Ni-cr alloy material

[Detailed Description of the Invention]

The The city resistance Celestial degree coefficient of until is small, and it is a high thing of electrical resistance which carries out nickel - Cr system system alloy fine Seki. Generally .nickel-Cr system alloy material is conventionally used widely as the heating element for high temperature, and a resistance object for face width. The reason has the features, like, for example as compared with Fe - Cr - aluminum thread alloy material, after heating embrittles, 4 Re and most except sulfuration gas carry out corrosive gas t This pair also at mechanical 'a, such as To ask and hot intensity, nickel-Cr system alloy material is stable, and it is. However, it compares with the +i side .F'e-Cr-aluminum system alloy material, and is f A mind 11 (a stake is low and a mind resistance temperature coefficient is greatly to . and ' from normal temperature to 11Wt article field . again). Acid high wings for women also has the fault that it is a little low, and by the time it moreover also satisfies oxidation-resistant 4:Wow enough, it will not have resulted. Although oxidation resistance is improved and Toward" D can also carry out . electrical resistance to 115micro ohm-tx 4Jl and a degree from making [ a part / at 40~45 atom % ]-in nickel - Cr system alloy material-.Cr Inclusive 1 This, since /a Engineering serves as Trouble . -- the thing of Or Inclusion before and behind 20 atom % with usually easy 7JTI Engineering between the colds is used. and -- adding A1 and Sl in order to improve the fault of mI Description is also Moxa moxa(ed) four times, processability is spoiled remarkably and Came becomes difficult [ between / Jfl / the colds, Bi[or coiling, etc. ] -- many (it has limited by The6atom%.) If the rapid-cooling solidification of the nickel -Or system alloy which consists of composition of union specification which Acute omegaf Research carried out there for the purpose of these artificers being immersed in -W[1tl processability, and providing a high nickel -Cr system alloy material of electrical resistance in view of these points is carried out, It found out that all the above-mentioned objects made it attain, and completed the 1 present invention. That is, the 1 present invention is Cr10~50atom%, and is A.I. Artificial Intelligence or 5~25 atoms of Si(s) %, The remainder consists of N1 substantially, and it excels in cold work nature, and is dc= mind resistance Resistance nickel. - (';r system alloy material and "being Cr, 10~50 atom %, (Ro) A1, or si 5-25 IQ child % (C) Fe, Co, -Nb, Ta, V, M.) Mn, Cu, germanium, Ga, Ti, Zr, Hf, Ca, Ce, One sort or two sorts or more of element 40 fields [ 1000% or less of ] chosen from the chip box which consists of Y and '■h (However, below 40 atoms of Fe(s)%, 0ONb, Ta, V, Mo, Mn) Cu, germanium, and Ga -- respectively -- less than 51 Kyoko %1 'I'i, Zr, Hf, Ca, C, e, Y, and each Th -- it is got blocked with the bottom of 1 My-f %Iu. so (Into) The sum total of /C To (0, (Ro), and (C) Into) excels [ remainder ] NY in the cold work nature which is 1nr++a child % substantially, and it is a high Crying i -Cr system alloy material of Straightforward resistance. +Alloy material V+ of 1'6 Ming is nickel-Cr system alloy D and t':r 5] Okiko, It cheats Solid 16 to 4 dark circles with aluminum or 5i251alpha child % talent, and is the conventional nickel -Cr system alloy material, 1 Brazen resistance 1 straight has seven usual states to Arouse, and far small city to an one Sentiment field and one [resistance [ mind ] degree coefficient -- a Psychic special order and oxidation resistance -- -proof -- it is the alloy material which was excellent in feeding habits, 1 fatigue resistance, bony septum f1 alpha, etc. 1 darkness. When the alloy material of the present invention is explained, it is required for aluminum or Sl to be 5~25atom% at Cr10~501 Kyoko %, and it is Cr15~45. Atom % is preferred and it is y. it is ~ 3737-atom maximum 1 quotient -- aluminum or Sl has preferred 7~2 () atom %, and its 7~15 atom % is the optimal. This er is not made [ raising character, such as mind resistance and I A mind resistance:1 Obsessively, acid-proof-ized 1 mechanical properties, 1-proof [% feeding habits, and fatigue resistance, or ] as for less than ten atom %, aluminum, or Sl to 1 in less than a 511it child. If Cr50atom%, A1, or Sl