Hair tonic and permanent waving composition

[Detailed Description of the Invention]

Use field A on <industry The present invention relates to the constituent the constituent for hair strengthening and a permanent wave, more nearly especially reactant silicone hair strengthening, and for a wave. In order that hair care (care of the hair) may be one of the main portions in the Vicor -Tea care (care on cosmetics) and very various products for a hair treatment (processing) may perform \ Caring, It is used in forms, such as a yellowtail shampoo conditioner, a shampoo, a AFTER shampoo conditioner, rinse, a Settling lotion, a spray, Di (hair coloring), bleach (mark agent), and permanent wave lotion. As a result of a request on the hair, these products are not in a metaphor only by giving gloss, the Carding easy which curled, softness, a color, and overall attractive appearance, and when [ ambiguous especially without advice of Expert ] Up \ use of is done, they also become hurting the hair. The bruise of the hair may happen also by the outside of other sources 1, for example, Carding, humidity, dryness, dirt, and sunlight, for example, purple, infrared irradiation, and environmental pollution. However, in Mostly, the bruise of the hair happens in the form of a physical and chemical change of the hair as a result of return of the hair form which curl of the hair by bleach, Fi, use of Di of an oxidizing quality, and an alkaline laxative lengthened, and waved and curled. the bruise of the hair -- slowly -- and -- they are various forms -- * treatment of the frequent hair -- " -- probably, it is Bribery. If various medicines are used over a long period of time with the product for a hair treatment, the hair organization which became weak will be produced. this -- good -- by better, lengthening what curled as an example of To delaminate influence, or making straight hair curl, when a natural structure of the hair changes, it happens. By destroying the disulfide bond of the keratin of the hair and forming the sulfhydryl group of isolation, the hair receives an operation of the constituent which makes the hair soft. Cleavage of a disulfide bond is made flexible that the rigidity of hair protein is decreased and it is easy to bend the hair. It is a thing of hydroxide of the constituent a sodium currently most widely used as a laxative (medicine for making the hair soft, and lengthening a permanent wave, or applying conversely), sulfite salt, or a thioglycolate system. When using a Thiog recall system constituent as a laxative, the hair is processed with a peroxide for an oxidizer metaphor, and hardness is endowed with the hair. In this operation, either of the degree of gA heated [ Overtemperature or ] can carry out especially operation of reduction. Both this kind of hair processing and the cold one and hot permanent processing need to observe the state of the hair by an eye, and it is necessary to do °C judging of them. after all, the permanent wave whether a straight permanent wave is once or usual which curled is needed once -- or [ that the state of that hair is greatly influenced by a beauty parlor salesclerk's subjective judgment, and a permanent wave has not oftener applied the hair enough for a subjective element ] -- or it applies too much and has become that either. a desired feel lacks the hair processed by the tablet for the hairs of the oxidizing quality in addition to the problem of the excess and deficiency of how to get a permanent -- rude touch -- Carding -- hard -- it is necessary to process with a conditioner Since the conditions of these hairs are normalized, the manufacturer of Hairstyle treatment Moxibustion product often sells the conditioner for post-processing as some kits usually made together with an acid oxidizing tablet. 1t of others! The special hair conditioning agent, for example, nonionic, and cationic agent which may be compatible with an oxidizer in elegance, or To. A hair conditioning agent is used also after a shampoo in order to help not only ' that comes out in relation to an oxidizer, or is used for post-processing of an oxidizer but making it easy to adjust the state of the hair widely and to treat. After a shampoo can also solve a tangle easily and the hair processed by the conditioning agent gives a feel desirable when it That by A row tidily [ when I am Carding-easy and it gets dry ] and °C Touches. It is thought that the operation of the conditioning agent to the hair, especially cationic conditioning agent , is deposition l This of suction of the medicine electrified in the sun