Transparent molding

[Detailed Description of the Invention]

[Field of the Invention] The present invention can be immersed in abrasion-proof nature, abrasion resistance, shock resistance, chemical resistance, flexibility, heat resistance, lightfastness, the 1st division-proof nature, etc., and the light-proof robustness is related with a transparent fabrication object suitable for optics, such as a good lens for glasses, and a lens for cameras, about a dyeing article. "Conventional technology] The plastic fabrication object represented by the plastic lens has the extremely outstanding shock resistance and transparency, and its demand is increasing sharply from those with Lightly and dyeing being easy in recent years. However, there is a fault that surface hardness of a plastic lens is low compared with inorganic glass, and a crack is attached easily. On the other hand, generally, Comparatively mechanical strength or since it is low, the plastic lens must thicken lens center thickness at unaccomplished glass, The serious fault that an end is generally remarkably thick especially in the advanced number lens for nearsightedness since the refractive index is low compared with an inorganic crow, and there is a tendency for appearance to make an issue of fashionability bad, and to have wear kept at arm's length is Be necessarily. Many trials which are going to improve the fault of the former ease of getting damaged are already proposed. For example, they are nothing (it is vacuum deposition about Something), such as 3i02, to the plastic substrate surface. The method (JP,58-204031,A) of covering, and a method of providing a polyorgano Silane system hard court film and an acrylic hard court film in the surface of a plastic substrate (USP3,986,997, USP4.211, 823, JP,57-168922,A) JP,59-38262,A, JP,59-51908,A, JP,59-51954,A, JP,59-78240,A, JP,59-89368,A, JP,59-102964,A, JP,59-109528,A, JP,59-120663,A, JP,59-155437,A, JP,59-174629,A, JP,59-193969,A, and JP,59-204669,A are indicated. It inquires [ an end becoming it remarkably thick to set in the latter fault, i.e. advanced number Lons of minus, on the other hand, and raising the refractive index of a plastic substrate for the purpose of improvement of appearance or a bad point in recent years, or ], and the proposal kana of many is carried out (JP,58-17527,B, JP,58-14449,B). JP,57-28117,A, JP,57-5490,A' No. 1 gazette, JP,57-1026,A (No. 11 gazette, JP,57-1049,A (No. 11 gazette, JP,58-18602,A, JP,58-721,A (No. 11 gazette, JP,59-87124,A, JP,59-93708,A, JP,59-96109,A).)) While improvement of the surface hardness by the vacuum deposition of inorganic substances, such as 8102 which is the above-mentioned conventional technology, is high hardness, it has a big problem on which adhesion nature with a substrate, heat resistance, shock resistance, heat-resistant water, lightfastness, etc. are reduced. There is also a serious fault of abolishing the stainability which is one of the features which a plastic lens has. The art of providing the Silang system and the acrylic hard court film which are indicated by JP,59-38262,A, JP,59-51908,A, etc. is heat resistance, If it is difficult to control film thickness uniformly and a refractive index applies to 1.55 or more substrates, while excelling in shock resistance and stainability, The interference fringes by the difference of the refractive index of the substrate with which a Have been used refractive index did not become a problem in the former, and Bert Cau 1 and a film produce less than 1.55 plastic lens On a substrate, and appearance worsens. This problem is Dissolution(ed) by bringing the refractive index of a Bert Cau 1~film close to the refractive index of a substrate, and is indicated about the constituent for coating which becomes JP,57-168922,A from the antimony pentoxide sol which has a high refractive index, and an organic silicon compound. however, this art -- stainability -- a large -- it has a Notice fault. 3i02 [ around 1-micron ] is covered with vacuum deposition on a plastic substrate in order to improve and to improve the surface hardness of a plastic, and antireflection both, and also the method of carrying out the antireflection film of a multilayer film to Cau 1 on it is indicated. (JP,56-1131,A (No. 11 gazette).) JP,59-48702,A and JP,59-7830,A "I@; gazette, The method of Cau I~ Carrying out the antireflection film which Membrane needs gave JP,59-78304,A the epoxy resin hardening film to polyorgano Silane system Bert Cau 1 at the surface of the plastic substrate, and also consists of inorganic substances is indicated. JP,56-1131,A (while the art currently indicated by 11@ gazette has antireflection with high hardness, it reduces adhesion nature, heat resistance, shock resistance, heat-resistant water, weatherability, etc., and is a big problem.) JP,59-48702,A and JP,59-783,A (the adhesion nature to a substrate being insufficient, generating deeply and thickly in a crack, and setting on use the art currently indicated by No. 11 gazette and the JP,59-78304,A @ gazette, while it has antireflection -- a large -- it has a Notice fault.) There is a big problem in the adhesion nature after hot water immersion which is easy to be dipped in water, alcohol, etc. common, weathering adhesion nature, etc.

