Fragrance composition

[Detailed Description of the Invention]

The present invention relates to the disposal method of an unpleasant smell, and the method for removing a bad smell of a certain kind, if it says in more detail. Probably spice production technology started in the cave dwelling of the human beings of prehistory. The spice manufacturer has used the natural aromatic chemical substance of the source of an animal, and a vegetable source until it continues till these days comparatively from the beginning. That is, for example, a natural perfume chemistry substance like oil refinement and Tooth like the oil of Para and the oil of a clove, or an animal secretion like perfume like this has been dealt with by the spice manufacturer obtaining the perfume of the conventional versatility. However, especially the spice researcher developed very much the characteristic of the spice for which it asks with A book art these days. These synthetic perfume chemical substances added the Shinji origin to the art of spice manufacture. It is because the compound to say and by which thing bee manufacture is carried out has usually stable chemical nature, and is cheap as compared with a natural perfume chemistry substance, and this natural perfume chemistry substance is moreover a mixture of the complicated substance whose chemical analysis is usually impossible, so handling is easier than a natural perfume chemistry substance. If it contrasts, ~ composition perfume chemical substance has known chemical structure, therefore the spice manufacturer can manufacture it so that a specific demand may be suited. This demand is diversified over the very wide range. Therefore, the compound which has the specific Arousal characteristic is needed very much in the technical field of a perfume constituent. Conventionally, the main efforts have been turned to providing the method of processing an unpleasant smell to people's Arousal in the technical field of spice. This smell includes various smells, such as a smell of the smell "kitchen of a bathroom, body odor, and a smoking smell, for example. Many products have been developed in order to remove these smells. It is raised as an example of the product which requires what is called "room Freshener" or a "room deodorant." Generally, these products have provided the concealment operation by either of the two mechanisms. Concealment perfume "it is provided by whether desirable perfume is depended on providing so much, or it is because the perfume which is mixed with an unpleasant smell and gives moreover more desirable perfume in another kind is provided in order to control an unpleasant smell. Sadly in the case of "both, set. "a lot of perfume which becomes unpleasant now now at itself must be used. A A unpleasant smell "in addition also in the concealment perfume level which can usually be put up with moderately, it may be detected. Therefore, especially the constituent and method for the unpleasant-smell removal which removes substantially the smell applied without being accompanied by an above-mentioned disadvantageous point are desired. Especially a harmful smell is caused by the compound which has remarkably those of whether a proton is given or to win popularity for Japan. Such a compound will be called the following "bad smell." The kind of an unfavorable criticism of a certain kind of compound is included at a stinking thing point by these including low-grade carboxylic acid, Thiol, Thiophenol, phenol, low-grade Amin, phosphines, and Alsin. Conventionally, it was found out as what has the capability to remove the bad smell which requires 4-cyclohexyl 4-methyl 2-Ventanone. Although the capability to remove a bad smell was not discovered before the present invention, the following compounds are indicated in literature. Cyclohexyl methanol [West Germany patent No. 878394 specification reference] Sis / transformer 14-methylcyclohexyl methanol [Rec.Trav.80, 595 (1961) reference] Cisuno transformer 4 - isopropyl cyclohexyl methanol [Rec.Trav.81 and 833 (1962) reference] Cisuno transformer 4-3rd class butyl cyclohexyl methanol [Rec. T The av. 89, 913 (1970) references] 1-cyclohexyl 1-ethanol [Comptesrend.13 skin 343 (1904) reference] IM cyclohexyl 