Sealant compositions or coating mixtures containing functional silane or siloxane adhesion promoters nonreactive with blocked isocyanates.

FIELD OF THE INVENTION

0001The present invention relates to a sealant or coating composition containing a blocked isocyanate-­terminated prepolymer, a polyamine or polyimine curing agent, and small amounts of functional silane or siloxane adhesion promoters which are nonreactive with blocked isocyanates. The sealant or coating compositions of the present invention are essentially free of any organosilanes which are reactive with the blocked isocyanate-terminated prepolymer.

BACKGROUND

0002Sealant and coating compositions desirably have a combination of properties which render them particu­larly suitable for their intended applications. Such compositions should be able to be packaged in sealed containers or cartridges and stored for relatively long periods of time without objectionable "setting up" or hardening, that is curing of the components in the package. The one component sealant composition should form a relatively tack-free surface upon application and upon exposure to atmospheric moisture should cure without the formation of bubbles within a suitable time. The two component system can be formulated into package stable systems with adjustable cure rate and cured sealant properties. When cured, they should adhere tenaciously to a wide variety of surfaces such as glass, aluminum, concrete, marble, and steel. They should also have sufficient elasticity and flexibility to withstand con­traction and expansion of panels, and the like, gener­ ally associated with temperature variations as a result of climatic changes and/or wind forces.

0003U. S. Patent No. 4,067,844 to Barron et al relates to polyurethane polymers in which a proportion of the isocyanate-terminated prepolymers are reacted with certain aminosilanes, or with the reaction product of a mercaptosilane with monoepoxide, or with the reaction product of an epoxysilane with a secondary amine.

0004U. S. Patent No. 4,507,443 to Barron et al relates to a sealant or a coating composition containing a blocked isocyanate-terminated prepolymer in which generally all of the NCO groups are blocked, a multifunc­tional imine curing agent, and an organosilane which is reactive with the blocked isocyanate.

0005U. S. Patent No. 2,942,019 to Pike et al re­lates to organosilicon methylideneamino compounds and a process for producing the same.

0006U. S. Patent No. 3,248,371 to Damusis relates to low temperature deblocking agents which are alkylene oxide adducts of tertiary amines and hydroxy-terminated tertiary nitrogen-containing polyether-based urethane intermediates.

0007U. S. Patent No. 3,267,078 to Damusis relates to polyether urethane coating compositions which are cured with diimine compounds.

0008U. S. Patent No. 3,627,722 to Selter relates to urethane sealant compositions in which part of the NCO groups are end-blocked with -Si(OR)₃ groups where R is a lower alkyl.

0009U. S. Patent No. 4,222,925 to Bryant et al relates to a sealant composition made from a polyurethane containing a small amount of N-beta aminoethyl, gamma-­aminopropyltrimethoxysilane and a reinforcing filler such as carbon black.

0010U. S. Patent No. 4,345,053 to Rizk et al re­lates to a moisture curable silicon terminated organic polymer made by reacting a polyurethane prepolymer having terminal active hydrogen atoms with an isocyanato organosilane having at least one hydrolyzable alkoxy group bonded to the silicon polymer.

0011U. S. Patent No. 4,374,237 to Berget et al relates to curable isocyanate prepolymers wherein a portion or all of the available isocyanate terminal groups have been reacted with a secondary amine-­containing silane monomer having two trialkoxysilane groups.

0012U. S. Patent No. 4,625,012 to Rizk et al re­lates to methods of making moisture curable polyurethane polymers having terminal isocyanate groups and pendant alkoxysilane groups by reacting an isocyanatosilane adduct, having terminal isocyanate groups and at least one hydrolyzable alkoxy group bonded to a silicon, with a polyisocyanate and a polyol.

0013U. S. Patent No. 4,687,533 to Rizk et al relates to a method for bonding a material to a non-­porous substrate such as glass utilizing a moisture curable sealant composition containing a filler and a polyurethane polymer having terminal isocyanate groups and pendant silane groups having at least one alkoxy group bonded to silicon.

0014German Patent 3,414,877 to Emmerling et al relates to moisture hardening polyurethane preparations containing adhesive agents such as aldimine or ketimine group containing alkylalkoxysilanes.

SUMMARY OF THE INVENTION

0015According to the concepts of the present inven­tion, improved physical properties such as improved adhesion and improved joint movement capabilities, are achieved when specific types of silanes or siloxanes which are non-reactive with blocked isocyanate groups are utilized. That is, blocked urethane sealants and coat­ings of the present invention can contain blends of specific types of adhesion promoters which are non-reac­tive with the blocked isocyanate-terminated groups of the prepolymer. Accordingly, the present invention specifi­cally excludes organosilanes which are reactive with blocked isocyanate-terminated prepolymers. Specific types of functional silanes or siloxanes which are not reactive with blocked isocyanates include epoxysilanes or epoxysiloxanes, isocyanatosilanes or isocyanatosilox­anes and ketiminosilanes or ketiminosiloxanes. The amount of such functional silane or siloxane compounds is generally small, as for example from about 0.1 part to about 10 parts by weight, desirably from about 0.2 to about 1.0 part by weight for every 100 parts by weight of the blocked prepolymer. When sealant compositions are made, a preferred range is from about 0.3 to about 0.7 parts by weight for every 100 parts by weight of the blocked prepolymer.

