Cosmetic mixture
Abstract
(57) [Abstract] Since this gazette is application data in front of an electronic application, the data of an abstract is not recorded.
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Projected expiry passed 24 August 2009, 17.1 years ago.
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15 claims: 15 independent, 0 dependent
- 1[Claim(s)] 【特許請求の範囲】 (1) A coat made to adhere from stable oil / water type emulsion consisting of a thin layer of the quality of non-rubber of a methacrylic acid 2-hydroxyethyl gay polymer, hygroscopicity, flexibility, and pliability. (1)メタクリル酸2-ヒドロキシエチルホモ重合体の非ゴム質、吸湿性、可撓性且つ柔軟性の薄層からなることを特徴とする安定な油/水型エマルジョンから付着させた皮膜。
- 2(2) Stable oil / water type emulsion containing a methacrylic acid 2-hydroxyethyl gay polymer which can form a coat given in the 1st paragraph of a claim. (2)特許請求の範囲第1項記載の皮膜を形成することができるメタクリル酸2-ヒドロキシエチルホモ重合体を含有することを特徴とする安定な油/水型エマルジョン。
- 3(3) Stable oil / water type emulsion of an application for patent containing combination of a solvent for methacrylic acid 2-hydroxyethyl gay polymers which has a methacrylic acid 2-hydroxyethyl gay polymer in a water phase, and a different degree of activity given in the 2nd paragraph of a range. (3)水性相中にあるメタクリル酸2-ヒドロキシエチルホモ重合体及び異なる活性度を有するメタクリル酸2-ヒドロキシエチルホモ重合体用溶剤の組み合わせを含有することを特徴とする特許請求の範囲第2項記載の安定な油/水型エマルジョン。
- 4(4) Local applied law making a thin layer of the quality of non-rubber of methacrylic acid 2-hydroxyethyl, hygroscopicity, flexibility, and pliability adhere on an outer skin from stable emulsion given in the 3rd paragraph of a claim. (4)特許請求の範囲第3項記載の安定エマルジョンからメタクリル酸2-ヒドロキシエチルの非ゴム質、吸湿性、可撓性且つ柔軟性の薄層を表皮上に付着させることを特徴とする局部適用法。
- 5(5) Cosmetics consisting of a coat given in the 1st paragraph of a claim. (5)特許請求の範囲第1項記載の皮膜からなる化粧品。
- 6(6) A combination thing for makeup containing emulsion given in the 2nd paragraph of a claim. (6)特許請求の範囲第2項記載のエマルジョンを含む化粧用配合物。
- 7(7) A combination thing for makeup containing emulsion given in the 3rd paragraph of a claim. (7)特許請求の範囲第3項記載のエマルジョンを含む化粧用配合物。
- 8(8) A plurality of plasticizers which have solvent power which is different to methacrylic acid 2-hydroxyethyl, respectively are contained, A thin layer of a methacrylic acid 2-hydroxyethyl gay polymer of an application for patent, wherein the pliability of a layer of a methacrylic acid 2-hydroxyethyl gay polymer is controlled by this given in the 1st paragraph of a range. (8)メタクリル酸2-ヒドロキシエチルに対してそれぞれ異なった溶解力を有する複数の可塑剤を含有し、これによってメタクリル酸2-ヒドロキシエチルホモ重合体の層の柔軟性が制御されることを特徴とする特許請求の範囲第1項記載のメタクリル酸2-ヒドロキシエチルホモ重合体の薄層。
- 9(9) An oil phase and an aqueous phase are contained, And oil / water type emulsion for makeup which uses the stable oil / water type emulsion of an application for patent containing three sorts of solvents if small [ a methacrylic acid 2-hydroxyethyl gay polymerization and for methacrylic acid 2-hydroxyethyl ] in the aqueous phase given in the 3rd paragraph of a range. (9)油相及び水相を含有し、しかもその水相中にメタクリル酸2-ヒドロキシエチルホモ重合及びメタクリル酸2-ヒドロキシエチル用の少なくと3種の溶剤を含有することを特徴とする特許請求の範囲第3項記載の安定油/水型エマルジョンを使用した化粧用油/水型エマルジョン。
- 10(10) A solvent for methacrylic acid 2-hydroxyethyl gay polymers, (a) Emulsion of an application for patent, wherein activity consists of a low fixity solvent more active than a fixity solvent and the (c) above-mentioned solvent (b) of low middle activity from a volatile solvent and the (b) above-mentioned solvent (a) in activity given in the 9th paragraph of a range. (10)メタクリル酸2-ヒドロキシエチルホモ重合体用の溶剤が、 (a)活性で揮発性の溶剤、 (b)上記溶剤(a)よりも活性が低い中間活性の不揮発性溶剤、及び (c)上記溶剤(b)よりも活性の低い不揮発性溶剤、 からなることを特徴とする特許請求の範囲第9項記載のエマルジョン。
- 11(11) Emulsion forms the (a) oil phase and an aqueous phase separately, (b) Mix an aqueous phase to an oil phase and make it either oil / water type emulsion or water / oil type emulsion, (c) Prepare a methacrylic acid 2-hydroxyethyl gay polymer in the state of solution together with a plasticizer for them, (d) An emulsifier in the oil / water type emulsion of supplying the solution to a water phase, and the (e) request, Another portion of a water phase finally mixed although desired oil / water type emulsion are formed as a part of water phase mixed with an oil phase is supplied, and a claim making in order of the multi stage story which includes mixing a phase of each (f) and making oil / water type emulsion -- a manufacturing process of oil / water type emulsion given in the 3rd paragraph. (11)エマルジョンが、 (a)油相及び水相を別個に形成すること、(b)油相に水相を混合して油/水型エマルジョンか又は水/油型エマルジョンのどちらかにすること、 (c)メタクリル酸2-ヒドロキシエチルホモ重合体をそれ用の可塑剤と一緒に溶液状態で準備すること、 (d)その溶液を水性相に供給すること、 (e)所望の油/水型エマルジョン中の乳化剤を、油相と混合される水性相の一部分として又は所望の油/水型エマルジョンを形成するのに最終的に混合される水性相の別な部分に供給すること、及び (f)各々の相を混合して油/水型エマルジョンを作ること、 を包含する多段階順序で作られることを特徴とする特許請求の範囲第3項記載の油/水型エマルジョンの製造法。
- 12(12) A solvent for methacrylic acid 2-hydroxyethyl gay polymers, (i) Although activity is lower than ethanol as an active volatile solvent, and a solvent of the (ii) above, they are 1 as a fixity solvent of middle activity, and 2-propylene glycol, And emulsion of an application for patent consisting of a nonionic surface-active agent as a low fixity solvent more active than a solvent of the middle activity of the (iii) above given in the 10th paragraph of a range. (12)メタクリル酸2-ヒドロキシエチルホモ重合体用の溶剤が、 (i)活性な揮発性溶剤としてのエタノール、(ii)上記の溶剤よりも活性が低いが中間活性の不揮発性溶剤としての1,2-プロピレングリコール、及び (iii)上記の中間活性の溶剤よりも活性の低い不揮発性溶剤としての非イオン性表面活性剤、からなることを特徴とする特許請求の範囲第10項記載のエマルジョン。
- 13(13) Emulsion of an application for patent, wherein a nonionic surface-active agent is an ethoxy rate of fatty alcohol given in the 12th paragraph of a range. (13)非イオン性表面活性剤が脂肪アルコールのエトキシレートであることを特徴とする特許請求の範囲第12項記載のエマルジョン。
- 14(14) Emulsion given in claim [, wherein ammonium salt of long chain fatty acid is an emulsifier ] 1-4ths, 6, 7, and 9-13 paragraph. (14)長鎖脂肪酸のアンモニウム塩が乳化剤であることを特徴とする特許請求の範囲第1-4、6、7及び9-13項記載のエマルジョン。
- 15(15) A coat, a layer, and emulsion of an application for patent containing an ultraviolet-rays interception agent given in the 1 to 14th paragraphs of a range. (15)紫外線遮断剤を含有することを特徴とする特許請求の範囲第1-14項記載の皮膜、層及びエマルジョン。
Independent claims15
2 paragraphs, as filed
[Detailed Description of the Invention]
The present invention relates to the special manufacturing process of the stable emulsion which can form the thin film of the quality of non-rubber of the methacrylic acid 2-hydroxyethyl gay polymer which can be made to adhere efficiently, hygroscopicity, flexibility, and pliability, and this thin film on an outer skin, and the starting stable emulsion. The present invention relates to the local applied law of the stable emulsion which adheres to the thin film of the quality of non-rubber of a methacrylic acid 2-hydroxyethyl gay polymer, hygroscopicity, flexibility, and pliability on an outer skin. Water resistance containing the combination of the ultraviolet-rays interception agent (sunscreeming agent) and methacrylic acid 2-hydroxyethyl gay polymer which adhered to the present invention on 1 outer skin, It is related with the special manufacturing process of the stable emulsion which can make the thin film of the quality of non-rubber, hygroscopicity, flexibility, and pliability, and the thin film, and the starting stable emulsion. The present invention relates to the local applied law of the stable emulsion which adheres to the thin film of the water resistance of the methacrylic acid 2-hydroxyethyl combined with the ultraviolet-rays interception agent, the quality of non-rubber, hygroscopicity, flexibility, and pliability on an outer skin. 4 Exhilaration 1 smetic and Jolletries, Vol, 99, and the 4th -- in i~54 pages (March, 1984) -- Charles and Mr. Hooks - most makeup agents have expressed the view - which can be prescribed as cream or a lotion. It has pointed out that the Temperature warming of the skin to which Mr. Hooks raises the smoothness, the suppleness, and the softness of the skin symbolizes the main characteristics of facial cream and a lotion. Oil of all sorts, a Supply temperature agent and a skin softener, for example, mineral oil, propylene glycol, and silicone are used to this object. Many substances are used in order to introduce various characteristics into the combination thing for makeup. Fatty alcohol acts as a Supply temperature agent, and also provides emulsion stability, viscosity control, and Conis Jinshi. one attribute to which it is said that fatty alcohol provides -- " -- when it rubbed and lengthens, smooth Mr. Hooks who it is finished and is "(refer to the 52nd page of the above-mentioned literature) says that it is used also for forming a soap emulsion system although stearic acid is a Supply temperature agent. Mr. Hooks has illustrated various ingredients which can be introduced into a cosmetic lotion. The cosmetics of Okay. come out to the leather and skin to which it is applied, and provide a certain amount of protection. The grade of protection. The resistance of the equality of the cosmetics as a coat on many factors, i.e., 1, and an outer skin, 2, humors, and the coat to the operation by perspiration, 34 Volatility of cosmetics Resistance of the coat to 4, wear, and a friction operation. It reaches. 5, resistance of the coat to ultraviolet rays, It is alike and is influenced. Much polymer thermoplastics has been used to various cosmetics uses. The thing of many of these substances is water solubility or water-dispersion. Therefore, all the lotions in which they were included lack water resistance typically. Even if polymer thermoplastics is, the thing, i.e., the polymeric mass, of a large molecule, when [ even ] the coat containing the thing of these large molecules is solubility-ized by moisture, these may be removed from the processing surface by the same grade urgency as the matching prescription thing for makeup which was made from the low-molecular quantity substance. Typically, a polymeric mass exists in a small quantity in cosmetics, and produces this from the fact that this adheres to a little polymeric masses on the skin. Erosion of the polymeric mass by comparatively a lot of moisture is enough to wipe away existence of a polymeric mass quickly from the skin surface. It is because they can provide a certain amount of makeup delayed persistency on an outer skin desirably [ using a damp-proof polymeric mass into the prescription thing for makeup ]. However, use of a damp-proof polymeric mass is completely difficult for this use. Though it has poor film formation nature and has good or suitable film formation nature when it adheres to this damp-proof polymeric mass as a very thin film on an outer skin, they often lack the indispensable characteristic of suitable cosmetics in many cases. By typical oil / prescription thing for water type makeup which this makes it a small quantity [ a polymeric mass ], and exists, When applying as a uniform coat containing the plasticizer needed for cosmetics, he can understand by recognizing that it is difficult to prescribe a polymeric mass in the mode which can secede from emulsion. For example, a plasticizer may be separated from a polymeric mass at the time of application. It says because emulsion is being destroyed by change of the chemicals. In addition, much important characteristics are required of the starting polymeric mass layer on the skin. for example, those who win popularity in processing of an outer skin typically -- and to have the arising feeling which is not preferred, it is required to make a coat thin as enough. As this coat does not have much fat, it is not vulnerable, or it is not adhesiveness, is not quality of rubber, or is not Oiled squirrel Should. 