Congealing mixture and manufacture

[Detailed Description of the Invention]

The present invention relates to the condensation (condensation) moderation thing in which the maximum size (the maximum particle diameter) of most particles was provided with the inorganic ultrafine particle (especially A bank note metal or a transition metal) which is 0.5~3000 nm. The present invention is To be involved to the substance containing this condensation mixture Production method and this particle. although a fluid carries out dilution distribution Things of the inorganic ultrafine particle and t] mind is carried out suitably -- the distributed thing of high concentration common -- or -- desirable -- a dry matter -- ink and paint -- fire-resistant ■ Name l carrying out -- or J: of a hyperviscous dissolution plus book -- it will be Must 12 if a To be used substance is mixed easily. High-concentration-izing or the trial to dry is 6, even when a fluid is removed and an ultrafine particle is processed with protection colloid in public [ fluid Removal ] even if in an ultrafine particle. - A not permissible superfluous condensation result was brought. This superfluous condensation is destructive Look about the valuable characteristic of an inorganic ultrafine particle. For example, a certain metal particle to which the maximum particle diameter carries out the right [ of the 2~45 nm (preferably 7~45 nm) ] has useful uL important as what is called transparent colorant. (As for transparent colorant, when light passes, the light of a specific wavelength is absorbed and generating Avoid a color) Most-less +i@ coloring material acts as a Bouto student of the color by multiplication of dispersion of light, and the absorptive action of light. Transparent With coloring agent is carried out, and when this capability to act is condensed more than the size whose metal particle is 45 nm, Lost generating of a light are divided, therefore according to dispersion becomes dominant. On the other hand, at least 2 nm or less of particle diameter is lost, and transparent coloring capability descends as particle diameter is set to 211 m from 7 nm. The problem of superfluous condensation blocks progress of the ultrafine particle of gold or silver as transparent colorant. For example, Cassius's purple is commercially supplied as transparent colorant, in this, adheres to the particles of the Stanick acid which a detailed gold grain distributes in water, and exists. Although this Stanick acid prevents superfluous condensation in a distributed thing [ Dilution ], when water is removed, superfluous condensation takes place and, as a result, the mask of the J:Coloring effect is carried out to absorption. The object of the present invention is to decrease the superfluous condensation problem relevant to a I cooperated constituent for an inorganic ultrafine particle, especially metal particles. Other objects include the formation of the simple method which obtains a constituent from the formation Rice cracker distribution thing of the substance containing this ultrafine particle. therefore, the present invention -- (a) -- while most maximum particle diameter combines with the inorganic ultrafine particle which is 0.5~3000 nm (desirable -- 1 -- 1~150Qnm), and (b) these ultrafine particles the surface is the quality of sparse liquid formed by a means to add lyophilic activity -- this quality of sparse liquid -- the above-mentioned means -- lyophilic Af -- it is sparse liquid to at least one liquid dispersion medium. the impermeability over above-mentioned liquid dispersion medium sufficient when removing the above-mentioned quality of sparse liquid from the distributed thing of the above-mentioned quality of sparse liquid in the above-mentioned liquid dispersion medium for the quantity of the above-mentioned quality of sparse liquid not to make it alike 5% or less -- owner To cover size stabilizer, A condensation mixture provided with condensation Metamorphic products provided with a polymer electrolyte devoted to a connective of the above-mentioned size stabilizer and an ultrafine particle Lie"1 is provided. Such existence of the ingredient of sparse liquid / Lyophilization payment stabilizer in this condensation mixture, under formation of a condensation mixture and the substance used widely, especially superfluous condensation -- Happenings -- in both under mixture to a notorious viscous dissolution plastic substance, good resistance is awarded to things to superfluous condensation of an ultrafine particle at the condensation mixture. The present invention adds the colloidal dispersion liquid of the (a) ultrafine particle to the distributed thing of the 1 method stabilizer in a liquid dispersion medium, Forming spontaneously the above-mentioned ultrafine particle and the 1 method stabilizer in a joint object, the above-mentioned size stabilizer is quality of sparse liquid which has the surface means which gave lyophilic activity to the surface, the above-mentioned sparse liquid substance -- J: -- Surface meanss are each sparse liquid and lyophilic in the above-mentioned liquid-dispersion-medium direction The above-mentioned quality of sparse liquid has sufficient impermeability to protect that the quantity of the above-mentioned quality of sparse liquid decreases to 5% or more at the time of removal of the above-mentioned quality of sparse liquid from the above-mentioned liquid dispersion medium to the above-mentioned liquid dispersion medium, (b) Processing the above-mentioned size stabilizer with the dispersion liquid of a polymer electrolyte strange product, before adding the colloidal dispersion liquid of the above-mentioned ultrafine particle to size stabilizer, the above-mentioned strange product is above-mentioned Cau 9=. It condenses with the above-mentioned size stabilizer and an ultrafine particle at the time of subscription of Lloyd dispersion liquid, and manufactures the condensation mixture provided with the \1 method stabilizer and the condensation strange product which are combined with the above-mentioned ultrafine particle, Or before adding the colloidal dispersion liquid of the above-mentioned ultrafine particle to size stabilizer, the above-mentioned usage stabilizer is processed with the dispersion liquid of the polymer electrolyte strange product condensed