Synergistic insecticide mixtures

The present invention relates to novel compositions of active compounds which, as active ingredients, contain in each case two compounds from the group of chloronicotinyl insecticides and have very good insecticidal properties.

[0002] It is known that chloronicotinyl insecticides can be used to control animal pests, especially insects. Chloronicotinyl Insecticides include the following compounds:

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thiamethoxam of formula (IV)

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(EP 0 580 553)

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(WO 91/04965)

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[0003] Although the efficacy of these compounds is good, it leaves somewhat to be desired in some cases when the compounds are used at low application rates or against specific pests.

[0004] JP2003063911 A2 describes a composition of acetamiprid, imidacloprid and silafluofen for controlling termites.

[0005] It has now been found that mixtures containing in each case at least two, in particular exactly two compounds from the group of chloronicotinyl insecticides, and especially those of formulas (I) to (VII), act synergistically and are suitable for combating animal pests. in agriculture.

[0006] Due to this synergy, much lower amounts of the active substance can be used, i.e. the effectiveness of the mixture is greater than the effectiveness of its individual components.

[0007] The ratio of the amount of both active substances used and the total amount of the mixture used depends on the species and the presence of insects or mites and can vary over a wide range. Optimal ratios and total application rates can be determined for each application in a series of tests.

[0008] The following suitable mixtures can be specifically mentioned:

Table

<td>Mixture No.</td><td>First substance The active</td><td>Second substance The active</td><td>Beneficial ratio mixing</td><td>A particularly advantageous mixing ratio</td>

<td>1</td><td>imidacloprid</td><td>clothianidin</td><td>100: 1 - 1: 100</td><td>10: 1 - 1: 10</td>

<td>2</td><td>imidacloprid</td><td>dinotefuran</td><td>II</td><td>II</td>

<td>3</td><td>imidacloprid</td><td>thiamethoxam</td><td>II</td><td>II</td>

<td>4</td><td>imidacloprid</td><td>thiacloprid</td><td>II</td><td>II</td>

<td>5</td><td>imidacloprid</td><td>acetamiprid</td><td>II</td><td>II</td>

<td>6</td><td>imidacloprid</td><td>nitenpyram</td><td>II</td><td>II</td>

<td>7</td><td>clothianidin</td><td>dinotefuran</td><td>II</td><td>II</td>

<td>8</td><td>clothianidin</td><td>thiamethoxam</td><td>II</td><td>II</td>

<td>9</td><td>clothianidin</td><td>thiacloprid</td><td>II</td><td>II</td>

<td>10</td><td>clothianidin</td><td>acetamiprid</td><td>II</td><td>II</td>

<td>11</td><td>clothianidin</td><td>nitenpyram</td><td>II</td><td>II</td>

<td>12</td><td>dinotefuran</td><td>thiamethoxam</td><td>II</td><td>II</td>

<td>13</td><td>dinotefuran</td><td>thiacloprid</td><td>II</td><td>II</td>

<td>14</td><td>dinotefuran</td><td>acetamiprid</td><td>II</td><td>II</td>

<td>15</td><td>dinotefuran</td><td>nitenpyram</td><td>II</td><td>II</td>

<td>16</td><td>thiamethoxam</td><td>thiacloprid</td><td>II</td><td>II</td>

<td>17</td><td>thiamethoxam</td><td>acetamiprid</td><td>II</td><td>II</td>

<td>18</td><td>thiamethoxam</td><td>nitenpyram</td><td>II</td><td>II</td>

<td>19</td><td>thiacloprid</td><td>acetamiprid</td><td>II</td><td>II</td>

<td>20</td><td>thiacloprid</td><td>nitenpyram</td><td>II</td><td>II</td>

<td>21</td><td>acetamiprid</td><td>nitenpyram</td><td>II</td><td>II</td>

[0009] The active compound compositions are well tolerated by plants, exhibit favorable toxicity to warm-blooded animals and are suitable for combating animal pests, in particular insects, spider moths and nematodes that occur in agriculture. Preferably they can be used as plant protection agents. They are effective against normally sensitive and resistant species and against all or specific developmental stages. The said pests include:

[0010] From Isopoda, e.g. Oniscus asellus, Armadillidium vulgare, Porcellio scaber.

[0011] From Diplopoda, e.g. Blaniulus guttulatus.

[0012] From the order Chilopoda, e.g. Geophilus carpophagus, Scutigera spp.

[0013] From Symphyla, e.g. Scutigerella immaculata.

[0014] From the order Thysanura, e.g. Lepisma saccharina.

[0015] From the Collembola order, e.g. Onychiurus armatus.

[0016] From the order Orthoptera, e.g. Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria.

[0017] From the order Blattaria, e.g. Blatta orientalis, Periplaneta americana, Leucophaea maderae, Blattella germanica.

[0018] From the order Dermaptera, e.g. Forficula auricularia.

[0019] From the order Isoptera, e.g. Reticulitermes spp.

[0020] From the order Phthiraptera, e.g. Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp.

[0021] From the order Thysanoptera, e.g. Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella occidentalis.

[0022] From the order Heteroptera, e.g. Eurygaster spp., Dysdercus intermedius, Quadrata ham, Cimex lectularius, Rhodnius prolixus, Triatoma spp.

[0023] From the order Homoptera, e.g. Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis, Phylloxera vastatrix, Pemphigus spp., Maorosiphum avenae, Myzus spp., Phorodon humuli, Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp., Psylla spp. [0024] From the order Lepidoptera , e.g. Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Bucculatrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxoa spp., Feltia spp.,Earias insulana, Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Tinea pellionella, Hofmannophila pseudospretella, Cacoecia given, Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Homon magnanima, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae.Oulema oryzae.Oulema oryzae.

[0025] From the order Coleoptera, e.g. Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa ​​decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachna varivestis, Atomaria spp., Oryzaephilus surinamensis, Anthonomus spp., Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp.,

Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica, Lissorhoptrus oryzophilus.

[0026] From the order Hymenoptera, e.g. Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.

[0027] From the order Diptera, e.g. Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp. , Hyppobosca spp., Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Tipula paludosa, Hylemyia spp. , Liriomyza spp. [0028] From the order Siphonaptera, e.g. Xenopsylla cheopis, Ceratophyllus spp.

[0029] From the Arachnida class, e.g. Scorpio maurus, Latrodectus mactans, Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp., Hyalomma spp. , Ixodes spp., Psoroptes spp., Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp.

Plant parasitic nematodes include, e.g., Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp. ., Bursaphelenchus spp.

[0031] According to the invention, all plants and parts of plants can be treated. By plants is meant, in the present context, all plants and plant populations, such as desired and undesired wild or utilized plants (including naturally occurring crop plants). Useful plants can be plants that can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods, or by a combination of these methods, including transgenic plants and plant varieties that are possible or impossible to protect by plant breeders. Parts of plants may mean all aerial and underground parts and organs of plants, such as momentum, leaf, flower and root, an example list includes leaves, pins, stems, trunks, flowers, fruit flesh, fruits and seeds, as well as roots, tubers and rhizomes.

lettuce, leaf beet, spinach and salad chicory, cabbage, such as, for example, cauliflower, broccoli, cabbage, Brassica oleracea (L.) convar acephala var. sabellica L. (fodder cabbage), kohlrabi, brussels sprouts, red cabbage, white cabbage and kale, fruit vegetables such as, e.g. aubergines, cucumbers, peppers, pumpkins, tomatoes, courgettes and sweetcorn, root vegetables such as, e.g. celery, maple, carrot, including yellow varieties, Raphanus sativus var. niger and var. radicula, beetroots, snakes and celery, legumes, such as, for example, peas and beans, and vegetables from the Allium family, such as, for example, leeks and onions). lettuce, leaf beet, spinach and salad chicory, cabbage, such as, for example, cauliflower, broccoli, cabbage, Brassica oleracea (L.) convar acephala var. sabellica L. (fodder cabbage), kohlrabi, brussels sprouts, red cabbage, white cabbage and kale, fruit vegetables such as, e.g. aubergines, cucumbers, peppers, pumpkins, tomatoes, courgettes and sweetcorn, root vegetables such as, e.g. celery, maple, carrot, including yellow varieties, Raphanus sativus var. niger and var. radicula, beetroots, snakes and celery, legumes, such as, for example, peas and beans, and vegetables from the Allium family, such as, for example, leeks and onions). red cabbage, white cabbage and kale, fruit vegetables such as, for example, aubergines, cucumbers, peppers, pumpkins, tomatoes, courgettes and sweetcorn, root vegetables, such as, for example, celery, maple, carrots, including yellow varieties , Raphanus sativus var. niger and var. radicula, beetroots, snakes and celery, legumes, such as, for example, peas and beans, and vegetables from the Allium family, such as, for example, leeks and onions). red cabbage, white cabbage and kale, fruit vegetables such as, for example, aubergines, cucumbers, peppers, pumpkins, tomatoes, courgettes and sweetcorn, root vegetables, such as, for example, celery, maple, carrots, including yellow varieties , Raphanus sativus var. niger and var. radicula, beetroots, snakes and celery, legumes, such as, for example, peas and beans, and vegetables from the Allium family, such as, for example, leeks and onions).

According to the invention, the treatment of plants and plant parts with active ingredient compositions is carried out directly or by treating their environment, habitat or during storage by conventional methods of treatment, e.g. by dipping, spraying, evaporating, spraying, spreading, coating, and in addition in the case of a reproductive material, in particular seeds, by treatment with one or more layers.

[0034] The mixtures according to the invention are particularly suitable for seed treatment. Thus, most damage to crop plants that are caused by pests occurs early when seeds are infected during storage and after seed introduction into the soil, and during and immediately after germination of the plants. This phase is particularly important because the roots and shoots of the growing plants are particularly sensitive and even a small damage can lead to the death of the entire plant. The protection of seeds and germinating plants by the use of suitable compositions is therefore particularly interesting.

[0035] The control of pests by subjecting plant seeds to seeds has been known for a long time and is subject to continuous improvement. However, the treatment of seeds is often the source of many problems that can not always be solved in a satisfactory manner. Thus, it is desirable to develop methods for protecting seeds and germinating plants that avoids the additional use of plant protection products after planting or after emergence of the plants. It is furthermore desirable to optimize the amount of active ingredient used in such a way as to obtain optimal protection of the seed and germinating plant from attack by the pest, but without damaging the plant itself by the active substance used. In particular, in the context of treatments for seeds, for optimum protection of seeds and germinating plants with the use of a minimum amount of plant protection products,

[0036] The present invention in particular also relates to a method of protecting seeds and germinating plants from attack by pests, by treating seeds with a composition according to the invention. Furthermore, the invention relates to the use of a composition according to the invention for treating seeds in order to protect the seeds and the germinating plant from pests. The invention furthermore relates to seeds which have been treated with a composition according to the invention for obtaining protection against pests.

One of the advantages of the present invention is that, due to the particular systemic properties of the compositions according to the invention, treating the seeds with these compositions not only protects the seeds, but also the plant upon emergence, from pests. In this way, immediate treatment of crops during or shortly after sowing can be avoided.

[0038] A further advantage is the synergistically enhanced insecticidal efficacy of the compositions of the invention compared to the corresponding single active compound that exceeds the sum of the activities of the two active ingredients used alone. This allows optimization of the amount of active substance used.

[0039] Furthermore, it can be considered advantageous that the mixtures according to the invention can also be used in particular for transgenic seeds, since plants derived from such seeds can express a protein directed against pests. By treating such seeds with the compositions of the invention, certain pests may already be controlled by the expression of e.g. an insecticidal protein, and the synergistic increase in efficacy of the composition of the invention is further surprising, which further enhances the effectiveness of protection against pest attack.

[0040] As mentioned above, the compositions of the invention are suitable for the protection of seeds of any plant variety used in agriculture, in greenhouses, in forestry, in horticulture or in vines. In particular, it refers to the seeds of maize, peanuts, canola, rapeseed, poppy, olives, coconut, cocoa, soy, cotton, beet (eg sugar and fodder), rice, sorghum and millet, wheat, barley, oats, rye , sunflower, sugar cane or tobacco. The compositions of the invention are also suitable for treating the seeds of the aforementioned fruit plants and vegetables. Treatment of seeds of maize, soy, cotton, wheat, canola or rapeseed is particularly important. Thus, e.g. a mixture according to the invention,

[0041] As already mentioned above, the treatment of transgenic seeds with a composition according to the invention is also particularly important. They are plant seeds which, as a rule, contain at least one heterologous gene that governs the expression of the polypeptide, in particular having insecticidal properties. In this context, heterologous genes in transgenic seeds may be derived from microorganisms such as Bacillus, Rhizobium, Pseudomonas, Serratia, Trichoderma, Clavibacter, Glomus or Gliocladium. The invention is particularly useful in the treatment of transgenic seeds that contain at least one heterologous gene derived from Bacillus sp. And whose gene product has activity against the corn borer and / or corn rootworm. This is particularly preferably a heterologous gene from Bacillus thuringiensis.

[0042] The composition of the invention is applied to the seeds alone or in a suitable preparation. Preferably, the seeds are treated in a condition where they are sufficiently stable to avoid damage during surgery. Typically, seeds can be treated at any time between harvest and sowing. Usually, seeds separated from the plant are used, and no cob, scales, stalks, coatings, hairs or fruit flesh are removed.

[0043] In seed treatment, it is usual to pay attention that the amount of the composition according to the invention applied to the seed and / or the amount of other additives is selected so that it does not adversely affect seed germination or that the resulting plant is not damaged. This should be taken into account, in particular, for active substances that may have a phytotoxic effect at certain application rates.

[0044] The compositions of the invention may be used directly, i.e. without additional ingredients and without dilution. As a rule, it is preferred to use the seed compositions in the form of a suitable formulation. Suitable formulations and methods for subjecting seeds to treatments are known to those skilled in the art and described, e.g. in the following documents: US 4272417 A, US 4245432 A, US 4808430 A, US 5876739 A, US 2003/0176428 A1, WO 2002/080675 A1, WO 2002 / 028186 A2.

[0045] The active compound compositions can be converted into conventional formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspoemulsion concentrates, natural and synthetic materials impregnated with the active compounds, and microcapsules in polymeric materials.

These formulations are prepared in a known manner, e.g. by mixing the active ingredients with diluents, i.e. liquid solvents and / or solid carriers, optionally using surfactants, such as emulsifiers and / or dispersants and / or foaming agents.

[0047] When water is used as a diluent, auxiliary solvents that can be used are, for example, organic solvents. The following are mainly suitable as liquid solvents: aromatic substances, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatic substances or chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g. mineral oil fractions, mineral and vegetable oils, alcohols such as butanol or glycol and ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, highly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.

[0048] As solid carriers, they are suitable:

[0049] e.g. ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as highly disperse silica, alumina and silicates; as solid supports for granules are suitable: e.g. crushed and fractionated natural rocks, such as calcite, marble, pumice, sepiolite and dolomite, as well as synthetic granules of inorganic and organic flours, and granules of organic material such as sawdust, coconut shells, corn cobs and tobacco stalks; as emulsifiers and / or foaming agents suitable are: for example, nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, e.g. alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates and protein hydrolysates; suitable dispersing agents are, for example, lignosulphite waste liquors and methylcellulose.

[0050] Adhesive agents may be used in the formulations. such as carboxymethylcellulose and natural and synthetic polymers in the form of powders, granules or latices, such as gum arabic, polyvinyl alcohol and polyvinyl acetate, and natural phospholipids, such as cephalins and lecithins, and synthetic phospholipids. Further additives can be mineral and vegetable oils.

[0051] It is possible to use coloring agents, such as inorganic pigments, e.g. iron oxide, titanium oxide and Prussian blue, and organic dyes such as alizarin dyes, azo dyes and metal phthalocyanine dyes, and trace media such as iron, manganese salts , boron, copper, cobalt, molybdenum and zinc.

[0052] The formulations generally contain 0.1-95% by weight of the active ingredient, preferably 0.5-90%.

[0053] Preferably, the active compound combinations according to the invention do not contain further active substances apart from the two chloronicotinyl insecticides of formulas (I) to (VII).

If appropriate, the active compound compositions according to the invention, in commercially available formulations and in the formulations formed from these formulations, may be present in a mixture with other known active compounds, such as insecticides, attractants, sterilants, bactericides. , acaricides, nematocides, fungicides, growth regulators or herbicides.

[0055] Insecticides include, e.g., phosphoric esters, carbamates, carboxyl esters, chlorinated hydrocarbons, phenylureas, substances produced by microorganisms, and the like.

[0056] Examples of particularly preferred components in mixtures are the following components:

Fungicides:

aldimorf, amprophylphos, potassium, potassium, potassium, andoprim, anilazine, azaconazole, azoxystrobin, benalaxyl, benodanil, benomyl, benzamacryl, isobutyl benzamacryl, bialaphos, binapacryl, biphenyl, bitertanol, blasticidin-S, bromuconazole, bupirimate, butiobate, calcium polysulfide, capsymycin, captafol , captan, carbendazim, carboxin, carvone, quinomethionate, chlobentiazon, chlorofenazol, chloroneb, chloropicrin, chlorothalonil, chlozolinate, chlozylacon, kufraneb, cymoxanil, cyproconazol, cyprodinil, cyprofuram, debakarb, dichlorofen, dichlobutrazole, dichlofluanid, dichlomezyna, dichloran, diethofencarb, difenoconazole , dimethacol, dimethomorph, diniconazole, diniconazole-M, dinocap, diphenylamine, dipyrrolithium, ditalimphos, dithianon, dodemorph, dodine, drazoxolone, edifenphos, epoxiconazole, etaconazole, ethymyol, etridiazole, famoxadone, fenapanil, fenarimol,fenbuconazole, fenfuram, fenitropane, fenpiclonil, fenpropidin, fenpropimorph, fentin acetate, fentin hydroxide, ferbam, ferimon, fluazinam, flumetover, fluoromide, fluquinconazole, fluroprimidol, flusilazole, flusulfamide, flutolanil, flutriafol, folpet, fosetyl aluminum, fosetyl sodium, phthalide, fuberidazole, furalaxyl, furametpyr, furkarbonil, furconazole, furconazole-cis, furmecycloxide, guazatine, hexachlorobenzene, hexaconazole, hymexazol, imazalil, imibenconazole, iminoctadine, iminoctadine alkylbenzenesulfonate, iminoctadine triacetate, iodocarb, ipconazole, iprobenfos (IBP), iprodion, irurnamycin, isopriptiol , izowaledion, kasugamycin, kresoxim-methyl, copper preparations such as: copper hydroxide, copper naphthenate, copper oxychloride, copper sulfate, copper oxide, copper toxin and Bordeaux mix, mankoper, mancozeb, maneb,meferimon, mepanipyrim, mepronil, metalaxyl, metamazole, metasulfocarb, methomam, metomeclamine, metsulfakaks, mildiomycin, myllobutanil, mychlozoline, nickel dimethylldithiocarbamate, nitrotal isopropyl, nuarimol, ofuras, oxadixyl, oxamocarb, oxolinic acid, oxycarboxim, oxyfentin, pachlobutrazol, pefurazoat , penconazole, pencycerone, fosfifen, pimaricine, piperine, polyoxin, polyoxorim, probenazole, prochloraz, procymidone, propamocarb, propanosine sodium, propiconazole, propineb, pyrazophos, pyrifenox, pyrimethanil, pyroquinone, piroxifur, quinconazole, quintocene (PCNB), sulfur and preparations sulfuric acid, tebuconazole, techloftalam, technazen, tetcalacis, tetraconazole, thiabendazole, ticaphen, thifluzamide, thiophanate-methyl, thiuram, thioximide, tolclofos-methyl, tolylfluanid, triadimefon, triadimenol, triazobutyl, triazoxide,trichlamide, tricyclazole, tridemorph, triflumizole, triforine, triticonazole, uniconazole, validamycin A, vinclozoline, viniconazole, zarilamide, zineb, ziram and

Dagger G,

OK-8705,

OK-8801, α- (1,1-dimethylethyl) -3- (2-phenoxyethyl) -1H-1,2,4-triazole o-1-ethanol, α- (2,4-dichlorophenyl) -3-fluoro -3-propyl-1H-1,2,4-tri azole o-1-ethanol, α- (2,4-dichlorophenyl) -3-methoxy-α-methyl-1H-1,2,4-triazole o- 1-ethanol, α- (5-methyl-1,3-dioxan-5-yl) -3 - [[4- (trifluoromethyl) phenyl] methylene] -1H-1,2,4-triazole-1-ethanol, (5RS , 6RS) -6-hydroxy-2,2,7,7-tetramethyl-5- (1H-1,2,4-triazol-1-yl) -3-octanone, (E) -a- (methoxyimino) - N-Methyl-2-phenoxyphenylacetamide, {2-methyl-1 - [[[1- (4-methylphenyl) ethyl] amino] carbonyl] propyl} carbamic acid isopropyl ester

O- (phenylmethyl) oxime H- 4-dicllyl'-enyl) -2- (lI-l, 2,4-tnazol-1-yl) ethanone,

- (2-methyl-1-naphthalenyl) -1H-pyrrole-2,5-dione,

1- (3,5-dichlorophenyl) -3- (2-propenyl) -2,5-pyrrolidinedione,

1 - [(diiodomethyl) sulfonyl] -4-methylbenzene,

1 - [[2- (2,4-dichlorophenyl) -1,3-dioxolan-2-yl] methyl] -1H-imidazole,

1 - [[2- (4-chlorophenyl) -3-fenylooksiranylo] methyl] -1H-1,2,4-triazole,

1- [1- [2 - [(2,4-dichlorophenyl) methoxy] phenyl] ethenyl] -1H-imidazole,

1- methyl-5-nonyl-2- (phenylmethyl) -3-pyrrolidinol,

2 ', 6'-dibromo-2-methyl-4'-trifluoromethoxy-4'-trifluoromethyl-1,3-thiazole-5-carboxanilide, 2,2-dichloro-N- [1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxamide, 2,6-dichloro-5- (methylthio) -4-pyrimidinyl thiocyanate,

2.6- dichloro-N- (4-trifluoromethylbenzyl) benzamide,

2.6- dichloro-N - [[4- (trifluoromethyl) phenyl] methyl] benzamide,

2- (2,3,3-triiodo-2-propenyl) -2H-tetrazole,

2 - [(1-methylethyl) sulphonyl] -5- (trichloromethyl) -1,3,4-thiadiazole,

2 - [[6-deoxy-4-O- (4-O-methyl-3-D-glucopyranosyl) -AD-glucopyranosyl] amino] -4-methoxy-1H-pyrrolo [2,3-d] pyrimidine-5 carbonitrile,

2-aminobutane,

2-bromo-2- (bromomethyl) pentanedinitrile,

2-chloro-N- (2,3-dihydro-1,1,3-trimethyl-1H-inden-4-yl) -3-pyridinecarboxamide,

2-chloro-N- (2,6-dimethylphenyl) -N- (izotiocyjanianometylo) -acetamide,

2- phenylphenol (OPP),

3.4- dichloro-1- [4- (difluoromethoxy) phenyl] -1H-pyrrole-2,5-dione,

3,5-dichloro-N- [cyano [(1-methyl-2-propynyl) oxy] methyl] benzamide,

3- (1,1-dimethylpropyl-1-oxo) -1H-indene-2-carbonitrile,

3- [2- (4-chlorophenyl) -5-ethoxy-3-isoxazolidinyl] pyridine,

4-chloro-2-cyano-N, N-dimethyl-5- (4-methylphenyl) -1H-imidazole-1-sulfonamide,

4-methyl-tetrazolo [1,5-a] quinazolin-5 (4H) -one

8- (1,1-dimethylethyl) -N-ethyl-N-propyl-1,4-dioxaspiro [4,5] decane-2-methanamine, 8-hydroxyquinoline sulphate,

2 - [(phenylamino) carbonyl] hydrazide, 9H-xanthene-9-carbonic acid, bis- (1-methylethyl) -3-methyl-4 - [(3-methylbenzoyl) oxy] 2,5-thiophene, cis-1 dicarboxylate - (4-chlorophenyl) -2- (1H-1,2,4-triazol-1-yl) cycloheptanol, cis-4- [3- [4- (1,1-dimethylpropyl) phenyl-2-methylpropyl] hydrochloride 2,6-dimethylmorpholine, [(4-chlorophenyl) azo] cyanoacetate, potassium bicarbonate, sodium methane tetrathiolate,

1- (2,3-Dihydro-2,2-dimethyl-1H-inden-1-yl) -1H-imidazole-5-carboxylate, N- (2,6-dimethylphenyl) -N- (5-isoxazolylcarbonyl) -DL-methyl alaninate, N- (chloroacetyl) -N- (2,6-dimethylphenyl) -DL-alaninate, N- (2,3-dichloro-4-hydroxyphenyl) -1-methylcyclohexanecarboxamide.

N- (2,6-dimethylphenyl) -2-methoxy-N- (tetrahydro-2-oxo-3-furanyl) acetamide,

N- (2,6-dimethylphenyl) -2-methoxy-N- (tetrahydro-2-oxo-3-thienyl) acetamide,

N- (2-chloro-4-nitrophenyl) -4-methyl-3-nitro-benzenesulfonamide,

N- (4-cyclohexylphenyl) -1,4,5,6-tetrahydro-2-pyrimidineamine,

N- (4hexylphenyl) -1,4,5,6-tetrahydro-2-pyrimidineamine,

N- (5-chloro-2-methylphenyl) -2-methoxy-N- (2-oxo-3-oxazolidinyl) -acetamide,

N- (6-methoxy) -3-pyridinyl) cyclopropanecarboxamide

N- [2,2,2-trichloro-1 - [(chloroacetyl) amino] ethyl] benzamide,

N- [3-chloro-4,5-bis- (2-propinyloksy) phenyl] -N'-metoksymetanoimidoamid.

N-formyl-N-hydroxy-DL-alanine sodium, O, O-diethyl [2- (dipropylamino) -2-oxoethyl] ethylphosphoramidamidothiocarboxylate, O-methyl-S-phenyl phenylphosphoramidamidothiocarboxylate,

S-methyl 1,2,3-benzothiadiazole-7-thiocarboxylate, spiro [2 H] -1-benzopyrano-2,1 '(3'H) -isobenzofuran] -3'-one.

Bactericides:

bronopol, dichlorophen, nitrapyrin, nickel dimethyldithiocarbamate, kasugamycin, octylinone, furancarboxylic acid, oxytetracycline, probenazole, streptomycin, techloftalam, copper sulfate and other copper preparations.

Insecticides / acaricides / nematicides [0057]

1. Otherbitotics e cetrylcholine (AChE)

1.1. Carbamates, e.g.

alanicarb, aldicarb, aldoxycarb, aliksycarb, aminbarbarb, bendiokarb, benfurakarb, bufenokarb, butakarb, butokrocoksym, butoxycarboxym, carbaryl, carbofuran, carbosulfan, chlloetokarb, dimethylane, etiopincarb, fenobucarb, phenothiocarb, formetanat, furatiocarb, isoprokarb, metam sodium, methiocarb, metomyl , metolkarb, oxamyl, pyrimicarb, promecarb, propoxur, thiodicarb, thiofanox, trimethacarb, XMh, xyloyl carbamate Triazamates

1.2 Organophosphorus compounds, e.g.

acephate, azamethiphos, azinophos (methyl, ethyl), bromophos ethyl, bromfenvinphos (methyl), butatiophos, cadusafos, carbofenothio, chloreoxifos, chlorphenvinphos, chloromiphos, chlorpyrifos (methyl / ethyl), coumafos, cyanofenphos, cyanophos, chlorfenvinphos, S-methyl demetone , S-methylsulfonic demetone, dialifos, diazinon, dichlofention, dichlorobos / DDVP, dicrotophos, dimethoate, dimethylvins, dioxaben14, phosphorus, disulfone, EPN, ethion, ethoprophos, etrymfos, famfur, fenamiphos, fenitrotion, fensulfothion, fention, flupiophobe, phonophos, formotion , fosmetylate, fosthiazate, heptenophos, iodofenphos, iprobenfos, isazophos, isofenphos, isopropyl o-salicylate, isoxation, malathion, mecarbam, methacryphos, methamidophos, methydation, mevinfos, monocrotophos, naled, ometoate, oxydemeton-methyl, parathion (methyl / ethyl), fentoat, forat, phosalone, phosmet, phosphamidon,phosphocarb, phoxim, pirimiphos (methyl / ethyl), profenofos, propafos, propetamphos, protiophos, protoat, pirachlofos, pyridafence, pyridation, chinalphos, sebufos, sulfotep, sulprofos, tebupirymfos, temefos, terbufos, tetrachlorwinfos, tiometon, triazophos, trichlorfon, wamidotion

2. Mooulatotykanałus oddwego / zćzezneod with the tension of the ductiles of the duct

2.1. Pyrethroids, e.g.

akininryine, alethrin (d-cis-trans, d-trans), beta-cyfluthrin, bifenthrine, bioaletrin, S-cyclopentyl bioaletrin isomer, bioethanomethine, biopermethrin, bioresmethrin, chlormaprine, cis-cypermethrin, cis-resmetrin, cis-permethrin, clitrin , cycloprotiine, cyfluthrin, cyhalothrin, cypermethrin (alpha-, beta-, theta-, zeta-), cyfenotrin, deltamethrin, empentrin (IR isomer), esfenvalerate, etofenprox, fenfluthrin, fenpropati- ine, fenpiiitrin, fenvalerate, flubrocytrynat, flucytryrate, flufenprox, flumetryn, fluvalinate, fubfenprox, oamma-cyhalothrin, imiprotrine, cadetine, lambdacyhalothrin, metofluthrin, permethrin (cis-, trans-), phenothrin (trans-isomer), praletrin, proflutryn, protrifenbut, piresmethrine, resmetrin, RU 15525, silafluofen, tau -fl luvinate, tefluthrin, teraletrin, tetramethrin (IR isomer), tralometin, transfluthrin,ZXl 8901, pyrethrin (pyrethrum)

DDT

2.2 Oxadiazines, e.g. indoxacarb

3. Agonis ^ i ^ / ^ i ^^^^ choke and tetylchlorine.n

3.1. Chloronicotinyl compounds, e.g.

acetamiprkd, clothianidin, dinotefuran, imidacloprid, nitenpyram, nitiazine, thiacloprid, thiamethoxam

3.2. Nicotine, bensultap, cartap

4. MoOulatoηrkeceptoraacctylocholinn

4.1. Spinosins, e.g. spinosad

5. CONTRIBUTORS p. GABA of the channel analyst

5.1. Cyclodene chlorooroanic compounds, e.g.

kamfechlor, chlordane, endosulfan, oamma-HCH, HCH. heptachlor, lindane, methoxy chlorine

5.2 Fiprole, e.g.

acetoprol, etyprol, fipronil, vaniliprol

6. Active orcish organ

6.1 Mektins, e.g.

avermectin, emamectin, emamectin benzoate, ivermectin, milbemycin

7. Mimetynthoπnowajuwegi1nago, nn.

diofenolan, epophenonate, phenoxycarb, hydroprene, kinoprene, methoprene, pyriproxyfen, tripren

8. Akowiści / śroOdtrorzrwaeącce eOd / zo

8.1 Diacyl hydrazines, e.g.

chromafenozide, halofenozide, methoxyfenozide, tebufenozide

9. Innibitooy biorywaegy echYnn

9.1. Benzoyl ureas, e.g.

bistrifluron, chlofluazuron, diflubenzuron, fluazuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, novilumuron, penluron, teflubenzuron, triflumuron

9.2. Buprofezin

9.3 Cyromazine

10. Otheritarians^attlegiająccgofc&gt; rfowrlowania, śroOktrorrywająccAkP

10.1 Diafentiuron

10.2 Cinoanoic compounds, e.g. azocyclic, cyhexatin, fenbutatin oxide,

11. Relations between 10 ^ 101 ^^ 011 Lltlenieiącgggo ('ooΓοιγΙοΥΎ'ίΐιιίίΐ) and the gradient of the proton H

11.1 Pyroles, e.g. chlorofenapir

11.2 Dinitrophenols, e.g. binapacyrl, dinobuton, dinocap, DNOK

12. Otherbitots nranappWue1egtrc&gt; waw city

12.1 MET1, e.g. Fenazachin, Fenopyroximate, Pirymidyfen, Pyridaben, Tebufenpirad, Tolfenpirad

12.2 Hydramethylnon

12.3 Dicofol

13. InnebitotynranappWue1egtrc&gt; waw placementsH

rotenone

14. Electron transport inhibitors of place III

Acechinocyl, fluacrypirim

15. Baksheevia, a bacterium that inhabits the membranes

Bacillus thuringiensis strains

16. Otherbititsits of the title of the fat

Tetrahykrofuran-2.4-cheers, e.g.

spiroclycofen, spiromesifen

Tetraminic acids, e.g.

3- (2,5-kimethylphenyl) -8-methoxy-2-oxo-1-azaspiro [4.5] ox-3-en-4-yl-ethyl carbonate (or: 3- (2,5-oxethyl-phenyl) -ster) 8-Methoxy-2-oxo-1-azaspiro [4.5] kec-3-en-4-yl-acetic acid, CAS-No .: 382608-10-8) and cis-3- (2,5-butenylphenyl) -8-methoxy ester -2-oxo-1-azaspiro [4,5] kec-3-en-4-yl-ethyl carbonic acid (CAS Registry No .: 203313-25-1)

17. Carbboxamamides, neefonikamid

18. Aggnińi ^ i. ο1 \ 1ορ; ιιηίικ'ΐ'ηίί: χηί.η | .λ amitraz

19. Otherbitifferentiated with magazza AATase ^ v. PJN^aIηjit

20. BIBCA ιηγ \ 2- | l. 1-Diinetyl-2- (methyl-L-tetral) -acetI-3-ionk-l- [2-inethyl-4- [1.2.2.2] tetrafluoro-1- (trifluoromethyl) ethyl] phenyl] -1,2-benzenecarboxamic acid ( CAS number: 27245165-7)

21. AAnlo-ii erejś ^: okayyy, ηei cronis of the Saints, tiooultaps oOkwy

22. Biololics, hhrmony or pheromones, τργ azacirachtin, Bacillus spec., Beauveria spec., Coclemony, Metarnhizium spec, aaecilomyces spec, turyngiensyna, Verticillium spec.

23. Compounds of ne ^^ nenew ^ ilLlb meswai-i: ynlimtchaniemamiZzizłanie

23.1 Fumigants, aluminum phosphide, methyl bromide, sulfuryl fluoride

23.2 Seekeeper's shoemaker's root-rppna-annea, η | + krni-t. Ponikamid, pinmotrozyna

23.3 Innebitonjwaron; ytoztonzy, ηei clofentezin, ethoxazole, hexytiazoks

23.4 amidk-lumet, 111 ^ 110 -; bceeonaγnmη bifebeazt, bronmnsonγklη PupsrOebyye, quinemetionate, chlorekimeform, chlorobenzylat, chloropicrin, clothiabin, cyclopren, bicycanil, fenoxacrym, fentrifanil, flubenzimine, flufenerim, flutezine, gospluron, hydramethylnon, japonilur, metoxadiazon, petroleum, piperonyl butoxide, potassium oleate, pyridalyl, sulfluramide , tetradifon, tetrasul, triaratene, verbutton, in addition (1R-cis) - [5- (phenylmethyl) -3-furanyl] methyl-3 - [(dihydro-2-oxo-3 (2H) furanylidene) methyl] -2,2-cyclopropanecarboxylate -2,2 -dimethyl (3-phenoxyphenyl) methyl-2,2,3,3-tetramethyl cyclopropanecarboxylate

1- [(2-Chloro-5-thiazolyl) methyl] tetrahydro-3,5-dimethyl-N-nitro-1,3,5-triazine-2 (1H) -imine

2- (2-Chloro-6-fluorophenyl) -4- [4- (1,1-dimethylethyl) phenyl] -4,5-dihydrooxazole

2- (acetyloxy) -3-dodecyl-1,4-naftalinodion

2-chloro-N - [[[4- (1-phenylethoxy) phenyl] amino] carbonyl] benzamide

2-Methylphenyl 2-chloro-N - [[[4- (2,2-dichloro-1,1-difluoroethoxy) phenyl] amino] carbonyl] benzamide propyl carbamate

4- [4- (4-ethoxyphenyl) -4-methylpentyl] -1-fluoro-2-phenoxybenzene

4-chloro-2- (1,1-dimethylethyl) -5 - [[2- (2,6-dimethyl-4-phenoxyphenoxy) ethyl] thio] -3 (2H) -pyridazinone

4-Chloro-2- (2-chloro-2-methylpropyl) -5 - [(6-iodo-3-pyridinyl) methoxy] -3 (2H) -pyridazinone 4-chloro-5 - [(6-chloro-3 -pyridinyl) methoxy] -2- (3,4-dichlorophenyl) -3 (2H) -pyridazinone Bacillus thuringiensis strain EG-2348 Benzoic acid [2-benzoyl-1- (1,1-dimethylethyl) hydrazide] 2,2- ester Dimethyl-3- (2,4-dichlorophenyl) -2-oxo-1-oxaspiro [4.5] dec-3-en-4-yl acid of [3 - [(6-chloro-3-pyridinyl) methyl] -2-butanic acid -tiazolidynylideno] cyanamide

Dihydro-2- (nitromethylene) -2H-1,3-thiazine-3 (4H) -carboxydehyde [2 - [[1,6-dihydro-6-oxo-1- (phenylmethyl) -4-pyridazinyl] oxy] ethyl ] ethyl carbamate N- (3,4,4-trifluoro-1-oxo-3-butenyl) glycine

N- (4-chlorophenyl) -3- [4- (difluormetoksy) phenyl] -4,5-dihydro-4-phenyl-1H-pyrazole-1-carboxamide

N-methyl-N '- (1-methyl-2-propenyl) -1,2-hydrazynodikarbotioamid

N-Methyl-N'-2-propenyl-1,2-hydrazinedicarbothioamid [2- (dipropylamino) -2-oxoethyl] ethylphosphoramidamidothiocarboxylate O, O-diethyl. A mixture with other known compounds such as herbicides is also possible, or with fertilizers and growth regulators.

[0059] When using active compound compositions according to the invention as insecticides in commercially available formulations and in the dosage forms prepared from these mixtures, they may further be present in a mixture with synergistic agents. Synergizing agents are compounds by which the activity of the active compounds is increased, it being unnecessary for the synergistic agent alone to be active.

[0060] The content of active ingredient in the dosage forms prepared from commercially available formulations can vary within a wide range. The concentration of the active substance in the dosage forms can be 0.0000001 - 95% by weight of the active substance, and preferably 0.0001 - 1% by weight.

[0061] They are used in the usual way specific to these dosage forms.

[0062] The active compound compositions according to the invention not only act against plant pests, but also in the veterinary medicine sector against animal parasites (ectoparasites) such as hard ticks, soft ticks, human motility, autumnal swine, flies (prickly and licking), larvae of parasitic flies, lice, hair lice, bird lice and fleas. These parasites include:

[0063] From the order Anoplurida, e.g. Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp.

[0064] From the order Mallophagida and subbranches Amblycerina and Ischnocerina, e.g. Trimenopon spp., Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp., Felicola spp.

[0065] From the order Diptera and sub-orders Nematocerina and Brachycerin, e.g. Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp. Hybomitra spp., Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp. , Calliphora spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp., Melophagus spp.

[0066] From the order Siphonapterida, e.g. Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp.

[0067] From the order Heteropterida, e.g. Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus ^spp.

[0068] From the order Blattarida, e.g. Blatta orientalis, Periplaneta americana, Blattela germanica, Supella spp.

From the Acari subclass (Acarina) and the Meta and Mesostigmata orders, e.g. Argas spp., Omithodorus spp., Otobius spp., Ixodes spp., Amblyomma spp., Boophilus spp., Dermacentor spp., Haemophysalis spp. Hyalomma spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp., Pneumonyssus spp., Sternostoma spp., Varroa spp.

[0070] From the order Actinedida (Prostigmata) and Acaridida (Astigmata), e.g. Acarapis spp., Cheyletiella spp., Ornithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp., Hypodectes spp.,

Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp.

[0071] The active compound compositions of the invention are also suitable for controlling arthropods that attack farm animals, such as e.g. cattle, sheep, goats, horses, pigs, donkeys, camels, buffalo, rabbits, chickens, turkeys, ducks, geese, Bee. By controlling these arthropods, the aim is to reduce the number of deadly cases and to reduce the productivity reduction (meat, milk, wool, skins, eggs, honey and the like), therefore, by using the active compound combination according to the invention cheaper and simpler livestock breeding is possible.

[0072] In the veterinary sector, the active compound compositions according to the invention are used in a known manner by enteral administration in the form of e.g. tablets, capsules, beverages, preparations for use in force delivery devices, granules, pastes, boluses, preparations for administration through gavage, suppositories, by parenteral administration, in such forms as e.g. injections (intramuscular, subcutaneous, intravenous, intraperitoneal and the like), implants, by nasal administration, by application to the skin in the form of e.g. baths or preparations for disinfection, spraying, pouring and applying, washing, dusting, and using articles containing the active substance, such as collars, earrings, tail features, leg bands, halters, marking devices, and the like.

[0073] For livestock, poultry and the like, the active compounds can be used as formulations (e.g., powders, emulsions, powdery products) containing the active ingredients in an amount of 1 to 80% by weight, directly or 100- to 10 000 dilution, or as a chemical bath.

[0074] The active compound compositions according to the invention are also suitable for combating animal pests, in particular insects, arachnids and mites, which are found in confined spaces, such as, for example, apartments, factory premises, offices, driver's cabs and the like. For controlling such pests they can be used alone or in combination with other active and auxiliary compounds used in insecticidal products for use in households. They are also active against sensitive and resistant species and towards all stages of development. Such pests include:

[0075] From the order Scorpionidea, e.g. Buthus occitanus.

[0076] From the order Acarina, e.g. Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallithal, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae.

[0077] From the order Araneae, e.g. Aviculariidae, Araneidae.

[0078] From the order Opiliones, e.g. Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium.

[0079] From the order Isopoda, e.g. Oniscus asellus, Porcellio scaber.

[0080] From the order Diplopoda, e.g. Blaniulus guttulatus, Polydesmus spp.

[0081] From the order Chilopoda, e.g. Geophilus spp.

[0082] In a row Zygomen, e.g. Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus.

[0083] From the order Blattaria, e.g. Blatta orientalies, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa.

[0084] From a row of Saltatoria, e.g. Acheta domesticus.

[0085] From the order Dermaptera, e.g. Forficula auricularia.

[0086] From the order Isoptera, e.g. Kalo-termes spp., Reticuliternes spp.

[0087] From the order Psocoptera, e.g. Lepinatus spp., Liposcelis spp.

[0088] From the order Coleptera, e.g. Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum ..

[0089] From the order Diptera, e.g. Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp. , Sarcophaga carnaria, Simulium spp., Stomoxys calcitrans, Tipula paludosa.

[0090] From the order Lepidoptera, e.g. Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.

[0091] From the order Siphonaptera, e.g. Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tung penetrans, Xenopsylla cheopis.

[0092] From the order Hymenoptera, e.g. Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum.

[0093] From the order Anoplura, e.g. Pediculus humanus capitis, Pediculus humanus corporis, Phthirus pubis.

[0094] From the order Heteroptera, e.g. Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans.

[0095] When using the active compound combinations according to the invention, the application rates can be varied to a large extent, depending on the method of application. In the case of treating parts of plants, the dose of the active compound compositions is usually between 0.1 and 10,000 g / ha, preferably between 10 and 1000 g / ha.

[0096] The good insecticidal effectiveness of the active compound combinations according to the invention can be seen from the examples below. While the individual active compounds exhibit poorer efficacy, the compositions exhibit activity that exceeds a simple additive effect.

[0097] The expected efficacy of given compositions of two compounds can be calculated as follows (cf. COLBY SR; "Calculating synergistic and antagonistic responses of herbicide combinations." Weeds 15, pp. 20-22, 1967);

[0098] If

X = efficacy expressed in%, destruction compared to the un-treated control sample in the case of the use of active substance A (active substance of the formula I) at a concentration of m in parts per million

Y = efficacy expressed in%, destruction compared to the untreated control in the case of the use of substance B (active substance of the formula I) in a concentration of n in parts per million

E = expected efficacy expressed in%, destruction compared to untreated control when using a mixture of active substances A and B in concentrations of min, to -oo "

[0099] When the actual destruction exceeds the calculated value, the effectiveness of the composition is superadditive, i.e. it has a synergistic effect.

Example A

Test with Aphis gossypii [0100]

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 2 parts by weight of alkylaryl polyglycol ether [0101] To prepare a formulation of the corresponding active ingredient, 1 part by weight of the active substance is mixed with a defined amount of solvent and emulsifier, and this concentrate is diluted with water containing the emulsifier to the desired concentration.

[0102] Cotton leaves (Gossypium hirsutum) heavily infested by the cucumber aphid (Aphis gossypii) are treated by immersing the active compound of the desired concentration in the formulation.

[0103] After the specified time, the destruction in% is determined. In this context, 100% means that all aphids have been destroyed; 0% means that the aphids have not been destroyed.

[0104] The results obtained in this test are shown in the table below.

Table A

Insects plant pests

Test with Aphis gossypii

<td>Active substances</td><td>Concentration of the active substance in parts per million</td><td>Destruction in% after 6 days</td>

<td>thiacloprid</td><td>0.8</td><td>25</td>

<td>clothianidin</td><td>0.8</td><td>0</td>

<td>Thiacloprid + clothianidin</td><td>0.8 + 0.8</td><td>Found * calculated **</td>

<td>(1: 1) according to the invention</td><td></td><td>98 25</td>

* found = actual insecticidal effectiveness ** calculated = effectiveness calculated according to Colby's formula

Example B

Test with Bemisia tabaci [0105]

Solvent: 7 cxęci \\ ago \ VYclidiinetvlotbmi; miidLi

Emulsifier: 2 parts of a polyiglycol disulfide ether to form a suitable active ingredient 1 part by weight of active compound is mixed with specific amounts of solvent and emulsifier and this concentrate is diluted with water containing the emulsifier to the desired concentration.

[0107] Cotton plants (Gossypium hirsutum) attacked by the whitefly 15 (Bemisia tabaci) in the form of eggs, larvae and purulent cocoons are sprayed with the active compound preparation at the desired concentration.

[0108] After a certain time, the degree of destruction in% is determined. In this context, 100% means that all whiteflies have been destroyed; 0% means that none of the whitefly has been destroyed.

[0109] The results obtained in this test are shown in the table below.

Table B

Insects plant pests

Test Bemisia tabaci

Active substances Concentration of active substance Destruction in% after 12 days in parts per million

Thioplycide 0.8 80

Clothianidin 0.8 35

Thiacloprid + clothianidin 0.8 + 0.8 Found * calculated ** (1: 1) according to the invention 92.5 857 * found = actual insecticidal effectiveness ** calculated = efficacy calculated according to Colby's formula

Example C

Test from Heliothis armigera [0110]

Solvent: 7 parts of dimei \ iatbimamide

Emulsifier: 2 parts by weight of alkylaryl with polyglycol [0111] To prepare a formulation, the active compound is mixed with 1 part by weight of active compound with specific amounts of solvent and emulsifier, and this concentrate is diluted with water containing the emulsifier to the desired concentration.

[0112] Soy sprouts (Glycine max) are treated by immersing in an active compound preparation of the desired concentration and settling on Heliothis armigera after the leaves are still wet. [0113] After a certain time, the degree of destruction in% is determined. In this context, 100% means that all caterpillars have been destroyed; 0% means that no caterpillars have been destroyed.

[0114] The results obtained in this test are shown in the table below.

Table C

Insects plant pests

Test with Heliothis armigera

<td>Active substances</td><td>Concentration of the active substance in parts per million</td><td>Destruction in% after 6 days</td>

<td>thiacloprid</td><td>4</td><td>35</td>

<td>clothianidin</td><td>4</td><td>45</td>

<td>Thiacloprid + clothianidin</td><td>4 + 4</td><td>Found * calculated **</td>

<td>(1: 1) according to the invention</td><td></td><td>90 64.25</td>

* found = actual insecticidal effectiveness ** calculated = effectiveness calculated according to Colby's formula

Example D

Test with Myzus persicae [0115]

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 2 parts by weight of a polyaryl polyglycol ether [0116] To prepare a formulation, the active compound is mixed with 1 part by weight of active compound with specific amounts of solvent and emulsifier, and this concentrate is diluted with water containing the emulsifier to the desired concentration.

[0117] Cabbage leaves (Brassica oleracea) heavily infested with peach aphid (Myzus persicae) are treated by immersing in a preparation of the active compound of the desired concentration.

[0118] After a certain time, the degree of destruction in% is determined. In this context, 100% means that all aphids have been destroyed; 0% means that the aphids have not been destroyed.

[0119] The results obtained in this test are shown in the table below.

Table D

Insects plant pests

Test with Myzus persicae

<td>Active substances</td><td>Concentration of the active substance in parts per million</td><td>Destruction in% after 6 days</td>

<td>thiacloprid</td><td>0.8</td><td>20</td>

<td>clothianidin</td><td>0.8</td><td>65</td>

<td>Thiacloprid + clothianidin</td><td>0.8 + 0.8</td><td>Found * calculated **</td>

<td>(1: 1) according to the invention</td><td></td><td>95 72</td>

* found = actual insecticidal effectiveness ** calculated = effectiveness calculated according to Colby's formula

Example E

Test with Plutella xylostella (normal strain) [0120]

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 2 parts by weight of a polyaryl polyglycol ether [0121] To prepare a formulation, the active compound is mixed with 1 part by weight of active compound with specific amounts of solvent and emulsifier, and this concentrate is diluted with water containing the emulsifier to the desired concentration.

[0122] Cabbage leaves (Brassica oleracea) are treated by immersing in a preparation of the active substance of the desired concentration and colonized by caterpillars of the chickworm ternia (Plutella xylostella / susceptible strain) when the leaves are still wet.

[0123] After a certain time, the degree of destruction in% is determined. In this context, 100% means that all caterpillars have been destroyed; 0% means that no caterpillars have been destroyed.

[0124] The results obtained in this test are shown in the table below.

Table E

Insects plant pests

Test with Plutella xylostella (normal strain)

<td>Active substances</td><td>Concentration of the active substance in parts per million</td><td>Destruction in% after 6 days</td>

<td>thiacloprid</td><td>20</td><td>15</td>

<td>clothianidin</td><td>20</td><td>60</td>

<td>Thiacloprid + clothianidin</td><td>20 + 20</td><td>Found * calculated **</td>

<td>(1: 1) according to the invention</td><td></td><td>100 66</td>

* found = actual insecticidal effectiveness ** calculated = effectiveness calculated according to Colby's formula

Example F

Heliothis armigera test [0125]

Solvent: 7 parts of CiClidimidol-lmiainide

Emulsifier: 2 parts by weight alkylamyl ether of diisomycol [0126] To prepare a formulation, the active compound is mixed with 1 part by weight of active compound with specific amounts of solvent and emulsifier, and this concentrate is diluted with water containing the emulsifier to the desired concentration.

[0127] Soy sprouts (Glycine max) are treated by immersing in the active compound formulation of the desired concentration and settling on Heliothis armigera after the leaves are still wet. [0128] After a certain time, the degree of destruction in% is determined. In this context, 100% means that all caterpillars have been destroyed; 0% means that no caterpillars have been destroyed.

[0129] The results obtained in this test are shown in the table below.

Table F

Insects plant pests

Test with Heliothis armigera

<td>Active substances</td><td>Concentration of the active substance in parts per million</td><td>Destruction in% after 7 days</td>

<td>imidacloprid</td><td>4</td><td>10</td>

<td>thiacloprid</td><td>0.8</td><td>0</td>

<td>Imidacloprid + Thiachloprid</td><td>4 + 0.8</td><td>Found * calculated **</td>

<td>(5: 1) according to the invention</td><td></td><td>20 10</td>

* found = actual insecticidal effectiveness ** calculated = effectiveness calculated according to Colby's formula

Example G Myzus test [0130]

Solvent: 7 cxęs \\ ngo \ VYclidiinetYlolórmainidLi

Emulsifier: 2 and the mixture is cooled with polyglycol ether. To prepare the preparation, the corresponding active ingredient 1 part by weight of the active substance is mixed with the specified amounts of solvent and emulsifier and this concentrate is diluted with water containing the emulsifier to the desired concentration.

[0132] Cabbage leaves (Brassica oleracea) heavily infested with the peach aphid (Myzus persicae) are treated by dipping into the active compound formulation at the desired concentration.

[0133] After a certain time, the degree of destruction in% is determined. In this context, 100% means that all aphids have been destroyed; 0% means that the aphids have not been destroyed. [0134] The results obtained in this test are shown in the table below.

Table G

Insects plant pests

Test with Myzus

<td>Active substances</td><td>Concentration of the active substance in parts per million</td><td>Destruction in% after 6 days</td>

<td>imidacloprid</td><td>0.16</td><td>10</td>

<td>thiacloprid</td><td>0.16</td><td>10</td>

<td>Imidacloprid + Thiachloprid</td><td>0.16 + 0.16</td><td>Found * calculated **</td>

<td>(1: 1) according to the invention</td><td></td><td>30 19</td>

* found = actual insecticidal effectiveness ** calculated = effectiveness calculated according to Colby's formula

Example H

Plutella test (normal strain) [0135]

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 2 parts by weight of a polyaryl polyglycol ether [0136] To prepare a formulation, the active compound is mixed with 1 part by weight of active compound with specific amounts of solvent and emulsifier, and this concentrate is diluted with water containing the emulsifier to the desired concentration.

[0137] Cabbage leaves (Brassica oleracea) are treated by immersing in the active compound preparation at the desired concentration and populating the chickworm moth (Plutella xylostella / normal strain) when the leaves are still wet.

[0138] After a certain time, the degree of destruction in% is determined. In this context, 100% means that all caterpillars have been destroyed; 0% means that no caterpillars have been destroyed.

[0139] The results obtained in this test are shown in the table below.

Table H

Insects plant pests

Plutella test (normal strain)

<td>Active substances</td><td>Concentration of the active substance in parts per million</td><td>Destruction in% after 7 days</td>

<td>imidacloprid</td><td>20</td><td>15</td>

<td>thiacloprid</td><td>4</td><td>0</td>

<td>Imidacloprid + Thiachloprid</td><td>20 + 4</td><td>Found * calculated **</td>

<td>(5: 1) according to the invention</td><td></td><td>55 15</td>

* found = actual insecticidal effectiveness ** calculated = effectiveness calculated according to Colby's formula

Example 1

Test with Spodoptera exigua [0140]

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: 2 parts by weight of a polyaryl polyglycol ether [0141] To prepare a formulation, the active compound is mixed with 1 part by weight of active compound with specific amounts of solvent and emulsifier, and this concentrate is diluted with water containing the emulsifier to the desired concentration.

[0142] Cabbage leaves (Brassica oleracea) are treated by immersing in the preparation of the active substance of the desired concentration and inhabited by the barnacle lampwort (Spodoptera exigua) when the leaves are still wet.

[0143] After a certain time, the degree of destruction in% is determined. In this context, 100% means that all caterpillars have been destroyed; 0% means that no caterpillars have been destroyed.

[0144] The results obtained in this test are shown in the table below.

Table I

Insects plant pests

Test with Spodoptera exigua

<td>Active substances</td><td>Concentration of the active substance in parts per million</td><td>Destruction in% after 7 days</td>

<td>imidacloprid</td><td>100</td><td>45</td>

<td>thiacloprid</td><td>100</td><td>0</td>

<td>Imidacloprid + Thiachloprid</td><td>100+ 100</td><td>Found * calculated **</td>

<td>(1: 1) according to the invention</td><td></td><td>55 45</td>

* found = actual insecticidal effectiveness ** calculated = effectiveness calculated according to Colby's formula

Example J

Spodoptera frugiperda test [0145]

Solvent: 7 cxęs \\ ngo \ VYclidiinetvlotbmi; miidLi

Emulsifier: 2 parts by weight polyalkyl ether of diisomycol [0146] To prepare a formulation, the active compound is mixed with 1 part by weight of active compound with specific amounts of solvent and emulsifier, and this concentrate is diluted with water containing the emulsifier to the desired concentration.

[0147] Cabbage leaves (Brassica oleracea) are treated by immersing in an active compound preparation of the desired concentration and populated with caterpillar nails (Spodoptera frugiperda) when the leaves are still wet.

[0148] After a certain time, the degree of destruction in% is determined. In this context, 100% means that all caterpillars have been destroyed; 0% means that no caterpillars have been destroyed.

[0149] The results obtained in this test are shown in the table below.

Table J

Insects plant pests

Test with Spodoptera frugiperda

<td>Active substances</td><td>Concentration of the active substance in parts per million</td><td>Destruction in% after 7 days</td>

<td>imidacloprid</td><td>0.8</td><td>20</td>

<td>thiacloprid</td><td>0.8</td><td>10</td>

<td>Imidacloprid + Thiachloprid</td><td>0.8 + 0.8</td><td>Found * calculated **</td>

<td>(1: 1) according to the invention</td><td></td><td>40 28</td>

* found = actual insecticidal effectiveness ** calculated = effectiveness calculated according to Colby's formula

Example K

Test from Bemisia tabaci [0150]

Solvent: 7 parts by weight of CiClidiinetyllbramamide

Emulsifier: 2 (1: 1): diethyl ether / polyglycol ether [0151] To prepare a formulation, the active ingredient is mixed with 1 part by weight of active compound with the given amounts of solvent and emulsifier, and the concentrate is diluted with water containing the emulsifier to the desired concentration.

[0152] Cotton plants (Gossypium hirsutum) attacked by whitefly 10 (Bemisia tabaci) in the form of eggs, larvae and purulent cocoons are sprayed with the preparation of the active compound of the desired concentration.

[0153] After a certain time, the degree of destruction in% is determined. In this context, 100% means that all whiteflies have been destroyed; 0% means that no whitefly has been destroyed.

[0154] The results obtained in this test are shown in the table below.

Table K

Insects plant pests

Test from Bemisia tabaci

<td>Active substances</td><td>Concentration of the active substance in parts per million</td><td colspan="2">Destruction in% after 10 days</td>

<td>imidacloprid</td><td>0.16</td><td>5</td><td></td>

<td>clothianidin</td><td>0.16</td><td>5</td><td></td>

<td>Imidacloprid + Chlotianidy-</td><td>0.16 + 0.16</td><td>It was found *</td><td>** calculated</td>

<td>on (1: 1) according to the invention</td><td></td><td>35</td><td>9.75</td>

* found = actual insecticidal effectiveness ** calculated = effectiveness calculated according to Colby's formula

Example L

Test from Heliothis armigera [0155]

Solvent: 7 cxęs \\ ngo \\ yclicliinetvlotbi'mainicki

Emulsifier: 2 parts by weight polyalkyl polyglycol ether [0156] To prepare a formulation, the active compound is mixed with 1 part by weight of active compound with specific amounts of solvent and emulsifier, and this concentrate is diluted with water containing the emulsifier to the desired concentration.

[0157] Soy sprouts (Glycine max) are treated by immersing in the active compound formulation at the desired concentration and settling on Heliothis armigera after the leaves are still wet.

[0158] After a certain time, the degree of destruction in% is determined. In this context, 100% means that all caterpillars have been destroyed; 0% means that no caterpillars have been destroyed.

[0159] The results obtained in this test are shown in the table below.

Table L

Insects plant pests

Test with Heliothis armigera

<td>Active substances</td><td>Concentration of the active substance in parts per million</td><td>Destruction in% after 6 days</td>

<td>imidacloprid</td><td>4</td><td>10</td>

<td>clothianidin</td><td>4</td><td>0</td>

<td>Imidacloprid + Chlotianidy-</td><td>4 + 4</td><td>Found * calculated **</td>

<td>on (1: 1) according to the invention</td><td></td><td>70 10</td>

<td colspan="3">* found = actual insecticidal effectiveness ** calculated = effectiveness calculated according to Colby's formula</td>

Example M

Test with Myzus persicae [0160]

Solvent: 7 (^; ^ &lt;s ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^

Emulsifier: 2 parts by volume of dihydric ether [0161] To prepare a formulation, the active compound is mixed with 1 part by weight of active compound with specific amounts of solvent and emulsifier, and this concentrate is diluted with water containing the emulsifier to the desired concentration.

[0162] Cabbage leaves (Brassica oleracea) heavily infested with a peach aphid (Myzus persicae) are treated by immersing in a preparation of the active compound of the desired concentration.

[0163] After a certain time, the degree of destruction in% is determined. In this context, 100% means that all aphids have been destroyed; 0% means that the aphids have not been destroyed.

[0164] The results obtained in this test are shown in the table below.

Table M

Insects plant pests

Test with Myzus persicae

<td>Active substances</td><td>Concentration of the active substance in parts per million</td><td>Destruction in% after 6 days</td>

<td>imidacloprid</td><td>0.16</td><td>50</td>

<td>clothianidin</td><td>0.16</td><td>0</td>

<td>Imidacloprid + Chlotianidy-</td><td>0.16 + 0.15</td><td>Found * calculated **</td>

<td>on (1: 1) according to the invention</td><td></td><td>70 50</td>

<td colspan="3">* found = actual insecticidal effectiveness ** calculated = effectiveness calculated according to Colby's formula</td>

Example N

Test with Spodoptera exigua [0165]

Solvent: 7 cxęs \\ ngo \ VYclidiinetvlotbmi; miidLi

Emulsifier: 2 (^^ - ^ ęseiY ag ^ t ^ ^ ^ Yćin-iibanybwYg of gel poiigiikolu [0166] To prepare the formulation odpowiednij of active compound, 1 part by weight of active compound is mixed with specified amounts of solvent and emulsifier, and the concentrate is diluted with water containing emulsifier to the desired concentration.

[0167] Cabbage leaves (Brassica oleracea) are treated by being dipped into the preparation substan15 the active compound of the desired concentration and populated armyworm (Spodoptera exigua) while the leaves are still moist.

[0168] After a certain time, the degree of destruction in% is determined. In this context, 100% means that all caterpillars have been destroyed; 0% means that no caterpillars have been destroyed.

[0169] The results obtained in this test are shown in the table below.

Table N

Insects plant pests

Test with Spodoptera exigua

Active substances Concentration of a personal substance Destruction in% after 6 days in parts per million

Imidachloprid 20 10

CClotianidin 20 10

Imidacloprid + CClotianidy- Found * calculated in (1: 1) according to the invention 20 + 20 70 19 * found = actual insecticidal effectiveness ** calculated = efficacy calculated in accordance with Colby's formula