1-propanol [J. enmity g.Chem.14 A 1089 (1949) reference] 1-cyclohexyl 2-methyl 1-propanol [JACS 82 A 880 (1960) Reference]1-cyclohexyl 1-butanol [J.Chg.Chem.14 1089 (1949) reference] 1-cyclohexyl 1-Bethanol UACS 82, 880 (1960) references] Sis / transformer 11 (2 1 Methylcyclohexyl)-1-ethanol [AhnChim. (Paris), 3, 555 (19 Island) reference] Cisuno transformer 1-(3-methylcyclohexyl)-1 - Eta / - Le [CaTsukid, J, and Chem, 46, and 1073 (1968) reference] Cisuno transformer 1-(4 1 methylcyclohexyl)11-ethanol [JACS 8L 4697 (1959) reference]2-cyclohexyl 2-pro / Tooth Knoll [JACS ? public 3200 (1954) reference] Cisuno transformer 2 1 (4 1 methylcyclohexyl) 1 2-propanol [Can.J.Chem41, The 1-8 (1963) reference] present invention "the bad smell removing method by use of a compound especially useful for bad smell removal ability is provided. The compound in which this surprising capability for a bad smell to be removable is shown, Table * I is carried out by the following structural formulae [the low-grade Alkyl machine which inside A of a formula expresses the low-grade Alkyl machine which has hydrogen or 1~5 carbon Ryoko, and RI and R2 express hydrogen respectively independently, or has 1~5 carbon atoms is expressed]. The term of "removing (bad smell)" used on these specifications shall mean the operation exerted on the feeling of the person of a smell and A, or a bad smell who makes the displeasure of the bad smell to A people's Vague sense reduce. This term should not be limited to the mechanism of either specification from which this result is obtained by that cause. The compound with inside RI of a formula useful to the present invention which is a Alkyl machine is denoted by the following formulas (the above-mentioned inside A of a formula has the above-mentioned definition), is made, and may be manufactured. The benzene of which ~ substitution was done as shown in the formula (1), or the benzene which is not replaced generates the phenyl Alkyl ketone which is acylated by Acyl chloride and corresponds under "Friedel crafts condition preferably. being shown in a formula (D) -- ** ing -- like -- ~ -- a catalyst with this suitable phenyl Alkyl ketone -- "-- the alkylation cyclohexyl methanol which is hydrogenated on a rhodium metal content catalyst and corresponds preferably is generated. The compound whose both in [ RI and R2 ] a formula are hydrogen is denoted by the following formulas (in the above-mentioned formula, A has the above-mentioned definition), is made, and may be manufactured. The cyclohexyl methanol in which it is first hydrogenated on a suitable rhodium catalyst, and the replaced benzoic acid or the benzoic acid which is not replaced corresponds and which it passes, and becomes Xahydro benzoic acid, and this is subsequently hydrogenated, and corresponds (formula (W)) is generated as shown in the formula (m). The compound which is a Alkyl machine with same both in [ RI and R2 ] a formula "it is expressed with the following formulas (in the above-mentioned formula, A has the above-mentioned definition), it makes, and may be manufactured. ~ substitution was carried out, and it passes and generates December Ki Sahydro benzoic acid or the 3rd class alcohol which is not replaced and which passes, makes Alkylester of Kisahydro benzoic acid react to Alkyl * and magnesium chloride, and corresponds as shown in formula (V). The compound which is a Alkyl machine with which inside RI and R2 of a formula differs "it is expressed with the following equations (in the above-mentioned formula, A has the above-mentioned definition), it makes, and may be manufactured. It is shown in the formula (W). "the 3rd class alcohol which makes replaced Funal kill ketone or the phenyl Alkyl ketone which is not replaced react to Alkyl magnesium chloride, and corresponds is generated, This is hydrogenated on a suitable rhodium catalyst and it deals in corresponding (formula (skin)) cyclohexyl Arco 1/To. The compound concerning the present invention "the Suzugo preparative bad smell used in the medium by which many moreover differ in a small quantity is effectively removable. For example, a Aerosol (spray etc.) "fluid (Wick type) "solid (set to room Freshener or a room deodorant also with the form of the