1 whose coat should be acceptance nature to other substances in which ink, dye, oil, or the skin that carried out the surface treatment contacts and which does not come out -- for example Since the polymeric mass in which makeup processing in which newspaper ink is dissolved or itself is dissolved by leather fat lard is not desired has the capability to produce high viscosity, they are those use, Sufficient fine-pores permeation nature to attain the effective combination to the skin should be provided, and the coat which moreover has moisture permeability should be provided. The attribute required of the effective makeup agent which has 1fi4 moistness on an outer skin layer is difficult to attain. For changing an effective damp-proof and thermoplastic film formation polymeric mass into an effective makeup agent, The capability, 2 a thin film is made to adhere from 1 and the stable liquid phase (so it does not have [ tactile impression and flexibility with good it, ] greasiness, weakness, adhesiveness, gummous, and oiliness), (11) The place where ink, dye, oil, or the skin that carried out the surface treatment contacts, Or resistance over other substances which the body like leather fat lard generates, (The easy permeation nature to the fine pores of the iiil skin, the feel of the smooth skin like velvet, (IV) the quality of non-rubber rubbing and lengthening a sex and fV) Adhesion , on the skin surface of the uniform plasticization thin film which has the 11i1 moistness which combined with breathability and Permeability (respiration) is required. Typically, an ultraviolet-rays interception agent is applied from the prescription thing for makeup designed to improve the function of this Agent. Generally these are used into acrylic emulsion. In J, Soc, Co5 a+et, Cheffi, 29, and the 641~649th page (197g), it is the R varnish hamburger outside, Use of the ultraviolet-rays interception agent like p-N and N-dimethylaminobenzoic acid octyl (PABA), and acrylic acid ammonium / acrylic ester polymer is indicated (see the "5ynopsis"), This polymer as which authors chose the acrylate thin film formation polymer as main thin film formation agents for manufacture of "ultraviolet-rays interception agent is skin adhesion nature, and is water resistance. However, if it is made to dry on the skin, the thin film will be easily removed by soap and water. The oil / water type emulsion containing an acrylate polymer and octyl Dimethyl PABA were prepared. '' which isostearic acid ammonium committed as main emulsifiers (refer to the 642nd page). The acrylate thin film formation polymer which can be made to solubilize by forming ammonium-ized salt into '' anionic soap emulsion was chosen. If this ultraviolet-rays interception agent is dried on the skin, ammonia occurs and an insoluble polymer adheres on the skin in this way. this "Escape amine conversion -- a thin film -- insoluble in water nature -- and it receives rubbing and becomes resistance. it carries out and this is easily removed by washing with soap and water among a rudder. ...... " (refer to the 646th page). A methacrylic acid hydroxyl ethyl gay polymer [poly] (methacrylic acid 2-hydroxyethyl) (with this specification, it is front Without by abbreviation "PHHMA") will be repeating unit type % type %, if it says widely. It has [X is hydrogen or methyl each among a formula, it A and at most one X is methyl]. P In the characteristic display with common The most of HHM A, it has X only as hydrogen. Term" polymeric mass - in this specification includes the polymeric structure which consists of a repetitive monomeric unit. In this specification, a polymer is specified as a larger polymeric mass than oligomer, and oligomer is specified as the structure of having a repetitive monomeric unit up to about 15 pieces, on them. The methacrylic acid hydroxyethyl gay polymer and the copolymer are indicated in many patent documents about use for the use of cosmetics. For example, April 13, 1971 is set to United States patent 3rd of issue, and No. 574.822, The outside of the outside of Mr. [ chef art ], the constituent for hairdressing, a Kaori discharge ingredient, the emulsion for makeup, A pest control agent, an ultraviolet-rays interception lotion, an aerosol, the enamel for nail polish, Facial cleansing cream, nutrition foundation cream, a hand cream, emollient cream, It has indicated using the solution of the shape of end PHEMA and PHEMA of Dress to the use of many like face powder, powder, and a stick lipstick (U.S. Pat. No. 3,677.518 besides the chef art). The cross reference to related application like said 3,681.089 No., said 3,681.248 No., said 3.697.643 No., and said 3,914,405 No. should be referred to. According to this patent, PHHMA is a usually vulnerable substance. And it is shown that it is sufficiently vulnerable so that it can be used for giving a play as lacquer for covering a nail to hairdressing again. Plasticization of PHEMA by Example 17 of this patent blending glycerol, sorbitol, diethylene glycol, the Zypro pyrene glycol, ethylene glycol, and (or) propylene glycol as a plasticizer is treated. Although this brought more flexible one the ground play, even when such plasticization was carried out, the polymer was rigidity as it was enough to maintain hair at the state where it carried out tightly. This showed that the feeling which is not preferred was caused to a user so that the fact that the coat on the skin resists the mobility of the skin may be reflected, when such a polymer was applied to the skin. In United States patent 3rd of issue, and No. 963.685, the Abra Hamm's has indicated June 15, 1976 about the manufacturing process of PHHMA. This patent has described the uses of many about PHHMA including what is shown in the United States patent besides the above-mentioned chef art. L Watermelon 1 The present invention relates to formation of the thin layer of the quality of non-rubber of the PHHMA coat to which it adhered on the outer skin, hygroscopicity, flexibility, and pliability. The present invention relates to the special manufacturing process of the stable emulsion of PHHMA, and this stable emulsion for makeup. The present invention includes local application of the stable emulsion which adheres to the thin film of the quality of non-rubber of PHEMA, hygroscopicity, flexibility, and pliability, in order to provide a makeup special feature on an outer skin. The present invention has planned formation of the thin layer of the quality of non-rubber, hygroscopicity, flexibility, and pliability to the PHHMA coat as a part of makeup agent to which it adheres on an outer skin. The 0 present invention about the manufacturing process in which the prescription thing for makeup of the stable emulsion of PHHMA and its stable emulsion of the present invention are special, The thin film of the quality of non-rubber of PHEMA, hygroscopicity, flexibility, and pliability includes local application of the stable prescription thing for emulsion makeup to which it adheres on an outer skin. The present invention relates to the thin layer of PHHMA which contained a plurality of plasticizers which have solvent power which is different to PHHMA, respectively, and controlled the pliability of the layer of PHEMA by this. The present invention contains an oil phase and an aqueous phase, and relates to the oil / water type emulsion for makeup which contains at least three sorts of solvents for PHEMA and P HEMA in the aqueous phase. The solvent for PHEMA, (i) An active volatile solvent, (ii) Although activity is lower than the above-mentioned solvent, they are a fixity solvent of middle activity, and fiiil. It consists of a low fixity solvent more active than the fixity solvent of the above-mentioned middle activity. The present invention mixes an aqueous phase to forming 1, an oil phase, and an aqueous phase separately, 2, and an oil phase, and it makes it either oil / water type emulsion or water / oil type emulsion, 3 PHEMA is prepared in the state of solution together with the plasticizer for them, supplying another portion of the water phase finally mixed although desired oil / water type emulsion are formed as a part of water phase mixed with an oil phase in the emulsifier in supplying 4 and this solution into a water phase, 5, and desired oil / water type emulsion -- and 6 and each phase are mixed and oil / water type emulsion is made, Formation of the oil / water type emulsion to include and which was made in order of the multi stage story is included. The present invention recognizes that the effective prescription thing for makeup of content Oil / water type emulsion should be based on the combination of some related matters in PHEMA. The important relation to this prescription thing is the quantity of PHHMA in emulsion, fi (factor connected to the solvent power of a plasticizer when dissolving PHHMA) of a plasticizer to the quantity of PHEMA, It is a relation between the validity of the emulsifier for combining each ingredient in emulsion so that the characteristic effective in the emulsion for coat formation of PHHMA useful as a makeup agent may be given. In addition, the present invention relates to formation