[Problem which an invention tends to solve] These artificers reached the present invention described below, as a result of inquiring wholeheartedly, in order to solve the above-mentioned problem. Namely, the present invention is excellent in pickpocket-proof Belief, abrasion resistance, a shock-proof j student, chemical resistance, flexibility, heat resistance, lightfastness, i'li1 Weather, stainability, etc., and is the color fastness to light or a good transparent fabrication object (it Compendiums.) about a dyeing article. Giving the above-mentioned characteristic or the made transparent fabrication object is provided, without producing the poor appearance by interference fringes in a plastic with a high refractive index which contains an aromatic ring and a halogen atom as other objects common (except for fluoride). Other objects of the present invention are for providing the transparent fabrication object which was able to be kept to endurance and the antireflection which has heat resistance. The means for solving one problem, i.e., the invention of the 1st of the present invention," consists of the next Drawing. As opposed to the organic silicon compound denoted by following general formula (I) on the surface of a transparent substrate, and/or the hydrolysis thing 100fflffi section, The polyfunctional epoxy resin which has an aromatic ring,/, and 1 Yellow aliphatic ring is related with the Gift-ized antimony particulates whose 10~300 weight sections and mean particle sizes are 1~200 mmicro, the hardening transparent membrane which consists of a constituent containing 25~800 weight sections, or the transparent fabrication object which it comes to cover. R1aR2bSi (OR3) +-r Yunare 2 (I)^ carrying out (inside R1 and R2 of a formula is an each Alkyl machine, an alkenyl group, and an aryl group) Or one or more sort Be necessary chosen from the hydrocarbon group which has a halogen group, an epoxy group, a glycidoxy machine, an amine machine, a mercapto group, a metacryloxy machine, or a cyano group, and R1 and R2 may be of the same kind respectively, or it may be by different species. R3 is a hydrolytic basis and a and b are O or 1. It is related with the transparent fabrication object with which it comes still more preferably to cover the transparent membrane which a transition metal compound and/or its reaction product come to contain in the above-mentioned constituent. The 2nd invention relates to the transparent fabrication object characterized by coming to cover the transparent membrane which provided the hardening tapetum lucidum which consists of the 1st above-mentioned invention or the 1st invention on the surface of a transparent substrate, and also consists of inorganic oxides. Yes which the present invention relates to a transparent fabrication object suitable for optics, and is denoted by the (A) following general formula (1) on the surface of a transparent substrate receives a silicon compound and/or 100 weight sections of its hydrolysis thing, (B) An aromatic ring and/or a fatty series ring It is related with the transparent fabrication object with which it comes to cover the hardening transparent membrane which the polyfunctional epoxy resin which it has becomes from the constituent containing 10~300 weight sections and the (C) mean particle size, the antimony oxide particulates of 1~200 mmicro, or 25~800 weight sections, and its manufacturing process. R'R2S! (OR3) 4- (a+b) inside R1 and R2 of the formula which is (I)-seen and is spread -- each Alkyl machine, Alkenyl group, aryl group or halogen group, epoxy group, glycidoxy machine, amine machine, mercapto group, and metacryloxy machine Necessarily may be one or more sorts chosen from the hydrocarbon group which has a cyano group, and R1 and R2 may be of the same kind, or they may be different species. R3 is a hydrolytic basis and a and b are O or 1. As a transparent substrate in the present invention, it is inorganic glass, Various plastics, for example, an acrylic resin, polycarbonate, diethylene glycol bisallyl carbonate Borimer, (Halogenation) Di(meth)acrylate polymer and its copolymer (urethane denaturation di(meth)acrylate polymer of halogenation> bisphenol A, its copolymer, etc. are used preferably.) of bisphenol A, The refractive index of a substrate is preferably applied to 1.55 or more things from the point of prevention of rainbow generating especially by the cross protection of light. It has an aromatic ring in a main chain and/or a side chain especially, and application to 1.55 or more plastics has a preferred refractive index. It has a Ah @ ring in a main chain and/or a side chain here, and a refractive index is 1.55 or more resin, For example, the polymer of the styrene derivative shown by the following general formula (n) (being here) R' expresses the halogen group except fluoride, a methyl group, a Edel machine, a methoxy group, an amino group, a 21~Ro machine, a phenyl group, and a phenoxy group, C is an integer of O~5, R' is of the same kind at the time of C>=2, and it is as Must, They are good phenol or various substitution phenol, those ethylene oxide, or a propylene oxide addition (polymer of meta-> acrylic ester) as Must at different species. Screw phenol or substitution screw phenol Rude is a polymer of the acrylic ester (meta) of those ethylene oxide or a propylene oxide addition, and Di (meta) acrylic ester, The polymer of the addition reaction thing of the mono-(meta)acrylic ester which has a hydroxyl group common, and various isocyanate compounds, The polymer of acrylic ester or Di (meta) acrylic ester, benzyl alcohol, or various substitution benzyl alcohol (polymer of meta-> bitter taste 1 Knoll acid ester) which has a biphenyl Japanese rank (meta) the polymer of divinylbenzene or various Replacement divinylbenzenes -- although a bisphenol A type epoxy resin, a screw phenol F type epoxy resin, etc. are mentioned as the example common