about 8.618454 - 9.097 Pa (0.18 lb/ft2, about 0.19
lbs/ft2, about 9.57 Pa (0.20 lbs/ft2), about 10.054 Pa (0.21
15 lb/ft2), about 10.53 Pa (0.22 lb/ft2), about 11.012 Pa (0.23 lb/ft2), about 11.4912 Pa (0.24 lb/ft2), about 11.970 Pa (0.25 lb/ft2), about 12.44 Pa (0.26 lb/ft2), about 12.92 Pa (0.27 lb/ft2), about 13.406 Pa (0.28 lb/ft2), about 13.8852 (0.29
lb/ft2), about 14.364 Pa (0.30 lb/ft2), about 14.842 Pa (0.31
20 lbs/ft2), about 15.321 Pascals (0.32 lbs/ft2), about 15.80 Pascals (0.33 lbs/ft2), about 16.279 Pascals (0.34 lbs/ft2), or about 16.758 Pascals (0.35 lbs/ft2), and levels in between.
This description would fit the base layer of a multilayer article.
Therefore, also the subject matter of the present invention is a polyolefin side element filled or unfilled
25 Filled, this item includes a polyolefin backing and has a weight of approximately 8.618 - 16.758 Pa (0.18 lb/ft).<sup>2</sup> to about 0.35 lbs/ft<sup>2</sup>(Where the element is shown
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Impact force of < 35 in.-lbs measured according to ASTM D4226,
Linear thermal expansion coefficient of > 4.5<sup>05-</sup>10 x inches/inches/feet measured according to ASTM D696 and optionally
Acceptable color uniformity of finished sides in accordance with ASTM D6864 and/or
5 Low delta E color is acceptable for the application required in accordance with ASTM D2244 and/or
Rating of 1-UL-94 V or 0-V and/or a flame spread index of >200 measured in accordance with ASTM E-84.
Co-extrusion is a process where multiple layer structures are manufactured simultaneously. This type of extrusion uses two or more extruders to melt and deliver plastic materials
10 Different viscosities into individual extrusions of a die that will extrude the material into the desired shape. Co-extrusion technology is used on any number of processes including blown film, coating, tube manufacturing and foils including bodies. Specifically for the construction markets, co-extrusion is chosen to produce items such as vinyl fencing, window profiles or building siding, in cases where the items are expected to withstand many years of service where exposure to outdoor weather and light
15 the sun. These elements are often composed of a thin “cap-stock” layer of polymeric compound containing weather-resistant additives and extruded over an identical or different polymeric compound that provides structural rigidity and impact resistance (“base layer”). The same or different levels of weatherproof additives, coloring materials, filling materials, flame retardants, and the like can also be applied to the base layer
20 Rear facing in any way with structural reinforcing materials, insulation barrier materials from materials of higher or lower density from microplastics to cellular foam plastics. Alternatively, a foamed polymeric structure can be made from the base layer, providing a significant amount of structural rigidity, strength and insulating properties. The compositions of this invention include base layer reinforcement materials composed of foamed polyolefin compounds including polyethylenes,
25 Polypropylene compounds, polyurethanes, vinyl chloride polymers and combined polyurethane compounds.
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Examples of co-extruded compositions suitable for sidewall elements include but are not limited to polyolefin capstock materials such as a homogeneous or copolymer polypropylene or a homogeneous or copolymer polyethylene with the same or identical or different polypropylene or polyethylene layer, which layer may be The base is optionally a foam composition or optionally has a separate 5-layer polypropylene or polyethylene backing layer prepared.
By combined co-extrusion process or post-lamination process.
Capstock materials can be different from the base layer, such as acrylics (a polymerized form of methacrylate ester compounds such as homopolymers or copolymers) available as ACRYLIGARD, SOLARKOTE and GELOY. Terbolimart includes poly(acrylo-10-nitrile-styrene) Acrylate, vinyl chloride polymers or copolymers
Or mixtures thereof.
The capstock layer may optionally contain any or all UV light absorbers, amine neutralized stabilizers, coloring agents, flame retardants, antimicrobial additives, and nucleating agents.
15 Other basecoat materials may include acrylic, PVC and PVC copolymers as described above. The base layers can optionally be a foam composition or optionally have a separate foamed polypropylene or polyethylene lining face plate prepared by a combined co-extrusion or post-forging process.
Each of the published US patents and US patent applications mentioned herein 20 are incorporated by reference.
The use of the singular form is synonymous with the use of the form "one or more of".
The term “about” refers to a variation that can be made, for example, during perfect measurement and handling procedures, through non-zero error in these procedures; Through differences in manufacturer, source or purity of ingredients used; Through the differences in the methods used; And so on. The term "about" 25 also includes those quantities that vary due to the equilibrium conditions of the resulting composition of a given elementary mixture.
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Whether or not modified by the term “about,” forms and safeguards include items equal to the quantities stated.
All numeric values here are modified by the term "about," whether or not explicitly stated as such. The term "around" generally refers to the range of numbers that an expert in the field can consider
5 Equal to the stated value (i.e., having the same function and/or result). In many cases, the term “about” can include numbers rounded to the nearest number.
The value modified by the term "about" of course includes the specified value. For example, "about 5.0" should include the number 5.0.
Current textures and elements offer unexpected advantages over siding materials such as PVC, wood, hardie board, aluminum, etc. Comprehensive polyolefin formulations and economically effective and robust components for outdoor use are disclosed. Show the following.
Molded in color with no paint required.
Wider and brighter color range.
Natural wood siding can be assembled.
15 Less maintenance and longer life cycle than wood siding.
Environmentally friendly - chlorine-free.
Sustainable – 100% recyclable.
Will not rust or corrode.
Less traction compared to PVC when exposed to heat, light and oxygen.
20 Below are some examples of disclosure.
Embodiment 1. A polyolefin composition including a polyolefin substrate incorporated therein
One or more additives selected from the group consisting of
a) one or more ultraviolet light-absorbing materials,
b) One or more disabled amine light stabilizers
25 c) one or more antioxidants,
Where the composition is shown
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Impact force of < 35 in.-lbs measured according to ASTM D4226,
Linear thermal expansion coefficient of > 4.5<sup>05-</sup>10 x inches/inches/feet measured according to ASTM D696 and optionally
Acceptable color uniformity of finished sides in accordance with ASTM D6864 and/or
5 Low delta E color is acceptable for the application required in accordance with ASTM D2244 and/or
UL-94 V or 0-V rating and/or flame spread index of >200 as measured in accordance with ASTM
.E-84
Embodiment 2. The polyolefin composition according to Embodiment 1 includes a polyolefin substrate incorporated therein
a) one or more ultraviolet light-absorbing materials,
<p dir="rtl">10 b) One or more disabled amine light stabilizers</p>
c) One or more antioxidants.
Embodiment 3. The polyolefin composition according to Embodiment 1 includes a polyolefin substrate incorporated therein
a) one or more ultraviolet light-absorbing materials,
b) one or more disabled amine light stabilizers,
<p dir="rtl">15 c) one or more antioxidants,</p>
d) One or more coloring materials f
e) One or more filling materials.
Embodiment 4. The polyolefin composition according to Embodiment 1 includes a polyolefin substrate incorporated therein
a) one or more ultraviolet light-absorbing materials,
<p dir="rtl">20 b) one or more disabled amine light stabilizers,</p>
c) one or more antioxidants,
d) one or more coloring materials,
e) One or more filling materials f
f) One or more flame retardants.
25 Embodiment 5. The polyolefin composition according to Embodiment 1 includes a polyolefin substrate incorporated therein
a) one or more ultraviolet light-absorbing materials,
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b) one or more disabled amine light stabilizers,
c) one or more antioxidants,
d) one or more coloring materials,
e) one or more filling materials,
5 f) One or more flame retardants
g) One or more antimicrobial compounds.
Embodiment 6. Polyolefin composition according to any of the preceding embodiments wherein the polyolefin substrate is polyethylene, polypropylene, ethylene/propylene copolymer, a mixture of polypropylene and polyethylene or a mixture of different types of polyethylene.
<p dir="rtl">10 Embodiment 7. A polyolefin composition according to any of Embodiments 1-5 wherein the polyolefin substrate is a homopolymer or copolymer of polypropylene, optionally blended with a homopolymer or copolymer of polyethylene wherein the mixture may also include a compatibility stabilizer.</p>
Model 8. Polyolefin composition according to any of the previous models, where
Ultraviolet light absorbing materials selected from the group of hydroxyphenyl compounds
<p dir="rtl">15 Benzotriazoles, hydroxyphenylbenzotriazoles, tris-aryl-s-triazines, hydroxybenzoates, 2-hydroxybenzophenones, and cyanoacrylates.</p>
Antioxidants selected from the group consisting of organophosphorus stabilizer/disabled phenolic antioxidant combinations, dialkylhydroxylamine stabilizers, 20 organophosphorus stabilizer/dialkylhydroxylamine stabilizer combinations, amine oxide stabilizers and stabilizer combinations
Organophosphorus/amine oxide stabilizer,
Coloring materials selected from the group consisting of organic and inorganic pigments,
Filling materials selected from the group consisting of natural fibers and inorganic filling materials
<p dir="rtl">25 Flame retardants selected from the range of chlorinated flame retardants, brominated flame retardants, phosphorus-based flame retardants, metal hydroxide compounds</p>
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metal hydroxide compounds, melamine-based compounds, antimony compounds, boart compounds and other flame retardants containing metals.
