Silicone elastomer coated cloth and its manufacture

[Detailed Description of the Invention]

The present invention relates to silicone elastomer covering cloth. As for an electric insulating phase exception, silicone elastomer covering cloth is used as a diaphragm, A material, and duct Pose from the former. Using it as a monthly interest for medical science or a monthly interest for garments is proposed (refer to ! samurai Kimiaki No. 2687 [ 42 to ] gazette, and JP,55-152863,A). However, the silicone elastomer adsorbed This 9 in the ground, and was [ using it as exterior 41 prickle of a building, or using it as a tent or a tarpaulin ] Dirty-easy, and it was not tried. Conventionally, polytetrafluoroethylene covering glass crossing and a polyvinyl chloride covering synthetic fiber fabric have been used for such a use. . however, Polytetrafluoro ethylene covering glass crossing -- it is expensive and moreover there is a fault that pliability - and flexibility-proof are scarce -- a polyvinyl chloride covering synthetic fiber fabric -- Weakness and low temperature -- "-- there is a fault that the pliability which comes out is missing. If Noriko~Elastomer is used for Generation 9 of polytetrafluoroethylene or polyvinyl chloride. Although a covering cloth or profit excellent in pliability, flexibility-proof, or itl Weather is also kneaded, If it is used in a place with much outdoors or dust for a long period of time and silicone resin will be used instead of 1, Dimensions/This and polytetrafluoroethylene out of which the problem of adsorbing the ground and the garbage of Si or others and being easy to become dirty comes, or polyvinyl chloride, Although there is dirt resistance, pliability and flexibility-proof fall victim and carry out, and ApprehendO, then 1 artificers are dirt resistance and pliability. It Inspection wholeheartedly that the /Ricorne distoma covering cloth which was excellent in all of flexibility-proof should be developed, and is /This result. Misfire ' Ming was reached. Namely, the 9 present invention. In an addition reaction hardening type or radical reaction hardening type silicone elastomer covering cloth, the silicone NISISTOMER covering cloth with which the Solicorn elastomer surface is characterized by covering the =l' Uniformity molar ratio of a Treatment machine machine and a silicon atom with the silicone resin layer which is 08~18 -- and . The addition reaction hardening type for platinum system catalyst r vehicles or an organic peroxide use radical reaction hardening type silicone elastomer constituent is covered on cloth, and heating hardening is carried out. Or [ that the average molar ratio of a reinforcement Norika filler content condensation reaction hardening type organic group and a silicon atom covers and carries out heating hardening of -" 2 from Norrkorn resin constituent Si This which is 08~18 ], A platinum system catalyst use Inquiry reaction hardening type or an organic peroxide use radical reaction hardening type silicone elastomer constituent is covered to A II, the average molar ratio of a platinum system catalyst use Inquiry reaction hardening type organic group and a silicon atom covers the L with the silicone resin constituent which is 08~18, and it is .. Subsequently, heating hardening of the * silicone NISISTOMER constituent and the Solicorn resin constituent is carried out simultaneously. In an addition reaction hardening type or radical reaction hardening type silicone elastomer covering cloth, the silicone elastomer surface is related with the manufacturing method of the silicone NISISTOMER covering cloth by which the average molar ratio of the organic group table silicon atom is covered in 0 and the silicone resin layer which is 8~18. When this is explained based on a drawing, 1 is cloth, it is l, 2i, and]:silicone Ejstoma-, and 3 is a silicone resin layer whose average molar ratio of an organic group and a silicon atom is 08~1.8. Cloth 1 achieves the function as for which U power carries out 1 intensity and dimensional stability. a material ---like -- glass fiber, carbon Woven fabric, silicon carbide fiber, and stainless steel -- textiles -- synthetic fibers, such as an inorganic fiber, nylon, polyethylene pre phthalate, polyacrylonitrile, polyvinyl alcohol, polypropylene, and a