It is used preferably, without being limited especially if it is the refractive index or 1.55 or more resin which has an aromatic ring. Even if it is with copolymer resin of the monomer which has these aromatic rings, and the monomer which does not have a copolymerizable aromatic ring, if the refractive index of the polymer has 1*55 or more, it is preferred similarly. As opposed to the organic silicon compound denoted by the surface of the transparent substrate of the above [ the present invention ] by the above-mentioned general formula (1), and/or its 100-fold hydrolysis thing Quick part, It is formed when 10~300 weight sections of epoxy resins which have an aromatic ring, and a mean particle size apply the tunic which has 25~800 weight sections of antimony oxide particulates which are 1~200 mmicro. Organic Le denoted by general formula R1aR2bSi4(OR3)□-b here although it is As the concrete example of representation of a Tokai matter compound and/or its hydrolysis thing, Methyl Sirigawa 1-, ethyl silicate, n-propyl silicate, Te l~Laalkoxysilane, such as i~propyl silicate, low petit Rusilikayej~, and 5ec-butyl silicate Miyabi t-butyl silicate And the hydrolysis thing and also methyl 1 Helimethoxysilane, methyl triphenoxysilane, It is Xylosilane to methyl Trimethoxye 1~Xylosilane and methyl 1~Rease 1, They are Reacetoxysilane and vinyl trimethoxy ethoxy Silane to Methylri butoxysilane, ethyl 1~methoxysilane, ethyl 1~Rie 1~Xylosilane, vinyl 1~Remixthoxysilane, vinyltriethoxysilane, and vinyl 1, Phenyl 1 Helimethoxysilane, phenyltriethoxysilane, phenyl triacetoxysilane, Gamma-chloropropyltrimetoxysilane, gamma-chloropropyl Trier 1~Xylosilane, gamma-Tarolo propyl triacetoxysilane, 3.3.3-1 Heli floro propyl 1~Remixthoxysilane, Gamma-methacryloxypropyltrimethoxysilane, gamma-aminopropyl trimethoxysilane, gamma-aminopropyl Trier 1~Xylosilane, gamma-Mercapto propyl 1~Remixthoxysilane, gamma-Mercapto propyl 1 helicopter Engineering 1~Xylosilane, N-beta-(aminoethyl)-gamma-aminopropyl trimethoxysilane, beta-cyano ethyltriethoxysilane, methyl triphenoxysilane, Chloromethyl trimethoxysilane, chloromethyl trimethoxysilane, Glycidoxy methyl triethoxysilane, glycidoxy methyl triethoxysilane, alpha-glycidoxy ethyl Trimet 1~Xylosilane, alpha-glycidoxy Ethyltria 1~Xylosilane, beta-glycidoxy ethyl Trimet 1~Xylosilane, beta-glycidoxy ethyl triethoxy silane, alpha-glycidoxy propyltrimethoxysilane, alpha-glycidoxy propyltriethoxysilane, beta-glycidoxy propyltrimethoxysilane, beta-glycidoxy propyl 1~Lethoxysilane, gamma-glycidoxypropyltrimetoxysilane, gamma-glycidoxy propyltriethoxysilane, gamma-glycidoxy propyl Tripovoxy silane, gamma-glycidoxy pro Piltri butoxysilane, gamma-Crysoxypropyl trimethoxy Ethoxysilane, gamma-glycidoxy propyl 1~Rif enoxy silane, alpha-glycidoxybutyl trimethoxysilane, alpha-glycidoxybutyl triethoxysilane, beta-glycidoxybutyl 1-Claw 1~Xylosilane, beta-glycidoxybutyl 1~Lethoxysilane, gamma-glycidoxybutyl 1~Remixthoxysilane, gamma-glycidoxybutyl 1 Heliethoxysilane, delta-glycidoxybutyl trimethoxysilane, delta-glycidoxybutyl j~1 Noe 1~Xylosilane, methyl trimetoxysilane (3, 4-epoxycyclohexyl), methyl (3, 4-epoxycyclohexyl) 1~Rie 1~Xylosilane, beta - (3, 4-epoxycyclohexyl> ethyl 1~Remixthoxysilane) beta-(3, 4-epoxycyclohexyl) ethyltriethoxysilane, beta-(3, 4-epoxycyclohexyl) ethyltriethoxysilane, It is Xylosilane to beta-(3, 4-epoxycyclohexyl) ethyl top 1, beta-(3, 4-epoxycyclohexyl) ethyl Trimet 1~Xyethoxysilane, beta-(3, d-epoxycyclohexyl) ethyl 1~Rif enoxy silane, It is Xylosilane to gamma-(3,4-epoxycyclohexyl) propyl Trimet l, gamma-(3,4-epoxycyclohexyl) propyl 1~Lethoxysilane, beta-(3, 4-epoxycyclohexyl) butyl 1~Remixthoxysilane, Trialkoxysilane, such as beta-(3, 4-EPO Kishishiku mouth hexyl) butyl 1~Rie 1~Xylosilane, 1~rear Siloxysilane, triphenoxysilane or the hydrolysis thing of those, and dimethyldimethoxysilane, Phenylmethyldimethoxysilane, Dimethyl diethoxysilane, phenylmethyldimethoxysilane, gamma-chloropropyl methyl dimethoxysilane, gamma-chloropropyl methyldiethoxysilane, dimethyldi acetoxysilane, r-metacryloxy propylmethyl dimethoxysilane, gamma-metacryloxy propyl Methyl cheese 1~Xylosilane, T-Mercapto propyl Methyl dimer 1~Xylosilane, gamma-Mercapto propylmethyl diethoxysilane, gamma-aminopropyl methyl dimethoxysilane, gamma-aminopropyl methyldiethoxysilane, methylvinyl dimethoxysilane, Methylvinyl diethoxysilane, glycidoxy methyl methyl dimethoxysilane, Glycidoxy methyl methyldiethoxysilane, alpha-glycidoxy ethyl methyl dimethoxysilane, alpha-glycidoxy ethyl methyldiethoxysilane, beta-Glycine 1 Hexylethyl methyl dimer 1 Hexisilane, beta-glycidoxy ethyl methyldiethoxysilane, alpha-glycidoxy pro Bill Mr. Jimme 1~Xylosilane, alpha-glycidoxy propyl methyldiethoxysilane, beta-Glyshitoki Cipro Pyramidjime 1~Xylosilane, beta-glycidoxy propyl methyldi Engineering 1~Xylosilane, gamma-glycidoxy propyl methyldimethoxysilane, gamma-glycidoxypropylmethyldietoxysilane, gamma-glycidoxy Provil methyldi propoxysilane, gamma-glycidoxy propylmethyl dibutoxysilane, gamma-glycidoxy propylmethyl dimethoxy Ethoxysilane, gamma-glycidoxy propyl methyldi Phenoxysilane, gamma-glycidoxy propyl Ethyl dimme 1~Xylosilane, gamma-glycidoxy propylethyl diethoxysilane, gamma-glycidoxy pro Bill ethyl diproxy silane, gamma-glycidoxy propyl vinyldimetoxysilane, Dialkoxy Silane, such as gamma-glycidoxy propyl Vinyl jie 1~Xylosilane, gamma-glycidoxy propyl phenyl dimethoxysilane, and gamma-Glycine 1~Xyprovil phenyl je 1~Xylosilane, diacyl Oxysilane, or the hydrolysis thing of those is the example. These Yes can also add one sort or two sorts or more of silicon compounds. Use of a silicon compound is preferred for especially Yes that contains an epoxy group and a glycidoxy machine in the object of stainability grant. As for these Yes, in order for a silicon compound to lower cure temperature and to advance hardening more, it is preferred to use