Untitled record

full description

hidden invention

This request is a request from the request No. 11323217, which was filed in the Kingdom of Saudi Arabia on 4/11/1422 AH corresponding to 2/4/3313 CE.

The following indications are related to a general group of styrene-butadiene rubber based on a solution of PO ratio.

solution-based styrene-butadiene rubber and a high percentage of vinyl 5 high from

(SSBR) - made with SSB with a high percentage of styrene and a high percentage of vinyl, modified with a specific percentage of styrene - and its preparation methods.

SSBR rubber with a high percentage of styrene and a high percentage of vinyl is considered a production player as a result of the liberties of polymerization of a polymer. Typically, 13 polar factors known as floaters are added to the polymerization system to achieve modification of styrene floaters. The use of certain buoyant agents can produce an SSBR with a high percentage of vinyl and a low content of styrene tel <6 (a styrene block a sequential styrene unit) than any of the 13:, recalling that the long hill styrene is right be augmented by disruption, for example, by S. Futamura and G. Day who noted disruption by about 18: q

<p>15th Delta was tested at 63°C when the styrene block content was increased from 3 to about 7</p>

<p>: A periodical titled 1987 AD, MILAD RM 1, Afhat RM 29 to 42,. A bag filled with carbon black. On the contrary, a modification of a modified form of styrene can result in better corrosion resistance and better edging resistance, especially in silica materials, according to the inventor of Hattori et al.:</p>

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(143rd Meeting of the Rubber Division of the ACS, Spring 1993, paper

22). Potassium 3,7-dimethyl-3-octylate jam

6531713 For the preparation of soft, low buoyant vinyl in polymer retardant. likewise,

Tarah Acrylamide Rum 6197889 The use of potassium 3,7-dimethyl-3-octylate 5 as randomizer causes a buoyant effect, because of Paralatin, the enzyme weight of the resulting polymer decreased (ranged between 2333-333333 μmol/mol).

In the laboratory of Akmaria Rum 2394768, sodium and potassium alcoholate were used

Hydrophobic low vinyl SSBR.

Tetramethylethylenediamine (TMEDA) is a buoyant carcinogen.

13 TMEDA yields a significantly greater weight gain compared to what is typically observed in anionic polymerization reactions when used for polymerization.

Ratio of styrene with SSBR polymerization of a polymer . 43styrene

Java, in the polymerization of rubber with high glycemic equilibrium.

The asymmetrical weighting of the enzyme in batches allows for anionic polymerization to be carried out by chain transfer, metal insertion, and/or reacting with an emulsion. This reaction reduces the polymer chains that persist at the conclusion of the polymerization reaction. At the present time, the SSBR is typically high in ion chain d le chain modes are modified. Although this chain at the end of the modification can improve the efficiency of the polymerization reaction, it requires that the amount of living chain frameworks be at a higher level than at the end of the polymerization reaction.

33 Moreover, the reaction rate is low and often requires an effect of 5 or 6 hours to reverse the polymerization of the monomer conversion with a current machine.

To choose, the sequencing is a method for the synthesis of SSBR, which has a high percentage of styrene and a high percentage of vinyl with a narrow weight distribution of the enzyme, a monomer conversion effect.

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99, a shorter polymerization time, and a large amount of live chain ends for polymerization of a polymerization are highly sought after.

Description of the invention

Invention No. 1

5 By way of introduction, a polymer that embodies the properties of the present guidelines will have at least the following properties: (a) a styrene block containing between 4 and 6 styrene units between about 2 and about 5X by weight of content aggregate of styrene in polymer; (b) The content of L0g7 ranges between about 30 and about 80 percent by weight of the total amount of 3-butadiene,! ; and (c) a styrene content of between about 4 and about 70 percent by weight of the polymer,

The polymerization process of a polymer comprising units derived from styrene monomer and 1,3-butadiene monomer embodies the properties of the present guidelines for the polymerization of monomeric units in the presence of a starter and a polar agent of formula A;

ap a evening?

1 5 where R and R2 are separately an alkyl group; where R5, R4, R3, 86, R7 and R8 are each selected separately from the group consisting of an alkyl group and a hydrogen; where the molar ratio between the polar agent and the active initiator is greater than about 0.5; where the styrene content in the monomer mixture added in the polymerization of the polymer is greater than about 0,4 wt.% of the total weight of the added monomers; Whereas, the polymerization of 0 2 polymer is carried out at a temperature of less than about 80 °C.

Put;;

Invention No. 2

By way of introduction, a process for the polymerization of a polymer comprising monomeric units derived from 3-butadiene monomestyrene monomer,[ which exemplifies the properties of the present guidelines includes the polymerization of the monomeric J units in the presence of a starter, a first polar agent, and a second polar agent. The first polar factor 5 has the formula (Aa):

R1'R2'NQ-NR3'R4' (AAA)

And the second polar factor has the formula (a):

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where 1, 82, 'R3, and ^R4 are individually selected from the group consisting of 1 0 alkyl group and hydrogen;

0) have a RI group, alkylene and R2 each separately being an alkyl group; The 3?, R7, 86, R5, R4 and R8 are each selected individually from the group consisting of an alkyl group and a .hydrogen.

A polymer that embodies the properties of the present guidelines has at least the following: (a) a content of 15 styrene 355LA5 ranging from about 40 to about 70 wt% of the total weight of the polymer; (b) a vinyl content of between about 30 and about 80 by weight, and preferably between about 40 and about 0, 7 by weight, of the total amount of 3^—butadiene not; and (c) a molecular weight distribution between about 1.05 and about 1.8.

Put;;

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Invention No. 3

By way of introduction, a polymer that embodies the properties of the present guidelines will have at least the following properties; (a) A content of a styrene block containing more than 4 consecutive styrene units between about 0 4 and about 0 7 percent by weight of the total 5 styrene content in the polymer; (b) Vinyl content ranging from about 25 to about 0-8 percent by weight of the lot

Total of 1,3-diene and preferably 1,3-butadiene; (c) The styrene curve ranges from about 0.2 to about 75 wt.% of the total weight of the polymer;

and (d) a molecular weight distribution (Mw/Mn) of 5. 1 or less. Includes a polymerization process

styrene is derived from monomeric comprising polymerization units of a polymer

0 1 monomer and 3-butadiene monomer,! Which embodies the properties of the current guidelines for the polymerization of monomer units in the presence of a starter, potassium alcoholate and a polar agent of the formula A:

R2? NS *

R40R7

where !R and R2 are separately an alkyl group; where R5, R4, R3, 5 1 86, R7 and R8 are each selected separately from the group consisting of an alkyl group and a hydrogen.

Invention No. 4

By way of introduction, a polymer that embodies the properties of the present guidelines will have at least the following properties: (a) a styrene block content containing more than 6 units 20 73,505 m in sequence between about 15 and about 35 percent by weight of the total content of L7355A5

in polymer; (b) Vinyl content between about 25 and about 80 percent by weight of the quantity

Put;;

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The ly of 1,3-butadiene; (c) The styrene content varies between about 25 and about 75 F

Lead by weight of the L weight of the polymer; and (d) a weight distribution (D) (Mw/Mn) of 1.5 or

A to. The polymerization process comprises a polymer consisting of identical monomeric units of styrene monomer and 1,3-butadiene monomer which blocks the properties of the current polymers by polymerizing 5 monomeric units p and iodine initiator, potassium alcoholate and organic ether

It is selected from the following dialkylethers in the form R1-O-CH2-CH(R3)-O-R2, where R1 and R2 represent the monoamine separately, the alkyl fluid b between 1 and 13 carbon atoms, R3 represents methyl, or methyl. Where is the significant ratio between potassium

alcoholate and the base initiator is 3.4 mol/mol or a l. In some embodiments, R1 is methyl 13 or ethyl and R2 is a branched alkyl group and t-butyl, in some embodiments, it is .t-butyl

Brief explanation of drawings

RM-1a: Demonstrates the effect of the addition of ditetrahydrofurylpropane (DOP)

dispersity medicinal agent on tetramethylethylenediamine tate (TMEDA)

Mw/Mn)) for weight distribution.

15th RM1b: shows the effect of adding DOP to TMEDA

dispersity 1.7 mol/mol (Tetate) Tetramethylethylenediamine

(Mw/Mn) for weight distribution.

Rm 1c: It shows the effect of adding TMEDA on (1 DOP mol/mol) a medicinal agent on the tate (Mw/Mn) to equalize the weight of the enzyme.

33 RM3: Explains the effect of adding DOP to TMEDA as a medical agent on the lifespan of a chain frame.

RM 2: shows the effect of adding TMEDA to DOP, a medical agent, on tire yield

The series on life.

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RM4: shows the effect of the axial ratio between DOP/TMEDA on the yield of the chain frame on life.

Description:

1

5 The current inventors - an exciting and exciting power, SSBR with a high ratio of styrene and vinyl with a narrow weight distribution, and a modification of styrene on the hill bearing 46 units so that its ratio ranges between 53 blockyrene and styrene around: 37 Effect of 6 consecutive units, so that the ratios are less than about 33:. Moreover, current inventors have also come - an exciting and unpredictable gesture - that it is important to prepare an SSBR.

13 The former was dissolved with a high proportion of styrene and a high proportion of vinyl using a starter (such as butyl lithium) and a floater (such as ditetrahydrofurylpropane, also known as 2,2-di(2- oxolanyl)propane or DOP) under the following conditions: styrene content ≥43: by weight, the pivotal ratio of DOP/ active initiator ≥ 3.5; and heat polymerization of a polymer ≥ 83 °C.

15th In the context of the current situation, the following definitions should be taken into account:

Expression with polymer

polymerization of polymerization of monomeric units

monomeric units . What is used here, the expression polymer includes the expressions homopolymer b (a polymeric material prepared from one type of monomer), and a copolymer b (a polymeric material prepared from two different types of polymers)

of monomer), and a polymer between an interpolymer (a polymeric material prepared from the effect of two different types of monomer).

The expression with an alkyl group in a straight, branched, or cyclic hydrocarbon chain, without substitution, or with an alkyl with substitution, preferably containing what is between 1 and 33 carbon

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atoms. Distinctive examples of alkyl iodide groups are substituted for use according to pharmacokinetics.

methyl, ethyl, propyl, iso-propyl. The current one: Consider the following, for example: H Al-Har and Ma Abu. cyclopropyl, butyl, iso-butyl, tert-butyl, sec- butyl, cyclobutyl

The expression process, when used to refer to the polymerization of a 5 polymer, refers to non-continuous, continuous, and/or continuous processes.

The expression “may is continuous” or “we are continuous” when used to indicate a polymerization process. It indicates a polymerization process that takes place in the reactor with more than 63 solvents. The monomer belongs directly to the initiator lug, or to the initiator lug, or to the initiator lug, or

13 A continuous match after adding the initiator over a certain period of time.

The expression continuous polymerization is a polymerization process in which solvent fed, monomer(s), and any monomers are supplemented by continuous polymerization. The polymerization of a polymer is successively loyal

15th In models, the reactor is driven by only one reactor.

An expression by the vinyl content of the quantitative percentage of the hydrophobic ratio (or weight) of butadiene iodine in mode 1, 3 in the polymer chain, based on how butadiene is removed (the total amount of polymerized butadiene) in the polymer.

Expression by styrene content in terms of water content (or weight) of styrene in the polymer, 33 based on the weight index of the polymer.

An expression for the styrene content of a styrene block. The weight ratio of the styrene modulated in a series of successive sequences of styrene units is indicated based on the relative amount of styrene polymerized in the polymerized styrene in the polymer.

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Expression by composition of a mixture of materials including a polymer and, optionally, reaction products and/or dissolution products mm^ of the polymer material.

Expression of an active initiator with (nBL,pm) is the amount of initiator (such as organ lithium) that is left in the polymerization reaction and has not been quenched by iodine in the middle of the reaction. Expression is initiator excess initiator

deactivate the (nBL,exc)

. impurities in the system

Expression of the total amount of monomer feed stream per minute of styrene and butadiene, per minute, pushed into a continuous polymerization reactor, 13 and typically, in an ECOOL continuous polymerization reactor.

An expression for the year transformation of the polymer Yar denotes the sleeping transformation of the polymer (such as the rimal transformation

sleep for the polymer, styrene and butadiene) which is determined for the last polymerization reactor.

By way of general introduction, a polymer that fills in the properties of the present rays will set the following properties on eating; (a) Content of styrene block containing between

15th 4 and 6 styrene units range between about 37 and about 53: by weight of the content of God to

styrene p-polymer; (b) The vinyl content ranges between about 23 and about 83 p by weight of the total amount of 1,3-butadiene; and (c) the styrene content ranges between about 43 and about 73 p by weight of the total weight of the polymer.

In some models, the ion-polymer that blocks the properties of the current rays contains a styrene content of 33 styrene block with a trace of 6 consecutive styrene units with no less than about 13

The percentage is by weight of the content of styrene in the polymer. In some models, ion-p-polymer, which blocks the properties of the current products, has a styrene block content with a trace of 6 consecutive styrene units with no less than about 35 pH by weight of the styrene content in the polymer.

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In some models, the polymer that fills the properties of the current styrene is made up of 4 styrene units in succession between about 23 and about 72 ft, which is modified by weight. Some models, meh

Styrene is supplied by 4 consecutive styrene units ranging between about 25 and about 73:

5 wt l th weight of styrene that is modified e.

In some models, the polymer produced in batches according to the current trends has a weight distribution of lyase (Mw/Mn) between about 1.35 and about 3. In some embodiments, the weight of the enzyme is distributed between about 1.1 and about 1.8. In some models, the weight distribution is between about 1.3 and about 1.6.

13 In some embodiments, the polymer produced in continuous cycle according to the current trends is a weighting of the enzyme (Mw/Mn) between about 1.5 and about 3.5. In some models, the weight distribution is between about 1.6 and about 3.4. In some models, the weight distribution is between about 1.8 and about 3.3.

In some models, the polymer that fills the properties of the current revenue has an average weight of 15 days according to the number greater than or equal to about 83333 mm/mol. In some models, the weight is equal

The average according to the number A is less than or equal to about 153,333 ym/mol. In some models, the average body weight is given according to the number greater than or equal to about 233333 m/mol,

In some models, the polymer that fills the properties of the current revenues has an average weight, according to the weight greater than or equal to and about 84,333 m/mol. In some embodiments, the average weight of the enzyme 33 is equal to or equal to about 155,333 m/mol. some models, yoon

The average weight of the enzyme according to the weight A is greater than or equal to and about 213333 m/mol.

In some embodiments, the ion-polymer quenches the current-earning properties of an angle according to ML 1+4 (Mooney at 133°C) between about 33 and about 153, and in some embodiments, the ion-polymer that blocks the current-earning properties of an angle according to ML 1+4 (Mooney at 133

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m) Between about 30 and about 120, in some embodiments, a polymer that embodies the properties of the current guidelines has a viscosity according to Ml 14 (Mooney at 100 C) between about 30 and about 90. Also by way of general introduction, the polymerization process of a polymer comprising monomeric units derived from styrene monomer and 3-butadiene monomer, [according to the current guidelines, involves polymerization of the monomeric units in the presence of a starter and a polar agent, where the polar agent has the formula I:

<img file="SA4498B1_D0001.tif" />

٤5

In some embodiments, R2 j RI separately is an alkyl group. In some embodiments, RI and R2 are individually an alkyl Cl—C4 group. In some 1 0 forms, RI and 52 are both methyl.

In some embodiments, 56, 86, R4, R3, R7 and R8 are each selected separately from the group consisting of an alkyl group and a hydrogen. In some embodiments, 03, 5, R4, 86, R7 and R8 are each selected separately from the group consisting of the hydrogen and the alkyl group C1-C4. In some embodiments, R7, R5, 86, R4, R3, and R8 each 1 5 are selected separately from the group consisting of methyb hydrogen - in some embodiments,

R7, R5t, R6, R4 and R8 are all hydrogen.

In some embodiments, the molar ratio between the polar agent and the active initiator is greater than about H. 0 . In some embodiments, the molar ratio between the polar factor and the active initiator ranges from about H.0 to about 10.

Put;;

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In some embodiments, the styrene content of the added monomer mixture by polymerization of the polymer is greater than about 43 m by weight of the L weight of the added monomers. In some models, it is done

The process of polymerizing a polymer according to the current trends at a temperature of less than about 83 ° C. In some models, the polymerization process is carried out according to the current trends at a temperature range that varies between about

5 13 °C and about 83 °C.

The primers currently preferred to be used according to the current trends include those suitable for anionic polymerizations. In some models, the initiator of use according to current trends is organ lithium (such as alkyl lithium).

Alkyl lithium agents represented for use according to current trends consider the following

Example H hot: n-butyllithium, sec-butyl lithium, tert-butyllithium, n-:

pentyllithium, what abo, and combinations of semen in some models, the prefix is ​​on -n

. butyllithium

In some embodiments, the transformation of the polymer is less than about 96 m by weight from the per cent of the monomer feed stream, in some models, the transformation of the polymer is about 98 m by weight. In some embodiments, the transformation of the polymer is better

From about 99 p mamma by weight.

In some embodiments, the ion-polymer that quenches the properties of the current dimer has a vinyl content ranging between about 23 and about 83 p, which is by weight of the total amount of 1,3-butadiene. In some embodiments, the vinyl content varies between about 43 and about 73 pH by weight.

33 In some models, the ion-polymer that blocks the properties of the current styrene contains a styrene block that contains between 4 and 6 styrene units ranging between about 37 and about 53 by weight of the styrene content in the polymer.

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In some models, the polymer that blocks the properties of the current rays contains a styrene block with more than 6 consecutive styrene units with no less than about 13

The percentage is by weight of the L content of styrene in the polymer.

In some models, an ion-polymer that blocks the properties of the current citrine content

5 A styrene block with effect of 6 successive styrene units with a content of less than about 35 p by weight of the styrene content in the polymer,

It is currently preferable for polymerization of a polymer to occur according to current trads in solvents, whereas hydrocarbon solvents are currently preferred. In some embodiments, the polymerization solvent contains alkane. Some models, please

13 Solvent polymerization on cyclohexane. In some embodiments, the solvent polymerization consists of a mixture of cyclohexane with one or more additives alkane.

Also by way of general introduction, the polymer is graded according to the current trends with a process of the type described herein.

In some models, polymers according to current trends are modified using a modifying agent (or 15 modifiers). Examples of modifying agents consider the following, for example:

Modifiers, amides, thioglycols, silicon alkoxides, silane-sulfide modifiers

From silane-sulfide, ma-abo, and minya combinations.

In some embodiments, the polymer can be modified according to the current trends using chain-link modification and/or interactions. Modifiers suitable for the chain frame may be selected and/

33 Or the coupling agents, according to the use of the mist and the appropriate substance. Consider examples of R-Arne coupling agents, for example hot H: tin tetrachloride, divinylbenzene, silicon tetrachloride, alkoxysilanes mercury, mAPO, and mina combinations,

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Examples of modified substances: Consider the following, for example: sulfenyl halides, what is mentioned in the order document, Acorup Rm 1316674, isocyanate, benzophenone, mercaptan, hydroxyl mercaptans, mercaptans, mercap, sulfur, m, 44,4, etc., documents, etc. ACOROP document No. 3224343, including the amendment

5 Consider the following, for example, hot: amines, amides, nitrile, and nitrile. P.O. 183141, and in the Parliament of the Republic of Korea, C. No. 4413341. In some embodiments, silanes are used, including Via, for example hot, epoxy-containing silanes.

13 To modify the polymer chain to use suitable silica fillers

What is Marouh, for example, in the ACORP application document RM-A-399374, ACORP application

Examples

Supplementary Amendment Articles and/or Substantive Amendment Articles These Articles are indicated in the Requisition Document

States RM 124665/3339.

15th By way of general introduction also, the soil covering the properties of the present grades contains a polymer of the type mentioned herein, in some embodiments, the composition according to the present grades also contains oil. In some embodiments, the composition according to the current trends also contains oil with an amount ranging between about 5 and about 43 percent by weight of the polymer weight. In some models, the composition according to the current tariffs contains oil.

33 In some embodiments, a formulation according to the present regulations contains a polymer of the type mentioned herein and one additive each. In some embodiments, the polymer is combined and/or reacts with one appropriate substance or effect, a vulcanization agent, and/or optionally one other host substance or effect, such as: uncrosslinked arsenic coupling agents

35 elastomeric polymers that do not have similar bonds (such as traditional elastomeric polymers

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The non-reactive bonds and the unreacted is a modified substance, and it has not been prepared and ready, and what is the abo, and combinations of them.

In some embodiments, formulations according to the present trends contain one or more suitable substances, acting as strengthening agents. Distinctive examples of suitable suitable materials, consider the following, for example, in hot: carbon black, silica, dual-phase filler of carbon and silica, magnesium carbonate, calcium carbonate, clay, apo, and ma. . In some models, a mixture of carbon black and silica is used, and the two-phase materials of carbon and silica are used, or a mixture of the dual-phase filler of carbon black and /13 or silica is used.

In some models, carbon black is prepared using the oven method, and if a specific surface area protects nitrogen adsorption between about 53 and 333 m 3 / day, and DBP oil absorption occurs between about 83 and about 333 ml / 133 m. 15 Such as FEF, ISAF, HAF or carbon black from the mouth of SAF). In some models, carbon black is used, of the same type. In some embodiments, carbon black or silica is warmed in an amount ranging between about 3 and about 133 by weight. To be removed by weight of polymer by weight. In some models, carbon black or silica is added to a percentage ranging between about 5 and about 133 by weight. In some models, carbon black or silica is incubated in an amount ranging between about 13 and about 133.

33 by weight. In some embodiments, carbon black or silica is added with an amount ranging from about 13 to 95 removed by weight.

Finally, by way of general presentation as well, a product that simulates the characteristics of the current revenues contains a single ingredient on each component of this mixture. In some models, the product is a component. In some embodiments, the product is a shoe component.

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The following examples, and I see the expressions represented, illustrate the properties according to the current trends, and they are presented only for the sake of clarification. This is led by examples of limiting the scope of ancillary protection elements or its equivalent.

examples

The monomer transformation was determined by measuring the tris of alkali materials in a polymer solution upon polymerization of a polymer. Any attempt is made for the raw materials when

133 By weight shift: butadiene (mBd) and styrene (mSt) polymer

Sleeping with dementia:

: TSC max= (mBd + mSt)/(mBd + mSt + mpolar agent + mBL + mcyclohexane) * 100

A sample was drawn from the polymer solution ranging between about 1 o'clock and about 13 o'clock, according to the amorphous transformation of the monomer 13, from the reactor directly from an Erlenmeyer urra with a capacity of 333 ml filled with

<p>53 ethanol (ml). Erlenmeyer's fill was weighed by sampling ("A") and after sampling ("B"). Ethanol-precipitated polymer was sieved on a weighted paper filter (Micro-glass, 93 mm diameter, MUNKTELL, weight “C”), and typified at 143 °C, using a Yaz HR73 moisture analyzer</p>

<p>15th (Mettier-Toledo) until the first showed a constant weight. Criterion 5 was used. Finally, a second tyveh period was carried out using 4 higher criteria to try on the polymer mound “D” for the sample. The fiber content of the sample was calculated.</p>

:TSC= (DC)/ (BA)*100

The sleep shift of the polymer was calculated as 100*TSC/TSC max:

<p>33 The lysosome weight and lysosome weight distribution of the polymer were quantified using Arvia chromatography-exclusion (SEC) at 43°C based on standard polystyrene levels. A sample of 9-11 (polymer mM) was dissolved in (13 ml tetrahydrofuran) to make a solution. The solution was filtered using 3.45 μm scales. Sample 133 was fed.</p>

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Meirou liter de-column GPC (1100 Hewlett Packard system 1100 µm POE 13 PLgel, MIXED-B columns). The following parameter was used: Refraction Index-detection as the detector for analyzing the molecular weight. Weight as polystyrene based on standard levels 5 (polystyrene EasiCaf PS1 (Easy A and B) from Polymer Laboratories. RM

The average lyzyme weight according to the number (Mn) and the average lyzyme weight according to the weight (Mw) are given based on the standard levels of polystyrene. The weight distribution of the lyase was expressed as the D = Mw/Mn dispersity.

The vinyl and styrene content of L was measured using 1H-NMR, by a method:

13 21561-2005 ISO. Using a BRUKER Avance NMR Spectrophotometer,

433 The styrene content of a styrene block, which consists of a trace of 6 successive styrene units, was determined according to the atomization method:

Rubber Chemistry and Technology, 1981, 54, No. 4, P Y. Tanaka et al,

15th 685-691 using ortho-ph-proton that gives us a resonance at a higher

From 6.7 ppm.

The content of the styrene block, which consists of 4 consecutive styrene units and traces, was determined according to the method carried out in the word document R 69713963 using the relative tool ortho and Ph-proton94.

33 The content of a styrene block, which consists of between 4 and 6 sequential units, was calculated from the difference between l of the previous styrene block content.

Mooney ML (133 ML) 4+1

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Molasses measured according to Mooney for polymers (without lubricant and oil) according to ASTM D (2004) 1646, preheating time of 1 min, rotor firing time of 4 m, at hot tubs of 4 +1 133 °C (133 ML ° C) on Yaz MV2000 E from Alpha

.Technologies

5 Comparative example RM1 (using DOP, 1 mol/mol, styrene p-monomer ratio: 31:, 65

°m(

Cyclohexane (355 mM) was added into a 3 liter reactor of nitrogen-purged stainless steel pulp washed with 1,3-butadiene (25.55 mM), and 9.45 styrene (9.45 mM). , and DOP 3.3737 (ml .).

13 35 mol: by weight a solution of n-cyclohexane (butyl lithium /DOP activator mol/mol 1 mol). The reaction was started by adding the following moles of n-butyllithium as 3.6378 mol / molex 3.1 M n-butyllithium solution:

amps and 3.3737 nBL,pm mmol for the reaction. The mixture was heated to 65 °C, stirring. The reaction was resumed after 23 minutes by adding a minimalist agent methanol. 4,6-bis . jam has been introduced

IRGANOX 1520 (Ciba) octy hiomethyl-o-cresol 15

antioxidant .

A sample was drawn using a sampling tube fitted with a stopcock stopper and needle to determine the content of the slurry. The TPL conversion ratio of 133: has been measured.

The resulting polymer was analyzed using D=, 326158 Mw, 315586 Mn GPC:

33 1.395.

The exact dosing and styrene block content were measured using 1H-NMR. The following products were tried: 1,2-polybutadiene (vinyl: 31.3 styrene, computed on the basis of the ratio of 63.3 (butadiene): citrine to styrene block (&lt; of 6 units): styrene: 3, styrene block: citrine to styrene block: 4- 6 13 :styrene units :.

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Assuming that the ratio of DOP/nBL,pm and heat saturation is in my intrinsic range, the styrene content of which is 31: It is low to achieve an initial content of styrene, which is 6 block styrene units.

Comparative Example Rm3 (Using DOP, 3.4 mol/mol, styrene ratio of monomer 43:, 63

5 °m(

The cyclohexane was treated with 3 L. (355 mM) in a core reactor using olea-free, nitrogen-purged stainless steel, with a capacity of 3 L. DOP mmol, 32.28: P-cyclohexane solution was fed to the reactor bucket (butyl lithium /DOP nAT mol/13 mol 3.2974). The reaction was started by adding the following hydrates of n-butyllithium

3.4451 mol/mm V solution: 3.23 mmol nBL,exc: cyclohexane for the amps conversion and 3.3647 nBL,pm mmol for the reaction. The mixture was heated to 63 °C, stirring.

The polymer was rotated after 133 minutes by adding 3.375 TMS (3.375 mol/mol), the remaining air-coupled polymer was added after 23 minutes by adding a world agent methanol. IRGANOX 15 1520 antioxidant was introduced.

A sample was drawn using a sampling tube fitted with a stopcock stopper and needle to determine the content of the slurry. The TPL transformation ratio of 97.34 has been measured:.

The resulting conjugated polymer was analyzed using D, 281586 Mw, 333339 GPC 1.7: 19 at 32: conjugated polymer.

33 The exact dose and styrene block content were measured using 1HNMR. The following products were tried: 1,2-polybutadiene (vinyl,: 41.4-styrene, computed on the basis of the ratio 47) butadiene: styrene block (&lt; of 6 units 2) styrene:, styrene block, dependent on 4 -6 34: styrene units:.

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Although the styrene and heat ions content are in my estimation range, the ratio of DOP/Nbl,pm to 3.2974 is low enough to achieve an initiating content of styrene-6 styrene block units.styrene units.

Comparative example Rum2 (using 3.4 DOP mol/mol, styrene p-monomer ratio 43:85 5°C)

The cyclohexane (355 mM) was refluxed in a nitrogen-purged 3 L reactor from stainless steel (1,3-Butadiene (37 m), and 18 (3.135 m), and 3.135 m), styrene-washed reactor. DOP mmol, 32.28: p-cyclohexane solution (fed into the reactor bucket (butyl lithium / nat mol DOP / 13 mol 3.2974). The reaction was started by adding the following quantities of n-butyllithium immediately

3.4451 mol/ym V solution: 3.23 mmol nBL,exc:cyclohexane mmol for the amps conversion and 3.3647 nBL,pm mmol for the reaction. The mixture was heated to 85 °C, stirring. The polymer was stirred after 23 minutes by adding (3.375 TMS mol/mol).

A sample was drawn using a sampling tube fitted with a stopcock stopper and needle to determine the content of the slurry. TPL turnover ratio of 95.63: has been completed.

The resulting conjugate polymer was analyzed using D=,278349 Mw, 313593 GPC 1.7 95: Mn at 33.2: conjugated polymer.

33 The exact dosing and styrene block content were measured using 1H-NMR. The following products were tried: polybutadiene-2,1 vinyl,: 43.1 styrene, calculated on the basis of the ratio of 22.4 (butadiene:, styrene to styrene block (&lt;6 units).

14 :) styrene 33: styrene units: styrene block

:.

٤٤٩٨

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Although the styrene content is optional, the proportion of butyl lithium / DOP that is wet is 3.4 you are low, and the temperature is wetted at 85 °C.

.units

5 Example Rm 1 (use 1, DOP mol/mol)

The cyclohexane (5338.11 mm) was refluxed in a nitrogen-purged 13 L reactor from pure stainless steel pulp and fed with 1,3-Butadiene (2.11 mm) (1,3-Butadiene (217.38 mm), 217.38 mm) and washed with nitrogen-purged , and 1.1866 DOP mmol) below the reactor (butyl lithium /DOP 3.9838).

13 The mixture was heated to 53 °C, stirring. The amps were calibrated in the system by adding butyl lithium in batches. Upon verifying the end point, polymerization of a polymer was started by adding an amount of butyl lithium ionizer nBL,pm of 1.3398 mmol (3.3585 mol/m cyclohexane solution) using a stirring pump for 1 minute and 33 seconds. polymerization of a polymer

15th The reactor ran at 65 °C for 23 minutes. The reaction was repeated after 333 minutes with the addition of a minimal agent methanol. IRGANOX 1520 antioxidant has been introduced.

A sample was drawn using a sampling tube fitted with a stopcock stopper and needle to determine the content of the slurry. The TPL conversion ratio of 99.36: has been measured.

The resulting polymer was analyzed using GPC: D, 755343 Mw, 587525 Mn

33 1.385. The exact triglycerides and styrene block content were measured using 1H-NMR.

The following products were tried: 1,2-polybutadiene (vinyl: 55.9 styrene, based on the ratio of 49) butadiene: styrene block (&lt; of 6 units: 8: styrene: 4 mL styrene block on styrene block styrene). 6 styrene units: 27:.

٤٤٩٨

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Example R3 (use of DOP 1, mol/mol)

cyclohexane (31326.28 yum) was added to a 43 L nitrogen-purged reactor of pureed 1,3-Butadiene (828.12 yum) stainless steel, and 4. (1567 DOP mmol) 5 was fed to the reactor bucket (butyl lithium /DOP mmol/ 1.3934 mol).

The mixture was heated to 53 °C, stirring. The electrodes were calibrated in the system by adding a step by step butyl lithium. Upon verification of the end point, polymerization of a polymer was started by adding a water of butyl lithium nBL,pm. Wet 2.8351 mmol of -n 3.3585 butyllithium mol/m p-cyclohexane solution) using a whisk pump about 13 minutes. The polymerization of a polymer began, the temperature of the reactor increased to 65 °C during 23 minutes, the transformation was completed after 93 minutes. A sample was taken and the resulting polymer was analyzed using D, 628345 Mw, 538621 Mn: GPC 1.337, the microarray and styrene block content were measured using 1H-NMR.

The reaction was carefully done with the addition of Darn's agent, and at the end the remaining sequencing sequencing was followed by 15 minutes after 23 minutes with the addition of the minimum agent methanol. IRGANOX 1520 antagonist has been entered

for the antioxidant block,

The following products were tried: 1,2-polybutadiene (vinyl: 52.8 styrene, calculated on the basis of the ratio of 47.6 (butadiene): styrene block (&lt; of 6 units): styrene: 8 styrene block: styrene block: 4- 6 styrene units: 33 27 :.

Example R2 (use of styrene: DOP, 41)

Cyclohexane (31194.98 μm) was added over a 43 L nitrogen-purged reactor from stainless steel pulp.

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(1,338.12 mmol), (1,3-Butadiene ym), (821.75 styrene ym), and (3.2136 mmol DOP) were fed to the reactor bucket (butyl lithium /DOP nmol/ 3.9833 mol).

The mixture was heated to 53 °C, stirring. The amps were calibrated in the system by adding butyl lithium in batches. Upon verification of the end point, polymerization of . is initiated

5 a polymer by adding a quantity of butyl lithium nbl,pm. Wet 3.2534 mmol of n- 3.3585 (butyllithium mol/m p-cyclohexane solution) using a stirrup pump for about one minute, when, then, the polymerization process of a polymer rose. The reactor was cooled at 65 °C for 23 minutes, after 313 minutes, the reaction was carried out by adding worldly agent methanol.

. antioxidant 13

A sample was drawn using a sampling tube fitted with a stopcock stopper and needle to determine the content of the slurry. The TPL transformation ratio of 96.24 has been measured:.

The resulting polymer was analyzed using D, 3578387 Mw, 1653619 Mn: GPC

1.56. The exact triglycerides and styrene block content were measured using 1H-NMR.

15th The following products were tried: 1,2-polybutadiene (vinyl: 41 styrene, calculated on the basis of the ratio 46.5 (butadiene:), citrine to styrene block (&lt; of 6 units), styrene:, styrene block: styrene: 6 39, stylish units:.

Example Rum 4) use of styrene: 46.5, DOP

The cyclohexane (31315.19 μm) was treated in a lye-free reactor and washed with nitrogen-purged 43 liters of stainless steel pulp.

(974,3-Butadiene yum), (888.15 styrene yum) and DOP (3.16139 mmol) were fed to the reactor (butyl lithium /DOP nat mol/ 3.9344 mol).

The mixture was heated to 53 °C, stirring. The amps were calibrated in the system by adding butyl lithium in batches. Upon verification of the end point, polymerization of . is initiated

٤٤٩٨

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a polymer by adding a quantity of butyl lithium nBL,pm saturated 3.326 mmol of -n- 3.3585 (butyllithium mol/m p-cyclohexane solution) using an agitating pump for about one minute, when, then, the polymerization of the polymerization of a polymer was started. At 65 °C in the reactor for 23 minutes, a sample was withdrawn after 133 minutes 5 using a sampling tube fitted with a stopcock and a needle to determine the content of the alkali.

The polymer was analyzed using GPC: 1.386 D, 1117669 Mw, and 868986 Mn. The polymer was stirred after 23 minutes by adding (3.378 mol/mol TMS). The reaction was thoroughly done after 343 minutes by adding a worldly agent methanol. The anti-oxidant IRGANOX 1520 was entered.

. antioxidant 13

The polymer was analyzed using 1.59 D, ​​1563337 Mw, 983413 GPC: Mn at 17: AT Arn. Accuracy and styrene block content were measured using -1H NMR. The following products were tried: 1,2-polybutadiene (vinyl,: 46.5 styrene, calculated on the basis of the ratio 43.2 (butadiene): styrene block (&lt; of 6 15 units): 9 styrene: styrene block: styrene block: 4 -6 styrene units: 43:.

Comparative Example Rum 4

The reaction was carried out in two CSTR reactors in series. The fuel for the ACCOOL reactor is 6.2 liters and 33 liters, and the second is 13.6 liters.

The sulfur has been characterized with a helicoidal stirrer suitable for mixing solutions of high viscosity solutions. The surprises were postponed and we were full of hope. By using the external circulation of water in the reactor rungs, the required temperature was regulated. It was fed with monos (1,2-) 1,2-Butadiene, DOP, cyclohexane, butadiene, styrene.

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Bde (and n-butyllithium loll Ars reactor Akol provider standards for the flow of the hill (Micromotion) allow the organization of current required nutrition and ensure a steady flow occurs. Was purified cyclohexane bam Arhr deceitfulness column of alumina. The aim of the initiator) n-butyllithium in cyclohexane (at the entrance to the reactor Akol. DOP and 1,2-butadiene were diluted in 5-cyclohexane in order to enable the synthesis of the controlled hydrates of the reaction. Alkaline waters are atomized, for example, the atomization of the solvent, such as the cyclohexane feed stream.

A ratio of monomer was used in the 13:13 feed stream. The following conditions were used in this soil: 44 butadiene: styrene: wt: 56: wt, DOP/nBL,pm (mol/mol) 3.18. The two reactor thermocouples were maintained at 85°C. of mortars and solvent to achieve a baking time of 45 minutes in the cooler reactor and 93 minutes in the cooler reactor

The second reactor. The following quantities were fed into the Ecool polymerization reactor 5.21 sty: reactor first µmol/min, 7.34 Bde µm/min, cyclohexane 93.57 µl/min, 3.3693 nBL,pm mmol/min, DEXc 3.164 mL/min, 3.3364 mol/min DOPc 3.1n mmol/minute, 1.3-3.131 Bde mmol/minute.

15th Inferior factor methanol and IRGANOX 1520 (phr3.15) antioxidant were added to the polymeric solution outside the second reactor. A transformation was attempted to YPL95: outside the edible reactor, and the attempted mol was transferred outside the second reactor.

The polymer released from the second reactor was analyzed using GPC titrated with polystyrene, 354734 Mn mm/mol, 537879 Mw mm/mol, 1.994 MWD. The 33 micrograms and styrene block content were measured using 1H-NMR. The following products were tried: 1,2-polybutadiene (vinyl) : 44.5 styrene, computed on the basis of the ratio 55 (butadiene: styrene block (&lt; of 6 units: 2) styrene: styrene block: styrene block: 4- 6 .: 35: styrene units

You are lysoid according to 4+1 Mooney ML for products z 69.1.

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The ratio of DOP/nBL,pm and the content of styrene I is in the incremental range, and you do not know the temperature of the reaction is high, so that SSBR Po 35: styrene block styrene units have been tried on 4-6 styrene units.

Ex 5 RM 43 T, Continuous Polymerization °C, DOP/initiator

5 (Natent 3)

The copolymerization of styrene-butadiene was carried out using the previous conditions. A ratio of monomer / lable feed stream 13: was used. The following conditions were used in this environment:

44 butadiene: styrene: wt: 56: wt, DOP/active 13 lithium (mol/mol) 3.44. The two reactors’ tubes were kept at 43°C. The water flow from the lubricant effluent was regulated. Grocery time is 73 minutes in the Akol reactor and 143 minutes in the second reactor. The following quantities were fed into the Ecole 2.41 Sty polymerization reactor: polymerization reactor first μm/min, 4.52 Bde μm/min, 58.33 cyclohexane μm/min, 3.3574 nBL,pm mmol/min,

15th 3.33729 nBL,exc mmol/minute, 3.14 DOP mmol/minute, 1, 3-Bde

3.31327 mmol/minute.

88.97: A lower factor methanol and IRGANOX 1520 (0.15 phr antioxidant) were added to the polymeric solution outside the second reactor. A transformation of 88.97 was attempted outside the edible reactor, and an attempt was made to transfer the salt outside the second reactor.

33 The polymer released from the second reactor was analyzed using GPC titrated with polystyrene: 1.817 MWD, 275572 Mw, 336733 Mn. The exact composition and content of styrene block were measured using 1H-NMR. The following products were tried: styrene 46:, polybutadiene-2,1 (vinyl), calculated on the basis of the ratio of 71.5 (butadiene)

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<p>:, citrine styrene block (&lt; of 6 units 9 :) styrene:, citrine styrene block: 4-6 43 styrene units:.</p>

Lymphatic according to 4+Mooney ML1 for the products you are 54.7.

The ratio of the DOP/active initiator, the styrene content, and the heat rate I am in the range of my preferences. Tried 5 on SSBR Output with trace of 33: styrene block.

.styrene units 6-4

invented rum 3

The current inventors, using an exciting and versatile method, have introduced a polymerization process to prepare SSBR with a high percentage of styrene and a high percentage of 13M vinyl. for Air) In some models, it is less than 2 hours. What will happen later, the research process uses the finest combination of a first and second polar agent. In some models, the first and second polar agents, the first and second polar agents, correspond to Warren TMEDA and DOP, respectively.

<p>15th Moreover, the current inventors have also come up with an exciting tool that is surprising that the use of certain combinations of chemical and second electrode agents (such as DOP and TMEDA) results in not only a narrow distribution of the enzyme weight of the polymer upon the completion of the polymerization process of the polymerization of a polymer. It will also not significantly increase the lifespan of the polymer chains upon completion of the polymerization of a</p>

<p>33 Compared with the use of polymer (tetramethylethylenediamine (TMEDA only, what u described in the Rum 3, or when you use the DOP only, what u described in the Rum 2. ATA current inventors also Anu was achieved Ntamj Lleida when the scourge Khaah ratio between TMEDA / DOP between About 3.5 and about 1 mole / mole, which is shown in Rum 4. By choosing, what will be done with more optimism. Indeed, the current inventors achieved - an exciting progress</p>

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For the tool and a flexible air - the development of RF weight-distribution using a combination of polar factors

Compared to using TMEDA only, RRF is life-saving as compared to using DOP only.

In the context of the current situation, the following definitions should be taken into account:

5 The term polymerization of monomeric units refers to a substance prepared by polymerization of monomeric units. What is used here, the expression “polymerb” includes the expressions with a homopolymer B (a polymeric material prepared from one type of monomer), with a copolymer B (a polymeric material prepared from two different types of monomers), and with an interpolymer between (a polymeric material 13 prepared from the effect of two different types of monomers).

The term “fluid” refers to a straight, branched, or toroidal hydrocarbon chain, with substituents or iodides with substituted, preferably containing between 1 and 33 carbon atoms. Distinctive examples of alkyl iodized groups substituted for use according to current trends consider the following for example:

methyl, ethyl, propyl, iso-propyl, cyclopropyl, butyl, iso-butyl, tort-butyl, 15

sec- butyl, cyclobutyl, and what abo.

The expression process, when used for a period of time, refers to the polymerization of a polymer that includes continuous, non-continuous, and/or continuous processes.

The expression “vinyl content” refers to the water content of the methanol (or by weight) butadiene iodine in the situation.

33 1, 3 in the polymer chain, based on the evidence of butadiene (no percent of polymerized butadiene) removed

polymerized butadiene ( q polymer .

The expression “styrene content” is a hydration ratio (or weight) of styrene in the polymer, based on the weight of the polymer.

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The term "composition" refers to a mixture of materials including a polymer and, optionally, reaction products and/or degradation products made up of the polymer material.

The term “active initiator” (nBl, pm) refers to the amount of initiator (eg an organic material containing lithium) that is involved in the polymerization reaction and that is not damped by the impurities present in the reaction medium.

By way of general introduction, a process for the polymerization of a polymer comprising the noose monomeric units of styrene monomer and 3-butadiene monomer,! According to current guidelines it contains the polymerization of monomeric units in the presence of an initiator, a first polar agent, and a second polar agent. In some embodiments, the first polar factor has 10A of the form (A):

R1'R2'NQ-NR3'R4' (AAA)

In some embodiments, the second polar factor has the form (a):

^٠'7, 2? evening?

In some embodiments 01, 52, 03, and R4 are each individually selected from the 1 5 group consisting of a hydrogenjalkyl group, in some embodiments, 31, 52, 83, and R4 are individually selected from the group consisting of Hydrogen Walk 9-0 alkyl group . In some embodiments, 31, “R3, R2, and R4 are each selected individually from the group consisting of methyb hydrogen. In some embodiments, 31, 52-, R3, and ^R4 are each

.hydrogen

-٣١-

In some embodiments, Q represents alkylene fluid. In some embodiments, the fluid alkylene has the formula -CH2n)-, where n is a whole number equal to or greater than 3, in some embodiments, n t1 is 3 (i.e., n is a whole number in some forms, ethylene), Ton 2 (i.e. Ton Q and propylene).

5 In some models, R1 and R2 alone represent an alkyl fluid, in some models, R1 and R2 are alkyl fluid separately, which is a C1-C4 alkyl fluid. Some models, R1 and methyl R2 are each.

In some models, R7, R6, R5, R4, R3, and R8 are chosen separately from the fluid that consists of alkyl fluid and hydrogen, in some models, R5, R4, R4, R6 and 13 are chosen separately. A unit of fluid consisting of hydrogen and alkyl fluid C1-C4. In some embodiments, R7, R6, R5, R4, R3, and R8 are selected separately from the fluid that consists of hydrogen and methyl. In some models, R3, R7, R6, R5, R4 and R8, no hydrogen is present.

In some embodiments, the quenching polar agent according to current trends is 15 (tetramethylethylenediamine (TMEDA). In some embodiments, TMEDA is used.

BP more than 3.2 mol/mol. In some embodiments, TMEDA is used more than 3.4 mol/mol. In some embodiments, TMEDA is used more than 3.5 mol/mol.

In some models, the second polar factor according to current trends is

2,2-di(2-oxolanyl)propane (also known as ditetrahydrofurylpropane)

33 or DOP). In some models, DOP is used at a rate greater than 3.3 mol/mol. In some models, DOP is used with a greater than 3.2 mol/mol. 3.5 mol/mol.

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In some models, the axial ratio between the second polar factor and the acoustic factor (such as DOP/TMEDA) ranges between about 3.31 and about 13. In some models, the axial ratio ranges between about 3.1 and about 2.

In some models, the pivotal ratio ranges between about 3.2 and about 1.

5 In some embodiments, the content of styrene p-polymer according to the current rates ranges between about 33 and about 83 p by weight of the total weight of the polymer. In some models, the content is gone

styrene is between about 43 and about 73 F, which is the weight of the polymer.

In some embodiments, the vinyl content of the polymer varies, according to the current rates, between about 23 and about 83 p by weight of the mechanical amount of 1,3-butadiene. In some embodiments, the vinyl content of the polymer varies according to the current rates between about 43 and about 73 by weight of the mechanical amount of 1,3-butadiene.

In some models, the polymer that fills the properties of the current revenues is a weight distribution between about 1.35 and about 1.8. In some models, the weight distribution of the enzyme is between about 1.1 and about 1.7. In some models, the weight distribution is between about 1.3 and about 1.6.

15th In some models, the polymer that fills the properties of the current revenues has an average weight according to the number greater than or equal to about 133,333 mm/mol. In some models, the average weight of the enzyme is given according to the number greater than or equal to about 153,333 mm / mol. In some models, the average weight of the enzyme is given according to the number greater than or equal to about 233333 m/mol.

In some models, the polymer that fills the properties of the current imports has an average weight of 33, according to the weight greater than or equal to about 183,333 mm/mol. In some models, the average weight of the enzyme is given according to the weight greater than or equal to about 333,333 mm / mol. In some embodiments, the average lysosome weight is calculated according to the weight r or equal to about 263,333 mmol/mol. In some models, the polymer according to the current trends has only one transitional heat matrix for mixing.

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(glass transition temperature (Tg). In some models, Tg ranges between -53°C and 33°C. In some models, Tg ranges between -23°C and 13°C.

In some models, the pivotal ratio between the causative agent and the active initiator is about about approx

3.2. In some models, the pivotal ratio is larger than about 3.4. In some models, the pivotal ratio is 5, tn, more than about 3.5.

In some models, the pivotal ratio between the second pole factor and the active initiator tun aper of

About 3.3. In some models, the pivotal ratio is larger than about 3.2. In some models, the pivotal ratio is larger than about 3.5.

The primers currently preferred to be used according to the current trends include those suitable for polymerization processes 13 anionic polymerizations. In some models, the initiator is used according to

The current nitrates are organ lithium (eg alkyl lithium). Representative alkyl lithium agents to use according to the current nitrates consider the following for example:

n-butyllithium n-butyllithium, sec-butyl lithium, tert-butyllithium, n-

pentyllithium, ma abo, and semen combinations, in some models, the prefix is ​​on -n

. butyllithium 15

It is currently preferable for polymerization of a polymer to occur according to current trads in solvents, whereas hydrocarbon solvents are currently preferred. In some embodiments, the polymerization solvent is an alkane. In some embodiments, the polymerization solvent is cyclohexane. In some embodiments, the polymerization solvent 33 comprises a mixture of cyclohexane m alkane with one or more additives.

Also by way of general presentation, the polymer is graded according to the current trads with a process of the type described herein. In some embodiments, a polymer that satisfies the properties of the present reflux will have the following properties if: (a) the styrene content ranges between about 43 and about 73 percent.

by weight of the weight of the polymer; (B) The vinyl content varies between about 23 and about 83 pH

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by weight of the daily percentage of 1,3-butadiene; and (c) a weight distribution between about 1.35 and about 1.8.

In some embodiments, the polymer is modified according to current trends using a modifying agent (or modifying agent). Examples of modifying agents include, for example, amines, mercury,

5 Bitter amides, Bitter silicon alkoxides, thioglycols, Modifiers of -silane sulfide, Ma Abo, and Minya combinations.

In some embodiments, a current adjustment of the polymer can be made according to the current trends using chain-route adjustment and/or interactions. Suitable modifiers for chain models and/or Arran coupling agents may be selected according to the use of the mist and the suitable material.

13 Consider examples of coupling agents, such as the hot H: tin divinylbenzene, silicon tetrachloride, tetrachloride, alkoxysilanes, etc., and menia combinations.

Examples of Modifying Substances Consider, for example, the following: sulfenyl halides, sulfenyl halides, what is not mentioned in the application document, Acorup Rm 1316674, isocyanate, benzophenone, mercury

15th Hydroxyl mercaptans, amides amides, acrobe rm 3464478. The nitrite was modified from what is not in the application document, ACOROPE RM 548799, ACOROPE application RM 513413, ACOROPE application RM 451634, and ACOROB application

33 No. 183141, and in the Republic of Korea, No. 4413341. In some models, buttermilk is used.

silanes including, for example, epoxy-containing silanes for modifying the polymer chain to use in silica fillers what is not, for example, in the Acorup application document RM-A-399374, acorup

RM-A-133345, Acorop Demand RM 3447366, Acorrup Demand RM 3693492. Examples

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Supplements to the amendment articles and/or the amendments to the regulations that are mentioned in the order document

States RM 124665/3339.

