JP2010143918A

Method for coloring or lightening human keratinous fiber by using anhydrous composition and monoethanolamine/basic amino acid mixture, and device appropriate therefor

Abstract

Problem to be solved.To provide an anhydrous composition (A) containing one or more fatty substances and one or more surfactants, monoethanolamine, and a composition containing one or more basic amino acids. The present invention relates to a method for dyeing or lightening human keratin fibers using a substance (B) and a composition (C) containing one or more oxidizing agents. When the method is a dyeing method, the anhydrous composition (A) does not contain organic amines and the composition (B) contains one or more oxidative dyes and / or direct dyes. According to the present invention, one of the compartments contains the above-mentioned anhydrous composition for cosmetics (A), another compartment contains the above-mentioned composition (B), and the last one contains the above-mentioned composition (B). With respect to a multi-compartment device containing the oxidation composition (C). [Selection diagram] None

JP2010143918A, drawing sheet 1 — Sheet 1 of 26

Term

Projected expiry 18 December 2029.

15 claims: 6 independent, 9 dependent

1
ヒトのケラチン繊維を着色または明色化するための、以下:a)1種または複数の脂肪性物質および1種または複数の界面活性剤を含有する無水組成物(A)、 b)モノエタノールアミンおよび1種または複数の塩基性アミノ酸を含有する組成物(B) c)1種または複数の酸化剤を含有する組成物(C) を使用する方法であって、方法が染色方法であるとき、無水組成物(A)は、有機アミンを含有せず、組成物(B)は1種または複数の酸化染料および/または直接染料を含有する方法。
2
脂肪性物質が、好ましくは、C 6 ~C 16 低級アルカン、植物、鉱物または合成由来の非シリコーン油、脂肪アルコール、脂肪酸および/または脂肪アルコールのエステル、ならびにシリコーンから選択されることを特徴とする、請求項1に記載の方法。
3
脂肪性物質の含有量が、無水組成物(A)の重量に対して、10重量%から99重量%、好ましくは20重量%から90重量%、より特定すれば、25重量%から80重量%であることを特徴とする、請求項1または2に記載の方法。
4
無水組成物(A)が、少なくとも1つの非イオン性界面活性剤、より特定すれば、モノオキシアルキレン化またはポリオキシアルキレン化された、モノグリセロール化またはポリグリセロール化された非イオン性界面活性剤から選択される非イオン性界面活性剤を含有することを特徴とする、請求項1から3のいずれか一項に記載の方法。
5
界面活性剤の含有量が、無水組成物(A)の重量に対して、0.1重量%から50重量%、好ましくは、0.5重量%から30重量%であることを特徴とする、請求項4に記載の方法。
6
塩基性アミノ酸が以下の式(I):[式中、Rは、以下: から選択される基を表す] の化合物から選択されることを特徴とする、請求項1から5のいずれか一項に記載の方法。
7
塩基性アミノ酸が、アルギニン、ヒスチジンおよびリジン、またはそれらの混合物から選択されることを特徴とする、請求項6に記載の方法。
8
モノエタノールアミンの含有量が、組成物(B)の重量に対して、0.1重量%から40重量%、好ましくは、0.5重量%から20重量%であることを特徴とする、請求項1から7のいずれか一項に記載の方法。
9
塩基性アミノ酸の含有量が、組成物(B)の重量に対して、0.1重量%から40重量%、好ましくは、0.5重量%から20重量%であることを特徴とする、請求項1から8のいずれか一項に記載の方法。
10
モノエタノールアミン/塩基性アミノ酸の重量比が0.1から10、好ましくは、0.3から10、そしてさらに優先的には1から5であることを特徴とする、請求項1から9のいずれか一項に記載の方法。
11
使用時に組成物(A)、(B)および(C)をその場で混合することにより得られる組成物をケラチン繊維に適用することを特徴とする、請求項1から10のいずれか一項に記載の方法。
12
組成物(A)、(B)および(C)を、好ましくは、組成物(A)、次いで(B)、その次に(C)の順または組成物(B)、次いで(A)、その次に(C)の順で、合間にすすぎをすることなく、連続的にケラチン繊維に適用することを特徴とする、請求項1から11のいずれか一項に記載の方法。
13
組成物(C)、次いで組成物(A)および(B)から得られる混合物を、合間にすすぎをすることなく、連続的にケラチン繊維に適用することを特徴とする、請求項1から12のいずれか一項に記載の方法。
14
組成物(A)+(B)/(C)の量の重量比R1および組成物(A)/(B)の量の重量比R2が0.1から10、好ましくは、0.3から3であることを特徴とする、請求項1から13のいずれか一項に記載の方法。
15
第1の区画に、請求項1から5のいずれか一項に規定の無水組成物(A)を、第2の区画に請求項1または6から10のいずれか一項に規定の組成物(B)を、第3の区画に1種または複数の酸化材を含有する水性組成物を備える多区画デバイス。

Independent claims15

51 paragraphs, as filed

The present invention comprises an anhydrous composition (A) containing one or more aliphatic substances and one or more surfactants, a monoethanolamine, and a composition containing one or more basic amino acids (B). ), And a method for dyeing or brightening human keratin fibers using a composition (C) containing one or more oxidizing agents, when this method is a dyeing method, an anhydrous composition. The product (A) does not contain an organic amine, and the composition (B) contains one or more oxidation dyes and / or direct dyes.

In the present invention, at least one of the compartments contains the above-mentioned anhydrous cosmetic composition (A), another compartment contains the above-mentioned composition (B), and the remaining one contains the above-mentioned oxidation composition (the above-mentioned oxidation composition (A). For multi-segment devices, including C).

Among the methods for dyeing human keratin fibers, for example, hair, oxidative dyeing or permanent dyeing can be mentioned. More specifically, the dyeing method uses one or more oxidation dye precursors, usually one or more oxidation bases which may be combined with one or more coupling agents.

Generally, the oxidation base is selected from ortho- or para-phenylenediamine, ortho- or para-aminophenol and heterocyclic compounds. These oxidation bases are colorless or slightly colored compounds that, when mixed with an oxidizing substance, allow the formation of colored chemicals via an oxidative condensation step.

The tones obtained using these oxidation bases often change when used in combination with one or more coupling agents, and the coupling agents are particularly aromatic meta-diamines, meta-aminophenols, meta-di. It is selected from phenol and certain heterocyclic compounds, such as indole compounds.

Due to the variety of molecules used as oxidation bases and coupling agents, it is possible to obtain a wide range of colors.

Direct or semi-permanent staining is also known. In the method conventionally used for direct dyeing, a direct dye, which is a colored and coloring molecule having an affinity for the fiber, is applied to the keratin fiber, and the molecule is diffused by leaving it on for a certain period of time. After infiltrating the fibers, rinse off.

Commonly used direct dyes are selected from nitrobenzene, anthraquinone, nitropyridine, azo, methine, azomethine, xanthene, acridine, azine and triallylmethane direct dyes.

This type of method does not require the use of oxidants to develop color. However, the use of oxidizing agents is not excluded for the purpose of obtaining not only coloring but also lightening effect. Such a method is called direct staining or semi-permanent staining under lightening conditions.

In the method of permanent or semi-permanent dyeing under lightening conditions, in most cases, an aqueous composition containing at least one oxidizing agent is used at the same time as the dye composition under alkaline pH conditions. The role of this oxidant is to break down the melanin in the hair, which, to varying degrees, leads to significant lightening of the fibers, depending on the nature of the oxidant present. Therefore, for relatively weak lightening, the oxidant is generally hydrogen peroxide. When stronger lightening is desired, a peroxygenated salt, such as a persulfate, is usually used in the presence of hydrogen peroxide.

In the method for lightening human keratin fibers, an aqueous composition containing at least one oxidizing agent is often used under alkaline pH conditions. This oxidant has the role of decomposing melanin in the hair, which, to varying degrees, leads to significant lightening of the fibers, depending on the nature of the oxidant present. Therefore, for relatively weak lightening, the oxidant is generally hydrogen peroxide. When stronger lightening is desired, a peroxide salt, such as a persulfate, is usually used in the presence of hydrogen peroxide.

One of the problems is that these methods for dyeing or lightening keratin fibers proceed under alkaline conditions and the most commonly used alkaline agent is aqueous ammonia. Ammonia water is particularly advantageous in this type of method. This is because aqueous ammonia can adjust the pH of the composition to an alkaline pH to activate the oxidant. However, this agent also causes swelling of the keratin fibers and opens the scale, so that the penetration of the dye at the same time as the penetration of the oxidant, and in the case of the dyeing method, essentially promotes the penetration of the oxidant dye into the fibers, therefore. The effect of the dyeing reaction is enhanced.

However, this basicizing agent is extremely volatile and is disliked by users due to the release of the characteristic, strong, and rather unpleasant odor of ammonia during this method.

In addition, higher content than necessary must be used to compensate for the evaporation of ammonia. This is not unaffected by the user, who may face not only discomfort due to odor, but also an increased risk of hypersensitivity, such as increased scalp irritation (stinging).

With respect to the option of simply substituting all or part of the aqueous ammonia with one or more other standard basers, the aqueous ammonia-based baser leads to the production of more effective compositions. No, but it is especially because these basicizing agents do not result in sufficient lightening of the colored fibers in the presence of oxidants.

<nplcit num="1"><text>Walter Noll, "Chemistry and Technology of Silicones" (1968), Academic Press</text></nplcit><nplcit num="2"><text>"Cosmetics and Toiletries", Vol. 91, January, 76, 27-32</text></nplcit><nplcit num="3"><text>Todd and Byers, "Volatile Silicone Fluids for Cosmetics"</text></nplcit><nplcit num="4"><text>CTFA (6th edition, 1995)</text></nplcit><nplcit num="5"><text>"Color Index International" 3rd Edition</text></nplcit>

The methods performed using existing compositions have drawbacks caused by the presence of large amounts of ammonia, but one of the objects of the present invention does not have such drawbacks and in the case of dyeing methods, In terms of the resulting dyeing power, chromaticity, and uniformity of dyeing on the fibers, the lightening method is compared to existing methods in terms of lightening and the uniformity of this lightening. It is to propose a method for dyeing or lightening human keratin fibers, carried out in the presence of an oxidant, which retains at least equivalent efficacy.