it, hydrolyzing. Hydrolysis is manufactured by pure water or chloride, and acetic acid Necessarily adding aqueous acids, such as sulfuric acid, and Agitation(ing). Pure water and the Necessarily can also do the Cong 1~roll of the degree of hydrolysis easily by adjusting the amount of addition of aqueous acids. Especially when hydrolyzing, eye Attendance of more than Mol [ basis / of a general formula (1) / hydrolytic ], the pure water not more than 3 time mol, or aqueous acids is preferred in respect of promotion of hardening. Since alcohol etc. generate when hydrolyzing, it is also possible to hydrolyze with a non-solvent or to perform hydrolysis, after mixing a solvent with an owner A silicon compound in order are possible or to hydrolyze still more uniformly. It is also possible to use the alcohol after hydrolysis, etc. under heating and/or decompression according to the object, removing them in an adequate amount, and it is also possible to add a suitable solvent after that. As these solvents, solvents, such as aromatic hydrocarbon, such as alcohol, ester, ether, ketone, halogenated hydrocarbon or 1~Ruen, and xylene, are mentioned. These solvents can also be used as two or more sorts of mixed solvents if needed. It cannot be overemphasized that heating beyond room temperature is also possible in order to promote a hydrolysis reaction according to the object and to advance reactions, such as preliminary condensation, common, and it is also possible to lower hydrolysis temperature beyond room temperature and to perform it in order to suppress preliminary condensation. As antimony oxide particulates of mean particle size 1~200mmicro in the present invention, Yes, such as water of 3 Decoction-ized antimony and/or antimony pentoxide and/or alcohol, are mentioned to a solvent as an example with concrete antimony oxide sol which colloid was made to distribute. Although the thing of mean particle size 1~20Qmmu is used for the object of the present invention, it is preferably used in the thing of the diameter of a particle of 5~100mmicro. That in which a mean particle size exceeds 200 mmicro has the bad transparency of a generation coat, and only the big thing of muddiness is obtained. Antimony pentoxide is preferably used from points, such as toxicity. In order to improve the dispersibility of antimony oxide particulates, even if it has added various kinds of surface-active agents and amine, it is satisfactory in any way. Antimony oxide particulates may be covered with other inorganic oxides, such as oxidization zircon. When the typical example of the polyfunctional epoxy resin which has the aromatic ring and/or fatty series ring which open in the present invention is given, they are following general formula (III> and (■). The epoxy resin shown by * and (V) can be mentioned. (It is here and, as for R, a glycidyl group, 1, m, nl, and n2 are the integers of O~15). Although not limited especially as this [ in the epoxy resin denoted by general formula (III) (IV), and (V) / epoxy / ■ ], 400 or less thing is preferably used from viewpoints of compatibility with Senju, the ease of dealing with it, etc. In the coating constituent used at the time of tunic formation of the present invention, various kinds of hardening agents can be used together for the object of making promotion of hardening, cold cure, etc. possible. As a hardening agent, various epoxy resin team-ized agents or various owner stage silicone resin hardening agents are used. as the concrete example of these hardening agents -- various kinds of owner Acid, those acid anhydrides, a nitrogen content organic compound, and various metal complex compound Rude -- metal Alkoxide -- various salt, such as organic carboxylate salt of an alkaline metal and carbonate, is mentioned common. These hardening agents can also be used by two or more sorts, mixing. The aluminum chelate compound shown especially in the following also in these hardening agents from points, such as existence of coloring of the stability of a paint and the coat after coating for the object of the present invention, is useful. An aluminum chelate compound here is an aluminum chelate compound shown, for example by general formula A.I. Artificial Intelligence X and Y3. However, inside of a formula As for X, at least Arrangement originating in the compound shown by OL (L is low-grade Alkali , and Y is a general formula % type % low-grade Alkyl machine) are a child and general formula % type %. At least Arrangement originating in the compound shown with a Also low-grade Alkyl machine is at least one chosen from a child, and n is Oll or 2. Although various kinds of compounds can be raised as an aluminum chelate compound especially shown by useful general formula A.I. Artificial Intelligence XnY3-1 as a hardening agent of the present invention, One especially desirable from viewpoints of the effect as the solubility to a constituent, stability, and a curing catalyst, etc., aluminum acetylacetonate, aluminum, Suetheaseto acetate monoacetyl Aletone-1~, aluminum G n-butoxide mono-Ethyl t:'l-acetate, and aluminum G 1so-propoxide monomethyl aceto -- acetate -- Which . These can also mix and use two or more sorts. Next, although the tunic obtained from a present invention constituent can be easily dyed in various dye, especially distributed Harvest, it is preferred that various kinds of transition metal compounds or the reaction product of those is added from the object of avoiding the color fastness to light of a dyeing article on Toward. As a concrete example of these metallic compounds, it is acetylacetonato metal salt, for example, Screw dithiol alpha-Diketone metal salt, screw phenyl Thiol metal salt, screw phenyl dithiol metal salt, Thiocate call metal salt, dithio Carbamine plating Salt, Sarych Lualdi Bidoximes metal salt, Thiobis Fell rate metal salt, and Sub phosphonic acid metal salt are mentioned. Especially, acetylacetonato