to the negative site on 11 hair protein and the medicine to the hair textiles top which arise as a result, and takes place. The cationic agent or the interface T A personality agent is chiefly used as a hair conditioning agent of cream rinse and a shampoo. The best result is obtained with the cationic surface-active agent which is the fourth class of amount compound of long-chain polymers, or amine salt of long-chain fat. the sun of the fourth class surface-active agent -- an electric charge is attracted by the surface electrified behind a screen of hair protein, when it is To car in the state where it became wet, wettability is granted, and the hand of the request is carried out and after dryness gives Ri. ORGANO silicone with the basis which may be hydrolyzed into a silicon atom whose medicine another type which deposits on the use To 11 ing hair with a prior art is Orr Nono silicone, It hydrolyzes into corresponding Syros Knoll, and it condenses to an ORGANO silicone polymer on hair textiles, it is covered, and the body (form) used for the conditioning of the hair and the both sides of a set is given. To which strengthens hair structure and indicates the solution provided by the prior art to it to be some of problems to which explanation of the it above-mentioned accompanies care of the hair although the profits with an above-mentioned conditioning agent substantial on the hair are brought about to be sure and which comes out. <The object and the feature of an invention> as for the present invention, the conditions that the hair became weak originate in any of the hair treatment agent added to environment or it by nature -- it is related with Line layer of being an imitation and processing the hair which became weak and strengthening. The present invention is alpha0 formula. [ -- R1 [ however, ] -- Cl-Cl and the fatty series machine of a carbon atom, for example, methyl, and ethyl, Substitution fat machine; chosen from the group which comprises Flo Bill, butyl, hexyl, octyl, Tesil, octadecyl;8-aminopropyl, N, and N-Diethyl- 8-aminopropyl and N-(propyl) urea or an alkenyl group, for example, vinyl, Allyl, Demeri; R2 is C, -C and the fatty series machine of a carbon atom, for example, methyl, ethyl, propyl, butyl, the alkyltrialkoxysilane that came out and had certain], To, and the solvent for Alkyl tri Alcokey Sisila y. This solvent is Ru from solution of water, ethanol, isopropyl alcohol, Tsunoxy / - roux 4, Xld ethanol, and isopropyl alcohol Also, nonoxy Knoll Decree. The hair to contain pulls and it is related with the constituent for strength strengthening. In order to obtain the constituent by the present invention, solution is prepared by adding Alkyl alkoxysilane to a suitable solvent, agitating. This constituent is about 0.5 thru/or 409 in a solvent. - And the alkyltrialkoxysilane of 2 thru/or 10 % upsilon/upsilon is comprised more preferably. Desirable solvent nature and water are the ethanol, in propyl alcohol, or Nonoxy Knoll's 4 solution which constitutes less than abbreviation Z 096 v/v of solvent total volume. Although it is stable for several days in the alcohol/aqueous phase in which above-mentioned Silang had water of o-2oyt, preparing, just before applying to the hair is preferred. If this solution is neglected under coexistence of water for a long period of time, the excessive polymerization of Silang and early sedimentation may take place, and it will reduce effect to that desired end of a constituent. The method of applying this constituent Paint the method and constituent which apply a constituent to the hair by dipping the shampooed hair into a constituent to an applicator, and the method of °C Moving it with a finger and a comb and applying it in the hair, is included. Processing is completed by carrying out blow dryness of the hair using heat air. To -- statement > of a desirable mode The present invention is based on discovery of hydrolyzing, forming eight reactant silanol groups under coexistence of a reactant Alkyl IJ alkoxysilane line with the alkoxy group which is easy to cause eight chemical changes, and water, condensing this mutually next and forming oligomer. The hydrogen bond of this oligomer is carried out to the functional groups (hydroxyl, amine, carboxyl, a Suluhi drill, etc.) which had A active hydrogen in the hair next. the time of dryness or hardening (cure) -- Open-This with the hair -- a stable covalent bond is formed while losing water simultaneously. Although hardening will take place also by Overtemperature, it is preferred by drying the hair using a hot air drier