Method for stabilization of carrageenan-containing toothpaste

[Detailed Description of the Invention]

The present invention relates to stabilization of a cosmetics constituent. It is related with the present invention stabilizing kneading toothbrushing which contains carageenan as a gelling agent in detail. Carageenan (Carrageenan) is a known ingredient of various makeup combination things and a toothbrushing combination thing. Generally, it is the useful gelling agent and thickener for cosmetics, and especially although it promotes it being suspended and holding the polish agent of the granular solid dispersed in the medium of thickening and the fluid of kneading toothbrushing, or a half-solid in it, it is useful. Although carageenan was stabilizer which should be satisfied, when a constituent received a mechanical operation, it was accepted that the viscosity of the constituent whose it is a gelling agent tends to fall. Even Then may decrease viscosity substantially in comparatively little operations which are experienced when kneading toothbrushing is carried by the pump or other methods at room temperature. It is often required to use the carageenan of the amount of additions exceeding sufficient quantity in which such viscosity does not decrease, in order to allow this and to obtain the product of desired viscosity in addition, and it is Oh. Although the fall of viscosity can be avoided to a significant grade by avoiding the operation to toothbrushing when the temperature of toothbrushing is lower than the Gueroult sol transition point of carageenan, At the ordinary factory which manufactures kneading toothbrushing, the time between the time of manufacturing toothbrushing Oriented matter and the time of preparing for restoration of it into a dispenser container may often be delayed. In this way, it is often cooled, and toothbrushing is sent and carried with a pump, or, probably, must be finished by other methods, before it is filled up. If a carageenan containing composition, for example, the constituent for which carageenan is contained as a gelling agent, is heated, the continuing heating device in which an opening mixture heater and others are ordinary in the production equipment of the usual toothbrushing although the viscosity of cooled kneading toothbrushing can be increased will be dissatisfied. It is because they make hygroscopic surface moisture and a volatile flavor ingredient lose, and change a flavor constituent for local overheating of a paste, and aeration and other toothbrushing ingredients are changed. Lost, since it usually heats slowly in order that production time may avoid the damage to a product -- it is divided. Since the mechanical operation beyond it which is not desirable usually needs to send out kneading toothbrushing outside out of a heating method, it arises. Since the temperature of carageenan content kneading toothbrushing is gone up to the Gueroult sol transition temperature of carageenan at least, the present invention uses heat by microwave, by this, conquers various serious obstacles over viscosity change of toothbrushing, and improves the stability. The patent made for this artificer and investigation of literature heated carageenan content kneading toothbrushing, and since [ the ] stability improvement was carried out and the viscosity was increased, they were not able to find out the indication about what microwave radiation is used for, or suggestion. in such investigation -- the most relevant thing -- U.S. Pat. No. 3469996 -- said -- 3535482 -- said -- 3963892 -- and -- said -- it is 4003554. U.S. Pat. No. 3469996 has indicated adjusting by exposing the shortening output of Moriglyceride to microwave radiation. U.S. Pat. No. 3535482 is related with using rapid heat by microwave for low-temperature pasteurization of fluid, sterilization, and concentration. U.S. Pat. No. 3963892 explains the heat by microwave of the flowing blood controlled to prevent overheating. Finally, U.S. Pat. No. 4003554 has indicated using microwave radiation in order to induce the phase change during kneading of a polar polymer. It is related with the quoted reference book irradiating material with microwave radiation, and exerting it on the character at influence, Although using microwave radiation is known well, and it is a known gelling agent and those various character is recognized by toothbrushing in this field in carageenan, in order to heat an extensive substance, The present invention is not indicated, neither has suggested it, or no reference books have suggested the wonderful useful result. According to the present invention, the method , of stabilizing the carageenan content cosmetics constituent which consists of turning microwave radiation to a carageenan content cosmetics constituent, and going up the temperature to the Gueroult sol transition temperature of carageenan at least, and cooling a constituent in inactivity to room temperature is provided. Within the limits of the present invention, before packing a kneading toothbrushing constituent in a dispenser container, the method of increasing the viscosity of carageenan content kneading toothbrushing is included by carrying out microwave radiation processing behind. In a certain case, such processing is performed after packing to the inside of carton and a box, and in other cases, both of the back before such packing are processed. The device which can be easily installed into a restoration line so that it may carry out, when the method of controlling the temperature which heats toothbrushing with microwave, the re-circulating method of heating, discontinuous heating, and such heat by microwave are desired within the limits of the present invention is included. The present invention is explained while referring to an accompanying drawing. In Drawing 1, mixer 11 blends cosmetics, for example, various ingredients of toothbrushing, and expresses the means which blends them and it makes into