polyvinylidene chloride, acetate, rayon, and cotton. In respect of zero light transmittance state which any of natural fibers, such as hemp, may be sufficient as, and Ro:textiles 9 knitting, a nonwoven fabric, and a net may be in process, and may shift, glass fiber and a transparent synthetic fiber are the points of 4 Weather to spread good 4, and they are glass fiber and carbon fiber. Inorganic fibers, such as silicon carbide fiber and stainless steel textiles, and polyethylene 17 Interior phthalate textiles. A polyvinyl alcohol fiber is preferred. The thickness of cloth is not limited especially if only pliability is maintained. Noricornni distoma 2 is waterproofness and protection-against-wind 9 elasticity (= j power carries out and it achieves the function to prevent a fray of cloth.). The example of representation of the addition reaction hardening type silicone elastomer of these, Diorganopolysiloxane and the ORGANO hydrogen policy Roxane which have, the thing, i.e., the silicon atomic bond alkenyl group, of platinum system catalyst use, a platinum system catalyst, and a reinforcement bulking agent are made into base resin, and it is an increase-in-quantity bulking agent (= J Addition reaction retardant, a Rewarding heat agent, fire retardant.) as an additional ingredient, It makes it come to harden the constituent which has contained paints etc. Here, as silicon atomic bond unsaturated machine content Diorthocarbovoroxane, it is the dimethylsiloxane Preference methylvinyl siloxane copolymer fluid or crude rubber of a dimethylpolysiloxane fluid 1 both-ends Dimethy kana nil silyl group blockade of 1 both-ends Dimethy kana nil silyl group blockade, Dimethylsiloxane diphenyl Siloxane methylvinyl siloxane copolymer fluid of a both-ends Methyl Hue end Jimiji kana nil silyl group blockade, or methyl of raw Co * Beam 1 both-ends Dimethy kana nil / Lil machine blockade (3*3, 3-) Co * Beam in a Dimethylenoxane methylvinyl siloxane copolymer of an IJ fluoropropyl Pori Shiroki Sun fluid 1 both-ends silanol group blockade is illustrated. As Orcahydride Empol Shiroki Sun Methylo of a methil-hydrogen-polysiloxane fluid 9 both-ends dimethylsilyl machine blockade of a Is 9 both-ends trimethylsilyl machine blockade, and an id -- dimethylsiloxane Methylo of LOGICAL ENVIRONMENT fluid 1 both-ends Trimethyl / Lil machine blockade, and an id -- Logiene borin roxan copolymer fluid 7 The methylphenyl Siloxane methyl high TRON Ennoloxane copolymer fluid of both-ends 7 Methi / l / phenyl / Lil machine blockade, and tetramethyl tetra-high Troj □ A / Cros Thet Cormorant / Loki Sun are illustrated. As a platinum system catalyst, they are platinum black and platinum chloride acid. The complex of a platinum tetrachloride, platinum chloride acid, and low-molecular Olefin, a platinum screw (acetylacetonato). A rhodium catalyst is illustrated. As a reinforcement bulking agent, they are A barnyard- Mus Rika and Heme 7 Rika who canal-ization-processed, 0 and example t of representation of a radical reaction hardening type silicone elastomer as which precipitation method silica, canal-ization-processed precipitation method Solica, and a carbon blank are illustrated" The Organovoline Locust, a reinforcement bulking agent, and organic peroxide are made into base resin, and it comes to carry out heating hardening of the constituent which has contained the Daisy bulking agent, side heat agent, and fire retardant 1M sum, the organic solvent, etc. as a Addition ingredient. 9 both ends are Trimethylsilyl machines as Diorgano policy Roxian at things, A Dimethy kana nil silyl group, methylphenyl vinyl noryl M i ft id: It is blocked by a silanol group, Main chains are dimethylpolysiloxane, a dimethylsiloxane methylvinyl siloxane copolymer, a dimethylsiloxane diphenyl siloxane copolymer, and a dimethylsiloxane methylvinyl siloxane copolymer. The thing of the shape of crude rubber which is a dimethylsiloxane methylphenyl Siloxane methylvinyl siloxane copolymer or a methyl (3,3,3-) Refluolo propyl ° methylvinyl siloxane copolymer is illustrated. The thing same as a reinforcement bulking agent as the above-mentioned is illustrated. as organic peroxide -- benzoyl peroxide and P-Chlorbenzyl birch sir -- an id. Dicumyl peroxide, G t-butyl par Okidite, 2.5-Dimethyl- 2, 5-Di (1-butylperoxy) Hexan, 2, 5-Dimethyl- 2, and 5-di-t-butyl peroxide Hexane are illustrated. Another example of radical reaction hardening type silicone NISISTOMER, The thing which makes base resin diorganopolysiloxane crude rubber and a reinforcement bulking agent, and it makes it come as an additional ingredient to harden by irradiation, and silicon atomic bond alkenyl group content Diorganopolysiloxane, and Mercaptoalkyl machine content ORGANO Borysiloxane and increase -- admiration -- an agent -- it makes it come to harden the constituent which makes a reinforcement bulking agent base resin by an ultraviolet exposure Among silicone nth Tomah illustrated above, addition reaction hardening type silicone NISISTOMER of the point of the homogeneity of hardening, quick nature, and the acquisition ease of materials and equipment to platinum system catalyst use and radical reaction hardening type silicone NISISTOMER of organic peroxide catalyst use are preferred. When it measures with [[[: of silicone NISISTOMER 2, and hardness scale A of JISK 6301, it is preferred that it is 20~72. It is because silicone elastomer covering cloth will become upright by less than 20 if a feeling of 1 elasticity of silicone elastomer covering cloth exceeds Scarce and 72. Although the thickness in particular of silicone elastomer 2 is not limited, those with grade The to which the convex part of cloth does not expose the minimum, and 10 Limit should just be grades at which the pliability of silicone elastomer cloth is maintained. the 2 present invention -- silicone elastomer When -- when hardening when saying, carrying out the designation of the It is and calling it a silicone NISISTOMER constituent, the thing before hardening shall be said Silicone resin layer 3 It is sticking thru/or uniting with Ha and silicone elastomer 2, It becomes dirty, without injuring the pliability of silicone elastomer 2, and is With about resistance. - The typical things of 3 which achieves the function which acts as Li, and this silicone resin are a condensation reaction hardening type thing and an addition reaction hardening type thing. As for condensation reaction hardening type silicone resin, what contains a reinforcement silica filler from an adhesive point with silicone NISISTOMER is preferred, Or [ processing the silicone resin constituent which makes base resin silanol group content organopolysiloxane resin and a reinforcement silica filler with high temperature baking ], Or [ heat-treating the silicone resin constituent which makes base resin organopolysiloxane resin and the reinforcement silica filler which have a condensation reaction machine like the alkoxy group of a silicon atomic bond, a diketo Kishimu machine, or an acyloxy machine ], Silanol group content organopolysiloxane resin, and the ORGANO Triquetoximsilane, organotrialkoxysilane. Tori ORGANO (N and N-dialkylamino) 7 run -- or the thing which comes to carry out heating hardening of the silicone resin constituent which makes base resin the crosslinking agent and reinforcement silica filler which have a silicon atomic bond condensation reaction machine like Organotri (in grotesque Penoxy) Silang is illustrated. Among these silicone resin, The thing which comes to carry out heating hardening of the silicone resin constituent which makes base resin silanol group content organopolysiloxane resin, the crosslinking agent which has a silicon atomic bond condensation reaction machine, and a reinforcement silica filler is preferred from an adhesive point with silicone NISISTOMER. The Shiroki Sun unit which constitutes this silanol group content organopolysiloxane resin. Although it is any one of (the here, R is an organic group and a A mesh machine, a phenyl group, a vinyl group, and a hexyl group are illustrated), or 2~4, the average molar ratio of it as the whole organopolysiloxane resin and a silicon atom is 0.8~1.8. When smaller than 08, it becomes easy to crack at the time of crookedness, and it is .. It is because it will become dirty if larger than 1.8, and resistance becomes small. 