PL337997A1

High-activity catalyst for use in production of polyethylene

Abstract

The present invention relates to a high activity catalyst composition for the (co-)polymerisation of ethylene, optionally with an alpha olefin of 3 to 10 carbon atoms, comprising a catalyst precursor and an organoaluminium cocatalyst, wherein the catalyst precursor consists of: (i) a silica carrier material, having from 0.3 to 1.2 mmoles of OH groups per gram of silica, (ii) a dialkylmagnesium compound of the formula RMgR1, where R and R1 are the same or different C2-C12 alkyl groups, in an amount comprised between 0.5 to 1.5 mmoles of dialkylmagnesium per gram of silica, (iii) a tetraalkyl orthosilicate, in which the alkyl groups contain from 2 to 6 carbon atoms, in an amount comprised between 0.2 to 0.8 mmoles per gram of silica, (iv) a chlorinated compound (X) having the formula RnSiCl4-n, wherein each R is the same or different and is hydrogen or an alkyl group and n is an integer from 0 to 3, in an amount comprised between 0.2 to 4 mmoles of X per gram of silica, and (v) a titanium compound in an amount comprised between 0.3 to 1.5 mmoles per gram of silica.

Term

Term ended

Projected expiry passed 22 July 2018, 8.2 years ago.

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34 members in 24 offices

This recordMember, by publication datePriority claim14 more offices are in the list below

Priority claims8

Priority claims
DocumentOfficeKindDate
97430020European Patent Office (EPO)A
97430020European Patent Office (EPO)A
9802181United KingdomW
9802181United KingdomW
97430020
EP19970430020
GB9802181
WO1998GB02181

Members34

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CA2295498A1CanadaA1
WO9905187A1World Intellectual Property Organization (WIPO)A1
AU8453698AAustraliaA
NO20000359D0NorwayD0
ZA986590BSouth AfricaB
NO20000359LNorwayL
EP0998503A1European Patent Office (EPO)A1
SK752000A3SlovakiaA3
ID24621AIndonesiaA
CN1264393AChinaA
BR9810814ABrazilA
TR200000182T2TürkiyeT2
PL337997A1This recordPolandA1
US6136745AUnited States of AmericaA
EA200000088A1Eurasian Patent Organization (EAPO)A1
HU0002642A2HungaryA2
HUP0002642A2HungaryA2
TW418217BTaiwan Province of ChinaB
KR20010022116ARepublic of KoreaA
EG21253AEgyptA
HU0002642A3HungaryA3
HUP0002642A3HungaryA3
NZ502349ANew ZealandA
JP2001510865AJapanA
EA001786B1Eurasian Patent Organization (EAPO)B1
AU737956B2AustraliaB2
HU220591B1HungaryB1
EP0998503B1European Patent Office (EPO)B1
AT223444TAustriaT
ATE223444T1AustriaT1
DE69807703D1GermanyD1
DE69807703T2GermanyT2
DZ2573A1AlgeriaA1
ES2183393T3SpainT3