the form of the desired end products. Toothbrushing of the present invention contains carageenan as a gelling agent. When building toothbrushing with room temperature, it is usually desirable to go up the temperature of at least 1 portion of a constituent at the Gerzol point of carageenan at least because of gelling of a carageenan ingredient. A uniformity machine or other processing units are considered to be expressed with mixer 11. Storage or maintenance 13 is shown and, probably, the temperature of a mixer will usually be lower [ because of the requirements for manufacture, ] in Drawing 1, than the Gueroult sol transition point in the meantime, although it can be directly put into a day pincer packing container, without cooling beforehand or carrying out, after mixing toothbrushing. In the usual manufacturing process, toothbrushing usually moves to a filling machine from a pump or a conveyer means from storage space, and this has a bad influence on gel and falls the viscosity of a product. So, by the method of the present invention, after storage or maintenance 13, a product is heated long enough, although temperature is raised from the Gueroult sol transition temperature in microwave heater means 15, A dispenser container is filled up in machinery 17 after that, in 19, it is packed and a container is sent to carton stuffing and the storage space expressed in number 21. As for the stored product, it is I and It was to have such viscosity large although processed similarly after an examination that it is accepted rather than the contrast products which do not receive heat by microwave. Since heat by microwave is a short period of time, for the minimum mechanical division at the Gueroult sol transition temperature which the character of heating and toothbrushing which were closed receive, decomposition of the flavor material is not accepted and the high viscosity of a product is obtained. In Drawing 2, microwave applicator 23 who surrounds lead pipe 25 with a microwave permeability wall is illustrated. This lead pipe 25 has flexible ends 27 and 29 and means 31 and 33 to conclude a part of arrangement (not shown) of a conveyor, a lead pipe, a pipe pipe, or a pipe to it in a standard toothbrushing restoration line. Exchange electric power supply line 35 carries electric power to electric power supply machine 37 for microwave generator 39. Microwave generator 39 generates microwave energy and it sends it to a microwave applicator through the means denoted by line 41. When the equipment to illustrate is automatic control and the product is not flowing through line 25, the microwave generator is turned OFF, and the flow of microwave energy is answered and adjusted to the temperature of the material in such a lead pipe (such adjustment -- on-―off operation -- or control of the electric power to a generator can perform). Flow sensor 43 has probe portion 45 connected to lead pipe 25, and is such a lead pipe from here, A sensor carries out the operation with which it cuts the current to electric power supply machine 37 which passes through the contact which expresses with number 47 when it is shown that there is no flow of material in It's rising. by coming out of a microwave applicator. Temperature sensor 49 with the probe with which it is expressed in number 51 of the flow sensor on lead pipe 25 connected downstream only, The signal which controls the electric power supply to a generator and an applicator is transmitted through line 53, and such supply is increased when the temperature of a product is lower than a desirable value (or it is turned ON). (while the product is flowing) In Drawing 3, it should be shown that lead pipe 55 is S type, and entrance portion 57 conveys a content through microwave applicator 59, returns it into it outside out of Acrylicator, is returned through it outside from the inside, and begin to pass exit line portion 61. In this way, toothbrushing or other carageenan content cosmetics pass microwave Acrylicator 3 times (or more number of times than it), It is a "solidification" period, when it is transmitted through there during a certain period to an applicator's outside, for example, 63 and 65, without the heat which occurred in material receiving additional heat in order to promote equalization of the heating effect. Of course, as shown in Drawing 2, system control can also be added to the strange method of the present invention in this drawing like the case of the processing shown in Drawing 1. In Drawing 4, conveyor 67 to which case 69 of the carton of the dispenser toothbrushing container with which it filled up is supported and moved is expressed, and those cases, carton, and a container are made from microwave permeability material. Case 69 moves in the direction of arrow 71 through microwave applicator 73, and applicator 73 heats the dispenser container in carton and a case so that it may illustrate. The interlocking device of a model and temperature control similar to the thing of Drawing 2 can be fitted to equipment of the mode shown in this drawing. Although the present invention is kneaded and it is most related with improvement of the stability of toothbrushing, and viscosity, the instruction is applicable also to manufacture of other charges of dressed lumber which were carageenan-thickened and were stabilized, for example, gel, paste shampoo, hand cleaner, and skin fleshy Youth, a skin cleaner, and spice. The constituent of a related model, for example, other various tablets which use medicine, Ointment, the thickened fluid soap, a detergent and carageenan or carageenan and other gum, or the mixture of a thickener like this, and stabilize and/or thicken a product, is improvable. Henceforth, especially kneading toothbrushing is explained. Kneading toothbrushing is often difficult to stabilize and thicken satisfactorily by the standard with one strict layer probably applied to such a product with the content of an insoluble granular material