chelate compound has the good stability in the inside of a paint, and is used preferably. As an amount of addition of these transition metal compounds, although it should be experimentally set by the use of a transparent fabrication object, and the kind of dilution solvent and the kind of other ingredients, it is 000 (preferably used in 11~10% of the weight of the range.) from points, such as chlorosis of solubility and a coat, to in a generation coat. 0.0 (if less than 11 % of the weight, the effect of addition is not acquired and 10% of the weight or more of addition does not have the violently preferred cloudy weather of a coat.) Even if, as for these transition metal compounds, metaled conjoint form voice changes with a certain chemical changes in the middle of coat generation, it is satisfactory in any way, but in order to acquire a bigger effect, it is desirable in being contained in a coat as chelate compound. The leg in which each ingredient of (△), (B), and the (C) ingredient which are contained in the hardening transparent membrane covered by the surface of the transparent substrate in the present invention is contained is 300-fold [ (B)10~] Okube (C> needs to be 25~800 weight sections.) to the (A)100Iffi section, That is, when the (B) ingredient is less than 10 weight sections, problems, such as poor stainability and reflective interference-fringes generating, are. If 300 weight sections is exceeded, sufficient surface hardness will not be obtained. On the other hand, if the (C) ingredient is less than 25 weight sections and a reflective interference ' A defect, which problem scent with faulty weatherability, and the 800-fold H section will be exceeded, Hayes will become high, transparency falls, and, in which problem with poor adhesion nature, a crack occurs on the surface. The solid content of the organic silicon compound in Hey and the present invention is general formula RI R2S i. (OR3) 4-a-b is suited and it is 0. - It carries out. It comes out and is calculated as R1R25iO(4-a-b) /2. ?L12 In the coating constituent used at the time of tunic formation of the present invention, It is also possible to use various kinds of surface-active agents for the object for which the flow at the time of an application is raised and the smooth nature of a coat reduces the coefficient of friction of the improvement Someday coat surface, A block with dimethylsiloxane and full Kylene oxide or a graft copolymer, a fluorochemical surfactant, etc. are especially effective. It is easily possible to distribute dyes and pigments and a filler, or to dissolve organic polymer, and to make a coat color, or to also make the practicality as coating agents, such as application nature, adhesion nature with a substrate, and improvement in physical properties, improve. It is also easily possible to add an antioxidant as an ultraviolet ray absorbent or a heat-resistant degradation improving method in order to raise weatherability. Although the tunic of the present invention is obtained by stiffening the above-mentioned coating constituent, hardening is performed by heat-treating. Heating temperature is quite wide range than the case of the conventional coating constituent, it can be used, and a result good enough is obtained by 50~250 degreeC. As an application means of the tunic applied on the transparent substrate of the present invention, coating methods usually performed, such as brush coating, immersion coating, roll coating, spray coating, spin paint, and sink coating, are easily usable. As a method which is a means also with effective also performing various kinds of pretreatments for the purpose of the improvement in sanctification, adhesion nature, water resistance, etc., and is used especially preferably, activation gas processing, medicine processing, etc. are mentioned to the application of the coating constituent in the present invention as Necessarily. In a present invention tunic, addition of various compounds is possible for the purpose of stainability, weatherability, the improvement in hardness, etc. as the example of the thing in which this addition is possible -- various fatty series system epoxy resins, acrylic resin, polyvinyl alcohol, and a cellulose system -- polymer -- there is organic polymers or a reactant organic compound. Inorganic this ghost particulates, such as silicon oxide, oxidization zircon, and titanium oxide, and the sol especially distributed by various carrier fluid from a point of compatibility and transparency may be used preferably common. The above-mentioned activation gas processings are the ion generated under normal pressure or decompression, and the gas by which electronic Rude was excited. As a method of making these activation gases generating, it is based, for example on the high-voltage electric discharge by a direct current under corona discharge and decompression, a low frequency wave, high frequency, or microwave, etc. Processing by the low-temperature plasma especially obtained by the high frequency electric discharge under decompression is preferably used from points, such as reproducibility and productivity. Although the gas in particular used here is not limited, as an example, Made by Fuji, nitrogen, hydrogen, carbon dioxide, sulfur dioxide, a helium, neon, argon, Freon, vapor, ammonia, - carbon monoxide, chlorine, - nitric oxide, nitrogen dioxide, etc. are mentioned. These are usable even if two or more sorts are mixed only not only in a kind. As desirable gas, the thing containing oxygen is mentioned in the above, and it may exist in natures, such as air. Preferably pure oxygen gas is effective on an adhesion disposition. It is also possible to raise the temperature of a processed substrate for the object same common on the occasion of the above-mentioned processing. On the other hand, as an example of medicine processing, acid treatment, such as Arc 1 A processing of caustic alkali