is made more than 251 Kyoko %, even if it carries out rapid solidification, they are N15SiNisAl and NiAl. Since compounds, such as NixCrgSil, deposit, processability falls easily and there is no 1 Clan as real material. If especially electrical resistance shows the maximum and makes it more than it near 40 atoms of Cr(s) %, electrical resistance will tend to fall to Gradually. Above-mentioned alloy composition t This F'e, Co, Nb, Ta, V, MO, MnCu, If below 411 Kyoko % adds one music or two sorts or more of elements chosen from the group which consists of germanium, Ga, Ti, Zr, Hf, Ca, germanium, Y, and 'Ph (Correcting, as for F'e, below 40 atom %, Co, Nb, Ta, V, Mo, Mn, Cu, germanium, and Ga are below 5.0 atom %, Ti, Zr, Hf, Ca, and Ce, respectively.) Y and Th are below 1.0 atom %, respectively. processability -- it A-mind-resists, and it can pull and can raise mechanical properties, such as breaking strength, Lifespan Maki, etc. more. if Special 1 This Fe is the range of 10~40 atom %, at the same time it will raise l"1 sex, without low-F carrying out high temperature strength, 1llI heat, and 1llit gas nature so much -- a price -- To dodge -- since things are made, it is desirable. Co, Nb, Ta, V, MolMn, CuGe, Ga, Ti, Zr, and Hf -- heat resistance, Thermal bulging rate, and 1-A-mind-resisting, pulling and carrying out Towards of the mechanical 'a, such as breaking strength, -- M -- it is a Childish element and has an effect in Ca, Ce, Y, and 'rh Ha life improvement. however, the addition of which - above was done -- if too more than a ridge, cold work nature falls, and it becomes weak, and is not suitable for use as a practical use alloy material. Impurities 1 of the grade which exists the alloy system of all above in Roughly and the industrial material of 4 usual states, for example, B, P. C and S Sn In As In few Europe, Sb etc. do not interfere with Soya(ing) tree @ Ming at all, even if contained. In order to manufacture the alloy of the present invention, heating fusion may be carried out in account alloy alloy Composition of Ail, # The atmosphere, or a vacuum, and this may be made to cool rapidly. As the rapid-cooling method. Although it is variously, the A piece rolling method Twins rolling method which is 1, for example, a liquid quenching method, and especially the spinning-in rotation liquid method are effective. A tabular alloy can also be manufactured by the piston Anoville method, the Spout quenching method, etc. A liquid quenching method (piece the rolling method, the spinning-in Twins rolling method 1 rotation liquid method) of 111 accounts, carrying out the object for Ij Talk of this rapidly cooling method, since it has the about 104~1115-degreeC/sec degree of cooling 1 vehicle and has an about 106~106-degreeC/sec cooling rate by the piston anvil method Spout quenching method -- #J Rate rapid-cooling Refers -- things are made. With the spinning-in account rotation liquid of 1ii1 method, inside of 1 rotation drum 10 water is put in as it This description JP,55-6494,A epsilon No. 3 gazette, the alloy which fused the wall e This water film in a drum in formation Proposal and this Water intake with centrifugal force is blown off from a silk-thread-spun nozzle, and it has 0 circular 1 To me. The method of obtaining a r+t+ line is said. Special -- for obtaining uniform 1Ifl Continuous wire 1 This, it is preferred 1 t whether peripheral velocity of 1 rotation drum is made into the degree of vehicle and the Fast of the fusion metal style which blows off from a silk-thread-spun nozzle or it, with to rub the speed of the fusion metal style which blows off especially the peripheral velocity of a rotation drum from a silk-thread-spun nozzle -- 5~30 th -- it is preferred to make it quick. As for the angle with the water film which was carried out with the fusion metal style which blows off from a silk-thread-spun nozzle as for wall t This formation in a drum, 20 degrees, with 7 are preferred. Continuation+4 for which"1 account is rotating the m hot water since the alloy material of the present invention contains $1 of many phi, or A1 and which carries out cooling fluid inside-of-the-body e This spout, and has a small uniform circular chip box side of Line spot for an emergency when rapid solidification is carried out! One line can be obtained. And it is front] when 81 or A1 is added into a nickel-Cr alloy.