of the thin layer of the water resistance of the P HHMA coat which it adhered on the outer skin from the oil / water type emulsion which uses the ammonium salt of long chain fatty acid as an emulsifier, and was insolubilized by disassembly of the ammonium salt from it, the quality of non-rubber, hygroscopicity, flexibility, and pliability. The present invention relates to the special manufacturing process of the stable emulsion of PHEMA, and the stable emulsion for makeup using the ammonium salt of long chain fatty acid as an emulsifier. The present invention includes the local applied law of the stable emulsion which adheres the oil/water which used the ammonium salt of long chain fatty acid as an emulsifier to the thin layer of the water resistance of P HHM A, a non-gum substance, hygroscopicity, flexibility, and pliability in order to provide a makeup special feature on an outer skin from emulsion. The present invention is the water resistance of a PHHMA coat as some cosmetics which it adhered on the outer skin from the oil / water type emulsion which uses the ammonium salt of long chain fatty acid as an emulsifier, and were insolubilized by disassembly of the ammonium salt from it, It includes forming the thin layer of a non-gum substance, hygroscopicity, flexibility, and pliability. The prescription thing for makeup of the emulsion of PHEMA with the stable present invention, And the 0 present invention about the special manufacturing process of the stable emulsion which uses the ammonium salt of long chain fatty acid as an emulsifier, The thin film of the water resistance of PHHMA, a non-gum substance, Hygroscopicity, flexibility, and pliability includes local application of the prescription thing for makeup of stable emulsion to which it adheres on an outer skin, using the ammonium salt of long chain fatty acid as an emulsifier. The present invention contains a plurality of plasticizers which have solvent power which is different to P HHM A, respectively, and the pliability of the layer of PHEMA is controlled by this, And it is related with the waterproof thin layer of PHEMA made the part of the waterproof layer of PHEMA by disassembly of the emulsifier in the emulsion by which PHHMA and a plurality of plasticizers were prescribed. The present invention contains an oil phase and an aqueous phase, and relates to the oil / water type emulsion for makeup which contains the ammonium salt of fatty acid as at least three sorts of solvents for PHEMA and PHEMA, and an emulsifier for them in the aqueous phase. The solvent for this PHEMA, (i) An active volatile solvent, (ii) Although activity is lower than the above-mentioned solvent, they are a fixity solvent of middle activity, and fiiil. It consists of a low fixity solvent more active than the solvent of the above-mentioned middle activity. The present invention mixes an aqueous phase to forming 1, an oil phase, and an aqueous phase separately, 2, and an oil phase, and it makes it either oil / water type emulsion or water / oil type emulsion, 3 It is PHEMA in a solution state together with the plasticizer for them! I:I It Provision, forming an emulsifier, when the portion of the emulsifier in supplying 4 and its solution into a water phase, 5, and desired oil / water type emulsion is supplied as a part of water phase and a part in an oil phase and each of oil / water type emulsion is mixed -- and . Formation of emulsion is included for the oil/water which includes mixing 6 and each phase and making oil / water type emulsion and which is made in order of a multi stage story. Water resistance which contains the combination of the ultraviolet-rays interception agent and methacrylic acid 2-hydroxyethyl gay polymer which adhered to the present invention on the outer skin in other examples, It is related with the special manufacturing process of the stable emulsion which can make the thin film of a non-gum substance, hygroscopicity, flexibility, and pliability, and this film, and the stable emulsion. The present invention includes local application of the stable emulsion which adheres to the thin film of the water resistance of the methacrylic acid 2-hydroxyethyl gay polymer combined with the ultraviolet-rays interception agent, a non-gum substance, hygroscopicity, flexibility, and pliability on an outer skin. It plans for the present invention to form the thin film of the water resistance of the combination of an ultraviolet-rays interception agent and PHHMA, a non-gum substance, hygroscopicity, flexibility, and pliability as a part of makeup agent to which it adheres on an outer skin. The 0 present invention about the manufacturing process in which the prescription thing for makeup of the stable emulsion of PHHMA containing an ultraviolet-rays interception agent and the starting stable emulsion of the present invention are special, The thin film of the water resistance of PHHMA which combined with the ultraviolet-rays interception agent, a non-gum substance, a moisture absorption agent, flexibility, and pliability includes local application of the prescription thing for makeup of stable emulsion to which it adheres on an outer skin. The present invention contains a plurality of plasticizers which have solvent power which is different to an ultraviolet-rays interception agent and PHHMA, respectively, and relates to the thin layer of PHHMA by which the pliability of the layer of PHHMA was controlled by this. The present invention contains the oil phase and aqueous phase containing an ultraviolet-rays interception agent, and relates to the oil / water type emulsion for the makeup which contains at least three sorts of solvents for PHEMA and PHEMA in the aqueous phase. The solvent for PHEMA is (i). Active volatile solvent, (ii) although activity is lower than the above-mentioned solvent -- middle -- an active fixity solvent -- and (iii) It consists of a low fixity solvent more active than the solvent of the above-mentioned middle activity. The present invention mixes an aqueous phase to the oil phase containing forming 1, an oil phase, and an aqueous phase separately, 2, and ultraviolet rays, and it makes it either oil / water type emulsion or water / oil type emulsion, 3 PHHMA is prepared by r'\4 liquefied voice together with the plasticizer for them, Another portion of the water phase finally mixed although desired oil / water type emulsion are formed as a part of water phase mixed with an oil phase in the emulsifier in supplying 4 and its solution into an aqueous phase, 5, and desired oil / water type emulsion is supplied, 6 and each phase are mixed and oil / water type emulsion is made, Formation of the oil / water type emulsion to include and which was made in order of the multi stage story is included. of 2 -- thin word * Ha PHEMA which can be used as an ingredient in the prescription thing for makeup and which is promoted is usually a brittle plastic of insoluble in water nature. Although this is characterized as hygroscopicity, this means that it has strong affinity to water. This polymer is hygroscopic as it is enough to absorb and keep moisture. PHHMA swells at the time of contact of water and a door, and, so, the coat of PHHMA on an outer skin may actually swell with the moisture which exists on the surface. Into the alcohol like methanol or ethanol, PHEMA is soluble and can dissolve into the solution of these alcohol and the water up to about 80 % of the weight. By these attributes, using P HE M A as lacquer for hairdressing is promoted. In order to be flexibility and to make PHHMA convert into the coat of pliability, without introducing a copolymer component into the structure, to plasticize by other substances of it and compatibility is required. Supposing a plasticizer is water solubility, it may exude from a mixture with PHHMA and may leave a brittle polymer behind. Anyway, if The most is plasticized with a desirable plasticizer in respect of endurance, the film-forming substance of the quality of rubber will be obtained. It was confirmed that it cannot be made the emulsion which can make the coat which is quality of non-rubber, and (or) rubs, and does not have omission on an outer skin produce unless it is made suitable such although PHEMA can be emulsified and it can plasticize however. In order for PHEMA to make the plasticization coat which has endurance peculiar under existence of a lot of moisture produce, it was confirmed that it can plasticize in the combination of water solubility and (or) a water-dispersion plasticizer. The present invention includes formation of the homogeneous coat which consists of a uniform dispersing element with at least two sorts which have solvent power which is different to the thin film, i.e., PHEMA, and PHEMA of multiplex plasticization PHEMA, respectively of different plasticizers. Present invention, In order to form the thin film which is compatibility as enough for an oil phase and PHEMA to distribute the ingredient and PHEMA of an oil phase uniformly on essence in a thin film so that it may be proved with the performance characteristic of a thin film It includes making the oil phase adhere at the same time it makes PHHMA adhere from the water phase of oil / water type emulsion. It specifies that the present invention is in the solvent ingredient which provides oleophilicity with sufficient PHEMA to secure the starting compatibility with the ingredient of an oil phase, and a solution state in formation of a thin film. Especially the present invention includes formation of the thin film containing an ultraviolet-rays interception agent and multiplex plasticization PHEMA, i.e., the homogeneous thin film which consists of a uniform dispersing agent with at least two sorts which have solvent power which is different to P HE M A and P HE M A, respectively of different plasticizers for P HE M A. In order that it may form the thin film which is compatibility as an oil phase and PHEMA of the present invention are enough to distribute uniformly the ingredient and PHHMA containing an ultraviolet-rays interception agent of an oil phase on essence in a thin film so that it may be proved with the performance characteristic of a thin film, It includes making the oil phase containing an ultraviolet-rays interception agent adhere at the same time it makes PHHMA adhere from the water phase of