1 whose average molar ratio of R and a silicon atom is 12~17 preferably, and the thing which canal-ization-processed Heem silica, wet process silica, and these silica fillers as a reinforcement silica filler are illustrated from such a viewpoint. what canal-ization-processed a wet process silica filler and But from an adhesive point with silicone NISISTOMER -- good -- Assassination -- 0 Addition reaction hardening type Noricornn is silicon atomic bond lower alkenyl group 9, for example, a vinyl group. The constituent which makes an allyl group owner-[To ORGANO Borysiloxane resin, ORGANO hydrogen poly / Loki Zhang, and platinum system catalyst Ointment hardens. About (l-1, +R '5I03. or R4 R"S i O↓+IZ'R2S r The leaves +R'81ON-222) the /Rokili * A glory which constitutes the ORGANO Borysiloxane resin which has certain 3 and a silicon atom-joint lower alkenyl group boundary SiO+l R obtains with any one or the plurality of (+in formula R' is a lower alkenyl group like vinyl group - or an allyl group, and +R2 are organic groups other than a lower alkenyl group), and SiO A +R25tO Di and S10 student are -- 2 2 2 Although 2 To il or one Oh are a plurality of combination, the average molar ratio of (R'l R2) and a silicon atom is 08~18 as the whole ORGANO Borin roxane resin. The reason and desirable range are as having mentioned above. What was mentioned above is illustrated about the ORGANO hydrogen Borin Roxian and a platinum system catalyst. Although 7VMii and i of silicone resin layer 3 and the pliability of Si IJ piece l-Elastomer covering cloth are not limited that it may especially be a 4n Do not know grade, they are &J and 05~300tt preferably. 0. Using Less Than 51Z Will Consider it as the Whole /Recording Elas I Maher Covering Cloth, if 30011 is Exceeded Difficultly Technically -- 10 -- 3 Which -C is because it Comes in whether it is for [ Upright ] A story -- symmetry(ing) what was Hardened when Calling it /Recon Resin by 1 and -7 Present Invention 3 and /Recon elastomer covering cloth of the present invention which shall symmetry the thing before hardening when calling it a silicone resin constituent. Mercy and cloth are made to cover and harden a silicone elastomer constituent, and subsequently to Norrkorn elastomer A2 a silicone resin constituent is covered and stiffened, Or first, a silicone NISISTOMER constituent is covered on cloth, a Norrkorn resin constituent is covered on the silicone elastomer constituent, and, subsequently it can manufacture by stiffening a silicone elastomer constituent and a silicone resin constituent simultaneously. It is preferred for cloth to scour or degreasing wash and to remove dirt and a foreign substance, when manufacturing this. It is still preferred to pretreat by an ORGANO alkoxysilane system primer further in the meaning of improving the adhesiveness to the cloth of silicone NISISTOMER. In order to cover a silicone NISISTOMER constituent on cloth, they are calendaring and knife coating. It drains off and chooses the method of Paint Si, dip coating, a spray, etc. suitably according to the quality of a silicone elastomer constituent. Calendaring is suitable when a silicone elastomer constituent is a solid-like. When liquefied, knife coating, brush coating, dip coating, or a spray is suitable. In order to stiffen a silicone elastomer constituent, relevant conditions are chosen according to the hardening mechanism. When it is a platinum system catalyst use addition reaction hardening type, heat vulcanization (for example, 100~400 degreeC for [ number part of Samurai~] several seconds), transfer molding, and compression molding (for example, 100~200 degreeC for [ 10 minute~] 30 seconds) are suitable. When it is an organic peroxide catalyst use radical reaction hardening type, it is heat vulcanization (for example). For [ 20 minute~] several seconds and compression molding (for example, 110~180 degreeC for [ 15 minute~] 3 minutes) are suitable by 150~550 degreeC. For covering a silicone resin constituent on silicone NISISTOMER, For brush coating, knife coating, dip coating, or a spray is suitable and covering on a solid silicone NISISTOMER constituent, drain off and Paint Si, dip coating, or a spray is suitable -- the spray is suitable for covering on Si and a liquefied silicone NISISTOMER constituent. For stiffening a silicone resin constituent. the time of being a platinum system catalyst use addition reaction hardening type, also when it is a condensation reaction hardening type -- heating hardening To eat -- from