to accelerate a reaction. If heat is applied, evaporation of a solvent and the subliving thing of a reaction will be promoted. - whenever -- water -- from the hair -- removing -- having -- if -- having generated -- combination -- a hydrolytic action -- being stable . The degree of polymerization and rate of polymerization of Silang are decided by A child of water and the organic substitution machine of Silang which can be used. The hair is made easy to make the form of the hair which made the intensity of the hair increase, for example, has curled hold, and to deal with, when this characteristic of Silang of the present invention applies it to the hair. Or it can obtain Silang of the present invention in a market, it can be manufactured by the method known for this one industry using the materials and the reagent which can be obtained in a market. Although Silang is solubilized in ethanol, isopropyl alcohol, and the organic solvent of many others, in the object of the present invention, the desirable solvents to Silang are the water/alcoholic mixture containing the water below zO capacity %. the water of quantity with this sufficient composition -- hydrolysis of Silang -- And -- or it can use for swelling of the hair textiles for many Infiltration, and a sake from that of the active ingredient before an omnibus process. in the medium of this composition, it asked by the generating (sedimentation of Shiroki Sun polymer) time of Hayes -- all (the stability over unexpected water is shown.) The solution which used the metaphor as 80/20 of ethanol/water in ethyl Trier toxin 2 Fusing is transparent Up\ for several days, and is To. It is accepted that generating of zeta Rubbed whose Capacity JiX of water increases exceeding 20% of total solvent composition, and earlier Hayes, and sedimentation of the Shiroki Sun polymer take place, and, in a constituent, effect declines to the desired end. The examining method relevant to the present invention and an example is as follows. It pulls and is strength. This examination is related with the measurement of the power (pulling strength in a destroying point) which the fracture of a hair sample takes which uses a fixed growth speed test machine, for example, an Instron [1nstron] tensile test machine. The fringe of hair with the long hair which should be examined is set in the chamber of the relative humidity of 50X in advance of use for at least 24 hours. The hair of 20 fringes chosen as the Jiaozuo sake from the fringe of each long hair is used for an examination. A portion 2 inches in length is started from the fringe of each hair, and it weighs to %0.1 microgram. The weighed portion is put in distilled water and they are at least 16-hour Eikyuuji and To fade away. Each hydrated hair sample is put in between Meal of the Instron tensile test machine which detaches 1 inch and is set, and is narrowed firmly. According to the method of a device, it pulls to A long time, and measures strength. It pulls, strength is power required for the fracture of the fringe of the hair, and it is To. This power is expressed using y power per Dislocation product of the fringe of @ hair. As Silica molybdic acid salt, Tooth°C, or molybdenum blue, with a Compared determination method, it ill(s), and the silicon content of the processed hair carries out ll Redundancy, and computes a result as Silang. The concentrated nitric acid of L loan Log-in and 5tnt is correctly added for the hair of abbreviation 0.7y ground 0.lIrTg in a beaker. It heats until it hardens a sample by drying, and it repeats until a white residual substance cuts addition and heating of nitric acid in a beaker. suction P Next, Cold addition moon-:10 chloride to a beaker at JOm, and treat °C and a content using a lake millipore filter. p this beaker -- 1:lOHydrochloric acid<f -- treat a Wash fluid that there is nothing. A filter is put on the bottom of a polyethylene beaker, 1.0-O hydrogen fluoride W! is added, and a filter is made to treat. Next, a beaker is covered and it is neglected for 80 minutes. Next, solution is heated to 40 degreeduring at least 10 minutes C in bathing, stirring the water of 25-, and the boric acid solution of 50-. It adds, while stirring the molybdic acid reagent of 4 A. Next, in 20 minutes, while stirring IOA/sulfuric acid of 20-, it adds. When yellow continues, solution is acidified, and less than [ back 2 minute ] is received with a photoelectric spectrophotometer, distilled water is received by 20 nm of hands, and it reads. When colorless solution is obtained, ore and solution are neglected for 2 thru/or 