Method and system for collecting and analyzing operational information from a network of components associated with a liquid energy commodity
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20 claims: 5 independent, 15 dependent
- 1Claims of equivalent WO 2012112759 A2 CLAIMS What is claimed is:1. A method for collecting and analyzing operational information from a network of components associated with a liquid energy commodity, comprising the steps of: measuring an amount of the liquid energy commodity in storage at one or more storage facilities in the network, and storing that measurement data in a first database at a central data processing facility;determining a flow rate of the liquid energy commodity in one or more selected pipelines in the network, and storing that flow rate data in a second database at the central data processing facility;ascertaining an operational status of one or more processing facilities in the network, and storing that operational status information in a third database at the central data processing facility;analyzing the measurement data, the flow rate data, and the operational status information to determine a balance of the liquid energy commodity in the network or a selected portion thereof at a given time;and communicating information about the balance of the liquid energy commodity to a third-party market participant.
- 10A method for collecting and analyzing operational information from a network of components associated with a liquid energy commodity, comprising the steps of:using a thermal imaging camera to collect images at one or more storage facilities in the network, transmitting the collected images to a central data processing facility, and analyzing the collected images to measure an amount of the liquid energy commodity in storage at each of the one or more storage facilities, and storing that measurement data in a first database at the central data processing facility;positioning one or more power monitoring devices to monitor power lines supplying electric power to particular pumping stations associated with selected pipelines in the network, each of the one or more power monitoring devices including sensing elements responsive to electric potential and magnetic flux densities associated with the power lines, therefore allowing for a measurement of electric potential and magnetic flux densities associated with the power lines, and thus a determination of power consumed by each particular pumping station, which, is then correlated to a flow rate of the liquid energy commodity in each selected pipeline in the network, and storing that flow rate data in a second database at the central data processing facility;using a thermal imaging camera to ascertain an operational status of one or more processing facilities in the network, and storing that operational status information in a third database at the central data processing facility;analyzing the measurement data, the flow rate data, and the operational status information to determine a balance of the liquid energy commodity in the network or a selected portion thereof at a given time;and communicating information about the balance of the liquid energy commodity to a third-party market participant.
- 13A system for collecting and analyzing operational information from a network of components associated with a liquid energy commodity, comprising:a storage measurement module for receiving and analyzing collected images of one or more storage facilities to measure an amount of the liquid energy commodity in storage at each of the one or more storage facilities, storing such measurement data in a first database;a flow rate determination module for receiving and processing measurements of electric potential and magnetic flux densities associated with power lines for pumping stations on one or more pipelines to determine a flow rate of the liquid energy commodity in each of said one or more pipelines, storing such flow rate data in a second database;an operational status module for receiving and processing information about an operational status of a processing facility, storing that operational status information in a third database;an analysis module for querying the first database, the second database, and the third database and analyzing the measurement data, the flow rate data, and the operational status information to determine a balance of the liquid energy commodity in the network or a selected portion thereof at a given time;and a communications module for communicating information about the liquid energy commodity to a third-party market participant.
- 15A method for collecting and analyzing operational information from a network of components associated with crude oil transport, comprising the steps of:using a thermal imaging camera to collect images of one or more storage tanks in the network, transmitting the collected images to a central data processing facility, and analyzing the collected images to measure an amount of crude oil in the one or more storage tanks, and storing that measurement data in a first database at the central data processing facility;positioning one or more power monitoring devices to monitor power lines supplying electric power to particular pumping stations associated with selected pipelines in the network, each of the one or more power monitoring devices including sensing elements responsive to electric potential and magnetic flux densities associated with the power lines, therefore allowing for a measurement of electric potential and magnetic flux densities associated with the power lines, and thus a determination of power consumed by each particular pumping station, which, is then correlated to a flow rate of crude oil in each selected pipeline in the network, and storing that flow rate data in a second database at the central data processing facility;using a thermal imaging camera to ascertain an operational status of one or more processing facilities in the network, and storing that operational status information in a third database at the central data processing facility;analyzing the measurement data, the flow rate data, and the operational status information to determine a balance of crude oil in the network or a selected portion thereof at a given time;and communicating information about the balance of crude oil to a third -party market participant.
- 20A method for monitoring transport of crude oil in a network that includes a production source, a pipeline, a processing facility, and one or more storage tanks, comprising the steps of:positioning one or more power monitoring devices to monitor power lines supplying electric power to selected pumping stations associated with the pipeline extending between the production source and the processing facility, each of the one or more power monitoring devices including sensing elements responsive to electric potential and magnetic flux densities associated with the power lines, therefore allowing for a measurement of electric potential and magnetic flux densities associated with the power lines, and thus a determination of power consumed by each selected pumping station, which, is then correlated to a flow rate of crude oil in the pipeline, and storing that flow rate data in a first database at a central data processing facility;using a thermal imaging camera to ascertain an operational status of the processing facility;and storing that operational status information in a second database at the central data processing facility;using a thermal imaging camera to collect images of the one or more storage tanks, transmitting the collected images to the central data processing facility, and analyzing the collected images to measure an amount of crude oil in the one or more storage tanks, and storing that measurement data in a third database at the central data processing facility;analyzing the flow rate data, the operational status information, and the measurement data to determine a balance of crude oil in the network at a given time;and communicating information about the balance of crude oil to a third -party market participant.
Independent claims5
147 paragraphs in 5 sections, as filed
Description of equivalent WO 2012112759 A2
IN THE UNITED STATES PATENT AND TRADEMARK OFFICE
0002Patent Application Under 37 C.F.R. §1.53(b)
0003for
0004METHOD AND SYSTEM FOR COLLECTING AND ANALYZING OPERATIONAL INFORMATION FROM A NETWORK OF COMPONENTS ASSOCIATED WITH A LIQUID ENERGY
COMMODITY
CROSS-REFERENCE TO RELATED APPLICATIONS
0007The present application claims priority to U.S. Provisional Patent Application Serial No. 61/443,510 filed on February 16, 2011, the entire disclosure of which is incorporated herein by reference. BACKGROUND OF THE INVENTION
0008The present invention is a method and system for collecting and analyzing operational information from a network of components associated with a liquid energy commodity, such as crude oil or natural gas liquid (NGL). Liquid energy commodities, such as crude oil, comprise a multi-billion dollar economic market. These commodities are bought and sold by many parties, and as with any traded market, information about the traded commodities is very valuable to market participants. Specifically, the operations of the various components and facilities of the production, transportation, storage, and distribution systems for each of these commodities can have significant impacts on the price and availability of these commodities, making information about said operations valuable. Furthermore, such information generally is not disclosed publicly by the various component owners or operators, and access to said information is therefore limited.
