Magnetic element temperature sensors

MAGNETIC ELEMENT TEMPERATURE SENSORS οπή ιηη’ϊκ ny mionsno 'iw«n

Eitan, MehuSai & Sadot Advocates and Patent Attorneys P-10896-IL1 , 1 221561/3

MAGNETIC ELEMENT TEMPERATURE SENSORS

This application is a division of co-pending application No. it 195154.

15 BACKGROUND OF THE INVENTION

Field of the Invention

The present invention is broadly concerned with magnetic element temperature sensors, detectors for use with such sensors, closed-ioop heating systems making use of the sensors and detectors to wirelessly determine the temperature of an object and to control the object’s 20 temperature, and corresponding methods. More particularly, the invention is concerned with temperature sensors made up of at least one magnetically susceptible sensor element, preferably formed of amorphous or nanocrystalline metal, and having a re-magnetization response under the influence of an applied alternating magnetic field which is different below and above at least one set point temperature, such as the Curie temperature of the sensor element These 25 temperature sensors can be used with correlated detectors for temperature sensing, and as a part of closed-loop heating systems. The temperature sensors may be incorporated into adhesive backed stickers that can be quickly and easily adhered to any number or type of objects, for example servitigware, so that the servingware, and food place thereon, can be heated by a closed-loop feedback heating system. WO 2007/134061 PCT/US2007/068483 2

Description of ike Prior Art A variety of applications for temperature sensors that can be read wirelessly exist in the marketplace. These applications vary from sensing and reporting the internal temperature of livestock to being part of a closed-loop temperature feedback system that allows a magnetic induction heater to precisely control the temperature of insulated food delivery boxes. Many of these applications are disclosed in U.S. Patent Nos. 5,954,984,6,232,585,6,320,169,6,953,919, and 6,208,253.

Many of those applications are currently being served by Radio Frequency Identification (RFED) temperature sensing systems. These RFID temperature sensing systems include an RFID reader/detector and its associated RFID ‘‘tag,” whereby the tag has some type of temperature sensor as part of its circuitry.

These prior RFID systems tend to be relatively expensive owing to die cost of the tags, and are unable to operate continuously in excess of 125° C, Moreover, they lack the ability to transmit information in the vicinity of metal or other conducting materials, particularly when the RFID tag is embedded within the conducting material.

Magnetic element markers (or “tags”) are commonly used as part of an electronic article surveillance (EAS) systems or other authentication systems. These markers or tags are passive, typically small, less expensive than RFID tags, can operate at high temperatures, and in some forms, can transmit their information wirelessly to a detector even when embedded within a conductor.

For example, EAS markers or tags made of soft magnetic amorphous alloy ribbons are disclosed in U.S. Patent No, 4,484,184, These ribbons have a composition consisting essentially of &e formula Ma Nb O<: X?I Ye Zn where M is at least one of iron and cobalt, N is nickel, O is at least one of chromium and molybdenum, X is at least one of boron and phosphorous, Y is silicon, Z is carbon, "a^'T are in atom percent, a ranges from about 35-85, b ranges from about 0-45. c ranges from about 0-7. d ranges from about 5-22, e ranges from about 0-15 and f ranges from about 0-2, and the sum of d+e+f ranges from about 15-25. Die marker ribbons are capable of producing field perturbations at frequencies which are harmonics of the frequency of an incident alternating magnetic field produced by a field transmitter. A detecting means is arranged to detect magnetic field perturbations at selected tones of die harmonics produced in the vicinity of die interrogation zone by the presence of the marker therewithal. Generation of harmonics by WO 2007/134061 PCT/US2007/068483 3 the marker is caused by nonlinear magnetization response of the marker to an incident magnetic field.

There is a need in the art for wireless temperature sensing systems using small, less expensive temperature sensing elements, that can operate continuously at temperatures in excess of 125° C, and that have the ability to transmit information even in the vicinity of metal or other conducting materials. Furthermore, it would be advantageous if such improved temperature sensing elements were able to carry predetermined data relating to the sensor itself or to the object to be temperature sensed, e.g., the identity of the object, object characteristics, or heating instructions. Finally, advantages would be realized if tire sensing elements could be used as a part of a closed-loop feedback heating system able to control the output of a heating device and thus control the temperature of an object, hi connection with another aspect of the present invention, restaurants and other foodserving establishments commonly use various devices to keep servingware (dinner plates, platters, bowls, pans, chafing dishes etc.) and (lie food thereon or therein warm after the food is placed upon the servingware. For example, plates of food prepared in restaurants must be kept warm while other plates of food destined for (fie same customer are still being prepared. Similarly, wanning trays are frequently used to keep serving platters and bowls and the food thereon warm.

The most common devices for keeping servingware and food warm are heat lamps which use radiation from various light sources; food wells, or steam tables, which use conduction from condensing steam generated via energy from either a petroleum-fueled flame below, or an electric element submerged in, a water bath below the servingware; and microwave ovens. Unfortunately, these heating devices are inefficient and have no convenient means to precisely control the temperature of tire servingware or food and thus frequently overheat or underheat the servingware and food.

For example, with heat lamp systems, the lamps are on continuously, even when there is no servingware below the lamps, thus wasting energy and unnecessarily heating surrounding areas. Furthermore, these systems have no temperature feedback from the food to the heat lamp and therefore continue to heat the food after it has been warmed above its proper temperature, resulting in overheating and drying of the food. To reduce the likelihood of overheating, heat lamps with reduced power ratings are sometimes used, but undersized heat lamps often do not WO 2007/134061 PCT/US2007/068483 4 generate enough energy to fully heat the servingware to a temperature high, enough to keep the food thereon warm enough. Finally, the rim of servingware placed under heat lamps often gets hotter than desired because foe heat lamps direct light upon the rim as well as the food on Hie servingware. This necessitates foe use of gloves or pot holders when handling the servingware and wastes energy used to unnecessarily heat the rim.

Similarly, steam table systems are energy Inefficient because they have no closed loop temperature feedback. Titus, to ensure safe food temperatures, these systems are typically operated at their highest temperatures, wasting energy and causing the food heated by the systems to become overheated and dried-out.

Microwave ovens also typically do not use temperature feedback information to allow closed loop temperature control of servingware placed therein. Some microwaves have temperature probes that can be inserted into food to provide temperature information so as to create a closed-loop temperature control system. However, such wired probes are not convenient, especially for high volume operations such as restaurants.

Tirus, there is a need in foe art for improved devices, systems, and methods for maintaining the temperature of food items after they are placed on or in servingware.

SUMMARY OF THE INVENTION

The present invention provides a wholly new class of temperature sensors, methods of temperature sensing and closed-loop heating systems. The invention is preferably predicated upon foe discovery that reliable temperature sensing can be obtained through use of magnetic temperature sensing elements, each having a characteristic re-magnetization response under the influence of an applied alternating magnetic field, wherein foe responses are temperature-sensitive and can be readily monitored.

In more detail, a preferred temperature sensor is configured for placement in thermal contact with an object in order to sense a parameter related to the temperature of the object, for example foe temperature of foe object, a desired temperature of the object, a temperature range of the object, a desired temperature range of foe object, a minimum temperature of foe object, a maximum temperature of the object, a heating property of the object, and material supported by the object. The sensor comprises at least one magnetically susceptible sensor element having a re-magnetization response under the influence of an applied alternating magnetic field, the re- WO 2007/134061 PCT/US2O07/O68483 5 magnetization response being defined by at least one short, detectible pulse of magnetic field perturbation of defined short duration and which is different below and above at least one set point temperature. Preferably, the set point temperature is die Curie temperature of the sensor element, or a temperature close (usually within about 25° C) of this Curie temperature. In most $ applications, die set point temperature is below about 400° C.

When such a temperature sensor element is placed in thermal contact with an object to be temperature-sensed, and an alternating magnetic field is applied to die sensor element of sufficient magnitude to cause die desired re-magnetization response, the sensor element operates in the manner of a "temperature switch/1 That Is, when die object is below the set point 10 temperature of the sensor element, a re-magnetization response from the sensor element is observed; when die object temperature reaches or exceeds the set point temperature, either no remagnetization response is observed, or die response is altered. Often, the re-magnetization response is altered in a predictable manner in a small range of temperatures below the set point temperature, above which the response disappears. In such instances, die information concerning 15 an aspect of the altered response (such as the magnitude of die response relative to a reference value) may be used to make a sensor element act as an infinite temperature sensor over a small temperature range prior to the set point temperature, and act as a temperature switch at the set point temperature whereabove no re-magnetization response is observed.

Normally, temperature sensors in accordance with the invention make use of a plurality 20 of sensor elements each having a different set point temperature dian the other sensor elements.

Preferably, diese plural sensor elements are designed to have successive different set. point temperatures which vary from lowest to highest and in at least a somewhat uniform' fashion, so diat die temperature of the object can be monitored over a range of temperatures corresponding to the design of die temperature sensors. In such a situation, the magnitude of the differences 25 between adjacent set points may define the resolution of the temperature sensor.

In order to most effectively make use of the temperature sensor of die invention, use is made of a detector correlated with the sensor elements. Such a detector generally has a device for generating an alternating magnetic field of sufficient magnitude to interrogate the sensor elements (i.e,, to cause re-magnetization responses of die sensor elements based upon the 30 temperature of the object), and a device for detecting such responses. In practice, the detector has a magnetic field generator coil and a field receiving coil both coupled with a signal WO 2007/134061 PCT/US2007/068483 6 processing unit In use, the detector generates the requisite alternating magnetic held, and the held receiving coil detects the re-magnetization responses of the sensor elements, issuing output signals to the signal processing unit. The signal processing unit, preferably in the fonn of a digital microprocessor, employs a decoding algorithm which allows determination of the object temperature. In preferred forms, the decoding algorithm comprises one or more look-up tables correlating the re-magnetization responses of the sensor elements with object temperature.