5 minutes, ■-Completion minnow 2-naphthol 4-sulfonic acid reagent Wo of ■-, in addition the next are mixed, and it reads by 8ZOsm in 20 minutes. the sample nature for analytical curves of yellow Silicone molybuti / acid-base density range (4ZOnm) -- taking and setting -- silicon (diluting to 25 A in 0.5 of 1~/ml person standard goods, l, 2, and a Hint 8 td'a-polyethylene beaker) The previously-mentioned operation after f~* It was was performed, and the process of heating solution for at least 10 minutes was created. The above-mentioned process is completed and the back reads Absorbance by 4"l Onrn. Next, Absorbance is plotted to m? silicon. Even in molybdenum blue density range (820 nm) ', silicon takes, and it sets, and processes by the method which diluted 50*100.200 and the 500-micro liter of standard goods (]-m&/d) to 25-, and mentioned them above about the analytical curve of Silica molybdic acid salt in the polyethylene beaker. Absorbance is read at 820 nm. The concentration of silicon is obtained from a suitable analytical curve. : whose Monitoring and law are as Pale <example> Example 1 * The hair sample beforehand weakened by sodium hydroxide was dipped in the ethanol / water (80/20) mixture solution of 8.0 % upsilon/upsilon of ethyltriethoxysilane (from Pe trarch Sya tetn, s 1Inc, and t Lgv-ittovyn+PA to acquisition). The hair is rinsed until superfluous Silang is lost, and blow dryness was carried out and it was made to harden using a hot air drier for about 10 minutes. The hair was examined using the above-mentioned method. :alpha whose result was as follows, and the hair which processed using sodium hydroxide solution were pulled, and showed reduction of 11 to 143'6 by strength. the beginning pulled the hair which was able to be weakened by the sodium hydroxide which used and processed the Silang containing composition to the 60th order (before processing), and it returned to 97 to 98316 of strength -- it pulled and was increasing to strength. When the hair which was able to be weakened by C and water oxidization Nato IJ Umu which carried out Silang processing was calculated as ethyl Triethoxysila/, it had taken in upsilon/upsilon silicon 0.4 to 1.4% of the weight. Example 2 * 95%V/V Nonoxy Knoll 4 solution of ethyltriethoxysilane was prepared. While stirring 40 copies of Silang / Nonoxy Knoll 4 phase just before processing of the hair (it added to the water of ten copies.) It soaked in hair Baby's whole which was able to be beforehand weakened by sodium hydroxide in Silang / Nonoxy Knoll 4/solution. solution is boiled for 80 minutes and on the hair -- it exceeded. The hair was rinsed until the solution of fault %@1 was exhausted, and blow dryness was carried out using the hot air drier. The data which the hair pulled and increased the 10 points by strength was obtained as a result of the examination. Example 8 * Water oxidization Nato IJ Umu 296-aqueous-Wf-uses, music processing is carried out for 45 minutes, and the hair (that is, he has not got permanent) sample of Up \ by birth was damaged severely. The sample damaged with alkali was washed with pH 7 shampoo, acid balance was recovered, and it dried at the surrounding temperature, and divided into the group of the fringe of the same size. Eight fringes were chosen, and the Silang containing composition of Example 2 lOg'F-used for 80 minutes, respectively, and it processed, and hardened and dried [ blow ]. The method used for processing of eight fringes was completely the same except the method of removing superfluous Silang. The Instron examination was carried out about all the fringes. The method of a result and the superfluous Silang removal is shown in Table 1. Table 1 It is the hair of contrast and Up \ by birth as a result of Instron of the fringe which processed. 20 29.49 Samurai 0.61 (notes ... the following tables are also the same)n .. Measurement count X ... Average value of measured value SEM4I41 .. It is shown that the fringe which carried out Silang processing way °C Is conspicuous, and intensity is increasing it as compared with the contrast which weakened the data of average standard error fil with alkali (obtaining abbreviation 15-20). Between the fringes which carried out Silang processing, that there is no difference of remarkable hair intensity shows that removal A * How to do has not had intensity-9 influence of the hair for the superfluous processing agent from the hair. After exceeding the desired hair form using the roller or lot for curl, when it processed and blow dryness of the hair is carried out using the Silang