Finely divided precipitated silicas with a high structure, process for their preparation and their use

The invention relates to a finely divided silica with a high structure, a process for the preparation of the silica and the use of the silica as a matting agent in lacquer films.

It is known that the matting ability of a silica depends on various factors, such as, for example, the type of silica, the grain size, the refractive index and also the coating system. The particle shape and particle size distribution of the secondary particles and the overall effective specific particle volume are of particular importance.

In addition to high efficiency, expressed in terms of the reduction in the degree of gloss compared to the unmatted lacquer film, matting silicas also have a number of other requirements. For example, the drying behavior of the paint films should not be impaired, the paint system should not thicken excessively, and the scratch resistance of the paint films should not be reduced by the silica introduced. An important point is the suspension behavior of the silica. The tendency of the silica to settle and to form hard soil bodies that are difficult to stir up again can be prevented or at least improved by a number of measures. For example, B. DE-AS 15 92 865 impregnation of silicas during the manufacturing process using wax emulsions.

It is known to use synthetic silicas as matting agents. Compare the pamphlets EP-PS 0 008 613 DE-PS 24 14 478 DE-AS 17 67 332 DE-OS 16 69 123 DE-AS 15 92 865

Numerous processes for the production of synthetic silicas are known (cf. Ferch in Chem.-Ing.-Techn. <u>48</u>, 922-33 (1976). In particular, it is known, for example according to US Pat. No. 4,243,428, to carry out the acid addition in a multistage manner and while keeping passages.

According to DE-PS 24 14 478, airgel-like matting agents can be obtained by structuring pyrogenic silica. For this, pyrogenic silica is moistened with alkaline water, ground and dried. This procedure for the production of matting agents is complex and expensive.

The matting agent according to DE-PS 24 14 478 is an excellent matting agent. It has the disadvantage that it thickens the paints too much. A solvent must therefore be added to work with the spray gun.

The object of the invention is to achieve the greatest possible savings in solvent requirements while maintaining the matting effect.

According to DE-PS 15 92 865, a wax-coated precipitated silica is produced and used as a matting agent.

This matting agent has the disadvantage that the paints produced with it have an undesirable blue haze on dark surfaces.

Another object of the invention is to produce a wax-coated matting agent that does not have a blue haze and has a better matting effect.

The invention relates to a fine-particle precipitated silica with a high structure <tables id="tabl0001" num="0001"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">BET surface (DIN 66132)</entry><entry namest="col2" nameend="col2" align="left">between 150 and 350 m² / g</entry></row><row><entry namest="col1" nameend="col1" align="left">Tamped density (DIN 53194)</entry><entry namest="col2" nameend="col2" align="left">between 60 and 120 g / l</entry></row><row><entry namest="col1" nameend="col1" align="left">DBP number</entry><entry namest="col2" nameend="col2" align="left">between 3.0 and 4.0 ml / g</entry></row><row><entry namest="col1" nameend="col1" align="left">Particle size distribution (measured with a Coulter Counter)</entry><entry namest="col2" nameend="col2" align="left">at least 70% from 1 to 6 µm,</entry></row><row><entry namest="col1" nameend="col1" align="left">that is made by</entry><entry namest="col2" nameend="col2" /></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">(The determination is made according to DE-PS 17 67 332, column 2, lines 30-64.)</entry><entry namest="col2" nameend="col2" /></row></tbody></tgroup></table></tables> that a mixture of water and sodium silicate is heated to a temperature of 70 to 80 ° C. with stirring, concentrated sulfuric acid is added to this template until half of the alkali present is neutralized, the reaction mixture is treated by means of a shear unit and, if appropriate, the temperature is raised at the same time 86 ± 5 ° C increased, after a period of 30 to 120 minutes adds concentrated sulfuric acid at a higher speed, shearing continues until the pH of the resulting silica suspension is 3.0 to 3.5, optionally diluting the silica suspension with water, optionally using a centrifugal pump and a hydrocyclone to remove the coarse fraction, filtering the silica using known filter devices, and filtering the silica filter cake sulfate-free washes, redispersed the silica filter cake with the addition of water using a stirrer to form a suspension with a solids content of 80 ± 10 g / l, optionally adding alkyldimethylbenzylammonium chloride to this suspension, spray-drying the suspension thus obtained and optionally grinding the dried product.

To determine the particle size with the Coulter Counter, approx.0.5g silica in 50 ml isotonic saline (0.5% NaCl and 0.089% Na₄P₂O₇ · 10 sts₂O in distilled water) with a magnetic stirrer and then treated with ultrasound (200 watts) for 1 minute. This suspension is added to 200 ml of isotonic saline and stirred.

A measuring capillary is immersed in the stirred suspension and an electric field is applied to it. When the particles pass through the measuring capillary, the electric field changes depending on the particle size.

Another object of the invention is a method for producing the fine-particle precipitated silica with a high structure <tables id="tabl0002" num="0002"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">BET surface (DIN 66 132)</entry><entry namest="col2" nameend="col2" align="left">from 150 to 350 m² / g</entry></row><row><entry namest="col1" nameend="col1" align="left">Tamped density (DIN 53 194)</entry><entry namest="col2" nameend="col2" align="left">swish 60 and 120 g / l</entry></row><row><entry namest="col1" nameend="col1" align="left">DBP number</entry><entry namest="col2" nameend="col2" align="left">between 3.0 and 4.0 ml / g</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Particle size distribution</entry><entry namest="col2" nameend="col2" align="left">at least 70% from 1 to 6 µm,</entry></row></tbody></tgroup></table></tables> which is characterized in that a mixture of water and sodium silicate is heated to a temperature of 70 to 80 ° C with stirring, concentrated sulfuric acid is metered into this template until half of the alkali present is neutralized, the reaction mixture is treated by means of a shear unit and optionally simultaneously increases the temperature to 86 ± 5 ° C, after a period of 30 to 120 minutes concentrated sulfuric acid at a higher rate, add until the pH of the resulting silica suspension is 3.0 to 3.5, if necessary dilute the silica suspension with water, if necessary remove the coarse fraction using a centrifugal pump and a hydrocyclone, filter the silica using known filter devices, wash the silica filter cake sulfate-free, redispersed the silica filter cake with the addition of water by means of a stirrer to a suspension with a solids content of 80 ± 10 g / l, optionally adding alkyldimethylbenzylammonium chloride to this suspension, spray-drying the suspension thus obtained and optionally grinding the dried product.

The invention is based on the task of producing silica particles with particle diameters in the grain size range from 1 to 6 μm. Particles smaller than 1 µm are ineffective for matting and usually cause undesired thickening of the paints. On the other hand, particles that are too large lead to a disadvantageous roughness of the surface in the finished paints. The task is to set appropriate particle sizes during the precipitation and to preserve them through suitable measures until the finished product. To ensure that all particles find the same growth conditions, the entire water glass is placed. Sulfuric acid is added in two steps. In the first step, the acid addition is measured so that after the end of the first stage of acid addition the silica begins to flocculate. During this growth phase, shear is added in addition to stirring to prevent excessive particle growth. The acid addition remains interrupted until the desired particle spectrum is reached. The remaining alkali content of the water glass is then neutralized in a second stage, while shearing continues. After a weakly acidic pH has been reached, the precipitation is complete.

The silica suspension is worked up in the usual way. There is a possibility that hard and coarse particles are formed by local acidification. These can be removed from the suspension using a hydrocyclone. The suspension is filtered, for example, with a frame filter press in which the filter cake is washed free of sulfate. The washed filter cake is redispersed in water, optionally a cationic surfactant is added and spray-dried. The cationic surfactant causes water to be displaced from the particle surface even in the aqueous phase, as a result of which the shrinkage process occurring during the drying process is largely prevented. In this way, it can be prevented that the particles accumulate to form larger, firm associations during drying. Depending on the desired fineness, the silica obtained can be used in this way or additionally ground. Due to the procedure described, light grinding is sufficient, ie only a small amount of grinding energy has to be used to deagglomerate the particles again.

The precipitated silica according to the invention can be used as a matting agent in paints.

It has the advantage that no additional solvent has to be used.

To improve the settling behavior of the silica products in paints, impregnation with emulsions is carried out in accordance with DE-PS 15 92 865.

Another object of the invention is a precipitated silica coated with an emulsion, which is produced from the precipitated silica according to the invention. The coating can be carried out by a known method according to DE-PS 15 92 865.

In addition to the same physico-chemical characteristics of the uncoated precipitated silica, the coated precipitated silica has a carbon content of 1 to 8% by weight.

In one embodiment of the invention, the precipitated silica can be coated using a silicone oil emulsion.

This precipitated silica can be used as a matting agent in paints.

In a special embodiment of the invention, the precipitated silica can have been coated by means of a polyethylene wax emulsion.

This precipitated silica can be used as a matting agent in paints.

It is particularly advantageous that the precipitated silicas coated with the wax emulsion do not produce a blue haze in the lacquer surfaces.

Examples

The process according to the invention is carried out in known apparatus.

The heart of the precipitation apparatus is a hard rubberized double jacket with a volume of 120 l, which is equipped with an agitator. For example, anchor stirrers, bar stirrers or turbines are suitable as stirrers. The reaction vessel can be heated and thermostatted via the double jacket with oil as the heat transfer medium. At the bottom of the reaction vessel, a drain pipe is attached, which has a branch in front of the bottom outlet valve. This branch leads to a shear unit (Dispax reactor) with which the contents of the reaction vessel can be circulated. The recirculated precipitation suspension is reintroduced into the top of the reaction vessel through the pipeline attached to the pressure side of the shaving unit. Water glass is added either via a dosing pump from a storage vessel or directly from a barrel using a barrel pump. The sulfuric acid is dosed from a storage vessel using a dosing pump.

For the filtration, the precipitation suspension is pumped with the help of a positive displacement pump into a frame filter press, on which the filter cake formed is washed with sulfate-free water.

The washed filter cake is either placed on trays and dried in a drying cabinet or dispersed in water and spray dried.

The dried silica can then be ground. The product dried in the drying cabinet usually has to be pre-ground using a toothed disc mill before the fine grinding is carried out using a pin or air jet mill. The spray-dried product can either be used directly or subjected to fine grinding.

The effectiveness of the uncoated precipitated silicas produced according to Examples 1-6 is compared in a black stoving lacquer with the product produced according to DE-PS 24 14 478. In addition to the solvent requirement, the gloss level according to Lange at a reflection angle of 60 ° and the grindometer value according to Hegman are assessed.

The gloss meter according to B. Lange, widely used in Germany, is used to determine the degree of gloss, which is a measure of the matting power of the tested matting silica. The Lange gloss meter uses a 45 ° angle of incidence and reflection. The measured gloss levels are given in percent. The smaller its value, the better the matting ability of the tested silica or, in other words, the less matting agent has to be used in order to achieve a specific degree of gloss.

The grindometer value is determined using a grindometer. The grindometer value, which is measured in µ, is a measure of the coarsest particles that are in the finished, sprayable paint mixture after the matting silica has been stirred in. It can be related to the formation of specks in the dry paint film. With the help of the grindometer, the dreaded, unwanted "spray grain" can be recognized.

The paint used has the following composition:<dl id="dl0001" compact="compact"><dt>7.5 parts by weight</dt><dd>Varnish pre-paste Tack® 1</dd><dt>47 Wt.</dt><dd>fatty acid modified alkyd resin 60% in xylene (Alftalt AR 481 m)</dd><dt>24th Parts by weight</dt><dd>Maprenal MF 800 55% melamine resin in isobutanol</dd><dt>6 Wt.</dt><dd>Butanol</dd><dt>4th Parts by weight</dt><dd>Ethyl glycol</dd><dt>10.5 parts by weight</dt><dd>Xylene</dd><dt>1 Wt.</dt><dd>Silicone oil Baysilon paint additive OL 17 1% in xylene</dd></dl>

2.6 parts by weight are incorporated. Product. The incorporation takes place by stirring for 10 minutes with a paddle stirrer at 2000 rpm. The paint is sprayed onto sheets in a dry layer of approx. 30 µm, air dried and baked at 180 ° C for 30 min.

The values ​​determined can be found in Table 2.

example 1

66 kg water and 21 kg soda water glass (d = 1.35 g / cm³; SiO module₂, : N / A₂O = 3.3) and the mixture was heated to 75 ° C. with stirring. Concentrated sulfuric acid (d = 1.83) is metered into this precipitation template at a rate of 1.45 l / h in 30 minutes. After 25 minutes of precipitation, the shaving unit (Dispax reactor) is switched on. Shortly after the end of the acid addition, silica begins to flocculate and the temperature of the precipitation is raised to 85 ° C. The acid supply remains interrupted for 20 minutes (waiting stage). After 50 minutes, the further acid is added at 1.81 l / h over a period of 15 minutes. The resulting silica suspension then has a pH of 3.4. The shaving unit is switched off.

The suspension is diluted with 28 l of water and applied to a hydrocyclone by means of a centrifugal pump with an inlet pressure of 4.5 bar. The ratio of coarse to fine suspension is 1:12.

The fine material suspension is passed through a frame filter press and washed free of sulfate.

The washed filter cake is redispersed with an Ultra-Turrax with the addition of water so that a suspension of 80 g / l is formed. An alkyldimethylbenzylammonium chloride (BARQUAT®) is added to the suspension so that 0.8 g / l of active ingredient are present in the suspension.

This suspension runs through a sieve with a mesh size of 120 µm, whereby coarse foreign particles are retained. Immediately afterwards the suspension is spray dried. The atomization takes place using a two-substance nozzle.

The dried product has the following physicochemical properties: <tables id="tabl0003" num="0003"><table frame="all"><tgroup cols="3" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><tbody valign="top"><row><entry namest="col1" nameend="col2" align="left">pH value (DIN 53200)</entry><entry namest="col3" nameend="col3" align="char" char=",">6,0</entry></row><row><entry namest="col1" nameend="col2" align="left">Water content (DIN</entry><entry namest="col3" nameend="col3" align="char" char=",">4,8 %</entry></row><row><entry namest="col1" nameend="col2" align="left">specific surface (DIN 66132)</entry><entry namest="col3" nameend="col3" align="char" char=",">272 m² / g</entry></row><row><entry namest="col1" nameend="col2" align="left">DBP intake (ml / g)</entry><entry namest="col3" nameend="col3" align="char" char=",">3,7</entry></row><row><entry namest="col1" nameend="col2" align="left">Tamped density (DIN 53194)</entry><entry namest="col3" nameend="col3" align="char" char=",">87 g / l</entry></row><row><entry namest="col1" nameend="col1" morerows="2" rowsep="1" align="left">Grain size distribution (Coulter counter)</entry><entry namest="col2" nameend="col2" align="right">&lt;1 µm</entry><entry namest="col3" nameend="col3" align="char" char=",">5 %</entry></row><row><entry namest="col2" nameend="col2" align="right">1 - 6 µm</entry><entry namest="col3" nameend="col3" align="char" char=",">84 %</entry></row><row rowsep="1"><entry namest="col2" nameend="col2" align="right">&gt; 6 µm</entry><entry namest="col3" nameend="col3" align="char" char=",">11 %</entry></row></tbody></tgroup></table></tables>

Example 2-5

Precipitated silicas are produced as described in Example 1, with the only difference that the duration of the interruption of the acid addition (= waiting stage) is varied.

The physico-chemical data of the products obtained are listed in Table 1

Example 6

A precipitated silica is produced as described in Example 1. In contrast to Example 1, heating to 85 ° C. is dispensed with during the second phase of acid addition. The waiting time is 30 minutes.

The physico-chemical data of the precipitated silica obtained are listed in Table 1.

Example 7 (coating with silicone oil emulsion)

A precipitated silica, as described in Example 1, is produced. In contrast to example 1, the waiting time is 60 minutes. After the end of the precipitation, 3.4 kg of an emulsion of silicone oil are added to the precipitated silica suspension.

The emulsion is made as follows: 0.24 parts by weight of Emulan AF are dissolved in 80 parts by weight of water. 20 parts by weight of Baysilon-Oil® AC 3031 are added while dispersing with an Ultra-Turrax.

The precipitation silica suspension is worked up as described in Example 1. The spray-dried precipitated silica is then ground in an air jet mill.

The physicochemical data are listed in Table 3.

Example 8 (coating with polyethylene wax emulsion)

The precipitated silica is produced as described in Example 1. The waiting time is 90 minutes. 45 l of the fine material suspension obtained are mixed with 625 g of a wax emulsion with stirring. The wax emulsion is produced in an autoclave which can be heated with steam and equipped with a disperser. In this, 4.8 parts by weight of an alkyl polyglycol ether (Marlowet® GFW) are first dissolved in 81.0 parts by weight of water at 100 ° C. at 100 ° C. 14.2 parts by weight of low-pressure polyethylene wax are then added and the mixture is heated to 130.degree. When 130 ° C is reached, the disperser is switched on and dispersed for 30 minutes. During this time the temperature is kept between 130 ° C and 140 ° C. After switching off the disperser and cooling to around 110 ° C, the finished emulsion is drained.

The polyethylene wax used is characterized by the following key figures: <tables id="tabl0004" num="0004"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">average molecular weight</entry><entry namest="col2" nameend="col2" align="left">1000</entry></row><row><entry namest="col1" nameend="col1" align="left">Freezing point</entry><entry namest="col2" nameend="col2" align="left">100 - 104 ° C</entry></row><row><entry namest="col1" nameend="col1" align="left">Dropping point</entry><entry namest="col2" nameend="col2" align="left">110 - 117 ° C</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Density (g / cm³)</entry><entry namest="col2" nameend="col2" align="left">0,93</entry></row></tbody></tgroup></table></tables>

The precipitation silica suspension is worked up as described in Example 1. The spray-dried precipitated silica is then ground in an air jet mill. The physicochemical data are listed in Table 3.

Example 9 (coating with polyethylene wax emulsion)

The precipitated silica is produced as described in Example 1. The waiting time is 90 minutes. 45 l of the fines suspension obtained are mixed with 860 g of a wax emulsion with stirring. The wax emulsion is produced in an autoclave which can be heated with steam and equipped with a disperser. In this, 4.8 parts by weight of an alkyl polyglycol ether (Marlowet® GFW) are first dissolved in 81.0 parts by weight of water at 100 ° C. at 100 ° C. 14.2 parts by weight of low-pressure polyethylene wax are then added and the mixture is heated to 130.degree. When 130 ° C is reached, the disperser is switched on and dispersed for 30 minutes. During this time the temperature is kept between 130 ° C and 140 ° C. After switching off the disperser and cooling to around 110 ° C, the finished emulsion is drained.

The polyethylene wax used is characterized by the following key figures: <tables id="tabl0005" num="0005"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">average molecular weight</entry><entry namest="col2" nameend="col2" align="left">2700</entry></row><row><entry namest="col1" nameend="col1" align="left">Freezing point</entry><entry namest="col2" nameend="col2" align="left">92 - 96 ° C</entry></row><row><entry namest="col1" nameend="col1" align="left">Dropping point</entry><entry namest="col2" nameend="col2" align="left">102 - 110 ° C</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Density (g / cm³)</entry><entry namest="col2" nameend="col2" align="left">0,92</entry></row></tbody></tgroup></table></tables>

The precipitation silica suspension is worked up as described in Example 1. The spray-dried precipitated silica is then ground in an air jet mill. The physico-chemical data are listed in Table 3.

Example 10

The application properties of the precipitated silicas obtained according to Examples 7, 8 and 9 are compared in three test lacquer formulations with a matting agent prepared according to DE-PS 15 92 865. The data are summarized in Table 4.

The degree of gloss is determined using gloss meters according to Lange or Gardner (ASTM D 523-53 T). According to Lange, the angles of incidence and reflection are 45 °, according to Gardner 60 ° and 85 °. The grindometer value is determined according to ISO 1524 in the black stove enamel.

The test lacquer formulations and the procedure are described below.

A) Black stove enamel

<tables id="tabl0006" num="0006"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><thead valign="top"><row rowsep="1"><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" align="center">Parts by weight</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Varnish pre-paste TACK® 1</entry><entry namest="col2" nameend="col2" align="char" char=",">7,5</entry></row><row><entry namest="col1" nameend="col1" align="left">Alkydal® R 40/60% in xylene</entry><entry namest="col2" nameend="col2" align="char" char=",">47,0</entry></row><row><entry namest="col1" nameend="col1" align="left">Maprenal® MF 800/55% in isobutanol</entry><entry namest="col2" nameend="col2" align="char" char=",">24,0</entry></row><row><entry namest="col1" nameend="col1" align="left">Butanol</entry><entry namest="col2" nameend="col2" align="char" char=",">5,0</entry></row><row><entry namest="col1" nameend="col1" align="left">Ethyl glycol</entry><entry namest="col2" nameend="col2" align="char" char=",">3,0</entry></row><row><entry namest="col1" nameend="col1" align="left">Xylene</entry><entry namest="col2" nameend="col2" align="char" char=",">8,5</entry></row><row><entry namest="col1" nameend="col1" align="left">Butyl glycol</entry><entry namest="col2" nameend="col2" align="char" char=",">3,0</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Baysilon® oil OL 17 1% in xylene</entry><entry namest="col2" nameend="col2" align="char" char=",">2,0</entry></row></tbody></tgroup></table></tables>

5 g of precipitated silica or matting agent are stirred into 100 g of lacquer with a paddle stirrer at 2000 rpm for 8 minutes. The viscosity of the mixture is adjusted with xylene to an outflow time of 20 seconds (Ford cup, DIN 4 mm nozzle).

The paint is sprayed onto sheet metal in a dry layer of approx. 30 µm, air dried and 30 min. Baked at 180 ° C.

B) polyester lacquer (UP lacquer)

<tables id="tabl0007" num="0007"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><thead valign="top"><row rowsep="1"><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" align="center">Parts by weight</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Roskydal® 500 A</entry><entry namest="col2" nameend="col2" align="char" char=",">36,0</entry></row><row><entry namest="col1" nameend="col1" align="left">Roskydal® tix 18</entry><entry namest="col2" nameend="col2" align="char" char=",">4,0</entry></row><row><entry namest="col1" nameend="col1" align="left">Tert.-butyl catechol 1% in monostyrene</entry><entry namest="col2" nameend="col2" align="char" char=",">0,5</entry></row><row><entry namest="col1" nameend="col1" align="left">Aerosil® 200</entry><entry namest="col2" nameend="col2" align="char" char=",">0,3</entry></row><row><entry namest="col1" nameend="col1" align="left">Barite, ground</entry><entry namest="col2" nameend="col2" align="char" char=",">20,0</entry></row><row><entry namest="col1" nameend="col1" align="left">Bayertitan R-FD-1</entry><entry namest="col2" nameend="col2" align="char" char=",">10,5</entry></row><row><entry namest="col1" nameend="col1" align="left">Pigment green 6001</entry><entry namest="col2" nameend="col2" align="char" char=",">1,5</entry></row><row><entry namest="col1" nameend="col1" align="left">Baysilon® oil OL 17 1% in toluene</entry><entry namest="col2" nameend="col2" align="char" char=",">2,0</entry></row><row><entry namest="col1" nameend="col1" align="left">Ethyl acetate</entry><entry namest="col2" nameend="col2" align="char" char=",">6,0</entry></row><row><entry namest="col1" nameend="col1" align="left">Monostyrene</entry><entry namest="col2" nameend="col2" align="char" char=",">18,4</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Octa-Soligen-Cobalt in Toluene (2.2% Co)</entry><entry namest="col2" nameend="col2" align="char" char=",">0,8</entry></row></tbody></tgroup></table></tables>

6.5 g of precipitated silica or matting agent are introduced into 100 g of this lacquer mixture before processing and dispersed for 8 minutes at 2000 rpm using a paddle stirrer. The viscosity of the mixture is adjusted to an outlet time of 20 seconds (Ford cup, DIN 4 mm nozzle) with ethyl acetate. The paint mixture is applied in layers of approx. 80 µm.

C) DD varnish

<tables id="tabl0008" num="0008"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><thead valign="top"><row rowsep="1"><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" align="center">Parts by weight</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Desmophen® 800</entry><entry namest="col2" nameend="col2" align="char" char=",">10,0</entry></row><row><entry namest="col1" nameend="col1" align="left">Desmophen® 1700</entry><entry namest="col2" nameend="col2" align="char" char=",">20,0</entry></row><row><entry namest="col1" nameend="col1" align="left">NC chips E 730</entry><entry namest="col2" nameend="col2" align="char" char=",">4,0</entry></row><row><entry namest="col1" nameend="col1" align="left">98% butyl acetate</entry><entry namest="col2" nameend="col2" align="char" char=",">18,0</entry></row><row><entry namest="col1" nameend="col1" align="left">Ethyl glycol acetate</entry><entry namest="col2" nameend="col2" align="char" char=",">22,8</entry></row><row><entry namest="col1" nameend="col1" align="left">Butoxyl</entry><entry namest="col2" nameend="col2" align="char" char=",">5,0</entry></row><row><entry namest="col1" nameend="col1" align="left">Shellsol® A</entry><entry namest="col2" nameend="col2" align="char" char=",">20,0</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Baysilon oil OL 17 10% in xylene</entry><entry namest="col2" nameend="col2" align="char" char=",">0,2</entry></row></tbody></tgroup></table></tables>

10.8 g of matting agent and 36 g of Desmodur® L / 75% in ethyl acetate are added to 100 g of the above mixture and dispersed for 8 minutes at 2000 rpm using a paddle stirrer. The mixture is adjusted to an outlet time of 18 seconds with ethyl acetate (DIN cup, 4 mm nozzle according to DIN 53211). The application takes place in layers of 30 - 40 µm.

As can be seen from Table 4, a significant improvement in the matting effect can be found in all test lacquer formulations compared to the prior art.<tables id="tabl0009" num="0009"><img file="EP0341383B2_D0001.tif" /></tables><tables id="tabl0010" num="0010"><table frame="all"><title>Table 2</title><tgroup cols="5" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="31.50mm" /><colspec colnum="2" colname="col2" colwidth="31.50mm" /><colspec colnum="3" colname="col3" colwidth="31.50mm" /><colspec colnum="4" colname="col4" colwidth="31.50mm" /><colspec colnum="5" colname="col5" colwidth="31.50mm" /><thead valign="top"><row rowsep="1"><entry namest="col1" nameend="col1" align="left">product</entry><entry namest="col2" nameend="col2" align="center">Viscosity DIN 4 mm sec.</entry><entry namest="col3" nameend="col3" align="center">Wt. Solvents on processing consistency</entry><entry namest="col4" nameend="col4" align="center">Grindometer value in µm</entry><entry namest="col5" nameend="col5" align="center">% Gloss 60 ° long</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">from example 1</entry><entry namest="col2" nameend="col2" align="right">33</entry><entry namest="col3" nameend="col3" align="left">1,5</entry><entry namest="col4" nameend="col4" align="right">50</entry><entry namest="col5" nameend="col5" align="char" char=",">38,5</entry></row><row><entry namest="col1" nameend="col1" align="left">from example 2</entry><entry namest="col2" nameend="col2" align="right">33</entry><entry namest="col3" nameend="col3" align="left">1,5</entry><entry namest="col4" nameend="col4" align="right">37</entry><entry namest="col5" nameend="col5" align="char" char=",">40,5</entry></row><row><entry namest="col1" nameend="col1" align="left">from example 3</entry><entry namest="col2" nameend="col2" align="right">32</entry><entry namest="col3" nameend="col3" align="left">-</entry><entry namest="col4" nameend="col4" align="right">28</entry><entry namest="col5" nameend="col5" align="char" char=",">42,5</entry></row><row><entry namest="col1" nameend="col1" align="left">from example 4</entry><entry namest="col2" nameend="col2" align="right">38</entry><entry namest="col3" nameend="col3" align="left">4,5</entry><entry namest="col4" nameend="col4" align="right">30</entry><entry namest="col5" nameend="col5" align="char" char=",">38,5</entry></row><row><entry namest="col1" nameend="col1" align="left">from example 5</entry><entry namest="col2" nameend="col2" align="right">31</entry><entry namest="col3" nameend="col3" align="left">-</entry><entry namest="col4" nameend="col4" align="right">28</entry><entry namest="col5" nameend="col5" align="char" char=",">47,0</entry></row><row><entry namest="col1" nameend="col1" align="left">from example 6</entry><entry namest="col2" nameend="col2" align="right">33</entry><entry namest="col3" nameend="col3" align="left">-</entry><entry namest="col4" nameend="col4" align="right">47</entry><entry namest="col5" nameend="col5" align="char" char=",">38,0</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Comparative product according to DS-PS 24 14 478</entry><entry namest="col2" nameend="col2" align="right">39</entry><entry namest="col3" nameend="col3" align="left">5,5</entry><entry namest="col4" nameend="col4" align="right">40</entry><entry namest="col5" nameend="col5" align="char" char=",">38,5</entry></row></tbody></tgroup></table></tables><tables id="tabl0011" num="0011"><table frame="all"><title>Table 3</title><tgroup cols="7" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="22.50mm" /><colspec colnum="2" colname="col2" colwidth="22.50mm" /><colspec colnum="3" colname="col3" colwidth="22.50mm" /><colspec colnum="4" colname="col4" colwidth="22.50mm" /><colspec colnum="5" colname="col5" colwidth="22.50mm" /><colspec colnum="6" colname="col6" colwidth="22.50mm" /><colspec colnum="7" colname="col7" colwidth="22.50mm" /><thead valign="top"><row rowsep="1"><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" align="center">pH value DIN 53200</entry><entry namest="col3" nameend="col3" align="center">Water content DIN 55921 (%)</entry><entry namest="col4" nameend="col4" align="center">specific surface DIN 66132 (m² / g)</entry><entry namest="col5" nameend="col5" align="center">DBP intake (ml / g)</entry><entry namest="col6" nameend="col6" align="center">Tamped density DIN 53194 (g / l)</entry><entry namest="col7" nameend="col7" align="center">Carbon content (%)</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">from example 7</entry><entry namest="col2" nameend="col2" align="char" char=",">6,2</entry><entry namest="col3" nameend="col3" align="char" char=",">4,7</entry><entry namest="col4" nameend="col4" align="right">205</entry><entry namest="col5" nameend="col5" align="char" char=",">3,7</entry><entry namest="col6" nameend="col6" align="right">64</entry><entry namest="col7" nameend="col7" align="char" char=",">1,7</entry></row><row><entry namest="col1" nameend="col1" align="left">from example 8</entry><entry namest="col2" nameend="col2" align="char" char=",">6,7</entry><entry namest="col3" nameend="col3" align="char" char=",">4,9</entry><entry namest="col4" nameend="col4" align="right">213</entry><entry namest="col5" nameend="col5" align="char" char=",">3,5</entry><entry namest="col6" nameend="col6" align="right">83</entry><entry namest="col7" nameend="col7" align="char" char=",">3,5</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">from example 9</entry><entry namest="col2" nameend="col2" align="char" char=",">6,7</entry><entry namest="col3" nameend="col3" align="char" char=",">4,9</entry><entry namest="col4" nameend="col4" align="right">203</entry><entry namest="col5" nameend="col5" align="char" char=",">3,6</entry><entry namest="col6" nameend="col6" align="right">79</entry><entry namest="col7" nameend="col7" align="char" char=",">4,0</entry></row></tbody></tgroup></table></tables><tables id="tabl0012" num="0012"><img file="EP0341383B2_D0002.tif" /></tables>

The trade names used in the examples gave the following meanings:

Varnish pre-paste Tack® 1

<tables id="tabl0013" num="0013"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><thead valign="top"><row rowsep="1"><entry namest="col1" nameend="col1" align="left">product</entry><entry namest="col2" nameend="col2" align="left">Composition (% by weight)</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" morerows="2" rowsep="1" align="left">Soot paste tack 1</entry><entry namest="col2" nameend="col2" align="left">18th Class HCC pigment black</entry></row><row><entry namest="col2" nameend="col2" align="left">36 Soybean oil-based alkyd resin</entry></row><row rowsep="1"><entry namest="col2" nameend="col2" align="left">46 Solvents</entry></row></tbody></tgroup></table></tables>

Alftalat AR 481 m

Characteristics: Short or medium oil, drying alkyd resins. Type of oil: castor oil Areas of application: stove enamels and primers for metal surfaces. Acid-curing paints. Combination nitrocellulose varnishes.<tables id="tabl0014" num="0014"><table frame="all"><tgroup cols="3" colsep="1" rowsep="1"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><thead valign="top"><row><entry namest="col1" nameend="col2" /><entry namest="col3" nameend="col3" rowsep="0" align="center">Alftalat AR 481 m</entry></row><row><entry namest="col1" nameend="col2" align="center">Composition of the 100% resin (approx.)</entry><entry namest="col3" nameend="col3" /></row></thead><tbody valign="top"><row rowsep="0"><entry namest="col1" nameend="col2" align="left">Oil content (triglyceride)</entry><entry namest="col3" nameend="col3" align="left">48 %</entry></row><row><entry namest="col1" nameend="col2" align="left">Phthalic anhydride</entry><entry namest="col3" nameend="col3" align="left">39 %</entry></row></tbody></tgroup><tgroup cols="3" colsep="1" rowsep="1"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><thead valign="top"><row><entry namest="col1" nameend="col2" align="center">viscosity</entry><entry namest="col3" nameend="col3" /></row></thead><tbody valign="top"><row rowsep="0"><entry namest="col1" nameend="col1" align="right">Flow time 4, DIN 53211/29 ° C</entry><entry namest="col2" nameend="col2" align="left">s</entry><entry namest="col3" nameend="col3" align="left">50 - 70²)</entry></row><row><entry namest="col1" nameend="col1" align="right">23 ° C</entry><entry namest="col2" nameend="col2" align="left">s</entry><entry namest="col3" nameend="col3" align="left">40 - 60²)</entry></row></tbody></tgroup><tgroup cols="3" colsep="1" rowsep="1"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><thead valign="top"><row><entry namest="col1" nameend="col2" align="center">Dynamic viscosity</entry><entry namest="col3" nameend="col3" /></row></thead><tbody valign="top"><row rowsep="0"><entry namest="col1" nameend="col1" align="right">DIN 53177/20 ° C</entry><entry namest="col2" nameend="col2" align="left">mPa. s</entry><entry namest="col3" nameend="col3" align="left">215 - 300²)</entry></row><row><entry namest="col1" nameend="col1" align="right">23 ° C</entry><entry namest="col2" nameend="col2" align="left">mPa. s</entry><entry namest="col3" nameend="col3" align="left">175 - 250²)</entry></row></tbody></tgroup><tgroup cols="3" colsep="1" rowsep="1"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><thead valign="top"><row><entry namest="col1" nameend="col2" align="center">Color number</entry><entry namest="col3" nameend="col3" /></row></thead><tbody valign="top"><row rowsep="0"><entry namest="col1" nameend="col1" align="left">Iodine color number DIN 6162</entry><entry namest="col2" nameend="col2" align="left">mg J / 100 cm³</entry><entry namest="col3" nameend="col3" align="left">&lt; 15²)</entry></row><row rowsep="1"><entry namest="col1" nameend="col2" align="left">Gardner Color Standard ASTM D 1544</entry><entry namest="col3" nameend="col3" align="left">&lt; 7²)</entry></row></tbody></tgroup></table></tables><tables id="tabl0015" num="0015"><table frame="all"><tgroup cols="3" colsep="1" rowsep="1"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><thead valign="top"><row><entry namest="col1" nameend="col2" /><entry namest="col3" nameend="col3" align="center">Alftalat AR 481 m</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Acid number DIN 53402</entry><entry namest="col2" nameend="col2" align="left">mg KOH / g solid.</entry><entry namest="col3" nameend="col3" align="left">&lt; 25</entry></row><row><entry namest="col1" nameend="col1" align="left">Density (delivery form) 20 ° C</entry><entry namest="col2" nameend="col2" align="left">g / cm³</entry><entry namest="col3" nameend="col3" align="left">about 1.02</entry></row></tbody></tgroup><tgroup cols="3" colsep="1" rowsep="1"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><thead valign="top"><row><entry namest="col1" nameend="col2" align="center">Non-volatile content</entry><entry namest="col3" nameend="col3" /></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">DIN 53216 (2g + 2cm³ Toluene / 1 h 125 ° C)</entry><entry namest="col2" nameend="col2" align="left">%</entry><entry namest="col3" nameend="col3" align="left">about 60</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Flash point (delivery form) DIN 53213</entry><entry namest="col2" nameend="col2" align="left">° C</entry><entry namest="col3" nameend="col3" align="left">approx. 27</entry></row></tbody></tgroup></table></tables>

Maprenal MF 800

Characteristics: Unplasticized, isobutyl etherified melamine formaldehyde resins. <tables id="tabl0016" num="0016"><table frame="all"><tgroup cols="3" colsep="1" rowsep="1"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><thead valign="top"><row><entry namest="col1" nameend="col2" /><entry namest="col3" nameend="col3" rowsep="0" align="center">Maprenal MF 800</entry></row><row><entry namest="col1" nameend="col2" align="center">Viscosity (delivery form)</entry><entry namest="col3" nameend="col3" /></row></thead><tbody valign="top"><row rowsep="0"><entry namest="col1" nameend="col1" align="right">Flow time 4 DIN 53211/20 ° C</entry><entry namest="col2" nameend="col2" align="left">s</entry><entry namest="col3" nameend="col3" align="left">60 - 90</entry></row><row><entry namest="col1" nameend="col1" align="right">23 ° C</entry><entry namest="col2" nameend="col2" align="left">s</entry><entry namest="col3" nameend="col3" align="left">50 - 80</entry></row></tbody></tgroup><tgroup cols="3" colsep="1" rowsep="1"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><thead valign="top"><row><entry namest="col1" nameend="col2" align="center">Dynamic viscosity</entry><entry namest="col3" nameend="col3" /></row></thead><tbody valign="top"><row rowsep="0"><entry namest="col1" nameend="col1" align="right">DIN 53177/20 ° C</entry><entry namest="col2" nameend="col2" align="left">mPas</entry><entry namest="col3" nameend="col3" align="left">250 - 430</entry></row><row><entry namest="col1" nameend="col1" align="right">23 ° C</entry><entry namest="col2" nameend="col2" align="left">mPas</entry><entry namest="col3" nameend="col3" align="left">220 - 360</entry></row></tbody></tgroup><tgroup cols="3" colsep="1" rowsep="1"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><thead valign="top"><row><entry namest="col1" nameend="col2" align="center">Color number (delivery form)</entry><entry namest="col3" nameend="col3" /></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Iodine color number DIN 6162</entry><entry namest="col2" nameend="col2" align="left">mg J / 100 cm³</entry><entry namest="col3" nameend="col3" align="left">&lt; 1</entry></row><row><entry namest="col1" nameend="col2" align="left">Gardner Color Standard ASTM D 1544</entry><entry namest="col3" nameend="col3" align="left">&lt; 1</entry></row><row><entry namest="col1" nameend="col1" align="left">Acid number DIN 53402</entry><entry namest="col2" nameend="col2" align="left">mg KOH / g solid.</entry><entry namest="col3" nameend="col3" align="left">&lt; 1</entry></row><row><entry namest="col1" nameend="col1" align="left">Density 20 ° C</entry><entry namest="col2" nameend="col2" align="left">g / cm³</entry><entry namest="col3" nameend="col3" align="left">about 0.99</entry></row><row><entry namest="col1" nameend="col1" align="left">Gasoline compatibility (n-heptane) DIN 53 187</entry><entry namest="col2" nameend="col2" align="left">cm³/ 1 g melamine resin (delivery form)</entry><entry namest="col3" nameend="col3" align="left">5 - 10</entry></row></tbody></tgroup><tgroup cols="3" colsep="1" rowsep="1"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><thead valign="top"><row><entry namest="col1" nameend="col2" align="center">Non-volatile content (delivery form)</entry><entry namest="col3" nameend="col3" /></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">DIN 53216 (2g + 2 cm³ Butanol / 1 h 120 ° C)</entry><entry namest="col2" nameend="col2" align="left">%</entry><entry namest="col3" nameend="col3" align="left">approx. 55</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Flash point (delivery form) DIN 53 213</entry><entry namest="col2" nameend="col2" align="left">° C</entry><entry namest="col3" nameend="col3" align="left">approx. 31</entry></row></tbody></tgroup></table></tables>

Baysilone paint additive OL 17

Polyether modified methylpolysiloxane <tables id="tabl0017" num="0017"><table frame="all"><tgroup cols="3" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" morerows="2" align="left">Delivery tolerances:</entry><entry namest="col2" nameend="col2" align="left">Appearance</entry><entry namest="col3" nameend="col3" align="left">clear, yellowish</entry></row><row><entry namest="col2" nameend="col2" align="left">Iodine color number, DIN 6162</entry><entry namest="col3" nameend="col3" align="left">Max. 3rd</entry></row><row><entry namest="col2" nameend="col2" align="left">Viscosity, DIN 53015, 23 ° C</entry><entry namest="col3" nameend="col3" align="left">650-850 mPas</entry></row><row><entry namest="col1" nameend="col1" morerows="3" align="left">Other key data:</entry><entry namest="col2" nameend="col2" align="left">Density, DIN 53217, 20 ° C</entry><entry namest="col3" nameend="col3" align="left">1,025-1,050 <maths id="math0001" num=""><math display="inline"><mrow><mfrac numalign="left" denomalign="left"><mrow><mtext>G</mtext></mrow><mrow><mtext>ml</mtext></mrow></mfrac></mrow></math><img file="EP0341383B2_D0003.tif" /></maths></entry></row><row><entry namest="col2" nameend="col2" align="left">Flash point, DIN 51758</entry><entry namest="col3" nameend="col3" align="left">approx. 80 ° C</entry></row><row><entry namest="col2" nameend="col2" align="left">Surface tension, DIN 53914, 23 ° C with Harkins-Jordan correction</entry><entry namest="col3" nameend="col3" align="left">approx. 21 mN / m</entry></row><row><entry namest="col2" nameend="col2" align="left">Refractive index, 23 ° C</entry><entry namest="col3" nameend="col3" align="left">1,447-1,451</entry></row><row><entry namest="col1" nameend="col1" morerows="8" rowsep="1" align="left">Solubility:</entry><entry namest="col2" nameend="col2" align="left">Gasoline hydrocarbons</entry><entry namest="col3" nameend="col3" align="right">u / l</entry></row><row><entry namest="col2" nameend="col2" align="left">Benzene hydrocarbons</entry><entry namest="col3" nameend="col3" align="right">l</entry></row><row><entry namest="col2" nameend="col2" align="left">Alcohols</entry><entry namest="col3" nameend="col3" align="right">l</entry></row><row><entry namest="col2" nameend="col2" align="left">Esters</entry><entry namest="col3" nameend="col3" align="right">l</entry></row><row><entry namest="col2" nameend="col2" align="left">Ketones</entry><entry namest="col3" nameend="col3" align="right">l</entry></row><row><entry namest="col2" nameend="col2" align="left">Glycol ether</entry><entry namest="col3" nameend="col3" align="right">l</entry></row><row><entry namest="col2" nameend="col2" align="left">Glycol ether acetates</entry><entry namest="col3" nameend="col3" align="right">l</entry></row><row><entry namest="col2" nameend="col2" morerows="1" rowsep="1" align="left">Explanations:</entry><entry namest="col3" nameend="col3" align="left">l = soluble</entry></row><row rowsep="1"><entry namest="col3" nameend="col3" align="left">u = insoluble</entry></row></tbody></tgroup></table></tables>

Baysilon-Oil® AC 3031

Chemical characterization of polysiloxane diol Physical data <tables id="tabl0018" num="0018"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Melting temperature softening temperature</entry><entry namest="col2" nameend="col2" align="left">&lt;- 60 ° C (pour point)</entry></row><row><entry namest="col1" nameend="col1" align="left">Boiling temperature</entry><entry namest="col2" nameend="col2" align="right">from approx. 130 ° C</entry></row><row><entry namest="col1" nameend="col1" align="left">Decomposition temperature</entry><entry namest="col2" nameend="col2" align="right">° C</entry></row><row><entry namest="col1" nameend="col1" align="left">PH value</entry><entry namest="col2" nameend="col2" align="left">approx. 7 - 8 (at 20 g / l water)</entry></row><row><entry namest="col1" nameend="col1" align="left">solubility in water</entry><entry namest="col2" nameend="col2" align="left">insoluble at 20 ° C</entry></row><row><entry namest="col1" nameend="col1" align="left">Odor</entry><entry namest="col2" nameend="col2" align="left">clear smell</entry></row><row><entry namest="col1" nameend="col1" align="left">Condition (20 ° C)</entry><entry namest="col2" nameend="col2" align="left">liquid</entry></row><row><entry namest="col1" nameend="col1" align="left">Vapor pressure (20 ° C)</entry><entry namest="col2" nameend="col2" align="left">&lt;100 mbar</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Density (20 ° C)</entry><entry namest="col2" nameend="col2" align="left">0.98 g / ml</entry></row></tbody></tgroup></table></tables>

Emulan AF

<tables id="tabl0019" num="0019"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Chemical character</entry><entry namest="col2" nameend="col2" align="left">Medium-high ethoxylated fatty alcohol, non-ionic.</entry></row><row><entry namest="col1" nameend="col1" align="left">Solubility (at 25 ° C, 10%)</entry><entry namest="col2" nameend="col2" align="left">In mineral oils, fatty oils, melted paraffins and fats well and mostly also clearly soluble. Clearly soluble in most organic solvents.</entry></row><row><entry namest="col1" nameend="col1" align="left">Chemical character</entry><entry namest="col2" nameend="col2" align="left">Fatty alcohol ethoxylate</entry></row><row><entry namest="col1" nameend="col1" align="left">Consistency (room temperature)</entry><entry namest="col2" nameend="col2" align="left">soft wax-like</entry></row><row><entry namest="col1" nameend="col1" align="left">Acid number (DIN 53402)</entry><entry namest="col2" nameend="col2" align="left">practically 0</entry></row><row><entry namest="col1" nameend="col1" align="left">Saponification number (DIN 53 401)</entry><entry namest="col2" nameend="col2" align="left">practically 0</entry></row><row><entry namest="col1" nameend="col1" align="left">pH value (1% aqueous solution or dispersion)</entry><entry namest="col2" nameend="col2" align="left">6 - 7,5</entry></row><row><entry namest="col1" nameend="col1" align="left">Active substance content</entry><entry namest="col2" nameend="col2" align="left">practical 100%</entry></row><row><entry namest="col1" nameend="col1" align="left">Density (g / cm³) (20 ° C) (DIN 51757)</entry><entry namest="col2" nameend="col2" align="left">approx. 0.91 (50, ° C)</entry></row><row><entry namest="col1" nameend="col1" align="left">Viscosity (mPa.s) (20 ° C) (DIN 53015)</entry><entry namest="col2" nameend="col2" align="left">-</entry></row><row><entry namest="col1" nameend="col1" align="left">Melting point</entry><entry namest="col2" nameend="col2" align="left">approx. 42 ° C</entry></row><row><entry namest="col1" nameend="col1" align="left">Freezing point</entry><entry namest="col2" nameend="col2" align="left">-</entry></row><row><entry namest="col1" nameend="col1" align="left">Dropping point (DGF M-III-3)</entry><entry namest="col2" nameend="col2" align="left">-</entry></row><row><entry namest="col1" nameend="col1" align="left">Flash point (DIN 51758)</entry><entry namest="col2" nameend="col2" align="left">approx. 190 ° C</entry></row><row><entry namest="col1" nameend="col1" align="left">HLB value (WC Griffin)</entry><entry namest="col2" nameend="col2" align="left">approx. 11</entry></row><row><entry namest="col1" nameend="col1" align="left">Main activity tendency (emulsion type)</entry><entry namest="col2" nameend="col2" align="left">Oil in water</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Solubility tendency</entry><entry namest="col2" nameend="col2" align="left">in mineral oil and polar organic media</entry></row></tbody></tgroup></table></tables>

Alkydal R 40

<tables id="tabl0020" num="0020"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><thead valign="top"><row rowsep="1"><entry namest="col1" nameend="col2" align="left">Short oil alkyd resin based on ricin oil.</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Oil content / triglyceride</entry><entry namest="col2" nameend="col2" align="left">approx. 40%</entry></row><row><entry namest="col1" nameend="col1" align="left">Phthalic anhydride</entry><entry namest="col2" nameend="col2" align="left">approx. 38%</entry></row><row><entry namest="col1" nameend="col1" align="left">Density / 20 ° C</entry><entry namest="col2" nameend="col2" align="left">approx.1.13 g / cm³</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">OH content</entry><entry namest="col2" nameend="col2" align="left">2,5 %</entry></row></tbody></tgroup></table></tables><tables id="tabl0021" num="0021"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><thead valign="top"><row rowsep="1"><entry namest="col1" nameend="col2" align="left">Delivery tolerance</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Iodine color number / 50% solution</entry><entry namest="col2" nameend="col2" align="left">Max. 5</entry></row><row><entry namest="col1" nameend="col1" align="left">Acid number / solvent-free</entry><entry namest="col2" nameend="col2" align="left">20 - 30</entry></row><row><entry namest="col1" nameend="col1" align="left">Viscosity / 20 ° C delivery form</entry><entry namest="col2" nameend="col2" align="left">3500-4500 mPa.s (cP)</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Flash point</entry><entry namest="col2" nameend="col2" align="left">approx. 27 ° C</entry></row></tbody></tgroup></table></tables>

Roskydal 500 A.

Unsaturated polyester resin (glossy polyester), reactive, hard curing. <tables id="tabl0022" num="0022"><table frame="all"><tgroup cols="3" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><thead valign="top"><row rowsep="1"><entry namest="col1" nameend="col3" align="left">Delivery tolerance *</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col2" align="left">non-volatile component</entry><entry namest="col3" nameend="col3" align="left">74 - 77 %</entry></row><row><entry namest="col1" nameend="col2" align="left">Hazen color number</entry><entry namest="col3" nameend="col3" align="left">Max. 100</entry></row><row><entry namest="col1" nameend="col2" align="left">Acid number / delivery form</entry><entry namest="col3" nameend="col3" align="left">10 - 20</entry></row><row><entry namest="col1" nameend="col2" align="left">Viscosity / 20 ° C</entry><entry namest="col3" nameend="col3" align="left">2200 ... 2600 mPa.s</entry></row><row><entry namest="col1" nameend="col1" morerows="1" rowsep="1" align="left">Other data:</entry><entry namest="col2" nameend="col2" align="left">Density / 20 ° C</entry><entry namest="col3" nameend="col3" align="left">1.12 g / cm³</entry></row><row rowsep="1"><entry namest="col2" nameend="col2" align="left">Flash point</entry><entry namest="col3" nameend="col3" align="left">approx. 37 ° C</entry></row></tbody></tgroup><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><tbody valign="top"><row><entry namest="col1" nameend="col3" align="justify">* = Test methods according to DIN 58184</entry></row></tbody></tgroup></table></tables>

Roskydal tix 18th

Thixotropic unsaturated polyester resin (paraffin type), reactive. <tables id="tabl0023" num="0023"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><thead valign="top"><row rowsep="1"><entry namest="col1" nameend="col2" align="left">Delivery tolerance *</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">non-volatile component</entry><entry namest="col2" nameend="col2" align="left">49...53 %</entry></row><row><entry namest="col1" nameend="col1" align="left">Iodine color number</entry><entry namest="col2" nameend="col2" align="left">Max. 2nd</entry></row><row><entry namest="col1" nameend="col1" align="left">Acid number / delivery form</entry><entry namest="col2" nameend="col2" align="left">Max. 15</entry></row><row><entry namest="col1" nameend="col1" align="left">Viscosity 20 ° C</entry><entry namest="col2" nameend="col2" align="left">thixotropic flow behavior</entry></row><row><entry namest="col1" nameend="col1" align="left">Density / 20 ° C</entry><entry namest="col2" nameend="col2" align="left">approx. 1.07 g / cm³</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Flash point</entry><entry namest="col2" nameend="col2" align="left">approx. 32 ° C</entry></row></tbody></tgroup><tgroup cols="2" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col2" align="justify">* = Test methods according to DIN 53184</entry></row></tbody></tgroup></table></tables>

<tables id="tabl0024" num="0024"><table frame="all"><tgroup cols="8" colsep="1" rowsep="1"><colspec colnum="1" colname="col1" colwidth="19.68mm" /><colspec colnum="2" colname="col2" colwidth="19.68mm" /><colspec colnum="3" colname="col3" colwidth="19.68mm" /><colspec colnum="4" colname="col4" colwidth="19.68mm" /><colspec colnum="5" colname="col5" colwidth="19.68mm" /><colspec colnum="6" colname="col6" colwidth="19.68mm" /><colspec colnum="7" colname="col7" colwidth="19.68mm" /><colspec colnum="8" colname="col8" colwidth="19.68mm" /><thead valign="top"><row><entry namest="col1" nameend="col8" align="left">Bayertitan R-FD-1</entry></row><row><entry namest="col1" nameend="col1" rowsep="0" align="center">Bavarian Titan</entry><entry namest="col2" nameend="col2" rowsep="0" align="center">% TiO₂</entry><entry namest="col3" nameend="col3" rowsep="0" align="center">Additional ingredients</entry><entry namest="col4" nameend="col4" rowsep="0" align="center">Oil number according to DIN 53 199</entry><entry namest="col5" nameend="col6" align="center">Lightening power</entry><entry namest="col7" nameend="col7" rowsep="0" align="center">Rel. Spreading power according to DIN 53 165</entry><entry namest="col8" nameend="col8" rowsep="0" align="center">Density according to DIN 53193</entry></row><row><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" /><entry namest="col4" nameend="col4" /><entry namest="col5" nameend="col5" align="center">after Reynolds</entry><entry namest="col6" nameend="col6" align="center">according to DIN 53 192</entry><entry namest="col7" nameend="col7" /><entry namest="col8" nameend="col8" /></row></thead><tbody valign="top"><row rowsep="1"><entry namest="col1" nameend="col1" align="left">F-FD-1</entry><entry namest="col2" nameend="col2" align="right">96</entry><entry namest="col3" nameend="col3" align="left">Al₂O₃</entry><entry namest="col4" nameend="col4" align="right">19</entry><entry namest="col5" nameend="col5" align="right">1900</entry><entry namest="col6" nameend="col6" align="right">750</entry><entry namest="col7" nameend="col7" align="right">112</entry><entry namest="col8" nameend="col8" align="char" char=",">4,1</entry></row></tbody></tgroup></table></tables>

Pigment green 6001

<tables id="tabl0025" num="0025"><table frame="all"><tgroup cols="3" colsep="1" rowsep="1"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><thead valign="top"><row><entry namest="col1" nameend="col2" /><entry namest="col3" nameend="col3" align="center">Pigment green 6001</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col2" align="left">Color index no.</entry><entry namest="col3" nameend="col3" align="left">77 335</entry></row><row><entry namest="col1" nameend="col2" align="left">Color index pigment</entry><entry namest="col3" nameend="col3" align="left">19</entry></row><row><entry namest="col1" nameend="col2" align="left">Chemical composition</entry><entry namest="col3" nameend="col3" align="left">Co-Al-Ti-Ni Zn oxide</entry></row><row><entry namest="col1" nameend="col1" align="left">Oil number 1)</entry><entry namest="col2" nameend="col2" align="left">g / 100 g</entry><entry namest="col3" nameend="col3" align="left">20</entry></row><row><entry namest="col1" nameend="col1" align="left">Loss on drying 2)</entry><entry namest="col2" nameend="col2" align="left">%</entry><entry namest="col3" nameend="col3" align="left">Max. 0.5</entry></row><row><entry namest="col1" nameend="col1" align="left">Ramming density 3)</entry><entry namest="col2" nameend="col2" align="left">g / l</entry><entry namest="col3" nameend="col3" align="left">1600</entry></row><row><entry namest="col1" nameend="col1" align="left">Sieve residue 4)</entry><entry namest="col2" nameend="col2" align="left">%</entry><entry namest="col3" nameend="col3" align="left">Max. 0.1</entry></row><row><entry namest="col1" nameend="col2" align="left">Color strength 7)</entry><entry namest="col3" nameend="col3" align="left">-</entry></row><row><entry namest="col1" nameend="col1" align="left">Opacity number 8)</entry><entry namest="col2" nameend="col2" align="left">%</entry><entry namest="col3" nameend="col3" align="left">190</entry></row><row><entry namest="col1" nameend="col1" align="left">Particle size (TEM)</entry><entry namest="col2" nameend="col2" align="left">µm</entry><entry namest="col3" nameend="col3" align="left">0,15-2,0</entry></row><row><entry namest="col1" nameend="col1" align="left">Density 9)</entry><entry namest="col2" nameend="col2" align="left">g / cm³</entry><entry namest="col3" nameend="col3" align="left">5,0</entry></row><row><entry namest="col1" nameend="col1" align="left">Water soluble portion 10)</entry><entry namest="col2" nameend="col2" align="left">%</entry><entry namest="col3" nameend="col3" align="left">Max. 0.5</entry></row><row><entry namest="col1" nameend="col1" align="left">Specific surface 11)</entry><entry namest="col2" nameend="col2" align="left">m²/G</entry><entry namest="col3" nameend="col3" align="left">-</entry></row><row><entry namest="col1" nameend="col2" align="left">pH value 12)</entry><entry namest="col3" nameend="col3" align="left">8,5-9,5</entry></row><row><entry namest="col1" nameend="col1" align="left">Heat resistance</entry><entry namest="col2" nameend="col2" align="left">° C</entry><entry namest="col3" nameend="col3" align="left">&gt; 500</entry></row><row><entry namest="col1" nameend="col2" align="left">Light fastness / full tone 13)</entry><entry namest="col3" nameend="col3" align="left">8</entry></row><row><entry namest="col1" nameend="col2" align="left">TiO₂Mix 1: 1</entry><entry namest="col3" nameend="col3" align="left">8</entry></row><row><entry namest="col1" nameend="col2" align="left">TiO₂Mix 1:10</entry><entry namest="col3" nameend="col3" align="left">8</entry></row><row><entry namest="col1" nameend="col2" align="left">Weather fastness / full tone</entry><entry namest="col3" nameend="col3" align="left">very good</entry></row><row><entry namest="col1" nameend="col2" align="left">Acid resistance</entry><entry namest="col3" nameend="col3" align="left">very good</entry></row><row><entry namest="col1" nameend="col2" align="left">Alkali resistance</entry><entry namest="col3" nameend="col3" align="left">Well</entry></row><row><entry namest="col1" nameend="col2" align="left">Lime fastness</entry><entry namest="col3" nameend="col3" align="left">Well</entry></row><row><entry namest="col1" nameend="col2" align="left">Fastness to solvents</entry><entry namest="col3" nameend="col3" align="left">very good</entry></row><row rowsep="1"><entry namest="col1" nameend="col2" align="left">Fastness to migration</entry><entry namest="col3" nameend="col3" align="left">very good</entry></row></tbody></tgroup><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><tbody valign="top"><row><entry namest="col1" nameend="col3" align="justify">Explanation of footnotes: 1) according to DIN ISO 787 / V, ASTM D 281 or JIS K 5101/9</entry></row><row><entry namest="col1" nameend="col3" align="justify">2) according to DIN ISO 787 / II, ASTM D 280 or JIS K 5101/21. With VOSSEN blue, backweighing takes place immediately after taking the sample out of the drying cabinet when hot.</entry></row><row><entry namest="col1" nameend="col3" align="justify">3) according to DIN ISO 787 / XI or JIS K 5101/18</entry></row><row><entry namest="col1" nameend="col3" align="justify">4) Cd, Co and Ti pigments according to DIN 53 195 (0.045 µm sieve) VOSSEN blue according to DIN ISO 787 / XVIII, (0.040 µ sieve), ASTM D 1514 or JIS K 5101 20</entry></row><row><entry namest="col1" nameend="col3" align="justify">5) according to ISO 787 / I</entry></row><row><entry namest="col1" nameend="col3" align="justify">6) according to ISO 787 / XVI</entry></row><row><entry namest="col1" nameend="col3" align="justify">7) according to DIN 53 204 and DIN 53 234</entry></row><row><entry namest="col1" nameend="col3" align="justify">8) in PVC soft, TiO₂ RN 56 = 100%</entry></row><row><entry namest="col1" nameend="col3" align="justify">9) according to DIN ISO 787 / X or JIS K 5101/17</entry></row><row><entry namest="col1" nameend="col3" align="justify">10) according to DIN ISO 787 / III or JIS K 51010/22</entry></row><row><entry namest="col1" nameend="col3" align="justify">11) according to DIN 66 131</entry></row><row><entry namest="col1" nameend="col3" align="justify">12) according to DIN ISO 787 / IX, ASTM D 1208 or JIS K 5101/24</entry></row><row><entry namest="col1" nameend="col3" align="justify">13) according to DIN 54 003 or JIS K 5101/15</entry></row></tbody></tgroup></table></tables>

Octa-Solingen-Cobalt

Octa-Solingen cobalt is a dry substance which, in addition to 2-n ethylhexanoic acid (C₈H₁₆O₂) Contains 16% Co.

Desmophen 800

Heavily branched, hydroxyl-containing polyester. <tables id="tabl0026" num="0026"><table frame="all"><tgroup cols="3" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><thead valign="top"><row rowsep="1"><entry namest="col1" nameend="col3" align="left">Key figures</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Song form</entry><entry namest="col2" nameend="col2" align="left">100 %</entry><entry namest="col3" nameend="col3" align="left">approx. 85%</entry></row><row><entry namest="col1" nameend="col1" align="left">Hydroxyl content:</entry><entry namest="col2" nameend="col2" align="left">approx.8.8%</entry><entry namest="col3" nameend="col3" align="left">7.5%</entry></row><row><entry namest="col1" nameend="col1" align="left">Acid number:</entry><entry namest="col2" nameend="col2" align="left">&lt; 4</entry><entry namest="col3" nameend="col3" align="left">&lt; 4</entry></row><row><entry namest="col1" nameend="col1" align="left">Color number according to DIN 6162:</entry><entry namest="col2" nameend="col2" align="left">7 - 10 *</entry><entry namest="col3" nameend="col3" align="left">3 - 8 *</entry></row><row><entry namest="col1" nameend="col1" align="left">Flash point according to DIN 51 758:</entry><entry namest="col2" nameend="col2" align="left">&gt; 200 ° C</entry><entry namest="col3" nameend="col3" align="left">-</entry></row><row><entry namest="col1" nameend="col1" align="left">DIN-EN 53</entry><entry namest="col2" nameend="col2" align="left">-</entry><entry namest="col3" nameend="col3" align="left">approx. 49 ° C</entry></row><row><entry namest="col1" nameend="col1" align="left">Density at 20 ° C according to DIN 51 757:</entry><entry namest="col2" nameend="col2" align="left">1.14 g / cm³</entry><entry namest="col3" nameend="col3" align="left">1.11 g / cm³</entry></row><row><entry namest="col1" nameend="col1" morerows="3" align="left">Viscosity (speed gradient D≈150 s^-1) at 20 ° C:</entry><entry namest="col2" nameend="col2" align="left">900 ± 100</entry><entry namest="col3" nameend="col3" align="left">900 ± 100</entry></row><row><entry namest="col2" nameend="col2" align="left">mPas **</entry><entry namest="col3" nameend="col3" align="left">mPas **</entry></row><row><entry namest="col2" nameend="col2" align="left">725 ± 75</entry><entry namest="col3" nameend="col3" align="left">725 ± 75</entry></row><row><entry namest="col2" nameend="col2" align="left">mPas **</entry><entry namest="col3" nameend="col3" align="left">mPas **</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Water content:</entry><entry namest="col2" nameend="col2" align="left">&lt; 0,15 %</entry><entry namest="col3" nameend="col3" align="left">&lt; 0,15 %</entry></row></tbody></tgroup><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><tbody valign="top"><row><entry namest="col1" nameend="col3" align="justify">* 50% in ethyl glycol acetate</entry></row><row><entry namest="col1" nameend="col3" align="justify">** 70% in ethyl glycol acetate</entry></row></tbody></tgroup></table></tables>

Aerosil

<u>R</u>

200

Aerosil^R 200 is a fumed silica with the following physico-chemical characteristics; <tables id="tabl0027" num="0027"><table frame="all"><tgroup cols="3" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Surface according to BET</entry><entry namest="col2" nameend="col2" align="left">m²/G</entry><entry namest="col3" nameend="col3" align="left">200 ± 25</entry></row><row><entry namest="col1" nameend="col1" align="left">Medium size of the primary particles</entry><entry namest="col2" nameend="col2" align="left">Nanometers</entry><entry namest="col3" nameend="col3" align="left">12</entry></row><row><entry namest="col1" nameend="col1" align="left">Ramming density 1)</entry><entry namest="col2" nameend="col2" align="left">g / l</entry><entry namest="col3" nameend="col3" align="left">approx. 50</entry></row><row><entry namest="col1" nameend="col1" align="left">Loss on drying 2) (2 h at 105 ° C) when leaving the factory</entry><entry namest="col2" nameend="col2" align="left">%</entry><entry namest="col3" nameend="col3" align="left">&lt; 1,5</entry></row><row><entry namest="col1" nameend="col1" align="left">Loss on ignition 2) 6) (2 h at 1000 ° C)</entry><entry namest="col2" nameend="col2" align="left">%</entry><entry namest="col3" nameend="col3" align="left">&lt; 1</entry></row><row><entry namest="col1" nameend="col1" align="left">pH 3) (in 4% aqueous dispersion)</entry><entry namest="col2" nameend="col2" /><entry namest="col3" nameend="col3" align="left">3,6 - 4,3</entry></row><row><entry namest="col1" nameend="col1" align="left">SiO₂ 5)</entry><entry namest="col2" nameend="col2" align="left">%</entry><entry namest="col3" nameend="col3" align="left">&gt; 99,8</entry></row><row><entry namest="col1" nameend="col1" align="left">Al₂O₃ 5)</entry><entry namest="col2" nameend="col2" align="left">%</entry><entry namest="col3" nameend="col3" align="left">&lt; 0,05</entry></row><row><entry namest="col1" nameend="col1" align="left">Fe₂O₃ 5)</entry><entry namest="col2" nameend="col2" align="left">%</entry><entry namest="col3" nameend="col3" align="left">&lt; 0,003</entry></row><row><entry namest="col1" nameend="col1" align="left">TiO₂ 5)</entry><entry namest="col2" nameend="col2" align="left">%</entry><entry namest="col3" nameend="col3" align="left">&lt; 0,03</entry></row><row><entry namest="col1" nameend="col1" align="left">HCl 5) 7)</entry><entry namest="col2" nameend="col2" align="left">%</entry><entry namest="col3" nameend="col3" align="left">&lt; 0,025</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Sieve residue 4) according to Mocker (45µm)</entry><entry namest="col2" nameend="col2" align="left">%</entry><entry namest="col3" nameend="col3" align="left">&lt; 0,05</entry></row></tbody></tgroup><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><tbody valign="top"><row><entry namest="col1" nameend="col3" align="justify">Technical data of the AEROSIL standard types 1) according to DIN 53 194</entry></row><row><entry namest="col1" nameend="col3" align="justify">2) according to DIN 55 921</entry></row><row><entry namest="col1" nameend="col3" align="justify">3) according to DIN 53 200</entry></row><row><entry namest="col1" nameend="col3" align="justify">4) according to DIN 53 580</entry></row><row><entry namest="col1" nameend="col3" align="justify">5) related to the substance annealed at 1000 ° C for 2 hours</entry></row><row><entry namest="col1" nameend="col3" align="justify">6) based on the substance dried at 105 ° C. for 2 hours</entry></row><row><entry namest="col1" nameend="col3" align="justify">7) HCl content is part of the loss on ignition</entry></row></tbody></tgroup></table></tables>

Desmophen 1700

Linear polyester containing hydroxyl groups. <tables id="tabl0028" num="0028"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><thead valign="top"><row rowsep="1"><entry namest="col1" nameend="col2" align="left">Key figures</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Hydroxyl content:</entry><entry namest="col2" nameend="col2" align="left">approx. 1.2%</entry></row><row><entry namest="col1" nameend="col1" align="left">Equivalent weight:</entry><entry namest="col2" nameend="col2" align="left">about 1418</entry></row><row><entry namest="col1" nameend="col1" align="left">Color number according to DIN 6162 *:</entry><entry namest="col2" nameend="col2" align="left">Max. 5</entry></row><row><entry namest="col1" nameend="col1" align="left">Flash point according to DIN 51758:</entry><entry namest="col2" nameend="col2" align="left">&gt; 200 ° C</entry></row><row><entry namest="col1" nameend="col1" align="left">Density at 20 ° C according to DIN 53217:</entry><entry namest="col2" nameend="col2" align="left">approx.1.19 g / cm³</entry></row><row><entry namest="col1" nameend="col1" align="left">Viscosity at 23 ° C **: (speed gradient D≈190 s^-1)</entry><entry namest="col2" nameend="col2" align="left">575 ± 75 mPas</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Water content:</entry><entry namest="col2" nameend="col2" align="left">&lt; 0,15 %</entry></row></tbody></tgroup><tgroup cols="2" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col2" align="justify">* 50% in ethyl glycol acetate</entry></row><row><entry namest="col1" nameend="col2" align="justify">** 70% in ethyl glycol acetate</entry></row></tbody></tgroup></table></tables>

NC chips E 730

NC-Chips E 730 is a collodion wool

Shellsol® A

Shellsol® A is an aromatic-rich carbon solvent with the following data: <tables id="tabl0029" num="0029"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Boiling point ° C ASTM d 107/86</entry><entry namest="col2" nameend="col2" align="left">160 - 182</entry></row><row><entry namest="col1" nameend="col1" align="left">Density at 12 ° C ASTM D-1298</entry><entry namest="col2" nameend="col2" align="left">0,874</entry></row><row><entry namest="col1" nameend="col1" align="left">Flash point ° C AP IP 170 PM ASTM D-93</entry><entry namest="col2" nameend="col2" align="left">47</entry></row><row><entry namest="col1" nameend="col1" align="left">Evaporation number (ether = 1) DIN 53 170</entry><entry namest="col2" nameend="col2" align="left">46</entry></row><row><entry namest="col1" nameend="col1" align="left">Refractive index n<maths id="math0002" num=""><math display="inline"><mrow><mfrac numalign="left" denomalign="left"><mrow><mtext>20</mtext></mrow><mrow><mtext>D</mtext></mrow></mfrac></mrow></math><img file="EP0341383B2_D0004.tif" /></maths> DIN 53 169</entry><entry namest="col2" nameend="col2" align="left">1.499</entry></row><row><entry namest="col1" nameend="col1" align="left">Color (Saybolt) ASTM D-156</entry><entry namest="col2" nameend="col2" align="left">+ 30</entry></row><row><entry namest="col1" nameend="col1" align="left">Viscosity 25 ° C mm²/ s ASTM D-445</entry><entry namest="col2" nameend="col2" align="left">0.810</entry></row><row><entry namest="col1" nameend="col1" align="left">Aniline point ° C = mixes ASTM D 611</entry><entry namest="col2" nameend="col2" align="left">15</entry></row><row><entry namest="col1" nameend="col1" align="left">Kauri-butanol value ASTM D-1133</entry><entry namest="col2" nameend="col2" align="left">90</entry></row><row><entry namest="col1" nameend="col1" align="left">Aromatic content vol% ASTM D-1319</entry><entry namest="col2" nameend="col2" align="left">98</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Surface tension b. 20 ° C mN / m ASTM D-971</entry><entry namest="col2" nameend="col2" align="left">29.5</entry></row></tbody></tgroup></table></tables>

Desmodur L

Aromatic polyisocyanate. <tables id="tabl0030" num="0030"><table frame="all"><tgroup cols="3" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><thead valign="top"><row rowsep="1"><entry namest="col1" nameend="col3" align="left">Key figures</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" /><entry namest="col2" nameend="col2" align="center">75 % delivery form</entry><entry namest="col3" nameend="col3" align="center">67 % delivery form</entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">NCO content *:</entry><entry namest="col2" nameend="col2" align="left">approx. 13%</entry><entry namest="col3" nameend="col3" align="left">approx.11.6%</entry></row><row><entry namest="col1" nameend="col1" align="left">Equivalent weight:</entry><entry namest="col2" nameend="col2" align="left">approx. 323</entry><entry namest="col3" nameend="col3" align="left">approx. 362</entry></row><row><entry namest="col1" nameend="col1" align="left">Color number according to DIN 6162 *:</entry><entry namest="col2" nameend="col2" align="left">Max. 5</entry><entry namest="col3" nameend="col3" align="left">Max. 5</entry></row><row><entry namest="col1" nameend="col1" align="left">Flash point according to DIN 53 213:</entry><entry namest="col2" nameend="col2" align="left">approx. + 1 ° C</entry><entry namest="col3" nameend="col3" align="left">approx. -38 ° C</entry></row><row><entry namest="col1" nameend="col1" align="left">Density at 20 ° C according to DIN 53217:</entry><entry namest="col2" nameend="col2" align="left">approx.1.17 g / cm³</entry><entry namest="col3" nameend="col3" align="left">approx.1.15 g / cm³</entry></row><row><entry namest="col1" nameend="col1" align="left">Viscosity at 23 ° C (mPas) *</entry><entry namest="col2" nameend="col2" align="left">1500±400</entry><entry namest="col3" nameend="col3" align="left">1500 ± 400</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Content of monomeric diisocyanate</entry><entry namest="col2" nameend="col2" align="left">&lt; 0,5 %</entry><entry namest="col3" nameend="col3" align="left">&lt; 0,5 %</entry></row></tbody></tgroup><tgroup cols="3" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="52.50mm" /><colspec colnum="2" colname="col2" colwidth="52.50mm" /><colspec colnum="3" colname="col3" colwidth="52.50mm" /><tbody valign="top"><row><entry namest="col1" nameend="col3" align="justify">* Delivery specification</entry></row></tbody></tgroup></table></tables>