Plating of ceramic matrix composite parts as metal-ceramic joining method in gas turbine hardware
13 claims: 3 independent, 10 dependent
- 1A method of joining a ceramic matrix composite article (2,14,28) to a metallic component (10,18,30), comprising providing said ceramic matrix composite article (2,14,28) with a metallic region (4,16,32) which bonds to said metallic component (10,18,30).
- 10A ceramic matrix composite article (2,14,28) comprising a mounting region said mounting region provided with a metallic region (4,16,32).
Independent claims3
17 paragraphs in 4 sections, as filed
0001The present invention relates to joining of ceramic matrix composites (CMCs) to metal components, such as metal parts of a gas turbine. More particularly, the invention provides a technique whereby metal may be joined to a CMC that can then be used to attach the CMC to a metal structure. In one embodiment, the technique provides a chemically bonded joint of metal to CMC to reduce issues related to different thermal expansion rates and alleviate having to make an extremely tight tolerance mechanical joint.
BACKGROUND OF THE INVENTION
0002It is known that ceramic matrix composites (CMCs) can be utilized in gas turbines at much higher temperatures than metals. Replacing metal parts, such as buckets, nozzles, shrouds, liners and transition pieces (TPs), with CMCs can allow operation at higher temperatures and/or reduce cooling requirements, thus increasing turbine efficiency. However, the CMCs must be mounted in some way to the metal structure of the turbine. This mounting is difficult not only because the CMC is a different material and hence cannot readily be welded to the metal but also because the CMC has a different coefficient of thermal expansion than the metal, so that as the CMC heats up, it expands at a slower rate than the metal, thereby making it difficult to mount to the metal.
0003<patcit id="pcit0001" dnum="US7249462B"><text>US 7,249,462</text></patcit> discusses CMC to CMC brazing with a mechanical joint. <patcit id="pcit0002" dnum="US6709230B"><text>US 6,709,230</text></patcit> discusses using an adhesive or sintered bond joint. <patcit id="pcit0003" dnum="US4643648A"><text>US 4,643,648</text></patcit> discusses using a sintered silicon nitride or carbide and hot isostatic pressing of metal powder to form the joint. <patcit id="pcit0004" dnum="US20090010755A1"><text>US 2009/0010755A1</text></patcit> discusses a method of bolting CMC to metal.
0004An improved way of joining CMCs to metal parts, such as metal parts employed in gas turbine components may be desired. The present invention seeks to satisfy that desire.
BRIEF DESCRIPTION OF THE INVENTION
0005It has now been discovered, according to the present invention, that it is possible to effectively join a CMC to a bond metal by utilizing brazing, vapor deposition, welding, plating (electroplating or electroless plating), or a combination thereof, to bind the bond metal onto the CMC. A metal mounting structure can then be brazed or welded to the bond metal. To minimize thermal expansion, narrow strips or circles, rectangles, or squares of metal can be plated to the CMC which can then be welded or brazed to an expansion joint to handle the differences in thermal expansion.
0006In a first aspect, the invention resides in a method of joining a ceramic matrix composite article to a metallic component, by providing the ceramic matrix composite article with a metallic region which bonds to the metallic component, thereby joining the ceramic matrix composite article to the metallic component.
0007In a second aspect, the invention resides in a ceramic matrix composite article comprising a mounting region which is provided with a metallic region to facilitate bonding of the ceramic matrix composite to a metallic component.
0008The invention allows for a much easier integration of CMC parts into a gas turbine, and eliminates the need for complicated mechanical mounts. The invention allows for expansion of the number of regions where CMCs can be successfully utilized, and may also allow for utilization in other devices, such as for example, rockets, steam turbines and nuclear equipment.
BRIEF DESCRIPTION OF THE DRAWINGS
0009Embodiments of the invention will now be described, by way of example only, with reference to the accompanying drawings in which: <ul id="ul0001" list-style="none"><li><figref idref="f0001">Figure 1</figref> is a CMC article onto which metal strips have been applied at a desired attachment location;</li><li><figref idref="f0001">Figure 2</figref> is a side view of the CMC article of <figref idref="f0001">Figure 1</figref> in the direction of arrow 2-2 in which a metallic flexible joint piece has been welded or brazed to the metal strips;</li><li><figref idref="f0001">Figure 3</figref> shows the CMC article of <figref idref="f0001">Figure 2</figref> inserted into a metal holder with the metallic flexible joint piece either brazed or welded to the metal holder on one side and the metal strips on the other, thereby providing a bond between CMC article and metal holder;</li><li><figref idref="f0002">Figure 4</figref> shows an alternative CMC-metal assembly;</li><li><figref idref="f0002">Figure 5</figref> is view in the direction of the arrows 5-5 in <figref idref="f0002">Figure 4</figref>;</li><li><figref idref="f0002">Figure 6</figref> shows an alternative embodiment of a CMC article mounted in a metal holder with a metallic flexible joint piece either brazed or welded to the metal holder as shown.</li></ul>
DETAILED DESCRIPTION OF THE INVENTION
0010Referring to <figref idref="f0001">Figure 1</figref>, there is shown a CMC article 2, in this case a turbine bucket, where metal plating in the form of metal strips 4 has been brazed, vapor deposited, welded, electroplated, bonded by electroless plating, or any combination thereof, on the CMC article 2 at the desired attachment location 6. The metallic strips are usually of nickel. More metal plating could be bonded to the CMC article 2 but, in this instance, metal strips only are used to reduce the impact of different thermal expansion rates between the metal of the strips and the CMC article. As an alternative to metal strips, discs, squares or other metallic shapes may be used.
0011<figref idref="f0001">Figure 2</figref> shows a side view of the CMC article 2 where a metallic flexible joint piece 8 has been welded or brazed to the metal strips 4. This accommodates different expansion rates between the CMC article and the metal component (metal holder), if needed.
0012<figref idref="f0001">Figure 3</figref> shows the CMC article 2 inserted into a metal component, in this case a metal holder 10. The metallic flexible joint piece 8 may be either brazed or welded to the metal holder 10 on one side and to the metal strips 4 on the other, providing a bond between CMC article 2 and the metal holder 10. The metallic flexible joint piece 8 may be locked into the metal holder 10 instead of welded/brazed, if desired.
0013<figref idref="f0002">Figure 4</figref> shows a metal/CMC assembly wherein the CMC component 14 is provided with metal strips 16 and the metal component 18 is provided with a flexible strip 20 which is bonded to the metal strips by any convenient method, e.g. brazing or welding. The intermediate non-bonded regions 22 of the flexible strip 20 are contoured as shown in <figref idref="f0002">Figure 4</figref> such that they contact the surface of the CMC component 14 between the metal strips as shown at 24 to provide a sealing effect. The flexible strip thus can vary in its profile from sinusoidal, to notched, to square wave. Wave amplitude may vary and some of the peaks may not come into actual contact with either the CMC article or the metal, but may still provide a sealing effect. In <figref idref="f0002">Figure 4</figref>, the flexible strip 20 is ribbon-like along the line of the joint and provides a seal in the region between the CMC 14 and the metal component 18.
0014<figref idref="f0002">Figure 5</figref> is view along the arrows line 5-5 in <figref idref="f0002">Figure 4</figref>. In <figref idref="f0002">Figure 5</figref>, the CMC is shown to the right and the metal component is shown to the left. The metal strip 16 is mounted to the CMC 14 and the flexible strip 20 is bonded to the metal strip 16. The flexible strip 20 could be wider than the metal strip if desired to improve sealing away from the strip.
0015<figref idref="f0002">Figure 6</figref> is an alternative embodiment showing the CMC article in the form of a bucket having a metal clam shell arrangement 30 which is clamped around a CMC vane 28, so that the joint piece can be attached to the rotor similarly to a metal bucket. The CMC component 28 is provided with metal strips 32 bonded thereto by any suitable method (e.g., brazing or welding) and a flexible metal strip 34 is bonded to the top of the metal strips 32 as described herein, to accommodate expansion and contraction between the CMC 28 and the metal holder 30.
0016As will be seen from <figref idref="f0002">Figure 6</figref>, the orientation of the joint can be varied, i.e., the joint may be disposed horizontally rather than vertically. Moreover, turbine buckets are but one example of a hot gas path component where the joint of the invention can be used. CMC shrouds, nozzles, seals and blades or pieces thereof could be joined similarly.
0017While the invention has been described in connection with what is presently considered to be the most practical and preferred embodiment, it is to be understood that the invention is not to be limited to the disclosed embodiment, but on the contrary, is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the appended claims.
Contents4
3 sheets
Sheet 1 Sheet 2 Sheet 3
Every citation, both ways
| Document | Relation | Office | Cited during |
|---|---|---|---|
| US2009010755A1 | Cites | United States of America | Applicant |
| US2009068004A1 | Cites | United States of America | Search report |
| US2010032143A1 | Cites | United States of America | Search report |
| US2996401A | Cites | United States of America | Search report |
| US2996401A | Cites | United States of America | Search report |
| US4643648A | Cites | United States of America | Applicant |
| US5248079A | Cites | United States of America | Search report |
| US6709230B2 | Cites | United States of America | Applicant |
| US7249462B2 | Cites | United States of America | Applicant |
| DATABASE WPI Week 198525, Derwent World Patents Index; AN 1985-149083, XP002670516 | Non-patent | – | Search report |
1 member in 1 office; this record represents the family
Priority claims2
| Document | Office | Kind | Date |
|---|---|---|---|
| 929878 | United States of America | – | |
| 201161929878 | United States of America | P |
Members1
| Document | Office | Kind | |
|---|---|---|---|
| EP2492444A1This record | European Patent Office (EPO) | A1 |
7 legal events, as the office reported them to INPADOC
Over the term
Point at a mark for the eventEvents
| Event | Code | |
|---|---|---|
| Application deemed to be withdrawnWithdrawn18D | 18D | |
| Information on the status of an ep patent application or granted ep patentGrantedSTATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWNSTAA | STAA | |
| First examination report despatched17Q | 17Q | |
| Request for examination filed17P | 17P | |
| Designated contracting statesAK | AK | |
| Request for extension of the european patentAX | AX | |
| Public reference made under article 153(3) epc to a published international application that has entered the european phaseORIGINAL CODE: 0009012PUAI | PUAI |
Numbers
- Publication
- 2492444
- Application
- 111929279
Titles3
- German
- Metall-Keramik-Fügeverfahren für Gasturbinen durch Metallisierung eines Teils aus Keramik-Matrix-Verbundwerkstoff
- English
- Plating of ceramic matrix composite parts as metal-ceramic joining method in gas turbine hardware
- French
- Procédé d'assemblage métal-céramique pour turbines à gaz, par placage de pièces en composé à matrice céramique
Classification
- CPC, 10
- C04B37/026
- C04B2237/123
- C04B2237/38
- C04B2237/40
- C04B2237/592
- C04B2237/72
- C04B2237/84
- F01D5/282
- F01D5/30
- F05D2300/6033
- IPC, 4
- F01D5 28
- C04B37 02
- B23K1 00
- B23K20 16
Designated states40
- Contracting states, 38
- Albania
- Austria
- Belgium
- Bulgaria
- Switzerland
- Cyprus
- Czechia
- Germany
- Denmark
- Estonia
- Spain
- Finland
- France
- United Kingdom
- Greece
- Croatia
- Hungary
- Ireland
- Iceland
- Italy
- Liechtenstein
- Lithuania
- Luxembourg
- Latvia
and 14 moreShow fewer
- Monaco
- North Macedonia
- Malta
- Netherlands (Kingdom of the)
- Norway
- Poland
- Portugal
- Romania
- Serbia
- Sweden
- Slovenia
- Slovakia
- San Marino
- Türkiye
- Extension states, 2
- Bosnia and Herzegovina
- Montenegro
