Method for forming reinforced pultruded profiles.
Abstract
A method and apparatus for forming a profile containing at least one layer of continuous fibers and at least one layer of discontinuous fibers. Such a method allows selective control of characteristics to achieve that a profile has an increased transverse strength and bending coefficient. The continuous fiber layer can be formed from one or more continuous fiber reinforced tapes ("CFRT") (12) containing fibers embedded within a thermoplastic polymer matrix, whereby a void fraction is minimized in turn and the bending coefficient are optimized. Furthermore, the tape (s) are consolidated so that the continuous fibers remain fixed in alignment with a substantially longitudinal direction (eg, the stretch extrusion direction). In addition to improving the tensile properties of the profile, the use of such tapes also allows for improved capacity when placed in the desired position within the stretch extrusion die. The discontinuous fibers are also integrated into a thermoplastic matrix, in such a way that they help in the union of the layers to achieve the desired resistance. At least a portion of the fibers are oriented in the transverse direction to provide increased transverse strength.

Term
4.7 yearsleft in the term
Expires 22 June 2031.
- Priority
- Filed
- Granted
- Today
- Expires
30 claims: 5 independent, 25 dependent
- 1NOVEDAD DE LA INVENCION NOVELTY OF THE INVENTION Habiendo descrito la presente invención como antecede, se considera, como novedad y por lo tanto se reclama como propiedad lo descrito en las siguientes:Having described the present invention as above, it is considered as a novelty and therefore what is described in the following is claimed as property: CLAIMS Z 1. A method of forming a draw profile having a cross-sectional shape, the method characterized by comprising: REIVINDICACIONES Z 1. Un método para formar un perfil de extraído por estirado que tiene una forma en corte transversal, el método caracterizado porque comprende: z jalar una cinta de fibra continua a través de una matriz de extrusión por estirado en una dirección longitudinal, en ✓ z pulling a continuous fiber tape through a stretch extrusion die in a longitudinal direction, in ✓ donde la cinta de fibra discontinua contiene fibras continuas que se orientan sustancialmente en la dirección longitudinal e integran dentro de una primera matriz polimérica termoplástica;wherein the discontinuous fiber tape contains continuous fibers that are oriented substantially in the longitudinal direction and integrated within a first thermoplastic polymeric matrix;z introducing a discontinuous fiber material into the stretch extrusion die, wherein the discontinuous fiber material contains integrated discontinuous fibers within a second thermoplastic matrix;and wherein the discontinuous fiber material is introduced into the draw extrusion die by supplying the discontinuous fiber material at an entry angle relative to the longitudinal direction, wherein the entry angle is approximately 45 ° or more. , and flowing fiber material 58 IMPIS ^ ζ IFUTTTUTO MEXICANO <· Jk z introducir un material de fibra discontinua en la matriz de extrusión por estirado, en donde el material de fibra discontinua contiene fibras discontinuas integradas dentro de una segunda matriz termoplástica;y en donde el material de fibra discontinua se introduce dentro de la matriz de extrusión por estirado mediante el suministro del material de fibra discontinua a un ángulo de entrada relativo a la dirección longitudinal, en donde el ángulo de entrada es de aproximadamente 45° o más, y fluyendo el material de fibra 58 IMPIS^ ζ IFUTTTUTO MEXICANO <· Jk M la non tbAb INDUSTRIAL discontinua a través de una entrada curveada desde el ángulo de entrada hacia la dirección longitudinal de forma tal que el material de fibra discontinua fluye en la dirección longitudinal antes de combinar el material de fibra 5 discontinua y la cinta fibra continua;y / dentro de la matriz de extrusión por estirado, combinar el material de fibra discontinua y la cinta de fibra continua para formar una primera y segunda capas del perfil, en donde la primera capa se coloca adyacente a la segunda capa e 10 incluye el material de fibra discontinua, y en donde la / segunda capa incluye la cinta de fibra continua. M la non tbAb INDUSTRIAL discontinuous through a curved inlet from the inlet angle towards the longitudinal direction such that the discontinuous fiber material flows in the longitudinal direction before combining the discontinuous fiber material and the continuous fiber tape;and / within the stretch extrusion die, combining the discontinuous fiber material and the continuous fiber tape to form a first and second layers of the profile, where the first layer is placed adjacent to the second layer and includes the material staple fiber, and wherein the / second layer includes the continuous fiber tape. Y y
- 4El método de conformidad con caracterizado porque la primera matriz la reivindicación 1, termoplástica incluye un primer polímero termoplástico y la segunda matriz termoplástica incluye un segundo polímero termoplástico, en donde el primer y segundo polímeros termoplásticos son los mismos. Four. The method according to characterized in that the first thermoplastic matrix in claim 1 includes a first thermoplastic polymer and the second thermoplastic matrix includes a second thermoplastic polymer, wherein the first and second thermoplastic polymers are the same. / /
- 8The method in accordance with the rei vi ndi c ^ c ^ op ^ 6,. ~ characterized in that the continuous fibers are under tension when impregnated with the thermoplastic matrix. 8. El método de conformidad con la reí vi ndi c^c^ óp^ 6, . ~ caracterizado porque las fibras continuas se encuentran bajo tensión cuando se impregnan con la matriz termoplástica.
- 1010% by weight to about 60% by weight of the tape and the continuous fibers make up from about 40% by weight to about 90% by weight of the tape. 10% en peso a aproximadamente 60% en peso de la cinta y las fibras continuas constituyen de aproximadamente 40% en peso a aproximadamente 90% en peso de la cinta. / 10. El método de conformidad con la reivindicación 1, caracterizado porque las fibras discontinuas incluyen fibras largas. / 10. The method according to claim 1, characterized in that the discontinuous fibers include long fibers. , ,
- 29The method in accordance with. claim 1, characterized in that the profile is solid. 29. El método de conformidad con . la reivindicación 1, caracterizado porque el perfil es sólido.
Independent claims5
282 paragraphs in 33 sections, as filed
(54) Title: METHOD FOR FORMING REINFORCED EXTRUDED OR STRETCHED PROFILES.
(54) Title: METHOD FOR FORMING REINFORCED PULTRUDED PROFILES.
(57) Summary
A method and apparatus for forming a profile containing at least one layer of continuous fibers and at least one layer of discontinuous fibers. Such a method allows selective control of characteristics to achieve that a profile has an increased transverse strength and bending coefficient. The continuous fiber layer can be formed from one or more continuous fiber reinforced tapes (CFRT) (12) containing integrated fibers within a thermoplastic polymer matrix, whereby a void fraction is in turn minimized and the coefficient bending are optimized. Furthermore, the tape (s) are consolidated so that the continuous fibers remain fixed in alignment with a substantially longitudinal direction (eg, the stretch extrusion direction). In addition to improving the tensile properties of the profile, the use of such tapes also allows for improved capacity when placed in the desired position within the stretch extrusion die. The discontinuous fibers are also integrated into a thermoplastic matrix, in such a way that they help in the union of the layers to achieve the desired resistance. At least a portion of the fibers are oriented in the transverse direction to provide increased transverse strength.
(57) Abstract
A method and apparatus for forming a profile that contains at least one layer of continuous fibers and at least one layer of discontinuous fibers. Said method allowing the selective control of features to achieve a profile that has increased transverse strength and flexural modulus. The layer of continuous fibers may be formed from one or more continuous fiber reinforced ribbons (CFRT) (12) that contain fibers embedded within a thermoplastic polymer matrix, whereby a void fraction and in turn is, is minimized and flexural modulus is optimized. Further, the ribbon (s) are Consolidated so that the continuous fibers remam fixed in alignment in a substantially longitudinal direction (eg, the direction of pultrusion). In addition to enhancing the tensile properties of the profile, the use of such ribbons also allows an improved handability when placing them into the desired position within the pultrusion die. The discontinuous fibers are also embedded within a thermoplastic matrix, in such a way as to assist in bonding of the layers to achieve the desired strength. At least a portion of the fibers are oriented in the transverse direction to provide increased transverse strength.
PATENT TITLE No. 349378
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Owner (s): TICONA LLC
Address: 8040 Dixie Highway, Florence, Kentucky, 41042, USA
Name: METHOD FOR FORMING REINFORCED EXTRUDING OR STRETCHING PROFILES.
Classification: CIP: B29C70 / 08; B29C70 / 52
CPC: B29C70 / 52; B29C70 / 08; B29C70 / 081: B29C70 / 521; B29C70 / 525;
B29B15 / 122; Y10T428 / 249921
Inventor (s): SHERRI M. NELSON; DAVID W. EASTEP; TIMOTHY A. REGAN
REQUEST
<td>Number:</td><td>International Presentation Date:</td>
<td>MX / a / 2012/014177</td><td>..... June 22, 2011</td>
<td></td><td>PRIORITY</td>
<td>Country:</td><td>Date: Number:</td>
<td>US</td><td>June 22, 2010 61 / 357,289</td>
Validity: Twenty years
Expiration Date: June 22, 2031
Issue Date: July 25, 2017 .....
The reference patent is granted based on articles 1 ', 2<sup>or</sup> fraction V, 6 'fraction lll and 59 of the Industrial Property Law
In accordance with article 23 of the Industrial Property Law, this patent is valid for twenty years, non-extendable from the date of filing the international application and will be subject to the payment of the fee to keep the rights in force.
Whoever signs this title does so based on the provisions of articles 6<sup>or</sup> Sections lll and 7 bis 2 of the Industrial Property Law (Official Gazette of the Federation pO.f; 06/27/1991. amended on 08/02/1994, 10/25/1996. 12/26/1997, 05/17/199 », 01/26/2004. 06/16/2005, 01/25/2006, 05/06/2009, 06/01/2010, 06/28/2010, 06/28/2010, 27 / 01/2012, and 04/09/2012); Articles 1 ', 3rd fraction V subsection a), 4th and 12<sup>or</sup> Sections I and III of the Regulations of the Mexican Institute of Industrial Property (DOF 12/14/1999. amended on 07/01/2002, 07/15/2004, 07/28/2004 and 09/07/2007); items 1<sup>or</sup>, 3<sup>or</sup>, 4<sup>or</sup>, 5<sup>or</sup> fraction V part a). 16 sections I and III and 30 of the Organic Statute of the Mexican Institute of Industrial Property (DOF, 12/27/1999, amended on 10/10/2002, 07/29/2004, 08/04/2004 and 09/13 2007); I<sup>or</sup>, 3 ° and 5 'subsection a) of the Agreement that delegates powers to the Deputy General Directors, Coordinator, Divisional Directors. Heads of Regional Offices, Divisional Sub-rectors, Departmental Coordinators and other subordinates of the Mexican Institute of Industrial Property. (DOF 12/15/1999, amended on 02/04/2000, 07/29/2004, 08/04/2004 and 09/13/2007).
This document is signed with an advanced electronic signature (FIEL), based on articles 7 BIS 2 of the Industrial Property Law; 3 of its Regulations, and 1 fraction lll, 2 fraction V, 26 BIS and 26 TER of the Agreement establishing the guidelines for the use of the Payment and Electronic Services Portal (PASE) of the Mexican Institute of Industrial Property, in the procedures indicated.
THE DIVISIONAL DIRECTOR OF PATENTS
NAHANNY CANAL REYES
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Tax | 1695 |) MX / 2017/61210 | MX / a / 2012/014177 | PCT patent title | 1220 | RRGO | Page (s) | 7ltmiU48EwSPpbWIJ9YxldCDS5Q =
Digital stamp:
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METHOD FOR FORMING EXTRUDED PROFILES OR
BACKGROUND OF THE INVENTION
Fiber-reinforced profiles are often formed by drawing (stretch extrusion) continuous fibers through a resin and then setting the fiber-reinforced resin within a stretch extrusion die. Since the profiles have continuous fibers oriented in the machine direction (longitudinal), they often show a high yield strength in the machine direction. The transverse strength properties of such profiles however are often poor, which can cause the material to fragment when stress is applied in a cross-machine (transverse) direction. In this regard, various attempts have been made to strength the profiles in the transverse direction. For example, US Patent No. 7,514,135 to Davies, et al., Describes a stretch extruded part formed by providing a first layer of reinforcing strands extended in a longitudinal stretch extrusion direction and forming a second layer over the first layer, the second layer containing at least minus some reinforcing fibers that extend in the transverse direction. However, a problem with this method is that it depends on a resin
<img file="MX349378B_D0003.tif" />
IMPI υβτττντβ ΜβΒΟΑΝΟ μ or non · Μ · jxdothuu thermoset to help achieve the desired strength. Such resins are difficult to use during manufacture and do not always have good bonding characteristics for layering with other materials. Furthermore, the method described herein is also problematic in that it is difficult to apply the transverse fibers at the selective locations (eg, where they are needed).
As such, there is currently a need for a method and apparatus for forming a draw-draw profile that contains a continuous fiber layer and a discontinuous fiber layer.
BRIEF DESCRIPTION OF THE INVENTION
In accordance with one embodiment of the present invention, a method of forming a stretch extrudate profile having a cross-sectional shape is described. The method comprises pulling a continuous fiber tape through a stretch extrusion die in a longitudinal direction, wherein the continuous fiber tape contains continuous fibers that are substantially oriented in the longitudinal direction and integrated within a first thermoplastic polymeric matrix. . A staple fiber material is presented in the extrusion die by
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rwtJusniiAi stretched wherein the staple fiber material contains staple fibers embedded within a second thermoplastic matrix. Within the stretch extrusion die, the staple fiber material and continuous fiber tape combine to form the first and second layers of the profile. The first layer is placed adjacent to the second layer and contains the staple fiber material. The second layer includes the continuous fiber tape.
According to another embodiment of the present invention, a stretch extrusion apparatus for forming a profile is described. The apparatus comprises a stretch extrusion die defining an inner cavity, a traction device that is configured to pull one or more continuous fiber ribbons through the inner cavity of the stretch extrusion die, an extrusion device with crosshead that is configured to extrude a staple fiber material into the inner cavity of the stretch extrusion die, and a mandrel positioned within the interior cavity of the stretch extrusion die. The mandrel has a first section over which it is configured to flow the discontinuous fiber material to form a first layer of the profile and a second section over which the continuous fiber tape is configured to flow to form a second layer of the
<img file="MX349378B_D0005.tif" />
Other characteristics and let's aspire do · the piriaewÍfee profile.
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INSTITUTO MEXICANO DILAKOflEDAD industrial invention are set forth in greater detail below.
BRIEF DESCRIPTION OF THE FIGURES
A complete and permissible description of the present invention, including the best mode thereof for one skilled in the art, is set forth more particularly in the remainder of the specification, including references to the attached figures, in which:
Figure 1 is a schematic illustration of one embodiment of a stretch extrusion system that can be employed in the present invention.
Figure 2 is a schematic illustration of one embodiment of an impregnation system for use in the present invention.
Figure 3A is a cross-sectional view of the impregnation matrix shown in Figure 2.
Figure 3B is an exploded view of one embodiment of a manifold assembly and a gate passage for an impregnation matrix that can be used in the present invention.
Figure 3C is a perspective view of one embodiment of a plate that at least partially defines
<img file="MX349378B_D0006.tif" />
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INRTTVI · MEXICANO ΜίΑηΟΗΠΜΟ rxrxrjTwvM an impregnation zone that can be used in the present invention.
Figure 4 is a side view of one embodiment of preform and stretch extrusion dies that may be used in the present invention, wherein the flow of the continuous and discontinuous fiber materials is illustrated as it passes through the dies. .
Figure 5 is a perspective view of the dies of Figure 4.
Figure 6 is a top view of one embodiment of a mandrel that may be used in the present invention to form the layer of discontinuous fiber, wherein the flow of the discontinuous fiber material is also illustrated as it passes over the mandrel.
Figure 7 is a sectional perspective view of the mandrel of Figure 6.
Figure 8 is an exploded perspective view of one embodiment of the mandrel section that can be used in the present invention to form the continuous fiber layer, wherein the flow of continuous fiber material is also illustrated as it passes over the mandrel. .
Figure 9 is a sectional perspective view of the mandrel of Figure 8.
Figure 10 is another perspective view of the <sub>6</sub> IMPI ^ a umi i uto muucanc ot u non age INDUSniAl chuck section of Figure 8, in which Figure 10A shows a right perspective view and Figure 10B shows a left perspective view of the chuck section.
Figure 11 is a cross-sectional view of one embodiment of a rectangular hollow profile that can be formed in accordance with the present invention.
Figure 12 is a cross-sectional view of another embodiment of a rectangular hollow profile that can be formed in accordance with the present invention.
Figure 13 is a side view of one embodiment of a stretch extrusion preform die system that can be used to form the profile of Figure 12.
Figure 14 is a perspective view of the preform and stretch extrusion die system of Figure 13.
Figure 15 is a cross-sectional view of yet another embodiment of a rectangular hollow profile that can be formed in accordance with the present invention.
Figure 16 is a cross-sectional view of one embodiment of an L-shaped hollow profile that can be formed in accordance with the present invention.
Figure 17 is a cross-sectional view of
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- numuto muucaho 'DE LA noniDA' tXDumuAi an embodiment of a solid U-shaped profile that can be formed in accordance with the present invention.
Figure 18 is a cross-sectional view of one embodiment of a rectangular solid profile that can be formed in accordance with the present invention. AND
Figure 19 is a cross-sectional view of one embodiment of a solid I-shaped profile that can be formed in accordance with the present invention.
The repeated use of reference characters in the present specification and figures is intended to represent the same or analogous features or elements of the present invention.
Definitions
As used herein, the term profile generally refers to a stretch extrudate part. The profile can be hollow or solid, and can have a wide variety of cross-sectional shapes, such as square, rectangular, circular, elliptical, triangular, I-shaped, C-shaped, U-shaped, J, L-shaped, ribbed, etc. Such profiles can be used as a structural member for linear window receptacles, deck planks, rails, balusters, shingles, decking, trim panels, pipe, trellis, posts,
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light poles, road sign, road signposts, etc.
As used herein, the term "hollow" generally means that at least a portion of the interior of the profile is a void space. The recessed space can optionally be extended over the entire length of the profile.
As used herein, the term continuous fibers generally refers to fibers, filaments, strands, or rovings (eg, a bundle of fibers) that have a length that is generally limited only by the length of the part. For example, such fibers may be greater than about 25 millimeters in length, in some embodiments about 50 millimeters or more, and in certain embodiments, about 100 millimeters or more.
As used herein, the term "staple fibers" generally refers to fibers, filaments, strands, or rovings that are not continuous. Such fibers typically have a length of about 25 millimeters or less. For example, staple fibers can include short or long fibers. Long fibers typically are those fibers that are from about 0.5 to about 25 millimeters in length, in some embodiments, from about 0.8 to about
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Di LA nOPIIDAt) INDUSTRIAL millimeters, and in some embodiments, from about 1 to about 12 millimeters. Short fibers typically are those fibers that are about 0.5 millimeters or less in length, in some embodiments about 0.01 to about 0.4 millimeters, and in some embodiments, about 0.05 to about 0.3 millimeters.
DETAILED DESCRIPTION OF THE INVENTION
It will be understood by one of ordinary skill in the art that the present discussion is a description of exemplary embodiments only, and is not intended to limit the broader aspects of the present invention.
Generally speaking, the present invention is directed to a method and apparatus for forming a profile containing at least one continuous fiber layer and at least one discontinuous fiber layer. Various characteristics of the method are selectively controlled to achieve a profile that has an increased transverse strength and bending coefficient. For example, the continuous fiber layer is formed from one or more continuous fiber reinforced tapes (CFRTs) containing fibers embedded in a thermoplastic polymer matrix. The fibers are integrated into the matrix through a process that minimizes the
<img file="MX349378B_D0009.tif" />
IMPI iunmra mwcano DEiAnomoA »rmwniiAi fraction with voids and in turn optimizes the bending coefficient. In addition, the tape (s) are consolidated so that the continuous fibers remain fixed in alignment with a substantially longitudinal direction (for example, the direction of stretch extrusion). In addition, to improve the tensile properties of the profile, the use of such tapes also allow the continuous fiber material to be easier to handle and place in the desired position within the stretch extrusion die. The discontinuous fibers are also integrated into a thermoplastic matrix. Among other things, this can aid in bonding the layers so that an adhesive is not required to achieve the desired strength. Also, instead of being oriented in the longitudinal direction, at least a portion of the fibers are oriented in the transverse direction to provide increased transverse strength.
Through the method and apparatus of the present invention, the formation of a wide variety of complex shapes and sizes is possible with little difficulty and without adversely affecting the strength properties of the resulting profile. Various embodiments of the present invention will now be described in greater detail.
The continuous and discontinuous fibers used in the profile can be formed from the same materials or IMPI ΐηητηπ · MEXICAN of la non AGE A-TF <I
INDUSTRIAL w different. Such materials can include any conventional material known in the art, such as metallic fibers; glass fibers (e.g. E glass, A glass, C glass, D glass, AR glass, R glass, Si glass, S2 glass), carbon fibers (e.g. graphite), boron fibers, ceramic fibers (e.g. e.g. alumina or silica), aramid fibers (e.g. Kevlar® available from EI duPont de Nemours, Wilmington, DE), synthetic organic fibers (eg, polyamide, polyethylene, paraphenylene, terephthalamide, polyethylene terephthalate, and polyphenylene sulfide), and other natural or synthetic inorganic or organic fibrous materials known to reinforce thermoplastic compositions. Glass fibers and carbon fibers are particularly desirable for use in continuous and / or discontinuous fibers. Such fibers often have a nominal diameter of from about 4 to about 35 microns, and in some embodiments, from about 9 to about 35 microns. The fibers can be twisted or straight. If desired, the fibers may be in the form of rovings (eg, a set of fibers) containing one type of single fiber or different types of fibers. Different fibers may be contained in individual strands or, alternatively, each strand may contain a different type of fiber. For example, in one mode,
IMPI wmuTo mixícaj * of INDUSTIIAl u fiofiety Certain wicks may contain continuous carbon fibers,
ΜΜ ** ^ · ^ »*** · ^ *** · '* I - -“ while other wicks may contain glass fibers. The number of fibers contained in each wick can count or vary from wick to wick. Typically, a wick can contain from about 1,000 fibers to about 50,000 individual fibers, and in some embodiments, from about 2,000 to about 40,000 fibers.
Any of a variety of thermoplastic polymers can be used to form the thermoplastic matrices in which the continuous and discontinuous fibers are integrated. Suitable thermoplastic polymers for use in the present invention may include, for example, polyolefins (for example, polypropylene, propylene-ethylene copolymers, etc.), polyesters (for example, polybutylene terephthalate (PBT)), polycarbonates, polyamides (eg Nylon ™), polyether ketones (eg polyether ether ketone (PEER)), polyetherimides, polyarylene ketones (eg polyphenylene diketone (PPDK)), liquid crystal polymers, polyarylene sulfides (eg, polyphenylene sulfide (PPS)), fluoropolymers (eg, polytetrafluoroethylene-perfluoromethylvinylether polymer, perfluoro-alkoxyalkane polymer, petrafluoroethylene polymer, ethylene-tetrafluoroethylene polymer, etc.), polyacetals,
<img file="MX349378B_D0010.tif" />
polyurethanes, polycarbonates,
IMPI ¡iwrmrro m «icano r <sub>to </sub>Dt u MomoAL · tNDUJTWAI styrenic polymers (eg acrylonitrile butadiene styrene (ABS)), and so on. ABS is a particularly suitable thermoplastic polymer. It should be understood that the polymer (s) used to form the continuous and discontinuous fiber materials may be the same or different.
To reduce the void fraction of the continuous fiber ribbon and ensure good impregnation, an extrusion device can be employed in the present invention to integrate the continuous fibers into a thermoplastic matrix. Among other things, the extrusion device facilitates the ability of the thermoplastic polymer to be applied over the entire surface of the fibers. For example, the void fraction may be about 3% or less, in some embodiments about 2% or less, and in some embodiments, about 1% or less. The void fraction can be measured using techniques well known to those of skill in the art. For example, the void fraction can be measured using a 'resin burn test' in which samples are placed in an oven (eg 600 ° C for 3 hours) to burn the resin. The mass of the remaining fibers can then be measured to calculate the weight and volume fractions. Such a combustion test 'can be performed in accordance with ASTM D
<img file="MX349378B_D0011.tif" />
2584-08 to determine the weights of the fibers and the thermoplastic matrix, which can then be used to calculate the void fraction based on the following equation:
Vf = ¡00 * (Pt-pd / pf where,
Vf is the void fraction as a percentage;
p<sub>c</sub> is the density of the compound as measured using known techniques, such as with a liquid or gas pycnometer (eg, helium pycnometer);
Pt is the theoretical density of the compound as determined by the following equation:
p, = 1 liV, p, - WJp<sub>m</sub>] p, „is the density of the thermoplastic matrix (eg, at the appropriate crystallinity);
Pf is the density of the fibers;
Wf is the weight fraction of the fibers; Y
W<sub>m</sub> is the weight fraction of the thermoplastic matrix.
Alternatively, the void fraction can be determined by chemically dissolving the resin in accordance with ASTM D 3171-09. Combustion and dissolution methods are particularly suitable for glass fibers, which are generally resistant to melting and
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KDI.STEIA! ^ J Chemical Dissolution. In other cases, however, the void fraction can be calculated indirectly based on the densities of the thermoplastic polymer, fibers, and tape in accordance with ASTM D 2734-09 (Method A), where the densities can be determined ASTM D792-08 Method A Of course, the void fraction can also be estimated using conventional microscope equipment.
Referring to Figure 2, an embodiment of an extrusion device is shown that can be used to impregnate fibers with a thermoplastic polymer. More particularly, the apparatus includes an extruder 120 containing a screw shaft 124 mounted within a barrel 122. A heater 130 (eg, an electric resistance heater) is mounted outside of barrel 122. During use, a thermoplastic polymer feedstock 127 is supplied to extruder 120 through hopper 126. Thermoplastic feedstock 127 is transported into cylinder 122 by screw shaft 124 and heated by frictional forces within cylinder 122 and by heater 130. Upon heating, raw material 127 exits cylinder 122 through cylinder flange 128 and enters a die flange 132 of impregnation die 150.
A continuous fiber strand 142 or a plurality of continuous fiber strands 142 is supplied from a spool
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INDUSTRIAL MU nOfltDAI or spools 144 to the 150 die. The wicks 140, gonQKaImgwfeg · are spaced some distance prior to impregnation, such as at least about 4 millimeters, and in some embodiments, at least about 5 millimeters. The raw material 127 can further be heated within the die by heaters 133 mounted on or around the die 150. The matrix is generally operated at temperatures that are sufficient to cause melting and impregnation of the thermoplastic polymer. Typically, the operating temperature of the die is greater than the melting temperature of the thermoplastic polymer, such as at temperatures from about 200 ° C to about 450 ° C. When proceeding in this manner, the continuous fiber strands 142 are integrated into the polymeric matrix, which can be a resin 214 (Figure 3A) processed from the raw material 127. The mixture is then extruded from the impregnating matrix. 150 to create an extrudate 152.
A pressure sensor 137 (Figure 3A) senses the pressure near the impregnation die 150 to allow control over the extrusion rate to be exercised by controlling the rotational speed of the screw shaft 124, or the feed rate of the feeder. . That is, the pressure sensor 137 is positioned close to the impregnation die 150 so that the extruder 120 can be operated! ΜΡΪ ^
ΙΝΓΤΤΤνΤβ MtUCaN · Κ LA ESOHEBAU muvniiAi by delivering a correct amount of resin 214 ^ to interact with the fiber wicks 142. After leaving the impregnation matrix 150, the extrudate 152, or impregnated fiber wicks 142, can enter a pre optional formed, or guide section (not shown) before entering a pressure point formed between two adjacent rollers 190. Although optional, rolls 190 can help consolidate extrudate 152 into a tape (or tape), as well as improve fiber impregnation and extrusion in any voided excess. In addition to rollers 190, other shaping devices may also be employed, such as a die system. The resulting consolidated belt 156 is pulled by roller-mounted travel guides 162 and 164. Offset guides 162 and 164 also pull extrudate 152 from impregnation die 150 and through rollers 190. Consolidated tape 156 can be wound into a section 171 if desired. Generally speaking, the tapes are relatively thin and typically have a thickness of from about 0.05 to about 1 millimeter, in some embodiments from about 0.1 to about 0.8 millimeters, and in some embodiments, from about 0.2 to about 0.4 millimeters.
Within the impregnation matrix, generally
<img file="MX349378B_D0013.tif" />
is IMPI ηβτττυτο Mexican
Μ M MIOPIMMD it is desired that the wicks 142 pass through more impregnation zone 250 to impregnate the wicks with the polymeric resin 214. In the impregnation zone 2 50, the polymeric resin can be forced generally and transversely through the wicks by means of the shear stress and pressure created in the impregnation zone 2 50, which significantly improves the degree of impregnation. This is particularly useful when compounding the tapes of a high fiber content, such as about 3-5% by weight fraction (Wf) or more, and in some embodiments, of about 40% Wf or more. Typically, matrix 150 will include a plurality of contact surfaces 252, such as for example at least 2, at least 3, 4 to 7, 2 to 20, 2 to 30, 2 to 40, 2 to 50, or more contact surfaces 252, to create a sufficient degree of penetration and pressure in the wicks 142. Although their particular shape may vary, contact surfaces 252 typically possess a curvilinear surface, such as a curved lobe, rod, etc. The contact surfaces 252 are typically also made of a metal material.
Figure 3A shows a cross-sectional view of an impregnation matrix 150. As shown, impregnation matrix 150 includes a manifold assembly 220, a gate passageway 27 0, and an impregnation zone 250. The
<img file="MX349378B_D0014.tif" />
IMPI iwtttuto méxicanq "THE PROHID" NDUMUM manifold assembly 220 is provided to flow polymeric resin 214 through it. For example, manifold assembly '220 may include a channel 222 or a plurality of channels 222. Resin 214 provided to impregnation matrix 150 may flow through channels 222.
As shown in Figure 3B, certain portions of the channels 222 may be curvilinear, and in exemplary embodiments, the channels 222 have a symmetrical orientation along a central axis 224. In addition, in some embodiments, the channels may be a plurality of branched gutters 222, which may include a first group of branched gutters 232, second group 234, third group 236, and, if desired, more groups of branched gutters. Each group may include 2, 3, 4, or more branched channels 222 outside of channels 222 in the preceding group, or from an initial channel 222.
The branched gutters 222 and the symmetrical orientation thereof generally and uniformly distribute the resin 214, such that the flow of the resin 214 exiting the manifold assembly 220 and overlying the wicks 142 is substantially and uniformly distributed in the wicks 142 This desirably allows for generally uniform impregnation of the wicks 142.
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Furthermore, the manifold assembly 220 in some embodiments may define an outlet region 242, which generally encompasses at least a downstream portion of the channels or gutters 222 from which the resin 214 exits. In some embodiments, at least a portion of the channels 222 disposed in the outlet region 242 has an increased area in a flow direction 244 of the resin 214. The increased area allows for further diffusion and distribution of resin 214 as resin 214 flows through manifold assembly 220, further allowing for a substantially uniform distribution of resin 214 on wicks 142.
As further illustrated in Figure 3A and Figure 3B, after flowing through manifold assembly 220, resin 214 can flow through gate passage 270. Gate passage 270 is positioned between manifold assembly 220 and impregnation zone 250, and is provided to flow resin 214 from manifold assembly 220 so that resin 214 covers wicks 142. In this way, resin 214 exits manifold assembly 220, such as through outlet region 242, as shown it may enter gate passage 270 and flow through.
When exiting manifold assembly 220 and passage n IMPI ^ <sup>ζ 1</sup> ínjtttuto μιχκλνο
Say LA NORITY INDUSTRY!
of gate 27 0 of matrix 150 As shown in Figure 3A, resin 214 contacts wicks 142 that pass through matrix 150. As discussed above, resin 214 can substantially and uniformly cover the wicks 142, due to the distribution of resin 214 in manifold assembly 220 and gate passage 270. In addition, in some embodiments, resin 214 may collide with an upper surface of each of the wicks 142, or a lower surface of each of the wicks 142, or both an upper and a lower surface of each of the wicks. 142. The initial impingement on the wicks 142 provides additional impregnation of the wicks 142 with resin 214.
As shown in Figure 3A, coated rovings 142 are traversed in the direction of travel 282 through impregnation zone 250, which is configured to impregnate rovings 142 with resin 214. For example, as shown in In Figure 3A and Figure 3C, the wicks 142 are traversed over the contact surfaces 2 52 in the impregnation zone. The collision of the rovings 142 on the contact surface 252 creates sufficient shear stress and pressure to impregnate the rovings 142 with the resin 214 coating the rovings 142.
In some modalities, as shown in the
<img file="MX349378B_D0015.tif" />
Figure 3A, impregnation zone 250 is defined between two spaced opposed plates 256 and 258. First plate 256 defines a first internal surface 257, while second plate 258 defines a second internal surface 259. Contact surfaces 252 can be defined at or extend from both of the first and second internal surfaces 257 and 259, or only one of the first and second internal surfaces 257 and 259. Figure 3C illustrates a second plate 258 and the various contact surfaces thereon that form at least a portion of the impregnation zone 250 in accordance with these embodiments. In exemplary embodiments, as shown in Figure 3A, contact surfaces 252 may be alternately defined on the first and second surfaces 257 and 259 such that the wicks alternately collide with contact surfaces 252 on the first and second surfaces 257 and 259. In this way, the wicks 142 can pass the contact surfaces 252 in a sinusoidal or tortuous wave-shaped path, which improves shear stress.
The angle 2-54 at which rovings 142 traverse contact surfaces 252 may generally be high enough to improve shear stress, but not so high to cause excessive forces to break the fibers. Thus, for example, angle 254 can
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MTnUIWMDROMB 23 “¿ΗΜί be in the margin between anrnxi ^ rlainpnte, 1 ° v approximately 30 °, and in some modalities, between approximately 5<sup>or</sup> and about 25 °.
In alternative embodiments, the impregnation zone 250 may include a plurality of pins (not shown), each pin having a contact surface 252. The pins can be static, rotate freely, or be rotatably driven. In further alternative embodiments, the contact surfaces 252 and the impregnation zone 250 may comprise any suitable shape and / or structures to impregnate the wicks 142 with the resin 214 as desired or required.
To further facilitate impregnation of the wicks 142, they can also be held under tension while they are present within the impregnation matrix. The tension can, for example, range from about 5 to about 300 Newtons, in some embodiments from about 50 to about 250 Newtons, and in some embodiments, from about 100 to about 200 Newtons per wick 142 or strand of fibers.
As shown in Figure 3A, in some embodiments, a landing zone 280 may be positioned downstream of the impregnation zone 250 in the direction of travel 282 of the wicks 142. The wicks 142
<img file="MX349378B_D0016.tif" />
IMPI wrnwc muicaho
BF THE INDUSTRIAL PROPERTY can traverse through landing zone 280 before exiting die 150. As further shown in Figure 3A, in some embodiments, a face plate 290 can join the impregnation zone 250. The plate face 290 is generally configured to measure excess resin 214 from wicks 142. Thus, the openings in the faceplate 290, through which the wicks 142 pass, can be dimensioned so that when the wicks 142 pass through, the size of the openings causes excess resin to pass through. 214 is removed from the wicks 142.
The impregnation matrix shown and described above is not one but one of several possible configurations that can be employed in the present invention. In alternative embodiments, for example, the fibers can be laid out in a cross-head matrix that is positioned at an angle relative to the flow direction of the molten polymer. As the fibers move through the crosshead die and reach the point where the polymer exits an extruder barrel, the polymer is forced into contact with the fibers. It should also be understood that any other extruder design can also be employed, such as a twin screw extruder. Still further, other components can also be used optionally
<img file="MX349378B_D0017.tif" />
<sub>2S</sub> IMPI or Μππντυ muucanc • í the noriuMO rxDujnuAi to help in the impregnation of the fibers. For example, a gas jet assembly can be employed in certain embodiments to help uniformly propagate a set or strand of individual fibers, each of which can contain up to more than 24,000 fibers, across the entire width of fused strand. . This helps achieve an even distribution of strength properties on the tape. Such an assembly may include a supply of compressed air or other gas striking in a generally perpendicular fashion into the motion fiber tows passing through the outlet ports. The set of dispersed fibers can then be introduced into a matrix for impregnation, as described above.
Regardless of the technique used, the continuous fibers are oriented in the longitudinal direction (the machine direction A of the system of Figure 1) to improve the elastic limit. In addition to fiber orientation, other aspects of the tape and stretch extrusion process are also controlled to achieve the desired strength. For example, a relatively high percentage of the continuous fibers can be used in the tape to provide improved strength properties. For example, continuous fibers are typically made up of
<img file="MX349378B_D0018.tif" />
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OF THE non HMD
INDUST1UAL about 40% by weight to about 90% by weight, in some embodiments from about 50% by weight to about 85% by weight, and in some embodiments, from about 55% by weight to about 75% by weight of the tape. Also, the thermoplastic polymer (s) typically comprise from about 10% by weight to about 60% by weight, in some embodiments from about 15% by weight to about 50% by weight, and in some embodiments, from about 25% by weight. to about 45% by weight of the tape.
Furthermore, a combination of multiple continuous fiber tapes can be employed that are laminated together to form a strong, integrated structure having the desired thickness. The number of tapes used can be based on the desired thickness and strength of the profile, as well as the nature of the tapes themselves. In most cases, however, the number of tapes is from 2 to 40, in some modes from 3 to 30, and in some modes, from 4 to 25.
As noted above, the discontinuous fiber material is also embedded within a thermoplastic matrix. For example, the staple fiber material can be a long fiber reinforced thermoplastic (LFRT) or a short fiber reinforced thermoplastic (SFRT). As known to those of skill in the art, the LFRT
<img file="MX349378B_D0019.tif" />
IMPI
WWTUTO M ENCANO
Dt LA FKiMSOAD INDUmiUL can be formed by impregnating the fibers in the manner described above, and subsequently cooling the impregnated fibers and cutting them into granules having a length of about 25 millimeters or less. SFRT can be formed by simply mixing the melt of the thermoplastic polymer with the short fibers using conventional extrusion compounding methods. The relative weight percentages of the thermoplastic polymer (s) and fibers may be within the ranges previously observed. Regardless of how these are formed, at least a portion of the discontinuous fibers is oriented at an angle relative to the longitudinal direction (ie, stretch extrusion direction) to provide increased transverse strength. For example, about 10% or more, in some embodiments about 20% or more, and in some embodiments, about 30% or more of the fibers can be oriented at an angle relative to the longitudinal direction. This angle, for example, can be about 10 ° to about 120 °, in some embodiments from about 20 ° to about 110 ° C, and in one embodiment, about 90 °. This can be accomplished by intentionally orienting the fibers in the desired direction, or by randomizing.
<img file="MX349378B_D0020.tif" />
Once the continuous fiber tape is formed and the
IMPI
ΙΝΠπίΠΌ MIUCANO
OF THE PROPERTY rNDL'STWA staple fiber material can then be supplied to the stretch extrusion system of the present invention. It will also be understood that the aforementioned steps may be formed in line with profiling. In such embodiments, some of the components described and shown in Figure 2 may not be used. In one embodiment, for example, the extrudate 152 exiting the impregnation die 150 can be supplied directly to the system used to form the profiles of the present invention.
Referring to Figure 1, a particular embodiment of the system is shown in which one or more continuous fiber ribbons 12 are initially provided in a winding package on a creel 20. The creel may be an unwind creel that includes a frame provided with horizontally rotating spindles 22, each supporting a bundle. A distribution creel can also be used, particularly if it is desired to include a twist in the fibers. It will also be understood that the tapes can also be formed in line with the formation of the profile. In one embodiment, for example, extrudate 152 exiting the impregnation die 150 of Figure 2 can be supplied directly to the system used to form a profile. A
IMPI
INSTITUTO MUSGAÑO DT LA nOPIEDAO ΙΝΓ »ISTMIA · tension regulation device 40 can also be used to help control the degree of tension of the belts 12. Device 40 can include an input plate 30 that lies on the vertical plane parallel to the rotation spindles 22 of creel 20. The tension regulating device 40 may contain cylindrical bars 41 arranged in a staggered configuration so that the tapes 12 pass over and under these bars to define a wave pattern. The height of the bars can be adjusted to modify the amplitude of the control voltage and wave pattern.
If desired, the tapes 12 can be heated in an oven 45 having any of a variety of known configurations, such as an infrared oven, convection oven, etc. During heating, the fibers are oriented unidirectionally to optimize heat exposure and maintain uniform heat throughout the entire profile. The temperature to which the tapes 12 are heated is generally high enough to soften the thermoplastic polymer to a degree that the tapes can bond together. However, the temperature is not that high to destroy the integrity of the material. For example, the temperature may range from about 100 ° C to about 300 ° C, in some modes of
IMPI
ΙίβηΜΌ MÜUCANQ roumui about 110 ° C to about 275 ° C, and in some embodiments, from about 120 ° C to about 250 ° C. In a particular embodiment, for example, an acrylonitrile-butadiene-styrene (ABS) is used as the polymer, and the tapes are heated to or above the melting point of ABS, which is about 105 ° C. In another embodiment, polybutylene terephthalate (PBT) is used as the polymer, and the tapes are heated to or above the melting point of PBT, which is about 224 ° C.
When heated, the continuous fiber tapes 12 may be provided in a consolidation matrix to aid in bonding different tape layers together, as well as for initial profile shaping and alignment. Referring to Figure 1, Figure 4, and Figure 5, for example, one embodiment of a consolidation matrix 50 for use in forming a hollow profile is shown in more detail. Although referred to herein as a single die, it should be understood that the consolidation die 50 may in fact be formed from multiple individual dies (eg, face plate dies). In this particular embodiment, the consolidation matrix 50 receives a first layer (or laminate) 12a of continuous fiber ribbons and a second layer (or laminate) 12b of continuous fiber ribbons.
<img file="MX349378B_D0021.tif" />
IMPI • βτπυτο MMiCANC
Dt U nOHEÜAD iNtxmui continuous fiber at one input end<sub>T</sub> T, ace tape<sub>F</sub>s within each layer are joined together and guided through the channels (not shown) of the matrix 50 in an A direction. The channels can be provided in any of a variety of orientations and arrangements to result in the desired reinforcement scheme . In the illustrated embodiment, for example, layers 12a and 12b are initially separated from each other in the vertical direction. As they pass through the channels of the matrix 50, the widths of the layers 12a and / or 12b optionally have tapes to help prevent pressure wedges, and keep the continuous fibers aligned and free from twisting. Within matrix 50, the tapes are generally held at a temperature at or above the melting point of the thermoplastic matrix used in the tape to ensure proper consolidation.
Although not specifically shown in Figure
1, Figure 4, and Figure 5, a mandrel may also be provided within the consolidation die 50 to help guide the laminates 12a and 12b into contact with each other on at least one side of the profile. In the illustrated embodiment, for example, a side portion 57 of the first layer 12a and a side portion 53 of the second layer 12b are angled so that they can contact each other and form one side of the hollow profile. However, the other
<img file="MX349378B_D0022.tif" />
IMPI
MEXICAN UWHTUTO
OF THE RNCXTTUAL ETHNICITY The side of the profile is typically left open within the consolidation matrix 50 so that the discontinuous fiber material can be subsequently applied to the interior of the profile in the stretch extrusion die. Of course, in those embodiments where the discontinuous fiber material is not applied within the hollow profile, the consolidation die 50 cannot be used at all since the entire profile can optionally be formed within the stretch extrusion die.
When in the desired position, layers 12a and 12b of the continuous fiber material are pulled into a stretch extrusion die 60. It is generally desired that the layers be allowed to cool somewhat after exiting the consolidation die 50 and before entering the stretch extrusion die 60. This allows the consolidated laminate to maintain its initial shape before advancing further through the system. Such cooling can be accomplished by simply exposing the layers to ambient atmosphere (eg, room temperature) or through the use of active cooling techniques (eg, water bath or air cooling) as is known in the art. In one embodiment, for example, the air within the layers (for example, with an air ring). Cooling between these phases, however, can generally occur
IMPI
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Dt THE INDOSTUAL TAKE »for a short period of time to ensure that these layers are still soft enough to conform. For example, after exit from consolidation matrix 50, the layers may be exposed to the environment for only about 1 to about 20 seconds, and in some embodiments, from about 2 to about 10 seconds, before entering second matrix 60. .
The configuration of the stretch extrusion die 60 depends in part on the desired shape and properties of the resulting profile. For hollow profiles, for example, the stretch extrusion die often contains a mandrel within it so that the fiber material flows between the inner surface of the die and the outer surface of the mandrel to form the desired shape. Solid profiles, however, are typically formed without a mandrel. Furthermore, although referred to herein as a single die, it should be understood that the stretch extrusion die 60 may be formed from multiple individual dies. In fact, the stretch extrusion die may preferably employ a first die section in which the discontinuous material is supplied and a second die section in which the continuous fiber material is formed. In Figure 4 and Figure 5, for example, a first matrix section 62 is used which supplies and forms the discontinuous fiber material 61 and a second matrix section 64 is used which forms the continuous fiber layers 12a and 12b.
IMPI • «Mexican wall OF 14 INDUSTRIAL PROPERTY
The particular manner in which the staple fiber material 61 is provided to the first die section 62 is shown in more detail in Figure 6, Figure 7, and Figure 8. As shown, a staple fiber material 61 is entered into the first die section 62 and is curved in its interior cavity. Although not required, a curved inlet allows the staple fiber material 61 to gradually flow in an A direction and toward a die outlet 67. In such embodiments, the angle β at which the discontinuous fiber material is provided relative to the flow direction A of the continuous fiber layers 12a and 12b may generally vary, although typically it is about 45 ° or more, in some modalities approximately 60 ° or more, and in some modalities, from approximately 75 ° to approximately 90 °. In certain cases, a non-perpendicular flow angle can be advantageous as it reduces and overcomes the back pressure in the matrix that can be caused by the high pressure flow of the discontinuous fiber material, sometimes leading to unwanted back flow. The angled entry orientation of the
LMPi Muicano m La noniDAD iNournuAi with its configuration
<img file="MX349378B_D0023.tif" />
The likelihood of dotted fiber, in curved combination, can also reduce static (dead spots) from forming within the matrix, which can lead to resin degradation, fiber immobilization or breakage.
As the first die section 62 enters, the discontinuous material 61 also flows over a mandrel 68. The mandrel 68 can be supported in a cantilevered manner so as to resist the forward force of the continuous material being pulled around and over the mandrel. Furthermore, although the entire mandrel is not shown herein, it is to be understood that it may nevertheless extend into the aforementioned consolidation matrix 50 to aid pre-formation of the continuous fiber material in the manner described above. Regardless, mandrel 68 shown in Figure 6, Figure 7, and Figure 8 has multiple sections to achieve the desired profile shape. More particularly, mandrel 68 contains a first mandrel section 69 that is solid and generally rectangular in cross section. In this way, the discontinuous material 61 passes over and around the mandrel section 69 from a proximal end 71 to its distal end 73. In doing so, the material 61 assumes the shape defined between the inner surface of the first die section.
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and an outer surface 75 of the mandrel section 69, which in this embodiment, is a hollow rectangular shape.
The final shape of the continuous fiber layer is formed in the second die section 64 of the stretch extrusion die 60, over and around the second section 79 of the mandrel 68 as shown in Figure 9 and Figure 10. The second mandrel section 79 contains a U-shaped recess 103 which engages a projection 77 of the first mandrel section 69 for connection therewith. In this embodiment, the second mandrel section 79 also contains a top wall 83 and bottom wall 85 which are generally perpendicular to direction A of material flow. An upward-facing surface 91 intersects a curved edge 93 of the upper wall 83 and slopes axially in direction A. Similarly, a downward-facing surface 95 intersects a curved edge of the lower wall 85 and slopes axially in direction A. Surfaces 91 and 95 both converge at an edge 97. During profile formation, the first layer 12a of the continuous fiber material is pulled onto surface 91 and assumes the shape defined between an inner surface of the stretch extrusion die 60 and the top wall 83. The second layer 12b of the continuous fiber material is pulled over the surface 95 and also assumes the
IMPI ^ h 3 7 · βτηντο muucano, ce the moMFDAC VA— • INDUSTRIAL defines the inner surface of the stretch extrusion die 60 and the bottom wall 85. Layer 12a and 12b are also gradually pulled into contact with each other at the edge 97 to form one side of the resulting profile. If necessary, the materials can be subjected to a subsequent compression stage, such as in a landing die section (not shown), to further increase the degree of adhesion between the layers at their edges.
Within die 60, the tapes are generally maintained at a temperature above the melting point of the thermoplastic matrix used in the tape to facilitate the ability to part and intermix together with the staple fiber material. However, the temperature is not so high as to destroy the integrity of the material. For example, the temperature can range from about 100 ° C to about 350 ° C, in some embodiments from about 120 ° C to about 320 ° C, and in some embodiments, from about 150 ° C to about 300 ° C.
If desired, the resulting profile can also be applied with a top coat to enhance the aesthetic appearance of the profile and / or protect it from environmental conditions. For example, referring to Figure 1, a coating layer can be applied by
<img file="MX349378B_D0024.tif" />
IMPI mmruro MftiGAMo OF PROPERTY
INDUSTRIAL an extruder oriented at any desired angle to introduce a thermoplastic resin into a coating die 72. The resin may contain any suitable thermoplastic polymer known in the art that is generally compatible with the thermoplastic polymer used to form the profile. Suitable coating polymers can include, for example, acrylate polymers, polyvinyl chloride (PVC), polybutylene terephthalate (PBT), ABS, polyolefins, polyesters, polyacetals, polyamides, polyurethanes, etc.
Although the coating resin is generally free of fibers, it can nevertheless contain other additives to improve the final properties of the profile. Additive materials employed in this phase may include those that are not suitable for incorporation into continuous fiber or staple fiber layers. For example, it may be desirable to add pigments to the compatible structure to reduce the work load of the shaped articles, or it may be desirable to add fire retardant agents to the composite structure to improve the fire retardant characteristics of the shaped articles. Since many additive materials are sensitive to heat, excessive amounts of heat can cause them to decompose and produce volatile gases. Therefore, if a material
IMPI
9 IMSTmn · MIJÜCANO
OF HtOnnTY RK
INDUSTIUai heat sensitive additive is extruded with an impregnating resin under high heat conditions, the result can be complete degradation of the additive material. Additive materials can include, for example, mineral reinforcing agents, lubricants, fire retardants, blowing agents, foaming agents, UV resistant agents, heat stabilizers, pigments, and combinations thereof. Suitable mineral reinforcing agents can include, for example, calcium carbonate, silica, mica, clay, talc, calcium silicate, graphite, calcium silicate, alumina trihydrate, barium ferrite, and combinations thereof.
Although not shown in detail herein, the coating matrix 72 may include various features known in the art to help achieve the desired application of the coating layer. For example, cover die 72 may include an entry guide that aligns the entry profile. The coating matrix may also include a thermal mechanism (eg, hot plate) that preheats the profile prior to application of the coating layer to aid proper bonding.
After optional coating, the shaped part 15 is finally cooled using a system of
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INDUSTMAL cooling 80 as known in the art. The cooling system 80, for example, can be a vacuum gauge that includes one or more blocks (eg, aluminum blocks) that completely encapsulate the profile while a vacuum draws the hot form against its walls as it cools. A cooling medium can be supplied to the gauge, such as air or water, to solidify the profile in the correct way.
Typically vacuum gauges are used when forming the profile. However, even if a vacuum gauge is not employed, it is generally desired to cool the profile after it exits the coating matrix (or the consolidation or matrix calibration matrix if no coating is applied). Cooling can be performed using any technique known in the art, such as a vacuum water tank, cold air stream or air jet, cooling liner, an internal cooling channel, cooling fluid circulation channels, etc. Regardless, the temperature at which the material is cooled is usually controlled to achieve optimal mechanical properties, partial dimensional tolerances, good processing, and an aesthetically favorable compound. For example, if the temperature of the cooling station is very high, the
IMPI INFHTU1 * MB1CANO DELA FOUNDAD material can swell in the tool and interrupt the process. For semi-crystalline materials7<sup>1</sup> ' a<sup>r </sup>Very low temperature in the same way can cause the material to cool very quickly and not allow complete crystallization, thus jeopardizing the mechanical and chemical resistance properties of the compound. Multiple independent temperature controlled cooling die sections can be used to impart the optimal balance of throughput and processing attributes. In a particular embodiment, for example, a vacuum water tank is used to maintain a temperature of from about 10 ° C to about 50 ° C, and in some embodiments, from about 15 ° C to about 3-5 ° C. .
As will be appreciated, the temperature of the profile as it progresses through any section of the system of the present invention can be controlled to produce final desired compound properties and optimal fabrication. Any or all of the assembly sections can be temperature controlled using electric cartridge heaters, circulating fluid cooling, etc., or any other temperature control device known to those of skill in the art.
Referring again to Figure 1, a traction device 82 is positioned downstream of the
<img file="MX349378B_D0025.tif" />
IMPI • Μτπυτυ MincAND
DELA INDUSTIUA MONEDAD The 80 cooling system which pulls the finish profile 16 through the system for a final calibration of the compound. Traction device 82 can be any device capable of pulling through the process system in a desired ratio. Typical traction devices include, for example, crawler tractors and oscillating tractors. If desired, one or more calibration matrices (not shown) can also be used. Such dies contain openings that are cut to the exact shape of the profile, initially graduated from a large size to the shape of the final profile. As the profile passes through it, any tendency to move or sag it is counteracted, and it is pushed back (repeatedly) into its correct shape. Once dimensioned, the profile can be cut to the desired length at a cutting station (not shown), such as with a cut-off saw capable of cross-cutting.
The resulting profile 16 is shown in greater detail in Figure 11. As illustrated, the profile 16 generally has a hollow rectangular shape. An inner layer 4 is formed by the discontinuous fiber material that extends around the entire profile and defines an inner surface 5. An outer layer 6 likewise is formed by the continuous fiber material that extends
- IMPI ^ iKtnvro Mexican
OF THE RETURN Q »^! LW around the perimeter of the inner layer 4 and is placed adjacent to it. The thickness of these layers and the relative proportion of the discontinuous and continuous fiber materials can be strategically selected to help achieve a particular yield strength and transverse strength (eg, bending coefficient) for the profile. For example, higher percentages of the staple fiber material (and / or thickness) generally result in higher transverse strength, while higher percentages of the continuous fiber material (and / or thickness) generally result in higher yield strength.
To optimize these properties, the ratio of the weight of the continuous fiber layer to the weight of the discontinuous fiber layer is typically from about 0.2 to about 10, in some embodiments from about 0.4 to about 5, and in some embodiments, from about 0.5 to about 4. For example, continuous fibers can comprise from about 10% by weight to about 90% by weight, in some embodiments from about 20% by weight to about 70% by weight, and in some embodiments, from about 30% by weight to about 60% by weight of the profile. Likewise, long fibers can comprise from about 0.5% by weight to about 50% by weight, in some embodiments of
<img file="MX349378B_D0026.tif" />
4 H * TI1UIUMWCAMO niUMonuM »rwbürmu about 1% by weight to about 40% by weight, and in some embodiments, from about 2% by weight to about 30% by weight of the profile. In this regard, the thickness of the inner layer 4 can be from about 0.1 to about 2.0 millimeters, in some embodiments from about 0.5 to about 1.5 millimeters, and in some embodiments, from about 0.6 to about 1.2 millimeters, and the thickness of the outer layer 6 can be from about 0.2 to about 4.0 millimeters, in some embodiments from about 0.5 to about 3.0 millimeters, and in some embodiments, from about 1 .0 to about 2.0 millimeters. The total thickness of layers 4 and 6 can likewise be from about 1.0 to about 4.0 millimeters, and in some embodiments, from about 2.0 to about 3.0 millimeters.
Profile 16 of Figure 11 also includes a cover layer 7 that extends around the perimeter of outer layer 6 and defines an outer surface 8 of profile 16. The thickness of cover layer 7 depends on the intended function of the part, although typically it is from about 0.1 to about 5 millimeters, and in some embodiments, from about 0.2 to about 3 millimeters.
<sub>45</sub> IMPI ^
Dt ΙΑ industrial PROPERTY
In the embodiments described and shown above, the discontinuous fiber material is positioned substantially around the entire interior perimeter of the profile. However, it should be understood that this is not required, and that it may be desired in certain applications to only apply the material to specific locations that are advantageous in accordance with a particular design. An example of such a profile is shown in more detail in Figure 12. As illustrated, profile 216 generally has a hollow rectangular shape. In this embodiment, an inner layer 206 is formed by the continuous fiber material that extends around the entire profile and defines an inner surface 205. The thickness of the layer 206 can be similar to the continuous fiber layer described above. with reference to Figure 11. In contrast to the embodiment of Figure 11, however, the profile 216 does not contain a discontinuous fiber layer. Instead, the staple fiber material is located in discrete layers 204 on the top and bottom surfaces 208 and 209 of the profile 216. Such discrete placement of the staple fiber material can provide improved transverse strength in only those locations where it is necessary for a particular application. A cover layer 207 can cover the periphery of the profile 216.
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ΙΝΓΤίηίΤΟ MEXICAN <sub>τ π</sub>· _ A „di u niaHEDAO
Figure 13 and Figure 14 illustratewpwnwa iroefeirdad of the consolidation matrix 250 and the ma-k 142? eyt'illS'tÚI'Í by stretching 260 that can be used to form the profile 216. Similar to the embodiments described above, the consolidation matrix 250 in this embodiment receives a first layer 212a and a second layer 212b of the fiber material continuous at input end 256. Layers 212a and 212b are guided through the channels (not shown) of the die 250 in an A direction. As they pass through the channels, the widths of the layers 212a and / or 212b are optionally taped and connected at one side as described above. When in the desired position, the layers 212a and 212b are pulled into the stretch extrusion die 260, which employs a first die section 262, a second die section 264, and a mandrel 268 extending through Of the same. Together, each of these components helps form the continuous fiber material. More particularly, as the continuous fiber layers pass over and around mandrel 268 from its proximal and distal end, they assume the shape defined between the inner surface of the matrix 260 and an outer surface of the mandrel, which in this embodiment , is a hollow rectangular shape. The staple fiber material 281 is then fed into the third die section 280
<img file="MX349378B_D0027.tif" />
IMPI λ -7 IRSTlTUIt »MUICAMO / de u noncoAo
FNPWnUxi via an entry portion, which is typically in the form of a crosshead die that extrudes the material at an entry angle as mentioned above. In this particular embodiment, however, the discontinuous fiber material 281 splits into an upper stream 240 and a lower stream 242 within the third die section 280. As streams 240 and 242 converge in direction A of material flow and are pulled through the matrix system, they form the upper and lower discrete layers 204, respectively, of profile 216. A cover layer 207 can then be applied using a coating matrix 272 as shown.
Of course, other hollow profiles can be formed in the present invention. Referring to Figure 15, for example, another embodiment of a generally rectangular hollow profile 316 is shown in more detail. In this particular embodiment, an inner layer 304 is formed by the discontinuous fiber material that extends around the entire profile and defines an inner surface 305. The thickness of layer 304 may be similar to the discontinuous fiber layer described above with reference to Figure 11. Contrary to the embodiment of Figure 11, however, profile 316 does not contain a continuous fiber layer around the periphery
<img file="MX349378B_D0028.tif" />
profile
Instead the material of
IMPI iwnTvro mexicaro BE LA monEBAD IWUIWIM continuous fiber se ^ pw * »**** ·· provides as a discrete vertical layer 3 06a and a horizontal layer 306b inside the interior of the 316 profile. A covering layer 307 is similarly provided to extend around the periphery of inner layer 304 and defines an outer surface 308 of profile 316.
Still another embodiment of a hollow profile is shown in Figure 16. In this embodiment, the profile 416 has a generally L-shaped cross section. An inner layer 406 of the L-shaped profile 416 may include the continuous fiber material and An outer layer 404 may include the staple fiber material. The discrete layers 409 of the discrete continuous fiber material can also be employed. Furthermore, a cover layer 407 may extend around the entire periphery of the profile 416 and defines an outer surface 408 thereof.
In addition to hollow profiles, the unique method and system of the present invention can also be used to form solid profiles. One embodiment is a solid U-shaped or C-shaped profile 516 as shown in Figure 17. In this particular embodiment, an inner layer 506 of the profile 516 can include the continuous fiber material and an outer layer 504 can include the staple fiber material. The thickness and relative weight percentages for
<img file="MX349378B_D0029.tif" />
IMPI
INSTITUI · mBican MIAHIOHBMD INDUSTRIAL each layer can be found within the margins described above with respect to the modality shown in Figure 11. A covering layer 507 can also extend around the entire periphery of the profile 516 and defines an external surface 508 Of the same. Still another suitable solid profile has a generally rectangular shape as shown in Figure 18. In this embodiment, the profile 616 contains a base layer 604 that is typically formed from the discontinuous fiber material and adjacent outer layers 606 thereof that are typically formed from the continuous fiber material. Still another embodiment of such a profile is shown in Figure 20 in the form of an I-beam. In this particular embodiment, profile 716 may include an inner layer 704 formed from the staple fiber material and outer layers 706 formed from the staple fiber material.
As will be appreciated, the particular profile embodiments described above are merely exemplary of the numerous designs that are possible by the present invention. Among the various possible profile designs, it should be understood that additional layers of continuous fiber material and / or staple fiber material may be employed in addition to those described above. In addition, the so ΐΜΠπυτο MBUCANo
DI U KOttlDAD CV-yimodalities described in the above are generally considered linear profiles to the extent that they have a cross-sectional shape that is substantially the same throughout the entire length of the profile. It should be understood, however, that the profiles can also be formed in the present invention, having a varied cross-sectional shape, such as curved, crooked etc.
Although no particular design is limited, the profiles of the present invention can achieve improved strength properties as referred to above. For example, the profiles can exhibit a relatively high bending coefficient and maximum flexural strength (in the transverse direction) compared to profiles having the same shape and size, but lacking the selective staple fiber reinforcement of the present invention. The term flexural coefficient generally refers to the ratio of stress to reinforce bending deformation (units of force per area), or the tendency of a material to bend. It is determined from the slope or stress-strain curve produced by the three point bending test (such as ASTM D790-10, Procedure A or ISO 178). For example, the profile of the present invention may exhibit a bending coefficient of approximately 2 Gigapascals (GPa) or more, in some
<img file="MX349378B_D0030.tif" />
IMPI tírnTUTO MíSUCAN · m INDUITUAL r & oncDAD modes from approximately 2 to approximately 25 GPa, in some modes from approximately 4 to approximately 20
GPa, and in some embodiments, from about 5 to about 15 GPa. Furthermore, the maximum flexural strength (also known as the coefficient of rupture or flexural strength) can be about 12 Megapascals (MPa) or more, in some embodiments from about 15 to about 50 MPa, and in some embodiments, from about 20 to about 40 MPa. The term maximum flexural strength generally refers to the maximum stress achieved in a stress-strain curve produced by a three point bending test (such as ASTM D7 90-10, Procedure A or ISO 178) in the direction transverse to room temperature. The ability of the material to withstand an applied stress in the transverse direction of the failure is represented. The ratio of the bending coefficient to the maximum bending strength is also controlled to achieve a balance between the transverse strength and coefficient. For example, the ratio may range from about 50 to about 2,200, in some embodiments from about 100 to about 1,000, in some embodiments from about 200 to about 800, and in some embodiments, from about 250 to about 1,000.
<img file="MX349378B_D0031.tif" />
IMPI iwsrmrro mixkan · M INDUSTRIAL PROPERTY about 600.
The profile can also have a very low void fraction such as about 3% or less, in some embodiments about 2% or less, and in some embodiments, about 1% or less. The void fraction can be determined in the manner described above, such as using a resin burn test in accordance with ASTM D 2584-08.
The present description can be better understood with reference to the following example.
EXAMPLE
Continuous fiber tapes were initially formed using an extrusion system as substantially described above and shown in Figure 2 and Figure 3. The fiberglass rovings (E-glass, 2200 tex) were used for the continuous fibers. with each individual tape containing three (3) strands of fiber. The thermoplastic polymer used to impregnate the fibers was acrylonitrile butadiene styrene (ABS), which has a melting point of approximately 105 ° C. Each tape contained 60% by weight of glass fibers and 40% by weight of ABS. The resulting tapes had a thickness of 0.2 to 0.4 millimeters and a void fraction of less than 1%.
<img file="MX349378B_D0032.tif" />
Once formed, the tapes were fed into a stretch extrusion / extrusion line operating at a speed of 1,524 meters per minute (5 feet per minute). Before consolidation, the tapes were heated in an infrared oven (power setting 160). The heated tapes were then delivered in a consolidation die having a U-shaped channel that received tapes and consolidated them together while forming the initial shape of the profile. Inside the matrix, the tapes remained at a temperature of approximately 121 ° C, just before the ABS matrix melting point. After consolidation, the resulting laminate was slightly cooled with ambient air. The laminate was then passed through the stretch extrusion die as shown in Figure 1. The long fiber granules were applied to the inner section of the U-shaped profile at 246 ° C. The resulting part was fed into a 0.254 cm (1 inch) landing section to impart the final solid U-shape and cooled using an oil-cooled dimension unit that set a temperature of approximately 26 ° C. It then used air cooling to complete the cooling process. The profile had a thickness of approximately 3.2 millimeters and a width of approximately 40 millimeters.
<img file="MX349378B_D0033.tif" />
IMPI imilWIU MKICANO Industrial M u ntoriEDAo
Ten (10) different U-shaped profile samples were formed as described above with different amounts of continuous fibers and long fibers. The amount of long fibers varied by using different percentages of long fibers in the granules, ranging from 0% by weight to 40% by weight, and the amount of continuous fibers varied by using different numbers of tapes, ranging from 2 to 7. The The manner in which each sample was formed is reflected below in Table 1.
Table 1
<td>Sample</td><td>Long Fibers in Granules (% by weight)</td><td>Number of Continuous Fiber Tapes</td><td>Weight Ratio of Continuous Fiber Material to Long Fiber Material</td>
<td> 1</td><td> 0</td><td> 7</td><td> —</td>
<td> 2</td><td> 20</td><td> 2</td><td> 1.21</td>
<td> 3</td><td> 20</td><td></td><td> 1.99</td>
<td> 4</td><td> 20</td><td> 4</td><td> 3.20</td>
<td> 5</td><td> 30</td><td> 2</td><td> 0.72</td>
<td> 6</td><td> 30</td><td> 3</td><td> 1.54</td>
<td> 7</td><td> 30</td><td> 4</td><td> 2.34</td>
<td> 8</td><td> 40</td><td> 2</td><td> 0.57</td>
<td> 9</td><td> 40</td><td> 3</td><td> 0.95</td>
<td> 10</td><td> 40</td><td> 4</td><td> 1.52</td>
To determine the strength properties of the profile, a three point bending test was performed in accordance with ASTM D790-10, Procedure A. A transverse edge of the profile was supported with a fixture, and the
IMPI ^ <sup>0</sup> IMTRUTO MBUCAN ·
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The load of the lastron meter was applied to the free edge of the U-shaped profile. The following equation was used to calculate the maximum tension load on the part: Maximum tension load = (6 * w * r where P „,<sub>M</sub>. = maximum load, L = length of the leveling arm, ir = width of the sample, t = thickness of the sample. The strength properties of the samples are set forth below in Table 2.
Table 2
<td>Sample</td><td>Maximum Flexural Strength (MPa)</td><td>Bending Coefficient (GPa)</td><td>Ratio of Bending Coefficient to Bending Strength</td>
<td> 1</td><td> 11.73</td><td> 26.6</td><td> 2268</td>
<td> 2</td><td> 35.39</td><td> 6.2</td><td> 175</td>
<td> 3</td><td> 32.36</td><td> 8.7</td><td> 269</td>
<td> 4</td><td> 32.76</td><td> 13.7</td><td> 418</td>
<td> 5</td><td> 30.94</td><td> 7.87</td><td> 254</td>
<td> 6</td><td> 27.17</td><td> 13.55</td><td> 499</td>
<td> 7</td><td> 26.57</td><td> 14.87</td><td> 560</td>
<td> 8</td><td> 27.93</td><td> 11.82</td><td> 423</td>
<td> 9</td><td> 26.57</td><td> 13.75</td><td> 518</td>
<td> 10</td><td> 29.66</td><td> 14.75</td><td> 497</td>
These and other modifications and variations of the present invention may be practiced by those of ordinary skill in the art, without departing from the spirit and scope of the present invention. Furthermore, it should be understood that the aspects of the various modalities may be interchanged in whole or in part. Further,
IMPI IHSTnvro MKKAHu. t> E INDUSTRIAL PROPERTY
<img file="MX349378B_D0034.tif" />
Those of ordinary skill in the art will appreciate that the foregoing description is by way of example only and is not intended to limit the invention as further described in the appended claims.
- IMPI
IMS UTUTO MEJtICAA *
FROM A NOMEDAO, INDUSTRY!
Contents33
55 sheets
Sheet 1 Sheet 2 Sheet 3 Sheet 4 Sheet 5 Sheet 6 Sheet 7 Sheet 8 Sheet 9 Sheet 10 Sheet 11 Sheet 12 Sheet 13 Sheet 14 Sheet 15 Sheet 16 Sheet 17 Sheet 18 Sheet 19 Sheet 20 Sheet 21 Sheet 22 Sheet 23 Sheet 24 Sheet 25 Sheet 26 Sheet 27 Sheet 28 Sheet 29 Sheet 30 Sheet 31 Sheet 32 Sheet 33 Sheet 34 Sheet 35 Sheet 36 Sheet 37 Sheet 38 Sheet 39 Sheet 40 Sheet 41 Sheet 42 Sheet 43 Sheet 44 Sheet 45 Sheet 46 Sheet 47 Sheet 48 Sheet 49 Sheet 50 Sheet 51 Sheet 52 Sheet 53 Sheet 54 Sheet 55
14 members in 10 offices
Priority claims7
| Document | Office | Kind | Date |
|---|---|---|---|
| 35728910 | United States of America | P | |
| 61357289 | United States of America | – | |
| 2011041433 | United States of America | W | |
| 61357289 | – | – | – |
| PCTUS2011041433 | – | – | – |
| US20100357289P | – | – | – |
| WO2011US41433 | – | – | – |
Members14
| Document | Office | Kind | |
|---|---|---|---|
| CA2800926A1 | Canada | A1 | |
| WO2011163349A2 | World Intellectual Property Organization (WIPO) | A2 | |
| WO2011163349A3 | World Intellectual Property Organization (WIPO) | A3 | |
| CN102947078A | China | A | |
| EP2585277A2 | European Patent Office (EPO) | A2 | |
| US2013149521A1 | United States of America | A1 | |
| JP2013530855A | Japan | A | |
| KR20130088033A | Republic of Korea | A | |
| RU2013102597A | Russian Federation | A | |
| CN102947078B | China | B | |
| US9409347B2 | United States of America | B2 | |
| BR112012032181A2 | Brazil | A2 | |
| MX349378BThis record | Mexico | B | |
| CA2800926C | Canada | C |
1 legal event, as the office reported them to INPADOC
Events
| Event | Code | |
|---|---|---|
| Grant or registrationFG | FG |
Numbers
- Publication
- 349378
- Publication, DOCDB
- 349378
- Publication, EPODOC
- MX349378
- Application
- 2012014177
- Application, DOCDB
- 2012014177
- Application, EPODOC
- MX20120014177
Titles2
- English
- METHOD FOR FORMING REINFORCED EXTRUDED OR STRETCHED PROFILES.
- Spanish
- METODO PARA FORMAR PERFILES DE EXTRUIDO O ESTIRADO REFORZADOS.
Classification
- CPC, 7
- B29C70/08
- B29B15/122
- B29C70/081
- B29C70/52
- B29C70/521
- B29C70/525
- Y10T428/249921