points, such as things and '1. j$ nature, it Dimensions good and is -- . A platinum system My sister use addition reaction hardening type / Ricoh / elastomer constituent Doubled covers an organic peroxide use radical reaction hardening type silicone constituent on cloth, and it is heating hardening Burn it, Or [ that the average molar ratio of a reinforcement bone Solica filler tau owner condensation reaction hardening type organic group and a silicon atom covers moreover with the silicone resin constituent which is 08~1.8, and carries out heating hardening ], It is an object for platinum system catalyst facilities (= J Addition reaction hardening type / Ricorne distoma constituent Dim covering an organic peroxide use radical reaction hardening type Norrkorn elastomer constituent) to cloth. resembling the /Ricorne distoma = constituent - platinum system catalyst use (if =J Addition reaction hardening type Solico 7 resin river composition is covered and heating hardening of the Norrkorn elastomer constituent and the silicone Reno constituent is subsequently carried out simultaneously) since Norrkorn resin layer 3 can manufacture efficiently Norrkorn elastomer *-2, and unification Si / zeta7 Ricorne distoma covering cloth -- good -- Assassination -- 1 and Si that writes, Obtainable with -- having had -- a Norrkorn elastomer -- -ed -- since it Covering, and it is flexible, it becomes dirty with flexibility-proof and resistance is excellent -- exterior Old 9 of a building -- for example, . Exterior income II of phase half-11 gymnasiums for pneumatic structures, or a garage. It can be widely used as a tent, a tarpaulin, skiwear, mountain-climbing wear, a raincoat, a conventionally publicly known monthly interest for 2[business, etc. Big glass Fabric textile or the transparent synthetic fiber fabric of percentage of void is chosen as cloth l, color-free transparent ~ as Solicorn elastomer 2 -- when choosing a translucent /Recon elastomer and choosing color-free transparent~*1'1' transparent corn resin as Norrkorn resin 3, /Ricorne distoma covering cloth is excellent in a light transmittance state. Inside of 1 which can smell an example of the present invention to 3 and the next which become suitable at an exterior phase exception of a building which needs lighting+1-, horticulture house monthly, and 1-2, and an example. Being [ it ]-with part Si] and a weight section are meant, and it is a physical-properties value mouth and the value measured according to JISK6301, and is viscosity C measured value of 125 degrees. Example 1 Both-ends Dimethylvinyl, the Lil machine blockade Dimethyl / Loggasano methylvinyl Shiro Kishan copolymer /(Co'A (methyl Vinyl enro Kiely y unit content Bo)) 40 copies of the wet process / IJ J A of u mol % 100 copy and specific surface area 230+u'/ jj are Layer line(ed) until it becomes uniform, and they are 2.4-dichlorbenzoyl par Okazai of purity 50 small Suspension, and 133 copies (it kneaded until it became uniform j- in addition.) to the 1st order. Next, it agitates by Ox which adds xylene and becomes uniform, and they are same job density 18 x 17 / 25 mm, It is Immersion in the account Solicorn rubber constituent of I- about 405.9/of weight n12.0.37 mm in thickness, it erases -- it neglect - carried out for 6 minutes into the hot wind of Restriction Si and 70 degreeC lightly by * raising 10 Manogur, and xylene was removed, into the hot blast stove of +5 o-e, it was neglected for 20 minutes and vulcanization was used as the deed / Recon elastomer covering glass fiber fabric. It is One arrival ttU of laver 21-Elastomer, and 2o5g / Off 112, and they are the whole Solicorn elastomer covering glass Finesse textiles! The thickness of At ease is Ah - in 08Q mm. The degree of history of A 1 of 7 Ricorne and Russ Tomah+16 Germany (being "50 Ah/This.) At least Dimethylenrokyrin single rj' 140-mol charge and methyl Shirozaki vomiting consist of 60-mol charge, 50 copies of methyl Borysiloxane resin whose /Lanol machine content is 0.9 * t % (it is tau1-/Uniformity molar ratio [ of a methyl group and a silicon atom ] &J■4), Specific surface area 230 +++", / -- jj -- wet process -- silica -- ten -- a copy -- and -- Vinyl -- To (methyl Ethyl°Tokinno-) -- 79910 -- a copy - and -- toluene -- 50 -- a copy -- from -- becoming -- a condensation reaction -- hardening -- type -- seven -- Recon -- resin -- a constituent -- one -- one -- an account -- silicone -- an elastomer -- covering -- glass -- Fibrous fabric -- one side -- " -- = -- a knife coating method It covers thinly and is /This. It is air-dry, and is neglected for 30 minutes in [ after removing toluene ] ';j9 The atmosphere of 150"C, and they are hardening Burn it/zeta about -C None resin button product. j7 of a Norrkorn resin layer -- seeing -- it is 15 lt -- It was. The Norrkorn V gin layer was covered with conditions with the same said of an anti-sequence side. in this way - the obtained silicone elastomer covering glass fiber fabric, Although it is flexible and being rubbed 1000 times by using vaseline as lubricant with the Scott type Massacre examination machine, it exfoliates between a silicone resin layer, and one layer of Noriyo/elastomers, and between one layer of /Ricorne distoma, and a glass fiber fabric (Riin seven /r). n -- cover with the With lining-ed [ silicone elastomer ] Norrkorn resin layer thinly covered with this Silicoulin layer -- the place which ' was and carried out outdoor exposure of the /Rico = Elastomer covering cloth, a Norrkorn resin layer -- thin -- covering (it is ~ -- the Dust stiffness from which silicone NISISTOMER covering cloth had adhered to the Okay. dirt Not 9 surface a little also in one year has been removed only by wiping lightly.) The silicone elastomer covering cloth which has not been covered with a Norrkorn resin layer is dirty in 1 previous month, and -. the surface -- a large number (Dust stiffness d which was being carried out the = Jth place -- even if wiped, Is and Mostly removal were not able to be carried out.) . Example 2 The Bee- Mus Rika 40 copy and diphenyl Scionji all 8 * part of 100 copies of both-ends Dimethy kana nil silyl group blockade Dimethylsiloxane methylvinyl Iroxan copolymer crude rubber (methylvinyl Shiro Kishan unit content 0.57 Mol %), and specific surface area 200 n+'/ g It kneaded on heating and obtained the Solid-like thing. It kneads until it adds 2.0 copies of both-ends trimethylsilyl machine blockade methyl high Delon en Bolin rokazazi (viscosity 20 cst), 0.0030 copy of platinum chloride acid (H2PtCd6.6H20), and 040 copies of methyl Futinol to this and becomes uniform, and it is profitable in a silicone elastomer constituent. Textiles textiles (plain weave and fabric density 18 X 17 / 25 mm, subtotal 405, and !i'/ n?) having covered thinly on both sides of thickness 0.37 mrn -- into the hot blast stove of 180 degreeC, it vulcanized by having neglected it for 10 minutes, and made this into the Solicorn elastomer covering glass fiber fabric. The thickness as the whole Sol Corn Elas] and Maher covering glass fiber fabric was 1.2 mrn. - whose hardness of Germany in a Solicorn elastomer was 61 Next, the condensation reaction hardening type Solicorn resin constituent used in Example 1 is thinly covered with the same Article f+ as Example 1 to both sides of account Solicorn elastomer [ of" 2 ] covering glass Fineness textiles, and heating hardening is carried out, 3 which obtained the Solicorn elastomer covering glass fiber fabric thinly covered with the Solicorn resin layer, and this Solicone Ethistomer covering glass fiber fabric, 3, Example 3 which there were optical penetrations 4/1, and it was a little harder than that of Example 1, and also were like it of Example 1 by flexibility-proof and Stain I+ resistance ('l immediately) 1 Both-ends methylphenyl vinyl group blockade Dimethyl 70 Gizan methylphenyl solo Kizan methylvinyl / Loki Zhang copolymer crude rubber (about Methyl Fu r Lung Loki Zhang A bill content rA) about 5 Morti, and methylvinyl / Rokirin mourn -- Inclusion limit 020 mol % 100 copy and a ratio -- surface filt30 (dance'/fJ To, - Mus Rika 30 copy and 80 copies of Hexa methyl disilazane, and 20 copies of water were kneaded on heating, and the solid-like thing was obtained.) this -- purity 50 weight charge's 2 *4-dichloro Benji * Il Pao -- affected -- it kneaded until it added 35 copies of ids - and became uniform, and the silicone elastomer constituent was obtained. Subsequently, it is the calendaring method about this silicone elastomer Group coverage, The glass fiber fabric beforehand made into Cleaning (shell textile and +8X17 fabric density / 25 mm) To heavy 1405 g/nt', 0 thinly covered to double-sided 1- of thickness 0.37 mm, and the next, The 100 copies of Published Lugano borisilo gyissan register ' A (average molar ratio of piece r of organic group and silicon is I6) 1 both-ends Dimethylphenyl lysoli blockade which at least dimethylsiloxane middle 30 mol % Tephenologyzan'F- becomes from 40-mol charge and 20 mol of Dimethy kana nil Shiogizan jli A~A charge Dimethyl/"7 21 copies of Ginan methyl high Dorothi Denki Kisan copolymers (content 50 Morti of the 4th place of a A mesh hydro-° Janse Roxane shell), It is Samurai about the addition reaction hardening type Norrkorn resin constituent (viscosity 1270 cst) which becomes [ whether it is also pro Pirua of the Benz river and rear Sole, or ], As it leads into the hot blast stove of 180-0, spraying thinly on an account / Ricoh / elastomer~constituent covering glass fiber fabric and becomes Beat for holding time 20 minutes, it is a deed about vulcanization and hardening. The Noriko-A elastomer covering glass fiber fabric thinly covered with the silicone resin layer was obtained. The thickness of the silicone resin layer was 60micro, and the thickness as the whole was 0.80 mm. The hardness of Solicorn elastomer Exposure was 37. The silicone elastomer covering glass fiber fabric obtained in this way, There was a light transmittance state, and although it is flexible and being rubbed 1000 times by using vaseline as lubricant with the Scott type Massacre examination machine, it did not exfoliate between one layer of silicone resin layer Toshiri corn elastomers, and between one layer of silicone elastomers, and a glass fiber fabric. The glass fiber fabric covered only with the above-mentioned silicone NISISTOMER constituent as a comparative example is led into the hot blast stove of 180 degreeC, and it vulcanizes by [ as becoming in / holding time / 20 minutes ], and is profitable in a silicone elastomer covering glass fiber fabric. Next, the place which carried out outdoor exposure of the silicone NISISTOMER covering glass fiber fabric thinly covered with the silicone resin layer, and the silicone NISISTOMER covering glass fiber fabric which has not been covered with a silicone resin layer, A" Also in one year, the silicone NISISTOMER covering glass fiber fabric thinly covered with the silicone resin layer hardly becomes dirty, but wear it a little on the 9 surfaces (although 7 Sat have removed stiffness only by wiping lightly). As for the ground which the silicone NISISTOMER covering glass fiber fabric which has not been covered with a silicone resin layer is dirty in 1 previous month, and were gaining on the 1 surface, Ri to remove was hardly able to remove This 9, either. Example 4 3.0 copies of 100 copies of both-ends methylphenyl vinyl group blockade dimethylsiloxane fluid (viscosity 2000cst) 9 both-ends trimethylsilyl machine blockade Dimethylsiloxane methylhydrogensiloxane copolymers (viscosity 20 cst), Platinum and 030 copies of complexes of Te I and lame Chilled divinyldisiloxane (the amount % of platinum content 0.5ffi), He is Yo Si to a knife coating method about the silicone NISISTOMER constituent which kneaded 15 copies of Hime silica and 050 copies of methyl Butinol of specific surface area 13on?/g which were canal-ization-processed with the trimethylsilyl machine until it became uniform, Polyethylene terephthalate fiber textiles pretreated by the primer which makes vinyl Trimethoquin silane and tetrabuthyl Orno titanate base resin beforehand (plain weave.) It covered to the Ha side of fabric density 29 X 28/25 Tomorrow 1 weight 247 g / Quiet, and thickness 0.25 mm. Next, 100 copies of ORGANO Borysiloxane resin which consists of 10 mol of dimethylsiloxane unit charges, 80 mol of Methyl-n-hexane unit charges *, and Dimethylvinyloxane accession-to-the-throne 10 Morti (it is 1.3 1 d of average molar ratios of an organic group and a silicon atom), 11 copies of tetramethyl tetrahydrogen cyclo Tetrasoloxane. Platinum and 052 copies of complexes of tetra-methyldi vinyl Cycloxane (0.6 % of the weight of platinum content), It leads into the hot blast stove of 150 degreeC, spraying thinly the addition reaction hardening type silicone resin constituent which consists of 080 copies of methyl