Antiperspirant/deodorant composition

[0001] Antiperspirant and / or deodorant compositions are used to reduce perspiration around the armpits (and underarms) and / or to kill bacteria in this region to reduce or eliminate body odor caused by bacterial growth in this region. Antiperspirants / deodorants can be provided in many forms, such as roll on, gel, or in a solid stick. These compositions are used around the armpits, and they dry as soon as their volatile carriers evaporate to leave active material. When the compositions on the roll on or gel dry, they can leave a feeling of stickiness and moisture on the skin.

[0002] It would be desirable to provide an antiperspirant / deodorant composition that reduces or eliminates stickiness and / or moisture, in particular for roll on applications where the water content is usually more than 50% of their composition.

[0002a] JP 62-111912 discloses an antiperspirant stick.

SUMMARY OF THE INVENTION [0003] The composition comprises: a. A structuring agent of a composition comprising at least one oil of plant origin with a melting point of 26 to 38 ° C, at least one oil of plant origin containing partially hardened soybean oil in an amount of 5% or less by weight; b. at least one active selected from the antiperspirant active ingredients and the deodorant active ingredients in an amount of 0.5 to 16% by weight of the composition based on the active weight; c. water in an amount that is at least 20% by weight of the composition to form a roll-on composition.

DETAILED DESCRIPTION OF THE INVENTION [0004] As is commonly used, ranges are used as a summary of the description of each value that is within a given range . Any value within the range can be selected as the end of the range. References to amounts in percent herein are based on the active weight of the material relative to the total weight of the composition, except for surfactants which are based on that as mentioned.

[0005] The present composition may be a liquid or gel. In liquid form, the composition can be formulated to become an antiperspirant and / or deodorant roll on. In liquid form, the composition may be an oil in an aqueous emulsion or water in an oil emulsion. In one embodiment, the composition is an oil in a liquid aqueous emulsion. In the form of a gel, the composition may be anhydrous or aqueous. The liquid can be contained in any roll on dispenser, which has a ball for applying the composition to the surface of the skin.

[0006] In one embodiment, the composition excludes glycerin (glycerol), sorbitol, ethylene glycol, propylene glycol, sunflower oil, borage seed oil and combinations thereof. If present in sufficient amounts, these materials increase the viscosity of the composition as well as the drying time of the product. In addition, the addition of these components does not add structure to the composition.

[0007] The composition contains vegetable oil with a melting point of 26 to 38 ° C, which consists of partially hardened As soybean oil as used herein, the term oil contains materials that are defined as liquid wax. The methyl and ethyl esters of vegetable oils have also been included in the definition of vegetable oils. This oil of plant origin provides the structure of the composition. In one form, this material is present in an amount of about 5% or less by weight of the composition. Levels significantly higher than 5% will give an oily / greasy feel to the composition and increase drying time. In one form, the amount of vegetable oil is about 1 to about 3% by weight of the composition. Examples of further oils of vegetable origin include, but are not limited to, both, coconut oil, safflower oil, palm oil, cottonseed oil and pine nut oil. In some embodiments, vegetable oils are partially cured versions of these oils. Lower levels of unsaturation can reduce the potential chemical interaction with other roll on ingredients and can also reduce the oil's tendency to oxidize and create a rancid odor that is more difficult to vent. Iodine value and percentage of saturation (which are inversely proportional to each other) are two ways to describe the degree of hardening present in oil of plant origin.

[0008] The presence of vegetable oil reduces the viscosity of the active antiperspirant which is in the aqueous phase. The addition of optional emollients in combination with vegetable oil can also give the desired effect if the total amount of emollients and vegetable oil is about 5% or less. Viscosity depends on the sensor panel of experts, consisting of at least 10 trained panelists who evaluate the properties of formulas in relation to the skin feeling. One of the product characteristics measured in the test, both on the forearm and on the feed, is viscosity. A trained panelist assesses the product viscosity by touching the product with your fingertips at specific intervals and rating the viscosity on a scale of 0 (no viscosity) to 10 (very high viscosity).

[0009] Improving the perception of moisture can also be achieved by providing a certain structure and body to the formula that the user perceives as providing wealth to the formula.

[0010] Vegetable oil is selected for partial hardening and has a melting point of 26 ° C (80 ° F) to 38 ° C (100 ° F). To achieve the desired melting point, at least one vegetable oil is partially hardened or a blend of unhardened with partially or fully hardened oils and / or waxes.

[0011] In one embodiment, the vegetable oil contains partially hardened soybean oil having an iodine value in the range of about 75 to about 80. Iodine value can be measured by ASTM D5554-95 (2006). This partially hardened soybean oil can be obtained from Cargill under the product name S-500. This material has the typical fatty acid distribution shown in the table below. The amounts shown are in% by weight.

<td>C16: 0</td><td> 10,5-11,2</td>

<td>C18: 0</td><td> 6,8-7,5</td>

<td>C18: 1</td><td> 61-65</td>

<td>C18: 2</td><td> 16-19</td>

<td>C18: 3</td><td> 0-0,2</td>

<td>saturated</td><td> 17,5-19,5</td>

<td>Trance</td><td> 34-39</td>

[0012] Another benefit of using partially hardened soybean oil is that it can provide a structure in the form of increased viscosity for the composition. The viscosity or structure of the liquid composition is measured in mPas (centipoise) by a Brookfield viscometer at 23 ° C using spindle 4 with RPM set to 20. The viscosity of the gel composition is measured in Pa (G 'and G ") by AR 1000 rheometer at 21 ° C using oscillatory mode.

[0013] An additional advantage of using partially hardened soybean oil in the context of the present invention is the easy aroma of the composition. The reduced level of unpleasant odor created during the aging of the composition during formulation with partially hardened soy oils, allows the fragrance to provide great fragrance hedonics without having to hide the unpleasant odor. Partially hardened soybean oils have a lower iodine value, which corresponds to fewer double bonds. The reduced number of double bonds provides less tendency to fragrance degradation.