Although the above and other objects are achieved by the present invention, one subject of the present invention is a method of dyeing or brightening human keratin fibers in the presence of an oxidizing agent, in which the following are: used: a) Anhydrous composition containing one or more fatty substances and one or more surfactants (A), b) Compositions containing monoethanolamine and one or more basic amino acids (B), c) Composition containing one or more oxidizing agents (C) (However, when the method is a coloring method, the anhydrous composition (A) does not contain an organic amine and the composition (B) contains one or more oxidative dyes and / or direct dyes). The present invention further comprises an anhydrous composition (A) containing one or more aliphatic substances and one or more surfactants in one compartment, monoethanolamine and 1 in another compartment. It also relates to a multi-compartment device comprising a composition (B) containing a species or a plurality of basic amino acids and another compartment comprising a composition (C) containing the species or a plurality of oxidants. In one aspect of this multi-partition device, the anhydrous composition (A) is free of organic amines and the composition (B) comprises one or more oxidative dyes and / or direct dyes. Other features and advantages of the present invention will become clearer as you read the descriptions and examples below. In the text below, the upper and lower limits of a range of values are included in that range unless otherwise noted. The human keratin fibers treated by the method according to the present invention are preferably hair. The cosmetic anhydrous composition (A) has a water content of 0% by weight or more, less than 5% by weight, more preferably less than 2% by weight, and more specifically less than 1% with respect to the weight of the composition. Have. It should be noted that the water may be in the form of bound water, such as water of crystallization of salts, or trace amounts of water absorbed by the starting material used in the preparation of the compositions according to the invention. In addition, when the method is a lightening method, the compositions used are direct dyes commonly used for dyeing human keratin fibers or for other purposes, as well as precursors of oxidative dyes (bases and coupling agents). However, when these are included, their total content does not exceed 0.005% by weight based on the weight of the anhydrous composition and the weight of the aqueous composition containing the oxidizing agent. Strictly speaking, at such a content, perhaps only the composition could be stained, so no staining effect would be observed on the keratin fibers. Preferably, the lightening method is carried out without the use of oxidation bases, coupling agents and direct dyes. When the method is a staining method, the anhydrous composition (A) does not contain organic amines, in particular this anhydrous composition has a pKb of 12 at 25 ° C (this value corresponds to the highest basic function). Contains less than organic amines. As mentioned above, the cosmetic anhydrous composition (A) contains one or more fatty substances. The term "fatty substance" is an organic compound that is insoluble in water (solubility is less than 5%, preferably less than 1%, more preferably 0.1%) at room temperature (25 ° C) and under atmospheric pressure (760 mmHg). Means. The aliphatic substance contains at least one hydrocarbon-based chain having at least 6 carbon atoms or at least 2 contiguous siloxane groups in its structure. In addition, fatty substances are generally soluble in organic solvents such as chloroform, ethanol, benzene, liquid petrolatum or decamethylcyclopentasiloxane under the same temperature and pressure conditions. According to the present invention, the fatty substance is selected from compounds that are liquid or pasty at room temperature and atmospheric pressure. More specifically, fatty substances are C6~ C16Selected from lower alkanes, non-silicone oils of animal, plant, mineral or synthetic origin, fatty alcohols, fatty acids, fatty acids and / or esters of fatty alcohols, non-silicone waxes and silicones. For the purposes of the present invention, fatty alcohols, fatty esters and fatty acids, more specifically, contain at least linear or branched, saturated or unsaturated hydrocarbon-based groups containing 6 to 30 carbon atoms. It is recalled that it contains one and its groups are optionally substituted by one or more hydroxyl groups (particularly 1 to 4). These compounds, when unsaturated, can contain 1 to 3 conjugated or unconjugated carbon-carbon double bonds. C6~ C16Lower alkanes are linear or branched, and in some cases cyclic. Examples include hexane, undecane, dodecane, tridecane, and isoparaffins such as isohexadecane and isodecan. Animal oils, vegetable oils, mineral oils or synthetically derived oils that can be used in the compositions of the present invention include: --Animal-derived hydrocarbon-based oils, such as perhydrosqualene, --Plant or synthetic triglyceride oils, eg liquid fatty acid triglycerides containing 6 to 30 carbon atoms, eg heptanic acid or octanoic acid triglycerides, or eg sunflower oil, corn oil, soybean oil, mallow oil, grapes Seed oil, sesame oil, hazelnut oil, apricot oil, macadamia oil, arara oil, castor oil, avocado oil, capricyl / capric acid triglyceride, for example, products sold by Stearineries Dubois or Miglyol from Dynamit Nobel. ) Products sold under the names 810, 812 and 818 (registered trademarks), jojoba oil and shea butter oil, --- Linear or branched hydrocarbons derived from minerals or synthetics containing more than 16 carbon atoms, such as volatile or non-volatile liquid paraffin, and derivatives thereof, petrolatum, liquid petrolatum, polydecene, eg, Hydrocarbon polyisobutenes such as Parleam®, preferably liquid paraffin, petrolatum, liquid petrolatum, polydecene and hydrogenated polyisobutene, such as Parleam, --Fluoro oil, eg BNFL Perfluoromethylcyclopentane and perfluoro 1,3-dimethylcyclohexane; perfluoro 1,2-dimethylcyclobutane; 3M to PF5050 (registered) sold under the names Flutec® PC1 and Flutec® PC3 by Fluorochemicals. Perfluoroalkanes such as dodecafluoropentane and tetradecafluorohexane sold under the names of Trademark) and PF5060®, or bromoperfluorooctanoic acid sold under the name Foralkyl® from Atochem; nonafluoro Methoxybutane and nonafluoroethoxyisobutane; perfluoromorpholin derivatives such as 4-trifluoromethylperfluoromorpholin sold by 3M under the name PF5052®. Fatty alcohols suitable for use in the present invention are more specifically selected from saturated or unsaturated, linear or branched alcohols containing 8 to 30 carbon atoms. Examples may include cetyl alcohol, stearyl alcohol and mixtures thereof (cetylstearyl alcohol), octyldodecanol, 2-butyloctanol, 2-hexyldecanol, 2-undecylpentadecanol, oleyl alcohol or linolyl alcohol. is there. Fatty acids that can be used with respect to the present invention are more specifically selected from saturated or unsaturated carboxylic acids containing 6 to 30, especially 9 to 30 carbon atoms. It is advantageous that the carboxylic acid is selected from myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid and isostearic acid. Esters of fatty acids and / or esters of fatty alcohols are advantageous when different from the triglycerides described above, especially saturated or unsaturated, linear or branched C.1~ C26Aliphatic monoacids or polyacids and saturated or unsaturated, linear or branched C1~ C26Aliphatic monoalcohols or polyalcohols can be mentioned, and the total number of carbon atoms in the ester is 10 or more. As monoesters, dihydroabiethylbehenate, octyldodecylbehenate, isosetylbehenate, cetyl lactate, lactate C12~ C15Alkyl, isostearyl lactate, lauryl lactate, linolyl lactate, oleyl lactate, stearyl (iso) octanate, isosetyl octanate, octyl octanate, cetyl octanate, decyl oleate, isosetyl isostearate, isosetyl laurate, isosetyl stearate, Isodecyl octanoate, isodecil oleate, isononyl isononanoate, isostearyl palmitate, methyl acetylricinolenate, myristyl stearate, octyl isononanoate, 2-ethylhexyl isononanoate, octyl palmitate, octyl pelargone, octyl stearate Octyldodecyl acid, oleyl erucate, ethyl and isopropyl palmitate, 2-ethylhexyl palmitate, 2-octyldecyl palmitate, alkyl myristate, such as isopropyl myristearate, butyl myristerate, cetyl myritearate, myristearic acid Examples thereof include hexyl stearate, butyl stearate, isobutyl stearate, dioctyl malate, hexyl laurate, and 2-hexyl decyl laurate, such as 2-octyldodecyl, myristyl millistearate, and stearyl millistearate. In addition, in this embodiment, C4~ C22Dicarboxylic acid or tricarboxylic acid ester and C1~ C22Alcohol esters, as well as mono-, di- or tricarboxylic acid esters, and C2~ C26Di-, tri-, tetra- or pentahydroxy alcohol esters can also be used. In particular, the following esters can be mentioned: diethyl sebacate, diisopropyl sebatate, diisopropyl adipate, di-n-propyl adipate, dioctyl adipate, diisostearyl adipate, dioctyl maleate, glyceryl undecylate, stearoyl stearate. Octyldodecyl acid, pentaerythritol monoricinoleate, pentaerythritol tetraisononanoate, pentaerythritol tetrapelargonate, pentaerythritol tetraisostearate, pentaerythritol tetraoctanoate, propylene glycol dicaprylate, propylene glycol dicaprate, elca Tridecyl acid, triisopropyl citrate, triisostearyl citrate, glyceryl trilactic acid, glyceryl trioctate, trioctyldodecyl citrate, trioleyl citrate, propylene glycol dioctanoate, neopentyl glycol diheptate, diethylene glycol diisononanoate, and distearate Polyethylene glycol acid acid. Among the esters described above, ethyl palmitate, isopropyl palmitate, myristyl palmitate, cetyl palmitate or stearyl palmitate, 2-ethylhexyl palmitate, 2-octyldecyl palmitate, alkyl myristate, such as isopropyl myristate, myristic acid Uses hexyl stearate, butyl stearate, isobutyl stearate, dioctyl malate, hexyl laurate, 2-hexyldecyl laurate, isononyl isononanoate or cetyl octanoate, such as butyl, cetyl myristate or 2-octyldodecyl myristate. It is preferable to do so. The composition further comprises C as a fatty ester.6~ C30、Preferably C12~ C22It can also contain sugar esters and diesters of fatty acids. Recall that the term "sugar" means an oxygen-bearing hydrocarbon-based compound containing multiple alcohol groups, with or without aldehyde or ketone groups, and containing at least 4 carbon atoms. Will be done. Such sugars can be monosaccharides, oligosaccharides or polysaccharides. Examples of suitable sugars that can be mentioned include sucrose (sucrose), glucose, galactose, ribose, fructose, maltose, mannose, arabinose, xylose and lactose, and derivatives thereof, in particular alkyl derivatives such as methyl derivatives. For example, there is methyl glucose. Fatty acid sugar esters are linear or branched, saturated or unsaturated C with the above-mentioned sugar esters or mixtures of esters.6~ C30, Preferably C12~ C22May be specifically selected from the group comprising esters of the fatty acids of the above or mixtures thereof. If unsaturated, these compounds may contain 1 to 3 conjugated or unconjugated carbon-carbon double bonds. Esters according to this embodiment can also be selected from mono-, di-, tri-, tetraesters and polyesters, and mixtures thereof. These esters are, for example, esters of oleic acid, lauric acid, palmitic acid, mistylic acid, bechenic acid, coconut fatty acid, stearic acid, linoleic acid, linolenic acid, capric acid and arachidonic acid or mixtures thereof, for example, especially oleo. It can be selected from an ester in which palmitic acid, oleic stearic acid and palmitostearic acid are mixed. Even more particularly preferred is the use of monoesters and diesters, especially mono-or dioleic acid, stearic acid, bechenic acid, oleopalmitic acid, linoleic acid, linolenic acid and oleostearic acid sucrose, glucose or methyl glucose. Is preferable. An example that can be mentioned is a product sold by Amerchol under the name Glucate® DO, which is methyl glucose dioleate. Examples of esters or esters of sugars and fatty acids that can be mentioned include: --Products sold by Crodesta under the names F160, F140, F110, F90, F70 and SL40, which are 73% monoester and 27% di and triester, 61% monoester and di, respectively. Formed