Cosmetic and household products.

BACKGROUND OF THE INFORMATION

0001Volatile silicons have found wide acceptance in a number of different types of products ranging from cosmetics to antifreeze formulations. Such silicons are good solvents for a variety of materials and serve to give excellent feel on skin and hair.

0002The most common types of volatile silicons are linear and cyclic siloxanes having from one to about seven siloxane groups. While these are the most common, there are other types which have been disclosed. Included among such other silicons are those in <u style="single">U.S. Patent 4,207,424</u>, June 10, 1980 to Winnick - <chemistry id="chem0001" num="0001"><img file="EP0333433A2_D0001.tif" /></chemistry>

0003Additional disclosures of volatile silicons are in <u style="single">U.S. Patent 4,355,062</u>, October 19, 1982 to Wang et al. Certain alkyl linear siloxanes such as <chemistry id="chem0002" num="0002"><img file="EP0333433A2_D0002.tif" /></chemistry> are disclosed in <u style="single">U.S. Patent 4,376,087</u>, March 8, 1983 to Poliniak et al. Cyclic silicones different from those mentioned above are disclosed in <u style="single">U.S. Patent 4,364,837</u>, December 21, 1982 to Pader. Still other volatile silicons are disclosed in Japanese unexamined applications <u style="single">JP 9108-046</u>, October 14, 1974; <u style="single">JP 1102-019</u>, September 7, 1976; <u style="single">JP 607-824</u>, June 15, 1981; <u style="single">JP 61 39-527</u>, October 31, 1981; and <u style="single">JP 7035-526</u>, February 26, 1982.

0004Although the references discussed above disclose a variety of volatile silicons in a variety of compositions, there is still the need for cosmetic and household products which incorporate volatile silicons.

0005It is therefore an object of the present invention to provide cosmetic and household products containing silicon materials which provide improved solvency and compatibility with other composition components.

0006This and other objectives will become readily available from the detailed disclosure below.

0007All percentages and ratios herein are by weight unless otherwise specified. Additionally, all measurements are made at 25°C unless otherwise specified.

SUMMARY OF THE INVENTION

0008The present invention relates to cosmetic and household products containing volatile silicons of the following structures:

a) Linear siloxanes

0009<chemistry id="chem0003" num="0003"><img file="EP0333433A2_D0003.tif" /></chemistry> where 1) X = 1 to 4, 2) total carbons ≦ 14, 3) R can be independently C₁ - C₁₀ alkyl, trialkyl siloxy and 4) at least one R per molecule muse be aryl, alkylaryl or aryl alkyl or C₁ - C₇ hydroxyalkyl or - R₁ R₂ wherein R₁ = C₁ - C₄ alkylene and R₂ = - O - R₃ wherein R₃ = C₁ - C₅ alkyl or R₂ = <chemistry id="chem0004" num="0004"><img file="EP0333433A2_D0004.tif" /></chemistry><chemistry id="chem0005" num="0005"><img file="EP0333433A2_D0005.tif" /></chemistry>

b) Cyclic siloxanes

0010<chemistry id="chem0006" num="0006"><img file="EP0333433A2_D0006.tif" /></chemistry> where 1) X = 1 to 4, -2) total carbons ≦ 14, 3) R can be independently C₁ - C₁₀ alkyl, trialkyl siloxy and 4) at least one R per molecule must be C₁ - C₇ hydroxyalkyl or - R₁ R₂ wherein R₁ = C₁ - C₄ alkylene and R₂ = - O - R₃ wherein R₃ = C₁ - C₅ alkyl or <chemistry id="chem0007" num="0007"><img file="EP0333433A2_D0007.tif" /></chemistry><chemistry id="chem0008" num="0008"><img file="EP0333433A2_D0008.tif" /></chemistry>

c) Silanes

0011<chemistry id="chem0009" num="0009"><img file="EP0333433A2_D0009.tif" /></chemistry> where 1) Z = 1 to 4, 2) total carbons ≦14, 3) R can be independently C₁ - C₁₀ alkyl, trialkyl (C₁ - C₃) siloxy and 4) at least one R per molecular must be selected from aryl, alkylaryl, araalkyl or C₁ - C₇ hydroxyalkyl or C₂ - C₁₀ alkyl or - R₁ R₂ where R₁ = C₁ - C₄ alkylene and R₂ = <chemistry id="chem0010" num="0010"><img file="EP0333433A2_D0010.tif" /></chemistry> The boiling point of all of these silicon compounds at 760mm is ≦260°C.

DETAILED DESCRIPTION OF THE INVENTION

0012The present invention as summarized above relates to cosmetic and household products containing silicon compounds having improved solvency and compatibility properties.

0013Examples of these materials include, among many others, the following: <chemistry id="chem0011" num="0011"><img file="EP0333433A2_D0011.tif" /></chemistry><chemistry id="chem0012" num="0012"><img file="EP0333433A2_D0012.tif" /></chemistry>

Cosmetic and Household Products

0014The volatile silicons described above find use in a number of different products. These include hair care products such as hairsprays, shampoos, mousses, styling gels and lotions, cream rinses/conditioners, hair tonics, hair dyes and colorants, home permanents and bleaches. Also included are skin care products such as cleansers, conditioners, lipsticks, eye makeup, fingernail polish, suntan products, antiperspirant/deodorant products and depilatories. Also included are household products such as waxes, polishes, heavy and light duty liquids, fabric softeners and window cleaners.

0015Given below are several detailed descriptions of suitable products of the type mentioned above.

Hair Care Products

0016The hair care products of the present invention contain the volatile silicon agents described above along with a carrier benefiting from the silicon. The term "carrier", as used herein, means one or more compatible vehicles which are suitable for administration to the hair of a human or lower animal. The term "compatible", as used herein, means that the components of the carrier are capable of being commingled with the silicons of the present invention, and with each other, in a manner such that there is no interaction which would substantially reduce the ability of the hair care products to provide its benefit under ordinary use situation.

0017Carriers suitable for use with the volatile silicon agents such as shampoos and cream rinse conditioners to hair are well known in the art, and their selection can be made without difficulty by a person skilled in the art. For example, carriers which are suitable are described in more detail in <u style="single">U.S. Patent 3,577,517</u>, to Kubot et al, issued May 4, 1971; <u style="single">U.S. Patent 3,907,984</u>, to Calvert et al, issued September 23, 1975; <u style="single">U.S. Patent 4,012,501</u>, to Farber, issued March 15, 1977; <u style="single">U.S. Patent 4,223,009</u>, to Chakrabarti, issued September 16, 1980; and <u style="single">U.S. Patent 4,283,384</u>, to Jacquet et al, issued August 11, 1981; the disclosures of all these patents being incorporated herein by reference in their entirety.

0018Shampoo compositions useful with the silicons of this invention utilize conventional components. The shampoos comprise from about 0.1% to about 20% of the volatile silicon; from about 5% to about 60% of a synthetic surfactant; and the balance water. Suitable surfactants include ammonium lauryl sulfate, ammonium laureth sulfate, triethylamine lauryl sulfate, triethylamine laureth sulfate, triethanolamine lauryl sulfate, triethanolamine laureth sulfate, monoethanolamine lauryl sulfate, monoethanolamine laureth sulfate, diethanolamine lauryl sulfate, diethanolamine laureth sulfate, lauric monoglyceride sodium sulfate, sodium lauryl sulfate, sodium laureth sulfate, potassium lauryl sulfate, potassium laureth sulfate, lauryl sarcosine, cocoyl sarcosine; ammonium cocoyl sulfate, ammonium lauryl sulfate, sodium cocoyl sulfate, sodium lauryl sulfate, potassium cocoyl sulfate, potassium lauryl sulfate, triethanolamine lauryl sulfate, triethanolamine lauryl sulfate, monoethanolamine cocoyl sulfate, monoethanolamine lauryl sulfate, sodium tridecyl benzene sulfonate and sodium dodecyl benzene sulfonate.

0019Shampoos can also contain a variety of nonessential optional components. Such conventional optional ingredients are well known to those skilled in the art, e.g., preservatives, such as benzyl alcohol, ethyl paraben, propyl paraben and imidazolidinyl urea; hair styling/setting polymers such as acrylate polymers and copolymers; cationic surfactants, such as cetyl trimethyl ammonium chloride, lauryl trimethyl ammonium chloride, tricetyl methyl ammonium chloride, stearyldimethyl benzyl ammonium chloride, and di(partially hydrogenated tallow) dimethylammonium chloride; thickeners and viscosity modifiers such as a diethanolamide of a long-chain fatty acid (e.g. PEG 3 lauramide), block polymers of ethylene oxide and propylene oxide, sodium chloride, sodium sulfate, polyvinyl alcohol, ethyl alcohol and water-soluble polymers such as xanthan gum, hydroxyethyl cellulose, guar gum and starch; pH adjusting agents, such as citric acid, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate; perfumes; dyes; and, sequestering agents, such as disodium ethylenediamine tetraacetate. Such agents generally are used individually at a level of from about 0.01% to about 10%, preferably from about 0.5% to about 5.0% by weight of the composition.

0020Another carrier useful with the present silicons are creme rinses/conditioners. Such a carrier preferably comprises two essential components: a lipid vehicle material and generally a cationic surfactant vehicle material. Such carriers are generally described in the following documents, all incorporated by reference herein: Barry, "The Self Bodying Action of the Mixed Emulsifier Sodium Dodecyl Sulfate/Cetyl Alcohol", 28 <u style="single">J. of Colloid and Interface Science</u> 82-91 (1968); Barry, et al., "The Self-­Bodying Action of Alkyltrimethylammonium Bromides/Cetostearyl Alcohol Mixed Emulsifiers; Influence of Quaternary Chain Length", 35 <u style="single">J. of Colloid and Interface Science</u> 689-708 (1971); and Barry, et al., "Rheology of Systems Containing Cetomacrogol 1000 - Cetostearyl Alcohol, I. Self Bodying Action", 38 <u style="single">J. of Colloid and Interface Science</u> 616-625 (1972).

0021Lipid materials include naturally or synthetically-derived acids, acid derivatives, alcohols, esters, ethers, ketones, and amides with carbon chains of from 12 to 22, preferably from 16 to 18, carbon atoms in length. Fatty alcohols and fatty esters are preferred; fatty alcohols are particularly preferred.

0022Lipid materials among those useful herein are disclosed in <u style="single">Bailey's Industrial Oil and Fat Products</u>, (3d edition, D. Swern, ed. 1979) (incorporated by reference herein). Fatty alcohols included among those useful herein are disclosed in the following documents, all incorporated by reference herein: <u style="single">U.S. Patent 3, 155,591</u>, Hilfer, issued November 3, 1964; <u style="single">U.S. Patent 4,165,369</u>, Watanabe, et al., issued August 21, 1979; <u style="single">U.S. Patent 4,269,824</u>, Villamarin, et al., issued May 26, 1981; <u style="single">British Speci­fication 1 ,532,585</u>, published November 15, 1978; and Fukushima, et al., "The Effect of Cetostearyl Alcohol in Cosmetic Emulsions", 98 <u style="single">Cosmetics &amp; Toiletries</u> 89-102 (1983). Fatty esters included among those useful herein are disclosed in <u style="single">U.S. Patent 3,341,465</u>, Kaufman, et al., issued September 12, 1961 (incorporated by reference herein).

0023Preferred esters for use herein include cetyl palmitate and glycerylmonostearate. Cetyl alcohol and stearyl alcohol are preferred alcohols. A particularly preferred lipid vehicle material is comprised of a mixture of cetyl alcohol and stearyl alcohol containing from about 55% to about 65% (by weight of mixture) of cetyl alcohol.

Deodorant/Antiperspirants

0024Deodorant/antiperspirant compositions utilizing the volatile silicons include a variety of components.

Antiperspirant Actives

0025Antiperspirant compositions comprise at least one anti­perspirant active. Antiperspirant actives useful in the present invention are well known in the art, and are disclosed generally in Miller and Hoag, "Personal Care Products", <u style="single">Handbook of Nonprescription Drugs</u>, 8th Edition, Chapter 19, pages 397-417 (American Pharmaceutical Association; 1986), the disclosures of which are incorporated herein by reference in their entirety. Antiperspirant actives useful herein are also more specifically disclosed in <u style="single">European Patent Application Publication No. 28,853</u>, published May 20, 1981, by Beckmeyer et al.; and European <u style="single">Patent Application Publication No. 117,070</u>, published August 29, 1984, by May, the disclosures of both these patent specifications being incorporated herein by reference in their entirety. Anti­perspirant actives include, for example, aluminum chlorohydrates, aluminum chloride, sodium aluminum chlorohydroxy lactate, buffered aluminum sulfate, and aluminum zirconium chloro­hydrates.

0026Preferred are astringent metallic salts including the inorganic and organic salts of aluminum, zirconium and zinc, and mixtures thereof. Particularly preferred are the aluminum and zirconium salts, such as aluminum halides, aluminum hydroxyhalides, zirconyl oxyhalides, zirconyl hydroxyhalides, and mixtures thereof. Such metal salts, and complexes thereof, are described in <u style="single">European Patent Specification Publication No. 117,070</u>, to May, published August 29, 1984, and <u style="single">U.S. Patent 4,137,306</u>, to Rubino et al., issued January 30, 1979, the disclosures of both these patent specifications being incorporated herein by reference in their entirety.

0027Preferred aluminum salts include those of the formula: Al₂(OH)_aCl_b.xH₂O wherein a is from about 2 to about 5; a + b = 6; x is from about 1 to about 6; and wherein a, b, and x may have non-integer values. Particularly preferred are aluminum chlorhydroxides referred to as "5/6 basic chlorhydroxide", wherein a = 5; and "2/3 basic chlorhydroxide", wherein a = 4. Processes for preparing aluminum salts are disclosed in the following documents, all incorporated by reference herein in their entirety: <u style="single">U.S. Patent 3,887,692</u>, to Gilman, issued June 3, 1975; <u style="single">U.S. Patent 3,904,741</u>, to Jones et al., issued September 9, 1975; <u style="single">U.S. Patent 4,359,456</u>, to Gosling et al., issued November 16, 1982; and <u style="single">British Patent Specification 2,048,229</u>, to Fitzgerald et al., published December 10, 1980. Mixtures of aluminum salts are described in <u style="single">British Patent Specification 1,347,950</u>, to Shin et al., published February 27, 1974, the disclosures of which are incorporated herein by reference in their entirety.

0028Zirconium salts are also preferred for use in antiperspirant compositions of the present invention. Such salts are of the general formula: ZrO(OH)_2-aCl_a.xH₂O wherein a is from about 1 to about 2, preferably from about 1.5 to about 1.87; x is from about 1 to about 7; and wherein a and x may have non-integer values. These zirconium salts are disclosed in <u style="single">Belgium Patent Specification 825,146</u>, to Schmitz, issued August 4, 1975, the disclosures of which are incorporated herein by reference in their entirety. Particularly preferred zirconium salts are those complexes also containing aluminum and glycine, commonly known as "ZAG complexes". Such ZAG complexes contain aluminum chlorhydroxide and zirconyl hydroxychloride of the formulae detailed above. These compounds in ZAG complexes are disclosed in the following patent documents, all incorporated by reference herein in their entirety: <u style="single">U.S. Patent 2 ,814,585</u> to Daley, issued November 26, 1957; <u style="single">U.S. Patent 3,679,068</u>, to Luedders et al., issued February 12, 1974; <u style="single">U.S. Patent 4,017,599</u>, to Rubino, issued April 12, 1977; <u style="single">U.S. Patent 4,120,948</u>, to Shelton, issued October 1 7, 1978; and <u style="single">British Patent Specification 2,144,992</u>, to Callaghan et al., published March 20, 1985.

0029The antiperspirant actives in total typically comprise from about 1% to about 50% by weight of the composition of the present invention, more preferably from about 5% to about 40%, and most preferably from about 5% to about 30%.

Deodorant/Antiperspirant Carrier

0030The selection of carriers for use with the volatile silicons of the present invention is readily made by one skilled in the art based on the form of the composition being prepared, for example, aerosol spray, roll-on lotion, or stick. Antiperspirant carriers are described in detail in <u style="single">European Patent Application Publication No. 28,853</u>, published May 20, 1981, by Beckmeyer et al.; and <u style="single">European Patent Application Publication No. 117,070</u>, published August 29, 1984, by May; the disclosures of both these patent specifications being incorporated herein by reference in their entirety. Carrier materials suitable for use for various composition forms are also described in detail as follows:

(i) Stick Antiperspirant Carriers

0031Antiperspirant compositions in stick form contain the volatile silicon, which may function as a liquid emollient and preferably contain one or more non-volatile emollients. Such materials include fatty acid and fatty alcohol esters, water-insoluble ethers and alcohols, polyorganosiloxanes, and mixtures thereof. Emollients among those useful herein are described in 1 <u style="single">Cosmetics, Science and Technology</u> 27-104 (M. Balsam and E. Sagarin ed. 1972), and <u style="single">U.S. Patent 4,202,879</u>, to Shelton, issued May 13, 1980 (both incorporated by reference herein).

0032The present compositions in stick form preferably contain a non-volatile silicone oil as an emollient material. Such silicone oils include polyalkylsiloxanes, polyalkyarylsiloxanes, and polyether­siloxane copolymers. The essentially non-volatile polyalkyl siloxanes useful herein include, for example, polydimethyl siloxanes with viscosities of from about 5 to about 100,000 centi­stokes at 25°C. Among the preferred non-volatile emollients useful in the present compositions are the polydimethyl siloxanes having viscosities from about 10 to about 400 centistokes at 25°C. Such polyalkyl siloxanes include the Vicasil series (sold by General Electric Company) and the Dow Corning 200 series (sold by Dow Corning Corporation). Polyalkylaryl siloxanes include poly methylphenyl siloxanes having viscosities of from about 15 to about 65 centistokes at 25°C. These are available, for example, as SF 1075 methylphenyl fluid (sold by General Electric Company) and 556 Cosmetic Grade Fluid (sold by Dow Corning Corporation). Useful polyether siloxane copolymers include, for example, a poly­oxyalkylene ether copolymer having a viscosity of about 1200 to 1500 centistokes at 25°C. Such a fluid is available as SF-1066 organosilicone surfactant (sold by General Electric Company). Polysiloxane ethylene glycol ether copolymers are preferred copolymers for use in the present compositions.

0033Antiperspirant compositions in stick form further preferably contain one or more materials having wax-like characteristics and having a melting point of from about 65°C to about 102°C. Such waxes include beeswax, spermaceti, carnauba, baysberry, candelilla, montan, ozokerite, ceresin, paraffin, hydrogenated castor oil (castor wax), synthetic waxes such as Fisher-Tropsch waxes, microcrystalline wax, and mixtures thereof. Castor wax is a preferred high-melting point wax useful herein. Such high-melting point waxes among those useful herein are disclosed in <u style="single">U.S. Patent 4,049,792</u>, to Elsnau, issued September 20, 1977 (incorporated by reference herein).

(ii) Aerosol Spray Deodorant/Antiperspirant Carriers

0034Compositions in aerosol spray form preferably contain one or more volatile materials, herein "aerosol propellants", which in a gaseous state, carry the other components of the spray composition in particulate or droplet form. The aerosol propel­lants useful in the present invention typically have a boiling point within the range of from about -45°C to about 5°C. The aerosol propellants are liquified when packaged in conventional aerosol containers under pressure. The rapid boiling of the aerosol propellant upon leaving the aerosol container aids in the atom­ization of the other components of the present invention.

0035Aerosol propellants useful in the compositions of the present invention in spray form include those well known in the art. Such aerosol propellants include the chemically-inert hydrocarbons such as propane, n-butane, isobutane and cyclopropane, and mixtures thereof, as well as halogenated hydrocarbons such as dichlorodifluoromethane (propellant 12), 1,1-dichloro-1,1,2,2-­tetrafluoroethane (propellant 114), 1-chloro-1,1-difluoro-2,2-­trifluoroethane (propellant 115), 1-chloro-1,1-difluoroethylene (propellant 142B), 1,1-difluoroethane (propellant 152A), and monochlorodifluoromethane, and mixtures thereof. Isobutane, used singly or admixed with other hydrocarbons, is preferred for use in the present aerosol spray antiperspirants.

0036Another preferred material for use in the aerosol compo­sitions in aerosol spray form is a silicone gum. As referred to herein, "silicone gum" materials useful in the present compositions are those non-functionalized siloxanes having a viscosity of from about 500,000 to about 100,000,000 centistokes at 25°C. These materials are incorporated in the present compositions at a level of from about 0.05% to about 5.0%, preferably from about 0.10% to about 2.0%. Preferred silicone gums include linear and branched polydimethyl siloxanes, of the following general formula: (CH₃)₃ SiO - Si (CH₃)₂ O _n - Si(CH₃)₃ wherein n is from about 2,000 to about 15,000, preferably from about 2,000 to about 7,000. The silicone gums useful herein may also be substituted with non-electronegative substituents. Silicone gums among those useful herein are available from a variety of commercial sources, including X2-1346 and Dow Corning 200 Fluid (manufactured by Dow Corning Corporation), PS240 (manufactured by Petrarch Systems, Inc.), and SE76, SE30 and SE32 Silicone Gums (manufactured by General Electric Company).

0037The aerosol compositions may also contain a bulking or suspending agent, at levels of from about 0.1% to about 7%, preferably from about 0.4% to about 3.5%. Such bulking/­suspending agents include talc, colloidal silicas, clays and mixtures thereof. Clays and colloidal silicas are particularly preferred. Clay bulking/ suspending agents include montmoril­lonite clays and hydrophobically treated montmorillonites, e.g., bentonites, hectorites and colloidal magnesium aluminum silicates. These materials are available from a variety of sources, including Laponite hectorite (sold by Laponite Industries, Ltd.) and Veegum magnesium aluminum silicate (sold by R. T. Vanderbilt Co.). A preferred clay bulking/suspending agent is hydropho­bically-treated montmorillonite, such as the Bentone bentonites (sold by NL Industries, Inc.). Colloidal silicas are also readily available, such as Cab-O-Sil pyrogenic colloidal silica (sold by Cabot Corporation).

(iii) Roll-on Lotion Deodorant/Antiperspirant Carriers

0038Antiperspirant/deodorant compositions of the present invention in roll-on lotion form typically comprise carrier materials similar to those utilized in aerosol spray forms except that no aerosol propellant is required. Antiperspirant/deodorant compositions in roll-on lotion form, and carrier materials useful therein, are described in detail in <u style="single">European Patent Application Publication No. 28,853</u>, published May 20, 1981, by Beckmeyer et al., the disclosures of which are incorporated herein by reference in their entirety.

0039Additional active components include bacteriostats and fungistats. The particular non-active components that may be useful will depend upon the form of application that is desired. Such components include, for example, emollients, colorants, perfumes, and emulsifiers. Optional components useful herein are described in the following documents, all incorporated by reference herein: U.S. Patent 4,049,792, to Elsnau, issued September 20, 1977; Canadian Patent 1,164,347, to Beckmeyer, et al., issued March 27, 1984; European Patent Specification 117,070, to May, published August 29, 1984; and Geria, "Formulation of Stick Antiperspirants and Deodorants," 99 <u style="single">Cosmetics &amp; Toiletries</u> 55-60 (1984).

0040Generally, the deodorant/antiperspirant carriers in total comprise from about 40% to about 99% by weight of the compo­sitions of the present invention, preferably from about 55% to about 95%, and most preferably from about 67% to about 94%.

0041Other cosmetic and household product compositions are disclosed in <u style="single">U.S. Patent 4,687,592</u>, August 18, 1987 to Collins et al; <u style="single">U.S. Patent 4,663,157</u>, May 5, 1987 to Brock; <u style="single">U.S. Patent 4,631,064</u>, December 23, 1986 to Juneja; and <u style="single">U.S. Patent 4,130,121</u>, December 19, 1978 to Wetzel. All of these references are incorporated herein by reference.

METHOD OF MANUFACTURE OF VOLATILE SILICONS

0042The compositions of the present invention can be prepared by methods which are well known in the art.

0043The following nonlimiting examples of the present invention are given solely for illustration and are not to be construed as limitations of this invention, many variations are possible without departing from the spirit and scope thereof. The silicones in the various examples are identified on pages 4 - 6.

EXAMPLE I

0044The following is a highlighting rinse representative of the present invention. <tables id="tabl0001" num="0001"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" align="right"><u style="single">Component</u></entry><entry namest="col2" nameend="col2" align="right"><u style="single">Weight %</u></entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">D&amp;C Red #17</entry><entry namest="col2" nameend="col2" align="char" char=".">0.10</entry></row><row><entry namest="col1" nameend="col1" align="left">Volatile Silicone A</entry><entry namest="col2" nameend="col2" align="char" char=".">5.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Cetyl Alcohol</entry><entry namest="col2" nameend="col2" align="char" char=".">2.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Ditallow Dimethyl Ammonium Chloride</entry><entry namest="col2" nameend="col2" align="char" char=".">1.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Ceteareth-20</entry><entry namest="col2" nameend="col2" align="char" char=".">1.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Kathon CG</entry><entry namest="col2" nameend="col2" align="char" char=".">.04</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Double Reverse Osmosis Water</entry><entry namest="col2" nameend="col2" align="left">q.s.</entry></row></tbody></tgroup></table></tables>

EXAMPLE II

0045The following is a shampoo representative of the present invention. <tables id="tabl0002" num="0002"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" align="center"><u style="single">Component</u></entry><entry namest="col2" nameend="col2" align="center"><u style="single">Weight %</u></entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Ammonium Lauryl Sulfate</entry><entry namest="col2" nameend="col2" align="char" char=".">15.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Jaguar HP-60¹</entry><entry namest="col2" nameend="col2" align="char" char=".">1.00</entry></row><row><entry namest="col1" nameend="col1" align="left">G.E. SE 30²</entry><entry namest="col2" nameend="col2" align="char" char=".">1.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Volatile Silicone D</entry><entry namest="col2" nameend="col2" align="char" char=".">1.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Kathon CG³</entry><entry namest="col2" nameend="col2" align="char" char=".">.04</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Double Reverse Osmosis Water</entry><entry namest="col2" nameend="col2" align="left">q.s.</entry></row></tbody></tgroup><tgroup cols="2" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col2" align="justify">¹: Hydroxypropyl guar gum offered by Hi-tek Polymers Inc.</entry></row><row><entry namest="col1" nameend="col2" align="justify">²: Silicone gum offered by General Electric.</entry></row><row><entry namest="col1" nameend="col2" align="justify">³: Offered by Rohm and Haas.</entry></row></tbody></tgroup></table></tables>

EXAMPLE III

0046The following is a men's grooming aid representative of the present invention. <tables id="tabl0003" num="0003"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" align="center"><u style="single">Component</u></entry><entry namest="col2" nameend="col2" align="center"><u style="single">Weight %</u></entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Volatile Silicone C</entry><entry namest="col2" nameend="col2" align="char" char=".">86.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Dow Corning X2-2G13¹</entry><entry namest="col2" nameend="col2" align="char" char=".">8.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Perfume</entry><entry namest="col2" nameend="col2" align="char" char=".">1.00</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Ethanol</entry><entry namest="col2" nameend="col2" align="char" char=".">5.00</entry></row></tbody></tgroup><tgroup cols="2" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col2" align="justify">¹: A copolymer of methyl-phenyl and diphenyl siloxane offered by Dow Corning.</entry></row></tbody></tgroup></table></tables>

EXAMPLE IV

0047The following is a hair styling mousse representative of the present invention. <tables id="tabl0004" num="0004"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" align="center"><u style="single">Component</u></entry><entry namest="col2" nameend="col2" align="center"><u style="single">Weight %</u></entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Gafquat 755</entry><entry namest="col2" nameend="col2" align="char" char=".">2.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Cocamine oxide</entry><entry namest="col2" nameend="col2" align="char" char=".">0.50</entry></row><row><entry namest="col1" nameend="col1" align="left">Kathon CG</entry><entry namest="col2" nameend="col2" align="char" char=".">0.04</entry></row><row><entry namest="col1" nameend="col1" align="left">Volatile Silicone C</entry><entry namest="col2" nameend="col2" align="char" char=".">2.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Isobutane</entry><entry namest="col2" nameend="col2" align="char" char=".">6.00</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Distilled Water</entry><entry namest="col2" nameend="col2" align="left">q.s.</entry></row></tbody></tgroup></table></tables>

EXAMPLE V

0048The following is a hair conditioning rinse representative of the present invention. <tables id="tabl0005" num="0005"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" align="center"><u style="single">Component</u></entry><entry namest="col2" nameend="col2" align="center"><u style="single">Weight %</u></entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Stearalkonium Chloride</entry><entry namest="col2" nameend="col2" align="char" char=".">2.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Stearyl Alcohol</entry><entry namest="col2" nameend="col2" align="char" char=".">0.90</entry></row><row><entry namest="col1" nameend="col1" align="left">Cetyl Alcohol</entry><entry namest="col2" nameend="col2" align="char" char=".">1.10</entry></row><row><entry namest="col1" nameend="col1" align="left">Volatile Silicone B</entry><entry namest="col2" nameend="col2" align="char" char=".">4.00</entry></row><row><entry namest="col1" nameend="col1" align="left">G.E. SE 30 Silicone Gum</entry><entry namest="col2" nameend="col2" align="char" char=".">1.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Kathon CG¹</entry><entry namest="col2" nameend="col2" align="char" char=".">0.04</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Distilled Water</entry><entry namest="col2" nameend="col2" align="left">q.s.</entry></row></tbody></tgroup><tgroup cols="2" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col2" align="justify">¹: Offered by Rohm and Haas.</entry></row></tbody></tgroup></table></tables>

EXAMPLE VI

0049The following is a hairspray composition representative of the present invention. <tables id="tabl0006" num="0006"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" align="center"><u style="single">Component</u></entry><entry namest="col2" nameend="col2" align="center"><u style="single">Weight %</u></entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Amphomer¹</entry><entry namest="col2" nameend="col2" align="char" char=".">3.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Aminomethyl propanol</entry><entry namest="col2" nameend="col2" align="char" char=".">.50</entry></row><row><entry namest="col1" nameend="col1" align="left">Volatile Silicone C</entry><entry namest="col2" nameend="col2" align="char" char=".">1.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Ethanol</entry><entry namest="col2" nameend="col2" align="char" char=".">70.5</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Isobutane Propellant</entry><entry namest="col2" nameend="col2" align="char" char=".">25.00</entry></row></tbody></tgroup></table></tables>

EXAMPLE VII

0050The following is a cold-wave hair perm representative of the present invention. <tables id="tabl0007" num="0007"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" align="center"><u style="single">Component</u></entry><entry namest="col2" nameend="col2" align="center"><u style="single">Weight %</u></entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Thioglycolic Acid</entry><entry namest="col2" nameend="col2" align="char" char=".">7.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Monoethanolamine</entry><entry namest="col2" nameend="col2" align="char" char=".">9.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Volatile Silicone C</entry><entry namest="col2" nameend="col2" align="char" char=".">3.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Polyethylene Glycol 400 Monostearate</entry><entry namest="col2" nameend="col2" align="char" char=".">0.50</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Distilled Water</entry><entry namest="col2" nameend="col2" align="left">q.s.</entry></row></tbody></tgroup></table></tables>

EXAMPLE VIII

0051The following is a cologne representative of the present invention. <tables id="tabl0008" num="0008"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" align="center"><u style="single">Component</u></entry><entry namest="col2" nameend="col2" align="center"><u style="single">Weight %</u></entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Volatile Silicone A</entry><entry namest="col2" nameend="col2" align="char" char=".">45.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Propylene Glycol</entry><entry namest="col2" nameend="col2" align="char" char=".">2.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Perfume</entry><entry namest="col2" nameend="col2" align="char" char=".">2.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Polydimethylsiloxane 350 cs.</entry><entry namest="col2" nameend="col2" align="char" char=".">1.00</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Isobutane</entry><entry namest="col2" nameend="col2" align="char" char=".">50.00</entry></row></tbody></tgroup></table></tables>

EXAMPLE IX

0052The following is an antiperspirant stick representative of the present invention. <tables id="tabl0009" num="0009"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" align="center"><u style="single">Component</u></entry><entry namest="col2" nameend="col2" align="center"><u style="single">Weight %</u></entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Crodomol PMP¹</entry><entry namest="col2" nameend="col2" align="char" char=".">15.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Syncrowax BB4¹</entry><entry namest="col2" nameend="col2" align="char" char=".">1.50</entry></row><row><entry namest="col1" nameend="col1" align="left">Incroquat Behenyl TMS²</entry><entry namest="col2" nameend="col2" align="char" char=".">12.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Incromide BEM²</entry><entry namest="col2" nameend="col2" align="char" char=".">12.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Volatile Silicone D</entry><entry namest="col2" nameend="col2" align="char" char=".">37.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Rezel 36q Superultrafine³</entry><entry namest="col2" nameend="col2" align="char" char=".">20.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Talc</entry><entry namest="col2" nameend="col2" align="char" char=".">1.00</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Cab-O-Sil M-5⁴</entry><entry namest="col2" nameend="col2" align="char" char=".">1.50</entry></row></tbody></tgroup><tgroup cols="2" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col2" align="justify">¹: Offered by Croda, Inc.</entry></row><row><entry namest="col1" nameend="col2" align="justify">²: Offered by Croda Surfactants, Inc.</entry></row><row><entry namest="col1" nameend="col2" align="justify">³: Offered by Reheis Chemical Company.</entry></row><row><entry namest="col1" nameend="col2" align="justify">⁴ Offered by Cabot Corporation.</entry></row></tbody></tgroup></table></tables>

EXAMPLE X

0053The following is a solid deodorant representative of the present invention. <tables id="tabl0010" num="0010"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" align="center"><u style="single">Component</u></entry><entry namest="col2" nameend="col2" align="center"><u style="single">Weight %</u></entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Volatile Silicone B</entry><entry namest="col2" nameend="col2" align="char" char=".">39.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Sodium Stearate</entry><entry namest="col2" nameend="col2" align="char" char=".">9.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Propylene Glycol</entry><entry namest="col2" nameend="col2" align="char" char=".">15.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Ethanol</entry><entry namest="col2" nameend="col2" align="left">q.s.</entry></row><row><entry namest="col1" nameend="col1" align="left">PPG-10 Cetyl Ether</entry><entry namest="col2" nameend="col2" align="char" char=".">10.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Isostearyl Alcohol</entry><entry namest="col2" nameend="col2" align="char" char=".">3.00</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Perfume</entry><entry namest="col2" nameend="col2" align="char" char=".">0.50</entry></row></tbody></tgroup></table></tables>

EXAMPLE XI

0054The following is a roll-on antiperspirant representative of the present invention. <tables id="tabl0011" num="0011"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" align="center"><u style="single">Component</u></entry><entry namest="col2" nameend="col2" align="center"><u style="single">Weight %</u></entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Volatile Silicone A</entry><entry namest="col2" nameend="col2" align="char" char=".">64.60</entry></row><row><entry namest="col1" nameend="col1" align="left">Isopropyl Myristate</entry><entry namest="col2" nameend="col2" align="char" char=".">5.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Tixogel VP¹</entry><entry namest="col2" nameend="col2" align="char" char=".">3.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Aluminum Zirconium Trichlorohydrate</entry><entry namest="col2" nameend="col2" align="char" char=".">25.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Ethanol (95%/5% water)</entry><entry namest="col2" nameend="col2" align="char" char=".">2.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Perfume</entry><entry namest="col2" nameend="col2" align="char" char=".">0.10</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Cab-O-Sil M-5²</entry><entry namest="col2" nameend="col2" align="char" char=".">0.30</entry></row></tbody></tgroup><tgroup cols="2" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col2" align="justify">¹: Offered by United Catyalysts Inc.</entry></row><row><entry namest="col1" nameend="col2" align="justify">²: Offered by Cabot</entry></row></tbody></tgroup></table></tables>

EXAMPLE XII

0055The following is a hand lotion representative of the present invention. <tables id="tabl0012" num="0012"><table frame="all"><tgroup cols="2" colsep="1" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><thead valign="top"><row><entry namest="col1" nameend="col1" align="center"><u style="single">Component</u></entry><entry namest="col2" nameend="col2" align="center"><u style="single">Weight %</u></entry></row></thead><tbody valign="top"><row><entry namest="col1" nameend="col1" align="left">Volatile Silicone D</entry><entry namest="col2" nameend="col2" align="char" char=".">3.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Mineral Oil</entry><entry namest="col2" nameend="col2" align="char" char=".">1.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Polydimethylsiloxane, 350C</entry><entry namest="col2" nameend="col2" align="char" char=".">1.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Stearic Acid</entry><entry namest="col2" nameend="col2" align="char" char=".">3.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Cetyl Alcohol</entry><entry namest="col2" nameend="col2" align="char" char=".">2.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Triethanolamine</entry><entry namest="col2" nameend="col2" align="char" char=".">1.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Glydant¹</entry><entry namest="col2" nameend="col2" align="char" char=".">.35</entry></row><row><entry namest="col1" nameend="col1" align="left">Glycerine</entry><entry namest="col2" nameend="col2" align="char" char=".">5.00</entry></row><row><entry namest="col1" nameend="col1" align="left">Carbopol 941²</entry><entry namest="col2" nameend="col2" align="char" char=".">0.20</entry></row><row rowsep="1"><entry namest="col1" nameend="col1" align="left">Distilled Water</entry><entry namest="col2" nameend="col2" align="left">q.s.</entry></row></tbody></tgroup><tgroup cols="2" colsep="0" rowsep="0"><colspec colnum="1" colname="col1" colwidth="78.75mm" /><colspec colnum="2" colname="col2" colwidth="78.75mm" /><tbody valign="top"><row><entry namest="col1" nameend="col2" align="justify">¹: Offered by</entry></row><row><entry namest="col1" nameend="col2" align="justify">²: Offered by B. F. Goodrich.</entry></row></tbody></tgroup></table></tables>