oil / water type emulsion. It specifies that the present invention is in the solvent ingredient which provides sufficient oleophilicity for PHEMA to secure the starting compatibility with the ingredient of the oil phase containing an ultraviolet-rays interception agent in formation of a thin film, and a solution state. The object of the present invention is to make 1 HE M A into the thin layer of the quality of non-rubber, hygroscopicity, flexibility, and pliability, when it is made to adhere on an outer skin. the prescription thing for makeup which can form the thin layer of the quality of non-rubber of PHHMA, Absorption d5 flexibility, and pliability when other objects of the present invention are made to adhere on an outer skin -- it is forming the stable emulsion of PHEMA into a lotion prescription thing preferably. Other objects of the present invention are to provide the manufacturing process of the stable emulsion of P HE M A which produces the thin layer of the quality of non-rubber of P HE M A, hygroscopicity, flexibility, and pliability, when it is made to adhere on an outer skin. In purple outside, the object of further others of the present invention is, when it is made to adhere on an outer skin! It is making combination of lA interception agent and PHHMA into the thin layer of water resistance, the quality of non-rubber, hygroscopicity, flexibility, and pliability. Water resistance of PHHMA which contains an ultraviolet-rays interception agent when the object of further others of the present invention is made to adhere on an outer skin, the prescription thing for makeup which forms the thin layer of the quality of non-rubber, hygroscopicity, flexibility, and pliability and which can carry out things -- it is forming the stable emulsion of PHEMA into a lotion prescription thing preferably. The object of further others of the present invention is to provide manufacture Death of the stable emulsion of J layer Wo student To disturb PHEMA of the water resistance of P HHM A containing an ultraviolet-rays interception agent, the quality of non-rubber, Hygroscopicity, flexibility, and pliability, when it is made to adhere on an outer skin. Other objects of the present invention will become clear from the following statements. PHEMA used in operation of the present invention consists of PHEMA of as [ the thermoplastic polymer substance of the essence top line which has a repeating unit of the above-mentioned formula (I), especially whose X of formula (I) are hydrogen ]. An "essence top line" is a line and means having Tg of 105 degreeC as it has it, although P HHMA is complete dissolution nature in the 50-50 weight mixture of ethanol and water. [ enough ] desirable -- this PHHMA -- at least -- about -- 50. OOO -- it has a weight average molecular weight of at least 100.000 still more desirably. The very desirable result was obtained when PHEMA which has a weight average molecular weight of 200. OOO at least was used. As the Abra Hamm's pointed out by the above-mentioned literature, PHHMA can polymerize to 1,000,000 and the weight average molecular weight beyond it. Although this PHEMA is usable to operation of the present invention, about -- the result in which more desirable The most of I HE M A which has a weight average molecular weight between 100.000~about 1 and OO0,000 is desirable to operation of the present invention -- about -- about [ 200. OOO~] -- it was obtained using PHHMA which has a weight average molecular weight of 400. OOO. To plasticize PHEMA so that it may become flexibility from un-plasticizing PHEMA, when it is made to adhere as a coat on arbitrary outer skins as indicated previously was desired in the field. However, before the present invention, when suitable for an outer skin, there was no literature which gives a statement suitable about manufacture of the effective prescription thing for makeup which contains PHHMA as a film-forming ingredient which brings about the coat of the pliability which copies out the pliability of the outer skin on essence. Although to introduce PHHMA into the prescription thing for water substrate makeup until now was desired, there was little information which leads to manufacture of the stable emulsion for water substrate makeup of oil / water type. How to make PHEMA as an ingredient in stable oil / water type emulsion which is flexibility moderately and can be used as cosmetics for providing the coat of pliability on the skin is explained below. The plasticization is performed exceeding the present invention only using PHEMA as a more flexible substance. It is because the fundamental characteristic is changed only as the improvement in which saying is insufficient as for flexibility is insufficient for the achievement of lotion processing of the skin which leaves a pleasant sensation moisture permeability [ P HHM A ] thin layer on the skin, using P HHMA effectively. On 0 essence target brought about by giving advanced pliability into PHEMA so that the coat may agree in the distortion and unevenness of pliability on the surface of the skin, when a pleasant sensation forms the coat containing PHEMA on the skin, The 0 present invention in which the PHEMA coat should have the pliability of the skin to which it is applied, and the pliability of levels, such as essence top Listen, PHHMA -- the following characteristic and * -- the surface top of that a coat can be made to adhere from the stable liquid phase, and genuine leather skin -- the feel of the good smooth skin of - feel -- To provide Easy permeation nature to the fine hole of that there are not tactile feeling and pliability with the good skin of a To sake, - greasiness, and oiliness, and - skin. - The quality of non-rubber rubs, lengthen and it is the characteristic, - combining with print resistance to the hair so that it may avoid making the hair agree in specific shape -- and - Attain the moisture resistance which combined with the permeability of air or moisture, and pliability which is characterized by making it effective stable oil / water type emulsion which has that the uniform plasticization coat characterized as alike can be made to adhere. Formation of the PHHMA thin film of the present invention on an outer skin is not measured easily. Since it adheres to this coat from the prescription thing for makeup, it adheres also to the makeup agent like oil, a surface-active agent, and a Supply temperature agent with it. The quality of a coat can only be measured from the characteristic given to the outer skin to which it was applied. The fact that the skin after processing is lower than the amount of moisture on the skin and that moisture evaporation loss (perspiration) owner Perilla frutescens (L.) Britton var. crispa (Thunb.) Decne. can be carried out, and the lotion public charges of long durability can be provided by other ingredients in cosmetics has supported firm belief that PHEMA exists as a coat on the skin. The excessive moisture kept on the skin carries out the operation which warms it, and it is the method of this softening the skin and smoothing. Generally it is admitted that PHHMA exists on account of the existence of PHHMA in a coat based on recognition of PHEMA these attributes and film-forming [ usual ] as some continuation coats which resist moisture permeation, and that PHEMA is uniformly distributed on the essence of On the film. As pointed out previously, many substances can be used for plasticizing PHHMA. When PHEMA was blended appropriately in the prescription thing for makeup and it combined with the plasticizer appropriately, elastic pliability P HHM A by which necessity is carried out to the makeup use like a makeup lotion could be acquired, but it was confirmed that it is not obtained. In plasticization of PHEMA, it starts and ranks next by selection of an active volatile solvent to PHEMA, and activity uses a solvent with low volatility low and graduated graduated to PHHMA. The solvent sum of PHEMA is the beginning of the plasticization. To PHEMA, an offensive solvent dissolves P HHMA and makes it the part of solution. Supposing such a substance tends to hold PHHMA as a solid coat, it will be used in the minimum quantity. However, supposing a solvent is volatility, the volatility to PHEMA is low, or in combination with the solvent of essence top fixity, it is abundant and can use it. Therefore, one adhesion of PHEMA plasticized with the solvent with the existing low volatility arises from the coat of the emulsion for makeup which adhered to the place where PHEMA is held liquefied by existence of a more volatile solvent as it depends and a volatile solvent evaporates. When a solvent with low volatility is dissolved easily more than needed by water, other solvents which cannot receive the easy solubilization by water easily and whose volatility is still lower can be made to exist at the time of combination of PHEMA to the aqueous phase of emulsion. The solvent sum for forming emulsion has the processing for using PHEMA as a film-forming substance effective in the prescription thing for makeup. In the present invention, the combination of the solvent covering the range from a volatile active solvent to a solvent with 1 low activity with low volatility (these can actually be called fixity by the standard of the present invention) is used as a plasticization ingredient. A term "volatility" and "fixity" are recognized as a relative term. So, a volatile solvent evaporates for convenience within 24 hours after the 10-mil coat made to adhere as a fluid on the outer skin which contains usual moisture under the ambient air temperature of 23 degreeC, and a normal pressure condition. A fixity solvent seems not to evaporate completely under these conditions. Selection of the solvent for generally making the aqueous phase containing PHHMA is explained in other places. However, it is enough to indicate that a plasticizer is a solvent to P HHMA in this portion. however, in many case, they may be the weak solvents which need an auxiliary solvent for validity -- if it says widely, desirable fixity plasticizers will be fatty series polyol, low-molecular quantity aliphatic polyether, and a nonionic surface-active agent. Fatty series polyols are 1.2-propylene glycol and 1.3-propylene glycol, They are the usually liquefied glycol and glycol ether like