Embodiment 9. Polyolefin composition according to any of the previous embodiments where the ultraviolet light absorbing materials are selected from the group consisting of 5-chloro-2-)3-t-butyl-2-hydroxy-5
5 Methylphenyl(-H2-benzotaryazole 5-5-chloro-2-(3-t-butyl-2-hydroxy-)
3,5(-2,methylphenyl)-2H-benzotriazole-bis-α-cumyl-2-hydroxyphenyl(-H2-benzotriazole 4,6,-(3,5-bis- -cumyl-2-hydroxyphenyl) -2H-benzotriazole2-diphenyl-2-)4-hexyloxy-2-hydroxyphenyl(-s-triazine 4-4)-2-6-diphenyl, 4,6-hexyloxy-2-hydroxyphenyl)-s -triazine-bis-)2,4-dimethylphenyl(-2-)2-
10 Hydroxy-4-octyloxyphenyl(-s-triazine 4-2)-2-(,6-bis-(2,4-dimethylphenyl hydroxy-4-octyloxyphenyl)-s-triazine, hexadecyl 3,5- Di-tart-butyl-4-
Hexadecyl 2,4-Hexadecyl 3,5-di-tert-butyl-4-hydroxybenzoate-di-tert-butyl phenyl 3,5-di-tert-butyl-4-hydroxybenzoate 2-3,5 4-di- tert-butylphenyl, di-tert-butyl-4-hydroxybenzoate and 4-octyloxy-2-hydroxybenzophenone 4
15 octyloxy-2-hydroxybenzophenone and amine-disrupted light stabilizers selected from the group
Consisting of
(1) 1-cyclohexyloxy-2,2,6,6-TTRmethyl-4-octadecylaminopiperidine,
(2) Bis(2,2,6,6-TTR Methyl Piperidin-4-yl) Sebacat,
(3(Bis)1-acetoxy-2,2,6,6-TTR methylpiperidin-4-yl) sebacate,
20 (4) Bis(1,2,2,6,6-pentamethylpiperidin-4-yl) sebacat,
(5(Bis)1-cyclohexyloxy-2,2,6,6-TTR methylpiperidin-4-yl) sebacat, (6(Bis)1-octyloxy-2,2,6,6-TTR Methylpiperidin-4-yl) Sebacat; (7(bis)1-acyl-2,2,6,6-TTR Methyl piperidin-4-yl) Sebacate,
(8(bis)1,2,2,6,6-pentamethyl-4-piperidyl) N-butyl-3,5-di-tert-butyl-4
<p dir="rtl">25 Hydroxybenzylmalonate</p>
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(9)2,4-Bis[(1-cyclohexyloxy-2,2,6,6-tetramethylpiperidin-4-yl)butylaminoa
6-(2-Hydroxyethylamino-2-triazine,
(10)bis(1-cyclohexyloxy-6,6,2,2-tetramethylpiperidin-4-yl)adipate,
(11)2,4-Bis[(1cyclohexyloxy-2,2,6,6-piperidin-4-yl)butylamido]-6-
E-chloro-8-tzeazine,
(12) 1-(2-Hydroxy-2-methylpropoxy)-4-Hydroxy-2,2,6,6-tetramethyl
piperidine,
(13) 1-(2-Hydroxy-2-methylpropoxy)-4-oxo-6,6,2,2-tetramethylpiperidine,
(14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyl oxy-2,2,6,6-tetra
<p dir="rtl">01 methyl piperidine,</p>
Methylpiperine
(15)Bis(1-(2-hydroxy-2-methylpropoxy)-2,2,6,6-tetramethylpiperidin-4-yl) sebacate,
(16)Bis(1-(2-hydroxy-2-methylpropoxy)-2,2,6,6-tetramethylpiperidin-4-yl) adipate,
15(17)2,4-Bisyl]-11-(2-Hydroxy-2-Methylpropoxy)-2,2,6,6-Tetramethylpiperidin-4-yl]-La-Butyl Amino (-6-) 2-Hydroxyethylamino)-2-triazine,
(18)4-benzoyl-2,2,6,6-tetramethylpiperidine,
(19) Di-(2,2,6,6,1-pentamethylpiperidin-4-yl)1-methoxybenzylidene malonate,
(20) 2,6,6,2-tetramethylpiperidin-4-yl octadecanoate,
20(21)Bis(1-octylOHCI-6,6,2,2-tetzmethylpiperidyl)succinate,
(22) 1,2,2,6,6-Pentamethyl-4-aminopiperidine,
(23) 2-Undecyl-7,7,9,9-tetramethyl-1-oxa-3,8-diaza-4-oxo-
Spiroa 4,5 Deccan,
(24) Tris(2,2,6,6-tetramethyl-4-piperidyl)nitrilotriacetate,
25(25)Tris(2-Hydroxy-3-(amido-(2,2,6,6-dimethylpiperidin-4-yl)propyl)zilotriacetate,
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(26) Tatar cyst (2,2,6,6-TTR methyl-4-piperidyl)-1,2,3,4-butane-TTR carboxylate,
(27) Tatar Cyst (1,2,2,6,6-Pentamethyl-4-piperidyl)-1,2,3,4-Butane-Ttr Carboxylate,
(28) 1,1'-(1,2-ethanediyl)-bis(3,3,5,5-TTR-methylpiarzenone),
(29) 3-N-octyl-7,7,9,9-TTR methyl-1,3,8-TRI azspiro[4.5]decane-2,4-dione,
5 (30) 8-Acetyl-3-dodecyl-7,7,9,9-Trmethyl-1,3,8-TrAzpyro[4.5]decane-
2,4-Dione,
(31) 3-Dodecyl-1-(2,2,6,6-TTR methyl-4-piperidyl(pyrrolidine-2,5-dione,
(32) 3-Dodecyl-1-(1,2,2,6,6-pentamethyl-4-piperidyl(pyrrolidine-2,5-dione,
(33) N',N-bis-formyl-N',N-bis)2,2,6,6-TTR-methyl-4-piperidyl(hexamethylenedi)
10 Amen,
(a33(bis)1-undecanyl oxy-2,2,6,6-ttr methylpiperidin-4-yl)carbonate,
(34) Reaction product 2,4-bis](1-cyclohexyloxy-2,2,6,6-piperidin-4-yl(butyl)
Amino[-6-chloro-s-triazine with N',N-bis(3-aminopropyl)ethylenediamine),
(35) Condensation product of 1-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-hydroxypiperidine
15 and succinic acid,
(36) Condensation product N',N-bis(2,2,6,6-Tr-methyl-4-piperidyl)-hexamethylenediamine
and 4-tart-octylamino-2,6-dichloro-1,3,5-tariazine,
(37) Condensation product N',N-bis(2,2,6,6-Tr-methyl-4-piperidyl)-hexamethylenediamine
and 4-cyclohexylamino-2,6-dichloro-1,3,5-tariazine,
20 (38) Condensation product N',N-bis-(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine
and 4-morpholino-2,6-dichloro-1,3,5-tariazine,
(39) Condensation product of N',N-bis-(1,2,2,6,6-pentamethyl-4-piperidyl)hexamethylenediamine and 4-morpholino-2,6-dichloro-1,3,5 -Tari Azin,
(40) Condensation product of 2-chloro-4,6-bis(4-N-butylamino-2,2,6,6-Tr-methylpiperidyl)-
25 1,3,5-Tariazine and 1,2-Bis)3-aminopropylamino(ethane,
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(41) Condensation product of 2-chloro-4,6-di-(4-N-butylamino-1,2,2,6,6-pentamethyl)
Piperidyl(-1,3,5-tariazine and 1,2-bis-)3-aminopropylamino(ethane,
(42) The reaction product of 7,7,9,9-tetramethyl-2-cycloundecyl-1-oxa-3,8-diaz-4-oxospyro[4,5]decane and epichlorohydrin,
5 (43) Poly[methyl,(3-oxy-(2,2,6,6-TTR)methylpiperidin-4-yl(propyl)]siloxane,
,CAS#182635-99-0
(44) The product of the C-malic anhydride reaction<sub>1</sub>8-C22-α-olefin-copolymer with 2,2,6,6-tatarymethyl-4-aminopiperidine,
(45) Oligomeric condensation product of 4,4'-hexamethylene bis(amino-2,2,6,6-tetramethyl)
10 Piperidine(and 2,4-dichloro-6-])2,2,6,6-tt-trmethylpiperidin-4-yl(butylamino[-s-tt-triazine) capped peripherally with 2-chloro-4,6- bis(dibutylamino)-s-taryazine,
(46) Oligomeric condensation product of 4,4'-hexamethylenebis(amino-1,2,2,6,6-pentamethylpiperidine)
and 2,4-dichloro-6-])1,2,2,6,6-pentamethylpiperidin-4-yl(butylamino[-s-tariazine 15) capped with 2-chloro-4,6- bis(dibutylamino)-s-taryazine,
(47) Oligomeric condensation product of 4,4'-hexamethylenebis(amino-1-propoxy-2,2,6,6-tetarymethylpiperidine) and 2,4-dichloro-6-])1-propoxy-2 2,6,6-Trmethylpiperidin-4-yl(butylamino[-s-tary azine) capped at the ends by 2-chloro-4,6-bis(dibutylamino(-s-tary azine),
20 (48) Oligomeric condensation product of 4,4'-hexamethylenebis(amino-1-acyloxy-2,2,6,6-
Tetramethylpiperidine (and 2,4-dichloro-6-])1-acyloxy-2,2,6,6-tetramethylpiperidin-4-yl(butylamino[-s-taryazine) terminally capped with 2 -Chloro-4,6-bis)dibutylamino(-s-taryazine)
(49) A product obtained by the reaction of (a) with (b), where (a) is a product obtained 25 by the reaction of 1,2-bis(3-aminopropylamino)ethane with cyanuric chloride and (b) is an expression on
(2,2,6,6-TTR-methylpiperidin-4-yl(butylamine).
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Form 01. A polyolefin composition according to any of the foregoing embodiments wherein the light stabilizers have a hindered amine selected from the group consisting of
(2) Bis(2,2,6,6-tetramethylpiperidin-4-yl) sebacate<sup>-</sup>bi S (2,2,6,6<sup>—</sup>tet2am ethyl pi peri din 4-yl) sebacate;
5(20)2,2,6,6-Tetramethylpiperidin-4-yl octadecanoate,
(14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine,
(33) T!,A1-bis-formyl-l1,l]-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine,
10 (36) Condensation product of 2e-bis(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylenediamine and 4-trit-octylamino-6,2-dichloro-e,3 1-Tari Azin,
(38) Condensation product of “2e-bis-(6,6,2,2-tetramethyl-4-piperidyl)hexamethylenediamine and 4-morpholino-6,2-dichloro-H,3,1-tri I adorn,
(39) Condensation product of, “2e-bis-(6,6,2,2,1-pentamethyl-4-piperidyl)hexamethylenediamine 15 and 4-morgolitho—6,2-dichlordo-e,3, 1-Taday Azin,
(44) The product of the reaction of maleic acid anhydride-22-a-8[C-olgin-copolymer with 6,6,2,2-tetramethyl-4-aminopiperidine,
(45) Condensed oligomeric compound 4,4-hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine) and 4,2-dichloro-6-[(2,2,6,6-tetramethyl) Piperidine-4-yl)butylamino]-5-tri-20 azpene peripherally covered by 2-chloro-4,6-pyrr (dibutylated amiibo)<sup>-</sup>S<sup>-</sup>See Azbin,
(47) An oligomeric compound resulting from the condensation of 4,4-hexamethylenebis(amino-1-propoxy-2,2,6,6-tetramethylpiperidine) and 4,2-dichloro-6-a(1-propoxy-2, 2,6,6-Tetramethylpiperidin-4-yl)butylamino]-5-triazine is peripherally covered by 2-chloro-4,6-bis(dibutylamino)-S-triazine
E2 and its binary and triple combinations.
Model 1 1. Polyolefin composition according to any of the preceding embodiments where
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Aminated stabilizers are binary and triple combinations selected from the group consisting of
(2)Bis(2,6,6,2-tetramethylpiperidin-4-yl)sebacate and
(36) Condensation product of 2e-bis(6,6,2,2-tetramethyl-4-piperidyl)-hexamethylenediamine and 4-trit-octylamino-6,2-dichloro-h,3, 1-Tray Azin,
E(2)bis(6,6,2,2-tetramethylpiperidin-4-yl)sebacat and
(38) Condensation product of, “2e-bis-(6,6,2,2-tetramethyl-4-piperidyl)hexamethylenediamine
-4-morpholino N,N'-bis-(2,2,6,6-tetramethyl-4-piperidyl)hexamethyleidiamine
2,6-Dichloro-H,3,1-triazine,
(2)Bis(2,2,6,6-tetramethylpiperidin-4-yl)sebacat and
10 (39) Condensation product of “2e-bis-(6,6,2,2,1-pentamethyl-4-piperidyl)hexamethylenediamine
and 4-morpholino-6,2-dichloro-e,3,1-triazine,
(2)Bis(2,2,6,6-tetramethylpiperidin-4-yl)sebacat and
(45) Oligomeric compound resulting from the condensation of 4,4-hexamethylene bis(amino-2,2,6,6-tetramethyl)
Piperidine) and 2,4-dichloro-6-[(2,2,6,6-tetramethylpiperidin-4-yl)butylamino]-5-tri
15 Aspen is covered by 2-chloro<sup>_</sup>4.6 lbs (dibutyl amiibo)<sup>-</sup>S<sup>-</sup>See Azbin,
(20) 2,2,6,6-tetramethylpiperidin-4-yl octadecanoate and
(45) Oligomeric condensation product of 4,4-hexamethylenebis(amino-2,2,6,6-tetramethyl)
piperidine) and
2,4-Dichloro-6-[(2,2,6,6-tetramethylpiperidin-4-yl)butylamino]-5-triazine coated
20 terminally with 2 for chloro<sup>_</sup>4,6 LPS (Dibutide Amino)<sup>-</sup>S<sup>-</sup>You see Azbin,
(2) Bis(6,6,2,2-tetramethylpiperidin-4-yl)sebacat and
(20) 2,6,6,2-tetramethylpiperidin-4-yl octadecanoate,
(2)Bis(2,6,6,2-tetramethylpiperidin-4-yl)sebacate,
(14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetra
25 methylpiperidine f
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(45) Oligomeric condensation product of 4,4-hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine) and 2,4-dichloro-6-[(2,2,6,6-tetramethyl Piperidine-4-yl)butylamino]-5-triazine is peripherally coated with 2chloro-4,6-bis(dibutylamino)-5-triazine,
(14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetra
E-methylpiperidine,
(20) 2,6,6,2-tetramethylpiperidin-4-yl octadecanoate and
(45) Oligomeric condensation product of 4,4-hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine) and 2,4-dichloro-6-[(2,2,6,6-tetramethyl Piperidine-4-yl)butylamino]-5-triazine is peripherally covered by 2-chloro-4,6-bis(dibutylamino)-5-triazine,
10(2)Bis(6,6,2,2-tetramethylpiperidin-4-yl)sebacate,
(14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine and
(36) Condensation product of 2e-bis(6,6,2,2-tetramethyl-4-piperidyl)-hexamethylenediamine and 4-trit-octylamino-6,2-dichloro-h,3, 1-Tray Azin,
15(2)Bis(6,6,2,2-tetramethylpiperidin-4-yl)sebacate,
(14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine and
(38) Condensation product of, “2e-bis-(6,6,2,2-tetramethyl-4-piperidyl)hexamethylenediamine and 4-morpholino-6,2-dichloro-e,3,1-tri Azbin 00
(2)Bis(2,6,6,2-tetramethylpiperidin-4-yl)sebacate,
(14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetra
1 -(2,hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tet a, methyl piperidine
and methylpiperidine
25 (39) Condensation product of 2e-bis-(2,2,6,6,1-pentamethyl-4-piperidyl)hexamethylenediamine
and 4-morpholino-6,2-dichloro-e,3,1-triazine.
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Embodiment 12. A polyolefin composition according to which of the foregoing embodiments includes a polyolefin substrate incorporated therein
c) A combination of tris(2,4-di-tert-butylphenyl) phosphate/immobilized phenolic antioxidant, where the immobilized phenolic antioxidant is selected from
5 The group consisting of tris(3,5-di-tert-butyl-4-hydroxybenzyl) isocyanurate-tris(3,5-di-tert-butyl-4-hydroxybenzyl) isocyanurate-tris-) 3,5-Di-
Tert-butyl-4-hydroxybenzyl(-2,4,6-trimethylbenzene-1,3,5-tris-(3,5-di-tert butyl-4-hydroxybenzyl)-2,4,6- trimethylbenzene, the calcium salt of the monoethyl ester of 3,5-di-tert-butyl-4-hydroxybenzylphosphonic acid 3-5,
10 di-tert-butyl-4-hydroxybenzylphosphonic acid, pentaerythritol tartar cyst [3-)3,5-di
-Tert-butyl-4-hydroxyphenyl propionate[ -pentaerythritol tetrakis [3-(3,5-di-tert butyl-4-hydroxyphenyl) propionate and octadecyl 3-)3,5-di-tert-butyl-4-
octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)hydroxyphenyl(propionate)
N,N,propionate-di(C16-C18) alkyl(hydroxylamine-N,N-di(C16)
15 C<sub>1</sub>8alkyl)hydroxylamine, tris(2,4-di-tart-butylphenyl) phosphate/N,N-di synthesis
(C16-C18 alkyl(hydroxylamine N,N-di(C).<sub>1</sub>6-C<sub>1</sub>8alkyl)hydroxylamine, di)-C<sub>1</sub>6
C<sub>1</sub>8) Alkyl methyl amine di(C).<sub>1</sub>6-C<sub>1</sub>8)alkyl methyl amine oxide or a combination of tris(2,4-di-tert-butylphenyl) phosphate/di(C16-C18) alkyl methyl amine oxide-di(C16)
C18)alkyl methyl amine oxide
20 Embodiment 13. A polyolefin composition according to which of the foregoing embodiments includes a polyolefin substrate incorporated therein
c) Combination of tris(2,4-di-tret-butylphenyl) phosphate/pentaerythritol tetrakis [3-(3,5-di-tret-butyl-4-hydroxyphenyl) propionate]-pentaerythritol tetrakis [3-] 3,5-di
tert-butyl-4-hydroxyphenyl) propionate]
25 Tris(2,4-di-tret-butylphenyl) phosphate/octadecyl 3-(3,5-di-tret-butyl) combination
octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl) 4-hydroxyphenyl(propionate-
٦٣٧٤
-٧٩-
N,N,propionate-di)C<sub>1</sub>6-C<sub>1</sub>8 Alkyl(hydroxylamine, combination of tris(2,4-di-tert-butylphenyl) phosphate/N,N-di(C16-C18) Alkyl(hydroxylamine, di(C)<sub>1</sub>6-C<sub>1</sub>8) Alkyl methyl oxide amine or a combination of tris(2,4-di-tert-butylphenyl) phosphate/di(C16-C18) alkyl methyl oxide amine.
5 Embodiment 14. A polyolefin composition according to which of the foregoing embodiments includes a polyolefin substrate incorporated therein
e) Filling material selected from the group consisting of calcium carbonate, magnesium hydroxide, talc, stonite and fly ash.
Embodiment 15. A polyolefin composition according to which of the foregoing embodiments includes a polyolefin substrate 10 incorporated therein
(f) One or more flame retardants selected from the group consisting of brominated flame retardants, phosphorus-based flame retardants, melamine-based compounds and antimony compounds.
Embodiment 16. A polyolefin composition according to which of the preceding embodiments includes a polyolefin substrate 15 incorporated therein
f) Melamine compound/polyol condensate.
Embodiment 17. A polyolefin composition according to which of the foregoing embodiments includes a polyolefin substrate incorporated therein
(f) Melamine polyphosphate, ammonium polyphosphate, pentaerythritol-di-methylphosphonate 20 pentaerythritol-di-methylphosphonate or a melamine/polyol condensate compound wherein the polyol
It is a linear, branched or cyclic alcohol, tartarhydric, pentahydric, hexahydric, C4-C6 aldose, or C4-C6 ketose, wherein the melamine compound is melamine phosphate, melamine pyrophosphate, melamine polyphosphate, or a combination thereof. Antimony oxide with decabromodiphenyl ether or tris[3-bromo-2,2-
25 Bis)bromomethyl(propyl[phosphate]tris[3-bromo-2,2-bis(bromomethyl)propyl
phosphate.
٦٣٧٤
-٨٠-
Embodiment 18. A polyolefin composition according to which of the foregoing embodiments includes a polyolefin substrate incorporated therein
g) One or more antimicrobial compounds selected from the group consisting of zinc oxide, copper, copper compounds, silver compounds, silver dispersions, supported silver, 3,5-dimethyl-
5 Tetrahydro-1,3,5-H2-thiodiazin-2-thione 3-5-dimethyl-tetrahydro-1,3,5-2H,
thiodiazin-2-thione, bis-tributyltinoxide, 4,5-bis-tributyltinoxide-dichlor-2-N-octyl-4-isothiazoline-3-one-N,,5-dichlor-2-n-octyl -4-isothiazolin-3-one4-butyl-benzisothiazoline, 10,10-N-butyl-benzisothiazoline'-oxybisphenoxyarsine, zinc-2-pyridinethiol-1-oxide, 2-methylthio-4-cyclopropylamino - 6-)ß,α-dimethyl
-methylthio-4-cyclopropylamino-6- -2-triazine-s-)10 propyl amino
2 ,dimethylpropylamino)-s-triazine-methylthio-4-cyclopropylamino-6-tart-butylamino-s-triazine,2-methylthio-4-ethylamino-6-)ß,α-dimethylpropyl Amino(-s-taryazine, 2,4,4'-tarychloro-2'-hydroxydiphenyl ether, 3-iodine-2-propenyl-butylcarbamate, carbendazim and thiabendazole.
15 Embodiment 19. A polyolefin composition according to which of the foregoing embodiments includes a polyolefin substrate incorporated therein
g) One or more antimicrobial compounds selected from the group consisting of silver supported on zeolite, silver supported on glass, elemental silver, nano- or micro-sized elemental silver, elemental silver dispersed in silicone oil, silver chloride, silver netart,
<p dir="rtl">20 Silver sulphate, silver phosphate, silver zirconate and silver apatite.</p>
Embodiment 20. A polyolefin composition according to which of the foregoing embodiments includes a polyolefin substrate incorporated therein
<p dir="rtl">a) one or more ultraviolet light-absorbing materials, aggregately, from about 0.10 to about 2.5% by weight, preferably from about 0.10 to about 1.5% by weight, more preferably from</p>
25 About 0.10 to about 0.95% by weight,
٦٣٧٤
-٨١-
b) one or more amine-impaired light stabilizers, in the aggregate, from about 0.10 to about 1.9% by weight, preferably from about 0.15 to about 1.5% by weight,
c) one or more antioxidants, in the aggregate, from about 0.05 to about 1.0% by weight, preferably from about 0.10 to about 0.75% by weight,
5 d) one or more coloring materials, in the aggregate, from about 0.10 to about 3.0% by weight, preferably from about 0.2 to about 1.0% by weight,
<p dir="rtl">e) one or more filling materials, in the aggregate, from about 5 to about 70% by weight, preferably from about 15 to about 40% by weight,</p>
<p dir="rtl">f) One or more flame retardants, in the aggregate, from about 1 to about 70% by weight,</p>
<p dir="rtl">10 Preferably from about 1 to about 50 wt%, more preferably from about 1 to about 40 wt%,</p>
And optionally
<p dir="rtl">g) One or more antimicrobial compounds, in aggregate, from about 0.001 to about 5.0% by weight, preferably from about 0.01 to about 4.0% by weight, more preferably from</p>
15 About 0.02 to about 2.0% by weight, the percentage by weight being based on the weight of the polyolefin substrate.
Example 21. Polyolefin composition comprising a polyolefin substrate selected from the group consisting of polyethylene, polypropylene, ethylene/propylene copolymer, a mixture of polypropylene and polyethylene and mixtures of various types of polyethylene incorporated therein
20 a) About 0.10 to about 0.95% by weight, in the aggregate, of one or more ultraviolet light absorbers selected from the group consisting of 5-chloro-2-(3-t-butyl-2-hydroxy-5-methylphenyl) H2-benzotaryazole 5-5-chloro-2-(3-t-butyl-2-hydroxy-
3,5(-2,methylphenyl)-2H-benzotriazole-bis-α-cumyl-2-hydroxyphenyl(-H2-benzotriazole4,6,-(3,5-bis- -cumyl-2-hydroxyphenyl)- 2H-benzotriazole2-di
25 Phenyl-2-)4-hexyloxy-2-hydroxyphenyl(-s-taryazine, 4,6-bis-)2,4-dimethylphenyl(-2-)2-hydroxy-4-octyloxyphenyl (-s-taryazine, hexadecyl 3,5-
٦٣٧٤
Di-tt-butyl-4-hydroxybenzoate, 4,2-di-tt-butylphenyl 3,5-di-tt-butyl-4-hydroxybenzoate and 4-octyloxy-2-hydroxybenzophenone,
b) About 0.15 to about 1.5! By weight of a di- or tri-amine-impaired light stabilizer combination selected from the group consisting of
E(2)bis(6,6,2,2-tetramethylpiperidin-4-yl)sebacat and
(36) Condensation product of 2e-bis(6,6,2,2-tetramethyl-4-piperidyl)-hexamethylenediamine and 4-trit-octylamino-6,2-dichloro-h,3, 1-Tray Azin,
(2)Bis(2,6,6,2-tetramethylpiperidin-4-yl)sebacate and
(38) Condensation product of, “2e-bis-(6,6,2,2-tetramethyl-4-piperidyl)hexamethylenediamine 10 and 4-morgolito—6,2-di-clodo-h,3,1- Have a nice day,
(2)Bis(2,6,6,2-tetramethylpiperidin-4-yl)sebacate and
(39) Condensation product of “2e-bis-(6,6,2,2,1-pentamethyl-4-piperidyl)hexamethylenediamine and 4-
Morpholino-6,2-dichloro-3,5,1-triazine,
15(2)Bis(6,6,2,2-tetramethylpiperidin-4-yl)sebacat and
(45) Condensed oligomeric compound 4,4-hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine) and 2,4-dichloro-6-[(2,2,6,6-tetramethyl) Piperidine-4-yl)butylamino]-5-triazine is terminally coated with 2-chloro-6,4-bis(dibutylamibo)<sup>-</sup>S<sup>-</sup>You see, Azin,
(20) 2,6,6,2-tetramethylpiperidin-4-yl octadecanoate and
20 (45) Oligomeric condensation product of 4,4-hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine) and
2,4-Dichloro-6-[(2,2,6,6-tetramethylpiperidin-4-yl)butylamino]-5-triazine is capped peripherally with 2-chloro-4,6-bis(dibutyl) amino)-5-triazine,
(2)Bis(2,6,6,2-tetramethylpiperidin-4-yl)sebacate and
25(20)6,2,2,6-tetramethylpiperidin-4-yl octa decanoate,
(2)Bis(2,6,6,2-tetramethylpiperidin-4-yl)sebacate,
٦٣٧٤
-٨٣-
(14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine and
(45) Oligomeric condensation product of 4,4-hexamethylenebis(amino-2,2,6,6-tetramethyl
Piperidine) and 2,4-dichloro-6-[(2,2,6,6-tetramethylpiperidin-4-yl)butylamino]-5-tri
5 Aspene is covered by 2 chloro<sup>_</sup>4.6 lbs (dibutyl amiibo)<sup>-</sup>S<sup>-</sup>See Azbin,
(14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetra
methylpiperidine,
(20) 2,6,6,2-tetramethylpiperidin-4-yl octadecanoate and
(45) Oligomeric condensation product of 4,4-hexamethylenebis(amino-2,2,6,6-tetramethyl
10-piperidine)and 2,4-dichloro-6-[(2,2,6,6-tetramethylpiperidin-4-yl(butylamino]-5-triazine terminally capped with 2-chloro-4,6-bis) Dibutylamino)-5-triazine,
(2)Bis(2,6,6,2-tetramethylpiperidin-4-yl)sebacate,
(14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine and
15 (36) Condensation product of “2e-bis(6,6,2,2-tetramethyl-4-piperidyl)-hexamethylenediamine and 4-tert-octylamino-6,2-dichloro-e,3 1-Tari Azin,
(2)Bis(2,6,6,2-tetramethylpiperidin-4-yl)sebacate,
(14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine and
20 (38) Condensation product of, “2e-bis-(6,6,2,2-tetramethyl-4-piperidyl)hexamethylenediamine and 4-morpholino-6,2-dichloro-h,3,1- Try it
And
(2)Bis(2,6,6,2-tetramethylpiperidin-4-yl)sebacate,
(14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetra
25 methylpiperidine f
٦٣٧٤
-٨٤-
(39) Condensation product of N',N-bis-(1,2,2,6,6-pentamethyl-4-piperidyl)hexamethylenediamine and 4-morpholino-2,6-dichloro-1,3,5 -Tari Azin,
c) About 0.10 to about 0.75 wt% of the combination of tris(2,4-di-tart-butyl-phenyl) phosphate/pentaerythritol tris(3-(3,5-di-tart-butyl-4-hydroxyphenyl)
pentaerythritol tetrakis [3-(3,5-di-tert-butyl-4-hydroxyphenyl)]5 propionate
propionate, combination of tris(2,4-di-tart-butylphenyl) phosphate/octadecyl 3-(3,5-di-tart-butyl-4-hydroxyphenyl) propionate, N,N-di(C)<sub>1</sub>6-C<sub>1</sub>8 Alkyl(Hydroxylamine, Tris(2,4-di-tert-butylphenyl) phosphate/N,N-di(C16-C18) Alkyl(Hydroxylamine, Di(C16-C18) Alkylmethyloxyamine or Tris(2) combination (4-Di-tart-butylphenyl)
<p dir="rtl">10 Phosphite/di(C16-C18) alkyl methyl oxide,</p>
<p dir="rtl">d) about 0.1 to about 3.0% by weight, in the aggregate, of one or more coloring materials selected from the group consisting of organic and inorganic pigments,</p>
<p dir="rtl">e) from about 15 to about 40% by weight, in the aggregate, of one or more fill materials selected from the group consisting of calcium carbonate, magnesium hydroxide, talc, stonite and fly ash,</p>
15 f) From about 1 to about 40% by weight, in the aggregate, of one or more flame retardants selected from the group consisting of melamine polyphosphate, ammonium polyphosphate, pentaerythritol-di-methylphosphonate, condensation product of melamine/polyol compounds and a combination of Antimony Tare Oxide with Deca Bromodiphenyl Ether or Tris[3-Bromo-2,2-Bis(Bromomethyl(Propyl] Phosphate)
Optionally tris[3-bromo-2,2-bis(bromomethyl)propyl] phosphate
20 g) About 0.02 to about 2.0% by weight, in the aggregate, of one or more antimicrobial compounds selected from the group consisting of zinc oxide, copper, copper compounds, silver compounds, silver dispersions, supported silver, 3,5-dimethyl-tetanate R-hydro-1,3,5-H2-thiodiazine-2-thione, bis-tarybutyl tinoxide, 4,5-dichloro-2-N-octyl-4-isothiazoline-3-one, N- Biotyl -benzisothiazoline,10,10'-oxybisphenoxyarsine-'10,10'
25 oxybisphenoxyarsine, zinc-2-pyridinthiol-1-oxide, zinc-2-pyridinthiol-1-oxide, 2-methylthio-4-cyclopropylamino-6-)ß,α-dimethylpropylamino(-s-tari) Azin, 2-
٦٣٧٤
-٨٥-
Methylthio-4-cyclopropylamino-6-tart-butylamino-s-taryazine, 2-methylthio-4-ethylamino-6-)ß,α-dimethylpropylamino(-s-taryazine) 2,4,4'-Trichloro-2'-Hydroxydiphenyl Ether, 3-iodine-2-propenyl-butylcarbamate
butylcarbamate, carbendazim and thiabendazole,
5 Where the composition is shown
Impact force of < 35 in.-lbs measured according to ASTM D4226,
Linear thermal expansion coefficient of > 4.5<sup>05-</sup>10 x inches/inches/feet measured according to ASTM D696 and optionally
Acceptable color uniformity of finished sides in accordance with ASTM D6864 and/or
10 Low delta E color is acceptable for the application required in accordance with ASTM D2244 and/or
UL-94 V or 0-V rating and/or flame spread index of >200 as measured in accordance with ASTM
.E-84
Example 22. A polyolefin composition comprising a homopolymer or copolymer of a polypropylene substrate, optionally blended with a homopolymer or copolymer of polyethylene where it can
<p dir="rtl">15 The mixture also has a compatibility stabilizer built into it</p>
<p dir="rtl">a) About 0.10 to about 0.95% by weight, in the aggregate, of one or more ultraviolet light absorbers selected from the group consisting of 5-chloro-2-(3-t-butyl-2-hydroxy-5-methylphenyl) H2-benzotaryazole 5-5-chloro-2-(3-t-butyl-2-hydroxy-</p>
3,5(-2,methylphenyl)-2H-benzotriazole-bis-α-cumyl-2-hydroxyphenyl(-H2-)
20 Benzotriazole 4,6,-(3,5-bis- -cumyl-2-hydroxyphenyl)-2H-benzotriazole2-diphenyl-2-)4-hexyloxy-2-hydroxyphenyl(-s-tariazine 4) -4)-2-6-diphenyl, 4,6-hexyloxy-2-hydroxyphenyl)-s-triazine-bis-)2,4-dimethylphenyl(-2-)2-
Hydroxy-4-octyloxyphenyl(-s-triazine 4-2)-2-(,6-bis-(2,4-dimethylphenyl hydroxy-4-octyloxyphenyl)-s-triazine, hexadecyl 3,5- Di-tart-butyl-4
25 Hexadecyl 2,4-Hexadecyl 3,5-di-tert-butyl-4-hydroxybenzoate-di-tert-butyl phenyl 3,5-di-tert-butyl-4-hydroxybenzoate 2-3,5 4-di- tert-butylphenyl,
٦٣٧٤
-٨٦-
di “tert-butyl -4-hydroxybenzoate and 4-octyloxy-2-hydroxybenzophenone 4-
octyloxy-2-hydroxybenzophenone
b) About 0.15 to about 1.5! By weight of a di- or tri-amine-impaired light stabilizer combination selected from the group consisting of
5(2)Bis(6,6,2,2-tetramethylpiperidin-4-yl)sebacate and
(36) Condensation product of 2e-bis(2,2,6,6-tetramethyl-4-piperidyl)-hexamethylenediamine and 4-trit-octylamino-6,2-dichloro-e,3, 1-Tray Azin,
(2)Bis(2,2,6,6-tetramethylpiperidin-4-yl)sebacat and
(38) Condensation product of, “2e-bis-(6,6,2,2-tetramethyl-4-piperidyl)hexamethylenediamine 10 and 4-morgolitho—6,2-dicludo-h,3,1- Have a nice day,
(2)Bis(2,2,6,6-tetramethylpiperidin-4-yl)sebacat and
(39) Condensation product of 2e-bis-(6,6,2,2,1-pentamethyl-4-piperidyl)hexamethylenediamine and 4-morpholino-6,2-dichloro-H,3,1 -Tray Azin,
(2)Bis(2,2,6,6-tetramethylpiperidin-4-yl)sebacat and
15 (45) Oligomeric compound resulting from the condensation of 4,4-hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine) and 2,4-dichloro-6-[(2,2,6,6-tetra) Methylpiperidin-4-yl)butylamino]-5-triazine is peripherally covered by 2-chloro-4,6-bis(dibutylamino)-5-triazine,
(20) 2,2,6,6-tetramethylpiperidin-4-yl octadecanoate and
(45) Oligomeric condensation product of 4,4-hexamethylene bis(amino-2,2,6,6-tetramethyl)
20-piperidine)and 2,4-dichloro-6-[(2,2,6,6-tetramethylpiperidin-4-yl(butylino]-5-triazine terminally capped with 2-chloro-4,6-bis) Dibutylamino)-5-triazine,
(2)Bis(2,2,6,6-tetramethylpiperidin-4-yl)sebacat and
(20) 2,2,6,6-tetramethylpiperidin-4-yl octadecanoate,
(2)Bis(2,2,6,6-tetramethylpiperidin-4-yl)sebacat,
25 (14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyl oxy-2,2,6,6-tetramethylpiperidine and
٦٣٧٤
-٨٧-
(45) Oligomeric condensation product of 4,4-hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine) and 2,4-dichloro-6-[(2,2,6,6-tetramethyl Piperidine-4-yl)butylamino]-5-triazine is peripherally covered by 2-chloro-4,6-bis(dibutylamino)-5-triazine,
(14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetra
E-methylpiperidine,
(20) 2,6,6,2-tetramethylpiperidin-4-yl octadecanoate and
(45) Oligomeric condensation product of 4,4-hexamethylenebis(amino-2,2,6,6-tetramethylpiperidine) and 2,4-dichloro-6-[(2,2,6,6-tetramethyl Piperidine-4-yl)butylamino]-5-triazine is peripherally covered by 2-chloro-4,6-bis(dibutylamino)-5-triazine,
10(2)Bis(6,6,2,2-tetramethylpiperidin-4-yl)sebacate,
(14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine and
(36) Condensation product of 2e-bis(6,6,2,2-tetramethyl-4-piperidyl)-hexamethylenediamine and 4-trit-octylamino-6,2-dichloro-h,3, 1-Tray Azin,
15(2)Bis(6,6,2,2-tetramethylpiperidin-4-yl)sebacate,
(14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine and
(38) Condensation product of, “2e-bis-(6,6,2,2-tetramethyl-4-piperidyl)hexamethylenediamine and 4-morpholino-6,2-dichloro-e,3,1-tri Azbin 00
(2)Bis(2,6,6,2-tetramethylpiperidin-4-yl)sebacate,
(14) 1-(2-Hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetra
Methylpiperidine f
(39) Condensation product of 2e-bis-(6,6,2,2,1-pentamethyl-4-piperidyl)hexamethylenediamine 25 and 4-morgolitho—6,2-diclodo-h,3, 1-Taday Azin,
٦٣٧٤
-٨٨-
c) About 0.10 to about 0.75 wt % of the combination of tris(2,4-di-tart-butyl-phenyl) phosphate/pentaerythritol tartar cyst [3-(3,5-di-tart-butyl-4-hydroxyphenyl)propionate [,
Tris(2,4-di-tret-butylphenyl) phosphate/octadecyl 3-(3,5-di-tret-butyl) combination
5 -4-Hydroxyphenyl)propionate, N,N-di(C16-C18 alkyl)hydroxylamine, combination of tris(2,4-di-tart-butylphenyl)phosphate/N,N-di(C16-C18 alkyl)hydroxyl Amin, Dai)C<sub>1</sub>6-C<sub>1</sub>8) alkyl methyl oxide amine or a combination of tris(2,4-di-tert-butylphenyl) phosphate/di(C16-C18) alkyl methyl oxide amine,
<p dir="rtl">d) About 0.1 to about 3.0% by weight, in the aggregate, of one or more coloring materials selected from</p>
<p dir="rtl">10 The group consisting of organic and inorganic pigments,</p>
<p dir="rtl">e) About 15 to about 40% by weight, in the aggregate, of one or more filling materials selected from</p>
The group consisting of calcium carbonate, magnesium hydroxide, talc, stunite and fly ash,
<p dir="rtl">f) from about 1 to about 40% by weight, in the aggregate, of one or more flame retardants selected from the group consisting of melamine polyphosphate, ammonium polyphosphate, pentaerythritol-di-</p>
15 Methyl phosphonate pentaerythritol-di-methylphosphonate, a condensation product of melamine/polyol compounds and a combination of antimony tear oxide with decabromodiphenyl ether or tris[3-bromo-2,2-bis)bromomethyl(propyl] phosphate and optionally
<p dir="rtl">g) About 0.02 to about 2.0% by weight, in the aggregate, of one or more antimicrobial compounds selected from the group consisting of zinc oxide, copper, copper compounds, compounds</p>
<p dir="rtl">20 Silver, silver dispersions, supported silver, 3,5-dimethyl-TTRhydro-1,3,5-H2-thiodiazine-</p>
2-Thione, bis-tributyltinoxide, 4,5-dichlor-2-N-octyl-4-isothiazoline-3-one, N-butyl-benzisothiazoline, 10,10'-oxybisphenoxyarsine, Zinc-2-pyridinethiol-1-oxide, 2-methylthio-4-cyclopropylamino-6-)ß,α-dimethylpropylamino(-s-tariazine, 2-methylthio-4-cyclopropyl) Amino-6-tart-butyl amino-s-taryazine, 2-methyl
25 Thio-4-ethylamino-6-)ß,α-dimethylpropylamino(-s-tariazine, 2,4,4'-tarichloro-
2'-Hydroxydiphenyl ether, 3-iodine-2-propenyl-butylcarbamate, carbendazim and thiabendazole,
٦٣٧٤
-٨٩-
Where the composition is shown
Impact force of < 35 in.-lbs measured according to ASTM D4226,
Linear thermal expansion coefficient of > 4.5<sup>05-</sup>10 x inches/inches/feet measured according to ASTM D696 and optionally
5 Acceptable color uniformity of finished sides in accordance with ASTM D6864 and/or
Low delta E color is acceptable for the application required in accordance with ASTM D2244 and/or
UL-94 V or 0-V rating and/or flame spread index of >200 as measured in accordance with ASTM
.E-84
Embodiment 23. A polyolefin composition according to which of the foregoing embodiments includes an incorporated polyolefin substrate
10 With it
b) A high-molecular-weight hindered amine compound and a low-molecular-weight hindered amine compound.
Embodiment 24. A polyolefin composition according to which of the foregoing embodiments includes a polyolefin substrate incorporated therein
a) One or more ultraviolet light absorbers, such as hydroxybenzoate
and hydroxybenzoate 15
b) A high-molecular-weight hindered amine compound and a low-molecular-weight hindered amine compound.
Embodiment 25. A polyolefin composition including a polyolefin substrate incorporated therein
A) Hydroxybenzoate, which absorbs ultraviolet light
b) A high-molecular-weight hindered amine compound and a low-molecular-weight hindered amine compound.
20 Embodiment 26. A polyolefin composition according to Embodiment 25 comprising a polyolefin substrate incorporated into one or more other compounds selected from the group consisting of
c) one or more antioxidants,
d) one or more coloring materials,
e) One or more filling materials f
25 f) One or more flame retardants.
٦٣٧٤
-٩٠-
Embodiment 27. A polyolefin composition according to which of the foregoing embodiments includes a polyolefin substrate in which an acrylic curing means is incorporated.
Example 28. Polyolefin composition including a polyolefin substrate incorporated with an acrylic curing medium.
Embodiment 29. The polyolefin composition according to Embodiment 28 includes a polyolefin substrate in which one or
5 More than other vehicles selected from the collection of
a) one or more ultraviolet light-absorbing materials,
b) one or more disabled amine light stabilizers,
c) one or more antioxidants,
d) one or more coloring materials,
10 e) One or more filling materials f
f) One or more flame retardants.
Embodiment 30. An extruded element comprising a polyolefin composition according to any of the preceding embodiments.
Embodiment 31. An extruded element according to Embodiment 30 is house panels, cladding, house base or roofing.
<p dir="rtl">15 Embodiment 32. An extruded element according to Embodiments 30 or 31 having a thickness of about 0.0762 -</p>
<p dir="rtl">0.1778 cm (0.030 inch to about 0.070 inch) and a weight of about 0.18 lb/ft<sup>2</sup> to about 0.31 lbs/ft<sup>2</sup>.</p>
Embodiment 33. Use of a composition according to any of Embodiments 1-29 in a fabrication item selected from the group consisting of house panels, cladding, house base and roofing.
20 Form 34. Polyolefin siding article, filled or unfilled. This element includes a polyolefin substrate and has a weight of about 0.0762 - 0.1778 cm (0.18 lb/ft).<sup>2</sup> to about 0.31 lbs/ft<sup>2</sup>(Optionally a thickness of about 0.0762 - 0.1778 cm (0.030 inch to about 0.070 inch) and where the item indicates
Impact force of < 35 in.-lbs measured according to ASTM D4226,
25 Linear thermal expansion coefficient of > 4.5<sup>05-</sup>10 x inches/inches/feet measured according to ASTM D696
And optionally
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Acceptable color uniformity of finished sides in accordance with ASTM D6864 and/or
Low delta E color is acceptable for the application required in accordance with ASTM D2244 and/or
UL-94 V or 0-V rating and/or flame spread index of >200 as measured in accordance with ASTM
.E-84
5 Embodiment 35. The polyolefin element according to Embodiment 34 is a compact wall element.
In the examples below and throughout the description, all parts and ratios are given by weight unless otherwise specified.
Examples
Example 1 Polypropylene Copolymer
Formulations are dry mixed with polypropylene copolymer and compound preparation in a 10" extruder to form 2" x 60" x 2" mil bars. The percentages by weight of the immobilized amine compounds will be found in the table below. Each formula also contains 20% by weight of calcium carbonate filler.
Each formula also contains 0.20% by weight of 5-chloro-2-(3-t-butyl-2-hydroxy-5-methylphenyl(-H2-benzotaryazole) 5-5-chloro-2-(3-t-). butyl-2-hydroxy-
15 methylphenyl)-2H-benzotriazole, 0.40 wt% of tris)2,4-di-tart combination.
Butylphenyl phosphate/pentaerythritol tartar sachet [3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate], 1.0 wt% titanium dioxide and 15 wt% melamine phosphate and pentaerythritol condensate.
All percentages by weight are based on the weight of the polypropylene copolymer.
<tr><td><p>TER2</p></td><td><p>TER1</p></td><td><p>BIN3</p></td><td><p>BIN2</p></td><td><p>BIN1</p></td><td><p>)20(</p></td><td><p>)2(</p></td><td><p dir="rtl">Formula</p></td></tr><tr><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>0.4</p></td><td><p>1</p></td></tr><tr><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>1.0</p></td><td><p>2</p></td></tr><tr><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>0.4</p></td><td></td><td><p>3</p></td></tr><tr><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>1.0</p></td><td></td><td><p>4</p></td></tr><tr><td></td><td></td><td></td><td></td><td rowspan="2"><p>0.4</p></td><td rowspan="2"></td><td rowspan="2"></td><td rowspan="2"><p>5</p></td></tr><tr><td></td><td></td><td></td><td></td></tr><tr><td></td><td></td><td></td><td></td><td rowspan="2"><p>0.4</p></td><td rowspan="2"></td><td rowspan="2"></td><td rowspan="2"><p>6</p></td></tr><tr><td></td><td></td><td></td><td></td></tr>
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<tr><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>1.0</p></td><td></td><td></td><td><p>7</p></td></tr><tr><td></td><td></td><td></td><td><p>0.4</p></td><td></td><td></td><td></td><td><p>8</p></td></tr><tr><td></td><td></td><td></td><td><p>0.4</p></td><td></td><td></td><td></td><td><p>9</p></td></tr><tr><td></td><td></td><td></td><td><p>1.0</p></td><td></td><td></td><td></td><td><p>10</p></td></tr><tr><td></td><td></td><td><p>0.4</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>11</p></td></tr><tr><td></td><td></td><td><p>0.4</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>12</p></td></tr><tr><td></td><td></td><td><p>1.0</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>13</p></td></tr><tr><td></td><td><p>0.4</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>14</p></td></tr><tr><td></td><td><p>1.0</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>15</p></td></tr><tr><td><p>0.4</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>16</p></td></tr><tr><td><p>1.0</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>17</p></td></tr>
Disabled amine compounds are those specified in the specific description.
BIN1 is a binary combination of hindered amines (2) and (36). BIN2 is a binary combination of hindered amines (2) and (45). BIN3 is a binary combination of hindered amines (20) and (45). (.
5 Formulas 5, 7, 8, 10, 11 and 13 have a 1:1 weight ratio of binary combinations.
Formula 6 contains 0.3% amine compounds (2) and 0.1% amine compounds (36). Formula 9 contains 0.3% amine compounds (2) and 0.1% amine compounds (45). Formula 12 contains 0.3% of amine compounds (20) and 0.1% of amine compounds (45).
10 TER1 is a ternary combination of hindered amine compounds (2), (45) and (14). TER2 is a ternary combination of hindered amine compounds (20), (45) and (14).
Formula 14 contains 0.2% of the retarded amine (2), 0.14% of the retarded amine (45) and 0.06% of the retarded amine (14).
Formula 15 contains 0.5% of the retarded amine (2), 0.35% of the retarded amine (45) and 0.15% of the 15 retarded amine (14).
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Formula 16 contains 0.2% of the retarded amine (20), 0.14% of the retarded amine (45) and 0.06% of the retarded amine (14).
Formula 17 contains 0.5% of the retarded amine (20), 0.35% of the retarded amine (45) and 0.15% of the retarded amine (14).
5 Formulas 1-17 are repeated, replacing 20% calcium carbonate with 40% calcium carbonate to produce formulas 18-34 respectively.
Formulas 1-17 are duplicated, replacing 20% calcium carbonate with 20% calcium to produce formulas 35-51 respectively.
Formulas 1-17 are repeated, replacing 20% calcium carbonate with 40% calcium to produce formulas 52-68 on
10 straight.
Formulas 1-17 are repeated, replacing 20% calcium carbonate with 20% wollastonite to produce formulas 69-85 respectively.
Formulas 1-17 are duplicated, replacing 20% calcium carbonate with 40% stunite to produce formulas 86102, respectively.
15 Formulas 1-102 rods have been tested for flame retardation and color stabilization after accelerated weather conditions.
Example 2 High Density Polyethylene
The formulations are dry mixed with high-density polyethylene and the compound is prepared in an extruder to form bars with dimensions of 2" x 60" x 2 mils. The percentage by weight of immobilized amine compounds used is given in the table below. Each formula also contains 20% by weight 20% calcium carbonate filler.
Each formulation also includes 0.20 wt % of 5-chloro-2-(3-t-butyl-2-hydroxy-5-methylphenyl(-H2-benzotriazole), 0.40 wt % of Tris(2,4-di) -Tart-butylphenyl phosphate/pentaerythritol tartar sachet [3-(3,5-di-tart-butyl-4-hydroxyphenyl) propionate], 1.0 wt.% titanium dioxide and 15 wt.%
25 The condensation product of melamine phosphate and pentaerythritol.
All percentages by weight are based on the weight of polyethylene.
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<tr><td><p>TER3</p></td><td><p>TER2</p></td><td><p>BIN4</p></td><td><p>BIN2</p></td><td><p>BIN1</p></td><td><p>)20(</p></td><td><p>)45(</p></td><td><p>)36(</p></td><td><p>)2(</p></td><td><p dir="rtl">Formula</p></td></tr><tr><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>0.2</p></td><td><p>103</p></td></tr><tr><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>0.5</p></td><td><p>104</p></td></tr><tr><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>0.2</p></td><td></td><td><p>105</p></td></tr><tr><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>0.5</p></td><td></td><td><p>106</p></td></tr><tr><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>0.2</p></td><td></td><td></td><td><p>107</p></td></tr><tr><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>0.5</p></td><td></td><td></td><td><p>108</p></td></tr><tr><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>0.2</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>109</p></td></tr><tr><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>0.5</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>110</p></td></tr><tr><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>0.2</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>111</p></td></tr><tr><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>0.5</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>112</p></td></tr><tr><td></td><td></td><td></td><td><p>0.2</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>113</p></td></tr><tr><td></td><td></td><td></td><td><p>0.5</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>114</p></td></tr><tr><td></td><td></td><td><p>0.2</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>115</p></td></tr><tr><td></td><td></td><td><p>0.5</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>116</p></td></tr><tr><td></td><td><p>0.2</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>117</p></td></tr><tr><td></td><td><p>0.5</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>118</p></td></tr><tr><td><p>0.2</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>119</p></td></tr><tr><td><p>0.5</p></td><td><p>---</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>----</p></td><td><p>120</p></td></tr>
Disabled amine compounds are those specified in the detailed description.
BIN4 is a binary combination of hindered amines (2) and (20).
Formulas 111-116 have a 1:1 weight ratio by the amount of binary combinations.
Formula 117 contains 0.1% of hindered amine, 0.07% of hindered amine (20).
5 Disabled woman (45) and 0.03% of disabled trustees (14).
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Formula 118 contains 0.25% of retarded amine (20), 0.175% of retarded amine (45) and 0.075% of retarded amine (14).
Formula 119 contains 0.1% of the retarded amine (36), 0.07% of the retarded amine (2) and 0.03% of the retarded amine (14).
5 Formula 120 contains 0.25% of amine (36), 0.175% of amine (2)
And 0.075% of Amin Maqa (14).
Formulas 103-120 are duplicated, replacing 20% calcium carbonate with 40% calcium carbonate to produce formulas 121-138 respectively.
Formulas 103-120 are duplicated, replacing 20% calcium carbonate with 20% calcium to produce formulas 13910 and 156 respectively.
Formulas 103-120 are duplicated, replacing 20% calcium carbonate with 40% calcium to produce formulas 157174 respectively.
Formulas 103-120 are duplicated, replacing 20% calcium carbonate with 20% stunite to produce formulas 192-175 respectively.
15 Formulas 103-120 are duplicated, replacing 20% calcium carbonate with 40% stunite to produce formulas 210-192 respectively.
Formulas 103-210 rods have been tested for flame retardation and color stability after accelerating weather conditions.
Example 3 Polypropylene copolymer
Example 1 is repeated,
20 By replacing 5-chloro-2-)3-t-butyl-2-hydroxy-5-methylphenyl(-H2-benzotaryazole)
With the substance -chloro-2-(3-t-butyl-2-hydroxy-5-methylphenyl)-2H-benzotriazole5
Ultraviolet light absorber (UVA) selected from 2-)3,5-bis-α-cumyl-2-hydroxyphenyl(-H2-benzotaryazole 2-2-3,5-bis- -cumyl)- 4,6-hydroxyphenyl-2H-benzotriazole-diphenyl-2-)4-hexyloxy-2
25 Hydroxyphenyl(-s-taryazine 4-,6-diphenyl-2-(4-hexyloxy-2-hydroxyphenyl)-s
4,6-triazine-bis-(2,4-dimethylphenyl(-2-)2-hydroxy-4-octyloxyphenyl(-)
٦٣٧٤
-٩٦-
s-tary azine, hexadecyl 3,5-di-tt-butyl-4-hydroxybenzoate and 2,4-di-tt-butylphenyl 3,5-di-tt-butyl-4-hydroxybenzoate,
By replacing Tris(2,4-di-tret-butylphenyl) phosphate/pentaerythritol tetar cyst [3-(3,5-di-tret-butyl-4-hydroxyphenyl)propionate] combination with an antioxidant selected from the Tris combination
5 (2,4-Di-tart-butylphenyl) phosphate/octadecyl 3-(3,5-di-tart-butyl-4-
Hydroxyphenyl(propionate, N,N-di)C<sub>1</sub>6-C<sub>1</sub>8 Alkyl(Hydroxylamine, Tris(2,4-di-tert-butylphenyl) phosphate/N,N-di(C16-C18) Alkyl(Hydroxylamine, Di(C16-C18) Alkylmethyloxyamine and Tris(2, 4-Di-tert-butylphenyl) phosphate/di(C16-C18) alkyl methyl oxide,
10 By replacing calcium carbonate, talc and astonite with magnesium hydroxide or fly ash and by replacing the condensate of melamine phosphate and pentaerythritol with a flame retardant selected from melamine polyphosphate, ammonium polyphosphate and a combination of antimony trioxide with decabromodiphenyl ether or Tris [3]. -Bromo-2,2-Bis)Bromomethyl(Propyl[Phosphate).
15 Example 4 High-density polyethylene Example 2 bis,
By replacing 5-chloro-2-)3-t-butyl-2-hydroxy-5-methylphenyl(-H2-benzotaryazole) with a UV light absorber selected from 2-)3,5-bis-α-cumyl- 2-Hydroxyphenyl(-H2-benzotaryazole, 4,6-diphenyl-2-)4-hexyloxy-2-hydroxyphenyl(-20s-taryazine, 4,6-bis-)2,4 -Dimethylphenyl(-2-)2-hydroxy-4-octyloxy
Phenyl(-s-taryazine, hexadecyl 3,5-di-tt-butyl-4-hydroxybenzoate and 2,4-di-tt-butyl phenyl 3,5-di-tt-butyl-4-hydroxybenzoate 2) -4-di-tert,
,butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate
By replacing Tris(2,4-di-tart-butylphenyl) phosphate/pentaerythritol tartar sac[3-(3,5-di-25-tart-butyl-4-hydroxyphenyl)propionate] combination with an antioxidant selected from the Tris combination. (2,4-Di-tart-butylphenyl) phosphate/octadecyl 3-(3,5-di-tart-butyl-4-
٦٣٧٤
-٩٧-
Hydroxyphenyl(propionate, N,N-di)C<sub>1</sub>6-C<sub>1</sub>8 Alkyl(Hydroxylamine, Tris(2,4-di-tert-butylphenyl) phosphate/N,N-di(C16-C18) Alkyl(Hydroxylamine, Di(C16-C18) Alkylmethyloxyamine and Tris(2, 4-Di-tert-butylphenyl) phosphate/di(C16-C18) alkyl methyl oxide,
5 By replacing calcium carbonate, talc and astonite with magnesium hydroxide or fly ash and
By replacing the condensate of melamine phosphate and pentaerythritol with a flame retardant selected from melamine polyphosphate, ammonium polyphosphate and a combination of antimony trioxide with decabromodiphenyl ether or tris[3-bromo-2,2-bis)bromomethyl(propyl] phosphate.
10 Example 5 Polypropylene homopolymer
Examples 1-4 are replicated by replacing polyolefin with a polypropylene homopolymer.
Example 6 Polypropylene has high melting strength
ExxonMobil's high melt strength polypropylene 341E15 homopolymer is crushed into a powder, which is mixed with powdered additives, filler and recycler.
15 Strengthening, calcium carbonate lubricant, powdered colorants and 500 ppm IRGANOX B 215 as curing and heat stabilizer. Formulas are fed via a gravity feeder at a rate of 12 lbs/hr to a 25 mm COPERION twin-screw extruder co-rotating at a controlled temperature of 220°C, winding speed of 150 rpm. The extruded polymer strands are cooled in a water bath and pelletized to achieve a granular form.
Specialty Minerals ULTRATALC 609 20 Talc is
The coloring material is an ocean blue dye
215-IRGANOX B is a 2:1 weight mixture of tris(2,4-ditret-butylphenyl(phosphite) and penta-erythritol tetarterase[3-]3,5-di-tart-butyl-4-hydroxy
phenyl[propionate]
<p dir="rtl">25 The prepared formulas were as follows. Percentages in % by weight based on polypropylene.</p>
<p dir="rtl">1 Blank polypropylene</p>
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<p dir="rtl">2 0.4% disabled amine light fixtures (2)</p>
<p dir="rtl">3 0.2% amine-retarded light fixtures (2) / 0.2% amine-retarded light fixtures (36)</p>
<p dir="rtl">4 0.3% amine-retarded light fixtures (2) / 0.1% amine-retarded light fixtures (36)</p>
<p dir="rtl">5 0.2% amine-disabled light fixtures (2) / 0.14% amine-disabled light fixtures</p>
5 (36)/0.06% hexadecyl 3,5-di-tert-butyl-4-
Hydroxybenzoate
<p dir="rtl">6 0.2% amine-retarded light fixtures (2) / 0.2% amine-retarded light fixtures (45)</p>
<p dir="rtl">7 0.3% amine-disabled light fixtures (2) / 0.1% amine-disabled light fixtures (45)</p>
<p dir="rtl">8 0.2% amine-disabled light fixtures (2) / 0.14% amine-disabled light fixtures</p>
10 (45) / 0.06% hexadecyl 3,5-di-tert-butyl-4-
hexadecyl 3,5-di-tert-butyl-4-hydroxybenzoate
<tr><td></td><td></td><td></td><td></td><td></td><td><p dir="rtl">Disabled LED light (20)</p></td><td><p dir="rtl">Stabilizers</p></td><td><p>٪0.4</p></td><td><p>9</p></td><td></td></tr><tr><td><p dir="rtl">Disabled</p></td><td><p dir="rtl">Amen</p></td><td><p dir="rtl">a light</p></td><td><p dir="rtl">Stabilizers</p></td><td><p>٪0.2</p></td><td><p dir="rtl">Disabled LED light (20) /</p></td><td><p dir="rtl">Stabilizers</p></td><td><p>٪0.2</p></td><td><p>10</p></td><td></td></tr><tr><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td><p>)45(</p></td><td></td></tr><tr><td><p dir="rtl">Disabled</p></td><td><p dir="rtl">Amen</p></td><td><p dir="rtl">a light</p></td><td><p dir="rtl">Stabilizers</p></td><td><p>٪0.2</p></td><td><p dir="rtl">Disabled LED light (14) /</p></td><td><p dir="rtl">Stabilizers</p></td><td><p>٪0.2</p></td><td><p>11</p></td><td><p>15</p></td></tr><tr><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td><p>)45(</p></td><td></td></tr><tr><td><p dir="rtl">Disabled</p></td><td><p dir="rtl">Amen</p></td><td><p dir="rtl">a light</p></td><td><p dir="rtl">Stabilizers</p></td><td><p>٪0.1</p></td><td><p dir="rtl">Disabled LED light (2) / 4</p></td><td><p dir="rtl">Stabilizers</p></td><td><p>٪0.2</p></td><td><p>12</p></td><td></td></tr>
(45) / 0.06% Disabled amine light fixtures (14)
<p dir="rtl">13 0.2% Disabled amine light fixtures (2) / 0.14% amine light fixtures</p>
20 Disabled (45) / 0.06 hexadecyl 3,5-di-tert-butyl-4-hydroxybenzoate
<p dir="rtl">14 0.2% amine-disabled light fixtures (2) / 0.14% amine-disabled light fixtures</p>
(45)/0.06% Impeded amine light stabilizers (14)/0.04% 5-chloro-2-(3-t-butyl-2-
Hydroxy-5-methylphenyl(-H2-benzotaryazole).
<p dir="rtl">15 0.2% amine-disabled light fixtures (2) / 0.14% amine-disabled light fixtures</p>
25 (45) / 0.06% hexadecyl 3,5-di-tert-butyl-4-
٦٣٧٤
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Hydroxybenzoate/0.04% 5-chloro-2-)3-t-butyl-2-hydroxy-5-methylphenyl(-H2-)
Benzo tare azul
<p dir="rtl">16 0.14% Disabled amine light fixtures (45) / 0.06% Disabled amine light fixtures</p>
5 (14) / 0.2% retarded amine light fixtures (20)
<p dir="rtl">17 0.14% retarded amine light stabilizers (45) / 0.06% hexadecyl 3,5-di-</p>
Tert-butyl-4-hydroxybenzoate/
0.2% disabled amine light fixtures (20)
The formulas are injection molded into 60 mil thick sheets, 1.75" x 2.5", using a die cutting machine.
10 50 BOY for injection molding with set temperature point of 450°F, mold temperature of 65°
F.
Triplicate panels of each format were mounted on frames and exposed to accelerated aging or weather using WOM (Atlas Ci65A 63°C black board, no light
15 102 minutes and 18 minutes of light, sprayed with water, with indoor and outdoor light filters
Borosilicate (.
The results of the average readings after 1912 hours of exposure to weather conditions will be as follows.
<tr><td><p dir="rtl">Delta luminosity at</p><p dir="rtl">60 degree</p></td><td><p dir="rtl">Shine at</p><p dir="rtl">60 degree</p></td><td><p dir="rtl">Initial brightness at 60 degrees</p></td><td><p dir="rtl">Delta E</p></td><td><p dir="rtl">Formula</p></td></tr><tr><td><p>48.2</p></td><td><p>2.5</p></td><td><p>50.7</p></td><td><p>22.6</p></td><td><p>1</p></td></tr><tr><td><p>20.3</p></td><td><p>29.8</p></td><td><p>50.0</p></td><td><p>0.7</p></td><td><p>2</p></td></tr><tr><td><p>22.0</p></td><td><p>32.8</p></td><td><p>54.9</p></td><td><p>0.7</p></td><td><p>3</p></td></tr><tr><td><p>22.9</p></td><td><p>33.7</p></td><td><p>56.6</p></td><td><p>0.8</p></td><td><p>4</p></td></tr><tr><td><p>9.7</p></td><td><p>47.5</p></td><td><p>57.3</p></td><td><p>0.9</p></td><td><p>5</p></td></tr><tr><td><p>21.9</p></td><td><p>34.3</p></td><td><p>56.2</p></td><td><p>0.6</p></td><td><p>6</p></td></tr><tr><td><p>23.3</p></td><td><p>33.6</p></td><td><p>56.9</p></td><td><p>0.8</p></td><td><p>7</p></td></tr>
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<tr><td><p>10.0</p></td><td><p>46.9</p></td><td><p>56.9</p></td><td><p>1.0</p></td><td><p>8</p></td></tr><tr><td><p>55.2</p></td><td><p>5.0</p></td><td><p>60.2</p></td><td><p>8.9</p></td><td><p>9</p></td></tr><tr><td><p>21.9</p></td><td><p>36.7</p></td><td><p>58.6</p></td><td><p>0.8</p></td><td><p>10</p></td></tr><tr><td><p>12.4</p></td><td><p>32.3</p></td><td><p>44.7</p></td><td><p>0.9</p></td><td><p>11</p></td></tr><tr><td><p>15.2</p></td><td><p>34.5</p></td><td><p>49.7</p></td><td><p>0.8</p></td><td><p>12</p></td></tr><tr><td><p>6.0</p></td><td><p>45.0</p></td><td><p>50.9</p></td><td><p>1.0</p></td><td><p>13</p></td></tr><tr><td><p>13.2</p></td><td><p>36.9</p></td><td><p>50.1</p></td><td><p>0.9</p></td><td><p>14</p></td></tr><tr><td><p>6.6</p></td><td><p>44.3</p></td><td><p>50.9</p></td><td><p>1.0</p></td><td><p>15</p></td></tr><tr><td><p>14.4</p></td><td><p>36.5</p></td><td><p>50.9</p></td><td><p>0.9</p></td><td><p>16</p></td></tr><tr><td><p>7.0</p></td><td><p>44.3</p></td><td><p>51.3</p></td><td><p>1.0</p></td><td><p>17</p></td></tr>
Formulas 5, 8 and 11-17 show excellent results.
Example 7 Polypropylene copolymer
The substrate is a PROFAX SG702 shock absorbent polypropylene copolymer in the form of
Pellets. The filling material is Heritage Plastics HT6P (60%) commercial masterbatch
<p dir="rtl">5 Polypropylene copolymer. The filling material is allowed to drop to 20% in all formulations.</p>
Procedure:
<p dir="rtl">1. Mixing in a 1kg mixing bag</p>
<p dir="rtl">2. Prepare the compound at 200°C</p>
10 3. Injection molding at 220°C (plate thickness 60 mils for weather-o-exposure processes)
)Meter
<p dir="rtl">4. Regular color and luster checks</p>
<p dir="rtl">5. Conduct a microscopic test for microscopic cracks and leaching</p>
<p dir="rtl">6. Regular weather forecasting with intervals of 0, 500, 1000, 2000, 3000, 4000 hours,</p>
<p dir="rtl">15 etc.</p>
٦٣٧٤
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The following formulas were prepared. Additives are present at 0.75 wt% based on polypropylene. Multi-component additive blends contain additives equal to % by weight.
<p dir="rtl">1 Hexadecyl 3,5-di-tart-butyl-4-hydroxybenzoate</p>
<p dir="rtl">2 2,4-di-t-butylphenyl 3,5-di-t-butyl-4-hydroxybenzoate 2-4-di-t,</p>
butyl phenyl 3,5-di-t-butyl-4-hydroxybenzoate 5
<p dir="rtl">3 Disabled safety light fixtures (2)</p>
<p dir="rtl">4 Light stabilizers with inhibited amines (2) / hexadecyl 3,5-di-tert-butyl-4-hydroxybenzoate</p>
<p dir="rtl">5 Disabled safety light fixtures (14)</p>
10 6 inhibited amine light stabilizers (14) / hexadecyl 3,5-di-tert-butyl-4-
Hydroxybenzoate
<p dir="rtl">7 Disabled safety light fixtures (36)</p>
<p dir="rtl">8 Aminated light stabilizers (36) / hexadecyl 3,5-di-tert-butyl-4-hydroxybenzoate</p>
15 9 Disabled security light fixtures (2) / Disabled security light fixtures (14) / Stabilizers
Disabled LED light (45)
<p dir="rtl">10 Blocked amine light stabilizers (2) / Blocked amine light stabilizers (14) / Blocked amine light stabilizers (45) / Hexadecyl 3,5-di-tert-butyl-4-hydroxybenzoate</p>
<p dir="rtl">11 Disabled security light fixtures (2) / Disabled security light fixtures (14) / stabilizers</p>
20 Light inhibited amine (45)/2,4-di-t-butylphenyl 3,5-di-t-butyl-4-hydroxybenzoate
12 Impeded amine light stabilizers (20) / hexadecyl 3,5-di-tart-butyl-4-hydroxybenzoate / impeded amine light stabilizers (39) / 4,6-bis-(2,4-dimethylphenyl) -2-)2-Hydroxy-4-octyloxyphenyl(-s-tariazine 4-6-bis-(2,4-dimethyl,
0.41% by total weight (phenyl)-2-(2-hydroxy-4-octyloxyphenyl)-s-triazine 25
٦٣٧٤
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The results of the delta E color change after precipitating weather at 1500 h and 4000 h are shown below.
<tr><td><p dir="rtl">4000 hour</p></td><td><p dir="rtl">1500 hour</p></td><td><p dir="rtl">Formula</p></td></tr><tr><td></td><td><p>18.2</p></td><td><p>1</p></td></tr><tr><td></td><td><p>16.5</p></td><td><p>2</p></td></tr><tr><td><p>3.7</p></td><td><p>3.8</p></td><td><p>3</p></td></tr><tr><td><p>3.5</p></td><td><p>4.0</p></td><td><p>4</p></td></tr><tr><td><p>6.7</p></td><td><p>6.8</p></td><td><p>5</p></td></tr><tr><td><p>4.9</p></td><td><p>5.3</p></td><td><p>6</p></td></tr><tr><td><p>3.7</p></td><td><p>3.3</p></td><td><p>7</p></td></tr><tr><td><p>2.9</p></td><td><p>3.5</p></td><td><p>8</p></td></tr><tr><td><p>2.9</p></td><td><p>3.0</p></td><td><p>9</p></td></tr><tr><td><p>2.9</p></td><td><p>3.5</p></td><td><p>10</p></td></tr><tr><td><p>2.0</p></td><td><p>2.1</p></td><td><p>11</p></td></tr><tr><td><p>3.5</p></td><td><p>3.8</p></td><td><p>12</p></td></tr>
Excellent results are achieved with formulas containing amine-challenged light stabilizers and benzoates
5 Ultraviolet light absorber.
The following additive formulas are used to obtain the shine.
1a 0.15% hexadecyl 3,5-di-tt-butyl-4-hydroxybenzoate
2 A 0.15% 2,4-di-t-butylphenyl 3,5-di-t-butyl-4-hydroxybenzoate
13 A 0.15% Retarded Amine Light Fixators (2) / Retarded Amine Light Fixators (14) /
10 Disabled safety light fixtures (45)
14 A 0.15% inactivated amine light stabilizers (2) / inactivated amine light stabilizers (14) / inactivated amine light stabilizers (45) / hexadecyl 3,5-di-tert-butyl-4-
Hydroxybenzoate
٦٣٧٤
-١٠٣-
15 A 0.15% Impeded amine light stabilizers (2) / Impeded amine light stabilizers (14) / Impeded amine light stabilizers (45) / 2,4-di-t-butyl phenyl 3,5-di-t-butyl - 4-Hydroxybenzoate 4-di-t-butyl phenyl 3,5-di-t-butyl-4-hydroxybenzoate2, the results of the percentage of glossiness obtained at 60 degrees at different time intervals are given below
<tr><td><p dir="rtl">4000</p><p dir="rtl">hour</p></td><td><p dir="rtl">3000</p><p dir="rtl">hour</p></td><td><p dir="rtl">2000</p><p dir="rtl">hour</p></td><td><p dir="rtl">1500</p><p dir="rtl">hour</p></td><td><p dir="rtl">1000</p><p dir="rtl">hour</p></td><td><p dir="rtl">Formula</p></td></tr><tr><td></td><td></td><td></td><td><p>٪13</p></td><td><p>٪25</p></td><td><p dir="rtl">1 a</p></td></tr><tr><td></td><td></td><td></td><td><p>٪15</p></td><td><p>٪29</p></td><td><p>1</p></td></tr><tr><td></td><td></td><td></td><td><p>٪14</p></td><td><p>٪29</p></td><td><p dir="rtl">2 a</p></td></tr><tr><td></td><td></td><td></td><td><p>٪14</p></td><td><p>٪38</p></td><td><p>2</p></td></tr><tr><td><p>٪8</p></td><td><p>٪13</p></td><td><p>٪52</p></td><td><p>٪82</p></td><td><p>٪86</p></td><td><p dir="rtl">13 a</p></td></tr><tr><td><p>٪26</p></td><td><p>٪43</p></td><td><p>٪64</p></td><td><p>٪78</p></td><td><p>٪88</p></td><td><p>13</p></td></tr><tr><td><p>٪11</p></td><td><p>٪36</p></td><td><p>٪88</p></td><td><p>٪89</p></td><td><p>٪89</p></td><td><p dir="rtl">14 a</p></td></tr><tr><td><p>٪10</p></td><td><p>٪20</p></td><td><p>٪79</p></td><td><p>٪87</p></td><td><p>٪87</p></td><td><p dir="rtl">15 a</p></td></tr><tr><td><p>٪74</p></td><td><p>٪81</p></td><td><p>٪83</p></td><td><p>٪84</p></td><td><p>٪85</p></td><td><p>15</p></td></tr>
5 Combinations of inhibited amine stabilizers and benzoate UV light absorbers provide superior shine in accelerated weather.
Example 8 Flame retardation property of a homogeneous polypropylene polymer
High melt strength 341E15 polypropylene homopolymer from ExxonMobil was dry mixed with the aforementioned additives, 0.5% zinc stearate, and 0.1% heat stabilizer.
10 IRGANOX B-225 thermal stabilizer. The formula compound is prepared by extruding on a 25 mm twin screw extruder at a temperature of 195-205 degrees Celsius at a duty cycle of 200 revolutions and a feed rate of 20 kg/hour. The prepared formulations were molded in a 94-UL vertical firing test furnace with dimensions of 0.5 x 5.0 x 0.125 inches.
٦٣٧٤
-١٠٤-
225-IRGANOX B is a 1:1 weight mixture of tris(2,4-ditret-butylphenyl)phosphate and penta-erythritol tartar cyst[3-[3,5-di-tart-butyl-4-hydroxyphenyl[propionate] [.
The following formulas were prepared. The additives were in percentages by weight based on polypropylene.
5 1 control - without flame retardants
<p dir="rtl">2 6% 960 0.6% / AFLAMMIT PCO Disabled amine light fixtures (34)</p>
<p dir="rtl">3 8% 960 0.8% / AFLAMMIT PCO Disabled amine light fixtures (34)</p>
<p dir="rtl">4 6% 960 0.6% / AFLAMMIT PCO Disabled amine light fixtures (47)</p>
<p dir="rtl">5 8% 960 0.8% / AFLAMMIT PCO Disabled amine light fixtures (47)</p>
10 960 AFLAMMIT PCO is an organic phosphorus flame retardant
flame retardant containing 24% phosphorus, available from Thor.
The classifications according to 94-V UL test are mentioned in the following table. 94-UL Test for Flammability
of Plastic Materials for Parts in Devices and Appliances, 5th Edition, October 29,
.1996
15
<tr><td><p dir="rtl">Dryness to paresthesias</p></td><td><p dir="rtl">Dryness due to</p><p dir="rtl">Burning</p></td><td><p dir="rtl">Post-flame time</p></td><td><p dir="rtl">classification</p></td></tr><tr><td><p dir="rtl">the</p></td><td><p dir="rtl">the</p></td><td><p dir="rtl">> 10 s</p></td><td><p>V-0</p></td></tr><tr><td><p dir="rtl">the</p></td><td><p dir="rtl">the</p></td><td><p dir="rtl">> 30 s</p></td><td><p>V-1</p></td></tr><tr><td><p dir="rtl">the</p></td><td><p dir="rtl">Yes</p></td><td><p dir="rtl">> 30 s</p></td><td><p>V-2</p></td></tr><tr><td><p dir="rtl">Yes</p></td><td></td><td><p dir="rtl">> 30 s</p></td><td><p dir="rtl">to fail</p></td></tr><tr><td><p dir="rtl">the</p></td><td></td><td><p dir="rtl">< 30 s</p></td><td><p dir="rtl">to fail</p></td></tr>
The results are listed below.
<tr><td><p dir="rtl">94-UL rating</p></td><td><p dir="rtl">Formula</p></td></tr>
٦٣٧٤
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<tr><td><p dir="rtl">Category</p></td><td><p>1</p></td></tr><tr><td><p>V-2</p></td><td><p>2</p></td></tr><tr><td><p>V-2</p></td><td><p>3</p></td></tr><tr><td><p>V-0</p></td><td><p>4</p></td></tr><tr><td><p>V-0</p></td><td><p>5</p></td></tr>
Example 9 Improving the melt strength of polypropylene
Proper melt strength is an important property in extruded polymer body elements. High melting strength is required to avoid deterioration or silencing of the polymeric film. The elements are formed into a sheet or body shape.
<p dir="rtl">5 When melting the polymer that comes out of the extruder die and during the drawing process in the following machines. Surprisingly, it has been found that improvement in melt strength can be achieved on commercially available high melt strength polypropylenes used in body extrusion applications by mixing the polymer in the melt with certain block or random polymers. Specifically, polyolefin copolymers, known as olefinic block copolymers, such as</p>
<p dir="rtl">10 INFUSE from Dow and VISTAMAXX from ExxonMobil have been found to improve the fusion strength properties of polypropylene and blends of polypropylene and polyethylene as shown below. There is a valuable property, which is the strength of the melting of the extruded body elements. The table shows that while individual high-density polyethylene and co-block polyartolefin individually have low melting strength, there are binary and tertiary combinations with polypropylene, in this case showing high-melting strength polypropylene.</p>
<p dir="rtl">15 HMS (melt strength) has higher melt strength and extension stress at break versus polypropylene with high melt strength alone.</p>
Polypropylene is a high melt strength 341E15 polypropylene homopolymer from ExxonMobil. The polyethylene is ALATHON L 5332CP, a high density polyethylene from LyondellBasell. Olefin block copolymers are 9010 INFUSE or INFUSE
20 9100 from Dow, 6102 VISTAMAXX, or VISTAMAXX 3020FL from ExxonMobil.
٦٣٧٤
-١٠٦-
<p dir="rtl">125 PARALOID K is an acrylic aid for vinyl from Dow, molecular weight 4.0 to</p>
<p dir="rtl">5.0 million, 106 Tg grade M.</p>
The following formulas have been tested. Proportions by weight.
<p dir="rtl">5 1 polypropylene</p>
<p dir="rtl">2 Polyethylene has a high density</p>
INFUSE 9010 3
<p dir="rtl">4 90% polypropylene / 10% 9010 INFUSE</p>
<p dir="rtl">5 90% high density polyethylene / 10% 9010 INFUSE</p>
10 6%70 polypropylene/30% polyethylene has high density
<p dir="rtl">7 63% polypropylene / 32% high density polyethylene / 5% 9010 INFUSE</p>
<p dir="rtl">8 63% polypropylene / 27% high density polyethylene / 10% 9010 INFUSE</p>
<p dir="rtl">9 Polypropylene</p>
15 10%95 polypropylene / 5% 9100 INFUSE
<p dir="rtl">11 90% polypropylene / 10% 9100 INFUSE</p>
<p dir="rtl">12 95% polypropylene / 5% 6102 VISTAMAXX</p>
<p dir="rtl">13 90% polypropylene / 10% 6102 VISTAMAXX</p>
<p dir="rtl">14 95% polypropylene / 5% VISTAMAXX 3020FL</p>
20 15%90 polypropylene / 10% VISTAMAXX 3020FL
<p dir="rtl">16 Polypropylene</p>
<p dir="rtl">17 99% polypropylene / 1% 125 PARALOID K</p>
<p dir="rtl">18 97% polypropylene / 3% 125 PARALOID K</p>
25 19%95 polypropylene / 5%125 PARALOID K
٦٣٧٤
-١٠٧-
The results of Formulas 1-8 are shown below. Vb is the velocity at break (mm/s). F is the force at break measured in cent Newtons (fusion force). Pull rate is the pull rate at breaking ratio of initial velocity to velocity at break, the higher the more is required. Extension pressure is the extension pressure Elongation stress at break in megapascals - the greater the extensibility of the polymer melt
<p dir="rtl">5 polymer melt the more the better.</p><table border="1"><tbody><tr><td><p dir="rtl">Extension pressure</p></td><td><p dir="rtl">Withdrawal rate</p></td><td><p>F</p></td><td><p>Vb</p></td><td><p dir="rtl">Formula</p></td></tr><tr><td><p>1.19</p></td><td><p>21.0</p></td><td><p>22.4</p></td><td><p>471.6</p></td><td><p>1</p></td></tr><tr><td><p>0.52</p></td><td><p>12.0</p></td><td><p>15.6</p></td><td><p>294.7</p></td><td><p>2</p></td></tr><tr><td><p>0.36</p></td><td><p>10.9</p></td><td><p>9.4</p></td><td><p>339.8</p></td><td><p>3</p></td></tr><tr><td><p>1.54</p></td><td><p>20.8</p></td><td><p>25.4</p></td><td><p>525.5</p></td><td><p>4</p></td></tr><tr><td><p>0.46</p></td><td><p>11.3</p></td><td><p>14.4</p></td><td><p>280.6</p></td><td><p>5</p></td></tr><tr><td><p>1.09</p></td><td><p>17.8</p></td><td><p>24.0</p></td><td><p>402.0</p></td><td><p>6</p></td></tr><tr><td><p>1.26</p></td><td><p>20.9</p></td><td><p>24.0</p></td><td><p>458.8</p></td><td><p>7</p></td></tr><tr><td><p>1.47</p></td><td><p>21.3</p></td><td><p>25.9</p></td><td><p>500.7</p></td><td><p>8</p></td></tr></tbody></table>
The results of Formulas 9-15 are reported below.
<tr><td><p dir="rtl">Extension pressure</p></td><td><p dir="rtl">Withdrawal rate</p></td><td><p>F</p></td><td><p>Vb</p></td><td><p dir="rtl">Formula</p></td></tr><tr><td><p>0.69</p></td><td><p>12.8</p></td><td><p>17.6</p></td><td><p>344.6</p></td><td><p>9</p></td></tr><tr><td><p>1.15</p></td><td><p>16.6</p></td><td><p>23.7</p></td><td><p>427.3</p></td><td><p>10</p></td></tr><tr><td><p>0.95</p></td><td><p>16.4</p></td><td><p>21.2</p></td><td><p>390.4</p></td><td><p>11</p></td></tr><tr><td><p>0.95</p></td><td><p>15.0</p></td><td><p>20.1</p></td><td><p>408.3</p></td><td><p>12</p></td></tr><tr><td><p>1.06</p></td><td><p>18.6</p></td><td><p>19.5</p></td><td><p>460.7</p></td><td><p>13</p></td></tr><tr><td><p>0.73</p></td><td><p>13.6</p></td><td><p>16.4</p></td><td><p>382.0</p></td><td><p>14</p></td></tr><tr><td><p>1.26</p></td><td><p>18.5</p></td><td><p>22.2</p></td><td><p>496.5</p></td><td><p>15</p></td></tr>
٦٣٧٤
-١٠٨-
The results of Formulas 16-19 are reported below.
<tr><td><p dir="rtl">Extension pressure</p></td><td><p dir="rtl">Withdrawal rate</p></td><td><p>F</p></td><td><p>Vb</p></td><td><p dir="rtl">Formula</p></td></tr><tr><td><p>0.877</p></td><td><p>14.5</p></td><td><p>18.8</p></td><td><p>374.1</p></td><td><p>16</p></td></tr><tr><td><p>0.704</p></td><td><p>13.7</p></td><td><p>16.1</p></td><td><p>377.6</p></td><td><p>17</p></td></tr><tr><td><p>1.185</p></td><td><p>18.4</p></td><td><p>21.7</p></td><td><p>464.8</p></td><td><p>18</p></td></tr><tr><td><p>1.109</p></td><td><p>16.9</p></td><td><p>21.4</p></td><td><p>454.1</p></td><td><p>19</p></td></tr>
٦٣٧٤
-١٠٩-
Contents29
28 members in 14 offices
Priority claims5
| Document | Office | Kind | Date |
|---|---|---|---|
| 201361883229 | United States of America | P | |
| 61883229 | United States of America | – | |
| 201461969498 | United States of America | P | |
| 61969498 | United States of America | – | |
| 2014002719 | International Bureau of the World Intellectual Property Organization (WIPO) | W |
Members28
| Document | Office | Kind | |
|---|---|---|---|
| CA2923385A1 | Canada | A1 | |
| WO2015044785A2 | World Intellectual Property Organization (WIPO) | A2 | |
| WO2015044785A3 | World Intellectual Property Organization (WIPO) | A3 | |
| AU2014326295A1 | Australia | A1 | |
| IL244447A0 | Israel | A0 | |
| CN105579503A | China | A | |
| KR20160065893A | Republic of Korea | A | |
| EP3049464A2 | European Patent Office (EPO) | A2 | |
| MX2016003734A | Mexico | A | |
| US2016244591A1 | United States of America | A1 | |
| JP2016531962A | Japan | A | |
| US2017137613A1 | United States of America | A1 | |
| BR112016006528A2 | Brazil | A2 | |
| AU2014326295B2 | Australia | B2 | |
| SA516370822B1 | Saudi Arabia | B1 | |
| SA6374B1This record | Saudi Arabia | B1 | |
| US10428204B2 | United States of America | B2 | |
| JP6598768B2 | Japan | B2 | |
| BR112016006528A8 | Brazil | A8 | |
| EP3049464B1 | European Patent Office (EPO) | B1 | |
| US10669403B2 | United States of America | B2 | |
| ES2796486T3 | Spain | T3 | |
| PL3049464T3 | Poland | T3 | |
| IL244447A | Israel | A | |
| IL244447B | Israel | B | |
| BR112016006528B1 | Brazil | B1 | |
| KR102294024B1 | Republic of Korea | B1 | |
| CA2923385C | Canada | C |
Numbers
- Publication
- 6374
- Publication, DOCDB
- 6374
- Application
- 417390189
- Application, DOCDB
- 417390189
Titles2
- Arabic
- تركيبات بولي أولفين لمواد بناء
- English
- Polyolefin Compositions for Building Materials
Classification
- CPC, 42
- C08K3/013
- C08K13/02
- B32B27/32
- C08K5/0008
- C08K5/0041
- C08K5/0058
- C08K5/0066
- C08K5/132
- C08K5/1345
- C08K5/17
- C08K5/32
- C08K5/3475
- C08K5/3492
- C08K5/526
- C08K2201/014
- C08L23/06
- C08L23/12
- C08K3/015
- Y10T428/2495
- C08K5/3435
- C08K2003/2224
- C08K2003/2241
- C08K3/22
- C08K2003/265
- B32B7/02
- C08K2003/0806
- C08K3/01
- C08K3/2279
- C08K3/26
- C08K3/34
- C08K5/005
- C08K5/053
- C08K5/138
- C08K5/52
- C08K5/521
- C08L2205/02
- C08L2205/24
- C08L2207/062
- C08L23/02
- E04D13/15
- E04D5/06
- E04F13/18
- IPC, 4
- C08K5 134
- C08K3 000
- C08K5 017
- C08K5 132