The magnetically susceptible sensor elements are advantageously formed as metallic bodies in an amorphous or nanocrystalline state. Such metallic bodies are preferably in. the fonn of very thin elongated wires or strips having a maximum cross-sectional dimension (e.g, diameter) of up to about 100 pm, and can be produced in a variety of manners. One particularly suitable fonn of the metallic bodies is the microwire form, comprising an inner metallic core and an. optional outer glass coating. Such microwires can be produced by the well-known Taylor method or as water-cast amorphous bodies. However, it is not necessary to make use of microwires in the context of the invention, so long as the sensors Include the requisite magnetically susceptible sensor elements. fo another aspect of the invention, new microwire-based composite or combination microwires are provided. In such constructions, an inner microwire made up of an elongated metallic body is shielded by means of an adjacent ferromagnetic sheath of known Curie temperature, which prevents or at least alters the re-magnetization response of the associated microwire metallic body at temperatures below the sheath Curie temperature (or at a known temperature close to the sheath Curie temperature). The sheath may be located in surrounding relationship with the inner microwire, or at least partially disposed about the inner microwire in sp aced relationship therefrom. One particularly preferred composite mi crowire includes an inner most magnetic susceptible micro wire body with a surrounding glass casing. The sheath is tubular and surrounds the glass casing, and has an outermost glass casing around the sheath. Such a composite design can readily be produced using a modified Taylor method. Specifically, a pair of inner and outer glass tubes are telescoped together with the magnetically susceptible metal within the inner tube and the ferromagnetic sheath material between die inner and outer tubes. These components are rendered molten and are quickly pulled to create the desired composite structure. WO 2007/134061 PCT/US2007/068483 7

In another aspect of the invention, a method of sensing the temperature of an object is provided. Tins method broadly comprises the steps of placing a temperature sensor in thermal contact with said object, the sensor comprising at least one magnetically susceptible sensor element having a re-magnetization response under Hie influence of an applied alternating magnetic held, and wherein the re-magnetization response is different below and above at least one set point temperature. Next, an alternating magnetic field is generated in the region of the sensor and of sufficient magnitude to cause the re-magnetization response of the sensor element. Thereupon, tile re-magnetization response of the sensor element is detected and used'to at least in paid determine whether the temperature of tire body (and therefore of the object) is above or below the set point temperature (e.g., other information may he used along with the detected re-magnetization response in the temperature detennination).

As noted previously, the sensor normally has a plurality of magnetically susceptible sensor elements, each having a different re-magnetization response under the influence of an applied alternating magnetic field and each re-magnetization response being different below and above a setpoint temperature, and wherein the setpoint temperatures of the sensor elements are different from each other. In such a case, the re-magnetization responses of at least certain of the plural sensor elements are detected and used to measure the temperature of the sensor elements and of the object,

Where a sheathed composite or combination mierowire sensing element is used, the associated ferromagnetic sheath prevents the re-magnetization responses of the associated mierowire body by magnetically saturating or biasing the body until the sensor elements and the object reach a temperature above die Curie temperature, or at some fixed temperature near the Curie temperature, of foe ferromagnetic sheath. Hie extent of magnetic saturation or biasing of the sensor element by the sheath can be designed to yield a series of different or altered remagnetization responses over a range of temperatures approaching foe Curie temperature of foe sheath. This behavior is identical to foe case described above for foe non-composite and noncombination sensor elements. Assuming that the correlated detector has a sufficient resolution and discrimination, these different or altered responses can be detected and used for temperature sensing. Tims, in such a case a single mierowire sensing element can exhibit a plurality of different setpoint temperatures. WO 2007/134061 PCT/US2007/068483

S

The invention also provides a unique structure and method for selectively measuring the temperature of an object made up of at least a pair of components designed to be placed in proximity to each other, with at least one of die components being heatable. For example, a heater and a correlated heatable consumable item (e.g., an induction heater and a container filled with heatable shaving cream) can be temperature monitored and controlled in accordance with die invention. In such a design an induction-heatable nozzle designed to connect to the container and to heat tire fluid exiting the container would be equipped with a temperature sensor in accordance with the invention, whereas the container would be equipped with a magnetic field-responsive data element (e.g., a conventional microwire) correlated with the nozzle-applied temperature sensor. The temperature sensor and data element are correlated such that the re-magnetization response of tire temperature sensor can only be decoded if both the temperature sensor and data element are simultaneously subjected to an interrogating alternating magnetic field. This ts usually accomplished by altering the decoding algorithm of the detecting device so that it will not detect and report object temperature unless both the temperature sensor and data element are present. When the container is situated on tire induction heater for heating purposes, the temperature sensor and data element are in proximity and tire re-magnetization responses of the sensor can be detected and used for temperature sensing.

This aspect of the invention is particularly advantageous because the manufacturer of the beater can be assured that only consumable items it also manufactures can be used with the heater; that is, if the consumable item of another manufacturer is used with the heater, no temperature monitoring can occur because that other manufacturer’s consumable item does not include the necessary correlated magnetic field-responsive data element. In addition, the heater can be designed so that it will not operate at all unless the appropriate consumable item is used.

The invention also provides systems for heating of objects making use of a temperature sensor in accordance with the invention. Such systems further include apparatus for heating the object, such as an induction or other type heating unit, along with a re-magnetization response detector of the type described. A controller coupled with the detector and heating apparatus is also provided in order io receive output signals from the detector and to control the operation of die heating apparatus in response to such output signals. hr these types of systems, the temperature of the object is successively or continuously monitored, and the controller varies the WO 2007/134065 PCT/OS2007/068483 9 operation of fee heating apparatus so as to heat fee object or to maintain it in a desired temperature range.

In another aspect of fee invention, a temperature sensor as described above is incorporated into an adhesive “sticker” feat can be quickly and easily adhered to a piece of 5 servingware such as a plate, dish, pan, glass, etc. As used herein, “adhesive” refers to any composition or structure capable of providing die degree of adherence required for attaching the temperature sensor to desired servingware, including without limitation traditional adhesives or “glues,” as well as mechanical connection structure such as Velcro® multiple hook and loop material or other fasteners. Once such a temperature sensor is adhered to a piece of servingware, 10 the servingware may be placed on or in the vicinity of an induction heater, heat lamp assembly, steam heating unit, microwave oven, or other type heating unit equipped wife a re-magnetization response detector as described above or other type of detector. The detector interrogates the , temperature sensor to sense the presence of fee servingware, the type of servingware, and fee desired temperature or temperature range of the servingware. A controller coupled with the 15 detector and heating unit receives signals from fee detector which are indicative of the temperature, or temperature range, of the servingware and which are used to control fee cycling or other operational parameter of the heating unit. Thus, the temperature of fee servingware may be continuously or periodically monitored, and fee heating unit may be controlled so as to heat the servingware to a desired temperature range and to maintain it within the temperature range. 20 The temperature sensor sticker described above may be formed by adhering a microwire sensor or a plurality of such microwire sensors to a substrate wife an adhesive and then placing a release layer over the exposed face of fee adhesive. Tire adhesive secures the micro wire sensor or sensors to the substrate and, when the release layer is removed, adheres fee entire temperature sensor sticker to a piece of servingware so that fee servingware (and food placed thereon) may 25 be monitored and heated as described above.

Advantageously, the temperature sensors of the invention can be quickly and easily adhesively attached to any existing servingware without making any aesthetic or structural changes to fee servingware. Titus, fee present invention allows temperature sensors to be quickly and easily attached to servingware so as to allow monitoring of a temperature parameter related 30 to fee servingware, for example fee temperature of the servingware, a desired temperature of fee servingware, a temperature range of the servingware, a desired temperature range of the WO 2007/134061 PCT/US2007/0684S3 10 servingware, a minimum temperature of the servingware, a maximum temperature of the servingware, a heating property of the servingware, and the temperature of a food supported on the servingware. Additionally, die sensor may be used to wirelessly control such a temperature parameter at any location during serving - such as at a wait counter, serving table, buffet counter, microwave oven, or other dining area location.

The temperature sensors can also be used with various types of energy sources (halogen, induction heating, steam, microwave, etc.) to heat the servingware using a temperature feedback, closed-loop control method. The temperature sensors permit temperature regulation of servingware wirelessly and indefinitely so that the servingware is automatically heated to and maintained at a preset temperature for as long as the servingware is positioned on or near a heating unit.

The present invention accomplishes the above whilebeing inexpensive to implement and with few or no changes to normal restaurant operational procedures.

BRIEF DESCRIPTION OF THE DRAWINGS

Figure I is a fragmentary view in partial section illustrating a prior art magnetic microwire element suitable for use in the present invention;

Fig. 2 is a graphical illustration of the magnetic characteristics of a microwire suitable for use in tire present invention, at temperatures below the Curie temperature of the microwire alloy;

Fig. 3A is a graph of time versus re-magnetization of an amorphous strip typically used in conventional in anti-shoplifting EAS markers or tags;

Fig. 3B is a graph of time versus re-magnetization of an amorphous microwire having a large Barldrausen discontinuity, used in the markers or tag commercially available from Sensormatic Co.;

Fig. 3C is a graph of time versus re-magnetization of a glass-coated amorphous magnetic microwire produced by the Taylor method;

Fig. 4 is an essentially schematic cross-sectional view of a magnetic temperature sensor attached to an object to be sensed and in accordance with a first embodiment of the invention;

Fig. 4A is an essentially schematic cross-sectional view similar to that of Fig. 4, but illustrating the components of a magnetic microwire temperature sensor split between two objects designed for placement in proximity to each other; WO 2007/134061 PCT/US2007/068483 Π

Fig. 5 is s schematic cross-sectional view of a temperature-sensing element in accordance with a second embodiment of the invention» depicting a glass-coated amorphous microwire magnetic element surround by a cylindrical sheath of a ferromagnetic metal or ferrite material and having a desired Curie temperature;

Fig. 6 is an essentially schematic cross-sectional view of a magnetic temperature sensor in accordance with the invention, making use of microwire data elements of tire type illustrated' in Fig. h and temperature-sensing elements as illustrated in Fig. 5;

Fig. 7 is a schematic cross-sectional view of another temperature sensing element in accordance with a third embodiment of the invention, wherein glass-coated microwire magnetic elements as illustrate in Fig. 1 and Ideated adjacent a shield of ferromagnetic metal or ferrite material having a desired Curie temperature;

Fig. 8 is an essentially schematic cross-sectional view of a magnetic element temperature sensor in accordance with the third embodiment of the invention including data elements as illustrated in Fig. 1 and temperature-sensing elements as illustrated in Fig. 7

Fig. 9 is a graph illustrating the Curie temperature versus percentage of copper for nickel-copper alloys suitable for use as sheaths for the temperature-sensing elements of the second embodiment of the invention, or as shields for the temperature-sensing elements of the third embodiment of the invention;

Fig. 10 is a schematic block diagram of a temperature reader/detector in accordance with the invention operable to interact with the magnetic element temperature sensors hereof; and

Fig. 11 is a schematic diagram illustrating magnetic element sensor-based, closed-feedback temperature control induction heating unit in accordance with the invention.

Fig. 12 is a perspective view of the bottom of a piece of servingware shown with a temperature sensor constructed in accordance with an embodiment of the invention attached thereto.

Fig, 13 is a perspective view of the temperature sensor of Fig. 12 before it has been applied to the servingware and before its adhesive release layer has been removed.

Fig. 14 is a perspective view of the temperature sensor of Fig. 13 after the adhesive release layer has been removed.

Fig. 15 is a vertical cross sectional view of the temperature sensor of Fig. 13. WO 2007/134061 PCT/US2007/068483 12

Fig. 16 is a schematic diagram in partial section illustrating a piece of servingware with a temperature sensor adhered thereto being heated by a flat-surfaced halogen heater.

Fig. 17 is a schematic diagram in partial section illustrating a piece of servingware with a temperature sensor adhered thereto being heated by a heat lamp heating unit.

Fig. 18 is a schematic diagram in partial section illustrating a piece of servingware having an induction heatable grid and shown with a temperature sensor adhered thereto being heated by an induction heater.

Fig. 19 is a side view of the servingware shown in Fig. 18 illustrating the induction heatable grid on the servingware.

Fig, 20 is a schematic diagram in partial section illustrating a piece of servingware with a temperature sensor adhered thereto being heated by a steam table heating unit.

Fig. 21 is a side view of tire servingware shown in Fig. 20.

Fig. 22 is a schematic diagram in partial section illustrating a piece of servingware with a temperature sensor adhered thereto being heated by a microwave heating unit.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

Prior Art Magnetic Elements and Detection Systems

In order to best understand the present invention, it is helpful to understand the nature and operation of present-day EAS and authentication systems employing magnetic elements (often referred to as ‘'‘magnetic markers”) and their corresponding detection systems.

One type of magnetic element often used is a glass-coated amorphous microwire. Such microwires, their product! on, magnetic properties, and behaviors below their Curie temperatures, have been disclosed in the technical and patent literature. See, for example, U.S. Patent Nos. 6,441,737 and 6,747,559; Horia Chirac, Preparation and Characterization of Glass Covered Magnetic Wires, Materials Science and Engineering A304-306,166-71 (2001); Donald et ah, The Preparation, Properties and Applications of Some Glass Coated Metal Filaments Prepared by the Taylor-Wire Process, Journal of Materials Science, 31, 1139-48 (1996); Wiesner and Schneider, Magnetic Properties of Amorphous Fe—P Alloys Containing Ga, Ge, and As, Phys. Stat Soh (a) 26, 71 (1974); and Antonenko etal,ZEg& Frequency Properties of Glass-Coaled Micro-wires, Journal of Applied Physics, voh 83, 6587-89. Continuous lengths of microwires WO 2007/134061 PCT/VS2007/06S483 13 have been produced inexpensively by what is generally called in the art die Taylor process whereby either a pre-alloyed ingot or the required elemental constituents are melted in a generally vertically disposed glass tube that is sealed at the bottom. Once die alloy is converted to a molten state, using radio frequency (”rf") heating for example, the softened bottom of the glass tube is 5 grasped and drawn into continuous microwire. Rapid reduction of alloy cross-section, together with use of secondary cooling means, cause die alloy to become amorphous or nanocrystalline during drawing. A typical microwire 20, anywhere from fen or less microns in total diameter to tens of microns in total diameter, is depicted in Tig. 1. The wire 20 has an alloy core 22, and glass 10 coating 24, wherein the alloy core 22 and die glass coating 24 can be physically coupled to each other continuously or only at several spatially separated points. Theglass-to-metal ratio, though variable, can be tightly controlled. For example, die typical thickness of glass-coating 24 may be from about 1-5 microns for a 45-60 micron core diameter microwire, and typically 1-3 microns for 30 micron core diameter microwire, Microwire elements for prior art BAS and Ϊ 5 authentication tags are usually cut to lengths ranging from 15mm to 75mm.

The microwire magnetic properties and resultant hysteresis loops can be controlled by varying the alloy composition and theglass-to-metal diameter ratio. Fig. 2 illustrates an idealized magnetic hysteresis loop response of a typical microwire 20 with a large Barkhausen discontinuity, suitable for use in the present invention as described below. When such a 20 microwire 20 is exposed to an external alternating magnetic field whose field strength, in the direction opposing the instantaneous magnetic polarization of the element is greater than die coercive force Hc, here shown ideally to be less than 10 A/m, the re-magnetization process results in the generation of a harmonically rich pulse tiiat is easily detected. The magnetic flux changes during the pulse give rise to a peak in the flux derivative over time. Accordingly, a voltage peak 25 will be observed in a receiving coil placed in the vicinity of the element and the reader/detector may correlate that voltage peak to the presence of a microwire element in the field,

Prior art glass-coated amorphous microwires 20 produced by the Taylor method can be fabricated so as to exhibit very low coercivities (substantially less than lOA/m), high relative permeabilities (substantially higher than 20000), substantially zero or slightly positive 30 magnetostrictions, and large Barkhausen discontinuities (which means that Ute microwires exist essentially only in bimodal magnetic states). WO 2007/134063 PCT/US2007/068483 14

The re-magnetization properties of the microwires 20 are also important, and distinguish such microwires from oilier types of prior ail magnetic elements. Referring to Fig. 3C (see U.S. Patent No. 6,556,139) it will be seen that .the re-magnetization peak width (measured at half amplitude level) was in the range of 25-80 micro seconds for a glass-coated amorphous microwire. In contrast (see Fig. 3B), markers or tags commercially available from Sensormatic Co. comprises an in-water-cast amorphous wire with large Barkhausen discontinuity, the peak width was in the range of about 200-500 micro seconds or more. Finally (see Fig. 3A), the peak width was about 1-2 milliseconds for amorphous strips typically used in anti-shoplifring markers or tags, e.g., aMeto GmbH 32-nwn marker or tag. Titus, microwires of the type illustrated in Fig. 1 exhibit extremely short re-magnetization peaks which allow discrimination of a micro wire response from background noise such as that caused by held interaction with other external objects.

Zhukov et ah, J. Mater. Res. 15 No. 10 Oct. (2000), describe the production of multi-bit markers when utilizing multiple amorphous glass-coated wire segments, each having a different dimension (length, gross diameter, etc.) or magnetic property (e.g., coercive field). For instance, if a plurality of magnetic mierowire elements exhibit different coercivities, respectively, each of their unique re-magnetization peaks can be detected in each magnetic field period, and their pattern may be recognized, for example, by methods described in U.S. Patent No. 4,203,544. U.S. Patent No. 5,729,201 describes a method to differentiate such a plurality of wires, even if they have the same magnetic properties and dimensions. A pennanent magnet bias field element in the vicinity of the wire serves to differentiate the amplitude of the external magnetic field generated by a reader/detectorthat is required to exceed the coercive force for re-magnetization of each magnetic element byway of its different proximity to each individual wire segment This leads to a phase difference in re-magnetization peaks detected, thus allowing differentiation of tire individual elements. U.S. Patent No. 4,134,538 describes multi-element tags (markers) constructed of magnetic elements, each characterized by a different coercive force and thereby permitting the assignment to any attached, object of a reference code with as many characters as magnetic elements utilized. One thus assigns, respectively, each character of the reference code to a magnetic element in the order of the values of their respective coercive forces, the signals corresponding to each magnetic element then appearing in the detection apparatus in the same WO 2007/13406Ϊ VCT/US2007/O68483 15 order of dephasing as the order of the coercive forces and each with amplitudes corresponding to the values assigned at the time of coding, thus reproducing the complete code in arrangement and in amplitude. U.S. Patent No. 6,622,913 teaches that data information may be encoded in binary form 5 by using microwire elements of different diameters or permeabilities, so that they produce considerably different responses to an alternating magnetic field produced by a transmitter. Accordingly, one type of microwire may present binary ’O’* and the oilier binary "1". For instance, an array of four microwires each with successively larger coercivities such that they are each easily distinguished by their detected phase differences over a period of an incident 10 alternating magnetic field, can be made to produce alternating high and low amplitudes of field perturbations (and thus alternating high and low voltage amplitudes at the detector) so that they represent a binary pattern of 1010. O.S. Patent Application No. 2005/0109435 describes several magnetic and optical methods of encoding multi-bit information on a single microwire. Tire stress sensitivity of 15 ferromagnetic amorphous glass-coated microwire can be used advantageously as the physical basis for affecting magnetic domain structure. Ferromagnetic amorphous glass-coated microwire encoding can result from a localized alteration of this domain structure. The alteration is readily accomplished by imposition of localized stresses or by selective crystallization of the amorphous alloy. Such changes are affected by a number of means, including localized heating via pulsed 20 laser, chemical thinning of the glass coating, coatings on the glass, and the like. Localized modifications of the glass-coating of ferromagnetic amorphous glass-coated microwires can be. used to effectively produce controlled changes in the magnetic domain structure of the amorphous alloy cores, thereby enabling encoding. The preferred method is to use laser pulses to locally heat the glass or alloy (independent heating can be accomplished by choice of 25 wavelength) causing changes in die structure of one or both, and thereby altering the extant stress fields or the basic magnetic characteristics.

Prior art HAS or authentication system detector devices used in conjunction with all types of magnetic elements used as magnetic markers typically use field transmitter unit and a magnetic field detector unit. The field transmitter generally has a frequency generator and a field generator 30 coil (constituting together an alternating magnetic field source) for creating the alternating WO 2007/134061 PCT/US2007/008483 16 magnetic field in the interrogation zone of the marker. The detector unit normally lias a field receiving coil and a signal processing unit thatitypically triggers an alarm device.

In prior art EAS systems, when a magnetic marker is located in the vicinity of the coils, die interrogating AC field causes tire switching of the magnetic element’s magnetization. Accordingly, very short pulses of magnetic field perturbations are received by the field receiving coil. These pulses are detected by die signal processing circuit, which produces an output to activate an alarm.

First Embodiment: Modified Chemistry Microwires for Curie Temperature Sensing

Tire first embodiment of the invention comprises a magnetic microwire temperature sensor having at least one and usually a plurality of magnetically susceptible microwires, with the individual alloys of at least certain of the microwires having modified chemistries and consequent different Curie temperatures, usually below about 400° C. Additionally, this embodiment includes a mi crowd re reader/detector capable of decoding temperature information derived -from foe sensor microwires.

Chemically modified individual microwires are preferably fabricated so that foe modified microwires retain large Barfchausen discontinuities, extremely low coercivities, and extremely high permeabilities below foeir respective Curie temperatures (with resultant hysteresis behavior of foe type depicted in Pig. 2). These modified microwires essentially completely lose their ferromagnetism above foeir Curie temperatures. Other microwires within foe array of the sensor need not have modified chemistries, but can operate as data elements according to any of the prior art methods of single or multi-bit encoding previously discussed.

The most preferred chemical modification of Fe-based and/or Co-based alloys used in prior art amorphous microwires is the adjustment of the atomic percentage of chromium therein. Chromium in amorphous iron-based (Fe80“XCrx){PC)20 alloys has a sizeable effect on foeir magnetic properties. An increase in Chromium percentage lowers the Curie temperatures, the average hyperfine fields, and the saturation magnetizations thereof, and on foe other hand markedly increases their initial permeabilities. For instance, an increase in foe Chromium percentage from 0% to 6.5% reduced the Curie temperature from 330° C to 155° C in certain tested samples. See, Henry et ah, Magnetic Measurements of Iron-Rich Amorphous Ailoys Containing Chromium: Mossbauer Study and B-HLoops, Journal ofMaterials Science 19:1000» WO 2007/134061 PCT/US2007/068483 17 0ό (1984); and Wijn, Magnetic Properties of Metals—d-Elements, Alloys, and Compounds,

Springer-Verlag, Berlin (1991).