glycerin, a jig rim, triglyme, and tetraglyme, Karr Bittor (carbitol)■, other methyls, and those monoalkyl ether like ethyl end block ether. In order to form the amount ingredient of polymers, the polymer can make non-end block ether react to ethylene oxide to the shape not of wax but a still more liquefied grade. As other useful polyols, they are sorbitol, 1.2-butylene glycol, 1.2-hexylene glycol, glucose, fructose, sucrose, PEG-8, PEG-4, the Zypro pyrene glycol, and honey (honeyl is mentioned.). A non-ion surface-active agent contains the molecule portion which is hydrophilicity (sparse oiliness), and other molecule portions which are sparse oiliness (hydrophilicity). These portions become the foundation which determines those surface activity by those parent tree-oleophilic balance (HLB). Mr. W See Griffin's EmulsifierEvaluation By Water Absorption, Proc, ofScientific 5 ection of Toilet Good As5 ocia-tion, Vol, 6, the 43~50th page (December 5, 1946) (c, A, 41, p, IL33H) Please refer to it. In operation of the present invention, if it becomes, when [ when those HLB(s) are low (about 2 or less / for example, /) ] plasticizing PHEMA effectively, those validity is low. weaker [ when those HLB(s) are middle (for example, about 8~about 8), those validity at the time of plasticizing PHHMA is good, but ] in addition than the prescription thing for commercial makeup is expected -- however . It turned out that the nonionic surface-active agent which has high HLB (less than [ About eight or more / for example, / typically ] 15) is an outstanding plasticizer [ on operation of the present invention, and as opposed to PHEMA ]. A suitable desirable nonionic substance to use it as a non-volatile (solvent) plasticizer is an organic fatty series ether compound. These contain at least three ether groups into the portion of the molecule which gives sparse oiliness (hydrophilicity) to a surface-active agent at at least one general ether group. As for an ether group, it is desirable to be guided by alkoxyl-ization of the active hydrogen compound which gives oleophilicity (hydrophobicity) to a surface-active agent. A desirable alkoxyl-ized compound is guided from ethylene oxide and (or) propylene oxide. The outstanding alkoxyl-ized compound is guided from alkoxyl-ization of the alcohol (a fatty series and aromatic series) by the combination of an ethylene oxide independent or ethylene oxide, and 1.2-Brovylene oxide, and provides high HLB. As for The most, it is [ the oleophilic (hydrophobicity) portion of a nonionic surface-active agent molecule ] preferred to contain the fatty series portion which continues and contains at least six -CH(s)2- although Hexylene bridge construction is formed at least into structure. An active hydrogen compound desirable although these plasticizers are formed is fatty alcohol which contains less than about 24 carbon atoms in at least about eight general carbon atoms. fatty alcohol is a hydrogenation variety of fatty acid -- although kicked -- them -- Al Ken's carbonylation -- it is also compoundable according to the synthetic pathway besides Like by hydrogenation of the oxo compound following it, or this Al Ken's hydration. Other nonionic surface-active agents which can be used differ in the quality of the oleophilic portion of a molecule. it is not so strict as long as it has preferably high HLB of Intermediate, when selection of this portion has few surface-active agents -- oleophilic portions may be Aralkyl, Al Caleel, etc. in this way. it is possible to include various Supply temperature agent / leather prefecture softeners other than the alcohol characterized previously and a surface-active agent in the prescription thing for makeup of the present invention -- and -- as these examples -- for example . Mineral oil, Squalane, petrolatum, squalene, fine quality wax, hydrocarbon like paraffine, Lanolin alcohol, lanolin, acetylated lanolin alcohol, acetylated lanolin, Hydrogenation lanolin, hydroxylation lanolin, lanolin like lanolin acid isopropyl, and a derivative, All [ Dimethicone Koboli / a Dimethy corn, cyclomethicone and ], a phenyl Dimethy corn, The silicone like a Steroxydimethi corn, stearic acid, isostearic acid, Fatty acid cetyl alcohol like myristic acid, linoleic acid, and Resolor acid, Stearyl alcohol, cetearyl alcohol, myristyl alcohol, It is fatty alcohol like isostearyl alcohol, octyl dodeca Nord, etc., Myristic acid iso propylene, the Barh Myzin acid isopropyl, the Barh Myzin acid octyl, spermaceti wax (spermacell), oleic acid isodecyl, propylene glycol deer Brillate / deer plate. Glutamic-acid glucose, neo pentanoic acid isodecyl, neo pentanoic acid in stearyl, Myristic acid myristyl, jojoba oil, cetyl palmitate, hydroxy stearic acid octyl, Tori oleic acid sorbitan, stearic acid octyl, dioctyl adipate, Propionic acid Arachidil, stearic acid isocetyl, Brovylene glycol di pelargonate, Lactic acid myristyl, CI□-0 alcoholic benzoate, myristic acid Milles 3, octanoic acid cetearyl, Octadodecyl stearoyl stearate, glyceryl dilaurate, Propylene carbonate, PPG-2 myristyl ether propionate, Diisopropyl sebacate, the Barh Myzin acid octyl, a neopentyl glycol deer plate, A Diiso pro Bilberry rate, lactic acid Sept Iles, isostearic acid Decyl, Butyl stearate, propylene glycol isostearate, fatty acid ester like isostearic acid isopropyl, Sesame , sweet oil of almonds, Apocaudo , hydrogenation soybean oil, malt oil, capryl lactam / capric acid triglyceride, apricot kernel oil, safflower oil, palm oil, grape seed oil, coconut palm oil, mink oil, peach kernel oil, Xia oil, Sea turtle oil, sunflower seed oil, hydrogenation vegetable oil, olive oil, U.S. bran oil, castor oil, Corn oil, cocoa fat, hydrogenation coconut palm oil, glyceryl octanoate, Like triglyceride, such as cherry kernel oil, linseed oil, and soybean oil, hydrolysis animal protein, Soluble collagen, collagen, milk protein, collagen amino acid, Amino acid and polypeptide like hydrolysis elastin, elastin, elastin collagen complex, and serine 5 Grishin, proline, leucine, Tyrazine, tryptophan, aspartic acid, valine, Alanine, isoleucine, glutamic acid, soybean Protein, and keratin amino acid. An atomic submarine, lecithin, an aloe vera, mucopolysaccharide (or hydrolysis), Other additive agents , like soybean sterol, cholesterol, lactic acid or salt, PPG-10 Sept Iles ether, PPG-11 stearyl ether, the poly amino sugar condensation thing, egg oil, and PPG-3 myristyl ether are mentioned. That it is important for the present invention uses PHHMA as stable cosmetics, and Acceptance is development (including a constituent and a method) of an emulsion system which makes it possible to provide as emulsion put in and made. As a result, especially the constituent of the present invention recognizes existence of an emulsifier requirements in adhesion of a PHEMA content coat. As the example of a typical emulsifier. Stearic acid salt of ammonium, potassium, and sodium, ammonium, Myristic acid salt of the pulmitic acid salt of potassium and sodium, ammonium, potassium, and sodium, Lauric acid salt of ammonium, potassium, and sodium, ammonium, Oleic acid salt of isostearic acid of potassium and sodium, ammonium, potassium, and sodium, Aluminium stearate, stearic acid magnesium, beeswax/Borax, The soap like lanolin acid soap, glyceryl stearate, stearic acid sorbitan, Polysorbate 80, polysorbate 65, polysorbate 60, polysorbate 40, polysorbate 20, stearic acid Grignole, PEG-2 stearate, PEG-1o stearate, PEG-30 stearate, PE040 stearate, PEG-1oo stearate, PEG-150 stearate, PEG-1000-stearate, Barh Myzin acid sorbitan, propylene glycol stearate, PEG25 propylene-glycol stearate, hydrogenation Soy glyceride, Recently gym glyceride (wheat germ glyceride), and palm Oil glyceride, Oleic acid glyceryl, lauric acid glyceryl, oleic acid sorbitan, PEG-12 distearate 5, polyglyceryl 10-Decaoret, PEG-8 oleate, Megu recess 20 sesquistearate, Ester like methyl glucose sesquistearate, cetyl alcohol, Stearyl alcohol, fatty alcohol like cetearyl alcohol, Carbomer (carbomer) 934■ (and salt), carbomer 940■ (and salt), The water-soluble polymer like carbomer 941■ (and salt), Xan tongue rubber, cell loss gum, polyvinyl pyrrolidone, carageenan, hydroxyethyl cellulose, gelatin, polyacrylamide, and hydroxypropyl methylcellulose, Lanolin alcohol, cholesterol, soybean sterol, hydrogenation lanolin, A Ranoste roll, the sterol like hydroxylation lanolin, Steareth 2, Stare Squirre- 20, ceteareth 5, ceteareth 20 in steareth 20, Ceres 10, laureth 3, laureth 3, laureth 23, Kosesu 6, Oleth 10, Oleth 20, octyl Dobins=20, Colet Xu 24, DihydroKoliseu 15, PEG10 soybean sterol, PEG-25 soybean sterol, Methyl guru Seth- 20, a PEG-5 soybean sprawl, PEG-5 Penta erythritol, PEG-40 castor oil, PEG-3 myristyl ether, ether like PEG-15 stearyl ether, Sodium lauryl sulfate, triethanol ammonium lauryl sulfate, Jethanol ammonium lauryl sulfate, sodium Cetyl sulfate, It is an anionic surface-active agent like Dioctyl sodium sulfosuccinate, disodium mono-cocamide sulfosuccinate, a sodium isostearyl 2-Rakuchi rate, sodium lauryl sulfate, sodium cocoyl Ithionate, etc. Oleyl solid in, sodium Lauryminodiprobionate, sodium C1~C, the both sexes surface-active agent like alkoxy propyl imino dipropionate, Stearemidji ethyl amine Phospho Fet, Cetrimonium bromide, Steal Aliconium chloride, the cationic surface-active agent like PEG-15 cocoamine, And lecithin, magnesium silicate aluminum, micro crystallite wax, kaolin, a Oshke light, Ceret Singh, Raul amide DEA, Stale amide DEA, 18 hecto of quarter Nium- light, casein acid sodium gelatin. Can be cited As indicated previously, to the 0 present invention which many emulsifiers provide with Supply temperature and (or) skin softening nature, the double function about many additive agents is accepted. A result with a certain kind of preferred emulsifier is brought about so that it may emphasize below. It has planned for the present invention to include other various additive agents in order to introduce special character. In operation of the present invention, to include a corrosive agent, an antioxidant, stabilizer, UV absorbent, vitamin, an outrider substance, a skin barrier, hormone, a vegetable extract, and the typical additive agent like essential fatty acid is not that it is exceptional. As an example of this additional ingredient, it is at