MX199818B

Continuous production of reduced gel content hydroxylated addition polymers

Abstract

A process is disclosed for the continuous production, with reduced gel formation, of free radical addition polymers from ethylenically unsaturated monomers containing at least one free hydroxyl group such as 2-hydroxyethyl methacrylate, from about 0 to about 5% by weight of an alpha-beta unsaturated carboxylic acid such as acrylic acid or methacrylic acid, and the remainder of the monomers used are free radical addition copolymerizable compounds such as styrene, methyl methacrylate and butyl acrylate. The free radical addition polymerization is conducted at from about 150 DEG C. to about 310 DEG C. under superatmospheric pressure in the presence of one or more solvents. The solvent or the volume average of the solvent mixture has an overall calculated root mean square value of the hydrogen bonding and polar contributions of each solvent's solubility parameters in the range of from about 6 to about 15. The solvent or solvents in total have sufficient volatility under the conditions being used to conduct the polymerization such that any liquid condensate of vapor mixture forming on interior surfaces of the reactor equipment located above the surface of the monomer reactants contains at least 50 mole percent of the solvent to reduce gel formation on such interior surfaces. The process permits the continuous polymerization of the polymers over extended periods of time with reduced formation of gel particles and gel deposits.

Term

Term ended

Expired 13 October 2015, 10.9 years ago.

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29 members in 17 offices

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Priority claims
DocumentOfficeKindDate
32500194United States of AmericaA
9512836United States of AmericaW

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US5508366AUnited States of AmericaA
CA2202902A1CanadaA1
WO9611957A1World Intellectual Property Organization (WIPO)A1
AU3763695AAustraliaA
NO971818D0NorwayD0
FI971636AFinlandA
FI971636A7FinlandA7
NO971818LNorwayL
MX9702860AMexicoA
EP0787154A1European Patent Office (EPO)A1
CN1164239AChinaA
KR970707167ARepublic of KoreaA
SG50359A1SingaporeA1
JPH10511992AJapanA
AU703253B2AustraliaB2
EP0787154B1European Patent Office (EPO)B1
AT182154TAustriaT
ATE182154T1AustriaT1
DE69510813D1GermanyD1
ES2134500T3SpainT3
DE69510813T2GermanyT2
DK0787154T3DenmarkT3
GR3031056T3GreeceT3
CA2202902CCanadaC
MX199818BThis recordMexicoB
CN1083456CChinaC
NO313050B1NorwayB1
KR100350338B1Republic of KoreaB1
JP3550152B2JapanB2