Monophase effervescent hair treatment composition achieving the effect of a pomade

The invention relates to a single-phase, foam-like hair treatment agent for achieving a pomade effect, in particular for achieving firmness and shine of the treated hair.

Research in the field of hair treatment agents has long been concerned with preparations in the form of pomades, which serve to facilitate shaping and to increase the shine and hold of the hairstyle. The dosage form of pomades is usually largely limited to non-transparent masses in the form of cream-like emulsions or gels. These dosage forms often lead to poor spreadability of the composition on the hair, which makes the hairstyle difficult, especially if only small hair sections are to be treated with the agent.

The conventional products used to achieve a pomade effect, that is to say to achieve an intensive shine and hold at the same time, usually have a high proportion of water-insoluble substances, such as fatty substances. However, the hair is heavily burdened by these fat bodies and the agent is difficult to remove without residue by shampooing. In addition, there is the problem of undesired separation of the water and fat phase in such products.

An improved application possibility offers itself in that the pomade is applied to the hair in the form of a foam, which breaks down when worked into the hair or when the hairstyle is created.

The object of the present invention was to provide a means with which an intensive pomade effect can be achieved, the negative properties typical of classic pomades such as poor spreadability on the hair, heavy stress on the hair, poor washability of the hair and Phase separation of the product should be avoided if possible.

Low to medium viscosity masses with the technical properties of a pomade can be applied with the help of an aerosol foam. The advantage of a propellant-containing aerosol product is the very easy generation of foam, even with small amounts of only slightly foaming ingredients. However, it is disadvantageous that the difficult problem arises of stabilizing the propellant gas in the aqueous phase for assembly as a single-phase product. In addition to the aesthetic unity of the product, phase separation can change the technical properties. If the aerosol product is to be contained in a transparent packaging, essentially only glass can be considered as packaging material. However, packaging an aerosol product in a glass package represents a potential safety risk.

Foaming without propellant gas is easily achieved by using strongly foaming surfactants from the class of anionic surfactants, amphoteric surfactants or nonionic surfactants. The disadvantage of using these surfactants in concentrations which are necessary for a pomade base to be foamed is that when incorporated into the hair, the foam does not break down, but rather that post-foaming, comparable to a shampoo, takes place on the hair, which is what is undesirable for the application of a pomade. In addition, pomade masses which contain large amounts of these surfactants are too viscous to ensure good foamability without the aid of propellant gas. Thinning with organic solvents leads to a lowering of the viscosity, but also brings about a drastic deterioration in the foamability. If it is diluted with water until an easily foamable viscosity of the mass is reached, this leads to a worsening of the pomade effect.

The task is solved by means of a hair treatment consisting of<ul id="ul0001" list-style="none" compact="compact"><li>(A) containing a single phase composition<ul id="ul0002" list-style="none" compact="compact"><li>(a1) at least one anionic surfactant containing a carboxylate group and</li><li>(a2) at least one nonionic emulsifier in combination with</li></ul></li><li>(B) a device for foaming the composition (A).</li></ul>

The agent can also be foamed excellently without propellant gas and can be worked well into the hair without disruptive re-foaming. It gives the hairstyle good formability, a long-lasting shine and a long-lasting soft feel.

The surfactant containing a carboxylate group is preferably present in an amount of 0.1 to 30 percent by weight, particularly preferably in an amount of 1 to 10 percent by weight and is particularly selected from sulfosuccinates, sulfosuccinamates, carboxylated fatty alcohol ethoxylates or carboxylated fatty acid amide ethoxylates or mixtures thereof.

Component (a1) preferably has the general formula (I)         R¹-X- (CHR²-CHR³-O)_n-Y-CO₂^-   1 mm^{m +}     (I) where -X- is -COO-, -CONH-, -O- or -NH-; -Y- represents an alkylene group with preferably 1 to 4 carbon atoms, in particular a methylene group, or -Y-CO₂^- represents a sulfosuccinate group; R¹ for a saturated or unsaturated, branched or unbranched hydrocarbon group with preferably 5 to 20 carbon atoms, which may be substituted with hydroxyl groups or R¹-X represents an alkoxylated or non-alkoxylated alkyl citrate group; R² and R³ independently represent hydrogen or a methyl group; n denotes the degree of alkoxylation, which is between 0 and 20, preferably between 0 and 10; M stands for one or more counterions neutralizing the negative charges of the anion, for example a metal ion or a quaternary ammonium ion and m denotes the valence of the counterion M. Is -Y-CO₂^-for a sulfosuccinate group, this is preferably of the form -C (O) -CHR⁴-CHR⁵-CO₂^-, one of the residues R⁴ and R⁵ Hydrogen and the other SO₃^- means. Stands R¹-X for an alkoxylated or non-alkoxylated alkyl citrate group, this is preferably of the form         R⁶O- (CH2CH2O)_n1-CO-CH2-C (OH) (CO- (OCH2CH2)_n2OH) -CH2-COO-, where R⁶ represents a saturated or unsaturated, branched or unbranched hydrocarbon group having preferably 5 to 20 carbon atoms, which may be substituted by hydroxyl groups, and n1 and n2 denote the degree of alkoxylation, which is in each case between 0 and 10, preferably between 0 and 5.

Surfactants containing a carboxylate group are particularly suitable as component (a1)<ul id="ul0003" list-style="dash"><li>Compounds of the general formula (II)         R¹-X- (CHR²-CHR³-O)_n-C (O) -CHR⁴-CHR⁵-CO₂^-   1 mm^{m +}     (II) where R², R³, n, m and M have the meanings given above and where at least one of the radicals R² and R³ Means hydrogen; R¹ represents a saturated or unsaturated, branched or unbranched hydrocarbon group preferably having 5 to 20 carbon atoms, which may be substituted by hydroxyl groups; -X- stands for -COO-, -CONH- or -NH- and the radicals R⁴ and R⁵ independently of one another hydrogen or SO₃^- mean, at least one of the two radicals being hydrogen. Suitable sulfosuccinates are known, for example, under the INCI names disodium ricinoleamido MEA sulfosuccinate, disodium cocamido MIPA sulfosuccinate, disodium PEG-4 cocamido MIPA sulfosuccinate, disodium PEG-5 lauryl citrate sulfosuccinate, disodium cocamido PEG-3 sulfosuccinate or disulfosuccinate Disodium Undecyleneamido MEA sulfosuccinate. A suitable sulfosuccinamate is known, for example, under the INCI name Disodium Tallow Sulfosuccinamate.</li><li>Alkyl citrates of the general formula (III)         R⁶O- (CH2CH2O)_n1-CO-CH2-C (OH) (CO- (OCH2CH2)_n2OH) -CH2- (III)         -CO- (OCH2CH2)_n3-O-CO-CHR⁴-CHR⁵-CO₂^-   1 mm^{m +}where m and M have the meanings given above; R⁶ represents a saturated or unsaturated, branched or unbranched hydrocarbon group preferably having 5 to 20 carbon atoms, which may be substituted by hydroxyl groups; the residues R⁴ and R⁵ independently of one another hydrogen or SO₃^- mean, at least one of the two radicals being hydrogen and n1, n2 and n3 being the degree of alkoxylation, which is in each case between 0 and 10, preferably between 0 and 5. A suitable alkyl citrate sulfosuccinate is known, for example, under the INCI name Disodium PEG-10 lauryl citrate sulfosuccinate or Disodium PEG-5 lauryl citrate sulfosuccinate (REWOPOL® SB CS 50 from Witco Surfactants GmbH, Germany).</li><li>Compounds of the general formula (IV)         R¹-X- (CH2CH2O)_n-CH2-CO₂^-   1 mm^{m +}     (IV) where n, m and M have the meanings given above; R¹ represents a saturated or unsaturated, branched or unbranched hydrocarbon group having preferably 5 to 20 carbon atoms, which may be substituted by hydroxyl groups, and -X-represents -COO-, -CONH- or -O-, in particular carboxylated fatty alcohol ethoxylates and fatty acid amide ethoxylates. A suitable carboxylated fatty alcohol ethoxylate is known, for example, under the INCI name Sodium Laureth-13 carboxylate.</li></ul>

Examples of suitable carboxylated fatty alcohol ethoxylates or fatty acid amide ethoxylates are Akypo Soft® types from Chem-Y, Miranate® LEC or Sandopan® LS-24 (INCI: sodium laureth-13 carboxylate) from Rhone Poulenc or Clariant.

The invention furthermore relates to the use of an anionic surfactant containing a carboxylate group for the production of a transparent, single-phase composition which can be foamed by means of a mechanical device, the surfactant containing a carboxylate group preferably being a sulfosuccinate, a sulfosuccinamate, a carboxylated fatty acid amide ethoxylate or a carboxylated fatty alcohol ethoxylate , in particular a surfactant of the general formula (I) containing a carboxylate group.

Suitable nonionic emulsifiers are, for example, the nonionic emulsifiers listed in the "International Cosmetic Ingredient Dictionary and Handbook", 7th edition, volume 2 in the section "Surfactants - Emulsifying Agents". The nonionic emulsifiers suitable as component a2 are preferably selected from ethoxylated fatty acids with 10 to 26 carbon atoms, ethoxylated mono- or polyhydric alcohols with 1 to 6 carbon atoms, ethoxylated fatty alcohols with 10 to 25 carbon atoms, ethoxylated hydrogenated or unhydrogenated castor oil, glyceride alkoxylates, Fatty acid glyceride polyalkylene glycol ethers or fatty acid partial glyceride polyalkylene glycol ethers each with less than 30 alkylene glycol units such as, for example, polyethylene glycol (7) glyceryl cocoate, polyglycol amides, fatty acid sugar esters, ethoxylated fatty acid sugar esters and partial glycerides. The degree of ethoxylation of ethoxylated surfactants is usually from 1 to 400 and is preferably greater than 3.

Suitable ethoxylated fatty acids are, for example, polyethylene glycol (75) laurate, polyethylene glycol (90) stearate, polyethylene glycol (120) stearate, polyethylene glycol (120) propylene glycol stearate, polyethylene glycol (150) dilaurate or polyethylene glycol (175) distearate.

Suitable ethoxylated fatty acid sugar esters are, for example, ethoxylated sorbitan fatty acid esters or polyethylene glycol (120) methyl glucose dioleate.

The partial glycerides can be mono- or diglycerides or mixtures of mono- and diglycerides. Examples of suitable compounds are polyethylene glycol (30) glyceryl cocoate, polyethylene glycol (80) glyceryl cocoate, polyethylene glycol (80) glyceryl tallowate, polyethylene glycol (120) glyceryl stearate, polyethylene glycol (200) glyceryl stearate, polyethylene glycol (200) glyceryl polyethylene glycol, 200) glyceryl palmitate. Hydrogenated polyethylene glycol (200) glyceryl palmitate is particularly preferred.

In a preferred embodiment, only those surfactants and emulsifiers are contained in the agent according to the invention which are water-soluble, ie those surfactants which are clearly soluble in water at 20 ° C. at a content of 1 percent by weight. Also preferred is an agent which is in a transparent, clear, single-phase form and in a transparent packaging. In addition to glass, the packaging material is preferably shatterproof, transparent plastic.

The agent is foamed without the aid of propellant gases or chemical propellants and incorporated into the hair as a foam and left in the hair without rinsing.

As component (B), the agent according to the invention has, in particular, a mechanical device for foaming composition (A). Mechanical foaming devices are to be understood as devices which allow the foaming of a liquid without using a blowing agent. A commercially available pump foamer, for example, can be used as a suitable mechanical foaming device.

Suitable foaming devices are described, for example, in EP 0 736 462 and the literature cited therein, and are available, for example, from Yoshino Kogyosho Co., Ltd., Japan. The pump foamer Daiwa F2 from Yoshino Kogyosho is particularly preferred.

Solvents with a boiling point below 600 ° C. can also be used in the composition (A) according to the invention. In a preferred embodiment, the agent according to the invention contains at least one polyhydric alcohol, in particular one with 2 to 4 carbon atoms, such as propylene glycol or glycerin. The solvents are present in an amount of 0.01 to 50 percent by weight, preferably in an amount of 2 to 30 percent by weight.

The agent according to the invention can additionally contain alcohols, in particular the lower alcohols with 1 to 4 carbon atoms usually used for cosmetic purposes, such as ethanol or isopropanol, in small amounts of up to 10 percent by weight. However, agents which contain no alcohols are preferred.

Also contained at room temperature are liquid, wax-like or solid polyethylene glycols or copolymers between ethylene glycol and propylene glycol.

The agent according to the invention can additionally contain water-insoluble solvents, for example unbranched or branched hydrocarbons such as pentane, hexane, isopentane and cyclic hydrocarbons such as cyclopentane, cyclohexane, paraffins and isododecane. However, preferred uses of the agent according to the invention do not contain such water-insoluble additives.

As a further additional constituent, the hair treatment composition according to the invention can contain at least one film-forming, hair-fixing polymer in an amount of preferably 0.01 to 10 percent by weight, particularly preferably 0.1 to 8 percent by weight. The polymer can be synthetic or natural in origin and nonionic, anionic or amphoteric in nature. The hair-fixing polymers can be used individually or in a mixture.

According to the invention, film-forming, hair-fixing polymers are understood to mean those polymers which, when used in 0.1 to 5% strength aqueous, alcoholic or aqueous-alcoholic solution, are able to deposit a polymer film on the hair and in this way to strengthen the hair.

If the polymers contain acid groups, they can be partially or completely neutralized with a suitable organic or inorganic base. Preferred bases are primary and secondary amines, especially alkanolamines such as aminomethylpropanol. If the polymers contain basic groups, these can be partially or completely neutralized with a suitable acid such as formic acid, pyrrolidone carboxylic acid, lactic acid, etc.

Suitable synthetic, nonionic, film-forming, hair-fixing polymers in the hair treatment composition according to the invention are homopolymers of vinylpyrrolidone, homopolymers of N-vinylformamide, copolymers of vinylpyrrolidone and dimethylaminoalkyl methacrylates, where alkyl can mean methyl ethyl or propyl, copolymers of vinylpyrrolidone and vinyl solid vinyl acetate, vinylpyrrolidone and vinyl acetate Vinyl acetate and vinyl propionate, polyacrylamides, polyvinyl alcohols, or polyethylene glycol / polypropylene glycol copolymers can be used.

Suitable synthetic film-forming, anionic polymers are, for example crosslinked or uncrosslinked vinyl acetate / crotonic acid copolymers, vinylpyrrolidone / vinyl acrylate copolymers, terpolymers made from acrylic acid, alkyl acrylate and N-alkylacrylamide, especially acrylic acid / ethyl acrylate / Nt-butylacrylamide terpolymers or terpolymers made from vinyl acetate, crotonate and vinyl alkanoateec, and especially vinyl vinyl acetate / vinyl alkanoate, especially methyl / Maleic anhydride copolymers and their monoesters.

Natural film-forming polymers or derivatives produced therefrom by chemical conversion can also be used in the hair treatment composition according to the invention. Polysaccharides or mixtures of oligo-, mono- and disaccharides (C-Pur® 01924 from Cerestar), Chinese balsam resin (rosin), cellulose derivatives such as hydroxypropyl cellulose with a molecular weight of 30,000 to 50,000 g / mol, or shellac in neutralized or unneutralized have proven successful Shape.

Amphoteric polymers can also be used in the hair treatment composition according to the invention. Amphoteric polymers either have free basic groups such as amino groups and free acidic groups such as carboxylic acid or sulfonic acid groups in the molecule and are capable of forming internal salts, or they contain both cationic groups such as quaternary ammonium groups and anionic groups such as carboxylate - or sulfate or sulfonate groups. Particularly suitable are copolymers formed from alkyl acrylamide, in particular octylacrylamide, alkylaminoalkyl methacrylate, in particular t-butylaminoethyl methacrylate and two or more monomers consisting of acrylic acid, methacrylic acid or their esters, as described, for example, under the trade name Resyn 28-4910 or amphomer LV-71 from NATIONAL STARCH, USA are available.

Furthermore, the agent according to the invention can contain water-soluble or water-insoluble silicone compounds in a concentration of 0.01 to 50 percent by weight, preferably in a concentration of 0.1 to 5 percent by weight. Volatile and non-volatile cyclomethicones and dimethicones and dimethicone copolyols are particularly preferred. Examples are: Polydimethylsiloxane (dimethicone), α-hydro-ω-hydroxypolyoxydimethylsilylene (dimethiconol), cyclic dimethylpolysiloxane (cyclomethicone), trimethyl- (octadecyloxy) silane (stearoxytrimethylsilane), dimethylsiloxane / glycol copolymer (dimethicone copolyodiloxane) dimethyl silicone diol group (dimethicone copolyoloxane), , Monomethylpolysiloxane with lauryl side chains and polyoxyethylene and / or polyoxypropylene end chains, (laurylmethicon copolyol), Dimethylsiloxane / glycol copolymer acetate (dimethicone copolyol acetate) Dimethylsiloxane / aminoalkylsiloxane copolymer with trimethylsilyl end groups (trimethylsilylamodimethicone). Preferred silicone polymers are: Dimethicone, which are marketed, for example, by Wacker, Munich, under the trade name Siloxane F-221 or by Dow Corning Europe, Brussels, under the trade name Dow Corning Fluid 200 / 0.65 cs; Cyclomethicones, which are marketed, for example, under the trade names Dow Corning 244 Fluid from Dow Corning Europe or Abil® K4 from Goldschmidt; Dimethiconols, which are sold, for example, under the trade names Silicone Fluid F-212 by Wacker or Unisil® SF-R by UPI.

The designations given in brackets above correspond to the INCI nomenclature (International Cosmetic Ingredients) as they are intended for the labeling of cosmetic active ingredients and auxiliaries.

Mixtures of silicone polymers are also suitable, for example a mixture of dimethicone and dimethiconol, which is sold, for example, under the trade name Dow Corning 1403 Fluid by Dow Corning Europe.

Of course, the agent according to the invention can also contain other conventional cosmetic additives, such as non-setting, nonionic polymers, non-setting, anionic polymers and non-setting, natural polymers, as well as their combination in an amount of preferably 0.01 to 15 percent by weight; Perfume oils in an amount of preferably 0.01 to 5 percent by weight; Opacifiers such as Ethylene glycol distearate, styrene / PVP copolymers or polystyrenes in an amount of preferably 0.01 to 5 percent by weight; Wetting agents, surfactants or emulsifiers with or without washing activity from the classes of anionic, cationic, amphoteric surface-active substances such as fatty alcohol sulfates, fatty alcohol ether sulfates, fatty acid alkanolamides in an amount of preferably 0.1 to 20 percent by weight; also contain humectants, dyes, light stabilizers, antioxidants, brighteners and preservatives in an amount of preferably 0.01 to 10 percent by weight.

The following examples are intended to explain the subject matter of the invention in more detail.

Examples

Example 1: Hair treatment agent for easier shaping

<tables id="tabl0001" num="0001"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="char" char=",">8.00 g</entry><entry namest="col2" nameend="col2" align="left">Disodium PEG-5 lauryl citrate sulfosuccinate (REWOPOL® SB CS 50)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">15.00 g</entry><entry namest="col2" nameend="col2" align="left">Hydrogenated castor oil, ethoxylated with 40 mol ethylene oxide (Cremophor® RH 410)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=","><u>77.00 g</u></entry><entry namest="col2" nameend="col2" align="left">water</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="char" char=",">100.00 g</entry><entry namest="col2" nameend="col2" /></row></tbody></tgroup></table></tables>

The agent can be foamed with the aid of a foaming agent to form a fine-pored, metastable foam, which breaks down completely when incorporated into the hair and gives the hair shine and hold.

Example 2: Hair treatment agent for easier shaping

<tables id="tabl0002" num="0002"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="char" char=",">8.00 g</entry><entry namest="col2" nameend="col2" align="left">Disodium PEG-5 lauryl citrate sulfosuccinate (REWOPOL® SB CS 50)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">5.00 g</entry><entry namest="col2" nameend="col2" align="left">Glycerin</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">15.00 g</entry><entry namest="col2" nameend="col2" align="left">Hydrogenated castor oil, ethoxylated with 40 mol ethylene oxide (Cremophor® RH 410)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=","><u>72.00 g</u></entry><entry namest="col2" nameend="col2" align="left">water</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="char" char=",">100.00 g</entry><entry namest="col2" nameend="col2" /></row></tbody></tgroup></table></tables>

Example 3: Hair treatment agent for easier shaping

<tables id="tabl0003" num="0003"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="char" char=",">8.00 g</entry><entry namest="col2" nameend="col2" align="left">Disodium ricinoleamido MEA sulfosuccinate (REWODERM® S 1333)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">5.00 g</entry><entry namest="col2" nameend="col2" align="left">Propylene glycol</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">15.00 g</entry><entry namest="col2" nameend="col2" align="left">Hydrogenated castor oil, ethoxylated with 40 mol ethylene oxide (Cremophor® RH 410)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">72.00 g</entry><entry namest="col2" nameend="col2" align="left">water</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="char" char=","><maths id="math0001"><math display="inline"><mrow><mover accent="true"><mrow><mtext>100.00 g</mtext></mrow><mo>¯</mo></mover></mrow></math><img file="EP0966950A2_D0001.tif" /></maths></entry><entry namest="col2" nameend="col2" /></row></tbody></tgroup></table></tables>

Example 4: Hair treatment agent for easier shaping

<tables id="tabl0004" num="0004"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="char" char=",">8.00 g</entry><entry namest="col2" nameend="col2" align="left">Disodium PEG-5 lauryl citrate sulfosuccinate (REWOPOL® SB CS 50)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">5.00 g</entry><entry namest="col2" nameend="col2" align="left">Propylene glycol</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">15.00 g</entry><entry namest="col2" nameend="col2" align="left">Hydrogenated castor oil, ethoxylated with 25 mol ethylene oxide (Arlatone® G)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">72.00 g</entry><entry namest="col2" nameend="col2" align="left">water</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="char" char=","><maths id="math0002"><math display="inline"><mrow><mover accent="true"><mrow><mtext>100.00 g</mtext></mrow><mo>¯</mo></mover></mrow></math><img file="EP0966950A2_D0002.tif" /></maths></entry><entry namest="col2" nameend="col2" /></row></tbody></tgroup></table></tables>

Example 5: Hair treatment agent for easier shaping

<tables id="tabl0005" num="0005"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="char" char=",">8.00 g</entry><entry namest="col2" nameend="col2" align="left">Disodium PEG-5 lauryl citrate sulfosuccinate (REWOPOL® SB CS 50)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">5.00 g</entry><entry namest="col2" nameend="col2" align="left">Propylene glycol</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">12.00 g</entry><entry namest="col2" nameend="col2" align="left">Hydrogenated castor oil, ethoxylated with 25 mol ethylene oxide (Arlatone® G)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">1.00 g</entry><entry namest="col2" nameend="col2" align="left">Hydrogenated glyceryl palmitate, ethoxylated with 200 mol ethylene oxide (REWODERM® LI S 80)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">74.00 g</entry><entry namest="col2" nameend="col2" align="left">water</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="char" char=","><maths id="math0003"><math display="inline"><mrow><mover accent="true"><mrow><mtext>100.00 g</mtext></mrow><mo>¯</mo></mover></mrow></math><img file="EP0966950A2_D0003.tif" /></maths></entry><entry namest="col2" nameend="col2" /></row></tbody></tgroup></table></tables>

Example 6: Hair treatment agent for easier shaping

<tables id="tabl0006" num="0006"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="char" char=",">8.00 g</entry><entry namest="col2" nameend="col2" align="left">Disodium PEG-5 lauryl citrate sulfosuccinate (REWOPOL® SB CS 50)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">5.00 g</entry><entry namest="col2" nameend="col2" align="left">Propylene glycol</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">15.00 g</entry><entry namest="col2" nameend="col2" align="left">Cremophor® RH 455</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">72.00 g</entry><entry namest="col2" nameend="col2" align="left">water</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="char" char=","><maths id="math0004"><math display="inline"><mrow><mover accent="true"><mrow><mtext>100.00 g</mtext></mrow><mo>¯</mo></mover></mrow></math><img file="EP0966950A2_D0004.tif" /></maths></entry><entry namest="col2" nameend="col2" /></row></tbody></tgroup></table></tables>

Example 7: Hair treatment agent for easier shaping

<tables id="tabl0007" num="0007"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="char" char=",">8.00 g</entry><entry namest="col2" nameend="col2" align="left">Disodium PEG-4 Cocamido MIPA sulfosuccinate (REWOPOL® SBZ)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">5.00 g</entry><entry namest="col2" nameend="col2" align="left">Propylene glycol</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">15.00 g</entry><entry namest="col2" nameend="col2" align="left">Hydrogenated castor oil, ethoxylated with 40 mol ethylene oxide (Cremophor® RH 410)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">72.00 g</entry><entry namest="col2" nameend="col2" align="left">water</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="char" char=","><maths id="math0005"><math display="inline"><mrow><mover accent="true"><mrow><mtext>100.00 g</mtext></mrow><mo>¯</mo></mover></mrow></math><img file="EP0966950A2_D0005.tif" /></maths></entry><entry namest="col2" nameend="col2" /></row></tbody></tgroup></table></tables>

Example 8: Hair treatment agent for easier shaping

<tables id="tabl0008" num="0008"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="char" char=",">8.00 g</entry><entry namest="col2" nameend="col2" align="left">Disodium Cocamido PEG-3 Sulfosuccinate (Beaulight® A 5000 S)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">5.00 g</entry><entry namest="col2" nameend="col2" align="left">Propylene glycol</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">15.00 g</entry><entry namest="col2" nameend="col2" align="left">Hydrogenated castor oil, ethoxylated with 40 mol ethylene oxide (Cremophor® RH 410)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">1.00 g</entry><entry namest="col2" nameend="col2" align="left">Cremophor® EL</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">71.00 g</entry><entry namest="col2" nameend="col2" align="left">water</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="char" char=","><maths id="math0006"><math display="inline"><mrow><mover accent="true"><mrow><mtext>100.00 g</mtext></mrow><mo>¯</mo></mover></mrow></math><img file="EP0966950A2_D0006.tif" /></maths></entry><entry namest="col2" nameend="col2" /></row></tbody></tgroup></table></tables>

Example 9: Hair treatment agent for easier shaping

<tables id="tabl0009" num="0009"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="char" char=",">8.00 g</entry><entry namest="col2" nameend="col2" align="left">Disodium Laureth-3 Sulfosuccinate (Texapon® SB 3)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">5.00 g</entry><entry namest="col2" nameend="col2" align="left">Propylene glycol</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">15.00 g</entry><entry namest="col2" nameend="col2" align="left">Hydrogenated castor oil, ethoxylated with 40 mol ethylene oxide (Cremophor® RH 410)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">72.00 g</entry><entry namest="col2" nameend="col2" align="left">water</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="char" char=","><maths id="math0007"><math display="inline"><mrow><mover accent="true"><mrow><mtext>100.00 g</mtext></mrow><mo>¯</mo></mover></mrow></math><img file="EP0966950A2_D0007.tif" /></maths></entry><entry namest="col2" nameend="col2" /></row></tbody></tgroup></table></tables>

Example 10: Hair treatment agent for easier shaping

<tables id="tabl0010" num="0010"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="char" char=",">8.00 g</entry><entry namest="col2" nameend="col2" align="left">Magnesium Laureth-11 carboxylate (Akypo Soft® 100 MgV)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">5.00 g</entry><entry namest="col2" nameend="col2" align="left">Propylene glycol</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">15.00 g</entry><entry namest="col2" nameend="col2" align="left">Hydrogenated castor oil, ethoxylated with 40 mol ethylene oxide (Cremophor® RH 410)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">72.00 g</entry><entry namest="col2" nameend="col2" align="left">water</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="char" char=","><maths id="math0008"><math display="inline"><mrow><mover accent="true"><mrow><mtext>100.00 g</mtext></mrow><mo>¯</mo></mover></mrow></math><img file="EP0966950A2_D0008.tif" /></maths></entry><entry namest="col2" nameend="col2" /></row></tbody></tgroup></table></tables>

Example 11: Hair treatment agent for easier shaping

<tables id="tabl0011" num="0011"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="char" char=",">8.00 g</entry><entry namest="col2" nameend="col2" align="left">Sodium Laureth-6 carboxylate (Akypo Soft® 45 NV)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">5.00 g</entry><entry namest="col2" nameend="col2" align="left">Propylene glycol</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">15.00 g</entry><entry namest="col2" nameend="col2" align="left">Hydrogenated castor oil, ethoxylated with 40 mol ethylene oxide (Cremophor® RH 410)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">72.00 g</entry><entry namest="col2" nameend="col2" align="left">water</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="char" char=","><maths id="math0009"><math display="inline"><mrow><mover accent="true"><mrow><mtext>100.00 g</mtext></mrow><mo>¯</mo></mover></mrow></math><img file="EP0966950A2_D0009.tif" /></maths></entry><entry namest="col2" nameend="col2" /></row></tbody></tgroup></table></tables>

Example 12: Hair treatment agent for easier shaping

<tables id="tabl0012" num="0012"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="char" char=",">8.00 g</entry><entry namest="col2" nameend="col2" align="left">Sodium Laureth-11 carboxylate (Akypo Soft® 100 BVC)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">5.00 g</entry><entry namest="col2" nameend="col2" align="left">Propylene glycol</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">15.00 g</entry><entry namest="col2" nameend="col2" align="left">Hydrogenated castor oil, ethoxylated with 40 mol ethylene oxide (Cremophor® RH 410)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">1.00 g</entry><entry namest="col2" nameend="col2" align="left">Tween® 40</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">71.00 g</entry><entry namest="col2" nameend="col2" align="left">water</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="char" char=","><maths id="math0010"><math display="inline"><mrow><mover accent="true"><mrow><mtext>100.00 g</mtext></mrow><mo>¯</mo></mover></mrow></math><img file="EP0966950A2_D0010.tif" /></maths></entry><entry namest="col2" nameend="col2" /></row></tbody></tgroup></table></tables>

Example 13: Hair treatment agent for easier shaping

<tables id="tabl0013" num="0013"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="char" char=",">8.00 g</entry><entry namest="col2" nameend="col2" align="left">Sodium Laureth-17 carboxylate (Akypo Soft® 160 NV)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">5.00 g</entry><entry namest="col2" nameend="col2" align="left">Propylene glycol</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">15.00 g</entry><entry namest="col2" nameend="col2" align="left">Hydrogenated castor oil, ethoxylated with 40 mol ethylene oxide (Cremophor® RH 410)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">72.00 g</entry><entry namest="col2" nameend="col2" align="left">water</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="char" char=","><maths id="math0011"><math display="inline"><mrow><mover accent="true"><mrow><mtext>100.00 g</mtext></mrow><mo>¯</mo></mover></mrow></math><img file="EP0966950A2_D0011.tif" /></maths></entry><entry namest="col2" nameend="col2" /></row></tbody></tgroup></table></tables>

Example 14: Hair treatment agent for easier shaping

<tables id="tabl0014" num="0014"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="char" char=",">8.00 g</entry><entry namest="col2" nameend="col2" align="left">Sodium Laureth-13 carboxylate (Miranate® LEC or Sandopan® LS-24)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">5.00 g</entry><entry namest="col2" nameend="col2" align="left">Propylene glycol</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">15.00 g</entry><entry namest="col2" nameend="col2" align="left">Hydrogenated castor oil, ethoxylated with 40 mol ethylene oxide (Cremophor® RH 410)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">1.00 g</entry><entry namest="col2" nameend="col2" align="left">Cremophor® EL</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">71.00 g</entry><entry namest="col2" nameend="col2" align="left">water</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="char" char=","><maths id="math0012"><math display="inline"><mrow><mover accent="true"><mrow><mtext>100.00 g</mtext></mrow><mo>¯</mo></mover></mrow></math><img file="EP0966950A2_D0012.tif" /></maths></entry><entry namest="col2" nameend="col2" /></row></tbody></tgroup></table></tables>

Example 15: Hair treatment agent for easier shaping

<tables id="tabl0015" num="0015"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="char" char=",">8.00 g</entry><entry namest="col2" nameend="col2" align="left">Disodium PEG-4 Cocamido MIPA sulfosuccinate (REWOPOL® SBZ)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">5.00 g</entry><entry namest="col2" nameend="col2" align="left">Propylene glycol</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">15.00 g</entry><entry namest="col2" nameend="col2" align="left">Hydrogenated castor oil, ethoxylated with 40 mol ethylene oxide (Cremophor® RH 410)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">1.00 g</entry><entry namest="col2" nameend="col2" align="left">Surfactant 193 (Dimethicone Copolyol)</entry></row><row><entry namest="col1" nameend="col1" align="char" char=",">71.00 g</entry><entry namest="col2" nameend="col2" align="left">water</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="char" char=","><maths id="math0013"><math display="inline"><mrow><mover accent="true"><mrow><mtext>100.00 g</mtext></mrow><mo>¯</mo></mover></mrow></math><img file="EP0966950A2_D0013.tif" /></maths></entry><entry namest="col2" nameend="col2" /></row></tbody></tgroup></table></tables>

Example 16: Comparison of different types of surfactants

The following compositions were examined for their technical properties. The foamability was assessed with the help of a pump foamer, foam quality 15 seconds after foaming, unwanted re-foaming when worked into the hair, durability of the hairstyle and shine. The assessment was made by evaluating the individual criteria of 5 independent persons, with a grade of 1 very good and a grade of 6 meaning unusable.

All information relates to active content in the recipe.

Raw materials used:

<ul id="ul0004" list-style="none" compact="compact"><li>(1) Arlatone® G</li><li>(2) Rewoderm® S 1333</li><li>(3) Ampho Betain AM®</li><li>(4) Texapon® N 70</li><li>(5) Oramix® NS 10</li></ul><tables id="tabl0016" num="0016"><table frame="all"><title>Table 1</title><tgroup cols="7" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="22.50mm" /><colspec colnum="2" colname="col2" colwidth="22.50mm" /><colspec colnum="3" colname="col3" colwidth="22.50mm" /><colspec colnum="4" colname="col4" colwidth="22.50mm" /><colspec colnum="5" colname="col5" colwidth="22.50mm" /><colspec colnum="6" colname="col6" colwidth="22.50mm" /><colspec colnum="7" colname="col7" colwidth="22.50mm" /><thead valign="top"><row rowsep="1"><entry namest="col1" nameend="col7" align="center">Active content of surfactant plus emulsifier constant (except F).</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" align="left">A</entry><entry namest="col3" nameend="col3" align="left">B</entry><entry namest="col4" nameend="col4" align="left">C.</entry><entry namest="col5" nameend="col5" align="left">D</entry><entry namest="col6" nameend="col6" align="left">E</entry><entry namest="col7" nameend="col7" align="left">F</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">PEG-25 Hydrogenated Castor</entry><entry namest="col2" nameend="col2" align="left">25</entry><entry namest="col3" nameend="col3" align="left">18</entry><entry namest="col4" nameend="col4" align="left">18</entry><entry namest="col5" nameend="col5" align="left">18</entry><entry namest="col6" nameend="col6" align="left">18</entry><entry namest="col7" nameend="col7" align="left">18</entry></row><row><entry namest="col1" nameend="col1" align="left">Oil (1)</entry><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" /><entry namest="col4" nameend="col4" /><entry namest="col5" nameend="col5" /><entry namest="col6" nameend="col6" /><entry namest="col7" nameend="col7" /></row><row><entry namest="col1" nameend="col1" align="left">Disodium Ricinoleamido MEA-</entry><entry namest="col2" nameend="col2" align="left">0</entry><entry namest="col3" nameend="col3" align="left">7</entry><entry namest="col4" nameend="col4" align="left">0</entry><entry namest="col5" nameend="col5" align="left">0</entry><entry namest="col6" nameend="col6" align="left">0</entry><entry namest="col7" nameend="col7" align="left">0</entry></row><row><entry namest="col1" nameend="col1" align="left">Sulfosuccinates (2)</entry><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" /><entry namest="col4" nameend="col4" /><entry namest="col5" nameend="col5" /><entry namest="col6" nameend="col6" /><entry namest="col7" nameend="col7" /></row><row><entry namest="col1" nameend="col1" align="left">Cocamodopropyl Betaine (3)</entry><entry namest="col2" nameend="col2" align="left">0</entry><entry namest="col3" nameend="col3" align="left">0</entry><entry namest="col4" nameend="col4" align="left">7</entry><entry namest="col5" nameend="col5" align="left">0</entry><entry namest="col6" nameend="col6" align="left">0</entry><entry namest="col7" nameend="col7" align="left">0</entry></row><row><entry namest="col1" nameend="col1" align="left">Lauryl ether sulfate 28% (4)</entry><entry namest="col2" nameend="col2" align="left">0</entry><entry namest="col3" nameend="col3" align="left">0</entry><entry namest="col4" nameend="col4" align="left">0</entry><entry namest="col5" nameend="col5" align="left">7</entry><entry namest="col6" nameend="col6" align="left">0</entry><entry namest="col7" nameend="col7" align="left">0</entry></row><row><entry namest="col1" nameend="col1" align="left">Decyl Glucoside (5)</entry><entry namest="col2" nameend="col2" align="left">0</entry><entry namest="col3" nameend="col3" align="left">0</entry><entry namest="col4" nameend="col4" align="left">0</entry><entry namest="col5" nameend="col5" align="left">0</entry><entry namest="col6" nameend="col6" align="left">7</entry><entry namest="col7" nameend="col7" align="left">0</entry></row><row><entry namest="col1" nameend="col1" align="left">Glycerin 86%</entry><entry namest="col2" nameend="col2" align="left">5</entry><entry namest="col3" nameend="col3" align="left">5</entry><entry namest="col4" nameend="col4" align="left">5</entry><entry namest="col5" nameend="col5" align="left">5</entry><entry namest="col6" nameend="col6" align="left">5</entry><entry namest="col7" nameend="col7" align="left">5</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">water</entry><entry namest="col2" nameend="col2" align="left">70</entry><entry namest="col3" nameend="col3" align="left">70</entry><entry namest="col4" nameend="col4" align="left">70</entry><entry namest="col5" nameend="col5" align="left">70</entry><entry namest="col6" nameend="col6" align="left">70</entry><entry namest="col7" nameend="col7" align="left">77</entry></row></tbody></tgroup></table></tables><tables id="tabl0017" num="0017"><table frame="all"><title>Table 2</title><tgroup cols="7" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="22.50mm" /><colspec colnum="2" colname="col2" colwidth="22.50mm" /><colspec colnum="3" colname="col3" colwidth="22.50mm" /><colspec colnum="4" colname="col4" colwidth="22.50mm" /><colspec colnum="5" colname="col5" colwidth="22.50mm" /><colspec colnum="6" colname="col6" colwidth="22.50mm" /><colspec colnum="7" colname="col7" colwidth="22.50mm" /><thead valign="top"><row rowsep="1"><entry namest="col1" nameend="col7" align="center">Assessment of professional characteristics</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" align="center">A</entry><entry namest="col3" nameend="col3" align="center">B</entry><entry namest="col4" nameend="col4" align="center">C.</entry><entry namest="col5" nameend="col5" align="center">D</entry><entry namest="col6" nameend="col6" align="center">E</entry><entry namest="col7" nameend="col7" align="center">F</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Foamability</entry><entry namest="col2" nameend="col2" align="right">3</entry><entry namest="col3" nameend="col3" align="right">1</entry><entry namest="col4" nameend="col4" align="right">2</entry><entry namest="col5" nameend="col5" align="right">3</entry><entry namest="col6" nameend="col6" align="right">3</entry><entry namest="col7" nameend="col7" align="right">2</entry></row><row><entry namest="col1" nameend="col1" align="left">Foam quality after 15 seconds</entry><entry namest="col2" nameend="col2" align="right">4</entry><entry namest="col3" nameend="col3" align="right">2</entry><entry namest="col4" nameend="col4" align="right">2</entry><entry namest="col5" nameend="col5" align="right">2</entry><entry namest="col6" nameend="col6" align="right">3</entry><entry namest="col7" nameend="col7" align="right">2</entry></row><row><entry namest="col1" nameend="col1" align="left">Foaming when working in</entry><entry namest="col2" nameend="col2" align="right">1</entry><entry namest="col3" nameend="col3" align="right">1</entry><entry namest="col4" nameend="col4" align="right">6</entry><entry namest="col5" nameend="col5" align="right">6</entry><entry namest="col6" nameend="col6" align="right">6</entry><entry namest="col7" nameend="col7" align="right">1</entry></row><row><entry namest="col1" nameend="col1" align="left">Hold the hairstyle</entry><entry namest="col2" nameend="col2" align="right">1</entry><entry namest="col3" nameend="col3" align="right">1</entry><entry namest="col4" nameend="col4" align="right">4</entry><entry namest="col5" nameend="col5" align="right">3</entry><entry namest="col6" nameend="col6" align="right">3</entry><entry namest="col7" nameend="col7" align="right">4</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">shine</entry><entry namest="col2" nameend="col2" align="right">2</entry><entry namest="col3" nameend="col3" align="right">1</entry><entry namest="col4" nameend="col4" align="right">6</entry><entry namest="col5" nameend="col5" align="right">6</entry><entry namest="col6" nameend="col6" align="right">6</entry><entry namest="col7" nameend="col7" align="right">4</entry></row></tbody></tgroup></table></tables>

With the criterion "foam quality after 15 seconds", a foam receives a good rating if it has as small a pore and as little collapse as possible 15 seconds after removal and before incorporation into the hair. Patterns C, D and E foamed very strongly when worked into the hair (shampoo effect), so that it was necessary to clean the hair.

The formulation B corresponding to the agent according to the invention improves the technical properties of the formulation A, which consists only of a nonionic surfactant, and has no disadvantages of the formulations C, D and E.

If the formulas B, C, D and E are compared with a formula F, in which the active content of Arlatone® G corresponds to that of the formulas B to E, it can be seen that the hold and shine of the hairstyle treated with this formula , are worse than those treated with formulation B.