base ON powder (a spice bag is also a dry spray) of inside, such as a spice ball "plastic, so that wax, and gel (organization gel stick)) Especially Also used(ing) is preferred. Other concrete uses are washing machine use in Also, for example, a "detergent A powder "fluid~brightening agent, or a textile softening agent. It is ~ so that it may be applied. To for example, the thing the Aro sol spray for Incense mass~cupboards through which it passes and which it puts into a cupboard, or for clothing preservation places Also set a lid, For example "paper towl, and bathroom tissue paper "sanitary napkin in a clothing deodorant so that according to other application which can be set to bathroom add-on like a towel "disposable dishcloth~disposable diaper and a sanitary container deodorant. An antiperspirant [ in / on A, for example, ~ antiseptic, and a cleaning agent like a toilet ball cleaner, and / the form of a lid, a For example~powder Twa Arosol t fluid, or a solid ], and the bottom deodorant of a pig, the deodorant for the whole body, or for example, t hair spray and a hair adjustment agent -- a rinse "Ha color -- and -- passing -- a Ya Di "permanent wave -- a depilation agent, Product A for hair care like a Hears tray toner, being [ carry out and / styling spritz / pomade /, such as a cream "lotion, ] for example, General purpose chopsticks, for example, "S-Selenium-Sulphide, "the product for hair care of medicine mixing in which coal tar also contains ingredients, such as salicylate or a shampoo agent -- or -- "-- for example, the powder for "legs -- a fluid or Odeco. In a product for care of a leg like A, the lotion for after a razor and a body lotion or soap, and cosmetics like a cylinder, a fluid, the letter of foaming, or powdered synthetic detergent for example, For example, in the bad smell control in a manufacturing process [ as / in textile finisher business or printer business (ink and paper) ], For example, in bad smell control [ as / in the process included by pulp industry, storage space meat processing, sewage disposal, or refuse disposal ], Or for example, textile finish products "in bad smell control of a product [ as / in rubber finish products, car Fretschner, etc. ], For example, in the product for care of the product for care an object for agriculture like the overflow stream of a dog kennel and a henhouse, and for pets, livestock like the charge of straw material in which a deodorant, a shampoo agent, a detergent, or an animal covers, for example, and a pet, For example, it exists in the seat of a theater, a subway, and a large-scale sealing air system like a means of transportation. The quantity of the above-mentioned compound which may be used is influenced by other elements like the concentration of that in the air which generally contains the specific bad smell and it which are included and the medium by which the compound is used, for example, temperature, humidity, and air circulation. An effective quantity should be used in order to remove a bad smell. Generally, this compound is effective when it exists in the air (a bad smell is contained) on about nine low level of about 0.01 per a cubic meter of air. Each concentration more than the amount of above is generally effective. However, from a practical aspect, probably, about one or more females per a cubic meter of air will be unnecessary, even when using for a bad smell even if most unpleasant and deep moreover. A useful new compound is Cisuno transformer 1 1 (4 1 ethyl cyclohexyl) 11-ethanol at the present invention, Sis / transformer 11 1 (4'-isopropyl cyclohexyl) 11 1 ethanol, "they are Sis / transformer 1-(the 4-3rd class butyl cyclohexyl)11-ethanol. In the present invention, it is as an example of the compound of useful others, For example, Tocyclo hexyl methanol, the Cisuno transformer 4 1 3rd class butyl cyclohexyl methanol, Cisuno transformer 4-methylcyclohexyl methanol~Sis / transformer isopropyl cyclohexyl methanol, 1-cyclohexyl 1-ethanol, a 1-cyclohexyl 1-pro / Tooth Knoll, 1-cyclohexyl 2-methyl 1-propanol, 1-cyclohexyl 1-butanol, 1-cyclohexyl 1-pen Tanol, Sis / transformer 1-(2'-methylcyclohexyl)11-ethanol, Sis / transformer 111(3'-methylcyclohexyl)-1-ethanol "Sis / transformer 11-(4'1 