in order to use kneading toothbrushing in mouth. Although especially the following explanation is related with toothbrushing, In other various cosmetics and the same constituent, many of ingredients used during toothbrushing are useful, and the examples of those ingredients are a solvent or Vehicle, a surface-active agent or a detergent, a thickener or a gelling agent, a polish agent, a softener, a buffer, a flavor agent, and spice. A toothbrushing constituent, for example, kneading toothbrushing, usually consists of Vehicle, a polish agent, a gelling agent and a surface-active agent, or washing material. The usual Vehicle of toothbrushing is low-grade polyhydric alcohol of water, 3~6 Hydoxyl machines per molecule, and 3~6 carbon atoms. The most desirable moistness Vehicle is usually the glycerol and sorbitol in a water medium. When manufacturing transparent toothbrushing often called gel toothbrushing, the refractive index of Vehicle to be used is almost the same as it of a polish agent, and the ratio of the hygroscopic surface moisture in a product is often kept at the minimum. Instead of glycerol and sorbitol, the alcohol and polyoxyethylene alcohols of other liquefied polyols, for example, polyethylene glycols, mannitol, and other sugars can also be used. A polish agent of toothbrushing is insoluble in water powdered material with a detailed particle size which usually passes a U.S. standard sieve series of 40 meshes. Preferably a diameter of 1~40 microns and such [ still more preferably are 2~20 microns in diameter, and / particle size distribution / usually ] a range are covered. The examples of a suitable inorganic water-soluble-powder-like material are phosphoric acid 2 calcium and tricalcium phosphate, Insoluble sodium metaphosphate, crystalline material silica, colloid silica, alumino silicate of a complex, Aluminium hydroxide (three hydrates of alumina are included), magnesium phosphate, Magnesium carbonate, calcium carbonate, calcium pyrophosphate, bentonite, Although it is talc, silicic acid calcium, calcium aluminate, an aluminum oxide, aluminum silicate, and xerogel of silica and those all have polish activity, it is not abrasiveness, so that it is inconvenient. the emulsification of the ingredient of toothbrushing with uniform synthetic organicity detergent or surface-active agent which can be used into the constituent of the present invention -- or -- otherwise, distribution is helped and a pure operation is added to a product. In a certain case, they are disinfection and help prevention. Although the organic surface-active agents to be used can be negative ion nature, nonionic, both ionicity, or positive ion nature, generally it is preferred as detergency ingredients main at least to use negative ion nature, nonionic materials, or those mixtures. Among the materials of negative ion nature and positive ion nature, it is usually found out that anionic material is excellent in almost all constituents, and, in addition to those pure capability to have excelled extremely, the reasons for such predominance are those desirable foaming operations. Generally, probably, the anionic detergent contains a long-chain hydrophobic fatty series or the poly lower alkoxy group, and hydrophilic radical. These detergents are usually the forms of the water-soluble salt of an alkaline metal at salt and a thing. The example of a useful anionic detergent is high-class aliphatic acid salt monoglyceride sulfate, High-class Alkyl sulfate, high-class line alkyl aryl sulfonate, They are high-class Olef in sulfonate, high-class Alkyl sulfo acetate, the high-class fatty series Acyl amide of a low-grade fat aminocarboxylic acid compound, high-class Alkyl poly low-grade alkoxy (3~100 alkoxy groups) sulfate, and higher-fatty-acid soap. Usually, probably a higher alkyl group is 10~18 or 12~16 carbon atom, like high-class Ole Huynh, probably fatty series machines are a Alkyl machine, preferably n ―Alkyl machine, and an aromatic series machine is benzene. The examples of such a material are sodium hydrogenation palm-oil-fatty-acid monoglyceride mono-sulfate, sodium lauryl sulfate, sodium line-like tridecyl benzene sulfonate, and sodium N ―Lauroyl sarcoside and sodium A cork. in the inside of a nonionic detergent, the chain of low-grade alkoxy alkylene oxide, for example, ethylene oxide, and propylene oxide , is included -- a punch line -- there are some from which a Renoxide chain constitutes a hydrophilic radical. The examples of such a material are Pluronics and Igepals. Ucons Neodols And Tergitols It comes out. The high-class fatty alcohol polyethylene oxide condensation product which has an ethoxy basis of 3~15 per molecule in alcohol including 10~18 carbon atom, for example, Neodol25-7, and Neodol45-11 are preferred. The additional detergent is indicated to a text, Schwartz, Perry, Berch, Srrface Active Agents, and Vol. (1958). Although a gelling agent is considered in addition in addition to the ingredient of toothbrushing of the four main models, It is accepted that other various additive agents exist during many toothbrushing, and those examples are a flavor agent, an enamel hardening agent, an anti-bacteria compound, a Astringent compound, a protein precipitation agent, and a Bubbling mixture. The among these most important thing is flavor material, and, in addition to a sweetener, for example, saccharin, it includes the same known substance in oil refinement, aldehyde, ester, alcohol, and this field. The examples of oil refinement are a Spear mint, a Papeete mint, winter green, Sassafras, a clove, a sage, a eucalyptus, lemon, and a lime. Sodium mono-Fluoro phosphate, sodium fluoride, and the first tin of fluoridation can be described among enamel hardening agents. When some of toothbrushing ingredients and auxiliary agents have too high a temperature, it may be local, and even Then may be decomposed, it may react to other ingredients, and decomposition produces the difference of the taste also with clear Then at few rates, and the difference may produce consumers' severe criticism about a product. Therefore, it is important to avoid such degradation. The gelling agent which can be used for manufacture of various toothbrushing constituents can be chosen from the material of nature, composition, or mixture which the wide range can obtain. Although carageenan is the extremely outstanding gelling agent among these, having the character which is not desirable to fall viscosity, and coming out comparatively only occasionally, when the gel receives a mechanical operation, but setting at a temperature lower than Gerzol temperature in the case of carageenan -- about 45~49degreeC -- in 46~48 degreeC, viscosity is reduced more narrowly. Although carageenan is the extremely outstanding gelling agent and the gel of very satisfactory toothbrushing is generated in rational concentration, It is required to secure that the product which receives a mechanical operation using more carageenan for this viscosity fall is viscosity sufficient for an end use, And even when sufficient quantity of carageenan is used, the end products from Batches which received the operation so that it might differ may be different viscosity depending on the received processing (processings of these may differ). Although it did not have I or Tattoi that the characteristic which carageenan shows is typical about other gelling agents, when carageenan is mixed with such other Agent, for example, sodium carboxymethyl cellulose, When were processed by the method of the present invention and it was at least 20% of the gelling agents in which the ratio of carageenan exists, improving the viscosity of toothbrushing products intentionally was accepted. It mixes with carageenan instead of sodium carboxymethyl cellulose, For example, polyvinyl pyrrolidone, tragacanth gum, hydroxypropyl methylcellulose, Methyl cellulose, starch, starch glycolate, polyvinyl alcohol, sodium alginate, Kaibo bean gum, and a hydrophilic colloid hydroxy vinyl polymerization object, for example, other toothbrushing gelling agents like Carbopols, can be used. Of course, the present invention is applicable in order to stabilize kneading toothbrushing and other makeup output which were thickened by the gum or the gelling agent which shows improvement of viscosity, if it heats like carageenan. The research relevant to the present invention is almost related to using the mixture of the sodium salt of commercial carageenan, for example, lambda, and Katupa carageenan, and is Oh. However, it is thought that the present invention is well applied like the calcium salt of other various carageenan salts, for example, lambda, Katupa, and iota carageenan, potassium salt, and sodium salt, and is applied to those various mixtures. Katupa carageenan and a locust -- the mixture with diligent gum has the often improved gelling power, and is suitable for application of the present invention. Probably, the main ratio of the carageenan which exists for the hardest gel is often a mixture of a Katupa type, the iota type or Katupa, and iota, since it thickens, without lambda carageenan's gelling to this by Katupa carageenan generating gel preferably instead. However, Katupa carageenan is since it gels most strongly with a potassium ion and iota carageenan is most strongly gelled with calcium ion, Probably, it will be desirable to use Katupa carageenan, when a potassium ion exists, and to use more iota type carageenan, when calcium ion exists in a system. Usually, probably, the medium of kneading toothbrushing or other cosmetics will be near by neutrality, when it is neutral or alkaline PH or is acidity. Although acid PH and especially strong acid PH tend to hydrolyze carageenan solution, when it is in the state where carageenan gelled, they are considered to be stable when it is generally Katupa or the iota type (lambda is not hydrolyzed and gelled). The 5000~range of the molecular weight of carageenan is usually about 500000, and most things currently used commercially are the ranges of about 100000~500000. Preferably, the range of such a molecular weight is 225000~275000. The Gueroult sol transition temperature of carageenan changes depending on composition of the medium by which specific carageenan or a carageenan mixture, and it exist. In this way, gelation temperature can be raised to the 60 degreeC grade from about 5degreeC about 1% of underwater Katupa carageenan by increasing a calcium ion content to about 1% from 0%. Similarly, 0 to 1% of increase in a calcium ion content will increase gelation temperature from about 44degreeC to 72 degreeC about iota carageenan. usually heating gelling of Katupa carageenan to the temperature more than about 70 degreeC, performing it by subsequently cooling, and usually forming hard gel at the temperature between 45~65 degreeC -- this gel -- temperature -- solidification temperature -- 10~20degreeC -- it re-fuses highly at the time of Noodle. When rum carageenan is mixed with the Katupa carageenan which is a desirable gelling agent of the present invention, it is I and It was that a Gerzol point is in the range of 45~49 degreeC in the toothbrushing constituent to explain. Technically, when this temperature does not cause the Gueroult sol transition, improvement of the viscosity of a product can be obtained by heating it more than such a temperature. A desirable carageenan mixture is brand name Viscarin. Although sold with GMC, they are other commercial products, for example, Gelcarin HWG, and Sea Gel. GH, Gelcarin DG, Gelcarin SI, SedKem5, Seaspen PF,Seaspen IN,Gelcarin LMR,Gelcarin MMR,Gelcarin HMR,Gelcarin MAC,Gelcarin MIF,SeaKem C,SeaKem D,SeaKem9 And SeaKem FL2 can be used similarly. Such a product can be obtained from the marine colloid division of a FMC corporation, And those explanation is monograph (Monograph)No.1 of a marine colloid company, and Technical. The technical report it is [ Seminar Nates ] entitled, marine colloid division of a FMC corporation, It is found out by New Jersey 07081 Springfield and publication. Probably, in the present invention, the ratio of the carageenan to be used is usually 0.1~5% of the weight of a range. When carageenan is only one sort of a thickener of some existing models, or a gelling agent, the ratio is at least 20% of the total quantity of a gelling agent which exists during kneading toothbrushing for a useful stabilization effect acquired by the present invention. And the total quantity of a gelling agent will knead and will not usually exceed 5% of the weight of toothbrushing. Usually, when carageenan is a thickener (although it is moreover some thickeners) Kneading toothbrushing will consist of about 10~70 or 75% of granular polish agent, 0.2~3% of carageenan, 0.2~20% of foaming agent, 2~50% of polyhydric alcohol, and 5~50% of water, when satisfying front conditions. If such an ingredient is used, various auxiliary agents can also exist 20% or less of kneading toothbrushing in a quantity usually smaller than 10% or less, preferably 5%. In a certain manufacture, polyhydric alcohol can be eliminated completely, and, in a certain case, moisture can be made into the minimum, but as for the mixture of water or polyhydric alcohol, preferably both, existing as Vehicle is preferred. For the outstanding heat by microwave, the polar substance should exist a certain Rosie (lossy) dielectric material, for example, water, or other polarity, and highly. It is an ingredient with water desirable to the altitude of a product to the object of the present invention, and is often indispensable. The ratio with an ingredient preferred about a water kneading toothbrushing system is 40~60% of polish agent, It is 0.5~2% of carageenan (or thickener mixture), 0.2~10% of foaming agent or a detergent, 5~35% of polyhydric alcohol, and 8~30% of water, and more desirable ratios are 45~55%, 0.5~1.5%, 15~30%, and 20~30%, respectively. About gel toothbrushing, these ratios are 10~50%, 0.5~2%, 5~15%, 30~75%, and 10~30%. The auxiliary agent content about both opaque and transparent kneading toothbrushing and gel is 0.5~5% of range preferably, and a flavor agent is the 0.5~2.5% preferably. When chloroform exists as a flavor means or a purge auxiliary agent, it can constitute 1~5% of addition of a product so that it may be allowed in a certain case. Neither of other auxiliary agents will usually exceed 5% of products in total. the patent of versatility [ manufacturing process / of suitable toothbrushing of the present invention ], and inside -- U.S. Pat. No. 3711604 -- and -- said -- it is indicated to 3840657, and toothbrushing is deaerated in these methods, or it has the air bubbles meant and added, and the method of the present invention is still more advantageous in these cases. A microwave generator and an applicator are the processing units known well, and, probably, do not need to explain in detail here. Although it is possible that the spectrum of microwave is an about 0.3~300-GHz grade, and a corresponding wavelength is in 1 mm from 1 m, It is usually 0.3~50 GHz, and probably, microwave radiation is 0.8~3 GHz, since it is using a 0.915~2.45-GHz belt in the U.S. as a practical matter (a 0.896-GHz belt is used in Britain). Industrial application of the versatility of microwave technology is The. Publication of International Microwave Power Institute (Canada), For example, Microwave Volume on Power in Industry and W.A.G.Voss and W.R.Tinga, It is indicated to the 2nd edition, the 1978 one monthly publication, Industrial Application of Microwave Energy, R.B.Smith, and 1976 annual publications. It is microwave as stated into these reference publications, Even if generated by any of a klystron or a magnetron (most things related to the present invention are magnetrons), in various industrial use, it has been used for various substances affected by heating, a polymerization, dryness, gelling, and other radiation. However, the statement of the method of the present invention, suggestion, or its profits do not exist in such a publication. It is not thought that the quantity of the microwave energy which should be transmitted to kneading toothbrushing according to the present invention is criticality-like as long as it fully rises, although the temperature of kneading toothbrushing is improved [ the viscosity in the room temperature of after-cooling products ]. In this way, in order to receive the result of desired thickening and stabilization, it is thought that temperature should be gone up above the Gueroult sol transition temperature of carageenan under the conditions to govern, but processing is useful as long as the increase effect of desired viscosity is acquired. A speed of supply, the irradiation time of microwave radiation, the quantity of production of kneading toothbrushing, etc. are easily calculable from the electric power of a microwave generator, and the specific heat of the product processed. In this way, since 1 kWh is equal per about 860 kcal, i.e., about 3420 British heat, 1 kW is equal to a part for about 14.3-kcal [// a minute and ], i.e., about 57 BTU(s),/. The electric power of a magnetron required in order to calculate a microwave applicator's efficiency (this can be made into about 50~60%) and to obtain the desired quantity of production is determined. Although the size of the microwave applicator who should install in fixed operation is usually determined by the production rate of various environment, for example, effective space, and a request, the material to process, etc., It seems that usually, it is 2 minutes or less at the time of short Nuclear and in-line processing, and heats kneading toothbrushing from 5 minutes to request temperature in short paddle time comparatively at the time of massive processing. Exposure of microwave is more preferably restricted to 30 seconds by 15 seconds in 1 minute. The following example explains the present