At the same time it carries out Towards of the performance at the time of /A, cooling 7 night -- outstanding small-gage wire organization potency (wire diameter spots which have field at time of 1 circular when rapid solidification is carried out in cooling surface body) 1: in the inside of the body -- since sex 'u which forms always small vJ-i+9 Continuous wire is Standing(ed), it is very desirable for obtaining uniform Storage lane line which has a field at the time of 1 circular. the alloy material of the present invention is To Postcode obtained by carrying out all Continuing of the cold work, and it can do in things -- the degree of 1 Dimension information -- and (since Moths character is improved more, rolling and drawing processing can be given, and it is .) Heat treatment of C glow raw [7 etc. can also be performed if needed. Face 1% Fast-ization of such a liquid quenching method the simplicity of Rod making(ing) material of the present invention. effects, such as low Me of the expense in Made f, and prefecture Co:non-Ruggy, -- Momota mu->-8 -- such (the object of the This liquid quenching method for four is carried out.) Crand5[] Original f%, Ai or Sl is as few as a fracture and Wear+6 (alloy material which could carry out the product made from 1 Ya of the /r Government building material, and was moreover obtained from the supersaturated solid solution with method of face-centered Ke 1 Baying over which Bite(ed) lambda Rice to 1). [ Ratio-like / one / in group 1i1i: i An enclosure large to 25 nX-f% / 1 Bite it is high. pulling. ] having electrical resistance higher than the conventional nickel -Cr alloy material -- resistance material and [-- the improvement in required heat resistance, oxidation resistance, corrosiveness-proof, fatigue resistance, life 11 alpha, etc. is also expectable 7 The. - an example is given -- if it becomes -- N155 IQ child %, Cr35atom%, and 5i1011 -- a child -- % -- the material which carried out the rapid solidification of the alloy by the A piece rolling method shows 150micro of omega-1 and high W Electricity ratio resistance -- moreover -- this self-Surplus material shuttlecock (ductility -- Toon -- breaking strength -- 65&v/d -- high (it can cold-roll.)) - If Cr and Sl are made more than this, breaking strength will improve. The tendency for t9C resistance and ductility to fall gradually is accepted. Same tendency Although breaking strength improves even if omega-1 is shown in the greatest '' in tM Re, nickel70atom%, Cr2O atom %, and A 110-atom % composition also about nickel-Cr-aluminum system alloy material as for the Electricity ratio resistance of 145micro and it adds Cr and A1 more, Electrical resistance and ductility tend to fall gradually. a In cold work 1 electrical property, i Machine characteristic, Corrosion-negative-proof, oxidation resistance, fatigue resistance, a life, etc., this alloy material is carrying out bet 4'd around which a top turns far compared with the conventional nickel -Or system alloy material. Several kinds are used as various kinds of large charges of Industrial waste material, such as high l Crystal In" stake material, Milky low anti-wood, A Hot wire, strong IW material in high 7' article atmosphere, and Reinforced paulownia IIJ 1fli5 meal 1 years old. next, Rina Kaifeng -- the example of real Us -- an adult -- a target is This description(ed). * the example of A couple -- A [ after fusing the nickel -Or -Si alloy which consists of -1~8. comparison iI/J-1~4 each By transit ■ Formation in argon atmosphere ] l legong blow-of-gas pressure 1.0AMcd, the silk-thread-spun nozzle made from a ruby of hole British 0.5#l1jlr -- 2500 r, p, and +n -- it came out and has changed l times -- direct -- t% 2 (N4 iron Ro 1 Le surface D1"a of 1tw taking out +1 of thickness 50 mum (rjJ 3 all)!) the ribbon d carried out -- Pushing and 4 terminal method -- Spirit resistance (i Electric resistivity (Itomega-1)], 5 mind resistance l Crystal degree Itokazu of the l Crystal If range from normal temperature to snodegreeC, and the Instron type tensile test machine -- IInu Breaking strength (kq/mA), Destruction growth (%), and 180degreedegree -- Grand shade bendability e Hold it 1 another room was carried out.) It is the result Table-1 (- This is shown collectively..) -// 1 ------ ' -2-1--11 He is Ming and others (it is Sadaaki Moto's alloy material, and since experiment editing 2~5.8~11 becomes high Cr-quantity 81, it shows A recitation Si mind specific resistance while its breaking strength (pulling breaking strength) improves, and its "electrical resistance temperature coefficient is also small.) etc. from table-1. since laboratory procedures 1 and 7 have little addition acid of 81 Crying Or respectively -- A mind resistance and breaking strength -- low (and the electrical resistance temperature coefficient is not improved greatly.) the rapid-cooling ribbon material obtained by dissolving in dance saturation becoming impossible all over it 1 evening top N1 in Sl and Cr since experiment 46.12 had much addition acid of Sl and Cr respectively -- Fragile -- < -- the sample with which measurement of * Arousal character, Country character, etc. is presented was not obtained. It is to a thickness of 10 micrometers about the ribbon material of experiment Beam 2~5.8~11. Rolling processing was 1 ability, without giving process annealing. Special t This and fracture strong Sleeping after rolling of Laboratory animals 10 improve with a +5n phrase / -, and, moreover, carry out heating and Redirect (5 times) heat treatment of cooling from room temperature to 950degreeC, and I examined it to the embrittlement, Fragility completely had raw Scratches and straw-mat ↑fft ratio low anti-A as high as 11thetamuomega-drawing, and was able to improve the number small to -1 and goods 1 system whenever [ * Reflex resistance box ] at +X 1 rl-'. Breaking strength and growth were performed on condition of trial length 2ai and =@ 4 times 4.17X10-'/sec using the Instron type Tensile test machine. Example-9~15. comparative example-5~8 After fusing nickel -Cr -A1 alloy which consists of various composition in A I legong atmosphere, it is 9M at argon gas blowout pressure 4.0, the silk-thread-spun nozzle made from a ruby of aperture 0.1[]# A -- 40Or, p, m, and inside diameter 500u Da that is coming out and rotating injecting to temperature 4degreeC formed in the cylinder drum, and the rotation cooling-water inside of the body of the depth 2.51, and making them carry out rapid solidification -- about [ diameter of mean line ] -- the continuation small-gage wire with the circular section of 0.095 n* was produced. The angle of contact of the fusion metal style which held the distance of the silk-thread-spun nozzle at this time and a rotation cooling fluid side to 1.5M++, and blew off from the silk-thread-spun nozzle, and its rotation cooling fluid side to make was 65 degrees. The jet speed from the silk-thread-spun nozzle of a fusion metal style was measured 1 This among the atmosphere from fixed metal m f& which carried out time jet and was dyed, and was about 5f] n-610 m///. The electrical resistibility of the got Rapid quenching 1a small-gage wire material, and ? "it measured about a mind resistance temperature coefficient, Bridge intensity, fracture growth, and 180-degree adhesion bendability. The union is summarized to table-2 and shown. Experiment 444~17*20~22 is the alloy material of the 1 present invention, and since it becomes high Cr-quantity A1, while they are high Wi, helmet specific resistance, and a low electrical resistance Warm skin coefficient, it shows Rude breaking strength, so that more clearly than table-2. '4! :1 Dirty mess 1! Since 1.19 has few amounts of addition of aluminum and Or respectively, Spirit resistance 1 mechanical properties are inferior compared with real vk Haruka 14~17.20~22 of the present invention. Since real * Dispatch 18*26 had too much addition acid of A1 and Cr respectively, the obtained thin wire rod was weak and the sample with which measurement of electrical resistance 1 mechanical properties etc. is presented was not obtained. 7-/ 7' 7~' //'' /'''' Next, Wire drawing processing was possible at 0.0501110 years old of narrow diameters, without giving process annealing for the small-gage wire of real vk Haruka 14~17.20~22 using a diamond dice. and -- without the electrical resistance characteristic is spoiled in any way by Wire drawing processing -- breaking strength -- large 11] -- TowardJ: -- it was able to carry out (for example, breaking strength became 115#/- when the eye line of experiment commonness 15 was Cold wire drawing(ed) up to 0.05 dragons X.). an example-16~22. comparative example-9~15nickel 55-XCr 55Si 10 Mx gold alloy -- in order to examine the effect of addition element M=Nb to kick, Ta, V, Mo, Mn, Ti, and Zr, By the same device as example-1, and the method, the ribbon material of thickness 50 Itm (width 3ag) was produced, and it measured about Rui resistance, one or so breaking strength Elongation, and 180-degree adhesion bendability. The result is summarized to table-3 and shown. It is The center Wk Beam 24.26.2850 and 52.34.36 so that more clearly than table-6. It is the alloy material of the present invention, They are Nb of two atom %, Ta, V, Mo, and Mn, respectively. In 5~1 *mu A 1. Branch 1 Prayer strength, electrical resistibility is Toward"-Si as sharply [ are what added T1 and Zr of 0.5 atom %, and ] as 5~20kq/-. And it had Tsubasa in which 180-degree adhesion bending is possible. However, since experiment & 25.27.29.31. W5.35.57 had too much addition acid, the sample with which rapid-cooling ribbon material presents measurement of Vl Qi resistance mechanical properties etc. easily was not obtained. Example-23 N155atom%, 'E'e50atom% 20 atoms of Cr(s) %. After fusing the alloy which consists of 5110atom% and A15atom% in argon atmosphere, they are Argonganu injection pressure 4.5 kQ/d, Aperture Q and silk-thread-spun nozzle made from a ruby of 15amQ 350 r, p, m and inside diameter 650#lI Tha which is coming out and rotating temperature-15-degreeC and the depth 5.01 which were formed in the cylinder drum -- it blows off in sodium chloride solution -- the very uniform continuation small-gage wire which does not almost have thickness spots with the circular section of jF Honesty in and 155g# Da was obtained. 811'Q v1 Separation of silk-thread-spun Noss ° Le at this time and 1 Tanabe fluid 1 river was held to 1.0 clues, and there was a dark antenna of the t valley-metal style which blew off from the silk-thread-spun nozzle, and its rotation cooling to make. The jet speed of # Molten metal style at this time was a part for 64[]tn/. A mind specific resistance of this small-gage wire 1551 tn-crx It is If 1tfi llffi degree 55 kg/-, and uses Bark and Die Y7 Nondisk for an emergency. It was made to '8 Easy in cold drawing processing to Wire diameter of Q and f]5 silk December, and breaking strength improved to 120 #/c-. Representative Account ball Yuzo amendment sound of one (spontaneity) March, Showa 58 271" Commissioner of JPO Mister 1, the display of an incident Japanese Patent Application No. No. 36225 [ 57 to ] 2, the title of an invention Old-Cr system alloy material Those who do 3 and amendment Relation with an incident Applicant for a patent 4, Generation Masato 6, the contents of amendment (1st page of 11 specification [Cold addition -" of the 20th line] is corrected with [cold work nature 1.) (2) Correct, saying "fatigue resistance, a life value, the feeling characteristic for distortion gauges of Acceptance, etc. having been excellent" in the 10th line with a writing [ the ] of page [ 4th ] "having been excellent in fatigue resistance, a life value, etc." (3) Insert the following text between the 5th line with a writing [ the ] of page [ 6th ] and the 6th line.

The composition and CrPower Moon5~35atom% which it is in [, especially the above-mentioned alloy composition range, and 7~20atom% and the remainder become [ Cr ] from nickel substantially in 15~35atom%, ^l, or Si, A.I. Artificial Intelligence, or Sl becomes 7~20atom% and a remainder real target from nickel, and it is .. Pe, Co, Nb, l'a, V, Mo, Mn, Cu, germanium, 1'i, Zr. Below 40 atom % added one sort or two sorts or more of elements chosen from the group which consists of Iff, Ca, Ce, and Y and Th (Fe(s) are below 40 atom %, Co, Nb, Ta, V, and Mo.). Mn, Cu, germanium, and Ga are below 3.0 atom %, respectively. Since the alloy material which Ti, Zr, Iff, Ca, Ce, and Y and Th become from below 1.0 atom % composition, respectively has the small thermoelectromotive force for copper and a distortion gauge factor is also large. 2- It is very desirable also as a charge of distortion gauge material. The improvement in the r it fatigue nature with a"(4) said document of page [ 9th ] of the 3~4th line, a life value, etc." is also corrected also with "improvement in fatigue resistance, a life value, the feeling characteristic for distortion gauges of Acceptance, etc." (5) Correct the 1-1i1 dense resistance agent of the 1~2nd line with a writing [ the ] of page [ 10th ], and an electrically heated wire" with [precision resistance (for example, feeling material for distortion gauges of Acceptance, etc.), and electrically heated wire-1. (6) Correct number of [electrical resistance temperature systems-1 of the The same page of the 14th line with an "electrical resistance temperature coefficient." (7) Add the following example after "example-23" of the 19th page of the writing.

[example-24 They are argon blowout pressure] and Okg/ cl about nickel65atom% and Cr2'O atom %, Si5atom%, and the alloy that passes and consists of 110atom%, it blew off from the nozzle made from a ruby with aperture phi of 0.3 mm to 500 *r, p, m, and the steel roll surface 20 cm in diameter currently come out of and rotated, and produced the 8 micrometers (rll 2 mm)-thick ribbon. The Instron type tensile test machine is used and it is .. giving distortion to a ribbon sample and measuring inside 1 electrical-resistibility 3-change in the range of 800 degreeC from normal temperature by a 4 terminal method -- various physical properties as a feeling material of distortion cage Acceptance -- +4 (a person -- the law was carried out.) As a result, electrical resistibility is +70micro ohm-cm and electrical resistance temperature coefficient zeta;II]. X 10-5 / K, and tensile strength 38 k g/mm2. It is copper-proof thermoelectromotive force 0.5X 1O-6 V/K and gauge factor 6.0 [ about ], and the alloy material of the 1 present invention is very useful also as a charge of cage material. -14- 283-