Also in general terms, the soil that cushions the properties of the present wills contains a polymer of the type mentioned herein. In some models, it also contains a composition according to the current trends

5 on oil. In some models, the composition according to the current tariffs contains oil.

In some embodiments, a formulation according to the present regulations contains a polymer of the type mentioned herein and one additive at all. In some embodiments, the polymer is combined and/or reacts with one appropriate substance or effect, a vulcanization agent, and/or optionally one other host substance or effect, such as:

13 Arren coupling agents, uncrosslinked elastomeric polymers that do not have cross-links (i.e., conventional abrasomal polymers that do not have cross-linked and which do not react, nor do they add) Minya combinations.

In some embodiments, a formulation according to the present trends contains one or more suitable substances, acting as 15 strengthening agents. Characteristic examples of suitable suitable substances consider the following, for example:

Carbon black, silica, dual-phase filler from carbon and silica, magnesium carbonate, calcium carbonate, clay, and Mina combinations. In some models, a blend of carbon black is used.

black and silica, and the corresponding bi-phase materials from carbon and silica, or a combination of the corresponding material

33 A dual-phase filler made of carbon, silica, carbon black and/or silica.

In some models, carbon black is purified by fumace method, and the specific surface area of ​​nitrogen adsorption changes between about 53 and 333 m 3 / day, and the effect of DBP oil absorption is between about 83 and about 333 ml / HAF 133 ,

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ISAF or black carbon from SAF (SAF). In some models, black carbon is used of the extra-curd type. In some models, black carbon or silica is added with an amount ranging between about 3 and about 133 by weight, for 133 is removed by weight of the polymer. Some models are done

Addition of black carbon or silica in an amount ranging between about 5 and about 133 is removed by weight. In some models, carbon black or silica is warmed with an amount ranging between about 13

And about 133 by weight. In some models, carbon black or silica is incubated with an amount ranging between about 13 and 95 percent by weight.

Finally, by way of general presentation also, a product that fulfills the characteristics of the current revenue contains one component of each component of this diet. In some models, the product is a star. In some models, the product is a shoe component.

Examples and the following representations of the actress are illustrated according to the current trends, and are presented for the sake of clarification. It shall be driven by means of limiting the scope of ancillary protection elements or their equivalent.

examples

The monomer transformation was determined by measuring the titration of a polymer solution at the end of polymerization of a polymer 15. Try any TRIZE of raw materials at 133:

By weight, the transformation of the hydrated butadiene (mBd) and styrene (mSt) polymers showed the sleeper with the mite:

: TSC max= (mBd + mSt)/(mBd + mSt + mpolar agent + mBL + mcyclohexane) * 100

A sample was drawn from the polymer solution ranging between about 1 o'clock and about 13 o'clock, according to the amorphous transformation 33 of the monomer, from the reactor in a match with an Erlenmeyer urra with a capacity of 333 ml filled with

53 ethanol (ml). Erlenmeyer's fill was weighed by sampling ("A") and after sampling ("B"). Ethanol-precipitated polymer was sieved on a weighted paper filter (93 mm fiberglass, MUNKTELL, weight “C”), and typified at 143°C, with a 73 mm moisture analyzer using a HR solvent.

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(Mettler-Toledo) until the first for a fixed weight, criterion 5 was used. Finally, a second tyveh period was carried out using higher criteria 4 to try on the polymer mound “D” for the sample: the content of the fibers of the sample was calculated.

:TSC= (DC)/(BA)*100

5 The sleep shift of the polymer was calculated as 100*TSC/TSC max:

The temperature transition temperature for vitrification, Tg, was calculated according to ISO 11357-2 (1999) using a heating rate of 33 mph with the following settings:

Sample weight: about 11 mm

Sample container: aluminum containers (closed and air-protected against steam leakage) 13

Temperature range: -153 °C, 133 °C

Heating rate: 33 rpm

Cooling Rate: Free Cooling (13 dL 33 rpm)

Cleaning oz: 33 ml He/min

15th Cooling agent: liquid nitrogen

Evaluation method: Inflection point

Elias: DSC Q2000 from TA Instruments

No-to-heat cycles Between heating and cooling, Tg was determined using data from the second heating cycle.

33

The lysosome weight and lysosome weight distribution of the polymer were quantified using Arvia chromatography-exclusion (SEC) at 43°C based on standard polystyrene levels. l sample

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9-11 polymer (mM) was dissolved in tetrahydrofuran (13 ml) to make a solution. The solution was filtered using 3.45 mm thermometers. A 133 mL sample was fed to a Hewlett Packard system 1100 GPC column with 3 13 mm PLgel columns. (MIXED-B) was used. The Refraction Index parameter was used.

5 detection as the detector for analyzing the

molecular weight. The weight of the lyase was calculated using polystyrene, based on calibration with .

EasiCal PS1 (Easy A and B) Standard polystyrene levels of Polymer Laboratories.

The average lysine weight according to the number (Mn) and the average lyse weight according to the weight (Mw) 13 are given based on the standard levels of polystyrene. The weight distribution of the enzyme was expressed in

Aura Doria El Tatt D = Mw/Mn dispersity.

The vinyl content and the L-styrene content were measured using 1H-NMR, by the ISO 2005-21561 method. Using a 433BRUKER Avance NMR spectrometer (MHz), and a 5 mm duplex electrode. CDCl3/TMS was used as a solvent with a weight ratio of 99.95:: 3.35. 15. The content of a styrene block, which consists of more than 6 styrene units, was determined.

Rubber Chemistry and P. Y. Tanaka et al, Sequences according to the ortho-ph- atomization method using relative substance, Rarat Technology, 1981, 54, No. 4, 685-691

proton that gives resonance at higher than 6.7 ppm.

Procedures for Determining Livingness of Chain Ends: 33 Using a combination of TMEDA and DOP results in a higher grain yield as the chain end

polymerization of a polymer . The ratio of the chain frame that is capable of residues when the polymerization process proceeds with a precarious polymer, as if the number of chains included in the polymer increases, the interaction between the suitable material and the rubber will improve and the cracking resistance of the resulting mummified compound will decrease.

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Polymer art was pretreated with an amount of N-methylpyrrolidone NMP after achieving a monomer transformation higher than 99 to assess the residue ability of the resulting polymer chains. The modification rate of the resulting polymer chains was analyzed using two different methods: Method 1 is based on comparing size exclusion chromatography (SEC) ratios of rheumatoid arthritis 5 (SEC) for UVA absorption with the Refraction Index detection of differential (SEC) in the kidneys. Method 3 includes adsorption on a silica gel column, which is not available in applications for Camry Aram 3339/3162668A1 and 3339/3332842A1. It turns out that the absolute values ​​that were tried using Method 1 and Method 3 13 are different and do not have the same requirements.

The comparative example of Leon 133 was adjusted according to the method, and the attempted data were calculated according to this Al-Lamry (MR Fora:).

RM Comparative Example 5: Using TMEDA only

A 15-liter nitrogen-purged cyclohexane (5271.18 mm) was added to the reactor in a 13-liter nitrogen-purged stainless steel pulp.

(1,3-Butadiene yum) (236,657), (434.12 styrene) yum, and (3.1335 mmol TMEDA) were fed to the reactor bucket (butyl lithium / TMEDA nmol/1.743 mol).

The mixture was heated to 53 °C, stirring. The amps were calibrated in the system by adding butyl lithium in batches. Upon verification of the end point, polymerization of 33 a polymer was started by adding an amount of nBUpm to 1.3175 mmol of 15 (n-butyllithium).

A solution of cyclohexane (P-cyclohexane) was used using a slurry pump for 3 minutes for 16 seconds. When the polymerization of a polymer was started. The temperature of the reactor increased to 65 °C during 23 minutes. Monomer 133: The resulting polymer was analyzed using GPC: Mw, 215898, Mn.

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629423, 3.33 D. (2.2 butadiene m) was added and then 1.23 NMP (1.23 mL) was added.

mol). After 15 minutes, the reaction was completed by adding inferior agent methanol. 4.6 bis was entered.

(Ciba) from IRGANOX 1520 tiare (octylthiomethyl)-o-cresol

antioxidant .

5 The exact dosing and styrene block content were measured using 1H-NMR. The following products were tried: 1,2-polybutadiene (vinyl,: 53.5 styrene, calculated on the basis of styrene ratio, : 29.1) butadiene, Tel 15:.

Azir Yas Doriya, the frigid temperature, and the desired temperature of one transitional doryah, for fritting, at -14.7 °C. The modification rate analysis resulted in 49: (RM1 method) and 48: (RM3 method) compared to the comparative example: 6 13 (133:).

RM Comparative Example 6: Using TMEDA only

The cyclohexane (5439.2 mm) was fed with a 13 L nitrogen-purged reactor from stainless steel milk. , and TMEDA

15th (2.759 mmol) below the reactor (butyl lithium / TMEDA Natmol / 2.355 mol).

The mixture was heated to 53 °C, stirring. The amps were calibrated in the system by adding butyl lithium in batches. Upon verification of the end point, polymerization of a polymer was initiated by adding an amount of nBL,pm. Wet 1.3235 mmol of (15 n-butyllithium: p-cyclohexane solution) using a 3 min 16 sec shaker pump. 33 The polymerization process was then started. The temperature in the reactor increased to 65 °C during 23 minutes. The completion of the reaction was checked after 363 minutes by taking samples and determining that the monomer conversion was 99.7:. The resulting polymer was analyzed using GPC: 1.893 D, 584353 Mw, 219636 Mn. (2.2 butadiene yum) was added, followed by (1.3386 NMP mmol). After 15 minutes, the reaction was completed.

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By adding a world factor methanol. IRGANOX 1520 ANTI-LIGHTENING INTRODUCED

. antioxidant

The exact dosing and styrene block content were measured using 1H-NMR. The following results were tried: 1,2-polybutadiene (vinyl.: 52 styrene, calculated

5 Based on the ratio of styrene,: 43.1 (butadiene mL 13:.

Yas Doriya, the hot fringing temperature, is visible, and it is desired to have a single transitional heated Doriyah, for frosting, at -9.8 °C. The results of the modulation rate analysis were used for the additional and imaginary variances 133 (Method Rem1) and 133 (Method Rem3).

Rm Comparative Example 7: Using DOP Only

13 cyclohexane (5338.11 mm) was added to a 13 L nitrogen-purged reactor from stainless steel milk. , and DOP (1.1866 mmol) below the reactor (butyl lithium /DOP current 3.981).

The mixture was heated to 53 °C, stirring. The amps were calibrated in the system by adding butyl 15 lithium in batches. Upon verification of the end point, polymerization of . is initiated

a polymer solution was added by adding an amount of nBL,pm to 1.31 mmol (15 n-butyllithium: cyclohexane solution) using an agitation pump. About one minute later, the polymerization process was started. The temperature of the reactor increased at 23 65 °C. The completeness of the reaction was checked after 133 minutes by taking samples and determining that the monomer was converted to: 99.49.

33 polymer using GPC: 1.385 D, 755343 Mw, 587525 Mn. 2.24 (butadiene ym) was added, followed by 1.357 mmol NMP (NMP). After 15 minutes, the reaction was completed by adding a worldly factor methanol. An anti-oxidant IRGANOX 1520 was introduced.

. antioxidant

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The exact dosing and styrene block content were measured using 1H-NMR. The following products were tried: 1,2-polybutadiene (vinyl, 55.9 styrene, calculated on the basis of the ratio of 8 styrene block,: 49) butadiene:.

Azir Yas, Doriyah, for the dripping temperature, and for one warm drizzle for the glazing temperature, at -7.1 °C. Adjustment rate analysis resulted in 5: 193 (Rum1 method) and 168: (Rim3 method) against the comparative example 6

)133 :(.

Rm Comparative Example 8: Using DOP Only

cyclohexane (33717.6 mm) was added into a 43 L nitrogen-purged reactor from 13 L stainless steel pulp, fed with 1,3-butadiene (1,326.66 mm) and 1635 mm. ), and DOP (5.11 mmol) below the reactor (butyl lithium /DOP current 1.335).

The mixture was heated to 53 °C, stirring. The amps were calibrated in the system by adding butyl lithium in batches. Upon verification of the end point, polymerization of a polymer was started by adding an amount of nBL,pm methylene 4.8883 mmol of (15 n-butyllithium: 15 p-cyclohexane solution) using an agitation pump about one minute.

polymerization of a polymer. The temperature in the reactor increased to 65 °C during 23 minutes. The reaction was carefully carried out after 323 minutes by adding a world agent methanol. IRGANOX 1520 ANTI-LICATIONS Entered

. antioxidant

33 A sample was withdrawn using a sampling tube fitted with a stopcock stopper and a needle to determine the content of the slurry. The TPL conversion ratio of 99.37 has been measured:.

The resulting polymer was analyzed using D, 827114 Mw, 643963 Mn: GPC 1.236. The exact triglycerides and styrene block content were measured using 1H-NMR. The following results were attempted:

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1,2-polybutadiene (vinyl,: 54.9 styrene, calculated based on the ratio of styrene,: 53.1) butadiene Tel 7.

Atheer Yas, Dorya, at the temperature of delamination, and Doreya, on the other hand, would like to have a temperature of one transitional temperature of frosting, at -3.7 °C.

RM 9 Comparative Example: Using DOP Only

5 cyclohexane (5312.12 mM) was dehydrated by a 13 L nitrogen-purged reactor from stainless steel milk. (styrene yum), and DOP (1.1835 mmol) below the reactor (butyl lithium /DOP oscillation 3.971).

The mixture was heated to 53 °C, stirring. The pumps were calibrated in the system by adding butyl

13 lithium in batches. Upon verification of the end point, polymerization of a polymer was started by adding an amount of nBL,pm. The temperature of the reactor was set at 65 °C for 23 minutes The completeness of the reaction was checked after 93 minutes by taking samples and determining the conversion of monomer 133: The polymer was analyzed

15th GPC: 554765 Mw, 693882 Mw, 1.345 P butadiene (2.24 μm) was added and then 1.3344 NMP (1.3344 mmol) was added. After 15 minutes, the reaction was completed by adding methanol to the input factor IRGAN 15 additive.

antioxidant . The exact dosing and styrene block content were measured using 1H-NMR. The following products were tried: 1,2-(vinyl, 55.3 styrene).

33 polybutadiene, calculated based on the ratio of styrene,: 44.8 (butadiene TL-12:. Atheer Yas, Dorya, the temperature of the frosting, and the desire of one Doriya, the heat of the transitional period, for frosting at -2.4 °C.

Adjustment rate analysis resulted in: 158 (Method Rum1) and 118: (Method Rum3) versus Comparative Example 6 (133).

RM example 6 Using TMEDA/DOP

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cyclohexane (5198.73 mm) was added into a 13 L nitrogen-purged reactor from stainless steel pulp. It was fed with 1,3-butadiene (298.28 mm) and 293.9 mm (9,9.9) butadiene. TMEDA (3.1514 mmol), and 1.1783 mmol DOP (DOP) reactor (butyl lithium /TMEDA 5 nmol/mol 1.778; butyl lithium /DOP 3.974) dipped.

The mixture was heated to 53 °C, stirring. The amps were calibrated in the system by adding butyl lithium in batches. Upon verification of the end point, the polymerization of a polymer was started by adding an amount of nBL,pm.

13 polymerization of a polymer. The temperature in the reactor increased to 65 °C during 23 minutes. The completion of the reaction after 143 minutes was checked by taking samples and determining that the conversion of monomer 133:.

The resulting polymer was analyzed using 1.372 D, 735648 Mw, and GPC: 573343 Mn. (2.2 m butadiene) was added, followed by (1.363 mmol NMP). After 15 minutes, the reaction was completed by adding a minimum agent methanol. 1520 IRGANOX 1520 antioxidant was introduced.

The exact dosing and styrene block content were measured using 1H-NMR. The following products were tried: polybutadiene-2,1 (vinyl,: 55.8 styrene, calculated on the basis of styrene ratio, : 53.6) butadiene, Tel 7:.

Atheer Yas, Doria, the temperature of flickering, and Doria, a single transitional temperature, for mixing, at 5.5 °C.

33 Adjustment rate analysis resulted in 328: (Rum1 method) and 331: (Rum3 method) versus comparative example 6 (133:).

Rm Example 7: Using TMEDA/DOP

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Cyclohexane (31,232.29 mm) was added into a 43 L nitrogen-purged reactor from fresh stainless steel pulp. It was fed with 1,3-butadiene (827.86 mm), and styrene TMEDA (1318 mm), (3.9533 mmol) and (1.2811 mmol) DOP (butyl lithium / TMEDA).

5 Nat Mall/mol 3,431; butyl lithium /DOP (3.611).

The mixture was heated to 53 °C, stirring. The amps were calibrated in the system by adding butyl lithium in batches. Upon verification of the end point, polymerization of a polymer was started by adding a water of Nbl,prn to 3.3592 mmol of 15 n-butyllithium (p-cyclohexane solution) using an agitation pump about one minute.

13 polymerization of a polymer . The temperature in the reactor increased to 65 °C during 23 minutes. The reaction was completed after 153 minutes by adding a world agent methanol. IRGANOX 1520 antioxidant has been introduced.

A sample was withdrawn using a sampling tube fitted with a stopcock stopper and a needle to determine the content of alkali. The wet shift ratio was measured: 99.14:.

15th The resulting polymer was analyzed with 1.39 D, 934348 Mw, 716366 Mn: GPC. The microparticle and styrene block content were measured using 1H-NMR. The following results were tried: 1,2-polybutadiene (vinyl,: 55.5 styrene, calculated on the basis of the ratio of styrene,: 28.7) butadiene, Tel 17:.

Atheer Yas, Doria, at the temperature of flickering, and he wants to dorya, at a temperature of one transitional temperature, for mixing at -13 °C.

33 Rm example 8: Using TMEDA/DOP

The cyclohexane (5134.3 mM) was filtered into a nitrogen-purged 13-liter reactor from stainless steel pulp.

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(1,3-butadiene yum) and (289.5 styrene yum), (3.3287 TMEDA mmol), and (1.1787 mmol DOP) were fed with the reactor (butyl lithium / TMEDA nitrate 1.696 mol/mol; butyl lithium /DOP 3.981).

The mixture was heated to 53 °C, stirring. The pumps were calibrated in the system by adding butyl

5 lithium in batches. Upon verification of the end point, the polymerization of a polymer was started by adding an amount of nBL,pm to 1.333 mmol of 15 (n-butyllithium: p-cyclohexane solution) using an agitation pump about one minute. a polymer The temperature of the reactor increased to 65 °C during 23 minutes The completion of the reaction was checked after 153 minutes by taking samples and determining that the monomer was converted

13 99.37:. The resulting polymer was analyzed using GPC: 833548 Mw, 579453 Mn:

1.285 D. (2.24 butadiene yum) was added, followed by (1.159 mmol NMP). After 15 minutes, the reaction was completed by adding inferior agent methanol. 1520 IRGANOX antioxidant was inserted.

The exact dosing and styrene block content were measured using 1H-NMR. 15 The experiment was carried out on the following results: 1,2-polybutadiene (vinyl, 56.3 - styrene, calculated on the basis of styrene ratio: 53.4) butadiene tel-7:.

Atheer Yas, Doria, the temperature of delamination, and Doria, of one transitional temperature, for delamination, at 6.1 °C.

Adjustment rate analysis resulted in 325: (Rum1 method) and 188: (Rum3 method) against the comparative example (133):

33 RM example 9: Using TM EDA/DOP

Cyclohexane (33951.95 μm) was added into a 43 L nitrogen-purged reactor from pure stainless steel pulp. It was fed with 1,3-butadiene (1,383 μm) and 1572.82 styrene μm. TMEDA

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(8.2477 mmol), and (4.8288 mmol DOP) the reactor floated (butyl lithium /TMEDA, 1.792 mol/mol; butyl lithium /DOP 1.329).

The mixture was heated to 53 °C, stirring. The amps were calibrated in the system by adding butyl lithium in batches. Upon verification of the end point, polymerization of . is initiated

5 A polymer was added by adding a quantity of nBL, pm to 4.6556 mmol of (15 n-butyllithium: p-cyclohexane solution) using an agitation pump. About one minute ago, the polymerization of a polymer was started. The temperature of the reactor increased to 65 °C. The completion of the reaction after 143 minutes was checked by taking samples and determining that the monomer conversion was 99.69: The resulting polymer was analyzed using Mw, 631421 Mn GPC:

13 791497, 1.374 D. (2.24 butadiene yum) was added, followed by 1.159 NMP

mmol). After 15 minutes, the reaction was completed by adding a worldly agent methanol. IRGANOX 1520 antioxidant was inserted.

The exact dosing and styrene block content were measured using 1H-NMR. The following products were tried: 1,2-polybutadiene (vinyl,: 55.3 styrene, calculated 15 based on the proportion of styrene, 52.3) butadiene, Tel 7:.

Atheer Yas, Doria, at the temperature of flickering, and he wants to dorya, at a temperature of one transitional temperature, for frosting at -5.8 °C.

Adjustment rate analysis resulted in 339: (Rum method 1) and 315: (Rum 3) method versus comparative example 6 (133:).

Example Rm 13: Using DOP/TMEDA (ratio 3.22)

33 cyclohexane (5333.58 mM) was added into a 13 L nitrogen-purged reactor from stainless steel pulp. It was fed with 1,3-butadiene (1,3-butadiene mm) and 29,8-9 mM nitrogen-purged pulp. TMEDA (2.57 mmol), and DOP (1.1772 mmol) in the lower reactor (butyl lithium /TMEDA, 3.967 mol/mol; butyl lithium /DOP 3.977).

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The mixture was heated to 53 °C, stirring. The amps were calibrated in the system by adding butyl lithium in batches. Upon verification of the end point, polymerization of a polymer was started by adding an amount of nBL,pm.

5 polymerization of a polymer . The temperature in the reactor increased to 65 °C during 23 minutes. The reaction was completed after 233 minutes by adding a world agent methanol. IRGANOX 1520 antioxidant has been introduced.

A sample was withdrawn using a sampling tube fitted with a stopcock stopper and needle to determine the content of the slurry. TPL turnover ratio of 98.36: has been completed.

13 The resulting polymer was analyzed using GPC: 25.1 D, 736321 Mw, 533936 Mn. The microparticle and styrene block content were measured using 1H-NMR. The following results were tried: 1,2-polybutadiene (vinyl, 55.8 styrene, calculated on the basis of styrene ratio, 51.4)butadiene, Tel 6:,

Atheer Yas, Doria, at the temperature of flickering, and he wants to dorya, at a temperature of one transitional temperature, for mixing at -9.9 °C.

15th RM example 11: Using DOP/TMEDA (ratio 2.22)

cyclohexane (5194.45 mm) was flooded with a 13 L nitrogen-purged reactor of sulfur-purged milk fed with 1,3-butadiene (3.11 mm), stainless steel (216.38 mm), The reactor (butyl lithium / TMEDA), TMEDA (3.2647 mmol), and DOP (1.1776 mmol) was lowered.

33 Nat mol/mol - 3.233; butyl lithium /DOP (DOP 3.975).

The mixture was heated to 53 °C, stirring. The amps were calibrated in the system by adding butyl lithium in batches. Upon verification of the end point, the polymerization of a polymer was started by adding an amount of nBL,pm.

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polymerization of a polymer . The temperature in the reactor increased to 65 °C during 23 minutes. The completion of the reaction was checked after 133 minutes by taking samples and determining the conversion of monomer 99.27:. (4.34 mmol) butadiene was added, followed by 1.31 mmol NMP. After 15 minutes, the reaction was completed by adding the minimum factor methanol. IRGANOX 5 1520 antioxidant was introduced.

The resulting polymer was analyzed using D, 721276 Mw, 594311 Mn: GPC 1.321. The exact triglycerides and styrene block content were measured using 1H-NMR. The following products were tried: 1,2-polybutadiene (vinyl, 55.9 - styrene, calculated on the basis of styrene ratio: 49.9) butadiene, Tel 7:.

13 Atheer Yas, Doria, at the temperature of flickering, and he wants to dorya, at a temperature of one transitional temperature, for mixing at -3.8 °C.

The modification rate analysis resulted in: 337 (Method Rem 1) versus Comparative Example 6 (133:).

Example Rm 13: Using DOP/TMEDA (ratio 1.67)

A cyclohexane (5187.95 mM) was added into a 13-liter nitrogen-purged reactor from stainless steel pulp.

15th The reactor was fed with (1,3-butadiene (216.38 mm), 1.7 29 (1,7) styrene), TMEDA (3.7135 mmol), and (1.1776 mmol DOP) into the reactor (butyl lithium / TMEDA, 3.631 mol / mol; butyl lithium /DOP 3.992).

The mixture was heated to 53 °C, stirring. The amps were calibrated in the system by adding butyl lithium in batches. When checking the end point, polymerization of 33 a polymer was started by adding a water of nBL,pm to 1.1861 mmol of 15 (n-butyllithium).

A solution of cyclohexane (P-cyclohexane) using an agitation pump about one minute, when the polymerization of a polymer began. The temperature of the reactor increased to 65 °C for 23 minutes. The completeness of the reaction was checked after 133 samples were taken. Monomer 133:.

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The resulting polymer was analyzed using D, 794175 Mw, 629275 Mn: GPC 1.343. 2.34 (butadiene yum) was added, followed by 1.33 mmol NMP. After 15 minutes, the reaction was completed by adding the minimum factor methanol. 1520 IRGANOX antioxidant was introduced.

5 The exact dosing and styrene block content were measured using 1H-NMR. The following products were tried: 1,2-polybutadiene (vinyl, 54.5 styrene, calculated on the basis of styrene ratio: 53.8) butadiene Tel: 7. The drizzle of glazing temperature was required, and Duria wanted one transitional temp of glazing at 3.8 °C. Adjustment rate analysis resulted in: 189 (Method Rem1) compared to the comparative example: 6 (133).

13 RM example 12: Using DOP/TMEDA (ratio 3.18)

A 13 L nitrogen-purged reactor was fed with 1,3-butadiene43,2 ym, cyclohexane (5333.87 mm) of stainless steel. TMEDA (3.3628 mmol), and DOP (3.2614 mmol) boil the reactor (butyl lithium /TMEDA 15 nmol/1.7 1.7 33; butyl lithium /DOP 3.398).

The mixture was heated to 53 °C, stirring. The amps were calibrated in the system by adding butyl lithium in batches. Upon verification of the end point, polymerization of a polymer was started by adding an amount of nBL,pm to 1.3134 mmol of 15 (n-butyllithium: p-cyclohexane solution) using an agitation pump about one minute. of a polymer The temperature of the reactor increased to 65°C during 23 minutes. The completion of the reaction after 183 minutes was checked by taking samples and determining that the monomer conversion was 99.9:. The polymer was analyzed using GPC 779935: Mw, 536393 Mn, 1.483 D. (2.24 butadiene yum) was added, followed by NMP 1.8 (27).

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mmol). After 15 minutes, the reaction was completed by adding a worldly agent methanol. IRGANOX 1520 antioxidant was inserted.

The exact dosing and styrene block content were measured using 1H-NMR. The following results were tried: 1,2-polybutadiene (vinyl, 55.1 styrene, calculated 5 based on styrene ratio: 45.4) butadiene Tel 9:.

Atheer Yas, Doriya, the temperature of the flickering, and the desire of one heated Doria Doria, for the temperature of flickering, at -1.3 °C. The modification rate analysis resulted in: 191 (Method Rem1) versus the comparative example 6 (133:).

Example Rm 14: Using DOP/TMEDA (ratio 3.25)

A 13-liter nitrogen-purged cyclohexane (5357.45 mM) was added into the nitrogen-purged 13-liter reactor of stainless steel pulp.

The feed was fed with (219.98 mmol), (1,3-butadiene mm), (296.23 mm) styrene (m), TMEDA (3.343 mmol), and (3.7173) DOP mmol) in the boil (butyl lithium / TMEDA, nmol/mol 1.681, butyl). lithium /DOP (3.593).

The mixture was heated to 53 °C, stirring. The amps were calibrated in the system by adding butyl 15 lithium in batches. When verifying the end point, polymerization of a polymer was started by adding an amount of nBL,pm to 1.3147 mmol of butyl lithium - n (15 : p-cyclohexane solution) using a shake pump about one minute, during the polymerization process. of a polymer The temperature of the reactor increased to 65°C during 23 minutes. The completion of the reaction was checked after 153 minutes by taking samples and determining that the monomer transformation 98.97:33.

The resulting polymer was analyzed using 1.4 D, 811981 Mw, 583671 Mn: GPC. (2.34 mmol butadiene) was added, followed by 1.3536 mmol NMP. After 15 minutes, the reaction was completed by adding a minimalist methanol agent. 1520 IRGANOX antioxidant was introduced.

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The microarray and styrene block content were measured using 1H-NMR. The following products were tried: polybutadiene-2,1 (vinyl, 56.3 styrene, calculated on the basis of styrene ratio, 53.4) butadiene, Tel 7:.

Atheer Yas, the dripping temperature, and one tandoor temp, for dripping, at 2.3°C.

5 The modification rate analysis resulted in 313: (method RM1) versus the comparative example 6 (133:).

2

The current inventors came as an exciting tool for a new SSBR with a high percentage of styrene, and a high percentage of vinyl with a narrow weight distribution of lyase, inclusion of styrene on a sequential hill with more than 4 and 73 styrene units, between 4 and 73 styrene units. And in particular, the other 13 are not really going away.

Moreover, the current inventors have also - an exciting and unpredictable way - that it is possible to prepare the former SSBR with a high percentage of styrene and a high percentage of vinyl using a lithium (butyl) starter.

ditetrahydrofurylpropane, which is also known as 2,2-di(2-oxolanyl)propane 15, or DOP with arca-potassium alcoholate. So some models, in the following circumstances:

Content of ≥ 33styrene: by weight, p.R. potassium alcoholate/initiator ≥3.35; Heat-polymerizing diaphragm ≥83°C.

In the context of the case investigation, the following definitions will be used:

The term polymerization of monomeric units refers to a substance prepared by polymerization of monomeric units. What is used here, the expression "polymerbe"?

The expressions include homopolymer B (a polymeric material prepared from one type of monomer), and a copolymer B (a polymeric material prepared from two different types).

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of monomer), and a polymer between B-interpolymer (a polymeric material prepared from the effect of two different types of monomer).

An expression with an alkyl group in a straight, branched, or cyclic hydrocarbon chain, with or without substitution, preferably containing between 1 and 33 carbon atoms.

5 Distinctive examples of alkyl iodide groups are substituted for use according to current trends.

Consider the following for example: methyl, ethyl, propyl, iso-propyl, hot and what is not. , cyclopropyl, butyl, iso-butyl, terl-butyl, sec- butyl, cyclobutyl

The expression process, when used for a period of time, refers to the polymerization of a polymer that includes continuous, non-continuous, and/or continuous processes.

13 The expression “Year Continuous” or “Continuous” when used to indicate a polymerization process, denotes a polymerization process, which takes place with more than 63 effects from the solvent in the reactor. The monomer may be directly coupled to the initiator host, or required to the initiator host, or required after the initiator host, or to a continuous match after the initiator host is added over a certain period of time.

15th Expression of continuous polymerization, continuous polymerization by Yair dangled the process of polymerization is Villa Dave solvent, monomer) Almonom Art (and any m Nat polymerized Ddhavih Paorh continuous loll reactor at rates specific Himah. In some models, the use of two or Impact of Mphaataat polymerization polymerization reactors loyal sequentially In some models, the reactor is driven by only one reactor.

33 The term “vinyl content” denotes the hydrophobic ratio (or weight) of butadiene moiodide in the 1, 3P mode of the polymer chain, based on the removal of butadiene (the lycified moiety of the polymerized butadiene).

.) butadiene polymerization

The expression “styrene content” refers to the hydration ratio (or weight) of styrene in the polymer, based on the weight of the polymer.

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Expression by styrene content of tlp yr indicative by weight ratio of miod styrene in the flux of successive sequences of styrene units based on the current amount of polymerized styrene in the polymer

. polymerized styrene in the polymer

Expression in a May arrangement refers to a mixture of materials including a polymer and, optionally, reaction products and/or 5 mM decomposition products of the polymer material.

Expression with an activating initiator (Nbl,pm) refers to the alkali water from the initiator (such as organ lithium) that is left in the polymerization reaction and has not been quenched by electrolytes in the middle of the reaction.

The expression with the initiator azmdb (nBL, exc) can deactivate the impurities in the system.

The expression for the per cent of the monomer feed stream is the per cent of the per cent of styrene and butadiene, per minute, driven into a continuous polymerization reactor, and typically, in a continuous polymerization of a polymer reactor.

An expression for the year transformation of the polymer Yar denotes the sleeping transformation of the polymer (such as the rimal transformation

15th sleep polymer, styrene and butadiene), which is determined by the last polymerization reaction and/or when the polymerization reaction ends.

By way of general introduction, a polymer that fills the properties of the present will have the following properties on the food: (a) a styrene block content containing a trace of 4 consecutive styrene units between about 43 and about 73 p the time by weight of the styrene content in

33 polymer; (B) vinyl content ranging between about 35 and about 83 F by weight of the daily amount of 1,3-butadiene; (C) styrene content ranging between about 33 and about 75 F by weight

by weight by weight of the polymer; and (d) a weight distribution of 1.5 or UL. In some models,

Yun F polymer, which blocks the properties of the current will, styrene block

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With an effect of 6 successive styrene units between about 5 and about 23 f, the same by weight of the styrene content in the polymer.

In some models, the ion-p polymer that normalizes the properties of the current returns is a level of l

The styrene ranges between about 35 and about 85 in the mammary gland by weight, and in some models it ranges between about 53

5 and 63 p mamma by weight.

In some models, polymer denaturation is done in batches, and in some models, polymer dentao is done in batches.

