Polytriazine compositions characterized as a reaction product of a polyaromatic cyanate and if desired,another cyanate compound

The present invention relates to polytriazine compositions, prepared from a type of novel polyaromatic cyanates. The novel polyaromatic cyanates are described in copending patent application

No. 73446 from which the present patent application has been divided out.

The novel polytriazine compositions have advantageous properties, and amongst these a very low uptake of water.

Ci 1. |1־< 16 לS

The invention relates to polytriazines/prepared from the polyaromatic cyanates.

It is known from German Patent Specification 5 No. 1,190,184 that high molecular weight polytriazines can be obtained by. polymerizing di functional or polyfunctional aromatic cyanates at elevated temperature, optionally in the presence of polymerization promoters. The polymers are characterize^ for example by their 10 remarkable stability at elevated temperatures and they are duroplastic in character after tempering for a sufficiently long period. The resistance of the polytriazines to acids and various solvents may also be emphasized.

In addition, it was found by V. V. Korchak et al. (cf. Vyso'komolekulyamye Soedineniya 1974, number 1, pages 15 to 21) that the.thermal and thermo-oxidative destruction of polytriazines based on aromatic cyanates is greatly influenced by moisture.

31,877-F /2

Finally, it is known from German Patent 1,720,740 that polyfunctional aromatic cyanates can be combined with powder-form and/or fibrous fillers or reinforcing materials and subjected either to a preliminary’or subsequent heat treatment at about 50’C. to 150°C, the resulting molding composition molded and hardened at temperatures in the range from about 150°C to ‘250°C. In many cases־the resulting moldings alsg show inadequate thermal stability after storage in a moist, tropical atmosphere.

Polytriazines which are hydrolytically stable are needed. Polyaromatic triazines which are thermally stable are further needed.

The invention relates more specifically to polytriazines which are the reaction products of between about 1 to 99 mole per cent of polyaromatic cyanates as hereinafter defined, and between 0 and 99 mole per cent of one or more cyanate containing compounds. There are advantageously used polyaromatic cyanates characterised bv having the formula (Dj.

(NCO-}_g Ar — B---Ar — (OCN) t

- B-----Ar-------(OCN) wherein:

Ar is a benzene, naphthalene, phenanl.hracene , anthracene, biphenyl or binaphthyl, or two or more aromatic radicals bridged by alkylene moieties;

<img file="IL84615A_D0001.tif" />

2a

84615/V

<img file="IL84615A_D0002.tif" />

<img file="IL84615A_D0003.tif" />

<img file="IL84615A_D0004.tif" />

<img file="IL84615A_D0005.tif" />

<img file="IL84615A_D0006.tif" />

and

XIII,

D is a״ alkyl, alkenyl, alkynyl, aryl, alkaryl, aralkyl, halo, alkoxy, nitro, carboxylate^sulfonyl, thio or carbonate moiety;

D¹ is C|_₅ alkyl;

Y is

0 π ״

-CH,,, -S, -S׳or S- ;

.

ט q, r and s are independently in each occurrence the integers 0, 1, 2, or 3; with the proviso that the sum of &lt;1. r and s is greater than or equal to 2;

t is iiidcpendci)Lly in each occur rence an integer of between 0 and 4 inclusive; and x is λ number between 0 and 5 inclusive, and (b) between 0 and 99 mole percent of one or more cyanate־contaוning compounds, which corresponds to the formula Ar-(OCN) wherein Ar is an aromatic radical and n is an integer of between 1 and 5, inclusive.

The process of preparation of these polyaromatic cyanates is characterized by first preparing cyanogen chloride in situ by contacting a solution of chlorine in a chlorinated hydrocarbon with an aqueous solution of alkali metal cyanide. Then the aqueous layer containing the alkalimetal chloride by-product is separated from the chlorinated hydrocarbon layer containing the cyanogen chloride. Then a solution of a polycyclic bridged hydroxy-substituted polyaromatic phenol in a suitable solvent is contacted with the cyanogen chloride solution in the presence of a tertiary amine to prepare the polyaromatic cyanates of this invention.

The invention relates also to polytriazines characterized as being the reaction product of (a) between 1 and 100 mole percent of the polyaromatic cyanate ester as defined and (b) between 0 and 99 mole percent of one or more cyanate-containing compounds known in the art as useful for the preparation of polytriazines.