[0014] Any surfactant that can be used in antiperspirant and / or deodorant compositions can be included. The surfactant can be included in any amount. In one embodiment, the amount of surfactant is from 2 to 12% by weight of the composition. The amount in the composition is based on how the material supplied. In another embodiment, the amount of surfactant is about 3 to about 10% by weight. In one embodiment, when the composition is an oil in water roll-on formula, the amount of surfactant is about 2 to about 5%. In one embodiment, when the composition is a water in oil gel composition, the amount of surfactant is about 3 to about 10%. Examples of surfactants include, but are not limited to, nonionic surfactants, silicon surfactants, and combinations thereof.

[0015] Nonionic surfactants that may be used include, but are not limited to, (a) sorbitol esters and ethoxylated sorbitol esters (e.g., PEG-20 sorbitan isostearate, <a href="http://megaslownik.pl/slownik/polsko_angielski/,monolaurynian+sorbitolu">sorbitol monolaurate</a>, <a href="http://megaslownik.pl/slownik/polsko_angielski/,polisorbat">polysorbate</a>-20, polysorbate-40, polysorbate-60, polysorbate-80); (b) ethoxylates (e.g., Ceteth-20, PEG-30 castor oil, PEG-40 hardened castor oil, PEG-60 hardened castor oil, Laureth-7,

Isolaureth-6, Steareth-10, Steareth-20, Steareth-21, Steareth-100, Ceteareth-12, Oleth-5, Oleth-10); (c) ethoxylated<a href="http://megaslownik.pl/slownik/polsko_angielski/,zwi%C4%85zek+addycyjny">addition compounds</a>e (e.g., PEG-25 stearate, glycerol stearate and PEG-100 stearate); (d) PEG esters (e.g., PEG-8 oleate, PEG-8 laurate, PEG-8 dilaurate, PEG-12 dilaurate, PEG-80 diisostearate, PEG-40 stearate);

(e) propoxylates (e.g. PPG-10 butanediol, PPG-50 oleyl ether, PPG-2-Ceteareth-9, PPG-3-deceth-3, PPG-5-ceteth-20); (f) ethoxylated modified triglycerides (e.g., PEG-20 corn glycerides, PEG-12 palm kernel glycerides); (g) alkylphenol aromatic ethoxylates (e.g. dinonylphenol ethoxylate with 9 moles EO, octylphenol ethoxylate with 20 moles EO, octylphenol ethoxylate with 40 moles EO); (h) block copolymers that are alkoxylated glycols having ethoxylated and propoxylated segments (e.g., POLOXAMER ™ 182 and 234, POLOXAMER ™ 105 Benzoate and MEROXAPOL ™ 174); and their combinations. In one embodiment, the nonionic surfactant is selected to have an HLB (hydrophilic-lipophilic balance) value of 8-16 (especially 8-12).

[0016] In one embodiment, the nonionic surfactant is selected from ethoxylated nonionic surfactants and propoxylated nonionic surfactants. These include, for example, but are not limited to, Steareth 2, Steareth 20 and Steareth 21. In oil in the form of an aqueous composition, a combination of two surfactants can be used, where the HLB value of one is from about 2 to about 8 (such as Steareth 2) and the HLB value of another is about 9 to about 18 (such as Steareth 20 and 21) [ [0017] Examples of silicon surfactants can be found in US Patent No. 6,485,716. Suitable silicon surfactants include silicone polyglycosides (e.g. <a href="http://pl.bab.la/slownik/polski-angielski/poli-dimetylosiloksan">polydimethylsiloxane</a> octyl ethoxy glycoside) and silicon copolyol with an HLB (hydrophilic lipophilic balance) &lt;8. The HLB value can be measured in various ways as described in conventional sources of information or as found in the data tables recording such values. It is assumed that all types of HLB measurement techniques can be used.

[0018] In general, silicon copolyols include, but are not limited to, copolyols of the following Formulas I and II. Pattern and materials can be represented by:

(R¹⁰) 3 SiO [(R¹¹) 2SiO] xSi (R¹²) (R^bO (C2H4O) p (C3H6O) sR^c) O] ySi (R¹³)3 _{where each of R}¹⁰, R¹¹, R¹²_{and R}¹³ may be the same or different and each is selected from C 1 -C 6, R alkyl^b is the -C.mH2m- radical; R^c is a terminating radical which may be hydrogen, an alkyl group of one to six carbon atoms, an ester group such as acyl, or an aryl group such as phenyl; m is two to eight; pis have values ​​such that the oxyalkylene segment - (C2H4O) p- (C3H.6O). s- has a molecular weight in the range from 200 to 5,000; the segment preferably has fifty to one hundred mole percent oxyethylene- (C2H4O) p- and one to fifty mole percent oxyethylene- (C3H6O) units. s-; x has a value from 8 to 400; ay is from 2 to 40. Preferably each of R¹⁰, R¹¹, R¹² and R¹³ is a methyl group; R^c is H; m is preferably a three or four, where the R group^b most preferably it is - (CH2) 3-; and the pis values ​​are such as to provide the molecular weight of the oxyalkylene segment - (C2H4O) p- (C3H6O) s- between about 1,000 and 3,000. In one embodiment, each pis should be between about 18 and 28. In one embodiment silicon copolyol is a copolyol<a href="http://pl.bab.la/slownik/polski-angielski/poli-dimetylosiloksan">polydimethylsiloxane</a>.

[0019] A second silicon polyether (copolyol) of formula II:

(R¹⁰) 3SiO [(R¹¹) 2SiO] xSi (R¹²) (R^bO (C2H4O) pR^c) O] ySi (R¹³) 3 in which p is between 6 and 16; x is between 6 and 100; iy is between 1 and 20 and other molecules have the same definition as defined in formula I.