from tri and tetraester 39%, monoester 52% and di, tri and tetraester 48%, monoester 45% and di, tri and tetraester 55%, monoester 39% and di, tri and tetraester 61% Corresponds to sucrose palmitostearate, and sucrose monolaurate. --Products sold under the name Ryoto Sugar Esters, for example B370, corresponding to sucrose behenate formed from 20% monoester and 80% di-triester-polyester. --Sucrose monodipalmitostearate sold by Goldschmidt under the name Tegosoft® PSE. Non-silicone waxes include carnauba wax, candelilla wax, esparto grass wax, paraffin wax, ozokerite, vegetable waxes such as olive wax, rice wax, hydrogenated jojoba wax or pure flower wax (pure flower wax). Absolute wax), for example, animal waxes such as the essence wax of the flower of Kurofusasuri sold by Bertin (France), for example beeswax or modified beeswax (Ceraberina) are particularly selected. Other waxes or waxy starting materials that can be used in accordance with the present invention are, in particular, marine waxes, such as products sold by Sophim under the reference number M82, and polyethylene waxes or polyolefin waxes in general. Is. The silicones that can be used in the cosmetic compositions of the present invention are volatile or non-volatile, cyclic, linear or branched silicones that are unmodified or modified with organic groups and at 25 ° C. 5 × 10-6From 2.5m2/ s, preferably 1x10-5From 1m2Has a viscosity of / s. Silicones that can be used in accordance with the present invention may be in the form of oils, waxes, resins or gums. Preferably, the silicone is selected from polydialkylsiloxanes, particularly organically modified polysiloxanes containing at least one functional group selected from polydimethylsiloxane (PDMS) and poly (oxyalkylene) groups, amino groups and alkoxy groups. To. Organopolysiloxane is defined in detail by Walter Noll, "Chemistry and Technology of Silicones" (1968), Academic Press. The organopolysiloxane may be volatile or non-volatile. In the case of volatile, silicone is selected from those having a boiling point between 60 ° C and 260 ° C, more specifically, and more specifically from: (i) Cyclic polydialkylsiloxane having 3 to 7 silicon atoms, preferably 4 to 5 silicon atoms. These are, for example, octamethylcyclotetrasiloxane sold by Union Carbide under the name Volatile Silicone® 7207 and by Rhodia under the name Silbione® 70045 V2, from Union Carbide. Decamethylcyclopentasiloxane sold under the name Volatile Silicone® 7158 and from Rhodia under the name Silbione® 70045 V5, and mixtures thereof. Also, dimethylsiloxane / methylalkylsiloxane type cyclopolymers, such as the following chemical structures:<chemistry num="1"><img file="JP2010143918A_D0001.tif" /></chemistry> Volatile Silicone® FZ3109, sold by Union Carbide, can also be mentioned. Also, a mixture of cyclic polydialkylsiloxane with an organosilicon compound, such as a mixture of octamethylcyclotetrasiloxane and tetratrimethylsilylpentaerythritol (50/50), and octamethylcyclotetrasiloxane and oxy-1,1'-bis (50/50). A mixture of 2,2,2', 2', 3,3'-hexatrimethylsilyloxy) neopentane can be mentioned. (ii) It has 2 to 9 silicon atoms and is 5 × 10 at 25 ° C.-6m2A linear volatile polydialkylsiloxane with a viscosity of / s or less. An example is decamethyltetrasiloxane, which is sold under the name SH200 by Toray Silicone. Silicones in this category are also found in Cosmetics and Toiletries, Vol. 91, January, 76, pp. 27-32, Todd and Byers, Volatile Silicone Fluids for Cosmetics. Has been described. Preferably, non-volatile polydialkylsiloxanes, polydialkylsiloxane gums and resins, polyorganosiloxanes modified with the above-mentioned organofunctional groups, and mixtures thereof are used. These silicones are particularly selected from polydialkylsiloxanes and can mainly include polydimethylsiloxanes containing a trimethylsilyl terminal group. Silicone viscosities are measured at 25 ° C, for example, according to ASTM Standard 445 Annex C. Among these polyalkylsiloxanes, the following commercial products can be mentioned, but not limited to: --Silbione® or Mirasil® oils of the 47 and 70047 series sold by Rhodia, eg Oil 70047V500000, --Mirasil® series oils sold by Rhodia, --Dow Corning 200 Series Oils, For example 60000mm2DC200 with viscosity of / s, etc. --General Electric's Viscasil® oils and certain oils from General Electric's SF series (SF96, SF18). Also mentioned are polydimethylsiloxanes containing dimethylsilanol end groups, known by the name dimethiconol (CTFA), such as Rhodia's 48 series oils. Polyalkylsiloxanes in this category can also include products sold by Goldschmidt under the names Abil Wax® 9800 and 9801, which are poly (C).1~ C20) Dialkylsiloxane. Silicone gums that can be used in accordance with the present invention are particularly preferably polydialkylsiloxanes, preferably polydimethylsiloxanes, with a large number average molecular weight of 200,000 to 1000000, which are used alone or as a mixture in a solvent. The solvent can be selected from volatile silicone, polydimethylsiloxane (PDMS) oil, polyphenylmethylsiloxane (PPMS) oil, isoparaffin, polyisobutylene, methylene chloride, pentane, dodecane and tridecane, or mixtures thereof. Products that can be used in accordance with the present invention are, more specifically, mixtures such as: A mixture formed from polydimethylsiloxane with hydroxylated chain ends, dimethiconol (CTFA), and cyclic polydimethylsiloxane, also known as cyclomethicone (CTFA), sold by Dow Corning, for example. Product Q2 1401. --A mixture formed from cyclic silicone and polydimethylsiloxane gum, such as General Electric's product, SF1214 Silicone Fluid. This product is obtained by dissolving SF30 gum corresponding to dimethicone having a number average molecular weight of 500000 in SF1202 Silicone Fluid oil corresponding to decamethylcyclopentasiloxane. --Two PDMS with different viscosities, especially a mixture of PDMS gum and PDMS oil, eg SF1236, a product of General Electric. Product SF1236 is 20m2The above-mentioned gum SE30 with a viscosity of / s and 5 × 10-6m2It is a mixture with oil SF96 having a viscosity of / s. This product preferably contains 15% SE30 gum and 85% SF96 oil. Organopolysiloxane resins that can be used in accordance with the present invention have the following units, R, where R represents an alkyl containing 1 to 16 carbon atoms.2SiO2/2, R3SiO1/2, RSiO3/2And SiO4/2It is a crosslinked siloxane system containing. Of these products, R is C, which is particularly preferred.1~ C4It represents a lower alkyl group, more specifically methyl. Among these resins are products sold under the name Dow Corning 593 or products sold by General Electric under the names Silicone Fluid SS4230 and SS4267, which have a dimethyl / trimethylsiloxane structure. It is silicone. In particular, trimethylsiloxysilicate type resins sold by Shin-Etsu Chemical Co., Ltd. under the names of X22-4914, X21-5034 and X21-5037 can be mentioned. The organically modified silicone that can be used in accordance with the present invention is the silicone described above that contains one or more organic functional groups attached to its structure via a hydrocarbon base group. In addition to the above-mentioned silicones, the organically modified silicones can also be polydiarylsiloxanes functionalized with the above-mentioned organically modifying groups, particularly polydiphenylsiloxanes and polyalkylarylsiloxanes. Polyalkylarylsiloxanes are, in particular, 1 × 10 at 25 ° C.-5From 5x10-2m2It is selected from linear and / or branched polydimethylsiloxane / methylphenylsiloxane and polydimethylsiloxane / diphenylsiloxane with a viscosity of / s. Among these polyalkylarylsiloxanes, examples that can be mentioned are products sold under the following names: --Rhodia 70641 Series Silbone® Oil, --Rhodia Rhodorsil® 70633 and 763 series oils, --Dow Corning 556 Cosmetic Grade Fluid Oil, --Bayer PK series silicones, such as product PK20, --Bayer PN and PH series silicones, such as products PN1000 and PH1000, --Some oils from General Electric's SF series, such as SF1023, SF1154, SF1250 and SF1265. Among the organically modified silicones, the following polydiorganosiloxanes can be mentioned: --C6~ C24Silwet from Union Carbide, an optional product with an alkyl group, having a polyethylene oxy and / or a polypropylene oxy group, eg, a product known as dimethicone copolyol sold by Dow Corning under the name DC1248. (Registered Trademarks) L 722, L7500, L77 and L11 oils, and sold by Dow Corning under the name Q2 5200, (C12) Alkylmethicone copolyol, --Products with substituted or unsubstituted amine groups, such as products sold by Genesee under the names GP4 Silicone Fluid and GP7100, or sold by Dow Corning under the names Q2 8220 and Dow Corning 929 or 939. The product you have. Substituted amine groups are especially C1~ C4It is an aminoalkyl group. --Products containing an alkoxylated group, such as products sold by SWS Silicones under the name Silicone Copolymer F-755, and Goldschmidt's Abil Wax® 2428, 2434 and 2440. Preferably, the fatty substance is C2~ C3Contains neither oxyalkylene units nor glycerol units. More specifically, the fatty substance is selected from liquid or pasty compounds at room temperature and atmospheric pressure. Preferably, the fatty substance is a compound that is liquid at a temperature of 25 ° C. under atmospheric pressure. More specifically, fatty substances are other than fatty acids. The fatty substance is preferably C6~ C16Lower Alcans, non-silicone oils derived from plants, minerals or synthetics, fatty alcohols, esters of fatty acids and / or fatty alcohols, and silicones. Preferably, the fatty material in the composition according to the invention is non-silicone based. Preferably, the fatty material is selected from liquid petrolatum, polydecene and liquid esters of fatty acids and / or fatty alcohols, or mixtures thereof. Anhydrous cosmetic compositions are advantageously 10% to 99% by weight, preferably 20% to 90% by weight, and more preferably 25% to 80% by weight, based on the weight of the anhydrous composition. Has a fatty substance content of. The cosmetic anhydrous composition (A) also contains one or more surfactants. Preferably, the surfactant is selected from nonionic and anionic surfactants. Anionic surfactants are, more specifically, from salts of the following compounds (particularly alkali metal salts, especially sodium salts, ammonium salts, amine salts, amino alcohol salts or alkaline earth metal salts, such as magnesium salts). Selected: --Alkyl sulfate, alkyl ether sulfate, alkylamide ether sulfate, alkylaryl polyether sulfate, monoglyceride sulfate, --Alkyl sulfonate, alkyl amide sulfonate, alkylaryl sulfonate, α-olefin sulfonate, paraffin sulfonate, --Alkyl phosphate, Alkyl phosphate ether, --Alkyl sulfosuccinate, alkyl ether sulfosuccinate, alkylamide sulfosuccinate, --Alkyl sulfoacetate, --Acyl sarcosinate, acylisethionate and N-acyl taurate, Fatty acids such as oleic acid, ricinoleic acid, palmitic acid or stearic acid, coconut oil acid or hydrogenated coconut oil acid salt, --Alkyl-D-galactodosideuronate, --Acyllactilate, --- Salts of polyoxyalkyleneized alkyl ether carboxylic acids, polyoxyalkyleneized alkylaryl ether carboxylic acids or polyoxyalkyleneed alkylamide ether carboxylic acids, especially those containing 2 to 50 ethylene oxide groups. -And their mixture. Note that the alkyl or acyl groups of these various compounds advantageously contain 6 to 24, preferably 8 to 24 carbon atoms, and the acyl group preferably represents a phenyl or benzyl group. Should. The nonionic surfactant is selected from, more specifically, monooxyalkyleneed or polyoxyalkyleneed, monoglycerolized or polyglycerolized, nonionic surfactants. More specifically, the oxyalkylene unit is oxyethylene or oxypropylene unit, or a combination thereof, and is preferably an oxyethylene unit. Examples of oxyalkyleneized nonionic surfactants that can be mentioned include, among others, alone or as a mixture: Oxyalkyleneization (C8~ C24) Alkylphenol, Saturated or unsaturated, linear or branched oxyalkyleneized C8~ C30alcohol, Saturated or unsaturated, linear or branched oxyalkyleneized C8~ C30Amide, Saturated or unsaturated, linear or branched C8~ C30Acid and polyethylene glycol ester, Saturated or unsaturated, linear or branched C8~ C30Acid and sorbitol