to the above-mentioned size stabilizer and an ultrafine particle, The maximum size of most above-mentioned ultrafine particles which manufacture the condensation mixture provided with the size stabilizer and the condensation strange product which are combined with the above-mentioned ultrafine particle is 0.5~3000 nm (preferably 4~1500 mm). It comes out and also provides the manufacturing method of a certain condensation mixture. the case where condensation generates this method and a liquid dispersion medium (solvent) dissociates from a condensation mixture -- most ultrafine particles -- enough -- interval Hey -- it has arranged and has secured the resistance to superfluous condensation. It is 10 for superfluous condensation of an ultrafine particle not only to to have resistance, but to obtain the dry condensation mixture (curdy or Cloud fall) which flows freely, after a dispersing agent is separated (for example, filtration, spray drying or heating while agitating). - It is possible. RiY -- better -- To -- this X1 payment stabilizer -- the surface -- Parental activity (it is the quality of sparse liquid which has the means which added 4F.), The h method for manufacturing a condensation mixture, using water as carrier fluid because of But can be done. Inorganic matter or an organic matter may be sufficient as this size stabilizer. Typical organic size stabilizer is Metamorphism polystyrene and Metamorphism fatty series polyolefin, vinyl aceti 1~, the copolymer of ethylene, poly acrylate or poly meta Acrylate-1~, and poly vinyl When also has a molecular weight of 5000 there is nothing, for example, few so that acetate and one dish of polyurethane may be FE (polytetrafluoroethylene) -- the giant molecule is included. A hydrocarbon chain forms a canal core, and in the case of polystyrene or fatty series polyolefin, the surface of this core forms the parent tree fellows of carboxyl fellows and hydro-"-Schill or sulfate fellows, and is Metamorphism(ed). Such hydrophilic fellows do the graft (Foundation; mouth J) of unsaturated acid or the acid anhydride on a core, Sublen, Olefin, or Te 1~rough Luoro ethylene is polymerized under existence of a surface-active agent including hydrophilic fellows, or it may sometimes form under existence of the residue from a free radical polymerization explosive <appointment medical mixture. The suitable acid anhydride of suitable unsaturated acid is a maleic anhydride, including acrylics or meta-acrylic acid. J of anion fellows like metal carboxylic acid like Noni delta> ffl [ like polyvinyl alcohol ] whose suitable interface Lively agent is, and oleic-acid potassium, or Ben L Sports A A acid, or Ceciltri rutile ammonium chloride: Inactive cation fellows are included. In the size stabilizer which contains owner polarity fellows common, owner Polar tribe exists in the surface of the size stabilizer which grants the hydrophobic core of hydrophilic activity, otherwise, approximately impermeability. as for this size stabilizer, a glass Dislocation temperature degree exists -- without it is and a required A 1 The curdy mixture depends for a crystalline melting point on freeze pulverization in the case of a foil crystalline polymer -- detailed powder -- easy -- Facial (Make -- below 60 degreeC is [ like ] preferred.) Typical inorganic size stabilizer contains Sulfon acid barium, carboxylic acid calcium, alumina or A cylinder, Chita Near, Seria, sulfuration Cadmium, or iron oxide. These compounds are approximately insoluble bamboos at water, and, so, are mainly hydrophobicity. However, ionization of these compounds is " for adding hydrophilic activity. - It leaves a net electric charge on the part surface. If necessary, a surface electric charge can be reversed processing on the surface used as the minus electric charge by the Cation covering agent, or by processing on the surface which carried out jF heavy electric load by the anion covering agent. Silica and alumino have an advantage very strong against heat, and, so, can mix it without the danger of decomposition to the plastic substance or fire-resistant substance under dissolution. It is colored and sulfuration Cadmium and iron oxide show possible use of IC size stabilizer. It is preferred that the density of this size stabilizer does not exceed 5.00/■ *. Such size stabilizer is used with the form which made the liquid dispersion medium distribute an ultrafine particle (preferably colloid). It is All as the maximum particle diameter of size stabilizer does not make 1Qum exceeded for this reason. however -- setting the particles of a byway into a condensation mixture more -- the ultrafine particle of high temperature (density) -- achievement To cover -- things -- 13- It is easy. On the other hand, small Mercy and condensation of an ultrafine particle become difficult not much. Therefore, the average value of the maximum particle diameter of usage stabilizer has preferred 2Qnm~5um. Inorganic usage stabilizer has an advantage which can be easily supplied to the range of this byway, and silica is an expensive value especially about this point. It is preferred for the surface of hot water of I''J Ultra fine particles to be made at this condensation mixture more highly than 60 % of the weight, and for a minimum to only be determined by the commercial element, and to direct o and the minimum beyond ooi % of the weight in a commercial example. The mechanism which the 1 method stabilizer combines with an ultrafine particle at the time of dryness is not fully understood. Probably, this mechanism will be physical or chemical. Probably, a hydrogen bond, ion attraction, and the power of panda Burles can explain partially at least. The balanced formula where at least two mechanism lived together and came out, and a certain form was stabilized will be formed. The joint means can determine also as inside wax whether there will be any potential size stabilizer by trial and error. The same consideration is applied to the plot which determines adaptation of condensation Metamorphism as combination and explains it. A condensation strange product is a -1-/l-condensation Topple sake (by Pl-1 additionally required value), It is manufacture Look about the condensation mixture provided with the size stabilizer which the polymer electrolyte of the giant molecule which can carry