Windproof waterproof breathable seamed articles

Breathable, waterproof and windproof sewn items

The present invention generally relates to waterproof and breathable sewn items that show high levels of curability and allow people who use them a high level of flexibility and strength of the article. The present invention is of particular interest for use in right hand cladding and adaptable foot coverings.

Background of the invention

Waterproof and breathable items are used for various purposes such as outdoor activities, sports activities, skiing, cycling, military operations and fire fighting operations. A sewn item, such as a glove, can be waterproof because its outer covering material is waterproof. Alternatively, such a glove can also be made waterproof by a state-of-the-art construction in which the cover material is air permeable and water permeable and another layer is disposed on the back side of the cover material that It consists of a functional layer material that is impermeable and permeable to water vapor (commonly referred to as a glove insert). Some materials suitable for such a functional layer include PTFE, expanded PTFE provided with hydrophilic agents and / or impregnation layers; Breathable polyurethane layers or elastomers, such as copolether esters and laminates thereof.

Due to the broad protective demands of such articles, they are commonly comprised of multiple layers of material that are typically bonded around the periphery of the glove. Typically, the increased glove thickness is directly related to a loss of touch sensitivity and dexterity. Touch sensitivity and dexterity have traditionally been improved by using thin glove constructions or by treating the surface of the gloves with a type of sticky or gripping material, such as a low modulus polymer coating applied to the outer surface of the areas of the fingers and the palm of the glove. However, these coatings show disadvantages such as the lack of sensation in the fingertips and control, when applied to gloves more than 0.254 mm thick. Several attempts have been made to provide improved touch sensitivity and dexterity; however, any of the successes has been limited.

Alternative thick thermoplastic film constructions have also been carried out in which complete insertion or sewing are comprised of thermoplastic film. Unfortunately, these thick polyurethane seams are intrinsically rigid, making them undesirable for glove inserts. Additionally, these thick polyurethane films have virtually no breathability, which also makes them undesirable for most applications of gloves or clothing.

US Patent 5,325,541 discloses a waterproof sock cover comprising an inner liner composed of a waterproof, water vapor permeable, substantially non-stretchable fabric, in which the water vapor permeable and waterproof inner liner fabric It is heat tight.

US Patent 5,981,019 discloses a composite membrane material preferably comprising a porous expanded polytetrafluoroethylene (PTFE) film laminated to a reinforcing material.

US Patent 5,036,551 describes elastomeric composite fabrics that have a layered construction and are made of a microporous polymeric membrane, a water vapor permeable polymer and an elastomeric thermoplastic nonwoven material. Elastomeric composite fabrics provide barrier properties with water vapor permeability and are useful in articles of clothing and other items that fit around another object.

US Patent 5,480,455 discloses a liner comprising an expanded polytetrafluoroethylene membrane coated on its inner surface with a polyurethane material to aid in moisture isolation.

US Patent 6,036,551 discloses elastomeric composite fabrics that have a layered construction and are made of microporous polymeric membrane, a water vapor permeable polymer and an elastomeric thermoplastic nonwoven material.

US Patent 4,430,759 discloses a glove that has three layers, an outer layer of leather, fabric or the like, an inner lining of an insulating material and an intermediate member of a thin plastic.

US Patent 5,981,019 discloses a seam that joins two laminates and protects against filtration and air passage.

EP 0410292 discloses an insert for lining cloth articles. The seams are joined uniformly and

They are easily slid over the inner protective lining of the fabric.

GB 2326606 discloses a composite water vapor permeable fabric used in clothing, footwear, hats, gloves, etc., comprising a laminate of an expanded polytetrafluoroethylene (PTFE) membrane sheet and a non-porous PTFE layer formed on top of it.

Although continuous attempts have been made to create a thin, durable, durable, waterproof, non-textile stitched article, none have been successful in meeting all these needs described above.

The present invention solves a long-standing need in the art of a multilayer non-textile stitched construction that is capable of forming flexible articles without the need for folding or pleating techniques. The present invention provides waterproof, thin, breathable, non-textile sewn items that are particularly well suited as inserts for right hand coating on glove systems or that can be used alone as a hand coating. The present invention has the added advantages of being strong for assembly in commercial factories without damage and imperviously lasting in field use.

Summary of the invention

The present invention provides a sewn article comprising (a) a first non-textile material comprising a first layer of microporous polymer and a first layer of thermoplastic polymer; (b) a second non-textile material that purchases a second layer of microporous polymer and a polymeric layer; and (c) a seam that joins said first non-textile material to said second non-textile material in which said seam has a stiffness of less than 0.984 g / mm determined using ASTM D6828 test procedure as described herein and a resistance of more than 0.7 N / mm determined using ASTM D1876 test procedure as described herein and wherein said seam is a thermal weld constructed through a welding tool.

The first non-textile material preferably shows impermeability and abrasion resistance at more than 63 cycles using the ASTM D3886 test procedure.

The present invention further provides a glove system comprising an outer covering material having an opening side for hand entry with an edge on the opening side for hand entry; and an insert comprising the sewn article; in which the glove insert is conformably sized to be inserted insertably into the respective cover.