polyoxyethylene ester, Saturated or unsaturated oxyethylene vegetable oil, -Ethylene oxide and / or propylene oxide condensate. Surfactants contain ethylene oxide and / or propylene oxide in a constant molar number between 1 and 100, preferably between 2 and 50. It is advantageous that the ionic surfactant does not contain oxypropylene units. In one preferred embodiment of the invention, the oxyalkyleneated nonionic surfactant is oxyethyleneated C.8~ C30Alcohol, as well as saturated or unsaturated, linear or branched C8~ C30It is selected from polyoxyethyleneated esters of acid and sorbitol. Monoglycerolization or polyglycerolization Examples of nonionic surfactants are monoglycerolization or polyglycerolation C.8~ C40Alcohol is preferably used. In particular, monoglycerol or polyglycerolized C8~ C40Alcohol corresponds to the following formula: RO- [CH2-CH (CH)2OH) -O]m-H However, R is a linear or branched C.8~ C40, Preferably C8~ C30Represents an alkyl or alkenyl group of, m represents a number from 1 to 30, preferably a number from 1 to 10. Examples of compounds suitable for use in the present invention are lauryl alcohol containing 4 mol of glycerol (INCI name: polyglyceryl-4 lauryl ether), lauryl alcohol containing 1.5 mol of glycerol, and oleyl alcohol containing 4 mol of glycerol. (INCI name: polyglyceryl-4 oleyl ether), oleyl alcohol containing 2 mol of glycerol (INCI name: polyglyceryl-2 oleyl ether), cetearyl alcohol containing 2 mol of glycerol, cetearyl alcohol containing 6 mol of glycerol, Examples include oleocetyl alcohol containing 6 mol of glycerol and octadecanol containing 6 mol of glycerol. Alcohol represents a mixture of alcohols, just as the value of m represents a statistic. This means that in commercial products, multiple types of polyglycerolated fatty alcohols can be present simultaneously in the form of a mixture. Among monoglycerolized or polyglycerolated alcohols, C containing 1 mol of glycerol8/ C10C containing 1 mol of alcohol and glycerol10/ C12C containing 1.5 mol of alcohol and glycerol12It is even more preferred to use alcohol. Preferably, the surfactant present in the anhydrous composition is a nonionic surfactant. More specifically, the surfactant content contained in the anhydrous composition occupies 0.1% by weight to 50% by weight, preferably 0.5% by weight to 30% by weight, based on the weight of the anhydrous composition. Cosmetic compositions (A) are anionic, cationic, nonionic, amphoteric or zwitterionic polymers or mixtures thereof, inorganic thickeners, and especially fillers, such as clays, talc, etc., especially anions. Organic thickeners, antioxidants, penetrants, sequestrants, fragrances, dispersants, film-forming agents, conditioners, containing sex, cationic, nonionic and zwitterionic polymer-binding thickeners, Various auxiliary agents conventionally used in hair dye compositions such as ceramides, preservatives and opalescents can also be included. The above-mentioned auxiliaries are generally present in an amount of 0.01 to 20% by weight, respectively, based on the weight of the composition (A). The composition can also include one or more inorganic thickeners selected from organic affinity clay, fumed silica, or mixtures thereof. The organic affinity clay can be selected from montmorillonite, bentonite, hectorite, attapargite, sepiolite, and mixtures thereof. The clay is preferably bentonite or hectorite. These clays are modified with quaternary amines, tertiary amines, amine acetates, imidazolines, amine soaps, fatty sulfates, alkylaryl sulfonates and amine oxides, and chemical compounds selected from mixtures thereof. Can be quality. Organic affinity clays that can be mentioned include quaternium-18 bentonite, such as those sold by Rheox under the names Bentone 3, Bentone 38 and Bentone 38V, United Catalyst's Tixogel VP, Southern Clay. Steer such as those sold by Claytone 34, Claytone 40 and Claytone XL, Bentonite 27 by Rheox, Tixogel LG by United Catalyst, and Claytone AF and Claytone APA by Southern Clay. Larconium Bentonite, Quarternium-18 / Benzarconium Bentonite, such as those sold by Southern Clay under the names Claytone HT and Claytone PS, Bentone Gel ODA, Bentone Gel ECO5, Bentone Gel EUG, Bentone Gel from Rheox IPP, Bentonite Gel ISD, Bentonite Includes quarternium-18 hectorite, such as those sold by Biophil under the names Simagel M and Simagel SI 345 under the names Gel SS71, Bentone Gel VS8 and Bentone Gel VS38. Humed silica can be obtained by high temperature hydrolysis of a volatile silicon compound in an oxyhydrogen flame to produce finely dispersed silica. This method makes it possible to obtain hydrophilic silica with a large number of silanol groups, especially on this surface. Such hydrophilic silicas are available, for example, from Degussa, Aerosil 130®, Aerosil 200®, Aerosil 255®, Aerosil 300® and Aerosil 380®, and Cabot. Depending on the company, Cab-O-Sil HS-5 (registered trademark), Cab-O-Sil EH-5 (registered trademark), Cab-O-Sil LM-130 (registered trademark), Cab-O-Sil MS-55 ( It is sold under the names of (registered trademark) and Cab-O-Sil M-5 (registered trademark). The surface of silica can be chemically modified by a chemical reaction that reduces the number of silanol groups. It is particularly possible to replace the silanol group with a hydrophobic group, then hydrophobic silica is obtained. Hydrophobic groups can be: A trimethylsiloxyl group, which is obtained by treating fumed silica, in particular in the presence of hexamethyldisilazane. Silica treated in this way is known by CTFA (6th edition, 1955) as "silica silylate". They are sold, for example, by Degussa under the reference code Aerosil R812® and Cabot under the reference code Cab-O-Sil TS-530®. --Dimethylsilyloxyl or polydimethylsiloxane group, which is obtained by treating fumed silica, in particular in the presence of polydimethylsiloxane or dimethyldichlorosilane. The silica treated in this way is known by CTFA (6th edition, 1995) as "silica dimethyl silylate". These are, for example, reference codes for Aerosil R972® and Aerosil R974® from Degussa and Cab-O-Sil TS-610® and Cab-O-Sil TS-720 from Cabot. Sold under a (registered trademark) reference code. Humed silica preferably has a particle size that may range from nanometers to micrometers, eg, about 5 to 200 nm. Preferably, the composition comprises hectorite, organically modified bentonite or optionally modified fumed silica. Inorganic thickeners, if present, account for 1% to 30% by weight of the weight of the composition. As mentioned above, the composition (B) used in the process according to the invention is, on the one hand, monoethanolamine and, on the other hand, one or more basic amino acids. The basic amino acids that can be used in the present invention are selected from those containing an additional amine functional group optionally contained in the ring or ureido functional group, more specifically. Such basic amino acids are preferably selected from those corresponding to formula (I) below:<chemistry num="2"><img file="JP2010143918A_D0002.tif" /></chemistry> However, R represents a group selected from:<chemistry num="3"><img file="JP2010143918A_D0003.tif" /></chemistry> The compounds corresponding to formula (I) are histidine, lysine, arginine, ornithine and citrulline, preferably arginine, lysine and histidine, or mixtures thereof. It is advantageous that the composition (B) has a monoethanolamine content in the range of 0.1% to 40% by weight, preferably 0.5% to 20% by weight, based on the weight of the composition. The more specific range of the content of basic amino acids is in the range of 0.1% by weight to 40% by weight, preferably 0.5% by weight to 20% by weight, based on the weight of the composition. Note that in one particularly advantageous embodiment, the weight ratio of monoethanolamine / basic amino acid is preferably in the range of 0.1 to 10, more preferably 0.3 to 10, and even more preferably 1 to 5. Should be. If the method according to the invention is a method for dyeing keratin fibers, the composition (B) also contains one or more oxidative dyes and / or direct dyes. Oxidation dyes are generally selected from one or more oxidation bases, which may be combined with one or more coupling agents. For example, the oxidation base is selected from para-phenylenediamine, bis (phenyl) alkylenediamine, para-aminophenol, ortho-aminophenol and heterocyclic bases, and their addition salts. Para-phenylenediamines that can be mentioned include, for example, para-phenylenediamine, para-toluenediamine, 2-chloro-para-phenylenediamine, 2,3-dimethyl-para-phenylenediamine, 2,6-dimethyl-para. -Phenylenediamine, 2,6-diethyl-para-phenylenediamine, 2,5-dimethyl-para-phenylenediamine, N, N-dimethyl-para-phenylenediamine, N, N-diethyl-para-phenylenediamine, N, N-dipropyl-para-phenylenediamine, 4-amino-N, N-diethyl-3-methylaniline, N, N-bis (β-hydroxyethyl) -para-phenylenediamine, 4-N, N-bis (β) -Hydroxyethyl) Amino-2-methylaniline, 4-N, N-bis (β-hydroxyethyl) amino-2-chloroaniline, 2-β-hydroxyethyl-para-phenylenediamine, 2-fluoro-para-phenylene Diamine, 2-isopropyl-para-phenylenediamine, N- (β-hydroxypropyl) -para-phenylenediamine, 2-hydroxymethyl-para-phenylenediamine, N, N-dimethyl-3-methyl-para-phenylenediamine, N, N- (β-Hydroxyethyl) -para-phenylenediamine, N- (β, γ-dihydroxypropyl) -para-phenylenediamine, N- (4'-aminophenyl) -para-phenylenediamine, N-phenyl -Para-Phenylenediamine, 2-β-Hydroxyethyloxy-Para-Phenylenediamine, 2-β-Acetylaminoethyloxy-Para-Phenylenediamine, N- (β-methoxyethyl) -Para-Phenylenediamine, 4-Amino There are phenylpyrrolidine, 2-thienyl-para-phenylenediamine, 2-β-hydroxyethylamino-5-aminotoluene and 3-hydroxy-1- (4'-aminophenyl) pyrrolidine, and their acid addition salts. Among the above-mentioned para-phenylenediamines, para-phenylenediamine, para-toluylenediamine, 2-isopropyl-para-phenylenediamine, 2-β-hydroxyethyl-para-phenylenediamine, 2-β-hydroxyethyloxy-para -Phenylene-diamine, 2,6-dimethyl-para-phenylenediamine, 2,6-diethyl-para-phenylenediamine, 2,3-dimethyl-para-phenylenediamine, N, N-bis (β-hydroxyethyl)- Para-phenylenediamine, 2-chloro-para-phenylenediamine and 2-β-acetylaminoethyloxy-para-phenylenediamine, and acid-added salts thereof are particularly preferred. Examples of bis (phenyl) alkylenediamines that can be mentioned include N, N'-bis (β-hydroxyethyl) -N, N'-bis (4'-aminophenyl) -1,3-diamino-propanol. N, N'-bis (β-hydroxyethyl) -N, N'-bis (4'-aminophenyl) ethylenediamine, N, N'-bis (4-aminophenyl) tetramethylenediamine, N, N'-bis (β-Hydroxyethyl) -N, N'-bis (4-aminophenyl) tetramethylenediamine, N, N'-bis (4-methylaminophenyl) tetra-methylenediamine, N, N'-bis (ethyl) -N, N'-bis (4'-amino-3'-methylphenyl) ethylene-diamine and 1,8-bis (2,5-diaminophenoxy) -3,6-dioxaoctane, and their addition salts is there. Para-aminophenols that can be mentioned include, for example, para-aminophenol, 4-amino-3-methylphenol, 4-amino-3-fluorophenol, 4-amino-3-hydroxymethylphenol, 4-amino-. 2-Methylphenol, 4-amino-2-hydroxymethylphenol, 4-amino-2-methoxymethylphenol, 4-amino-2-aminomethylphenol, 4-amino-2- (β-hydroxyethylaminomethyl) phenol And 4-amino-2-fluorophenol, as well as acid addition salts thereof. Ortho-aminophenols that can be mentioned include, for example, 2-aminophenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol and 5-acetamido-2-aminophenol, and their addition salts. There is. Heterocyclic bases that can be mentioned include, for example, pyridine derivatives, pyrimidine derivatives and pyrazole derivatives. Pyridine derivatives that can be mentioned include, for example, the compounds described in patents GB1026978 and GB1153196, such as 2,5-diaminopyridine, 2- (4-methoxyphenyl) amino-3-aminopyridine and 3,4-. There are diaminopyridines, as well as their addition salts. Other pyridine oxidation bases useful in the present invention are, for example, the 3-aminopyrazolo [1,5-a] pyridine oxidation bases described in patent application FR2801308 or their addition salts. Examples that can be mentioned are pyrazolo [1,5-a] pyrido-3-ylamine, 2-acetylaminopyrazolo [1,5-a] pyrido-3-ylamine, 2-morpholin-4-ylpyrazolo [1]. , 5-a] pyrido-3-ylamine, 3-amino-pyrazolo [1,5-a] pyridin-2-carboxylic acid, 2-methoxypyrazolo [1,5-a] pyrido-3-yl-amine, (3-Aminopyrazolo [1,5-a] Pyridine-7-yl) Methanol, 2- (3-Aminopyrazolo [1,5-a] Pyridine-5-yl) Ethanol, 2- (3-Aminopyrazolo [1,5] -a] pyrido-7-yl) ethanol, (3-amino-pyrazolo [1,5-a] pyrido-2-yl) methanol, 3,6-diaminopyrazolo [1,5-a] pyridine, 3, 4-Diaminopyrazolo [1,5-a] pyridine, pyrazolo [1,5-a] pyridine-3,7-diamine, 7-morpholin-4-ylpyrazolo [1,5-a] pyrido-3-ylamine, Pyrazolo [1,5-a] Pyridine-3,5-diamine, 5-morpholin-4-ylpyrazolo [1,5-a] Pyrido-3-ylamine, 2-[(3-Aminopyrazolo [1,5-a]] Pyridine-5-yl) (2-hydroxyethyl) amino] ethanol, 2-[(3-aminopyrazolo [1,5-a] pyrido-7-yl) (2-hydroxyethyl) amino] ethanol, 3-aminopyrazolo [ 1,5-a] Pyridine-5-ol, 3-aminopyrazolo [1,5-a] Pyridine-4-ol, 3-aminopyrazolo [1,5-a] Pyridine-6-ol and 3-aminopyrazolo [1,5-a] There are 5-a] pyridine-7-ol, as well as its addition salts. Examples of pyrimidine derivatives include the compounds described in Patent DE2359399, JP88-169571, JP05-63124, EP0770375 or Patent Application WO 96/15765, such as 2,4,5,6-tetraaminopyrimidine, 4-hydroxy-. 