out Inquiry arrival may be sufficient as the joint thing of size stabilizer or size stabilizer, and an ultrafine particle, and it combines with an ultrafine particle and the condensation strange product of A and 1@ as a result. the place of plurality [ product / this / condensation strange ] -- Take (t 4J To be -- things are preferred.) The selected condensation strange product of the polymer electrolyte flocculant of the amount of polymers which has a molecular weight of 1o and ooo at least preferably J: Is in simplification, and it is .. This flocculant manufactures size stabilizer and the directly spontaneous condensation thing of the joint thing of an ultrafine particle. It is possible for it to be determined beforehand and to choose the condensation strange product of only condensing with a kPH value instead of this, supposing control of the beginning of condensation is preferred. In this case, condensation does not occur until PH value of a distributed thing is adjusted to predetermined PH value. When particles are provided with a maximum of 1 method of Udah of 20~400 nm, the size stabilizer of especially the art that is not simple is high density (for example, 3.5 b/c+tl). The density of such 1 method stabilizer settles size stabilizer, even if size stabilizer has the characteristic required of colloidal dispersion. Therefore, it is preferred to add the polymers □ electrolyte condensation strange product which promotes distribution of high-density particles first to subscription of the colloidal dispersion liquid of an ultrafine particle to the q method stability rule, and it serves as condensation of the mixture provided with the size stabilizer combined to an ultrafine particle and a condensation strange product after A. The desirable condensation strange product has a molecular weight of 10.000~10.00o and ooo. A cationic polymer electrolyte like polyacrylamide or polyamide or an anionic polymer electrolyte like the salt of poly acrylate may be sufficient as a condensation strange product. Therefore, as for a condensation strange product, being used with the form of solution is preferred. In order to make the colloidal dispersion liquid of this inorganic ultrafine particle, various conventional churning art exists. For example, this churning art may be made by supersonic vibration or quick churning. Since distribution gives the range, Cry, and the particle diameter distribution that often carries out single distribution, it is preferred to separate metal from the solution of the ingredient of one, with 10, and to be made. For example, 1% or less of particles usually have the maximum usage which was widely different from the average maximum scantling number of 4 or more Qnm. from the average maximum number of all the particles, the particles of 50% or more of number have the maximum size different 10 nm or less, come out and are often. the way such narrow single distribution distribution makes a condensation mixture -- * -- color characterized in existence of the narrow maximum peak (line spectrum) in a pure village and Strange radiation Speak 1 helmet as long as it is saved widely and an ultrafine particle is transparent colorant as a result . It is possible to obtain a generating To shake coloring mixture. The colloidal dispersion liquid of the ultrafine particle was discovered as what has valuable processing with disturbance protection colloid about atomic spatial arrangement. Such protection Co [1 id is a substance used as the cause of being able to adhere to id particles for = one day, and expanding considerably by a liquid dispersion medium. The boundary and protection colloid of a fluid [ that it cannot move ] generate expansion in the grade in which the circumference of the ultrafine particle was formed. This protection colloid is helpful for decreasing the reverse result at the time of adding an electrolyte to colloidal dispersion liquid suddenly. The mountains of protection colloid do not decrease in number below from 5% during dryness. However, attaching the 1 method stabilizer to an ultrafine particle should observe that protection Co 17-Lloyd of direct or an intervention may be passed. The present invention provides especially the condensation mixture most (When is also 70% few) whose ultrafine particles are one or more kinds of the money metal or the transition metals which have 5 or the 4~45-nm maximum particle diameter for 2~. A desirable metal is gold, silver, or copper. It can use as transparent colorant which applies a color which spreads through yellow and green from red to until purple. Therefore, the specific color to obtain changes particle diameter, comes out, and is adjusted to a certain range. Gold and a silver granule child are extremely strong with heat in it being as Blame as organic transparent colorant, and gold is extremely strong to light. As for the particle diameter of the greater part of this gold, it is preferred to have the maximum size of 7~45 nm or 12~45 nm (or if a little dispersion is allowed 50 nm). As for the particle diameter of most eyes, on the other hand, it is preferred to have a maximum of 4 3~25-nm method. the condensation mixture can obtain a stable transparent coloring mixture, when thermoforming of increasing resistance Horn of overly detailed copper or cobalt to heat and this condensation mixture is carried out to a film -- it Throat discovery(ed). however, copper grain child 18- or I -- Price -- having had -- the stable coloring made with a constituent is good also from the ultrafine particle of a copper compound. This film may be pulled to powder, without spoiling the published by stability of a color. It is not preferred that particles use for the mountain of lack of the stability in air and water the ultrafine particle as for which the dogged'J protection layer of an oxide consists nothing of a positive metal from cobalt. A platinum group especially platinum, Bala Dilam,]] Jeum, and ruthenium provide the example of addition of a useful non-money metal. It was discovered that the present invention is also suitable for use by transparent colorant, for example, the metal oxide metallic compounds which are red oxide of iron, especially an oxide, and also the oxide that are specific Topple and transparent colorant, for example, the ultrafine particle provided with red oxide of iron. In the case of an oxide, before the maximum particle diameter becomes a problem which cannot permit dispersion, it is made above from 50 nm. For example, particle diameter of 150 nm or more is practical. The red Sour Von acid of other ultrafine particles was carried out, for example, and they are provided with paints like Wren acid Cadmium, yellow titanic acid Nipple, and blue Al Min acid cobalt. The substance containing present invention &, -U, and the inorganic ultrafine particle of the model mentioned above is also provided. In the case of the ink or paint prepared for the Specification-1-It was plastics substance prepared for extrusion molding, and use, or the fire-resistant enamel before ignition (sintering), the substance or the mixture contains the ultrafine particle (weight % which removed the condensation mixture) of 0.01~5% of Wealth. This particle may make the condensation mixture of the present invention work together to a substance using mixing a substance or the mixed art known well. For example, plastic material can use watch Melting mixture or (using a strange cell or a Deio ° Sna mixer) high-speed fluid mixture art for internal fuel-air mixture like dissolution art, To Banbury, or two O-Ramil. Ink and enamel formation may be made by the bed or a ball mill. For paint, churning mixing of the condensation mixture is only carried out at a paint substrate. Therefore, paint is added to an ultrafine particle and also contains a flocculant and size stabilizer. With reference to drawings, a detailed description of the invention is carried out to below. Refer to the distillation water for water in the following example. The 1st and 2nd examples As following, golden] Lloyd part watering solution made solution of gold chloride acid return (reduction), '-lu-detached C money and was prepared. In /19.2 % of the weight, the gold chloride acid of 0.lo containing gold dissolved in the distillation water of 1 A rice 1~Le, and this solution was equally divided into three. - - one solution was used for the 1st example, and the solution of another side was used for the 2nd example. both solution was heated to boil Topple, carrying out continuation churning, and was diluted with side lid standing water by each after that -- acid 3 sodium was added quickly that it cannot go away 1% of the weight. The quantity of acid water solution is shown in Table A that he may want to be added. Next, the distributed thing of all the ultrafine particles which it was considered as protection colloid, 1.25x1< millimeter shoes 1~Le added *C1 % of the weight gum arabic solution to each solution, and the colloidal dispersion liquid of the golden transparent ultrafine particle was formed, and was protected by lc0 gum arabic, Light was absorbed to all the ultrafine particles, and C monochromatic light (most leading light) was generated. 21- The monochromatic light which the maximum average size (evaluation value by an electron microscope) of the gold grain of each solution was shown in Table A, and was seen with the naked eye is also shown. The radiated spectrum of these two colloidal dispersion liquid is shown in Drawing 1. The size of all the ultrafine particles can change by changing the ratio of citric acid to gold chloride acid so that I may be understood from one table A. The easy method of becoming coarser particles, therefore shifting the change monochromatic light of the ratio of citric acid / gold chloride acid from an orange purple is provided as the ratio of citric acid becomes lower. In the case of the 1st example, a pure color and J What is luminescent line radiation are 60 nm or less in bandwidth, or, in the case of the 2nd example, are 1100 n in bandwidth, and it is the Depart 22-3rd example so that I may be understood from Drawing 1. Golden more detailed particles were made Made 36 as follows using hydrogenation Boron thorium. 2. Gold chloride Acid power of 5X10 -3 mol /, and dm' '1 of solution of J C l>' III was mixed with sufficient vigor by 31! of hydrogenation Boric acid 1~Riu l\ of 0 - 3 mol of lXl(s)[ of the cold of five lots ]/dm3 on ice. The Co [] id dispersion liquid of all the 1 ultrafine particles were formed, and these dispersion liquid were carrying out the right [ of the correspondence Covering instep-purple ] to the color of the peak remarkable in 525 nm. This gold grain had the maximum size of 3~25 nm. The 4th example Silver colloidal dispersion solution was prepared as following from silver nitrate. water - cooling -- agitating quickly the hydrogenation Boric acid water solution of 0 or 02 mol (M) carried out in 5.2X10 -3-mol nitric acid solution -- 4r -- Added. The hydrogenation III acid solution of the ratio of 10 poly Cosmium was used to one nitrate. Reduction manufactured spontaneously the I II id dispersion liquid of dark yellow of the transparent metallic silver ultrafine particle. 5 to which protection colloid When of the ultrafine particle protected by polyvinylpyrrolidone was carried out at the manufacture To cover sake, and 9/1 of polyvinylpyrrolidone was added the 25 sums, and this silver granule child make the 4~25-nm maximum Mowing method these dispersion liquid A 1, This average maximum XJ method was Eye disorder(ed) as it is a range which is 10~12 nm. Drawing 2 shows radiation Speak 1~Le of the silver colloidal dispersion liquid of dark yellow. The 5th example The procedure of the 4th example was mixed by the Thet Acetic acid ethylene Diamine of 1 Quickly % of solution 5 But of silver nitrate, and the ratio of nitrate With borohydride was similarly repeated by 3 to 1 except To reduce it. The silver granule child was obtained by doing the maximum size of 2 nm or less the right. The 6th example Copper colloidal dispersion solution returned copper and compound solution of boria Crayy 1~, carried out copper M 81, and was prepared as follows. 201! of 0.3 mol of copper chloride solution -- 25 of solution of the sodium salt of 8% of the weight of polyacrylic acid -- it is mixed awfully and it is assumed that it is that in which the complex of Copper and boria Crayy 1~ is formed there. This mixture is diluted 100 times, 100 Disagreeable are heated by 80 and ~100-degreeC, and, as for this diluted mixture, 3 Disagreeable of 1.25-mol hydrazine hydrate solution are added after that. The colloidal dispersion liquid of the transparent copper ultrafine particle of red [ reduction / which was assumed to be a compound thing of this copper / thing ] was made. Kicking Rafn of 25 ma/J was added to this colloidal dispersion liquid by the protection]1] id blunder. Drawing 3 should show the spectrum for Formation of this copper colloidal dispersion liquid, and be elaborate -- not being cut -- a kana monochrome ingredient -- Cost -- it is -- having generated on the wavelength (560 and ~575nm) which obtains red is understood. The 7th example Colloidal dispersion solution of] PAL]~ changes a copper chloride into a cobalt chloride for the procedure of the 6th example, It ring-former-agent-When instead of hydrazine, and it replaces, is prepared for 0.02t Le of hydrogenation TIP M To 1~Riu l\, and is l This, 1 which manufactured the 1■ Lloyd dispersion liquid of :1 Barthes ultrafine particle whose reduction is black, and these dispersion liquid were transparent to such an extent that they were not thickness sufficient for absorption * Look blackness by all about the light in which particles pass this. This cobalt particle is several minute room arrangement 25. - - if it is in the air -- instability C1 -- it is required to change into a condensation (curdy) mixture quickly so, and to distribute to a protective layer Something to that of a plus books substance. The 8th example colloidal dispersion solution of red oxide of iron added iron oxide to water, added supersonic vibration to water for about 15 minutes, came out, and was prepared. As a result, it is ■] colloid Dispersion Wisdom of the rust color of an iron oxide ultrafine particle. the -- the 9~11th example Colloidal dispersion solution of three kinds of paints, what is called red Sulfon acid selenic acid Cadmium (the 9th example), yellow titanic acid nickel (the 10th example), and blue Al Min acid cobalt (the 11th example) was made as follows. 25-g paints are added to the distillation water of 250 yil, and receive the supersonic vibration for 15 minutes -- water [The dispersion liquid of Pigment were manufactured. After that, dispersion liquid are Acceptance (Made.) about the operation of a colloid mill until it becomes colloid. The particle diameter in id dispersion liquid was estimated to be 1000nn+ on this = the 1st. 26- the -- the 12~18th example =1 which enjoyed good popularity well Work 1 according to the 1st, 2nd, or 4th example "] id dispersion liquid were changed into C condensation mixture using =I a stabilizer and a condensation strange product. . the -- as the solution of the microsphere of the latex which distributed in water the judicial stabilizer used for the 12~18th example -- vinyl Product It was the canal polystyrene which is supplied from the Limited and which was Metamorphism(ed) monopolistically. a microsphere has the average maximum size of about 1 um, and was Metamorphism(ed) by existence of the actual existence machine which it is believed that is a carboxyl group which forms hydrophilic activity, comes out, and is. the microsphere in latex of various concentration -- and -- being used! High of latex was used for 3, the 17th J>J, and the 18th example of Facial expression which are shown in Table B, and was distributed solution of ! and the :Harvest method stable method stabilizer mosquito. again -- water (wabi of J To silica particle; the quantity of a tortoise and the used silica dispersion liquid is shown in Table B.) the selected condensation strange product -- mainly -- each 3 uperfloc587 from a cyanamid company -- it was cationic huge polymers polyamine or huge polymers poly mulberry Turnari amine supplied under the name of J:Facial expression 3 uperfloc521. This flocculant is supplied with the solution containing about 25 % of the weight. The various judicial stabilizer, latex, or dispersion liquid of Hanging was added to 720 Granting of = one-day id dispersion liquid made by the 1st, 2nd, or 4th example. Distillation water attaches with the sediment of a condensation mixture, and the connective by condensation spontaneously after A. [1 It was succeedingly added in a various quantity of the To be condensation strange product. The sediment was dried and it was discovered that the ultrafine particle Lie" Kicked by judicial (passing protection colloid probably) stabilizer is included. The density of the ultrafine particle contained in the color of this sediment and this is shown in Table B. . When polystyrene is included in 5 dried by heating these sediments in the air of 90 degreeC, and these sediments, ' The heated sediment reaches the glass-transition temperature of polystyrene, with the temperature of"-, and a film cuts with formation because of But* by pressurizing the glass board by which facing arrangement was carried out in parallel on both sides of the sediment. Except that 3 from which the film of the thickness of 9Qum was made by this method, and this film formation operation As a result(ed) and monochromatic light shifted in the blue direction slightly, nothing changed. This shows that the condensation mixture is carrying out the right [ of the very strong resistance ] to superfluous condensation (lump Down) of an ultrafine particle. On the other hand, to the sediment containing silica, -C formation was able to do that a weak film dries the sediment on the glass board of 90 degreeC. Again, film formation operation is only CIF 1 to the blue direction slightly about the wavelength of monochromatic light. - It became a cause to carry out. The 19th example the -- the procedure of the 12~18th example was repeated using different 2 10 id dispersion liquid of an ultrafine particle in that protection colloid Gem is not carried out. if it compares with the 12th to 18th examples by which protection] Lloyd processing was carried out in all the cases respectively -- the wavelength of the monochromatic light of a sediment -- the blue direction -- Sis 1-One -- the good slightly short wavelength direction -- One"-- To be -- although things were detected by apparatus The advantage using [ checked / the shift of the color / with the naked eye therefore ] protection Collo Idi is mainly thunder!? It is increasing resistance A J of the colloidal dispersion liquid of an ultrafine particle to the sudden contamination by an exception. A hen" is carried out and it is Surrender].

Mouth 1 Of course - The boria Crayy 1~acid size stabilizer which can be distributed in a condensation mixture and conventional water provided with gold was made as follows. Distributed solution of the boria Crayy 1~acid containing 338% of the weight of a solid was obtained from low and Haas arrival by proprietary name P rimal B85. These dispersion liquid added the water of 250 if to 13*2 g, and were diluted. 180 -- disagreeable dilution dispersion liquid were mixed by 720 il of the 2l l] id dispersion liquid of the gold made by the 1st example as J:. 25 Disagreeable of the condensation strange product which contains 51-g uperfloc587 in the water of 100 xl were added to this mixture. Spontaneous condensation occurred, and the condensation mixture was filtered and dried. The 21st example Also in use of the condensation strange product of To train Pl-1 dependence, the present invention has described use of Bolte 1~rough Ruorozylene (PTFE), and the beginning of condensation as size stabilizer. This PTFE is proprietary name it ostaflon from a kiss 1-greeting to that of Off A Lubbel. It was obtained as distributed solution by T F 5032. The solid of 60-fold However % provided with the particles of PTFF which has the surface Metamorphism(ed) by a certain unidentified hydrophilic substance regarded as these dispersion liquid being oxidization polyethylene (hydrophobicity) is included. These PTFE dispersion liquid are 10 (the water of 250 xi was added to] and it diluted.) before use. On the other hand, the condensation strange product of PI-1 dependence was distributed solution of the polyacrylic acid obtained from low and Haas by proprietary name primalA1. These dispersion liquid are 20! The water of 250yl was added to] and it diluted. Laugh which attaches a condensation mixture as follows. 4001Ji of the colloidal dispersion 32-liquid of the gold made by the 2nd example was mixed by 50- of the dilution PTFE dispersion liquid of the account of J]. this -- mixture tJ churning was carried out and the dilution poly acrylics dispersion liquid of that Contact 1111 were added. It is l of this mixture after that! -1 value added dilute sulfuric acid, and was adjusted to 2*5 or less. Therefore, condensation occurs spontaneously and it is l This. Carrier fluid was filtered and this condensation mixture was dried. After You, this condensation mixture was compressed between the colds (by 1 and pressure of 5x10'MNz"+n'), and formed the cold sintering disk of 1.5nnn pressure. This disk was purple and translucent. The 22nd example It is made as follows and the condensation mixture containing copper is l This. 1801 of the Borisirenushi method stabilizer used for the 12th example was added to 720 xi of the][-1 id dispersion liquid made by the 6th example. This joint thing was made to add and condense 180'II of the polyamine solution used for the 12th example. Although the obtained sediment was pink, it changed green about 10 minutes afterward. However, when it changed into a film with the art which dried this sediment quickly and was used for the 12~18th [ 33-] examples, the pink film which a condensation mixture shows the thing of an ultrafine particle it solidifies and is [ a thing ] resistant to ?I Can * (superfluous condensation) was possible. Although the color of this fill l Oh unstable The * Was in the air too much, the color changed to stable transparent green. In this case, clarify, it '+Z Is and it is . what kind of copper compound was formed. Therefore, A and" arrival to an ultrafine particle are Departure 1 to defunct law stabilizer. - It is assumed that carried out or the resistance of superfluous condensation declined. It calls 23rd CF3 and is the 24th example. Instead of copper dispersion liquid, in the case of the 23rd example, the procedure of the 22nd example was made by the 7th example as"-, and was repeated using IC] PAL 1~-1 "oxidization ironworker which was made by 8th example using l id dispersion liquid in the case of C1 or 24th example" 1 Coid dispersion liquid. As a result, the condensation mixture containing the ultrafine particle of transparent black 2] Halt or rust iron oxide precipitated. These sediments were changed [ that these condensation mixtures carry out the right / of the -C quantity resistance / to superfluous condensation of an ultrafine particle, and ] into the film which protected the color of the Not shown sediment. The color of the sediment containing" PAL 1~ was unstable to air, so, it came to perform conversion on a film within 115 minutes of formation of precipitation, and Re did not become. However, the village of the film was stable. the -- the 25~27th example (The example of these explains the condensation mixture provided with the paints of three kinds of mixture, what is called red Suloneon acid selenic acid Cadmium (the 25th example), yellow Chihung acid nickel (the 26th example), and blue Al Min acid cobalt (the 27th example).) 250Il Ha This added of the water containing 50 g of Metamorphism police Bren latex by which 151! of the pigment dispersion liquid made by the 9th example as J: was used for the 12th example. 31! of dispersion liquid which made the water of 100 yl distribute S'upOrNoc587 of 59 was added, and spontaneous precipitation occurred. Carrier fluid was filtered and this condensation mixture enjoyed [ which Buy(ed) and dried to the glass slide thinly and was heated by 100 degreeC / of 12 a little more than red ] good popularity well 1 qj. 1 by which the same procedure was repeated by the 10th and 11th examples using 1511 of the dispersion liquid of Chitan acid Nickle and Al Min acid Cobal I~ made respectively one by one, as a result the yellow colored strongly -- J and a Facial expression blue film were obtained. The 28th example This example explains the modification art using the high-density size stabilizer of the form of a coarse particle. The dispersion liquid of barium sulfate (Smallpox 4.5 q/cm) are the solution which melted 197 g of l'ill'19 barium in 1 liter of water within the beaker of 5 A rice 1~Le to the water of 1 A rice 1~Le 109.5 (it was flooded one, it mixed and made from the solution which melted the non-anhydrous Acid thorium of].) It was obtained by settling barium sulfate out of dispersion liquid slowly. This barium sulfate was washed with twice fresh water, for the formation To cover reason, agitated dispersion liquid, settled these dispersion liquid among a single horseman, and moved water-contacting [ that ] calmly. The particles of the obtained barium sulfate had 40- and the 120-nm maximum \1 method. The stable dispersion liquid of barium sulfate in water did ' churning of Washing 36-Clean particle by Mizuuchi of 5 A rice 1~Le, and formed dispersion liquid, and after that, they added 12J of the Prevention +l Knee d Kaji delta A polymer electrolyte condensation strange product, and it made precipitation. This strange product equips iso proper tool solution with 30 pile skewer% of the 4th class of boria Crayy 1 Le ammonium hydroxide, and is one-pipe Was done from the whereabouts eta To △E3 S chemicals * Limited to State A of Cheshire 1~Tsukubo 1~. this poly acrylate is considered to have a molecular weight of 5000, comes out and is. As for C same number, l [1 fault is used, and fresh water is distributed, it washes in cold water, and barium sulfate particles are him 1 1 apparatus before the 2nd filtration; : and washing in cold water are repeated 3 times. The flush Ore"l child was re-distributed by water and the dispersion liquid containing 16 pile article% of a solid were manufactured. 18 g of these dispersion liquid was added to 400 yl of the Co D id dispersion liquid of the silver prepared by the 3rd example. the [ 3 by which the condensation mixture provided with the condensation strange product which spontaneous condensation started when these dispersion liquid were agitated by n be, and adhered to the ultrafine particle at joint Topple size stabilizer was manufactured, and ] -- the example of a 29~31 fruit style 37- the 12th, 13th, or 16th example Riko -- the made condensation mixture -- order -- high-density polyethylene (the 29th example) and polymethyl meta-acrylics Fl'3 (the 30th example) or polystyrene (the 31st example) is mixed next by the appearance like Showing -- 1=, each condensation mixture -- the particles, r D 1akon I polymethyl meta-acrylic acid, or polystyrene of high-density polyethylene for commercial deduction molding (grade) in the bottom of existence of a Te 1~Rahyd mouth franc -- Shook (Shooting -- mixture). J: a condensation mixture pastes up this tetrahydro franc on the above-mentioned particles -- particles were stickily looked like [ obtaining ] and it split. Then, the superfluous Te 1~Rahyd mouth franc was Oil spillage(ed). Such a particle Stickiness mixture is loaded with board material by 7j\ spittle of the catapult of single A screen]- of the deduction Topple former. Deduction molding of these charge things was carried out at the board of 3 myn thickness. In formation of these board material, the color which occurs in a 150 degreeC gold grain was red, the color in which it colors by a 25-nm gold grain was maroon, and the color in which it colors by a silver granule child was golden color. These are useful colors. single Screwo sword outfeeder is how to completely twist an effect for paints as When at mixed J To to the Plastic material (especially crystalline Polynrefine) which come out and is taking the shift of a color into calculation. 3* which will induce a result with a more effective mixer sufficient probably 11 lambda and the 33rd example These examples explain use of a condensation mixture, in order to make the paint containing the paint containing silver (the 32nd example) or gold (the 33rd example). 19 of the condensation mixture containing the silver made by the 11th example as J, dissolved in the acid-proof propyl of 10yf. Therefore, the organic sol which Keep eta Carried out the silver ultrafine particle was obtained. Using the spatula, the car carried out paint When of this solution, it was used, and was put in and agitated by the paint substrate provided with nitroglycerine cellulose dispersed to acetic acid Alkyl which can be supplied commercially. Paint was applied to paper after that and the enveloping layer of the thickness of golden 300um was obtained at the time of dryness. The same procedure was made by the 20th example and repeated using the condensation mixture containing gold. The obtained dry coat was magenta. The 34th example Colored Printing, Inc. was made as follows. The condensation mixture containing the gold made by the 17th example as J, was printed and crushed using the mortar and the wooden pestle. 1.5 g of this condensation mixture printed and crushed -- Peace mill (2I-mouth cell [of J Conventional 24 in 1-A printer's ink W months (] was mixed and color ink was manufactured.)) This ink was thinly added to paper and formed covering which has a color which ink dries there and is shown with the magenta liable to pink. The 35th example The procedure of the 371st example was made by the 28th example instead of all the 1.5-g pulverization condensation mixtures, and 1 g of the pulverization thing of the condensation mixture containing barium sulfate An egg was used, and it was repeated. Obtained dry covering was golden color. 236 and the 37th example These examples explain the condensation mixture provided with silica (the 36th example) or alumina (the 37th example), and 40- as size stabilizer in an enamel solvent for ornament porcelain to be gold. 12 *5 Jf of the dispersion liquid of S uperfloc521 used for the 14th example at 1 Ri 1-Le of the colloidal dispersion liquid of the gold in which the condensation mixture was made by the 1st example -- 4 pile lot% of assistant () Was done (average banishment 50nn+) -- 12.5nf of silica part watering solution was added, and it was made. This condensation mixture was collected and dried by filtration. The dry condensation mixture was ground using the mortar and the pestle, and 1105u was screened. The ball mill of the condensation mixture by which 87* was sorted out was carried out in slurry solution containing 42 g of the enamel solvent supplied commercially [ the former provided with lead silicate glass ]. It dries by 100 degreeC, and before a volume dried a 30-minute room at the vacuum furnace of 100 degreeC, the wire net of 75um was passed by this mixture. 20 g of this vacuum-drying mixture is about 15 (the mixture which it Roll mill by the organic Spider medium of l, and is screen-stenciled was formed.). This mixture was screen-stenciled by porcelain and burned by 700~900 degreeC. Smooth glass T41 which has the Ma Angel color liable to pink - The Namel film was obtained and it was shown that the special feature of all the ultrafine particles is not that it is Lost. the same procedure used 4% of the weight of alumina instead of silica, used 23.5xl of 1% of the weight of poly Acry acid dispersion liquid instead of 3uperfloc521, came out, wound, replaced with, and was carried out. The magenta glass enamel film liable to [ same ] pink was obtained. Work directly " to spread" this example explains the capability of the condensation mixture for To be heavy to dye of Absorb 11, and is [ come out and ] in it. The △1covar black supplied at two kinds of dye and what is called Williams (bounce low) and T rypan blue were inspected. these -- Dyed -- 1 -- lily Iatty of Diaries And Power Larris' of C It is indicated to Co1our I ndex published by bread Ford England (SDCBE) in 1971, and be. These statements are referred to here. therefore, △1covar black -- S olvent squirrel i~ being carried out as Black33 -- Trypan blue -- color index N and 2385Q -- 1 it-eat B lue When is carried out, and it is listed. Distributed solution of AlcOMar black was first mixed by suspension solution of the yellow condensation mixture provided with the silver on I was honored barium sulfate according to the 28th example. This mixture was agitated and was A(ed) Nakashizu 1 overnight [ - ]. Dyed -- 1 was absorbed by the condensation mixture and caused a condensation mixture which changed from yellow green. For comparison, the procedure used the dispersion liquid of barium sulfate instead of the condensation mixture, and was repeated. Dye was not absorbed, therefore a color did not change, either. It was repeated using distributed solution of Trypan blue instead of the above-mentioned procedure being Alcouar black. This Trypan blue was absorbed by the condensation mixture and became a cause by which a color changed from yellow to gray. On the other hand, it was not absorbed only with barium sulfate, therefore a color change did not take place. Clearly, a possibility that the color of a condensation mixture will be changed by dye an ultrafine particle or by usually absorbing stain 1'3+ on a mixture is provided. Therefore, the condensation mixture containing the absorbed dye also provides the present invention. .

[Brief Description of the Drawings]

In the radiated spectrum of the Co [] id dispersion liquid of the diameter (25 nm) of a large of all the ultrafine particles, and a byway (15 nm), Drawing 1 is a Show J-figure and Drawing 2 is Show (a figure and Drawing 3 are figures showing radiation Speak l~Le of the colloidal dispersion liquid of a copper ultrafine particle.) about the radiated spectrum of the il lT+ id dispersion liquid of a silver ultrafine particle. Applicant Johnson Macey Public Limited Company =44 - First Japanese rice 1+ RIO (taking Youth- Tooth 7 A 1) 450 550 650 A & & (IrLwL)