Brief description of the drawings

Embodiments of the invention will be described together with the Figures, in which Figure 1 shows a cross-sectional view of the upper side of a glove insert representing the orientation of the layers. Figure 2 shows a cross section of a thermoplastic polymer layer adhered to a microporous layer through an adhesive layer. Figure 3 shows a cross section of a thermoplastic polymer layer adhered to a microporous polymer layer through an adhesive layer. Figure 4 shows a cross section of a waterproof sealed edge formed by joining two identical non-textile materials. Figure 5 shows a cross section of a waterproof sealed edge formed by joining two different non-textile materials. Figure 6 shows a cross section of a sealed waterproof edge formed by joining two non-textile materials in which the seam is formed by sealing a thermoplastic polymer layer with a microporous polymer layer, resulting in the formation of a layer of Interface. Figure 7 shows a hand coating system constructed using three main layers in which an insulation layer is introduced into a waterproof and breathable insert, which is introduced into an outer layer of a hand coating of the invention.

Detailed description of the invention

The present invention provides a material suitable for making waterproof and breathable sewn items useful as hand covers, inserts for glove systems, foot covers and other clothing.

For the purposes of this application it should be recognized that the following terms have the meaning set forth below unless otherwise indicated:

"Adhered" or "adhered together" means that the polymeric material (eg expanded PTFE film) and the textile material are joined together by suitable bonding means. The joining means can be adhesive points, adhesive applied as a continuous grid pattern, adhesive

applied as continuous lines, a layer of breathable continuous adhesive, a fusion-bonded interface or any other material that provides adhesion between the desired layers. "ASTM D3886 test procedure" - for the purposes of the present patent, the ASTM D3886 test procedure must refer to a method by which a multidirectional mode with sandpaper 0 is used as an abrasive against said first non-material. textile; wherein the first non-textile material is held in a fixed position by an inflatable diaphragm and in which a pressure of four psi (27.58 KPa) is applied to said diaphragm and a one-pound load (0.45 Kg) to abrasive. For comparison of results, sandpaper 0 from Norton Abrasives Worchester, MA A621 Emery Grit 0 must be used; part number 662611 01290. "Breathable" refers to materials that have a Water Vapor Transmission Rate (MVTR) of at least about 1,000 (grams / (m2) (24 hours)). "Compound" refers to a material formed from two or more parts. For example, a composite material can be formed by multiple layers of compounds in which each layer can be attached to another layer through suitable bonding means. The composite materials of the present invention do not require any textile layers.

"Dexterity" refers to the ability to perform a difficult action quickly and skillfully with the hands or facilitate rapid handling. Right-handed gloves provide the ability to perform a difficult action without the need to remove the gloves.

"Expanded PTFE" or PTFEe is used to indicate a membrane comprising a microporous PTFE structure in which there are PTFE nodes interconnected by PTFE fibrils. The basic construction and properties of expanded PTFE are described in several references, including US Pat. Nos. 3,953,566; 3,962,153; 4,096,227 and 4,187,390, all incorporated herein by reference.

"Insertion" refers to a sewn article that provides the user with the protective barrier to prevent toxic and / or non-toxic liquids from contaminating the skin. The insert can provide impermeability and / or breathability to a sewn article. An example of an insert is a glove layer that is inserted between the outer cover and a user's hand to provide protection to the user's hand.

"Interface layer" refers to a layer formed by the union of two polymeric layers. For example, in the present invention the interface layer is formed by sealing a thermoplastic polymer layer with a microporous polymer layer, which results in the formation of an interface layer in which heat allows the thermoplastic polymer layer to be combine with the porous polymer layer.

"Laminate". For the purposes of the present application, "Laminate" indicates a compound comprising a polymer layer and at least one textile layer which are typically adhered to each other.

"Microporous" is used to indicate a continuous layer of material comprising microscopic pores. The present invention preferably uses a microporous polymer membrane having a microscopic structure of open interconnecting micro-holes. It shows air permeability and as such, imparts or does not prevent water vapor permeability. The microporous membrane typically used is 5 micrometers to 125 micrometers thick, more preferably of the order of about 5 micrometers to about 40 micrometers. Useful polymers of the microporous membrane material include plastic polymers, as well as elastomeric polymers. Examples of suitable polymers include polyesters, polyamide, polyolefins including polypropylene and polyester, polyketones, polysulfones, polycarbonates, fluoropolymers, polyacrylates, polyurethanes, copolyethers, copolyetheramides and the like. Preferred polymers are plastic polymers. The most preferred microporous polymeric membrane material is expanded microporous polytetrafluoroethylene (PTFE). These materials are characterized by a multiplicity of open microscopic interconnection voids, high void volume, high resistance, soft, flexible and stable chemical properties, high water vapor transfer and a surface that shows good pollution control characteristics. United States Patent No. 3,953,566 and United States Patent No. 4,187,390 describe the preparation of such microporous expanded polytetrafluoroethylene membranes and are incorporated herein by reference.

"Touch sensitivity" refers to the ability to feel or touch and sensitivity to the stimulation of the sense of touch. For example, the tactile gloves allow the sensation in the fingertips and the control.

"Thermoplastic" refers to materials capable of softening repeatedly by increasing the temperature and hardening by reducing the temperature. It refers to those materials that, when heated, undergo a substantially physical change instead of a chemical one and that in the softened stage can be shaped into articles by molding or extrusion or by melt bonding to another material.

"Textile" is used to indicate a woven, knitted or non-woven material, which uses synthetic fibers, natural fibers or combinations of synthetic and natural fibers.

"Waterproof" is determined by conducting an impermeability test as follows: materials or compounds (or sewn flat materials or compounds) are tested to determine the impermeability by

the use of a modified Suter test apparatus, which is an exposure to low water inlet pressure. Water is forced against a sample area of ​​approximately 10.8 cm in diameter sealed by two rubber gaskets in a clamp arrangement. The sample opens at atmospheric conditions and is visible to the operator. The water pressure in the sample is increased to approximately 69 millibars by a pump connected to a water tank, as indicated by an appropriate probe and regulated by an in-line valve. The test sample is at an angle and the water is recirculated to ensure contact of water and not air against the bottom surface of the sample. The upper surface of the sample is visually observed for a period of 3 minutes for the appearance of any water that could be forced through the sample. Liquid water observed on the surface is interpreted as a filtration. An approved or degree of impermeability is given if no visible liquid water is observed in 3 minutes. The approval of this test is the definition of "waterproof" as used herein.

"Global Filtration Test for Gloves" (WGLT) is used to determine the impermeability of a glove. The global glove leak meter is a device that applies air pressure inside a finished (complete) glove to detect holes in the waterproof component. This test is set forth in United States Patent No. 4,776,209, incorporated by reference. The air that seeps through is seen as air bubbles passing through a water reservoir. The test is not destructive. Specifically, this test is performed with air pressure adjusted to 138 millibar of gauge pressure.

In one embodiment, the present invention provides a sewn article comprising a first non-textile material comprising a first layer of microporous polymer and a first layer of thermoplastic polymer; a second layer of non-textile material comprising a second layer of microporous polymer and a polymeric layer; and a seam that joins said first non-textile material to said second non-textile material to form an article. Surprisingly, the seam shows a stiffness of less than 0.984 g / mm. A stiffness of less 0.984 g / mm is desirable to provide good dexterity to a sewn article. Even more surprising, the seam shows a strength greater than 0.7 N / mm. A seam strength of more than 0.7 N / mm is considered to provide adequate durability for field use and for ease of manufacturing.

The first non-textile material is comprised of a first layer of microporous polymer adhered to a first layer of thermoplastic polymer. The second non-textile material comprises a second layer of microporous polymer and a polymeric layer. In another embodiment, the second non-textile material may comprise only a polymeric layer.

The first non-textile material and the second non-textile material may share certain similar properties or show independent properties with each other, including but not limited to: breathability, impermeability, abrasion resistance and wind protection.

For example, the first non-textile material and the second non-textile material can both show breathability. The first non-textile material and the second non-textile material can both show impermeability. In certain desired embodiments, the first non-textile material and the second non-textile material are breathable and waterproof. These material properties may depend in part on the materials chosen for the desired applications.

In another aspect of the present invention, the first non-textile material and the second non-textile material show different properties. For example, the first non-textile material or the second non-textile material may show the properties of breathability and / or impermeability.

In a preferred embodiment of the present invention, at least one of the microporous polymer layers comprises an expanded polytetrafluoroethylene. In a further preferred embodiment of the present invention, the microporous polymer layer of the first non-textile material and the microporous polymer layer of the second non-textile material both comprise an expanded polytetrafluoroethylene.

In a preferred embodiment of the present invention, the first layer of thermoplastic polymeric film comprises a thermoplastic polyurethane.

The seam that joins said first non-textile material to said second non-textile material is of considerable flexibility because the seam shows a stiffness of less than 0.984 g / mm and also shows a strength of more than 0.7 N / mm. The seam is exceptional in the sense that it is softer and more flexible than the durable waterproof seams previously available.

As readily understood by one skilled in the art, examples of suitable sealing means for forming such seams include but are not limited to impulse sealing, radio frequency sealing, ultrasonic welding, microwave welding and thermal sealing. In a preferred embodiment, the seam is constructed by thermal welding through a welding tool. During the thermal welding construction of the seam, the first microporous polymer layer or said second microporous polymer layer acts as a release agent to prevent adhesion of the layer to the welding tool after contact.

In another aspect of the present invention the sewn articles show surprising abrasion resistance. For example, at least the first non-textile material may also show impermeability and abrasion resistance to

more than 63 cycles using the ASTM D3886 test procedure. In a preferred embodiment, at least the first non-textile material shows abrasion resistance greater than 300 cycles.

Figures 1 to 7 are provided herein to demonstrate the present invention. Figure 1 shows an article sewn in the form of a glove insert 5 of the present invention. The glove insert 5 is shaped to include a finger part 6 that wraps the user's fingers, a dorsal or back part (not shown) that covers the back of the user's hand, a thumb part that wraps the user's thumb 7, a palm part covers the user's palm, a cuff part that wraps the user's wrist and an opening for hand entrance 70 through which the user slides his hand into the glove insert 5. The finger part 6 is shown in these figures as having four separate finger covers. It could also be in the form of a mitt or a lobster pattern (two separate finger covers) without departing from the principle of the invention.

The glove insert 5 is formed from a first non-textile material 10 and a second non-textile material 20. The first non-textile material 10 and a second non-textile material 20 are joined around the desired periphery by a suitable sealing means. to form a seam 30. It is preferred that the seam be a sealed waterproof edge. An opening 70 is provided to allow the user's hand to enter the glove insert.

The first piece of non-textile material 10 forms a side of the glove insert 5 with a first palm part 11 of the palm or front side of the glove insert 5 as well as a first thumb side 12 of the thumb part 7. The second piece of non-textile material 20 forms the opposite side of the finger part, a second thumb side for the thumb part as well as a second palm part of the back side in the insertion of the glove 5. A palm part of the glove insert is thus formed from the first palm part 11 of the first piece of non-textile material 10 and the second palm part of the second non-textile piece 20 which adhere to each other. , as will be described later with reference to the additional figures.

The thumb part 7 of the glove insert 5 has a thumb tip 8, an outer edge of the thumb towards the side of the fingers 9 on the side of the thumb part adjacent to the part of the fingers and an outer edge of the thumb towards the radial side 3 on the radial side of the glove insert 5. The thumb part 7 is formed from the first thumb side 12 of the first piece of non-textile material 10 and the second thumb side of the second piece non textile 20. The finger part 6 has a radial finger side 4 on the radial side of the glove insert 5 and a ulnar side 2 on the ulnar side of the glove insert 5. A fork 31 is positioned between the thumb part 7 and the finger part 6. The fork 31 is therefore placed in the position in which the radial side of finger 4 meets the outer edge of the thumb towards the side of the fingers 9. The cuff portion 75 (present in both dorsal and ulnar parts) of the glove insert 5 is adjacent to the hand inlet 70 of the glove insert 5 and has an outer cuff edge of the ulnar side 85 on the ulnar side of the glove insert 5.

As shown in Figure 2, the first non-textile material 10 is comprised of a first layer of microporous polymer 40 adhered to a first layer of thermoplastic polymer 60. The first layer of microporous polymer 40 and the first layer of thermoplastic polymer 60 is they can adhere through an adhesive 50. Similarly, as shown in Figure 3, the second non-textile material 20 is comprised of a second microporous polymer layer 45 adhered to a polymeric layer 80. The second microporous polymer layer 45 and the polymeric film layer can be Adhering through a second adhesive 55. The adhesive layers, including both adhesive 50 and second adhesive 55, can be applied continuously or discontinuously, depending on the desired result. If an area of ​​a breathable article is desired, the adhesive layer has to be a continuous breathable adhesive or a discontinuous adhesive. A breathable adhesive refers to a hydrophilic adhesive. The breathable hydrophilic adhesive is selected to provide high water vapor transmission as well as good adhesion between the layers. Examples of breathable adhesives include but are not limited to polyurethane polyethers and polyurethane moisture cured polyethers. The adhesive layer may additionally include fillers if desired. The discontinuous adhesive can be breathable or non-breathable, the application of a discontinuous adhesive layer to adhere the microporous polymer layer to a polymeric layer or thermoplastic polymer layers can be produced by various procedures such as, but not limited to, screen printing, gravure and spraying, of which all are known to a person skilled in the art.

The microporous polymer layers 40 and 45 may be comprised of similar or different materials as illustrated in Figures 2 and 3. The microporous polymer layer may comprise expanded PTFE, microporous films made of thermoplastic polymers, microporous films made of thermostable polymers as well. as well as microporous films made from elastomeric polymers. Examples of suitable polymers include polyesters, polyamide, polyolefins including polypropylene and polyester, polyketones, polysulfones, polycarbonates, fluoropolymers, polyacrylates, polyurethanes, copolyethers, copolyetheramides and the like. The preferred microporous polymer material is microporous expanded PTFE. In general, the microporous polymer layer may vary in thickness.

The microporous polymer layer used in the present invention may optionally be coated with one or more additional continuous polymeric layers, such as adhesives or oleophobic layers. For a breathable construction, the continuous polymeric layers used are of a hydrophilic polymer. The hydrophilic layer selectively transports water by diffusion but does not support flow of liquid or pressure-driven air. This

feature imparts to the barrier layer and in turn to items made of it, such as socks or gloves, good pollution control features as it works as a barrier to contaminants of all sizes. In addition, the water vapor transmission characteristics of the material allow user comfort characteristics. It is preferred that at least one of the microporous polymer layers 40 or 45 comprises an expanded polytetrafluoroethylene.

The thermoplastic polymer layer 60 may comprise thermoplastic polyurethane films, silicone films, copolyether films, amide copolyether films, individually or in combination with other suitable continuous water vapor permeable polymers. It is preferred that the thermoplastic polymer layer comprises continuous water vapor permeable polymeric polyurethanes, particularly those containing oxyethylene units, such as those described in US Patent No. 4,532,316.

The thermoplastic polymer layer 60 can be monolithic or microporous. The type of specific polymer used should be chosen so that its junction temperature is in the desired range for the production of airtight seam 30, as shown in Figure 4. It is helpful that the melting point of the thermoplastic polymer is below the melting or degradation temperature of the microporous polymer.

Thermoplastic polymers with binding temperatures between 50 ° C and 200 ° C are desirable. Thermoplastic polymers with higher bonding temperatures can be used in the present invention, as long as their bonding temperature is below about 400 ° C, the temperature at which microporous membrane materials such as expanded PTFE begin to soften or melt. . The use of a thermoplastic polymer allows the pattern to heat around a desired periphery to weld pieces of pattern material together.

Thin thermoplastic polyurethane films are particularly useful, since they can produce flexible, ductile and soft composite layers which in turn can create more dexterous and tactile gloves that include these compounds. It is desirable that the thermoplastic polymer layer have a thickness of less than 50.8 µm and even more preferable, less than 38.1 µm and in a more preferred conformation, less than or equal to 25.4 µm. Thin thermoplastic polyurethane films are available from a variety of sources known to a person skilled in the art. A preferred embodiment uses a monolithic thermoplastic polyurethane as the first thermoplastic polymer layer 60.

As shown in Figure 4, a sewn article can be constructed by the present invention using two opposite layers of the same non-textile material, so that the opposite sides of the sewn article are comprised of identical materials. As shown in this Figure 4, the first non-textile material 10 is comprised of a first layer of microporous polymer 40 and a first layer of thermoplastic polymer 60. The first microporous polymer layer 40 and the first thermoplastic polymer layer 60 can be adhered through an adhesive 50. For simplicity of illustration when similar components are shown, Figure 4 shows two layers comprising elements 40, 50 and 60. Two identical thermoplastic polymer layers 60 are oriented so that they are in contact with each other. In this view the two layers of thermoplastic polymer are joined by a seam 30 that has a waterproof sealed edge constructed using a thermal weld seam. However, any other suitable seam may be used depending on the desired application. When the present invention is practiced in this way using a first non-textile material 10 and a second non-textile material comprised of identical materials, the composition and attributes of the article are uniform therethrough. However, anyone reading the present description should understand that it is necessary that all the described elements of the first non-textile material 10 and the second non-textile material 20 be present to practice the present invention. Therefore, it is possible to have a first layer of microporous polymer 40 and the second layer of microporous polymer 45 which are comprised of the same material. Additionally, it is possible that the first thermoplastic polymer layer 60 and the polymeric layer comprise the same material and that the bonding of the layers is through the use of an adhesive layer 50 that can be identical to the second adhesive layer 55 if construction uniformity is desired throughout an entire article.

Figure 5 shows a cross-section of a waterproof sealed edge or seam 30 formed by joining a sheet of the compound layer shown in Figure 2 and a sheet of the compound layer shown in Figure 3. As shown in Figure 5, the sealed article is therefore comprised of different non-textile layers. As further shown in Figure 5, the second non-textile material is comprised of a second layer of microporous polymer 45 which differs in its composition from that of the first layer of microporous polymer 40 of the first non-textile material. In addition, the first thermoplastic polymer layer 60 differs in composition from the polymeric film layer 80. An expert may wish to use different materials in the first non-textile material 10 and the second non-textile material 20 depending on the intended application of the sewn article. Similarly, an expert can choose to use different adhesives or adhesive application procedures in different areas of an article. It is important to note that although thermoplastic polymer is required to be present in the first non-textile material, it is not necessary that such thermoplastic polymer be present in the second non-textile material. Only the second non-textile material is required to comprise a layer of polymeric film, which may or may not be a thermoplastic polymer. It is also important to note that the thermoplastic polymer can be coupled with the microporous polymer layer or the polymer layer of the opposite material through a seam 30.

As shown in Figure 5, different materials can be used in the polymeric layers of the first non-textile material 10 and the second non-textile material 20. A weld seam can be used to join the opposite composite layers of the first non-textile material 10 and the second non-textile material 20. The layer of compound called second non-textile material 20 may be comprised of expanded PTFE or another second layer of microporous polymer 45, a second layer of adhesive 55 which can be of the same adhesive 50 or of a different one that joins the first layer of microporous polymer to a thermoplastic layer 60. Any or all of the polymeric layer 80 may be different from the materials used for layers 40, 50 and 60, respectively in the composite layer designated as the first non-textile material 10. The specific polymeric layer 80 may be chosen to impart some property particular that cannot be achieved with the first thermoplastic polymer layer 60. For example, a right and durable insert can be produced using a first thermoplastic polymer layer 60 to form the joint to the adjacent adjacent layer different from the second non-textile material 20. Thus, the polymeric film layer 80 can be chosen to impart desired characteristics to the second non-textile material 20 while the first thermoplastic polymer layer of the first non-textile material 10 can be chosen to impart different physical characteristics, thereby providing an article. sewn that can be engineered efficiently to meet specific user requirement needs in view of environmental requirements

or of application.

Figure 6 shows the cross-section of a waterproof hermetic edge of a sewn article. Sewing is formed by joining two non-textile materials. In this case a thermoplastic polymer layer is sealed to a microporous polymer layer resulting in the formation of an interface layer 35 in which the two polymeric layers meet. The interface layer 35 provides strength and durability to the construction while also imparting dexterity. As one skilled in the art will understand, the sewn items of the present invention may comprise any shape and, when desirable, may be transformed into an insert for clothing, hand covers or desirable foot covers for a particular application. Also, an insert in the form of a hand cover can be incorporated as an integral element of a glove system or can be used in a separate application for use as a thin and right hand cover.

Figure 7 generally illustrates a glove system 95. The glove system of the present invention comprises an outer cover material 90 and an insert 5. The insert 5 comprises a first non-textile material comprising a layer of microporous polymer and a first layer of thermoplastic polymeric film; a second non-textile material comprising a microporous polymer layer and a second polymeric film layer; and a seam that joins said first non-textile material to said second non-textile material. It is preferred that the seam has a stiffness of less than 0.984 g / mm and a strength greater than 0.7 N / mm in which, the glove insert is conformably sized to be inserted insertably into the respective outer shell. The glove system may further comprise an insulator or insulating layer 92. In certain applications it may be desirable to include a glove liner positioned or disposed within the cover material, in which the glove insert is located between the glove liner and the cover material.

In a preferred embodiment, the insertion of the glove system is breathable. In a further preferred embodiment, the first non-textile material of the glove system insert shows impermeability and abrasion resistance at more than 63 cycles using an ASTM D3886 test procedure. It is further preferred that the first non-textile material of the insert show impermeability and abrasion resistance at more than 300 cycles.

The impermeability of a glove can be tested using the Global Filtration Test for Gloves described above.

The cover material is shaped to comprise an entrance opening such as an opening side for hand entry with a cover edge on the opening side for hand entry. As described above, the glove insert comprises a first non-textile material comprising a layer of microporous polymer and a first layer of thermoplastic polymeric film; a second non-textile material comprising a microporous polymer layer and a second polymeric film layer; and a seam that joins said first non-textile material to said second non-textile material. The seam has a stiffness of less than 0.984 g / mm and a strength greater than 0.7 N / mm. The glove system may optionally include an insulating layer. The cover material is preferably waterproof. The glove system may also optionally comprise a cuff sleeve disposed close to said hand opening located within the cover with a lower cuff edge and an upper cuff edge, said lower cuff edge being disposed within the cover below. from the edge of the cover by a predetermined lower length and connected to the edge, the edge of the upper fist projects over the edge of the cover by a predetermined upper length; wherein the lower fist edge is connected directly to the cover below the cover edge. The lower cuff edge can be adhesively attached to the cover by a waterproof adhesive seam; join the cover by a sewn seam that is sealed on the sleeve of the inner cuff by means of a waterproof seam sealing tape or join by any other suitable means. In a desired embodiment the cover material may be provided with an inner coating layer. The glove insert and the glove liner are disposed within the cover material and in which the insert of the glove is between the glove liner and the cover material. As used herein, a "glove system" means at least one outer glove cover 90 and an insert 5. The glove system may also optionally include a

Insulation layer 92 (shown) and / or an additional inner liner (not shown). Insulation or other inner linings typically comprise textile layers of hair or wool to provide thermal advantages. As will be understood, the insulation layer 92 may be made from any material that is desirable for a particular application. Also, the glove insert 5 can be incorporated as an integral element of a glove system 95 or can be used alone. The glove insert is comprised of a first non-textile material comprising a layer of microporous polymer and a first layer of thermoplastic polymeric film; and a second non-textile material comprising a microporous polymer layer and a second polymeric film layer. A seam joins the first non-textile material to the second non-textile material and the seam surprisingly has a stiffness of less than 25 g / in and a strength of more than 4 pli. When a glove system is used, the glove insert is defined by a first hand-shaped part comprising the first non-textile material 10 and a second hand-shaped part comprising a second non-textile material 20 sized concurrently in relationship with the first hand-shaped part, the first and second hand-shaped parts being sewn together, to form a hand cover having a plurality of fingers, a thumb finger, a palm part and a dorsal part. In embodiments for which the glove system may further comprise an insulation layer 92, the insulation layer is located between the user's hand and the glove liner when the glove is in use. When used as an integral element of a glove system, the insert is conformably sized to insert insertably into a respective glove cover. The outer glove cover or cover 90 can be produced from any suitable material, such as but not limited to knitted, woven or non-woven materials, leather, composite fabrics or any other suitable material. The outer glove cover may have a pattern according to any suitable pattern, such as but not limited to the Clute Cut Pattern, Gunn Cut Pattern or the Fourchette Pattern, for example. As shown in Figures 1 and 7, the glove system 10 may include any of the following: a palm part 11, finger parts 6, a part of the thumb 7 or an inlet opening 70 directed inwardly with Regarding the user. Although the glove system 5 is illustrated as a conventional glove system, in the sense that it includes an individual finger for each finger of a human hand and a finger for the thumb, it should be understood that the content of the present The invention can be applied to other glove systems that have less than four fingers, but at least one. Additionally, the glove system may be provided with an area that yields elastically (not shown) near a part of the cuff 75 to provide close contact of the glove system to the wearer's wrist.

Although the variations in the present invention are obvious to one skilled in the art, it is specifically mentioned that in certain embodiments of the sewn article, the first layer of thermoplastic polymeric film may comprise a thermoplastic polyurethane. The first microporous polymer layer of the first non-textile material and the microporous polymer layer of the second non-textile material can both comprise expanded polytetrafluoroethylene.

In one embodiment, the composite layer of the first non-textile material 10 is formed by adhering the expanded PTFE layer 40 to the thermoplastic layer 60 using adhesive 50. The orientation of the composite layers of the first non-textile material 10 and the second non-textile material 20 can be adapted as required for individual applications. For example, when they are formed in a hand cover for which the back of a user's hand requires a different level of protection than the palm, the layers of the first non-textile material 10 and the second non-textile material 20 can be orienting so that the second non-textile material 20 is inverted with the polymeric film layer facing outwards, away from the joining surface of the first layer of the thermoplastic polymer 60 of the first non-textile material 10. The only limitation is that at least one layer of thermoplastic polymer has to be oriented towards the corresponding composite layer. In each of these embodiments, a waterproof, right-handed and durable non-textile glove insert can be produced when the layers composed of the first non-textile material 10 and the second non-textile material 20 are sealed around the periphery by a seam 30 as He has previously described being waterproof and airtight.

The first layer of particular thermoplastic polymer 60 is chosen based on the barriers themselves required by the final application. The requirement that the sewn article comprises at least one layer of thermoplastic polymer is critical for the present invention. The thermoplastic polymer layer provides the ability to form a soft but strong enough seam when sealed to a corresponding surface. In certain embodiments of the present invention, more than one layer of thermoplastic polymer may be present. Hand covers produced in accordance with the present invention are desirable for use as insertions in glove systems, hand coating systems comprising a cover, insert and liner. Hand coatings can also be used as an application for a separate non-textile glove for a hand coating to meet the needs of many varied applications through the selection of appropriate material. For example, a hand coating without any cover or lining could be used as a cleanroom glove produced only from layers of first non-textile material and second non-textile material. An example of this type is the use of the combination of expanded PTFE and thermoplastic polyurethane made in accordance with the content of the present invention.

As shown in Table 1 below, it has been observed that the articles of the present invention are flexible, thin and strong, which results in gloves that are dexterous and durable.

Table 1 - Comparison of sewing property

<dl><dt>Sewing Property Measure </dt><dd>Present Invention A-Non-textile TPU insert (1 thousand used TPU films) B-2 Non-woven layer / PTFEc / PU C-3 Non-woven layer / PTFEe / PU D-PTFEe Insertion E-2 Knit Layer / TPU Laminate </dd></dl>

<dl><dt>Thickness (µm) </dt><dd> 127,0 50,8 355,6 558,8 96,5 520,7 </dd></dl>

<dl><dt>Resistance (N / mm) </dt><dd> 0,79 0,14 1,21 22,1 0,33 2,1 </dd></dl>

<dl><dt>Rigidity (g / mm) </dt><dd> 0,433 0,15 1,18 3,58 0,433 1,73 </dd></dl>

Table 1 compares the breathable non-textile insert of the present invention, (A) a polyurethane film insert; (B) a 2-layer insert of expanded PTFE / polyurethane / nonwoven textile laminate; (C) an insert

5 3-layer non-woven textile / expanded PTFE / polyurethane / non-woven textile laminate; (D) the expanded PTFE / polyurethane insert manufactured by a fusion bonded compound as described in US Patent 4,194,041 and (E) a 2 layer insert of knitted textile / polyurethane laminate.

A further surprising attribute of the present invention is the flexibility of the resulting seams. The comparison of flat film properties, including thickness, MVTR and abrasion resistance for the embodiment of Example 1 with the same comparative products described for Table 1 is shown in Table

two. The comparison of these data clearly shows that the present invention provides significantly greater abrasion resistance than all comparative inserts tested, including those with a textile layer.

Table 2 - Base Layer Property Comparison

<dl><dt>Film Property Measured </dt><dd>Invention A-Insertion of TPU film only (1 thousand TPU films used) B- 2 layers non woven / PTFEc / PU C 3 layers non-woven / PTFEc / PU D-only PTFE coated film E- 2 layers of knitted / laminar TPU </dd></dl>

<dl><dt>Thickness (µm) </dt><dd> 63,5 20,3 165,1 304,8 33,0 279,4 </dd></dl>

<dl><dt>MVTR (g / cm2 / 24 h) </dt><dd> 9.900 12.000 8.400 7.000 10.600 6.400 </dd></dl>

<dl><dt>Abrasion (cycles) </dt><dd> 1750 25 375 700 63 1.000 </dd></dl>

Sample A has the lowest stiffness, but inadequate seam strength and poor abrasion resistance. Similarly, sample D, as described in US Patent No. 4,194,041 has an acceptable low stiffness and somewhat improved seam strength; Unfortunately, sample D has a lower abrasion resistance and seam strength than desired. Surprisingly, this

twenty The invention provides an insert or sewn article with low stiffness seams, good breathability of seam strength and superior abrasion resistance.

The sewn items of the present invention may comprise, in addition to decorations, fasteners, treatments for the surface of gloves or independent inserts with a type of sticky or gripping material, such as a low modulus polymer coating applied to the outer surface of the finger areas

25 and palm of the glove.

The following test procedures were used to evaluate the properties and performance of the present invention and comparative products:

Waterproof (initial)

Procedure B of procedure ASTM D751 describes the test used for impermeability. In this test, the sample is held, a fixed hydrostatic head of 48.3 millibars minimum is applied and a minimum of 3 is maintained

minutes An approval result is considered as absence of filtration after 3 minutes where filtration is defined as the appearance of one or more droplets anywhere within the test area with a minimum diameter of three and a half inches (8.89 cm). The side of the sample that faces the cover must be used to test the impermeability of the sample.

Thickness

The ASTM D1777 test procedure entitled "Conventional Test Method of Textile Material Thickness" was used to measure the thickness of laminated layers 10 and 20, comparative materials, as well as hermetic seams.

Rigidity

The ASTM D6828 test procedure entitled "Conventional Test Method to Determine Fabric Stiffness by the Knife / Groove Method" was used to measure the stiffness of the seams shown in Table 1. This procedure involves extending a flat material of 10 , 2 cm X 10.2 cm through a specified hole and then press the material with a knife to force it to move through the hole. For sewing test, this test procedure was modified so that a glove seam travels along an edge of the 10.2 cm X 10.2 cm test sample, with the seam oriented perpendicular to the blade during the rehearsal

For the purposes of the present patent the following test parameters have been used: the groove thickness is maintained at 0.64 cm. The beam is 100 grams. The average of at least four individual measurements was recorded. In order to test the seams, a test sample of 10.2 cm X 10.2 cm with seam was obtained along one side. The seam was oriented perpendicular to the penetrating blade during the test.

Strength, breaking energy, hardness and sewing module

The ASTM D1876 test procedure entitled "Conventional Adhesive Resistance Resistance Test Method (T-Peel Test)" was used to measure the resistance to seam breakage shown in the Table

1. The test samples were cut at 15.2 cm X 2.54 cm. A length of 10.2 cm was used.

MVTR

The ASTM E96 test procedure entitled "Materials Water Vapor Transmission Test Methods" was used to measure the breathability of the materials shown in Table 2. For the purposes of this patent the following test parameters have been used: the water procedure, inverted cup (procedure section 12.4 of ASTM E96-00); temperature = 70 ± 2 degrees Fahrenheit; HR + 50 ± 2%; air speed = 580 ft / min (176.78 m / min) test interval + 2 hours. The water-oriented side is the side that would be oriented towards the body during use. For the present invention the thermoplastic side was used. The sealant used for the test was a thermoplastic polyurethane 4 thousand thick. Three to five individual measurements were recorded for each type of material. Specifically, the inverted cup procedure was used with a free air flow rate of 168 ± 15 mpm measured 5.1 cm above the test sample. The air flow was measured at least 5.1 cm from any other surface and allowed to run for 2 hours. The resulting weight measurements were taken only at the beginning and at the end of the test. The dimensions of the cup were 6.35 cm in diameter and 5.1 cm deep.

Abrasion resistance to impermeability

The ASTM D3886 test procedure entitled "Abrasion Resistance of Textile Fabrics (Inflated Diaphragm Method)" was used to measure the abrasion resistance of the materials shown in Table 2. The specific test parameters were that the multidirectional mode be used with sandpaper 0 as the abrasive. [Sandpaper 0 was obtained from Norton Abrasives Worcester, MA A621 EmeryGrit: 0; Part No. 662611 01290].

The samples were tested by abrasion of the side of the material oriented on the opposite part of the body (towards the cover). The abrasion test was conducted in a multidirectional manner using sandpaper 0 as the abrasive. A solid rubber diaphragm pin without electrical contact (ground) was used.

The diaphragm has a smooth surface without lumps. The diaphragm was inflated to 275.8 ± 17 millibars. A load of one pound (0.45 kg) was applied to the abrasive. The test was completed at 250 cycles or 100 double strokes per revolution. The abrasive paper was changed every 125 cycles. Once the abrasion is complete, the test samples were tested using the water permeability test procedure specified as ASTM D751.

The pressure was applied by inflating a diaphragm to 275.8 millibars. The diaphragm used had no contact pin. A load of 4.45 N was applied to the abrasive. After the number of predetermined abrasion cycles, the ASTM D751 test procedure was used as described above to test the impermeability.

Maximum tensile load and breaking energy

The ASTM D5035 test procedure entitled "Conventional Method for Breaking Force and Textile Strip Elongation" was used to measure the resistances shown in Table 1. The specific test used was the 2.54 cm cut strip procedure. wide with a feed rate of 30.5 cm / min.

The following non-limiting examples are provided to further illustrate the present invention:

Example 1 - Waterproof, windproof, breathable non-textile insert

A waterproof, windproof and breathable non-textile insert was produced as follows. For example, a microporous expanded PTFE film was produced weighing approximately 25 g / m2 and approximately 40 µm thick. Next, the expanded PTFE film adhered to a 25.4 µm thick monolithic thermoplastic polyurethane film (available from Deerfield Urethane, South Deerfield, MA, part number PT1710S) using a continuous layer of applied breathable polyurethane adhesive at a coverage rate of 8 to 10 g / m2. The breathable polyurethane adhesive was a moisture-cured polyether polyurethane adhesive, as described in US Patent 4,532,316.

A gravure process was used for lamination. The multilayer construction was then allowed to cure. This resulted in an article (in accordance with what is shown in Figure 2) having a total thickness of approximately 6.35 mm and an average MVTR of approximately 9,900 g / 24 h / cm2. Once the desired waterproof, windproof and breathable layer has been produced, a non-textile glove insert of the present invention was produced by matching two opposing pieces of thermoplastic expanded PTFE / adhesive / polyurethane compound in the form of a hand each. The two opposite composite pieces were stacked together, with the thermoplastic polyurethane surfaces facing each other and the PTFEe surfaces facing outward at the top and bottom of the stack. Heat was applied to the top of the stack using a steel die heated at approximately 165 ° C for three seconds under a pressure of approximately 22.06 millibars, thereby welding the polyurethane film layers of each of the two together. pieces in the pile. The steel die was shaped in the form of a hand, so that the two pieces joined together in the form of a hand. A steel ruled blade that was formed in the shape of a hand slightly larger than the heated steel die was used to cut the two joined pieces. This glove insert was air permeable when tested with a filtration detector as described by US Patent 4,776,209. The seam strength was measured to be approximately 0.79 N / mm and the stiffness of the seam was measured to be approximately 0.43 g / mm.

A finished glove was subsequently constructed by joining the glove insert of the present invention to an outer wear-resistant cover and an inner lining material using the following traditional glove construction procedure. The insert was reversed (turned around) and adhesive tabs were attached to the fingertips and fists on the polyurethane film side of the insert. These tabs were then attached to corresponding locations of the textile glove liner. Once attached to the liner, the insert was inverted again over the liner. Then the adhesive tabs were attached to the fingertips and the fist on the side of the PTFEe film of the insert. The glove cover was reversed and the adhesive tabs were then attached to corresponding locations on the inside of the cover. Once attached to the insert, the glove cover was inverted again over the insert and the lining. The cuffs of all the components joined together and were closed, resulting in a finished glove comprising a cover, insert and lining that are integrally connected to prevent separation of the layers. The finished glove was tested and found to be waterproof and windproof when tested with the air filtration detector described above at a pressure of approximately 275.8 millibars.

Example 2 - Application of discontinuous adhesive

A non-textile insert layer was produced as described above in Example 1, with the exception that the breathable polyether polyurethane adhesive was applied discontinuously using PTFEe film gravure. This non-textile layer was subsequently used to complete the glove inserts of the present invention using the same insertion construction procedure described above. These non-textile glove inserts were subsequently constructed in finished gloves using the same glove construction procedure described above.

Example 3 - Non-breathable adhesive

A non-textile layer film was produced as in Example 2, with the exception that the adhesive used was an MDI-based non-breathable moisture-cured polyurethane polyether as described in US Patent 4,532,316, incorporated in the Present document by reference. This non-textile layer was subsequently used to produce complete non-textile glove inserts of the present invention using the same insertion construction procedure described in Example 1 above. These non-textile glove inserts were subsequently constructed in finished gloves using the same glove construction procedure described in Example 1 above.

Although some illustrative embodiments of the present invention have been described in detail above, those skilled in the art will readily appreciate that many modifications are possible without materially departing from the novel content and advantages described herein. Accordingly, all such modifications are intended to be included within the scope of the present invention, as defined in the following claims.