of sodium etc., chloride, sulfuric acid, fault manganese Awakening potassium, and potassium dichromate, leading solvent processing in which it has an aromatic ring, etc. are mentioned. It uses together continuously or gradually and the above pretreatment can also be carried out enough. In medicine processing, Mixture of potassium dichromate/sulfuric acid is especially effective on an adhesion disposition. The film thickness in particular of the tunic in the present invention is not limited. However, it is preferably used among 0.1 micron ~ 20 microns from points, such as maintenance of adhesive strength, and hardness. Especially preferably it is 0.4 micron ~ 10 microns. They are workability, tunic thickness regulation, etc. to various solvents as Necessarily to the application of a tunic, Although diluted and used, as a dilution solvent, water, alcohol, ester, ether, halogenated hydrocarbon, Dimethylform amide, dimethyl sulfoxide, etc. can use many things according to the object, and it can also use a mixed solvent if needed. However, water, alcohol, Dimethylform amide, ethylene glycol, diethylene glycol, 1 Heliethylene glycol, benzyl alcohol, phenethyl alcohol, phenyl Seru Lube, etc. are preferably used from points, such as the dispersibility of antimony oxide. It is related with the transparent fabrication object which the 2nd invention provides the transparent membrane which consists of inorganic oxides common on the hardening tapetum lucidum which contains antimony oxide particulates on the surface of the transparent substrate which is the 1st above-mentioned invention, and is characterized by things. When these transparent membranes perform suitable combination, giving antireflection can also give reflective increase nature. When forming a transparent membrane, the above-mentioned activation gas processing, medicine processing, etc. may be performed beforehand. Especially, the surface treatment by activation gas is effective in being carried out within the same chamber avoiding not only a productivity drive but adhesiveness on Toward much more, although it is also possible to carry out by dividing with vacuum deposition, Ion Bray Tyng, etc. who mention below. when applying this activation gas processing, it is optimized by the constituent of the tunic which contains antimony oxide as processing conditions, curing conditions, film thickness, the existence of dyeing, etc., respectively -- Flying -- it is and should be set experimentally. As for the transparent membrane which consists of an inorganic oxide of the present invention, it is preferred whether I may be a monolayer or may be a multilayer and that it is a transparent membrane which consists of an inorganic oxide with oxygen gas barrier nature, and also especially its thing covered as the 1st layer on the above-mentioned tunic is preferred. After closing the tunic containing antimony oxide in Must and others and dyeing it as most desirable real IM mode of the present invention using a disperse dye etc., what provides the transparent membrane which consists of the above-mentioned inorganic oxide is mentioned. As a substance which forms the transparent membrane which consists of this inorganic Brewed material, a substance with high hardness is essentially used preferably, and various kinds of nothing Ha Minifilium are used. The oxide of metal or half-metal is contained as this nothing Ha rat ghost. below in 20x 1O-11aK -cm/cnf -sec -cmHg, the oxygen permeability coefficient defined below as an inorganic oxide used especially preferably forms (7) fi Ming film, and is jq To. An oxygen permeability coefficient is a measure showing the permeability of oxygen gas, and is a value defined as follows here. That is, a unit area (CXfl) hits in the 1-cm-thick monotonous surface, and 1-ohmmHO is the amount of oxygen (ri) penetrated to per [ unit time (sec) when it is able to smell ] about an oxyecoia-partial-pressure difference. Also in this inorganic oxide, S i 02, aluminum2O3, Yb2O3, and two r02 are especially used preferably from a viewpoint of the improvement in dyeing color fastness to light. These non-ff(s)! Various embodiments, such as mixture with other inorganic oxides and formation of a double layer membrane according to superposition common, are possible for an oxide. Combining the above-mentioned inorganic oxide suitably as an example especially applied preferably to the object for glasses lenses and camera lenses in these embodiments, using other inorganic substances together depending on the object, and giving antireflection is mentioned. After dyeing the tunic which contains the antimony oxide particulates formed on the surface of the transparent substrate as a desirable embodiment 5~80-fold% [ M ] by a disperse dye etc., the thing the above-mentioned antireflection was made to give is mentioned. Although an antireflection film may be a monolayer or may be a multilayer, it is preferably applied in the multilayer film more than two-layer from a point of the antireflection effect. As a substance which forms this antireflection film, an inorganic substance with hardness high in wood quality is used preferably, and the oxide of metal, metal, or half-metal, fluoride, the Kay ghost, a boride thing, carbide, a nitriding thing, a sulfide, etc. are mentioned. As all the 1M ghost, Sin, SiO2, ZrO2, aluminum2O3, Tie, TiO2, Ti 203, Y2O3, Yb2O3, MgO, Ta205 *CeO2, HfO2, etc. are mentioned. As fluoride, MClF2.A.I. Artificial Intelligence F3.BaF2.CaF2.Na3AlF6.Na5aluminum3F14 etc. is mentioned. Si3N+ etc. are mentioned as metal nitride. Cr, W, Ta, etc. are mentioned as a metal. Not only a kind but these substances can mix and use two or more sorts. A vacuum evaporation method, the sputtering method, an ion plating method, the ion beam assisting method, etc. are mentioned to the method of making the above-mentioned substance forming as a monolayer or a multilayer antireflection film.