2,5,6-triaminopyrimidine, 2-hydroxy-4,5,6-triaminopyrimidine, 2,4-dihydroxy-5,6-diaminopyrimidine and 2,5,6-triaminopyrimidine, and theirs. It is a reciprocal form when an additional salt and a remutable equilibrium are present. Examples of pyrazole derivatives include the compounds described in patents DE3843892 and DE4133957, as well as patent applications WO94 / 08969, WO94 / 08970, FR-A-2733749 and DE19543988, such as 4,5-diamino-1-methylpyrazole. 4,5-diamino-1- (β-hydroxyethyl) pyrazole, 3,4-diaminopyrazole, 4,5-diamino-1- (4'-chlorobenzyl) -pyrazole, 4,5-diamino-1,3 -Dimethylpyrazole, 4,5-diamino-3-methyl-1-phenyl-pyrazole, 4,5-diamino-1-methyl-3-phenylpyrazole, 4-amino-1,3-dimethyl-5-hydradinopyrazole , 1-benzyl-4,5-diamino-3-methylpyrazole, 4,5-diamino-3-tert-butyl-1-methylpyrazole, 4,5-diamino-1-tert-butyl-3-methylpyrazole, 4,5-diamino-1- (β-hydroxyethyl) -3-methylpyrazole, 4,5-diamino-1-ethyl-3-methylpyrazole, 4,5-diamino-1-ethyl-3- (4' -Methoxyphenyl) pyrazole, 4,5-diamino-1-ethyl-3-hydroxymethylpyrazole, 4,5-diamino-3-hydroxymethyl-1-methylpyrazole, 4,5-diamino-3-hydroxymethyl-1 -Isopropylpyrazole, 4,5-diamino-3-methyl-1-isopropylpyrazole, 4-amino-5- (2'-aminoethyl) amino-1,3-dimethylpyrazole, 3,4,5-triaminopyrazole , 1-Methyl-3,4,5-Triaminopyrazole, 3,5-diamino-1-methyl-4-methylaminopyrazole and 3,5-diamino-4- (β-hydroxyethyl) amino-1-methyl There is pyrazole, as well as its additional salts. 4,5-Diamino-1- (β-methoxyethyl) pyrazole can also be used. Preferably, 4,5-diaminopyrazole is used, and more preferably 4,5-diamino-1- (β-hydroxyethyl) pyrazole and / or salts thereof are used. Further mentioned pyrazole derivatives include diamino-N, N-dihydropyrazolopyrazolone, particularly those described in patent application FR-A-2886136, such as the following compounds and their addition salts: 2 , 3-Diamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazole-1-one, 2-amino-3-ethyl-amino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazole-1-one, 2-amino-3-isopropyl-amino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazole-1-one, 2-amino -3- (Pyrrolidine-1-yl) -6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazole-1-one, 4,5-diamino-1,2-dimethyl-1,2 -Dihydropyrazole-3-one, 4,5-diamino-1,2-diethyl-1,2-dihydropyrazole-3-one, 4,5-diamino-1,2-di- (2-hydroxyethyl)- 1,2-Dihydropyrazole-3-one, 2-amino-3- (2-hydroxy-ethyl) amino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazole-1-one, 2-Amino-3-dimethylamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazole-1-one, 2,3-diamino-5,6,7,8-tetrahydro-1H , 6H-pyridadino [1,2-a] pyrazole-1-one, 4-amino-1,2-diethyl-5- (pyrrolidin-1-yl) -1,2-dihydropyrazole-3-one, 4- Amino-5- (3-dimethylaminopyrrolidin-1-yl) -1,2-diethyl-1,2-dihydropyrazole-3-one, 2,3-diamino-6-hydroxy-6,7-dihydro-1H , 5H-pyrazolo [1,2-a] pyrazole-1-one. 2,3-Diamino-6,7-dihydro-1H, 5H-pyrazolo [1,2-a] pyrazole-1-one and / or salts thereof are preferably used. Preferred heterocyclic bases include 4,5-diamino-1- (β-hydroxyethyl) pyrazole and / or 2,3-diamino-6,7-dihydro-1H, 5H-pyrazolo [1, 2-a] Pyrazole-1-one and / or salts thereof are included. The composition of the dyeing method (B) may also include one or more coupling agents selected to be advantageous from those conventionally used for dyeing keratin fibers. Among these coupling agents, among others, meta-phenylenediamine, meta-aminophenol, meta-diphenol, naphthalene-based coupling agents and heterocyclic coupling agents, and their addition salts can be mentioned. .. For example, 1,3-dihydroxybenzene, 1,3-dihydroxy-2-methylbenzene, 4-chloro-1,3-dihydroxybenzene, 2,4-diamino-1- (β-hydroxyethyloxy) benzene, 2- Amino-4- (β-hydroxyethylamino) -1-methoxybenzene, 1,3-diaminobenzene, 1,3-bis (2,4-diaminophenoxy) propane, 3-ureidaniline, 3-ureido-1- Dimethylaminobenzene, sesamole, 1-β-hydroxyethylamino-3,4-methylenedioxybenzene, a-naphthol, 2-methyl-1-naphthol, 6-hydroxyindole, 4-hydroxyindole, 4-hydroxy-N -Methylindol, 2-amino-3-hydroxypyridine, 6-hydroxybenzomorpholine, 3,5-diamino-2,6-dimethoxypyridine, 1-N- (β-hydroxyethyl) amino-3,4-methylenedi Oxybenzene, 2,6-bis (β-hydroxyethylamino) toluene, 6-hydroxyindolin, 2,6-dihydroxy-4-methylpyridine, 1-H-3-methylpyrazole-5-one, 1-phenyl- 3-Methylpyrazole-5-one, 2,6-dimethylpyrazolo [1,5-b] -1,2,4-triazole, 2,6-dimethyl- [3,2-c] -1,2, Examples thereof include 4-triazole and 6-methylpyrazolo [1,5-a] benzoimidazole, their acid addition salts, and mixtures thereof. In general, the oxidation base and coupling addition salts that can be used in the present invention are, among other things, hydrochlorides, hydrobromates, sulfates, citrates, succinates, tartrates, lactates, tosyls. It is selected from acid addition salts such as acid salts, benzene sulfonates, phosphates and acetates. Each oxidation base is preferably 0.0001% to 10% by weight, preferably 0.005% to 5% by weight, based on the total weight of the composition. If a coupling agent is present, its content is preferably 0.0001% to 10% by weight, respectively, based on the total weight of the composition, and 0.005% by weight, based on the total weight of the composition. It is preferably from% to 5% by weight. The composition of the dyeing method (B) can also include one or more direct dyes. For direct dyes, these dyes are more specifically selected from ionic and non-ionic species, preferably from cationic or non-ionic species. Examples of suitable direct dyes that can be mentioned are the following direct dyes: azo dyes, methine dyes, carbonyl dyes, azine dyes, nitro (hetero) aryl dyes, tri (hetero) arylmethanes, alone or in admixture. Dyes, porphyrin dyes, phthalocyanine dyes and natural direct dyes. More specifically, azo dyes contain -N = N-functional groups, in which two nitrogen atoms do not bond to one ring at the same time. However, it is not excluded that one of the two nitrogen atoms in the -N = N- sequence is bound to the ring. Methine dyes are, more specifically, compounds having at least one sequence selected from> C = C <and -N = C <, in which two atoms do not bond to one ring at the same time. However, it should be pointed out that one of the nitrogen or carbon atoms in the sequence can be attached to the ring. More specifically, the dyes of this system are methine, azomethine, mono- and diarylmethane, indamine (or diphenylamine), indophenol, indoaniline, carbocyanine, azacarbocyanine and their isomers, diazacarbocyanine. And their isomers, derived from compounds of the type such as tetraazacarbocyanine, and hemicianin. For carbonyl dyes, examples of carbonyl dyes include acridone, benzoquinone, anthraquinone, naphthoquinone, benzanthrone, anthraquinone, pyrantron, pyrazole anthrone, pyrimidino anthrone, flavantron, idantron, flavon, (iso) biolantron. , Isoindolinone, benzimidazolone, isoquinolinone, anthrapyridone, pyrazoloquinazolone, perinone, quinacridone, quinophthalone, indigoid, thioindigo, naphthalimide, anthrapyrimidine, diketopyrrolopyrrole and coumarin. Examples of cyclic azine dyes include azine, xanthene, thioxanthene, fluorindin, acridine, (di) oxazine, (di) thiazine and pyronin. The nitro (hetero) aromatic dye is, more specifically, a nitrobenzene or nitropyridine direct dye. For porphyrin or phthalocyanine type dyes, it is possible to use cationic or non-cationic compounds, optionally containing one or more metals or metal ions, such as alkali metals, alkaline earth metals, zinc and silicon. Is. Examples of particularly suitable direct dyes that can be mentioned are nitrobenzene dyes, azo direct dyes, azomethine direct dyes, methine direct dyes, azacarbocyanine direct dyes, eg, tetraazacarbocyanine (tetraazapentamethine), either alone or as a mixture. ), Kinones, in particular anthraquinone, naphthoquinone or benzoquinone substantive dyes, azine, xanthene, triallylmethane, indamine, indigoid, phthalocyanine and porphyrin substantive dyes, as well as natural substantive dyes. These dyes can be single chromophore dyes (ie containing only one dye) or multiple chromophores, preferably two or three chromophores, even if the chromophores are the same. They may be different, may or may not be derived from the same chromophore. It should be noted that each polychromatic dye contains multiple radicals derived from molecules that absorb in the visible light range of 400 to 800 nm. Moreover, this absorption of the dye does not require prior oxidation or combination with other species. In the case of polychromophore dyes, the chromophores are attached to each other via at least one linker, which can be cationic or non-cationic. Preferably, the linker is a linear, branched or cyclic C1~ C20Alkyl chain of, at least one heteroatom (such as nitrogen or oxygen), and / or at least one group containing such an atom (CO, SO)2) Is inserted in the optional choice, and at least one heterocycle that may or may not be condensed to the phenyl nucleus is inserted in the optional choice, and at least one quaternary nitrogen atom bonded to the above ring and at least one It has one other heteroatom (oxygen, nitrogen, sulfur, etc.) optionally, at least one substituted or unsubstituted phenyl or naphthyl group is optionally inserted, and at least one quaternary ammonium group. C replaced by two optional choices1~ C15Substituted with an alkyl group, the linker has no nitro, nitroso or peroxy groups. If the heterocyclic or aromatic nuclei are substituted, they are, for example, substituted by: hydroxyl, C.1~ C2Alkoxy, C2~ C4Hydroxyalkoxy, acetylamino or one or two C1~ C4One or more Cs substituted with an alkyl group and optionally substituted with an amino group carrying at least one hydroxyl group.1~ C8Alkyl groups, or two groups, together with the nitrogen atom to which they are attached, form a 5- or 6-membered heterocycle that optionally has another heteroatom that is the same as or different from nitrogen. Can be one or more Cs1~ C8Alkyl group; halogen atom; hydroxyl group; C1~ C2Alkoxy group; C2~ C4Hydroxyalkoxy groups; amino groups; one or two identical or different Cs that optionally support at least one hydroxyl group1~ C4Amino group substituted with an alkyl group. Among the benzene-type direct dyes that can be used, the following compounds can be mentioned, but not limited to: - 1,4-Diamino-2-nitrobenzene, - 1-Amino-2-nitro-4-β-hydroxyethylaminobenzene - 1-Amino-2-nitro-4-bis (β-hydroxyethyl) aminobenzene - 1,4-Bis (β-Hydroxyethylamino) -2-nitrobenzene - 1-β-Hydroxyethylamino-2-nitro-4-bis (β-hydroxyethylamino) benzene - 1-β-Hydroxyethylamino-2-nitro-4-aminobenzene - 1-β-Hydroxyethyl Amino-2-nitro-4- (Ethyl) (β-Hydroxyethyl) Aminobenzene - 1-Amino-3-methyl-4-β-hydroxyethylamino-6-nitrobenzene - 1-Amino-2-nitro-4-β-hydroxyethylamino-5-chlorobenzene - 1,2-Diamino-4-nitrobenzene - 1-Amino-2-β-Hydroxyethylamino-5-Nitrobenzene - 1,2-Bis (β-Hydroxyethylamino) -4-nitrobenzene --- 1-Amino-2-tris (Hydroxymethyl) Methylamino-5-Nitrobenzene - 1-Hydroxy-2-amino-5-nitrobenzene - 1-Hydroxy-2-amino-4-nitrobenzene - 1-Hydroxy-3-nitro-4-aminobenzene - 1-Hydroxy-2-amino-4,6-dinitrobenzene - 1-β-Hydroxyethyloxy-2-β-Hydroxyethylamino-5-nitrobenzene - 1-Methoxy-2-β-Hydroxyethylamino-5-nitrobenzene - 1-β-Hydroxyethyloxy-3-methylamino-4-nitrobenzene - 1-β, γ-dihydroxypropyloxy-3-methylamino-4-nitrobenzene - 1-β-Hydroxyethylamino-4-β, γ-dihydroxypropyloxy-2-nitrobenzene - 1-β, γ-dihydroxypropylamino-4-trifluoromethyl-2-nitrobenzene - 1-β-Hydroxyethylamino-4-trifluoromethyl-2-nitrobenzene --- 