[0020] It should be understood, as in both formulas I and II indicated above, that siloxane-oxyalkylene copolymers may, in alternative forms, take the form of blocked polyethers in which the linking group R^b, oxyalkylene segments and the terminating radical R^c occupy positions related to the ends of the siloxane chain rather than being connected to a silicon atom in the siloxane chain. Thus, one or more of R substituents¹⁰, R¹¹, R¹² and R¹³which are connected to the two terminal silicon atoms at the end of the siloxane chain can be substituted in place of the R-segment^b-O- (C2H4O) p- (C3H6O) sR^c or R-segment^b-O- (C.2H.₄ABOUT)_p-R^.c. In some cases it may be necessary to provide an R-segment^b-O- (C₂H₄ABOUT)_p8 (CsH6O) SR^c or R-segment^b-O- (C2H4O) p^c at sites that are in the siloxane chain as well as at one or both ends of the siloxane chain.

[0021] Specific examples of suitable copolyols <a href="http://pl.bab.la/slownik/polski-angielski/poli-dimetylosiloksan">polydimethylsiloxane</a> are commercially or experimentally available from various suppliers, including Dow Corning Corporation, Midland, Mich .; General Electric Company, Waterford, NY; Witco Corp., Greenwich, Conn .; and Goldschmidt Chemical Corporation, Hopewell, Va. Examples of specific products are DOW CORNING 5225C from Dow Corning, which is 10% copolyol<a href="http://pl.bab.la/slownik/polski-angielski/poli-dimetylosiloksan">polydimethylsiloxane</a> in cyclomethicone; DOW CORNING 25185C, which is 45-49% copolyol<a href="http://pl.bab.la/slownik/polski-angielski/poli-dimetylosiloksan">polydimethylsiloxane</a> in cyclomethicone; SILWET L-7622 from Witco; ABIL EM97 from Goldschmidt, which is 85% copolyol<a href="http://pl.bab.la/slownik/polski-angielski/poli-dimetylosiloksan">polydimethylsiloxane</a> in cyclomethicone D5; and various copolyols<a href="http://pl.bab.la/slownik/polski-angielski/poli-dimetylosiloksan">polydimethylsiloxane</a> commercially available or in literature.

[0022] It should also be noted that different concentrations of copolyol can be used in cyclomethicone <a href="http://pl.bab.la/slownik/polski-angielski/poli-dimetylosiloksan">polydimethylsiloxane</a>. While a concentration of 10% in cyclomethicone is often seen commercially, other concentrations can be created by ripping off cyclomethicone or adding additional cyclomethicone. Higher concentration materials such as DOW CORNING 2-5185 can be used in one embodiment.

[0023] In one embodiment, 0.5-5% by weight (in particular 1.0-2.0%) of 10% silicon copolyol, such as copolyol <a href="http://pl.bab.la/slownik/polski-angielski/poli-dimetylosiloksan">polydimethylsiloxane</a> it is possible to use a cyclomethicone mixture in which the amount of added mixture is selected in such a way that the level of silicon copolyol in the composition ranges from 0.05-0.5% (especially 0.1%) (e.g. 1% 10% copolyol <a href="http://pl.bab.la/slownik/polski-angielski/poli-dimetylosiloksan">polydimethylsiloxane</a> in a mixture of cyclomethicone).

[0024] The composition may additionally contain betaine. The betaine of this invention is not a surfactant. Betaine in the IUPAC nomenclature is 1-carboxy-N, N, N-trimethylmethananine internal salt hydroxide, with alternative names, including carboxymethyl trimethyl ammonium betaine or (carboxymethyl) trimethyl ammonium hydroxide internal salt or betaine glycine or glycine betaine or glycine betaine or trimethylglycol. For convenience, the material of formula A (C₅H₁₁WELL₂; mass = 117.08 amu; molecular mass = 117.15; analysis as C: 51.26; H: 9.46; N: 11.96; A: 27.32) will be referred to as Betaine here.

© θ \ ch₃ \ _Γ I® / '

H3C-Ν-CH₂

CH_and

<img file="PL2114532T3_D0001.tif" />

[0025] The hydrochloride form is also within the scope of the present invention. The hydrochloride form may be represented by Formula Aa, which will be referred to as Betaine Hydrochloride:

<img file="PL2114532T3_D0002.tif" />

[0026] The use of Betaine will refer to Betaine of Formula A or Betaine Hydrochloride of Formula Aa. For more information on betaine, see U.S. Patent No. 6,969, 510.

[0027] Betaine may be included in the composition in any amount. In one embodiment, the combined amount of vegetable oil and / or wax with betaine is about 10% or less by weight of the composition. In another embodiment, the total amount is about 4 to about 8% by weight. In another embodiment, the weight ratio of betaine relative to vegetable oil and / or wax is 3: 1 to 1: 1.

[0028] The composition may additionally contain ionizable inorganic salts. These ionized salts have the form MaXb, where a = 1 or 2 and b = 1 or 2; M is a member selected from Na⁺¹, Li ⁺¹, K ⁺¹, Mg ⁺², Ca ⁺², Sr ⁺² and Zn ⁺² and X is a member selected from chloride, bromide, iodide, citrate, glycate, lactate, glycinate, glutamate, ascorbate, aspartate, nitrate, phosphate, hydrogen phosphate, dihydrogen phosphate, formate, malonate, maleate, succinate, carbonate, sulfate, sulfate, . In some embodiments, the selected salts have been selected from NaCl and ZnCl2. As will be appreciated by those skilled in the art, while it may be possible under certain conditions to add salt directly to a portion of the mixture during production, it is desirable to add the salt as a mixture or a solution of the salt in a carrier or solvent, especially in water. Of course, different concentrations of salt masterbatch can be made.

[0029] When the composition comprises an antiperspirant active agent, any known antiperspirant active materials can be used in the composition. Antiperspirant active agents include, but are not limited to, aluminum hydrochloride, aluminum chloride, sesqui-aluminum hydrochloride, aluminum-zirconium hydroxychloride, assemblies or addition compounds of the above-mentioned glycol active ingredients, such as propylene glycol (e.g., "Rehydrol" II from Reheis Chemical Co.) and their combinations. Known aluminum zirconium salts in combination with neutral amino acids such as glycine (e.g. Tetrachlorohydrex Gly aluminum zirconium) can also be used. In general, any active ingredient of Category I antiperspirant listed in the Food and Drug Administration's Monograph on Antiperspirant Drug Products can be used for over-the-counter human use (October 10, 1973).