The novel polytriazines are surprisingly more stable to hydrolysis than prior art polytriazines.

The polytriazincs of this invention can be used as cure-in-place resins or fabricated in the form

31,877-F /2 of shaped articles, where thermal stability., chemical inertness and solvent resistance are desirable or required.

Ar is .1 benzene, naphlliaIene. phennnlhrocene.

anthracene. ״>' l>i״al»btl.yI. ״r two er more aromatic radicals bridrjed by alkylene moletie־;

lycyclic aliphatic radical refers herein to radical which contains two or more cyclic aliphatic radicals may contain double or triple bonds.

to the

Po any aliphatic rings. The polycyclic one or more aliphatic radicals correspond preferred polycyclic formulas

<img file="IL84615A_D0007.tif" />

<img file="IL84615A_D0008.tif" />

׳84615/4

<img file="IL84615A_D0009.tif" />

<img file="IL84615A_D0010.tif" />

<img file="IL84615A_D0011.tif" />

XIII , wherein:

Y is

CH-, -S-,

If

-פor

11

-פו! 0 and D¹ is . alkyl.

כ״1

B is more preferably a radical which corresponds to one of the formulas II, III, IV, V, VI, VII, VIII or XIII with radicals corresponding to formulas II, III, IV, V or XIII being even more preferred, and radicals corresponding to formula II being most preferred.

D is an alkyl, alkenyl, alkynyl, aryl, alkaryl, ’aralkyl', halo, alkoxy, nitro, carboxylate₇sulfonyl₎thio or carbonate moiety;

D¹ is alkyl;

Y is nitro, carboxylate, sulfone, sulfide or carbonate moieties. Preferred.substituents are alkyl,

0_1-10 alkenyl, nitro, and halo moieties, with C₁_₃ alkyl, C, , alkynyl, bromo and chloro moieties being

X “ J most preferred.'

Preferably, q, r and s 'are independently 1 or

2, and are most preferably 1. Preferably, t is independently an integer of 0, 1 or 2, more preferably 0 or 1, and most preferably/O. Preferably, x is between 0 and

2 inclusive, and more preferably between 0 and 1 inclusive.

'The polyaromatic cyanates o-f-tfeie—invention usually exist as a mixture of many isomers. Further, these polyaromatic cyanates usually are found as a mixture of compounds in which x is between .0 'and 5. Usu15 ally the number given for x in a particular mixture is an average number.

In one preferred embodiment the polyaromatic cyanates correspond־to the formula

CCN ד

<img file="IL84615A_D0012.tif" />

Jx wherein x is a real number of between 0 and 5, inclusive.

The polyaromatic cyanate esters of this invention are generally prepared by contacting a suitable 25 polyaromatic phenol with cyanogen chloride, in the

31,877-F presence of a tertiary amine. It is preferable to preparethe cyanogen chloride in situ by contacting a solution of chlorine in a chlorinated hydrocarbon solvent with an aqueous solution of an alkali metal cyanide. The reaction mixture separates into an organic layer of the chlorinated hydrocarbon containing the cyanogen chloride and an aqueous layer containing the alkali metal chloride salt. Generally, the alkali metal cyanide and.chlorine are reacted in a molar ratio of between 1.0:1.0 and 1.0:1.15, preferably between 1.011.0 and 1.0:1.05; and most preferably 1.0:1.0. An ־ excess of either may result in undesirable consequences, .that is, excess chlorine may later react with the phenol, and excess alkali metal cyanide may result in a lower product purity. This contacting is done at a temperature of 0^eC or below, preferably less than -15°C. Above 0°C the cyanog.en chloride will trimerize. Preferable solvents for the chlorine are the aliphatic chlorinated hydrocarbons, such as, for example, methyl chloride, chloroform, and. 1,1,1-trichloroethane. The preferred alkali metal cyanide is sodium .cyanide. .

•

The aqueous layer and organic layer are then separated. The separation of the organic layer from the aqueous layer is advantageous as the presence of the. aqueous layer in further processing adversely affects the purity of the polyaromatic cyanates eventually prepared.

The organic layer containing the cyanogen chloride is then contacted with a polycyclic bridged hydroxy-substituted polyaromatic compound dissolved in a suitable solvent in the presence of a tertiary amine.

31,877-F

-8Polycyclic bridged hydroxy-substituted polyaromatic compounds useful in this process correspond to the formula • ⁽?^}t (HO־» Ar — גי t

B—- Ar(OH)_r (DL. (D) (OH) * 9 wherein Ar, B, D, q, r, s, t and x are as defined־ hereinbefore.

In one' preferred embodiment the polycyclic bridged hydroxy-substituted polyaromatic compounds correspond to the formula

OH wherein x is as defined hereinbefore. The polycyclic bridged hydroxy-substituted polyaromatic Compounds used usually exist as a mixture of isomers. Further, the polycyclic bridged hydroxy-substituted polyaromatic compounds are found as a mixture of compounds־ in which X is between 0 and 5. Usually the number given for x is an average number. The solvents used for the polycyclic bridged hydroxy-substituted polyaromatic .

compounds are secondary alcohols, tertiary alcohols, or chlorinated hydrocarbons. Preferred solvents are secondary alcohols or aliphatic chlorinated hydrocarbons, with isopropyl alcohol and methylene chloride most preferred.

31,877-F

-9The process is preferably done at a temperature of 0°C or below, more preferably -15^eC or below. .

For complete, conversion of the hydroxy moieties on the aromatic radicals to cyanate moieties, at 5 least 1 mole of cyanogen chloride for each hydroxy equivalent is needed. It is preferable to use an excess of 10 mole percent of cyanogen chloride for each hydroxy equivalent .to insure complete conversion.

The tertiary amine acts as a hydrochloride 10 acceptor, and as a result a tertiary amine hydrochloride salt is a by-product of the process. Generally, at least one mole of tertiary amine for.each hydroxy equivalent is used. Hydroxy equivalent refers herein to the average molecular weight of the polycyclic . 15 bridged hydroxy-substituted polyaromatic compound divided by the average number of hydroxy moieties per molecule.

The polyaromatic cyanates can be recovered from the reaction solution in the following manner.

The reaction mixture is first contacted with a dilute aqueous solution of base, such as a bicarbonate, to remove the excess cyanogen chloride. Then the reaction mixture is contacted with water to remove the tertiary .amine hydrogen chlor.ide salt. Thereafter, the reaction 25 solution is contacted with a dilute aqueous acid solution to neutralize any base present. A 1-20 weight percent solution of hydrochloride, phosphoric or sulfuric״ acid can be used, preferably a 5-10 weight percent solution. The reaction solution is then contacted with water to remove any impurities which may be present. The reaction solution is dried over a dessicant to remove the water, and the solvent is stripped off.

31,877-F -9-

ד

The polyaromatic cyanate recovered is of surprisingly high purity and can be used directly to / prepare polytriazines.

The polycyclic bridged hydroxy-substituted polyaromatic compounds useful, in this invention can be prepared by.reacting an .aromatic compound, containing at least one aromatic hydroxy moiety and one position on the aromatic ring which can be alkylated, with an unsaturated polycyclic aliphatic compound under conditions 10 such that a polycyclic bridged hydroxylsubstituted polyaromatic, compound useful in this invention is prepared.

Suitable substituted aromatic'hydroxy compounds which can be employed herein include any such 15 compounds which contain one or two aromatic rings, at least one phenolic hydroxyl group and at least one ortho or para.ring position with respect to a hydroxyl group available for alkylation.

».

Particularly* suitable hydroxy-substituted aromatic compounds which can be employed herein include, for example, phenol, .chlorophenol, bromophenol, methylphenol, hydroquinone, catechol, resorcinol, guaiacol, pyrogallol, phloroglucinol, isopropylphenol, ethylphenol, propylphenol, t-buty!phenol, isobutylphenol, octylphenol, 25 nonylphenol, cumylphenql, p-phenylphenql, o-phenylphenol, m-pheny!phenol, bisphenol A, dihydroxydiphenyl sulfone, or mixtures thereof.

The hydroxy-substituted polyaromatic compound is contacted with the unsaturated polycyclic aliphatic 30 compound optionally in the presence of a solvent.

31,877-F • -10-11Preferred solvents include chlorinated hydrocarbons., aliphatic hydrocarbons, aromatic hydrocarbons and nitro-substituted hydrocarbons. In general the hydroxy-substituted polyaromatic compound is contacted with 5 the unsaturated polycyclic aliphatic compound in a mole ratio of between 20.0:1.0, and 1.0:1.0, preferably between 10.0:1.0 and 1.5:1.0.

These reactants are preferably contacted in . the presence of a catalyst.

10. Acid catalysts which can be employed herein include, for example, Lewis acids, .alkyl, aryl and aralkyl sulfonic acids, and disulfonic, acids of. diphenyloxide and alkylated diphenyioxide, sulfuric .acid, or mixtures thereof. Preferable catalysts are such Lewis acids as BF_ gas, organic complexes of boron trifluoride w .

such as those complexes formed with phenol, cresol, ethanol, or acetic acid. Also Lewis acids include, for example, aluminum chloride, zinc chloride, or stannic . chloride‘. Also catalysts include, for example, activated 20 _clays, silica, or silica-alumina complexes.

In preparing the compounds which contain ah average of more than one phenolic hydroxyl group and more than one aromatic ring per molecule, the reaction between the phenolic hydroxyl-containing compounds and 25 the unsaturated hydrocarbons can be conducted at temperatures of from 33״C to 270^eC, preferably from 33^eC to 210^eC.

The polyaromatic cyanates of this invention are’ useful in preparing polytriazines . The polytria30 zines of this invention comprise the reaction product

31,877-F

-12of (a) between 1 and 100 percent by weight of the polyaromatic cyanate of this invention,_־ and (b) between and 99 percent by weight of a cyanate which is useful . for preparing triazines, such cyanates being well-known to .those skilled in the art. The prior art cyanates useful in this invention include those corresponding to the formula ArfOCN)_n wherein Ar is an aromatic radical, and n is an integer of from 1 to 5. Preferable cyanates include those corresponding to the formula

<img file="IL84615A_D0013.tif" />

wherein each R is the same or different and repre15 sents hydrogen, halogen, straight and branched ^cl־^c20 ^al^yl׳ phenyl, alkoxy radicals having from . 1 to 4 carbon atoms, alkoxy carbonyl radicals hav.ing from 1 to 4 carbon atoms in the alkyl group;' or two adjacent radicals R on the same nucleus may 20 together form a carbocyclic 5- or 6-membered ring,.

two adjacent radicals R may, together with a hetero atom (0, S, N), form a 5- or 6-membered heterocyclic ring,

R’ has the same meaning as R or represents 25 the group

31,877-F

<img file="IL84615A_D0014.tif" />

(R)_b (OCN)_d

A represents a direct bond, a C.-C״ alkylene

X X v group optionally substituted by 0_χ₄ alkyl or phenyl, a cycloaliphatic or aromatic 5- or 6-membered ring optionally interrupted by oxygen,, a sulfonyl group (-SO₂-), a carbonyl dioxide .10 group, (-OCO-) 11 0 or a carbonyl group;

a.represents a number of from 1 to 5 when ®SI, and a.number of from 2 to 5 when e=0;

b represents 5-a when eSl and 6-(a+d) when e=0; .־ c represents 5-d;

d represents a number of from 0 to.5, and e represents 0, 1, 2 or 3, with a proviso that the sum of a and d is always a number from 2 to 5.

The following compounds are specifically mentioned as examples of conventional cyanates within one or more of the formulas noted above: 1,3- and 1,4-dicyanatobenzene, 2-tert-butyl-l,4-dicyanatobenzene,

31,877-F

-142,4-dimethyl-l,3-dicyanatobenzene, 2,5-di-tert-butyl-1,4-dicyanatobenzene, tetramethyl-1,4-dicyanatobenzene,

2,4,6-trimethyl-l,3-dicyanatobenzene, 4-chloro-l,3-dicya. natobenzene, 1,3-, 1,4-, 1,5-/1,6-, 1,7-, 1,8-, 2,6- or.

2,7-dicyahatonaphthalene, 1,.3,5-tricyanatobenzene; 4,4'-.dicyanatodiphenyl, 2,2'-dicyanatodiphenyl,5,5 ,' 3,3 ׳ '-tetramethyl-4., 4'-dicyanatodiphenyl, 3,3 ', 5,5 '-tetrachloro-4,'4 ׳ -dicyanatodiphenyl,. 3,3',5,5 ׳-tetrachloro-2,2'-dicyanatodiphenyl,. 2,2 ' ,.6,6 ' -tetrachloro-4,4¹ -dicyanatodiphenyl׳,

10. 4,4'-bis-[(3-cyanato)-phenoxy]-diphenyl, 4,4'-bis-[(4-cy-^,. anato)-phenoxy]-diphenyl; 2,2'-dicyanato-1,1'-binaphthyl;. 4,4'-dicyanatodiphenyl ether, 3., 3 ', 5,5 ' - tetramethyl-4,4 ׳ -dicyanatodiphenyl ether,. 3,3',5,5'-tetrachloro-4;4'-dicyanatodiphenyl ether, 4,4’-bis-[p-cyanatophenoxy]-diphe15 nyl ether, 4,4'-bis-[p-cyanatophenylisopropyl]-diphenyl ether, 4,4¹-bis-[p-cyanatophenoxy]-benzene, 4,4'-bis-[m-cyanatophenoxy]-diphenyl ether, 4,4'-bis-[4-(4-cyanatophenoxy)-phenyl sulfone]-diphenyl ether; 4,4׳-dicyanatodiphenyl sulfone, 3,3',5,5'-tetramethyl-4,4'-dicyanato20 diphenyl sulfone, 3,3 ', 5-, 5 ׳-tetrachloro-4,4' -dicyanato• diphenyl sulfone, 4,4'-bis-[p-cyanatophenylisopropyl]-diphenyl sulfone, 4,4¹ -bis-['(4-cyariato)-phenoxy]-diphenyl sulfone, 4,4'-bis-[(3-cyanato)-phenoxy]-diphenyl sulfone, 4,4'-bis-[4-(4-cyanatophenylisopropyl)-phenoxy]25 -diphenyl sulfone, 4,4'-bis-[4-cyanatophenyl־sulfone)-jphenoxy]-diphenyl. sulfone, .4,4'-bis-[4-(4-cyanato)-diphenoxy]-diphenyl sulfone, 4,4׳-dicyanatodiphenyl methane, 4,4'-bis-[p-cyanatophenyl]-diphenyl methane, 2,2-bis-(p-cyanatophenyl)-propane, 2,2-bis-(3,5-dimethy1_T

-4-cyanatophenyl)-propane, 2,2-bis-(3,5-dichloro-4-cyanatophenyl)-propane, 1,1-bis-[p-cyanatophenyl]-cyclohexane, bis-[2-cyanato-l-naphthyl]-methane, 1/2-bis-[p-cyanatophenyl]-1,1,2,2-tetramethyl ethane, 4,4'-dicyanatobenzophenone, 4,4'-bis-(4-cyanato)-phenoxybenzophenone,

31,877-F

-15.. ./.,. . ' . .

1,4-bis-[p-cyanatophenylisopropylj-benzene, 2,2 ',5,5'-tetracyariatodiphenyl sulfone; polycyanic acid esters of novolaks (reaction products of phenol &lt;?r alkyl- or halogen-subs.tituted phenols with formaldehyde in. acid solution) having from 3 to 5.OCN groups and the like. . Preferred conventional .cyanate containing compounds include 2,2-bis(p-cyanatophenyl)-propane and 2,3-bis(3,5-dibromo-4-cyanatophenyl)-propane.

The polytriazines of this invention prefer- ‘ 10 ably comprise thia reaction product of. (a) between 25 and 100 percent by weight of the polyaromatic cyanates ®£ this invention, and (b) between 0 and 75 percent by. ., weight of a cyanate which is useful in preparing polytriazines. More preferably, the polytriazines of this 15 invention comprise the reaction product (a) between 50 and 100 percent by weight“of a polyaromatic cyanate of this invention, and (b) between 0 and 50 percent by weight of a cyanate useful in preparing polytriazines. The prior art cyanates may comprise mono-, di- and 20 polycyanates.

The polytriazines of this invention may comprise up to 30 percent of monocyanate compounds, for example, ArfOCN)_n wherein n=l. The use of monocyanates give the polytriazines modified properties, for example,' 2S solubility, glass transition temperature., moisture resistance and impact resistance.

The formation of polytriazines arise from the cyclotrimerization of aryl cyanates to prepare 1,3,5-triaryloxytriazines. The use of the difunctional and 30 polyfunctional polyaromatic cyanates of this invention

31,877-F

-16in the cyclotrimerization process results in the preparation of a three dimensional network polymer which is hard, infusible and insoluble.

The term polytriazines as used in this inven- tion refer to both fully cured polytriazine polymers, and partially cured polytriazine prepolymers . Fully cured polytriazines are essentially free of cyanate functionalities. The prepolymers are cyanate group-containing polytriazines of liquid, wax-like or.'solid 10 consistency and are soluble in organic solvents. These prepolymers are highly stable in storage. These prepolymers, may be later converted to high molecular weight polytriazines when exposed to polymerization conditions. Prepolymers are prepared to permit easy handling of a resin prior_to. final use. ־Further, these prepolymers are useful in the production of coatings on such substrates as metals, cermics, glass and earthenware, and as impregnating lacquers or laminating resins.

r In the preparation of the polytriazines, aro:20 matic polycyanates are contacted in the presence of a catalyst at a temperature of between 2Q°C and 200°C, optionally in the presence of a solvent. Preferable temperatures are between 80°C and 180°C. The prepolymers are prepared by the same process, except either ‘a 25 lower temperature or a lower amount of catalyst is used, so that the aromatic polycyanates do not completely polymerize.

The rate of polymerization is dependent upon the temperature and the catalyst amount. As either, or 30 both, increase, the rate of polymerization increases. At higher temperatures, a lower amount of .catalyst is

31,877-F -16-17-

: . . י . . . י /. .

• necessary for the desired amount of polymerization than is.necessary at lower temperatures.

•

Useful catalysts include acids, base's, salts, nitrogen and phosphorus compounds,, for example, Lewis acids such as A1C1_3׳ BF_3׳ FeCl_3׳ TiCl_4׳ ZnCl_2׳ SnCl₄;

proton acids such as HC1, H_?O.; aromatic hydroxy comw עד pounds such as phenol, p-nitrophenol, pyrocatechol, dihydroxy naphthalene, sodium hydroxide, sodiummethylate, sodium phenolate, trimethylamine, ׳triethylamine,'tribu'10' tylamine, diazobicyclo-(2,2,2)-octane, quinoline, isoquinoline., tetrahydroisoquinoline, tetraethyl ammonium chloride, pyridine-N-oxide, tributy!phosphine, phospholine-A³-l-oxa-l-phenyl, zinc octoate, tin octoate, zinc naphthenate, cobalt salts of ^carl50xyli^c acids and' 15 mixtures thereof. Preferable catalysts are the cobalt salts of C₆_₂₀ carboxylic acids, with cobalt naphthenate and cobelt octoate being most preferred.

Generally, any amount of catalyst which catalyzes, the preparation of poly tri azines is suitable.

Preferably, between 0.001 and 10 percent by weight of the cyanates of catalyst is used.

Solvents useful in this. invention can be any compound which dissolves the aromatic polycyanates and does not interfere with the reaction. Suitable solvents .25 include aromatic hydrocarbons, alcohols and ketones.

The polyfunctional aromatic polycyanates may be combined with the powder-form or fibrous fillers or reinforcing materials either before. or after heat treatment of the aromatic polycyanates and by basically any method. For example it is possible to impregnate

31,877-F

-18powder-form or fibrous fillers or reinforcing materials such as quartz sand or glass cloths, with the aromatic cyanates, optionally in solution. , Examples of the solvents which may be used’ for this purpose and which, 5 _ generally, have to be removed again afterwards, are inert solvents such as methylene chloride, 'acetone,. methylethyl ketone, xylene, ethyl acetate benzene, toluene, tetrahydrofuran, chlorobenzene, dibutyl ether, dimethyl formamide and tetramethylene sulfone.

Suitable fillers and reinforcing materials are, generally, in any powder form and/or fibrous products, for example, of the type commonly used in the production of moldings based on unsaturated polyester resins or epoxide resins. Examples of products such as 15 these are, primarily, granular fillers such as quartz powder, ground shale, asbestos powder., powdered corundum, chalk, iron powder, aluminum powder, sand, or gravel, also inorganic or.organic fibers, more especially glass fibers in the usual textile forms of fibers, filaments,.

rovings,. yarns, nonwovens, mats dr cloths. In this connection, amino silane-based finishes have'proven &lt;0 . ’ be particularly effective. It is also possible to use corresponding textile structures of organic, preferably synthetic fibers (polyamides, polyesters) or on the basis of quartz, carbon, .metals, etc., as well as monocrystals (whiskers).

The end products combined with fillers or reinforcing materials may be used in .particular in vessei and pipe construction by the winding technique, in 30 electrical engineering, in mold construction and tool making and also in the construction of heavily stressed components, in the lightweight construction of vehicles in aeronautical and astronautical engineering.

31,877-F

The following examples are included for illustrative purposes only, and are not intended to limit the scope of the invention or claims.

Example 1

Polytriazine castings of each of the following cyanate-containing compounds are prepared.

. OCN

2.7

OCN , I and '3 wherein formula I is an example of this invention and formulas II and III are not.

The polytriazine castings of the aromatic cyanates of formulas I and II are prepared 'by heating

31,877-F

-20about 6 g of the respective cyanate along with about

200 parts per million of cobalt naphthenate at 150°C for 1 hour and 20 minutes and then at 200^eC for 3 hours.

The castings of formula III are prepared by heating about 6 g of formula III along with 200 parts per million of cobalt, naphthenate at 1SO°C for 2 hours and 250°C for 90 minutes.

«

All of the castings are monitored by differential scanning calorimetry to insure the castings have no uncured cyanate functionalities.

A casting of each of the polytriazines is exposed to the following test conditions. In Test 1, the castings are boiled in water for 96 hours. In Test 2, the castings are immersed in 20 weight percent hydrochloric acid for 2.5 hours at room temperature and then at reflux for 4.5 hours. In Test 3, the castings are immersed .in 40 weight percent sodium hydroxide at room temperature for 2.5 hours, then at reflux for 4.5 hours.

Each casting is weighed before and after each test. Table I. compiles the test results.

TABLE I

Weight Change (%) Test Cyanate I . Cyanate II Cyanate III +0.63 + 1.08+1.26 +0.26 - 4.35+1.55

-1.69 -28.68-5.78

31,-877-F

-21The weight gains are due to the adsorption of water by the samples. The. weight losses are due to the decomposition of the polymer due to hydrolysis. Generally, water is adsorbed by the polymer prior to hydrolysis.

The example demonstrates that the polytriazine prepare'd from the compound corresponding to formula' I is significantly mor'e resistant to hydrolysis than the polytriazines prepared from compounds corresponding to formulaII or III. Visual inspection of the castings after Test 2 shows that the casting prepared from the compound corresponding to formula I has no change in appearance, whereas the casting prepared from the compound corresponding to formula II has lost its transparency due to surface pitting. A visual inspection after Test 3 of the casting prepared from the compound corresponding to formula I shows slight surface pitting, whereas a visual inspection of the castings prepared from the compound corresponding to formula II after . Test 3 shows the casting to have numerous voids throughout and that the casting readily crumbles under physical stress. . .

Example 2 ׳

An 85 percent solution of polyaromatic cyanate I in methyl isobutyl ketone containing 0.016 weight percent of cobalt naphthenate are used to impregnate fiberglass cloth. Eight plys of the impregnated cloth are laid.up and cured in a press at 175°C and 300 psi (2.07 MPa) for 1 hour to give a 0.062 .inch (1.57 mm) thick laminate which has a glass transition temperature of '265°C. The laminate shows a 0.09 percent by weight absorption of water after boiling for ah hour at 15 psi.

31,877-F -21-22Example 3

A 50 percent solution of a polyaromatic cyanate corresponding to the formula

<img file="IL84615A_D0015.tif" />

<img file="IL84615A_D0016.tif" />

in methyl ethyl ketone containing 0.02 percent of cobalt octoate is used to .impregnate fiberglass cloth, six plys of which are laid up and cured in a press at

175°C and 300 psi (2.07 MPa) for 1 hour. A laminate using the polyaromatic cyanate of formula II (not an example of the invention)“is prepared in the same manner. Both laminates are subjected to humidity aging at 71״C for 1000 hours at 100 percent humidity. The laminate prepared from formula IV shows water absorption of 0.59 percent, while the laminate prepared from formula II absorbs 0.83 percent water (the experimental error is 0.01 percent). This example demonstrates that the polytriazines prepared from polyaromatic cyanates of this invention absorb significantly less water than polytriazines prepared from'prior art cyanates.

Example 4

A fiberglass cloth laminate is prepared from a 50 percent solution of formula IV in methyl ethyl ketone without catalyst. The laminate is heated at 150^qC for 15 minutes, and then inserted into a 215 °C press at contact pressure. The temperature is raised

31,877-F

-23to 250°C over a period of 8 minutes and a pressure of

100 psi (0.689 MPa) is then applied. After 45 minutes, • the laminate is removed and post-cured .for 1 hour at

250°C and then for 1 hour at 275°C. . The laminates are of an E glass Style 7781, A 1100 Finish, 6-ply and 27. percent resin.

The laminate is divided into different por•tions and several tests are run. In the control, the flexural strength and flexural modulus are determined 10 at room temperatures (23°C) and 190°C. This testing is done in accordance with ASTM D-790. other portions of the laminate are exposed to different conditions and thereafter the flexural'.strength and flexural modulus are tested.

•

In Test 4 the laminate is exposed to air at

200^eC for 500 hours. In Test 5 the laminate is exposed to 100 percent humidity at 50°C for 570 hours. In Test 6 the laminate is. immersed in CH-CI, for 7 days. In Test 7 the laminate is immersed in methanol for 7 days.

In Test 8 the laminate is. immersed in toluene for 7 days. The percentage of the flexural strength and modulus of each laminate compared to the control at room temperature is calculated. The laminates are also weighed before and after each treatment and the percent change relative to the standard is calculated. The results are compiled in Table II.

Table II demonstrates that glass laminates prepared using the polyaromatic cyanates of this invention are stable to heat, humidity and contact with com30 ׳ mon solvents such as methanol and toluene.

31,877-F ׳ “ . i !

1 י !

u TABLE II ?

H ‘ ;

j . Flexural Strength , Flexural Modulus ;

! “ ׳ 1 room room !.

temperature 190*0 temperature 190°C ' ;

<td>^!</td><td> Test</td><td> Weight Change</td><td> 103 ־ psi (MPa)</td><td> % Of Standard</td><td> 103 psi (MPa)</td><td> X Of Standard</td><td> 103 psi (MPa)</td><td> Xof Standard</td><td> 103 psi (MPa)</td><td colspan="2"> % of Standard</td>

<td></td><td> Standard</td><td></td><td> 70.5 , (486)</td><td> M .</td><td> 66.0 (455) « *</td><td> 94</td><td> 3.08 (21.2)</td><td> • a»</td><td> 3.19 (22.0)</td><td> 103</td><td> t _t i:</td>

<td> .</td><td> 4</td><td>.23</td><td> • 63.7 (439)</td><td> 90</td><td> 58.9 (406)</td><td> 84 1</td><td> 3.23 (22.3)</td><td> 105</td><td> 3.12 (21.5)</td><td> 101</td><td> 1</td>

<td> 1 N .' ן</td><td> 5</td><td> + 0.4</td><td> 72.5 (500)</td><td> 103</td><td> 56.6 (390)</td><td> 80</td><td> 3.49 (24.1)</td><td> 113 .</td><td> 2.79 (19.2)</td><td> 1» 1</td><td> 1</td>

<td></td><td> 6 1</td><td> +12.56</td><td> 43.‘5 (300)</td><td> 62</td><td> 4.</td><td> י*</td><td> 2.09 (14.4)</td><td> 68</td><td> -</td><td> -</td><td></td>

<td></td><td> 7 .</td><td> + 0.69</td><td> 57.1 (394)</td><td> 80</td><td> .</td><td> a.</td><td> 3.24 (22.3)</td><td> . 105 »</td><td></td><td> -</td><td></td>

<td></td><td> 8</td><td> + 0.27</td><td> 73.3 (505)</td><td> 104</td><td> .</td><td> 1</td><td> 3.21 (22.1)</td><td> 104</td><td> 1</td><td> -</td><td> 1</td>