EP1605282A1

Optical device comprising a salt in liquid state

Abstract

Adaptable refractive index medium (I) in contact with a portion of an optical component comprises at least a salt, which is in liquid state at a temperature of the use and storage of the optical component. An independent claim is also included for an optical system comprising an optical component and (I), where (I) is in contact with a zone of the optical component.

EP1605282A1, drawing sheet 1
Sheet 1 of 7

Term

Term ended

Projected expiry passed 1 June 2025, 1.3 years ago.

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22 claims: 5 independent, 17 dependent

  1. 1
    An optical device comprising an optical component and an optical medium of different optical indices, said optical component being at least partially immersed in said medium, characterized in that said medium comprises at least one salt which is in the liquid state in the temperature range of use and storage of said optical component.
  2. 5
    Apparatus according to any one of claims 2 to 4 wherein said range is from -10 ° C to + 70 ° C.
  3. 6
    Apparatus according to any one of the preceding claims, wherein said medium contains a mixture of at least two salts.
  4. 8
    Device according to any one of claims 6 and 7, wherein the composition of said mixture remains stable over time.
  5. 9
    Apparatus according to any one of the preceding claims, wherein said salt contains an anion and a cation.
  6. 11
    Device according to any one of claims 9 and 10, wherein said cation is chosen from ammonium NH 4 + , the sulfonium HSO 3 + Phosphonium PH 4 + Li lithium + , pyridinium C 5 H 5 NH + , the imidazolium cations (C 3 H 6 NOT 2 X 1 X 2 ) + , the ammonium cations (X 1 X 2 X 3 X 4 NOT 4 ) + , sulfonium cations (X 1 X 2 X 3 S) + phosphonium cations (X 1 X 2 X 3 X 4 P) + , and pyridinium cations (X 1 C 5 H 4 NX 2 ) + , in which X 1 , X 2 , X 3 , X 4 represent aromatic or aliphatic type groups.
  7. 12
    Device according to any one of claims 9 to 11, wherein said salt has for cation N, N 'dialkylimidazolium of general formula:in which R 1 and R 2 are aliphatic or aromatic groups containing an anion.
  8. 13
    Device according to Claim 12, in which R 1 and R 2 similar or different each contain at least one anion selected from F - , Cl - , Br - , I - , BF 4 - , PF 6 - , AsF 6 , ClO 4 - , AlClO 4 - , CF 3 COO - , C 3 F 7 COO - , CF 3 SO 3 - , C 4 F 9 SO 3 - , (CF 3 SO 2 ) 2 NOT - , (CF 3 SO 2 ) 2 C - .
  9. 14
    Device according to any one of claims 12 and 13, wherein R 1 and R 2 , the same or different, are an aliphatic group chosen from the methyl group -CH 3 , the ethyl group -C 2 H 6 , the propyl group -C 3 H 7 and the butyl group -C 4 H 9 .
  10. 16
    Apparatus according to any one of the preceding claims, wherein said optical component is a long-pitched Bragg grating, called "LPG".
  11. 18
    Apparatus according to any of claims 16 and 17, wherein the optical response of said grating is substantially constant within the range of use of said optical component.
  12. 20
    An apparatus according to any one of claims 1 to 15, wherein said optical component is a section of photonic crystal fiber.