[0030] In other embodiments, the antiperspirant active agent is an aluminum salt and / or a zirconium aluminum salt, such as those described above, which are further stabilized by betaine and calcium salt. More information on betaine and calcium salt stabilizing antiperspirant salts can be found in US Patent Application Publication No. 2006/0204463 to Tang et al.

[0031] In other embodiments, the antiperspirant active ingredient such as those described above is selected to have a low metal relative to chloride. Examples of these antiperspirant active ingredients can be found in US Patent No. 6,375,937 to Chopra et al. and in U.S. Patent Application Publication No. 2004/0109833 Tang et al.

[0032] In other embodiments, the type of salt of interest here, glycine-free tetrasol or aluminum zirconium octanol is used where the aluminum zirconium salt is stabilized by Betaine and has a metal to chloride ratio of 0.9: 1 to 1 , 3: 1 (and in other embodiments about 0.9: 1 to about 1.2: 1 or about 0.9: 1 to about 1.1: 1). For tetra salts, the Al / Zr atomic ratio may be about 3.2: 1 to about 4.1: 1.0 and the Betaine: zirconium molar ratio may be 0.2: 1 to 3.0: 1 (or in other forms 0.4: 1 to about 1.5: 1). Another salt that can be used is Betaine buffered aluminum chloride in which the metal to chloride ratio is 0.9: 1 to 1.3: 1 (and in other embodiments about 0.9: 1 to about

1.2: 1 or about 0.9: 1 to about 1.1: 1). For octasols, the Al / Zr atomic ratio is about 6.2: 1 to about 10.0: 1 and the Betaine: Zr molar ratio is 0.2: 1 to 3.0: 1 (or in other forms about 0.4: 1 to about 1.5: 1). In one embodiment, in the case of a salt that contains zirconium, Betaine is included during the synthesis of the salt so as to maximize the stabilizing effect that this ingredient has (especially from the zirconium species). Alternatively, it can be added at a later time to the glycine-free salt along with additional active phase ingredients to form an active compound stabilized with Betaine.

[0033] Examples of commercially available glycine-free tetra- and octa-salts with low M: Cl ratio include, but are not limited to, REZAL ™ AZP 955 CPG and REZAL ™ AZP 885 respectively (both from Reheis Chemical Company, Berkeley Heights , NJ). A more detailed description of the formation of such commercially available salts can be found, for example, in US Patent Nos. 7,074,394 and 6,960,338. Further examples of the formation of such salt complexes are described in US Patent Application Publication No. 2004/0198998 and US Patent No. 7 105 691.

[0034] In addition to the anti-irritant properties of Betaine, it has also been found that antiperspirant solutions retain their fragrance stability against aging when the Al / Zr salt is used in combination with Betaine.

[0035] Additionally, the active ingredient of the antiperspirant may be the active ingredient of the antiperspirant stabilized by the calcium salt. Examples of active ingredients of the calcium salt stabilized antiperspirant can be found in US Patent Application Publication No. 2006/0204463.

[0036] In addition, any new ingredient not mentioned in the monograph, such as aluminum nitrate hydrate and its combination with zirconyl hydroxychlorides and nitrates, or aluminum tin hydrochloride may be included as an antiperspirant active. Antiperspirant active compounds may include, but are not limited to: astringent aluminum salt, astringent zirconium salt, aluminum bromohydrate, aluminum hydrochloride, aluminum dihydrochloride, sesqui-aluminum hydrochloride, chlorohydrex PG aluminum, dichlorohydrex PG aluminum, sesqui- chlorohydrex PG aluminum, chlorohydrex PEG aluminum, dichlorohydrex PEG aluminum, sesquichlor aluminum , aluminum sulfate, aluminum zirconium hydrochloride, aluminum zirconium trihydrochloride, aluminum zirconium tetrachloride, aluminum zirconium pentachloride, aluminum zirconium octachahydride, propylene glycol tetrachlorhydrex aluminum zirconium, trichlorohydrex Gly aluminum zirconium, tetrachlorohydrex Gly aluminum zirconia, pentachlorohydrex Gly aluminum zirconium, acetohlorohydrex Gly aluminum zirconia, buffered aluminum sulfate, aluminum chlorate In one embodiment, the active ingredient of the antiperspirant is a hydrochloride salt. In another embodiment, the active ingredient of the antiperspirant is propylene glycol tetrachlorhydrex aluminum zirconium [0037] When the composition comprises a deodorant active ingredient, any known deodorant active ingredient can be used. Examples of deodorant active ingredients include, but are not limited to, antibacterial active ingredients, alcohols,

2,4,4'-trichloro-2'-hydroxy phenyl ether (Triclosan), octoxyglycerin (SENSIVA ™ SC 50), benzethonium chloride, polyhexamethylene biguanides, triethylcitrate, 2 amino-2-methyl-1-propanol (AMP), cetyltrimethylammonium bromide , cetylpyridinium chloride, bactericides and bacteriostatic agents.

[0038] The composition may also contain solid particles, which include, but are not limited to, talc, mica, fragrance capsules, or hydrophobically modified starches, such as aluminum octenyl succinate starch (MACKADERM ™ ASTRODRY ™ from McIntyre Group Ltd.). If the composition is in a liquid form and is dispensed by a ball applicator, the medium sized suspension particles are of such a size that it can pass through the applicator so as to prevent damage to the applicator. Typically, the average particle size does not exceed 150 microns.

[0039] In some embodiments, the composition as an optional ingredient may also contain at least one unsaturated alpha ester, an anti-odor beta, or a mixture of such materials. In some embodiments, the level of anti-odor composition intended to provide appreciable odor control benefits provided from the antiperspirant and / or deodorant composition is about 0.05 to about 0.45% by weight based on the total composition. Materials for the unsaturated alpha and beta esters to counteract the unpleasant odor are included in the oil phase of the antiperspirant composition. Examples of those elements that counteract the unpleasant odor can be found in US Patent Nos. 6,611,064 and 6,495,097. For example, in this invention, a mixture of alpha unsaturated esters, beta neutralizing odor, shows unexpected stability in an antiperspirant composition containing glycine-free salts with a low metal: chloride ratio (M:

Cl). Examples of the unsaturated alpha, beta ester can be found in WO2005 / 025523, which was filed in the United States as U.S. Application No. 10/571 488. [0040] Examples of the unsaturated alpha ester beta include, but are not limited to:

(1) alkyl esters of 3-phenyl-2-propenoic acid in which R¹ is a substituent on the benzene ring and which is selected from alkyl, alkoxy, aryl or substituted aryl. In some embodiments, R¹ is selected from H, C1 to C8alkyl, C1 to C8alkoxy, or aryl; and R² is a self-substituting hydrogen carboxylic acid group to form an ester, where R² has more than 6 carbon atoms, aryl or substituted aryl, in some forms of R² is C6 to C12alkyl or is a benzyl group; and (2) a fumaric or maleic acid ester having linear carbon chains of an ester with 3-9 carbon atoms, for example dihexyl fumarate;

(3) e-phenylpropenoic acid ester selected from octyl methoxycinnamate, phenylethyl cinnamate, benzyl cinnamate; and (4) an aliphatic unsaturated ester such as dihexyl fumarate.

[0041] The composition may contain emollients in any amount to achieve the desired softening effect. In one embodiment, the amount of emollients is up to about 6% by weight of the composition. In another embodiment, the amount is up to about 2%. Emollients are known in the art and are used to provide a soothing effect on the skin. Non-volatile emollients are more preferred in the present invention. Classes of non-volatile emollients include non-silicon and silicon emollients. Non-volatile, non-silicon emollients include C12-15 alkyl benzoate. The non-volatile silicon material may be a copolymer of polyether siloxane, polyalkarylsiloxane or polyether siloxane. An exemplary non-volatile silicon material in the present invention is phenyl trimethicone. Non-limiting examples of emollients can be found in US Patent No. 6 007 799. Examples include, but are not limited to, PPG-14 butyl ether, PPG-15 stearyl ether, PPG-3 myristyl ether, stearyl alcohol, stearic acid, glyceryl monorycinolate, isobutyl palmitate, glycerol monostearate, isocetyl stearate, sulfate wax, glycol oleyl alcohol propylene, isopropyl laurate, mink oil, sorbitan stearate, cetyl alcohol, hardened castor oil, stearyl stearate, hardened soy glycerides, isopropyl isostearate, hexyl laurate, dimethyl brasidate, decyl oleate, diisopropyl adipate, n14 dibutyl sebacate, diisopropyl sebacate, 2-ethylhexyl palmitate, isononyl isonononate, isodecyl isonononate, isotridecyl isononate, 2-ethylhexylate, 2-ethylhexylate Di- (2-ethylhexyl) succinate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, octacosanol, butyl stearate, glycerol monostearate, polyethylene glycols, oleic acid, triethylene glycol, lanolin, castor oil, acetylated lanolin alcohols, acetylated lanolin, petrolatum, lanolin isopropyl ester, fatty acids, mineral oils, butyl myristate, isostearic acid, palmitic acid, PEG-23 oleyl ether, isopropyl oleate , cetyl lactate, lauryl lactate, myristyl lactate, quaternized hydroxy alkyl, amine gluconate, vegetable oils, isodecyl oleate, isostearyl neopentanoate, myristyl myristate, ethoxy oleyl myristate, diglycol stearate, ethylene glycol monostearate, myristyl stearate, isopropyl lanolate, paraffin waxes, licorice acid, hydrocotyl stearate. In one embodiment, [0042] In one embodiment, the emollient is selected from linear silicones, cyclic silicones, hydrocarbons, polyhydroxy alcohols having more than 3 carbon atoms, liquid or solid polyalkylene glycol ethers containing a propylene glycol (PPG) particle and terminating in an alkyl , ether and their combinations. In another embodiment, the emollient is volatile silicon with a flash point of 100 ° C or less, such as cyclomethicone or trisiloxane. In another embodiment, the emollient is a non-volatile silicon, such as dimethiconol or longer chain dimethicone.

[0043] By volatile silicon material is meant a material that has measurable vapor pressure at ambient temperature. For parts of volatile silicon, examples of volatile silicones (especially silicas with a flash point of 100 ° C or less at atmospheric pressure) include cyclomethicone (especially cyclopentasiloxane, also called "D5"), "hexamethyldisiloxane" and low viscosity dimethicone (for example, Dow Coming liquid 200 with a viscosity of 0.5-5 centistokes). Such volatile silicon include conventional volatile cyclic and linear silicon. Illustratively, but in no way limiting, volatile silicones are one or more members selected from cyclic polydimethylsiloxanes, such as those represented by Formula III:

<img file="PL2114532T3_D0003.tif" />

where n is an integer of 3-7, especially 5-6. For example, DC245 (or DC-345 version) from Dow Coming Corporation (Midland, Mich.) Is a type of cyclomethicone that can be used. These include tetramer (or octylmethylcyclotetrasiloxane) and pentamer (or decamethylcyclopentasiloxane). Volatile linear silicones may also be included in this group of volatile silicones and they are one or more members selected from linear polydimethylsiloxanes such as those of formula IV:

<img file="PL2114532T3_D0004.tif" />

which have a viscosity of 0.5-5 cSt.

[0044] Examples of such volatile silicones include one or more members selected from cyclomethicones D4, D5 and D6; and linear dimethicones with viscosities in the range of 0.5-5 cSt.

[0045] The composition may contain additional materials that are included in the antiperspirant and / or deodorant compositions. Examples include, but are not limited to, monohydric alcohols, fragrances, and preservatives. [0046] When water is present, for example in a liquid roll on composition, the amount of water in the composition is such that it represents 100% by weight of the composition when all materials are added to the composition, including any optional materials. In some embodiments, the amount of water is at least about 20%, 30%, 40%, 50%, 60%, 70%, 80% or 85% by weight of the composition.

[0047] The total dry mass of the composition is the amount of non-volatile materials in this composition. The dry matter percentage is measured by the CEM Smart System moisture / dry mass analyzer, which uses the microwave energy to dry the samples. In one embodiment, the amount of dry matter is less than 25%. In another embodiment, the amount of dry matter is less than 20%.

[0048] The invention is further described in the following examples. The examples are illustrative only and in no way limit the scope of the invention as described and included in the claims.

[0049] Roll on liquid compositions can be prepared using the formulas and procedures given below.

[0050] Execution procedure

1. Water phase: Mix DI water and surfactants:

a. Heat Part 1 water to 84-85 ° C.

b. Melt and add the water phase surfactant (i.e. Steareth 20) to the heated water. Mix until all solids have dissolved.

c. Maintain a temperature of 80-84 C.

2. Oil phase: Mix emollients and surfactant.

a. Weigh PPG 15.

b. Melt the oil phase surfactants (ie Steareth 2), add to PPG-15.

c. Add emollients and unalloyed oils of plant origin.

d. Add BHT

e. Heat to 50 ° C, mixing all ingredients.

f. Continue mixing, bring to 64-66 ° C.

3. Using a ** Rustin disc, add the Oil phase to the Water phase under high shear mixing (360 rpm). Addition factor: about 20 g / min. Stop heating. Reduce the mixing speed to 320 rpm.

4. When the temperature drops to 68-70 ° C, add EDTA solution, continue stirring at 320 rpm.

5. Active phase added

a. Increase mixing speed to 350 rpm and slowly add part 2 of water - (cold).

b. Add the active ingredient antiperspirant, continue mixing at 350 rpm.

c. Let the temperature drop to 44-46 ° C.

d. Slow down the mixing speed to 320 rpm. Add solution

Quaternium 15.

e. When the temperature is 35 ° C or less, slowly add the fragrance with a dropper, continue mixing at 320 rpm.

f. Continue mixing for an additional 10-15 minutes after completing the fragrance.

[0051] Alternatively, the homogenization step may be included between step 3 and

4. Using a Silverson homogenizer, homogenize for 5 minutes after completing the oil phase addition.

[0052] Alternatively, the antiperspirant active compound solution can also be added together with the water and water phase surfactants, [0053] Viscosity is measured in mPas (centipoise) using a Brookfield viscometer at 23 ° C with spindle 4 and RPM set to 20 .

[0054] All amounts shown in the examples below are weight% based on the active mass of the material except surfactants that are based as provided. The amount of tetrasodium EDTA tetrahydrate includes the weight of the hydrate. EDTA is 80%, so the active weight is 0.2% by weight.

<td>'ΖΊ cn</td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>ο</td><td>ο</td><td>* Γ Ί</td><td>ο</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>cn</td><td>ο</td><td></td><td> 6,91</td><td> 2170 |</td>

<td>cn</td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 0,75</td><td> 2,3</td><td>ο</td><td>ο</td><td>ο</td><td>ο γΊ</td><td> 0,0</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>ο</td><td></td><td> 5,10</td><td> 2000 |</td>

<td>cn</td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>ο</td><td>ο</td><td>ο</td><td> 0,0</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>WHAT</td><td>ο</td><td></td><td> 4,91</td><td></td>

<td>cn cn</td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>ο</td><td>ο</td><td>* Γ Ί</td><td>ο</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>ο</td><td></td><td> 6,91</td><td> 2170 |</td>

<td>cn</td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>ο</td><td>ο</td><td>Ο</td><td>* Γ Ί</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>ο</td><td></td><td> 6,91</td><td>1510 I</td>

<td>Ο cn</td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>ο</td><td>ο</td><td>ο</td><td>&gt; Ο)</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>ο</td><td></td><td>&gt; ΖΊ WHAT</td><td>Ο What 00</td>

<td>CR</td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>ο</td><td>'Οι</td><td>ο</td><td>Ο</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>ο</td><td></td><td> 8,41</td><td> 1710 |</td>

<td> 00</td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>ο</td><td>ο</td><td>ο γΊ</td><td> 0,0</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>&gt; Ο) θ '</td><td></td><td> 5,91</td><td> 2400 |</td>

<td>ι&gt;</td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>ο</td><td>ο</td><td>ο</td><td> 0,0</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>ο</td><td></td><td> 4,91</td><td> 2150 |</td>

<td></td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>ο</td><td>ο</td><td> 0,75</td><td> 0,0</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>ο</td><td></td><td> 5,66</td><td>Ο ο 00</td>

<td>'ΖΊ</td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>ο</td><td>ο</td><td> 0,0</td><td>&gt; Ο)</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>ο</td><td></td><td> 8,41</td><td>ο 00</td>

<td></td><td>ζΖ! σ</td><td></td><td>ο</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>ο</td><td>ο</td><td> 0,0</td><td>Ο</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>ο</td><td>θ '</td><td> 3,91</td><td> 200 1</td>

<td>* Γ Ί</td><td>ζΖ! σ</td><td></td><td>ο</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>ο</td><td>ο</td><td> 3,0</td><td>Ο</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>ο</td><td>θ '</td><td> 6,91</td><td> 2500 |</td>

<td>cn</td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>ο</td><td>ο</td><td>'Οι</td><td> 0,0</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>ο</td><td></td><td> 8,41</td><td> 2430 |</td>

<td> -</td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>ο</td><td>'Οι</td><td>ο θ '</td><td>&gt; Ο)</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>ο</td><td></td><td> 6,91</td><td> 1670 |</td>

<td>ο</td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>'Οι</td><td>ο</td><td>ο θ '</td><td>&gt; Ο)</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>ο</td><td></td><td> 6,91</td><td> 1720 |</td>

<td>CR</td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td> 0,75</td><td>ο</td><td> 0,0</td><td>Ο</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>ο</td><td></td><td> 5,66</td><td> 1700 |</td>

<td>WHAT</td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>ο</td><td>'Οι</td><td> 0,0</td><td>Ο</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>ο</td><td></td><td> 6,41</td><td>Ο ο</td>

<td>ι&gt;</td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>ο</td><td>'Οι</td><td>&gt; Ο)</td><td> 0,0</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>ο</td><td></td><td> 6,91</td><td>ο &gt; ΖΊ &gt; ΖΊ</td>

<td></td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td></td><td>ο</td><td>Ο</td><td> 0,0</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>ο</td><td></td><td> 5,91</td><td>1510 I</td>

<td>&gt; ΖΊ</td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>ο</td><td>ο</td><td>ο γΊ</td><td>ο</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>ο</td><td></td><td> 5,91</td><td> 2115 |</td>

<td></td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>ο</td><td>ο</td><td> 0,0</td><td>ο γΊ</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>ο</td><td></td><td> 5,91</td><td> 1530 |</td>

<td>* Γ Ί</td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>ο</td><td>ο</td><td>ο γΊ</td><td> 0,0</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td></td><td></td><td> 5,91</td><td> 2340 |</td>

<td>cn</td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td>ο</td><td>ο</td><td>ο</td><td> 0,0</td><td>ο γΊ</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td></td><td></td><td> 5,91</td><td> 2120 |</td>

<td></td><td>ζΖ! σ</td><td> 0,6</td><td> 0,6</td><td> 1,56</td><td> 2,3</td><td></td><td>ο</td><td>ο</td><td>ο γΊ</td><td>ο</td><td> 0,25</td><td> 0,05</td><td>θ '</td><td>γΊ</td><td>ο</td><td></td><td> 6,91</td><td> 2670 |</td>

<td></td><td>Water</td><td>Steareth 20</td><td>Steareth 21</td><td>PPG-15 stearyl ether</td><td>Steareth-2</td><td>palmitate isopropyl</td><td>VARIONIC^TMAPM-PPG 3alkohol myristyl</td><td>Cyclopentasiloxane (DC245 - Dow Corning)</td><td>Partially hardened S500 oil (Cargill)</td><td>Unhardened Soy S100 (Cargill)</td><td>sodium EDTA tetrahydrate</td><td>Di-tert butyl cresol pair</td><td>Quaternium-15</td><td>Aluminum chloride hydrate, Anhydrous (LOCRON^TM, Clariant)</td><td>carbowax^TMglycol polyethylene 400NF</td><td>-C CŚ &amp; Ν</td><td>% OIL PHASE *</td><td>| Viscosity mPas |</td>

*% of the oil phase is the sum of PPG-15 stearyl ether, Steareth-2, di-tert butyl para cresol, cyclopentasiloxane and soybean oil.

[0055] In Examples 1-25 above, compositions that contained vegetable oil had a higher level of viscosity (structure increase) compared to compositions that did not have oil.

[0056] Additional examples are provided in the table below. You can do them using the methods described above.

<td></td><td> 26</td><td> 27</td><td> 28</td><td> 29</td><td> 30</td><td> 31</td><td> 32</td><td> 33</td><td> 34</td>

<td>Steareth-20</td><td> 0,6</td><td> 0,6</td><td> 0,6</td><td> 0,6</td><td> 0,6</td><td> 0,6</td><td> 0,6</td><td> 0,6</td><td> 0,6</td>

<td>Steareth-21</td><td> 0,6</td><td> 0,6</td><td> 0,6</td><td> 0,6</td><td> 0,6</td><td> 0,6</td><td> 0,6</td><td> 0,6</td><td> 0,6</td>

<td>Steareth-2</td><td> 2,3</td><td> 2,3</td><td> 2,3</td><td> 2,3</td><td> 2,3</td><td> 2,3</td><td> 2,3</td><td> 2,3</td><td> 2,3</td>

<td>PPG-15 stearyl ether</td><td> 1,56</td><td> 1,56</td><td> 1,6</td><td> 1,6</td><td> 1,56</td><td> 1,56</td><td> 1,56</td><td> 1,56</td><td> 1,0</td>

<td>Cyclopentasiloxane (DC245 with Dow Corning)</td><td> 0</td><td> 0</td><td> 1,5</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td>

<td>myristyl ether PPG-3</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0,6</td>

<td>Aluminum starch octenyl succinate (ASTODRY ™ McIntyre)</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 1,5</td><td> 1,0</td><td> 0</td><td></td>

<td>Jojoba oil</td><td> 0</td><td> 0</td><td> 3,5</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td>

<td>Soybean oil S700 (Cargill)</td><td> 3</td><td> 1,5</td><td> 0</td><td> 3,0</td><td> 1,5</td><td> 0</td><td> 0</td><td> 0</td><td> 1,5</td>

<td>Soybean oil S500 (Cargill)</td><td> 0</td><td> 0</td><td> 0</td><td> 0,0</td><td> 0</td><td> 1,0</td><td> 1,0</td><td> 3,0</td><td> 0,0</td>

<td>Hardened polyisobuten FANCOL ™ Polyiso-200</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 1,5</td>

<td>Isododecane (Permetyl 99A)</td><td> 1,5</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td>

<td>Diisopropyl Adipate (Ceraphyl 230)</td><td> 0</td><td> 1,5</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td>

<td>Neopentyl glycol diheptonoate and LEXFEEL ™ D5 isododecane</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 1,5</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td>

<td>aluminum chlorohydrate (anhydrous) (Locron, Clariant)</td><td> 12</td><td> 12</td><td> 12,5</td><td> 12,5</td><td> 12,5</td><td> 12,0</td><td> 12,0</td><td> 12,0</td><td> 12,5</td>

<td>Water</td><td>QS</td><td>QS</td><td>QS</td><td>QS</td><td>QS</td><td>QS</td><td>QS</td><td>QS</td><td>QS</td>

<td>di-tert butyl para-cresol</td><td> 0,05</td><td> 0,05</td><td> 0,05</td><td> 0,05</td><td> 0,05</td><td> 0,05</td><td> 0,05</td><td> 0,05</td><td> 0,05</td>

<td>tetrasodium EDTA tetrahydrate</td><td> 0,25</td><td> 0,25</td><td> 0,25</td><td> 0,25</td><td> 0,25</td><td> 0,25</td><td> 0,25</td><td> 0,25</td><td> 0,25</td>

<td>Quaternium 15</td><td> 0,1</td><td> 0,1</td><td> 0,1</td><td> 0,1</td><td> 0,1</td><td> 0,1</td><td> 0,1</td><td> 0,1</td><td> 0,1</td>

<td>Smell</td><td> 1</td><td> 1</td><td> 1</td><td> 1</td><td> 1</td><td> 1</td><td> 1</td><td> 1,3</td><td> 1</td>

<td>Ester mixture unsaturated alpha, beta neutralizing odor</td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td> 0,2</td><td></td>

<td>Viscosity</td><td> 1240</td><td> 990</td><td> 1180</td><td> 1510</td><td> 960</td><td> 1710</td><td> 1680</td><td> 2500</td><td> 1140</td>

[0057] The examples in the table below include betaine. They can be made using the methods described above.

<td></td><td> 35</td><td> 36</td><td> 37</td><td> 38</td><td> 39</td><td> 40</td><td> 41</td>

<td>Steareth-20</td><td> 0,6</td><td> 0,6</td><td> 0,6</td><td> 0,6</td><td> 0,6</td><td> 1,2</td><td> 0,6</td>

<td>Steareth-21</td><td> 0,6</td><td> 0,6</td><td> 0,6</td><td> 0,6</td><td> 0,6</td><td> 0,0</td><td> 0,6</td>

<td>Steareth-2</td><td> 2,3</td><td> 2,3</td><td> 2,3</td><td> 2,3</td><td> 2,3</td><td> 2,3</td><td> 2,3</td>

<td>PPG-15 stearyl ether</td><td> 1,56</td><td> 1,56</td><td> 1,56</td><td> 1,56</td><td> 1,56</td><td> 1,56</td><td> 1,56</td>

<td>Cyclopentasiloxane (DC245 with Dow Corning)</td><td> 0</td><td> 0</td><td> 1,5</td><td> 1,5</td><td> 0</td><td> 0</td><td> 1,5</td>

<td>Jojoba oil</td><td> 0</td><td> 0</td><td> 1,5</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td>

<td>S100 Soybean Oil (Cargill)</td><td> 3,0</td><td> 1,0</td><td> 0</td><td> 1</td><td> 0</td><td> 0</td><td> 1</td>

<td>S500 Soybean Oil (Cargill)</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 1,0</td><td> 1,0</td><td> 0</td>

<td>FANCOL hydrogenated polyisobuten^TM Polyiso-200</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 1,5</td>

<td>zirconium aluminum tetrachlorohydrate (anhydrous) (Z498-Summit)</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 12,0</td><td> 0</td><td> 0</td>

<td>aluminum chlorohydrate (anhydrous) (LOCRON^tm from Clariant)</td><td> 12,5</td><td> 12,5</td><td> 12,5</td><td> 12,5</td><td> 0</td><td> 12,0</td><td> 12,5</td>

<td>Water</td><td>QS</td><td>QS</td><td>QS</td><td>QS</td><td>QS</td><td>QS</td><td>QS</td>

<td>di-tert butyl-vapor-cresol</td><td> 0,05</td><td> 0,05</td><td> 0,05</td><td> 0,05</td><td> 0,05</td><td> 0,05</td><td> 0,05</td>

<td>tetrasodium EDTA tetrahydrate</td><td> 0,25</td><td> 0,25</td><td> 0,25</td><td> 0,25</td><td> 0,25</td><td> 0,25</td><td> 0,25</td>

<td>Quaternium 15</td><td> 0,1</td><td> 0,1</td><td> 0,1</td><td> 0,1</td><td> 0,1</td><td> 0,1</td><td> 0,1</td>

<td>Smell</td><td> 1</td><td> 1</td><td> 1</td><td> 1</td><td> 1</td><td> 1,0</td><td> 1</td>

<td>Trimethyl glycine - betaine</td><td> 3</td><td> 3</td><td> 3</td><td> 3</td><td> 0</td><td> 0,0</td><td> 3</td>

<td>CaCl₂ (anhydrous)</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 0</td><td> 1,0</td><td> 0</td>

<td>Viscosity</td><td> 1780</td><td> 2100</td><td> 3160</td><td> 1990</td><td> 2200</td><td> 1810</td><td> 1560</td>

[0058] The following formula is an example of water in an oil gel composition that can be made using the following procedure. The sample sizes are about 500 grams. Silicon copolyol (PEG / PPG-18/18<a href="http://pl.bab.la/slownik/polski-angielski/poli-dimetylosiloksan">polydimethylsiloxane)</a>, silicon, soybean oil and aroma are weighed and combined in a beaker. The mixture is mixed at 400-600 rpm with Lightnin Mixer Model LI003. After the mixture becomes visually homogeneous, the active phase containing the antiperspirant active ingredient in water and the rest of the ingredients (tripropylene glycol, ethanol and additional water) are added to the oil phase during mixing. The whole mixture is stirred for 15 minutes. The mixture is then homogenized for 13 minutes with a 40-60 reading on a Powerstat Variable

Tansformer (Superior Electric Co, Bristol, CT) using a homogenizer from

Greerco Corp (Hudson, NH). A Brookfield viscometer with an E spindle and at room temperature (about 23 ° C) was used to determine the viscosity of this water in the oil formula. Please note that the spindle speed E is 2.5 rpm.

<td>Material</td><td>Quantity</td>

<td>Cyklometikon (DC345 from Dow Corning)</td><td> 6</td>

<td>Phenyltrimethicone (DC556 from Dow Corning)</td><td> 1</td>

<td>Dimethicon (DC200 from Dow Corning)</td><td> 2</td>

<td>PEG / PPG-18/18 dimethicone in cyclopentasiloxane (DC5225C from Dow Corning - 10% active)</td><td> 9</td>

<td>Soybean oil S-500 (Cargill)</td><td> 1</td>

<td>Propylene glycol tetrachlorohydrex of zirconium aluminum (Reheis 36 GPC) (active base)</td><td> 16</td>

<td>Tri propylene glycol</td><td> 3,3</td>

<td>SD Alcohol 40</td><td> 8</td>

<td>Smell</td><td> 0,7-1</td>

<td>Water</td><td>QS</td>