[Example] Example 1 (1) Manufacture of resin to be coated As opposed to 1 mol of hydroxyl group-containing compound which combined 1 mol of acrylic acid with 2 mol of ethylene oxide accretionary prism of tetra-Brom bisphenol A by etherification, The substrate by which the surface treatment was carried out by performing low-temperature plasma treatment in the substrate which did the CAS 1~polymerization of 70 copies of monomers and 30 copies of styrene which contain a 0*9-mol addition Scooped up polyfunctional acrylate monomer for Hexa methylene di-isocyanate by making isopropyl peroxide into a polymerization initiator was obtained. The refractive index of the obtained resin was 1.6. (2) Manufacture of a coating constituent (a) gamma-glycidoxy propyl 1~Remixthoxysilane 95.3C] is taught into the reaction machine provided with the manufacture rotation child of a gamma-glycidoxypropyltrimetoxysilane hydrolysis thing, It is 0. (21.8 ohms of 11-N aqueous hydrochloric acid is dropped gradually.), maintaining solution temperature at 10 degreeC and agitating by magnetic Steller. Cooling after the end of dropping was stopped and the hydrolysis thing of gamma-glycidoxy propyl 1~Remixthoxysilane was obtained. (b) Manufacture of a paint To the above-mentioned Silang hydrolysis thing, they are methanol 216g and Dimethylform amide 216q, Addition mixture of fluorochemical surfactant 0.5C] and the bisphenol A type epoxy resin (shell chemicals company make brand name Epikote 827) 67.5Q is carried out, After adding colloid 5 Hayao-ized antimony sol (chemicals company make brand name antimony sol A-2550 mean particle size 60 from eight m micro) 270C], and 13.5 g of aluminum Acetylarethonate and agitating enough, it was considered as the coating constituent. (3) Production of a plastic fabrication object The coating constituent prepared above (2) to the resin obtained with the above (1) to be coated was pulled up, on condition of for 10-cm/in speed, the immersion application was carried out, subsequently preliminary hardening for 82 degreeC / 12 minutes was performed to resin to be coated, and it heated common for 93 degreeC / 4 hours, and acquired the plastic fabrication object. (4) Quality assessment The performance of the acquired plastic fabrication object examined in accordance with the following method. 1 Conclusion is shown in the 1st table. (b) Steel wool hardness # By the steel wool of 0O00, rub a Paint side, get damaged, and judge condition. A judging standard is A... It is not stained with a crack even if it rubs strongly. B ... If it rubs quite strongly, a crack will attach a few. C ... A crack also attaches weak friction. However, it rubbed and performed the number of times by five round trips. (Ro) Adhesion nature The grid which reaches the substrate of 1 mm was put into the coat side 100 fl!il with the steel knife from on the coat, cellophane pressure sensitive adhesive tape (brand name" Scotch tape '' Nichiban Co., Ltd. products) was stuck strongly, and it removed quickly in the direction 90 degrees, and investigated the existence of coat exfoliation. (C) Transparency The transparency was observed for the acquired plastic fabrication object with the naked eye. A judging standard is O... Even if it applies a strong light, it becomes cloudy, and is not stretched and put. △ ... If a strong light is applied, it will accept in cloudy weather. x ... Even if it does not apply a strong light, cloudy weather is To be in slight Le depth. (D) Reflective interference fringes Black cloth was put on the lower part of the acquired plastic fabrication object, from the position of 10 cm of upper parts, the fluorescence pair was applied, catoptric light was observed with the naked eye, and the existence of interference fringes was judged. (Ho) Stainability Disperse dye Dyebath which consists of red, blue, and 3 colors of yellow was prepared, solution temperature was maintained at 93 degreeC, and dyeing was performed for 5 minutes. Total light transmittance was measured for the acquired dyeing fabrication object in the color computer (made in Suga Trial Ha). The judging standard made good 50% or less of total light transmittance. (What) Weatherability The acquired plastic fabrication object was exposed to the outdoors for three months, and the adhesion nature of the coat was evaluated. Example 2 It carried out similarly except [ all ] changing a coating constituent into the constituent shown in the 1st table in Example 1. The performance of the acquired plastic fabrication object is shown in the 1st table. Example 3 In Example 1, it is polycarbonate (refractive index = it carried out similarly except [ all ] changing into 1.58>.) about resin to be coated. The performance of the acquired plastic fabrication object is shown in the 1st table. Comparative example 1~3 It carried out similarly except [ all ] changing a coating constituent into the constituent shown in the 1st table in Example 1. The performance of the acquired plastic fabrication object is shown in the 1st table. Example 4~5, comparative example 4~5 It carried out similarly except [ all ] changing an epoxy resin into the compound shown in Table 1 in Example 1. The performance of the acquired plastic fabrication object is shown in the 1st table. However, phase separation is caused in comparative example 5, coating is impossible, and it is Necessary. Example 6 (1) Manufacture of a paint After adding Acetyl acetone C1(U) 1.1g' as a transition metal compound common into the coating constituent used in Example 1 and agitating enough, it was considered as the coating constituent. (2) Creation of a transparent fabrication object EXAMPLE -- the coating constituent prepared above (1) to the same plastic base by which activation gas processing was carried out was pulled up, it Dip coating F carried out to having used by] on condition of for 10-cm/in speed, subsequently preliminary hardening for 82 degreeC / 12 minutes was performed, and it heated for 130 more degreeC / 2 hours, and acquired the transparent fabrication object. (3) Dyeing of a transparent fabrication object Disperse dye Dyebath which consists of red, blue, and 3 colors of yellow was prepared, and solution temperature was maintained at 93 degreeC, and the transparent fabrication object acquired above (2) was immersed in this for 10 minutes, and it was dyed it. The acquired transparent fabrication object was dyed by Brown whose total light transmittance is 40%. (4) Dyeing color-fastness-to-light examination It is a fadeometer (it was exposed to Suga Test Instruments (stock> products) for 20 hours, and the lower type estimated color fastness to light using the total light transmittance before and behind exposure.) about the transparent fabrication object acquired above (3). It means that the light-proof robustness of a dyeing article is excellent in the smaller one of a numerical value, and it turns out that the tunic containing a transition metal compound is good. A test result is shown in the 2nd table. Color fastness to light (%) = (T2-71) total light transmittance (/ (To-T1)) T1 before X100TO:dyeing : it is the total light transmittance after all the light transmittance T2:dyeing after dyeing and before exposure, and exposure -- the refractive index of a tunic has 1.58, there is also no rainbow pattern by the difference of the refractive index of a base and a tunic, and appearance is good -- Necessary. Example 7 In Example 6, it is Acetyl acetone nickel about a transition metal compound. It carried out similarly except [ all ] changing into (II). A test result is shown in the 2nd table. Comparative example 6 Metal salt of the transition metal was not added in Example 6, but others were all performed similarly. A test result is shown in the 2nd table. 