0016Sealants or coating compositions of the present invention can be moisture curable and form compositions that adhere tenaciously to a wide variety of surfaces and form tack-free surfaces after being exposed to the atmosphere for only a short period of time. When a two-­part system it utilized, mixture of the two separate components forms a cured sealant within a matter of hours after application.

DETAILED DESCRIPTION OF THE INVENTION

0017The present invention relates to a urethane sealant composition or coating admixture comprising a blend of a blocked isocyanate-terminated prepolymer and an adhesion promoter which is non-reactive therewith. Moreover, the present invention relates to such a ure­thane sealant composition or coating admixture which is essentially or desirably free of any organosilane com­pounds which are reactive with the blocked isocyanate-­terminated prepolymer. The blends of the present inven­tion when a one-part system desirably contain a poly­imine curing agent and when a two-part system generally contain a polyamine curing agent. The blends can also contain various conventional additives and the like and upon cure yield a sealant or coating having improved physical properties and especially improved adhesion properties.

0018Considering the urethane prepolymers, the urethane prepolymers of the present invention are gener­ally made from a polyisocyanate and any conventional intermediate utilized in the preparation of urethane sealants or coatings. Thus, the intermediate can be a polyether polyol, a polyester polyol, and the like wherein the polyol is a diol or a triol. Such urethane intermediates are well known to the art and to the liter­ature. Specific examples include polyethylene ether diols or triols, polypropylene ether diols or triols, polybutylene ether diols or triols, polytetramethylene ether diols or triols, and block copolymers of such diols and triols, and/or blends thereof. Specific ex­amples of hydroxyl-terminated polyesters include any hydroxy-terminated polyester prepared from poly-basic acids or anhydrides as for example adipic acid and phthalic anhydride, and polyols in which the hydroxyl functionality of the polyester prepolymer is greater than 2, and preferably greater than 2.3. The intermediates generally have a molecular weight of from about 1,000 to about 25,000.

0019The prepolymers of the present invention are made by reacting the above-noted polyol intermediates with a polyisocyanate generally having the formula R(NCO)_n wherein n is 2, 3 or 4 and R is an aliphatic, an aromatic, or an aliphatic substituted aromatic having from 4 to 20 carbon atoms and preferably from 6 to 15 carbon atoms. Desirably the aliphatic groups are alkyl groups. Examples of specific di- or triisocyanates which can be utilized include p,p′,p˝-triisocyanato triphenyl methane, p,p′-diisocyanato diphenyl methane (MDI), hexa­methylene diisocyanate, naphthalene-1,5-diisocyanate, and various isomers of toluene diisocyanates (TDI) such as 2,4-tolylene diisocyanate, 2,6-tolylene diisocyanate, and mixtures thereof. MDI and TDI are preferred. Inasmuch as an adhesive type composition is desired, the equiva­lent weight ratio of the polyisocyanate to the polyol intermediate, that is, the NCO/OH ratio is from about 1.8 to about 2.2 and preferably from about 2.0 to about 2.1. The formation of the prepolymer while occurring at am­bient temperature is generally conducted at higher tem­peratures to reduce the reaction time, as from between 40^o to about 125^oC with from about 60^o to about 100^oC being preferred.

0020In order to provide a prepolymer that is more stable during storage, the isocyanate-terminated prepoly­mer described above is substantially "blocked" with a blocking agent that reacts with the terminal isocyanate groups of prepolymer. Blocking agents useful in the present invention include any conventional blocking agents as well as those known to the art and to the literature that produce blocked terminal isocyanates that do not readily react with moisture in air at room temper­ature (about 25^oC). However, upon exposure of the curing agents to moisture, they will "unblock" the isocyanate and react with the same. General types of blocking agents include various phenol type compounds, various oxime compounds, various ester compounds, and the like. Examples of suitable blocking agents include phenol, 3-­methoxyphenol, 4-methoxyphenol, nonylphenol, meta-cresol, paracresol, 4-chlorophenol, meta-hydroxybenzaldehyde, ortho-hydroxybenzaldehyde, parahydroxybenzaldehyde, hydroquinone, 1-hydroxy-2-propanone, 3-hydroxyacetophe­none, 4-hydroxyacetophenone, ethyl acetyl acetate and cyclohexanone oxime. A sufficient amount of the blocking agent is utilized to react with the isocyanate prepoly­mers to substantially "block" the terminal isocyanate groups and preferably to block all of the terminal iso­cyanate groups. The amount of blocking agent utilized is such that the equivalent weight ratio of the blocking agent to the terminal isocyanate groups is at least 0.85 and can be a large excess since it often serves as a plasticizing agent.