the kind of corrosive agent, Methyl paraben, propyl paraben, quaternium 15, iso Dazolidinyl urea, Butyl paraben, dehydroacetic acid (or salt), sorbic acid, sodium Pyrithione, Ethyl paraben, benzoic acid (or salt), formaldehyde, DMDM hydantoin, Benzoyl paraben, triclosan, guru Taral, chlorhexidine Glico Nate, Methyliso thiazolinone, 2-Brom nitril propane 1, 3-Diol, At the kind of antioxidants, such as a 0-Cymene- 5-oar, and stabilizer, it is BHA, Tocopherol (or acetate), BHT, ascorbic acid (or palmitate), EDTA (and salt), propyl gallate, benzophenone 2-benzophenone 4, dilauryl thiodipropionate, etc., At the kind of UV absorbent, they are octyl Dimethyl PABA and PABA and urocanic acid, By the kind of Vitan, such as benzophenone 2, benzophenone 5, benzophenone 9, and ethyl dihydroxy PABA, and Vitan outrider substance, Retinal (or palmitate) (vitamin A), tocopherol (or acetate) (vitamin E), At the kind of skin barriers, such as Aranjaine calcium punt Chinatown, pan tenor (vitamin B outrider substance), erotic calciferol (vitamin D), and Pante nil ethyl ether, they are dimethicone, a Allan fin, etc., At the kind of hormone, it is in the kind of vegetable extracts, such as pregnenolone succinate, Camomile, rosemary, Sime, common marigold oil, friend power oil, The Hofler Wa - Extract, a Curie extract, a Linis extract, the Matricaria extract, a carrot extract, a gentian extract, a palm mint extract, Sandwiched ° Shin extract, a pine needle extract, a scouring rush extract, the Papaver rhoeas extract, etc., Linoleic acid , is mentioned in the kind of essential fatty acid. As other various ingredients for the constituent for makeup of the present invention, Ribonucleic acid (and salt), oats Dress, methyl nicotinate, nicotinic acid hexyl, Royal jelly, a Allant in acetylmethyl Onin cell extract, mineral salt, The poly amino sugar condensation thing, benzyl alcohol, an aluminum Chlor hydrate, Salicylic acid, Dexterity yeast, Alland Inn polygalacturonic acid, adenosine disodium triphosphate, almond Powered by Translate, oatmeal rye wheat Dress, a corn meal, Erag powder, walnut Shell fancy, an apricot kind (pulverization), etc. are mentioned. The above-mentioned ingredient is given into the emulsion for makeup according to standard operation. If it says about the object of the present invention for forming the oil / water emulsion for makeup containing an ultraviolet-rays interception agent, one or more sorts in UV absorbent can be added to the prescription thing for makeup in the quantity of the range to about 20% of the weight of total prescription thing weight. However, in the case of being typical, the quantity does not exceed about 12 % of the weight on the same standard, and does not exceed about 10 % of the weight preferably. UV absorbent is included into the oil phase of the oil / water type emulsion of the present invention. The quantity of an ultraviolet-rays interception agent (UV absorbent) is influenced by the Samprote cushion factor (SPF) which the emulsion for makeup is expected. Please refer to Arch besides Mr. Sayer's Cosmeticsand Toiletries, Vol, 96, the 49th page (September, 1981), and Mr. Sayer, Dermstol, 115, and the 46~49th page (1979). carrying out the oil / water type emulsion for makeup of the present invention based on the total prescription thing weight of emulsion -- typical -- about 50~ -- about 90% of the weight of water -- preferably 65~80% of the weight of water is contained. The feature of the oil / water type emulsion for makeup of the present invention makes it requirements for them to be the stability between the minimum periods for at least two years. Stable oil / water type emulsion of the present invention contain PHHMA of 2.0 % of the weight of abbreviation 0.05~abbreviation based on the gross weight of emulsion. the standard that the quantity of PHEMA in emulsion is the same in the desirable example of the present invention -- about -- 0.1~about 1.5 -- still more desirable about 0.3~ -- it is about 13 % of the weight. The ingredient in stable oil / water type emulsion of the present invention contains oil, moisturizer (moisture absorption agent), and emulsifier other than PHHMA. These substances and I tl V, and M A constitute an important ingredient, when using; mountain / water type emulsion for makeup as a skin lotion. PHHMA is difficult to Konan-ize in a useful oil phase moderately for a makeup use, and since it is moreover insoluble in water nature, the solvent sum of it is carried out for easy combination in a prescription thing. Typically, if an oil phase has little weight of emulsion, it will occupy 5 % of the weight of Chicks, preferably 15 % of the weight of abbreviation 7~abbreviation of the weight of emulsion. The remainder is an aqueous phase. As indicated previously, the solvent sum of PHEMA is the beginning of the plasticization. P The solvent sum of HE M A is the beginning of the combination in an emulsion prescription thing. Plasticization of PHEMA is related with the solvent sum of PHEMA for the explanation of 6 following about coat+1'J Sex and coat performance of P HE M A to make the emulsion of this investigation. The useful solvent for PHEMA is an organic fluid used in combination with independent or water. Many of solvents which may cross this f8 agent to the range to a water-dispersion thing from a water-soluble thing (It becomes an effective solvent, although it is not effective in ialpha Germany as 8 Deleting, however when the stronger solvent to PHEMA uses it as a part of solvent combination used as a part of solvent combination.) In this case, the auxiliary solvent of this strong one can be called the common solvent of the solvent of PHEMA and the weaker one. The solvent of the active higher one is water solubility. With The most, six, it is and the solvent which are a Powerful active solvent and a typical more volatile solvent is low-grade alkanol containing the carbon atom of four 2~abbreviation like ethanol, an n-proper tool, an iso proper tool, an n-proper tool, n-butanol, the second butanol, and in butanol. methanol is an effective solvent -- although kicked -- it -- toxicity -- a palm -- it should be avoided from the upper reason. Although these alkanol plasticizes PHEMA in a small quantity, they are not used on account of [ the ] volatile as a permanent plasticizer. - They are chosen as Mu as a volatile solvent ingredient, when mixing PHHMA and making it an emulsion prescription thing. PHEMA -- the inside of a low-grade alkanol water mixture -- soluble is there -- 0 by which things are known, for example, PHEMA, can be dissolved into a water-ethanol mixture to water (80%), and 80 / 20 weight mixture of ethanol (20%). A small amount of water can also be used under useful rather than it. In this field of the present invention, alkanol can be called combining water and PHHMA. (The Like fatty series polyol, for example, 1.2-propylene glycol, of glycol and glycol ether of usually liquefied as other solvents useful as a plasticizer) 1.3-propylene glycol, glycerin, a jig rim, triglyme, tetraglyme, these monoalkyl ether, for example, car Vitols■(carbitols) ■, other methyls, ethyl end block ether, etc. are mentioned. In order to form the amount of polymers, the polymer can make non-end block ether react to ethylene oxide to the shape not of wax but a still more liquefied grade. Desirable polyol is 1.2-propylene glycol. These solvents are effective plasticizers to PHEMA, not only when solubilizing PHEMA, but when assisting final plasticization of the PHHMA coat to which it adhered on the outer skin. These are a fixity solvent / plasticizer. These are All low-grade alkanol soluble, and can use low-grade alkanol for so tying up those solubility or rates of solution to water and PHHMA. Since polyol and polyether have large solubility in underwater rather than PHHMA, it can also use for their raising the solubility of underwater PHHMA. It is based on the high solvent power to PHHMA, its relatively low volatility, its significant hygroscopicity, and its desirable toxicological character that 1.2-propylene glycol is preferred. So, the combination of low-grade alkanol and polyol can also be used under useful. By desirable prescription of PHEMA to emulsion, a solvent / plasticizer ingredient is actually used for raising the solubility of PHEMA to the inside of a water phase through the result attained by low-grade alkanol, the polyol, or the ether ingredient of a solvent system. The kind of the last of a solvent/plasticizer is a nonionic surface-active agent which has both a molecule oleophilic (hydrophobicity) portion and a molecule sparse oiliness (hydrophilicity) portion. These portions become the foundation which determines those surface activity by those oleophilic-hydrophilicity balance (HLB) previously at indication To deceive. Those validity at the time of plasticizing PHHMA in rate of Fuca in operation of the present invention, supposing those HLB(s) are that it is low (about 2 or less [ for example, ]) is low. When those HLB(s) are middle (for example, about 4~about 8), in addition, those validity at the time of plasticizing PHHMA is lower than what the prescription thing for commercial makeup is expected, although it is good. However, it turned out that the nonionic surface-active agent which has high HLB (15 or less [ About eight or more / for example, / typically ]) is an outstanding plasticizer [ on operation of the present invention, and as opposed to PHEMA ]. The most of a nonionic substance is weak among the solvents to PHEMA. Generally, they are used in combination with other more active solvents like low-grade alkanol, and polyol/polyether. Although these may be solvents with weak The most, they achieve a plurality of functions. Generally, The most of volatility is [ them ] low among a solvent/plasticizer, and they serve to Guest-ize the oil phase to which it adhered into the coat, and PHHMA to which it adhered. A suitable desirable nonionic substance to use it as a fixity solvent / a plasticizer is an organic fatty series ether compound. They contain at least three ether groups into the portion of the molecule which gives hydrophobicity (hydrophilicity) to 9 and a surface-active agent at at least one general ether group. As for an ether group, it is desirable to be guided by alkoxyl-ization of the active hydrogen