2nd Table Example 8~11, comparative example 7 (1) Dyeing of a coating thing Disperse dye bath which consists of red, blue, and 3 colors of yellow the coating thing produced by making it be completely the same as that of the above-mentioned Example 1 was prepared, Dyebath was maintained at 93 degreeC, and dyeing was performed for 5 minutes. the total light transmittance of the obtained coating thing is 50% -- Brown dyeing was carried out. (2) Production of a transparent fabrication object Ion beam cleaning is performed by considering the dyeing coating thing obtained with the above (1) as a pretreatment, optical film thickness was set as lambda/2 (lambda is 521 nm) by the vacuum evaporation method, respectively, and both sides were made to cover 5i02, aluminum2O3, Yb2O3, and ZrO2. It examined also about the thing which does not make inorganic Completed item cover as a comparative example. (3) Dyeing color-fastness-to-light examination In accordance with the method of Example 6, it completely carried out in a similar manner. A test result is shown in the 3rd table. However, a test is not the same day as Example 6. 3rd Table Example 12~13, comparative example 8 It carried out similarly except [ all ] changing into a multilayer film as the inorganic oxide of (2) is shown in the 4th table in Example 8. Each acquired transparent fabrication object was a good antireflection transparent fabrication object which has a red-purple reflective interference color. Other Trial sales results are shown in the 4th table. It examined also about what has not covered the inorganic oxide as a comparative example. (b) Steel wool hardness # Rub a Paint side by the steel wool of 0000, and judge condition with A tumor. A judging standard is A... It is not stained with a crack even if it rubs strongly. B ... If it rubs quite strongly, a crack will attach a few. C ... A crack also attaches weak friction. However, it rubbed and performed the number of times by 20 round trips. (Mouth> adhesion nature) The grid which reaches the substrate of 1 mm is put into a coat side with 100 steel knives from on a tunic, and it is cellophane pressure sensitive adhesive tape (brand name '' Scotch tape *' Nichiban Co., Ltd. products > were stuck strongly, and it removed quickly in the direction 90 degrees, and investigated the existence of tunic exfoliation.). (C) Appearance The transparency and the degree of coloring were observed for the acquired transparent fabrication object with the naked eye. (D) Color fastness to light It carried out like Example 6. However, a 721~day is not the same day in Example 6. Example 14 (1) Production of a foul prevention film On the same coating tunic as the above-mentioned example 8 Used, Zr0z/TiO2 of an unaccomplished substance and Ta205.5io2 were set as this order by the vacuum evaporation method, optical film thickness was set up at lambda/4 (lambda is 521 nm), respectively, and both sides of the lens were made to carry out multilayer covering. The reflective interference color of the acquired antireflection plastic transparent fabrication object presented green, and total light transmittance was 98%. (2) Quality assessment The performance of the acquired plastic transparent fabrication object examined in accordance with the following method. A result is shown in the 5th table. (b) Steel wool hardness # By the steel wool of 0O00, rub a Paint side, get damaged, and judge condition. A judging standard is A... It is not stained with a crack even if it rubs strongly. B ... If it rubs quite strongly, a sea gull will attach a few. C ... A crack also attaches weak friction. It rubbed and performed the number of times by 20 round trips. (Ro) Adhesion nature The grid which reaches the substrate of 1 mv interval was put into the coat side with 100 steel knives from on the coat, cellophane pressure sensitive adhesive tape (brand name ''' Scotch tape '' Nichiban Co., Ltd. products) was stuck strongly, and it removed quickly in the direction 90 degrees, and investigated the existence of coat exfoliation. (Ha Transparency The transparency was observed for the acquired plastic transparent fabrication object with the naked eye. A judging standard is O... Cloudy weather is not accepted even if it applies a strong light. △ ... Cloudy weather will be accepted if a strong light is applied. X ... Even if it does not apply a strong light, it becomes cloudy, and they are Power bow 2 To be. (D) q anti-sun interference fringes Black cloth was put on the lower part of 1q Was done plastic fabrication object, from the position of 10 cm of upper parts, the fluorescent light was applied, foul light was observed with the naked eye, and the existence of interference fringes was judged. (Ho) Weatherability The acquired plastic fabrication object was exposed to the outdoors for three months, and the adhesion nature of the coat was evaluated. Example 15 It carried out similarly except [ all ] changing a coating constituent into the constituent shown in the 5th table in Example 14. The performance of the acquired plastic fabrication object is shown in the 5th table. Comparative example 9~11 It carried out similarly except [ all ] changing a coating constituent into the constituent shown in the 5th table in Example 14. The performance of the acquired plastic fabrication object is shown in the 5th table. Comparative example 12 The plastic fabrication object in which all of Without and others have antireflection for the application of a coating constituent similarly in Example 14 was acquired. The performance of the acquired plastic fabrication object is shown in the 5th table. "EFFECT OF THE INVENTION" The transparent fabrication object acquired by the present invention is excellent in a pickpocket-proof positivity, abrasion resistance, shock resistance, chemical resistance, flexibility, heat resistance, lightfastness, weatherability, stainability, etc., and the color fastness to light can use it as a good transparent fabrication object about a dyeing article. The above-mentioned characteristic can be given, without producing the poor appearance by interference fringes in a plastic with a high refractive index which contains an aromatic ring and a halogen atom common (except for fluoride). It is even if it applies to the transparent substrate which the fire-resistant improvement in a general plastic has an effect, and has a high refractive index, There is no generating of interference fringes, and also it has the durable To high hardness surface, and since the color fastness to light of a dyeing article is good, the lens for vision correction with thin thickness is preferably used also for lenses, such as a camera and binoculars, from the first.