Continuing. Currently, it is preferable, therefore, to process the production in batches. polymer according to current trends

If the weight distribution (Mw/Mn) is 1.5 or L, such as between about 1.35 and about 1.4, in some embodiments, the weight is balanced between about 1.1 and about 1.4. some models,

13 One weighs the weight between about 1.3 and about 1.25.

In some models, the polymer that fills the properties of the current revenues gives an average weight according to the number greater than or equal to about 333333 mm/mol. In some embodiments, the average lysosome weight is given by the number A, less than or equal to about 43,333 m/mol. In some models, the average weight of the enzyme is given according to the number greater than or equal to about 553333 m/mol.

15th In some models, the polymer that fills the properties of the current revenues has an average weight of more than or equal to and about 353333 mm/mol. In some models, the average weight of the enzyme is determined according to the weight greater than or equal to about 533,333 mm / mol. In some embodiments, the average weight of the enzyme is determined according to the weight greater than or equal to about 633,333 m/mol.

Please note that there are no previous models in any combination, including combinations of preferred models.

33 currently,

Also by way of general introduction, a process for the polymerization of a polymer . is presented

1,3-butadiene and styrene monomer are made of monomeric units.

The monomer according to the current traps contains the polymerization of monomeric units, an iodine initiator, a potassium alcoholate and a polar agent, where the polar agent is I:

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<img file="SA4498B1_D0002.tif" />

In some embodiments, R2 j RI separately is an alkyl group, in some embodiments, RI and R2 are separately an alkyl Cl group^-C4. In some embodiments, RI and 52 are both methyl.

5 In some models, 56, 5, R4, R3, R7, and each of them is selected separately from

The group consisting of an alkyl group and a hydrogen. In some embodiments, 03, 5, R4, 86, R7 and R8 are each selected separately from the group consisting of the hydrogen and the alkyl group C1-C4. In some embodiments, R4, 5, 56, R3, R7 and R8 are each selected separately from the group consisting of methyb hydrogen, in some embodiments,

0 1 R7, R5, R5, R4 and R8 are each hydrogen.

In some embodiments, the molar ratio between the polar agent and the active initiator is greater than about 100• In some embodiments, the molar ratio between the polar agent and the active initiator ranges between about 00 and about 3.

In some embodiments, the styrene content in the monomer mixture added in the polymerization of a polymer is greater than about 0.4 by weight of the total weight of the monomers added.

In some embodiments, the polymerization process is carried out according to current guidelines at a temperature of less than about 80 °C. In some embodiments, the polymerization process is carried out according to current guidelines at a temperature between about 0°C and about 80°C.

Put;;

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The primers currently preferred to be used according to the current trends include those suitable for anionic polymerizations. In some embodiments, the initiator of use according to the current uses is an organ lithium (such as alkyl lithium).

5 n-pentyl lithium, butyl lithium -t, butyl lithium-s, n-butyllithium, etc., and Minya combinations. In some embodiments, the initiator is n-butyllithium.

In some embodiments, the transformation of the polymer is less than about 96 p by weight of the per cent of the monomer feed stream, in some models, the transformation of the polymer is less than about 98 wt by weight Some embodiments, the transformation of the polymer into a strong

13 From about 99 p mamma by weight.

In some embodiments, the ion-polymer that quenches the properties of the current rays has a vinyl content ranging between about 35 and about 83 p by weight of the total amount of 1,3-butadiene. In some embodiments, the vinyl content varies between about 43 and about 75 pH by weight.

Some of the embodiments of the procedure according to the present doses, potassium alcoholate complement the

. potassium-3,7- dimethyl 3-octylate 15

In some process models, according to the current trends, the variance between the polar factor and potassium alcoholate varies between about 23:1 and about 1:5.

Thanks to the process, according to the current trends, polymers can be prepared, which is not mentioned here.

It is currently preferable for polymerization of a polymer to occur according to 33 current trojans in solvents, whereas hydrocarbon solvents are currently preferred. in some models,

The polymerization solvent is ideal for the alkane. In some embodiments, the polymerization solvent is cyclohexane, and in some embodiments, it is hoped

alkane m cyclohexane on a mixture of polymerization solvent

Add one or more.

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Also by way of general introduction, the polymer is graded according to the current trends with a process of the type described herein.

In some embodiments, a current adjustment of the polymer can be made according to the current trends using chain-route adjustment and/or interactions. Modifiers suitable for the chain frame may be selected and/

5 Or R-Arne coupling agents according to the use of the mastic and the painful substance, consider the examples of R-Arne coupling agents, for example the following: tin tetrachloride, divinylbenzene, silicon tetrachloride, alkoxysilanes, and other compounds, etc.

Consider examples of modifying agents, for example the hot H: amines, 13 amides, silicon alkoxides, thioglycols, silane-sulfide modifiers.

Acorob Rm 1316674, isocyanate, benzophenone, hydroxyl mercaptans, sulfenyl halides, what is in demand Minya. The most important amendment is extrapolated. Consider the following

15th Hot example: Myrrh bate amines, mr bate amides, mr bate amides, and nitrile modifiers are what is not mentioned in the application document Akorob Rm 548799, Akorob’s application Rm 513413, the application Aquorob Rm 41,41634 widow

Acmria Rm 4413341. In some embodiments, silanes including Via, for example hot H, epoxy silanes are used to modify the polymer chain.

33 polymer chain To use in silica fillers what is not, for example

Example, in Akorup Requisition Document RM-A-399374, Acorop Requisition RM-A-133345, Requisition

Acorup RM 3447366, and Acorop Request RM 3693492. As supplementary examples of Articles of the Amendment and/or Mary’s Articles, these Articles are indicated in the International Request Document No. 124665/3339.

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By way of general introduction also, the soil permeating the properties of the present wills contains a polymer of the type mentioned herein. In some embodiments, the composition according to the current tariffs also contains additives, such as oil. In some embodiments, the composition according to the current trends also contains oil with an amount ranging between about 5 and about 43 percent, by weight of the polymer weight. q some

5 Models, formulated according to the current trends, contain oil.

In some embodiments, a formulation according to the present regulations contains a polymer of the type mentioned herein and one additive at all. In some embodiments, the polymer is combined and/or reacts with one appropriate substance or effect, a vulcanization agent, and/or optionally one other host substance or effect, such as:

<p>13 Arran coupling agents, uncrosslinked elastomeric polymers that do not have crosslinks (i.e. conventional crosslinked elastomeric polymers, intermediates, intermediates) Minya combinations.</p>

In some embodiments, the composition according to the current trends contains one or more appropriate substances, which act

<p>15th strengthening factors. Distinctive examples of suitable suitable materials, consider the following, for example: carbon black, carbon black and silica, biphasic adaptive materials such as carbon black, carbon silica, clay, calcite, carbonium silica, clay, and clay. . In some models, a combination of carbon black and silica, and the corresponding biphasic materials of carbon and silica or</p>

<p>33 A combination of dual-phase filler, carbon black and/or silica is used.</p>

In some models, carbon black is prepared using the oven method, and if a specific surface area protects nitrogen adsorption between about 53 and 333 m 3 / day, and DBP oil absorption occurs between about 83 and about 333 ml / 133 m. like FEF,

35 ISAF, HAF or carbon black from the mouth of SAF. In some models, this is done

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The use of black ribbon of the super ferrous type. In some models, carbon black or silica is added in an amount ranging between about 3 and about 133 by weight per 133 removed by weight of polymer, in some models, carbon black or silica is added in an amount ranging between 5 and about 133 by weight. In some models, the black straw or silica is added with a water gradient

5 Between about 13 and about 133 it is still by weight. In some models, carbon black or silica is added in an amount ranging from about 13 to 95 removed by weight.

Finally, by way of general presentation as well, a product that simulates the characteristics of the current revenues contains a single ingredient on each month of this mixture. In some models, the product is a product. In some embodiments, the product is a shoe component.

13 The following examples, and I see the expressions represented, show the properties according to the current trends, and are presented only for the sake of illustration. This is led by examples of limiting the scope of ancillary protection elements or its equivalent.

examples

The monomer transformation was determined by measuring the titration of the lipids of a polymer solution upon the polymerization of a polymer. Try any TRIZE of raw materials at 133:

15th By weight, butadiene hydrates (mBd) and styrene (mSt) were shifted according to the oligopolymer.

For the equation:

TSC max= (mBd+ mSt)/(mBd+ mSt + mpolar agent + mBL+

(mcyclohexane*100): A sample of the polymer solution ranging between about 1 o’clock and about 13 o’clock, according to the monomer transformation, was drawn from the reactor by Erlenmeyer

33 333 ml capacity filled with (53 ml) ethanol. The filled Erlenmeyer cylinder was weighed prior to sampling (“A”) and after sampling (“B”). The precipitated polymer from ethanol was sieved over a weighted paper filter). A ball of thin oily fibre, 93 mm in diameter, MUNKTELL, weight “C”), lyophilized at 143°C, using a Mettler-Toledo HR73 moisture analyzer until the first constant weight was used.

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Criterion 5. Finally, a second typhoid period was carried out using higher 4 criteria to try the 'D' sleepy mound for the fine sample on a gradual basis. The polymer content was calculated in the sample as follows:

:TSC= (DC)/(BA)*100

The sleep shift of the polymer was calculated as 100*TSC/TSC max:

5 The lysosome weight and the lysosomal weight distribution of the polymer were quantified using Arvia chromosomal exclusion (SEC) based on standard polystyrene levels. A polymer sample (9-11 mm) was dissolved in (13 ml tetrahydrofuran) to make a solution. The solution was agitated

solution was filtered using 3.45 μm mrah. Sample was fed 133 mL into a Hewlett Packard system GPC (1100) column dropper, 13 3 PLgel mirro columns.

13 MiXED-B meter at 43°C. The detector for analyzing the molecular weight was used. Refraction Index detection was used based on calibration guides with

Polymer of polystyrene EasiCal PS1 Standard Levels (Easy A and B)

Laboratories. The average lysine weight was measured according to the number (Mn) and the average lyzyme weight was given according to the number (Mw) of 15, given based on the parameters of the standard polystyrene levels.

The vinyl and styrene content were measured using 1H-NMR,

Following ISO 2005-21561, using a BRUKER Avance NMR Spectrophotometer

433 Meahertz), 5 mm double whisk. CDCl3/TMS solvent was used with a weight ratio of 3.35.

<p>33 :: 99.95:. The styrene block content of 6 units was determined.</p>

Rubber Chemistry in Y. Tanaka et al, sequenced according to the styrene ortho atomization method using Relative Article and Technology, 1981, 54, No. 4, 685-691

<p>Ph-proton giving resonance at higher than 6.7 ppm, the content of a styrene block of 4 sequential styrene units and the effect of which was determined according to the structural method in the document</p>

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The word gram is 69713963 using the relative tool ortho Ph-proton that gives a resonance between 6.94 and 6 ppm. The content of the styrene block, which varies between 4 and 6 successive units, was calculated from the difference between the contents of the previous styrene block.

5 Comparative example RM 13: (use of KDMO) K-3,7-dimethyl-3-octylate or K below)

((hexanes 53: q))

5,276.55 mM of cyclohexane was added and a 13 L nitrogen-purged reactor was centrifuged from the stainless steel pulp. fed with 236.17 yum of 432.72, 1,3-butadiene yum of styrene, and 3,382

13 mmol of (53 K-3,7-dimethyl-3-octylate: ph-heptane) in the reactor (K/ butyl lithium nmol/mol/3.376). The mixture was heated to 53°C. Stirring. The amps in the system were calibrated by adding Butyl lithium in batches Upon checking the end point, polymerization of a polymer was started by adding 1,466 mmol of 15 n-butyllithium: p-cyclohexane solution using a 1-min agitation pump.

15th 19 sec. When did the polymerization of a polymer begin? dariah rose

The temperature in the reactor is 65°C for 23 minutes. The reaction was completed after 333 minutes by adding methanol

Diga agent, 1520 IRGANOX antioxidant has been introduced.

A sample was taken using a sampling tube fitted with a stopcock stopper and a needle to determine the solids content. tm yas shift ratio of 99.57:. The resulting polymer was analyzed using

33 GPC: 1.364 D, 674699 Mw, 522626 Mn. Detailed training and content

styrene block using 1H-NMR. The following products were tried: styrene 55.3:, 1,2-polybutadiene (vinyl, calculated on the basis of the ratio of 13.2) butadiene:, styrene tel styrene block with a trace of 4 styrene: 83 styrene block with a trace of 6 units 29 styrene:.

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Comparative example Rum 11: (use 53) K-3,7-dimethyl-3-octylate: p-hexanes)

5239.39 mM of cyclohexane was added and a 13 L nitrogen-purged reactor was centrifuged from the stainless steel pulp. fed with 235.28 yum of 298.37, 1,3-butadiene yum of styrene, and 3.5311

5 mmol of (53 K-3,7-dimethyl-3-octylate: p-heptane) reactor inferior (K/ butyl lithium n mol/ 3.28 mol).

The mixture was heated to 53 °C, stirring. The amps were calibrated in the system by adding butyl lithium in batches. When checking the end point, the polymerization of a polymer was started by adding the following water of 1.326 mmol of 15 (n-butyllithium: a solution of

13 P cyclohexane (using a pump of 1 min 53 sec.). When the polymerization of a polymer began, the temperature of the reactor increased to 65 °C in 23 minutes.

After 144 minutes, the reaction was completed by adding methanol, an anti-oxidant. IRGANOX 1520 was added.

A sample was taken with a sampling tube fitted with a stopcock stopper and a needle to determine the content of 15 albite. The TPL transformation ratio of 99.18:, has been measured.

The resulting polymer was analyzed using GPC: 1.637 D, 823735 Mw, 513426Mn.

The microparticle and styrene block content were measured using 1H-NMR. The following products were tried: polybutadiene-2,1 vinyl,: 53.2 styrene, calculated on the basis of the ratio of 34.2 (butadiene:, styrene block, which has a trace of 4

33 64 styrene units: a styrene block with a footprint of 6 units

.: 33 styrene

Example Rum 15: (Using 53 K-3,7-dimethyl-3-octylate: (P DOP/hexanes)

5233.55 mM of cyclohexane was typified in a 13 liter nitrogen-purged reactor from stainless steel pulp reactor.

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steel, and was fed with 234.98 mM of 433.63, 1,3-butadiene mM of styrene, 3.5351 mmol of (53 k-3,7-dimethyl-3-octylate: pH: 3.4837 mmol mol DOP) heptane in the reactor (K/ For butyl lithium (mol/mol 3.259), butyl /DOP lithium (3.241). The mixture was heated to 53°C. Stirring, the amps were calibrated at

5 The system was added by adding butyl lithium in batches. When the end point was checked, the polymerization of a polymer was started by adding the daily amount of 1.4386 mmol of n-15 (butyllithium: cyclohexane solution) using a stirring pump for 1 minute 22 seconds. When the polymerization process started. The heat cycle in the reactor was 65 °C for 23 minutes The reaction was completed after 333 minutes by adding the working methanol

13 Deqa. IRGANOX 1520 antioxidant has been introduced. A sample was taken with a sampling tube fitted with a stopcock stopper and a needle to determine the alpha content. TAML Transformation Ratio: 99.11. The resulting polymer was analyzed using GPC: 533396Mn, 1.479 D, 743517 Mw. The micronutrient profile and styrene block content were determined by 1H-NMR. The following products were tried: vinyl: 55.5 styrene.

15th 73 styrene: 1,2-polybutadiene, calculated on the basis of the ratio 43 (butadiene: styrene block with a trace of 4 units, and styrene block with a trace of 6 units.: 34 styrene).

Example R 16: (Use 53) K-3,7-DIMETHYL-3-OCTYLATE: (P/hexanes)

(DOP .)

33 5239.39 mM of cyclohexane was added and a 13 L nitrogen-purged reactor was centrifuged from the stainless steel pulp. The reactor was fed 235.28 mM of 298.37, 1,3-butadiene mM 3.1365, styrene (53 mmol) of K-3,7-DIMETHYL-3-OCTYLATE: p-heptane, and 3.4837 mmol of DOP (butyl lithium). /K active mol/ 3.1 mol, /butyl DOP

35 lithium (3.298 mol/mol). The mixture was heated to 53 °C, stirring. Calibrated.

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Pumps into the system by adding butyl lithium in batches. When the end point was checked, the polymerization of a polymer was started by adding a current of 1.3266 mmol of 15 (n-butyllithium: p-cyclohexane solution) using a stirring pump for 1 minute 53 seconds. When the polymerization of a polymer began. Doria Al-Harra rose

5 In the reactor 65 °C, an anti-oxidant was entered, after 133 minutes, the reaction was completed by adding methanol, an anti-oxidant, and an IRGANOX 1520 needle was inserted. TMYS conversion ratio of 99.18: . The resulting polymer was analyzed using GPC: 1.226 D, 813267 Mw, 636718Mn. The accurate training and content of Citrine Tel has been completed

13 styrene block using 1H-NMR. The following results were tried: 54.4 styrene 1,2-polybutadiene (vinyl), calculated on the basis of the ratio of 27.6 (butadiene): 73 styrene: styrene block with a trace of 4 units, and styrene hill styrene block with a trace of 6 34 styrene units:.

Example Rum 17: (use 53) k-3,7-dimethyl-3-octylate: (P DOP/)hexanes

15th 1 1.7,534 M of cyclohexane was centrifuged in a 13 L nitrogen-purged reactor, from stainless 23148 ​​pulp. steel from 298.35, 1,3-butadiene from 3.1198 mmol styrene (53 k-3,7-dimethyl-3-octylate: p-heptane), and 1.1846 mmol DOP was fed into the reactor (butyl lithium /K Nat mol/ 3.387 mol, butyl /DOP

33 lithium (3.894 mol/mol). The mixture was heated to 53 °C, stirring. Calibrated.

A pump in the system by adding butyl lithium in batches, when checking the end point, polymerization of a polymer was started by adding a water of 1.2816 mmol of (15 n-butyllithium: p-cyclohexane solution) using a vacuum pump at 1 minute 53 seconds. The polymerization of a polymer process

35 In the reactor 65 °C, during 23 minutes, the reaction was completed after 133 minutes by adding methanol.

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Diga agent, IRGANOX 1520 has been entered as an antioxidant. A sample was taken with a sampling tube fitted with a stopcock and a needle to determine the alpha content. 99.58 turnaround ratio: . The resulting polymer was analyzed using GPC: 1.346 D, 733763Mw, 557938Mn. The accurate training and content of Citrine Tel has been completed

5 styrene block by 1H-NMR. The following results were tried: 54.5 styrene 1,2-polybutadiene (vinyl), calculated on the basis of the ratio 53 (butadiene): styrene tel styrene block with a trace of 4 styrene units: 86 styrene block with a trace of 6 units 33 styrene:.

Example Rum 18: (Use 53) K-3,7-dimethyl-3-octylate: (P) DOP/hexanes

13 5,244.72 mM of cyclohexane was added and a 13 L nitrogen-purged reactor was centrifuged from the stainless steel pulp.

237.57 yum of 18,431, 1,3-butadiene yum of 3.1333, styrene mmol mol of

53 K-3,7-dimethyl-3-octylate: p-heptane), and 2.521 mmol DOP was fed into the reactor (butyl lithium /K nmol/mol 3.133, butyl lithium /DOP 15 nmol/mol-3.948) The mixture was heated up to 53° C. Stirring The amps were calibrated at

The system was added by adding butyl lithium in batches. When the end point was checked, the polymerization of a polymer was started by adding the total amount of 1.1978 mmol of n-15 (butyllithium: cyclohexane solution) using a whisk pump for 1 minute 46 seconds, when the polymerization process of a polymer started. Doria Al-Harra

33 The CC65 reactor was defective for 23 minutes. The reaction was completed after 333 minutes by adding Diga-acting methanol. IRGANOX 1520 antioxidant has been introduced. A sample was taken with a sampling tube fitted with a stopcock stopper and a needle to determine the alkali content. The wet shift ratio was measured: 99.12:. The resulting polymer was analyzed using GPC: 659395Mn, 1.374 D, 859395 Mw. The precise dose and styrene content have been measured.

35 block using 1H-NMR. The following products were tried: vinyl, 55.1 styrene.

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1,2-polybutadiene), calculated based on the ratio of 62.9 (butadiene): styrene block with a trace of 4 styrene units: 66, and styrene block with a trace of 6 units: 19 styrene.

Example Rum 19: (Using 53 k-3,7-dimethyl-3-octylate: (P DOP/hexanes)

5 5417 mM of cyclohexane was typified into a 13 liter nitrogen-purged reactor, from stainless steel pulp. 233.38 mM of 271 mmol, 1,3-butadiene was fed 3.113 mmol styrene of 53 k-3,7-dimethyl-3-octylate: p-heptane), and 1.14 mmol DOP (butyl lithium / The rated K mol/mol was 3.135, butyl lithium /DOP rated was 13 mol/mol-1.367). The mixture was heated to 73 °C, stirring. The amps were calibrated in the system by adding butyl lithium in batches. When checking the end point, the polymerization of a polymer was started by adding the following 1.37 mmol of n-15 (butyllithium: cyclohexane solution) using a 23-second agitation pump. The temperature was constant at 15 °C in the reactor at 73 ° C. The reaction was finalized after 133 minutes by adding degas-acting methanol. IRGANOX 1520 antioxidant has been included. A sample was taken using a sampling tube fitted with a stopcock stopper and a needle to determine the alpha content. Turnaround Ratio of 98.88: . The resulting polymer was analyzed using Mw, 672383-Mn: GPC 883836, D 1.238. The exact dosing and styrene block 33 content were measured using 1H-NMR. The following products were tried: 1,2-(vinyl, 55.6 styrene polybutadiene, based on the ratio of 43.6) butadiene: styrene block with a trace of 4 units 52 styrene, and styrene block styrene with a trace of 6 units. : 13 styrene

Example Rum 33: (Using 53 k-3,7-dimethyl-3-octylate: (P DOP/hexanes)

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5287 mM of cyclohexane was typified into a 13 L nitrogen-purged reactor, from stainless steel pulp. It was fed with 433.53 mm of 368 mmol, 1,3-butadiene, 3.111 mmol styrene of (53 k-3,7-dimethyl-3-octylate: p-heptane), and 1.117 mmol.

5 The reactor was driven by DOP (butyl lithium /K nmol/mol 3.389, butyl lithium /DOP nmol/mol 3.889). The mixture was heated to 73 °C by stirring, the amps were calibrated in the system by adding butyl lithium in batches. When checking a point. Finally, the polymerization of a polymer was started by adding the following water of 1.36 mmol of n-15 (butyllithium: p-cyclohexane solution) using an agitation pump for about 23 seconds.

13 When the polymerization of a polymer began. The temperature was kept constant in the reactor at 73°C. The reaction was resumed after 93 minutes by adding methanol.

Work carefully. IRGANOX 1520 antioxidant has been introduced. A sample was taken using a sampling tube fitted with a stopcock and a needle to determine the alpha content. Turnaround Ratio 99.95: Yes. The resulting polymer was analyzed using GPC:

15th 1.356 D, 761925 Mw, 636718Mn. The accurate training and content of Citrine Tel has been completed

styrene block using 1H-NMR. The following products were tried: 43.7 styrene:,1,2-polybutadiene (vinyl), calculated on the basis of the ratio 43 (butadiene:, styrene block which has a trace of 4 styrene units, and citrine hill block of styrene with a trace of 4 styrene). 7 styrene units:.

33 Example Rum 31: (Use of 53 k-3,7-dimethyl-3-octylate: (q) DOP / hexanes

18,787 mM of cyclohexane was filtered in a 43 liter nitrogen-purged reactor, from stainless steel pulps. Feed was 3,242 mmol of 56,939, 1,3-butadiene, 1,692 mmol styrene (53 mmol K-3,7-dimethyl-3-octylate: p-heptane), and 2.294 mmol

35 DOP is below the reactor (butyl lithium /K, 3.396 mol/mol, butyl lithium /DOP).

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The mixture was heated to 85 °C by stirring. The amps in the system were calibrated by adding butyl lithium in batches. When the end point was checked, polymerization of a polymer was started by adding the following water from 17.6 mmol-mol n 15 (butyllithium: a solution of p-cyclohexane) by nitroen pressure during 5 seconds.

5 When the polymerization of a polymer began. The temperature was kept constant in the reactor at 65 °C. The reaction was finalized after 63 minutes by adding the methanol factor Dica, then 1520 IRGANOX antioxidant was included. A sample was taken with a sampling tube fitted with a stopcock stopper and a needle to determine the alkali content. The wet shift ratio was measured: 99.67:. The resulting polymer was analyzed with GPC; 353673Mn,

1.39 D, 375487 Mw 13

The microparticle and styrene block content were measured using 1H-NMR. The following products were tried, 1,2-polybutadiene (vinyl: 38 styrene, calculated on the basis of the ratio 38.9) butadiene: a styrene block with a trace of 4 45 styrene units, and a styrene block styrene with a trace of 6 units.

15 13 :.

Examples and comparison examples show that the current plans provide a matrix copolymer of butadiene - styrene with a specific content of styrene, which has a trace of 4 successive styrene units, with a content of arc with a content of high molecule styrene with a content of vinyl styrene. Using a process according to the current tradat, the polymerization of polyarte

33 The new and severed products are applied to the protective elements using polymerization techniques with a high yield potential. The properties of the polymers according to what was referred to here are properties that precede any previous modifications, such as covering the frames, arranging, dilkh, the foregoing. As a result of achieving the current intentions to provide polymers with a narrow weight distribution, it is possible to try to obtain a large amount of the live chain frameworks when

The polymerization of a polymer, so that it is possible to make a uniform adjustment of the method

35 smooth running.

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4

The current inventors came as an exciting tool for a new SSBR with a high percentage of styrene and a high percentage of vinyl with a narrow weight distribution of the enzyme, and the inclusion of styrene on the hill with the effects of 15 styrene and 6 mixtures of groups: There are 5 other things that are not mentioned below. In some embodiments, SSBR, which has a high proportion of styrene and a high proportion of vinyl, also includes styrene in the form of a successive hill with more than 4 styrene units ranging between about 63 and about 83 F by weight.

Moreover, the current inventors have also - an exciting and unpredictable move - that it is possible to prepare an earlier SSBR with a high percentage of styrene and a high percentage of vinyl.

2-(2-ethoxyethoxy)-2-like (dialkylethers and) butyl lithium 13 using a starter (such as

methylpropane potassium alcoholate, in some embodiments under conditions

the following:, ≥25styrene content: by weight, p.m. potassium alcoholate/initiator ≤3.4; Heat polymerization of a polymer ≥ 93 °C.

In the context of the current situation, the following definitions should be taken into account:

15th The term polymerization of monomeric units refers to a substance prepared by polymerization of monomeric units. What is used here, the expression polymer includes the expressions homopolymer B (a polymeric material prepared from one type of monomer), with a copolymer B (a polymeric material prepared from two different types of monomers), and a polymer between (interpolymer). A polymeric compound prepared from traces of 33 different types of monomers.

The expression with an alkyl group in a straight, branched, or cyclic hydrocarbon chain, with no substitution or with no substitution, preferably contains between 1 and 33 carbon atoms. Distinctive examples of alkyl neutralizing fluids are substituted for use according to pharmacokinetics.

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The present: methyl, ethyl, propyl, iso-propyl, consider the following, for example, hot and what is abo. , cyclopropyl, butyl, iso-butyl, tert-butyl, sec- butyl, cyclobutyl

The expression process, when used for a period of time, refers to the polymerization of a polymer that includes continuous, non-continuous, and/or continuous processes. Expression

5 Either continuous or continuous. When used at a time during the polymerization process, there is a polymerization process in which more than 63 are carried out: From the solvent in the reactor, additives are added to the polymerization process. Rather, the polymerization of the polymer begins with the polymerization of a polymer. The monomer may be directly transferred to the initiator host, or to the initiator host, or to the initiator host, or directly to the initiator host, or to the continuous after addition of the initiator over a certain period of time.

13 Expression by continuous polymerization It is a polymerization process in which the solvent, the monomer (monomer), and any additional polymerization components are flown in a continuous process into a reactor with specified ratios. In some embodiments, two or more polymerization of a polymerization reactor loyal to the series, in some models, the reactor is driven by only one reactor,

An expression for the vinyl content of iodine indicative of the hydrophobic ratio of the mound (or by weight) butadiene iodine in the situation.

15th 1 and 3 in the polymer chain, based loll still butadiene) of the Mieh Mechanism of Bout was convicted monomer

polymerization butadiene ( p-polymer.

An expression for styrene content in a yyer indicates the hydration ratio (or weight) of styrene in the polymer, based on the weight of the polymer.

Expression with the content of styrene block styrene block A weight percentage of the modulated styrene is expressed as 33 or more successive sequences of styrene units based on the percentage of the polymerized styrene in the polymerized styrene.

The expression in a different order refers to a mixture of materials including a polymer and, optionally, reaction products and/or degradation products m^mon of the polymer material.

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Expression with a stimulating initiator (nBL,pm) refers to the axial water from the initiator (such as organ lithium) that is left in the polymerization reaction and has not been quenched by electrolytes in the reaction medium. Deactivate the impurities in 5 the system, deactivate the impurities in 5 the system, expressing the per cent of the monomer feed stream, deactivating the impurities in 5 the system, deactivating the impurities in the monomer feed stream. Driven by a continuous polymerization reactor, and typically, a continuous polymerization of a polymer reactor is okol,

An expression for the yyer yr transformation of a polymer denotes a slumbering transformation of a polymer (eg the sleeping rimal transformation of a polymer of styrene and butadiene) which is determined by the last polymer reactor and/or upon sintering

13 polymerization reaction.

By way of general introduction, a polymer that fills in the properties of the present rays will set the following properties on eating; (a) The styrene content of a styrene block containing a trace of 6 successive styrene units between about 15 and about 25 f by weight of the styrene content in the polymer; of 1,3-butadiene; (c) the styrene content ranges from about 25 to about 75 f by weight of the polymer; Models, polymer according to the current trends also have the following additional features on eating: (e) A styrene block content that contains a trace of 4 successive styrene units between about 83 and about 83 p, corresponding by weight of the styrene content in the polymer.

33 In some models, ion p-polymer that blocks the properties of the current styrene block styrene content with a trace of 6 successive styrene units between about 33 and about 23 p, the same by weight of the styrene content in the polymer.

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In some models, the polymer that clogs the properties of the current flows has a level of styrene that ranges between about 43 and about 65 F by weight, in some models between about 53 and 63 F by weight.

In some models, the polymer is produced in batches, and in some models, a continuous 5 cycle is produced. Currently, it is preferable, however, to produce polymer in batches according to current rates if the weight distribution (Mw/Mn) is 1.5 or L, such as between about 1.35 and about 1.45. In some models, the weight distribution is between about 1.1 and about 1.4. In some models, the weight distribution is between about 1.3 and about 1.25.

In some embodiments, the polymer is produced in a continuous process according to current trends.

13 In some models, the polymer that fills the properties of the current revenues has an average weight according to the number greater than or equal to about 333333 mm/mol. In some models, the average weight of the enzyme is given according to the number greater than or equal to about 233333 mm / mol. In some models, the average weight of the enzyme is given according to the number greater than or equal to about 533,333 m/mol.

In some models, the polymer that fills the properties of the current revenues has an average weight of 15 pounds, according to the weight greater than or equal to about 233333 mm/mol. In some models, the average weight of the enzyme is given according to the weight greater than or equal to about 433,333 mm / mol. In some embodiments, the average weight of the enzyme is determined according to the weight greater than or equal to about 633,333 m/mol.

The previous models are presented according to what was previously described in any combination, including combinations of the currently preferred models.

33 As a general introduction also, a process for the polymerization of a polymer is described

1,3-butadiene monomer and styrene monomer are identical to monomeric units

According to the present indications, it contains the polymerization of monomeric units with iodine initiator, potassium alcoholate and dialkylether.

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In some models, the pivotal ratio between dialkylethers and the active initiator is about 3.5. In some embodiments, the pivotal ratio between dialkylethers and the passive initiator ranges between about 3.5 and about 13.

In some embodiments, the styrene content of the monomer mixture is added to the polymerization

5 polymerization of a polymer more than about 25 µF by weight of the weight of a of the added monomers.

In some models, the polymerization process is carried out according to the current trends at a temperature of less than about 93 °C. In some models, the polymerization process is carried out according to the current rates at a temperature range between about 13 ° C and about 83 ° C,

13 The initiators that are currently preferred to be used according to the current tariffs include those suitable for anionic polymerization processes, in some models, the initiator of use according to the current nitrates is lithium (lithium organyl) (lithium organyl) lithium (a. Agents of alkyl lithium represented for use according to the current usages, consider the following, for example: -n n-pentyl lithium, butyl lithium -t, butyl lithium-s, butyllithium, etc.

15th And combinations of Minya, in some models, the initiator includes. n-butyllithium

In some embodiments, the transformation of the polymer is greater than about 96 wt% of the mechanical water of the monomer feed stream, in some embodiments, the transformation of the polymer is greater than

Out of about 98 pH in some embodiments, the transformation of the polymer is greater than about 99 pH by weight.

33 In some embodiments, the ion-polymer that quenches the properties of the current rays has a vinyl content ranging between about 35 and about 83 p by weight of the total amount of 1,3-butadiene. In some embodiments, the vinyl content varies between about 23 and about 75 pH by weight.

Some embodiments of the process according to the present excipients, potassium alcoholate complement potassium-2, 7-di-2-methyl- or tetate.

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In some process models, according to the current trends, the significant ratio between dialkylethers and potassium alcoholate is between about 43:1 and about 5:1.

Thanks to the process according to the current practices, polymer can be prepared what is not mentioned here,

It is currently preferable to take polymerization of a polymer according to

5 For the current p-solvents, hydrocarbon solvents are preferred. Currently, in some embodiments, a polymerization solvent is preferred over alkane. In some embodiments, the polymerization solvent is cyclohexane. There are some models, hopefully

alkane M cyclohexane was added to a mixture of polymerization solvent

one or more.

13 Also by way of general introduction, the polymer is graded according to the current trends with a process of the type described herein.

In some embodiments, it is possible to modify the polymer h according to current trends using chain-link modification and/or interactions. The suitable modifiers for the chain model and/or the arran coupling agents can be selected according to the use of the mist and the appropriate substance. meditate examples

15th R-Arne coupling agents include, for example, the following: tin tetrachloride, divinylbenzene, silicon tetrachloride, alkoxysilanes bitters, mAPO, and semen combinations.

Examples of modifiers include, for example, hot myl: amines, emes, silicon alkoxides, thioglycols, silane-sulfide modifiers.

33 What is sulfenyl halides, what is mentioned in the application document, ACOROPE RM 1316674,

Isocyanate, benzophenone, hydroxyl mercaptans, what is not in the order document, Acorup RM 3464478, acrylamide compounds, what is not in the order document, Acorup RM 3224343, and what is not, and their combinations. And the adverb of the superlative modification, consider the following, for example, in hot:

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Nitrile is not permitted in the ACORP application document No. 548799, ACOROB application No. 513413, ACOROB application No. 451634, and ACOROB application No. 183141, and in the country

Acrylic Code 4413341. In some embodiments, silanes are used including, for example, the following: epoxy-containing silanes are used to modify the

<p>5 A polymer chain for use in silica fillers, for example, the Akorob Demand Document RM-A-399374, the Acurorob Order RM-A-399374, the Acurorob Rm-A 343-44, Request Document RM69-1333 Supplementary examples of the amendment articles and/or the amendments to the regulations that these articles refer to in the order document.</p>

States RM 124665/3339.

<p>13 By way of general introduction also, the matrix that cushions the properties of the present wills contains a polymer of the type mentioned herein. In some models, the soil according to the current trends contains</p>

It also contains additives, such as oil, which, in some models, contain a formulation according to current trends.

Also on oil with an amount ranging between about 5 and about 43 F, which is the weight of the polymer. In some models, the composition according to the current tariffs contains oil.

<p>15th In some embodiments, a formulation according to the present regulations contains a polymer of the type mentioned herein and one additive each. In some embodiments, the polymer is combined and/or reacts with one appropriate substance or effect, a vulcanization agent, and/or optionally one other host substance or effect, such as: uncrosslinked arsenic coupling agents</p>

<p>33 elastomeric polymers that do not have cross-links (i.e. conventional polymers that do not have cross-links and that do not have a modified substance, and that have not been prepared and prepared), and their analogues.</p>

In some embodiments, formulations according to the present trends contain one or more suitable substances, acting as strengthening agents. Distinctive examples of relevant and appropriate materials consider the following, for example:

35 carbon black, silica, dual-phase filler

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From carbon and silica, magnesium carbonate, calcium carbonate, clay, and mabo, and semen combinations. In some models, a combination of carbon black and silica is used, and a double-phase filler of carbon and silica, or a combination of a dual-phase filler of carbon, silica, and carbon black and/

5 or silica.

In some models, carbon black is prepared by the oven method, and if a specific surface area protects nitrogen adsorption between about 53 and 333 m 3 / day, and DBP oil absorption is between about 83 and about 333 ml / 133 m (such as FEF). HAF, ISAF or carbon black from the mouth of SAF. In some models, 13 carbon black is used of the most flammable type. In some models, carbon black or silica is used in an amount ranging between about 3 and about 133 by weight, while 133 is removed by weight of the polymer. In some models, carbon black or silica is warmed with an amount ranging from about 5 to about 133 removed by weight. In some models, carbon black or silica is tamed with an amount ranging between about 13 15 and about 133 by weight. In some models, carbon black or silica is tamed by weight.

silica in an amount ranging from about 13 to 95 by weight.

Finally, as well as for general presentation, a product that fills the characteristics of the current revenues contains a single component of a salty diet of this mixture. In some models, the product is car tires. In some embodiments, the product is a shoe insert.

33 The following examples, and I see the expressions represented, illustrate the properties according to the current trends, and they are presented only for the sake of clarification. This is led by examples of limiting the scope of ancillary protection elements or its equivalent.

examples

The monomer transformation was determined by measuring the sulfur content of the polymer solution. When the polymerization of a polymer begins, an attempt is made on any sulfur material at 133:

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By weight conversion of butadiene (mBd) and styrene (mSt) hydrates to a sleeping polymer

in the following decimal

TSC max- (mBd+ mSt)/(mBd + mSt + mpolar agent + mSL+

(mcyclohexane*100): A sample of a polymer solution was drawn between about 1 day

5 About 13 m, according to the monomer transformation, from the reactor directly from the reactor a 333 ml Erlenmeyer tube filled with 53 ml ethanol ( ethanol) was directly drawn from the reactor. The weight of the filled Erlenmeyer tube was determined by “B” sample taking (A). The precipitated ethanol polymer was sieved over a weighted paper filter (Micro-glass, 93 mm diameter, MUNKTELL, weight “C”), and lyophilized at 143 °C, using a moisture analysis assay.

13 Mettier-Toledo (HR73 moisture analyzer) until the first showed a constant weight. Criterion 5 was used.

Optionally, a second typhoid period was carried out using higher 4 criteria to try the 'D' sleepy mound for the fiber sample on a gradual basis. The polymer content was calculated in the sample as follows:

:TSC= (DC)/(BA)*100

15th The sleep shift of the polymer was calculated as 100*TSC/TSC max:

The lysosome weight and the lysosomal weight distribution of the polymer were quantified using Arvia chromosomal exclusion (SEC) based on standard polystyrene levels. The sample (9-11 mm polymer) was atomized (13 ml tetrahydrofuran) to make a solution. The solution was filtered using 3.45 mm scales. A 133 mM sample was fed.

33 The Hewlett Packard system GPC (1100) column was dewatered by 13 columns PLgel 3 µm MiXED-B at 43°C. The Refraction Index detection factor was used only as the detector for analyzing the molecular weight was calculated. As a polystyrene based on manual titration with

Polymer of polystyrene EasiCal PS1 Standard Levels (Easy A and B)

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Laboratories. The average lysosome weight is given according to the number (Mn) and the average lyzyme is given according to the weight (Mw) given based on the polystyrene standard levels.

Vinyl and styrene content were measured using 1H-NMR, ISO method.

5 21561-2005. Using a 433BRUKER Avance MIA NMR Spectrophotometer

The styrene block, which consists of traces of 6 sequential styrene units, was determined according to the atomization method, Y. Tanaka et al. al q :

Using Rubber Chemistry and Technology, 1981, 54, No. 4, 685-691

13 The relative instrument ortho Ph-proton that gives a resonance at higher than 6.7 ppm. The content of the styrene block, which consists of 4 consecutive styrene units and traces, was determined according to the method carried out in the word document R 69713963 using the relative substance ortho 6 and Ph-proton94. The content of a styrene block, which consists of 4 to 6 sequential units

15th Calculation of the difference between l of the contents of the former styrene block.

Comparative example RM 13: (use of KDMO) K-3,7-dimethyl-3-octylate) or K below ((53: p-hexanes)).

5276.55 mM of cyclohexane was added and a 13 L nitrogen-purged reactor was centrifuged.

33 steel . 236.17 mM of 432.72, 1,3-butadiene mM of styrene, and 3.382 mmol of (53 K-3,7-dimethyl-3-octylate: p-heptane) were fed butyl lithium /K (butyl lithium /K) nmol/ 3.376 Mall (.

The mixture was heated to 53 °C, stirring. The amps were calibrated in the system by adding butyl lithium in batches. Upon verification of the end point, polymerization of . is initiated

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a polymer by adding a total of 1,466 mmol of 15 (n-butyllithium: p-cyclohexane solution) using a stirring pump for 1 min 19 sec.

When did the polymerization of a polymer begin? The temperature in the reactor increased to 65 °C during 23 minutes. The reaction was resumed after 333 minutes by adding a 5-minute methanol agent. IRGANOX 1520 antioxidant has been introduced.

A sample was taken using a sampling tube fitted with a stopcock stopper and a needle to determine the content of the solids. The TPL conversion ratio of 99.57:.

The resulting polymer was analyzed using GPC; D, 674699 Mw, 522626 Mn 1.364. The exact triglycerides and styrene block content were measured using 1H-NMR.

13 The following products were tried: 1,2-polybutadiene (vinyl) : 55.3 styrene, computed on the basis of the ratio 13.2 (butadiene : citrine &lt;6 (styrene block) sequential units) 42: and citrine tel &lt;4 (styrene block) sequential units. 86: -

Rum 12 Comparative Example: (Using 3-(3-CMX) ethoxyethoxy)-2-methylpropane)

5266.99 mM of cyclohexane was added, typhoid into a lye-free reactor and washed 15 L with nitrogen-purged 13 L a stainless steel pulp reactor. 235.97 mm of 432.23 mm of styrene, 1,3-butadiene, and 2.6713 mmol of CMX were fed to the reactor (butyl lithium /CMX n mol/mol = 3.57).

The mixture was heated to 53 °C, stirring. The amps were calibrated in the system by adding butyl 33 lithium in batches. When the end point was checked, polymerization of a polymer was started by adding a total of 1.439 mmol of 15 (n-butyllithium: p-cyclohexane solution) using a 1 min 47 sec agitation pump.

. polymerization of a polymer

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The temperature of the reactor rose to 65 ° C in the course of 23 minutes. The reaction was resumed after 333 minutes by adding Diga agent methanol. IRGANOX 1520 ANTI-LICULATIONS INTRODUCED

. antioxidant

A sample was taken with a sampling tube fitted with a stopcock stopper and a needle to determine the content of 5 albite, TPR 98.35: measured.

The resulting polymer was analyzed using D, 731914 Mw, 587297 Mn: GPC 1.339. The exact triglycerides and styrene block content were measured using 1H-NMR. The following products were tried: 1,2-polybutadiene (vinyl: 55.3 styrene, calculated on the basis of the ratio of 43.3 (butadiene): styrene tel &lt;6 (styrene block).

13 sequential units (56:, and styrene block &lt;4), sequential units (=71:.

Example Rum 33: (Using 53 K-3,7-dimethyl-3-octylate: (P CMX /hexanes)

5,243 mM of cyclohexane was typified in a nitrogen-purged 13 L reactor from a stainless steel pulp reactor. fed with 234.48 mM of 431.33, 1,3-butadiene mM of styrene,

15th 3.1338 mmol of (53,7-dimethyl-3-octylate: K-3,7-dimethyl-3-octylate) heptane

The reactor was impelled with 2.5544 mmol CMX (butyl lithium /K mol / 3.391 mol, butyl lithium /CMX rated 3.8). The mixture was heated to 53 °C under stirring. From the end point, the polymerization of a polymer was started by adding the following water of 1.2317 mmol.

33 of 15 (n-butyllithium: cyclohexane solution) using a stirring pump for 1 minute 43 seconds. When the polymerization of a polymer began. The temperature of the reactor increased to 65 °C for 23 minutes, the reaction was completed after 153 minutes. By adding deca-agent methanol, IRGANOX 1520 antioxidant was inserted, and a sample was taken by means of a sampling tube equipped with a stopcock stopper and a needle to determine the content of substances

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Alaba. Turnaround ratio of 99.62: . The resulting polymer was analyzed using GPC: 1.2 D, 783217 Mw, 631932Mn. The exact dosing and styrene block content were measured using 1H-NMR. The following products were tried: , 55: 1,2-polybutadiene (vinyl styrene), computed on the basis of the ratio 42.2 (butadiene: citrine 5 &lt;6 styrene block sequential units) 38: styrene block &lt;4, styrene block sequential units. (75:.

Example Rum 32: (Using 53 K-3,7-dimethyl-3-octylate: (P CMX /hexanes)

5636.74 mM of cyclohexane was added and refluxed into a nitrogen-purged 13 liter nitrogen-purged reactor with a 13 liter stainless steel pulp reactor. The reactor was fed with 317.6 mm of 367.8, 1,3-butadiene from styrene, 3.116 mmol of 53 K-3,7-dimethyl-3-octylate: p-heptane, and 2.467 mmol CMX in the reactor (butyl lithium / K mol/mol 3.3837, butyl /CMX lithium (2.467). The mixture was heated to 53 °C, stirring. The pumps were calibrated in the system by adding butyl lithium in batches. When checking the end point, the polymerization was started.

15th polymerization of a polymer by adding the nightly 3.7 mmol of n- (15-butyllithium: p-cyclohexane solution) using a 53-second whisk pump. Minutes After 133 minutes, the reaction was completed by adding methanol, an anti-oxidant, 1520 IRGANOX. Samples were taken using 33 sampling tubes fitted with a stopcock stopper and a needle to determine the alpha content. TM Yas turnover ratio of 99.47:.

The resultant polymer was analyzed using D, 892869 Mw, 636994 Mn: GPC 1.47, the microarray and styrene block content were measured using 1H-NMR. The following products were tried: 1,2-polybutadiene (vinyl, 52.9 styrene,

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Calculated based on the ratio of 25.5 (butadiene: citrine &lt;6 (styrene block sequential units) 39:, and citrine tel &lt;4 styrene block sequential units (=74:.

Example Rum 34: (Using (53K-3,7-dimethyl-3-octylate): CMX/hexanes)

2568.39 yM of cyclohexane was added and washed into the lye-free reactor.

5 a nitrogen-purged 13-liter reactor from a stainless steel core. fed with 294.2 mm of 365.56 mm of styrene, 1,3-butadiene, 3.1132 mmol of K-3,7-dimethyl-3-octylate (53), heptane

And 2.2314 mmol CMX was precipitated by the reactor (butyl lithium /K current mol/mol 3.397, butyl lithium /CMX current 3.917). The mixture was heated to 73°C, stirring. It was calibrated

13 Pumps into the system by adding butyl lithium in batches. When the end point was checked, the polymerization of a polymer was started by adding a current of 1.1216 mmol of (15 n-butyllithium: p-cyclohexane solution) using a stirring pump for 1 minute 53 seconds. When the polymerization process started, the polymerization of a polymer was started The temperature was kept constant in the reactor at 73 °C during the reaction.The minimum reaction was completed after 143 minutes by adding

15th De-agent methanol, IRGANOX 1520 antioxidant was introduced. A sample was taken with a sampling tube fitted with a stopcock stopper and a needle to determine the content of the alkaline material. The wet shift ratio was measured: 99.71:. The resulting polymer was analyzed with GPC: 1.445 D, 912473 Mw, 623355Mn. The microarray and styrene block content were measured using 1H-NMR.

33 The following products were tried: 1,2-polybutadiene (vinyl.: 29.6 styrene,

Calculated based on the ratio of 23.4 (butadiene: styrene block &lt;6 sequential units) 33:, and citrine tel &lt;4 styrene block sequential units: 64:.

Example Rum 35: (Using 53 K-3,7-dimethyl-3-octylate: (P CMX /hexanes)

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5874.42 mM of cyclohexane was added and refluxed into a 13 L nitrogen-purged nitrogen-purged reactor with a stainless steel pulp reactor. fed with 294.4 mm of 367.73 mm of styrene, 1,3-butadiene, 3.1391 mmol of K-3,7-dimethyl-3-octylate (53: p-heptane), and 2.2226

5 mmol/mol CMX of the reactor (butyl lithium /KN 3.383 mol/mol, butyl /CMX

lithium battery (3.516). The mixture was heated to 53° C. The stirred, the ampoules were calibrated in the system by adding butyl lithium in batches, when checking the end point, the polymerization of a polymer was started with an addition of 1.2-35 mol lithium polymer. (butyllithium: p-cyclohexane solution) using a stirrer pump 1 min 13 sec.

13 When the polymerization of a polymer began. The temperature was kept constant in the reactor at 53°C during the reaction. The reaction was resumed after 313 minutes by adding Diga-factor methanol. IRGANOX 1520 antioxidant has been introduced. A sample was taken with a sampling tube fitted with a stopcock stopper and a needle to determine the content of the allergen. The TPL conversion ratio was 98.34:. The resulting polymer was analyzed using GPC:

15th 1.3355 D, 676792 Mw, 561837 Mn. The accurate training and citrine content has been completed

Tel styrene block Using 1H-NMR, the following products were tried: styrene 29.9:, 1,2-polybutadiene (vinyl), calculated on the basis of the ratio of 44 (butadiene: citrine, &lt;6) styrene block (31:, and styrene block &lt;6) sequential units. styrene block (&gt;4 sequential units) 65 :.

33 Examples and comparison examples show that the current results provide a matriarchal copolymer of styrene-dienepo with a specific content of styrene based on the effect of 4 sequential styrene units, with a narrow content of vinyltyrene and a content of lipids required. Using a process according to current trends, the polymerization of new and slitting polymers is provided in the protection elements by using high yield plastic polymerization techniques. for properties

35 Polymers, according to what has been titled, have properties that precede any previous modifications, such as covering the frames,

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R-Arn, Delkh, the above-mentioned. As a result of achieving the current intentions to provide polymers with a narrow weight distribution, it is possible to try a large amount of the framework of the live chain when polymerization of a polymer, so that a regular adjustment of the chain frames can be made.

The full contents of each of the articles and documents of the said inventions are included in the name of 5 patients, who are in the process of providing them with any information or specifications.

The current law, or the current exposure, is the approved one.

The foregoing has been provided for clarity and clarification, and its growth is not led to limit the scope of the appended elements of protection. Many of the changes to the currently preferred models described here will be within the capacity of an individual with ordinary skill in the art, and will remain within the scope of the ancillary elements of protection and their equivalent.

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