Process for the halogenation of 3,3,3-trifluoropropene
Abstract
1. A process for preparing a compound of formula CF3CHFCH2X, where X is Cl or F, comprising contacting the 3,3,3-trichloropropene (1243zf) with a compound of formula AB selected from Cl2, Br2, I2, ClF, ClBr and ICl, HF and catalyst in the presence tsinkhromovogo to form a compound of formula CF3CHFCH2X. 2. The method of claim 1, which is carried out at a pressure of from about 100 to about 2000 kPa (1-20 bar). 3. The method of claim 1, which is carried out at a temperature from about 50 ° C to about 400 ° C. 4. The method of claim 1 wherein the compound of formula AB represents Cl2. 5. The method of claim 1, wherein the molar ratio of 1243zf: compound of formula AB is from about 10: 1 to about 1: 5. 6. The method of claim 5, wherein the molar ratio of 1243zf: compound of formula AB is from about 5: 1 to about 1: 2. 7. The method of claim 1 wherein HF is used in molar excess compared to the amount of 1243zf and / or a compound of formula AB. 8. The method of claim 7, wherein the molar ratio of HF: 1243zf is from about 2: 1 to about 150: 1. 9. A method according to any one of the preceding claims, wherein tsinkhromovy catalyst is an oxide, oxyfluoride or fluoride of chromium, comprising zinc or a zinc compound. 10. The method of claim 9 wherein tsinkhromovy catalyst is an oxide, oxyfluoride or fluoride of chromium, comprising zinc or a zinc compound in an amount from about 0.01 wt.% To about 25 wt.%.
Term
No projected expiry on record.
- Priority
- Filed
- Published
- Today
11 claims: 3 independent, 8 dependent
- 1This invention provides a process for the preparation of a compound of formula CF 3 CHFCH 2 X, wherein X is Cl or F, the process comprising contacting 3,3,3-trifluoropropene (1243zf) with a compound of formula AB selected from Cl 2, Br 2, I 2, CIF, ClBr, and ICI and HF in the presence of a zinc / chromia catalyst to produce the compound of formula CF 3 CHFCH 2 X.
- 21. A process for preparing a compound of formula CF3CHFCH2X, where X is Cl or F, comprising contacting 3,3,3-trihlorp ropena (1243zf) with a compound of formula AB selected from Cl2, Br2, I2, ClF, ClBr and ICl, HF and catalyst in the presence tsinkhromovogo to form a compound of formula CF3CHFCH2X.
- 109. A method according to any one of the preceding claims, wherein tsinkhromovy catalyst is an oxide, oxyfluoride or fluoride of chromium, comprising zinc or a zinc compound.
Independent claims3
34 members in 13 offices
Priority claims4
| Document | Office | Kind | Date |
|---|---|---|---|
| 0806389 | United Kingdom | A | |
| 08063893 | United Kingdom | – | |
| 08063893 | – | – | – |
| GB20080006389 | – | – | – |
Members34
| Document | Office | Kind | |
|---|---|---|---|
| AU2009235215A1 | Australia | A1 | |
| CA2721124A1 | Canada | A1 | |
| CA2796517A1 | Canada | A1 | |
| WO2009125201A2 | World Intellectual Property Organization (WIPO) | A2 | |
| WO2009125201A3 | World Intellectual Property Organization (WIPO) | A3 | |
| KR20110004434A | Republic of Korea | A | |
| EP2294040A2 | European Patent Office (EPO) | A2 | |
| CN102056876A | China | A | |
| US2011112340A1 | United States of America | A1 | |
| JP2011516534A | Japan | A | |
| HK1153728A | Hong Kong, China | A | |
| RU2010145335A | Russian Federation | A | |
| RU2463285C2 | Russian Federation | C2 | |
| US2013102815A1 | United States of America | A1 | |
| EP2599764A2 | European Patent Office (EPO) | A2 | |
| CA2721124C | Canada | C | |
| US8552228B2 | United States of America | B2 | |
| KR101326733B1 | Republic of Korea | B1 | |
| JP2013237684A | Japan | A | |
| EP2599764A3 | European Patent Office (EPO) | A3 | |
| RU2012124129AThis record | Russian Federation | A | |
| US2014012050A1 | United States of America | A1 | |
| US8629307B2 | United States of America | B2 | |
| US8697923B2 | United States of America | B2 | |
| ZA201007983B | South Africa | B | |
| CN102056876B | China | B | |
| RU2523546C2 | Russian Federation | C2 | |
| CN104030883A | China | A | |
| JP5732492B2 | Japan | B2 | |
| CA2796517C | Canada | C | |
| IN2406DEN2015A | India | A | |
| BRPI0911254A2 | Brazil | A2 | |
| EP2294040B1 | European Patent Office (EPO) | B1 | |
| CN104030883B | China | B |
1 legal event, as the office reported them to INPADOC
Events
| Event | Code | |
|---|---|---|
| The patent is invalid due to non-payment of feesMM4A | MM4A |
Numbers
- Publication
- 2012124129
- Publication, DOCDB
- 2012124129
- Publication, EPODOC
- RU2012124129
- Application
- 12412904
- Application, DOCDB
- 2012124129
- Application, EPODOC
- RU20120124129
Titles2
- Russian
- ?????? ????????? 2,3,3,3-????????????????
- English
- METHOD FOR PRODUCING 2,3,3,3-tetrafluoropropene
Classification
- CPC, 7
- C07C17/087
- C07C17/04
- C07C17/204
- C07C17/206
- C07C17/25
- C07C17/275
- C07C21/18