containing composition of the present invention, Silang combined with the hair is not a loan making hair intensity increase, and maintaining at the form of Up \ when the hair is dried was also found out. With alkali, it weakened, and came out and this effect was shown with both a certain hair and the hair of Up \ by birth. Even after [ which arose as a result ] shampooing one's hair by carrying out permanent wave foil Riyadera, the form is maintained, a permanent wave loses its shape in the form of the hair in front of a permanent wave, and it is Publication(ing) resistance to the tendency which tries to return in it. Example 4 * ltheta% sodium lauryl sulfate Wenshi solution purification of the hair sample of dark brown Up \ by birth from a single lot was carried out, and it is tap water, rinsed, and carried out blow dryness at room temperature. The sample was divided into 18 fringes of each 10 inches in length, and weight IJ. l fringe -- " -- it chose the sake [ as contrast / of Up \ by birth / '' ], and set aside other five fringes for the Silang processing. The 12 remaining fringes were set for the object for alkali treatment. before processing -- each fringe -- quietly -- Carding -- and it twisted around the curling rod (C %rling rods) separately. Alkali treatment was dipped in twisted ii, t-2, and 0% of sodium hydroxide solution for 1 hour, and was carried out. Next, every month was passed and it rinsed for at least 10 minutes under the tap water of Release. Astringent which dries the twisted fringe with a towel, and attaches to pH 7 and 0 buffer solution for 1 hour, make recover acid balance, and completeness l exceed -- mu Aspiration rg - it removed. Finally the twisted fringe was dried at room temperature. In order to carry out silyl-ization, the ethanol / water (80:20) solution of Mol, such as Silang indicated to Table 2 and 8, were prepared separately. a roll -- Rita with a volume -- Up \ by birth -- and the fringe which carried out alkali treatment was separately processed for 30 minutes using 100ffft of 0.26 M Silang solution. Blow dryness of the fringe which is Roll was carried out for 4 minutes after the Silang processing using the ■600 W prore drier, and water was sprinkled to the whole. it is Roll -- it was made to Silence for fringe 85 minutes, and finally the drier was set to high temperature and blow dryness was carried out for 15 minutes. It is Up\ by birth which was not silyl-ized, and the contrast which carried out alkali treatment also carried out the same drying process. Room temperature is made to balance-ize, it loosens from a curling lot carefully after °C, and the fringe of the hair is a A phrase beam to a curl maintenance board (curl veten is on board). The attachment Rita sample was made into the bottom of 100 / 95X relative humidity next. Curl maintenance data was periodically taken over 24 hours. A fringe is removed from Shou and soaked for 1 minute in the bottom of the tap water of sink One by one, and it dries, dips for 80 more minutes in that of °C water, and one mosquito, takes out by them, air-dries by them, it jumps twice, and rinses again. The pattern was estimated as the length of curl of the last of six fringes, and curl stability was searched for. Data and a comment were summarized to clothes 2 and Table 8. Clothes 8 sample dark -- Degree Hair 0.00 of Up \ of contrast by birth : L '/-16 Octathis tri ethoxy 10.84 1 12.' 78 Silang Octyl triethoxysilane ?, 20 1 11.048-amino pro Piltri 4.70 1 11.35 ethoxy Silane Vinyltriethoxysilane 4.90 1 11 and %14N-() lJc Toxy silyl 6.90 110.88 propyl urea All solution is Question Mol (j, Silang'fi:□u9 comment which is 2tll) inside. carrying out Mostly curl Looking -- the body wave with a good Vo 1 A wave in which a diligent body wave is [ t very good body wave Up / nothing / S-wave pattern ] good Well diligent body wave example 5 * from the single lot of the hair of dark brown Up \ by birth -- respectively -- iJRei- weight 1.5±0.1, and [ 9. / 10 inches ] in length -- a lot was built. I for; over which two fringes were covered for the permanent wave in random (since it is referred to as 1, it selects, and they are collagen amino and r Gide professional formular CColLagen Am, and i?I.) It processed using Ac1d Professional Forrmbla"3'] (ltr ingredient 20, ZX ammonium thioglycolate, lOX To] and a Lumblebro mate). The fringe of the hair of 14 Up \ by birth was twisted around the rod, and it attached to 2X Water rain-ized Nato ll Umu solution for 1 hour. The twisted fringe is rinsed until alkali gets hot, it was processed with pH 7 and 0 buffer solution, and the acid balance of the hair was made for the back to recover it. This fringe was rinsed until buffer solution was exhausted, and processing which was indicated in Tables 4 and 5 was performed. The method which carried out alkali treatment and was used for evaluation and hardening of the hair 7 is a thing of real M11 A 14 statement, and is rash. The same time heat was applied also to the control sample. All the processed fringes to write were made to balance-ize under the temperature of the surrounding conditions, and humidity. The length of # From the hill and each curl was carefully measured for the fringe from the curling rod to 0.1crrL after balance-izing. It attached to the curl maintenance board and the back made the fringe into 100''F / 95 circle relative humidity for 24 hours. Next, a fringe is removed from a board and a flash is carried out with the tap water of sink Release for 1 minute, and also it dips in the beaker of water for 80 minutes, it takes out, and is a 2 times flex time shampoo (it jumps by FJepsilonz Shampoo■], and it was made to rinse and air-dry until soap was lost). Last Carew's length and the shape of each class were evaluated carefully, and curl stability was defined. A result is shown in Table 4 and clothes 5. Clothes 4 Curl maintenance Alkali treatment contrast 'i iuand2 - alkali treatment / FJ%ETES" 1 1 F>-4-Alkali Treatment /80Y6ETBS" l 16.U - Alkali treatment / urea Bullet'-90 XETES'l lts, ii+ - alkali treatment / salt swelling 4-80 9 B:TES"l 14..2 - alkali treatment /DET" -- inner 8CjXETES'2 , l5-2 -- 'l -M A bird 0 alkali %R/DMF" -- inside A BONETE! 3"2 (i, 7 4O-60 (notes for Table 4.5 scents)) 1, i, and l : lij(ing) and carrying out a Z O permanent wave -- 7Ii:contrast 2 (1) ETBS= Ethyl tri ethoxy 7 run (8 (1 / 11 Al Cau (2) DET-Diethyltol amide (8) DMF= Diethyl form amide)) (4) Salt # Jun ... The Silang processing is preceded and it is 28M LiCl3/U-5 hi N'al?(5) urea swelling about the hair... In advance of Syros/processing, the hair is for [ the hearts ] commented in 4MUrinary cumulus#' and i1 autumn. Earl \ kana curl, an S-wave pattern good ys-wave pattern good without S-wave pattern S-wave pattern with Pleasant good S-wave pattern very -- N -- woman S-wave Pattern age -- S-wave Pattern / solution with tight good curl extremely It swells by go4 Water Bath. Hair contrast of Up \ by birth 2 6.9 -- "Hair / 5 X A'T ES of Up \ by Birth" 2 12-2 -- by Birth -- T71\ (D14 Hair / * Expansion Fr4'-5jJ6ETEs" 2 12.6 by Birth (Di\ (Dm Hair 7Wg Swelling [ -596 ] "ETBS" 2] 2.6 Al A sword Processing Contrast))) 27 and 5 alkali-treatment 15 NETES"Z i24 alkali treatment / urine purple swelling'-555ETES"2 il and 47 -- power -- a good body wave and :l2 (J) J lfjM/Salt swelling 'llr'-596ETB S -- "2 10-4 comment grounds 0.60 with very slight curl and no S-wave pattern -- ±0.80 northeast lambda -- body wave ground upsilon with good f body wave±O ~ The im b-It ly -A/, B-wave pattern ML Samurai 0 On [ i and oo ] S-wave pattern with good good S-wave pattern top O Silyl-izing of the hair to which alkali treatment of the diligent S~wave pattern table 4 was carried out on the curling rondo i Must, the curl which made the curl pattern equivalent to having been built by the conventional permanent wave processing, and produced it in the contrast which carried out alkali treatment -- a real wage increase -- thick -- it cut. °C In the fringe formed into "shape memory" a alkali Soril, it shampooed repeatedly, after was held and it was. [ of curl ] Table 5 gives the good stable curl to the Silang constituent of the present invention, or the hair which carried out alkali treatment -- and formation of a body wave pattern with stable curl maintenance of the hair still still more by birth -- after silyl-izing -- the time -- a sentence -- improving -- having -- things -- being shown -- Listen . the soul and the range of the concept that the present invention will seemingly be new -- ^ -- please understand that there is nothing [ 11-To be ] and they are an improvement and change, or Musical ability. Written amendment (method) % Formula % 1, the display of an incident The Showa 60 patent application No. [ two ] 76902, the title of an invention Relation between hair strengthening, constituent 3 for permanent waves, and the person incident that carries out amendment Applicant-for-a-patent name Revlon Parrot Holted 4, representative 5, object of amendment Fair copy 6 of the handwriting specification of attachment in a request, the contents of amendment There is no amendment of the contents as an attached sheet.