Synergistic mixtures of anthranilamide invertebrate pest control agents

TITLE

SYNERGIC MIXTURES OF AGAINST

ANTHRANILAMIDE INVERTEBRES

FIELD OF THE INVENTION

This invention relates to invertebrate pest control mixtures which contain a biologically effective amount of an anthranilamide. of a oxide or salt thereof and at least one other invertebrate pest control agent, and methods of their use in controlling invertebrate pests, such as arthropods, both in agricultural and non-agricultural environments.

BACKGROUND OF THE INVENTION

The control of invertebrate pests is extremely important to achieve high crop yields. Invertebrate pest damage to crops and stored agricultural crops! 5 can significantly reduce productivity and. therefore, impose high costs on the consumer. It is also important to control invertebrate pests in forestry, greenhouse crops, ornamentals, nursery crops, stored foods and fibrous products, livestock, domestic applications, lawns, and products in 20 wood, public and animal health. Many products are marketed for these purposes and are used as a single agent or a mixed agent. However, more cost-effective and environmentally sound compositions and methods are always being sought.

It is always desirable to be able to reduce the amount of chemical agents released into the environment while ensuring effective pest control. Although combinations of pest control agents have been studied, generally no high synergistic action has been found. Synergy is described as the cooperative action of two large groups of a mixture, allowing the total effect to be greater than or longer than the sum of the effects of the two (or more) taken independently (see p. ML Yames, Y (. '? / ?. ٠ /. Plant Pathology 1964. 70. 73-80). Therefore, it is highly desirable to obtain an arthropodicidal composition which exhibits a high control effect with a concomitant reduced cost of plant production and a reduced environmental burden.

MA 28699US

WO 03, (() 1.5519 discloses ΛΖ-acyl antranilic acid derivatives of

- formula 1 as arthropodicides

٦ إ 8 دح () ك ١5 ا 820 ؛ ا 7 ؛ 'ال 1

WO 2 () 06/0 () 7595

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oil, among others, R ا es ؛ CH ؟, F, C) or Br; R- 'is ​​F, Cl, Br, 1 or CF,; R 'is 5 CF ؟, Cl, Β1' or OCflCF؟ ; R * 'is. C1-C4 alkyl; r4١١ is H or CH؟ ; and R⁵ is ('-') or Br.

SUMMARY OF THE INVENTION

This invention relates to a mixture containing a compound (a) of formula 1, 3٠b ؛ 'omoWJ4-chloiO-2-methyl-6 - [(methyla, mino) carbonylj! () Phenyl ؛ -l- (3-ch ) oro-2-py'ridiny'l) -lL-py٦'azole-5-carboxamide, a ، v-oxide or a salt thereof.

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and component (b) or component (b) is at least one invertebrate pest control agent selected from the group comprising

MA 28699US wo 2006/007595 PCT / IJS2005023Î13 (bl) on.؟ neonicotinoids;

(b2) cholinesterase inhibitors;

(b.؟) sodium channel modulators;

(b4) chitin synthesis inhibitors;

(b5) tic ecdysone agonists;

(bb) inhibitors of lipid biosynthesis;

(b7) macrocyclic lactones;

(b8) GABA dependent chloride channel blockers;

(b9)) juvenile hormone mimics;

i (؛ (b 10) ryanodine receptor ligands;

(b11) ؛ 'octopamine receptor ligands;

(b 12) transport inhibitors of mitochondria elections:

(113) neeistoxin analogues;

(bldjlepyridalyl;

؟. ؛ (bffijleflonicamid;

(b16) lapymetrozine;

(bl7) ladieldrin:

(b 18) lametaflumizone;

(b 19) biological agents; and the salts of compounds (b1) to (b1 8).

This invention also discloses a composition for controlling an invertebrate pest containing a biologically effective amount of a mixture of the invention and at least one additional component selected from the group consisting of a surfactant, a diluent. solid and liquid diluent; Said composition optionally also contains an effective amount of at least one additional biologically active compound or agent.

This invention also discloses a method of controlling an invertebrate pest comprising contacting the invertebrate pest or its environment with a biologically effective amount of a mixture or composition of the invention, as described herein.

MA 28699US wo 2006/007595 r٠C'٠T / bS2٥05 ./ (1238١. ا

This invention also discloses a spray composition, containing a mixture of the invention and a propellant. This invention also discloses a bait composition containing a mixture of) the invention; one or more food substances; optionally an attractant and optionally a humidifier.

This invention also discloses a trap device used in the fight against invertebrate pests, and which contains said bait composition and a housing adapted to receive said bait composition, where the housing has at least one dimensioned opening which allows passage. of the invertebrate pest in order to access said bait composition from a location outside the housing, and where the housing is. also suitable for placement in or near a location of potential or known activity of the invertebrate pest.

DETAILS OF THE INVENTION

As used herein, the terms contain, containing, includes, a, having or any other variation thereof. aim to cover non-exclusive inclusion. For example, a composition, a mixture, a process, a method, an article or. a device that includes a. set of elements is not necessarily limited to these elements but possibly includes other elements not expressly listed or inherent in such a composition, mixture, process, method, article or apparatus. In addition, unless otherwise specified, or denotes one or inclusive and not one or exclusive For example, a condition A or B is satisfied by one of this qua. follows: A is true (or present) and B is false, (or not present), A is false (or not present.) e) B is true (. or present), and both A and B are true ( we present).

The use of one or more is also intended to describe elements and components of the invention. This is done only for the sake of convenience and to convey a general sense of the invention. This description should be interpreted as including one or at least one and the singular also includes the plural unless otherwise specified.

The compounds, mixtures and compositions of this invention may exist as one, or more of several steoisomers. The various stereoisomers include enantiomers, diastereomers, atropisomers and geometric isomers. A person skilled in the art will realize that a stereoisomer may be more active and / or may display beneficial effects when enriched compared to others.

MA 28699US wo 2006/007595 PCT / ٧S2OO5.'O23X! 3 stereoisomers or when separated from other stereoisomers. In addition, the professional knows how to separate, enrich and / οιι selectively prepare! ' said stereoisomers. Thus, the present invention discloses a mixture consisting of a compound of formula 1, an A-oxide or a salt thereof, said compound of formula 1,, A-oxide or a salt thereof. are referred to herein as component (a): and at least one invertebrate pest control agent, which may be a compound (or a salt thereof) selected from (b1) to (b18) or a biological agent selected from (b19) and which is also referred to herein as component (b) ”. The compositions of the present invention may optionally include at least one biologically active compound or addition agent which. if present in a composition, will differ from the compound of formula 1 and component (b). These additional biologically active compounds or agents, including insecticides, fungicides, nematicides, bactericides, acaricides, growth regulators such as rooting stimulants, chemosterilants, semiochemicals. repellents, attractants, pheromones, food stimulants, other biologically active compounds or bacteria, viruses or entomopathogenic fungi. aiming 1 '؛ forming a multi-component pesticide creates an even greater range of agricultural or non-agricultural utility. These additional biologically active compounds or agents may be present as a mixture of stereoisomers, individual stereoisomers, or in optically active form.

Salts of the compounds in the mixtures and compositions of the present invention include acid addition salts, with inorganic or organic acids such as hydrobromic acid. hydrochloric, nitric, phosphoric. sulfuric, acetic, butyric, funaric. lactic, maleic, malonic, oxalic, propionic. salicylic, tartaric, 4toluenesulfonic or valeric. The salts of the compounds of the invention also include those which are formed with organic bases (for example, so pyridine or triethylamine) or inorganic bases (for example, hydrides, hydroxides or sodium carbonates. , potassium, lithium, calcium, magnesium or barium) when the compound contains an acid group such as a carboxylic acid or phenol.

Embodiments of the present invention include:

.؟. ١ Embodiment 1 A mixture containing a component (a) and a component (b), where component (a) is a

MA 28699US wo 2006/007595 a compound of formula 1, an / oxide or a salt thereof.

Embodiment 2.

Embodiment 3.

The mixture of embodiment 1 or component (b) is at least an invertebrate pest control agent selected from the group consisting of (b1) neonicotinoids, (b2) cholinesterase inhibitors and (b3) modulators ( sodium channels.

The mixture of Embodiment L where component (b) is a compound selected from (b1) neonicotinoids.

Embodiment 4.

The mixture of embodiment 3, wherein component (b) is selected from the group consisting of pyridylmethylamines such as acetamiprid and thiacloprid; nitromethylenes such as nitenpyram and nithiazine; and nitroguanidines such as clothianidin. dinotefuran, imidacloprid and thiamethoxam.

'Embodiment 5.

Embodiment -؟ a.

Embodiment ١b.

Embodiment 5e.

Embodiment 5il.

.30 Embodiment 5e.

Embodiment 6.

The mixture of embodiment 4. wherein component (b) is dinotelian liana, imidacloprid. nitenpyram, thiacloprid or thiamethoxam.

! .... c mixture of embodiment component (b) is dinotefuran.

The mixture of embodiment component (b) is imidacloprid.

The mixture of the embodiment inode component (b) is. nitenpyram.

The mixture of embodiment component (b) is thiacloprid.

The mixture of embodiment component (b) is thiamethoxam.

The mixture of the embodiment where the or the or component (b) is a compound selected from (b2) cholinesterase inhibitors.

MA 28699US

Embodiment 7.

wo 2 () 06., () 0754?

The mixture of embodiment 6 where component (b) is selected from the group consisting of organophosphates such as acephate, azinphosmethyl, chlorethoxyfos, chlorprazophos. chlorpyrifos, chlorpyrifos-nethyl, coumaplios, cyanofenphos. den٦eton-S-methyl, diazinon, dichlorvos, dimethoate, dioxabenzolbs, disulfoton, dithicrofos, fenamiphos, -fenitrothion, fonofos, isofenphos, isoxathion, malathion, methamidophos, methidathion, mipafox, oxydorcton-methidathion, miposhylate, oxydorcton-metocrotathion, parthyl phthalate, oxydorctton-metathion, parthyathion, miposhylate, oxydorcton-methocrotathion, parthyl phthalate, oxidor-metricotton , phosalone, phosmct, phosphamidon, phoxime, pirimiphos-methyl. profenofos, pyraclofos, quinalphos-nethyl e, stalprofos, lemephos, terbufos, tetrachlorvinphos. thicrofos. taaphos and trichlofon; and carbamates such as aldicarb, aldoxycarbc, bendiocaabe, benfuracarb, butocarboxime.

carbaayl, carbofuran, carbosulfan, cthiofencarb, furathiocarb, mcthiocaabe, methomyl (Laainate'U. oxamyl (Vydate 'ا, pirimicarb, propoxur, ahiodicarb, triazamate and xylyicarb.

Embodiment 8.

Embodiment 8a.

Embodiment 8b.

Embodiment 9.

The mixture of the embodiment component (b) is methomyl or oxamyl.

The mixture of embodiment component (b) is methomyl.

The mixture of embodiment component (b) is oxamyl.

The mixture of component (b) is a compound selected from (b31 modulators; sodium channels.

th achievement

7, where إ:

8. where the

1, where the

Embodiment 1 (). The mixture of embodiment 9, wherein component (b) is selected from the group consisting of pyrethroids such as allethrin, alphacypeimuthrin, betaeyfluthrin, betacypermethrin, bifenthrin, cyluthrin, cyhalothrin, cypemethrin.

MA 28699US

WO 2006./007595

PCF 1282005. () 228 3 ا deltamethrin, esenvalerate, fenfluthrin, fenpropathrin, fenvalerate. flncythrinate. gamma ،. 'yhalothrinc. lambda-cyhalothrinc, metotlulhrin, permethrin, profluthrin, resmethlin, tauluvalanate. tefluthrin, tetramethrin, tralomethrin. transluthrin and zetacypemcha٠ine; non-ester pyrethroids such as etofenprox, flulenpiOX, halfenprox, protrifenbute and silalluolen; oxadiazines such as indoxacarb; and 'natural pyrethrins such as einerin 1 and cinerira II, jasmoline 1 and jasmoline 11, pyrcthrin 1 and pyrethrin II.

Mode of realization !. The mixture of embodiment 10, where component (b) is deltamethrin, indoxacarb, or lambda-cyhalothrin.

Embodiment 11a. The mixture of embodiment 11, where component (b) is deltamethrin.

Embodiment 11 b. The mixture of embodiment 11, where component (b) is indoxacarb.

Embodiment 11 c. The mixture of embodiment 11, where component (b) is lambda-cyhalothrin.

Embodiment 12. The mixture of embodiment 1, wherein component (b) is a compound selected from (b1) chitin synthesis inhibitors.

Embodiment 13. The mixture of motle ، embodiment 12, where component '(b) is selected from the group comprising bistrifluron, buprofezin, chloafluazuron.

cyromazinc, diflubenzuron, l liacycloxuron.

flufenoxuron, hexaflumuron, luLenuron, novaluron. noviflumuron, penfluron, tellubenzuron and triflumuron.

Embodiment 14. The mixture of the mode ، le i'éalisat'i ، ١n! 3. or component (b) is hexallumuron or novaluron.

Embodiment 14a. The mixture ، read embodiment 14. wherein component (b) is hexaflumuron.

Embodiment 14b. The mixture of embodiment 14, where the

MA 28699US wo 200 (, / 0 () 7545 component (b) is novaluron.

Embodiment 15. The mixture of Embodiment 1. or component (b) is a compound selected from (b5) ecdysone agonists.

Embodiment 16. The blend of Embodiment 15, where component (b) is selected from. group consisting of azadirachtin, cl) romafenozide, haloenozide, methoxyfenozide and tebufenozide.

Embodiment 17. The (mixture of embodiment 1. wherein component iO (b) is a compound selected from (b6) lipid biosynthesis inhibitors.

Embodiment 18. Th e mixture of embodiment 17. wherein component (b) is spi romesifen or spirodiclofen.

Embodiment 19. The mixture of. Embodiment 1. wherein component (b) is Lin a compound selected from (b7) macrocyclic lactones.

Embodiment 20. The mixture of embodiment 19, wherein component (b) is selected from the group consisting of spinosade, abamectin, avenu ectin, dorameetine, 2 (1 enaamectin, eprinoniectinc, ivermectin, milbemectin, milbemycin oxime. Moxidectin , nemadectin and selamectin.

Embodiment 21. The mixture of embodiment 2 (), where component (b) is spinosade or abamectin.

Embodiment 2 la. The mixture of embodiment 21- where component (b) is spinosade.

Embodiment 21 b. The mixture of embodiment 21. wherein component (b) is abamectin.

Embodiment 22. The mixture of embodiment 1, where component (b) is a compound selected from (b8) GABA dependent chloride channel blockers.

Embodiment 2.3. The mixture of embodiment 22, wherein component (b) is selected from the group consisting of

MA 28699US wo 2006-007595

CT / US2OO5 / O238 endosulfan.

ethiprole, fipronil and

Method of implementation 24.

Embodiment 25.

Embodiment 2 (7.

'Embodiment 27.

Embodiment 271.

Embodiment 27b.

Embodiment 28.

acetoprol, vaniliprole.

The mixture of embodiment 23. where component (b) is fipronil.

The mixture of embodiment 1, or component (b) is a compound selected from (b9) juvenile hormone mimetics.

The blend of embodiment 25. wherein component (b) is selected. from the group comprising epofenonane, fenoxycarb, hydroprene. lmaoprene. methoprene, pyriproxyfcne and triprene.

The mixture of embodiment 2 (, ١ where component (b) is fenoxycarb or. methoprene.

The mixture of embodiment 27, component (b) is fenoxycarb.

The mixture of embodiment 27. component (b) is methoprene.

The mixture of 1١٦ (') of realization 1, or the where the

Embodiment 29.

where the c (imposing (b) is a compound selected from (b 10) ryanodine receptor ligands.

The mixture of embodiment 28 or component (b) is selected from the group consisting of ryanodine and other products of Ryania speciosa Vahl. (Flacourtiaceae) which are receptor ligands for ryanodine, anthranil imides and phthalic acid shyants like flubendiamide.

Mode of realization 30.

Embodiment 3 1.

Mode of realization 3 1 a.

The mixture of embodiment 1, where component (b) is a compound selected from (b11) loctopamine receptor ligands.

The mixture of Embodiment 30. wherein component (b) is amitraz or chlortlimeform.

! ... c mixture of embodiment 3!, where component (b) is amitraz.

MA 28699US wo 2006..1) 07595

Embodiment .32.

The mixture of embodiment 1. wherein component (b) is a compound selected from (b 12) inhibitors of electron transport of mitochondria.

Embodiment 33.

The mixture of embodiment 32- where component (b) is selected from a group comprising aequinocyl chlorlenapyr, diafenthiuron, dicofol, fenpyroximate, hydramethylnon, rotenone, tebufenpyrad and

Embodiment 34.

enazaquin. pyridabene, tolfenpyrad.

The mixture

Embodiment 341.

Embodiment 34 ؛).

Embodiment 34c.

Embodiment 35.

of embodiment 34, where component (b) is chlorofnapyr, hydramethylnon or pyridabene.

The mixture of embodiment .34, component (b) is chlorienapyr.

The mixture of embodiment 34. component (b) is hydramethylnon.

The mixture of embodiment 34. component (b) is pyridabene.

The mixture of embodiment 1.

where the where the

Embodiment 36.

Embodiment 37.

Embodiment 38.

Embodiment 39.

Embodiment 4 ().

or component (b) is a compound selected from (b 13) analogs of 1 ؛) ne cistoxin.

The mixture of embodiment 35. wherein component (b) is selected from the group consisting of bensultap. cartap, thiocyclam and thiosultap.

Mixture of the embodiment 36. where component (b) is artap.

The mixture of embodiment 1. where component (b) is pyridalyl.

The mixture of embodiment 1. wherein component (b) is flonicamid.

The mixture of embodiment 1, where component (b) is pymetrozine.

Embodiment 41.

e mixture of embodiment I. where the

MA 28699US

٦ [٩8.O2؟ PCT.'US20 () component (b) is dieldrin.

Embodiment 42. The mixture of embodiment 1. where component (b) is metaflumizone.

Embodiment 43. The mixture of Embodiment I .. wherein component (b) is an agent selected from (b 19) biological agents.

Embodiment 44. The mixture of Embodiment 43 where component (b) is selected from the group consisting of Bacillus thuringiensis ssp. aizawai, Bacillus thuringiensis ssp. kurstaki, delta-endotoxins؟ tansies of Bacillus thurhrgiensis, Beauvaria bassiana, granulosis virus (CpGV and GmGV) and nuclear polyhedrosis virus (NP١7. eg Gemstar).

Embodiment 45. The mixture of Embodiment 1 where component (b) is. a compound selected from dinotefuran, inidacloprid, nitenpyram, thiacloprid, thiamethoxam, mcthorayl, oxamyl. deltamethrin, indoxacarb, lambda-cylialothin, hexallumuron. novaluron, abamectinc, spinosadc, fipronil, lenoxycarb, methoprene, amilraze. chlorfenapyr, hydramethylnon, pyridabene. cartap, flonicamid, pymetrozine and dieldrinc.

Embodiment 46. The mixture of embodiment 1. wherein component (b) comprises at least one invertebrate pest control agent of two different groups selected from (b1). (62). (6.3). (64).

(6.5), (66). (b7), (68), (69), (610), (b 11), (b 12), (613), (614), (b5), (616). (617), (618) and (619) and where any compound selected from one (.groups (61) to (bl 8) can be a bare saline ft ').

The embodiments also to be noted: are arthropodicidal compositions of the present invention containing a biologically effective amount of a mixture of embodiments I to 46 and to .5 ؛ least one additional component selected from the group consisting of a surfactant, a solid diluent, a liquid diluent, and optionally at least one compound

MA 28699US wo 2006/007595 PCT / US2OO5 / O2٠٩ “1.١

OR an additional biologically active agent. Embodiments of the invention also include methods of controlling an invertebrate pest comprising contacting the invertebrate pest or its environment with a biologically effective amount of a mixture of one of Embodiments 1 to 46. (eg, a composition described herein).

A method of bringing the invertebrate pest or its environment into contact with a biologically effective amount of. mixture of embodiment 14, 6, 7, 9, 10, 15-20. 22. 23, 25, 26. 28-33. 35, 36, 38-45 or 46.

ا () The embodiments of the invention also include a spray composition containing a mixture of one of embodiments 1 to 46 and a propellera11. A spray composition containing the mixture of Embodiment 1-4 is suitable. 6, 7١ 9. 1 (). 1 5-20.

22, 23, 25, 26, 28-33, 35, 3 (1, 38-45 or 46. Embodiments of the invention also include a bait composition containing a mixture of one of the embodiments. 1-46; one or more food substances; optionally an attractant; and: optionally a moisturizer.

should be noted a bait composition containing the mixture of ؛ node of realization .1.-4, 6, 7. 9. 10. 15-20. 22. 23, 25, 26, 2 (8-3.3. 35. 36. .38-45 or 20 46.

The embodiments of the invention also include an invertebrate pest control device, which contains said bait composition and a housing adapted to receive said bait composition, where the housing ا at least one opening sized to allow the passage of the invertebrate pest in order to access said bait composition from a location outside the housing, and where the housing is adapted to be placed in a location or near a location of potential or known activity of the invertebrate pest. Of note is a device where the bait composition contains the mixture of Embodiment 1-4, 6. 7, 9, 10. 15-20. 22. 23. 25. .١!) 26, 28-33, 35, 36, 3845 or 46.

The compound of Formula 1 can be prepared by one or more methods and variations thereof as described in World Patent Application Publication WO 03/015519. Synthetic methods of preparing heterocycles and tertiary amine ty-oxides are well known to one skilled in the art and include the oxidation of heterocycles and tertiary amines with peroxyacids such as the acid. peracetic and! '- chloroperbenzoic acid (MCPBA), peroxide

MA 28699US wo 2006/007595 PCT / US2005 / 02٠١S13 of hydrogen, alkyl hydroperoxides such as Zbutyl hydroperoxide, sodium perborate, and dioxiranes such as dimethydioxirane. These methods of preparing Aoxydcs are widely described and studied in the literature, see for example: TI .. Gilchrist in Comprehensive

Organic Synthesis, vol. 7, pages 748-750, s. V. Ley, Pergamon Press Edition; M. Tisler and B. Stanovnik in Comprehensive Heterocyclic Chemistry vol. 3, pages 18-20, A.. 1. Boulton and A. McKillop, Pergamon Press Editions; MR Grimmett and BRT Keene in Advances in Heterocyclic Chemistry, vol. 43, pages 149-161. AR Katritzky, Academic Press Editions; M. Tisler and B.

It) Stanovnik in Advances in Heterocyclic Chemistry, vol. 9, pages 285-291. AR Katritzky and A.. 1. Boulton, Editions Academic Press; and G. w. H. Cheeseman et E. s, (. ؛. Werstiuk in Advances, '7? Heterocyclic Chemistry, vol. 22, pages 390-392, AR Katritzky and A.. 1. Boulton, Editions Academic Press.

! 5 The control agent for invertebrate pests of groups (bl) ٠ (1,2), (b3), (174), (b5), (b6), (b7), (b8). (69), (bl ()), (bl 1), (bl2) ١ (1,13), (114), (bl5), (b 16), (b 17) and (1,18) is described in published patents and scientific journals. Most of the compounds of groups (b1) to (b 18) and biological agents of group (b.19) are marketed as active ingredients in products for the control of invertebrate pests. These compounds and biological agents are described in treatises such as The Pesticide Manual, 13th edition, c. D. s. Thomlin (Ed.), British Crop Protection Council, Surrey, CK. 2 () 03. Some of these groups are described further below.

Neonicotinoids (group (bl))

All neonicotinoids act as agonists of the nicotinic acetylcholine receptor in the central nervous system of insects. They cause excitement of the nerves and eventual paralysis, leading to death. Due to the action of neonicotinoids, there is no cross resistance to conventional classes of insecticides such as carbamates, organophosphates and pyrethroids. A study of neonicotinoids is described in Pestology 2003, 27, pages 60-63; Annual Review of Entomology 2003,؟ ؛ ي, pages 339-364; and references cited therein.

Neonicotinoids act as contact poisons and ingestion poisons, combine systemic properties with relatively low application rates, and are relatively non-toxic to vertebrates. This

MA 28699US wo 2 () () 6.07595 ؛ 'CTI 82 () 05,1) 235 ا اً group includes many compounds, including pyridylmethylamrnes such as acetamiprid and thiacloprid; nitromethylenes such as nitenpyram and nithiazine; nitroguanidines such as clothianidin. dinotefuran. imidacloprid and thiamethoxam.

Cholinesterase inhibitors (group (b2))

Two chemical classes of compounds inhibit cholinesterase; one class represents organophosphates and the other represents carbamates. Organophosphates involve phosphorylation of the enzyme, while carbamates involve reversible carbamylation of the enzyme. The organophosphates include acephate, azinphos-methyl, chloethoxyfos. chlorprazophos, chlorpyrifos. chlorpyrifos-methyl, coumaphos. cyanofenphos, demeto-S-methyl, diazinon, dichlorvos, dimethoate, dioxabenzofos. disulfoton. dithicrofos, fenamiphos, fenitrothion. fonofos. isofenphos, isoxathion, malathion, methamidophos, methidathion, mipafox, monocrotophos, oxydemetoimethyl, parathion. parathion-methyl. phorate, phosalone, phosmet, pbosphamidon. phoxime, pirimiphos-methyl. profenofos, pyraclofos. quinalphos-methyl, sulprofos, temephos, terbufos, tetrachlorvinplros, thicrofos, triazophos and trichlofon. The carbamates include aldicarb, aldoxycarb, bendiocarb, benfuracarb, butocarboxim. carbaryl. 20 carbofuran, carbosulfan, ethiofencarb, furathiocarb, methiocarb. methomyl (!., annate ''), oxamyl ('Vydate), pirimicarb, propoxur. thiodicarb, triazamate and xylylcarhe. A general review of the mode of action of insecticides is presented in Insecticides with Novel Modes of Action: Mechanism and Application. 1. Ishaaya, et al (Edition), Spmiger: Berlin. 1998.

Sodium channel modulators (group (b3١)

Insecticidal compounds acting as sodium channel modulators disrupt the normal functioning of voltage-dependent sodium channels in insects, causing rapid paralysis or. shock after the application of these insecticides. Studies known! ' insecticides which target sodium channels (nerve membranes are: published, for example, in Toxicology 2002, 171. pages 359; Λ, 'ν (Management.؟ d. 2001, 57, pages 153-164: and references cited therein. The sodium channel modulators are grouped together based on the similarity of their ؛ ' Fourth class clinical structure including pyethroids, non-ester pyrthroids, oxidiazines, and natural pyrethrins. 'Pyethroids include al lethrinc. alphacypcmrethrinc. betacyfluthrin. betacypermethrin.

MA 28699US wo 2006/007595 PCT / US2OO5 / O2. ؛ ١ ، I3 bifenthrin, cyfluthrin. cyhalothrin, cypermethrin, deltamethrin, esfenvalerate, fenfluthrin, fenpropathrin, fenvalerate, flucythrin, gammacylialothrin, lambda-cyhalothrin, metofluthrin, permethrin, profluthrin. resmethrin. taufluvalinate, tefluthrin, tetramethrin-tralomethrin, transfluthrin and zetacypermethrin. Non-ester pyrethroids include etofenprox, flufenprox, halfenprox, protrifenbute, and silafluofen. Oxadiazines include indoxacarb. Natural pyethrins include Cinerin 1, Cinerin IL, Jasmolin 1, Jasmolin II, Pyrethrin 1, and Pyrethrin II.

Other groups of insecticides

Chitin (b4) synthesis inhibitors include bistrifluron.

buprofezin. chlorfluazuron, cyi'omazine, diflubenzuron, flucycloxuron, flufenoxuron. hexaflurauron, lufenuron, novaluron, noviflumuron, penfluron, teflubenzuron and triflumuron.

Agonists of ('ecdysone (b5) include azadirachtin, chrontafenozide, halofenozide, methoxyfenozide and tebufenozice.

Lipid biosynthesis inhibitors (bb) include spiromesifen and spirodiclol'en.

Macrocyclic lactones (b7) include spinosade, abamectin. avermectin, doramectin, cmamectin, cprinomectin, ivennectin.

milbemectin, milbemycin oxime, moxidectin, nemadectin and selamectin.

G AB A (bS) dependent chloride channel blockers include acetoprole, endosulfan, ethiprole, fipronil and vaniliprole.

Juvenile hormone (b9) mimetics include epofenonan, fenoxycarb, hydropene, methopene. pyriproxilene and tripene.

The ryanodine receptor ligands (b1 ()) include ryanodine and other related products of Ryania speciosa Valil. (Flacourtiaceae), anthranilides other than the compound of formula 1 and phthalic acid diamides (disclosed in .1-A-11-240857 Ct .ΙΡ-Α-2001-1.31141) such as .10 flubendiamide.

Octopamine receptor ligantls (bll) include amitraz and chlorditnefonne.

Mitochondrial electron transport inhibitors (bl2) include ligands that bind to complex 1, II or 111 sites for

MA 28699US wo 2006/007595 PCT, 'US2OO5O23S ز inhibit cellular respiration. Such inhibitors of electron transport of mitochondria include acequinocyl, chlorfenapyr, diafenthiuron, dicofol. fcnazaquine, fcnpyroximatc. hydramethylnon, pyridabcne, rotenone. tebufenpyrad and tolfenpyrad.

Analogs of ncreistoxin (b 13) include bensultap, cartap.

thiocyclam and thiosnltap.

Biological agents (b 19) include entomopalhogenic bacteria such as Bacillus thuringiensis ssp. ا ؛) ، '»ئه Bacillus thuringiensis ssp. kurstaki. encapsulated delta-endotoxins from Bacillus thuringiensis, entomopathogenic fungi such as Beauvaria bassiana, and entomopathogenic viruses such as granulosis virus (CpGV and Cm (iV) and nuclear polyhedrosis virus (NPV, eg Gemstar) .

Other insecticides, acaricides, nematicide exist many insecticides, acaricides and: nematicides 5 ؛ known, such as those disclosed in The Pesticide Manual 13^e'(' 2003 edition, including those whose mode of action is still not clearly defined and those which constitute a class of unitary compounds, including amidoflumet ('S-1955). bifenazate, chlorofenmidine, dieldrin, diofenolan, fenothiocarb, flufenerim (UR-5O7O1), metaldehyde, metaflumizone (BASF-320). لآ) methoxychlor; bactericides such as streptomycin; acaricides such as chinomethionate. clrlorobenzilate, cyhexatin, dienochlor, etoxazole, fenbutatin oxide, hcxythiazox and propargite.

The weight ratios of component (b) to the compound of formula 1. Noxide or salt thereof in the mixtures, compositions and methods of the present invention are typically 150: 1. to i: 200, preferably 150: 1 to 1:50, most preferably 50: 1 to 1:10, and most preferably 5: 1 to 1: 5. it should be noted mixtures, compositions and methods where component (b) is a compound selected from (b1) neonicotinoids and the weight ratio of component (b) to compound of formula 1, sel'-oxide or؟ salt (') thereof is 150: 1 to 1: 200. Mixtures, compositions and methods where component (b) is compost should be mentioned chosen from (b2) cholinesterase inhibitors and the weight ratio ، .lu component (b) to the compound of formula² ؛. Α'-oxide or salt thereof is 20 (.): 1 to 1: 100. Mixtures, compositions and methods should also be mentioned where component (b) is a compound selected from (b.3) sodium channel modulators and the weight ratio of component (b) to

MA 28699US wo 20 () 6: 0 () 7595 PCT ؤا&gt; ”02٠-د composed of formula !. A oxide or salt thereof is 1 () 0: 1 1:10 ا.

Also to be noted! - also mixtures, compositions and methods of the present invention where component (b) is a compound selected from (b1) neonicotinoids and the weight ratio of component ('b) to compound of formula ! ١ A-oxide or salt thereof is 10: 1 to 1:50. 11 - Also mixtures, compositions and methods of the present invention where component (b) is a compost of (b2) cholinesterase inhibitors and the weight ratio of component (b) to compound of formula 1 , A-oxide or salt thereof is 150: 1 to 1:25. It should also be noted ا () mixtures, compositions and methods of the present invention where component ('b) is a compound of (b3) sodium channel modulators and the weight ratio of component: (b) to compound of formula 1, A-oxide or salt (.the latter is from 50'1 to 1: 5.

suitable tie Signals ؛ - mixtures, compositions and methods 5 ؛ where component (b) contains at least one compound (or a salt thereof) or a biological agent from two different groups selected paimi (b1), (b2). (b3), (b4), (b5), (bb), (b7), (h), (b9), (blO), (bll), (bl2), (bl), (bl4), (bl .؟). (b 16), (b 17), (b18) and (b19).

Table 1 lists specific combinations of the compound of Formula 1 with other invertebrate pest control agents, which are illustrative of the mixtures, compositions and methods of the present invention. The first column of Table 1 mentions the group to which component (b) belongs (for example, b1 in li) first row '). The second column of the. Table 1 lists specific invertebrate pest control agents (eg, Acetamiprid in the first row). The third column of Table 1 lists a typical range of application rate weight ratios of component (b) to compound of formula 1 (e.g. ', 15 (.): 1 to 1: 200 acetamiprid to connpose of formula 1 by weight). The fourth and fifth columns 3 () respectively set forth one embodiment of a range of weight ratios and another embodiment of a range of weight ratios of application rates. Thus, for example, the first row of Table 1 specifically discloses the combination of the compound of formula أ with acetamiprid, identifies that 'acetamiprid belongs to group' (b1) of components (b), and indicates that ' Acetamiprid and the compound of formula 1 are typically applied in an UII weight ratio of 150: 1 to 1: 200: one embodiment being 10: 1 to 1: 1 () () and another embodiment citing 5: 1 to! 8

MA 28699US

١vo 2 () 06/0 () 7595

PCT / ٦JS2005-023SB

2.5: إ. The other rows of Table 1 should be interpreted similarly.

