Process for the continuous preparation of linear thermoplastic polyesters
Abstract
Process for the continuous production of linear thermoplastic polyesters, whereina) a transesterification or esterification of aliphatic and / or aromatic dicarboxylic acids having a molecular weight <300 or their ester-forming derivatives with aliphatic and / or cycloaliphatic diols having a molecular weight <250 which additionally contain poly (alkylene oxide) glycols having a molecular weight of 400 to 4000 may be passed at a temperature above 240 ° C and under reduced pressure from top to bottom through a substantially vertical tubular precondensation zone to form a precondensate and vapor diols having a molecular weight <250,b) separating the precondensate and vaporous diols andc) discharges the precondensate from the sump, characterized in that in the step a) a temperature of 250 to 360 ° C, a pressure of 0.5 to 20 Torr and a residence time of 3 to 10 minutes and the tubular precondensation zone is provided with internals having a free surface of 0.3 to 1.5 m² / l and in the step c) the precondensate is further condensed at a temperature of 240 to 290 ° C under a pressure of 0.5 to 20 Torr and a residence time of 10 to 40 minutes and receives granulierfähigen polyester.
Term
Term ended
Projected expiry passed 6 June 2009, 17.3 years ago.
- Priority
- Filed
- Published
- Projected expiry
- Today
Every citation, both ways
| Document | Relation | Office | Category | Cited during |
|---|---|---|---|---|
| EP0000918A2 | Cites | European Patent Office (EPO) | A | Search report |
| GB1263637A | Cites | United Kingdom | A | Search report |
| FR1545487A | Cites | France | A | Search report |
| DE2043187A1 | Cites | Germany | A | Search report |
| GB2184129A | Cites | United Kingdom | Y | Search report |
| FR2240246A1 | Cites | France | A | Search report |
| US4154920A | Cites | United States of America | Y | Search report |
| GB819721A | Cites | United Kingdom | A | Search report |
3 priority claims, no other members on record
Priority claims3
| Document | Office | Kind | Date |
|---|---|---|---|
| 3820362 | Germany | A | |
| 3820362 | Germany | – | |
| DE19883820362 | – | – | – |
40 legal events, as 5 offices reported them to INPADOC
Over the term
Point at a mark for the eventEvents
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| Be: lapsedLapsedBERE | BERE | EP | |
| Announcement of lapse in spainLapsedFD2A | FD2A | ES | |
| Lapsed in a contracting state [announced via postgrant information from national office to epo]LapsedPG25 | PG25 | EP | |
| Lapsed in a contracting state [announced via postgrant information from national office to epo]LapsedPG25 | PG25 | EP | |
| Notification of lapseLapsedST | ST | FR | |
| Nl: lapsed or anulled due to non-payment of the annual feeLapsedNLV4 | NLV4 | EP | |
| Lapsed in a contracting state [announced via postgrant information from national office to epo]LapsedPG25 | PG25 | EP | |
| Patent ceasedCeasedPL | PL | CH | |
| Gb: european patent ceased through non-payment of renewal feeCeasedGBPC | GBPC | EP | |
| Lapsed in a contracting state [announced via postgrant information from national office to epo]LapsedPG25 | PG25 | EP | |
| Annual fee paid to national office [announced via postgrant information from national office to epo]GrantedPGFP | PGFP | EP | |
| Lapsed in a contracting state [announced via postgrant information from national office to epo]LapsedPG25 | PG25 | EP | |
| Lapsed in a contracting state [announced via postgrant information from national office to epo]LapsedPG25 | PG25 | EP | |
| Lapsed in a contracting state [announced via postgrant information from national office to epo]LapsedPG25 | PG25 | EP | |
| Lapsed in a contracting state [announced via postgrant information from national office to epo]LapsedPG25 | PG25 | EP | |
| Lapsed in a contracting state [announced via postgrant information from national office to epo]LapsedPG25 | PG25 | EP | |
| Annual fee paid to national office [announced via postgrant information from national office to epo]GrantedPGFP | PGFP | EP | |
| Annual fee paid to national office [announced via postgrant information from national office to epo]GrantedPGFP | PGFP | EP | |
| Annual fee paid to national office [announced via postgrant information from national office to epo]GrantedPGFP | PGFP | EP | |
| Annual fee paid to national office [announced via postgrant information from national office to epo]GrantedPGFP | PGFP | EP | |
| Annual fee paid to national office [announced via postgrant information from national office to epo]GrantedPGFP | PGFP | EP | |
| Annual fee paid to national office [announced via postgrant information from national office to epo]GrantedPGFP | PGFP | EP | |
| European patent in force as of 2002-01-01IF02 | IF02 | GB | |
| No opposition filedOpposition26N | 26N | EP | |
| No opposition filed within time limitOppositionORIGINAL CODE: 0009261PLBE | PLBE | EP | |
| Information on the status of an ep patent application or granted ep patentGrantedSTATUS: NO OPPOSITION FILED WITHIN TIME LIMITSTAA | STAA | EP | |
| Fr: translation filedET | ET | EP | |
| It: translation for a ep patent filedITF | ITF | EP | |
| It: translation for a ep patent filedITF | ITF | EP | |
| Gb: translation of ep patent filed (gb section 77(6)(a)/1977)GBT | GBT | EP | |
| Corresponds to:REF | REF | EP | |
| Definitive protectionFG2A | FG2A | ES | |
| Designated contracting statesAK | AK | EP | |
| (expected) grantORIGINAL CODE: 0009210GRAA | GRAA | EP | |
| First examination report despatched17Q | 17Q | EP | |
| Request for examination filed17P | 17P | EP | |
| Designated contracting statesAK | AK | EP | |
| Search report despatchedORIGINAL CODE: 0009013PUAL | PUAL | EP | |
| Designated contracting statesAK | AK | EP | |
| Public reference made under article 153(3) epc to a published international application that has entered the european phaseORIGINAL CODE: 0009012PUAI | PUAI | EP |
Numbers
- Publication
- 0346735
- Publication, DOCDB
- 0346735
- Publication, EPODOC
- EP0346735
- Application
- 110212
- Application, DOCDB
- 89110212
- Application, EPODOC
- EP19890110212
Titles3
- English
- PROCESS FOR THE CONTINUOUS PREPARATION OF LINEAR THERMOPLASTIC POLYESTERS
- German
- Verfahren zur kontinuierlichen Herstellung von linearen thermoplastischen Polyestern
- French
- Procédé pour la préparation continue de polyesters linéaires thermoplastiques
Classification
- CPC, 1
- C08G63/78
- IPC, 3
- C08G63 66
- C08G63 78
- C08G63 80
Designated states1
- Contracting states, 1
- Netherlands (Kingdom of the)