1-β-Hydroxyethylamino-3-methyl-2-nitrobenzene - 1-β-Aminoethylamino-5-methoxy-2-nitrobenzene - 1-Hydroxy-2-chloro-6-ethylamino-4-nitrobenzene - 1-Hydroxy-2-chloro-6-amino-4-nitrobenzene - 1-Hydroxy-6-bis (β-hydroxyethyl) amino-3-nitrobenzene - 1-β-Hydroxyethylamino-2-nitrobenzene - 1-Hydroxy-4-β-Hydroxyethylamino-3-nitrobenzene. For azo, azomethine, methine and tetraazapentamethine direct dyes that can be used in accordance with the present invention, the cationic dyes described in patent applications WO95 / 15144, WO95 / 01772 and EP714954, FR2189006, FR2285851, FR2140205, EP1378544 and EP1674073. Can be mentioned. Thus, in particular, the following dyes of formulas (I) to (IV), preferably compounds of formulas (I) and (III), can be mentioned:<chemistry num="4"><img file="JP2010143918A_D0004.tif" /></chemistry> [During the ceremony, D represents a nitrogen atom or -CH group R1And R2Can be the same or different, hydrogen atom; -CN, -OH or NH2It may be substituted with a group, or it may be combined with the carbon atom of the benzene ring to form a heterocycle with an optional oxygen or nitrogen C.1~ C4Alkyl group (this heterocycle is one or more Cs1~ C4May be substituted with an alkyl group); represents a 4'-aminophenyl group, R3And R'3Can be the same or different, hydrogen atoms, or halogen atoms selected from chlorine, bromine, iodine and fluorine, or cyano, C.1~ C4Alkyl, C1~ C4Represents an alkoxy or acetyloxy group X-Represents an anion preferably selected from chlorine, methyl sulphate and acetic acid, A represents a group selected from the following structures A1 to A18, with A1, A4, A7, A13 and A18 being more advantageous]<chemistry num="5"><img file="JP2010143918A_D0005.tif" /></chemistry> [In the formula, R4May be substituted with a hydroxyl group C1~ C4Represents an alkyl group, R5Is the following C1~ C4Represents an alkoxy group]<chemistry num="6"><img file="JP2010143918A_D0006.tif" /></chemistry> [During the ceremony, R6Is a hydrogen atom or C1~ C4Represents an alkyl group R7Represents a hydrogen atom, an alkyl group optionally substituted with a -CN group or an amino group, a 4'-aminophenyl group, or R6Along with, optionally containing oxygen and / or nitrogen, C1~ C4Forming a heterocycle that may be substituted with an alkyl group, R8And R9May be the same or different, such as hydrogen atoms, such as halogen atoms such as bromine, chlorine, iodine or fluorine, C.1~ C4Alkyl or C1~ C4Represents an alkoxy group or a CN group X-Represents an anion preferably selected from chlorine, methyl sulphate and acetic acid, B represents a group selected from the following B1 to B6 structures]<chemistry num="7"><img file="JP2010143918A_D0007.tif" /></chemistry> [In the formula, R10Is C1~ C4Represents an alkyl group, R11And R12Can be the same or different, hydrogen atom or C1~ C4Represents an alkyl group]<chemistry num="8"><img file="JP2010143918A_D0008.tif" /></chemistry> [During the ceremony, R13Is a hydrogen atom, C1~ C4Represents an alkoxy group or a halogen atom such as bromine, chlorine, iodine or fluorine. R14Is a hydrogen atom, C1~ C4It represents an alkyl group or, in combination with the carbon atom of the benzene ring, optionally contains oxygen and / or one or more Cs.1~ C4Forming a heterocycle that may be substituted with an alkyl group, R15Represents a hydrogen atom or a halogen atom such as bromine, chlorine, iodine or fluorine. R16And R17Can be the same or different, hydrogen atom or C1~ C4Represents an alkyl group D1And D2Represents a hydrogen atom or -CH group, which may be the same or different m = 0 or 1, preferably 1. R13When represents an unsubstituted amino group, D1And D2At the same time represents the -CH group, understood to be m = 0, X-Represents an anion preferably selected from chlorine, methyl sulphate and acetic acid, E represents a group selected from the structures of E1, E2 and E7 below, more specifically E1, E2 and E7]<chemistry num="9"><img file="JP2010143918A_D0009.tif" /></chemistry> [In the formula, R'is C1~ C4Represents an alkyl group At m = 0, D1When is a nitrogen atom, E can also represent a group of structure E9:<chemistry num="10"><img file="JP2010143918A_D0010.tif" /></chemistry> [In the formula, R'is C1~ C4Represents an alkyl group. ]<chemistry num="11"><img file="JP2010143918A_D0011.tif" /></chemistry> [During the ceremony, The symbol G is the following structure G1From G3Represents a group selected from]<chemistry num="12"><img file="JP2010143918A_D0012.tif" /></chemistry> [In the formula, structural structure G1From G3Ha: R18Is C1~ C4Alkyl group, C1~ C4Represents a phenyl group that may be substituted with an alkyl group, or a halogen atom selected from chlorine, bromine, iodine or fluorine. R19Is C1~ C4Represents an alkyl or phenyl group R20And R21Can be the same or different, C1~ C4Represents an alkyl group, a phenyl group, or G1In, one or more C1~ C4Alkyl, C1~ C4Alkoxy or NO2Benzene rings substituted with groups are formed together or G2In, one or more C1~ C4Alkyl, C1~ C4Alkoxy or NO2Benzene rings optionally substituted with groups are formed together to form R20May represent a hydrogen atom, Z is an oxygen or sulfur atom, or -NR19Represents a group M is -CH, -CR (R is C1~ C4(Representing alkyl) or -NR22(X-)rRepresents a group K is -CH, -CR (R is C1~ C4(Representing alkyl) or -NR22(X-)rRepresents a group P is -CH, -CR (R is C1~ C4(Representing alkyl) or -NR22(X-)rRepresents a group r represents 0 or 1 R22Is O-Atom, C1~ C4Alkoxy group, or C1~ C4Represents an alkyl group R23And R24Can be the same or different, a hydrogen atom or a halogen atom selected from chlorine, bromine, iodine and fluorine, C1~ C4Alkyl or C1~ C4Alkoxy group, or NO2Represents a group X-Represents an anion preferably selected from chlorine, iodine, methyl sulphate, ethyl sulphate, acetic acid and perchloric acid. However, R22But O-When representing, r represents 0, K or P or M is -N- (C1~ C4) Alkyl X-When representing, R23Or R24Is preferably a non-hydrogen atom, K is -NR22(X-)rWhen representing, M = P = -CH, -CR, M is -NR22(X-)rWhen representing, K = P = -CH, -CR, P is -NR22(X-)rWhen representing, K = M and -CH or -CR, Z represents a sulfur atom, R21But C1~ C4When representing alkyl, R20Is other than hydrogen, Z is -NR22Represents R19Is C1~ C4When representing alkyl, structure G2R of the base18, R20Or R21At least one of the bases of1~ C4Other than alkyl groups, The symbol J represents: -(a) Structure J below1Based on]<chemistry num="13"><img file="JP2010143918A_D0013.tif" /></chemistry> [In the formula, structure J1Is: R25Is a halogen atom selected from hydrogen atom, chlorine, bromine, iodine and fluorine, C1~ C4Alkyl or C1~ C4Alkoxy group, -OH, -NO2, -NHR28, -NR29R30Or C1~ C4-Represents an NHCO alkyl group or R26Together with, they form a 5- or 6-membered ring that optionally contains one or more heteroatoms selected from nitrogen, oxygen and sulfur. R26Is a halogen atom selected from hydrogen atom, chlorine, bromine, iodine and fluorine, C1~ C4Alkyl or C1~ C4Represents an alkoxy group or R27Or R28Together with, they form a 5- or 6-membered ring that optionally contains one or more heteroatoms selected from nitrogen, oxygen and sulfur. R27Is a hydrogen atom, -OH group, group NHR28Or NR29R30Represents R28Is a hydrogen atom, C1~ C4Alkyl group, C1~ C4Monohydroxyalkyl, C2~ C4Represents a polyhydroxyalkyl group or a phenyl group R29And R30Can be the same or different, C1~ C4Alkyl group, C1~ C4Monohydroxyalkyl, or C2~ C4Represents a polyhydroxyalkyl group -(B) 5- or 6-membered nitrogen-containing heterocyclic group, which may contain other heteroatoms and / or carbonyl groups and may contain one or more Cs.1~ C4It may be substituted with an alkyl, amino or phenyl group, in particular the following structure J2Is the basis of. ]<chemistry num="14"><img file="JP2010143918A_D0014.tif" /></chemistry> [In the formula, structure J2Is: R31And R32Can be the same or different, hydrogen atom, C1~ C4Represents an alkyl or phenyl group Y is the -CO- group or<chemistry num="15"><img file="JP2010143918A_D0015.tif" /></chemistry> Represents a group When n = 0 or 1, and n represents 1, then U represents the -CO- group. ] In the structures (I) to (IV) defined above, C1~ C4The alkyl or alkoxy group preferably represents methyl, ethyl, butyl, methoxy or ethoxy. Among the compounds of formulas (I) to (III), the following compounds are preferred:<chemistry num="16"><img file="JP2010143918A_D0016.tif" /></chemistry> Further azo direct dyes that can be mentioned include the following dyes listed in the 3rd edition of Color Index International: --Dispar thread 17 --Basic Red 22 --Basic Red 76 --Basic Yellow 57 --Basic Brown 16 --Basic Brown 17 --Disperse Black 9. Further, 1- (4'-aminodiphenylazo) -2-methyl-4-bis (β-hydroxyethyl) aminobenzene can also be mentioned. The quinone substantive dyes that can be mentioned are the following dyes: --Dispar thread 15 --Solvent Violet 13 --Disperse Violet 1 --Disperse Violet 4 --Disperse Blue 1 --Disperse Violet 8 --Disperse Blue 3 --Disperse Red 11 --Disperse Blue 7 --Basic Blue 22 --Disperse Violet 15 --Basic Blue 99 And, in addition, the following compounds: - 1-N-Methylmorpholinium propylamino-4-hydroxyanthraquinone - 1-Aminopropylamino-4-methylaminoanthraquinone - 1-Aminopropylaminoanthraquinone --5-β-Hydroxyethyl-1,4-diaminoanthraquinone --2-Aminoethylaminoanthraquinone - 1,4-Bis (β, γ-dihydroxypropylamino) anthraquinone. Adin dyes that can be mentioned include the following compounds: --Basic Blue 17 --Basic Red 2. Triarylmethane dyes that can be used in accordance with the present invention include the following compounds: --Basic Green 1 --Basic Violet 3 --Basic Violet 14 --Basic Blue 7 --Basic Blue 26. Indoamine dyes that can be used in accordance with the present invention include the following compounds: - 2-β-Hydroxyethylamino-5- [bis (β-4'-hydroxyethyl) amino] anilino-1,4-benzoquinone - 2-β-Hydroxyethylamino-5- (2'-methoxy-4'-amino) anilino-1,4-benzoquinone --3-N-(2'-Chloro-4'-Hydroxy) Phenylacetylamino-6-Methoxy-1,4-benzoquinoneimine --3-N- (3'-Chloro-4'-Methylamino) Phenylureide-6-Methyl-1,4-benzoquinoneimine --3- [4'-N- (ethyl, carbamilmethyl) amino] Phenylureide-6-methyl-1,4-benzoquinoneimine. Tetraazapentamethine-type dyes that can be used include the following compounds listed in the table below:<tables num="1"><img file="JP2010143918A_D0017.tif" /></tables> X-Preferred represents an anion selected from chlorine, iodine, methyl sulphate, ethyl sulphate, acetic acid and perchloric acid. For polyaromatic staining, more specifically, at least one optionally condensed, further at least one quaternary nitrogen atom attached to a heterocycle and at least one other optionally. Substituted with at least one optional, having a 5- or 6-membered aromatic heterocycle with a heteroatom (nitrogen, sulfur, oxygen, etc.) and optionally having at least one group OR. It has a phenyl or naphthyl group, where this R is a hydrogen atom, optionally substituted C1~ C6Alkyl group, optionally substituted phenyl nuclei, or at least one group N (R')2This R'can be the same or different, hydrogen atom, optionally substituted C1~ C6Represents an alkyl group or an optionally substituted phenyl nucleus, the group R', together with the nitrogen atom to which they are bonded, optionally forms a saturated 5- or 6-membered heterocycle. Or, or instead, one and / or both of the groups R', together with the carbon atoms of the aromatic ring located ortho with respect to the nitrogen atom, are 5- or 6-membered saturated. Examples include symmetric or asymmetric azo and / or azomethine (hydrazone) two or three chromophore dyes that may form a heterocycle. Preferred aromatic-cationic heterocycles, which may be mentioned, have 1 to 3, preferably 1 or 2 nitrogen atoms, one of which is a quaternary 5- or 6-membered ring, and the like. There is a heterocycle in which the heterocycle is optionally fused to the benzene nucleus. It should also be noted that the heterocycle may optionally have another heteroatom other than nitrogen, such as sulfur or oxygen. If the heterocycle or phenyl or naphthyl groups are substituted, they are, for example, substituted by: hydroxyl, C1~ C2Alkoxy, C2~ C4One or two Cs carrying hydroxyalkoxy, acetylamino or at least one hydroxyl group optionally1~ C4One or more Cs optionally substituted with an amino group substituted with an alkyl group1~ C8Alkyl groups or two groups can be combined with the nitrogen atom to which they are attached to form a 5- or 6-membered heterocycle, optionally having another heteroatom that is the same as or different from nitrogen 1 One or more Cs1~ C8Alkyl group; halogen atom; hydroxyl group; C1~ C2Alkoxy group; C2~ C4Hydroxyalkoxy groups; amino groups; one or two same or different Cs that optionally support at least one hydroxyl group1~ C4Amino group substituted with an alkyl group. These polychromic groups are saturated or unsaturated and may or may not be optionally attached to an aromatic heterocycle, and at least one linker containing at least one quaternary nitrogen atom optionally. Are combined through. Preferably, the linker is at least one heteroatom (such as nitrogen or oxygen) and / or at least one group having such a heteroatom (CO or SO).2) Is optionally inserted and may or may not be fused to the phenyl nucleus, at least one heterocycle is optionally inserted and at least one quaternary nitrogen atom attached to the ring and Optionally having at least one other heteroatom (oxygen, nitrogen, sulfur, etc.), at least one substituted or unsubstituted phenyl or naphthyl group optionally inserted, and optionally at least one quaternary C in which the ammonium group is substituted with two optional choices1~ C15Linear, branched or cyclic C substituted with alkyl groups1~ C20It is an alkyl chain and this linker has no nitro, nitroso or peroxy groups. Bonding of the linker to each chromophore is generally done via a heteroatom substituent on the nucleus of phenyl or naphthyl or via the quaternary nitrogen atom of the cationic heterocycle. The dye can contain the same or different chromophores. Examples of such dyes are, in particular, EP1637566, EP1619221, EP1634926, EP1619220, EP1672033, EP1671954, EP1671955, EP1679312, EP1671951, EP167952, EP167971, WO06 / 063866, WO06 / 063867, WO06 / 063868, WO06 / 063869, EP1408919. , EP1377264, EP1377262, EP1377261, EP1377263, EP1399425, EP1399117, EP1416909, EP1399116 and EP1671560. It is also possible to use the cationic direct dyes described in the following patent applications: EP1006153, cationic or which describes dyes with two anthraquinone-type chromophores attached via a cationic linker. It has EP1433472, EP1433474, EP1433471 and EP1433473, which describe the same or different dichromophore dyes attached via a non-cationic linker, and three chromophores, one of which is the anthraquinone chromophore, where EP6291333 specifically describes dyes in which two chromophores of the azo or diazacarbosianin form or their isomers are attached. Natural substantive dyes that can be used include Lauson, Juglone, Alizarin, Purpurin, Carminic Acid, Kermesic Acid, Purprogalin, Protocatecaldehyde, Indigo, Isatin, Curcumin, Spinulosin, Apigenidine and Orcein. Extracts or simmered products containing these natural dyes, especially henna-based paps or extracts, can also be used. When present, the direct dye, more specifically, accounts for 0.0001% to 10% by weight, preferably 0.005% to 5% by weight, based on the total weight of the composition. The composition (B) used in the dyeing method can contain one and / or other dyes, optionally two dyeing compositions, one containing an oxidative dye and the other a direct dye. It can also correspond to a thing. The composition (B) used in the dyeing method or the lightening method can be an aqueous or non-aqueous composition. The term "aqueous composition" means a composition comprising more than 5% by weight, preferably more than 10% by weight, and even more preferably more than 20% by weight. Preferably, the composition (B) is an aqueous composition. The composition may optionally contain an organic solvent. Examples of organic solvents that can be mentioned include C such as ethanol and isopropanol.2~ C4Linear or branched alkanols, glycerol, polyols and polyol ethers such as 2-butoxyethanol, propylene glycol, dipropylene glycol, propylene glycol monomethyl ether, and diethylene glycol monomethyl ether and monoethyl ether, as well as benzyl alcohol or phenoxyethanol, etc. There are aromatic alcohols, and mixtures thereof. If a solvent is present, its content is usually based on the weight of the composition (B), 1 wt% to 40 wt% of the range circumference, preferably in the range from 5% to 30% by weight. The cosmetic composition (B) is further mentioned in the context of the composition (A), such as anionic, cationic, nonionic, amphoteric or zwitterionic surfactants or theirs. Mixtures, anionic, cationic, nonionic, amphoteric or zwitterionic polymers or mixtures thereof, inorganic thickeners, especially fillers such as clay, talc, especially anionic, cationic, nonionic and Various organic thickeners containing polymer-binding thickeners, antioxidants, penetrants, metal ion blockers, fragrances, dispersants, film-forming agents, conditioners, ceramides, preservatives, opalescent agents, etc. Auxiliary agents can also be included. The above-mentioned auxiliary agents are generally present in an amount of 0.01% by weight to 20% by weight, respectively, based on the weight of the composition (B). The composition may also contain one or more organic thickeners. These thickeners include fatty acid amides (coconut monoethanolamide or diethanolamide, oxyethylated alkyl ether carboxylic acid monoethanolamide), polymeric thickeners, such as cellulose-based thickeners (hydroxyethyl cellulose, hydroxypropyl). Cellulose or Carboxymethyl Cellulose), Guar Gum and Derivatives thereof (Hydroxypropyl Guar), Microbial Derived Gum (Xanthan Gum, Sclerogulcan Gum), Acrylic Acid or acrylamide Propanosulonic Acid Crosslinked Homopolymers and Associated Polymers (in Aqueous Medium) Can be selected from polymers with hydrophilic regions and hydrophobic regions of the fatty chain (alkyl or alkenyl having at least 10 carbon atoms) that can reversibly bind to each other or to other molecules. .. In one particular embodiment, the organic thickener is a cellulose-based thickener (hydroxyethyl cellulose, hydroxypropyl cellulose or carboxymethyl cellulose), guar gum and derivatives thereof (hydroxypropyl guar), gums derived from microorganisms. (Xanthan gum, screlogulcan gum) and acrylic acid or acrylamide propanesulfonic acid crosslinked homopolymers, preferably those containing cellulose-based thickeners, especially hydroxyethyl cellulose. If an organic thickener is present, its content is typically in the range of 0.01% to 20% by weight, preferably 0.1% by weight to 5% by weight, based on the weight of the composition. .. Finally, the method is carried out using the composition (C) containing one or more oxidizing agents. More specifically, the oxidants are hydrogen peroxide, urea peroxide, bromic acid or ferricyanide alkali metal salts and peroxide salts, such as alkali metal or alkaline earth metal persulfates, perboric acid or percarbonates. It is selected from salts, and peracids and their precursors. This oxidant is advantageously composed of hydrogen peroxide, especially as an aqueous solution (aqueous hydrogen peroxide solution), the concentration of which is more specifically 0.1% to 50% by weight of the weight of the oxidation composition. More specifically, it can range from 0.5% to 20%, and more preferably from 1% to 15%. Depending on the desired degree of lightening, the oxidizing agent may also preferably contain an oxidizing agent selected from the peroxide salts. Preferably, when the method is a staining method, the oxidant is not selected from salts and peracids, as well as precursors. The oxidation composition can be aqueous or non-aqueous. The term "aqueous composition" means a composition comprising more than 5% by weight, preferably more than 10% by weight, and even more preferably more than 20% by weight. Preferably, the composition (C) is an aqueous composition. The composition may also contain one or more organic solvents. Examples of organic solvents that can be mentioned are linear or branched C.2~ C4Alkanol, eg ethanol and isopropanol; glycerol; polyol and polyol ether, eg 2-butoxyethanol, propylene glycol, dipropylene glycol, propylene glycol monomethyl ether, diethylene glycol monomethyl ether and monoethyl ether, and even aromatic alcohols, eg, There are benzyl alcohol or phenoxyethanol, as well as mixtures thereof. When the solvent is present, its content is typically in the range of 1% to 40% by weight, preferably in the range of 5% to 30% by weight, based on the weight of the oxidized composition (C). .. The oxidation composition can also contain one or more acidifying agents. Examples of acidifying agents that may be mentioned include inorganic or organic acids such as hydrochloric acid, ortholic acid, sulfuric acid and the like, carboxylic acids such as acetic acid, tartaric acid, citric acid or lactic acid and the like, and sulfonic acids. Generally, the pH of the oxidizing composition (C) is less than 7 when it is aqueous. The oxidation composition (C) can also contain other components conventionally used in the art, particularly those already detailed in the context of the compositions (A) and (B). Ultimately, the oxidation composition (C) takes various forms, such as solvents, emulsions or gels. In the first aspect of the present invention, the composition obtained by mixing the above-mentioned anhydrous composition (A), the above-mentioned composition (B) and the above-mentioned aqueous oxidation composition (C) on the spot at the time of use. Is applied to moist or dry keratin fibers. In this embodiment, the weight ratio R1 of the amount of the composition (A) + (B) / (C) and the weight ratio R2 of the amount of the composition (A) / (B) are in the range of 0.1 to 10, preferably 0.3. Take the range from to 3. Preferably, when the method is a staining method, the weight ratio R1, (A) + (B) / (C) ranges from 0.5 to 1. In a second aspect of the method, the compositions (A), (B) and (C) are applied continuously to moist or dry keratin fibers without rinsing in between. Preferably, the composition (A), then (B), then (C) or (B), then (A), and then (C) is applied. In another aspect, the composition (C), then the mixture obtained from the compositions (A) and (B), can be applied continuously without rinsing in between. In these two embodiments, the weight ratio R1 of the amount of composition (A) + (B) / (C) and the weight ratio R2 of the amount of composition (A) / (B) are more specifically 0.1. It ranges from to 10, preferably 0.3 to 3. Moreover, regardless of the mode in which it is used, the mixture present on the fiber (caused by an in-situ mixing or partial or completely continuous application of the compositions (A), (B) and (C)) Generally, it is left for about 1 minute to 1 hour, preferably about 5 to 30 minutes. The temperature in the method has traditionally been between room temperature (15-25 ° C) and 80 ° C, preferably between room temperature and 60 ° C. After treatment, human keratin fibers are optionally rinsed with water, optionally washed with shampoo, then rinsed with water and then dried or left to dry. If the composition applied to the hair (containing compositions (A), (B) and (C)) contains aqueous ammonia or a salt thereof, the content is relative to the weight of the final composition. (NH3It is pointed out that the weight of the final composition (represented as) is 0.03% by weight or less, and more specifically, 0.01% by weight or less. The final composition is obtained from a mixture of compositions (A), (B) and (C), which mixture is prior to application of the keratin fibers (in-situ preparation) or directly on the keratin fibers (premix). Continuous application with or without, does not rinse in between) is shown to be done. If the composition contains aqueous ammonia or a salt thereof, the amount of basalizing agent is (NH3It is preferably greater than the amount of ammonia water (represented as). However, the compositions (A), (B) and (C) preferably do not contain aqueous ammonia. In one embodiment, the composition according to the invention obtained after mixing the compositions (A), (B) and (C) described above is such that after mixing, the amount of fatty material exceeds 20% by weight. Preferably, it exceeds 25% by weight, and even more preferably, it exceeds 30% by weight. The following examples are for the purpose of explaining the present invention, and are not limited to that.