invention. Unless it mentions specially, all the parts are based on weight. EXAMPLE % Glycerol 4.5 sorbitol 17.5 Viscarin GMC (copper rum carageenan, made in a FMC corporation) 1.0 sodium benzoate 0.5 Sodium saccharin 45.3 fumed silica 0.2 water (Cab-O-Sil) 22.4 phosphoric-acid 2 calcium (90% hydrate) M5) 5.0 Sodium lauryl sulfate 1.5 Sodium fluoride 0.5 Sodium monofluorophosphate 1.0 Peppermint flavor agent 0.6 100.0 Prescription of the upper opaque kneading toothbrushing is obtained by mixing, after distributing carageenan in glycerol at first in room temperature in an ordinary mixer by a known method and mixing an ingredient by high temperature, preferably about 70 degreeC underwater succeedingly. However, the last mixture temperature is about 37degreeC, using the mixture for 30 minutes, in the rear of total mixed time, it performs deaeration by decompression of 700mmHg, subsequently kneads it, moves toothbrushing, and stores it overnight. From storage space, kneading toothbrushing is mechanically carried to an automatic filling apparatus, and it kneads with this device, and fills up the tube for toothbrushing. Then, the content of such a tube is examined about the consistency after the storage for two days. The used examination includes measurement of the Brookfield Helipas viscosity, and measurement of the degree of thickening so that it may mention below. Viscosity examines a number of samples which knead at the temperature of about 27 degreeC and have toothbrushing using the suitable spindle of the Brookfield viscosity meter, and measures them by averaging a result. As comparison, the synthetic organicity polymer dispenser container which has a body part of polyethylene and the cap of polypropylene is filled up with toothbrushing, Sealed, sufficient microwave energy to raise the temperature of a line intermediary and a content from about 27degreeC for heat by microwave to the temperature of the range of about 57 degrees C~71 degreeC for 15 seconds each was made to absorb, and it cooled in inactive to about 27 degreeC. After settling for two days, toothbrushing in such a pipe was measured about the consistency. In the examination of a consistency, reading of the Brookfield Helipas viscosity is supplemented with and checked using a "cubane (Cuban)" tester. Measurement of such viscosity is performed by using a Brookfield viscosity meter RVF type together with Helipas (Helipath) and TF spindle in 4 rpm. In the "Kukoban" examination of a check, the interval of horizontal OFF intermediary extraction and a lattice increases the lattice of a parallel stick one by one through the orifice of the size which fixed toothbrushing from the tube. A test result is expressed as the greatest space number (number of 1~12). This number expresses the longest distance between the sticks supported without destroying the ribbon of toothbrushing. As for reading of Brookfield, and a cubane tester's reading, being connected directly substantially are I and It was. Controlled study increases reading of viscosity about an unsettled product substantially by processing of I got it microwave using many samples, and an increase in viscosity is Centipoise and almost always size from 50%. It is often about 90% and it is shown that an increase in average is about 73%. The reported result is similarly obtained, when carrying out heat by microwave of the toothbrushing within a glass tube, although it is above. The same result is performed within the microwave applicator who illustrates microwave processing roughly to Drawing 2, Processed kneading toothbrushing deaerates in a batch mixer with decompression connection, and it settles overnight, and it is obtained, when [ at which it subsequently carries to an automatic filling machine ] carrying out between heat by microwave and cooling radiationally in after-restoration inactive. In such operation, when performing restoration at a still warm temperature preferably higher than the Gueroult sol transition temperature, heated kneading toothbrushing is that which is low viscosity (it will increase viscosity compared with contrast if it cools), and it can accelerate such restoration. In the strange method of the above-mentioned experiment, microwave radiant energy is set many times at passage for kneading toothbrushing by which a pump transfer is carried out through the line which passes through the inside of a microwave applicator, In order that it can glare and a line may promote the mixture during heating in a certain case, it can have guidance inside. As shown in Drawing 3, when using passage many times, toothbrushing can be periodically taken out from a microwave room, and also distribution of the improved heat can be promoted (a microwave heater already gives the outstanding heat distribution compared with other various heating methods). A toothbrushing tube will be filled up with the Ivy products attached using the device of Drawing 3, and they will increase viscosity calmly like the above-mentioned product after cooling. In other strange methods of the present invention, it is a microwave permeability dispenser container about kneading toothbrushing, For example, after filling up a Made thing and a cap (cap of polypropylene), or other seal means from polyethylene and polypropylene, it ranks next, After [ before packing into the carton of a dispenser container, and a case ], It can glare with microwave with the quantity calculated so that such a product might be heated at temperature to the request of the range of 45~75degreeC preferably 46~60degreeC, or 46~48 degreeC, and after that, a product is cooled without having a mechanical operation. Since the material of a case and carton is essentially transparent to microwave radiation like the plastic material of the polymer of a dispenser tube, kneading toothbrushing is the only substance heated to such an extent that it can accept. Kneading toothbrushing in such a tube has large viscosity and consistency similarly