Butinol, and 50 copies of xylene on the above-mentioned silicone NISISTOMER constituent covering polyethylene terephthalate fiber textiles, Silicone elastomer covering 4~Ri which K Carried out, performed vulcanization and hardening, and was thinly covered with the +7'J-' y resin layer so that it might become in [ holding time ] 10 minutes was obtained. It covered with Nisirikonee distoma and silicone resin similarly about the opposite side of polyethylene terephthalate fiber textiles. The thickness of the silicone resin layer of the silicone NISISTOMER covering polyethylene terephthalate fiber textiles obtained in this way was 36/L, and the thickness as the whole was 0.85 mm. /Recicone Essistomer independent hardness was 32. This Solicorn elastomer covering polyethylene rente Refereeley There is a light transmittance state and A textiles textiles are .. Although it is flexible and being rubbed 1000 times by using vaseline as lubricant with the Scott type Massacre examination machine, it did not exfoliate between a silicone resin layer and one layer of silicone NISISTOMA, and between one layer of silicone NISISTOMA, and polyethylene terephthalate fiber textiles. As the polyethylene terephthalate fiber textiles covered only with the above-mentioned silicone NISISTOMER constituent as a comparative example are led into the hot blast stove of 150 degreeC and it becomes in [ holding time ] 10 minutes, it is a deed about vulcanization. Silico To 1 which obtained Elastomer covering polyethylene Terefukule 1 and Fabric textile, 0 similarly covered with silicone NISISTOMER about for [ the ] opposite, and the next, It covers with Silicone elastomer covering poly Enalenderettele 1 and Fabric textile, and the Norrkorn resin layer which were thinly covered with the silicone resin layer (place which carried out outdoor exposure of the /Recon elastomer covering Borie" Chilenodere phthalate textiles textiles which 2-C are not). Silico thinly covered with the silicone resin layer Although the Stop stiffness, as for, No edistomer covering polyethylene rente Reftale l-Fabric textile was carrying out prickle arrival to the Is-It is very dirty"r To 1 surface a little also in one year has been removed by /C Over wiped lightly, it has not covered with a silicone resin layer -- carrying out silicone elastomer covering cloth -- 11 previous months -- d -- almost is removable, even if it is dirty, a large number have adhered to the 1 surface and it wipes /This-1-Itau stiffness -- Inside and This .. Example 5 It pretreats by the primer in Example 4 which makes vinyl Trimethicosilane and tetrabuthyl Orno titanate base resin beforehand, and is Juice instead of 7 It was poly Ehelendere phthalate textiles textiles. The carbon fiber fabric made into Let's take a close look (31' Weave-Ri, fabric density 14 X 13 / 25 mm, weight 340 g/n?) using 0.78 mm in thickness -- 1 - other ' Condition pregnancy, The silicone resin layer of 3 which was thinly covered with the Norrkorn resin layer like Example 4, and obtained the /This / Rico =-Elastomer covering carbon fiber fabric, and the /Ricorne distoma covering carbon fiber fabric obtained in this way carries out thickness, and it is 141micro, and is thickness C" as the whole, 1.4 3, Example 6 Which are Flexible as for Ah/Xi0, and this Coworker carbon fiber textile-ed [ 7 Rico *-Elastomer ], Became Dirty with Outstanding Field] Crookedness Affair, and Had Resistance by Mm * It smells example 2. - It is vinylon Non-woven fabric of thickness 0.50 mm C and comparatively [ glass Fiberized fiber textiles ], Using the horizontal stockinet made from no irone 66 of thickness 0.50 dragon, the silicone elastomer covering cloth which used the same conditions as other condition Si l and Example 2, and was thinly covered with the /Ricorn resort layer was obtained. This Solicorn elastomer covering cloth is flexible, becomes dirty with field 1 outstanding flexibility, and resists (11 - 1 which it had).

[Brief Description of the Drawings]

1 whose Drawing 2 the 1st figure is carried out, it is a sectional view of the silicone elastomer covering cloth of 11. former, and is a sectional view of 7 Rigon elastomer covering cloth of one example of the 1 present invention 1 Cloth, 2 Silicone Elastomer 13 Norrkorn Resin Layer Drawing 1 Drawing 2