compound which gives oleophilicity (hydrophobicity) to a surface-active agent. A desirable alkoxyl-ized compound is guided from ethylene oxide and (or) propylene oxide. The outstanding alkoxyl-ized compound is guided from alkoxyl-ization of the alcohol (a fatty series and aromatic series) by the combination of an ethylene oxide independent or ethylene oxide, and 1.2-propylene oxide, and provides high HL B. As for The most, in order to form Hexylene bridge construction at least into structure, it is [ the oleophilic (hydrophobicity) portion of a nonionic surface-active agent molecule ] preferred that the fatty series portion which continues and contains at least six -CH(s) and - is included. The active hydrogen compounds with preferred forming these solvents/plasticizers are at least about eight carbon atoms and fatty alcohol which generally contains the carbon atom of about 24 ends. fatty alcohol is a hydrogenation variety of fatty acid -- although kicked -- them -- Al Ken's carbonylation -- it is also compoundable according to the synthetic pathway besides Like by hydrogenation of the oxo compound following it, or this Al Ken's hydration. Other nonionic surface-active agents which can be used differ in the quality of the oleophilic portion of a molecule. Selection of this portion is not so strict as long as a surface-active agent has middle, preferably high HL B at least. In this way, oleophilic portions may be Aralkyl, alkanol, etc. As indicated previously, the emulsion prescription thing for makeup of the present invention is mainly water. Water constitutes the continuous phase of emulsion and an oil phase constitutes the discontinuous phase of emulsion. An aqueous phase is not only water. This contains the solvent/plasticizer to PHEMA and PHEMA. The emulsion prescription thing for makeup of the present invention constructs the a large number phase of each ingredient which leaves by one or more oil phases, and includes one or more water phases after that, is Fit and is manufactured. It is prepared separately, subsequently it is mixed and each phase generates request emulsion. Mixture with a phase and a phase is performed using sufficient churning for that of raw To give up in the degree of mixing to mean. The oil phase prepared separately is often formed in General by mixing at the temperature which had the oil phase ingredient raised. The raised temperature is needed for To(ing) compatibility to the amount of substance which makes a solid substance usually Pickling and has Limit and the compatibility by which the law was carried out at a temperature lower than it raw, and applying it to it. The raised temperature exceeds about 35 degreeC, and when typical, the raised temperature is often within the limits of 0 degree of Strike C~about 100-degreeC. However, when the most, it turned out that the raised temperature is within the limits of 0 degree of Strike C~about 85-degreeC. The oil phase formed by making it such ranks next, and in order to form either oil / water type emulsion or oil / Awed emulsion, it is mixable with water. if I will form what kind of emulsion -- Chi -- it is not important. Even if the emulsification inversion of water / type emulsion is required for saying in the end or the last process of Role, it will be because the last finish emulsion is oil / water type emulsion. P Typically, HE M A is given into an aqueous phase in combination with at least 1 portions of a solvent and a plasticizer. P It is preferred to mix at least 1 portions of the organic solvent and a plasticizer with P HE M'A with sufficient churning to dissolve HHM A and form solution. This mixture is mixable into many of water phases with sufficient churning to form solution. The feature of a phase and desired emulsification Cropping with a separate prescription thing is forming a water phase separately with the emulsifier to a whole milk-ized prescription thing. The phase means [ term / "it forms separately" ] that the water phase containing an oil phase and P HE M A is separate. The separate phase containing an emulsifier can make it mix with an oil phase in the first stage, in order to form either oil / water type emulsion or oil / water type emulsion as middle emulsion. After an appropriate time, many of aqueous phases are mixed by Kono middle emulsion, and the last emulsion is generated. In the performance of the present invention, it turned out that it is very important for selection of an emulsifier. In the case of a certain kind of prescription thing, it was confirmed that the selection of an emulsifier can bring about real Agari profit in respect of stability and performance to the performance of the emulsion for makeup obtained. The desirable emulsifier in operation of the present invention is ammonium stearate, Stearic acid triethanol ammonium, sodium lauryl sulfate, Lauryl sulfate triethanol ammonium, Russ Lil sulfuric acid Jethanol ammonium, It consists of an anionic surface-active agent like Sept Iles sodium sulfate, Dioctyl sodium sulfosuccinate, disodium mono-cocamide sulfosuccinate, in stearyl 2-sodium lactate, cetearyl sodium sulfate, and cocoyl iso thionic acid sodium. A desirable emulsifier is the ammonium salt of what contains CI□ in a long-chain-fatty-acid type target in a carbon chain. At the most -- a desirable thing -- the inside of rust -- c tae -- the ammonium salt of the long chain fatty acid which contains CI6 * preferably, For example, it is the ammonium stearate formed by the on-site reaction of stearic acid (typically given into an oil phase), and ammonium hydroxide (typically given into a water phase). It actually became clear that it was when ammonium stearate is special. It became clear that this was the outstanding emulsifier. It says because this forms and maintains stable emulsion to an altitude stable to heating of about 40 degreeC over six months or more. The surface-active agent characteristic provided with ammonium stearate because [ high / volatile ] accompanies secession of Anni Ham when emulsion is applied on the skin, After the makeup coat generated on the skin uses PHEMA as a coat, it is changed as enough to have film-forming [ optimal on account of the rapid insolubilization ]. It becomes good this contributing and carrying out a deer to the moisture permeability of the coat obtained, and a coat coming to keep much moisture on an outer skin, and protecting an outer skin from a foreign substance element. Other features are that the transudation according [ the plasticizer in a coat ] to the influence of moisture becomes low. Use of the ammonium hydroxide combined with stearic acid hangs down generation of graceful emulsion six on the makeup which rubs and does not have the omission characteristic, and is To. The quantity of the solvent/plasticizer in emulsion is not so strict. All the quantity which provides the profits of the present invention is usable. Typically, in the emulsion of the present invention, it is desirable to use a volatile solvent/plasticizer of one at least about 3 times the weight of this to the weight of P HE M A. Usually, the amount of a volatile solvent/plasticizer used is within the limits of the 15 times as many abbreviation 4~abbreviation of the weight of PHHMA in emulsion. The concentration of a solvent/plasticizer with low volatility is changed according to the quantity of P HHM A which exists in emulsion based on the tactile feeling effect for which the emulsion for makeup is asked, when supplying the skin. For example, a polyol solvent / plasticizer may exist from about 10 ffiffi(s)% within the limits of about 20 times of the weight of PHHMA in emulsion, On the other hand, a nonionic surface-active agent solvent / plasticizer is about 10 (it may be within the limits of @.) of the weight of PHHMA in [ abbreviation 0.01!ffi% to ] emulsion. These values can be adjusted to the upper and lower sides of these Value of, in order to acquire the special makeup effect. It illustrated that the mode at the time of forming oil / water type emulsion by an experimental study to the capability of p HIs M A which Formation suitable definite period stable emulsion for the makeup object J [5 times was important. The following table I illustrates commercially the Directionality of the typical conventional technology for making the makeup lotion products which Acceptance puts in and are made (in the case of these, PHHMA is used). Process processing of the phase was a 3 Aikata style for generating emulsion using typical addition of the aqueous phase to oil phase emulsion. It was heated by 71 degreeC in order for phase A to carry out raw [ of the mixture of the ingredient in a phase ] in each case. An aqueous phase of phase B used into emulsion for makeup is typical. And an antiseptic, a Supply temperature agent, and a gelling agent are contained. Although it turned out that the small ball of PIIHMA precipitates from emulsion to an each side, this shows the instability of emulsion. O 00 Acoa'> Crack Rich 1 ) -- Off N A 1A1\ Various )L All the , Floodgate A sigma Obligation Emulsion was made using the typical aqueous phase added according to the oil phase emulsion manufacture procedures previously indicated about Example 1~4. Although the output of Examples 5 and 6 glanced and it seemed that commerce top Acceptance is a lotion put in and made, however when seen strictly, they showed that PIEMA was being suspended in emulsion, respectively. Although the small ball of PHEMA existed, when the emulsion prescription thing was rubbed and lengthened on the skin, they became the gum substance coat which became hard on the outer skin, respectively. As indicated previously, low-grade alkanol is an effective solvent which serves to combine other plasticizers to PHEMA (coupling). Some experiments which illustrate that propylene glycol as using low-grade alkanol like ethanol and an auxiliary solvent and many surface-active agents are used for the following table nl as a binding material for solubilizing PIEMA in a water system are shown. P) IEMA was used at 8 % of the weight based on the research findings from other solubility tests. The experiment operations used in Example 7~11 shown in the following table ■ are the following process, 1, and solubilizing PHEMA in ethanol first, adding 1.2-propylene glycol subsequently, and forming homogeneous solution, It included adding gradually dissolving 2 and a surface-active agent ingredient underwater, 3, and the solution from above 2 under Takeshi who does not develop from above 1 to solution. 2 n It turned out that a solvent/plasticizer must be added to water, otherwise transparent solution is not obtained. Stable emulsion cannot be obtained to the place name excluding Etah Knoll and 1.2-propylene glycol from the above-mentioned prescription thing. Table IV is AlsoC which illustrates preparing a-izing Cake lotion prescription thing as phase C in this case -- by supplying PHEMA ?g liquid from a common aqueous phase. Tolophi Yu) Steller's sea lion 1 A 1 A Bebe L ) The prescription thing of Table ■ was made into emulsion by the following two methods. 1, and typical oil / water type emulsion:phase Bl were added to phase A -- it ranked next zero, phase B-2 was added to this mixed phase A and phase Bl, and they were set to suitable pH of about 6 O. Then, phases C and D were added one by one. The oil phase was set to 71 degreeC and it mixed with other phases using the moderate shear mixing according [ on the temperature and ] to a standard propeller blade mixer. 2, and typical oil / water type emulsion:phase B1 were added to phase A -- it ranked next eight and added phase C to this mixed phase A and phase Bl -- it ranked next zero and set this solution to suitable pH by addition of phase B-2 -- it ranked next zero and introduced Neat. Oil phase 71 degreeC was used and it mixed with other phases using the moderate shear mixing according [ on this temperature and ] to a standard propeller blade mixer. The result of these two methods used to the prescription thing of Example 12 was as following. Acceptance put A and the above-mentioned operation 1 into the commercial target on a borderline, and they brought about the possible product. PHHMA is slight when a lotion is applied to the skin -- it rubbed and omission was obtained. According to the experimental study, it turned out that the addition speed of phase C is too quick, but this has suggested that correlation is between the speed at the time of mixing performance, emulsification speed, i.e., an oil phase, and an aqueous phase. The product which thin Acceptance in which a PIEMA small ball exists puts in B and the above-mentioned operation 2, and is not made was brought about. According to research, it turned out that the pH control in the end of operation is needed for stabilizing PIEMA in an aqueous phase. Table V illustrates the denaturation of the prescription thing of the above-mentioned formula V by replacing triethanol amine by stearyl pyridinium chloride. > To sell Mum 1, Fu k V 1 A 1 A O District ° A, 1 L * '> It passes. The operation used to Example 13 was the operation which used stearyl pyridinium chloride for making emulsion to Example 12 except for having added as a part of phase B. The stearyl pyridinium chloride of some levels was also studied. The prescription thing of Example 13 found viscous past To. Although emulsion was stable in the first stage, separation arose in - night. Two table vI where it turned out that the correlation on performance is generally between selection and the prescription thing of an emulsifier so that it might be Prediction(ed), Addition of the glycerin for judging combination of silicone 200 (poly dimethylsiloxane) for raising the experiment at the time of using cetearyl sodium sulfate which is other emulsifiers, and the graceful nature of makeup, and the influence which it has on moistness is illustrated. These prescription things have the oil phase (A) thinned for reducing viscosity, and the quantity of PHHMA in the prescription thing of Examples 15 and 16 decreased. 2S ■ = > It passes and is ■. delta A Workers sigma 1 ''iJO low 0DE-: I: Truth To of rising Mouth To 11 A tea ceremony Q Driving axis 0 Sir Black snap -000cI:1 cQ N A Bird Rich 1 ) -- all 1-.1-, Si 1 A 11- O What Ward A L ^ The operation for making the emulsion of Example 14~16 was the same as operation 1 used in the above-mentioned table ■. According to the researches of other as 12 with zero same example which added phase C very slowly, in these examples, it turned out in the last prescription thing that the quantity of BRIJ78 can decrease to 0.02% of the weight. This helped to avoid Violence between mixtures of emulsion. The prescription thing of example of Like 14 prepared in the top brought about the lotion consider that is a product which commerce top Acceptance puts in and is made. PHEMA rubbed the lotion of Example 14 on the skin, and it did not cause omission. When saying about Example 15, silicone is PIEMA and non-compatibility and it became clear that at least 1 portion of PIEMA was settled. Re-prescription will be needed for combining the silicone which starts into this kind of lotion prescription thing. When saying about Example 16, glycerin is not fully compatibility in the solvent system of a prescription thing, therefore it is PIIEMA and non-compatibility and settled at least 1 portion of PIIEMA. As pointed out previously, it became clear that the ammonium stearate formed by the on-site reaction of ammonium hydroxide and stearic acid was a unique emulsifier. Primary table ■ that brings about the emulsion stability which helped for the volatility of an ammonium group to reveal the optimal PHEMA coat organization potency, and was excellent in the salt to this These examples containing the prescription thing about Examples 17 and 18 illustrate use of the ammonium hydroxide as an emulsifier, and stearic acid, and use of PIEMA of various levels. cr+ See. 5 Translate 8 ) -- all Steller's sea lion Si 1) s+ D Bebe A L -- all (0111 %J (Immediately)) Grass A Black A (1) mountain Black material @P A tip The following example illustrates the ultraviolet-rays interception agent content prescription thing included by the present invention. N The operation used in Examples 17.18 and 19 is as following. The weight of each ingredient of 1 and phase A was weighed, and it put into the suitable beaker to heat [ and ] to 160"F (71'C). The weight of each ingredient of 2 and phase Bl was weighed, and it put into the suitable beaker to heat [ and ] under 180 (71'C). Ammonium hydroxide 20ii dish % solution for 3 and phase B-2 was prepared separately. This was not heated. The weight of each ingredient of 4 and phase C1 was weighed, and it heated at 100 degrees F (38degreeC). The weight of each ingredient of 5 and phase C2 was weighed, and it mixed by carrying out as following in the suitable container. (a) 1.2-propylene Gut call was added to ethanol (ETDH), and the mixture was agitated. (b) PHEM^ was mixed in ETOII / propylene glycol solution under Takeshi who does not do high by a Rheydt Nin (Lightnin) type mixer. Mixture was continued until it added phase C1 gradually at phase C2 under 6 and Takeshi that does not do high and the mixture became uniform. At this process, it did not heat at all intentionally. 7 and phases A and Bl were heated at 160 degrees F (71'C) -- mixture was continued until it ranked next zero, and it added phase Bl to phase A gradually and it became uniform. Phase B-2 was added to the mixture of 8, phase A, and phase Bl, and emulsion was made. Mixture was continued until emulsion looked uniform. 9 and mixed phase C were heated to 100''F (38degreeC). When forming emulsion from the combination of 10, phase B-2, and the mixture of phases A and B1, mixed phase C was added at most under moderate churning at the emulsion by the flow of 6 m 12 / part / 1,000mbeta end products. When addition of 11 and phase C was completed, Neat was added to the emulsion. Churning was continued until 12 and emulsion reached room temperature (ambient air temperature, about 23degreeC). 13 Finish emulsion had p H of 5.8~6.4 within the limits. Example 17 contained 0.5% of the weight of P112MA. The emulsion of Example 17 was the good emulsion for makeup, and when it was applied to the skin as a lotion, it was rubbed, and it did not show omission or gummous at all. According to the promotion storage examination, it was shown that this emulsion keeps that characteristic over six months or more at the temperature under 100 (38degreeC). Example 18 contained PIIHMA of the 122-fold circle. This emulsion brought about the lotion which Acceptance puts in as cosmetics and is made. however, this lotion (emulsion) is few at the time of application on the skin -- it rubbed and omission nature was shown. On the promotion storage condition for 2~3 months, some of PIIEMA(s) precipitated by 40 degreeC. The ultraviolet-rays interception agent content lotion was designed to provide at least 10 SPF. This lotion had all the useful features of the lotion of Example 17.
Every citation, both ways
| Document | Relation | Office | Cited during |
|---|---|---|---|
| US3697643A | Cites | United States of America | Search report |
17 members in 10 offices
Priority claims6
| Document | Office | Kind | Date |
|---|---|---|---|
| 23560188 | United States of America | A | |
| 23563088 | United States of America | A | |
| 23605388 | United States of America | A | |
| 235601 | United States of America | – | – |
| 235630 | United States of America | – | – |
| 236053 | United States of America | – | – |
Members17
| Document | Office | Kind | |
|---|---|---|---|
| US4883659A | United States of America | A | |
| EP0356196A2 | European Patent Office (EPO) | A2 | |
| AU4025089A | Australia | A | |
| IL91422D0 | Israel | D0 | |
| ZA896460B | South Africa | B | |
| JPH02167347AThis record | Japan | A | |
| EP0356196A3 | European Patent Office (EPO) | A3 | |
| US5039516A | United States of America | A | |
| AU625678B2 | Australia | B2 | |
| EP0356196B1 | European Patent Office (EPO) | B1 | |
| AT96305T | Austria | T | |
| DE68910230D1 | Germany | D1 | |
| DE68910230T2 | Germany | T2 | |
| ES2059774T3 | Spain | T3 | |
| IL91422A | Israel | A | |
| CA1340619C | Canada | C | |
| JP3162690B2 | Japan | B2 |
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Numbers
- Publication
- 2-167347
- Application
- 1216178
Titles2
- Japanese
- 【発明の名称】化粧用配合物
- English
- COSMETIC MIXTURE
Classification
- CPC, 3
- A61Q19/00
- A61K8/8152
- A61Q17/04
- IPC, 13
- A61K8 06
- A61K8 34
- A61K8 36
- A61K8 39
- A61K8 81
- A61K8 72
- A61K8 92
- A61Q17 04
- A61Q19 00
- B01J13 00
- C08J5 18
- C08L33 04
- C08L33 14