rather than contrast toothbrushing by which microwave processing is not carried out such. In other strange methods of the present invention, the device illustrated to Drawing 2 is installed into the restoration line for restoration of the above-mentioned carageenan stabilization kneading toothbrushing, A flow sensor and a temperature sensor are operated as mentioned above, kneading toothbrushing is heated more than the Gueroult sol transition temperature of the carageenan in 48degreeC and its environment, and kneading toothbrushing with which this was filled up has the viscosity of the improved room temperature which increased. Of course, kneading toothbrushing is accepted after cooling, and does not receive a significant mechanical operation in a degree, but is sent to restoration A head in the state warm desirable still. After a specific experiment is completed, this device is easily changed into other filling lines which carry the Calah Genin thickening kneading toothbrushing similarly, and microwave processing of such a constituent is carried out similarly. The above-mentioned various products do not show the inconvenient loss of a flavor at all, and they do not show the proof of decomposition of a large ingredient at all rather than being able to set to various contrast. By using an above-mentioned device and method, the grade of the quality control about the viscosity of a product can be improved, and such viscosity of the commercial last product can be close brought by a desired standard. When superfluous carageenan is beforehand used as a thickener and stabilizer, in addition, the product of the viscosity which can decrease to many to about 50%, simultaneously can permit the ratio in it can be obtained. The present invention is applicable to carageenan and other supplementary thickeners, for example, the constituent containing sodium carboxymethyl cellulose. For example, in the upper prescription, when replacing the half of carageenan with sodium Carboxy cellulose and performing the same processing, the increase in viscosity is not so large, but they are Then and about 23% in the grade which may be perceived in addition. However, when cellulose gum is used instead of carageenan and carageenan does not exist, the increase in viscosity is insufficient for observing. The present invention is applicable to prescription of other various toothbrushing of those other than what was mentioned above in this example. For example, carageenan is used by the same ratio or an equivalent ratio instead of the gum and the thickener which are shown here, When performing same thickening in Sagarin and Cosmetics:Science andTechnology which are added here by quotation, and formula 1~15 indicated to 339 - 341 pages, If heat by microwave of the kneading toothbrushing obtained is carried out as mentioned above, the result which improves desirable viscosity and consistency similarly can be obtained. If microwave processing of the transparent gel toothbrushing which was thickened by carageenan or was partially thickened by the carageenan-ized agent, for example, Viscarin GMC, is carried out by the above-mentioned method, the viscosity and the consistency which were improved will arise similarly. If cellulose gum is used instead of carageenan, the same result will not be obtained, and after heat by microwave, if toothbrushing is attached for mechanical-acting or stirring at a temperature lower than the Gueroult sol transition temperature, the same result will not be obtained. The front example illustrated operations and those various advantages of the present invention. According to the present invention, maintenance and viscosity of the fluid makeup products which contain carageenan as a gelling agent, for example, the viscosity of kneading toothbrushing ,, a consistency, and a form can be increased and controlled clearly from them and the accompanying explanation. According to the present invention, the level of the carageenan used in order to obtain the request viscosity of the end products can be decreased. Although the viscosity of a product is maintainable by maintaining until it processes makeup products in high temperature and a product is filled up with this temperature, Such a thing cannot usually be carried out in toothbrushing because of discontinuation of normal manufacture and not 24-hour manufacture but the work of every day of 8 hours, an operation stop, and conversion. When the remarkable loss of volatile matter like hygroscopic surface moisture and a flavor agent stores a product at the time of heat, it may take place. The air between such mixtures is introduced, and since [ that it is Lost in volatile matter ] it is divided, generally re-heating in Reservoir is dissatisfied. It is comparatively late to heat the lead pipe of kneading toothbrushing continuously by electricity, vapor, or other means, and it is inefficient-like, and is uneven, and a product may burn. Since such all the faults are conquered by the present invention and a product becomes thin in addition for microwave processing, pumping is carried out by low power consumption, and better mixture is obtained, and the process of restoration and a transfer can be carried out more easily and more quickly. When comparing with the conventional heating method, according to heat by microwave provided with a momentary changeover switch and alternative electric power control, the detected conditions can sometimes be answered immediately. In this way, when it kneads in a microwave applicator and toothbrushing does not move a lead pipe any longer so that it may indicate in the example, the electric power is turned off immediately, and when temperature rises above a request limit, interception or reduction of such electric power takes place. A response is not delayed. All the sent electric power kneads, it is under toothbrushing, and changes to heat, and the breaking Lost thing does not exist in essence. Kneading toothbrushing is heated and a wall, a lead pipe, etc. are not heated (except for the case where it is based on conduction). A microwave radiation unit does not heat the working clearance which encloses a unit. The microwave device is beautiful, and is quiet, and tends to receive perception control of temperature, heat transfer speed, viscosity, and a flow. Such a sensor prevents the excess of heating of a product, and shortage. It can further increase that heating of a product is an inside, and is uniform, and such homogeneity stirs the place of microwave, or by moving in a part mechanically [ when it passes along a lead pipe before microwave for a product ] (however, it is not thought that this is required). It can be increased by the heating rate by increasing the electric power to apply changing the time when a product is exposed to microwave, and by re-circulating through material. Heating according [ kneading toothbrushing and the original highest makeup products of hygroscopic surface moisture ] to microwave becomes quick, and I hear that the microwave radiation further accelerates heating as temperature increases the advantage of the method of the present invention. A system is a preferably closed system, and when a product passes along microwave radiation before by this, aeration or evaporation does not take place and it does not lose a flavor agent by evaporation. Since the above-mentioned various advantages were very important, it examined extensively [ the method of the present invention ] and proved the result of the early laboratory. Kneading toothbrushing containing a carageenan gelling agent came to hand from what is commercially manufactured in the country of a certain number, and it examined about whether those viscosity is improved by the method of the present invention. Examining [ and ] 13 kinds manufactured by different prescription under the conditions of various manufactures and restoration of different kneading toothbrushing, viscosity is 46~89% of range, and increased an average of 69%. About the group of other samples of nine nations, the increase in average viscosity is 62%, and only one sample is low Made from 40%. 50:50 carageenan: The sample from the commercial manufacture containing a cellulose gum thickener showed the increase in an average of 42% of viscosity (11 kinds of samples). Therefore, while it is expected that the quantity of a gum mixture besides the carageenan which manufactures and uses kneading toothbrushing with higher viscosity, or carageenan can be decreased, in addition, the plant according to the present invention can obtain desired viscosity, and can maintain the standard of quality control. In such equipment, it elaborates on a microwave unit and it is installed between toothbrushing Reservoir and the last restoration unit, It is heated before filling up finished toothbrushing, and even when a harsh mechanical operation is received before restoration, it should be made for toothbrushing to have the consistency improved in room temperature. As an exception method, the plastic tube in which it filled up with toothbrushing can be heated with microwave as mentioned above. However, improvement of viscosity is obtained, even when toothbrushing is heated, and it subsequently stores overnight and is made to return to room temperature before restoration. the experiment of a laboratory -- kneading toothbrushing -- the initial temperature -- 25degreeC -- in order to heat to a high temperature, requiring about 1 kW per kg was shown. Depending on the cost of electric power, it elaborates on this work, and from 0.1 cent per 5-oz usual tube of toothbrushing, it is smallness and can collect such costs by saving the gelling agent by which Deleting expense is carried out. In this way, if a 20-kW microwave unit is used, kneading toothbrushing by which it was heated at the time of 1200kg (i.e., about 7500)/[ o'clock and ] tube /can be manufactured. Not increasing in an additional experiment, to such an extent that the repetitive microwave processing can accept the viscosity of a product (about 5% or more), that the viscosity of a product is not dependent on the cooling rate after exposure to the microwave of a product, Heat, and It was. According to the storage examination about the processed product, after storing [ long ] by six months, although the viscosity of kneading toothbrushing is still quite higher than an unsettled product, it is shown about the product and the unsettled product which were processed at the time of storage that viscosity usually decreases somewhat.

[Brief Description of the Drawings]

Drawing 1 expresses roughly carageenan content cosmetics, for example, the manufacturing process from mixture of kneading toothbrushing , to storage. Drawing 2 is an approximate line figure of the microwave applicator equipment in the conveyance line of toothbrushing. Drawings 3 are some schematic plan views of change of the device of Drawing 2. Drawing 4 is a side view of a conveyor which has a microwave applicator suitable in order to heat packed toothbrushing who unites. 11 ... mixer, 13 ... storage or maintenance, 15 ... microwave heater means, 17 ... dispenser filling machine, 19 ... packing, 21 ... storage, 23 ... microwave applicator, 25 ... lead pipe of a microwave permeability wall, 27 ... flexible end part, 29 ... flexible end part, 31 ... fastening means, 33 ... fastening means, 35 ... exchange electric power supply line, 37 ... electric power supply machine, 39 ... macroscopic wave generator, 41 ... line, 43 ... a flow sensor and electric power interlocking device, 45 ... probe portion, 47 ... contact, 49 ... a temperature sensor and electric power regulator, 51 ... probe, 53 ... line, 55 ... lead pipe, 57 ... entrance portion, 59 ... microwave applicator, 61 ... exit line portion, 63 ... a macroscopic wave applicator's outside, 65 ... macroscopic wave applicator, 67 ... conveyor, 69 ... case, 71 ... arrow, 73 ... microwave applicator.