0009Certain data is collected by organizations such as the United States Energy
0010Information Administration ("EIA"), typically via surveys of selected owners and/or operators. However, the length of time required to collect and compile this data and then disseminate it to the public or market participants can range from days to months, so that the collected and compiled data is usually delayed and of limited value for short-term trading purposes.
SUMMARY OF THE INVENTION
0012The present invention is a method and system for collecting and analyzing operational information from a network of components associated with a liquid energy commodity, such as crude oil or natural gas liquid ( GL).
0013In accordance with the method and system of the present invention, sensors or measurement devices are deployed at various points in a network to collect data. The method then generally comprises the steps of: (a) measuring an amount of the liquid energy commodity in storage at one or more storage facilities in the network, and storing that measurement data in a first database at a central data processing facility; (b) determining a flow rate of the liquid energy commodity in one or more selected pipelines in the network, and storing that flow rate data in a second database at the central data processing facility; (c) ascertaining an operational status of one or more processing facilities in the network, and storing that operational status information in a third database at the central data processing facility; (d) analyzing the measurement data, the flow rate data, and the operational status information to determine a balance of the liquid energy commodity in the network or a selected portion thereof at a given time; and (e) communicating information about the balance of the liquid energy commodity to a third -party market participant.
0014With respect to storage facilities, at each selected storage facility in a particular network, there is a measurement of the amount of crude oil or other liquid energy commodity in storage. For instance, most crude oil is stored in large, above-ground tanks that either have: a floating roof, which is known as an External Floating Roof (EFR); or a fixed roof with a floating roof internal to the tank, which is known as an Internal Floating Roof (IFR). Thus, each tank in a particular location can be researched using publicly available resources or visual inspection, and all relevant information about each tank, including volume capacity information, tank type (i.e., floating roof or fixed roof), and physical dimensions, is stored in a database. Then, on a predetermined schedule, an inspection of each tank at the particular location is conducted that includes the collection of one or more photographic images (i.e., visible spectrum) or video of each tank, and/or the collection of infrared images or video of each tank. The collected photographic images and the collected infrared images of each tank are then transmitted to a central processing facility for analysis to obtain a measurement of the amount of crude oil or other liquid energy commodity in storage.
0015With respect to pipelines, in order to maintain the pressure of the liquid energy commodity, pumping stations are positioned along pipelines. The pumps used at each of these pumping stations are typically electrically driven induction motors. In order to perform a remote determination of the amount and rate of flow in a particular pipeline at a given time, one preferred form of analysis is based on monitoring the real-time electric power consumption of some number of pumping stations along a selected pipeline. In one exemplary implementation, a monitoring device is deployed and used to monitor one or more power lines supplying electric power to each selected pumping station. The monitoring device is primarily comprised of sensing elements responsive to electric potential and the magnetic flux densities associated with the one or more power lines, therefore allowing for periodic or continuous measurements of the electric potential and magnetic flux densities associated with the one or more power lines, and thus a determination of power. Data from such monitoring devices is then transmitted to the central data processing facility. At the central data processing facility, a model of the pipelines and the pumping stations in the particular network is developed that includes computations of the elevation gain or loss between any monitored pumping station and the next pumping station downstream using standard geographical elevation data. The pressure differential between the output or discharge side of any particular monitored pumping station and the input side of the next station downstream is then estimated. A range of possible flow rates for the pipeline from minimum possible flow to maximum possible flow for the pipeline is plotted versus the equivalent expected power consumption at the monitored pumping station.
0016Once such power consumption determinations have been made for any particular pumping station, power changes at each pumping station can be correlated to changes in flow through each pumping station. Thus, since the monitoring devices described above allow for periodic or continuous measurements of power consumed at a particular pumping station, the collected data from those monitoring devices can be used to determine flow through and between pumping stations. With respect to processing facilities, a liquid energy commodity enters a refinery or other processing facility at some point in the network. In the method and system of the present invention, the operational status of such processing facilities is ascertained. One preferred method for monitoring the operation of processing facilities is by using fixed thermal imaging cameras. A thermal imaging camera can acquire thermal data and record images of emissions and heat signatures of various key units that can be used to ascertain whether a processing facility is functioning as expected or not.
0017With data and information about the three fundamental components of a particular network - (i) storage facilities, (ii) pipelines, and (iii) processing facilities - it is possible to determine total "balances" of the liquid energy commodity. For example, "balances" of interest to market participants with respect to crude oil include, but are not limited to: the amount of crude oil in storage in a given market region at a given time; the amount of crude oil flowing into a market region from adjacent market regions; and/or the amount of crude oil being processed into gasoline and other petroleum products. Once such an analysis has been completed, information about the balance of the crude oil or other liquid energy commodity in the network can be communicated to market participants and other interested parties, i.e., third parties who would not ordinarily have ready access to such information.
0018DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic view of an exemplary network associated with crude oil production;
0019FIG. 2 is a schematic view of an exemplary network associated with crude oil transport and processing;
0020FIG. 3 is an exemplary image in which the outline of three tanks has been found and marked on the image using the Sobel edge detection method; FIG. 4 is an exemplary image with the outline of three tanks from FIG. 3 overlaid on a subsequent collected image;
0021FIG. 5 is a graph that illustrates the one-dimensional shape of an edge in an image;
0022FIG. 6 includes a pair of 3x3 convolution masks used in a Sobel edge detection method;
0023FIG. 7 illustrates how a convolution mask in a Sobel edge detection method is applied to an input image;
0024FIG. 8 is a plot of flow rate (barrels per day) against expected power consumption (MW) for an exemplary pumping station;
0025FIGS. 9(a)-(d) are a series of thermal images illustrating the ramp-down of a fluid catalytic cracking unit at a refinery;
0026FIG. 10 illustrates a storage hub that is connected to three pipelines;
0027FIG. 1 1 is a plot illustrating how directly measured data is fitted using a standard mathematical regression model to historic data;
0028FIG. 12 is a schematic view of another exemplary network associated with crude oil production;
0029FIG. 13 is a flow chart depicting the general functionality of an implementation of the method and system of the present invention in connection with the exemplary network of FIG. 12; and
0030FIG. 14 is a schematic representation of the core components in an exemplary implementation of the method and system of the present invention.
0031DETAILED DESCRIPTION OF THE INVENTION The present invention is a method and system for collecting and analyzing operational information from a network of components associated with a liquid energy commodity, such as crude oil or natural gas liquid (NGL).
0032For example, since crude oil is a fossil fuel, it is typically drilled or mined at locations where there are naturally occurring deposits or reservoirs. Once collected at such a location (for example, from a well), the crude oil is typically pumped directly into a pipeline or stored in above-ground storage (e.g., tanks) or underground storage (e.g., salt dome caverns). From such storage facilities, it can then be transported via pipelines to refineries or other processing facilities for processing. Thus, there is an interconnected network of crude oil wells, crude oil pipelines, crude oil storage facilities, and crude oil refineries.
0033For another example, natural gas is extracted at locations where there are naturally occurring reservoirs. The extracted natural gas is then processed into "dry" natural gas or "wet" natural gas at processing plants, the latter of which is termed natural gas liquid (NGL). The NGL is then transported using NGL pipelines and stored at NGL storage sites. The NGL may then be separated into at what are termed "purity" products such as ethane, propane, and butane. These NGL products can then be processed at ethylene cracking facilities which take NGL products in and process them into petrochemical industry feedstocks such as ethylene, propylene, etc.
0034In accordance with the method and system of the present invention, sensors or measurement devices are deployed at various points in a network to collect data. The method then generally comprises the steps of: (a) measuring an amount of the liquid energy commodity in storage at one or more storage facilities in the network, and storing that measurement data in a first database at a central data processing facility; (b) determining a flow rate of the liquid energy commodity in one or more selected pipelines in the network, and storing that flow rate data in a second database at the central data processing facility; (c) ascertaining an operational status of one or more processing facilities in the network, and storing that operational status information in a third database at the central data processing facility; (d) analyzing the measurement data, the flow rate data, and the operational status information to determine a balance of the liquid energy commodity in the network or a selected portion thereof at a given time; and (e) communicating information about the balance of the liquid energy commodity to a third -party market participant.
0035As will become clear in the description that follows, many of the operational steps of the method and system of the present invention, including the collection of data and the various computational steps associated with the analysis of that collected data, are preferably achieved through the use of a digital computer program, i.e., computer-readable instructions stored and executed by a computer. Thus, execution of the requisite routines and subroutines can be carried out using standard programming techniques and languages. With benefit of the following description, such programming is readily accomplished by one of ordinary skill in the art.
0036For example, with respect to crude oil, there is an interconnected network of crude oil wells, crude oil pipelines, crude oil storage facilities, and crude oil refineries. For purposes of the subsequent discussion, and as shown in FIGS. 1 and 2, a "network" for crude oil can thus be characterized as having three fundamental components: (i) crude oil storage facilities; (ii) crude oil pipelines; and (iii) crude oil refineries or other processing facilities.
0037Understanding and collecting information about the operation of these components and the flow of crude oil between these components allows for the modeling of the network and monitoring of the real-time network dynamics. In other words, by taking certain physical measurements of the crude oil (or other liquid energy commodity) at various points in the network, it is possible to determine total "balances" of the crude oil in different functional parts of the network. For example, "balances" of interest to market participants with respect to crude oil include, but are not limited to: the amount of crude oil in storage in a given market region at a given time; the amount of crude oil flowing into a market region from adjacent market regions; and/or the amount of crude oil being processed into gasoline and/or other petroleum products.
0038Referring still to the crude oil market, in the U.S., the amount of crude oil stored in tanks located at either terminals, storage hubs, or oil refineries (including crude oil in transit in pipelines) is of the order of 340 million barrels. 55,000 miles of pipelines transport crude oil from American production wells (notably in the states of Texas, Louisiana, Oklahoma, and Wyoming), import terminals (notably seaports in the Gulf of Mexico), or overland across the border from Canada to various regional markets. These markets are divided into five large regions in the U.S. known as Petroleum Administration for Defense (PAD) Districts. Crude oil pipelines typically vary in diameter from eight to thirty inches. Larger interregional pipelines, which service refineries or storage hubs, are generally more relevant to overall market dynamics than smaller intra-regional pipelines. The market relevance of crude oil in storage varies depending on the purpose of the crude oil being stored. For example, crude oil stored at refineries is available for refining at any particular point in time into gasoline and/or other petroleum products. Crude oil stored at major oil storage hubs may be indicative of the amount of crude oil being stored by financial speculators or by suppliers to refineries downstream of the storage hub. Other tank storage may be primarily used to maintain appropriate pressures and volumes in order to successfully operate the required flow dynamics on a particular pipeline.
0039Storage Facilities
0040In accordance with the method and system of the present invention, at each selected storage facility in a particular network, there is a measurement of the amount of crude oil or other liquid energy commodity in storage. For instance, one preferred method for measuring the amount of crude oil being stored in a particular tank is described in commonly owned and co-pending U. S. Patent Application Serial No. 13/089,674 entitled "Method and System for Determining an Amount of Crude Oil Stored in a Particular Location," which is incorporated herein by reference.
0041As described in U. S. Patent Application Serial No. 13/089,674, most crude oil is stored in large, above-ground tanks that either have: a floating roof, which is known as an External Floating Roof (EFR); or a fixed roof with a floating roof internal to the tank, which is known as an Internal Floating Roof (IFR). Thus, each tank in a particular location can be researched using publicly available resources or visual inspection, and all relevant information about each tank, including volume capacity information, tank type (i.e., floating roof or fixed roof), and physical dimensions, is stored in a database. Then, on a
0042predetermined schedule, an inspection of each tank at the particular location is conducted that includes the collection of one or more photographic images (i.e., visible spectrum) or video of each tank, and/or the collection of infrared images or video of each tank. Such images can be collected by aerial means, through use of ground-placed, fixed cameras, or via satellite imaging. In the case of an aerial image acquisition, such as a helicopter flyover, the helicopter preferably flies a defined and repeatable flight route and adheres to a pre-defined sequence for image acquisition, which facilitates the subsequent analysis. Alternatively, fixed thermal imaging cameras may take infrared images at predetermined intervals. In any event, the collected photographic images and the collected infrared images of each tank are then transmitted to a central processing facility for analysis.