methylcyclohexyl)11-ethanol, 2-cyclohexyl 2-propanol, and Sis / transformer 121(4'1 methylcyclohexyl)-2-propanol can be raised. Next, an example explains the present invention in detail. The specific explanation in an example should not be interpreted as what limits the range of the present invention. The sign "female ' elbow" means the weight (expressed with 9) of the substance which exists in the 1-cubic meter air. Example 1 It is the 70% benzene solution 42.6 evening of a sodium bis(methoxy Ethoxy)aluminum hydride about the solution of Sis / transformer 14-methylcyclohexyl carboxylic acid of the 127 evenings (0.09 mol) in the benzene of Sis / transformer 4-methylcyclohexyl methanol 20 desk. It returned by the excess 10%. what was obtained by carrying out flowing-back heating of the mixture after the completion of addition calmly in between by 3 Facial expression, and subsequently ethyl acetate decomposing a superfluous sodium bis(methoxyethoxy)aluminum hydride -- 60 -- ' -- it poured into the mixture of dark HCI and the water of the second of 60. Two layers arise. "separation from a water layer recovered the organic layer. This organic layer was washed with dark salt water solution at water, sodium carbonate solution, water, and the last. Distillation removed the benzene solvent and it obtained the rough product (it is shown that this output is 4-methylcyclohexyl methanol and GLC analysis contains Sis, a 16% transformer, and a 1% solvent 73%) of the 12.0 evenings which contain a small quantity in addition. n color 5=1.463 Wing The distillation which lets a Biguro column pass to Short refined this output, and it obtained Cisuno transformer 4-methylcyclohexyl methanol. A 50 degrees of boiling point C side / 0.25 sides, n color 5:1.4620. GLC shows that this output is a mixture of 4-methylcyclohexyl methanol of 81:19 Sis / transformer. Example 2 Sis / transformer 4-iso pro Pilsik. 17 [ it passes and ] in the benzene on Xyl methanol 25. Temperature added the solution of the Cisuno transformer 4-isopropyl cyclohexane carboxylic acid of 09 (0.1 mol), while 70% solution 48 of the sodium bis(methoxyethoxy)aluminum hydride Worship(ed) at speed which 80q This carries out. Reduction was completed 5 minutes after the completion of addition. The operation same with having used it in Example 1 recovered, and it essentially obtained a pure output. The yield 13.9 evening, n color 3= M.4680. Sis / transformer 4-Isopro pill cyclohexyl methanol of the 12.6 evenings (80.6% yield) were obtained by distillation which lets a short Biguro column pass. A 71 degrees of boiling point C side / 0.2 sides "n color 4= 1.4 rice porridge 0. example 3 Sis / the transformer 4-3rd class butyl cyclohexyl methanol 25 -- ' -- the ethyl 4-3rd class butyl cyclohexane carboxylate (GI" C) of the 21.2 evenings (0.1 mol) in benzene it analyzes 67.4% as the Sis opposite-sex object and 326% of a transformer opposite-sex object -- having had -- while Gambling(ing) in 31.8 Tha solutions of the 70% benzene solution of the sodium bis(methoxyethoxy)aluminum hydride diluted with the benzene on loom, it added. The mixture was refluxed quickly and the exoergic reaction to generate closed it. It was shown that reduction completed GLC immediately after addition. Continue 3 Female Ocean. "it (ed) and came out, and the superfluous sodium bis(methoxyethoxy)aluminum hydride was destroyed by addition of ethyl acetate, and benzene solution was poured out into 20M dark HCI of Hikami. It collects by the operation same with having used it in Example 1, and is 17. Rough Cis / the transformer 4-3rd class butyl cyclohexyl methanol of the 0 evening (100% yield) were obtained. n color 5= 1. 4694, 10000% of purity by GLC. although each opposite-sex object was not divided by GLC analysis, the Cis- opposite-sex object was Elution(ed) after the transformer (Bissoo cutlet -- realistic) opposite-sex object. This output was distilled, and gave Sis / the transformer 4-3rd class Buchir cyclohexyl methanol, and 78 boiling point 0 A 0.25 side was n visitor =1.4691 and the yield 16.0 evening. EXAMPLE 4 Cisuno transformer 1 - (4'-isopropyl cyclohexyl)-1-ethanol 30 -- ' -- the solution of p-isopropyl aceto Phenone of the 1642 evenings (0.1 mol) in the weight % Triethyl amine solution (it can set in isopropanol) of 1 of isopropanol and the 1 evening In 6000 and 3.92 kg' ground initial pressure, it hydrogenated in the pearl device under existence of carbon top 5% rhodium catalyst 5.09 [ about ]. Hydrogen absorption is quick and ended suddenly 80 minutes afterward. Decreased pressure was (disagreeable [ calculated value of 2.24k9J ]). [ 2.17k9' ] Subsequently, what was obtained by Incarnation(ing) a catalyst was washed, and Isopropanol solution was evaporated on the rotation evaporator, and rough Cisuno transformer 11(4'-isopropyl cyclohexyl)-1-Ethanol of the 17.2 evenings was obtained. n visitor = it was shown that 1.461&GLC analysis and an IR spectrum contain the ketone to which this output corresponds 13.6%. a rough product -- 50 -- ' -- dissolving into ethanol -- "-- it returned in dark water-ized matter shelf matter sodium solution further. Output was poured out into triple the amount [ about ] of the cold water of the capacity of that, and, subsequently the benzene of 50 skins was made to extract twice. The extract was mixed, this was completely washed until it became neutrality, and the benzene solvent was removed on the rotation evaporator, and the alcohol of the 15.5 evenings was obtained. 96.7% of n color 3=1.465December purity. This alcohol was distilled through the Holmann column. Boiling point 7 is O A 0. It is ~74qo/0.3 piece 4 ribs. n color 5=1.46502.1 evening (splinter group 1) boiling point 74oo/0.3 willow Splinter group 2 by n color 5= 1.466411.2 evening (splinter group 2) GLC was 99.7% of pure Cisuno transformer 1-(4'-isopropyl cyclohexyl)-1-ethanol. Example 5 Cisuno transformer 1 - (The 4'-3rd class butyl cyclohexyl) 40 containing the weight % triethyl amine solution of 1 of the 11-Ethanol 10.0 evening (it can set in Isopropanol) -- ' -- the solution of the p-3rd class Petylacetophenone of the 45.8 in in propyl alcohol evening (0.26 mol), 730 and 3. On 5% rhodium carbon catalyst 14.02, it hydrogenated in the pearl device with the initial pressure of 92k9'. hydrogen absorption is very quick (0.78 mol/(hour)) -- and 5.88 kg' -- (-- calculated value 5.89k9/-- disagreeable --) -- it stopped suddenly after decreased pressure. A catalyst is Overturning(ed), and it washes completely by Isopropanol, and, subsequently mixes a furnace solution, This was evaporated on the rotation evaporator in 5 Hino 50q0 (worldly), the isopropyl alcohol solvent was removed, and rough Cis / transformer 1-(the 4'-3rd class butyl cyclohexyl)-1-Ethanol of the 50.0 evenings were obtained. n color 4= 1.4634. GLC analysis shows existence of 4.38% of Isopropanol, the expected alcohol of 63. female %, ketone corresponding to 30.0%, and 0.32% of high boiling point material. This rough substance contains ketone of the 15.0 evenings (0. 22 mol of females) corresponding to desired alcohol. a rough substance -- 100 -- ' -- dissolving into ethanol and setting subsequently to room temperature overnight -- 20 -- ' -- it returned with the solution of hydrogenation shelf matter sodium of the underwater 0.9 evening (20 over%), and obtained the output of request Z of the 46.2 evenings. n color 5= 1.4700. This was 95.96% of Sis / transformer 1-(the 4-3rd class butyl cyclohexyl)11-ethanol as a result of analysis. This was refined by the distillation which lets a Holmann column pass. Z boiling point 70~8December0/0.8 rib n answer = 1.46071.2 evening (splinter group 1) boiling point 82~83 qo/0.8 piece n visitor; 1.469639.5 evening (splinter group 2) pot residue The 4.6 evening (splinter group 3) 2 output (splinter group 2) was analyzed as Sis / transformer 1-(the 4 1 3rd class butyl cyclohexyl)11-ethanol (97.9% of purity). This will be crystallized if it allows to stand at room temperature. Example 6 p-ethyl aceto Phenone (0.636 mol) of the 93% purity of the 2 Sis / transformer 11 1 (4'-ethyl cyclohexyl) 11-ethanol 100.4 evening -- 70 -- ' -- dissolving into isopropyl alcohol Tritilia of weight % of 1 of the 8.0 evenings Three Min solutions (it can set in Isopropanol) was added, and the solution was hydrogenated in the pearl device on the 5% rhodium carbon catalyst of the 14.2 evenings with 75degreeC and 3.92k9-/enmity initial pressure. Hydrogen absorption was quick, was the (=0.71 mol/hour) of abbreviation 4.2k9' almost per hour, was carried out That 3 and stopped after the total decreased pressure of the (calculated value [ of 15.32 kg ] ' ground) of 15.7 kg/. The catalyst was Desertification(ed) and, subsequently was completely washed by Isopropanol. The furnace solution was mixed, and Isopropanol was removed on the rotation evaporator by 503O A 5 A port, and the rough product of the il9.7 evening was obtained. n every -- 4= i.4540. GLC analysis is alcohol of 74.8% of request of this rough product, and 8.5% of corresponding ketone, and it is shown that the remainders are a solvent and a low-boiling-point thing. carrying out the solvent of this rough product into [of ethanol of 200, and setting it subsequently to room temperature overnight -- 40 -- ' -- rough Cis / transformer 1-(4-ethyl cyclohexyl)11-ethanol of the 104.8 evenings which return with the hydrogenation side matter sodium of the 0.75 underwater evenings, and do not contain Ketoso were obtained. n visitor = 1.462 Wing The following were obtained by distilling this through a short Biguro column. Boiling point 45~88qo/4.5 rib The n Ascent 5= 1.4467 (splinter group -) boiling point 8800 sides/4.5 sides n color 5= 1.4642 (splinter group 2) splinter group 2 is a mixture of 30:70 of the stereoisomeric form of 11(4'-ethyl cyclohexyl)-1-ethanol. Example 7 The following bathroom bad smell concentration things were adjusted. Ingredient Weight section Skatole 0.916-Thionaphthol 95% solution of 0.91 thioglycolic acid 21.18n-caproic acid 6.00p-Cresyl iso /ゞ Rare 2.18N-methyl morpholine 6.00 Zypro pyrene glycol The Aerosol can which has the above-mentioned bad smell at 62.82 or less concentration was prepared. Bathroom bad smell Aerosol Ingredient Weight section Bathroom bad smell concentration thing 0.1 Dipro pill glycol 49 injection agent {a} Trichloromonofluoromethane 47.5 {b} It was chosen in order that the perfume of dichloro Fluoro methane 47.5 "spice for cologne (SpiceforCOloLiue)" might use it for the bad smell removal examination of an examination compound. The perfume of "the spice for cologne" contained the following ingredients. Ingredient Weight section lava gin -- an application -- Alice oil 60 Amilmo fur aldehyde 20 amyl salicylate 150 Pencil acetate 30 linalool 30 Cedar wood oil 10 geraniol 130 iso blur goal 60 methyl anthranilate (weight % solution of one in the Zypro pyrene glycol) 20 Muskoki silole 60 Kumarin 50 phenylethyl acetate 30 acetic-acid Terpyl 100 Katsura leaf oil 40 petitgrain-oil SA 60 ylang-ylang oil 130 phenyl acetaldehyde Dimethylasse tar 15 cinnamic alcohol Although a Aerosol can is prepared using the perfume constituent of the 5 and 000 above, Mixture which should be examined in that case was made to exist as follows as a bad smell removal agent. Weight % "Spice for cologne" The compound which should be examined 0.45 times 0.05 injection agent 'a Trichloromonofluoromethane} It had the 49.75{b dichloro Fluoro methane 49.751 00-00 entrance door and the discharge fan, and the testing laboratory where the amount of whole picture loves 29.9, and there is, and an inside size has 3.33x3.64x2.42 (m) was prepared. The discharge fan's capacity was a part for /in 14.3. In order to check whether a certain remains bad smell may be detected before operating a discharge fan for 5 minutes between examinations and carrying out the next examination subsequently, in order to make discharge into a sufficiently clear thing, the stinking thing check was conducted. After the testing laboratory was exhausted suitably, the bad smell of the bathroom was Love on the floor(ed) from the Aerosol can during about 5 seconds. The dew of the perfume constituent Aerosol was carried out 19 seconds after 10~ at the time during about 5 seconds (5 seconds are the average number of hours for which this Aerosol will usually be used by the housewife). 1 minute afterward, two persons' examination 0 member (one person is those who became skillful in spice manufacture and stinking thing evaluation, and they are those who do not have this skillful art at all except knowing the perfume in which the others of one person are common) went into the testing laboratory, and recorded line nothing and a perception result for the smell evaluation for bad smell detection. All the Tha examinations were carried out without getting to know what the substance in which every judge is examined is. The amount of large abbreviation of bad smell concentration thing content Aerosol introduced all over the testing laboratory based on the flow velocity which passes along the valve used for the Aerosol can is as follows. 0 bad-smell concentration thing content Aerosol Quantity (with Respect ') bath Room The quantity of perfume constituent content Aerosol introduced all over 267 testing laboratories is the 9th/of about 260. It was made to mix into an evening "spice for cologne" perfume constituent Aerosol can according to the above-mentioned operation of the compound shown in Table 1, and they were examined on those bathroom bad smell removal ability using the above-mentioned test operation. The result is shown in Table 1. Table 1 compound operation 1 Evaluation Sis / transformer 4-methylcyclohexyl Meta-Nord Sis / transformer 4-Isof which is daily [ U* Wo ] clear and becomes whole Insect phrase neutrally. To Ropyl cyclo Perfume, severer Xyl meta-Nord Sis / transformer 4-3rd class petit Lucik which can carry out VU recognition. passing -- U husband -- fresh Kidle methanol U it is fresh and clear [ it is very much clear, and ] moreover . -- fresh -- Wo every day -- a minor residual odour and - An. It passes and is Xyl- 1-ethanol. U Residual odour 1-Conch hexyl lr propanol 1-cyclohexyl 2-methyl 1-pro who was very light and became clear VO Clear, it is light and weak -- FAE* Lost ball U clear -- residual odour 1-A thump hexyl 1-butanol 1-cyclohexyl 1-Bethanol with light and sufficient Necessity There is WV bad smell, it carries out, and they are Sis with a residual odour / transformer 1 of rudder spice. - (2' - Methylsik U outdoor green residual odour.) [ very ] It passes and they are Xyl-1-Etah Nord Sis / transformer 1-( U to 3'-methyl cyclo moreover minor residual odour Xyl)-1-Etah Nord Sis / transformer 1. - (4" Methylsiks.) [ very ] passing -- those first with a medicine smell in U Husband best -- clear -- a residual odour strong against neutral Xyl river 1-Etanol every day, and an unpleasant mixture smell -- however -- carrying out bad smell Ground mud -- Sis / transformer 11(to 4" ethyl cyclo X Xyl)-1-ethanol clear -- FA8 [ strong ] -- minor -- residual odour Sis / transformer 1-(4" iso pro Pilsy U Clohexyl)-1-Etah Nord Sis / transformer 1- (a 4'-3rd class Butsi U husband -- very much clear -- moreover -- A sign -- it is -- residual-odour-less The.) It passes and is Xyl 1-ethanol. U husband It is very clear and, moreover, the bad smell removal ability of the compound is shown by the following stage valuation bases in the smell 2-cyclo Heginel 2-propanol above of a sea breeze in A sign and Or. "FAE" means the fresh air effect. U* "Remarkable" - the fresh air effect writes -- < -- and a minor residual odour is produced very much, or a residual odour is not produced at all. U "Excellent" - V with the fresh air effect and a minor and comfortable remains primary odor (background) "very good" - It is although there is no fresh air effect, However, all bad smells remove and are various grades, however those [ W ] with a remains primary odor which are not high. Those of a "good"-trace with a bad smell, Those [ x ] with a remains primary odor in which the bad smell of the quality which changed still more remains and which can be permitted comfortably strongly [ so ] Those peculiar with a bad smell which can be clearly identified although there is no "quite good"-intenseness, those [ Y ] with a remains primary odor which can be permitted at most Although "defect"-intenseness is decreasing by Youth 1000, Those peculiar overwhelming with a bad smell and nonpermissible unpleasant remains Odor exist over the whole. Z "With no operation" These are especially surprising results, when "spice for cologne" perfume constituent Aerosol is examined without using this compound and it considers that both judges have perceived existence of a bad smell. Although the present invention was indicated about a certain kind of specific embodiment in this specification, the present invention is not limited to this.