Table .1

<td>Component (b)</td><td>Agent of interest against invertebrate pests</td><td>Typical weight ratio</td><td>Preferred weight ratio</td><td>Strong weight ratio preferred</td>

<td>b ا</td><td>Acetamiptid</td><td> 11:200؛ 150:1</td><td>10: 1 to 1: 100</td><td> 5:12 1:25</td>

<td>bl</td><td>Cltliianidin</td><td>100: 1 to 1: 400</td><td> 10:12 1:25</td><td> 5:131:5</td>

<td>bl</td><td>Dinotelrane</td><td>150: 1 to 1: 500</td><td> 10:12 1:100</td><td> 5:12 1:25</td>

<td></td><td>Inidacloprid</td><td>100: 1 to 1:40 (.)</td><td> 10:12 1:25</td><td>5: 1 to 1:10</td>

<td> 1'1</td><td>Nitenpyram</td><td> 150:111:200</td><td> 10:12 1:50</td><td> 5:12 1:25</td>

<td>bl</td><td>Nithiazine</td><td> 11:200؛ 150:1</td><td> 10:12 1:50</td><td></td>

<td>bl</td><td>hacloprid</td><td>100: 1 to 1: 250</td><td> 15:12 1:30</td><td> 5:121:5</td>

<td>bl</td><td>Thianiethoxam</td><td>150: 1 to 1: 500</td><td> 20:12 1:50</td><td></td>

<td> 1,2</td><td>Methomyl</td><td>100: 1 to 1:50</td><td> 50:12 1:25</td><td>5: 1 a. 1:10</td>

<td>b2</td><td>Oxamvl</td><td>1 (1 (1-1 to 1:50</td><td>50: 1 to 1:10</td><td>ا 5: 121: 1</td>

<td> 1,2</td><td>Tbiodicarb</td><td> 200:111:100</td><td> 150:12 1:25</td><td> 50:12 1:5</td>

<td>b2</td><td>'rriazatnate</td><td> 200:111:100</td><td> 150:12 1:25</td><td> 50:12 1:5</td>

<td> 13</td><td>Bifcntlirine</td><td>100: 1 to 1:10</td><td>1: 5 to ؛: 50</td><td> 10:12 1:1</td>

<td>b3</td><td>Deltamethrinc</td><td>50: 1 to 1: 500</td><td> 25:12 1:50</td><td> 1():)2 1:10</td>

<td> 1,3</td><td>Esfcnvaléralc</td><td>100: 1 to 1:10</td><td> 50:12.1:5</td><td> 5:121:1</td>

<td>b.3</td><td>Idoxacarb</td><td>100: 1 to 1: 100</td><td> 25:12 1:25</td><td></td>

<td> 13</td><td>lambda-eylialotlirinc</td><td>50: 1 to 1:10</td><td> 25:12 1:5</td><td> 5:121:1</td>

<td rowspan="2">b.3 14</td><td rowspan="2">pyrethrin Bupi.oféz2 2 2c</td><td> 100:12 1:10</td><td> 50:12 1:5</td><td> 5:121:1</td>

<td> 200:12 1:150</td><td> 100:12 1:50</td><td> 50:12 1:5</td>

<td>b4</td><td>Cyromazine</td><td> 200:12 1:150</td><td> 11:50'؛ 100:1</td><td>ا 50: 121: 5</td>

<td>b4</td><td>Hexaflumuron</td><td> 200:12 1:150</td><td> 100:12 1:10</td><td> 50:12 1:1</td>

<td>b4</td><td>Lufenuron</td><td> 200:1 2 1:150</td><td> 100:12 1:50</td><td> 5():12 1:5</td>

<td> ...</td><td>Novaluron</td><td> 250:12 1:150</td><td> 100:12 1:10</td><td> 50:12 1:1</td>

<td> 1,5</td><td>Azadirachtin</td><td> 100:12 1:120</td><td> 20:12 1:10</td><td></td>

<td> 05</td><td>Meloxyfonozide</td><td>-50: 1 to 1: 750</td><td> 25:1 2 1:250</td><td>1: 1 to 1: 100</td>

<td> 1,5</td><td>Tdbuttnozide</td><td> 50:1 2 1:250</td><td> 25:12 1:150</td><td> 1:25)؛1:1</td>

<td>b (.</td><td>Spirodiclofon</td><td>200 :! at 1: 200</td><td> 20:12 1:))0</td><td> 10:1:1.1:10</td>

<td> 1,(1</td><td>Spiromesil'en</td><td> 200:12 1:200</td><td> 20:12 1:20</td><td> 10:12 1:10</td>

<td> 1,7</td><td>Abamectin</td><td> 50:12 1:500</td><td> 25:13 1:250</td><td> 5:12 1:100</td>

<td> 1,7</td><td>Emamectin benzoate</td><td> 50:12 1:10</td><td> 25:12 1:5</td><td> 5:121:1</td>

<td> 1,7</td><td>Spinosade</td><td>50: 1 to 1:10</td><td>25: 1 to 1: 5</td><td> 5:12 1:1</td>

)9

MA 28699US wo 2006'007595 PCWS2 ،) O5Z (»23« 1١

<td></td><td>Fipronil</td><td>50: 1 to 1: 100</td><td>25: 1 to 1:50</td><td></td>

<td>b9</td><td>Fenxycarb</td><td> 1:100 ١؛ 250:1</td><td>150: 1 to 1:50</td><td>50: 1 to 1:10</td>

<td> 1,9</td><td>Mcthoprcne</td><td>500: 1 to 1: 100</td><td> 250:111:50</td><td> 5():111:10</td>

<td>b9</td><td>Pyriproxyfen</td><td> 200:111:100</td><td> 100:111:50</td><td> 50:13.1:10</td>

<td>bit)</td><td>.Antliranilamidc</td><td>100: 1 he 1: 200</td><td>20: 1 to 1: 100</td><td> 1:50 3؛ 1:1</td>

<td>() ؛ B</td><td>Flubendiamide</td><td>10 (.): 1 to 1: 200</td><td>20: 1 to 1: 100</td><td> 1:111:50</td>

<td>h III</td><td>Ryanodine</td><td>100-1 to 1-17 (1</td><td>20: 1 to 1:10</td><td> 1:161:5</td>

<td>b! ا</td><td>Amitraz</td><td>250: 1 to 1: 100</td><td>100: 1 to 1:50</td><td>25: 1 to 1:10</td>

<td> 1,12</td><td>Chlorfenapyr</td><td> 1:200('؛ 1200:1</td><td>400: 1 to 1: 100</td><td> 200:16 1:50</td>

<td> 1,12</td><td>Hydramethylnon</td><td>100: 1 to 1: 500</td><td>20: 1 to 1: 100</td><td> ()؛:1:111</td>

<td> 12</td><td>Pyridaben</td><td>200: 1 to 1: 100</td><td>1 (.) (.): 1 to 1: 5 (.)</td><td> 50:13 1:10</td>

<td> 1,13</td><td>C'artap</td><td>100: 1 to 1: 1000</td><td>50: 1 to 1: 500</td><td> 5:16 1:100</td>

<td>bl4</td><td>Pyridalyi</td><td> 11:100'؛ 200:1</td><td> 100:1()1:50</td><td> 50:1(11.-10</td>

<td> 1,15</td><td>Flonicamide</td><td> 1:500 3؛ 20:1</td><td>15: 1 to!: 250</td><td> 5:13 1:50</td>

<td> 616</td><td>Pynetrozine</td><td> 1:500 1'؛ 200:1</td><td> 150:111:250</td><td>50: 1 to 1:50</td>

<td> 1,17</td><td>Dieldrin</td><td>200: 1 to 1: 500</td><td> 100:1(11:100</td><td> 25:16 1:50</td>

<td>bis</td><td>Metadiimizone</td><td> 200:1 5 1:200</td><td> 1:100 3؛ 100:1</td><td>20: 1 to 1:20</td>

<td> 1,19</td><td>٦sis ؛ e ؛. Picked us (t uti١ii</td><td>50: 1 to 1:10</td><td> 25:111:5</td><td> 5:13.1:1</td>

<td>hio</td><td>Beauvanu bassiana</td><td> 50:1()1:10</td><td>25: 1 to 1: 5</td><td> 5:13.1:1</td>

<td>b 19</td><td>NIA / (eg. Gemstar)</td><td>50: 1 to 1:10</td><td>^{25: 1 to 1: 5}</td><td>ا., = 31</td>

It should be pointed out that mixtures and compositions of this invention can be mixed with one or more biologically active compounds or agents, including insecticides, fungicides, nematicides, bactericides, acaricides, growth regulators. 5 such as rooting stimulants, chemosterilants, seniochemicals, repellents, attractants, pheromones, food stimulants, other biologically active compounds or bacteria, viruses or entomopathogenic fungi, to form a multi-component pesticide. thus generating an even wider range of agricultural and non-agricultural use. ، Thus, the present invention also relates to a mixture or a composition which contains a biologically effective amount of a compound of formula 1, an / oxide thereof or a salt thereof suitable for agricultural or non-agricultural uses ('component (a)): and 1.1 an effective amount of at least 1.111 compound (or a salt thereof) or an additional biologically active agent, selected from the group comprising (1) 1 ), (112),

MA 28699US wo 2006/007595 PC٠T / ٧S2OO5 / (٠23X دا (b3), (b4). (B-5), (b6), (b7), (b8). (B9), (blO) ١ (bl 1) , (bl2), (b! 3), (bl4) ١ (b 15).

(blb), (b17), (b18), (b19) (component (b)); and which may also contain at least one of a surfactant, a solid diluent or a liquid diluent and which optionally also contains an effective amount of at least one compound or an additional biologically active agent. If present with the mixtures and compositions of this invention, such additional, biologically active compound (or compounds) or agent (or agents) will differ from components (a) and (b), said compound (or compounds) or agent (or Additional, biologically active agents) may be an insecticide, an acaricide, a nematicide, or a fungicide. Examples of insecticides include a compound (or a salt thereof) selected from the group consisting of amidoflumet (S-1955 ), bifcnazate. chlorofenmidine, diofenolan, fenothiocarb, flufenerim (LJ 14-5 () 7 () 1). metaldehyde, methoxychlor; and examples of fungicides include acibenzolar-s-methyl. azoxystrobin, benalazy-M, benthiavalicarb, benomyl, blasticidin-S, Bordeaux mixture (tribasic copper sulfate).

boscalid, bromuconazole, buthiobate, cai-propamide, captafol, captan, carbendazim, chloroneb, chlorothalonil, clotrimazole, copper oxychloride, copper salts, cymoxanil, cyazofamid. cyflufenamidc. cyproconazole. cyprodinil, diclocymct, diclomezine. diclorane, 20 difenoconazole, dimethomorph, dimoxystrobin, diniconazole, diniconazoleM, dotline, edifenphos, epoxiconazole, ethaboxam, famoxadone, fenarimol, fenbuconazole, fenhexamid, fenoxanil, fenpiclonentilide, propimide hydroxinate, propimidate, fenpiclonentide, propidine fluazinam. lludioxonil, flumorph, fluoxastrobin, fluquinconazole, llusilazole.

flutolanil, flutriafol. folpet, fosetyl-alurninium, luralaxyl, furametapyr, guazatin, hexaconazole, hymexazol, imazalil, imibenconazole, iminoctadine, ipconazole, iprobenfos, iprodione, iprovalicarb, isoconazole, isoprothiolcylane, kasugamyin. kesoxim-methyl. mancozeb, nianèbe, mefenoxam, mepanapyrime, mepronil, metalaxyl, metconazole, .0 ا metominostrobin / fenominostrobin, metrafenone, miconazole, myclobutanil. ηέο-asozine (ferric methanearsonate), nuarimol, oryzastrobin. oxadixyl, oxpoconazolc. penconazole, pencycuron, picobenzamide, picoxystrobin. probenazole. prochloraz, propamocarb, propiconazole, proquinazid, prothioconazole. pyraclostrobin. pyrimethanil, pyrifenox, pyroquilone.

.1.5 quinoxyfen, silthiofam, simeconazole, sipconazole, spiroxamine. sulfur, tebuconazole, tetra conazole. tiadinil, thiabendazole, thifluzamide.

thiophanate-methyl. thiram, tolylfluanid, triadimefon, triadimenol.

triarimol, tricyclazole, trifioxystrobin, triflumizole, triforin, triticonazole.

MA 28699US wo 2006'007595 PCT / US2005 ، '02 .١gl3 uniconazole, validamycin. vinclozolin and zoxamide. ! ..., The compositions of this invention can be applied to plants genetically transformed to express proteins toxic to invertebrate pests (such as Bacillus thuringiensis toxin}. The effect of the invertebrate pest control compounds of this invention, exogenously applied.

may be synergistic with the toxic proteins expressed.

The weight ratios of these various mixing partners to the compound of formula 1 ... (V-oxide or salt thereof of this invention are typically 20 (): 1 to 1: 150: in one embodiment this ratio Weight is 150: 1 to 1:50, in another embodiment 50: 1 to 1:10 and in another embodiment 5: 1 to 1: 5.

The mixtures and compositions of this invention are useful for controlling invertebrate pests. In some cases, combinations with other active ingredients control invertebrate pests. 15 having a similar control spectrum but a different mode of action will be of particular benefit for resistance management.

Formulation / Utility

The mixtures of this invention can generally be used as a formulation or composition with a carrier which is suitable for agricultural or non-agricultural uses and which comprises at least one of a liquid diluent, a solid diluent or a surfactant. The ingredients of the formulation, mixture 01.1 of the composition can be selected to suit the physical properties of the active ingredients, the mode of application and the environmental factors such as the type of soil, 2.5 humidity and temperature. Useful formulations include (liquids such as solutions (including emulsifiable concentrates), suspensions, emulsions (including microemulsions and / or suspo-emulsions) and the like, which may optionally be thickened into gels. other useful formulations include solids such as dustings, powders. 3 ؛.) granules, pellets, tablets, films (including seed coating), and the like which are water-dispersible (wettable) or water-soluble,! .. the active ingredient may be encapsulated (microencapsulated) and formed also in a suspension or a solid formulation; alternatively, the entire formulation of active ingredient can be encapsulated (or overcoated),!, encapsulation, can control or delay the release of the active ingredient. The compositions of the invention may also contain

MA 28699US

١.i I ؛ 2٩ () '. PC'T / LiS2005

WO 2006.007595 optionally plant nutrients, for example a fertilizer composition containing at least one plant nutrient selected from azote phosphorus, potassium, sulfur, calcium, magnesium, iron. copper, boron, manganese, zinc and molybdenum. 11. should be mentioned 5 ries compositions consisting of at least one fertilizer composition containing at least one nutrient vegeta) selected from nitrogen, phosphorus, potassium, sulfur, calcium and. magnesium. The compositions of the present invention, which contain at least one plant nutrient, can be in the form of liquids or solids. It is worth mentioning t (, solid formulations in the form of granules, small sticks or tablets. Solid formulations containing a fertilizer composition can be prepared by mixing the mixture or composition of the present invention with the fertilizer composition with the formulation ingredients, and then preparing the formulation by methods such as granulation or granulation. extrusion. Alternatively, solid formulations can be prepared by atomizing a solution or suspension of a mixture or composition of the present invention in a volatile solvent onto a fertilizer composition previously prepared in the form of mixtures of sizes. stable, for example granules.؟, small 01.1 sticks of the 20 tablets, then evaporating the solvent, Sprayable formulations can be diluted in suitable media and used in spray volumes of about one to several hundred liters per hectare. The high content compositions can mainly be used as intermediates for other formulations.

The formulations will typically contain effective amounts of active ingredient, diluent and surfactant within the following approximate ranges which total .100 weight percent.

<td rowspan="2"></td><td colspan="3">Weight in ^,¼)</td>

<td>Active ingredients</td><td>Diluent</td><td>Surfactant</td>

<td>Granules, tablets and powders</td><td> 0.001-90</td><td> 0-99.999</td><td> ؟1-0</td>

<td>hydrodispersal and water soluble.</td><td></td><td></td><td></td>

<td>Suspensions, emulsions, solutions (including</td><td> 1-50</td><td> 40-99</td><td> 0-50</td>

<td>including emulsifiable concentrates)</td><td></td><td></td><td></td>

<td>Dust</td><td> 1-25</td><td> 70-99</td><td> 0-5</td>

<td>Pellets Cl pellets</td><td> 0.001-99</td><td> 5-99.999</td><td> 0-15</td>

<td>(. (high tax charges</td><td> 90-99</td><td> 0-10</td><td> 0-2</td>

MA 28699US wo 2006 00715 PCTÛ3S2OO5 / O2.3S3

Typical solid diluents are described in Watkins, et al. Handbook of Insecticide Dust Diluents ™ / Carriers, 2nd Edition, Dorland Books, Caldwell, New Jersey. Typical liquid diluents are described in Marsden, Solvents Guide, 2nd edition. Interscience, New York. 19-50. لآ McCutcheon's Detergents and Emulsifiers Annual, \ ١١ ج ١ ا ١١ ةعال ١ \ ١. Ct٦١ \ ١., Ridgewood. New 'Jersey, as well as Sisely and Wood, Encyclopedia؟ ،' / ا "'/ ، / ،' ، '.] ،' Shore Agents, Chemical Publ. Co,. Inc., New York. 1964, cite surfactants and recommended uses. All formulations may contain minimal amounts of additives to reduce foam, caking, corrosion, microbiological growth and the like, or thickeners to enhance viscosity.

Surfactants include, for example, polycthoxylated alcohols, polyethoxylated alkylphenols, polycthoxylated sorbitan fatty esters, dialkylsulfosuccinates. alkyl sulfates. alkylbenzenesulfonates, 1.5 organosilicones. YW-dialkyltaurates, lignin sulfonates, naphthalne formaldehyde sulfonate polycondensates, polycarboxylates, glycerol esters and polyoxyethylene / polyoxypropylene block copolymers, and alkylpolyglycosides oil the number of glucose units, denoted by degree polymerization (DP), can vary from 1 اذ) to 3 and the alkyl units can vary from C (١-C | t (see Pure ، 7 „، / Applied Chemistry 72, 1255-1264). Solid diluents include, for example, clays such as bentonite, montmorillonite, attapulgite and kaolin, starch, sugar, silica, talc, diatomaceous earth. urea, calcium carbonate, sodium carbonate and sodium bicarbonate and sodium sulfate.

Liquid diluents include, for example, water, (Y. ، Ydimethylformamide. dimethylsulfoxide, / v-alkylpyrrolidone, ethyleneglycol, polypropyleneglycol, paraffins, alkylbenzenes, alkylnaphthalenes, glycerin, triacetin, olive, castor, linseed, tung, sesame, males, peanuts, cottonseed, soybean, rapeseed and coconut, fatty acid esters, ketones such as cyclohexanone, 2-heptanone, isophorone and 4-hydroxy-4- methyl-2-pentane. acetates and alcohols such as methanol. cyclohexanol, decanol and tetrahydrofurfuryl alcohol.

Formulations useful of this invention may also contain substances known to be formulation aids, including antifoaming agents, formogens and colorants, and well known to those skilled in the art.

MA 28699US wo 2 () 06 (0 () 7595 PCTÙS2005 / 023XB

Antifoaming agents can include water-dispersible liquids including polyorganosiloxanes such as Rhodorsil) 416. Fihnogers can include polyvinyl acetates. polyvinyl acetate copolymers. polyvinylpyrrolidone-vinyl acetate copolymers. polyvinyl alcohols, copolymers of polyvinyl alcohols and waxes. Colorants can include hydrodispersible liquid dye compositions such as Pro-lzed * Colorant Red. Those skilled in the art will appreciate that this list is not an exhaustive list of formulation aids. Suitable examples of formulation aids include those listed herein and those listed in McCutcheon's 2 () (-) 1- Volume 2: Functional Materials- published by MC Publishing Company, and in PCT Publication 'wo 03 / 024222.

Solutions, including Cmulsifiable concentrates, can be prepared by simply mixing the ingredients. Dusts and powders can be prepared by mixing and. usually by grinding using a hammer mill or jet mill. Suspensions are usually prepared by liumide grinding; see, for example, US 3,060,084. Granules and pellets can be prepared by atomization of the active substance on preformed granular carriers or by agglomeration techniques. See BrowningAgglomeration, Chemical Engineering, December 4, 1967, pages 147-48. Perry's Chemical Engineer's Handbook, 4th edition, McGraw-Hill, Neu York, 1963. pages 8-.37 et seq., And wo 91 / 1.3546. Pellets can be prepared as described in US 4,172,714. Water-dispersible and water-soluble granules can be prepared as taught by US 4,144,050, US 3,920,442 and DE 3,246,493. The tablets can be prepared as disclosed in US 5,180,587. US 5,232,701 and. US 5,208,030. Films can be prepared as taught by GB 2,095,558 and US 3,299,566.

.١0 For further information on the art of formulation, see the

US 3,235,361, column 6, line 16., to column 7, line 19- and Examples 10-41; theU.S. 3,309,192, column 5, row 43, to column 7, row62, and the examples (8,! 2, 15.39.41,52.53,58, 132. 1.38-140, 162-164, 166. 167 and 169182; the US 2,891,855, column 3, line 66, to column 5, line 17, cl. 5.5 Examples 1-4; Klingman, Weed Control as a Science, Far Wiley and Sons. Inc., New York, 1961. pp. 81-96; and Hance et.al. Weed Control Handbook, 8^عال'اedition, Blackwell Scientific Publications, Oxford, 1 (389; Developments in

MA 28699US

PCT'US2O () 5O22SL٦ formulation technology, [) .ا B Public ؛ lions, Richmond, UK-, 2000.

In the following examples all weights are in percentages and all accumulations are [-) repaired in a conventional manner, active ingredients refer to the aggregate of invertebrate pest control agents consisting of a component (b) in combination with the compound of formula 1, Y-oxide or a salt thereof. A person skilled in the art can, by means of the foregoing description, fully benefit from the present invention. I-.es following examples should therefore be considered merely illustrative and not restricting the disclosure, the weight ؛ () are in percentages unless otherwise indicated.

I cgmplc ١

Wettable powder

<td>Active ingredients</td><td> '؛’65.0</td>

<td>Polyethylene glycol dodecylphenol ether</td><td> 2.0(!'</td>

<td>Sodium lignosulfonate Sodium silicoaluminate</td><td> 4.0</td>

<td>Montmorillonite (calcined!</td><td>'؛) (اا 2</td>

Example B

Granule

Active ingredients! 0 (). (؛

Attapulgite granules (low volatile Madeira, d (). () ('- ;,

0.71 / 0.30 mm, US sieve No. 25-50)

Here: !! i ': e C

Extruded pellet

Active ingredients

Anhydrous sodium follows Raw calcium lignosulphonate Sodium alkylnaphthalenesulphonate Calcium bentonite, magnesium

Example D

Emulsifiable concentrate /٠؛؛().(-؛2 Active ingredients

(, '10 .0 Mixture of soluble sulfonates! [™ and polyoxyethylene ether.

071 .. (,) 7 Isophorone

MA 28699US

WO 2006/007595

PCT'1.82 (105/02¾c

Example t;

Microemulsion

Active ingredients 5 () (ا h

Polyvinylp٠yrrolidone-vinyl acetate copolymer 30. () ؛, '؛؛

Alkylpolyglycoside 30. () ',,

Glyceryl monooleate! 5.0 ,,

Example F

Seed coating

Active ingredients (, '' polymer of plyviiylpyrrolidone-vinyl acetate

Glycolic wax

Lignosulfonal calcium

Polyoxyethylene-polyoxypropylene block copolymers, Stearic alcohol (POE 20)

Polyorgaiosilo.xane

Red dye

,/؛)20.00

<img file="MA28699B1_D0003.tif" />

Example G

Fertilizer stick

Active ingredients

Copolymer of styrene and pyrrolidone Tristyrylphenyl 1 (ethoxylate

3.80¾

2.30¾

Talc

0.80¾

, ؛؛! 5.00 (BASF) 30.00¾

38.00¾

Cornstarch

Slow Acting Fertilizer Nitrophoska Permanent 15-9 Kaolin

:؛7)10.60

Water

The compositions and mixtures of this invention are characterized by favorable metabolic and / or soil residual patterns and display activity in controlling a wide range of agricultural and non-agricultural invertebrate pests. (In the context of this disclosure, controlling invertebrate pests means inhibiting the development of invertebrate pests (including their mortality), said! () Development causing a significant reduction in bed food production or other damage ΟΙ. Ι damage due to pests; the expressions! -Datives are defined analogously). As referred to by this disclosure, the term invertebrate pest includes arthropods, gastropods and

MA 28699US wo 2006/007595 PCT / L82٠0258t5 nematodes of economic importance as pests. The term arthropod includes insects, mites, spiders, scorpions, chilopods, diplopods, woodlice, and symphylae. The term gastropod includes snails, slugs, and other stylommatophores. The term nematode includes all helminths, such as roundworms, heartworms and phytophagous nematodes (Nematoda), fluke (Trematoda), acanthocephala and tapeworms (Cestoda). Those skilled in the art will appreciate that not all compositions or mixtures are equally effective against all pests. The compositions and mixtures of this invention display activity against economically important agricultural and non-agricultural pests. The agricultural term relates to the production of field crops such as food and fiber and includes the cultivation of corn, soybeans and other vegetables, rice, ceteals (e.g., wheat, oats, barley, rye, rice, corn), edible leafy vegetables (e.g. lettuce, headed cabbage and other cabbage crops), fruit vegetables (e.g. , tomato, pepper, eggplant, crucifers and cucurbits), potatoes, sweet potatoes, grapes, cotton, fruit trees (e.g. pome fruits, stone fruits and citrus fruits), berries (berries, cherries) and other specialty crops (eg, canola, sunflower, olives). The term non-agricultural refers to other horticultural crops (e.g. greenhouse plants, nursery plants, or ornamentals that are not grown in fields), residential and commercial structures in urban and industrial settings, lawns (commercial, golf, residential, recreation, etc.), wood products, stored products, agroforestry and vegetation management, applications in public health (human) and animal health (domestic animals, livestock, poultry, non-domestic animals such as 5 () animals living in nature). In view of the spectrum of invertebrate pest control and its economic importance, protection of agricultural crops from lesions and damage caused by invertebrate pests by controlling them is covered by some examples of the invention.

Agricultural or non-agricultural pests ،؟ include larvae of the order Lepidoptera, such as armyworms, harvest moths, spanworms, and heliothinae of the noctuidae family (for example, the

MA 28699US wo 2006 / 00759.5 PCWS2OO5O23813 Fall armyworm (Spodopferafilgiperda JE Smith), beet armyworm (Spodoptera exigua Hiibner), noile cutworm (Agroiis ipsilon Hufnagel). cabbage looper (Trichoplusia Hübfier), leafy moth (Heliothis ١ &lt;ا »ع '،' ١.'غ '? /' آ Fabricius)); borers, coleophores, weaving caterpillars, cone moths, nail caterpillars, and skeletons of the family Pyralidae (e.g. European corn borer (Ostrinia nubilalis Htbner), orange worm (Amyelois transiteda Walker) ), corn rootworm (Crambos ccdiginosellus Clemens), meadow moth (Pyralidae: Crambiriae) such as meadow moth, 0 (Herpetogramma Walker)); winders, pimples, seed moths and fruit moths.؟ from the family Tortricidae (for example, the apple moth (Cydia pomonella Linnaeus), the fruit moth (Endopiza viteana Clemens), the oriental fruit moth (Grapholita molesta Busck)); and many other economically important Lepidoptera (e.g., diamondback moth (Pliitella xylostella Linnaeus), pink cotton bollworm (Pectinophora gossypiella Saunders), gypsy moth (Lymantria dispar Limiaeus)) ; nymphs and adults of the order Blattodea including cockroaches of the families Blattellidae and Blattidae (eg, oriental cockroach (Blatta orientedis Limiaeus), Asian cockroach (Blatella asahmai Mizukubo).

German cockroach (Blattella germanisa Linnaeus), ؛ cockroach ('؛ Brown hides (Supella longipalpa Fabricius), American cockroach (Periplaneta americuna Limiaeus), brown cockroach (Periplaneta bnmnea Burmeister), Madeira cockroach (Leucopiusea Fabrice madera ), the brown smoky cockroach 22- (Peripl ، net fliligiiosu Se٣٧ \ ce١ ١١'à ثد ١ ، ii١٠'à١ \ i٦e (Periplaneia australasiae Fabr.), the African ash cockroach (Nanphoeta cinerea Olivier) and the smooth cockroach (Symplocepallens Stephens)); larvae and adults of the order Coleoptera which SC feed on leaves, including weevils of the Anthribidae families. Bruchidae and Curculionidae (for example, .10 Cotton weevil (Anthonomus grandis Boheman), aquatic rice weevil (Lissorhoptrus oryzophihts Kuschel), grain weevil (Sitophitus granarius Linnaeus), rice weevil (Sitophilus orvzae) Linnaeus); annual bluegrass weevil (Listronotns macidicollis Dietz). the calender of bluegrass (Sphenophorus parvulus Gyllenhal). the cha.sse grille 1.؟ (Sphenophorus n'CT? ، 7 / n.) 'Denver's calender (Sphenophorus cicatristriatns Fahraeus)); ground fleas, cucumber leaf beetles, root insect larvae, leaf beetles, Colorado potato beetles, and leafminer flies of the

2.9

MA 286 US wo 20067007595 PC ^ ٧S2tJ05 / O23XI.3

Chrysomelidae (for example, the Colorado potato beetle (Leptinotarsa ​​decemlineata Say). the western niiiis rootworm (Diahrotica virgifera virgifera LcConte)); triongulins and other beetles of the Scaribaeidae family (for example, the Japanese beetle (Popillia japonsca 5 Newman), the oriental beetle (Anomale orientalis Waterhouse), the northern mask chafer (Cyclocephala borealis Arrow), the mask chafer southern (Cyclocephala immaculata Olivier), black grass beetle (Ataenius spvetuliis Haldeman), June beetle (Coiinis nitida Linnaeus), Asian garden beetle (Maladera Castanea Arrow), May / June beetles (Phyllophaga spp.) and European chafer (Rhizotrogus majalis

Razoumowsky)); carpet beetles of the Dermestidae family; wireworm larvae of the Elateridae family; bark beetles of the family Scolytidae and the flour beetle of the family Tenebrionidae. In addition, agricultural and non-agricultural pests include adults and larvae of the order Dermaptera, including earwigs of the family Dermaptera.

Forficulidae (eg, European earwig (Forficnla anricularia Linnaeus), black earwig (Chelisoches mono Fabricius)); adults and nymphs of orders Hemiptera and Homoptera such as bedbugs of the family Miridae. bed cicadas of the family Cicadidae, leafhoppers (eg Empoasca spp.) of the family Cicadcllidae. the fulgores of the families Fulgoroidae and Delphacidae, the membracidae of the family Membracidae. psyllids of the family Psyllidae, white flies of the family Aleyrodidae, aphids of the family Aphididae, phylloxera of the family Phylloxeridae, scale insects of the fa mily Pseudococcidae. mealybugs of the 'Coccidae- des families

Diaspididae and Margarodidae, reticulated bugs in the Tingidae family, wood bugs in the Pentatomidae family, grain bugs (for example, the southern hairy bug (Blissus lencopterus hirfus Montandon) and hairy bugs (Blissus insularis Barber)) and other seed bugs of the family Lygaeidae, spittlebugs of the family Cercopidae. the bedbugs of the bed squash family Coreidae, and the chicks and dysdercus of the family Pyrrhocoridae. Also included are adults and larvae of the order Acari (mites) such as tetranykes and red tetranykes of the family Tetranychidae (e.g., apple red mite (Paiiofiychus idmi Koch), two-spotted spider mite. (Tetranychus urticae Koch), McDaniel's tetranyke (Tewanvchux mcdanieU Mc (.} Reg0r)); ؛ flat mites of the family Tenuipalpidae (e.g. lemon mite (Brevipalpus lewisi

MA 28699US wo 2006/007595 PCT / US2005 / 02381 ز

McGregor)); plant mites and bud mites of the Eriophyi dae family and other mites feeding on leaves and mites important to human and animal health, i.e. house dust mites of the family Epidermoptidae, the human demodex of the family Demodicidae, e! the flour waxes of the family of

Glycyphagidae, ticks of the order Ixodidae (for example, the deer tick (Ixodes scapuiaris Say), the Australian tick that induces paralysis (Ixodes holocyclus Neumann), the American dog tick (Dermacemtor variahilis Say), the American star tick (Amblyomma americanum! 0 Linnaeus)) and the common psoropte and the scabies sarcopte of the families of

Psoroptidae, Pyemotidae and Sarcoptidae adults and immatures of the order Grthoptera. including grasshoppers, locusts and crickets (e.g., the traveling locust (e.g., Mekmophis sanguinipes Fabricius, M. differcntialis Thomas), American locusts (e.g.,) 5 Schistocerca americana Drury) ٠ desert locusts (Schistocerca gregaria

Forskal). the migratory locust (Locusta migratoria Linnaeus), the stinking locust (Zonocenis spp.). house cricket) 4 ، '/? ،' / ؛? donieslicits Linnaeus), the.! mole crickets (eg, red mole cricket (Scapteriscus vicinus Scudder) and southern mole cricket (.؟ ، .- ، y&gt; / ra'h '،.' u.١ 'borellii Giglio-Tos)); adults and immatures of the order Diptera, including leafminers, midges, fruit flies (Tephritidae), oscines (eg. Fried Oscinella Linnaeus), ground maggots, house flies (eg Musca domestica Linnaeus), small house flies (eg Farmia canicularis Linnaeus, E femoralis Stein), stable flies (eg . Stomoxys calcitrans Linnaeus), facial flies.

horn flies, calliphores (eg Chrysomya spp .. Phormia spp.). and other musk flies, horse flies (الا ('؛' example, Tabarms spp.), hypoderma (for example, Gastrophilus spp .. ٥،2١ '// 7 / .١' spp.), varrons (for example, Hypoderma spp.), mussels in.) ؛) roe deer (for example, G / 7p١.'١٠'ops spp.), barbins of sheep (eg.

Melophagus؟. ”7, '،' (&lt;؛ Linnaeus) and other Brachyceres, mosquitoes (eg, Aedes spp .. Anopheles .spp., Culex spp.), Black flies (eg. Prosimiilium Spp. . Simidium spp.), Biting midges, sandflies, sciarids and other nematocera; adults and immatures of the order Thysanoptera, including onion thrips (Thrips tabaci Lindeman), laughing thrips (Frankliniella spp.) and other leaf-feeding thrips; insect pests of the order Hymenoptera, including ants (for example, the frame ants

MA 28699US wo 2006) 007595 PCT7US20050238J3 red (Camponotus ferruginous Fabricius), the black pest-boi. 8 (Camponotus pemnsylvanicus De Geer), the pharaoh ant (Monomoriuni pharaonis Linnaeus), the little fire ant (Wasmannia Roger launctata), laauropata fire ant (Solenopsis geminata Fabricius), imported red ant 5 (Solenopsis invicla Buren), Argentine ant (Iridomyrmex humilis Mayr), pointer ant (Paratrechina longicornis Latreille), the turf ant (Tetramorium caespiturn Linnaeus), the brown ant of the ell amps (Lasius alienus Fbrster), the fragrant ant (Tapinoma sessile Say)), bees (including carpenter bees), hornets, wasps! 0 ؛ Elders, wasps and tenthedes (Neodiprion spp.; Cephas spp.); insect pests of the family Formieidae, including the Florida carpenter ant (Camponotus floridanus Buckley), the ant (Teehnomyrmex albipes fr. Smith), the ؛) big head ants (Pheidole sp.) And the ghost ant (Tapinoma melarioceplialum Fabricius); insects 5 ؛ pests of the order Isoptera, including termites from families of

Termitidae (example. Macrotermes sp.), Kalotermitidae (example Cryptotermes sp.). and Rhinotennilidae (for example Reticulitermes sp .. Coptotermes .sp.), the yellow-legged termite (Reticulitermes jlavipes Kollar), the crepuscular termite (Reticulitermes hesperns Banks), the coptoterm of 2 (»Formosa (Υ'ο ^ γν ،) 7 &lt;ν „، '. ١' formosanus shiraki). the drywood termite (Incisitermes immigrons Snydei), the West Indian drywood termite (Cryptotermes brevis Walker), the drywood termite (Incisitermes .١- „ι '، / ، ν'.ί Light), subterranean termites from the south-east (Reticulitermes virginieus Banks), the drywood termite from the west (Incisitermes, BÎTO, 'Hagen), arboreal termites such as Nasutitermes sp. and other economically important termites'; insect pests of the order Thysanura such as silverfish (Lepisma saccharine Linnaeus) and thermobia (Therniohiu domeslica Packard); insect pests of the order Mallophaga. including the head louse (Pediculus humanus capitis De Geer). the 2011 ؛ of the body 3 ا) (Pediculus hurnanus hurnanus Linnaeus), the mallophagus of the body of poultry (Menacanthus stramineus Nitszch), the mallophagus of the dog

،. '،? /? A De Geer), chicken louse (Goniocotes gallinae De Geer), sheep louse (Bovicola ovis Schrank), large cattle louse (Haematopinus eurysternus Nitzscli), ox louse ( Linognathus vituli .35 Linnaeus) and ،! 'Other sucking and biting lice which attack humans and animals; insect pests of the order Siplonoptera, including the oriental rat flea (Xenopsylla cheopis Rothschild), the cat flea (Ctenocephalides felis Bouche), the dog flea (Ctenocephalides ،. '، „1.3 ؛

MA 28699US wo 2006 / 007.595 CT / US2OO5 / O2.381 3

Cutis), poultry fleas (Ceratophylliis gallinae Schrank), chicken fleas (Echidnophaga gallinacea؟ Vestwood), human fleas (Pidex irritans Linnaeus) and other fleas afflicting mammals and birds. Other arthropod pests covered include: spiders of the order Araneae such as the brown recluse spider (Loxosceles rechtsa Oertsch &amp; Mulaik) and the black widow (Latrodeclus mactans Fabricius). and chilopods of the order Scutige romorpha such as the sculiger (Scutigera coleoptrata Linnaeus).

The mixtures and compositions of the present invention are also active against members of the classes Nematodes, Cestodes, Trematodes and Acanthocephali, including economically important members of the orders Strongylida, Ascaridida, Oxyurida, Rhabditida, spirurida. and Enoplida such as, but not limited to, economically significant agricultural pests (i.e. cecidogenic nematodes of the genus Meloidogyne, root nematodes of the genus Pratylenchus. nematodes of the genus Trichodorus, etc.) and pests of human and animal health (i.e. all economically important trematodes, tapeworms and roundworms, such as Strongylus vulgaris in horses, 7b.ro (.. '،; / ra cams in dogs, Haemonchus contained in اة 0١٦ أ ١ ا ١ لما ٦ ا الا Dirofiluriii irrrrmtis لاسا c (\ ١ei ا؟ جل ins, Anojjlocephlcr perjolia, in horses, /fè.w'ifèi hepatica Linnaeus in ruminants, etc.).

The use of a mixture of this invention for the control of white fly (Bemisia argcHtifolii), where one embodiment is to use a mixture in which component (b) is composed of ؛ (b1), for example, imidaclopridc, thiacloprid or thiamethoxam: a compound (b2٠), for example, thiodicarb; a compound (b3), for example, deltamethrin; mid compound (bd), for example, buprofezin, cyromazine, hexafluniuron or novalurorr; a compound (b7), for example, spinosade; a compound (b8), for example, fipronil; a compound (b9), for example, ؛؛ r methopene; a compound (b 12), for example, pyridabene; or 1.1! ٦ compound (bl3), for example, cartap. Also noteworthy is the use of a mixture of this invention for the control of the white fly (Bemisia argeniijblii), wherein another embodiment is to use a mixture wherein component (b) is at least one control agent. control of 35 invertebrate pests (or a salt thereof) from two different groups selected from (bl), (b2), (b.3), (b4), (b5), (bb), (b7) . (b8). (b9), (b 10), (bll), (bl), (b 13), (bl4) ١ (bL٩), (b 16), (b! 7). (bis) and (bl ()).

MA 28699US wo 2006/007595 PCT / US2OO5 / O23813 should be noted) use of a mixture of this invention for controlling berry thiips (Frankliniella occidentalism, where one embodiment is to use a mixture in which component ( b) is a compound (b1), eg, imidacloprid; a compound 64 ؛), eg, hexaflumuron; or a compound (b 13), for example, cartap. 11 Also noteworthy is the use of a mixture of this invention for the control of berry thrips (Frankliniella occidentalism, where another embodiment is to use the mixture in which component ('b) is at least one agent. invertebrate pest control ir) (or a salt thereof) from two different groups selected from (b1), (b2), (b3). (64), (65), (16). (67), (68), (69), (bl)), (bl 1), (612). (613), (614). (615). (616), (617). (b18) and (619).

It should be noted that the use of a mixture of this invention for the control of the potato leafhopper (Empoasca fabae), wherein one embodiment is to use a mixture wherein component (b) is a. compound (b1), for example, dinotefuran, imidacloprid or nitenpyram; a compound (62), for example, methomyl or oxamyl; a compound (63), eg, deltamethrin, esfenvalerate or lambdacyhalothrin; a compound (64), eg, hexaflumuron, lufenuron OR! Novaluron; a compound (b.؟), for example, methoxyfenozide; a compound (b7), for example, abanectin or spinosade; a compound (b9), for example, inethoprene; a compound (b1 1) ١ for example, amitraz; a compound (b 12١. for example, hydramethylnon or chlorfenapyr; a compound (b1 ,؟) .. flonicamid; or a compound (b.16), pymetrozine. 11 Also noteworthy is the use of a mixture of this invention for the control of leafhopper (the potato (Empoasca fabae), where another embodiment is to use a mixture of which the component (b) is at least one invertebrate pest control agent (or 11.11 salt thereof) from two different groups selected from (b1), (b2), (63), (64), (65), ( b6), 3 (1 (67), (68), (69), (bl (.)). (b11), (612), (613), (b11), (615), (616). (117), (b I 8) and (119).

Of note is the use of a mixture of this invention for the control of the corn leafhopper (Peregrines maidis), where one embodiment is to use a mixture in which component (b) is a. compound (b1), for example, dinotefuran ΟΙ.Ι thiacloprid; a compound (62), for example, triazamate; a compound (63). for example, indoxacarb; Ι.ΙΠ compound (69), for example, fenoxycarb; a compound (b! 4). pyridalyl ', a

٦4

MA 28699US wo 2006 ...- 0 () 7595 PCT / US2005 / 02.3813 Compound (b 15), flonicamid; a compound (b 16), pymetrozine; 0 (1 a compound (b 17), dieldrin. 11 Also noteworthy is the use of a mixture of this invention for controlling the maize leafhopper (Peregrines niaidis), where another embodiment is to use a mixture in which component (b) is at least an invertebrate pest control agent (or a salt thereof) from two different groups selected from (b1), (b2), (1) 3). (b4), (1) 5), (b6), (1) 7), (b8), (b9), (blO), (b 11 '), (1) 12), (bl3), (b 14), (bl5), (b! 6), (b7 ؛), (bl8) and (b 19).

It should be noted that the use of a mixture of this invention 0 ا to control melon aphid. (Aphis gossypii), where one embodiment is to use a mixture in which component (b) is a compound (b1), for example, imidaclopridc. niteupyram, thiacloprid or thiamethoxam; a compound (b2), for example, oxamyl; a compound (13), for example, lambda-cyhalothrin: a compound (b4), for example, novaluron: a compound (1-) 7), for example, abamecline; a compound (b8). for example, fipronil; a compound (9 &lt;- ؛), for example fenoxycarb, methoprene or pyriproxyfen; a compound (b11). for example, amitraz; a compound (b 12). for example, chlorfenapyr or pyridaben; a. compound (1) 13). for example, cartap; a compound (b 15). llonicamid; a compound (b 16), pymerozin. or a compound (1) 17 '). dieldrin. 1! Also noteworthy is the use of a mixture of this invention to control the melon aphid (Aphis gossypii). wherein another embodiment is to use a mixture wherein component (b) is at least one invertebrate pest control agent (or a salt thereof) of two different groups selected from (b1) , (b2), (b3). (b4), (b5), (b6), (b7), (18), (b9), (b10), (b11), (b 12).

(b 13), (b! 4), (115). (bl6) ١ (1) 171. (1) 18) and (bl9).

Of note is the use of a mixture of this invention for controlling the green peach aphid (Myzus persicaej, where one embodiment is to use a mixture in which component (b) is a compound (b 1). ), for example, acetamiprid, dinotefuran or imidacloprid; a compound (1) 2), for example oxamyl; a compound (17), for example, spinosade; a compound (!, &lt;-)), for example ', methoprene; a compound (b15). flonicamid, a compound (b 16). pymetrozine: or a compound (b 17). dieldrin. Also of note is the use of a mixture of this invention for the control of the green peach aphid (Myzus persicae). or another embodiment is to use a mixture in which component (b) is at least one invertebrate pest control agent

MA 28699US wo 2006/00759.؟ PCT / US2005 / 023gB (OR a salt thereof) from two different groups selected from (b1), (b2), (b3). (b4), (175). (b6), (17). (b8). (b9), (blO) ١ (bll), (bl2) ٠ (bl.3) ٠ (bl4). (b 15). (116). (bl). (18) and (b 19).

Of note is the use of a mixture of this invention for the control of beet armyworm (Spodoplera exigu, where one embodiment is to use a mixture in which component (b) is a compound (b1). for example, imidacloprid; a compound (b2), for example, methomyl or oxamyl; or a compound (13), for example, indoxacarb. 11 Also noteworthy is the use of a mixture of this invention for the control of beet armyworm (Spodoplera exigua), where another embodiment is to use a mixture in which component (b) is at least one Invertebrate pest control agent (or a salt thereof) from two different groups selected from (b1), (b2). (b.3), (14), (15), (bb), (b7), (18), (19), (bio), (bll), (112).

(b 13). (b 14), (115), (b 16) ٠ (b 17). (b 1 8) and (b 19).

Of note is the use of a mixture of this invention to control cabbage looper (Trichoplusia ni), where one embodiment is 1 ؛ using a mixture in which component (b) is a compound (11), for example, imidacloprid; a compound (b2), for example. Methomyl or oxamyl; or a compound (13), for example, indoxacarb. Also of note is the use of a mixture of this invention to control cabbage looper ('Trichoplusia ni), or another embodiment is to use a mixture in which component (b) is at least one invertebrate pest control agent (or a salt thereof) from two different groups selected from (b1), (12), (13), (14), (15), (16). (17), (18), (19), (110), (bll), (112). (113), (114), (115), (116). (bl7), (bl8) and (b! 9).

should 'report'! ' The use of a mixture of this invention for controlling the Diamondback Moth (Plutella xylostella), wherein one embodiment is to use a mixture wherein component (b) is a compound (11 ). pal 'example, imidacloprid; a compound (12), for example, methomyl or oxamyl; 1,111 compound 13), for example, indoxacarb; or a compound (b 15), flonicatnide. Also worthy of note is the use of a mixture of this invention for controlling the Diamondback Moth (Plutella where another embodiment is to use a mixture in which component (b) is air less. an agent binds control of invertebrate pests (or flaxseed from it) of places groups

MA 28699US wo 2006/007595 PCT / US2005.'O23Xt3 different selected from (bl), (b2), (b3), (b4), (b5), (b6), (17), (b8), (b9) , (b 10), (bl!), (b 12), (bl3١, (bl4). (bl.؟), (b) 6), (b! 7), (bl8) and (1,19) .

The control of invertebrate pests in agricultural and non-agricultural applications involves applying a composition or mixture of this invention, in an effective amount, to the pest environment, including the agricultural and / or non-agricultural site of infestation, in the area to be protected, or directly on the pests. Agricultural applications include protecting field crops geese against invertebrate pests, typically by application of a composition or. a mixture of the invention to the seeds of the crop before seeding, to the foliage, to the stems, to theirs and to the fruits of field crops, or to the soil or other growing medium before or after planting. Non-agricultural applications.؟ refer to the control of invertebrate pests in areas other than fields of field crops. Non-agricultural applications include controlling invertebrate pests in stored grains, beans and other food products, and in textiles such as clothing and carpets. Non-agricultural applications also include the control of invertebrate pests in plants.؟ ornamental trees, forests, yards, roadsides, railway estates, and on lawns such as lawns, golf courses and pastures. Non-agricultural applications also include controlling invertebrate pests in homes and other buildings potentially occupied by people and / or pets, ranching, ranching, zoo or other animals. Non-agricultural applications also include the control of pests, such as termites, which can damage ؛ ' wood or other structural materials used in buildings. Non-agricultural applications also include protecting the health of geese, humans and animals by controlling parasitic invertebrate pests or those that transmit disease.؟ infectious. Such ravaged! '؟ include, for example, quid, ticks, lice, mosquitoes, mites and fleas.

Hence, the present invention also discloses a method of controlling an invertebrate pest in agricultural or non-agricultural applications, which consists in bringing the invertebrate pest or its environment into contact with a biologically effective amount of a mixture containing the compound of formula 1, an anoxide or a salt thereof, and ata minus an invertebrate pest control agent (or a salt thereof) selected from the group

MA 28699US wo 2006/007595 PCT7US2005 / 023X13 including (bl), (1) 2), (b3), (b4). (b5), (b6) ١ (b7), (b8), (b9), (blO), (bll), (bl2) ١ (bl3), (1) 14). (bl5), (bl6) ١ (1) 17), (bl8) and (bl9). Examples of compositions ؛ 1 ؛) Properties containing an effective amount of compound of formula 1 and an effective amount of component (b) include granular compositions where component (b) is present in the same granule as compound of formula 1, .'٧- Oxide or salt thereof or in separate granules independent of those of the compound of formula 1, Y-oxide or salt thereof. 11 It is appropriate to point out an embodiment where component (b) is a compound (1) 1), for example, imidaclopri.de., a compound (b2), for example.

methomyl. or oxamyl, or a compound (b.3), for example, indoxacarb, or component (b) comprises at least one invertebrate pest control agent (or a salt thereof) of two different groups if selected from among (1) 1 '), (b2), (1) 3). (b4), (1) 5), (1) 6), (b7), (1) 8), (69), (bio), (bll). (1) 12). (1) 13). (1) 14). (bl5). (bl6), (bl7) ١ (b! 8) and (bl9).

One embodiment of a contact method includes spraying. Alternatively, a granular composition comprising a mixture or a composition of the invention can be applied to the foliage of plants or to the ground. The mixtures and compositions of this invention are effectively delivered also by supply to plants, contacting the plant with a mixture or composition of this invention which contains the compound of formula 1, a Y-oxide or a salt thereof. here and an invertebrate pest control agent selected from components (b), and which is applied in the form of a liquid formulation for irrigation of the soil, of a granular formulation prevalent in the soil, a nursery treatment or an immersion of the plants. Desirably, a composition of the present invention in the form of a liquid formulation for soil irrigation. Also worth mentioning is a method of controlling an invertebrate pest which comprises bringing the edaphic environment of the invertebrate pest into contact with a biologically effective amount of a mixture of the present invention. It is also appropriate to mean such methods where the mixture is that of Embodiment 1-4. 6, 7, 9 1 (), 1.5-2 (), 22, 23, 25. 26, 28-33, 35, 3 (1, 3845 or 46.

The mixtures and compositions of this invention are also effective by topical application to the site of infestation,!) Other contacting methods include the application of a mixture or composition of the invention by. direct spray and effect spray

MA 28699US wo 2006/007595 PCT / US20O5 / O23813! 'Emanate, aerial application, freezing, seed coating, microencapsulation, systemic delivery, baits, ear tags, boluses, nebulizers, fumigants, aerosols, powder and many more . One embodiment of a contact method is a dimensionally stable fertilizer granule, stick or tablet containing a mixture or composition of the invention. The compositions and mixtures of this invention can also imbue the materials of manufacture of invertebrate pest control devices (eg, insect nets). Seed coatings can be applied to all 1) ؛ types of seeds, including the seeds from which geese will germinate, genetically modified plants expressing specialized characteristics. Representative examples include seeds expressing proteins toxic to invertebrate pests, such as Bacillus thuringieiisis toxin or those expressing herbicide resistance, such as Roundup Ready seeds. A mixture OR composition of this invention may be incorporated into a bait composition which is consumed by an invertebrate pest or which is used in a device such as a trap, bait station and the like. Such a composition learned peak Lit to be in the form of granules which contain (a) active ingredients, in particular the compound of 2 (1 formula 1, lin A-oxide or a salt thereof; (b) a control agent. invertebrate pests or a salt thereof selected from the group consisting of (bl), (62), (b3), (b4), (65). (66), (67), (68), (1) 9 ), (blO), (bll), (.612). (613), (614), (b1-616), (؟), (b1), (618) and (619); (c) -one or more food substances; (d) optionally an attractant, and (e) optionally one or more humectants, it should be noted granules 0) 11 bait compositions which contain about 0.001-31) ،! 'active ingredients, about 40-99% goose substance food and or attractant; and optionally about 0. () 5-10 (¾ ،! 'moisturizer, which are effective in controlling invertebrate soil pests at low application rates, especially in doses of the ingredient. active ingredients which are fatal to ingestion rather than direct contact Some food substances can act both as a food source and as an attractant Food substances include carbohydrates, proteins and fats. As food substances we mention vegetable flour, sugar, starches, animal fat, vegetable oil, yeast extracts and dairy ingredients. A liter ،! 'Attractants, we cite odorants and flavoring agents, such as fruit or vegetable extracts, perfume, or another component of animal or vegetable origin, pheromones or other agents which attract

MA 28699US wo 2006/007595 i ؛ 'C17٧S20O5 / O23s 3 إ target invertebrate pests. As (! Humidifiers, i.e. moisture retaining agents, we mention glycols and other polyols, glycerin and sorbitol. A bait composition (and a method of using such a bait composition) used to control at least one invertebrate pest selected from the group comprising ants, termites and cockroaches, separately or together. A device for controlling an invertebrate pest optionally comprises the present bait composition and a housing adapted to receive the bait composition, where the housing has at least one opening dimensioned to allow the passage of the invertebrate pest in order to access 1 ؛ the bait composition from a location outside the housing, and where the housing is also adapted to be placed in or near a site of potential or known activity of the invertebrate pest.

The mixtures and compositions of this invention can be applied without other adjuvants, but most often the application will be that of a formulation comprising one or more active ingredients with suitable carriers, diluents and surfactants and optionally in combination with food according to the intended end use. One method of application involves the. spraying an aqueous dispersion or a refined oil solution of the mixture or composition of the present invention. Combinations with spray oils, spray oily concentrations, wetting adhesives, adjuvants, other solvents and synergists such as piperonil butoxide often enhance the effectiveness of the compound. For non-agricultural uses, such sprays can be applied from spray containers such as a canister, bottle or other container, either by means of a pump or by releasing them from a pressurized container, for example, a pump. pressurized aerosol can. Such spray compositions can take various forms, for example, linen spray, mist, foam, smoke or nebulization. Such spray compositions can also contain proj.7irlsei.irs. foaming agents, etc., as required. Desirable is a spray composition which contains a mixture (. A composition of the present invention and a propellant. Representative propellants include, but are not limited to, methane, ethane, propane. Butane, isobutane, butene, pentane, isopentane, neopentane, pentene, hydrofhiorocarbons. chlorofluorocarbons, dimethyl ether. and mixtures thereof. A composition should be reported to

MA 28699US

WO 2 () () 6, -0 () 7595

PCT / US2005 ، '02٠٦ “B sprays) - (and a method of using such a spray composition delivered from a spray container) used to control at least one invertebrate pest selected from the group consisting of mosquitoes , black flies, stable flies, deer flies, horse flies, wasps, yellow jackets, hornets, ticks, spiders, ants, midges and the like, separately or together.

The rate of application required for effective control (i.e., a biologically effective amount) will depend on actors such as the species of invertebrate pest targeted, the life cycle of the pest, its life stage, its size, location, time of year, animal species 01.1 host plant, feeding behavior, mating behavior, ambient humidity, temperature and the like. Under normal circumstances, application rates of about () .01 to 2 kg of active ingredient per hectare are sufficient to control pests in agricultural ecosystems, but a rate as low as (.). ( ) () 01 kg / hectare may be sufficient Ota a rate as high as 8 kg / hectare may be required. For non-agricultural applications, effective application rates will vary within the range of about 1.0 to 50 mg / square meter but a rate as low as 0.1 rng / square meter may be sufficient or tan rate as high as 150 mg / meter square may be required. A competent person (! Years of age! ') Can readily determine the biologically effective amount necessary for the desired level of invertebrate pest control.

Synergy is described as the cooperative action of two components (e.g. component (a) and component (b)) in a mixture, so that the total effect is greater than more prolonged than the sum of the effects of the two more) taken independently (see P. Μ. I ... Tames, Neill., /. Plant Pathology 1964, 70, 7.5-80). Mixtures containing the compound of formula 1 with other invertebrate pest control agents have been shown to exhibit synergistic effects against certain important invertebrate pests.

The presence of a synergistic effect between two active ingredients is established using Colby's equation (see s. R .. Colby, Calculating Synergistic and Antagonistic Responses of Herbicide Combinations, Weeds.

: (202.2 ١٦ /, 1967 as

4)

MA 28699US

WO 2006/007595 CT / US? 0 () 5 / () 2٩813

P = A + BAxB

100

Applying Colby's method, the presence of a synergistic interaction between two active ingredients is established by first calculating the predicted activity, p, of the mixture based on the activities of the two applied components alone. If p is less than the effect established experimentally, this means that there is a synergistic effect. If p is equal to or greater than the effect established experimentally, ؛ 'interaction between the two components is characterized as being inically additive or antagonistic. In the equation above, A is the observed result of one component applied alone at! () A rate X. B is the observed result of the second component applied at rate y. The equation estimates p. that is, the observed result of mixing A at rate X with B at rate y. if their effects are strictly additive and no interaction takes place. To solve the Colby equation, the active ingredients of the mixture are applied in the tests separately as well as in a combination.

BIOLOGICAL EXAMPLES OF THE INVENTION

The tests.؟ The following demonstrate the effectiveness of controlling the mixtures or compositions of this invention against specific pests. The protection afforded by controlling pests by means of the mixtures or compositions, however, is not limited to these species. Analysis of oral synergy of antagonism between oral mixtures and compositions is determined by the Colby equation. The data concerning the؟ '("mean tic mortality for the compounds to be tested" alone are inserted into the Colby equation. If the (1 ؛, mean observed mortality (obs) is greater than p, the (.0' ؛ Expected mortality, cecr means that the mixture or composition has ، '؛ Such synergistic lines. If the observed mean ١ اً? ا mortality is equal to or less than the expected% mortality, the mixture or composition has neither synergistic effect nor antagonism. In these weights, compound 1 is the compound of formula 1.

TESTA .50 To evaluate the control of the white fly (ÆcmAfo o7'g07C / 7o / 7 /

Bellows and Perring) by contact and / 'or by systemic means, each test device consists of a small open container containing a 12-14 day old goose cotton. The test devices are pre- ؛ nfested by placing them

MA 28699US

١vo 2006 .. 07595

PCT / IJS2005 023 “دا in cages infested with adults of white flies so that spawning can occur on cotton leaves. The adults are removed from the plants by means of a nozzle blowing an air jet, and the test apparatuses are covered. The test devices are then stored for 2-3 days before spraying.

The compounds to remain are formulated using a solution containing 10 (1'0 acetone, 90% water and a non-ionic surfactant 300 ppm Χ-77 * Spreader Lo-Foam Fomrula containing the alkylarylpolyoxyethylcne, fatty acids free, glycols and 2-propanol (Loveland Industries, Inc.) to provide the desired concentration in ppm. The formulated solutions 1 tested are then applied in volumes of 1 ml. by an SU.12 atomizer nozzle with 118 .JJ custom body (Spraying Systems Co. '), positioned 1.27 cm (.0.5 inch) from the top of each test device.

The results of the experimental compositions in this test are 5 ؛ aftershocks three times. After the atomization of 1 ؛؛ Formulated composition 1 tested, each test device was allowed to dry for one hour and the cover removed. The devices.؟ test are kept for 13 days in a phytotron at 28٥c and 50-70 () ؛؛ relative humidity. Each test device is then evaluated under a binocular microscope for insect mortality; 20 the results are shown (.! In Tables 2A and 213.

Table 2 A

<td colspan="5">White ntouehe</td>

<td>Compound 1 (ppm)</td><td colspan="2">Imidacloprid Report (ppm)</td><td>11؟ Dead. (observed)</td><td>% Death. (calculated)</td>

<td> '} L—</td><td colspan="2"> 0</td><td></td><td></td>

<td> 8</td><td> ()</td><td> -</td><td> 4</td><td> ..</td>

<td> 10</td><td> ()</td><td></td><td> 1</td><td>ل</td>

<td> 0 0</td><td> 10</td><td></td><td> 1</td><td></td>

<td> 0</td><td colspan="2"> 48</td><td> 25</td><td> -</td>

<td> ١)</td><td colspan="2"> 10 1:1.7</td><td> 24</td><td> 1</td>

<td> ١؛</td><td colspan="2">3.7 ؛, 22 'TT]</td><td> 46</td><td> ٦</td>

<td> 6 8</td><td colspan="2"> 48 .1:8.0 !0 1:1.3</td><td>83 4٢ 'T-</td><td>2.5 TT TT 5</td>

<td> 8</td><td colspan="2"> 22 1:2.8</td><td> 59</td><td> 6</td>

<td> 8</td><td colspan="2">1: 6 ا 48</td><td> 87</td><td> 28</td>

<td> 10</td><td colspan="2"> 10 1:1</td><td> 2.1</td><td> ،.</td>

<td> 10</td><td colspan="2"> 22 1:2.2</td><td> 68</td><td> .5</td>

<td> 10</td><td colspan="3">59 ا 1: 4.8 48</td><td> 26</td>

MA 28699US * indicates that the observed mortality ٥4) is greater than the mortality () / ،) calculated ،! 'After the Colby equation.

WO 2006'007595

PCTZ٧S2OO5.٠ '(&gt; 23813

Table 2Β

<td>White vloucfre c imposed) Methomyl Compound 1 ٢ Methomyl Compound 1 + Methomyl Compound 1 '٠- Methomyl</td><td>Rate (ppm) 6 ؛) ؛ ).) 1'6 () 0! 6 10) 10 ',)</td><td>% Death. (obs) 4 8 4</td><td>Rate (ppm) 100 10 ؛. 8 00 ؛ ؛ 8 1000 ب 8</td><td>٠/٠, Death. (obs) 3 () 0 9</td><td>False (ppm), 1.0 10 (.) 0 10 +10 10. (. 100 10 (1000</td><td>% Morl. ; (obs) إ 6 ؛ ١) داً</td>

<td>Amitraz</td><td> 500</td><td> 5</td><td> 1000</td><td> 0</td><td> 2000</td><td> 0</td>

<td>Compose 1 - Amitraze</td><td> ٩00 ٠ ١)</td><td> 0</td><td> 8' 500</td><td>إ)</td><td> 10+500</td><td> 1</td>

<td>Amitraz ؛ اً Compound</td><td>00 (') ا: 6</td><td> (.)</td><td> 8+1000</td><td> 0</td><td> 10(1000</td><td> 0</td>

<td>Amitraz ؛ 1 Compound</td><td> 0 '' 2()()0</td><td> 0</td><td> 8 2000</td><td> 0</td><td> 10+ 2000</td><td> (.1</td>

<td>Thiamcthoxamc</td><td> 5</td><td> 15</td><td> 15</td><td> 78</td><td> 30</td><td> 92</td>

<td>Compo.se) + -Thiamé! Hoxamè</td><td> 5 ؛ 6</td><td> ....</td><td> 8 - 5</td><td> 28*</td><td> 10(5</td><td>٦٦8 ك 7</td>

<td>Ihiamethoxamc - ؛ - (Composes</td><td> 15- ١)</td><td> 93*</td><td> 8+15</td><td> 80*</td><td> 10-15</td><td>١'ا ١ ه</td>

<td>Compound 1 - ؛ Thiarnethoxam</td><td colspan="2"> (&gt;'50 99*</td><td colspan="2"> 8 + 30 96*</td><td colspan="2"> 10.(-30 100*</td>

<td>Pyridaben</td><td> 20</td><td> ؛2</td><td> 30</td><td> 55</td><td> 50</td><td> ؛ 5'1</td>

<td>Compound 1 -t Pyridabnc</td><td> (,''20</td><td> '!</td><td> 20 '٠- 8</td><td> 4</td><td> 10 ... 20</td><td> 18</td>

<td>pyridaben ؛ Compose i</td><td> 6 ' 50</td><td> 18</td><td> 8-‘.30</td><td> 38</td><td> 1()+-30</td><td> 4+</td>

<td>Pyridaben ؛ ا Compound</td><td> (.)'؛ 6</td><td> 100*</td><td> 8 , 50</td><td> 100*</td><td> !0 + 50</td><td> 100*</td>

<td>Flonicamid</td><td> 0.1</td><td> 2</td><td> 0.2</td><td> 2</td><td> 0.-5</td><td> 2</td>

<td>Compound 1 + Flonicamid</td><td> 1 .'؛ 6</td><td> 0</td><td> 8+ 0.1</td><td> 0</td><td> 0.1'0؛</td><td> ..' ؛</td>

<td>Compound 1 + Flonicamid</td><td>.٦٠٠. ا '٦ ا</td><td> 0</td><td> 8+0.2</td><td> 0</td><td> 10 ' 0.2</td><td> (.(</td>

<td>Compound 1 ⁴ Flonicamid</td><td> 6 ( 0.5</td><td> 0</td><td> 8(.().5</td><td> 2</td><td> 0.5 ..؛.()1</td><td>(غ </td>

<td>Dieldrin</td><td>K!</td><td> 0</td><td> 100</td><td> (,)</td><td> 100</td><td> 0</td>

<td>Composed! Dieldrin</td><td> 0؛ '&lt;)</td><td>ا</td><td> 8 10</td><td> 0</td><td> 1()+-1()</td><td>(أ</td>

<td>Compound 1 t- Dieldrin</td><td> 6 100</td><td> 0</td><td> 100 '؛ 8</td><td> 0</td><td> 10 + 100</td><td> ؛؛</td>

<td>Composed ٠ اً- Dieldrin</td><td> 6 1000</td><td> 0</td><td> 8+100()</td><td> 0</td><td> 10 -1000</td><td>أ ؛</td>

<td>Spinosade</td><td> !00</td><td> 66</td><td> 1.50</td><td> (,9</td><td> 300</td><td>5 وع</td>

<td>Spinosade - ؛ ؛ Compound</td><td>Λ١'.١ ٠ ١ ؛</td><td> 75*</td><td> 8 ' )00</td><td> 88*</td><td> 10.(..100</td><td> 78'*</td>

<td>Compound i ب Spinosade</td><td> 50 ١)</td><td> 96*</td><td> 50؛ 8</td><td> 80*</td><td> 10 ، 150</td><td> 96* :</td>

<td>Compound ا - Spinosade</td><td> 00؛. '' 6</td><td> 100*</td><td> 8 300</td><td> 1()()*</td><td> 300 ..؛'10</td><td> 100*</td>

<td>Fipronil</td><td> 50</td><td> 1</td><td> '.00</td><td> ١؛</td><td> 1000</td><td> ٦,'</td>

<td>Composed ا + Fiprom!</td><td> (&gt; 50</td><td> 5</td><td> 8 + 50</td><td>ح</td><td>١ دج ا \</td><td> ٦١</td>

<td>Fipronil ا ؛ Compound</td><td> 100 ؛'6</td><td> 2</td><td> 8 100</td><td> 26*</td><td> 100 ..:. 0؛</td><td> *9؛</td>

<td>Compound اً (- Fipronil</td><td> 6 ' 1000</td><td> 16</td><td> 8 + 1000</td><td> 16</td><td> 10-(.100()</td><td> 23</td>

<td>Pyriproxifen</td><td> 10</td><td> 100</td><td> 15</td><td> 100</td><td> 20</td><td> 100</td>

<td>born;! Pyriproxi '؛ ؛ ' Compound</td><td> 6 '10</td><td> 77</td><td>10 ا 8</td><td> 85</td><td> 1().((1</td><td> ؛ 100</td>

<td>Compose 1 ؛ Pyriproxifenc</td><td> 6'15</td><td> 98</td><td> 8..:..15</td><td> 100</td><td> 10+15</td><td> ()(.؛؛</td>

<td>Compound I + Pvriproxilene</td><td> 6 '' 2.0</td><td> 99</td><td> 8..(.20</td><td> 90</td><td> 20 ؛. 10</td><td> 10(1</td>

<td>Pymeirozin</td><td> 10</td><td> 3</td><td> 100</td><td> 7</td><td> 1000</td><td> ١+</td>

<td>Compound 1 1- Pymetrozine</td><td> 6-10</td><td> 0</td><td> 8+10</td><td> (.)</td><td> 10 + 10</td><td>ر (. ؛</td>

<td>Compound 1 - ؛ ' Pvmetozinc</td><td> 6.(100</td><td> 3</td><td> 8+100</td><td> 0</td><td> 100 -؛ (11</td><td>b</td>

<td>Compound ٠- اً- Pymetrozine</td><td> 6,1000</td><td> 0</td><td> 8 + 100()</td><td> 0</td><td> 10+1000</td><td> 1</td>

<td>Buprofezin</td><td> 500</td><td> 75</td><td> 500</td><td> 65</td><td> 1000</td><td></td>

<td>Compound ٠ اً Buprofczinc</td><td> 300 ٠ ١)</td><td>٦ ح</td><td> 8 + 300</td><td> 99*</td><td>١ΰ١0 لآ .٠٠</td><td>98 * I</td>

<td>Compound 1 + Buprofezin</td><td> 6 , 500</td><td> 93*</td><td> 500 ٠٠؛٠٠٠ 8</td><td> 97*</td><td> 11).,-500</td><td> 96*</td>

<td>Compound 1 4 Buprofezin</td><td> 6 ’ 1000</td><td> 99*</td><td> 8+1000</td><td> *'00؛</td><td> 000؛ +11</td><td> ؛ *98</td>

<td>Chlorenapyr</td><td> .0</td><td> ١)</td><td> 100</td><td> 14</td><td> 1000</td><td> '18</td>

<td>Compound i 'أ Chlorfénapyt</td><td> 10 ٠' 6</td><td> 8</td><td> 8+10</td><td> 10*</td><td> 10 : 10</td><td> ؛</td>

<td>Chlorfenapyr) ؛ Compound</td><td> 6 ⁴ 100</td><td> 2</td><td> 8(-100</td><td>اً</td><td> ()10 ,-0؛</td><td> ٠&lt;</td>

<td>Compound ا + Chlorlcnapyr</td><td> ()00؛*.()</td><td> 35*</td><td> 8+1000</td><td> 49*</td><td> 10+1000</td><td> 13</td>

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PCT / US200.5.O238I3

White fly

Chlorpynfos

Compose 1 Chlorpyrilbs Compost 1 I- Chlorpyril'os Compose 1 ؛ - Chlorpyri 1'os

Cyromazine

Compound 1 - + - Cyroinazinc

Compound 1 + Cyromazinc

Compound 1 -: - Cwomazine

Fenoxycarbc

Compound 1 -: - Fenoxycarb Compound 1 1

Compound 1 + - Fenoxycarb Methoprene Compound 1 -: - Methoprene Compound 1 Methoprene Compound 1 - + Methopene Indo.xaearbe

Compound 1 -: - Indoxacarb Compound! 1- hidoxacarb Compound 1, liiloxacarb Tltiodicarb

Compound 1 Thiodicarb Compound 1 -1111 '- ؛ (. Licarb Comoose ؛ + Thiodicarb lebiifenozide

Compound 1 1'ébufénoz.ide Compound 1 Tunoz idc Compound 1 - + Tébulnozidc

Oeltamethrin

Compound 1 -: Detamcthrin Compose 1 - ؛ - Delrtamérthnne Con١ | 7osé 1 ب [? Cltametlirine Oxamyl Compound 1 -, Oxamyl Compose 1 -, Oxamyl Compound 1 7 Oxamyl llexallumuron

Compose 1 llexallumuron Compose 1 - ؛ Uexaflumuron Compose 1 + ؛؛ cxallumuron

Acetamiprid

Compose 1 + Acélami pride

Compound 1 Acetamiprid

Tain

ا ؛ (ااا (ا)

500

500 ٠- 6

6-1-1000

2000 .٠- 6

10

6-10

()6-1-10

()100:-6

1'ا Death.

<img file="MA28699B1_D0004.tif" />

,!Have

6-1-20 50()

-:- 500

0()11.1 -٠ 6

()0()2

-:- 1 (1 : 3

6-:-1(.)

100 6+100 6 --- ).()()() 6-3000

100 : 100

1000

- 3000

30 ٠ 6

-t- 40, - 50

0.1 * ١) 0-3 - 0 إا -٠ ة

0؛

1-10) 0 ؛) - ١-) 360 ؛ i)

1)

ب 6 ؛ Acsanid -ل 1 Compose

Cartap

Compose 1: Cartap Cartap ؛ ؛ Compost Carlap - ؛ ؛ ؟ Compos

Esfen valeralc

E.sfenValérie - ((؛ Compost Compound 1 + Esfenvilerarte Çompost 1) Eslenvalcrarte 'fliiaclopride

Compound 1 - + Thiacloprid Compound 1 lia loprid؟ 1 Compound i -: - lit t'lopri

- 0.5

- 50

6(-100

6-:-200

I

6+15 6 25

35 ٠ 6

Tain (obs) (ppin)

1000 + :500

0(.)10 ؛8

()200 +-8

100

-i- 1 0

8-:-100

8-1000

I

--، 20 1000 + 500 + 10()()

2000

؛.

29*

52*

63*

39*

26*

13'*

91'

81*

89*

99 *% Death.

(obs)

؛

84*

75*

66*

()

35*

59:+

78*

8+3

8-,-1()

1)01' : 100

8-,-1000

-,- 3000

10(.)(.)

8-1(.)0

-: 1000

8.: 3000

30 ؛- 8

40 -,-8

8 -, - 50 oA

8-:().1

- 0.3

L٠٦r

-: 10

60 -؛- 8

360 + 8

؛ ٢ 8

5 ٢- 8 t 20

0.2

0.1 ب 8

ة; () .- ؛ 8

00؛

-t- 50

8-:-10() )- 200

258+15 + 25 + 35

14*

II *

41*

75.*

1-4

0

'٠

*6(7

75

*100

Tam (ppm)

2000

10-: 500

1()+- 1000

10+ 2000

1000

* لا * 10 -: - 10

* 88 100 ب 10

*01 1.0,0..10

؛2 20

2-:- 10

10-).10

1.)2-,- 10 2000 (.)50-, 10 00()11()1 2000 -,- 10 10 0-1؛

3. +. 10 10-:-()1 0()30

(.)(') 1 -؛ 10 0(.)()1-,-10 00()3-- 10 3000.

10-100 :- 1000

If.), -5000 .50

10:-30

1()+40

1()-1 .50

1.0.1. 10

0.3 ٠'؛٠ 3)1

1 ..؛)1

IT

1()-(10 10-(--60

-).-.360

10.:..1 1(.)--5

20 -:- 0؛

0.5

I () -: 0.1

1 () :-(). 2 1 (): 0.5 200 I

50-:- 0؛ 00؛ - 10 200 -,- 10

35

5؛ - 10

25. (. 10 ؟3 - 0؛

؛ .Death%

(obs)

(؛

8

33*

*90

: * ع 9

.٢

١.١

: ٩:٠؛

*0؛

(ألا

؛ *75

87’

16*

25*

97*

99*

MA 28699US

PCT ٧S2OO5 0238 (3

W0 2006،007١95

<td>White vlouche lambda-kyhatthriria lambda-cyhalothrin ؛ 1 Tambda-cylialothrin compound '؛ - ا Lambda-cyhalothrin compound ؛ 1 Compost</td><td>I. ' % Death, tppm) (nbs) ! i.) () ٠) () ؛ '6 (') 56 ١) 6 ؛؛ 25 ٠ 6</td><td>Rate% Death. ) (ppm) fobs (50 2 (؛ [.. ؛ - s * 23 لب 8 14 () 25 -, - 5</td><td>Rate / 0 Death. ؛ (ppm) (obs) () (') ؛ 250 * 11 10 -, - 10 10 1 50 10 * 10 i 250 89</td>

<td>Uydramelltiytnon Compose ؛ tlydramethylnon Compost 1 Hydramethylnon Compost t -٠- Hydramethylnon</td><td>0 ؛) I :( ؛ 0 knock ؛,) 0 1000+ &lt;)</td><td>To 100 5 10 ؛ - s 1 0 (, 1 ؛ X 0 0 () 1) 1--5</td><td> 0 000؛ 3 0-1-100) 2 11000()1</td>

<td>Methoxyfen Compost t, Methoxyfenozide Compost i - Methoxyfenozide Compound t ب Methoxyfenozide</td><td>6-10 i) 6 -) - 50 6</td><td>to 2 8-Ό 3 50 '- ؛ - 8</td><td> 50 1 !0-2 2 1 10’50 4</td>

<td>Nitenpyram Compound 1. - Nitenpyram Compost i ؛ Niienpyram Compound ا ل Nitcnpvram</td><td>20 53 6 -, - 26- 59 * 6 - 3 fl 56 64 1) 4 - ؛ - 6</td><td> 30 54 81.20 61* 5(--30 79 81..40 99*</td><td>Tf 85 days 10:20 4'7: ا 55: 30-10 * 1 () 40 - () 1</td>

<td>h Pyridatyl - '- Pyridalyl ؛ ! Compost Compost i - Pyridalyl Pyridalyl ا Compose Dinotéfuranc 1 Dinotefurane ا Compose Dinotcfurane أ ا Compose Dinatfurane -ا ا C'on١posé</td><td>0 0! 0 (؛ 1-1-6 0 ؛ 21 - 6 6 -: - too 1 --قآ - “-------- ---- آ ؛ آ --- - - - 4 (, ؛ ا- 6 6-1 () 0 too</td><td>0 10 '؛ - ؛ - 8 0 0 ؛ s 97 3 10 -1- 8 74 25 ';. ؛ 9 (، 8-1-100</td><td>0 00) أ) 0 ؛ -'- ؛)) ' '؛ (.10 '. ؛. 10 100 00! 19 0-10 ؛ ! 0-1-25 88 (0- (00 9χ</td>

<td>Novalurw Compost 1- ؛ Novaluron Cotnposc 1 - Novalui'on Compost 1 * Novaluron</td><td>إ, 7,</td><td> 10 0 8-2 8* ؛ 110 8 *67 ()25 8-1</td><td>28 '250' * 1 ؛ 10 -'to * 41 250 - () 1</td>

TEST B

To assess control of berry tripe (FranklinieUii occidentalis Pergande) by contact and, or by systemic means, each test device consists of a small open container containing a bean plant (var. Sun) 5 to 7 days old.

The solutions to be tested are formulated and atomized 3 laws as described for ballast A. / After atomization, the test devices are allowed to dry for one hour, 23. to 27 adult thrips are added to each device, then one. black screen cover is placed on the surface. The devices of لا ؛ test are maintained for 7 days at 25٥c and 45-55®) relative humidity. Each test device is then visually assessed for insect mortality; the results are shown in Tables 3 A and 3 B.

MA 28699US wo 2006: 007545

Table 3Λ

<td colspan="4">Berry thrips</td>

<td>ا Compose ج ؛ -</td><td>Iniidaelopride Report .............. .- ؛. pprn) _ ٠٠u ............................ ...................................</td><td>؟ / "Death, (observed)</td><td>° / u Death, (ealeulél</td>

<td>ح ٦ if</td><td> 0</td><td> 1 1)........................</td><td> ٠ ' ... . ... .</td>

<td> ٦ 0 —</td><td> 11</td><td>'-O--</td><td> -</td>

<td>ا)</td><td> ----٢—-٢——₇٦-—</td><td> 37</td><td> '</td>

<td> 0</td><td> 501</td><td> 90</td><td> -</td>

<td>X</td><td>1: 1.4 اً!</td><td> 2.3</td><td> 22</td>

<td> 8</td><td> 7? 1:9.0</td><td> 60</td><td rowspan="2">——- (لا --— 34٠.</td>

<td> 8 25</td><td> 1:70 501 2.3:1 ؛1</td><td> (20 17</td>

<td> 25</td><td> 77 1:3.1</td><td> 63</td><td> 48</td>

<td> 25</td><td> 501 1:22.4</td><td> 90</td><td> 92</td>

<td> 81</td><td> 7.4:1 ؛1</td><td> 37</td><td> 44</td>

<td> 81</td><td> 77 1:1.1</td><td> 70</td><td> 50</td>

<td> 81</td><td> 501 1:6.9</td><td> 93</td><td> 93</td>

Table 3Β * indicates that the 1؟ observed mortality is greater than 1؟ mortality calculated from Colby's equation.

<td>Berry thrips</td><td>Rate 41؟ Dead. (pptn) (obs)</td><td>Tau *% Death. Tau * ٠٠ / “, Death. (ppm) (obs) i (ppm) (obs)</td>

<td>؛ Compound ؛ Methomy Methomy) ٠٠! ٠ Compound 1 Compound 1 4 'Methomyl Methomyl ٠٠ ؛ ٠ 1 Compound</td><td>44 0! 60 ١ ؛ 3 * 80 30 .1. 0, * ال 100-10.4 100 0-4.300 (</td><td>1) 4,100 ؛ 49 50 00 (300: 60 109 60 30 ؛ 100 ؛ 60 30 .٠. 50 504 1.00 80 d 100 -100 80 * 50 .'- 300 ،) () 1 111) ..- 3 (.) 0 40</td>

<td>Amitraz Amitraz د ؛ Compound Compound 1 4 Amitraze Amitraze ٠. ؛ .. ؛ Compound</td><td>40 10 * 70 10 ب 9 ؛ 60 10-4-100 50 10.1000</td><td> 20 ؛)00( 30 100 4)6 0( ،. ()()( : 40 10 4 50 60 4)(.)1-. 100 ؛ *70 100-- 50 *60 000؛ 1004 ؛ 30 1000 ’.()5</td>

<td>ritiametltoxam Compound 1: Thiancthoxamc Compound 1 4 Thiaméihoxane Compound 1 ٠٠ ؛ ٠٠ Thiametlioxam</td><td> ، 20 10.45 20 70 70 0؛ 40 250 04؛</td><td>4) 9 '250' 4 80 0? ' ؛) 5 5 () 0 (30 5 .؛ 50 1) 1) ؛ 'أ 100: 40 70 -, () 5 40 (؛ ١ '4) 0) () () 250 4-50</td>

<td>Pyridabene 4- Pyrtdaben ؛ Compound I yridabéne ٠ ؛ ٠٠ Compound i Pyridabéne ٠ ؛ ٠ ا ١o١e ؛ Com flora camide llonicamid ٠. (Compound Compose i 4- tUoiiieiinide lonieamide ب ا Compose</td><td>10 30 10 5 10 50 10-1-80 50 10-200 80 * 10 20 10 * 10 ، 10 10) 00 ؛ ؛) ؛ 70 1000 .... (ا ؛</td><td>60 60- إ 50 80 30 1.4! 0.1 (20 10 4 50 (! 2 () 8. () 10 ؛ '(». 80' 50 70,200 - 100 ؛ 60 200- 50 70,000 ؛ , 80 100 50 '10 60:) 00'10 40 Si.). '..) 00 70 100 -100 * 0 80,000 ؛ - 100 70 1000- 50</td>

<td>Dieldrin Compound 1 ٠. Dieldnne Compose i .... ûieidrme Compound i 4 Dieldrin</td><td>20 0 (, .. 10 10 00 ؛ 4 10 20 1000 .- .؛ t ؛ '</td><td>؛) ؛ 1) 1) 1 r ؛) 2 '() آ),' 0'1 10 ؛ 100 ؛ 20 10 * 50 (00 40 100-100 t ؛ '50 0 *!) 00 ؛ '00 ؛ ؛ 30 1000 .٠ 50</td>

MA 28699US wo 2006/007595

PCT / US2OO5٠ / () 2٦813

<td rowspan="2">Thrips of fitiits pttifs Spmosade Compose 1 + Spinttsade t Spinosade اً Compose Spinosade ب ا ؛؛ Compose</td><td rowspan="2">']'to the (ppm) د 3 '؛ 0 اً</td><td rowspan="2">.Death ٠ / "ا ؛ '، 30 30 90</td><td rowspan="2">Tux (ppm) 0.5 50, 0.! 50-0.5 5 () .. '. 3</td><td colspan="2">”/ ؛, Death,: Rate</td><td rowspan="2">% Mut. إ ((, its) ا 90 إ 10 ؛ (.) 5 60 ا ('.) () ؛</td>

<td>(obs) 60 If) 50 70</td><td>, (ppm) 1 () (), (0.1 10 ().,. (). 5 10 (): -. 1</td>

<td>nil ,، ip١٠ ؛ i</td><td> ().5</td><td> 100</td><td>Ί</td><td> ) 00</td><td> 10</td><td></td>

<td>Composed إ- اً'- Fipronil</td><td>0.5 + 0 ا</td><td> )00</td><td> 5()..,.. 0.5</td><td> 100</td><td> 1 100-0.5</td><td> 100</td>

<td>Compose i -ا- Fipron i)</td><td> 10 + 2</td><td> 100</td><td> 50-1-2</td><td> !00</td><td> 1 100.-12</td><td></td>

<td>Compound] Fipronil</td><td> 10-1-10</td><td> )00</td><td> 50.1-. 10</td><td> 1()0</td><td> 100*10</td><td> 100</td>

<td>Pyriproxyfen</td><td>() اً</td><td> )00</td><td> 100</td><td> 100</td><td> : !000</td><td> 1()()</td>

<td>Compound 1 -ا 'Pyriproxyfen</td><td>(0 'II ؛</td><td> ,00</td><td>ه [.., .. 50</td><td> 100</td><td> 10(.)-1-10</td><td> 100</td>

<td>Composes د اً Pyriproxyfône</td><td> )0+1(.'(()</td><td> 1**1)</td><td> 50+.100</td><td> 100</td><td>0 () 1 -, .. 100 ا</td><td> 10(1</td>

<td>Compound 1 + Pyriproxyfen</td><td> )0.1000</td><td> 100</td><td> 50+1000</td><td> 100</td><td> 100*1000</td><td> 10(.:)</td>

<td>Pymelrozmc</td><td> 10</td><td>00 ا</td><td> 100</td><td> 00؛</td><td> 000؛</td><td> 100</td>

<td>Compose 1 t 'Pymetrozine</td><td> 1().1-10</td><td> 100</td><td> 5()..,.. 10</td><td> 1.00</td><td> ) 100+10</td><td> 100</td>

<td>Compound ب اً Pymetrozine</td><td> '10 ..:..100</td><td> 100</td><td> 0(:-1 .٠. 50</td><td> 100</td><td> ' 10()+1()0</td><td>؛.) ؛) اً</td>

<td>Compound ب اً Pymetrozine</td><td> 1()..:. 1000</td><td> 100</td><td> 50-1000</td><td> 1(.)0</td><td>0 () (.) () 1. '.. () 0 ؛ ا</td><td> 1(00</td>

<td>Buprofezine</td><td> 10</td><td> 20</td><td> 00؛</td><td> 20</td><td> 1()()(0</td><td> 30</td>

<td>Compound 1 i Buprofezinc</td><td> 10 10</td><td> 20</td><td> 50 + 0</td><td> 10</td><td> 100.+ 10</td><td> 30</td>

<td>Compound اً + Buprofezin</td><td> 100 .٠ 0؛</td><td> 0</td><td> 5()..,. 100</td><td> 1(.)</td><td> )001)00</td><td> 20 .0 1</td>

<td>Compose ب- اً- Buprofczme</td><td> 1000 ٠ 10</td><td> 20</td><td> 50+1000</td><td> 20</td><td> ; 100+100()</td><td></td>

<td></td><td> 5</td><td> 40</td><td> 20</td><td> 70</td><td> 150</td><td> ؛ 90</td>

<td>Chlorfenttpyr + ؛ Compound</td><td> 1(11-. 5</td><td> 20</td><td> 5 ٠؛٠. 50</td><td> 30</td><td> : 100 .,.. 5</td><td> 40</td>

<td>Compound ا t 'Otlorfenapyr</td><td> 10 ., 20</td><td> 40</td><td> 50 + 20</td><td> 30</td><td> : 10()-:20</td><td> 4() :</td>

<td>Compound 1 * Chlorfenapyr</td><td colspan="2"> 1().,150 90</td><td colspan="4"> ؛ 0() 150 -+100 90 150 .,..()5</td>

<td>ClilorpyriPos</td><td colspan="2"> 10 20</td><td colspan="4"> 0؛ 1000 10 100</td>

<td>Composed.! -) Chlorpyrios</td><td>(ا ؛.,. ر ؛ ا</td><td> 20</td><td> 50 11()</td><td> 40</td><td> 100+10</td><td> 1!)</td>

<td>Compound 1 - ؛ Chlorpyrifos</td><td> 00؛،()(</td><td> 20</td><td> 00؛ ..,..()5</td><td>to</td><td> 00؛ -00؛</td><td> 10</td>

<td>Compound 1 -f Chlorpyrifos</td><td> )0*1000</td><td> 30</td><td> 50,-1000</td><td> .1(.)</td><td> 1000 ؛100</td><td> 20</td>

<td>Cvromazinc</td><td> 200</td><td> 70</td><td> 500</td><td> 80؛</td><td>i 1000</td><td> 70</td>

<td>Compound ا i Cyttmazinc</td><td> 10 ، 200</td><td> 20</td><td> 50 +- 200</td><td> 70</td><td>MOO - 200</td><td> 80</td>

<td>Compound ب ا Cyromazinc</td><td> 1(),500</td><td> 80</td><td> 50 + 500</td><td> 40</td><td> !00 1(..500</td><td> 40</td>

<td>Compose! ، Cvromazine</td><td> 000؛ ...'-10</td><td> 50</td><td> 5011-1000</td><td> 70</td><td> 100-1000</td><td> ؛)؛,.</td>

<td>،, -) ؛ (&gt; ، 'Cîo١ اً</td><td> 10</td><td> 40</td><td> 00؛</td><td> 70</td><td> 1000</td><td> 60</td>

<td>arbc ، ١١١, ii (ا Compile</td><td> )0..,.10</td><td> 20</td><td> 0؛ 11..()5</td><td> 60</td><td> 100.10</td><td> 7(0*</td>

<td>Compose i أ) -cnttxycarbe</td><td>Ο () ؛., 0 ؛</td><td> 60</td><td> 50 111 100</td><td> 70</td><td> 100 1 1(.)(.0</td><td> 0</td>

<td>FcnoxycarlJc ؛ اً Compound</td><td> )0-1-1000</td><td> 20</td><td> 000؛-؛ 50</td><td> 4(.)</td><td> 10().-1000</td><td> 80*</td>

<td>Melhoprénc</td><td> )!)</td><td> &lt;80</td><td>1 CO</td><td> +1)</td><td> 1000</td><td> 70</td>

<td>Métliopr ne ؛ - أ Compound</td><td> 10 - 10</td><td> 50</td><td>0 ؛ 50 i</td><td> 50</td><td>() 1, () 10 ا</td><td> *0,</td>

<td>Méthoprcne ؛ اً Compound</td><td> 100 ٠٠' 10</td><td> 40</td><td> 50 -1-1()0</td><td> 50</td><td> 00؛ , 00؛</td><td> 8()*</td>

<td>Compose 1 t- Mctltoprnc</td><td> 101-1000</td><td> 60</td><td> 1000؛ 50</td><td> 70</td><td>i) 00. (- 1000</td><td> ...</td>

<td>IndoxiiCcirbe</td><td> 1</td><td> 50</td><td> 500</td><td> 50</td><td> 3000</td><td> 5(}</td>

<td>Compound i) ndoxacarb</td><td> 10.11</td><td> 60</td><td> 50 1, 1</td><td> 60</td><td>ί 100.1.1</td><td>ء) ١ ا ،</td>

<td>Compound ل ا) ndoxacarb</td><td> (0-.5()0</td><td> 50</td><td> 50 1- 500</td><td> 40</td><td> 100-500</td><td> 60</td>

<td>Indoxacarb ا (imposed ؛:.)</td><td> !()...1.2,000</td><td> 50</td><td> 50 1- 3000</td><td> 60</td><td> 3000؛.. 100</td><td> 80*</td>

<td>Triazamatc</td><td> (؛!</td><td> 70</td><td> 1()1()0</td><td> 80</td><td> 3000</td><td> 90</td>

<td>Cotnposé 1 -t Triazamatc</td><td> 10 ٠,؛)؛</td><td> 60</td><td> 50*1.10</td><td> 70</td><td> 100*10</td><td> 9(0*</td>

<td>Composed! -ا Triazamatc</td><td> 1000 ,-0؛</td><td> 70</td><td> 50+ 1000</td><td> 60</td><td> : 100-1)000</td><td> 80</td>

<td>Triazamatc ؛ 1 Compose</td><td> )0.13000</td><td> 70</td><td> 50.1,. 3000</td><td> 80</td><td> 100.3000 ٠؛</td><td> 80</td>

<td>Thiodicarb</td><td> 20</td><td> 60</td><td> 200</td><td> 80</td><td> '2000 ؛</td><td> 000؛</td>

<td>Compound اً t Thiodicarb</td><td> 10 ,.20</td><td> 60</td><td> 50 + 20</td><td> 50</td><td> 100 + 20</td><td> 40</td>

<td>Compound 1 + Thiodicarb</td><td> 10 .-200</td><td> 80</td><td> 50 ., 2()0</td><td> ١0)</td><td> 100 - 20()</td><td> 70</td>

<td>Thiodicarb ؛ اً Compound</td><td> 10- 2000</td><td> 90</td><td> 50 ., 2000</td><td> 100</td><td> 100+ 2000</td><td> 90</td>

<td>Tébttfïiozide</td><td>00 إ</td><td> 70</td><td> 1001</td><td> 60</td><td> 3()(.)0</td><td> 60</td>

<td>Compound i ٠ ï'ébufénoztd ،;</td><td> )0-1-100</td><td> 50</td><td> 50 ,. 100</td><td> 70</td><td> (.)0 ؛ ..,.()10</td><td> 90*</td>

<td>Tebuenod ؛ Compound i</td><td> 000؛ . 0؛</td><td> 80</td><td> 5()-. 1000</td><td> 70</td><td>1 ..) () () 1 ..,. () () اً ؛</td><td> ١0</td>

<td>Compound '1 ؛ ebufeno zide</td><td>0 () () أ .., () ؛</td><td> 70</td><td> 5()....3()()()</td><td> 90*</td><td> 1 10()..,.30()0</td><td> 60</td>

MA 28699US

PCT / US2OO5ZO238i3 wo 2006/007595

<td>Small Thrips ،, beds tietamethrin Cnmpe.sé] + Dltamethrin Compo.se ب ا Dcllamethrinc Compound '..٠ ؛ Dehamelhrin</td><td>Rate (ppm) اا / ”,؛ ا it)! 3 () 0 ()</td><td>% Death, fobs) 70 5 (.) 70 70</td><td>Rate - '(ppm)! 000 50 +10 000 ؛ - ؛ - 50 3000 + 50</td><td>٥ / &lt;&gt; Murt. , - أ ٠١ اا ... 70 70 70 SO</td><td>Rate (ppm) 3000 100 + 10 100,1000 10 ()) 3000</td><td>Dead. ؛ ٠/٠ ((obs 50 (71 70 70</td>

<td>ctxamvl</td><td> ؛</td><td> 3()</td><td> 50</td><td> 40</td><td> .500</td><td>too</td>

<td>Compose ا 'Oxamyl</td><td>ا. 0 ؛</td><td> 20</td><td> ؛ ٠ 50</td><td> 40</td><td>اً ..... too</td><td> ؛ *70</td>

<td>Cinposé i, - Oxamyl</td><td>It) - 50</td><td> 30</td><td> 50..,.. 50</td><td> 60</td><td>50 ..! .. () () ا</td><td> 60</td>

<td>Compound 1 + Oxamyl</td><td>to.,. 500</td><td> 00؛</td><td> 5() -. 500</td><td colspan="2">10 (.) I (»-. 500</td><td> 1(.)0</td>

<td>, Acetamiprid</td><td>ا</td><td> 70</td><td> ()(.)؛</td><td> 90</td><td> 30)00</td><td> 100</td>

<td>Compound 1 ا- Acetamiprid</td><td>إ'ا. ؛ .It</td><td> 70</td><td> ؛ ٠٠؛٠٠ 50</td><td> 60</td><td> 10()..:.. !</td><td>(Λ</td>

<td>Acetamiprid ٠ ؛ - ا Compound</td><td> 10 + 100</td><td> 50</td><td> 50 , 100</td><td>so</td><td> 100+ 100</td><td>SO</td>

<td>Composed of 1 t Acetamiprid</td><td> 1()..,..30()0</td><td> 100</td><td> 5()..-30()0</td><td> 100</td><td> 100 + 3000</td><td> 1)),,</td>

<td>Cartap</td><td>i</td><td> 40</td><td> 10(»</td><td> 1.00</td><td> 3000</td><td> 100</td>

<td>Compose i -) - Cartap</td><td> .؛ , 10</td><td> 100*</td><td> 1 .٠. 50</td><td> 100*</td><td> 10() +1</td><td>إ * 100</td>

<td>Cartap ٠ ؛ ٠ 1 Compost</td><td>1000., 0 إ</td><td> !00</td><td> 000؛+ 50</td><td> 100</td><td> 100 +1000</td><td> 100</td>

<td>Composed! + Cartap</td><td> 3000 ٠. 10</td><td> 100</td><td> 50 .+ 3()()0</td><td> 100</td><td> 100 + 3000</td><td>too</td>

<td>Esferutléraie</td><td>() إ</td><td> 20</td><td> 20</td><td> 40</td><td> 30</td><td> 30</td>

<td>Compose 1 ..٠ ؛ EsPenvaleral</td><td> 0! . ؛)؛</td><td> 40</td><td> 50+- !0</td><td> 60</td><td>too +10</td><td> ؛20</td>

<td>Esfenvalerate ٠- ؛ ٠- 1 Compound</td><td>to'20</td><td> 50</td><td> 50 0</td><td> 50</td><td> 1(.)0-- 20)</td><td> 40</td>

<td>Composed 1 'Es cnvalérale</td><td> ()3-:() ؛</td><td> 40</td><td> 50-3()</td><td> 50</td><td> 100-3()</td><td> 10</td>

<td> 1 ~٦٠^،</td><td>أ</td><td> 20</td><td>. '.) (.) ا</td><td> .30</td><td> 3000</td><td> 40</td>

<td>Compound 1 -ا Thiaclopridc</td><td>ا .٠ ؛ ؛) I</td><td> 30</td><td>ا + 50</td><td> 30</td><td> 100 ..-. 1</td><td> 30 :</td>

<td>Thiaclopridc ا. ا Compose</td><td>100 -ا) اً</td><td> 30</td><td> 50+10(.)</td><td> 30</td><td> 100+ 10()</td><td> ؛.)&lt;٠)</td>

<td>Compound 1 ؛ -Thiacloprid</td><td colspan="2"> 10+.3000 60</td><td colspan="4">50 -.-. 31.) () 0 50 too +. 3000 70</td>

<td>Earn da-c٠'١hai ؛ t.hrine</td><td colspan="2">() 4. 0 اً</td><td colspan="4"> 50 40 250 40</td>

<td>Composed! t Lambda-cyhalothrinc</td><td> 10 - (.؛؛</td><td> 40</td><td> 0؛ .,..()5</td><td> 40</td><td> 10(.)..,. 10</td><td> 40</td>

<td>Cot١١posé! -'٠- Lambda-cyhalothrin</td><td>50 ٠ (آا</td><td> 4٠0</td><td> 50.)50</td><td> 50</td><td> 10() .,. 50</td><td> 50</td>

<td>Compose] -ا- Liimbda-cyhalothrtnc</td><td>250 i () اً</td><td> 30</td><td> 5().,250</td><td> 40</td><td> 100-,250</td><td> 60</td>

<td>l-fydramethylnon</td><td>ا) اً</td><td> 60</td><td> .5(),).</td><td> ,3</td><td> 1000</td><td> 40</td>

<td>؛ Llydramethyltwi ؛ - 1 Compound</td><td> 1().,10</td><td> (.)؛،</td><td> 50 + 10</td><td> 60</td><td> 10)0-, 10</td><td> 50</td>

<td>Hydramethylnon - ؛ ا Compose</td><td> ()(), ؛؛1</td><td> 40</td><td> 50+ 500</td><td> 60</td><td> 500 + 00؛</td><td> 30</td>

<td>Composed! ٠ ؛ Hydramethylnon</td><td>to 000</td><td> 40</td><td> 5().,..1()00</td><td> 30</td><td> 100+1000</td><td> ...</td>

<td>Clothianidin</td><td> 00؛</td><td> 90</td><td> 500</td><td> 00؛</td><td> !000</td><td> 100</td>

<td>Compose 1 ؛ Clothianidin</td><td> (.)('.)؛ ., 10</td><td> 60</td><td> 5() +100</td><td> 90</td><td> 100+100</td><td> ؛؛٦</td>

<td>Clothianidin ٠ ؛ ؛ Compound</td><td> 10 + 500</td><td>so</td><td> 50 + 500</td><td>SO</td><td> 500 .؛..()10</td><td> ؛ 90</td>

<td>Clothianidinc + - ؛ Compound</td><td>000 ؛ , to</td><td> 100</td><td> 50 + 10()0</td><td> 00؛</td><td> 100--. 1000</td><td>ا 10</td>

<td>Lucnuron</td><td> (؛؛</td><td> ،)()</td><td> ()؛)!</td><td>SO</td><td> 500</td><td>؛ so</td>

<td>Compound 1 .٠! .. ufenuron</td><td> 10..)0</td><td> 90</td><td> 50-, )0</td><td>too *</td><td> ؛.,؛٠,٠٠ 100</td><td> ؛؛(:٠٠،</td>

<td>(j٢0i ؛ (i.uféi ؛ ٠ ؛ Compose</td><td> 1()+.100</td><td> 90</td><td> 50 , )00</td><td> 9()</td><td> 100 100</td><td> -)(,</td>

<td>éim٢on '؛ 1 u - ل C'ompo.sé</td><td> 0) ,- 5()0</td><td> 9(.)</td><td> 50 + 500</td><td> *00 ؛1</td><td> 100 . 5(.)0</td><td>؛) با</td>

<td>Abameclinc</td><td></td><td> 00؛</td><td> 10</td><td> (.)؛'؛؛</td><td> 100</td><td> 100</td>

<td>Abamectme ​​؛ ٠ Compound I</td><td>اً., '() ا</td><td>too</td><td> 50 ,. 1</td><td> 100</td><td> ؛ 100</td><td> ....</td>

<td>Abaniectinc ، ا Compound</td><td>10 Ίο</td><td> '!(.)()</td><td>50 ..... to</td><td> 00؛</td><td> 10().-10</td><td> 00؛</td>

<td>Compound ا + Abamectinc</td><td> 00؛ + 10</td><td> 100</td><td> 5(.).,. 1 (.)(.)</td><td> 00؛</td><td> (.؛()( 100</td><td> ()(.؛؛</td>

<td>Methoxy Penozide</td><td>tl)</td><td> 60</td><td> 50</td><td> 60</td><td> 500</td><td> (,()</td>

<td>Compound 1 ؛ Mcthoxyenozide</td><td> 0؛ 0؛</td><td> 50</td><td> 5().,-10</td><td> 60</td><td> 100 -10</td><td> 50</td>

<td>Compound 1 + Methoxvl'enozide</td><td>50 ..,. () اً</td><td> 40</td><td> 50-50</td><td> 50</td><td> 100--50</td><td> 4,)</td>

<td>Composed of tMetlioxyfcnozicie</td><td> 10 + .500</td><td> 60</td><td> 50- 500</td><td colspan="2">() 50 ..-. () 10 إ (),)</td><td></td>

<td>blitcnpyram</td><td> ١'</td><td> 20</td><td> 50</td><td colspan="2"> 50 500</td><td>SO</td>

<td>Niienpv٦٠،١n٦ ا Compose</td><td>5. ، .. (؛ اً</td><td> 30</td><td> 50 - 5</td><td> 30</td><td> 1()0-:- +</td><td> 40</td>

<td>Composed! + Xitctrpyram</td><td>so ، () ؛</td><td> 50</td><td> 50 + 50</td><td> 50.)</td><td> 100-50</td><td> 40</td>

<td>Compose ا - Nitenpyrar</td><td> 10 . 500</td><td> 90</td><td> 50-500</td><td>SO</td><td> !()،)..,.. 500</td><td> 90</td>

<td>Pyridaiyi</td><td> ٠١</td><td> 30</td><td> 50</td><td> 60</td><td> '()()؛'</td><td> ؛0(؛؛</td>

<td>Compound 1 -, lyidaiyl</td><td>لآ.,. 6 '</td><td> 50</td><td> 50 ,5</td><td> 50</td><td> 5-,- 00؛</td><td> .30</td>

<td>Compound 1 + Pyridalyl</td><td> 10 + 50</td><td> 60</td><td> 5().,5()</td><td> 50</td><td> 10())50</td><td> 50</td>

<td>Compound 1 ٠٠ 'Pyridalyl</td><td> 10 + 500</td><td> 90</td><td> 5()+50()</td><td> )(.)()</td><td> 10().-500</td><td>، .I!)</td>

.49

MA 28699US

3 ؛ 238 () / 5 () 13820 ا ٦٦ ح ١ ل

WO 2006/007595

<td>berry hips Dinoruran Compose 1 ؛ Dinolefurane Compose r - ؛ - Dinot fiiranc Dial 1! Dinotefuran</td><td>Rate% Death. ٠l'l'٠n&gt; ..... ، '^,1'M 0.5 50 ) 0: 0.5 40 10-26 40 10 + 510 60</td><td>Rate% Death. Rate% Death, (ppm) (obs) (ppm) (obs) 70 00 ((.) &lt;.؛ 20 * 80 0.5 + 100 ؛ 70 5. () ..: .- 50 * 80 20 -, -. () 10 1 80 20 + 50 80 100+ 100 80 50 + 100</td>

<td>fwvaluron Compound ؛ ' ا-- blovaluro n Compound r + Novaluron Compound r ، Novaluron</td><td>50 ؛ 40 1 :-() 1 (() '100 60 you ١ 100 () 60</td><td> 100 50 1000 80 50 + ! 70 1()()--7 50 50+100 80* ;100-100 80* 70 000؛ ,-00؛ 1 50 000(,-50</td>

TEST c

To assess control of the potato leafhopper (Empoasva fabae Harris) by contact and / or by systemic means, each test apparatus consists of a small open container containing 5 5-year-old Longio bean plants. 1 6 days (primary leaves having emerged). White sand is added to the soil surface, and one of the primary leaves is excised before application. The compounds to be tested are formulated and atomized with 3 repetitions as described for test A. After atomization, the test devices are left to dry! - for one hour before their! () Infestation with 5 potato leafhoppers (adults aged 18,121 days). A black screen cover is placed on the surface of each container. The test devices are held for 6 days in a phytotron at 19-21 د (. 'And 50-7 () (h) relative humidity. Each ballast apparatus is then visually assessed for insect mortality; the results are: set out in) 5 Tables 4Α and 4Β.

table 4٨

Cicadclle ، le. The apple ، the potato

<td>1 ؛ Compost) (ppm)</td><td colspan="2">linidadopndc Report 'τ4' - - '</td><td>Dead. م؟ ((observed</td><td>1 '+. My. (calulated)</td>

<td>٠ 4. () -إ</td><td colspan="2"></td><td> (.)</td><td> -</td>

<td> 1٢4</td><td colspan="2">~ ~ Ί ~ '————— ٠</td><td></td><td> -</td>

<td> 4.6</td><td colspan="2"> — —7—--</td><td> 0</td><td> -</td>

<td> (.')</td><td colspan="2"> 0.2</td><td> 20</td><td></td>

<td> 0</td><td colspan="2"> 0.4</td><td> 0</td><td></td>

<td>- ت</td><td colspan="2">لك 2 2 اا)</td><td> 2() 7</td><td> 20</td>

<td> 0.4</td><td>0.4 i:</td><td></td><td> 0</td><td rowspan="3">Α2٠1٦</td>

<td> 0.4</td><td colspan="2">1: 2.5 ا '71 0.2</td><td> 60</td>

<td> 1.4</td><td colspan="2"></td><td> 27</td>

<td>4. اً</td><td> 0.4 3.5</td><td>اً</td><td> 27</td><td> 0</td>

<td> 1,4</td><td> 1 1.4</td><td> 1</td><td> 40</td><td> .3.0</td>

<td> 4.6</td><td> 0.2 23</td><td>ا</td><td> .1.3</td><td> 20</td>

<td> 4.6</td><td colspan="2"> 0.4 11.5:1</td><td> 33</td><td> 6</td>

<td> 4.6</td><td colspan="2"> 4.6:1 ؛ 1</td><td> 7.3</td><td> 20</td>

MA 28699US

PCT / ٧S2005. ، O2.٦8B * indicates that the observed mortality i is greater than the mortality 1'0 calculated from Colby's equation.

WO 2006/1) 07595

Table 4Β

<td>Potato citadel</td><td>Rate</td><td>% Death.</td><td>Rate</td><td>'3'1 Death.</td><td>Rate</td><td>% Death.</td>

<td></td><td>(ppm)</td><td>(obs)</td><td>(ppm)</td><td>(obs)</td><td>(ppm)</td><td>(obs)</td>

<td>Compound t</td><td>ل</td><td> 23</td><td> 14</td><td> 37</td><td> 50</td><td>i -</td>

<td>Methomyl</td><td> !</td><td> 0</td><td> ٦</td><td> 53</td><td> 5</td><td> !()((</td>

<td>Compound t Methomyl</td><td> ؛ 4</td><td> 53*</td><td> 14-1</td><td> 40</td><td>50-t!</td><td> 53</td>

<td>Compound t أ Methomyl</td><td> 4 - 2</td><td> 67*</td><td> 14 + 2</td><td> 93*</td><td> 50+2</td><td> 87*</td>

<td>Compound 1 ا Methomyl</td><td> ‘1 - 5</td><td>too</td><td> 14-5</td><td> 100</td><td> 5-؛- 50</td><td> 93</td>

<td>Amitraz</td><td> (.؛؛</td><td> 0</td><td> 00؛</td><td> 7</td><td> !000</td><td>٦. إ</td>

<td>Amitra'zc ، ؛ imposed)'.)</td><td>() ا ٠ 4</td><td> ()</td><td> 14(10</td><td> 40</td><td> 5()-(-10</td><td> 40</td>

<td>Compound l + Amitraze</td><td> 4 ، 10()</td><td> 1.</td><td>100 اً 14</td><td> 93*</td><td> 50 - 100</td><td> 80*</td>

<td>Compound 1 - (- Amitraze</td><td> -).-1000</td><td> 53*</td><td> 14-1000</td><td> 87*</td><td> 50 -(-1000</td><td> 93*</td>

<td>Fhiamethoxam</td><td> 0.1</td><td>SO</td><td> 2.(؛</td><td> 1.00</td><td> 0,4</td><td> !00</td>

<td>Compound t ؛ Thiamethoxam</td><td> 4 - 0.1</td><td> 70</td><td> 14-0.1</td><td> ١٦)</td><td> 50-(-0.1</td><td> 61</td>

<td>Composes lliiamethoxam</td><td> 4 - 0.2</td><td> 73</td><td> 02 -؛- 14</td><td> 73</td><td> 50+0,2</td><td> 60</td>

<td>rhiamethoxam '؛ .1 Compound</td><td>0.4 - اً 4</td><td> 93</td><td>0.4 ب 14</td><td> 100</td><td> 50 + 0,.4</td><td> 00؛</td>

<td>Pyridabénc</td><td> 1</td><td> 0</td><td> 2.5</td><td> 13</td><td> 10</td><td> !00</td>

<td>Compound 1 t- Pyridatene</td><td> ؛ ., 4</td><td> 7</td><td>ا - 14</td><td> ...</td><td> 50-(- !</td><td> 33</td>

<td>Compound 1 i Pyridabénc</td><td> 2.5 -٠ 4</td><td> 20</td><td> 2.5'؛. 14</td><td> 33</td><td> 50-2.5</td><td> 47</td>

<td>Compound 1 + Pyridaben</td><td>10 ؛ · أت</td><td> 47</td><td> 14+10</td><td> 33</td><td> 50-(-10</td><td> !00</td>

<td>Flonieamide</td><td> !00</td><td> 10(.)</td><td> -)00</td><td> 100</td><td> 1000</td><td> ...</td>

<td>Compound 1 ٠ Flonieamide</td><td> 4-(-100</td><td> 100</td><td> 14-(-10()</td><td> 100</td><td> 100 ٠-50</td><td> 00؛</td>

<td>Compound 1 ؛ Flonieamide</td><td> 4 - .)00</td><td> 100</td><td> 14-(- 400</td><td> 93</td><td> 50 -!- 40()</td><td> 100</td>

<td>Compound 1. -اً- Flonieamide</td><td> 4-1000</td><td> 100</td><td> 1.4-1000</td><td> !00</td><td> 50 -1000</td><td> 00؛</td>

<td>Dicldrin</td><td> 25</td><td> 27</td><td> ' 5</td><td> 100</td><td> 0؛</td><td> 00؛</td>

<td>Compound 1 - (- Dieldrme</td><td> 4*- 2.5</td><td> 33</td><td> 14-(-2.5</td><td> 93*</td><td> 50 -2.5</td><td> 3.3</td>

<td>Compound 1 -t- Dieldrinc</td><td> 4 - 5</td><td> 67</td><td>5 إ 14</td><td> 100</td><td> 5((--5</td><td> 100</td>

<td>Compound ا - Dieldrin</td><td> 0؛ ! 4</td><td> 100</td><td> 14.(10</td><td> 100</td><td> 50 -10</td><td> 73</td>

<td>Spinosade</td><td> 0؛</td><td> 4'7</td><td> 30</td><td> 73</td><td> !00</td><td> 80</td>

<td rowspan="2">Spinosade ؛ 1 Compound Spinosade -اً- 1 Compound</td><td>10 - ا-</td><td> 57*</td><td> 10 - 4؛</td><td> 73*</td><td> 50 -!- !0</td><td> *00؛</td>

<td> 4 . 50</td><td> 100*</td><td> 14-(-30</td><td> 100*</td><td> 50 -30</td><td> *00؛</td>

<td>Spinosade - ؛ - 1 Compound</td><td> 4-100</td><td> 100*</td><td> 14(-100</td><td> 100*</td><td> 50-100</td><td> *00؛</td>

<td>Fipronil</td><td> 0.5</td><td> 7</td><td> .1</td><td> 20</td><td> 1.5</td><td> 2*</td>

<td>Compound 1 -i- Fipronil</td><td> 4 - 0.5</td><td> 20</td><td> 14 0.5</td><td> 40</td><td> 50-((.5</td><td> 60</td>

<td>Compound 1 -t- Fipronil</td><td> 4 - !</td><td> 40</td><td> 1-1</td><td> 53</td><td rowspan="2"> ؛ )- ؛)5 50+1.5</td><td> 93*</td>

<td>Compound t Fipronil</td><td> 1.5 ؛-4</td><td> 5'3*</td><td> 14-1.5</td><td> 33</td><td> ٦?'</td>

<td>Pyri proxyfene</td><td> 10</td><td> 13</td><td> !00</td><td> 0</td><td> 1000</td><td></td>

<td>Compound i Pyriproxylene</td><td> 10 - ٠(-.</td><td> 13</td><td> 14 + 10</td><td> 53*</td><td> 50-10</td><td> ٦٩.</td>

<td>(. '(. imposed 1 ل Pyriproxyl'ene</td><td> 4-100</td><td> 33*</td><td> 14 - !00</td><td> .13</td><td> 50 - 100</td><td> 5 +</td>

<td>Compound أ Pyriproxytcne</td><td>1000 -ع</td><td colspan="2"> 33* 1-11000</td><td> 53</td><td> 50 -1000</td><td> 40</td>

<td>Pymetrozine</td><td> ١.'.</td><td> 0</td><td> 15</td><td> 13</td><td> 200</td><td> 60</td>

<td>Compound .1 Pymetro one</td><td>2 - ب.</td><td> 20</td><td> 1+-(-2</td><td> 60*</td><td> 50 *- 2</td><td> ~3*</td>

<td rowspan="2">Compound 1 اً Pymetrozine Compound 1 ب Pymelrozine</td><td colspan="2" rowspan="2"> *53 15 '٠ 4 53 (.)20-! 4</td><td> 14-15</td><td> 60*</td><td> 5((-15</td><td> 73 *</td>

<td> 14(-200</td><td> 87*</td><td> 50 - 200</td><td> ؛)7'</td>

<td>Bupro 1'ézine</td><td> 10</td><td> 20</td><td> 100</td><td> 20</td><td> 1000</td><td> 0</td>

<td>Compound 1 Bupro 1'ézine</td><td> 10 ؛ 4</td><td> 0</td><td> 14+10</td><td> !3</td><td> 50 ، 10</td><td>ع ٠ ي</td>

<td rowspan="3">Compound 1 -1- Buprolizine ؛ Compose 1 - Bupro iZin ؛ Llorfenapy ' ١y r] I اثا 11 ؛ ؛ 1 قة Chlori'énapvr! ا Compound</td><td> 100 ؛4 1000 - 4</td><td colspan="3"> 0 100-)114 20 0 000؛ -14 13</td><td> 50.-100 50-!-1000</td><td> 0</td>

<td> 1 ؛ . 4</td><td> 73 57*</td><td> ,٠٠٦؛</td><td> 100 80</td><td> 20 ! - ؛.)5</td><td> !00 !00*</td>

<td> 5؛ 4</td><td> !00</td><td> 14-(-5</td><td> !00</td><td> ٠٠١. ) („)٦</td><td> 00؛</td>

<td>Clilorfii ipiu - ؛ - 1 ؛ ^ Compo</td><td> 4 - 20</td><td>Κί</td><td> 14-20</td><td> ()()؛</td><td>5 (! -. 2Ο</td><td> !00</td>

<img file="MA28699B1_D0005.tif" />

MA 28699US

WO 20 (16.0 () 7595

0(210..820)05.,()2.1813

<td>Potato leafhopper (/ hlrpyniiis Compose 1 ت Clalorpynlbs Compound 1 -tChlorpyrilbs Compound 1 + Chlorpyrilos</td><td>Rate (ppm) K).-1 - (1 ()) - ؛ - too 4 .... 1000</td><td>% Death. (obs) 13 ة 0</td><td>Rate (ppm) 100 14-1--10 100 ؛ 14 00 () 1 - 1 14</td><td>% Word. (obs) 0 0 13</td><td>Rate (ppm) 1000 50 1-10 100 -٠- 50 1000 ؛ 50</td><td>% Mart (obs) Ï</td>

<td>Cyromazine</td><td> ؛,؛؛</td><td> .</td><td> 10.0</td><td> 0</td><td>i (.) () (. 1</td><td></td>

<td>Compound 1 + Cyrominc</td><td>10 اً- 4</td><td> 7</td><td> 1+1()</td><td> 7</td><td> 50-,-10</td><td> 60*</td>

<td>Cyromaztnc ؛ ا Compound</td><td>too - ؛ - 4</td><td> 0</td><td> 100 +4؛</td><td>لا</td><td>50+ too</td><td> 100’</td>

<td>Compost1 ؛ Cyromazine</td><td>1000 -اً 4</td><td> 13</td><td> 14-1000</td><td> 27</td><td> 50 + 1000</td><td> 33</td>

<td>Fenoxycarb</td><td> !0</td><td> 0</td><td> 100</td><td> 20</td><td> 1000</td><td> 0</td>

<td>Compost 1 ٠ Fenoxycarb</td><td> 10-؛-؛‘</td><td></td><td> 14+-10</td><td> 13</td><td> 50-1-10.1</td><td> 40</td>

<td>Compound 1 ا Fenoxycarb</td><td>100 -د 4</td><td>لا</td><td> 14 + 100</td><td> 13</td><td> 50-100</td><td> 20</td>

<td>Compound 1 t Fenoxycarb</td><td> 1000 ؛4</td><td> '13</td><td> 14.-1000</td><td> 27</td><td> 50-,-1000</td><td> 13</td>

<td>Methoprene</td><td> 10</td><td> 0</td><td>lot</td><td> 0</td><td> 1000</td><td> (.)</td>

<td>Compound 1 -1- Methoprene</td><td> -1 - 10</td><td> 20</td><td> 14-1-10</td><td> 100*</td><td> 50 -1-10</td><td> ،03*</td>

<td>Compound 1 + Methoprene</td><td> 4-100</td><td> 13</td><td> 14 100</td><td> 73*</td><td> 50 100</td><td> ،&gt;3*</td>

<td>Compound 1 1 Methoprene</td><td> 4 - 1000</td><td> 87*</td><td> 14-1000</td><td> 8(1*</td><td> 50 -,.1000</td><td> 100*</td>

<td>Indoxacarb</td><td> 0.5</td><td> 33</td><td> 1</td><td> 20</td><td> 2</td><td> + ٦</td>

<td>Compound 1 1 Indoxacarb</td><td> 4-- 0.5</td><td> 7</td><td> 410.5؛</td><td> 20</td><td> 50 0.5</td><td> ٠١7</td>

<td>Compose 1 1 Indoxacarb</td><td>إ ه- ا</td><td> 0</td><td> 1+---11</td><td> 47</td><td>1 د 50</td><td> ؛٦٠</td>

<td>Indoxacarb - ؛ 1 Compound</td><td> 4-2</td><td> 0</td><td> 14,2</td><td> 27</td><td> 50 -1-2</td><td> 87»</td>

<td>Triazamatc</td><td> ٦.0</td><td>أ .1</td><td>i</td><td> (0</td><td> 2</td><td> 7</td>

<td>Compound 1 -اً- Triazamatc</td><td>0.5. م.</td><td> !3</td><td> 14,-(0.5</td><td> 33</td><td> 0.5 ؛ 50</td><td> 80*</td>

<td>Triazamatc - ؛ - ١ Compound</td><td>1 اً 4</td><td> 13</td><td> 14-1-1</td><td> .33</td><td>50 -, - i</td><td> 20</td>

<td>Compound 1 -t- Triazamatc</td><td> 2 ؛4</td><td> 0</td><td> 11-2</td><td> 80*</td><td> 50 -1-2</td><td> 7</td>

<td>Thiodicarb</td><td> 0.08</td><td> 0</td><td> 0.16</td><td> 20</td><td> 0.4</td><td> 20</td>

<td>Thiodicarb '- ؛ - 1 Compound</td><td> 4 - 0.08</td><td> 7</td><td> 14-0.08</td><td> 47*</td><td> 08.(.؛ - 50</td><td> ؛2</td>

<td>Compound) ؛ Thiodicarbc</td><td> 4’0.16</td><td> 13</td><td> 14-0.1(1</td><td> 1.3</td><td> 50-0.16</td><td> 60</td>

<td>Compound 1 ؛ Thiodicarbc</td><td> 0.4 -؛- 4</td><td> 20</td><td> 14(-0.4</td><td> 0</td><td> 50.)-(-0.4</td><td> 93*</td>

<td>Tebufenozide</td><td> 3</td><td> 40</td><td> — 4</td><td> 27</td><td> .</td><td> 20</td>

<td>Compound] -٠- Tébufcnozide</td><td> 3 -٠- 4</td><td> 27</td><td> 14 + 3</td><td> 2'7</td><td> 50 - 3</td><td> 93*</td>

<td>Compound ب ا- Tcbrrfénozidc</td><td> 4-؛ 4</td><td> 40</td><td> 4 ٠ 14</td><td> 67*</td><td> 50-4</td><td> 47</td>

<td>Tebuteozide - ؛ 1 Compound</td><td> 5 ؛4</td><td colspan="2"> 20 14 15</td><td> 100*</td><td> 50 15</td><td> 47</td>

<td>Deltamethrinc</td><td> 04</td><td> 7</td><td> 0.2</td><td> 7</td><td>I</td><td> 60</td>

<td>Compound 1 ٢ Dehamétlmrme</td><td> 1 .؛.؛ 1-4</td><td> 13</td><td> 1.(1 -٠ 14</td><td> 53*</td><td> 50 0.1</td><td> 73*</td>

<td>Deltamcthrinc - ؛ - .1 Compound</td><td> 0.2 .؛ 4</td><td> 40</td><td> 14-,- 0.2</td><td> 33</td><td> 50 -- 0.2</td><td> 1(0(0*</td>

<td>Deltamethrinc (؛ Compound</td><td> 4’1</td><td> (,()</td><td> 14-1-1</td><td> 100*</td><td> 50..(..1</td><td> !00*</td>

<td>Oxamyl</td><td> 0.1</td><td> 20</td><td> 2</td><td> 20</td><td> 100</td><td> 1(00</td>

<td>Compound 1 -1- Oxamyl</td><td>1.1 ؛ د 4</td><td> 7</td><td> 14-:-0.1</td><td> 73*</td><td> 50’0.1</td><td>X'7 *</td>

<td>Oxamyl - ؛ - 1 Compound</td><td>2 ،. اك</td><td> 1</td><td> 14-,-2</td><td> 33</td><td> 5(0-,..2</td><td> 60</td>

<td>Compound ا- ا- Oxamyl</td><td> 4-, 100</td><td> 93</td><td> 14-100</td><td> 100</td><td> 50-11)0</td><td> 1(0(0</td>

<td>ttexaflimuron</td><td>roof</td><td> !3</td><td> 1000</td><td> 1.3</td><td> 3000</td><td> ١7</td>

<td>lexaflumuron! - ؛ - ا Comnpose</td><td>too ؛ 4</td><td> '1</td><td> 14 , 100</td><td> 33</td><td> 50 -- 1(.)0</td><td> 80*</td>

<td>Compound 1 + Hexatlumuron</td><td> 000؛ 4</td><td> 13</td><td> 141-1000</td><td> 80*</td><td> 50 + 1000</td><td>s &lt;٠7 ب</td>

<td>lexaflumuron - ؛ - ؛ Compound</td><td> 4 31.1()0</td><td> 33</td><td> 14 1-3()0()</td><td> 53</td><td> 50 + 3000</td><td> 8(0’</td>

<td>Acetamiprid</td><td> 1</td><td> '21</td><td>ن</td><td> 60</td><td> 12</td><td> -—٦٦</td>

<td>Compound 1 t- Acetamipridc</td><td> 1 - ؛٠-</td><td> 7</td><td> 1 -,- 4؛</td><td> 20</td><td> 1 ؛ 50</td><td>٦T</td>

<td>Compound 1 -٠- Acetamiprid</td><td> 4 -- 4</td><td> 60</td><td> 14+-4</td><td> 60</td><td> .50 - 4</td><td> 60</td>

<td>Compound 1 -1- Acctamiprid</td><td>12 اً- 4</td><td> 87</td><td> 14+12</td><td> 10(0*</td><td> 12؛ 50</td><td> ،0.3</td>

<td>Cartap</td><td> 0.1</td><td> 20</td><td>'ï - -</td><td> 73</td><td> !0</td><td> ؛0(10</td>

<td>Cartap - ؛ - 1 Compost</td><td> 4--- 0.1</td><td> 33</td><td> 14.’-().1</td><td> 4.7</td><td> 50-0.1</td><td> ؛١)</td>

<td>Cartap - ؛ - .1 Compound</td><td> 1 -؛ 4</td><td> 60</td><td> 14+-1</td><td> 73</td><td> 50 - 1</td><td> 47</td>

<td>Compound 1 -i- Cartap</td><td> 4+10</td><td> 100</td><td> 10--,-؛1</td><td> 100</td><td> 50)-,-10</td><td> 0(0؛</td>

<td>Es٢en \ 'aléra (e</td><td>وا 0</td><td> 47</td><td></td><td> 80</td><td> 2</td><td> ٦٦</td>

<td>Esfenvalerate - ؛ - 1 Compound</td><td>0.5 -ل 4</td><td> 20</td><td> 14 1().5</td><td> 67*</td><td> 50-0.5</td><td> 73</td>

<td>Compose 1 + Esfenvalèrate</td><td> 4 -- 1</td><td> 61</td><td> 14 + 1</td><td> 87</td><td> 50 -,- 1</td><td> ،)3</td>

<td>Compound 1 Esfenvalerate</td><td> 4</td><td> 87*</td><td> 14,-2</td><td> 53</td><td> 50.) ,-2</td><td> 93*</td>

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<td>Potato leafhopper Thiaclopnde Compound 1 ؛ Thiacloprid Compound ا + Tiliacloprid Composed 1 ل 'fhiacloprid</td><td>t aux / ٠ Death. ؛ False '(' ٥ Death, (ppnt) (obs) (ppm) (obs) 0 2 1 '1' 73 II د 9 د 0 ا ج 4 -, - 0.2 27 I 14-10.2 53 4-0.5 53 14, (). 5 80 4 1.5 100 * 14 +1.5 100 *</td><td>.11) 51 4 “Laux (Its ,؛) (ppm) 80 1.5 '* () ؛) ا 50: 0.2 80 5. (), 50 * 00 ؛ 1.5--50</td>

<td>Lambda-cyhalothrin Compound 1 -r- Lambda-cyhallhnnc Compound 1 -1 lambda-eyhaohrin Compound 1 '٠- Lambda-cyhaleahrin</td><td> 0.01(, 73 0.08 0 4 -(,.016 47 :14,().0)6 100* *93 18)4+1؛ *47 18.()-4 *100 1) + 14 *100 1.4 + 4</td><td> 0.4 87 50-0.(06 1()()- 50-0,08 87* 50--0,4 100*</td>

<td>Hydramethylnon Co١٦٦pose 1 ؛ Hydrai'nèlhylnon Compound 1 -t- Hydramethylnon Compound 1 + · Hydramethylnon</td><td>4- (1.05 27 14-0.01 (C * 73 1- 14 ؛ 2014 * 87 2- + 14 40 4-2</td><td>١ ا ١). 2 ; 50-0.01 “00 ؛ ا -, - ؛,)? '100 2-, 50</td>

<td>Clothianidinc Compound 1 + Clolhianidine Compound 1 ؛ Cloahianidin Compound 1 ؛ Clhianidin</td><td>10 93 '100 100 4 - 00 ا 10 + 14 100 0 ا 4-, 100 io () 00 ن 100-1 14 إ 4 -, - 1000 100 14 -, - 1000 100</td><td> 00! 1000 ؛)()؛' ()؛-,-50 ()؛)! 100- 50 100 50+1000</td>

<td>Lufenuron Lulenuron ؛ Composed in Lulenuron ؛ 1 Compose (..ompose 1 Lutenuron Abamcune Abaniecline- ؛ 1 Compound Abamecaine + ا t'omposé Abamecaine ٠ Compound 1</td><td>53 0.4 40 0.08 * 87 0.08 - 14 * 60 08 .؛) - 4 67 14-0.4 ا 47 4.4 - 4 27 2 + 14 47 4-2 00 ؛ 100; 47 0 ؛ * 93 1) 1- 14 * 87 10 4 100 100- 14 100 100 د 4 100 () 100- 14 100 4 + 1000</td><td>2 40 50 -0.08 87 * 73 م 0 ١0 * 100 '٠ ا) ١ 00 ؛ 1) 10) 1 * 93 ؛-) ؛ , 100 0 () 1--70 00 ؛ 1000- 50</td>

<td>Methoxyfenozide Compound 1 - ؛ Methoxyfenozide Compound 1 t- Methoxyfenozide Compound 1 + Methoxyfenozide</td><td>3! 0.4 3 ا 0.08 * 73 14-0.08 13 4-0.08 7 '14-1-0.4 13 4-0.4 * 00! 2+ 14 27 2'4</td><td> 50-1,()8 1(10* 50-0,4 100* *00؛ 2-1()5</td>

<td>Nitcnpyram Compound 1 + 'Nitenpyram Compound î atsiiaenpyrm Compound 1 tNitenpvram</td><td>73 1): 7 ؛: :( :) * 100 0.3 - 14 '7 0.3 - 4 * 110 0.4 '4 ؛ - 7 4 ة - ؛, - * 00 ؛ 0.5. + 14 7 0.5 --- 4</td><td>* 00 ؛ 3, () '- ا'ن 5 13 50-0.4 3 ؛ 0.5-50</td>

<td>Pyridaiyl '' ' Compound 1 + Pyridalyl Pyridalyl 'ا- ا Compound Pyridalyl - ؛ - 1 Compound</td><td>'7 0.5 ؛ 0.5 7 Co 'ت 4 13 5 + 14 0 4 + 5 13 50- + 114 13 4-50</td><td> ؛)2 0,5 - 50 ٦ 50-5 7 50 -50</td>

<td>Dinotcfuranc Compound 1 ؛ Dinotcfurane Compound 1 - ؛ - Dinotefuran Compound a + Dinotéfura ne</td><td> 002 7 0.08 7 4,-0 02 7 14 + 0.02 53* *67 0.08- 4؛: 7 008- 4 *100. 14-0.4 1 *(.)()؛ 4+)--4</td><td>47 0.4 * (.) ؛) 50-0. () 2 I * 100 50-0.08 * 100 0.4 -: - 50</td>

<td>Novaluron Compose 1 ا Novaluron Compound '1 - Novaluron Compound 1 ؛ Novaluron</td><td>7 510 7 ؛ 251 i 4: 250 7 i 14 250 60 * ن 67 500 - ؛ - ذا 13 0 () 5 4 * 7 ') 1000- 14 * 47 4-1-1000 إ</td><td>1000 III 0 ' * 67 250 -, ؛) 5 * 0 ؛) ؛ غ - 50 * 9.3 (.) 0 (.) 1 - () 5</td>

TEST D

To assess' May leafhoppers l (Peregrines w ، 7 / ، //. W by contact and / or by systemic means, each test device consists of a small open cylindrical container containing a 3 to 4 day old corn plant 5 (, ear) . White stable is added to the surface of the soil prior to application. The compounds to be tested are formulated and atomized with 3 repetitions as described for test A. After atomization, the testing apparatus

MA 28699US

د ؛ 82005/0238 ؛ Τ'Ο ') (؛ wo 2006.007595 test are left to dry for an hour before being post-infested with 10-20 maize leafhoppers (nymphs 18-20 days old) which are spread over the sahle with a salt shaker A black screen cover is placed on the surface of each container The test devices are kept for 6-5 days in a phytotron at 19-21C and 5O-7O٥'t relative humidity. Each test device is then visually assessed for insect mortality; the results are shown in Tables 5A and 5Β.

Table 5Α

<td colspan="4">Cicadelledumais</td>

<td>1 ؛ Compound (ppm)</td><td>Imidacloprid Report (ppm)</td><td>% Death, (observe)</td><td>(;-)Word. (calculation%</td>

<td> 5</td><td>- - 7 - ί لنخل -</td><td>٦ pl</td><td></td>

<td> 50</td><td> 0</td><td> ،1</td><td></td>

<td> 150</td><td>δ T:</td><td> 28</td><td></td>

<td> 0</td><td colspan="2"> 0.1 27</td><td> -</td>

<td> (.)</td><td colspan="2"> ٦ 37 0.3</td><td> --</td>

<td> 0</td><td colspan="2"> 1(- 60</td><td> -</td>

<td> 5</td><td>ot 50: 1</td><td>أ</td><td> 31</td>

<td rowspan="2"> ٩ — ٢ —</td><td> ().3 16.7:1</td><td> 8</td><td> 41</td>

<td> 1 5:1</td><td> 15</td><td> 62</td>

<td> 50</td><td> 0.1 500:1</td><td>ن ،</td><td> 34</td>

<td> 50</td><td> 67:1؛ 0.3</td><td> .5</td><td> -43--—’</td>

<td> 50</td><td>- 50: 1 '1 ا</td><td> 13</td><td> 64</td>

<td> 150</td><td> 0.1 1500:1</td><td> 8</td><td> 47</td>

<td> 150 150</td><td>ill ٠ رن 50: 1 ؛ - (- 1 “'-</td><td> 5</td><td> 55 - ؛٦........</td>

Table 513 * indicates that the observed mortality '؛' U is greater than the mortality T0 calculated from Colby's equation.

<td>Corn cicadelk</td><td colspan="2">Rate ٥ / ο Death. ا Rate / ١ &lt;ا! Mt, Rate '؛ To Death, (ppm) (obs) (ppm) (obs) (ppm) (obs)</td>

<td>c'ompo.sé 1 Methomyl Compound i + Methonyl Compound ؛ Mcthomy, Compound 1 - Methomyl</td><td colspan="2"> 28 ~ 500 19 “00 - ا 15 20 - 6 5. () ؛ 500 23 0.5 ؛ 100 إ 5 5.20 ΐ'ο 2 1 -1 06 500 ί ؛ 100 20 '1 7 I ة 2; 0 ااً 34 2 ؛ 100 إ 2 2 ؛ 0 ذ</td>

<td>Amitiaze Compound .1 -ا Amitraz (./(.imposed 1 -i- Amitraz Compound ؛ + Amitraz</td><td> 5 6 20-.-5 2 ؛؛ 50-:()2</td><td>5 50 3 0 ؛ 0 5 -: - 500 (. ') 1: 5) 10 و) () 1.1-500 ؛ 3 () 1 + () 10 10 50 + 500 8 50 + 00 ؛</td>

<td>Thiamétl xame ١mc ؛ ١ox ؛ ١iamét ؛ T -: ؛ Compound Tiliamethoxam - ؛ - ؛ Compound Tliiametl ') o.xaine د ؛ Compound</td><td> 1.00 2..0 (.)()؛. 20:0.2 100 0.4-:()2 100 06 ! 20</td><td> 00؛ ,).() 00؛ 0.4 8(؛ 2.((-:-(501 73 0.2(00؛ 100 0.4- 500 00؛ 0.4-00؛ 100 0.6- 500! 100 0.6 ؛ 00؛</td>

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ب اً O2? S / S2O0١^: ا '^ا٦٦ ب (ا

WO 2006. ") 7595

<td>Leafhopper (111 corn iyridahnc Compose 1 ؛ Pyridabene Compound 1 ؛ Pyridabene Compound 1 + Pyridabene</td><td>False (ppm) 2 ب 20 2 ()) -2.5 20 I 3</td><td>% M rt. (lbs) 10 57 * 48 * 19 *</td><td>Rate. (PP ™) .. 100: -2.5 1 () 0 -: - 3</td><td>% Death, (obs) 14 16 17</td><td>'!'to the (ppm) soo 2 500 - 2.5 500 +3</td><td>1. Death.&gt; + ؛ ' ((obs ن</td><td></td>

<td>Flonicamid</td><td> 2</td><td> 52</td><td> 15</td><td> 42</td><td> 150</td><td> 90</td><td></td>

<td>Compound 1 + Flonicamid</td><td> 20 + 2</td><td> 100*</td><td> 10()-,.2</td><td> 31</td><td> 2 .٠. 500</td><td> 68</td><td></td>

<td>Compound 1 t Flonicamid</td><td> 20-15</td><td> 100*</td><td> 100-(-15</td><td> 50</td><td> 500 + 15</td><td> 100*</td><td></td>

<td>Flonicamid - ؛ - 1 Compound</td><td> 20-1-150</td><td> 59</td><td> 100-(.-15()</td><td> 42</td><td> 500 - 150</td><td> 100</td><td></td>

<td>Dieldrin</td><td> 0.1</td><td> 37</td><td> 0.2</td><td>لأ</td><td> 0..3</td><td> 71</td><td></td>

<td>Compound 1 -٠ Dieldrin</td><td> 20 + 0.1</td><td> 32</td><td> 100 -(-(.)..1</td><td> 92*</td><td> 500 --,-0,1</td><td> ؛:98</td><td></td>

<td>Compound 1 + Dieldrin</td><td> 20 !. 0.2</td><td> 88*</td><td> 11+0-00</td><td> 88*</td><td>0.2 ا 00+</td><td> 10</td><td></td>

<td>Compound 1 + Dieldrin</td><td> 20 - 0,3</td><td> 36</td><td> 100 + 0.3</td><td> *00؛</td><td> 500 + 0,3</td><td>بب: ٠٦ (ن</td><td></td>

<td>Spinosadc</td><td> 5</td><td> 1.00</td><td> 10</td><td> 100</td><td> 20</td><td> 100</td><td></td>

<td>Compound ا + Spinosadc</td><td>5 ز 20</td><td> 100</td><td> 100 + 5</td><td> 100</td><td> 500 : 5</td><td> ()؛.11</td><td></td>

<td>Spinosade + ؛ Compound</td><td>20 iO</td><td> 100</td><td> 100 -.(..1()</td><td> 100</td><td> 500.(10</td><td> 00؛</td><td></td>

<td>Compound ب إ Spinosade</td><td> 20- 20</td><td> 100</td><td> 1()()-(- 20</td><td> 100</td><td> 500 -20</td><td> ()()؛</td><td></td>

<td>Fipronil</td><td> 0.5</td><td> 5</td><td> 1</td><td> 41</td><td> 1,5</td><td> ١٦</td><td> ؛</td>

<td>Compound 1 - + Fipronil</td><td> 20 - 0.5</td><td> 29*</td><td> 100 : 0.5</td><td> 5</td><td> 500 .., 0,5</td><td></td><td></td>

<td>Compound 1 + - Fipronil</td><td> ؛ - 20</td><td>2 و</td><td> 100 ,-1</td><td> 7</td><td> .500 - 1</td><td> 1؛</td><td></td>

<td>Compose 1. + Fipronil</td><td> 2(.)-1.5</td><td> 15</td><td> 100+15</td><td> 9</td><td> 500 -1,5</td><td> 8</td><td></td>

<td>Pyriproxylnc</td><td> (؛؛</td><td> 0</td><td> 100</td><td> 8</td><td> 1000</td><td> 12</td><td></td>

<td>Compound '1 Pyriproxyfenc</td><td> 10 ٠ 20</td><td> ،)</td><td> 100 -(-1()</td><td> 17</td><td> 10 :٠ 500</td><td> 14</td><td></td>

<td>Pyriproxytnc + ؛ Compound</td><td> 20 -100</td><td> 28*</td><td> 100-)1()0</td><td> 10</td><td> 5()0-:.- 100</td><td> 6</td><td></td>

<td>Pyriproxyfenc ؛ 1 Compound</td><td> 20 +1000</td><td> 11</td><td> 100-1000</td><td> 5</td><td> 50(.1+100()</td><td> 3</td><td></td>

<td>lymetroziic</td><td> 2</td><td> 51</td><td> 10</td><td> 29</td><td> 30</td><td>S9</td><td></td>

<td>Compound 1 Pymetrozinc</td><td> 2. -؛ 20</td><td> 20</td><td> 100 .,-2</td><td> 32</td><td> 5(.)0-2</td><td> ١٦)</td><td></td>

<td>Compound 1. ب .Pymetrozinc</td><td> 20.-10</td><td> 50*</td><td>1ΟΟ-ΙΟ</td><td> 58*</td><td> 0؛ :.,-500</td><td> ...</td><td></td>

<td>Compound 1 + Pyncirozinc</td><td> 20-30</td><td> 81</td><td> 100-30</td><td> 89</td><td> 500 -.,. 30</td><td> !00*</td><td></td>

<td>Buprofezin</td><td> 10</td><td> 96</td><td> 100</td><td> 97</td><td>0 ذ 10 10 ج 500</td><td> 98</td><td></td>

<td>Compound 1 + Buprofezin</td><td> 20-10</td><td> 92</td><td> 00-10؛</td><td> 86</td><td></td><td> 89</td><td></td>

<td>Compound 1 -1 Buprofezin</td><td> 20-100</td><td> 94</td><td> 100 + 100</td><td> 90</td><td> 500 ., 10(.)</td><td> :.)8</td><td></td>

<td>Compound 1 -ا- Buprofezin</td><td> 20 - 1000</td><td> 93</td><td> 100 + 1000</td><td> 80</td><td> 500+1000</td><td> 96</td><td></td>

<td>Chlorfenapyr</td><td> 1.5</td><td> 31.</td><td> 2,5</td><td> 15</td><td> 3.5</td><td> 11</td><td></td>

<td>Compound 1 'Chlorfenapyi</td><td> 20 - 1.5</td><td> 68*</td><td> 100 -. 1,5</td><td> 41</td><td> 5()0 -. 1.5</td><td> 64*</td><td></td>

<td>Compound 1 -t Chlorfcnapyr</td><td>5 ن ٠ 20</td><td> 18</td><td> 1(+() , 2,5</td><td> ؛:42</td><td> 50().:. 2.5</td><td> 18</td><td></td>

<td>(imposed 1 - * - ChlorfénapyT</td><td> 3.5 ؛ ١0</td><td> 34*</td><td> 100-3.5</td><td> *(؛3</td><td> 500 .-.3.5</td><td>X</td><td></td>

<td>Chlorpyrifos</td><td> 0 1</td><td> 46</td><td> 0.2</td><td> 24</td><td> 0..3</td><td>ب'أ</td><td></td>

<td>Compound 1 - Chlorpyrifos</td><td> 20+().1</td><td> 40</td><td> ؛.('.) +100</td><td> 29</td><td> 5()0 0.1</td><td> ١٠١</td><td></td>

<td>Compound 1 * Chlorpyrifos</td><td>20 I 1 ..). 2</td><td> 47*</td><td> 0.2 .٠. 100</td><td> 2(.)</td><td>0.2 ، () ؛ لآ</td><td> ٦٦</td><td></td>

<td>Compound 1 -! '- Chlorpyrifos</td><td> 20-:-().3</td><td> 14</td><td> 100 + 0.3</td><td> 50*</td><td> 500 , ().3</td><td> 58*</td><td></td>

<td>Cyromazine</td><td> 200</td><td> 4</td><td> 500</td><td> 8</td><td> 10()0</td><td>S</td><td></td>

<td>Cyromazine - ؛ - 1 Compound</td><td> 2(! - 200</td><td> 8</td><td>i () :) .. '. 200</td><td> 4</td><td>00 ا- () 50</td><td>ا &lt;؛</td><td></td>

<td>Compound 1 -٠ Cyromazine</td><td> 500 ؛- 20</td><td> 20</td><td> 100 +500</td><td>X</td><td> 500 + 500</td><td> 7؛</td><td></td>

<td>Cyromazine ؛. Compound</td><td>1000- ا) 2</td><td>f)</td><td> 10( + +)()00</td><td> 40*</td><td> .50()..:.))..)011</td><td>٦ ل</td><td></td>

<td>Fenoxycarb</td><td> 10</td><td> 8</td><td> 1(.)0</td><td> 2</td><td> ؛.)()() 1</td><td> ٦</td><td></td>

<td>Compound 1, - Fcnoxycarb</td><td> 20 10</td><td> 24</td><td> 1.0 ٠ 100</td><td> 86*</td><td> 500 , 10</td><td> *١)9</td><td></td>

<td>Compound 1 -٢ Fcnoxycarlx</td><td> 20 ! 100</td><td> 49*</td><td> 100 + 100</td><td> 78*</td><td> 500-+100</td><td> !00*</td><td></td>

<td>Fenoxycarb - ؛ - 1 Compound</td><td> 20-.-10()0</td><td> 1.9</td><td> 10(1 + 1000</td><td> 74*</td><td> 5()().,.. 1(.)00</td><td> 61*</td><td></td>

<td>Methoprene</td><td> 5؛</td><td> 10(.)</td><td> 50</td><td> 65</td><td> 150</td><td> 86</td><td></td>

<td>Mel'hoprenè - ؛ - 1 Compound</td><td> 20-15</td><td> 10()</td><td> 10()+-15</td><td> 73</td><td> 500 -15</td><td> 100</td><td></td>

<td>Compound 1. - ؛ - Methoprene</td><td> 2(.).: 50</td><td> 16</td><td> 10()- + 50</td><td> 1'7</td><td> 500 50</td><td>ب 3 (&gt;</td><td></td>

<td>Compound 1. + Methoprenc</td><td> 20 -:-15()</td><td> 74</td><td> 100 + 150</td><td> 2</td><td> 50؛ : 1.)50</td><td> 87</td><td></td>

<td>lndoxacarb</td><td> 51)</td><td> 3</td><td> 500</td><td> 4</td><td> 1000</td><td>X ؛</td><td></td>

<td>Compound. I ا lndoxacarb</td><td> 20-: 50</td><td>ΙΟ</td><td>Ι00- + 50</td><td> 4</td><td> : 50() .,. 50</td><td> 100*</td><td></td>

<td>Compound 1 ٠- Indoxacarb</td><td> 20 : 500</td><td> 2</td><td> 10(),-5(.)0</td><td> 30</td><td> 500 + 500</td><td> ؛:()(.؛ 1</td><td></td>

<td>Compound 1 f indoxacarb</td><td> ) 2() - 3()()0</td><td> 4</td><td> 3000 ؛ 100</td><td> 6</td><td> .. 5()().+ 300()</td><td> 100*</td><td></td>

MA 28699US

WO 2 () 06 107595

PC'r٠ / ٧S2005.٠O23XI3

<td rowspan="2">Corn leafhopper Triazamate Compound ا i Tnazamate Compound i ب Triazamate Compound) 1 ؛ Triazamate</td><td rowspan="2">(to the (ppm) 59 20 - 50 20, 75 100. ؛ .. () 2</td><td rowspan="2">% .Vlurt. (alls) ...... * ؛ 100 * -00 ( ٦</td><td rowspan="2">Rate (ppm) 100 + 50 100 + 75 100,100</td><td colspan="2">١ „1 أ.) '١Τ ،، Ι ½1 (lbs) (ppm) '</td><td rowspan="2">؛ .1 Death, fobs) j إ 94 * 100 12 . ')</td>

<td> 94 *؛73 63 94</td><td> 0(.)1 50 ’؛٠٠ (.-)50 ؟7 ., 500 100+ 500</td>

<td>Thiodicarbc</td><td> 0.05</td><td> -</td><td> 0 16</td><td> 6</td><td> 0.4</td><td>'نم.</td>

<td>Compound ا Thiodicarb</td><td> 0.05 ؛ 20</td><td> 3</td><td>0.08 ا 100</td><td> 40*</td><td> 500 .,. 0.08</td><td>13 i</td>

<td>Compound 1 + Thiodicarb</td><td> 20 + 0.16</td><td> 5</td><td> 100+0.16</td><td></td><td> 509)-0.16</td><td>he</td>

<td>Compound 1. ؛! 'Hiodicarb</td><td> 20 +0.4</td><td> 2</td><td>100 s 0.4</td><td> 4</td><td> 500 .). ().،1</td><td> 5</td>

<td>Tebufenozide</td><td> 100</td><td> 12</td><td> 000؛</td><td> 16</td><td> 3000</td><td> 1 7؛</td>

<td>Compost i + Tebufenozide</td><td> 20)10()</td><td> 6</td><td> !00 + 100</td><td> 15</td><td> 00! ٠٠؛٠٠ 500</td><td>ع</td>

<td>Composed! ؛ Tebufenozide</td><td> 20 +1000</td><td> 8</td><td> 1000؛ 00؛</td><td> 80*</td><td> 1000؛. 500</td><td>إ</td>

<td>Compound 1 + 'febufenozide</td><td> 20 + 3000</td><td> ٦</td><td> 100-13000</td><td> 1</td><td> 500 + 3()00</td><td>] 4 ج- i</td>

<td>Deltancthrin</td><td> ؛.()</td><td> 11</td><td> 0.2</td><td> 14</td><td> 0.3</td><td></td>

<td>Compound 1 + Dellametl iri ne</td><td> 20 + 0.1</td><td> 11</td><td> 100 + ().1</td><td> 8</td><td> 500-).().1</td><td></td>

<td>Deltamethrin ب [؛ Compost</td><td> 20 + 0.2</td><td> 12</td><td> 0.2 ..؛-()0؛</td><td> 14</td><td> 500-)- 0.2</td><td> *00؛</td>

<td>Compound 1, - Deltamethrin</td><td> 20 + 0.3</td><td> 6</td><td> 100 + 0.3</td><td> 100*</td><td> 500.). 0.3</td><td>ا +00 ؛</td>

<td>Oxamyl</td><td> 0.08</td><td> 2</td><td> (+!6</td><td> 5</td><td> 0.2</td><td> ( 6 ؛ 8</td>

<td>Compound 1 + Oxamyl</td><td> 20(.1).08</td><td>ج</td><td> 100+0.08</td><td> 7</td><td>0.08 ..إ- 500</td><td></td>

<td>Compound 1 + O.xamvl</td><td> 20 + 0.16</td><td> 8</td><td> 100+0.16</td><td> 2</td><td> 500 ’ 0.16</td><td> ١١.</td>

<td>Compound 1. ؛ - Oxamy!</td><td> 20 ’0.2</td><td> ٦</td><td> 100 + 0.2.</td><td> 6</td><td> 500 + 0.2.</td><td>i</td>

<td>Hexaflumuron</td><td> 100</td><td> ١)</td><td> 1000</td><td> 5</td><td> 3000</td><td> 4</td>

<td>Compound 1) !؛ cxallumuiwi</td><td> 00؛ .،.()2</td><td> 2</td><td> «)1 + 00؛</td><td> ٦</td><td> (01؛ - 500</td><td>ا ؛</td>

<td>Compound 1) ٠ l iexaflumuromm</td><td> 000؛ ’ 20</td><td>أ 1</td><td> 100 + 1000</td><td> 13</td><td> 500 +1900</td><td> 4؛</td>

<td>llexailumuitn ؛ ؛ Compound</td><td> 20 ’ 300()</td><td> 8</td><td> 100 + 3000</td><td> ؛1</td><td> 500 + 3009</td><td> ?٠</td>

<td>Acetamiprid</td><td> 0.3</td><td> 43</td><td> 0.4</td><td> 85</td><td> 0.5</td><td> !00</td>

<td>Compound 1 1 Acetamiprid</td><td> 20 + 0.3</td><td> 3</td><td> 100 + 0.3</td><td> ١)</td><td> 500 .... 0.3</td><td> :</td>

<td>Acetamipiide ٠ ؛ Compound</td><td> 20 + 0.0</td><td> 14</td><td> 100+0.4</td><td> 86</td><td> 500 -.,.(.).4</td><td>ب * (؛ 10</td>

<td>Acetamiprid. - ؛ Compound</td><td> ؟.()؛20</td><td> 41</td><td> 100’9.5</td><td> 100</td><td> 500 .-)-0.5</td><td>100 * d</td>

<td>Cartap</td><td> 0.3</td><td> 100</td><td> 3</td><td> 100</td><td> .3()</td><td> )00</td>

<td>Compound 1 ٢ Cartap</td><td> 20’0.3</td><td> 100</td><td> 100 + 0.3</td><td> 100</td><td> .500 . 0.3</td><td> 100</td>

<td>Compost 1 'Cai tap</td><td> 20 + 3</td><td> 00؛</td><td> 100 + 3</td><td> 1(.)0</td><td> 500-.. 3</td><td> 100</td>

<td>Cartip - ا '، Compos</td><td> 20’30</td><td> .100</td><td> 100*30</td><td> 100</td><td> 500 + 30</td><td> 1()0 :</td>

<td>1 sfcnxaletate</td><td> 0.1</td><td>—آ--</td><td> 0.3</td><td> 6</td><td> 0.9</td><td> ٦ ٢</td>

<td>Compound 1 f Esfenvaldratc</td><td> 0.1 ’٠ 20</td><td> ،)</td><td> 160 + 0.1</td><td> 3</td><td> 500 .' 0.1</td><td>f '</td>

<td>Compound ٠ ا Esfen valerate</td><td> 20 . 0.3</td><td> 4</td><td> 100 + 0.3</td><td> 4</td><td> 500 : 0,3</td><td></td>

<td>Compound I) Es envalerate</td><td> 20-’ 0.9</td><td> 5</td><td> 100.+ 0.9</td><td> '7</td><td> 0.9 .؛- 500</td><td> 10</td>

<td>Thiacloprid</td><td> 0.3</td><td> ('</td><td> 3</td><td> 10()</td><td> 30</td><td> (')؛)'؛</td>

<td>Comjw.sc) إ J'hiacloprid</td><td> 20”. 0.3</td><td> *؛81</td><td> 190+ 0.3</td><td> 100:*</td><td> 500 .... 0.3</td><td> !00*</td>

<td>Compound 1 1- Tliiaelopridc</td><td> 20 1 .3</td><td> 100</td><td> 3'00؛</td><td> 100</td><td> 500 .’ 3</td><td> 00؛</td>

<td>Compound ا i- ïhiacloprid</td><td> 30 ؛ 20</td><td> 10(.)</td><td> 100..... 30</td><td> 100</td><td> 500 ... 3(.-)</td><td> 100</td>

<td>Lambda-cyhalothrin</td><td> 6؛ 0.9</td><td> 7</td><td> 0.08</td><td>رك</td><td> 0.4</td><td> 28</td>

<td>Composed ب إ lambda-cyhalothrin</td><td> 20’0.016</td><td> 9</td><td> 10) + 0.01(1</td><td> 12</td><td> 500 -().016</td><td>إ ١</td>

<td>Compound 1 1 lrmbda-cyhalothrin</td><td> 20 ..،.().08</td><td> 9</td><td> 100 + 0.08</td><td>ا</td><td> 0.08 ٠! 500</td><td> 1!</td>

<td>Compound 1 'L ntbda-cyhalolhnnc</td><td> 2().,.().4</td><td> 34</td><td> 0.4 .؛..()10</td><td> 51</td><td> 500 ’. 0.4</td><td> 6؛</td>

<td>llydramethylnoti</td><td> (.).(.)!</td><td>نم.</td><td> 1</td><td> )</td><td></td><td>١ ا</td>

<td>Compose 1 + Hvdraniethvlnmin</td><td> 20 0.01</td><td> 19</td><td> 100 + 0.01</td><td> 7</td><td> 01.().. 00؟</td><td></td>

<td>llydramcthylnon ؛ ا Compound</td><td> 20’ 1</td><td> ١)</td><td> 100+1</td><td> 8</td><td> ؛ ( 500</td><td></td>

<td>Compound 1 إ Hvdrcimeil'ivhion</td><td> 2 .1 ١)2</td><td> 14</td><td> 10()-+2</td><td> 1.3</td><td> 500 ... 2</td><td> ;]</td>

<td>7 ا_اعشنض </td><td> 10</td><td> 100</td><td> 00؛</td><td> 100</td><td> ؛00()'؛.'</td><td> !()()</td>

<td>Compose ا: Clothiamdine</td><td> 20’10</td><td> 00؛</td><td>ΙΟ ،. () () ؛</td><td> 100</td><td> 500 +10</td><td> 100</td>

<td>Compound 1 tClothiamdine</td><td> 20’100</td><td> 100</td><td> 100 ..’100</td><td> 100</td><td></td><td> 00؛</td>

<td>Compound 1 + Clothianidin</td><td> 20 1()00</td><td> 100</td><td> 100-+1000</td><td> 100</td><td>00 (؛ (ا. (ة 5</td><td> )00</td>

<td>Lîféow'on</td><td> 0.08</td><td> 9</td><td> 0.4</td><td> ٦</td><td> 2</td><td></td>

<td>Composes i + 1,111'enuron</td><td> 20:0.08</td><td> 5</td><td> 100-)-0.08</td><td> ٦</td><td> 500 .. 0.08</td><td></td>

<td>Compound 1 1 Lufenuron</td><td> 20 .+ 0.4</td><td> 9</td><td> 100)-0.4</td><td> 5</td><td> 500 .’ 0.4</td><td></td>

<td>Compose 1 + Lulenuron</td><td> 20 .1.2</td><td> 20</td><td> 10() + 2</td><td> 6</td><td> 500 + 2</td><td> ؛!</td>

MA 28699US

PCT / US2ID23K 13

WO 20 () 6/0075 () 5

<td>Leafhopper (lu ma '(., Abamectin Compose 1 ، Abameetine Compose .1 Abameetine Composed 1 'Abameetine</td><td>Rate ١r ؛ &lt;rl. (ppm) (obs) ١.ç ٦ 17 1.6. ؛. (') 2 19 7 -) () 2 (.) () (() 4- (21</td><td>Silence '14, .Vlort. ; Rate% Death, (ppm) (trbs) i (ppm) (obs) 100 '40' ؛ 9 1 Il [II I 6 1.0 - 500 10 1.6-: () () ؛ 56 8 ٠.500 roc) 8 100 * i :) 10 40 ؛ 500 ا 100 40 + 00 ؛</td>

<td>Methoxylenozide 1 Metlioxyi'enode ؛ ، Compound ؛ ، (+ ١١٠١fei١: Compose 1 'Metb 1 eno / ide ١'l١،١ ؛ le \ ؛ Compound</td><td> 3 20-10 2 100-؛-20 0؛ 1000'20</td><td>10 00 () 1 2 0 (: 1 7 () 1 -: 500 ؛ 10 10 + 100 100: -100 5 reoo-100 13 ؛ 1 1000 + 500 إ 4 1000-0 () 1 100 3 ا) ق 1 ةةا 1'7) 11 '</td>

<td>Mlenpvram Compose 1 ؛ - btenpyram Compost 1 ٠ bitenpyram Compose 1 + Nilenpyram</td><td>1 ؛ ;.,.re 0 (11 20: 0.2 (.) (.) 1 0.3 - :() 2</td><td>15 0.1 ؛ 500: * 100 1. () -: - 100 100 0.2 + 500 أ 100 0.2 -) - 100 () 10 500-0.3 ا 100 0.3 -: - 0 () 1 ؛ 1 1000 ز 6 100</td>

<td>Pyridalyl lv ridai ٦! Compose ؛ 1 yndaiy + ؛ Compost Pyridalyl ب 1 Compost</td><td> 10 2 20--10 7 4 100 ؛ 20 9 20:1000</td><td>* 66 10) -500 ؛ 13 10-.106 * 48 ؛) 10 + 500 ؛ 10 100 -) () () 1 38 1000 + 500 ؛ * 61 1000-إ 100</td>

<td>Dinoteibrane Compost 1 'أ' Dinotefuran Compose 1 ب Dinottfi liana Compose 1 - ؛ Dinottfiiranc</td><td> 0.02 5 20(0.02 6 20-:-0.08 8 20-:-0.4 89</td><td>86 0.4 ا 5 0.08 * 100 10.02 500 ؛ 4 0.02 + 100 * 1 0 ؛ 8 () ؛ (ا 00 ؛ 68 08 ؛ () ؛ 106 * 100 0.4: 500 إ * 100 0.4 (100</td>

<td>Novation Compose 1 إ Novation Compost 1 + Novaturon Compost 1 'Novaluron</td><td>250 7 2 (): - 250 7 2Ο - 5Ο () 7 20 -) () () 0 .4</td><td>100,000 ؛ ؛ 5,500 6,250 - 500 ؛ 6 250 + 100 6,500 - (- 500 إ 2,500 + 00 ( , -500 + 1000 lt ؛ 9 1000+ 100</td>

TESTED

P (ألاز 'to assess the fight against the cotton melon aphid (Aphis gossypii G lover) by contact and / or by a systemic means, each rest device consists of a small open container containing a cotton plant aged 6 to 7 5 This is pre-infested by placing on a leaf of the tested plant 40 aphids on a piece of excised leaf from a crop plant (excised leaf method). The larvae move towards the tested plant bed as the piece of leaf dries up. After the pre-infestation, the floor of the test apparatus is covered with a layer of sand.

The compounds to be tested are formulated and atomized as described for test A. The applications are repeated three times. After atomization of the formulated compounds to be tested, each test apparatus is left to dry for one hour, with a black screen cover placed on the surface. The tie test devices are kept for 6 days in a phytotron 1 2-19 ؛ '؛ 'C and 5 () - 7 () ٥-1) relative humidity. Each test device is. then visually assesses as to ٠١ ؛ insect mortality; the results are shown in tables (- ؛ A and 6.B.

MA 28699US

PCTZUS2005Z023٠٩13

930 2()06/()()7595

Table 6Α

<td colspan="5">Melon aphid</td>

<td>(Compound ا (ppm)</td><td colspan="2">Imidacloprid Report (ppm) إ</td><td>'30 Death. (observed)</td><td>Ί'ο Morri, (calculated)</td>

<td> 08</td><td colspan="2">ت 0</td><td> 12</td><td></td>

<td> 4.5</td><td rowspan="2"></td><td> -</td><td> 32</td><td rowspan="2"> ......... .. -</td>

<td> 2.5</td><td> -</td><td> 23</td>

<td> ()</td><td> (.').05</td><td> -</td><td> 12</td><td></td>

<td> 0</td><td> 0.8</td><td></td><td> 10</td><td></td>

<td> 0</td><td> 2.1</td><td> -</td><td> 40</td><td></td>

<td> 0.5</td><td> 0.05</td><td> 16:)</td><td> 14</td><td>زد</td>

<td> 0.8</td><td> 0.3</td><td> 2.7:1</td><td> 26</td><td> 21</td>

<td> 0-8 4.5</td><td> 0.05</td><td> 1:2.6 90:1</td><td> 97 38</td><td> 47 ()؛،</td>

<td> 4.5</td><td colspan="3"> 0.3 15:1 67</td><td> 39</td>

<td> 4.5</td><td colspan="2"> 2.1 2.1:1</td><td> 100</td><td> 59</td>

<td> 25</td><td colspan="2"> 0,05 500:1</td><td> 81</td><td> 32</td>

<td> 25</td><td colspan="2"> 0.3 83:1</td><td> 82</td><td> 31</td>

<td>5 ش</td><td colspan="2"> 2.1 11.9:1</td><td> 9'7</td><td> .54</td>

Table 6Β

o mortality calculated from '؟ observed mortality is greater than &lt;؛ '؟ indicates that the *.! 'Colby equation

<td>Puce, -on of melon 7 sides ، ا</td><td>!'to the (ppm)</td><td>'؛ ا, Death. (obs)</td><td>Rate اأا (ا (ا</td><td>% .M ، ٠rt. (obs)</td><td>Rate (ppm)</td><td>.أ ٠ ا ,، ١1 „'٠' (Olbs)</td>

<td>Compound اً</td><td> 4</td><td> 25</td><td> 20</td><td> ؛4</td><td> 100</td><td> 4() :</td>

<td>Meihnyl</td><td> 2</td><td> ؛(</td><td> ! 5</td><td> 35</td><td> ]5</td><td> ؛ ؛’6</td>

<td>Methumyl - ؛ ؛ Compound</td><td> 2 .٠ 4</td><td> 13</td><td> 20’2</td><td> 51</td><td> 100). 2</td><td> 29</td>

<td>Methomyl ٠٠! - ا ؛ Compost</td><td> 4’5</td><td> 13</td><td> 20 65</td><td> 4'7</td><td> 100 ’5</td><td> (1*</td>

<td>Methomyl ٠. ؛ Compound</td><td> 4’15</td><td> 75</td><td> 1 20’15</td><td>ب</td><td>5 ؛. ن 00 (</td><td> 98* )</td>

<td>Amitraz</td><td> (')؛</td><td> 20</td><td>00 اً</td><td> 35</td><td> 1000</td><td> 29</td>

<td>Amitraz ٠ ؛ ٠ اً Compound</td><td> - ...</td><td> 54*</td><td> 20’ 10</td><td> 54</td><td> !00’ 10</td><td> '*(*</td>

<td>Amitraz. ، اً Compound</td><td> 4’100</td><td> 48</td><td> 20’100</td><td> 85*</td><td> 7)0؛ ٠’ 00(</td><td> 90*</td>

<td>Amitraz '؛ Compound</td><td> 4’1000</td><td> 50</td><td> 20). 1000</td><td> 77*</td><td> 100 .+-1000</td><td> 89*</td>

<td>Thiamhame</td><td> 0.2</td><td> 24</td><td> 0.4</td><td> 48</td><td> 0.6</td><td> ١؛6</td>

<td>Compound 1: * niiamethoxamc</td><td>0.2 ى 4</td><td> 46</td><td> 20*. 0.2</td><td> 33</td><td> 1(1.+ 0.2</td><td>If) () *</td>

<td>Compound 1 + 'Thiamethoxam</td><td> 4 .... 0.4</td><td>اً 6</td><td> 04 ٠ 20</td><td> 65*</td><td> 1.4 ٠-(’ 100</td><td> 100*</td>

<td>Compound 1 ٢ Thiametlioxotme</td><td> 4-.().6</td><td> 98*</td><td> 20 + 0.6</td><td colspan="2">0.6 (100 إ * 92 10 to 15</td><td> 100* ’</td>

<td>Pvridabene</td><td>- آ ---</td><td>اًاً</td><td> [ 2</td><td colspan="2"></td><td> ؛7</td>

<td>Compose اً + Pvridabtne</td><td>أ., .. 4</td><td> 33</td><td>اً + 2.0</td><td> 41</td><td>اً.: .. 100</td><td>ه ١ ز.ة</td>

<td>C (imposed 1 اً Pyridabéne</td><td> 2 ٠’٠ 4</td><td> 21</td><td> 20 0 2</td><td> 53</td><td> 2 . 00؛</td><td>^؛ * ا</td>

<td>Compose 1 ٠٠:٠٠ Pyridabènc</td><td> 4..)-10</td><td> 47</td><td> 20 + 10</td><td> 73</td><td> 100')()</td><td> *00؛</td>

<td>Flonieamide</td><td> 0.2</td><td> 9</td><td>ا (</td><td> 46</td><td> 5</td><td> 2؛.’</td>

<td>Compound ا اً Flonieamide</td><td> 0.2 ؛ 4</td><td> 96*</td><td> 2().,.-0.2</td><td> 69*</td><td>2..0 ٠'٠ 00 ا</td><td> 64*</td>

<td>Compose 1 - Flonieamide</td><td> 4’!</td><td> 7 !</td><td> 20+)</td><td> 72*</td><td> ؛ ٠’ 00؛</td><td> , ٠’^:بب ؛</td>

<td>'o.mcaini ، k ؛ ٢: [ئ ١ ة 0 ح | ٦٦ لنئ.)</td><td>5 ؤ.</td><td> *00؛</td><td> 5 .؛’20</td><td> 86</td><td> ١- 100</td><td> : *00؛</td>

<td>Dieldrin</td><td>ا</td><td> 13</td><td> 5</td><td> 26</td><td> 50</td><td>. ١6 م</td>

<td>Compound 1 + Oieldrme</td><td> 1 ٠’ 4</td><td> 49'*</td><td> 20+1</td><td> 83*</td><td>اً ٠ '؛.) () ؛</td><td> *0* :</td>

<td>iric ، ؛ l,) ie ؛ اً Compound</td><td> 4 ’ 5</td><td> 58*</td><td> 5 ؛ 20</td><td> 92*</td><td> 10()+5</td><td>ب إ,;?</td>

<td>Compose i; [') icldrine</td><td> 4 ’. 50</td><td> 98*</td><td> 50-’.-20 ................................................؛....</td><td colspan="2"> '100* 100 +50</td><td> )00* .</td>

MA 28699US

PCT / L1S20O5 / 023813 wo 2006/007595

<td>Melon aphid /, mi ll bpinosadt ' Compound 1 ؛ Spinosadc Compound 1 'Spinosadc Compound 1 -.- Spinosade</td><td>Rate (ppm) 0 ؛ +11. + 4-1-100 () () () 1 - ؛ - 4</td><td>11 Death. ' (؟. (Ob 16 * 51 40 * 77</td><td>Rate (ppm) 00 ؛ 10--20 (1) 1.0 - (- 20 20 + 1000</td><td>'Cl Mort, (obs) '35 39 62 54</td><td>Rate (ppm) “1111 100 +10 100 - 100 100 -.- 10 (41</td><td>4&gt; Death, (obs) 30 46 54 ١٩)</td>

<td>Fipronil</td><td></td><td> 27</td><td> .1</td><td> 44</td><td>s</td><td>Χ5</td>

<td>Compose 1 '- Fipronil</td><td> 2 1؛</td><td> 27</td><td> 2 ؛ 20</td><td> 64*</td><td> 100 -, ,2</td><td> 81*</td>

<td>Fipronil - ؛ - ؛ Compound</td><td>.: i -٠- 4</td><td> 44</td><td> 2() + 4</td><td> 89*</td><td> 1++11- +</td><td> 83*</td>

<td>Compound 1 + - Fipronil</td><td> 4 + 8</td><td> 85*</td><td> 8-؛- 20</td><td> 81</td><td> 100 -8</td><td>* 98 ح</td>

<td>pyriproxyfin</td><td> 10</td><td> 14</td><td> 100</td><td> 28</td><td> 1000</td><td></td>

<td>Compound 1 + Pyriproxyfen</td><td> 4-110</td><td> 38</td><td> 20 + 10</td><td> 25</td><td> 10 ؛ 100</td><td> ؛+69</td>

<td>Pyriproxyfen - ؛ - 1 Compost</td><td> 4+100</td><td> 22</td><td> 20-100</td><td> 53</td><td> 100-100</td><td> ١)5</td>

<td>Compose 1 - + Pyriproxyfen</td><td> 4-,-1000</td><td> 25</td><td> 20 -1 1000</td><td> 59</td><td> 1()0 + 1()00</td><td> 95*</td>

<td>Pymetrozine</td><td> 0.1</td><td> 22</td><td> 0.5</td><td> 38</td><td> 2</td><td> 62</td>

<td>Pymétrozint ؛ - 1 Compost</td><td> 4-.- 0.1</td><td> 29</td><td> 20+ 0,1</td><td> 82*</td><td> 100 ’ 0,1</td><td> + 7</td>

<td>Compound 1 - Pymétrozint '</td><td> 4-,-)).5</td><td> 35</td><td> 20 + 0,5</td><td> 38</td><td> 1,+,+ + 0 5</td><td> 91</td>

<td>ymetrozine '! - ؛ - 1 Compound</td><td> 2 ؛ 4</td><td> 73</td><td> 20+2</td><td> 88*</td><td> 100 + 2</td><td> 100*</td>

<td>Buprollizine</td><td> 1(1</td><td> 34</td><td>ة 10</td><td> 30</td><td> 1000</td><td> 36</td>

<td>Compound 1 Biiprofezin</td><td> 4 + 10</td><td> 34</td><td> 20 + 10</td><td> 2.4</td><td> 100 + 10</td><td> 56</td>

<td>Buprofëzinc - ؛ - 1 Compound</td><td> 4-’-100</td><td> 41</td><td> 20 + 100</td><td> 31</td><td> 100 -؛ 100</td><td> 10*</td>

<td>Buprofizine ؛ 1 Compound</td><td> 4+1000</td><td> 31</td><td> 20-+1000</td><td> 32</td><td> 1000 ؛100</td><td> 78*</td>

<td>Chlorfenapyr</td><td> 1</td><td> 27</td><td> 1,0</td><td colspan="2"> 57 : 150</td><td> '67.......</td>

<td>Compound 1 د Chl + rlcnapyr</td><td> 1 -؛- 4</td><td> 29</td><td> 2()+-1</td><td> 52</td><td> 100- 1</td><td> 38</td>

<td>Chlorfenapyr - ؛ - 1 Compound</td><td> 4 + 10</td><td> ...</td><td> 20 + 10</td><td> 51</td><td> 100-10</td><td rowspan="2"> 75 100*</td>

<td>Compound 1 -) - Chlorfenanvr</td><td> 4 + 150</td><td> 100*</td><td> 20 + 150</td><td> 96*</td><td> 100-'- 150</td>

?١؛

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: 4 '' 8 ب 7٠٦

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* ؛ Κ.Μ

* ه () ا ٦ ~ آ ؛ 43

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100... ! 100-5

50 ؛ 100 1000 0 ؛ ٠ 100 (,) 0 (.- 100 1000 ؛ 100 iOOO 1 (1 (1 - 10

100 ؛ 100 «)()؛-؛100 1000 ()(--؛- 00( 100(100 1000؛ 100

30 (,)1-.- ؛)(.):’ 20 ٦ 100 30 .1'10

4(4

72*

5()

72*

91*

96*

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5 ؛26

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20+10؛25

100 ؛ 2029 i 20 + 1000

100 '' ؛ - '' 16 20 + 10 إ () 2

100--20 ؛25

1000 2 ('- ί ا * 60

100 م 43

10 ؛ 2044

100 ؛ 20 إ 50

1000؛.- 2045

20 ؤ 10 :-(,) 2 أ 32

30 - ؛ - 0 ذ ؛ 5 ؛

..... 1 ,5 + 50

4-10

4,-100

00 ؛ ا 4 إ

II 10

10-؛--4

100 -؛- 4

000( ٠ 4

10

10 ، 4

4+100

1000 -. 4

10

10؛ 4

4-20

30 .-4

Chlorpyrifos

Compound 1 -Chlorpyrilos

Compound 1 -i Chlorpyrifos Compound ؛ -I-Chlorpy il'os Cyromazinc

Compound) i- Cyromazinc Coniposc 1 'Cyromazinc Cpiipos! ) + Cyromazinc Fenoxycarb

Compound ا * Fenoxycarb Compound 1 'Fenoxycarb Compound ٠' اً 'l ؛ éi١ oxycarb

Methoprene

Méthtiprénc لي 1 ؛ ، Compos Compose! + .Methoprene ١prènc. ، Méth ٠ ١mp ،) sé 1 ، c

ك, ب ؛ 7 i اب 30, ؛ ١ () 2 دب (ا ؛ 4 ٠؟ 2

٢ يأ ٦ ب'ح - () 2, '17 +

Indoxaciirbe

Comptsé i د- Ilidpxat'arbe Compost ا 'liiduxacarbt Compos ,! 1 'Indxacarb

Friazamate

<td>Triazamale - ؛ - 1 Compound</td><td> 2 -؛ 4</td><td> 20</td><td></td><td> 20 + 2</td><td> 18</td><td></td><td> 2 ؛ 100</td><td> ١١-؛-</td>

<td>Triazamatc - ؛ - 1 Compound</td><td> 4 - 20</td><td> 53</td><td> .؛</td><td> 20 1-20</td><td> 43</td><td></td><td> 20, -00؛</td><td> 58</td>

<td>Iriazamatc - ؛ - 1 Compound</td><td colspan="6"> 0(,)1 0()1-::20 ; 96 00؛ -4</td><td> 100- 114)</td><td> 100</td>

<td>lliiodicarbc</td><td> 3</td><td> 49</td><td> ؛</td><td> 10</td><td> 32</td><td></td><td> '' 30 —</td><td> 69</td>

<td>Thiodicarbc - ؛ - 1 Compound</td><td> 4 -,- 3</td><td> 33</td><td> ٦</td><td> 3 -؛- 20</td><td> 37</td><td></td><td> 100 , 3</td><td> ؛٦</td>

<td>liiodicarb '- ؛ - Compound i</td><td> ()؛--4</td><td> 36</td><td></td><td> 20-,-1()</td><td> 43</td><td></td><td> ()؛-”100</td><td> 54</td>

<td>Tlriodicarb - ؛ - 1 Compound</td><td> 4+30</td><td> 35</td><td> .......... ;</td><td> 20+ 30</td><td> 80</td><td colspan="2"> 30 ’ 00؛ :</td><td> %*</td>

<td>'Febufenozide</td><td> 0.5</td><td> 21</td><td> ؛</td><td> 1.5</td><td> ٠٦7</td><td></td><td> 3</td><td> ١- ٦</td>

<td>Febufenozide - ؛ - 1 Compound</td><td> 4 ,-0,5</td><td> 36</td><td> ؛</td><td>20-i- 0.5</td><td> 49</td><td></td><td> 0.5 -٠ (,)()؛</td><td> 1</td>

<td>Tebufenozide - + - ؛ Compound</td><td> 4 '- 1.5</td><td> 39</td><td> ؛</td><td>20 -ί-1.5</td><td> 57</td><td></td><td>ن ؛ ؛ 00 ؛</td><td> 8,5*</td>

<td>Compost 1 + -febufenozide</td><td> -1-1</td><td> 42</td><td> ؛</td><td> 20 + 3</td><td> 45</td><td></td><td> 1() + 3</td><td> 8,3*</td>

MA 28699US

Î3 ، ؛ O23 ، PDS2OO5٠ wo 2006 1.07595

<td>1'11 ، trill (III cotton melon Diltmethme (.. 'yes (, dare ؛ ا Deltamethrin Compound ا Dtitaa + aertitme Compound ا -!.)</td><td>Rate Ippnt) (1.1 ا 0, 1 ، 2 .6, 4 6.3 ..1 .. 4</td><td>'. Mart ٠/٠ ؛ ...... (٠ 52 28 28 47</td><td>! 'aux (ppi)' '7, 0.2 ؛ 20 0.3 ٠٠ ؛ ٠ 20</td><td>To death.;' ((obs 39 29 3.1 52 7 اً</td><td>Rate (ppm) too - (). ( ! 00 + (). 2 100 + 0.3</td><td>Murt. &lt;؛ '؟ ؛ ((، Tits 85 58 + - + 45</td>

<td>() xamyl</td><td>t</td><td> 29 ;</td><td> 10</td><td></td><td> 1000</td><td> ()؛)1</td>

<td>Compose 1 + (() xamvl</td><td>ا 4</td><td> 35</td><td>2C .. (.. 1</td><td> 61*</td><td>؛ '؛) () L</td><td> 75*</td>

<td>Compound إ ا- Oxamyl</td><td> 4-. 1(1</td><td> 47</td><td> 20 ..,-10</td><td> 71*</td><td> 10().,-10</td><td> ٩٩٩٦ .</td>

<td>Compound 1 ١ 'Oxamyl</td><td> 4+ 1000</td><td> 100</td><td> 2.0-.. 1000</td><td> 100</td><td> 100+1000</td><td> ؛ 100</td>

<td>llexaflunuron</td><td> 30</td><td> 32</td><td> 1(.)0()</td><td> 30</td><td> 3000</td><td> ;،٠٩</td>

<td>Hesailiaatiuroia ؛ ا Compound</td><td>30 ب ٠ ،</td><td> 40</td><td> 30 ٠-&lt;-٠ 20</td><td> 60</td><td>100 to 30</td><td> ؛ 47</td>

<td>llexaflutnurttri- ؛ ا Compose</td><td> ()0(.11 ٠٠'٠ 4</td><td> ؛ *74</td><td> 2(),-1000</td><td> 65</td><td>000 ؛ + too</td><td>a جن 7</td>

<td>Composed! ب llexaflumuro η</td><td> 4 + 3000</td><td>أ 42</td><td> 20 +3000</td><td> 60*</td><td> !00+30(»</td><td> 69*</td>

<td>Acctami pride</td><td> 0.02</td><td> 42 ;</td><td> 0.08</td><td> 67</td><td> ....</td><td> 100 !</td>

<td>Compound, + Aeélanaipnde</td><td>-1 i 0.02</td><td> 41</td><td> 20 + 0.02</td><td> 49</td><td> ؛.()0؛</td><td> 6,7</td>

<td>Compound '1 -tAceiamipride</td><td> 0.04 .٠. 4</td><td> 55</td><td> 20+0.08</td><td> 85*</td><td> 0.02</td><td> 86*</td>

<td>Acetamiprid + ؛ Compound</td><td> 4. + 0.4</td><td> 94</td><td> 2(1 + 0.4</td><td> 85</td><td> 100+ 0.08</td><td> 10(.( :</td>

<td></td><td></td><td></td><td></td><td></td><td> !00 +0.4</td><td> . . . .</td>

<td>Cartap</td><td> 0.2</td><td> 29</td><td> 2</td><td> 34</td><td> 200</td><td> ٨٦'</td>

<td>Composed! - Cartap</td><td> .4 ..,.. 0.2</td><td> 79*</td><td> 2(,1- 0.2</td><td> 86*</td><td> !00 ، 0.2</td><td> 83*</td>

<td>Compose I ب Cartap</td><td> 4.+ 2</td><td> ؛ *64</td><td> 20 + 2</td><td> 5()</td><td> 100-.-2</td><td> 55</td>

<td>(oa apos ، 1 (, 111,1 (, 1</td><td> 200 .؛4</td><td> ؛ *91</td><td> 20 +200</td><td> 86</td><td> 200 + 00؛</td><td> 100*</td>

<td>؛:. Slcnealaale</td><td>—Ί</td><td colspan="2"> 95 : 0.3</td><td> .</td><td> 1</td><td> !06</td>

<td>Com ('ΙΌ 1 - t 1 \ .iterai ،'</td><td> 4-0.1</td><td>Ί١</td><td> ’11 . 0.1</td><td> 88</td><td>too .., .. (.). 1</td><td> 91,</td>

<td>F sti-â 'mleral compound</td><td> 4 .1.0.3</td><td>Ώ.</td><td> 20+-0,3</td><td> 8!</td><td>, .. ؛؛., () To</td><td> 87</td>

<td>Compose 1 ؛ tslaie'alérale</td><td> ؛ 4.</td><td> 75</td><td> 1 ٠؛٠ 20.</td><td> 91</td><td>1 () () ..,. t</td><td> 100</td>

<td>'I'hiaelopnde</td><td> 0 3</td><td> .50</td><td> 1.5</td><td> 100</td><td> 6</td><td> 100</td>

<td>Compound t ؛ ! 'hiacloprid</td><td> 0.3 ٠ 4</td><td>إ 64</td><td> 29 ..,..().3</td><td> 8.4*</td><td> 100-0.3</td><td> (+,+ :</td>

<td>Compound i '* Thiaclopridc</td><td> 41.5</td><td> 96</td><td> 20+1.5</td><td> 100</td><td> 10()+1.5</td><td> 1)1)</td>

<td>Compose t -f Thiaclopridc</td><td> ١)؛'4</td><td> 100</td><td> 2().(-6</td><td> 100</td><td>too-6</td><td> 1()0</td>

<td>Lambda-cyhalothrin</td><td> 0.08</td><td> 22</td><td> 0.4</td><td> 81</td><td> 2</td><td> 100</td>

<td>la-cvlial ، laiane. ؛ 1 iim '؛ Compo.sc</td><td> 4)0.08</td><td> 39</td><td> 0.08 +-؛)2</td><td> 66*</td><td> 100 .,</td><td> ١١٩)</td>

<td>Compound i '٠' Lambda es'halothriiic</td><td> 0.4 ٠- 4</td><td> 100*</td><td> 20 ,. 0.4</td><td> 84</td><td> 0.08</td><td> 100*</td>

<td>Coaaaposed ؛ + Lambda-cx'halothrin</td><td>4 i 2</td><td> 10() </td><td> 20+2</td><td> 1(.)0</td><td> 100..,0.4</td><td> 160</td>

<td></td><td></td><td>إ ...</td><td></td><td></td><td> 100:2</td><td></td>

<td>Mead laylnon</td><td> 500</td><td></td><td> 1000</td><td> 40</td><td> !500</td><td> 39</td>

<td>Compound أ + liydrameth ylaa on</td><td> 4 -+ 500</td><td> 3()</td><td> 20 + 500</td><td> 75*</td><td>too- 500</td><td> 6'?*</td>

<td>IJydramethyhton د ؛ Compound</td><td>4 + K.) ")</td><td> 53</td><td> 20 + 1000</td><td> 66</td><td>too. ، 1000</td><td> ١٩؛</td>

<td>Compound 1 + Hydramcthylnon</td><td> 4+1500</td><td> 54</td><td> 20+1500</td><td> 66</td><td> 10()., '!500</td><td> ؛;:7-7</td>

<td>Cloihianidinc</td><td> 0.08</td><td> 75</td><td> ....</td><td> 91</td><td></td><td> (،(؛</td>

<td>Compose) + Clothianidin</td><td> 4 .... 0.08</td><td> 94*</td><td> 20-+. 0.08</td><td> 84</td><td> 1.00 -</td><td>2 با</td>

<td>'، 1 CJothianidiai ؛ Compound</td><td> 4 : 0.4</td><td>2 ح&gt;</td><td> 20 + 0.4</td><td> 88</td><td> 0.08</td><td> 100</td>

<td>ihianidiaac ,، ؛ '.)' اً Compound</td><td> 2 ؛ 4</td><td> 100</td><td> 20 + 2</td><td> 100</td><td> 100 , 0.4</td><td> 00؛</td>

<td></td><td></td><td></td><td></td><td></td><td> 100+2</td><td></td>

<td>1.1.1 fenu'0.1</td><td> 08.؛)</td><td>لآ</td><td> 0.4</td><td> 39</td><td> ١-</td><td>١Ν</td>

<td>Compound). - Lül'éni ΌΠ</td><td> 4 0.08</td><td> 37</td><td> 20+0.08</td><td> ٩٧١</td><td> 100 :.</td><td> 51</td>

<td>Compose t ، 1 aaféainroaa</td><td> 4 ... 0.4</td><td> 34</td><td> 20 + 0.4</td><td> 66</td><td> 0.()8</td><td> ٦٠٠١</td>

<td>Compound 1 'Jurmutoai</td><td> 4 , 2</td><td> 40</td><td> 20 + 2</td><td> ١١)</td><td> 0.4 ؛ 100</td><td> 54</td>

<td></td><td></td><td></td><td></td><td></td><td> 1(.)0-2</td><td></td>

<td>Abamecline</td><td> 0.08</td><td> 35</td><td> 0.4</td><td>SS</td><td> ......... .. _٠ — ..</td><td> ؛)10</td>

<td>Compose ا a Abanaect te</td><td> 4 ’ 0.08</td><td> 43</td><td> 20 - 0.08</td><td> 5،)</td><td> ,.؛؛10</td><td>g م ١</td>

<td>Compound 1 i Abamecline</td><td> 4 - 0.4</td><td> 100*</td><td> 20 + 0.4</td><td>too *</td><td> (.).08</td><td> 93*</td>

<td>Compound 1 ل Abamecline</td><td> 4-2</td><td> 1(.)0</td><td> 2 .٠. 20</td><td>too</td><td> ( 100 -0.4</td><td> ,.)4</td>

<td></td><td></td><td></td><td></td><td></td><td> 100-.2</td><td></td>

<td>Methoxyftnozide</td><td> 5</td><td> 32</td><td> 50</td><td> 54</td><td> 50()</td><td> 35</td>

<td>Compound t - ؛ ' Method.xyTcnozidc</td><td> 4 + 5</td><td> 32</td><td> 20+5</td><td> 62*</td><td> 5 ٢ 100</td><td> =,-(</td>

<td>Compound 1 + Methoxvfenozidc</td><td> 4 .... 50</td><td> 54*</td><td> 20 + 50</td><td> 46</td><td> 1()().:.50</td><td> 62</td>

<td>Composed of t + Mcthoxynozide</td><td> 4+ 500</td><td> 38</td><td> 2() + 500</td><td> 50</td><td> 10()-500</td><td> 54</td>

MA 28699US

PCTAJS2005 / 023813

WO 2 () 06 107595

<td rowspan="2">Melon / cotton aphid Niten Tarn Nilenpyram ؛ 1 Compose Nitenpyira + ا Compose i 'Nitenpyram ؛ ، Compos</td><td rowspan="2">Tau (ppm) 0.2 0.2 ؛ 4 0.4 -ا 4 0.6: 4</td><td rowspan="2">%. Word. (O) 'S) .. .. 2. 55 62</td><td>Taui ، (ppm)</td><td rowspan="2">Wall, (obs, 49 71 * 94 * 100 *</td><td rowspan="2">Rate (ppm) 0.2. ؛ 100 0.4 ؛ 100 ,). 0 -.: .. 100</td><td rowspan="2">'1 Death, (obs) 71 26 ج</td>

<td> 0.4 20 -1-0.2 20-0.4 20 0.6</td>

<td>Pyridalyl</td><td>ا</td><td> ٦٦</td><td> 1.5</td><td> .34</td><td> 2</td><td> 3.2</td>

<td>Pyridalyl · ا ؛ Compost</td><td> 4 ... 1</td><td> 30</td><td> 20 + 1</td><td> 43</td><td> ؛ .٠٠ 100</td><td> 51</td>

<td>Compound n '1' Pyridalyl</td><td> 4-1..5</td><td> 42</td><td> 1.5 .20٠</td><td> 55</td><td> 100 +1.5</td><td> ٦)١)</td>

<td>t- Pyridalyl ؛ (Compost</td><td> 4:--2</td><td> 33</td><td> 2 ؛ 20</td><td> 59</td><td> 100 + 2</td><td> 64</td>

<td>Dinotdftirane</td><td> ؛</td><td> 31</td><td> 2</td><td> 64</td><td> 5</td><td> ;)2</td>

<td>Dinolslii me ا ؛ imposed'.)</td><td>i ؛ 4</td><td> 20</td><td> 20 + 1</td><td> 62</td><td> 1 ٠:٠()(.)؛</td><td> 76*</td>

<td>Dial! ! ٠+ 01 lot Italy</td><td> 2 ٠؛٠٠ 4</td><td> -45</td><td> 20 + 2</td><td> 82</td><td> 100-2</td><td> 89</td>

<td>Dinoteluran - ؛ - ؛ Compound</td><td> 5 .٠ 4</td><td> 100</td><td> 20+5</td><td> 96</td><td> 100 + 5</td><td> 96</td>

<td>؛ Xovaluroi</td><td> 50</td><td>2S</td><td> 250</td><td> 30</td><td> 1000</td><td> 29</td>

<td>Novalun ؛ Dial! i</td><td> 4 ... 50</td><td> 34</td><td> 20 + 50</td><td> 70*</td><td> 50 ؛-100</td><td> 78*</td>

<td>Dial! أ + Novaluron</td><td> 250 .؛. 4</td><td> 52*</td><td> 250 ؛ 20</td><td> 89*</td><td> 100 :- 250</td><td> ..</td>

<td>Novaluron إ ؛ ! Dial</td><td> 000؛+4</td><td> 48*</td><td> 201000</td><td> 89*'</td><td> 100+1000</td><td> 86*</td>

TEST F

To assess the control of the green peach aphid (Myzus ع ؛ ء '، ١7.'ام' Sulzer) by contact and / or by a systemic means, each ballast device is made up of a small open container containing a radish 12 5 to 15 days old. The latter is p٢é-infested by placing: on a leaf of the plant tested 30 to 40 aphids on a piece of leaf excised from a cultured plant tested (excised leaf method). The larvae move over the tested plant as the piece of leaf dries out. After the pre-infestation, the soil of the test apparatus is covered with a seizure layer.

These compounds to be tested are formulated and atomized as described in test A, in three applications. After atomization of the formulated compound to be tested, each test apparatus is smoothed to dry for one hour, then a screen cover is placed on the surface. The test devices are kept for 6 days in a phytotron at 19-21٥c and 50-7 (.) ¾) humidity. Each test apparatus is then visually assessed for insect mortality; the results are shown in Tables 7Α and '713.

table 7٨

<td colspan="4">Green ptclner aphid</td>

<td>Compound ؛ (ppm) .... ii H! ... ، 1_—: ΤΙ-— i ...-.-. · 1</td><td>Report lmidaclopri (ppm) —ب.٦٠__ع —— ب.للع. . . ...¹ i ~ p ..... . , iii</td><td>٠؟ '&lt;, Death. (observed.)</td><td>،. ' O Death, (calculated)</td>

<td> 2.1 3.9</td><td></td><td>5 ٦, نح</td><td></td>

<td> 7.5</td><td>... --- .....-... ب ....- 0.08</td><td>(1 AT..................</td><td></td>

<td> 0</td><td> 0.15</td><td> 12</td><td> -</td>

<td> (.)</td><td> 0.26</td><td> 50</td><td rowspan="2"> ٩</td>

<td> 2.1</td><td> 0.08 .2(,:.1</td><td></td>

MA 28699US

أك ؛ S ن 2 0/5 () () 2 PCI '. ·' US wo 2006 1) 07595

<td> 2.1</td><td colspan="3"> ( 0.1'5 14:1.</td><td> 32</td><td> 16</td>

<td> 21</td><td> (-).26</td><td colspan="2"> 8.1:1</td><td> 92</td><td> 53</td>

<td> 3.،)</td><td> (-2.(38</td><td> 49</td><td> 1</td><td> 46</td><td> 6</td>

<td> ؟,3</td><td> 04 5</td><td> 26</td><td> 1</td><td> 59</td><td> 14</td>

<td> 3.9</td><td> 0.26</td><td> 15</td><td> 1</td><td> 84</td><td> 51</td>

<td> 7.5</td><td colspan="2"> 0.08 94</td><td> 1</td><td> 51</td><td> 10</td>

<td> 7.-5</td><td> 0.15</td><td> 50</td><td> 1</td><td> 52</td><td> 17</td>

<td> 7.5</td><td> 0-26</td><td> 29</td><td> 1-</td><td> 64</td><td> 53</td>

Table 7Β * indicates that the observed mortality is greater than the% mortality calculated from the equation of c lby.

<td>Green peach aphid Compound i Methiomyl Compesé ا Metliomyl Compound 1 1 Methomuyl Compound 1 + - Methomyl</td><td colspan="2">Rate% Death. Tau.٠ / ٠ ١ Death, (ppm) (obs), (ppm) (tibs) 35 20; 24 0 ؛ 61 100 20 1) 5 32 50 ؛ 1) 2 ؛ 40 0150 ؛ * 80,100 ،. 20 إ 67 100- 10 100 1200 ؛ 20 94 200'10</td><td>'(' ؛ Lux 1 Death. (ppm) (oils) 40 36 200 101 .., 40 + 50 35 40 +100 7 ،) * 0 (-11,200 ؛ 40</td>

<td>Amiiraze Amiiraze ا 1 Compound Amitrazc ؛ ؛ Compound Amiiraze ؛ Compound</td><td colspan="2"> 2! 00؛ ; 16 10 21 1+10)2 ; 29 10:10 11 100++)2 :٠ 13 100 ٢ 10 *63 20+1000 *72 1000'10</td><td>1000 34 40--10 56 * i 28 100 -ا 40 * 69 1000 + 40</td>

<td>Tlmiamethoxam Compound 1 + Thiamhoxam Compound 1 + Imiamélho xamc Compound 1 + rhiamethoxam</td><td colspan="2">94 4. (-) إ 35 2-0 17 10.2,) 2 ؛ 24 0.2 ؛ 10 * 98 0.4 + 20 ا 81 0.4 + 10 92 0.6 + 20 1 100 0.6'10</td><td>ا ؛ - ؛ () [0.6 35 0.2 + 40 ؛ +8 0.4 + 40 ; 100 6.,) .- (41</td>

<td>Pyridaben Compe i Pyridabéne Compound 1 ؛ - Pyridabéne Compost 1 + Pyridabn</td><td colspan="2">14 10 ا 100 ؛ »0 + 1 ؛ ¹ 11 1'1) 1 18 20 + 10 إ 29 10'10 70 60 -, - (2: 42 60 10</td><td>60 60 6 إ ٠'- 1) 4 : (4 إ 10-40 49 60 .٠ 40</td>

<td>Flonicarnide Compound 1 - Flonicarnide Compose 1 ؛ - Flonicarnide Compound 1 -٠ Flonicarnide</td><td> 01 16 10 '-0.1 .36 10-0.2 34 10 + 2 66*</td><td> 6.2 10 20 + 0.1 22 20+.().2 50* 2().4-2 81*</td><td> 3 4 0.1 ٠-40 ?٦ 40-0.2 *79 2:.(-)4</td>

<td>Dicldrin Compound 1 ب Dieldfimac Compost1 ؛ t Dicldiie Compound 1 -i-).) Ieldrme</td><td> 10 59 10.10 41 10'100 .51 *82 000؛ 04؛</td><td> 100 43 20 +10 43 20+100 75* 20+1000 77*</td><td>41 ن 28 40-10 * أ. 100 -. 40 * 86 40 + 1000</td>

<td>Spinosadc Compound 1 ٢ Spinosadc Compose 1 ا Spintsade Compound] ٠ Spinosadc</td><td> 1-0 25 11) + 10 37 11)-100 48 10 -1000 72*</td><td>100 46 2.0 + 10 IX ؛ 3 100 -, - 20 * 100 20 + 1000</td><td> 1000 59 41, , 10 92* *69 (؛10-40 16 40+1000</td>

<td>Fipronil Compound 1, Fipronil Compound 1 'ا' Fipronil Compound 1 + Fipronil</td><td colspan="2">(؛ -. 4 2 17 ί 34 2 + 20; 22 2'10 31 اذ - 20 44 4 ··· ١) 1 00 8 ٠١٠٠ '20 إ 28 8 ي 0 ل</td><td>50 8 * '- * 2 د 40 46 4, - 40 99 40 + 8</td>

<td>PyriproxyFene Composed 1 'Pyriproxyene Compound 1 t Pyriproxyenc Compound 1, Pyriproxyenc</td><td colspan="2">12 - 100 'أ 23 10 27 10 + 20 35 10+ 10 24 100 ؛ 20 10 + 100 46 * j 49 20 + 1000 إ 28 1000 + 10</td><td> 26 1000 40 ()؛'40 *50 40+100 *64 40+1000</td>

<td>pyieliozine Compound 1- ٠ Pyirtrozin Compose 1 Pynictrozine Compound '- Pyinclrozine</td><td colspan="2">41 '0.5 آ 13 04 ί * 57 0.1 + 20 إ 17 1-0 + 0 ؛ * 79 0-5 + 20 ؛ 38 0.5 ؛ 10 * 00 (2 + 20 ؛ * 94 2'19</td><td>* 64! .0; 40 * ا 5-, 1 ٠ 40 85 2- + 1-) 4</td>

MA 28699US

WO 200 (007595

PCT / US2005 / 023813

<td>Green peach aphid ÎSuproi'tzriie Compost! - Birprftzme Compose! ٠- Buprofëzine Compost I أ Bupr ftzinc</td><td>1 aux (ppm) 10 10 10 10-1 () 0 10 + (0 () 0</td><td>٠/٠ Death, (obs) 63 2.8 51 41</td><td>Rate (ppm) 100 20- 10 20 + 100 20 +1000</td><td>“/ 0 Death, (obs) 63 41 53 5 (-1</td><td>Rate (ppm) 1000 4 () ... 10 40 -, - 100 4 ()., 10 () 0</td><td>ا. Death. + ؛ (obs) 54 ' 35. ؛ 6 56</td>

<td>Chlorftnapyr</td><td> 1.5</td><td> ٦2</td><td> ٦'</td><td> .36</td><td> 35</td><td> 100</td>

<td>Chlorftnapyr ؛ .. إ Compost</td><td> 10 -(.5</td><td> 39</td><td> 20 1.5</td><td> 29</td><td> 40 -. !-5</td><td> ؛ .12..</td>

<td>Compost 1 + Chlorftnapyr</td><td> 10 - 7</td><td> 59*</td><td> 20 + 7</td><td> 54</td><td> .40 + 7</td><td> 5.4</td>

<td>Compost 1 + Chlorftmrpvr</td><td> !0-35</td><td> 100</td><td> 2(.).,-35</td><td> 1()(-)</td><td> 4()+35</td><td> 100</td>

<td>Chlorpyrifos</td><td> 0؛</td><td>~ π ~</td><td> 100</td><td> 18</td><td> 1000</td><td> ()</td>

<td>Chlorpyrribs ؛ ؛ Compost</td><td> 101-(0</td><td> 11</td><td> 20-10</td><td> 12</td><td> 10 -؛ 40</td><td> 28</td>

<td>Compost 1 chlorpyrifos</td><td> (0(100</td><td> 17</td><td> 2()..-100</td><td> 20</td><td> ..4()-,.-100</td><td> 1(.)</td>

<td>Compound 1 1- Chlorpyrifos</td><td> 10-1-1000</td><td> 14</td><td> 2()+1(1</td><td> 20</td><td> 40 ,1+ +1+(+</td><td> 7 ١'</td>

<td>Cvromazinc</td><td> 10</td><td> 24</td><td> 100</td><td> 33</td><td> 1000</td><td> 65</td>

<td>Compose 1 + Cyromazine</td><td> 10 -10</td><td> 18</td><td> 0+10</td><td> 1(-)</td><td> 40-(-10</td><td> 32</td>

<td>Compost 1 أ Cvromazine</td><td> 1(),-100</td><td> 18</td><td> 20+-10()</td><td> 6</td><td> 40-1()0</td><td> 19</td>

<td>Compost 1: Cyromazine</td><td>() () !.) I ؛ -10</td><td> 4(1)</td><td> 20--1000</td><td> 24</td><td> 40 -1000</td><td> 65</td>

<td>Ftnoxvcarb</td><td> 11.)</td><td> (7</td><td> 100</td><td> 16</td><td> 1(.)00</td><td> ؛ 18</td>

<td>(- '؛. imposes 1 - Ftnoxycarb</td><td> 10-(0</td><td>I,</td><td> 20 .-10</td><td>ب ٦</td><td> .40 -10</td><td> 2</td>

<td>Compost 1 Ftnoxvcarbe</td><td> 00؛ .-10</td><td> 31</td><td> 20 -100</td><td> 23</td><td> 4(),-100</td><td> 64*</td>

<td>Compost 1: Fcnoxycarb</td><td> 10 -. 1(.)00</td><td> 19</td><td> 20-1000</td><td> 3(2</td><td> 40 .,.)000</td><td> 54* .. 1</td>

<td>Mtlhoprtne</td><td> 1(.1</td><td colspan="2"> 27 .00</td><td> 2.3</td><td> 1()()0</td><td> 45</td>

<td>(Compose 1 -, .Mtlhoprtne</td><td> (.؛! - 10</td><td> (5</td><td> 20 -10</td><td> 95*</td><td> ٠10؛.. 40</td><td> 82.</td>

<td>Compost 1 - Mtthop one</td><td> 1(.1-101)</td><td> 28</td><td> 20+10()</td><td> 44</td><td> 00؛-40</td><td> ؛؛</td>

<td>Compost 1 + Mtlhoprtne</td><td> 10-1()00</td><td> 15</td><td> 20 + 101)0</td><td> 5()</td><td> 40 , 1000</td><td> (12</td>

<td>؛ ١a ، 'ai٠bt, Indo</td><td> 10</td><td> 9</td><td> 20</td><td> ’7</td><td> 3(.)</td><td> 8</td>

<td>Indoxacarbc ؛ 1 Compost</td><td> 10-10</td><td> (0</td><td> 20-10</td><td> 13</td><td> 40 , 10</td><td> ؛ +1</td>

<td>Compost 1 ا Indoxacarbc</td><td> 10 :. 20</td><td> 12</td><td>2C + 20</td><td> 20</td><td> 40+20</td><td> 22</td>

<td>Compost 1 'Indoxacarbc</td><td> (-)3 ٠؛ 10</td><td> 8</td><td> 1)3 ؛ ,)2</td><td> 23</td><td> 40 + 30</td><td> 2(.1</td>

<td>Triazamaie</td><td> 0.1</td><td colspan="2"> 1 :, ]</td><td> 2</td><td> 100</td><td> 100</td>

<td>Compost 1 +٠ Triazamale</td><td> 10 )-0-1</td><td> 4</td><td> 20 + 0.1</td><td> 5</td><td> 4(),().1</td><td> ؛؛</td>

<td>Compose 1 1 azamatc</td><td> !0 1</td><td> ٦</td><td> 30+1</td><td> 5</td><td> -40 : 1</td><td> ؛ 10</td>

<td>Compose 1 r Iriazamate</td><td> 1(-) .,-100</td><td colspan="2"> 100 1 20-100</td><td> 100</td><td> 40-.)00</td><td>100 I إ 98</td>

<td>Ihrodrcarb</td><td> 2(-)</td><td> 10</td><td> 150</td><td> 17</td><td> 900</td><td></td>

<td>llaiodicarb ؛ 1 Compost</td><td> 10 ., 20</td><td> 7</td><td> 20.,-20</td><td> 18</td><td> 40 .... 20</td><td> ؛ ١'</td>

<td>Compost) ٠ 'Utiodicarbc</td><td>10 -Iso</td><td> 19</td><td> 20-,. 1.50</td><td> 47*</td><td> 40+150</td><td> -+(-+</td>

<td>liiodicarb '- ؛ 1 Compost</td><td> 10-,-9(.)(-)</td><td> 100*</td><td> 2()--90()</td><td> ......</td><td> 900 .؛..(-)4</td><td> *()).)؛</td>

<td>Ttbuftnozidc</td><td> 100</td><td> 8</td><td> 000؛</td><td> 7</td><td> 30()(.)</td><td> 9</td>

<td>Compost م ا Ttbufcwzidc</td><td> 00؛ . 10</td><td> 23</td><td> 2()- 100</td><td> 9</td><td> (.؛10 ٠؛ 40</td><td> 3؛</td>

<td>Ttbuftnozidc ؛ ا Compose</td><td>() () ؛-) 1 ().,. I</td><td> 22</td><td> 2(1+1000</td><td> 20</td><td> 40+ 1(.)00</td><td> 22</td>

<td>Compost! ٠ Ttbufcnozide</td><td> 10 .,. 3000</td><td> 2؛</td><td> 2(-, +3000</td><td> 33</td><td> 40..,. 3000</td><td> 1.5</td>

<td>Deltamel hrine</td><td> 250</td><td> 9</td><td> ، 300</td><td> 3</td><td> 1000</td><td> ،)</td>

<td>Compost 1 ؛ Dell inittnne</td><td> 10 250</td><td> 5</td><td> 20 + 250</td><td> ٦</td><td> 40 - 250</td><td> ()؛</td>

<td>Detamtihrin ؛ 1 'Compose</td><td> 10 : 300</td><td> ()</td><td> 20--...31</td><td> ١</td><td> 40.300</td><td></td>

<td>Compost 1 + Dellamtthrine</td><td> 10-100()</td><td> !1</td><td> 1 2().-1000</td><td> 5</td><td> ،10-!006</td><td> !3</td>

<td>Oxamyl</td><td> 40</td><td> 8</td><td> 7(-)</td><td> 1-8</td><td> 100</td><td> ٦؛</td>

<td>1 Oxarnvl ؛ Compound</td><td> 0:40؛</td><td> 29</td><td> ٠40,20 ؛</td><td> 31</td><td> 40 - 40</td><td> 28</td>

<td>Compose1 ؛ , Oxamyl</td><td> 70 ٠٠-(.)؛</td><td> 42*</td><td> : 20+70</td><td> 57*</td><td> ()7 ٠٠؛٠ 40</td><td>ح ٠</td>

<td>Composed ٢ ا Oxamyl</td><td>I (- ') ..- 1 () (-)</td><td> 63*</td><td> 20+100</td><td> 85*</td><td> 40 .-10()</td><td> 70*</td>

<td>llexaflumurort</td><td> 00؛</td><td> 8</td><td> 1()0(.)</td><td>h</td><td> 3000</td><td> 3؛</td>

<td>Compose 1 ، llexaflumuroit</td><td> 10 : 10(-)</td><td> (،؛</td><td> 20 + 100</td><td> ؟2</td><td> 40 +100</td><td> 46*</td>

<td>Compost 1 1 flexaflumuro n</td><td> 000؛ . 10</td><td> 41*</td><td> , 20+1000</td><td> 30</td><td> 40 + 1000</td><td> 9؛</td>

<td>lexallumuron ؛ - 1 ؛ Compose</td><td> 3000 ؛ 10</td><td> 20</td><td> 2()+-3000</td><td> 20</td><td> 40 -30()0</td><td> 39</td>

<td>Actiamipride</td><td> 1-2-؛</td><td> 27</td><td> 0-4</td><td> 52</td><td> 0.6</td><td> 46</td>

<td>Compost 1 + Actiamipride</td><td> 10 - 0.2</td><td> 26</td><td> 20-0.2</td><td> 31</td><td> 40 - 0.2</td><td> 8؛</td>

<td>Compost ا 'ا' Actiamipride</td><td> 10 + 0-4</td><td> 59</td><td> 20 + 0.4</td><td> 75*</td><td> 40 ,. 0.4</td><td> ١)6</td>

<td>Actiamipride ؛ ا Compost</td><td> ١).() .٠؛.. 10</td><td> 73*</td><td> 0.6 + 20 ؛</td><td> 98*</td><td> 40-0.6</td><td> 98*</td>

MA 28699US

PCT / US2005.O23K 1.3

WO 2006/007595

<td>Green aphid dll fishing Cartiip Compose ٠- اً- Cartap Compose 1 + Cartap Compound 1 -t- Cartap</td><td>Rate (ppm) j »“ ٠o 10'0.4 0.6 ؛ 10</td><td>+. Dead. ....._ (_ ¥ ؟.) 28 21 13</td><td>Rate (ppm) 0.4 0.2 ؛ 20 0.4 + 20 20 + 0.6</td><td>% M rf. (obs) 26 13 9 ؛ 11</td><td>Rate (ppm.) (). ('&gt; 0.2 -, - ؛) 4 0.4 '40 0.6--, '(.) 4</td><td>Mart. (ebs) 17 20 14</td>

<td>Esfcn valerate</td><td> 50</td><td> 100</td><td> 1000</td><td> 41</td><td> 3000</td><td>ذ 2</td>

<td>Compound ٠ 'اً E, sfenvaléraie</td><td> 10 + 50</td><td> 10</td><td> 20 -50</td><td> 2()</td><td> 40 50</td><td> ؛2</td>

<td>Compound ا + Esfenvalérale</td><td> 10-1000</td><td> 47</td><td> 20+1000</td><td> 24</td><td> 40-,1000</td><td> 32</td>

<td>Composed! - ؛ ' Esfenvalerate</td><td> 10 ،- 3000</td><td> 30</td><td> 3000-؛20</td><td> 24</td><td> 40-3000</td><td> 23</td>

<td>Thiacloprid</td><td> 0.2</td><td>ذاً</td><td> 0 3</td><td> 68</td><td> 0.4</td><td>Ï2</td>

<td>Compound ا Thiacloprid</td><td> 10 + 0.2</td><td> 30</td><td> 20--0.2</td><td> 42</td><td> .40 - 0.2</td><td> 64*</td>

<td>Compound 1 +٠ Thiacloprid</td><td> 10 - 0.3</td><td> 13</td><td> 20- 0.3</td><td> ؛4</td><td> 40 0.3</td><td> 70*</td>

<td>Compose ا t- Thiacloprid</td><td> 0.4 ؛ 10</td><td> 36</td><td> 20--0.4</td><td> 69*</td><td>4. () ب 40</td><td> 72*</td>

<td>Lambda-cvhalothrinc</td><td> 0.010</td><td> 4؛</td><td> 0.08</td><td> 15</td><td> 0.4</td><td> 3(.)</td>

<td>Compound 1 ا Lambda-cyhalolhrinc</td><td> 10 + 0.016</td><td> 30</td><td> 20 + 0.016</td><td> 16</td><td> 0.015 + (»٠</td><td> 15</td>

<td>Compound 1 + Lambda-cyhalothrin</td><td> 10-0.08</td><td> 25</td><td> 0.08 ؛-20</td><td> 39</td><td> 40 -,- 0.()8</td><td> 9</td>

<td>Compound 1 't- Lambda-cyhalothrin</td><td> 10 + 0.4</td><td> 36</td><td> 20 -0.4</td><td> 36</td><td> 40 +0.4</td><td>lb</td>

<td>llydramethylnon</td><td> 500</td><td> 18</td><td>I ',,'</td><td> 8</td><td> 1500</td><td>Ί</td>

<td>Compound, + llydramethylnon</td><td> 10 ، 500</td><td> 23</td><td> 20 --500</td><td> 21</td><td> 40 500</td><td> 8؛</td>

<td>Compound i أ ا Ivdramethylnon</td><td> 10 -1000</td><td> 25</td><td> 20+ 1000</td><td> 24</td><td> 000؛ , 40</td><td> 59*</td>

<td>Compound اً t Hydramethylnon</td><td> 1500 .-؛10</td><td> 18</td><td> 20+1500</td><td> 28</td><td> 40-1500</td><td> 7 ٠٦</td>

<td>(ohianidic</td><td> 0.08</td><td> 100</td><td>مجا</td><td>0 ة 1</td><td> 7</td><td> 100</td>

<td>Compound اً + clothianidme</td><td> 10+ 0.08</td><td> 100</td><td>20 ot) 8</td><td> 100</td><td> 40 0.08</td><td> 00؛</td>

<td>Compound ب أ Clothiaoidine</td><td> 11.) +0.4</td><td> 101.)</td><td> 20+0.4</td><td> 100</td><td> 40 0.4</td><td> ؛)(')؛</td>

<td>Compose i + Clolhianidioc</td><td> 2+ 0؛</td><td> 100</td><td> 20 + 2</td><td> 00؛</td><td> .40 + 2</td><td> 100</td>

<td>Lid'eiuron</td><td> 50</td><td> 34</td><td> 250</td><td> 15</td><td> 000؛</td><td>2s</td>

<td>Lufenuron ؛ 1 Compose</td><td> 50 -؛- 10</td><td> 29</td><td> 20 -,- 50</td><td> 58*</td><td> 40-,-50</td><td> (؛4</td>

<td>Compound 1 'Lulcnuron</td><td> 250 ؛-10</td><td> .35</td><td> 20 , 250</td><td> ...</td><td> 40 '250</td><td>سم 7٦</td>

<td>Compo.sc! ٢ Lut'é uru</td><td> )0-1000</td><td> 49*</td><td> 20-1000</td><td> 18</td><td> 40-1000</td><td> 51</td>

<td>Abamecline</td><td> 0.08</td><td> 47</td><td> ,3.4</td><td> 100</td><td> ١'</td><td> 100</td>

<td>Compound ا + Abamecline</td><td> 10 0.08</td><td> 59</td><td> 20 -0.08</td><td> 100*</td><td> 40 0.08</td><td> 42</td>

<td>Compose ا - Abamcctme</td><td> 10-0.4</td><td> 1(.)0</td><td> \ -04</td><td> 97</td><td>4 &lt;، - راب</td><td>I () (')</td>

<td>ء ompose اً) .bimeelme</td><td> 10 -2</td><td> 100</td><td> 1 .(٦</td><td> 00؛</td><td>؛ ا ؛</td><td> 1..,0 ؛</td>

<td>١léth „x١féi١o, rt ، lè</td><td>K)</td><td> 7</td><td> (0</td><td> 17''</td><td> 11)()0</td><td> ١؛</td>

<td>Compound ؛ t Methoxyfenozidc</td><td> 10-؛-10</td><td>وه</td><td> ؛)1 ؛2</td><td> 17</td><td> 4(.)..,..11.)</td><td> ٦)؛</td>

<td>Composed ٠ اً Mcthoxycnozide</td><td> 100- 0؛</td><td> 8</td><td> 20+ 100</td><td> 17</td><td> 40,100</td><td> 19</td>

<td>Compound اً + Methoxyfenozidc</td><td> 10 + 1000</td><td> ؛2</td><td> 20 + 1000</td><td> 19</td><td> 40-101+0</td><td> 2 +</td>

<td>Nitenpyram</td><td> 0.2</td><td> 7</td><td> 0.4</td><td> 17</td><td> 0.6</td><td>0 ذ</td>

<td>Compound ا- ا- Nitenpyram</td><td> 10 + 0.2</td><td> 25</td><td> 20+0.2</td><td> 16</td><td> 0.2 -؛. 40</td><td>0 أ</td>

<td>Compound 1 -i- .Nitenpyram</td><td> 10-0.4</td><td> 24</td><td> 20 + 0.4</td><td> 60*</td><td> 40 -،- 0.4</td><td> ١</td>

<td>Compound ب ا Nitenpyram</td><td> 10 + 0.6</td><td> 75*</td><td> 20 + 0.6</td><td> 52</td><td> 40 + 0.6</td><td> 58</td>

<td>Pyridaly!</td><td> 1</td><td> 18</td><td> 10</td><td> 8</td><td> 20</td><td> ١.</td>

<td>Compound 1 ٠, · Pyridaly!</td><td> 10-1</td><td> 7</td><td> 20-1-1</td><td> 19</td><td> -40- 1</td><td> 18</td>

<td>Pyridalyl ؛ ا Compose</td><td> 0؛ -10</td><td> 11</td><td> 20.1.10</td><td> 17</td><td> 0؛ , 40</td><td> 5؛</td>

<td>Compose ا, Pyridalyl</td><td> 10'-20</td><td> 24</td><td> 20 + 20</td><td> 27</td><td> 4(, -'- 20</td><td></td>

<td>Dinoiélbrane</td><td> ٦-</td><td> 24</td><td></td><td> 32</td><td> 5</td><td> ؛6</td>

<td>Dinotefuran ؛ ؛ Compound</td><td> 10-, 1</td><td> ،3</td><td> 20 -,- 1</td><td> 12</td><td> ؛ 40</td><td>؛ إ اً,)</td>

<td>Compound 1 -٢ Dinotefuran</td><td> 10+2</td><td> 30</td><td> 20 + 2</td><td> 27</td><td> -40 ,- 2</td><td> 2.</td>

<td>Dinolefuran ؛ ا Compound</td><td> 10 1-5</td><td> 82*</td><td> 20-,5</td><td> 87*</td><td> 4(.)-. 5</td><td> 89*</td>

<td>silt. ؛ 'Nos</td><td> 250</td><td> 14</td><td> 500</td><td> 24</td><td> 1000</td><td> 2.5</td>

<td>Novaluron - ؛ Compound</td><td> 250 ' 0؛</td><td> 31</td><td> 2.50 ٢ (.؛2 (</td><td> 47</td><td> 40 + 250</td><td> ٢</td>

<td>Novaluron, ؛ Compound</td><td> 500 0؛</td><td> .34</td><td> 20+7)0</td><td> 29</td><td> 40 - 500</td><td></td>

<td>Compose 1 ا Novaluron</td><td> 10 + 1000</td><td> 28</td><td> 20-+1000</td><td> 49</td><td> 40+1000</td><td> 7.4*</td>

MA 28699US

WO 2006 007595

PCT'υ S2OO5.'023 X1 ل

TEST G

Hair!' to assess the systemic control of the white fly (Bemisiu argentifolii), each test device consists of a 1 () inch (2.4.؟ cm) pot containing sand and a tomato plant (var. Tiny Tim) at the true leaf stage, 5-10. Oxanyl is in a liquid formulation such as Vydate® L and Compound 1 is in a powder formulation (uiliable with 507'0 of active ingredient. Compounds to be tested in approximately 200 mL of water per pot are applied by drip irrigation inside a greenhouse. The activity of the white fly is evaluated on a natural population by removing 5 old leaves on which nymphs are clearly visible. When there are no more leaves with clearly visible nymphs, 5 old leaves are removed from a random pattern. The leaves are evaluated for dead and alive nymphs. For all tests, analysis is done by Fisher's LSD test for separation, at ρ = 0.05 (see KA Gomez and AA Cornez, Statistical Procedures for Agricultural Research, 2٥^me edition, John Wiley &amp; Sons. New York, page 680). Average comparisons are Elites at last valuation date only. The results are shown in Table 8.

Table 8

<td colspan="7">White muff</td>

<td>Compose / mix</td><td>mg</td><td colspan="2">Day 6</td><td>.lour</td><td> 13</td><td>Day 20</td>

<td></td><td>aipot</td><td>Number ، le</td><td>.Morl ,؛ '“</td><td>Number of</td><td>. ؛ Mor, ا '</td><td>Number re لا ',, Motl.</td>

<td></td><td></td><td>nymphs</td><td></td><td>nymphs</td><td></td><td>nymphs</td>

<td>Oxainyl</td><td> 00؛</td><td>(,) لات.</td><td>ج)</td><td> 506</td><td> 34</td><td> 404 28</td>

<td>Compound 1</td><td> 20</td><td> 6 ؛ 3</td><td> 44</td><td> !94</td><td> ،)9</td><td> 300 : 100 '</td>

<td>Oxamyl ؛ Compound l</td><td> 100-1 20</td><td> 228</td><td> 20</td><td> 31</td><td> 70</td><td> 83 ٢ 62؛</td>

<td>Untreated</td><td> 0</td><td> 512</td><td></td><td> :534</td><td> '7</td><td> 47 ؛ 53</td>

TEST H

To assess the systemic control of the beet armyworm (Spodoptera exigua), the test device consists of a 10 inch (25.4 cm) pot filled with sand and containing a tomato plant (var. Tiny Tim). at the true leaf stage. 5-10 Oxamyl is in a liquid formulation such as Vydate. Compound 1 is in a wettable powder formulation with 50% of active ingredient. Compounds to be tested in approximately 200 11-11. .. of water per pot are applied by drip irrigation inside a greenhouse. Samples are taken from the plants on the date shown by cutting out excavation discs and placing each disc on a layer of agar gel in a 16-well, 1.5 oz plate. (B-150-8 .028 Natural, Clear Pack. ¢ .1 (.)., Franklin Paris. II ..

MA 28699US

PCT / US2OO5 / O23X 13 wo 2006/007595

6 (.) 131). A larva (the beet armyworm is added to each well and the wells are covered. The plates are kept in a phytotron at 25٥c. 16 hours of light: 8 hours in the dark, 6 () (! Ο relative humidity for 4. Days The percent mortality (abbreviated as% Mort.) And percent feed (abbreviated as% Feed) are visually assessed, the results are set forth in Table 9. For all weights, l The analysis is made by the LSD ballast. Average comparisons are made on each valuation date only.

Table 9 beet extract

<td></td><td></td><td colspan="2">Day 6 ٠ new &amp; old</td><td colspan="2">Day! ٠٩-old growth</td><td colspan="2">. far! 2 old 'growth</td>

<td>Compound / mixture</td><td>ï ai / pot ؛ m</td><td>1 Word.</td><td>ا Food.</td><td>“؛; Dead.</td><td>.Food (؛, '؛</td><td>مرا Death.</td><td>% Food.</td>

<td>Oxamyl</td><td> ¾0</td><td> 26</td><td> 49</td><td> 35</td><td> 43</td><td> 70</td><td> 40</td>

<td>؛ Compound</td><td> 20</td><td> 99</td><td> 0</td><td> 100</td><td> 0</td><td> ٦(؛</td><td> 0</td>

<td>Oxamyl (Composed</td><td>too -t- 20</td><td> ؛)10</td><td> ٥</td><td>too</td><td> (.1</td><td> 100</td><td> ؛')</td>

<td>Untreated</td><td> 0</td><td> 1</td><td> ٦٦</td><td> 0</td><td> 92</td><td colspan="2"> 61 ؛ 0</td>

<td></td><td></td><td colspan="2">20 اأا 0 آل ..... new growth</td><td colspan="2">2.0 '01 .11 ؛ old growth</td><td colspan="2" rowspan="5"></td>

<td>Compound / mixture</td><td>nmai-po;</td><td>.My ,;'?</td><td>'he feeds</td><td>? '(. Death.</td><td>.Food, ؛ '؟</td>

<td>Oxamyl</td><td>too '' '</td><td> 25</td><td> 92</td><td> 31</td><td> ؛١)</td>

<td>Compound i</td><td> 20</td><td> 100</td><td> 0</td><td> 100</td><td> (')'</td>

<td>Oxamyl ؛ -Compound 1 Untreated</td><td>20 - ؛ - too 0</td><td> ؛)10 3!</td><td> () 93</td><td> 96 '61</td><td> 60</td>

! 0 TESTI

To evaluate the control of the beet armyworm (Spodoptera exigua). methomy'1 is in a liquid formulation as active ingredient Lannatc * LV (29؟ / ،)). Compound 1 is in a formulation of water dispersible granules in water (WDG) with 350% of active ingredient. The 15 compounds to be tested are dissolved in water. Sufficient water is added to constitute 100 ppm of active ingredient for each compound. Serial dilutions are made to obtain the appropriate concentrations. To achieve the desired concentrations of each compound in the mixture, double desired concentrations of each (the partner compounds in the 3 () mixture are, mixed together in equal volumes.

The dilute solutions of the compounds to be tested are atomized until they run off onto tomato plants aged 3 weeks. The plants are placed on a rotating table atomizer (10 rpm). The solutions tested are applied by a nozzle ١ ؛ slot blowing an air jet (Spraying Systems 25 1 2 2 4 40) at 10 psi (69 LPa). After each treated plant has dried, its

MA 28699US

PCT / OS2OO5 / O23813

١vo 2006.007595 leaves are excised, the leaves are cut into pieces, which are placed alone in 5.5 cm by 3.5 cm wells of a sixteen-well plastic plate. Each well contains a humidified 2.5 cm square chromatography paper to prevent drying out. An insect is placed in each well. There are two plates for each treatment. The plates are kept in a phytotron at 25 ° (. ', 1 (١ hours of light: 8 hours in the dark, 60% relative humidity for 4 days. The test is visually evaluated at 72 hours for ٥/٠ of mortality and feeding ؛ '؟ ”; the results are shown in Table 10.

Table .10

Beetroot legion 1

Compound 1 (ppm ') 0.6 () 0.30 0 (209 0.163 0.076 0.041 0.022 0

Methômyï (fpm) j Report

<img file="MA28699B1_D0006.tif" />

too

37.8

2 (. 1.6 ° ','. Death.

I Food ؛ / ''16

44' (,

10

(ا

—.- ن-— ---—-- ؛ بماً ——— ل ---- ٢٢ ——— آ —————-— ί ----- · ٢ · ٦٦-—

16.3

——ب 0.209

3 41 ؛ 1:100

<img file="MA28699B1_D0007.tif" />

ا 5: ا; ٢ ؛.

ي ٢ "^—د م

Ϊ٢٦1Γ '

0.163

0.076

0.041 .0.22

TEST ل

To evaluate the control of the leaf-feeding cabbage looper (Trichoplusia ni), cabbage plants (var. Stonehead) were grown in 1 (') cm pots filled with Metromix potting soil indoors. aluminum plates until test size (28 days, 3-4 whole sheets) is reached. The compounds to be tested are formulated and atomized on the plants tested as described for test 1. After drying for 2 hours, the treated leaves are excised and infested with a cabbage looper per well and covered. The test devices are placed on plates and put in

MA 28699US

WO 2006 ... () (17595

3.! ١S.S2005 / 02 ؛ 0٦ phytotrons at 25٥c and 6 ()؟ '() relative humidity for 4 days. Each test device is then visually evaluated for% mortality and% feeding; the results are shown in Table 1 1.

Table 11

<td colspan="4">Cabbage arpUeusc</td>

<td>(١om !, osd 1 (ppm) 0.057</td><td>Jndoxacarbc: Report (ppm) _______</td><td>^α/ α Muri. (observed) ٦٩</td><td>.Food. ,) '؛؛ 24</td>

<td> 0.0-52</td><td>إ (.)</td><td> ()</td><td> 82</td>

<td> (.)</td><td> ؛ 0.27</td><td> 56</td><td> 38</td>

<td> 0</td><td> 0.140</td><td>إ 3</td><td> 68</td>

<td> 0.057</td><td>1: 4.7 إ 0.27</td><td> 63</td><td> 9</td>

<td> 0.022</td><td> 0.146 1:4.7</td><td> 38</td><td> 13</td>

<td> 0.017</td><td> 0.082 1:4.7</td><td>b</td><td> 86</td>

<td> 0</td><td>(الم</td><td> 3</td><td> ٩٦</td>

TEST K

To evaluate the control of the Diamondback Moth (Plutella xylostella). Cabbage plants (stonehead var.) are grown in ، 10 cm filled pots ، Metromix potting soil inside aluminum plates until test size (28 days, 3-4 whole leaves) ) - The 10 compounds to test sound! formulated and atomized on the tested binders to the point of runoff using the rotary table atomizer as described, for ballast 1. After drying for 2 days, the treated leaves are excised and infested with a diamondback moth by well and covered. The devices sont) e test are 'placed on plates and mi.s dams a 5 ؛ phytotron at 25٥c and: €) ()% relative humidity for 4 days. Each test device is then visually evaluated; Table I 2.Α shows both the results of 1 ؛ mortality and 0'0 feeding; and Tables 1213 and 12C show only the results of% mortality.

Table Ι2Α

<td colspan="5">False-Ueigire of crucifers</td>

<td>Compose 1 ......... (ppm) 0.030</td><td>Indoxacarb (P ؛ ™)</td><td>Report</td><td>% Death, (observe) 78</td><td>.AlimenU ٠ ؛ '؟ 0 '' 1'111'1 '</td>

<td> 0.013</td><td colspan="2"> 0</td><td> 34</td><td> 2.1</td>

<td> 0.007</td><td colspan="2"> 0</td><td> 3؛</td><td> 10.0</td>

<td> 0 ---·-٦٢-----</td><td colspan="2"> :=:;.٢٠ ٢</td><td> 50 47</td><td> 04 '0.5'</td>

<td> ('.)</td><td> 0 776</td><td></td><td> 25</td><td> 3.5</td>

<td> 0</td><td> 0.147</td><td></td><td> 33</td><td> 13.8</td>

<td> 0.030</td><td> 0.340</td><td> 1:1)</td><td> 56</td><td> 0.4</td>

MA 28699US

PCT / US2OO5٠ ، O23813

WO 2006/007595

<td> 0.013</td><td> (),147 1:11</td><td> -32</td><td> 4.0</td>

<td> 0.007</td><td>1:34 ؛ 0.226 ا</td><td> 30</td><td> 3,8</td>

<td> 0</td><td> 0</td><td> 24</td><td> 51,9</td>

Table 12Β * indicates that the observed mortality is greater than the ٠4) mortality calculated from the Colby equation, '.

<td>Cruciferous fake</td><td>Rate : (PP١) ع </td><td>Death. ، ٥/٥ ((obs</td><td>Rate (ppm)</td><td>"To death. (obs)</td><td>Rate (ppm)</td><td>٩4ι Death. ؛ ((obs</td>

<td>؛ Compound</td><td></td><td> ٠ 87 “</td><td> 0.02</td><td> ٦٦</td><td> 0.04</td><td> 93</td>

<td>Methomyl</td><td> 30</td><td> 80</td><td> 40</td><td> 90</td><td> 50</td><td> 80</td>

<td>Compound 1 -٠ Mcthomyl</td><td> : 0.(11 -‘ 30</td><td> 90</td><td> 0.02 -30</td><td> 60</td><td> 0.04 + 3()</td><td> 70</td>

<td>Mélhomvl ؛ - 1 Compound</td><td> 0,01 --40</td><td> 90</td><td> 0.02 ,-40</td><td> 70</td><td> 0.04 -,. 40</td><td> 90</td>

<td>Composes 1. ٠ Mcthomyl</td><td> 0.01-50</td><td> 70</td><td> 0.02 -150</td><td> 70</td><td> 50 -؛- 0.04</td><td> 80</td>

<td>Amitraz</td><td> 0؛</td><td> 70</td><td>ICO</td><td> 20</td><td> 1000</td><td> 50</td>

<td>Compose .1 ٠ Amitraze</td><td> 0.01 -, 10</td><td> 80</td><td> 0.02 -10</td><td> 20</td><td> 0.04+ 10</td><td> 50</td>

<td>Amitraze ؛ - 1 Compound</td><td>r (.ro- ؛ 0.01.</td><td> 70</td><td> 0.02 -1()()</td><td> 50</td><td> 0.()4 -)--10(.)</td><td> 0؛</td>

<td>Compound 1 أ Amitraze</td><td> 1000-٠-0.01</td><td> 80</td><td>000 ؛ ب 0.02</td><td> 60</td><td> 0.04 + 1000</td><td> 6()</td>

<td>Thiamethoxam</td><td> 30</td><td> 90</td><td> 40</td><td> 100</td><td> 50</td><td> 100</td>

<td>Compound 1 + Thiamethoxam</td><td> 0.01 - 30</td><td> 80</td><td>0.02 T 30</td><td> 60</td><td> 0.04-,- 30</td><td> 90</td>

<td>Compound î 'ا Thiamethoxam</td><td> -... ...</td><td> 50</td><td>0.02 t- 40</td><td> 50</td><td> 0.04 -, 40</td><td> 00؛</td>

<td>Compound 1 - Thiamethoxam</td><td> . 0.01-)-50</td><td> 80</td><td>0.02: 150 ز 150</td><td> 80</td><td> 0.04 + 50</td><td> 100</td>

<td>Pxridabene</td><td>roo</td><td> 100</td><td></td><td> 80</td><td> 200</td><td> 100</td>

<td>Compound 1 + Pyridabene</td><td> 100.؛. 0.01</td><td> 80</td><td> 00؛ -؛ 2(.).0</td><td> 60</td><td> 00؛ -,- 0.04</td><td>١'او</td>

<td>Compound ا + Pyridabene</td><td> 50؛--( 01.(.) ؛</td><td> 90</td><td> 150 ٢ 0.02</td><td> 80</td><td> 0.04 -)-150</td><td> 100</td>

<td>Compose 1 ل Pyridaben</td><td> 0.01 : 200</td><td> 90</td><td> 0.02 -)- 200</td><td> 90</td><td> 200 ؛-0.04</td><td> 90</td>

<td>Flonicamid</td><td> ؛ </td><td> 0</td><td> !5</td><td> 60</td><td> 1000</td><td> 30</td>

<td>Flonicamid ؛ 1 Compound</td><td> )).01--,-1</td><td> 90</td><td> 0.02 -1</td><td> 100*</td><td> 1 :-؛،().()</td><td> 90</td>

<td>Compound 1 ؛ Flonicamid</td><td> 0.01-15 ؛</td><td> 100</td><td> 0.02,15</td><td> 90</td><td> 0.04-,-15</td><td> *00؛</td>

<td>Compound 1 e Flonicamid</td><td> 1000 - ؛(.).() ؛</td><td> 100*</td><td> 0.02 -,-100()</td><td>D00 *</td><td> 0.04 + 1000</td><td> 90</td>

<td>rnieldfinc</td><td> 2</td><td> 90</td><td> 2.5</td><td> 100</td><td> 3</td><td> 100</td>

<td>Included 1 ٠ ITieldrin</td><td> 0.01)-2</td><td> 80</td><td> 0.0)3 · 2</td><td> 9(.)</td><td> 0.04-,-2</td><td> 100</td>

<td>Dieidrine: ؛ Compound</td><td> -0.01-2.5</td><td> ')0</td><td>0.02 -ί-2.5</td><td> 90</td><td> 0.04-2.5</td><td> ...</td>

<td>Compound 1 + Dieidrine</td><td> 0.01:3</td><td> 80</td><td> 0.()2-3</td><td> 90</td><td> 0.04 -3</td><td> 10))</td>

<td>Spinosadc</td><td> 10</td><td> 100</td><td> 100</td><td> 90</td><td> 1000</td><td> ....</td>

<td>Compound .1 + Spinosadc</td><td> 10 - ؛0.0 ؛</td><td> 90</td><td> 0.02+10</td><td> 10(.)</td><td> 0.04-. 10</td><td> 10()</td>

<td>Compound r + Spinosiide</td><td> 0.01-,1()0</td><td> 100</td><td> 0.02 ،100</td><td> 1(.)0</td><td> 0.04-100</td><td> 90</td>

<td>Compose ا: Spinosadc</td><td> «)(.؛1 0.01</td><td> ]()(.)</td><td> (.).02)-1()00</td><td> 1(.)0</td><td> 0.04+ 1(.)00</td><td> 100</td>

Table 12C

<td>Diamondback Moth</td><td>Rate (ppm)</td><td>% Death. - ("1'7)</td><td>Rate (ppm). ؛</td><td>.Dead (½} (obs ؛</td><td>Rate (ppm)</td><td>O / 'o Death. (obs)</td>

<td>. ؛ Compound</td><td> 0.0025</td><td> 79'</td><td> 6.02</td><td> - 77</td><td> - 0.04 ؛</td><td> ~75~—</td>

<td>Fipronil</td><td> .10</td><td> 100</td><td> : 100</td><td> 100</td><td> 1000</td><td> 00؛</td>

<td>Compound 1) - Fipronil</td><td> 0.0027 - 1(.)</td><td> 100</td><td> 0.02 + 10</td><td> 100</td><td> 1().04-1()</td><td> ()()؛</td>

<td>Compound! - ؛ Fipronil</td><td> 0.0025 : 100</td><td> .100</td><td> ) 0.02+100</td><td> 100</td><td> 100 -؛ 0.04</td><td> !00</td>

<td>Compound 1 -) - Fipronil</td><td> 006؛ ؛ 025().()</td><td> 100</td><td> ().()2+1000</td><td> 100</td><td> 04)4'1000</td><td> 100</td>

<td>Pyriproxyfen</td><td> 7</td><td> 100</td><td> 20</td><td> 100</td><td> 200</td><td> 100</td>

<td>Compound 1: - Pyripro.xylene</td><td> 0.0025)2</td><td> 100</td><td> 0.02 + 2</td><td> 100</td><td> 2 0.04 ؛</td><td> )00</td>

<td>Compound 1 - Pyriproxyfen</td><td> 20 -٠- 0.0025</td><td> 100</td><td> 0.02 + 20</td><td> 100</td><td> 20 +؛0 0</td><td> ؛101</td>

<td>Pyriproxyfen - ؛ - 1 Compound</td><td> 0.0025 200</td><td> 10(.)</td><td> 0.02+200</td><td> 100</td><td> 200 : 0.04 ؛</td><td>roo</td>

<td>Pymctrozinc</td><td> 250</td><td> 100</td><td> 000؛</td><td> !00</td><td> 2000</td><td> 00؛</td>

<td>Pynetrozine - ؛ - .1 Compound</td><td> 0.0025-)-250</td><td> 100</td><td> 0.02 + 250</td><td> 100</td><td> 0.04+ 250</td><td> ؛)(.)؛</td>

<td>Pynétiozinc - (- ؛ Compound</td><td> 0.0027-,-1()00</td><td> 100</td><td> 0.()2+10()0</td><td> 100</td><td> 0.04+ !()00</td><td> ؛؛0!</td>

<td>Compound 1 + Pymetrozine</td><td> 0.0025 -! 2000</td><td> 100</td><td> 04)2+21)</td><td> 100</td><td> : 0.04 .+ 2001)</td><td> )00</td>

MA 28699US

82005/023813 ؛,) 37 PC

WO 2 () 06 007595

<td>Diamondback Moth Buprolne Compound ٠ ؛ Buprofezin Compound i T Buprofezin Compound ؛ ا Buprofezin</td><td>Rate (ppm) (). () 025 - 10 0.1) 025 -100 0. () 025 -1000</td><td>% Death. (obs) 30 20</td><td>False (ppm) 1 (,) 0 0.02 + 10 0.02,100 0 02 + 1000</td><td>11 + 5 Death, (obs) 2 !.) 40 10 20</td><td>Rate (ppm) 1000 0.04-10 0.04 - 100: 0.04 + 1000</td><td>Dead. (obs) 60 40</td>

<td>Chlorfenapyr</td><td> 1.5</td><td> 90</td><td> 3,5</td><td> 100</td><td> 1</td><td> 7()</td>

<td>Chlorfenapyr أ ؛ Compound</td><td> 0,0025 : 1.5</td><td> 100</td><td> (&gt;,02 + 1.5</td><td> '70</td><td> 0.04-1.5</td><td> 90</td>

<td>Compound 1 -r Chlorfcnapyr</td><td> 0.0025 +5.5</td><td> 90</td><td> 0.02+3.5</td><td> 7(.)</td><td> 0.04-3.5</td><td> 90</td>

<td>Compound l + Chlorfenapyr</td><td> 0.0025 + 7</td><td> 90</td><td> 0.02 + 7</td><td> 90</td><td> : 0,04-7</td><td> 90</td>

<td>Chlorpyrifos</td><td> 10</td><td> 80</td><td> 100</td><td> 40</td><td> 1000</td><td> 50</td>

<td>Compound 1 r-Chlorpyrifos</td><td> 0.0025 + 10</td><td> 20</td><td> 1).()2 + 10</td><td> 2()</td><td> 0 04 +10</td><td> 30</td>

<td>Compose 1 ب Chlorpyrifos</td><td> 00! ٠ 0.0025</td><td> 0</td><td> 0.02 !100</td><td> 10</td><td>0.04 + 100 ا</td><td> 50</td>

<td>Compound 1 ؛ Chlorpyrifos</td><td> '0.0025',.-1000</td><td> 30</td><td> 0,02+1000</td><td> 20</td><td> 0,04+1000</td><td> 90</td>

<td>Cyromazine</td><td> 20</td><td> 60</td><td> 40</td><td> 90</td><td> 60</td><td> 80</td>

<td>Compose]. + Cyromazine</td><td> : ().0()25-20</td><td> 20</td><td> 20 -.؛..02,(.:&lt;</td><td> 30</td><td> 1 0.04 + 20</td><td> 90</td>

<td>Compound I + Cyromazine</td><td> 0.0025 +4()</td><td> 80</td><td> 0.02 + 40</td><td> 80</td><td> 40+ 0.04 ؛</td><td> 90</td>

<td>Compose 1 Cyromazine</td><td> 0.0025+ 60</td><td> 90</td><td> 0,02+60</td><td> 90</td><td>i 0.04, -60</td><td> 80</td>

<td>Fenoxycard</td><td> 10</td><td> 90</td><td> 100</td><td> 90</td><td> 1000</td><td> 90</td>

<td>Fenoxycarbc ا ؛ ' Compound</td><td> 0.0025 10</td><td> 80</td><td> 9,02:10</td><td> 70</td><td> 0,04-10</td><td> 90</td>

<td>Compound أ أ Fenoxycarb</td><td> 0.0025 + 100</td><td> (,0</td><td> 0,02+100</td><td> 80</td><td> 0.04-100</td><td> 90</td>

<td>Compose, ا Fenoxycarb</td><td> 0.0025 - 1000</td><td> 90</td><td> (1,02 -1000</td><td> 60</td><td> 1000 ؛0.04</td><td> 80</td>

<td>iVlethoprenc</td><td> 10</td><td> 90</td><td> 100</td><td> 00؛</td><td> ؛.)()(,) 1 </td><td> 90</td>

<td>Compound 1 + Methoprene</td><td> (.)..0025 10</td><td> 90</td><td> 0؛ ٠,-٠ 2(),0</td><td> 90</td><td> : 0,04 -10</td><td> 90</td>

<td>Composes ب ا Mélhoptènc</td><td> 0.0025 .)100</td><td> 90</td><td> ()()!٠-&lt;- 0.02</td><td> 90</td><td> 0.04 -,-10(1</td><td> 9(,)</td>

<td>Compound 1 ا Methoprene</td><td> 0.0025(1000</td><td> 90</td><td> 1000 ؛0,02</td><td> 90</td><td> 1().04.-,-1()()0</td><td> 90</td>

<td>lndoxacarb</td><td> 0.02</td><td> 80</td><td> 0.05</td><td> 40</td><td> 0.4</td><td> (,)</td>

<td>Compound 1 - lndoxacarb</td><td> 0.0025-‘ 0.02</td><td> '70</td><td> 0.02 + 0.02</td><td> 80</td><td> : 0.04 + 0.02</td><td> 90</td>

<td>Compost1 ؛ r- lndoxacarb</td><td> 0.0025+.().05</td><td> 60</td><td> (&gt;,02 + 0.05</td><td> 90</td><td> 0,04 : 0.05</td><td> 90</td>

<td>Compound 1 -! lndoxacarb</td><td> 0.4-؛ 0.0025</td><td> 10</td><td> 0,02+0,4</td><td> 60</td><td> 0.04-0.4</td><td> 90*</td>

<td>Triazamate</td><td> 250</td><td> 90</td><td> 350</td><td> 60</td><td> 500</td><td> 50</td>

<td>Compound ا - Ti'iazamate</td><td> 250 ,٠ 00.25.(.)</td><td> 60</td><td> 0.02 -250</td><td> 50</td><td> 0,04 -, 250</td><td> 50</td>

<td>Compose ا - + Triazamate</td><td> 0.0025 ' 350</td><td> 30</td><td> ),02 1.,5.50</td><td> 60</td><td> 0,04 +350</td><td> 8(,)</td>

<td>Compound 1 ؛ ' Triazamate</td><td> 0.0025 + 500</td><td> 30</td><td> 9,02+ 500</td><td> 40</td><td> 0,04 !'500</td><td> 80</td>

<td>Thiodicarb</td><td> 100</td><td> 90</td><td> 1000</td><td> 90</td><td> 3000</td><td> 90</td>

<td>Compound 1 -Thiodicarb</td><td> 0.0025 , 100</td><td> 90</td><td> 100 ٠٠؛- 0,02</td><td> 90</td><td> : 0,04.' 1 (')(,!</td><td> 90</td>

<td>Composes fhiodicarb</td><td> .().0025 +1000</td><td> 90</td><td> 0.02+1()00</td><td> 90</td><td> 0()10؛0.04</td><td> 90</td>

<td>Compost the phiodicarb</td><td> 0.0025 +.3000</td><td> 90</td><td> 0,02 -+3(.)(.)0</td><td> 90</td><td> 0.04,3000</td><td> ،)()</td>

<td>Tebufenozide</td><td> 150</td><td> 90</td><td> 200</td><td> 90</td><td> ,300</td><td> 90</td>

<td>Compound 1 Tebufenozide</td><td> 0.0025 -, 150</td><td> 70</td><td> :),()2.,.-15()</td><td> 90</td><td> 0.04 -, 150</td><td> 90</td>

<td>Compound it Tébufcnozidc</td><td> 0.0025 . 200</td><td> 40</td><td> (),()2 +200</td><td> 90</td><td> (),04- 20()</td><td> 9(1</td>

<td>Compound 1 + Tebufenozide</td><td> 0.()025.-.30()</td><td> 80</td><td> 0.02 + 3()0</td><td> 80</td><td> 0.04 +300</td><td> 90</td>

<td>Deltamethrin</td><td> 0.1</td><td> 90</td><td> 0,3</td><td> 90</td><td> . 1</td><td> 90</td>

<td>Compound 1 'Deltamethrin</td><td> 0.0025-0.1</td><td> 80</td><td> 0.02+ 0,1</td><td> 90</td><td> ؛.() :- 1+0,(,) :</td><td> 90</td>

<td>Compound 1 f Deltamethrin</td><td> 0.0025 - 0.3</td><td> 60</td><td> 0,3 ٠٠&lt;٠ 0.02</td><td> 70</td><td> 0.04 &gt; 0.3</td><td> 90</td>

<td>Composes ب Deltamethrin</td><td>0.0025 + i</td><td> 90</td><td> 0.02+1</td><td> 90</td><td> 0,04-1</td><td> 80</td>

<td>Oxamyl</td><td>i</td><td> 60</td><td> ]0</td><td> 20</td><td> 100</td><td> 30</td>

<td>Oxamyl + إ Compound ؛</td><td> 0.(.)(.)25 .... 1</td><td> 30</td><td> 0.02+1</td><td> 30</td><td> 0.04 -+ 1</td><td> 70</td>

<td>Oxamyl ٠ ؛ Compound</td><td> ()؛ ٠؛ 0.0025</td><td> 10</td><td> 0.02، 10</td><td> 20</td><td> : 0.04 '' 10</td><td> 10</td>

<td>Compound 1 ٢ Oxamyl</td><td>100 i ؛ 0.002</td><td> 2(.)</td><td> 0,02 ..-100</td><td> 20</td><td> 0.04-1()()</td><td> 80</td>

<td>llexallumuron</td><td> 0 5</td><td> 70</td><td> 1</td><td> 30</td><td> 2</td><td> 70</td>

<td>Compound] + llexallumuron</td><td> 0,5 ٠,- 0,0025</td><td> 20</td><td> 0.02 + 0.5</td><td> 70</td><td> 0.04 - 0,5</td><td> 90</td>

<td>Co npose 1 'llexallumuron</td><td> 0.0025 , 1</td><td> 80</td><td> 1 .٠. 0,02</td><td> 90*</td><td> 0.04 : !</td><td>٠ ب ٠ () ي</td>

<td>Compose 1 llexallumuron</td><td> 0.0025 + 2</td><td> 70</td><td> 0.02 + 2</td><td> 80</td><td> 0.04-2</td><td> 90</td>

<td>Acetamipnde</td><td> 0.3</td><td> 90</td><td> 1</td><td> 80</td><td> ؛':</td><td> 70</td>

<td>\ Compose 1 - Acelamiprid</td><td> 0,0025 + 0,3</td><td> 0</td><td> ().()2 + 0.3</td><td> 10</td><td> 0.3 '-؛ 0,04</td><td> 30</td>

<td>Compound l 1 Acetamiprid</td><td> 0,0025 :. 1</td><td> 20</td><td> 0.02+1</td><td> 20</td><td> 0,04+1</td><td> 70</td>

<td>Compound 1 '٠' Acetamiprid</td><td> 0,0025 -3</td><td> 20</td><td> 0.02 + 3</td><td> 40</td><td> 0.04+3</td><td> 7(,)</td>

PCT / US2OO5 / O23813

MA 286 US

WO 2006 + 0 () 7595

<td>Diamondback Moth Cartap Compound i - Caraap Compound ا Carta), Compound ا - + - Cartap</td><td>Your JX (ppm) 1 () (1 ) 1, () 025 -10 (1 -0.0025 -, - 100 () () () () 25 -, - 3000</td><td>% Death, ((, bs) 60 90 90 * 100</td><td>Rate (ppm) 10 () 0 0.02-100 0.02 -, - 1000 0.02 * 3000</td><td>% Death, (obs) 90 90 ! 00 * 100 *</td><td>tux -. (ppm) 3000 0.04-100 () .04 -,) 000 0.04 -, - 3000</td><td>؛ .Death% ز (Obs) ؛ :: 90) ! 00 * i</td>

<td>Esfén١٠'aléraie</td><td> 0.(.)1</td><td> 90</td><td> 0.05</td><td> 80</td><td> 0.2</td><td> 80</td>

<td>Composed! ب Esfenvaléraic</td><td> 0.()025-+ 0.1)1</td><td> 60</td><td> ().02-().01</td><td> 70</td><td> (0.(.)4 -0.(1!</td><td> &lt;)(0</td>

<td>Compose! - Eslfenvalerate</td><td> ١( (؛ ٩ 12)()0</td><td> 70</td><td> 0.02-0.()5</td><td> 60</td><td> 0.04 -(.0.05</td><td> +)0</td>

<td>Compound د ا- Esfenvalérale</td><td> ()0015 0 2</td><td> 50</td><td> 0.02 -)-0.2</td><td> 80</td><td> 0.(31-+-().2</td><td> 80</td>

<td>Tlooacloprid</td><td> 0.1</td><td> 80</td><td> 0.3</td><td> 40</td><td> !5</td><td> 90</td>

<td>Compound 1 ٢ Thiaclnpridc</td><td> 0.0025 - 0.1</td><td> 30</td><td> 0.02 + 0.1</td><td> 20</td><td> 0.04 +-0.1</td><td> 80</td>

<td>Composed! hiaclopridc</td><td> 0.0025 - 0.3</td><td> 10</td><td> 0.02-0.3</td><td> 30</td><td> 0.().1. + 0.3</td><td> 70</td>

<td>Thiacloprid + - ؛ Compound</td><td> 0.0025-,-15</td><td> 90</td><td> 0.02+15</td><td> 90</td><td> 0.(81 + 15</td><td> 90</td>

<td>lambda-cyhalothrin</td><td>١) ٦ ل ٢. ا ٢</td><td> 90</td><td> 0.()8</td><td> '70</td><td> 0.4</td><td> +)() :</td>

<td>Compound 1 1 nda-cyhalothrin</td><td> 0.016 ؛- 0.0025</td><td> 50</td><td> 0.02+0016</td><td> 90</td><td> 0.04 +().()16</td><td> 90</td>

<td>Compound '1 + - limbdacylialothrin</td><td> 0.0025-0.08</td><td> 80</td><td> 0.08 -؛-0.02</td><td> 60</td><td> 0.04+ 0.08</td><td> 90</td>

<td>Compound a - ؛ - laonbda-cyhaioihnne</td><td> 0.0025)().4</td><td> 90</td><td> 0.02 + 04</td><td> 9(.)</td><td> 0.04-+-0.4</td><td> 100* )</td>

<td>llydramélliylmm</td><td> 0.01</td><td> 70</td><td> 0.05</td><td> 5(.)</td><td> (1 +</td><td> (,0</td>

<td>Compound 1 llvdraméthvlnon</td><td> ؛0.0 ( 025().0</td><td> 50</td><td>I () () .. ؛ 1) 0</td><td> 60</td><td></td><td> 7(.0</td>

<td>Coottposc 1! d imethylnooi</td><td> 0.0025 ,-0.05</td><td> 0</td><td> ؟().()+0.02</td><td> 60</td><td> ؛0.0-+-0.04</td><td> 70</td>

<td>Compound 1 IXdidiuélhyliion</td><td> 0.0025-().2</td><td> 20</td><td> '؛) 00</td><td> 10</td><td> 0.04+0.2</td><td>so</td>

<td>Clothtamdmc</td><td> 0.016</td><td> 40</td><td> 0.08</td><td> “Ίο</td><td> (1.4</td><td>(لا</td>

<td>Compound 1, Clothianidinc</td><td> 0.0025-: 0.01(,</td><td> 70</td><td> 0.02 +-0.016</td><td> 40</td><td> 0.04-0.(016</td><td> 70</td>

<td>Compound 1 -, Clolhianidine</td><td> 0.0025-0.08</td><td> 30</td><td> 0.02 ,-0.(18</td><td> 50</td><td> 0.04 - 0.08</td><td> 9(0*</td>

<td>Compound i - ؛ - Clothianidin</td><td> 0.0025 - 0.4</td><td> 20</td><td> (.1.02 +-0.4</td><td> 50</td><td> 0.04- 0.4</td><td> !00*</td>

<td>Lufenuron</td><td> 0.08</td><td> 80</td><td> 0.4</td><td> 80</td><td>j٦J</td><td> 90</td>

<td>Compound i - Lufenuron</td><td> 0.0025 -0.08</td><td> 50</td><td> 0.02+- 0.08</td><td> 30</td><td> 0.04 + 0.08</td><td> ,٠„</td>

<td>Compose 1 ----- li'éu on</td><td> 0.0025 -,- 0.4</td><td> 60</td><td> 0.02 + 0.4</td><td> 60</td><td> 0.()4-,- 0.4</td><td> ,؛,)1</td>

<td>Compound) l ... ufenuron</td><td> 0.0025 -2</td><td> 70</td><td> 0.,.)2,-2</td><td> 70</td><td> 0.04 , 2</td><td> 0'0؛!</td>

<td>Abamecainc</td><td> 0.()2</td><td> 90</td><td> 0.08</td><td> 90</td><td> 0..4</td><td> 1()(0</td>

<td>Compound 1 i- Abamectinc</td><td> 0.0025 + 0.02</td><td> 90</td><td> 0.02 + 0.02</td><td> 90</td><td> 0.()4 , 0.()2</td><td> 100*</td>

<td>Composed! Abamectinc</td><td> 0.0025,-0.08</td><td> 100*</td><td> 0.02 + 0.08</td><td> 100*</td><td> 0.04-:-0.()8</td><td> ,+(.0</td>

<td>Compound إ- أ- Abamectinc</td><td> 0.0025 - 0.4</td><td> 90</td><td> 0.02+0.4</td><td colspan="2"> !(.)(.) 0.()4 -, 0.4</td><td> 100*</td>

<td>Methoxyfenozide</td><td> 0.08</td><td> 90</td><td> 0.4</td><td> 90</td><td> 2</td><td> (؛(،</td>

<td>Compo.se! Mâhoyenozide</td><td> 0.0()25 ,-(.).08</td><td> 80</td><td> 0.()2 + 0.08</td><td> *1)0؛</td><td> 0.04 -)-0.(.)8</td><td> !00*</td>

<td>Methoxvfenode - ؛ - ؛ Compound</td><td> 0.002.5 - 0.4</td><td> 90</td><td> 0.02 + 0.4</td><td> 80</td><td> 0.04 0.4</td><td> *0)0)؛</td>

<td>Compound i Methoxyfenozide</td><td> 0.0025 -:- 2</td><td> 100*</td><td> 0 02 -)-2</td><td> 90</td><td> 0.04 -:- 2</td><td> ,.)(.0</td>

<td>Nitenpyram</td><td> 30</td><td> 90</td><td> 75 ٠</td><td>so</td><td> 150</td><td> (؛(٠,</td>

<td>Compound 1 + Nitenpyram</td><td> 0.0025- 3()</td><td> 90</td><td>30- + ذ 0 0</td><td> 100*</td><td> 0.(.)4 , 30</td><td> 9()</td>

<td>Compound ا + Nitenpyram</td><td> 0.0()25 , 75</td><td> 100*</td><td> , 0.02 + 75</td><td> 90</td><td> (0.04 - 75</td><td> !00*</td>

<td>Niaenpyram ؛ - (Compose</td><td> 0.0025-150</td><td> 100*</td><td> 150 +- 2(0.1 ؛</td><td> 111*</td><td> 0.04-,150</td><td> 11',+*</td>

<td>Pyridalyl</td><td> 0.5</td><td> ...</td><td> 0.6</td><td> 10(.:.0</td><td> 0.7</td><td>icio</td>

<td>Compound 1 - Pyridalyl</td><td> 0.0025 -0.5</td><td> 90</td><td> 0.5 + 0.02 ؛</td><td> 90</td><td> 0.04 -,-(.0.5</td><td> ،00</td>

<td>Compound ا Pyridalyl</td><td> ,؛.(.) : 0.0025</td><td> 80</td><td>0.6 - + - 2 (). 0 ا</td><td> 100</td><td> 0.04 - 0 (,</td><td> 90</td>

<td>Compound i + - Pyridalyl</td><td> 0..()025 + 0.7</td><td colspan="2"> 90 0.02 1. 0.7</td><td> 90</td><td> 0 04 - « 7</td><td> 70؛</td>

<td>Dinoieluranc</td><td> ؛</td><td> 80</td><td> 2.5</td><td> (,()</td><td> 7.5</td><td> 7()</td>

<td>Dinolefirranc - ؛ Compound</td><td>ا-- 0.00.25</td><td> 100*</td><td> 0.02 + 1</td><td> 90</td><td> .؛ -: 04).0</td><td> ...</td>

<td>Compound ه اً- Dinoicftiranc</td><td> 0.0025-:- 2.5</td><td> 90</td><td> 0.02-,-2.5</td><td> ()0</td><td> 0.04 -,- 2.5</td><td> 100*</td>

<td>Compose]: ٠ Dinotciuranc</td><td> 0.0025,7-5</td><td> 100*</td><td> .0.02-+ 7.5</td><td> 90</td><td> 0.04- 7.5</td><td>wo *</td>

؛ .-, es table. 2؟ to 12 show mixtures and compositions of the present invention demonstrating control of a broad spectrum of invertebrate pests, some of which have a remarkable synergistic effect. As the mortality rate did not exceed 100 (1-6 , the unexpected increase in insecticidal activity can be maximal only when the ingredients

MA 28699US wo 2006/007595 PC17US2OO5.'O2.١X ١١ ا Separate assets are applied at rates ensuring much less than 100% control. Synergy is possibly unavoidable at low application rates where the individual active ingredients alone have little activity. However, high activity is sometimes observed for combinations where the active ingredient applied alone at the same application rate has essentially no activity. The synergy is indeed very remarkable.

Suitable mixtures of the compound of formula 1 where the pest control agent among components (b1) is imidacloprid. Particularly of note are weight weights of component (b) to compound of formula 1 in the mixtures and compositions of the present invention which are typically from 200: 1 to 1: 150. in an embodiment of 1.50: 1 to 1:50. in another embodiment from 50: 1 to 1:10 and in another embodiment from 5: 11: 5.

Hence, this invention discloses not only improved compositions but also methods of their use for the control of invertebrate pests, such as arthropods, in both agricultural and non-agricultural environments. The compositions of this invention exhibit a high effect in controlling invertebrate pests; Therefore, their use as arthropodicides can reduce the cost of 21) crop production and the environmental burden.