0043With respect to the analysis of a tank with a floating roof, one preferred form of analysis is to determine the height of the roof relative to the top of the selected tank using standard image pixel number determination techniques. For example, tank levels can be measured by drawing two vertical lines, such as LI and L2. When measuring tank levels for floating roof tanks, the LI line is drawn on the inside of the tank from the top of the tank down to the top of the lid and approximates the height the roof has been lowered. The L2 line is drawn on the outside of the tank from the top of the tank down to the bottom of the tank and approximates the height of the tank. The respective lengths of the L 1 and L2 lines are then measured. Such measurement is optimized, for example, by ensuring an appropriate camera angle and distance from the tank, using high-resolution equipment for image acquisition, and/or ensuring consistent and proper placement of the LI and L2 lines on the image.
0044Based on the determined height of the roof (which is indicative of the liquid level) and the stored volume capacity information and/or the stored physical dimensions of the selected tank, the amount of crude oil in the tank can be calculated. For example, if the roof is at the halfway point, i.e., at a 50% height relative to the top of a 200,000-barrel tank, and the tank has a typical cylindrical construction with a constant diameter from the base to the top, it is calculated that 100,000 barrels of crude oil are in the tank. Stated another way, tank level percent of capacity can be calculated by 1 - (D1/D2), where Dl and D2 are the respective measured lengths of LI and L2 in image pixels. Tank level percent of capacity is then multiplied by the tank capacity to calculate the number of barrels of crude oil in the tank.
0045With respect to the analysis of a tank with a floating roof, in another preferred form of image analysis, the top, roof, and the base of a tank are identified in either a photographic image or infrared image. Automated elliptical form fitting or detection algorithms employing mathematical transformations, such as a Hough transform, can then be used to fit an elliptical plane on each of the top, roof, and the base of the tank. Based on the determined height of the roof relative to the base and/or the top of the tank (which again is indicative of the liquid level) and the stored volume capacity information and/or the stored physical dimensions of the selected tank, the amount of crude oil in the tank can again be calculated.
0046With respect to tanks with fixed roofs, the liquid level within a selected tank can be ascertained from the collected infrared images, as the temperature of the stored oil is different than that of the gas above it in the tank. One preferred form of analysis to determine the height of the liquid level in the tank is to measure the pixel distance from the liquid-gas boundary to the base of the tank. Based on the ascertained liquid level within the tank and the stored volume capacity information and/or the stored physical dimensions of the selected tank, the amount of crude oil in the tank can again be calculated.
0047Furthermore, with respect to tanks with fixed roofs and determination of liquid level from the collected infrared images, one particular method of analysis is described in detail below.
0048In this particular method of analysis, infrared images are collected for each tank of interest at selected intervals (e.g., every five minutes) and transmitted to the central data processing facility for analysis. Although the camera that collects the infrared images is preferably fixed in position, it is acknowledged that there is often some minor movement of the camera. Thus, feature detection is used to find the tank location in each infrared image, thus ensuring an accurate calculation of the amount of crude oil in the tank.
0049Edges in images are areas with strong intensity contrasts, i.e., a significant change in intensity from one pixel to the next. There are various methods and techniques for detecting edges in an image, which can be generally grouped into two categories: gradient and
0050Laplacian methods. A gradient method detects the edges by looking for the maximum and minimum in the first derivative of the image. A Laplacian method searches for zero crossings in the second derivative of the image to find edges. Referring now to FIG. 5, an edge has the one-dimensional shape of a ramp.
0051Employing a gradient method, the derivative of the one-dimensional shape thus shows a maximum located at the center of the edge. Based on this one-dimensional analysis, the theory can be carried over to two dimensions as long as there is an accurate approximation to calculate the derivative of a two-dimensional image. In this case, a Sobel operator is used to perform a two-dimensional spatial gradient measurement on a particular infrared image in order to find the approximate absolute gradient magnitude at each point in the infrared image. See R. Gonzalez and R. Woods, Digital Image Processing, Addison Wesley (1992), pp. 414- 428. The Sobel edge detection method uses a pair of 3x3 convolution masks (FIG. 6), one estimating the gradient in the x-direction (columns) (Gx) and the other estimating the gradient in the y-direction (rows) (Gy). A convolution mask is usually much smaller than the actual image. As a result, the mask is applied and slid over the image, manipulating a square of pixels at a time.
0052Specifically, in use, the mask is slid over an area of the input image (from the beginning of a row), changes the value of the pixel and shifts one pixel to the right, and then continues to the right until it reaches the end of the row. It then starts at the beginning of the next row. FIG. 7 illustrates how a convolution mask in a Sobel edge detection method is applied to an input image, with the mask being applied over the top left portion of the input image and equation (1) below being used to calculate a particular pixel in the output image. The center of the mask is placed over the pixel that is being manipulated in the image; for example, pixel (a<sub>22</sub>) is converted to pixel (b<sub>22</sub>) by:
0053b<sub>2</sub>2 = (an * mil) + (ai<sub>2</sub> * mi<sub>2</sub>) + (ai<sub>3</sub> * m ) + (a<sub>2</sub>i * m<sub>2</sub>i) + (a<sub>22</sub> * m<sub>22</sub>) +
0054(a<sub>23</sub> * mi<sub>23</sub>) + (a<sub>3</sub>i * m<sub>3</sub>i) + (a<sub>32</sub> * m<sub>32</sub>) + (a<sub>33</sub> * m<sub>33</sub>) The Gx mask highlights the edges in the horizontal direction, while the Gy mask highlights the edges in the vertical direction. After taking the magnitude of both and adding, the resulting output detects edges in both directions.
0055In practice, a Sobel edge detection image is computed for each collected infrared image. Then, for each edge detection image, the tank location is found by determining the best fit to one or more features. Each feature is a set of pixel locations where the Sobel edge detection image should contain an edge and have a black color. FIG. 3 is an exemplary image in which the outline of three tanks has been found and marked on the image using the Sobel edge detection method, and FIG. 4 shows how this outline of three tanks can be overlaid on a subsequent collected image.
0056In this particular method of analysis, after finding the tank location, the tank level is computed based on a vertical line starting at the bottom of each tank, as also shown in FIG. 4. Each vertical line is searched upward from the bottom of the tank for the next edge location, which is the oil level location. The number of pixels between the bottom of the tank and the oil level location (pixel_height) is used to compute the tank percent full as follows:
0057Percent Full = 100 * (pixel_height) / (total pixel height of tank)
0058Furthermore, in this particular method of analysis, the flow rate with respect to a certain tank can be calculated by the rate of change of the storage levels within the tank:
0059Flow_i = (S_i - S_i-1) * Tank_Capacity * 24 / 100
0060where S_i = (L_i + L_i-1 + L_i-2 + L_i-3 + L_i-4 + L_i-5 + L_i-6) / 7 and S_i-1 = (L_i-1 + L_i-2 + L_i-3 + L_i-4 + L_i-5 + L_i-6 + L_i-7) / 7 where Tank Capacity is in barrels, and L i is the tank Percent Full at hour i. When Flow_i < 0, then Flow_i is set to zero since only oil flowing in to a tank is being considered.
0061No matter which technique of analysis is employed, the objective again is to obtain a measurement of the amount of crude oil in storage in the particular network, which is stored at the central data processing facility.
0062With respect to storage of NGL products, such as ethane, propane, and butane, similar image collection and analysis on the vertical and horizontal tanks commonly used to store such products can be carried out in order to obtain a measurement of the amount of the NGL product in storage in the particular network.
0063Pipelines
0064Along with measuring the amount of crude oil or other liquid energy commodity in storage in a particular network, there is a determination of the amount and rate of flow in selected pipelines in the particular network.
0065For instance, a large inter-regional crude oil pipeline typically runs for hundreds of miles. In order to maintain the pressure of the flowing crude oil, crude oil pumping stations are typically constructed every 80-100 miles. The pumps used at each of these pumping stations are typically electrically-driven induction motors, with horsepower (hp) ranging from 500-4500 hp. Crude oil pipeline flow data in real-time is generally only known to the owners, operators, and shippers on the pipeline. In order to perform a remote determination of the amount and rate of oil flow in a particular pipeline at a given time, one preferred form of analysis is based on monitoring the real-time electric power consumption of some number of pumping stations along a selected pipeline.
0066Specifically, in one exemplary implementation, a monitoring device is deployed and used to monitor one or more power lines supplying electric power to each selected pumping station. The monitoring device (also referred to herein as "power monitoring device") is primarily comprised of sensing elements responsive to electric potential and the magnetic flux densities associated with the one or more power lines, therefore allowing for periodic or continuous measurements of the electric potential and magnetic flux densities associated with the one or more power lines, and thus a determination of power. The construction and use of such monitoring devices is described in commonly owned U. S. Patent No. 6,771,058 entitled "Apparatus and Method for the Measurement and Monitoring of Electrical Power Generation and Transmission," and U.S. Patent No. 6,714,000 entitled "Apparatus and Method for Monitoring Power and Current Flow," each of which is incorporated herein by reference.
0067Data from such monitoring devices is then transmitted to a central data processing facility. At the central data processing facility, a model of the pipelines and the pumping stations in the particular network is developed that includes computations of the elevation gain or loss between any monitored pumping station and the next pumping station downstream using standard geographical elevation data. The pressure differential between the output or discharge side of any particular monitored pumping station and the input side of the next station downstream is then estimated. The pressure change calculations also take typical minimum and maximum pressures for the pipeline into account for use as reasonable computation boundary values.
0068For example, a preferred flow model takes into account the pipeline length and elevation change between a monitored pumping station and the next pumping station downstream. The pipeline length, elevation change, and power usage are used to estimate the pressure differential between the output side of the first pumping station and the input side of the next pumping station downstream. In other words, the frictional pressure differential or head loss (HeadLoss (H) in feet) between any two pumping stations on a selected pipeline can be calculated from the variables set forth below. See Pipeline Rules of Thumb
0069Handbook, Gulf Professional Publishing (5th Edition) (2001).
0070Sg = Specific Oil Gravity (API)
0071Q = Flow Rate (gal/min)
0072H = Head Differential at Pump (ft)
0073D = Diameter of Pipe (ft)
0074L = Length of Pipeline Segment (ft)
0075E = Pump Efficiency
0076V = Oil Velocity (ft/sec)
0077KV = Kinematic Viscosity (cSt)
0078HeadLoss = Head Loss (ft)
0079The flow rate (Q) values range from zero to the maximum flow rate of the pipeline. The flow rate (Q) is related to oil velocity as follows: Q = Flow Rate = , (<sup>bbls / da</sup>y bblsl day) J gal )
0080(60 * 24 * 0.0238095) 34.286 [mm)
(V)
0082To obtain the kinematic viscosity, a CentiStokes (cSt) value is based on an assumption of API and temperature, and then is converted into units of (ft<sup>2</sup> 1 sec) : (c¾) * i0.0763910
0083KV = Kinematic vis cos ityi ft I sec) = -—
00841000000
0085Fanning's equation is then used to compute the frictional pressure drop (HeadLoss) between pumping stations for a given flow rate (Q), pipeline segment length (L) and elevation profile. Fanning's equation for expressing the frictional pressure drop of oil flowing in a pipeline is a function of a frictional loss (j) derived from the Reynolds number (Re).
0086L V<sup>2</sup> f*V<sup>2</sup>*L
0087HeadLoss(ft) =f — = (9)
0088D2*g 2*32.174*
0089V * D
0090Re =Re ynolds number = (10)
0091KV f 64
0092/ = friction loss= fRe≤2200 / =— , otherwise use Table 1 (11)
0093Re
0094<img file="WO2012112759A2_D0001.tif" />
0095Table 1; Re > 2200 (Turbulent Flow)
0096The hydraulic horsepower required to pump oil along a particular pipeline segment is computed as follows, where H is head differential (ft) on the discharge side of the pump:
0097Sg * Q * H
0098HP = Horsepower (12)
00993960 * E
0100The pump efficiency (E) is estimated to range between 0.25 and 0.40. The power consumed by any particular pump can then be computed directly from pump horsepower using a horsepower to power unit conversion factor c, which is equal to 0.000746.
0101MW = Megawatt = HP * 0.000746 (13)
0102Using equations (12) and (13) and setting H = (HeadLoss) (from equation (9)), a range of possible flow rates (Q) for the pipeline from minimum possible flow to maximum possible flow for the pipeline is plotted versus the equivalent expected power consumption at the monitored pumping station.
0103For example, for a major U.S. pipeline flowing from the Gulf Coast to a major U.S. storage hub in Oklahoma, flow rates can range from 0 to 350,000 barrels per day, with the diameter of the pipeline (D) = 2.44 feet. For a monitored pumping station at location x, the distance of the line (L) from that pumping station to the next downstream pumping station at location y = 368,062 feet. For a typical mid-range flow rate for the pipeline of 200,000 barrels per day, the corresponding flow rate Q (gallons/minute) = 5833.28. The kinematic viscosity v = 0.004 centiStokes. The elevation difference between pumping station x and pumping station y = 353 feet. The resultant head loss (HeadLoss) is 181.1 feet.
0104A plot of flow rate (barrels per day) against expected power consumption (MW) is shown in FIG. 8.
0105Once such power consumption determinations have been made for any particular pumping station, power changes at each pumping station can be correlated to changes in flow through each pumping station. Thus, since the monitoring devices described above allow for periodic or continuous measurements of power consumed at a particular pumping station, the collected data from those monitoring devices can be used to determine flow through and between pumping stations.
0106Once the flow rate between consecutive pumping stations has been computed, one preferred method of deriving total pipeline flow is to compute an average of the estimated flow rates at several pumping stations to determine the flow rate on the pipeline as a whole.
0107The approach is often used when fewer than half the pumping stations are monitored on a given pipeline.
0108Another preferred method of deriving total pipeline flow uses Monte Carlo simulations to model power usage at all pumping stations along a given pipeline and is used when half or more than half of the pumping stations are monitored. The simulations use inputs from the monitored pumping stations, as well as predictions of power usage at pumping stations along the pipeline which are not monitored. The power usage at the unmonitored pumping stations is modeled with a uniform distribution from zero to a maximum power usage based on the number of pumps and the type of pumps at each pumping station. For a given flow value, each Monte Carlo simulation uses the same observed power usage for the monitored pumping stations and performs a random sample of the power usage uniform distributions for the unmonitored pumping stations. Equations (6) to (13) are used to simulate pressure head profile along the entire pipeline. If the pressure head profile along the pipeline goes below the minimum pressure or above the maximum pressure, the simulation is flagged as invalid. The pipeline flow regime, zero barrels per day to capacity, is divided in a finite number of intervals. For each flow value at the center of each flow interval, a large number of Monte Carlo simulations are performed and the number of valid simulations is recorded. An overall pipeline flow is computed using the following expected value: <img file="WO2012112759A2_D0002.tif" />
0109Totv
0110where f_i is i flow value
0111v_i is the number of valid simulations for J, and
0112Totv is the total number of valid simulations for all flow intervals.
0113Finally, in certain circumstances, it may be impossible or impractical to monitor realtime electric power consumption of some number of pumping stations along a selected pipeline. However, it would still be advantageous to know whether a particular pumping station was on or off. Accordingly, a thermal imaging camera (like those used for monitoring storage facilities, as described above) may be used to assess the on/off condition of one or more pumping stations. Similarly, although electrically-driven induction motors are commonly used at pumping stations, some pumps may be driven by gas or diesel-powered motors. Such motors typically exhaust through one or more stacks, so the operation and operational levels (including number of pumps on or off) of the pumping station can also be assessed using a thermal imaging camera directed at the stacks or ancillary equipment.
0114Processing Facilities
0115Crude oil invariably enters an oil refinery at some point in the network to be processed into gasoline and/or other petroleum products, such as diesels, jet fuels, heating oil, etc. The ability of the various units at the refinery to utilize the incoming crude oil is dependent on the proper functioning of such units. Refineries are highly complex facilities which generally are designed and intended to function year-round on a 24 hour-a-day, 7 day- a- week schedule. However, disruptions and malfunctions of equipment at these facilities occurs on a relatively frequent basis and can have immediate impact on market dynamics. Specifically, if particular units at one or more refineries are off-line, there is a decreased demand for crude oil at the affected refineries and a decreased supply of gasoline and other refined products in markets supplied by affected refineries. So-called refinery unit ramp- downs and ramp-ups are of particular market interest, but, in addition, there is also an interest in the flow rates of crude oil into each refinery and the amount of crude oil in storage at each refinery at any given time.
0116Therefore, in the method and system of the present invention, the operational status of one or more processing facilities, such as refineries, in the network is ascertained. With respect to the term "processing facilities," this term is also intended to include any facility in a network in which there is some handling of the liquid energy commodity that can be monitored, even if there is no material change to the liquid energy commodity, such as buffering, transfer, or surge overflow facilities. In any event, one preferred method for monitoring the operation of processing facilities is by using fixed thermal imaging cameras. A thermal imaging camera can acquire thermal data and record images of emissions and heat signatures of various key units that can be used to ascertain whether the processing facility is functioning as expected or not.
0117FIGS. 9(a)-(d) are a series of thermal images illustrating the ramp-down of a fluid catalytic cracking unit (FCCU) at a refinery. As reflected in FIGS. 9(a)-(d), each primary unit at a refinery typically has one or more exhaust stacks associated with it, which generally function as exhausts for heating devices, such as furnaces, heat exchangers, etc., or exhausts for emission control devices, such as wet gas scrubbers, electrostatic dust precipitators, etc. In general, if a particular unit is functioning normally, a characteristic level of heating is observed on a thermal image of the stack. In addition, a characteristic emission via a plume emanating from the top of the stack is also present and visible. When the unit is turned off, or not operating normally, the heating and emissions from such stacks are seen to be either absent completely or display some abnormal characteristics (e.g., excess heating or excess emissions). Similarly, aside from the stacks, a characteristic level of heating can be observed on the thermal images for many other of types of equipment associated with a unit, including, but not limited to, vessels, piping, duct work, heat exchangers, furnaces, and/or ancillary equipment.
0118Returning to FIGS. 9(a)-(d), in this particular example, the FCCU is in far right of the image, as illustrated by the arrow. In FIG. 9(a), the FCCU is shown in normal operating mode. As shown in FIG. 9(b), during the start of ramp-down, emissions are seen from a stack in the middle of the FCCU, and the FCCU itself shows relative cooling with respect to neighboring units. In FIG. 9(c), the body of the FCCU shows continuing cooling; the emitting stacks remains hot, but emissions from it are reduced. In 9(d), both FCCU and the stack have completely cooled down, and ramp-down of the FCCU is complete.
0119Each primary unit at a refinery also has emergency control devices, such as flares, blowdown stacks, and other devices which can burn off or dissipate inline streams of feedstocks, processing chemicals, and associated by-products in the case where the units need to be shut-down rapidly. Such emergency control devices can also be used in the normal operation of such units to control the amounts of feedstocks, processing chemicals, and associated by-products in the process streams. These emergency control devices can also be observed by a thermal imaging camera as operating at characteristically levels (typically low or off) when the associated units are operating normally and at abnormal levels (typically emitting at abnormal and elevated levels) when the associated units are experiencing issues, are being started up, or being shut down.
0120In any event, thermal images such as those shown in FIGS. 9(a)-(d) can be analyzed visually or by using automated image analysis to ascertain the operational status of the primary units of a refinery. For further discussion of the image analysis techniques that may be utilized, reference is made to commonly assigned and co-pending U.S. Patent Application Serial No. 13/269,833 entitled "Method and System for Providing Information to Market Participants About One or More Power Generating Units Based on Thermal Image Data," which is a continuation of U. S. Patent Application Serial No. 12/053,139. Each of these patent applications is incorporated herein by reference.
0121Additionally, while the above discussion is directed to refineries which refine crude oil into gasoline and/or other petroleum products, the monitoring technology is also applicable to such processing facilities as: (a) fractionation facilities, where NGLs are separated from the crude oil for subsequent processing into such products as ethane, propane, and butanes; (b) upgrading facilities (or upgraders), which process raw crude oils after mining and prepare the crude oils for delivery to and subsequent refining at crude oil refineries; (c) ethylene cracking facilities, where NGL products and/or petroleum liquids (such as naphtha) are processed into petrochemical industry feedstocks such as ethylene, propylene, etc.; and (d) natural gas processing facilities, which produce NGL from natural gas.
0122Balances
0123Now, having described the monitoring of the three fundamental components of a particular network - (i) storage facilities, (ii) pipelines, and (iii) processing facilities - it is possible to determine total "balances" of the crude oil or other liquid energy commodity. For example, and as mentioned above, "balances" of interest to market participants with respect to crude oil include, but are not limited to: the amount of crude oil in storage in a given market region at a given time; the amount of crude oil flowing into a market region from adjacent market regions; and/or the amount of crude oil being processed into gasoline and other petroleum products.
0124Referring again to FIG. 1 , in order to determine the physical balances of crude oil or other liquid energy commodity in a particular network, the combined data from the monitoring of these three fundamental components can be used to estimate physical balances of interest.
0125For example, FIG. 10 illustrates a storage hub (i.e., a collection of storage tanks) 100 that is connected to three pipelines: Pipeline A, Pipeline B, and Pipeline C. Using the techniques of analysis described above, measurement of the amount of crude oil in each storage tank is made, and then a sum of all such measurements yields the collective amount in storage at the storage hub 100 at a given time. Then, a determination of the real-time inflows and outflows of oil into the storage hub 100 can be made on a periodic basis from the data collected from the monitoring devices for the power lines supplying electric power to selected pumping stations along each of the three pipelines. For example, if Pipeline A and Pipeline B are incoming, and Pipeline C is outgoing, a net inflow into the storage hub 100 can be computed from a summation of the inflows less any outflows:
0126NetlnflowIntoHub = (Pipeline A<sub>FLOW</sub> + PipelineB <sub>FLOW</sub> ) - Pipeline C<sub>FLOW</sub> ^
0127Thus, with the measurement of the collective amount in storage at the storage hub 100 at a given time and subsequent periodic determinations of inflows and outflows, a substantially real-time determination can be made as to the amount of crude oil in storage at the storage hub 100 at a given time. Furthermore, additional modeling may then be possible to determine operational parameters, such as the effect on storage levels at the storage hub 100 for various operational conditions of the incoming and outgoing pipelines, the use of certain storage tanks to contain crude oil from certain pipelines, what crude oil is in transit through the storage hub 100 and what crude oil stays at the storage hub 100.
0128For another example, data collected from the monitoring devices for the power lines supplying electric power to selected pumping stations (PSl, PS2, PS3, PS4, PS5) along each of the pipelines can be combined with information obtained from the analysis of thermal images of a refinery (not shown) connected to the pipelines to determine the balances of crude oil in transit to the refinery, in storage at the refinery, and being processed at the refinery at any given time.
0129It is further contemplated that, in addition to combining directly measured data collected at different locations in a particular network as described above, data can also be obtained from third-party and publicly available data sources, such as that provided by the United States Energy Information Administration ("EIA"), to deliver estimations and predictions of parameters of market interest related to commodity supply, demand, and storage. For example, one such parameter of interest is the total volume of crude oil in storage in the PAD 2 market region at any given time. EIA publishes an amount for this value weekly, typically on Wednesday morning at 10:30 AM EST. Directly measured data and EIA data can be effectively combined using a standard mathematical regression model. Specifically, the standard mathematical regression model is used to fit the directly measured data to the historic PAD 2 crude oil storage inventory data published by EIA. The determined PAD 2 crude oil inventories are then estimated going forward using the resultant model. Referring now to FIG. 11 , in one example, directly measured data is obtained using the techniques described above for: (i) the storage levels at a major PAD 2 storage hub; (ii) the crude oil flow rates into PAD 2 (collected from six pipelines entering the PAD 2 region from PAD 3); and (iii) refinery unit operational data (collected from nine PAD 2 refineries). This directly measured data is then fitted using a standard mathematical regression model to historic PAD 2 crude oil storage inventory data published by EIA. The determined crude oil inventories based on the model output ("Model" line in FIG. 1 1) can then be compared to actual PAD 2 crude oil inventory data ("PAD 2" line in FIG. 1 1), and PAD 2 crude oil inventories can then be estimated going forward using the resultant model.
0130For another example, FIG. 12 is a schematic view of another exemplary network associated with crude oil production. In FIG. 12, crude oil originating from an oil platform 200 (or other production source) is delivered to a pipeline 210. Along the pipeline 210, there are four sensor locations - SI, S2, S3, S4, as further described below in Table 2. The pipeline 210 is then connected and delivers the crude oil to a fractionation facility 212, which is monitored by a sensor S5, as also described below in Table 2. From the fractionation facility 212, crude oil flows to a storage facility 214, which is monitored by sensor(s) S6, as also described below in Table 2.
0131Finally, in this exemplary implementation, there is an additional data input, as represented in FIG. 12 by S7. This additional data input, S7, is used to further verify the collected data and results of the various computational analyses. Specifically, in the exemplary network shown in FIG. 12, crude oil in the storage facility 214 is delivered to one or more ships at a sea terminal for export. Much data about ships that transfer crude oil is publicly known and available, including ship capacity and ship location via Automatic Identification System (AIS) ship tracking services. While a particular ship is in port at the sea terminal, a visual camera or an infrared camera can be used to estimate flow rate of oil delivered to the particular ship by measuring the change in ship draft (i.e., the change in ship position relative to the waterline) over time. That delivery of oil should be equal to the reduction in oil level in the storage facility 214. Of course, such technology can be similarly used when ships are delivering oil to a storage facility.
0132Monitored Component Sensor Type Output
0133S I Pumping Station 1 Power Monitoring Device mW / Flow Rate
0134S2 Pumping Station 2 Thermal Imaging Camera Operational Status
0135(On / Off)
0136S3 Pumping Station 3 Power Monitoring Device mW / Flow Rate
0137S4 Pumping Station 4 Thermal Imaging Camera Operational Status
0138(On / Off)
0139S5 Fractionation Facility Thermal Imaging Camera Operational Status
0140(On / Off)
0141S6 Storage Facility / Tank(s) Thermal Imaging Camera(s) Level / Volume
0142S7 Ship Visual or Thermal Imaging Draft / Flow Rate
0143Camera(s)
0144Table 2
0145Referring now to FIG. 13, the outputs from S I, S2, S3, and S4 are used to determine power changes at each pumping station along the pipeline 210, which can then be used to determine flow rate of the crude oil through the pipeline 210, as indicated by block 300 of FIG. 13, and that flow rate data is stored in a database at a central data processing facility.
0146The output from S5 is used to determine the operational status of the fractionation facility 212, as indicated by block 302 of FIG. 13, and that operational status information in also stored in database at the central data processing facility. The output from S6 is used to measure an amount of the crude oil in storage at the storage facility 214, as indicated by block 304 of FIG. 13, and that measurement data is also stored in a database at the central data processing facility.
0147At the central data processing facility, an analysis is performed on the flow rate data, the operational status information, and the measurement data to determine total "balances" of the crude oil in different functional parts of the network, as indicated by block 310 of FIG.
014813. For example, with respect this exemplary network, "balances" of interest to market participants would include, but are not limited to: the amount of crude oil flowing into the network at a given time, the amount of crude oil in storage in the network at a given time; and/or the amount of crude oil flowing out of the network at a given time.
0149Referring still to FIG. 13, once the analysis has been completed, information about the balance of the crude oil in the network can be communicated to market participants and other interested parties, i.e., third parties who would not ordinarily have ready access to such information, as indicated by block 320. It is contemplated and preferred that such communication to third-party market participants could be achieved through electronic mail delivery and/or through export of the data to an access-controlled Internet web site, which third-party market participants can access through a common Internet browser program, such as Microsoft Internet Explorer®. Of course, communication of information and data to third- party market participants may also be accomplished through a wide variety of other known communications media without departing from the spirit and scope of the present invention.
0150FIG. 14 is a schematic representation of the core components in an exemplary implementation of the method and system of the present invention. As shown in FIG. 14, the central data processing facility 10 includes a first database 20, a second database 22, and a third database 24. Of course, these databases 20, 22, 24 could be integrated into a single database at the central data processing facility 10. Furthermore, the central data processing facility 10 hosts a digital computer program, i.e., computer-readable instructions stored and executed by a computer, that includes appropriate modules for executing the requisite routines and subroutines for performing the operational steps of the present invention. Thus, an exemplary system for determining an amount of a liquid energy commodity stored in a tank in accordance with the present invention includes: (a) a storage measurement module 40 for receiving and analyzing collected images of one or more storage facilities to measure an amount of the liquid energy commodity in storage at each of the one or more storage facilities, and storing that measurement data in a first database 20; (b) a flow rate determination module 42 for receiving and processing measurements of the electric potential and magnetic flux densities associated with power lines for pumping stations on a pipeline to determine a flow rate of the liquid energy commodity in each selected pipeline, and storing that flow rate data in a second database 22; (c) an operational status module 44 for receiving and processing information about an operational status of a processing facility and storing that operational status information in a third database 24; (d) an analysis module 50 for querying the databases 20, 22, 24 and analyzing the measurement data, the flow rate data, and the operational status information to determine a balance of the liquid energy commodity in the network or a selected portion thereof at a given time; and (e) a communications module 60 for communicating information about the liquid energy commodity to a third-party market participant.
0151One of ordinary skill in the art will recognize that additional embodiments and implementations are also possible without departing from the teachings of the present invention. This detailed description, and particularly the specific details of the exemplary embodiments and implementations disclosed therein, is given primarily for clarity of understanding, and no unnecessary limitations are to be understood therefrom, for modifications will become obvious to those skilled in the art upon reading this disclosure and may be made without departing from the spirit or scope of the invention.
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Numbers
- Publication
- 2676232
- Publication, DOCDB
- 2676232
- Publication, EPODOC
- EP2676232
- Application
- 127475945
- Application, DOCDB
- 12747594
- Application, EPODOC
- EP20120747594
Titles3
- German
- VERFAHREN UND SYSTEM ZUM SAMMELN UND ANALYSIEREN VON BETRIEBSINFORMATIONEN IN EINEM NETZWERK FÜR KOMPONENTEN MIT EINEM FLÜSSIGENERGIEPRODUKT
- English
- METHOD AND SYSTEM FOR COLLECTING AND ANALYZING OPERATIONAL INFORMATION FROM A NETWORK OF COMPONENTS ASSOCIATED WITH A LIQUID ENERGY COMMODITY
- French
- PROCÉDÉ ET SYSTÈME POUR COLLECTER ET ANALYSER DES DONNÉES OPÉRATIONNELLES EN PROVENANCE D'UN RÉSEAU DE COMPOSANTS ASSOCIÉ À UNE MATIÈRE PREMIÈRE COMPRENANT DE L'ÉNERGIE LIQUIDE
Classification
- CPC, 10
- G06Q10/0631
- F17D1/08
- F17D3/01
- F17D3/18
- G01F1/00
- G01F15/06
- G01F23/00
- G01F23/2925
- Y02P90/82
- F17D3/00
- IPC, 8
- G06Q50 02
- F17D3 00
- G01F1 00
- G01F15 06
- G01F23 00
- G01F23 292
- G06Q10 06
- G06Q50 06
Designated states1
- Contracting states, 1
- Türkiye