0021The curing agents of the present invention include the various polyamine and the various polyimine compounds. The particular type of curing agent utilized generally depends upon whether a two part urethane sealant or coating system is utilized or a one part system. When a two part system it utilized, the curing agent is contained as a separate component or composi­tion which is not mixed with the prepolymer component or composition until immediately prior to application of the sealant or coating composition. Generally, any conven­tional polyamine curing agent can be utilized including those known to the art and to the literature. An example of a typical polyamine curing agent is a diamine or a triamine represented by the formula <chemistry id="chem0001" num="0001"><img file="EP0343523A2_D0001.tif" /></chemistry> wherein R is an aliphatic, or an aliphatic substituted aromatic, with the aliphatic group being connected to the amine group having from 1 to 25 carbon atoms and prefer­ably from 2 to 10 carbon atoms, with x being 0 or 1, and preferably 0. Examples of specific amine compounds include ethylene diamine, butylene diamine, propylene diamine, decamethylene diamine, octamethylene diamine, and the like.

0022Another class of suitable polyamine compounds are the various amine terminated polyethers. These compounds are generally diamines or triamines containing polyether groups therein wherein the number of ether repeating units can vary as from 2 up to about 150. The molecular weight of the amine terminated polyethers is generally from about 200 to about 7000. Such compounds are produced by the Texaco Chemical Co. under the brand name Jeffamine such as the M series, the D series, the ED series, the DU series, the BuD series, and the Jeffamine T series. Such amine terminated polyethers are described in the bulletin, "The Jeffamine Polyoxyalkyleneamines", by the Texaco Chemical Co., Copyright 1985, NPD-024 102-­0745, which is hereby fully incorporated by reference. A particularly preferred compound is the Jeffamine D com­pounds which have the following formula: <chemistry id="chem0002" num="0002"><img file="EP0343523A2_D0002.tif" /></chemistry> wherein n is from 2 to about 100 and preferably from about 4 to about 20.

0023Still another class of suitable polyamine compounds are the polyamide polyamines made from poly­amines and dicarboxylic acids having from 2 to 36 carbon atoms such as oxalic acid, malonic acid, succinic acid, adipic acid, suberic acid, azelalic acid, dimerized fatty acids, trimerized fatty acids, and the like.

0024When a one part system it utilized, that is a composition in which all of the components of the poly­urethane sealant or coating are contained together, a polyimine curing agent is generally utilized. The poly­imines will not react with the blocked isocyanate-­terminated prepolymer unless exposed to moisture as upon application of the sealant. Various polyimines can be prepared by reacting any of the above polyamine compounds with either a ketone or an aldehyde as well known to those skilled in the art and to the literature. The end result is the production of various ketimine compounds or aldimine compounds. Examples of specific ketimine type compounds which can be utilized are set forth in U.S. Patent No. 4,507,443 which is hereby fully incorporated by reference.

0025Regardless of whether a one part or two part system is utilized, the amount of the polyamine or poly­imine curing agent is from about 0.6 to about 1.5 weight equivalents and preferably 0.8 to 1.2 weight equivalents per equivalent of a blocked isocyanate.

0026When a two component system it utilized, as noted above, one of the components contains the prepoly­mer and the second component contains the curing agent. The curing agent component generally contains the amine curing agent, and various additives in conventional amounts, if desired, such as various plasticizers, pig­ments, thickeners, drying agents, and the like. The pre­polymer or base component contains various conventional additives or compounding ingredients such as fillers, thixotropic agents, extenders, pigments, plasticizers, UV absorbers, solvents, and the like. Typically, the pre­polymer component contains large amounts of a filler such as talc, various types of silicates, various types of clays, calcium carbonate, and the like, in an amount of from about 60 to about 200 parts by weight per 100 parts by weight of the prepolymer; a thickening agent such as a thixotropic compound in an amount of from 0 to about 30 parts by weight per 100 parts by weight of the prepoly­mer; UV absorbers in an amount of usually less than 1 or 2 parts by weight per 100 parts by weight of the prepoly­mer; and plasticizers in an amount of from about 0 to about 50 parts by weight per 100 parts by weight of the prepolymer. Solvents, which are generally utilized to adjust the viscosity of the prepolymer or base component to a desired range, constitute generally less than 10 percent volatility of the total prepolymer component for sealant compositions. In coating compositions, the amount of solvent is generally higher.

0027The present invention is the utilization of certain types of adhesion promoters which are non-reac­tive with the blocked isocyanate-terminated prepolymers. That is unlike U.S. Patent No. 4,507,443, the adhesion promoters of the present invention are specific func­tional organic silane or functional organic siloxane compounds which do not react with the blocked isocyanate prepolymers. Accordingly, the sealant compositions and coating admixtures of the present invention are essen­tially free from, exclude, or do not contain organosilane compounds which react with the blocked isocyanate-­terminated prepolymers. Such isocyanate reactive organosilane compounds are not within the ambit of the present invention inasmuch as their reaction has found to degrade mechanical properties such as movement capabili­ty. It has been found, however, that the use of an epoxysilane or an epoxysilane, an isocyantosilane, or an isocyantosiloxane, or a ketiminosilane or a ketimino­siloxane improves various physical mechanical properties such as elongation, modulus, movement capability, as well as adhesion.

0028The various functional silane compounds of the present invention which are nonreactive with blocked isocyanates can generally be represented by the formula <chemistry id="chem0003" num="0003"><img file="EP0343523A2_D0003.tif" /></chemistry> or a siloxane derivative thereof, which X is a functional group such as an epoxy group, an isocyanate, or a ketimine. R¹ is an intermediate or linking hydrocarbon group such as an ali­phatic, desirably an alkyl, having from 1 to 16 carbon atoms with from 2 to 6 carbon atoms being preferred. A preferred R¹ group is propyl. R¹ can also be a cycloali­phatic such as a cyclo alkyl having from 4 to 8 carbon atoms. A less desired R¹ group is an aromatic or an alkyl substituted aromatic having from 6 to 15 carbon atoms. The R² group is an aliphatic, such as an alkyl, having from 1 to 25 carbon atoms or less desirably an aromatic or an alkyl substituted aromatic having from 6 to 15 carbon atoms. The number of such "a" groups is 0, 1, or 2. Each alkoxy group, independently, is 0 or 1, that is "b", "c", and "d" is 0 or 1, with the proviso that "a" + "b" + "c" + "d" = 3. R³, R⁴, and R⁵, inde­pendently is an alkyl having from 1 to 10 carbon atoms, with 1 to 4 carbon atoms being preferred, or an aromatic or an alkyl substituted aromatic having from 6 to 12 carbon atoms. Preferably all three alkoxy groups exist with said groups being methoxy. Thus, trimethoxysilyl is a highly preferred silane group.

0029The various X groups, as noted, can be an epoxy group, an isocyanato group, or a ketimino group. Numer­ous epoxy groups can exist. For example, the epoxy group can be an epoxy group per se (i.e., ethylene oxide), glycidoxy - a preferred group, 2-alkylglycidoxy wherein the alkyl group has from 1 to 4 carbon atoms with methyl being desired, an epoxycycloalkylene group wherein the alkylene group has from 4 to 10 carbon atoms with epoxycyclohexyl being desired. Inasmuch as the specific epoxy group of glycidoxy is preferred, a preferred epoxy­silane of the above formula is gamma-glycidoxypropyltri­methoxysilane.

0030With regard to X being an isocyanate group, it is precisely that, that is an NCO group. A preferred isocyanatosilane is isocyanatopropyltrimethoxysilane.

0031Considering the ketiminosilanes, the X portion has the formula <chemistry id="chem0004" num="0004"><img file="EP0343523A2_D0004.tif" /></chemistry> where R⁶ and R⁷, independently, is an aliphatic and desirably an alkyl having from 1 to 10 carbon atoms and preferably from 1 to 4 carbon atoms, less desirably an aromatic or an alkyl substituted aromatic having from 6 to 15 carbon atoms, or is hydrogen. A preferred keti­minosilane is the methylisobutylketone based ketimine of gamma-aminopropyltrimethoxysilane.

0032The epoxysilanes, the isocyanatesiloxanes, and the ketiminosiloxanes, are merely siloxane oligomers of the above-noted epoxysilanes, isocyanatosilanes or ketiminosilanes. The oligomers can be a dimer, trimer, etc. and can be defined as having 2 to about 50 repeat­ing units of the silicon atom.

0033Utilizing the specific functional silane or siloxane compounds of the present invention which are nonreactive with blocked isocyanates, it has been found that better physical properties are obtained as set forth hereinafter. In contrast, the different organosilanes previously utilized which reacted with free isocyanate groups as well as with blocked isocyanate groups did not yield the improved properties of the present invention.

0034Urethane sealants of the present invention can be utilized as caulking compounds for windows, panels, concrete, masonry, stone, and the like. When utilized as a protective coating composition, a solvent material such as toluene, benzene, xylene, hexane, heptane, and the like, is generally added to provide a coating composition having a consistency suitable for application as by spraying, bushing, roll coating, and the like.

0035The invention will be better understood by reference to the following examples.

EXAMPLE 1

(Control)

0036A blocked isocyanate-terminated polymer was formed according to the following procedure.

0037About 2000 parts by weight of a polyol consist­ing of a copolymer of propyleneoxide with ethyleneoxide having an hydroxyl number of 26 was admixed with 556 parts by weight of toluene and azeotroped to remove 356 parts by weight of toluene. After cooling under nitrogen atmosphere, 166 parts by weight of an 80/20 weight per­cent mixture of 2,4-tolylene diisocyanate and 2,6-tolyl­ene diisocyanate were added at room temperature. The resulting mixture was heated to 90^oC and held at that temperature for three hours to form the isocyanate terminated prepolymer. About 209 parts by weight of nonylphenol then were added to the reaction mixture and the mixture was maintained at 90^o for one hour. About 0.2 parts by weight of stannous octoate (a catalyst for promoting blocking of the isocyanate terminated polymer) was added to the mixture and the mixture was maintained at 90^oC for an additional two hours. The resulting blocked isocyanate terminated prepolymer was formulated according to the following recipe. <tables id="tabl0001" num="0001"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Blocked isocyanate terminated polymer described above</entry><entry namest="col2" nameend="col2" align="right">100 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Thixcin R, a Thixotrope, made by NL Industries</entry><entry namest="col2" nameend="col2" align="right">15 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Benzoflex, 9-88, a plasticizer made by Monsanto</entry><entry namest="col2" nameend="col2" align="right">26 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Calcium carbonate</entry><entry namest="col2" nameend="col2" align="right">60 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Paraffin wax</entry><entry namest="col2" nameend="col2" align="right">2.2 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Process oil</entry><entry namest="col2" nameend="col2" align="right">4.4 parts</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">A ketimine prepared from Jeffamine D-400, and methylisobutylketone</entry><entry namest="col2" nameend="col2" align="right">10.7 parts</entry></row></tbody></tgroup></table></tables>

0038Samples prepared from above formulation were cured for one week at room temperature, one week at 120^oF, and one week at 158^oF. Physical properties of the cured sample are given in Table I and are used as the control for Examples 2, 3 and 4.

EXAMPLE 2

0039A prepolymer described in Example 1 was formu­lated according to the following recipe. <tables id="tabl0002" num="0002"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Blocked isocyanate-based polymer</entry><entry namest="col2" nameend="col2" align="right">100 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Thixcin-R</entry><entry namest="col2" nameend="col2" align="right">15 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Benzoflex 9-88</entry><entry namest="col2" nameend="col2" align="right">26 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Calcium Carbonate</entry><entry namest="col2" nameend="col2" align="right">60 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Paraffin wax</entry><entry namest="col2" nameend="col2" align="right">2.2 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Process Oil</entry><entry namest="col2" nameend="col2" align="right">4.4 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Ketimine from Jeffamine D-400 and Methyl isobutyl ketone</entry><entry namest="col2" nameend="col2" align="right">10.9 parts</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Gamma-glycidoxypropyltrimethoxysilane</entry><entry namest="col2" nameend="col2" align="right">0.2 parts</entry></row></tbody></tgroup></table></tables>

0040Samples prepared according to the above formulation were cured for one week at room temperature, one week at 120^oF, and for one week at 158^oF. Physical properties and the adhesion data of the cured samples is given in Table I. Data in Table I clearly shows that addition of epoxysilanes such as gamma-glycidoxypropyl­ trimethoxysilane in small concentration significantly improves the adhesion without effecting the physical properties.

EXAMPLE 3

0041100 parts of methylisobutylketone were azeo­troped and 52 parts by weight of methylisobutylketone were removed to dry the methylisobutylketone. To the remaining methylisobutylketone, 45 parts by weight of gamma-aminopropyltrimethoxysilane is added at room tem­perature. The above reaction was stirred at room tem­perature for 30 minutes and then heated to 60^oC and held at that temperature for 4.5 hours. Excess methyliso­butylketone and methanol was then removed by distil­lation. A ketiminosiloxane, so prepared is used in the following formulation. <tables id="tabl0003" num="0003"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Blocked isocyanate-based polymer</entry><entry namest="col2" nameend="col2" align="right">100 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Thixcin R</entry><entry namest="col2" nameend="col2" align="right">15 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Benzoflex</entry><entry namest="col2" nameend="col2" align="right">26 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Calcium carbonate</entry><entry namest="col2" nameend="col2" align="right">60 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Paraffin wax</entry><entry namest="col2" nameend="col2" align="right">2.2 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Process Oil</entry><entry namest="col2" nameend="col2" align="right">4.4 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Ketimine from Jeffamine D-400 and Methylisobutyl ketone</entry><entry namest="col2" nameend="col2" align="right">10.5 parts</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Ketiminosiloxane prepared as set forth above</entry><entry namest="col2" nameend="col2" align="right">0.2 parts</entry></row></tbody></tgroup></table></tables>

0042Samples prepared according to the above formulation were cured according to the procedure given in Example 1. Physical properties and the adhesion data for the cured samples are given in Table I. Data in Table I clearly shows that addition of a small amount of ketiminosiloxane improved the adhesion without signifi­cantly effecting physical properties.

EXAMPLE 4

0043A prepolymer described in Example 1 was formu­lated according to the following recipe. <tables id="tabl0004" num="0004"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Blocked isocyanate-based prepolymer</entry><entry namest="col2" nameend="col2" align="right">100 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Thixcin R</entry><entry namest="col2" nameend="col2" align="right">15 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Benzoflex</entry><entry namest="col2" nameend="col2" align="right">26 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Calcium carbonate</entry><entry namest="col2" nameend="col2" align="right">60 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Paraffin wax</entry><entry namest="col2" nameend="col2" align="right">2.2 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Process Oil</entry><entry namest="col2" nameend="col2" align="right">4.4 parts</entry></row><row><entry namest="col1" nameend="col1" align="left">Ketimine from Jeffamine D-400 and Methylisobutyl ketone</entry><entry namest="col2" nameend="col2" align="right">10.5 parts</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Isocyanatopropyltrimethoxysilane</entry><entry namest="col2" nameend="col2" align="right">0.3 parts</entry></row></tbody></tgroup></table></tables>

0044Samples prepared from the above formulation were cured according to the procedure given in Example 1. Physical properties and the adhesion data for the cured samples is given in Table I. Data in Table I clearly shows that addition of a small amount of isocyanato­silanes improves both adhesion as well as physical pro­perties of the cured sample. <tables id="tabl0005" num="0005"><table frame="all"><title>TABLE I</title><tgroup cols="5" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="31.50mm" /><colspec colnum="2" colname="col2" colwidth="31.50mm" /><colspec colnum="3" colname="col3" colwidth="31.50mm" /><colspec colnum="4" colname="col4" colwidth="31.50mm" /><colspec colnum="5" colname="col5" colwidth="31.50mm" /><thead valign="top"><row rowsep="1"><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" align="center">Example 1 (Control)</entry><entry namest="col3" nameend="col3" align="center">Example 2 (Epoxysilane)</entry><entry namest="col4" nameend="col4" align="center">Example 3 (Ketiminosilane)</entry><entry namest="col5" nameend="col5" align="center">Example 4 (Isocyanatosilane)</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Elongation %</entry><entry namest="col2" nameend="col2" align="right">983</entry><entry namest="col3" nameend="col3" align="right">975</entry><entry namest="col4" nameend="col4" align="right">887</entry><entry namest="col5" nameend="col5" align="right">1350</entry></row><row><entry namest="col1" nameend="col1" align="left">100% Modulus, psi</entry><entry namest="col2" nameend="col2" align="right">68</entry><entry namest="col3" nameend="col3" align="right">67</entry><entry namest="col4" nameend="col4" align="right">87</entry><entry namest="col5" nameend="col5" align="right">66</entry></row><row><entry namest="col1" nameend="col1" align="left">Tensile strength, psi</entry><entry namest="col2" nameend="col2" align="right">196</entry><entry namest="col3" nameend="col3" align="right">160</entry><entry namest="col4" nameend="col4" align="right">258</entry><entry namest="col5" nameend="col5" align="right">268</entry></row><row><entry namest="col1" nameend="col1" align="left">Dry Adhesion Glass</entry><entry namest="col2" nameend="col2" align="right">100% AD</entry><entry namest="col3" nameend="col3" align="right">100% COH</entry><entry namest="col4" nameend="col4" align="right">100% COH</entry><entry namest="col5" nameend="col5" align="right">100% COH</entry></row><row><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" align="right">10.1 pli</entry><entry namest="col3" nameend="col3" align="right">57.4 pli</entry><entry namest="col4" nameend="col4" align="right">50.0 pli</entry><entry namest="col5" nameend="col5" align="right">49.2 pli</entry></row><row><entry namest="col1" nameend="col1" align="left">Anodized Aluminum</entry><entry namest="col2" nameend="col2" align="right">100% ADH</entry><entry namest="col3" nameend="col3" align="right">100% COH</entry><entry namest="col4" nameend="col4" align="right">100% ADH</entry><entry namest="col5" nameend="col5" align="right">100% ADH</entry></row><row><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" align="right">5.6 pli</entry><entry namest="col3" nameend="col3" align="right">49.7 pli</entry><entry namest="col4" nameend="col4" align="right">40.2 pli</entry><entry namest="col5" nameend="col5" align="right">45.0 pli</entry></row><row><entry namest="col1" nameend="col1" align="left">Milled Aluminum</entry><entry namest="col2" nameend="col2" align="right">100% ADH</entry><entry namest="col3" nameend="col3" align="right">100% ADH</entry><entry namest="col4" nameend="col4" align="right">100% ADH</entry><entry namest="col5" nameend="col5" align="right">100% ADH</entry></row><row><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" align="right">2.3 pli</entry><entry namest="col3" nameend="col3" align="right">9.6 pli</entry><entry namest="col4" nameend="col4" align="right">8.2 pli</entry><entry namest="col5" nameend="col5" align="right">7.6 pli</entry></row></tbody></tgroup><tgroup cols="5" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="31.50mm" /><colspec colnum="2" colname="col2" colwidth="31.50mm" /><colspec colnum="3" colname="col3" colwidth="31.50mm" /><colspec colnum="4" colname="col4" colwidth="31.50mm" /><colspec colnum="5" colname="col5" colwidth="31.50mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" align="left">Notes:</entry><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" /><entry namest="col4" nameend="col4" /><entry namest="col5" nameend="col5" /></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col5" align="justify">COH represents cohesive nature of sealant failure</entry></row><row><entry namest="col1" nameend="col5" align="justify">ADH represents adhesive nature of sealant failure</entry></row><row><entry namest="col1" nameend="col5" align="justify">pli represents pounds per linear inch</entry></row><row rowsep="1"><entry namest="col1" nameend="col5" align="justify">psi represents pounds per square inch</entry></row></tbody></tgroup></table></tables>

EXAMPLE 5

0045A blocked isocyanate-based prepolymer was prepared using 3000 grams of polyol consisting of a copolymer of propyleneoxide with ethyleneoxide, 150 grams toluene, 259.8 grams of an 80/20 weight percent mixture of 2,4-tolylenediisocyanate and 2,6-tolydiisocyanate, and 344 grams of nonlyphenol according to a procedure similar to the one described in Example 1.

0046A prepolymer so prepared was formulated accord­ing to formulation given in Table II. <tables id="tabl0006" num="0006"><img file="EP0343523A2_D0005.tif" /></tables><tables id="tabl0007" num="0007"><img file="EP0343523A2_D0006.tif" /></tables>

0047Data in Examples 2 through 5 clearly shows that the mechanical properties are not effected sig­nificantly when the epoxysilane level was varied from 0.2 parts to 0.7 parts per 100 grams of the polymer. This data further shows that adequate adhesion is obtained with 0.4 or more parts of the epoxysilane per 100 grams of prepolymer.

EXAMPLE 6

0048A blocked isocyanate terminated polymer was formed according to the following procedure.

0049About 181.9 pounds of a polyol consisting of a copolymer of propyleneoxide with ethyleneoxide with an hydroxyl number of 26.7 was admixed with 18.75 pounds of toluene. To this mixture, 15.82 pounds of an 80/20 weight percent mixture of 2,4-tolylene diisocyanate and 2,6-tolylene diisocyanate were added at room temperature. The resulting mixture was heated to 85^oC and held at that temperature for two hours. Nonylphenol in an amount of 20.9 pounds was then added to the mixture and the mixture was maintained for one hour at 85^oC. About 6.2 grams of stannous octoate were added to the mixture and the mix­ture was maintained for two hours and fifteen minutes. The resulting reaction product was a blocked isocyanate terminated prepolymer. This prepolymer was used in Examples 6, 7, and 8. Recipe and the sealant evaluation is given in Table III. <tables id="tabl0008" num="0008"><table frame="all"><title>TABLE III</title><tgroup cols="4" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="39.37mm" /><colspec colnum="2" colname="col2" colwidth="39.37mm" /><colspec colnum="3" colname="col3" colwidth="39.37mm" /><colspec colnum="4" colname="col4" colwidth="39.37mm" /><thead valign="top"><row rowsep="1"><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" align="center">EXAMPLE 6</entry><entry namest="col3" nameend="col3" align="center">EXAMPLE 7</entry><entry namest="col4" nameend="col4" align="center">EXAMPLE 8</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Polymer</entry><entry namest="col2" nameend="col2" align="char" char=".">200</entry><entry namest="col3" nameend="col3" align="char" char=".">200</entry><entry namest="col4" nameend="col4" align="char" char=".">200</entry></row><row><entry namest="col1" nameend="col1" align="left">Thixcin R</entry><entry namest="col2" nameend="col2" align="char" char=".">30</entry><entry namest="col3" nameend="col3" align="char" char=".">30</entry><entry namest="col4" nameend="col4" align="char" char=".">30</entry></row><row><entry namest="col1" nameend="col1" align="left">Benzoflex 9-88</entry><entry namest="col2" nameend="col2" align="char" char=".">52</entry><entry namest="col3" nameend="col3" align="char" char=".">52</entry><entry namest="col4" nameend="col4" align="char" char=".">52</entry></row><row><entry namest="col1" nameend="col1" align="left">Calcium Carbonate</entry><entry namest="col2" nameend="col2" align="char" char=".">120</entry><entry namest="col3" nameend="col3" align="char" char=".">120</entry><entry namest="col4" nameend="col4" align="char" char=".">120</entry></row><row><entry namest="col1" nameend="col1" align="left">Paraffin Wax</entry><entry namest="col2" nameend="col2" align="char" char=".">4.5</entry><entry namest="col3" nameend="col3" align="char" char=".">4.5</entry><entry namest="col4" nameend="col4" align="char" char=".">4.5</entry></row><row><entry namest="col1" nameend="col1" align="left">Process Oil</entry><entry namest="col2" nameend="col2" align="char" char=".">8.9</entry><entry namest="col3" nameend="col3" align="char" char=".">8.9</entry><entry namest="col4" nameend="col4" align="char" char=".">8.9</entry></row><row><entry namest="col1" nameend="col1" align="left">Ketimine prepared from Jeffamine D-400 and Methylisobutyl ketone</entry><entry namest="col2" nameend="col2" align="char" char=".">17.2</entry><entry namest="col3" nameend="col3" align="char" char=".">17.2</entry><entry namest="col4" nameend="col4" align="char" char=".">17.2</entry></row><row><entry namest="col1" nameend="col1" align="left">Gamma-Aminopropyltrimethoxysilane</entry><entry namest="col2" nameend="col2" align="char" char=".">0.6</entry><entry namest="col3" nameend="col3" align="char" char=".">0.0</entry><entry namest="col4" nameend="col4" align="char" char=".">0.0</entry></row><row><entry namest="col1" nameend="col1" align="left">Ketiminosiloxane (see Example 3)</entry><entry namest="col2" nameend="col2" align="char" char=".">0.0</entry><entry namest="col3" nameend="col3" align="char" char=".">0.6</entry><entry namest="col4" nameend="col4" align="char" char=".">0.0</entry></row><row><entry namest="col1" nameend="col1" align="left">Gamma-Glycidoxypropyltrimethoxysilane</entry><entry namest="col2" nameend="col2" align="char" char=".">0.0</entry><entry namest="col3" nameend="col3" align="char" char=".">0.0</entry><entry namest="col4" nameend="col4" align="char" char=".">0.6</entry></row><row><entry namest="col1" nameend="col1" align="left">Elongation, %</entry><entry namest="col2" nameend="col2" align="char" char=".">700</entry><entry namest="col3" nameend="col3" align="char" char=".">900</entry><entry namest="col4" nameend="col4" align="char" char=".">1100</entry></row><row><entry namest="col1" nameend="col1" align="left">100% Modulus, psi</entry><entry namest="col2" nameend="col2" align="char" char=".">94</entry><entry namest="col3" nameend="col3" align="char" char=".">82</entry><entry namest="col4" nameend="col4" align="char" char=".">75</entry></row><row><entry namest="col1" nameend="col1" align="left">Tensile strength, psi</entry><entry namest="col2" nameend="col2" align="char" char=".">153</entry><entry namest="col3" nameend="col3" align="char" char=".">144</entry><entry namest="col4" nameend="col4" align="char" char=".">121</entry></row></tbody></tgroup><tgroup cols="4" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="39.37mm" /><colspec colnum="2" colname="col2" colwidth="39.37mm" /><colspec colnum="3" colname="col3" colwidth="39.37mm" /><colspec colnum="4" colname="col4" colwidth="39.37mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" align="left">Adhesion (See Note 1)</entry><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" /><entry namest="col4" nameend="col4" /></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Concrete, pli</entry><entry namest="col2" nameend="col2" align="char" char=".">53.1</entry><entry namest="col3" nameend="col3" align="char" char=".">51.2</entry><entry namest="col4" nameend="col4" align="char" char=".">23.8</entry></row><row><entry namest="col1" nameend="col1" align="left">Glass, pli</entry><entry namest="col2" nameend="col2" align="char" char=".">42.3</entry><entry namest="col3" nameend="col3" align="char" char=".">51.5</entry><entry namest="col4" nameend="col4" align="char" char=".">36.1</entry></row><row><entry namest="col1" nameend="col1" align="left">Anodized Aluminum, pli</entry><entry namest="col2" nameend="col2" align="char" char=".">47.7</entry><entry namest="col3" nameend="col3" align="char" char=".">59.5</entry><entry namest="col4" nameend="col4" align="char" char=".">46.6</entry></row><row><entry namest="col1" nameend="col1" align="left">Milled Aluminum, pli</entry><entry namest="col2" nameend="col2" align="char" char=".">42.3</entry><entry namest="col3" nameend="col3" align="char" char=".">41.5</entry><entry namest="col4" nameend="col4" align="char" char=".">44.6</entry></row></tbody></tgroup><tgroup cols="4" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="39.37mm" /><colspec colnum="2" colname="col2" colwidth="39.37mm" /><colspec colnum="3" colname="col3" colwidth="39.37mm" /><colspec colnum="4" colname="col4" colwidth="39.37mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" align="left">Note 1.</entry><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" /><entry namest="col4" nameend="col4" /></row></thead><tbody valign="top"><row rowsep="1"><entry namest="col1" nameend="col4" align="justify">Nature of adhesion was cohesive in all these samples.</entry></row></tbody></tgroup></table></tables>

0050The data in Examples 6, 7 and 8 show the use of three different types of nonreactive silanes produce good adhesion results.

0051While in accordance with the Patent Statutes, the best mode and preferred embodiment has been set forth, the scope of the invention is not limited thereto, but rather by the scope of the attached claims.