(Staining Example 1) The following compositions are prepared (unless otherwise noted, the unit of quantity is g%).

At the time of use, mix the following: - 10 parts by weight composition A 4 parts by weight composition B1 --15 parts by weight Platinium international 20-volumes oxidizer (Amount of hydrogen peroxide: 6% by weight)

Each mixture is then applied to a natural hair tress (NG) containing 90% gray hair and a permanent-waved hair tress (PWG) containing 90% gray hair. ..

The bath ratio of the "mixture / bundle" is 10/1 (g / g), respectively.

The leaving time is 30 minutes at 27 ° C.

After this time, the hair tresses are rinsed, washed with Elvive Multivitamin Shampoo and dried.

The composition of the present invention exhibits a strong, difficult-to-select gloss effect.

(Staining Example 2) The following compositions are prepared (unless otherwise noted, the unit of quantity is g%).

Each mixture is then applied to a natural hair tress (NG) containing 90% gray hair and a permanent-waved hair tress (PWG) containing 90% gray hair. ..

The bath ratio of the "mixture / bundle" is 10/1 (g / g), respectively.

The leaving time is 30 minutes at 27 ° C.

After this time, the hair tresses are rinsed, washed with Elvive Multivitamin Shampoo and dried.

The compositions of the present invention are very bronze and exhibit a dyeing effect that is almost non-selective.

(Lightening Example 3) Prepare the following compositions (unless otherwise noted, the unit of quantity is g%).

At the time of use, mix the following: - 10 parts by weight composition A 4 parts by weight of composition B1 or composition B2 --15 parts by weight Platinium international 20-volumes oxidizer (Amount of hydrogen peroxide: 6% by weight)

Each mixture is then applied to a bundle of natural hair (tone depth 4).

The bath ratio of the "mixture / bundle" is 10/1 (g / g), respectively.

The leaving time is 30 minutes at 27 ° C.

After this time, the hair tresses are rinsed, washed with Elvive Multivitamin Shampoo and dried.

result The pH of the mixture obtained with composition B1 is the same as the pH obtained with composition B2, i.e. pH = 9.9.

Hair tress coloring is done using the CIE Lab system (light source: D65, angle 10 °, with reflector component) Minolta CM2600d, CIE L*a*b Measured by the system.

Brightening is performed according to the following formula: ΔE*Evaluated by calculating the value of ab: ΔE*ab = [(L*0-L*1)2+ (a*0-a*1)2+ (b*0-b*1)2]1/2In the formula, L*0, A*0And b*0Is the Lab coefficient of the untreated hair bundle, L*1, A*1And b*1Is the Lab coefficient of the lightened hair bundle.

ΔE*The higher the value of ab, the greater the difference in coloration between the untreated and lightened hair bundles, and therefore the more efficient the lightening.

Better lightening can be obtained with composition B1 (invention) than with composition B2 (control).

Every citation, both ways

Citations
Document	Relation	Office	Cited during
JP2014512334A	Cited by	Japan	Search report
JP2004262886A	Cites	Japan	Examiner
WO9704739A1	Cites	World Intellectual Property Organization (WIPO)	Search report
WO9704739A1	Cites	World Intellectual Property Organization (WIPO)	Examiner
JPH11508542A	Cites	Japan	Search report
JPH11508542A	Cites	Japan	Examiner
JPS59106413A	Cites	Japan	Examiner

15 members in 6 offices

This recordMember, by publication datePriority claim

Priority claims10

Priority claims
Document	Office	Kind	Date
0807294	France	A	2008-12-19
0807294	France	A	2008-12-19
0807294	France	–	2008-12-19
0807307	France	A	2008-12-19
0807307	France	A	2008-12-19
0807307	France	–	2008-12-19
2008200807294	–	–	–
2008200807307	–	–	–
FR20080007294	–	–	–
FR20080007307	–	–	–

Members15

Family members, oldest first
Document	Office	Kind
EP2198834A2	European Patent Office (EPO)	A2	2010-06-23
FR2940057A1	France	A1	2010-06-25
FR2940060A1	France	A1	2010-06-25
JP2010143918AThis record	Japan	A	2010-07-01
US2010175706A1	United States of America	A1	2010-07-15
CN101780015A	China	A	2010-07-21
US7909888B2	United States of America	B2	2011-03-22
BRPI0911109A2	Brazil	A2	2012-02-28
EP2198834A3	European Patent Office (EPO)	A3	2012-03-28
FR2940060B1	France	B1	2012-10-12
FR2940057B1	France	B1	2012-10-19
EP2198834B1	European Patent Office (EPO)	B1	2015-03-18
JP5748953B2	Japan	B2	2015-07-15
BRPI0911109B1	Brazil	B1	2017-05-09
BRPI0911109B8	Brazil	B8	2017-05-30

16 legal events, as the office reported them to INPADOC

Over the term

Point at a mark for the event

Events

Legal events, newest first
	Event	Code
2021-05-22	Cancellation because of no payment of annual feesLAPS	LAPS
2020-04-30	Receipt of annual feesJAPANESE INTERMEDIATE CODE: R250R250	R250
2019-05-07	Receipt of annual feesJAPANESE INTERMEDIATE CODE: R250R250	R250
2018-05-08	Receipt of annual feesJAPANESE INTERMEDIATE CODE: R250R250	R250
2015-05-22	Certificate of patent or registration of utility modelJAPANESE INTERMEDIATE CODE: R150R150	R150
2015-05-21	First payment of annual fees (during grant procedure)JAPANESE INTERMEDIATE CODE: A61A61	A61
2015-04-14	Written decision to grant a patent or to grant a registration (utility model)JAPANESE INTERMEDIATE CODE: A01A01	A01
2015-04-01	Decision of grant or rejection writtenTRDD	TRDD
2015-02-18	Transfer to examiner for re-examination before appeal (zenchi)AppealJAPANESE INTERMEDIATE CODE: A911A911	A911
2015-02-05	Written amendmentJAPANESE INTERMEDIATE CODE: A523A521	A521
2014-10-15	Decision of refusalJAPANESE INTERMEDIATE CODE: A02A02	A02
2014-04-08	Written amendmentJAPANESE INTERMEDIATE CODE: A523A521	A521
2014-01-08	Notification of reasons for refusalJAPANESE INTERMEDIATE CODE: A131A131	A131
2013-12-19	Report on retrievalJAPANESE INTERMEDIATE CODE: A971007A977	A977
2012-07-21	Written amendmentJAPANESE INTERMEDIATE CODE: A523A521	A521
2012-07-21	Written request for application examinationJAPANESE INTERMEDIATE CODE: A621A621	A621

Method for coloring or lightening human keratinous fiber by using anhydrous composition and monoethanolamine/basic amino acid mixture, and device appropriate therefor

Abstract

Term

Priority claims10

Members15

Over the term

Events

Numbers

Titles2

Classification