Other chemical changes to Fe-based and Co-based alloys can also be utilized to alter the magnetic characteristics of amoxphous microwire elements. For example, Co can be substituted for Fe in certain FCZBN alloys, and the resultant Curie temperature exhibits an sinusoid-like behavior with increasing Co content, and reveals two maxima at 3 and 12.5 atomic % Co and a minimum at 7.5 atomic % Co (Yao et ah, Co Dependence of Curie Temperature in Amorphous Fe Co Zr B Nb Alloys With High Glass Forming Ability,Journal of Physical Science; Condensed Matter, Voh 16' 6325-34 (2004). IEEE Transactions on Magnetics, Voh 22,1349-51 (1986) presents a process whereby Co-P amorphous alloys· wito'qhigh'F content can be electrolytically obtained. The Curie temperature of these alloys shows a linear behavior in Curie temperature versus composition up to 28-29% P. For higher concentrations, a constant Curie temperature is observed.

As explained above, toe first embodiment preferably makes use of a plurality ofmagnetic microwire temperature sensing elements whose chemistries have been changed so that the micro wires become paramagnetic at individual temperatures (usually about 400° C or below) within specific design temperature range of the overall temperature sensor. For example, Fig. 4 depicts a temperature sensor 26 having a total of four temperature-sensing micro wires 28-34 forming an array 36. Each of the microwires 28-34 has its chemistry modified using any of toe forgoing techniques such as an increasing atomic percentage of chromium, with the result that the Curie temperatures of toe microwires are different and are all exceeded during toe normal operating temperature range of the sensor 26. The remaining two micro wires 38 and 40 are data elements. An optional permanent magnetic bias field element 41 can also be employed.

In the Fig. 4 embodiment, the micro wires 28-34 are arranged in parallel relationship where toe spacing42 is equal to toe sum of the radii of each adjacent microwire (spacing 42 may be larger than the sum of toe radii), and are held together by a thermally conducting adhesive (not shown) that also adheres the microwires to an object 44 to be temperature-monitored.

In this exemplary embodiment, toe magnetic coercivity of each microwire 28-34 and 38-40 is altered by appropriate chemical changes in the alloys thereof, and specifically toe chromium content of each alloy, in order to ensure that each of toe six microwires is uniquely detectable within each period in toe order of their location within die overall array. Of course, other prior WO 2007/134061 PCT/US20O7/068483 18 art techniques for changing alloy chemistry as well as for adjusting coercivity can also be used for this purpose. Additionally, each of the six microwires 28-34 and 38-40 are of tire same length (e.g., 20mm.) except for microwire 38, which is significantly longer (e.g., 40mm), Tins extra length for tire microwire 38 ensures that tire detected re-magnetization peak from this data 5 element microwfre is larger in amplitude than all other re-magnetization peaks.

Fig, 10 illustrates an exemplary detector device 46 used to detect temperatures sensed by sensor 26, corresponding to the temperature of the object 44. The detector 46 broadly includes an alternating magnetic field transmitter unit in the form of a frequency generator 48 coupled with a field generator coil 50, such that the transmitter unit is operable to create an alternating 10 magnetic field for interrogating sensor 26. The overall device 46 further includes a field receiving coil 52 operably coupled with a digital signal processing unit 54 and a temperature display 56. As illustrated, tire processing unit 54 is equipped with communication ports 58 and 60, and maybe operably coupled with frequency generator 48 via connection 62. Additionally, frequency generator 48 maybe equipped with an optional input 61 permitting remote control of 15 die generator.

The signal processing unit 54 operates using a decoding algorithm having the capability to decode the magnetic field perturbation information received upon interrogation of the sensor 26. Preferably the decoding algorithm is in the form of one or more look-up tables for different sensors in accordance with die invention, stored within memory associated with the unit 54. In 20 the case of a detector 46 specific to sensor 26, the temperature look-up table would have bodi the expected phase position (phase relationship from die stop bit and/or from each other) for each of the four temperature sensing micro wire elements 28-34, as well as the temperatures to report for each of the acceptable detected bit codes from the array 36 of microwires 20 (some bit codes may be unacceptable because they make no logical sense according to the phased microwire 25 order of Curie temperatures and thus are the product of a mis-read by defector 46).

As described, the sensor 26 and detector device 46 are correlated so that die device 46 can, by proper interrogation of sensor 26, ascertain die temperature of object 44. Such correlation involves matching the bit logic of sensor 26 with the decoding algorithm^), in this case, the temperature look-up table(s) stored in the memory of signal processing unit 54, Those 30 skilled in die art will appreciate that a wide variety of bit logics and corresponding algoridims WO 2007/134061 PCT/US2007/068483 19 tables can be provided. However, the following discussion provides one exemplary system in the context of the sensor 26 arid detector device 46 of Fig. 10,

Again referring to Fig. 4, assume that the least significant bit of the four temperature-sensing element microwires 34-38 is microwire 28, which can be denominated the “first” microwire. Thus, when object 44 is below die Curie temperature of the first microwire 28, the microwire 28 will still produce its characteristic short re-magnetization pulse under the influence of the alternating magnetic field generated by device 46, When object 44 has a temperature above the Curie temperature of foe first microwire 28, the microwire 28 will no longer produce its short re-magnetization pulse under foe influence of foe applied alternating magnetic field, and therefore its bit will be missing (a “0” value) from the detected temperature-sensing element array of bits.

The remaining temperature-sensing microwires 30-34 each have respective, chemically modified alloys therein, so that the Curie temperatures of foe microwires are successively and in stepwise fashion slightly higher than that of foe first microwire 28. Thus, foe “second” micro wire 30 has a slightly hi gher Curie temperature than die first microwire 28, and foe “third” and “fourth” microwires 32 and 34 each have successive, slightly higher Curie temperatures than the lower-order microwires. In this manner foe re-magnetization pulses (bits) of the microwires 30-34 will disappear (i.e., become a “0" value) under foe influence of foe applied magnetic field from detector 46 at respective temperatures each higher than that of foe first microwire 28 and of all preceding lower-order microwires.

For example, if foe object 44 has a temperature below foe Curie temperatures of both the first and second microwires 28 and 30, all bits of foe array 36 will be read (i.e,, become a “1 ” value) by the device 46. If the object 44 has a temperature above foe Curie temperature of first microwire 28, but below the Curie temperature of second microwire 30, the first bit will have disappeared to the device 46 as a *O” value, and the remaining bits corresponding to microwires 30-34 will be read as a “1” value by the device 46.

As noted above, the device 46 contains algorithm(s) in foe form of look-up table(s) that recognize foatthe disappearance of foe first temperature hit and foe appearance of the second and all higher temperature bits means that foe temperature of object 44 exists somewhere between the first and second Curie temperatures of foe first and second microwires (temperature bits) 28 and 30 (as used herein, detection or determination of sensor or object temperature can refer to WO 2007/134061 PCT/US20O 7/068483 20 a single temperature or an approximated temperature within a range of temperatures). Thus, by reading the temperature-sensing bit data generated by the array 36. and correlating the binary value of this data to the look-up table of interest, tire temperature of object 44 can be determined within the temperature range defined by the interval between the first and second microwire Curie temperatures. Of course, tliis logic applies to all four of Hie microwires 28-34, of the simple Fig. 4 example.

If die number N of temperature-sensing microwires on a given magnetic element temperature sensor have identified Curie temperatures of known increasing sequential order, and these Curie temperatures are selected to beat least somewhat consistent in their increments from one to another, the sensor can’ detect temperatures horn, the first to the N“' Curie temperatures. The resolution of such a sensor is the increment between sequential Curie temperatures. It will be appreciated that even if tire sequential Curie temperatures are not exactly consistent, die relevant look-up table can be constructed and die sensor can properly function.

The microwire alloys of tliis embodiment can have dieir Curie temperatures quantified before or after the alloys have been processed into microwires. In this fashion the complete microwire sensor can be calibrated for temperature sensing. For a given temperature range to be measured, the greater the number of micro wires whose Curie temperatures are quantified and are near-equally spaced within die temperature range, the higher the resolution of the microwire temperature sensor. Preferably, temperature sensors in accordance with this embodiment have at least 20 temperature-sensing microwires, each having sequentially higher Curie temperatures, with first to Nlb microwires and with no more than a 5° C increment between successive microwires.

In cases where a certain temperature-sensing microwire does not disappear in proper sequence with die other microwires (due to a mis-read by die reader/detector, a lack of thermal contact with the others, or other reason), the lack of an acceptable look-up table value preferably causes the reader/detector algorithm of device 46 to attempt a re-read of the sensor 26. If continuous re-reads show the same anomalous temperature data, the reader/detector algorithm can discard the temperature data, use die last measured temperature (or the last measured temperature plus a delta temperature that is based upon a calculation involving the last measured rate of change of temperature and reading time interval), and then try again at the next scheduled read interval. Preferably, steps are taken to ensure that all microwires make good thermal contact WO 2007/134061 PCT/US2007/068483 21 with each other and the object 44 whose temperature is to be measured. One such step is to attach all of the microwires to a thin, thermally conductive substrate. Another step is to employ thermally conductive encasing or potting materials as described hereinafter.

It is known that up to 40 microwires may be detected within a period, and accordingly a magnetic element temperature sensor of this embodiment may contain many more than four temperature-sensing microwires 20 and many more than one (not counting the stop bit) data elements. Data elements, especially if each is encoded with multi-bit data, can be used to store correlation information (such as linear or non-linear relationship constants) that can allow the detector algorithm to decode the “specific numerical value” (temperature bits) to its associated temperature value. This is particularly valuable where a look-up table method is not used. Thus, die magnetic element temperature sensor 26 may store in its data elements data such as a permanent ID code or a “class of object” code. Tins ability to store a “class of object” code allows a single reader/detector algorithm to read several different types of micro wire temperature sensors, each with its own unique look-up table, and still decode toe correct temperature.

It will be appreciated that a number of different encoding/decoding strategies can be employed in sensor 26 and device 46 without departing from the scope of the present invention, providingthat each temperature-sensingmicrowire is designed to lose its re-magnetization pulse properties under the influence of the alternating magnetic field generated by device 46 above its Curie temperature. One option would be the use of bias field element 41, which serves to differentiate the amplitude of the external magnetic field generated by device 46 that is required to exceed the coercive force for re-magnetization of each microwire, owing to its different proximity to each individual mierowire 28-34 and 38-40. This leads to a phase difference in re-magnetization peaks detected by detector 46, thus facilitating differentiation of the six individual microwires. Other variations would include without limitation means to determine a stop or “delineation” bit between temperature-sensing elements and data elements, encoding and decoding of non-temperature data, and differing lengths for some or all of the microwires in order to alter the magnetic responses thereof, Additionally, changes in magnetic properties at temperatures close to the Curie temperatures of the individual temperature-sensing microwires can alter but not entirely eliminate tire detectable re-magnetization pulses thereof. Such altered re-magnetization pulses, having predictable behaviors over specific temperature ranges below the Curie temperatures, may also be used to decode temperature information. This can allow WO 2007/134061 PCT/VS2007/06S483 22 each temperature-sensing microwire to accurately sense more than one temperature. e.g., from a small interval below the Curie temperature up until the Curie temperature.

Second Embodiment; Microwires with Ferromagnetic Sheaths for Temperature Sensing 5 Tliis second embodiment comprises a magnetic element temperature sensor 64 having a plurality of composite temperature-sensing microwires 66 each including a magnetically susceptible microwire of the prior art type described above that has no intentional reduction of its Curie temperature, such that it will retain its large Barkhausen. discontinuity and other magnetic properties as depicted in Fig. 2 throughout the entire operating range of the sensor 64. 10 This microwire structure further includes a surrounding, tubular, structure 68. The overall second embodiment further includes a microwire temperature detector similar to detector 46 having stored rdgorithm(s) capable of decoding the temperature information derived from interrogation of the sensor 64.

In particular, each of the composite micro wires 66 has an innermost alloy 70 surrounded 15 by an intermediate glass coating 72, such that this inner portions of tire composite micro wires 66 are conceptually identical with previously described prior ait microwires 20, Additionally, the structure 68 of the microwires 66 include a tubular sheath 74 of ferromagnetic metal or Ferrite material (such as NiZn or MhZn) surrounding tire coating 72, and an optional outermost glass coating 76 surrounding the tubular sheath 74. The sheath 74 has a Curie temperature carefully 20 chosen so that the individual, inner microwire alloy 70 will produce its signature perturbations (and thus re-magnetization voltage pulses at the detector) only when the microwire is placed in tire alternating magnetic field generated by the detector, and then only above the Curie temperature (or above some temperature near the Curie temperature) of tire ferromagnetic sheath 74. Hence, when the composite microwire 66 experiences a temperature below the Curie 25 temperature of the ferromagnetic sheath 74 (or below some temperature near this Curie temperature), the sheath 74 is ferromagnetic, thus altering tire signature pulse of the microwire 66. Tills may prevent re-magnetization of the composite microwire 66 owing to magnetic saturation caused by tire sheath 74, or may allow the resulting re-magnetization as a biased or “altered'’ signal from the composite microwire 66. For example, the re-magnetization pulse may 30 be offset in phase from its location above the sheath Curie temperature, or tire biasing effect of WO 2007/134061 PCT/US2007/068483 23 the sheath may allow altered re-magnetization responses below and above a plurality of different set point temperatures.

When the composite microwire 66 experiences a temperature above the Curie temperature of die sheath 74, die sheath becomes paramagnetic and thus has no effect upon tire signature pulse of the alloy 70, Therefore, above the individual Curie temperatures of the sheaths 74 (or above some temperatures near these Curie temperatures), the composite microwires 66 act normally (i.e., they cause the detector 46 to detect a voltage pulse as expected in phase, amplitude or the like, as recorded in a look-up table or via some other decoding algorithm). However, when die composite microwires 66 experience temperatures below the Individual Curie temperatures of their sheaths 74, they are either not detectable by the detector, or are detectable but have dieir magnetic properties altered, especially in relation to signature pulses detected above temperatures of the Curie temperatures of their sheaths 74.. Such altered magnetic properties would not fit the parameters of the look-up table or other decoding algorithm, such as phase relationship to an alternating current from the frequency generator 48, or pulse duration.

If the material making up tubular sheath 74 is a ferromagnetic metal, the sheath 74 may be only microns thick or as thick as required for saturation for inner micro wire alloy 70, and for manufacturability. One method of forming the ferromagnetic sheath 74 is described in U.S. Patent No. 7,011,911 entitled “Amorphous Microwire and Method for Manufacture Thereof” Other methods include flame spraying or sputtering. When using these methods for creating the sheath 74, it is not necessary that there be an outermost coating 76. A modified Taylor method may also be employed, wherein an inside glass tube and an outside glass tube are coaxially and telescopically aligned such that the inside glass tube resides within the walls of the outside glass tube. Hie alloy 70 is inside the center glass tube in ingot (rod-shaped) or constituent metal form, whereas the material making up tubular sheath 74 is located between the interritted glass tabes. This sheath material may be in ingot (possibly several rods) or constituent metal form. The alloys are heated to molten by magnetic induction or other suitable means and the resultant molten metal and glass is quickly drawn io form a composite microwire 66.

Techniques are known in the art for adjusting the Curie temperatures of ferromagnetic alloys by addition of trace elements of specific metals. Thus, any number of alloys may be used to make up the tubular sheaths 74. Fig. 9 illustrates that small additions of certain metals (in this case Copper) to feiromagnetic metal elements (in this case Nickel) so as to form a true alloys can WO 2007/134061 PCT/US2O07/O684S3 24 alter the Curie temperature of the resultant ferromagnetic alloys in a predictable way. Also, additions of small amounts of Chromium to iron yield alloys whose Curie temperatures are predictable. See U.S. Patent No. 5,954,984, for a discussion, on modifying the Curie temperature of Nickel with Copper and Aluminum,

The alloys or Ferrite materials used in the fabrication of the tubular sheaths 74 can have their Curie temperatures (or regulation temperatures near their Curie temperatures) quantified before or after the alloys or Ferrite materials have been processed into tubular sheaths 74. Thus, the magnetic element temperature detector 46 carl be readily calibrated for temperature sensing. As before, for a given temperature range to be measured, the more temperature-sensing composite microwires 66 whose sheath Curie temperatures are quantified and are near-equally spaced within the temperature range, the higher the resolution of the temperature sensor. It is preferred to have at least 20 temperature-sensing composite microwires 66, each having a sequentially higher sheath Curie temperature, at most 5° C above the next lowest order sheath. Of course, if the sheath 74 alters the re-magnetization pulse of the microwire 66 over a range of temperatures nearthe Curie temperature of thesheath 74 (say, for instance, by detectably shi fting the phase of the re-magnetization pulse), it maybe possible for the detector to sense and decode multiple temperatures for each micro wire 66 within a certain range, thus requiring fewer microwlres 66 to allow a sensor to accurately measure temperatures over a wide range.

If the material making up the tubular sheaths 74 is a Ferrite or some blend of materials with Ferrite, then the sheath may either be adhered to the glass layer 72, a separate cylindrical bead, or other sintered Ferrite cylindrical object with a central hole such that the alloy 70 and surrounding glass 72 may be placed therein. Alternately, die tubular sheath 74 could be formed as a part of the glass layer 72 by using a glass-ferrite material for layer 72 in lieu of pure glass. U.S. Patent No. 6,909,395 entitled “Radar Absorbing Coatings” describes Ferrite/glass composite material that can be used to either adhere directly to a metal wire or other shape of metal object, or can be adhered to a layer of pure glass that is already adhered to tide metal.

Referring now to Fig. 6, the sensor 64 includes a plurality of micro wires 20 presenting an array 78 of data elements, and a plurality of temperature-sensing composite microwires 66 forming an array SO thereof. The microwires 20 and composite microwires 66 are attached to a sensor or tag substrate S2. which is as thin and as thermally conductive as possible so that the WO 2007/134061 PCT/US2007/06S483 25 sensor 64 maybe placed ill intimate thermal contact with an object (not shown) for temperature measurement purposes.

The micro wires 20 making up array 78 have chemistries giving individual Curie temperatures above die planned operating temperature range usually less than about 400° C for 5 the sensor 64. The composite microwires 66 within array 80 are preferably spaced apart by a distance 84, such that the ferromagnetic or Ferrite tubular sheath 74 of each individual composite microwire 66 does not affect its neighbor composite microwire once the tubular sheath 74' of the individual microwire experiences a temperature above its Curie temperature.

In this simple embodiment, assume that each data element of array 78 is laser coded to 10 a logic state of ** 1 ” or “0. ” Furfh errnore, assume that each of the data el em ents is the same length (say, 20mm) except for terminal elements 83 and 86, winch are significantly longer (say 40mm), Tins extra length ensures that the detected re-magnetization peaks from data elements 83 and 86 are larger in amplitude than the others. Finally, assume that the data element 83 is laser coded to a logical “1 ” value whereas data element 86 is laser coded to a logical ‘O’* value. As described 15 in the first embodiment, each of the elements of both arrays 78 and 80 are made so that the detected phase order matches the depicted alignment order from top (microwire 83) to bottom (composite microwire 88), the latter having the highest sheath Curie temperature of die composite microwires of the array 80. In such case, the detector 46 assigns the first detected pulse (in phase relationship) with the highest amplitude with a logic level “1 ” as the start bit (here 20 depicted as microwire 83) and the last detected data microwire 86 with highest amplitude and with a logic level “0” as the stop bit AH data microwires between the start and stop bits 83 and 86 are detected by the microwire temperature reader/detector as data bits. The intervening data microwires can be used, as described in the first embodiment, for a variety of functions such as tag identification number and “class of object” code. 25 in order to decode the temperature information from sensor 64, assume there are “N” composite microwires from the array 80 drat have ferromagnetic sheaths 74 such that all of the respective sheaths 74 have Curie temperatures which are exceeded (or have regulation temperatures “near” the Curie temperatures) during the normal operating range of the sensor 64. The least significant bit of these N composite microwires 66, detected in phase relationship just 30 after the stop bit 86, and at a specified phase relationship from the stop bit 86, is deemed the “first” composite microwire 89. Thus, the first composite microwire 89 will begin producing its WO 2007/134061 PCT/US2007/068483 26 normal short pulse perturbation only at temperatures above the Curie temperature of its sheath 74, and hence the detector 46 will only then detect its voltage pulse (bit). The first composite microwire 89 will not produce its normal short pulse perturbation below the Curie temperature of its sheath 74. and therefore i ts bit will either be missing from tire b its detected by detector 46, or its pulse will be so altered as to be clearly detectable by the detector 46 as an “altered’* microwire. A “second** composite microwire 90 in phase relationship from the stop bit 86 (the next-to-least significant bit) has a ferromagnetic sheath 74 of slightly higher Curie temperature than that of the first composite microwire 89. The bit of composite'microwire 90 will not be read by the detector 46 or its voltage signal will be detected as “altered” at temperatures below tins higher sheath Curie temperature (or higher temperature near the sheath Curie temperature), but will appear’ as expected in phase and duration at a higher temperature than that of the first composite microwire 89.

Tims, if the sensor 64 is subjected to a temperaturebelow that of the Curie temperatures (or designated temperatures below the Curie temperatures) of both toe first and second composite microwires 89 and 90, no composite microwires will be detected by the detector 46 (assuming that all subsequent higher order composite microwires in array 80 have sheaths 74 with a higher Curie temperature). If the sensor 64 is subjected to a temperature above the sheath Curie temperature (or related temperature) of the first composite microwire 89 but below the sheath Curie temperature (or related temperature) of the second composite microwire 90, the first bit will be read by toe detector 46 but toe second bit will either still not be read by the detector 46 or will have an “altered” signal as read by the detector. Finally, if the sensor 64 is subjected to a temperature hitler than the sheath Curie temperature (or related temperature) of both toe first and second composite microwires 89 and 90, both toe first and second composite microwires will be read by the detector 46.

The detector 46 contains a decoding algorithm that recognizes that toe appearance of the first temperature bit of first composite microwire 89, but toe lack (or alteration of) of toe second temperature bit of second composite microwire 90, and thus signals via display 56, that the sensor temperature exists somewhere between, toe first sheath Curie temperature and the second sheath Curie temperature. Thus, if the sensor 64 is placed in intimate thermal contact with an object whose temperature is of interest, then by reading the composite microwire array bit output WO 2007/134061 PCOTS2007Z0684S3 27 of die sensor 6 4, the detector 46 determines the object’s temperature within the temperature range defined by the interval between the first and second sheath Curie temperatures (or between then- respective temperature near their Curie temperatures).

If the number of composite microwires 66 on the sensor 64 have sheath Curie temperatures known to be in increasing sequential order is increased to “N” composite microwires, and these sheath Curie temperatures are selected to be at least somewhat consistent in their increments from one another, the sensor 64 has detectable temperature range from the first to tire N1’’ sheath Curie temperatures, and has a temperature resolution defined by tire increment between sequential sheath Curie temperatures.

More generally, tire detector 46 decoding algorithm is built to understand that the appearance of tire first through the N~lIh temperature bits generated by the corresponding compositemierowires 66 in tlreir normal pulse state, together with the lack of theNa' temperature bit corresponding to NtJl composite microwire 66 in its normal pulse state, establishes that the sensor temperature exists somewhere between the N*-l'h sheath Curie temperature and the sheath Curie temperature (or between their respective temperatures near the sheath Curie temperatures). The detector algorithm preferably reports this sensor temperature to be the midway temperature between Ν~1Λ and N1’’ Curie temperatures.

Preferably, the acceptable composite micro wire bit patterns and their corresponding sensor temperatures are stored in a look-up fable within the memory of detector 46. Tims, when an acceptable bit pattern is detected by detector 46 from a correlated sensor 64, this pattern is compared against the look-up table to find tire correlating sensor temperature.

In cases where one or more composite micro wires 66 of array SO do not appear in their normal state in proper sequence with the others (due to a mis-read by the detector 46, a lack of thermal contact with the other composite microwires, or some other reason), the detector algorithm preferably attempts a re-read of the sensor 64. If continuous re-reads show the same anomalous bit pattern, the detector algorithm can discard the temperature data, use the last measured temperature (or the last measured temperature plus a delta temperature that is based upon a calculation involving the last measured rate of change of temperature and reading time interval), and then try again at the next scheduled read interval. WO 2007/134061 P C TZU S2002/068483 28

Third Embodiment: Micrvwires with Separate but Adjacent Ferromagnetic Saturation Elements for Temperature Sensing

The third embodiment is conceptually very similar to the second embodiment and differs in the nse of feiromagnetic sheath saturation or biasing elements as separate entities which do 5 not need to touch the surface of the adjacent temperature-sensing microwires, as compared wi th the sheaths 74 of the second embodiment which are bonded or otherwise affixed to central microwxre structure. Referring to Fig. 7, a combination microwire 92 is illustrated and includes a microwire 20 of the type previously described that has no intentional reduction of its Curie temperature, such that it will retain its large Barkhausen discontinuity and other magnetic 10 properties as depicted in Fig. 2 throughout the entire operating range of the sensor. Also, the combination microwire 92 includes an adjacent ferromagnetic sheath 94. The sheath 94 is located near enough to the associated microwire 20 so as to prevent by magnetic saturation or biasing re-magnetization of the microwire 20 and consequent generation of its signature perturbation until the combination microwire 92 experiences a temperature above the Curie 15 temperature (or above some temperature near die Curie temperature) of the sheath 94, Again, as in the case of the second embodiment, the sheath 94 can be designed so that the associated microwire 20 will exhibit a series of different re-magnetization responses below and above different set point temperatures below the sheath Curie temperature, and if desired such multiple different responses can be used for temperature sensing and determination. 20 fn more detail, the sheath 94 is preferably in the form of a thin rectangular sheet of feiTornagnetic metal whose size is not significantly wider than that of the associated microwire 20, and whose flat surface may be bent into a half-round shape (or, in the case Ferrite, may be sintered into a half-round or some other suitable shape). The Curie temperature of the shield 94 is carefully chosen so that the associated microwire 20 will produce its signal perturbation (and 25 thus a re-magnetization pulse of voltage) when the combination microwire 92 is placed in an alternating magnetic field of the detector 46 and only when the combination microwire 92 experiences a temperature above the Curie temperature (or above some fixed temperature near the Curie temperature) of the sheath 94. The sheaths 94 need only be microns thick or as thick as needed for saturation of the associated microwire 20, and for easeof manufacturing. Tire same 30 types of alloys or Ferrites described in connection with the second embodiment may be used in the fabrication of sheath 94. Furthermore, magnetic inks (using either ferromagnetic powder or WO 2007/134061 PCT/US2OO7/068483 29

Ferrite powder) are also suitable and have the advantage of being printable on a supporting substrate for die combination microwires 92. .

Referring to Fig. 8, a temperature sensor 96 is illustrated, which is in all respects identical with sensor 64, save for the use of combination microwires 92 in lieu of the composite 5 microwires 66, Accordingly, like reference numerals from Fig. 6 are used in Fig. 8 to denote identical components, and an “a” designation has been used to distinguish the combination micro wires 92 from the composite microwires 66.

Tire operation of sensor 96 is identical to that of sensor 64, and makes use of a similar detector 46 having appropriate decoding algorithms (preferably look-up tables) correlated with 10 the sensor 96. Accordingly, a detailed description of this operation is unnecessary.

The above-described three embodiments, and indeed other embodiments within the scope of the present invention, can be varied in a number of different respects. For example, Fig. 4A depicts an alternative arrangement advantageous for some product applications, Specifically, in Fig. 4A a sensor 26a is provided wherein the microwire data element 40 is attached to a first 15 object 44a, whereas the remaining data microwire 38 and the temperature-sensing microwires 28-34, and optional bias element 41, are attached to a second object 44b, The bit logic of sensor 26a is identical with that of sensor 26, meaning that, evert though the components of the sensor 26a are separated onto objects 44a and 44b, the overall sensor 26a will only operate when all of the sensor components are within the alternating magnetic field generated by detector 46. ff this 20 condition does not exist, then no successful reading using the detector 46 can occur. This construction can be used, for example, to control heating of a two-part object by a heater only if the heater’s detector detects both part of the sensor (and thus both objects 44a and 44b), and to correspondingly prevent any heating unless both pails of the sensor are present and within the magnetic field of detector 46. In such a case the heater control would typically be coupled with 25 the signal processing unit 54 of detector 46.

Of course, this same design concept maybe used when more than two objects are present.

Additionally, more sophisticated data encoding methods such as those described above may be used to correlate one or more pieces of the overall sensor 26a with matching pieces thereof. Such methods may include laser encoding the first data element 40, with a matching multi-bit code for 30 stop data bit 38. WO 2007/134061 PCT/US2007/068483 30

Although the Fig. 4A alternative has been described with reference to sensor 26 of the hrst embodiment, it will be appreciated that the same modification may be used with sensors 64 and 96 of the second and third embodiments if desired.

The microwires forming a part of die sensors 64 and 96, just as in the case of die 5 m i crowires 20 of sensor 26, may be bound onto an obj ect 44 or a thermally conductive substrate such as substrate 82 using an appropriate adhesive. In another alternative, the microwires 20, composite microwires 66 and/or combination microwires 92 may be encased in very thin, non-ferromagnetic, thermally conductive material such as a graphite-filled polymer material that is compression or injection moldable, such as one within the family of materials sold by SGL 10 Carbon under the designation RIDURID®. Other useable high-temperature materials include ceramic potting materials sold by Aremco under the designation Ceramamcast 510, or other flexible high-temperature polymers. With use of such materials the thickness and overall thermal mass of the encasing material should be kept to a minimum in order to minimize thermal lag between the object to be temperature monitored and the core alloy materials of the microwires. 15 Additionally, the microwires of the described embodiments may be twisted into a thread or woven into the structure of an object to be temperature-monitored if appropriate. For instance, the microwires may be woven into a carbon fabric cloth, so long as good thermal contact can be maintained and suitable art means are used to distinguish each temperature-changing element from each other and from each of tire distinctly identified data elements (to include a stop bit), 20

Closed-Loop Feedback System for Heating Devices

The magnetic element temperature sensors and associated detectors of this invention can easily be used in place of the RFID tag and associated RFID reader/detector, respectively, in the closed-loop temperature regulating induction heating systems described in U.S, Patent Nos. 25 6,320,169 and 6,953,919. Thus, a myriad ofheating applications may be accomplished with a temperature-regulating magnetic element technology induction heating system which is similar to the prior RFID systems but with the RFID components replaced by the present sensor and detector components. For instance, a smart range such as described in U.S. Patent No. 6,953,919, a thermal dispensing system as described in U.S. Patent No. 6,822,204, a food delivery system 30 such as described in U.S, Patent Nos. 6,504,135, 6,444,961, 6,274,856, and 6,232,585, and various wanning devices such as cups, bowls, sizzle platters, plates, ski boots and oilier items WO 2007/134061 PCT/US20O7/068483 31 described in U.S. Patent No. 5,954.984 can be modified in. accordance with the present invention.

Furthermore, the same components (sensor and detector) can be integrated into other types of closed loop heating systems that are not induction based, such as closed-loop temperature controlled infrared, halogen and resistive heating systems.

Referring to Figure 11, a closed-loop induction heating system 98 includes a microwire detector 46 (see Fig, 10) incorporated into an induction heating device 100 in lieu of an RFID reader/detector. Tire device 100 includes a control microprocessor 102 operably coupled with detector 46, solid state inverter 104, and rectifier 106, as well as an induction work coil 108 coupled to inverter 104, An AC power source 109 and current sensor 109a are operably coupled with rectifier 106. The field generator and receiving coils 50 and 52 are integrated into a sensor component 110 located beneath a support element 112.

The system 98 is designed to control die temperature of a graphite heating disk 114 such as described in U.S, Patent No. 6,657,170 having on or more embedded microwire sensors 116 of &e present invention. The disk 114 has graphite layers 118 above and below sensor 116 as shown. Of course, any other induction-heatable object can be controlled instead of the disk 114, such as a multiple-ply cooking utensil (pot or pan, for example) having one or more embedded sensors 116 therein. The feedback of temperature information from the sensor(s) 116 is detected by the detector 46 and this information can be used to control the induction heating of disk 114 via control microprocessor 102. If desired, die microwire sensors and detectors of die invention may be used to control other types of heating devices such as halogen or resistive heaters, microwave ovens, or gas or electric ranges as described below with other embodiments of the invention.

Temperature Sensor Slicker

In another aspect of the invention illustrated in Figures 12-22, a temperature sensor similar to the ones described above is incorporated into an adhesive-backed “sticker” 120 that can be quickly and easily adhered to an existing piece of servingware 121such as a plate, dish, pan, pot, bowl, tray, glass, etc. Once sucha temperature sensor sticker is adhered to a piece of servingware, die servingware may be placed on or in the vicinity of an induction heater, heat lamp assembly, steam heating unit, microwave oven, or other type heating unit equipped with a re-magnetization response detector or other type detector. The detector interrogates the WO 2007/134061 PCT/US2007/0684S3 32 temperature sensor to sense the presence of the servingware, the type of serving ware, and temperature data for the servingware. A controller coupled with the detector and heating unit receives signals from die detector winch are indicative of the temperature, or temperature range, of the servingware and which are used to control the cycling or other operational parameter of the heating unit. Tirus, the temperature of the servingware may be continuously or periodically monitored, and the heating unit may be controlled so as to heat the servingware to a desired temperature range and to maintain it within the temperature range.

Referring to Figures 12-15, an embodiment of a temperature sensor sticker 120 may be formed by adhering a micro wire sensor 122 or a plurality of such microwire sensors to a substrate 124 with an adhesive 126 and then covering the exposed face of the adhesive with a release layer 128. When die release layer is removed, the temperature sensor sticker may be adhered to a piece of servingware 121 so that die servingware (and food placed thereon) may be monitored and heated as described below. hi more detail, the microwire sensor 122 is preferably a glass-coated amorphous magnetic microwire sensor'as described above. The temperature sensor 120 may include only one microwire sensor 122 as shown or may include several. Each microwire sensor 122 preferably comprises a plurality of parallel microwires 130 as best shown in Figure 14. The number of micro wires in each micro wire sensor 122 depends upon the desired operating range of the temperature sensor 120 as well as the number of bits of data storage required. The individual microwires 130 are preferably small in diameter, approximately 25-35 microns, and between 10 - 40mm in length. This allows the overall temperature sensor 120 to be relatively thin and small in diameter as discussed below.

The microwires 130 making up toe microwire sensor 122 can store data or information relating to the servingware to which the temperature sensor 120 is attached. For example, the microwires may store data indicating toe type and size of toe servingware, heating properties for toe servingware (e.g. its thermal conductivity and mass), the type of food typically placed on toe servingware, and a desired temperature or temperature range for the servingware. Each temperature sensor 120 may store data unique to toe particular servingware to which it is attached so that each piece of servingware (and food thereon) can be heated appropriately.

The substrate 124 holds toe entire temperature sensor 120 together and provides toe individual microwires 130 a semi-stiff structure to be aligned with when die temperature sensor WO 2007/134061 PCT/US20O7/O68483 33 120 is assembled. The substrate 124 also allows the temperature sensor 120 to be easily handled, oriented, and placed upon die servingware 121. The substrate 124 is preferably circular with a diameter of approximately 20mm and a thickness of0.005 inches, but it maybe formed in other shapes and sizes without departing from the scope of die present invention. The substrate 124 5 can be formed of any suitable material but is preferably formed of polymer film material such as PET, polyethylene, polypropylene, etc, or a cellulose, paper, or other pulp-type material.

The substrate 124 can remain permanently upon the servingware 121 or can be chosen from a material that dissolves in water. If fee substrate 124 is designed to remain with the servingware 121, it is preferably formed of translucent film with a continuous use temperature 10 greater than that of the servingware to which it is attached. For a dissolvable substrate, the substrate maybe formed of a material similar to that of DissolvX™ labels by Paxar. Such labels simply disintegrate in a dishwasher at any temperature within seconds. Several other companies such as Spectrim Label and Equipment, Inc. also sell dissolvable labels that are suitable for the substrate. 15 The adhesive 126 serves several purposes. First, it secures the microwires 130 winch form the microwire sensor 122 to the substrate 124 in a proper orientation. Second, it allows the entire temperature sensor sticker 120 to be affixed permanently to a piece of servingware 121 when tile release layer 128 is removed. The type of adhesive used preferably has tire following properties: 1) it should firmly bond the microwires 130 to the servingware, 2) it should survive 20 long-term in the use environment of the servingware (i.e, be resistant to tire cleaning solvents used, be capable of operating at the use temperature of the servingware, etc.), and 3} it should be easily cured in minimal time.

In one embodiment of tire temperature sensor 120, the adhesive 126 is cured within seconds by an ultraviolet light source, and the substrate 124 dissolves away the first time the 25 servingware 121 is washed in water. Just about any adhesive may be used, an example of which is selected from IheDYMAX OP Series family of Ultraviolet light (UV) curable optical assembly adhesives from a company called DYMAX. These adhesives are optically clear, high strength, low stress high performance UV curable optical assembly adhesives that cure in seconds upon exposure to UV light, DYMAX OP Seri es UV cure resins are single component, low outgassing, 30 low shrinkage resins that have a gap filling capability to % inch or more, as well as a long room temperature shelf life. They are ideal for applications such as fee attachment of ceramic, glass, WO 2007/134061 PCT/US2O07/O68483 34 quartz, metal and plastic components to glass. The release layer 128 may be formed of any suitable material sucli as a film selected from either the Dupont® Tedlar® family of polyvinyl fluoride films or the 3M Fluoropolymer, 2.9 Mil Medical Release Liner 9956.

Referring to Figure 15. the thickness of file adhesive 126 between the substrate 124 and 5 the release layer 128 need not be much more than the diameter of the individual micro wires 130,

For example, the thickness of the adhesive layer 126 may be approximately 30 - 50 microns when used with microwires 130 that are approximately 30 microns in diameter. The thickness of the release film is approximately 0.003 inches. The overall thickness of file temperature sensor 120 (with the release layer attached) is preferably approximately 0.01 inches, but may be 10 between 0.005 - 0.03 inches.

The temperature sensor 120 may be assembled by machine using means known widely in the art to pick and place wires onto adhesive layer substrates. Many temperature sensors are advantageously made on one large substrate sheet with one large release liner and then individual temperature sensors are die-cut out of the large sheet. 15 Once assembled, the temperature sensors 120 can be quickly and easily affixed to any type of servingware, Figure 12 shows a dinnerware plate 121 with a temperature sensor 120 affixed to the bottom of fine plate within file plate’s foot 123 or lower rim. The dinner plate is shown as an example only, as the temperature sensor 120 may be affixed to any type of servingware. 20 Before attaching the temperature sensor 120, the attachment area of the servingware 121 should first be cleaned to remove oils or other contaminants that may prevent bonding of the adhesive. If the servingware is a dinnerware plate or similar object, it may simply be washed in a dishwasher. Referring to Figures 13 and 14, the release layer 128 is then removed to expose one face of the adhesive layer 126, The entire temperature sensor 120 is then placed on the 25 servingware with file exposed adhesive face against the servingware, A UV light curing spot lamp such as the BlueWave© 200 UV Light Curing Spot Lamp from DYMAX® Corporation may then be used to cure the adhesive. Die hglitguide of the curing lamp is focused on the substrate and after approximately 5 seconds of exposure, the adhesive layer 126 is cured and the mtcrowires 130 making up the microwave sensor 122 are 3 0 permanently bonded to the underside of the plate 121. WO 2007/134061 PCT/US2007/068483 35

These steps may be repeated forother plates or servingware, then all the servingwaremay be placed in a dishwasher. If the substrate 126 is formed of dissolvable material» it will dissolve in the dishwasher, leaving behind Just the thin microwires 130 and the thin adhesive layer 126 as shown in Figure 12. The plates or other servingware are now ready for use within a 5 servingware warming system described below.

The specific process for affixing the temperature sensors 120 to the servingware may be modified. For example, a different cleaning solvent may be used to prepare the application area on the servingware· When adhesives other than UV-curable adhesives are used, a heat cure or air temperature cure, rather than the UV light cure, may be used, or the adhesive may not require 10 any curing. Finally, the substrate 126 may be permanent rather than dissolvable, thus requiring no dissolving step in the process.

Various Embodiments of The Servingware Warming System

Once the temperature sensors 120 are assembled and adhered to the servingware, one or more pieces of die servingware with food thereon may be kept warm by a servingware warming 15 system described below. Each embodiment of the servingware wanning system comprises a heating unit of some kind whose power output is controlled, at least in part, by information read from tire temperature sensor 120 on a piece of servingware. The servingware warming system employs a temperature feedback, closed-loop control method described in more detail below. Although a specific piece of servingware may be shown as the preferred servingware for each 20 embodiment below, the embodiments may use various sizes, shapes, or types of servingware, as long as the servingware is fitted with a temperature sensor 120.

Flat-Surfaced Halogen Heater Equipped With A Microwire Reader/Detector for Closed-Loop Temperature Feedback 25 Figure 16 illustrates a servingware wanning system 132 comprising a flat-surfaced halogen heater 134 such as that marketed by Deni or such as the Aroma PHP-323 Electric Halogen Range, in electronic communication with a microwire reader/detector 136 whose antenna 138 is in communication with a temperature sensor 120 on a piece of servingware 121. The halogen heater 134 includes a power supply and control circuitry 140, a halogen heater 30 control microprocessor 142, an inner ring-type halogen lamp 144, an outer ring-type halogen lamp 146, a reflective light guide 148, and a flat surface top 150 upon which the servingware 121 WO 2007/134061 PCT/US2007/06S483 ' 36 rests. The power supply and control circuitry 140 gets its power from a conventional alternating current power supply 152 and thereafter uses tire electricity to provide power to tire inner· and outer halogen lamps 144, 146, wherein die amount of power is determined by the control microprocessor! 42 and is affected by switching/rheostat control within the control circuitry 140.

The halogen lamps Ϊ44, 146 may be dimmed or shut off completely with a very fast reaction time after commands from the microprocessor 142 are acted upon by the switching/rheostat control within the control circuitry 140. Since the thermal mass of the top 150 is small, and most plates and many other types of servingware have a raised rim 123 or foot that prevents the majority of the servingware from touching die top 150, the thermal energy transfer between die halogen heater 134 and (he servingware 1.21 is essentially all via radiation. Tlius, since halogen lamps have their power output nearly instantaneously adjusted by the microprocessor 142. temperature regulation of the servingware 121 on the top Ϊ 50 is possible with good precision.

Once die halogen heater unit 134 is plugged in and turned on, the microwire reader/detector 136 sends out a pulse of low frequency current to its associated antenna 138, which then produces a pulse of low frequency interrogation magnetic field once per second or at some other interval. If no servingware 121 is on the top 150, die microprocessor 142 does not allow the power supply and control circuitry 140 to output power to the halogen lamps 144,146. Once a piece of servingware 121 with a temperature sensor 120 is placed on the top 150, the micro wire reader/detector 136 senses the presence of the servingware and reads die data stored on the temperature sensor 120. As discussed above, this data may indicate the size of die servingware, heatingproperties ofthe servingware such as its thermal conductivity and mass, the type of food that is typically placed on the servingware, a desired temperature or temperature range for die servingware, and any other useful information. The microprocessor may then use this data to control die heating unit 134. For example, die microprocessor 142 may use the size information to determine whether die outside ring-type halogen lamp 146 needs to be turned on (for larger pieces of servingware that need a large heated surface area.) or if only the inner ring-type halogen lamp 144 needs to be turned on. The light reflector 148 ensures tiiat if only the inner ring-type halogen lamp 144 is on die light is only directed directly above die inner-ring lamp. Tins keeps die outside edge of the servingware relatively cool (except by minimal WO 2007/134061 PCT/US2007/068483 37 conduction from the center of the plate) so that the servingware may be picked up by a waiter, waitress, or oilier person without burning the person’s hands.

Once the microprocessor 142 determines the size of servingware and desired temperature range, the microwire reader/detector 136 and antenna 138 continues to interrogate the temperature sensor 120 once per second or at any other interval so as to determine the temperature of the servingware. This temperature information is used to determine how much power to apply to die halogen lamp(s) 144 and/or 146. Changing die intensity of the lamps 144, 146 or simply cycling the lamps on and off in some variable duty cycle, based upon temperature feedback, allows the halogen heater 134 to regulate the temperature of the servingware 121 at the pre-coded temperature of the temperature sensor 120. When the servingware is removed from the top 150, the microwire reader/detector 136 determines that the temperature sensor is no longer present and thus communicates with the halogen heater's microprocessor 142 which shuts off current to the halogen lamps 144, 146.

Heat Lamp System Employing a Microwire Reader/Detector for Closed-Loop Temperature Feedback A common radiation heating method used by restaurants to keep single-serving food portions warm is to use one or more ‘heat lamps” that are most often positioned above a table or counter upon which full plates of food are set while waiting for a waiter or waitress to deliver the plates to customers. “Heat lamps” as used herein may include infrared emitters, halogen lamps, halogen lights, infrared bulbs, infrared tubes, or infrared lamps. Heat lamps use relatively low amounts of energy, heat quickly, and are low cost. Infrared emitters differ from standard illuminating lamps in their low filament temperature, resulting in much less light and more infrared radiation.

Heat lamps are often simply halogen bulbs within a metal focuser enclosure, whereby foe infrared radiation is focused like a spotlight down onto plates of food. Halogen lamps, bulbs, tubes and other forms of emitter produce more than 80% of their heat in radiant form at the short wave end of foe electromagnetic spectrum. Consequently this energy is transmitted through air with little loss, only being absorbed by the food arid plate at which it is shined.

Figure 17 illustrates an exemplary servingware wanning system 154 utilizing a heat lamp 156 such as foe model DL-750-CL heat lamp sold by the Hatco Corporation, Electric current to WO 2007/13406Ϊ PCI7US2O07/O68483 38 the heat lamp is controlled by a halogen power supply and control circuitry 158 which in turn takes its instructions from a control microprocessor 160, The control microprocessor 160 communicates with a reader/detector 162 which is connected to a transmitting and receiving antenna 164. A glass or thin non-ferromagnetic counter 166 supports servingware 121 equipped with a temperature sensor 120. The heat lamp embodiment of tire servingware warming system operates substantially the same as tire flat-surface halogen heater embodiment described above except for tire differences in the heating technologies. Namely, the heat lamp 156 is cycled on and offby the microprocessor 160 and power supply and control circuitry 158 at least partly due to information read from the temperature sensor 120 by the reader/detector 162.

Magnetic Induction Equipped Food Well Employing Microwire Reader/Delector and Utilizing Induction-Heatable Food Pans for Closed-Loop Temperature Feedback

Figure 18 illustrates an embodiment of a servingware warming system which utilizes an induction heating system 168 including induction coils or elements 170, an induction power supply and control circuitry 172 connected to a conventional power source 174, a microprocessor or other control unit 176, and a microwire reader/detector 178 and associated antenna 180, In tins embodiment, the servingware is a pan 182 which can be placed in a food well 184.

To minimize costs, only one raicrowire reader/detector 178 and associated antenna 180 is required per food well 184. Each food pan 182 has two temperature sensors 120 attached at the small-dimension ends of the food pan. The temperature sensors 120 can of course be attached to other parts of the pan 182 so long as they can be interrogated by Uie reader/detector 178 and antenna 180.

The food pan 182 may be constructed by using a polymer pan body material such as polyethersulfone or polyimide. As illustrated in Figure 19, a copper trace resistive grid 186 is bonded to the outside surface of tire pan so as to form a continuous circuit whose pathway traces over all sides of the pan. On the two small-dimension ends of the food pan reside the susceptor-portion of tire copper resistive circuit grid. This susceptor-portion is designed to have enough of an inductance so as to couple well magnetically with the work coil 170 of the induction beating unit 168. On each of the susceptor portion sides, near the bottom edge of the pan, is attached a temperature sensor 120 across several of tire copper resistive grid traces so that die temperature sensor 120 is assured thermal contact with at least one copper trace. Since the WO 2007/134061 PCT/US2007/068483 39 copper traces are identical in cross sectional area they should heat at an identical rage. Thus, if the resistive grid is applied over the pan surface in a uniform density, the heating of the pan should be even.

The operation of the magnetic induction-equipped food well system is nearly identical to the heat lamp embodiment except for the differences in heating technologies. Namely, the servingware 182, made with die attached complete-circuifheafing grid 186 shown in Figure 19, is inductively heated over its entire surface to a uniform temperature by the induction heater 168, which is ccmtrolled by information read from die temperature sensor 120 attached to- the pan’s heating grid by the microwire reader/detector 178 in communication with the control circuitry 172. Heating is accomplished by inducing current to flow along the resistive grid 186 by magnetically coupling the induction work coil 170 to the susceptor-end of the microwire sensor-equipped food pan. This induced current fosters Joule heating along the surface area of tire pan, which is in turn conducted tlirough the pan. to the food {herein.

Water Bath Food Well Equipped with Microwire Reader/Detectorfor Closed-Loop Temperature Feedback A common device used by restaurants to keep food in multi-serving portions warm is a “steam table.” A steam table is a table in which one or more containers of food (usually rectangular pans) are kept warm by hot water or steam circulating below the pans within a “food well”. The steam table may only accommodate one food container or it may accommodate many food pans for buffet style service. Often, tire food well has a Calrod resistive heating element within the water bath that heats the water to a high temperature, often high enough to convert tire water to steam, so as to keep die food pan within the food welt and thus the food therein, warm. For single food well systems such as buffet chafing dish systems, a can of petroleum material is often used to heat the water within die food well. The food pans themselves are typically made from either stainless steel or high temperature polymer materials such as polyethersulfone or polyimide.

Figures 20 and 21 illustrate a steam fable 188 embodiment of the servingware wanning system. In this embodiment, the servingware is a pan 190 placed in a standard water-bath food well 192 such that toe pan is heated over its entire surface by steam generated by a submersed Calrod element 194. Hie power of the Calrod element 194 is controlled by a power supply and WO 2007/134061 PCT/OS2007/068483 40 control circuitry 196 which in turn is controlled by a microprocessor or other control unit 198 at least partially in response to data read from a temperature sensor 120 on the pan by a reader/detector 200 and its associated antenna 202.

To minimize costs, only one microwire reader/detector 200 and associated antenna 202 5 is required per food well 192. Each food pan 190 has two temperature sensors 120 attached to the small-dimension ends of the food pan(the pans are typically rectangular in shape), but the temperature sensors may be placed elsewhere as long as they can be interrogated by the reader/detector 200 and antenna 202.

Hie operation of the steam table embodiment 188 is virtually identical to the heat lamp 10 embodiment, except for the differences in heating technologies.

Microwave Oven Equipped with Microwire Reader/Detector

Figure 22 illustrates a microwave oven 204 embodiment of the servingware warming system. In this embodiment, the servingware may be a serving dish 206, bowl, plate, browning 15 d evice that employs mi cro wave-susceptible mated al s, or any other microwave-safe food holder.

The sensor-applied servingware 206 is placed in the microwave oven 204 whose magnetron 208 power output is controlled by a power supply and control circuitry 210 which is in turn controlled by a microprocessor or other control device 212.in accordance with information read from die temperature sensor 120 by a microwfre reader/detector 214 and its associated antenna 216. 20 It is important to note that the inner microwave housing should be made with tinn noir-magnetic sheet metal so that the microwfre antenna 216 may be placed on the outside of the microwave’s inner housing. The low transmit and receive frequency (near 100 to 300 Hz) allows the temperature sensor 120 to be read successfully by the microwire antenna 216, It is also important to note that the antenna 216 should be as large in surface diameter as the bottom floor of die 25 microwave so as to achieve the maximum read range as well as to ensure that die user may place the servingware 206 at any location within the microwave 204 and still achieve communication between the temperature sensor 120 and the antenna 216.

The operation, of tliis microwave embodiment is virtually identical to feat of fee heat lamp embodiment, except for fee differences in heating technologies. Since most microwaves control 30 their output power by variable duty cycling of fee magnetron’s power, it is possible to synchronize fee communication periods of the reader/detector 214. antenna 216, and temperature WO 2007/134061 PCT/OS2007Z068483 41 sensor 120 to the off-times of the magnetrons duty cycle. Tins allows the reader/detector 214 to communicate successfully with the temperature sensor 120 despite the microwave radiation within the microwire heater.

Although the invention has been described with reference to the preferred embodiment 5 illustrated in the attached drawing figures, it is noted that equivalents may be employed and substitutions made herein without departing from the scope of die invention as recited in the claims. For example, the temperature sensor 120 may be formed of materials and in shapes and sizes not disclosed herein without departing from the scope of the claims.

Having thus described the preferred embodiment of the invention, what is claimed as new 10 and desired to be protected, by Letters Patent includes the following: