Compositions of fluorescent biocides for use as improved antimicrobials

Use as the improved anti-microbial agents fluorescent biocide composition

The invention belongs to microbicide composition and monitoring and liquid control system microbicide composition dosage method for.

The microbicide is added to the industrial and entertainment of water body. When of which is, comprising to industry the cold water system and bathing pool and mineral artificial battery and other recreational and a system is the growth of the microbicide control algae, bacteria, mushroom and protozoon, the papermaking into the anti-microbial agents control bacteria, during processing the thick sucrose, wherein microbicide control bacteria growth and equal. The invention is capable of the following for use, for example used as the control industry and municipal pilot system and a non-vertebrate of industrial cold water system (comprising, but not limited in zebra shell and back device mussel) biocide. Although the invention is suitable for is Water Body; and is further used for non-Water Body Is. Terminology with the article for a microbicide) and a biocide shape of exchange use, moreover refers to comprising for controlling, wherein a federal pesticide and antifungal and a to gnaw the water and non-fluent body is system animal and preparation method FIFRA (a) stipulated the injurious insect shape of.

The immediate determinant liquid system for killing at the dosage form method, wherein the bacteria growth amount of the measuring system or to the active microbicide sampling of the aqueous method of open and is time-consuming. Are method for determining the bacteria growth of the sampling of the liquid system with comprising a handle. The) is bacteria to grow, comprising generally type multiple microbicide to the system, a microorganism growth amount of till culture medium stable can reduce or. The aqueous method and good in the device of laboratory, time-consuming, a labour intensity of moreover the error is big. Position of the invention, not exist fast and determining to supply into the system and killing microorganism dosage accurately the scene analytic method. The invention relates to outer the growth composition or comprising a microbicide system, uniform with the proportion with the microbicide are at least one inert fluorescent material, wherein a drug adding to the microbicide the fluorescent additive layer to be determining through a a of the system is fast the microbicide amount. The basin bottom of the invention, the liquid system is the Water Body Is.

Use of pursuit monitoring industry water body is corrosion inhibitor and boiler scale inhibitor and used for processing of the effects of the male knowledge technology. Hoots the concentrations of simulating patent 4,783,314 claimed is made second transition metal pursuit material of fluorescence measuring method for monitoring corrosion inhibitor and boiler scale inhibitor. Hoots et al. the simulating patents 4,966,711 and 5,041,386 of five-pointed of upper and a fluorescent additive with the corrosion and/or the boiler scale inhibitor and is proportional second, is used for monitoring to assign the industrial water body is corrosion and/or the concentration of boiler scale inhibitor. The method and device thereof fluorescence the simulating patent 4,992,380,5,006,311 and 5,132,096 claimed is monitoring industry water treatment of. The simulating patent 5,128,419 and 5,171,450 claimed is a fluorescent part of the material of the soluble polymer concentration for monitoring of the industrial water treating process. Member patent 55) 003668(1980) claimed is stored into the lithium of a material indirect of microbicide concentration, atomic spectrometry absorption according for monitoring biocide concentration of use. The method claim is pursuit material publicly and obtaining results analysis for atom absorbing spectrophotometer. Compared to the fluorescence method, atomic absorbing spectrometry is quite expensive . Moreover, with the relates to a compound device and a open type flame and combustible gas supply and equal are not suitable for the opening country of the shortcoming.

Simulating patent 4,242,602 claimed is a monitoring multiple types of water treating components ultraviolet spectrophotometric method. The method relates to use with a special software's computer hardware's expensive and analyzing device; A suspension device can calibrate with special formed on the part. Moreover, so the water the expanding can change the adjusting. European patented claim 466303 claimed is a method, how relates to the treatment processing water comprises upper and material with the microbicide reaction. Continuous meter and microbicide reaction material, moreover is determined the microbicide concentration of the loss of the material. The method of troublesome, needs special device and comprises two or more of a separatedly.

The invention claims a turner convenient to use, and accurately determining the liquid system is, particularly the industrial water body is composed questions of the microbicide concentration's method solved arranged on listed.

A of the invention meshes end of the field of claims a is suitable for controlling the liquid system, particularly the industrial water body is a industry of the bacteria, mushroom, the protozoon and seaweed the non-spinal column animal of microorganism for killing composition, the composition of which the continuous of the wherein the system is connected with the fluorescence measuring method.

The purpose of the invention is of the field of claims the use pipette simple monitoring industry the two sides of which the liquid system body is continuous, fast and monitoring novel fluorescence head microorganism composition.

The purpose of the invention is of the field of claims a novel fluorescent biocide inner and outer ends of and concentration of microorganism for maintaining method.

The further purpose of the invention is of the field of claims a novel fluorescent biocide composition and a measuring system loss microbicide method.

The goals of the invention is a socket are as follows.

Special 1 indicates of the cooling industry at activeness to kill curing the micro-processing for production of the concentration and biocide (non-fluorescence pursuit material) part or exhausts completely.

Special 2 preparation for the invention composition control industry cooling mounted biocide the procedure and biocide feeding the comparison of the turn.

Special 3 expressed for use microbicide result, and preparation of during using the product feeding and continuous feeding, wherein the inert fluorescence compounds (with fluorescent method) and active microbicide (with HPLC) between the micro-processing.

Special 4 expressed for use microbicide result, and preparation of the micro-processing between inert fluorescence compounds and microbicide active ingredients basically.

And the upper, a of the invention goals end of the field of claims a novel fluorescent microbicide enrichments, the feeding convenient for and measuring with the industrial fluorimeter first. The other, based on the fluorescence reading, which is or the limit control the reel of the microbicide, and is fixed by the reading value of which. The substratum composition of the invention comprises (active ingredient) comprises 0.0005~10.0wt% inert organic fluorescent substance to the microbicide (active ingredient). Based on active microbicide weight is provided with the upper 0.005~2.0wt%, the most preferred connected 0.025~1.0wt% the is provided with a fluorescence organic compound. A card of the upper weight percent binding the fluorescence compounds amount of the biocide surface is, is in the range the upper ends or the lower limiting is not essential, a important middle of said according says body is adhered is arranged at composition can exist, wherein the lower microbicide concentration with for picking and a fluorescence measuring method. Therefore, the weight ratio of active microbicide and fluorescent capable of the 10∶1~1000∶1 of the dish. Capable of a higher in the fluorescent, wherein the is generally uneconomical, is nonessential.

Fluorescence organic compounds of said capable of applies from the material. The cleaning the fluorescence organic compounds essential requirements of can consider, good is: 1. Reinforcing to activeness to kill and around the bottom of microorganism, basically and second; 2. Is the industrial microbicide around the bottom system, basically and second; (3). Wherein fluorescence device is provided with a into system the wave length of the compounds to respectively; And 4. aerosol lines on or the connecting a of an microbicide diluent.

Outside the claim, wherein the fluorescent compounds of said upper part is of the concentration to into a of the liquid system, can be or aerosol fans are uniformly.

The clearly is the thin water body is, comprising a fluorescent compounds, wherein a of the concentration is basically is of.

Be used in the invention the fluorescence compounds, comprising following; the two and three sulfonation naphthalene, comprising wherein of salt, specifically each isomers of naphthalene single sulfonic acid and disulfonic acid a of the inert thereof is used for the invention. The naphthalene single sulfonic acid and disulfonic acid isomer and water-soluble, moreover generally of buy from the market, and can use the known fluorescent parsing method for detecting and lower of. The preferably naphthalene is unitary and disulfonic acid isomer of the naphthalene monosulfonic acid (“NSA”), for example 1-NSA and 2-NSA of salt and naphthalene disulfonic acid (“NDSA shape or a NDA”), for example 1,2-NDSA, 1,3-NDSA, 1,4-NDSA, 1,5-NDSA, 1,6-NDSA, 1,7-NDSA, 1,8-NDSA, 2,3-NDSA, 2,4-NDSA of salt. Of said inert tracers multiple (; the two and three sulfonation naphthalene and mixtures) generally with the environment preparation for industrial microbicide the Water Body Of. And preferably fluorescence thereof 2-NSA and 1,5-NDSA and according to the discovery reaching and high and at least about 540℃ (1004°F temperature), and 285℃ (545°F) at least 24 hours, wherein the pressure reaches and height of approximately 1500 pounds/a square inch and at least is subjected with the industrial water body and corresponding (, moreover surpasses a frequently) on the disposable sleeve, is thermostble. The pair of inert fluoresent thereof not vaporize of the steam.

A of the group of inert fluoresent tracers for the invention process, wherein the sulfonation derivatives of pyrene, for example 1,3,6,8) pyrene four sulfonic acid, and each pair of salts of the sulfonation pyrene derivatives. The other water-soluble pursuit material display fluorescences, wherein a common claims personnel to the field of obvious. And cleaning of equality, a traced biocide thereof are of the invention, the thereof according by good is: (1). Thermostble, is supplied the industrial microbicide assigns the system to place of the temperature and according to decompose;

(2). The first or Banlian of measuring, moreover cloth is supplied the measuring concentration of into industrial microbicide the system capable of convenient to carry and accurate and reappear; 3. Are to type the chemical part of into industrial microbicide the water usually, basically of the external material; 4. Cloth, no any one how type strips according into industrial microbicide system of water can possibly in the material consumption basically and is disturbed; 5. Is from coming, or folding usually to which is in a of part of the industrial microbicide the water with base, respectively; affected6. With a use of installing mop agent with inert thereof in the system for can be blend, thus simply not skin wherein potency; (7). Wanting with parallel to the industrial microbicide of the system the bottom part of the accommodating, moreover of any storing and transporting conditions of the surface of the stabilizing killing microbial agent; Not only and 8. in cushions anti-microorganism's system. Moreover, the is arranged; the base and environment safety.

Compositions and methods of the invention can be used for so-called non-oxidized and oxidized microbicide. Layer biocide of normal of the invention can be suitable for of obtain, comprising (, but not limited in the following materials: Hypochlorite bleaching agent, hydrogen with; acetyl hydroperoxide, living single potassium sulphate and containing chloro- further glycolylurea, two oxygen methyl ethyl group glycolylurea and chlorine isocyanuric acid salt. Compositions and methods of the invention can is also used for reaction form killing the biological composition the ingredients. The material of sodium comprising bromide and response and production hypobromite bleaching agent, which is with multiple living article to the hypochlorite bleaching agent foot sole strength material.

The invention can find the non-oxidized biocide of according to serviceable comprising a of result, comprising (, but not limited in the following materials: Two containing lower nitrilo-D propionamide and thiocyanogen methyl benzole and thiazole and methyl dithiocarbamates and four deuterium methyl 噻 two hydrazone thioketone (Tetrahy-drodimethyl thiadiazone thione), three butyl quicklime and bromo nitro group propylene glycol, the bromo nitro-styrene and dithio- cyanic acid Asia methyl and methyl/methyl different thiazole ketone, benzole and different thiazole ketone and lauryl guanidine hydrochloride, poly six methyl drug root, four methylol arrowhead sulphate, glutaraldehyde and alkyl group further phenmethyl ammonium chloride and two decyl further ammonium chloride, poly (oxygen ethenyl (further imino root) and two), decyl sulfo- ethanolamine and three butyl azines.

Is located fluorescent and so-called different thiazole ketone of material the invention (e.g. by Rohm and Haas Corporation with Kathon  materials are made of the), and 2) decyl (sulfo-) ethanolamine matched with the glutaraldehyde the preparation of.

Terminology of the article for a biocide) refers to for industrial and/or recreational and a is equal to demands pest control insect's water body is injurious insect, a reagent according to bacteria, mushroom, seaweed, protozoon and non-vertebrate and other pest insects of.

A preferred the composition of the invention is, a mixture for and 1.0wt% 10%1,3,6,8- pyrene four sulfonic of sodium (a) with a composed of a (1.5% active different thiazole ketones) 99wt% different thiazole ketone biocides.

The general composition of the invention according to the inert organic fluorescent substance and microbicide of the ration simple device is, one end of the fluorescence compounds and active microbicides is a dustproof the range method is made.

The hopes when is water body, wherein a water as the fluorescence compounds the diluent. The clearly for non-water body is, and diluent can be visible aerosol to the fluorescence compounds. Moreover the fluorescence compounds and diluent surface is able to the aerosol the system of each. Microbicide with multiple for carrying belt is in the polyoxyethylene diluent, comprising a fluorescent pursuit made of the invention can be used to the aerosol the polyoxyethylene diluent or can uniformly fragrant. Which is the water body and a biocide of the polyoxyethylene diluent comprising, comprising a thereof of such use can be visible easy or aerosol the flat dispersible of the water body. The clearly is made of the non-water body and a biocide of the polyoxyethylene diluent, comprising a thereof according and is can be visible is the dissolution or at least fans of the non-water body are.

Fixes the composition and a telescopic fluorescent of measuring device the invention can, and accurately determining the first for example (, but not limited in) is industry water treating and papermaking and other field microbicide gametocide concentration, which can accurately, and recovery invests which the microbicide the dosage according economically to the system a. Therefore, the is the improved of the field of claims corrector with misused industrial biocide ordinariest staggered method of independently, which is the biocide the dose not is correct to the system.

The other, the composition and method of this invention, are to the product are with the environment released with a important method for a certificate and recording from the industrial water body, and aim of the control emitting of virulent compounds. Moreover the invention also reduced of the greatest the dustproof the product dosage of microorganism control needed to provide the method. The invention claims further claims the control processing system (for example microbicide dosage frequency and amplitude) to the improved processing the anti-microorganism method behaviour. The invention microbicide comprising a monitoring way of inert thereof, 314 claims (merges an A/D converter through for example US-4,992,380 and US-4,783 of each substituting) about same. The invention can also determining biocide's flow arranged on liquid system, comprising capable of measuring the biocide of the exist easily or the area of the excessive concentration with. The invention is also suitable for determining the system the loss of biocide.

A of the invention for the treatment, wherein the meter is the system is of the system for killing the biological dose not according to know on the loss of biocide. The generally method comprises the following steps: a) to a liquid system is a 0.0005~10wt% basically is the inert fluorescence compounds the microbicide; b) is of the measuring in the system fluorescence compounds the fluorescence intensity, a of uniform to the system the first outer the organism, dosec) for determining with the known method for killing the biological dose with the system; ofAnd d) of the uniform of the biocide total amount of step b) for determining, deducts to measure the step (c) is reality for killing of the biological dose, calculates the biocide consumption.

The card of the upper explanation the surface of the measuring fluorescence compounds the step (C) and method of fluorescence. The method can be a enumerates plant the method any method, comprising the chromatography, the aqueous method of process or production method thereof. With a to determine to the biocide total level, a measuring the fluorescence. The method capable of a short time use, capable of the long time system, the thereof or a belt of the angle biocide a long and comprises a head part or the decomposition on the circuit.

The invention can also be used for into the microbicide to system automatic, and aim of make the biocide concentration is equal to or greater than of the inhibiting concentration lowly. The bottom of the invention, determining through a fluorescence the measuring system is the biocide amount. The pressure the fluorescence strength according is lower than the current value known, and fluorimeter part of the signal to the controller or the pump, a of type fixing biocide, till achieving telescopic fluorescent intensity. The fluorimeter part of the signal to the pump, alarm device or modem device, generally is in for known, so the article not give the discussion. The other, based on the through the loss result according of loss by, and arranged according to the proportional with the loss is the ration to the liquid system the biocide, a into the biocide to the system. The method can be used for of the system and system the biocide concentration is arranged or is higher than stipulate of the biocide inhibiting concentration layer lowly.

Usually; a fluoresent thereof in the microbicide composition of the invention the concentration is, and curve of the fluorescent radiations of lines concentration. Through a of comparison, for determining by linear radiating reaction the concentration of. The high concentration grains, a observe the ideal behaviour negative the deviation. The working curve of still determining on the thereof the concentration, or a pendant till grains concentration the sampling simple dilution of the linear radiating reaction range. Around the electrodes thin sampler, of which the fluoresent thereof concentration methods, to liquid effusion extractor and so on, wherein the concentration is mounted in the concentration range of steps. A fluorescence to the biological material the invention composition, preferably determining with a fluorescence method. The fluorescence method, the known the length of the light wave injection sampler, the electric comprising the biocide sampling device. The wave length for is fixed by the sampling radio-fluorescence frequency. Moreover, so the system and collaterals components of the frequency - panel the known device is a fluorescent. A sampling stimulation, the measuring strong the radiating according to from the. Is suitable for the field fluorimeter is capable of changing each channel to buy. Is suitable for the field production fluorimeter can be from suitable agile Sizhou of the Nalco of to buy TRASAR superiorly  the made commodity.

When the telescopic fluorescent reagent, a obtain the frequency-identification device of gametocide supplier seat head. The cannot obtain the table, for determining for stimulation and measuring through the simple measuring (radiating) with length.

An through for to the invention microbicide of the fluorescent reagent, a immediate is or ppt with a price and high portable instrument is a (100 billion and number of baikal) layer is a daily quantitative of ppm layer thereof. Although is aligned elaborated is connected with the fluorescent material pursuit to the biocide, wherein a not higher violate the invention flavour and range effect, a according to with is supplied into system the micro-processing of industrial microbicide there is proportional directly to into the fluorescence pursuit material of the system.

Wherein this invention the composition and measuring for controlling water body is micro-organisms and algae grower, briefing the device is assorted.

The invention can is widely used for the microbicide concentration with affects wherein performance of each system, for example the water body is, Water Yifei the water mixing system or the non-water liquid the system, a specific of with levigator, waste treating, a solid separating and located into a a oil field, paper is, cooling water system and equal.

The system according the invention can medicine, and one other surface control the water liquid system with the bathing pool and mineral artificial pond, the paper machine and a oil and preparation field water supply and for processing comprising a industry cold water system and entertainment the biological growth.

The invention's fluorescent biocide further can be used for preventing the water body is at growth; the water body is a (, but not limited in food) and cosmetic, and soap, shampoo and equal to be to determine the microbicide amount of the product with for controlling quality or under the common directly sleeved fast.

The explain with examples the invention, used to this invention the microbicide composition of the following explanation of the industrial open loop cold water system.

Hoots US-4,783,314 (merged is a through the magnifier each substituting) publicly and pipette detail discussed for matching pursuit material monitoring boiler scale and corrosion coating concentration of the cold water system. Although microbicide's spending rate is wider than faster a common boiler scales or the corrosion coating spending rate, and introduced of the article background technology viewpoint part of Hoots, how capable of comprises a pursuit material biocide of the industrial water treating.

The successful of the invention pursuit industrial biocide, storing the user to determine, the system exhausts the active ingredient the invention (to system abnormally, wherein the non active agents comprising a thereof to biocide into a dosage of) is, and sleeved with by the active ingredient continuous system with consumption.

Special 1 expressed of the cooling industry at activeness to the biological of the concentration with a functional the micro-processing between the tier which. the equation is: ln2 (v/F the δ) =T; the formula of THE collecting system. Moreover the F δ said (release material, drift and leakage) from the volumetric flow rate according of the system flows out, T-SHAPED represents of the constant speed dilution and collecting effect of seaweed to the deep mixing the first biocide the system and a time. The biocide active ingredient (, but not exceptionally can, in subjected to the time of the stable and concentration according fluoresent thereof) part or exhausts of approximately is placed 5. The concentration interval the stable and; the is lower than the active ingredient theoretically constant device required there are two times.

Finger and special at the 1, preferably exhausts the active ingredients biocide of the pathological system, the active which (concentration the C δ) can indicate with the equation lower with a time micro-processing: Cδ = (Fa/Fδ); Ca&lsqb1-e- (Fδ /v) t&rsqb);) is in > and volume constantly (dv/dt=0), Fa is current the system the biocide volumetric flow rate, Ca is arranged on the product the active ingredient concentration, F flows out the system (e.g. release material, drift leakage and volumetric flow rate . Moreover the is a time. Formula of the bottom of the material balance of active ingredients concentration's on for mixing system is to a differential equation. The active which is stable concentration and 5 of keeping the times of the restore to 97% and. Special 1 drew the equation diagram of curves, the concentration and aperture T) is equal to ln2 (v/F the δ) and a timing function.

The around the vote loss of active ingredients, interval the stable and concentration is different from the theory concentration. The case, which is consumes constant, comprising active interval which the stable and concentration is lower than the theoretical value, formed is lower than the loss two times. For example, so the stable and concentration is 100mg/l moreover consumes constantly the 5mg/l, comprising stable interval the concentration is left (100mg/l-2×5mg/l) or 90mg/l. A common circumstances foldable supporting geometric progression and limiting and induction are with the invention is: C δ =Ca (Fa/F δ) and s (0.5n-1) /-0.5 of the formulation, the volume of the constant (Dv/dt=-0), Ca of the product the active ingredient concentration, Fa to the system biocide volumetric flow rate, the F δ is flows out the system (release material, drift leakage and volumetric flow rate, Ca (Fa/F the δ) without of the loss the stable and concentration, MIDDLE of the loss system of active ingredients, moreover n is the same time (T) =ln2 (v/F) and a time tier of. Otherwise, wherein the stable and handle (a CaFa/F δ) thickly and same time tier of the n) known. A solves the equation to PROMOTE extract can be simply the accurate and convenient surveying surface is traced the interval loss system of biocide. Special 1 one layer of the constant system consumes claim 5% situations the equation diagram of curves. The curve of the equation of the picture is left side 100% embarking expressed. A curve is between 1 the left corner expressed loaded for of active ingredients first of and circumstance according afterward contains system loss of neglect with reconstituted.

Explain to the detail the invention claims a lower by such.

By such 1 and 1 weight 10wt%1,3,6,8- latifoliae pyrene four sulfonic of sodium brine lixiviants and 80,72 water, each of 13.39 Kathon of  (886-F of guest Spain and France and Asia, Fylla results the Fillat Rohm; &amp Different thiazole ketone biocide's 14.1wt% active infusion device according Haas Corporation buys) and 6.79 parts by weight the copper nitrate 41.2wt% with solutions frame is bought of Ohio Cincinnati Shepard of the preparation, comprising a fluorescent belt biocide composition. The mixture is made of simple mixing method, comprising the pyrene sulfonic acid on 0.1 weight parts capable and active ingredient.

By such 2) is prevent of the material 1 to supply refinery's into industrial open loop cooling system. Reinforcing into the system comprises basically of the inert fluorescence compounds to the there biocide, and is fluorescence method and liquid chromatography monitoring, and aim of determining the fluorescence monitoring the effect. The interval loss system of biocide is very small. The liquid chromatography to claim expensive device, a complex method and long time of obtain and; because of and the practical scene method. To use preparation, a data are connected with one end of laboratory and results with the lower relevance with the liquid chromatography's type between the special preservation of scene fluorometric assay. Between the two method wherein the relevant water-proof, the invention claims a quick, simple and accurate economical and scene analytic method. The measuring, wherein a of the commodity Shadowscan II Type fluorimeter is suitable Linow Sizhou of the Nalco of connection pin connected with the fluorescence measuring. The fluorimeter (stimulation) and 400nm (emitting) is installed in the length 365nm.

For feeding microbicide method for in turn pursuit biocide system surpasses to use, improved cooling tower's killing micro-organisms controlling.

Special preparation 2 biocide processing feeding comparison and is capable. When for non-oxidized biocide of the preliminarily anti-micro-organism treatment, usually and circumference of the feeding 2 or 3 times. Based on the top material (arranged cold water) is made of a plurality frequent lower dose of a dose of medicine or other dilution and not television and practical, the is hard determining the biocide concentration. When the biocide concentration is higher than wherein inhibiting concentration lowly, the biocide effect and moreover, the is lower than wherein Mm used lowly generally without an effect. Biocide according studies of treating system of inhibiting concentration lowly is 25~30ppm. A card from special 2 for the fluorescence control method concentration is a PLC controller reliably, moreover of the logarithmic system and protecting so it non-microorganism growth phenomenon for continuously; compared to a feeding are in turn; a rubber a dose of medicine a lower moveable late arrival lower disposable vagina a dose of medicine is 48 method of basically head with a protective function. The fluorescence biocide disposal it is otherwise, wherein around the prevention system presented microorganism to provide a continuous and not disturbed biocide feeding.

Special 3 preparation of which the biocide concentrations between the liquid the chromatography and invention method for relevance. For research of the implementation of claims from indicate of the liquid the chromatography and invention method of two days of relevance, wherein the data of shown is between 4 to.

Special expressed 4) of the reference this invention method uses the microbicide of the industrial cooling system for testing result, preferably the result according a liquid the chromatography by. The special 4, an X-RAY plate (- shaft expressed) of which the product biocide active ingredient with the invention the ppm thereof, and a Y shape (moves shaft expressed) of which the product biocide active ingredient with a liquid the chromatography the ppm thereof. Special 4 preparation of compared with a fluorescence composition method and liquid chromatography of the invention is, the results of the scene and which is provided with a through relevance of the industrial cooling system and capable earlier.

By such 3 made by such 1 pursuit to the biological material so the cooling industry at to revolve. The biocide known is a low dose is virulent to the fish. The tower's the material an fish into of water flow; the discover the fish death arranged on the water. The natural deduction surface is a rechargeable to the operators in cooling tower, thinks of the fish of drains water of the cooling other end microbicides or gametocide agents installing mop according discovered invasive. And to the fluorescence and water-proof of the water, the thereof in the water of the biocide for suitable for use of the support layer. The sleeve and cooling end of the side shoulder avoid the responsibility of fish death.

By such 4) by such 1 pursuit killing a biomaterial so the cooling industry at to revolve. An into the tower's the fish material of water flow, discovered the fish death arranged on the water. The water to the current of water made the fluorescence and water-proof thereof layer to indicate the excessive biocide is supplied to the end. Moreover the excessive biocide discharged of the current of water correspondingly, the invention and biocide and down in operation and consistently. And and confirmation and shock-absorption active biocide to water, the cooling tower system main dealt with the fish death is responsible for.

By such 5 paper is clear water control system the use and bacteria growth with industrial microbicide processing. Although top is successful, and with remarkable fluctuation of the dosage and use microbicide. Biocide is a to the paper is type, a reinforcing 0.1wt% 1,3,6,8) pyrene four sulfonic of sodium salt active ingredient. The other; and an industrial fluorimeter of the aqueous system return circuit, the fluorimeter capable of providing the 365nm electric wave length and reads the 400nm emitting device is. The system, is fixed on the signal control microbicide feeding to microbicide's feeding pump and fluorimeter, a control at a. Not only for the invention method and composition, and connected to the system microbicide dosage to achieve obvious and adjusting.

By such 6 by examples are of the invention the control zebra shell and sodium bromide the effect. The Midwestern wherein the area, the scene formed hypobromite) processing water drinking to control the zebra shell of watering system and a gas and sodium bromide agent. Sodium to bromide infusion apparatus of the system is; a 0.1wt%1,3,6,8- pyrene four sulfonic of sodium salt. Is taking aqueous system other is provided with an industrial fluorimeter, adjusting fluorimeter of a to provide the 365nm electric wave length and reads the 400nm fluorescence emitting light. Assistant on the fluorimeter the alarming device connected, so it is biocide processing is lower than the processing layer is disposed to the alarming. The fluorimeter for common gametocide feeding calibration method of bromide salt. Wherein the fluorescent intensity, wherein the indicates sodium bromide feeding interrupt, alarm device sounding, to the making for the factory to solve the feeding problem.

By such 7, wherein placed to make bacterial content to maintain the safety edge, is the hydrogen with a control hotel's spring water. At least a limiting of personnel, the superoxide concentration aqueous method of test is conducted and. Is an industrial fluorimeter the spring catchment's circulation line. The fluorimeter opening pump by type hydrogen with any a to the system, so the system and fluorescent layer of set. The system for calibrates multiple days later, wherein a fluorescent preparation intensity when the biocide is lower than of the concentration according to claims a safe residual concentration steps, the fluorimeter and superoxide automatic. The invention method can be past manual system automatic. Moreover, the conveying is to guaranteeing of the amount of biocide lapping enhanced the safety.

The system consumptions of by such 8, biocides is made of microorganism control of the electrodes of substances. The system according the combined commodity supply of the implement such 1) is by such 2). Microbicide stable the concentration with the liquid chromatography, and theory stable the concentration with is known of the acquiring thereof. For mathematical relationship of the front, determining the interval loss system of the biocide active ingredient. Cooling system comprises a quantitative know the biocide is consumed the degree. And the operation and capable of the remedial treating to reduce the loss system (for example for cleaning removing biomembrane, gametocide a removing reducible compounds and equal). Moreover the recovery of the contribution quantitative of the operation and so the foldable supporting publicly from the invented of reducing system loss with a great degrees or eliminated is not hoped. The method can reduce display consume body the biological dose moreover of skin so to the microbicide volume, such a cost. The biocide is a suspension, so the invention, the steps at least one virulent material to prevent successful micro-organisms controlling, and can also improve the exercise the integrated safety.

By such 9) is arranged on an open loop water cooling system of gametocide processing factory, according a of the cushion ration containing by such 11) is basically the inert fluorescence compounds the product, such activeness to the microbiological product concentration to achieve 150ppm. A surveying the middle system water (release material the fluorescence compounds fluorescence, by interval the concentration of the operating the method 10 significantly is higher than based on the field dosage of the system is capacity . Moreover the fact the fluorescence measuring preparation for biocide concentration clearly is higher than 250ppm of multiple method. The conclusion is from the mirror is: The biocide parallel to the release the material emitting point . Moreover the mixing during type microbicide product and foot. By the thickness is not uniform, wherein each medicament refers to into the large-tonnage product is dispersed into to release to foresee accurately suitably, accordingly of the waste products. A subject by the fluorometric assay concentration, so the operators in know end of the biocide between the seat for distributed distributor is concave-convex, moreover a locking the positions of the biocide adding position of transfusion to the automatic the fluorescence measuring to indicate of the biocide and process for distributed on the uniformly mixing other gears. Promulgates of the system with multiple fluorescent measuring, comprising a non-uniform mixing phenomenon of the other parts of system. The more effective of biocide dramatically decompression the cost.

By such 10, the use of layer halogen biocide is limited so the paper pulp and papermaking field and hydrogen with a more and substances. And for, an of enough a telescopic of the pan handle to the technological process to be H2O2 and ground (30wt% with) infusion device. Back of the pot, parallel to the ration 1,5) naphthalene disulfonic acids, so the fluorescence compounds concentration to achieve 0.013wt%. The shock-absorption, the compositions are 2 days later is stable (>94%). (Of concentration is 0.001wt%) is provided with corresponding electromagnetic valves are wherein disodium salt and other side of the base inert fluorescence compounds 1,3,6,8) pyrene four sulfonic acid four sodium salt. And a inert the fluorescence compounds traced hydrogen with a can be used for papermaking field, the reinforcing to of the contents of the system, comprising the invention is the inert fluorescence compound with the micro-processing of the oxidant is proportional. The oxidant the base in the paper machine can easily and fast the immediate of. And residual superoxides of the system loss of the oxidant can (of hydrogen with four and residual hydrogen with amount of) and meter is between the comparison fluorescence intensity the extending and calculates the method of the loss.

Superoxide total amount of parallel with fluorescent method, wherein the residual for determining with the method.

Considering the invention of the explanation, we requested the following each one of platinum: