Crystalline polypropylene, process for preparing the same, polypropylene composition, and thermoformed article

CA 02256707 1998-11-26 o - r _ι --. a v>... .

i.iii ——· . - *.. L A ί i tî 1

DESCRIPTION

CRYSTALLINE POLYPROPYLENES, PROCESS FOR PREPARING

THEREOF, POLYPROPYLENE COMPOSITIONS, AND THERMOFORMED

PRODUCTS

FIELD OF THE ART

The present invention concerns crystalline polypropylenes, that are especially excellent in hardness and rigidity, high in melt tension, and have excellent molding properties, process for preparing such polypropylenes, and compositions and thermoformed products obtained from such polypropylenes.

BACKGROUND ART

Crystalline polypropylenes are excellent in hardness, rigidity, heat resistance, surface gloss 20 (luster), etc., and have been conventionally used in various applications. In particular, crystalline polypropylenes are used in automobile bumpers, etc., that require high rigidity.

Such crystalline polypropylenes are used upon 25 blending various modifiers according to the application,

CA 02256707 1998-11-26 and are generally blended with an impact resistance modifier, such as polyethylene, rubber material, etc.

Priorly, in order to compensate for the lowering of rigidity that accompanies the addition of the impact resistance modifier, an inorganic filler, such as talc, has been added.

However, there is a limit to the rigidity improvement effect that can be provided by the addition of an inorganic filler, and for example in systems using 10 a large amount of impact resistance modifiers, it was difficult to obtain a polypropylene resin composition of adequately high rigidity even upon addition of an inorganic filler.

Polypropylene resins that are even more improved in rigidity were thus desired especially in thermoformed product applications requiring hardness and high rigidity.

It is known that the rigidity of polypropylene can be improved by raising its crystallinity 20 (stereoregularity), and it is also considered that the rigidity of polypropylene is so desired that the wider molecular weight distribution (Mw/Mn) of the crystalline components (components insoluble in 64°C decane) contained in the polypropylene is obtained.

CA 02256707 1998-11-26

The present inventor also carried out research toward improvement of the rigidity of polypropylene, and found that even if a crystalline polypropylene contains components insoluble in 64°C decane of a wide molecular weight distribution (Mw/Mn), the polypropylene cannot always be sufficiently satisfactory in rigidity, elongation, and toughness if the polypropylene has a wide molecular weight distribution in both the high molecular weight side and low molecular weight side.

The present inventor then found that crystalline polypropylenes and polypropylene compositions containing crystalline components (components insoluble in 64°C decane), which not only have a wide molecular weight distribution (Mw/Mn) but also have a wide molecular weight distribution (Mz/Mw), as determined from the zaverage molecular weight and weight-average molecular weight of said components insoluble in decane, of 5 or more, and which have a pentad isotacticity of 98% or more, and for which the frequency dependence value D of the viscoelastic loss tangent under constant strain is

4.0 or more, are extremely excellent in rigidity, and has thereby been lead to complete the present invention.

Polypropylenes of wide molecular weight distribution have been proposed priorly, and for example in Japanese laid-open patent publication No. 59-172507

CA 02256707 1998-11-26 is disclosed the production of a polypropylene (PP) by two-stage polymerization to produce a high molecular weight component (35 to 65wt.% of polypropylene of (η) =

1.8 to 10dl/g in the first stage) and a low molecular weight component (65 to 35wt.% of polypropylene of (η) =

0.6 to 1.2dl/g in the second stage), and then finally to produce polypropylene of (η) = 1.2 to 7dl/g and Mw/Mn of to 20. Also, in Japanese laid-open patent publication

No. 4-370103 is disclosed the production of a high molecular weight component having MFR = 0.0001 to 10g/10 minutes in the stage of producing the component of highest molecular weight in multiple-stage polymerization and a low molecular weight component of

MFR = 10 to 1000g/10 minutes in the stage producing the low molecular weight component. In Japanese laid-open patent publication No. 8-3223 are disclosed polypropylenes having Mw = 1.2 to 2 million, Mw/Mn of 30 to 70, and containing 7 to 15wt.% of a high molecular weight component of Mw > 5 million and 20 to 50wt.% of a low molecular weight component of Mw < 100 thousand.

However the polypropylenes that are disclosed in these patent publications all have a wide distribution both in the high molecular weight side and low molecular weight side and such polypropylenes cannot always be

CA 02256707 1998-11-26 sufficiently satisfactory in rigidity, elongation, and toughness as mentioned above.

In Japanese laid-open patent publication No. 4202507 is disclosed a process of producing PP by 5 polymerizing a PP component (0.1 to 35wt.%) of (η) = 5 to 40dl/g using a prepolymerized catalyst and then polymerizing the remaining PP components in another polymerizer to obtain PP having MFR = 0.1 to 2000g/10 minutes. In Japanese patent publication No. 7-5668 is disclosed highly crystalline polypropylenes having an

MFR of 0.1 to 200g/10 minutes with which the MFR value and the ratio of absorbance at 997cm¹ and 973cm^-1(997cm^-1/973cm^_1) in the IR spectrum satisfy specific relationships, said IR absorbance ratio of the initial precipitate component, that comprises 2 to 3wt.% of the total amount dissolved when the polypropylene is dissolved in xylene, is 0.97 or more, and the Mw of said precipitate component/Mw of total PP is 3 or more.

Although the above patent publications disclose polypropylenes that contain high molecular weight components, none of the publications disclose the widening of the molecular weight distribution at the high molecular weight side without widening the molecular weight distribution at the low molecular 25 weight side.

CA 02256707 2002-12-04

72932-292

DISCLOSURE OF THE INVENTION

The crystalline polypropylenes of the present 5 invention are characterized in containing components insoluble in 64°C decane that satisfy the following characteristics (1) to (5):

(I) The intrinsic viscosity (η) (in 135°C decalin) is

0.5 to lOdl/g?

(2) the molecular weight distribution (Mz/Mw) as determined by gel permeation chromatography (GPC; solvent: o-chlorobenzene, measurement temperature :

140°C) is 5 or more;

(3) the pentad isotacticity (mramm percentage), which is a stereoregularity index determined by the measurement of the ¹³C-NMR spectrum, is 98% or more;

(4) the D value, determined using formula (1) below from the loss tangents, tanSo.os and tanôio measured at the frequencies, 0.05rad/sec and lOrad/sec, respectively, by a melt viscoelasticity measuring device under a temperature of 230°C and constant strain, and said loss tangent measurement frequencies, is 4.0 or more; and (5) the molecular weight distribution (Mw/Mn) as determined by gel permeation chromatography (GPC? solvent: o-dichlorobenzene, measurement temperature: 140°C) is 6.0 to 20.

CA 02256707 1998-11-26 log(0.05) - log(10) log ( tan5₀.05) - Ιθα (tanôio) (1)

It is preferable for the number-average molecular weight Mn of the components insoluble in 64°C decane to be 25000 or more.

It is preferable for the crystalline polypropylene of the present invention to contain 60wt.% (% by weight) or more of the above-described components insoluble in

64°C decane.

It is preferable for the crystalline polymer to contain a prepolymer as a nucleating agent.

The abovementioned polypropylene may specifically be a homopolypropylene or a propylene block copolymer.

The crystalline polypropylene can be produced by multiple-stage polymerization of propylene, optionally, along with another monomer in the presence of a catalyst for preparing highly stereoregular polypropylene.

In the present invention, it is preferable to perform the abovementioned multiple-stage polymerization in three stages, wherein in the first stage crystalline polypropylene having an intrinsic viscosity (η) of 8 to 20dl/g is produced at an amount

CA 02256707 1998-11-26 corresponding to 0.5 to 15wt.% of the finally obtained crystalline polypropylene, in the second stage crystalline polypropylene having an intrinsic viscosity (η) of 3 to 10dl/g is produced at an amount corresponding to 0.5 to 30wt.% of the finally obtained crystalline polypropylene, and in the third stage crystalline polypropylene having an intrinsic viscosity (η) of 0.8 to 4.0dl/g is produced at an amount corresponding to 99 to 55wt.% of the 10 finally obtained crystalline polypropylene.

The multiple-stage polymerization may also be carried in two stages, wherein in the first stage crystalline polypropylene having an intrinsic viscosity (η) of 8 to 20dl/g is produced at an amount corresponding to 0.5 to 15wt.% of the finally obtained crystalline polypropylene and in the second stage crystalline polypropylene having an intrinsic viscosity (η) of 0.8 to 4.0dl/g is produced at an amount corresponding to 99.5 to 85wt.% of 20 the finally obtained crystalline polypropylene.

In the present invention, the crystalline polypropylene may be obtained by blending two or more types of crystalline polypropylene that differ in intrinsic viscosity (η), and may be obtained for example by blending 0.5 to 15wt.% of crystalline polypropylene

CA 02256707 2002-12-04

72932-292 having an intrinsic viscosity (η) of 8 to 20dl/g with

99.5 to 85wt.% of crystalline polypropylene having an intrinsic viscosity (η) of 0.8 to 4.0dl/g.

The polypropylene composition of the present 5 invention comprises components soluble in 140°C decane and, optionally, components insoluble in 140^DC decane, in which the components soluble in 140°C decane that are also components insoluble in 64°C decane are crystalline polypropylenes that satisfy the characteristics (1) to (5) given above.

This polypropylene composition preferably contains

70wt.% or more of the components soluble in 140°C decane and it is preferable that the components insoluble in

64°C decane are included in an amount of 60wt.% or more of the components soluble in 140°C decane.

It is preferable that the polypropylene composition of the present invention contains a nucleating agent.

It is also preferable with the polypropylene composition of the present invention that the components 20 soluble in 140°C decane that are also components soluble in 64°C decane comprise an ethylene/a-olefin copolymer or a styrene copolymer, and that the components insoluble in 140°C decane conprise an inorganic filler selected from among talc, glass fiber, potassium titanate, and barium sulfate.

CA 02256707 1998-11-26

The thermoformed product of the present invention is formed of the crystalline polypropylene or polypropylene composition described above.

BEST MODE FOR CARRYING OUT THE INVENTION

Crystalline polypropylenes (may also be referred to hereinafter simply as polypropylenes) and polypropylene compositions containing such crystalline polypropylenes are presented of the present invention.

First, a description of the crystalline polypropylenes shall be given.

In the present invention, the term, polymerization, may be used to refer not only to homopolymerization but also inclusively to copolymerization, and the term, polymer, may be used to refer not only to a homopolymer but also inclusively to a copolymer.

Crystalline Polypropylene

The crystalline polypropylene of the present invention contains the below-described components insoluble in 64°C decane at an amount of 60wt.% or more, preferably 65 to 100wt.%, and more preferably 70 to lOOwt.%.

CA 02256707 1998-11-26

These components insoluble in 64°C decane are those which are considered to be the crystalline components in the polypropylene, and in the present specification, the components insoluble in 64°C decane may also be referred to as crystalline components.

The components insoluble in 64°C decane of the crystalline polypropylene (polymer) are the components which precipitate at 64°C after said polymer is dissolved in 140°C decane.

Specifically, approximately 500ml of decane and approximately 2g of sample (polypropylene) are weighed accurately and introduced into a transparent flask set inside a glass, double-tube type constant temperature bath and then dissolved completely by stirring for approximately 1 hour at 140°C. Thereafter, the temperature of the solution is dropped gradually to 64°C while stirring, and after the solution temperature has become constant at 64°C, stirring is continued a day and night and the precipitated components insoluble in decane are separated by filtration from a glass filter (or a metal net of 300 mesh, filter paper, etc., according to the circumstances).

The components insoluble in decane (powder-form) that have been obtained by filtration are then dissolved completely in approximately 500ml of decane at

CA 02256707 1998-11-26 approximately 140°C, then reprecipitated in excess acetone, and then separated by filtration. The decaneinsoluble components that have thus been obtained are dried a day and night under reduced pressure in a vacuum drier set to approximately 80°C and then weighed accurately.

The components soluble in 64°C decane are obtained by pouring the filtrate obtained by the abovementioned hot filtration at 64°C into 1 to 2 liter of methanol and then precipitating by adding 2 to 2 liter of acetone.

The components insoluble in 64°C decane (crystalline component) obtained by decane separation of the crystalline polypropylene as described above satisfy all of the following characteristics (1) to (4):

(1) The intrinsic viscosity (η) (in 135°C decalin) of the components insoluble in 64°C decane is 0.5 to

10dl/g, preferably 1.0 to 8.0dl/g, and preferable still at 1.2 to 5.0dl/g.

(2) The molecular weight distribution (Mz/Mw) of the 20 components insoluble in 64°C decane as determined by gel permeation chromatography (GPC; solvent: ochlorobenzene, measurement temperature: 140°C) is 5 or more, preferably 5.5 to 30, and especially preferable

6.0 to 20.

CA 02256707 1998-11-26

In the GPC of the components insoluble in 64°C decane, a greater Mz/Mw value of the molecular weight distribution (Mz/Mw), determined from the z-average molecular weight and the weight-average molecular weight, indicates that the distribution is wider at the high molecular weight side.

In the present invention, the Mz/Mw value of the components insoluble in 64°C decane is 5 or more as described above and a large amount of the high molecular 10 weight components is thus contained.

The molecular weight distribution (Mw/Mn) of the components insoluble in 64°C decane is preferably 5.0 or more and especially preferable 6.0 to 20.

Also, the number-average molecular weight of the components insoluble in 64°C decane should be 25000 or more, preferably 28000 or more, and preferably still at

30000 or more.

(3) Though the components insoluble in 64°C decane of polypropylene generally is the crystalline component, the components insoluble in 64°C decane of the crystalline polypropylene of the present invention are especially high in crystallinity, and the pentad isotacticity (mmmm percentage), which is a stereoregularity index, of the crystalline components is

CA 02256707 1998-11-26

98% or more, preferably 98.2 to 100%, and preferably cjL··. , 17

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DESCRIPTION

CRYSTALLINE POLYPROPYLENES, PROCESS FOR PREPARING

THEREOF, POLYPROPYLENE COMPOSITIONS, AND THERMOFORMED

PRODUCTS

FIELD OF THE ART

The present invention concerns crystalline polypropylenes, that are especially excellent in hardness and rigidity, high in melt tension, and have excellent molding properties, process for preparing such polypropylenes, and compositions and thermoformed products obtained from such polypropylenes.

5

BACKGROUND ART

Crystalline polypropylenes are excellent in hardness, rigidity, heat resistance, surface gloss 20 (luster) , etc., and have been conventionally used in various applications. In particular, crystalline polypropylenes are used in automobile bumpers, etc., that require high rigidity.

I

CA 02256707 1998-11-26 log(0.05) - log(10) log(tanôo.o5) - log(tanôio) (1)

The abovementioned loss tangent (tanÔ) value is specifically determined as follows.

That is, the components insoluble in 64°C decane of the crystalline polypropylene are press molded at 230°C and formed into a disk-shaped sheet of 2mm thickness and

12.5mm radius. Using this sheet, the loss elastic moduli, G'(MPa) and G(MPa), at a frequency of

0.05rad/sec and the loss elastic moduli, G' and G, at a frequency of 10rad/sec are measured at 230°C and under constant strain with a melt viscoelasticity measuring device to determine the loss tangent (tanÔ = G/G') values at the respective frequencies.

It is considered that with the crystalline components (components insoluble in 64°C decane) of the crystalline polypropylene, the larger the frequency dependence value D of the viscoelastic loss tangent under constant strain, the greater the content of high 20 molecular weight components.

The crystalline polypropylenes according to the invention that contain components insoluble in 64°C decane that satisfy the above characteristics (1) to (4)

I

CA 02256707 1998-11-26 are especially excellent in hardness and rigidity as well as high in melt tension and excellent in molding properties .

In particular, the crystalline polypropylenes of 5 the present invention contain components insoluble in

64°C decane (crystalline component) that have a wide molecular weight distribution (Mz/Mw), determined from the z-average molecular weight and weight-average molecular weight, of 5 or more, a pentad isotacticity of

98% or more, and a viscoelastic characteristic as specified by the D value of 4.0 or more, and a polypropylene that contains such crystalline components exhibits extremely high rigidity. Furthermore, excellent toughness is exhibited when the components insoluble in 64°C decane have a number-average molecular weight Mn of 25000 or more.

Polypropylenes of the prior art, in evaluations of components insoluble in 64°C decane having (η) value equivalent to that of the present invention, did not 20 satisfy the characteristics of molecular weight distribution (Mz/Mw) of 5 or more, a viscoelastic characteristic as specified by the D value of 4 or more, and a pentad isotacticity of 98% or more at the same time.

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Though it is preferable for the components insoluble in 64°C decane (crystalline components) with the above-described characteristics to be usually comprised only of units derived from propylene, units that are derived from minute amounts of other monomers may also be contained according to necessity as long as the objects of the present invention are not spoiled.

Other monomers include for example, α-olefins other than propylene, such as ethylene, 1-butene, 1-pentene,

1-hexene, 4-methyl-1-pentene, 3-methyl-l-pentene, 1heptene, 1-octene, 1-nonene, 1-decene, 1-dodecene, etc., vinyl compounds, such as styrene, vinylcyclopentene, vinylcyclohexane, vinylnorbornane, etc., vinyl esters, such as vinyl acetate, etc, unsaturated organic acids and derivatives thereof, such as maleic anhydride, etc., conjugated dienes, and non-conjugated polyenes, such as dicyclopentadiene, 20 1,4-hexadiene, dicyclooctadiene, methylene norbornene,

5-ethylidene-2-norbornene, etc. Among the above, ethylene and α-olefins of 4 to 10 carbon atoms are preferable. Also, two or more of the above may be copolymerized.

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The crystalline polypropylene of the present invention is not specified in particular besides having components insoluble in 64°C decane that satisfy the characteristics given above as the components insoluble in 64°C decane, and the components soluble in 64^QC decane may be atactic polypropylene components or copolymerized rubber components such as those mentioned above. For example, olefin rubber components or conjugated diene rubber components, etc., may be contained as the components soluble in 64°C decane.

The crystalline polypropylene may specifically be a homopolypropylene or a propylene block copolymer. In the present invention, even if a large amount of a rubber component, such as EPR (ethylene/propylene copolymer), is contained as the components soluble in 64°C decane along with the abovementioned components insoluble in 64°C decane, excellent rigidity is exhibited. It is preferable that such a polypropylene is a propylene block copolymer since it will then be excellent in impact resistance as well as rigidity, and a propylene block copolymer which has the intrinsic viscosity (η) of the rubber component is 0.5 to 10dl/g is especially preferable.

It is also preferable for the crystalline polypropylene of the present invention to contain a

CA 02256707 1998-11-26 homopolymer or copolymer of a branched olefin, such as

3-methyl-1-butene, 3,3-dimethyl-l-butene, 3-methyl-lpentene, 3-ethyl-l-pentene, 4-methyl-1-pentene, 3methyl-1-hexene, 4-methyl-1-hexene, 4,4-dimethyl-lhexene, 4,4-dimethyl-l-pentene, 4-ethyl-l-hexene, 3ethyl-1-hexene, 3,5,5-trimethyl-1-hexene, vinylcyc1opentane, vinyleye1ohexane, vinyleye1oheptane, vinylnorbornane, allylnorbornane, styrene, dimethylstyrene, allylbenzene, allyltoluene, allylnapthalene, vinylnaphthalene, etc., as a prepolymer. Among the above, 3-methyl-1-butene, etc., are especially preferable.

Such a prepolymer derived from a branched olefin acts as a nucleating agent for crystallization.

The above described crystalline polypropylene of the present invention should have a melt flow rate (MFR

ASTM D1238-65T, 230°C, under load of 2.16kg) of usually

0.1 to 200g/10 minutes and preferably 0.5 to 100g/10 minutes. The molding properties are satisfactory when the melt flow rate value is within such ranges.

Production of Crystalline Polypropylene

Although the process for preparing the crystalline polypropylene of the present invention is not specified in particular as long as the polypropylene can be

CA 02256707 1998-11-26 produced so as to contain the above-described components insoluble in 64°C decane, crystalline polypropylene can be formed for example by multiple-stage polymerization of propylene, in which a catalyst for preparing highly 5 stereoregular polypropylene is used to perform the polymerization of the second stage onward in the presence of a polymer obtained in the first stage and upon changing the polymerization conditions.

With the present invention, it is preferable to use a catalyst for preparing highly stereoregular polypropylene in the production of polypropylene containing the above-described crystalline components, and for example, a catalyst, comprised of;

(a) a solid titanium catalyst component containing 15 magnesium, titanium, halogen, and electron donor, (b) an organometallic compound, and (c) an organosilicon compound (c-1) of formula (i) below or a compound having two or more ether bonds between which are interposed a plurality of atoms, can be used.

R^anSi(0R^b)4__n . . . (i) (In the above formula, n is 1, 2, or 3, at least one of the R^a ' s is a secondary or tertiary hydrocarbon group, the R^a ' s may be the same as or different from each other when n is 2 or 3, R^b is a hydrocarbon group of 1 to 4

CA 02256707 1998-11-26 carbon atoms, and the R^{b 1} s may be the same as or different from each other when 4-n is 2 or 3.)

The abovementioned solid titanium catalyst component (a) may be prepared by bringing a magnesium compound, titanium compound, and electron donor in contact with each other.

Magnesium compounds that have reducing ability and magnesium compounds that do not have reducing ability can be used as the magnesium compound to be used in the 10 preparation of a titanium catalyst component.

Here, magnesium compounds having a magnesium-carbon bond or a magnesium-hydrogen bond may be given as examples of magnesium compounds that have reducing ability. Specific examples of such magnesium compounds 1 5 that have reducing ability include dimethylmagnesium, diethylmagnesium, dipropylmagnes ium, dibutylmagne sium, diamylmagnesium, dihexylmagnesium, didecylmagnesium, ethylmagnesium chloride, propylmagnesium chloride, butylmagnesium chloride, hexylmagnesium chloride, amylmagnesium chloride, butylethoxymagnesium, ethylbutylmagnesium, butylmagnesium hydride, etc.

Specific examples of magnesium compounds that do not have reducing ability include magnesium halides, such as magnesium chloride, magnesium bromide, magnesium iodide, magnesium fluoride, etc.; alkoxymagnesium

CA 02256707 1998-11-26 halides, such as methoxymagnesium chloride, ethoxymagnesium chloride, isopropoxymagnesium chloride, butoxymagnesium chloride, octoxymagnesium chloride, etc.; aryloxymagnesium halides, such as phenoxymagnesium chloride, methylphenoxymagnesium chloride, etc.;

alkoxymagnesiums, such as ethoxymagnesium, isopropoxymagnesium, butoxymagnesium, n-octoxymagnesium,

2-ethylhexoxymagnesium, etc.; aryloxymagnesiums, such as phenoxymagnesium, dimethylphenoxymagnesium, etc.; and carboxylates of magnesium, such as magnesium laurate, magnesium stearate, etc.

These magnesium compounds without reducing properties may be compounds derived from the abovementioned magnesium compounds with reducing properties or may be compounds derived in the process of preparing the catalyst component. To derive a magnesium compound that does not have reducing ability from a magnesium compound with reducing ability, the magnesium compound with reducing ability may be brought in contact with a polysiloxane compound, halogen-containing silane compound, halogen-containing aluminum compound, ester, alcohol, halogen-containing compound, ketone or other compound with an active carbon-oxygen bond.

The magnesium compound may also be derived from metal magnesium in the process of catalyst preparation.

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Two or more magnesium compounds may be used in combination.

The abovementioned magnesium compound may form a complex compound or double compound with aluminum, zinc, 5 boron, beryllium, sodium, potassium, or other metal or may be a mixture with another metal compound.

Although various magnesium compounds besides those mentioned above can be used in the present invention, it is preferable that the magnesium compound take the form 10 of a halogen-containing magnesium compound in the solid titanium catalyst component (a) that is obtained in the final stage. Thus in the case where a magnesium compound that does not contain a halogen is used, it is preferable to subject the magnesium compound to a contact reaction with a halogen-containing compound in the process of preparing the catalyst component.

Among the above, magnesium compounds that do not have reducing ability are preferable, halogen-containing magnesium compounds are preferable still, and magnesium 20 chloride, alkoxymagnesium chloride, and allyloxymagnesium chloride are especially preferable.

With the present invention, it is preferable that the magnesium compound is used in liquid form in the process of catalyst component preparation, and in the 25 case where a magnesium compound among the abovementioned

CA 02256707 1998-11-26 magnesium compounds is a solid, the magnesium compound can be made liquid in form by the use of an electron donor.

In the case where a magnesium compound among the abovementioned magnesium compounds is a solid, the magnesium compound can be made liquid in form by the use of an electron donor (liquifier).

For the liquifier, use can be made of an alcohol, phenol, ketone, aldehyde, ether, amine, or pyridine, etc., indicated below or tetraethoxytitanium, tetra-npropoxytitanium, tetra-i-propoxytitanium, tetrabutoxytitanium, tetrahexoxytitanium, tetrabutyoxyzirconium, tetraethoxyzirconium, or other metal acid ester, etc., as an electron donor.

Among the above, use of an alcohol or metal acid ester is especially favorable.

The reaction of liquefying the solid magnesium compound is generally carried out by a method in which the solid magnesium compound is brought in contact with 20 an abovementioned liquifier and heating as necessary.

This contact is normally carried out at a temperature of to 200°C, preferably 20 to 180°C, and preferably still at 50 to 150°C.

Also a hydrocarbon solvent, etc., may be made to coexist in the liquefying reaction, and for example, an

CA 02256707 1998-11-26 aliphatic hydrocarbon, such as pentane, hexane, heptane, octane, decane, dodecane, tetradecane, kerosene, etc.;

an alicyclic hydrocarbon, such as cyclopentane methylcyclopentane, cyclohexane, methylcyclohexane, cyclooctane, cyclohexene, etc.; a halogenated hydrocarbon, such as dichloroethane, dichloropropane, trichloroethylene, chlorobenzene, etc.; or an aromatic hydrocarbon, such as benzene, toluene, xylene, etc., may be used.

In the preparation of the solid titanium catalyst component (a), it is preferable to use a quadrivalent titanium compound of the following formula as the titanium compound.

5 Ti (OR) gX₄-g (In the above formula, R indicates a hydrocarbon group, X indicates a halogen atom, and g satisfies 0 < g < 4.)

Specific examples of such a titanium compound include tetrahalogenated titaniums, such as TiCl₄, TiBr₄,

Til₄, etc . ;

CA 02256707 1998-11-26 trihalogenated alkoxytitaniums, such as Ti(OCH₃)Cl₃, Ti(OC₂H₅ ) Cl₃ , Ti(O-n-C₄H9 ) Cl₃ , Ti(OC₂H₅)Br₃ ,

Ti(0-iso-C₄H9)Br₃ , etc . ;

dihalogenated dialkoxytitaniums, such as 5 Ti (OCH₃) ₂C1₂, Ti (OC₂H₅) ₂Cl₂ , Ti (O-11-C4H9) ₂Cl₂,

Ti(OC₂H₅)₂Br₂, etc.;

monohalogenated trialkoxytitaniums, such as Ti(OCH₃)₃Cl, Ti{OC2H5)3CI, Ti (O-n-C₄H₉ ) 3CI, Ti ( OC₂H₅ ) ₃Br, etc . ; and tetralkoxytitaniums, such as Ti(OCH₃)₄, Ti(OC₂H5)₄,

Ti(O-n-C₄H9)₄, Ti(0-iso-C₄H9> ₄, Ti(0-2-ethylhexyl)₄, etc .

Among the above, halogen-containing titanium compounds are preferable, tetrahalogenated titaniums are also preferable, and titanium tetrachloride is particularly preferable. Two or more of the above titanium compounds may be used as combinations. Also, the titanium compound may be used upon dilution in a hydrocarbon compound or halogenated hydrocarbon compound, etc.

Examples of the electron donor used in the preparation of the solid titanium catalyst component (a) include alcohols, phenols, ketones, aldehydes, esters of organic and inorganic acids, organic acid halides, ethers, acid amides, acid anhydrides, ammonia, amines,

CA 02256707 1998-11-26 nitriles, isocyanates, nitrogen-containing cyclic compounds, oxygen-containing cyclic compounds.

More specific examples include alcohols of 1 to 18 carbon atoms, such as methanol, ethanol, propanol, pentanol, hexanol, octanol, 2-ethylhexanol, dodecanol, octadecyl· alcohol, oleyl alcohol, benzyl alcohol, phenylethyl alcohol, cumyl alcohol, isopropyl alcohol, isopropylbenzyl alcohol, etc.;

phenols of 6 to 20 carbon atoms, which may contain 10 a lower alkyl group, such as phenol, cresol, xylenol, ethyl phenol, propyl phenol, nonyl phenol, cumyl phenol, naphthol, etc.;

ketones of 3 to 15 carbon atoms, such as acetone, methyl ethyl ketone, methyl isobutyl ketone, acetophenone, benzophenone, acetylacetone, benzoquinone, etc . ;

aldehydes of 2 to 15 carbon atoms, such as acetaldehyde, propionaldéhyde, octylaldehyde, benzaldehyde, tolaldehyde, naphthaldehyde, etc.;

organic acid esters of 2 to 30 carbon atoms, such as methyl formate, methyl acetate, ethyl acetate, vinyl acetate, propyl acetate, octyl acetate, cyclohexyl acetate, ethyl propionate, methyl butyrate, ethyl valerate, methyl chloroacetate, ethyl dichloroacetate, methyl methacrylate, ethyl crotonate, ethyl

CA 02256707 1998-11-26 cyclohexenecarboxylate, methyl benzoate, ethyl benzoate, propyl benzoate, butyl benzoate, octyl benzoate, cyclohexyl benzoate, phenyl benzoate, benzyl benzoate, methyl toluate, ethyl toluate, amyl toluate, ethyl ethylbenzoate, methyl anisate, n-butyl maleate, diisobutyl methylmalonate, di-n-hexyl cyclohexenecarboxylate, diethyl nadicate, diisopropyl tetrahydrophthalate, diethyl phthalate, diisobutyl phthalate, di-n-butyl phthalate, di-2-ethylhexyl phthalate, γ-butyrolactone, δ-valerolactone, cumarin, phthalide, ethyl carbonate, etc.;

acid halides of 2 to 15 carbon atoms, such as acetyl chloride, benzoyl chloride, toluyl chloride, anisyl chloride, etc. ;

ethers of 2 to 20 carbon atoms, such as methyl ether, ethyl ether, isopropyl ether, butyl ether, amyl ether, anisole, diphenyl ether epoxy-p-methane, etc. ;

acid amides, such as acetic acid amide, benzoic acid amide, toluic acid amide, etc . ;

acid anhydrides, such as acetic anhydride, phthalic anhydride, benzoic anhydride, etc.;

amines, such as methylamine, ethylamine, dimethy lamine, diethylamine, ethylenediamine, tetramethylenediamine, hexamethylenediamine, tributylamine, tribenzylamine, etc.;

I

CA 02256707 1998-11-26 nitriles, such as acetonitrile, benzonitrile, trinitrile, etc.;

nitrogen-containing ring compounds including pyrroles, such as pyrrole, methylpyrrole, dimethylpyrrole, etc.; pyrroline; pyrrolidine; indole;

pyridines, such as pyridine, methylpyridine, ethylpyridine, propylpyridine, dimethylpyridine, ethylmethylpyridine, trimethylpyridine, phenylpyridine, benzylpyridine, pyridine chloride, etc.; piperidines;

quinolines; isoquinolines; etc.; and oxygen-containing ring compounds, such as tetrahydrofuran, 1,4-cineole, 1,8-cineole, pinolfuran, methylfuran, dimethylfuran, diphenylfuran, benzofuran, cumaran, phthalan, tetrahydropyran, pyran, dihydropyran,

5 etc. .

Multivalent carboxylates having the skeletons expressed by the general formulae below can be given as particularly preferable examples of organic acid esters.

R³ —C—COOR¹

R⁴—C—COOR² r3 COOR¹

R⁴ COOR²

R³ — C— OCOR⁵

R⁴—C— OCOR⁶

In the above formulae, R¹ indicates a substituted or non-substituted hydrocarbon group. R² , R⁵, and R^s

CA 02256707 1998-11-26 indicates hydrogen or substituted or non-substituted hydrocarbon groups. R³ and R⁴ indicates hydrogen or substituted or non-substituted hydrocarbon groups and, preferably at least, one of either a substituted or non5 substituted hydrocarbon group. R^ and R⁴ may be joined together to form a cyclic structure. In the case where a hydrocarbon group among R¹ to R⁶ is substituted, the substituent contains a heteroatom, such as N, O, S, and has a group such as C-O-C, COOR, COOH, OH, SO3H, -C-N-C, 10 NH2, etc.

Specific examples of such a multivalent carboxylate include :

aliphatic polycarboxylates, such as diethyl succinate, dibutyl succinate, diethyl methylsuccinate, diisobutyl a-methylglutarate, diethyl methylmalonate, diethyl ethylmalonate, diethyl isopropylmalonate, diethyl butylmalonate, diethyl phenylmalonate, diethyl diethylmalonate, diethyl dibutylmalonate, monooctyl maleate, dioctyl maleate, dibutyl maleate, dibutyl 20 butylmaleate, diethyl butylmaleate, diisopropyl βmethylglutarate, diallyl ethylsuccinate, di-2-ethylhexyl fumarate, diethyl itaconate, dioctyl citraconate, etc. ;

alicyclic polycarboxylates, such as diethyl 1,2cyclohexanecarboxylate, diisobutyl 1,2CA 02256707 1998-11-26 cyclohexanecarboxylate, diethyl tetrahydrophthalate, diethyl nadicate, etc.;

aromatic polycarboxylates, such as monoethyl phthalate, dimethyl phthalate, methylethyl phthalate, monoisobutyl phthalate, diethyl phthalate, ethylisobutyl phthalate, di-n-propyl phthalate, diisopropyl phthalate, di-n-butyl phthalate, diisobutyl phthalate, di-n-heptyl phthalate, di-2-ethylhexyl phthalate, di-n-octyl phthalate, dineopentyl phthalate, didecyl phthalate, benzylbutyl phthalate, diphenyl phthalate, diethyl naphthalenedicarboxylate, dibutyl naphthalenedicarboxylate, triethyl trimellitate, dibutyl trimellitate, etc.; and esters of heterocyclic polycarboxylic acids, such as 3,4-furandicarboxylic acid.

Other examples of multivalent carboxylates include esters of long-chain dicarboxylic acids, such as diethyl adipate, diisobutyl adipate, diisopropyl sebacate, di-nbutyl sebacate, di-n-octyl sebacate, di-2-ethylhexyl sebacate, etc ..

Furthermore, with respect to the electron donor, the organosilicon compounds and polyether compounds mentioned below, water, and anion, cation, and non-ionic surfactants, etc., may be used as electron donor (c).

CA 02256707 1998-11-26

Among the above, it is preferable to use a carboxylate with the present invention, and it is especially preferable to use a multivalent carboxylate, in particular, a phthalate.

Two or more types of such electron donors may be used in combination.

In bringing an abovementioned titanium compound, magnesium compound, and electron donor in contact with each other, other reaction reagents of silicon, phosphorus, aluminum, etc., may coexist, and a carrier may be used to prepare a solid titanium catalyst component (a) that is carried on a carrier.

Examples of such a carrier include AI2O3, SiC>2,

B2O3, MgO, CaO, T1O2, ZnO, SnO2, BaO, ThO, and resins, such as styrene-divinylbenzene copolymer, etc. Among these, AI2O3, SiO2z and styrene-divinylbenzene copolymer can be used favorably.

Although the solid titanium catalyst component (a) can be prepared employing various methods including 20 known methods, a few examples of the preparation method shall be described briefly below.

(1) A method in which a hydrocarbon solution of the magnesium compound containing the electron donor (liquifier) is subject to contact reaction with the 25 organometallic compound, and the solid is subject to

CA 02256707 1998-11-26 contact reaction with the titanium compound after being precipitated or while being precipitated.

(2) A method in which a complex comprised of the magnesium compound and the electron donor is subject to a contact reaction with an organometallic compound and then subject to a contact reaction with the titanium compound.

(3) A method in which the contact product of an inorganic carrier and the organic magnesium compound is contacted and reacted with the titanium compound and the electron donor. With this method, said contact product may be contacted and reacted with a halogen-containing compound and/or an organometallic compound.

(4) A method in which a carrier on which the magnesium compound is carried is obtained from a mixture of a magnesium compound solution, containing the liquifier and optionally a hydrocarbon solvent, the electron donor, and the carrier, and said carrier is thereafter brought in contact with the titanium compound.

(5) A method in which a solution containing the magnesium compound, titanium compound, electron donor and optionally a hydrocarbon solvent is brought in contact with a carrier.

CA 02256707 1998-11-26 (6) A method in which a liquid-form organic magnesium compound is contacted with a halogencontaining titanium compound. In this case, an electron donor is used at least once.

(7) A method in which after a liquid-form organic magnesium compound is contacted with a halogencontaining titanium compound, the product is contacted with the titanium compound. In this case, an electron donor is used at least once.

(8) A method in which an alkoxy group containing a magnesium compound is contacted with a halogencontaining titanium compound. In this case, an electron donor is used at least once.

(9) A method in which a complex comprised of an alkoxy group containing magnesium compound and the electron donor is contacted with the titanium compound.

(10) A method in which a complex comprised of an alkoxy group containing magnesium compound and the electron donor is contacted with an organometallic compound and then contacted and reacted with the titanium compound.

(11) A method in which the magnesium compound, electron donor, and titanium compound are contacted and reacted in an arbitrary order. Prior to the reaction, the respective components may be pretreated with the

CA 02256707 1998-11-26 electron donor, a reaction assistant such as an organometallic compound or a halogen-containing silicon compound.

(12) A method in which a liquid-form magnesium compound without reducing ability is reacted under the presence of an electron donor with a liquid-form titanium compound to precipitate a solid magnesiumtitanium complex.

(13) A method in which the reaction product obtained by (12) is furthermore reacted with the titanium compound.

(14) A method in which the reaction product obtained by (11) or (12) is furthermore reacted with the electron donor or the titanium compound.

(15) A method in which a solid product obtained by crushing the magnesium compound and the electron donor and the titanium compound is treated with a halogen, a halogen compound, or an aromatic hydrocarbon. This method may include a process in which just the magnesium compound, a complex comprised of the magnesium compound and the electron donor, or both of the magnesium compound and the titanium compound is/are crushed. Alternatively, pretreatment with a reaction assistant followed by treatment with a halogen, etc., may follow the crushing process. Organometallic compounds and

CA 02256707 1998-11-26 halogen-containing silicon compounds may be used as the reaction assistant.

(16) A method in which the magnesium compound is crushed and then contacted with the titanium compound.

The electron donor is used along with a reaction assistant according to necessity in the process of crushing and/or contacting the magnesium compound.

(17) A method in which the compound obtained by any of (11) to (16) above is treated with a halogen, a 10 halogen compound, or an aromatic hydrocarbon.

(18) A method in which the contact reaction product of a metal oxide, organic magnesium, and a halogen-containing compound is contacted with the electron donor and preferably the titanium compound.

(19) A method in which a magnesium salt of an organic acid, a magnesium compound such as an alkoxymagnesium and an aryloxymagnesium is brought in contact with the titanium compound electron donor and, optionally, a halogen-containing hydrocarbon.

(20) A method in which a hydrocarbon solution containing the magnesium compound and an alkoxytitanium is brought in contact with the electron donor and, optionally, a titanium compound. In this process, it is preferable that a halogen-containing compound such as a halogen-containing silicon compound coexists.

CA 02256707 1998-11-26 (21) A method in which a solid magnesium-metal (aluminum) complex is precipitated by reacting a liquidform magnesium compound without reducing ability with an organometallic compound and then reacting the complex with the electron donor and the titanium compound.

Although the usage amounts of the respective components used in the contact process differ according to the preparation method and cannot be specified in general, it is desirable to use, for example, 0.01 to 10 moles and preferably 0.1 to 5 moles of electron donor and 0.01 to 1000 moles and preferably 0.1 to 200 moles of titanium compound per mole of magnesium compound.

The solid titanium catalyst component (a) thus obtained contains magnesium, titanium, halogen, and electron donor, and in this solid titanium catalyst component (a), it is desirable for the halogen/titanium ratio (atomic ratio) to be approximately 2 to 200 and preferable at approximately 4 to 100, the electron donor/titanium ratio (molar ratio) to be approximately 20 0.01 to 100 and preferable at approximately 0.02 to 10, and the magnesium/titanium ratio (atomic ratio) to be approximately 1 to 100 and preferable at approximately 2 to 50 .

In the present invention, an organometallic 25 compound (b) is used as a catalyst along with the solid

CA 02256707 1998-11-26 titanium catalyst component (a) described above. As this organometallic compound, a compound that contains a metal selected from among groups I to III of the periodic table is preferable. Specific examples include the following organic aluminum compounds, complex alkylates of a group I metal and aluminum, and organometallic compounds of a group II metal.

(b-1) Organic aluminum compounds of the general formula, R¹!^! (OR² ) _nHpXg (wherein R¹ and R² are hydrocarbon groups which may be the same as or different from each other, with each normally containing 1 to 15 and preferably 1 to 4 carbon atoms, X indicates a halogen atom, m is a number that satisfies 0 < m < 3, n is number that satisfies 0 < n < 3, pisa number that satisfies 0 < p <3, q is a number that satisfies 0 < q < 3, and m + n + p + q - 3) .

(b-2) Complex alkylates, comprising a group I metal and aluminum and having the general formula, M¹AlR¹4 (wherein M¹ is Li, Na, or K and R¹ is the same as the above).

(b—3) Dialkylates, comprising a group II or group

III metal and having the general formula, R¹R²M² (wherein R¹ and R² are the same as the above and M² is Mg, Zn, or

Cd) .

Examples of organic aluminum compounds belonging to (b-1) described above include:

CA 02256707 1998-11-26 compounds of the formula,

Rl_mAl(OR2)₃_i_n (wherein R¹ and R² are the same as the above and m is a number that preferably satisfies 1.5 < m < 3);

compounds of the formula,

Rl_mAl-X3-m (wherein R¹ is the same as the above, X is a halogen, and m preferably satisfies 0 < m < 3);

compounds of the formula,

0 Rl_mAlH₃-m (wherein R¹ is the same as the above and m preferably satisfies 2 < m < 3); and compounds of the formula,

R¹rnAl(OR²)_nXq

5 (wherein R¹ and R² are the same as the above, X is a halogen, 0 < m < 3, 0 < n < 3, 0 < q < 3, and m + n + q = 3) .

Specific examples of aluminum compounds of (b-1) include trialkylaluminums, such as triethylaluminum, tributylaluminum, etc.; trialkenylaluminums, such as triisoprenylaluminum, etc . ;

dialkylaluminum alkoxides, such as diethylaluminum ethoxide, dibutylaluminum butoxide, etc.; alkylaluminum sequialkoxides, such as ethylaluminum sesquiethoxide, butylaluminum sesquibutoxide, etc.;

CA 02256707 1998-11-26 partially alkoxylated alkylaluminums with an average composition expressed by R¹2.5Al (OR²) 0.5/ etc . ; dialkylaluminum halides, such as diethylaluminum chloride, dibutylaluminum chloride, diethylaluminum bromide, etc.;

partially halogenated alkylaluminums, including alkylaluminum sesquihalides, such as ethylaluminum sesquichloride, butylaluminum sequichloride, ethylaluminum sesquibromide, etc.; and alkylaluminum dihalides, such as ethylaluminum dichloride, propylaluminum dichloride, butylaluminum dibromide, etc . ;

dialkylaluminum hydrides, such as diethylaluminum hydride, dibutylaluminum hydride, etc. ;

alkylaluminum dihydrides, such as ethylaluminum dihydride, propylaluminum dihydride, etc., and other partially hydrogenated alkylaluminums; and partially alkoxylated and halogenated alkylaluminums, such as ethylaluminum ethoxychloride, butylaluminum

0 butoxychioride, ethylaluminum ethoxybromide, etc.

Also, organic aluminum compounds in which two or more aluminum atoms are bonded via an oxygen atom or nitrogen atom can be given as compounds similar to (b

1). Examples of such compounds include 2 5 (C₂H₅) ₂A1OA1(C₂H₅)2 , (C₄H₉)₂A1OA1(C4H9)2z

CA 02256707 1998-11-26 (C2H5) ₂A1N(C2H5) Al (C2H5) 2, and aluminoxanes, such as methylaluminoxane.

Examples of the above-described compounds of (b-2) include

LiAl(C₂H₅)4,

LiAl(C7H15) 4, etc .

Among these, organic aluminum compounds, especially trialkylaluminums are favorable.

Two or more of organometallic compounds of (b) can be used in combination.

In addition to the above-described titanium catalyst component (a) and organometallic compound (b) used as catalysts, an organosilicon compound (c-1) or a compound having two or more ether bonds having a plurality of atoms interposed in between (c-2) is used as an electron donor in the present invention.

The organosilicon compounds (c-1) used in the present invention are of the following formula.

0 R^anSi (OR^b) 4__n ...(i)

In the above formula, n is 1, 2, or 3, each of the

R^a's is a secondary or tertiary hydrocarbon group when n is 1, at least one of the R^a's is a secondary or tertiary hydrocarbon group when n is 2 or 3, the R^a ' s

CA 02256707 1998-11-26 may be the same as or different from each other, each of the R^b,s is a hydrocarbon group of 1 to 4 carbon atoms, and the R^b's may be the same as or different from each other when 4-n is 2 or 3.

Examples of the secondary or tertiary hydrocarbon group in the organosilicon compound <c-l) of formula (i) include cyclopentyl groups, cyclopentenyl groups, cyclopentadienyl groups, such groups with a substituent, and hydrocarbon groups in which the carbon adjacent the

Si is a secondary or tertiary carbon.

Specific examples of substituted cyclopentyl groups include cyclopentyl groups with an alkyl group, such as the 2-methylcyclopentyl group, 3-methylcyclopentyl group, 2-ethylcyclopentyl group, 2-n-butylcyclopentyl group, 2,3-dimethylcyclopentyl group, 2,4dimethylcyclopentyl group, 2,5-dimethylcyclopentyl group, 2,3-diethylcyclopentyl group, 2,3,4trimethylcyclopentyl group, 2,3,5-trimethylcyclopentyl group, 2,3,4-triethylcyclopentyl group, tetramethylcyclopentyl group, tetraethylcyclopentyl group, etc.

Examples of substituted cyclopentenyl groups include cyclopentenyl groups with an alkyl group, such as the 2-methylcyclopentenyl group, 325 methylcyclopentenyl group, 2-ethylcyclopentenyl group,

CA 02256707 1998-11-26

2-n-butylcyclopentenyl group, 2,3-dimethylcyclopentenyl group, 2,4-dimethylcyclopentenyl group, 2,5dimethylcyclopentenyl group, 2,3,4trimethylcyclopentenyl group, 2,3,55 trimethylcyclopentenyl group, 2,3,4triethylcyclopentenyl group, tetramethylcyclopentenyl group, tetraethylcyclopentenyl group, etc .

Examples of substituted cyclopentadienyl groups include cyclopentadienyl groups with an alkyl group, such as the 2-methylcyclopentadienyl group, 3methylcyclopentadienyl group, 2-ethylcyclopentadienyl group, 2-n-butylcyclopentadienyl group, 2,3dimethylcyclopentadienyl group, 2,4dimethylcyclopentadienyl group, 2,515 dimethylcyclopentadienyl group, 2,3diethylcyclopentadienyl group, 2,3,4trimethylcyclopentadienyl group, 2,3,5trimethylcyclopentadienyl group, 2,3,4triethylcyclopentadienyl group, 2,3,4,520 tetramethylcyclopentadienyl group, 2,3,4,5tetraethylcyclopentadienyl group, 1,2,3,4,5pentamethylcyclopentadienyl group, 1,2,3,4,5pentaethylcyclopentadienyl group, etc.

Examples of hydrocarbon groups in which the carbon adjacent Si is a secondary carbon include i-propyl

CA 02256707 1998-11-26 group, s-butyl group, s-amyl group, a-methylbenzyl group, etc., and examples of hydrocarbon groups in which the carbon adjacent Si is a tertiary carbon include tbutyl group, t-amyl group, a, a'-dimethylbenzyl group, adamantyl group, etc.

Examples of organosilicon compounds (c-1) of formula (i) in which n is 1 include trialkoxysilanes, such as cyclopentyltrimethoxysilane,

2-methylcyclopentyltrimethoxysilane, 2,310 dimethylcyclopentyltrimethoxysilane, cyclopentyltriethoxysilane, iso-butyltriethoxysilane, tbutyltriethoxysilane, cyclohexyltrimethoxysilane, eyelohexyltriethoxysilane, 2-norbornanetrimethoxysilane, 2-norbornanetriethoxysilane, etc.

Examples in which n is 2 include dialkoxysilanes, such as dicyclopentyldiethoxysilane, tbutylmethyldimethoxysilane, t-butylmethyldiethoxysilane, t-amylmethyldiethoxysilane, dicyclohexyldimethoxysilane, eyelohexylmethyldimethoxysilane, cyclohexylmethyldiethoxysilane, 2norbornanemethyldimethoxysilane, etc., and dimethoxy compounds of the following formula (ii)

CA 02256707 1998-11-26

<img file="CA2256707C_D0001.tif" />

In the above formula, each of R^a and R^c is each independently a cyclopentyl group, substituted 5 cyclopentyl group, cyclopentenyl group, substituted cyclopentenyl group, cyclopentadienyl group, substituted cyclopentadienyl group, or a hydrocarbon group in which the carbon adjacent the Si is a secondary or tertiary carbon.

Examples of such dimethoxy compounds of formula (ii) include dicyclopentyldimethoxysilane, dicyclopentenyldimethoxysilane, dicyclopentadienyldimethoxysilane, di-t-butyldimethoxysilane, di(2-methylcyclopentyl)dimethoxysilane, di(3-methylcyclopentyl)dimethoxysilane, di (2-ethylcyclopentyl) dimethoxysilane, di (2,3-dimethylcyclopentyl) dimethoxysilane, di (2,4-dimethylcyclopentyl) dimethoxysilane, di(2,5-dimethylcyclopentyl)dimethoxysilane, di(2,3-diethylcyclopentyl)dimethoxysilane, di(2,3,4-trimethylcyclopentyl)dimethoxysilane,

CA 02256707 1998-11-26 di (2,3,5-trimethylcyclopentyl·)dimethoxysilane, di(2,3,4-triethylcyclopentyl)dimethoxysilane, di (tetramethylcyclopentyl)dimethoxysilane, di (tetraethylcyclopentyl) dimethoxysilane, di(2-methylcyclopentenyl)dimethoxysilane, di(3-methylcyclopentenyl)dimethoxysilane, di(2-ethylcyclopentenyl)dimethoxysilane, di(2-n-butylcyclopentenyl) dimethoxysilane, di(2,3-dimethylcyclopentenyl)dimethoxysilane, di(2,4-dimethylcyclopentenyl)dimethoxysilane, di(2,5-dimethylcyclopentenyl)dimethoxysilane, di(2,3,4-trimethylcyclopentenyl)dimethoxysilane, di(2,3,5-trimethylcyclopentenyl)dimethoxysilane, di(2,3,4-triethylcyclopentenyl)dimethoxysilane, di(tetramethylcyclopentenyl)dimethoxysilane, di (tetraethylcyclopentenyl)dimethoxysilane, di{2-methylcyclopentadienyl)dimethoxysilane, di (3-methylcyclopentadienyl)dimethoxysilane, di (2-ethylcyclopentadienyl)dimethoxysilane, di(2-n-butylcyclopentenyl)dimethoxysilane, di (2,3-dimethylcyclopentadienyl)dimethoxysilane, di(2,4-dimethylcyclopentadienyl)dimethoxysilane, di{2,5-dimethylcyclopentadienyl)dimethoxysilane, di {2,3-diethylcyclopentadienyl)dimethoxysilane,

5 di (2,3,4-trimethylcyclopentadienyl)dimethoxysilane,

CA 02256707 1998-11-26 di(2,3, 5-trimethylcyclopentadienyl)dimethoxysilane, di(2,3,4-triethylcyclopentadienyl) dimethoxysilane, di (2,3,4,5-tetramethylcyclopentadienyl) dimethoxysilane, di(2, 3, 4,5-tetraethylcyclopentadienyl)dimethoxysilane, di(l,2,3,4,5pentamethylcyclopentadienyl)dimethoxysilane, di (1,2,3,4,5-pentaethylcyclopentadienyl)dimethoxysilane di-t-amy1-dimethoxys ilane, di(a,a'-dimethylbenzyl)dimethoxysilane, di(adamantyl)dimethoxysilane, adamantyl-t-butyldimethoxysilane, eyelopentyl-t-butyldimethoxysilane, diisopropyldimethoxysilane, di-s-butyldimethoxysilane, di-s-amyldimethoxysilane, isopropyl-s-butyldimethoxysilane, etc.

Examples of compounds of formula (i) in which n is include monoalkoxysilanes, such as tricyclopentylmethoxysilane, 20 tricyclopentylethoxysilane, dieyelopentylmethylmethoxysilane, dicyclopentylethylmethoxysilane, dicyclopentylmethylethoxysilane, eyelopentyldimethylmethoxysilane,

CA 02256707 1998-11-26 eyelopentyldiethylmethoxysilane, cyclopentyldimethylethoxysilane, etc .

Among the above, dimethoxysilanes, especially dimethoxysilanes of formula (ii) are preferable, and to be more specific, dicyclopentyldimethoxysilane, di-tbutyldimethoxysilane, di (2methylcyclopentyl)dimethoxysilane, di(3methylcyclopentyl) dimethoxysilane, and di-tamyldimethoxysilane are preferable.

Two or more of the abovementioned organosilicon compounds (c-1) may be used in combination. In the compound used in the present invention having two or more ether bonds between which are interposed a plurality of atoms (shall also be referred to hereinafter as polyether compound)(c-2), the atoms that exist between the ether bonds is one or more of atom selected from among carbon, silicon, oxygen, sulfur, phosphorus, and boron, and the number of such atoms is two or more. Preferably, a relatively bulky 20 substituent, or to be more specific, a substituent of two or more carbon atoms, preferably three or more carbon atoms with a straight-chain, branched, or cyclic structure, preferably a branched or cyclic structure, is bonded to the atoms between the ether bonds. A compound is also preferable with which a plurality, preferably 3

CA 02256707 1998-11-26 to 20, preferably still 3 to 10, and preferably still more 3 to 7 carbon atoms are contained in the atoms that exist between the two or more ether bonds.

Compounds of the following formula can be given as examples of such a polyether compound.

p22 pn+1 R²ⁿ r24 i i i i

R²¹-C-O-C- ... -C-O-C-R²⁶

II II _r23 _R1 _Rn _r25

In the above formula, n is an integer that 10 satisfies 2 &lt; n &lt; 10, each of R¹ to R^2S is a substituent having at least one element selected from among carbon, hydrogen, oxygen, halogen, nitrogen, sulfur, phosphorus, boron, and silicon, and any of R¹ to R²⁶, preferably R¹to R²ⁿ may jointly form a ring other than the benzene ring and may contain an atom other than a carbon atom in the main chain.

Specific examples of such polyether compounds include

2-(2-ethyIhexyl)-1,3-dimethoxypropane,

2-isopropy1-1,3-dimethoxypropane,

2-butyl-1,3-dimethoxypropane,

2-s-butyl-1,3-dimethoxypropane,

2-cyclohexyl-l,3-dimethoxypropane,

CA 02256707 1998-11-26

2-phenyl-1,3-dimethoxypropane,

2-cumyl-l,3-dimethoxypropane,

2-(2-phenylethyl)-1,3-dimethoxypropane,

2-(2-cyclohexylethyl)-1,3-dimethoxypropane,

2-(p-chlorophenyl)-1,3-dimethoxypropane,

2-(diphenylmethyl)-1,3-dimethoxypropane,

2-(1-naphthyl)-1,3-dimethoxypropane,

2-(2-flurophenyl)-1,3-dimethoxypropane,

2-(1-decahydronaphthyl)-1,3-dimethoxypropane,

2-(p-t-butylphenyl)-1,3-dimethoxypropane,

2.2- dicyclohexyl-1,3-dimethoxypropane,

2.2- dicyclopentyl-l,3-dimethoxypropane,

2.2- diethyl-1,3-dimethoxypropane,

2.2- dipropyl-1,3-dimethoxypropane,

2,2-diisopropyl-l,3-dimethoxypropane,

2.2- dibutyl-1,3-dimethoxypropane,

2-methyl-2-propyl-1,3-dimethoxypropane,

2-methyl-2-benzyl-l,3-dimethoxypropane, 2-methyl-2-ethyl-l,3-dimethoxypropane,

0 2-methyl-2-isopropyl-1,3-dimethoxypropane,

2-methyl-2-phenyl-1,3-dimethoxypropane,

2-methyl-2-eyelohexy1-1,3-dimethoxypropane,

2.2- bis(p-chlorophenyl)-1,3-dimethoxypropane,

2.2- bis(2-cyclohexylethyl)-1,3-dimethoxypropane,

5 2-methyl-2-isobutyl-1,3-dimethoxypropane,

CA 02256707 1998-11-26

2-methyl-2-(2-ethylhexyl)-1,3-dimethoxypropane,

2.2- diisobutyl-l,3-dimethoxypropane,

2.2- diphenyl-1,3-dimethoxypropane,

2.2- dibenzyl-1,3-dimethoxypropane,

2,2-bis(cyclohexylmethyl)-1,3-dimethoxypropane,

2.2- diisobutyl-l,3-diethoxypropane,

2.2- diisobutyl-l,3-dibutoxypropane,

2-isobutyl-2-isopropyl-1,3-dimethoxypropane,

2-(1-methylbutyl)-2-isopropyl-l,3-dimethoxypropane,

2-(1-methylbutyl)-2-s-buty1-1,3-dimethoxypropane,

2.2- di-s-butyl-l,3-dimethoxypropane,

2.2- di-t-butyl-1,3-dimethoxypropane,

2.2- dineopentyl-l,3-dimethoxypropane,

2-isopropyl-2-isopentyl-l,3-dimethoxypropane,

2-phenyl-2-isopropyl-l,3-dimethoxypropane,

2-phenyl-2-s-butyl-1,3-dimethoxypropane,

2-benzyl-2-isopropyl-1,3-dimethoxypropane,

2-benzyl-2-s-butyl-1,3-dimethoxypropane,

2-phenyl-2-benzyl-1,3-dimethoxypropane,

0 2-cyclopentyl-2-isopropyl-l,3-dimethoxypropane,

2-cyclopentyl·-2-s-butyl-1,3-dimethoxypropane,

2-eye1ohexy1-2-isopropyl-1,3-dimethoxypropane,

2-cyclohexyl-2-s-butyl-1,3-dimethoxypropane,

2-isopropyl-2-s-butyl-l,3-dimethoxypropane

2-cyclohexyl-2-cyclohexylmethy1-1,3-dimethoxypropane,

CA 02256707 1998-11-26

2.3- diphenyl-1,4-diethoxybutane,

2.3- dicyclohexyl-l,4-diethoxybutane,

2.2- dibenzyl-1,4-diethoxybutane,

2.3- dicyclohexyl-1,4-diethoxybutane,

2,3-diisopropyl-l,4-diethoxybutane,

2.2- bis(p-methylphenyl)-1,4-dimethoxybutane,

2.3- bis(p-chlorophenyl)-1,4-dimethoxybutane,

2.3- bis(p-fluorophenyl)-1,4-dimethoxybutane,

2.4- diphenyl-l,5-dimethoxypentane,

2,5-diphenyl-l,5-dimethoxyhexane,

2.4- diisopropyl-l,5-dimethoxypentane,

2.4- diisobutyl-l,5-dimethoxypentane,

2.4- diisoamyl-1,5-dimethoxypentane,

3-methoxymethyltetrahydrofuran,

3-methoxymethyldioxane,

1,3-diisobutoxypropane,

1.2- diisobutoxypropane,

1.2- diisobutoxyethane,

1.3- diisoamyloxypropane,

1,3-diisoneopentyloxyethane,

1.3- dineopentyloxypropane,

2.2- tetramethylene-l,3-dimethoxypropane,

2.2- pentamethylene-1,3-dimethoxypropane,

2.2- hexamethylene-l,3-dimethoxypropane,

5 1,2-bis(methoxymethyl) cyclohexane,

CA 02256707 1998-11-26

2,8-dioxaspiro[5,5]undecane,

3.7- dioxabicyclo[3,3,1]nonane,

3.7- dioxabicyclo[3,3,0]octane,

3,3-diisobutyl-l,5-oxononane,

6,6-diisobutyldioxyheptane,

1,l~dimethoxymethylcyclopentane,

1,1-bis (dimethoxymethyl) cyclohexane,

1.1- bis (methoxymethyl)bicyclo [2,2,1] heptane,

1.1- dimethoxymethylcyclopentane,

2-methy1-2-methoxymethyl-1,3-dimethoxypropane,

2-cyclohexyl-2-ethoxymethyl-1,3-diethoxypropane,

2-cyclohexyl-2-methoxymethyl-1,3-dimethoxypropane,

2.2- diisobutyl-l,3-dimethoxycyclohexane,

2-isopropyl-2-isoamyl-1,3-dimethoxycyclohexane,

5 2-cyclohexyl-2-methoxymethyl-l, 3-dimethoxycyclohexane, 2-isopropyl-2-methoxymethyl-1,3-dimethoxycyclohexane,

2-isobutyl-2-methoxymethyl-1,3-dimethoxycyclohexane,

2-cyclohexyl-2-ethoxymethyl-l,3-diethoxycyclohexane,

2-cyclohexyl-2-ethoxymethyl-1,3-dimethoxycyclohexane, 20 2-i sopropyl-2-ethoxymethyl-1,3-diethoxycyclohexane,

2-isopropyl-2-ethoxymethyl-1,3-dimethoxycyclohexane,

2-isobutyl-2-ethoxymethyl-l,3-diethoxycyclohexane,

2-isobutyl-2-ethoxymethyl-1,3-dimethoxycyclohexane, tris(p-methoxyphenyl·) phosphine, methylphenyl-bis (methoxymethyl) silane,

CA 02256707 1998-11-26 diphenyl-bis (methoxymethyl) silane methylcyclohexyl-bis (methoxymethyl) silane, di-t-butyl-bis(methoxymethyl) silane, cyclohexyl-t-butyl-bis (methoxymethyl) silane, i-propyl-t-butyl-bis(methoxymethyl)silane, etc .

Among the above, 1,3-diethers are used preferably, and 2,2-diisobutyl-l,3-dimethoxypropane, 2-isopropyl-2isopentyl-1,3-dimethoxypropane, 2,2-dicyclohexyl-l,3 dimethoxypropane, and 2,2-bis(cyclohexylmethyl)-1,310 dimethoxypropane are used especially preferably.

Two or more of the above polyether compounds (c-2) may be used in combination.

In the present invention, an organosilicon compound (c-1) and a polyether compound (c-2) mentioned above can be used in combination as the electron donor (c).

Furthermore, organosilicon compounds of the following formula may also be used in combination.

Rn.Si ( OR ' ) 4-n (In the above formula, R and R' are hydrocarbon groups, &lt; n &lt; 4, and organosilicon compounds indicated by this formula do not include organosilicon compounds (c-1) of formula (i) given above.)

CA 02256707 1998-11-26

Specific examples include trimethylmethoxysilane, trimethylethoxysilane, dimethyldimethoxysilane, dimethyldiethoxysilane, diisopropyldimethoxysilane, diphenyldimethoxysilane, phenylmethyldimethoxysilane, diphenyldiethoxysilane, bis-o-tolyldimethoxysilane, bis m-tolyldimethoxysilane, bis-p-tolyldimethoxysilane, bis p-tolyldiethoxysilane, bis-ethylphenyldimethoxysilane, ethyltrimethoxysilane, ethyltriethoxysilane, vinyltrimethoxysilane, methyltrimethoxysilane, n10 propyltriethoxysilane, decyltrimethoxysilane, decyltriethoxysilane, phenyltrimethoxysilane, γchloropropyltrimethoxysilane, methyltriethoxysilane, ethyltriethoxysilane, vinyltriethoxysilane, nbutyltriethoxysilane, phenyltriethoxysilane, γ15 aminopropyltriethoxysilane, chlorotriethoxysilane, ethyltriisopropoxysilane, vinyltributoxysilane, trimethylphenoxysilane, methyltriallyloxysilane, vinyltris(β-methoxyethoxysilane), vinyltriacetoxysilane, etc

Ethyl silicate, butyl silicate, dimethyltetraethoxydisiloxane, etc., may also be used.

In the present invention, prepolymerization can be performed in advance in the process of producing crystalline polypropylene using a catalyst comprised of the abovementioned solid titanium catalyst (a), organometallic compound (b), and electron donor (c).

CA 02256707 1998-11-26

In the prepolymerization process, an olefin is polymerized in the presence of solid titanium catalyst (a), organometallic compound (b) and optionally electron donor (c).

As the olefin to be prepolymerized, straight chain olefins, such as ethylene, propylene, 1-butene, 1octene, 1-hexadecene, 1-eicocene, etc., and olefins with a branched structure, such as 3-methyl-lbutene, 3-methyl-l-pentene, 3-ethyl-l-pentene, 4-methyl1-pentene, 4-methyl-1-hexene, 4,4-dimethyl-1-hexene,

4,4-dimethyl-1-pentene, 4-ethyl-1-hexene, 3 -ethyl-1hexene, allylnaphthalene, allylnorbornane, styrene, dimethylstyrenes, vinylnaphthalenes, allyltoluenes, allylbenzene, vinylcyclohexane, vinylcyclopentane, vinylcycloheptane, allyltrialkylsilanes, etc., may be used and these may also be copolymerized.

Among the above, 3-methyl-l-butene, 3-methyl-lpentene, 3-ethyl-1-hexene, vinylcyclohexane, allyltrimethylsilane, dimethylstyrene are especially preferred for use.

It is especially preferable to use the catalyst with which 3-methyl-l-butene is prepolymerized since the polypropylene that is produced will be high in rigidity.

It is desirable to perform the prepolymerization so that approximately 0.1 to 1000g, preferably at

CA 02256707 1998-11-26 approximately 0.3 to 500g of polymer will be produced per Ig of solid titanium catalyst component (a).

If the prepolymerization quantity is too large, the production efficiency of the (co)polymer in the main 5 polymerization may drop and fish-eye may tend to occur easily in films, etc., formed from the (co)polymer obtained.

In the prepolymerization process, the catalyst can be used at a considerably higher concentration than the 10 catalyst concentration in the system for the main polymerization.

It is usually desirable for the solid titanium catalyst component (a) to be used at a concentration in terms of titanium atoms per 1 liter of polymerization 15 volume of approximately 0.01 to 200 millimoles, preferably at approximately 0.05 to 100 millimoles.

It is usually desirable for the organometallic compound (b) to be used at an amount of approximately

0.1 to 100 millimoles, preferably at approximately 0.5 to 50 millimoles per 1 mole of titanium atom in the solid titanium catalyst component (a).

Although the electron donor (c) may or may not be used in the prepolymerization, it can be used at an amount of 0.1 to 50 millimoles, preferably 0.5 to 30 millimoles, and preferably still at 1 to 10 millimoles

CA 02256707 1998-11-26 per 1 mole of titanium atom in the solid titanium catalyst component (a).

It is preferable to perform the prepolymerization under mild conditions and by adding the olefin to be 5 prepolymerized and the abovementioned catalyst to an inert hydrocarbon medium.

Examples of the inert hydrocarbon medium include aliphatic hydrocarbons, such as propane, butane, pentane, hexane, heptane, octane, decane, dodecane, kerosene, etc.; aiicyclic hydrocarbons, such as cyclopentane, cyclohexane, methylcyclopentane, etc.;

aromatic hydrocarbons, such as benzene, toluene, xylene, etc.; halogenated hydrocarbons, such as ethylene chloride, chlorobenzene, etc.; and mixtures of the above hydrocarbons. It is especially preferable to use an aliphatic hydrocarbon.

The prepolymerization temperature may be a temperature at which the prepolymer that is produced will not dissolve in practical terms in the inert hydrocarbon medium and is usually set to -20 to +100°C, preferably -20 to +80°C, and preferably still at 0 to +40°C.

The prepolymerization may be carried out by the batch method, continuous method, etc.

CA 02256707 1998-11-26

Hydrogen, etc., may be used in the prepolymerization process to adjust the molecular weight.

In the present invention, it is desirable to use the solid titanium catalyst component (a) (or the prepolymer catalyst) at an amount of approximately

0.0001 to 50 millimoles, preferable at approximately

0.001 to 10 millimoles in terms of titanium atoms per 1 liter of polymerization volume.

It is desirable to use the organometallic compound (b) at an amount of approximately 1 to 2000 moles, preferable at approximately 2 to 500 moles in terms of metal atom per 1 mole of titanium atom in the polymerization system. It is desirable to use the electron donor (c) at an amount of approximately 0.0001 to 50 moles, preferable at approximately 0.01 to 20 moles per 1 mole of metal atom in the organometallic compound (b).

In multiple-stage polymerization of polypropylene using the catalyst described above, the propylene may be copolymerized with a different monomer mentioned above in any stage or in all stages as long as the objects of the present invention are not spoiled.

In the present invention, it is preferable to polymerize the propylene in multiple stages and it is

CA 02256707 1998-11-26 preferable to produce crystalline polypropylene of different molecular weight in each stage. For example, if the polymerization of propylene is to be performed in two stages, crystalline polypropylene of an intrinsic viscosity (Th_st) of 8 to 20dl/g, preferably 8.5 to 15dl/g can be produced in the first stage at an amount corresponding to 0.5 to 15wt.% of the finally obtained crystalline polypropylene, and then crystalline polypropylene of an intrinsic viscosity (T|2nd) of 0.8 to

4.0dl/g can be produced in the second stage at an amount corresponding to 99.5 to 85wt.% of the finally obtained crystalline polypropylene.

Also for example, if the polymerization of propylene is to be performed in three stages, crystalline polypropylene of an intrinsic viscosity (îlist) of θ to 20dl/g, preferably 8.5 to 15dl/g can be produced in the first stage at an amount corresponding to 0.5 to 15wt.% of the finally obtained crystalline polypropylene, and crystalline polypropylene of an 20 intrinsic viscosity (η_2ηά) of 3 to 10dl/g, preferably 4 to 9dl/g can then be produced in the second stage at an amount corresponding to 0.5 to 30wt.% of the finally obtained crystalline polypropylene, and then crystalline polypropylene of an intrinsic viscosity (η_3Γά) of 0.8 to

4.0dl/g, preferably 0.8 to 3.0dl/g can be produced in

CA 02256707 1998-11-26 the third stage at an amount corresponding to 99 to

55wt.% of the finally obtained crystalline polypropylene.

In this process, it is preferable that an inequality

H (Tllst) ⁺ (TUrd) ) /2} - 1 &lt; (Tknd) — Π (T|ist) ⁺ (Hard) )/2} + 1 be satisfied.

In each of the abovementioned stages, propylene is homopolymerized or propylene and another monomer are copolymerized to produce crystalline polypropylene, and it is desirable to produce a crystalline polypropylene that contains units derived from propylene at an amount of more than 90 mole %, preferably 95 to 100 mole % in each stage.

Though the order of the abovementioned stages is not specified in particular and the polymerization may be carried in an order that differs from those given above, the above orders are preferable.

The molecular weight of crystalline polypropylene obtained in each stage can be adjusted for example by changing the amount of hydrogen supplied to the polymerization system.

In the present invention, just the high molecular weight components of the crystalline polypropylene obtained by the above-described polymerization may be

CA 02256707 1998-11-26 taken out and used as the crystalline polypropylene.

The high molecular weight components of the crystalline polypropylene can be obtained as the components of the crystalline polypropylene obtained by polymerization that are insoluble in 85 to 125°C decane, or to be more specific, as components that are precipitated at 85 to

125°C upon dissolving said polypropylene and are then collected by hot filtration, etc. The chip contact method, etc., using seed polymer (chips) may be used for 10 the precipitation of these components. In the chip contact method, the precipitation temperature of the high molecular weight components does not necessarily have to be set to the abovementioned temperature range.

In the present invention, in addition to the process of production of the crystalline polypropylene components by the above-described multiple-stage polymerization, a process of copolymerization of propylene and ethylene may be further carried out to form a propylene/ethylene copolymer rubber component and 20 thereby produce the crystalline polypropylene of the present invention as a propylene block copolymer.

The polymerization may be carried out by a gas phase polymerization method or a liquid phase polymerization method, such as the solution 25 polymerization method and suspension polymerization

CA 02256707 1998-11-26 method, and a different method may be employed in each of the stages described above. The polymerization may also be carried out by any of the batchwise, semicontinuous, and continuous methods, and each of the above-described stages may be carried out in a plurality of polymerizers, for example, two to ten polymerizers.

An inert hydrocarbon may be used as the polymerization medium and liquid propylene may also be used as the polymerization medium.

With regard to the polymerization conditions of each stage, the polymerization temperature is suitably selected to be in the range of approximately -50 to

2Q0°C, preferably at approximately 20 to 100°C, and the polymerization pressure is suitably selected to be in 15 the range of normal pressure to 100kg/cm², preferably at approximately 2 to 50kg/cm².

In the polymerization process, it is desirable for the above-described solid titanium catalyst component (a) (or the prepolymer catalyst) to be used at a 20 concentration in terms of titanium atoms per 1 liter of polymerization volume of approximately 0.0001 to 50 millimoles, preferably at approximately 0.001 to 10 millimoles .

It is desirable for the organometallic compound (b) 25 to be used at an amount corresponding to approximately 1

CA 02256707 1998-11-26 to 2000 millimoles, preferably at approximately 2 to 500 millimoles in terms of metal atom per 1 mole of titanium atom in solid titanium catalyst component (a). It is desirable for the electron donor (c) to be used at an amount of approximately 0.001 to 50 millimoles, preferably at approximately 0.01 to 20 millimoles per 1 mole of metal atom in organometallic compound (b).

If a prepolymer catalyst has been used, the solid titanium catalyst component (a) and organometallic 10 compound (b) may be added anew as necessary. The organometallic compound (b) used in prepolymerization and that used in main polymerization may be the same as or different from each other.

The electron donor (c) is used in at least one of either the prepolymerization process or the main polymerization process, and, for example, it is used in only the main polymerization process or in both the prepolymerization and main polymerization processes.

The electron donor (c) used in prepolymerization and that used in the main polymerization may be the same as or different from each other.

The respective catalyst components described above do not have to be added anew in each of the processes that are carried out subsequently but may also be added as suitable.

CA 02256707 1998-11-26

When the catalyst described above is used, the degree of crystallization or the stereoregularity index of the polypropylene that is obtained will not be lowered and the catalyst activity will not be lowered even when hydrogen is used in the polymerization process .

In the present invention, since polypropylene can be produced at a high yield per unit quantity of the solid titanium catalyst component, the amount of the catalyst, and in particular the halogen content in the polypropylene can be reduced in a relative manner. The operation of removing the catalyst in the polypropylene can thus be omitted and rusting of the die will be unlikely to occur in the process of molding a molded product using the polypropylene obtained.

The crystalline polypropylene of the present invention may also be obtained by blending two or more types of crystalline polypropylenes of different an intrinsic viscosity (η) produced using the above20 described catalyst for production of highly stereoregular polypropylene. For example, the crystalline polypropylene may be obtained by blending

Û.5 to 15wt.% of crystalline polypropylene having an intrinsic viscosity (η) of 8 to 20dl/g with 99.5 to

CA 02256707 1998-11-26

85wt.% of crystalline polypropylene of an intrinsic viscosity (η) of 0.8 to 4.0dl/g.

Polypropylene Composition

The polypropylene composition of the present invention is comprised of components soluble in 140°C decane and optionally components insoluble in 140°C decane and the components soluble in 140°C decane that are also components insoluble in 64°C decane are comprised of the crystalline polypropylene that satisfies the characteristics {1) to (4) given above.

The polypropylene composition of the present invention simply has to contain the crystalline polypropylene described above and components besides said crystalline polypropylene are not specified in particular.

The components soluble in 140°C decane that are also components insoluble in 64°C decane of the polypropylene composition are components that remain after eliminating inorganic filler and other components insoluble in 140°C decane from the polypropylene composition, in other words, the components which precipitate at 64°C upon separation of the components soluble in 140°C decane by decane as was done with the crystalline polypropylene described above.

CA 02256707 1998-11-26

The elimination of components insoluble in 140°C decane from the polypropylene composition is carried out as follows.

300ml of decane, 500cc of glass beads, and approximately 2g of sample (polypropylene composition) are placed in a transparent flask set inside a constant temperature bath. Stirring is then performed while heating the constant temperature bath to approximately 146°C to dissolve the sample (the sample solution becomes turbid at first).

When the sample solution becomes transparent, the decane solution, in which the polypropylene is dissolved, is transferred to a beaker of 1 liter while performing vacuum suction on said beaker to separate the components soluble at 140°C from the components insoluble at 140°C. (If the sample solution that has been transferred to the beaker is colored at this time, the solution is returned to the flask, glass beads are added as necessary, and the solution is reheated to approximately 146°C and stirred to dissolve the sample.)

Then in order to separate the components soluble at

140°C, the decane solution in the beaker from which the components insoluble in 140°C decane have been removed in the above manner is combined with the wash liquid

CA 02256707 1998-11-26 resulting from washing the interior of the flask by adding 150ml of decane.

It is desirable for the polypropylene composition of the present invention to contain 70wt.% or more of 5 the components soluble in 140°C decane.

It is desirable for the above-described crystalline polypropylene (components insoluble in 64°C decane) to be contained in said components soluble in 140°C decane at an amount of 60wt.% or more, preferably 65 to

100wt.%.

In addition to the crystalline polypropylene described above, the polypropylene composition may specifically contain, for example, rubber components, additives, other polymers, inorganic fillers, etc., as other components.

Of said other components, inorganic compounds, such as the inorganic filler are usually the components of the polypropylene composition that are insoluble in

140°C decane while the organic compounds are usually the 20 components of the polypropylene composition that are soluble in 140°C decane.

The polypropylene composition of the present invention may contain rubber components for improving the impact strength, and it is desirable that this

CA 02256707 1998-11-26 rubber component is an ethylene/a-olefin copolymer and/or a styrene copolymer.

Such a rubber component is a component of the polypropylene composition that is soluble in 140°C 5 decane and that is also a component that is soluble in

64°C decane. Normally included among said components soluble in 64°C decane are components soluble in 64°C decane of the crystalline polypropylene itself (atatic polypropylene components and/or copolymer rubber components).

It is desirable that the ethylene/a-olefin copolymer is a random copolymer of ethylene and an aolefin of 3 to 20 carbon atoms and to be an elastomerlike substance.

It is desirable that the ethylene/a-olefin copolymer contains 25 to 90 mole % of units derived from ethylene and 10 to 75 mole % of units derived from an aolefin of 3 to 10 carbon atoms.

Examples of such α-olefins include propylene, 120 butene, 1-pentene, 1-hexene, 1-heptene, 1-octene, 1decene, 1-dodecene, 1-hexadodecene, 4-methyl-l-pentene, etc .

Among the above, α-olefins of 4 to 10 carbon atoms are preferable.

CA 02256707 1998-11-26

The ethylene/a-olefin copolymer may also contain units derived from other polymerizable monomers as necessary and to the extent that will not spoil the characteristics of the present invention.

Examples of such other polymerizable monomers include vinyl compounds, such as styrene, vinylcyclopentene, vinylcyclohexane, vinylnorbornane, etc.; vinyl esters, such as vinyl acetate; unsaturated organic acids and derivatives thereof, such as maleic 10 anhydride, etc.; conjugated dienes; and non-conjugated polyenes, such as 1,4-hexadiene, 1,6-octadiene, 2methyl-1,5-hexadiene, 6-methyl-l,5-heptadiene, 7-methyl1,6-octadiene, dicyclopentadiene, cyclohexadiene, dicyclooctadiene, methylene norbornene, 515 vinylnorbornene, 5-ethylidene-2-norbornene, 5-methylene2-norbornene, 5-isopropylidine-2-norbornene, 6chloromethyl-5-isopropenyl-2-norbornene, 2,3diisopropylidene-5-norbornene, 2-ethylidene-3isopropylidene-5-norbornene, 2-propenyl-2,220 norbornadiene, etc.

The ethylene/a-olefin copolymer may contain 10 mole % or less, preferably 5 mole % or less, and preferably still 3 mole % or less of the units derived from such other polymerizable monomers.

CA 02256707 1998-11-26

The ethylene/a-olefin copolymer may contain two or more types of units derived from α-olefins of 3 to 20 carbon atoms and may also contain two or more types of units derived from other polymerizable monomers.

It is desirable that the density of such an ethylene/a-olefin copolymer is 0.850 to 0.895g/cm³, preferably 0.855 to 0.890g/cm^.

It is desirable that the melt flow rate (MFR: ASTM

D1238; 190°C, under a load of 2.16kg) of the ethylene/a olefin copolymer is 0.01 to 100g/10 minutes, preferably

0.05 to 50g/10 minutes.

It is preferable that the ethylene/a-olefin copolymer has an intrinsic viscosity (η) (measured in

135°C decalin) of 1 to 5dl/g, a glass transition temperature Tg of -50°C or less, and a density of 0.850 to 0.900g/cm³.

Specific examples of such an ethylene/a-olefin copolymer include ethylene/propylene random copolymer, ethylene/1-butene random copolymer, ethylene/propylene/1-butene random copolymer, ethylene/propylene/ethylidene-norbornene random copolymer, ethylene/1-hexene random copolymer, ethylene/l-octene random copolymer, etc.. Among these, the ethylene/propylene random copolymer, ethylene/125 butene random copolymer, and ethylene/l-octene random

CA 02256707 1998-11-26 copolymer can be used especially preferably and two or more of these may be used in combination.

The ethylene/a-olefin copolymer may be produced by a conventionally known method using a vanadium catalyst, titanium catalyst, or metallocene catalyst, etc. The above-described ethylene/a-olefin copolymer is excellent in compatibility with the above-described polypropylene, and a polypropylene composition with excellent impact resistance and excellent fluidity as well as excelent rigidity can be formed from these components.

It is desirable that the styrene copolymer is a styrene block copolymer comprised of block polymer units derived from an aromatic vinyl and block polymer units derived from a conjugated diene.

Specific examples of aromatic vinyls that form this styrene copolymer include styrene, a-methylstyrene, 3methylstyrene, p-methylstyrene, 4-propylstyrene, 4dodecy1styrene, 4-eye1ohexy1styrene, 2-ethyl-4benzylstyrene, 4-(phenylbutyl)styrene, 120 vinylnaphthalene, 2-vinylnaphthalene, etc. Among these, styrene is preferable.

It is desirable that the styrene copolymer used in the present invention contains 5 to 80wt.%, preferably 8 to 80wt.% of aromatic vinyl polymer units. The aromatic vinyl unit content can be measured using the usual

CA 02256707 1998-11-26 methods, such as the infrared spectroscopy method, NMR spectroscopy method, etc.

Examples of conjugated dienes include butadiene, isoprene, pentadiene, 2,3-dimethylbutadiene, and 5 combinations of the above. Among these, isoprene and combinations of butadiene and isoprene are preferable.

In the case where the conjugated diene block polymer unit is formed from butadiene and isoprene, it is preferable that units derived from isoprene is contained at an amount of 40 mole % or more.

The conjugated diene block polymer unit thus comprised of butadiene/isoprene copolymer units may be a random copolymer unit, a block copolymer unit, or a tapered copolymer unit of butadiene and isoprene.

In the present invention, all or part of the carbon-carbon double bonds in the conjugated diene block polymer unit may be hydrogenated.

Though the hydrogenation ratio is determined according to the desired heat resistance, weather 20 resistance, etc., said ratio can be 50% or more, preferably 70% or more. If heat resistance and weather resistance are especially required of the resin composition of the present invention, it is preferable that the hydrogenation ratio is 80% or more.

CA 02256707 1998-11-26

The form of the styrene block copolymer thus comprised of an aromatic vinyl block polymer unit (X) and a conjugated diene block polymer unit (Y) is indicated for example as X(YX)_n or (XY)_n [where n is an integer greater than or equal to 1].

Among the above, copolymers of the form X(YX)_n and especially of the form X-Y-X are preferable, and to be more specific, polystyrene/polyisoprene (or isoprene/butadiene)/polystyrene block copolymers are 10 preferable.

In such a styrene block copolymer, the aromatic vinyl block units (X), which are hard segments, exist as crosslinkage points for the conjugated diene rubber block units (Y) to form a physical crosslink (domain).

The conjugated diene rubber block unit (Y) that exists between the aromatic vinyl block units (X) is a soft segment and has rubber elasticity.

The copolymerized diene units of the styrene block copolymer obtained in the above manner are hydrogenated 20 as necessary by a known method.

Specific examples of styrene copolymers used in the present invention include:

styrene/isoprene block copolymers (SI) and their hydrogenated forms (SEP),

CA 02256707 1998-11-26 styrene/isoprene/styrene block copolymers (SIS) and their hydrogenated forms (SEPS; polystyrenepolyethylene/propylene-polystyrene block copolymers), styrene/butadiene copolymers (SB) and their 5 hydrogenated forms (SEB), styrene/butadiene/styrene block copolymers (SBS) and their hydrogenated forms (SEBS; polystyrenepolyethylene/butylene-polystyrene copolymer), etc., and to be more specific, include HYBRAR (made by Kuraray 10 Co., Ltd.), Kraton (trade name; made by Shell Chemical

Co., Ltd.,), Cariflex TR (made by Shell Chemical Co.,

Ltd.), Solprene (made by Phillips Petroleum Co.),

Europene SOLT (made by ANIC Co.), Tufprene (made by

Asahi Chemical Co., Ltd.), Solprene-T (made by Japan 15 Elastomer Co.), JSRTR (made by Japan Synthetic Rubber

Co,), Denka STR (made by Denki Kagaku Co.), Quintac (made by Nihon Zeon Co.), Kraton G (made by Shell

Chemical Co., Ltd.), Tuftech (made by Asahi Chemical

Co., Ltd.) (All of the above are trade names.), etc.

Among the above, SEBS, SEPS, etc. are used preferably.

It is desirable that the styrene copolymer used in the present invention normally has a melt flow rate (MFR: ASTM D1238, 200°C, under load of 2.16kg) of 0.1 to

CA 02256707 1998-11-26

150g/10 minutes and an intrinsic viscosity (η) (in 135°C decalin) of 0.01 to 10dl/g, preferably 0.08 to 7dl/g.

It is also desirable that the crystallinity as measured by the X-ray diffraction method is 0 to 10%, preferably 0 to 7%, and preferably still 0 to 5%.

It is desirable that the density is 0.88 to 0.94g/cm³.

Two or more types of the abovementioned styrene copolymers may be used in combination.

Also in the present invention, an ethylene/a-olefin copolymer and a styrene copolymer may be used in combination.

In preparing the polypropylene composition of the present invention, an abovementioned ethylene/a-olefin

5 copolymer and/or styrene copolymer may be used at an amount of 0 to 70 parts by weight, preferably 0 to 50 parts by weight based on 100 parts by weight of crystalline polypropylene.

Additives that may be contained in the 20 polypropylene composition of the present invention include nucleating agents, antioxidants, hydrochloric acid absorbents, heatproofing stabilizers, weathering agents, light stabilizers, ultraviolet absorbing agents, slip agents, anti-blocking agents, anti-fogging agents, 25 lubricants, antistatic agents, flame retardants,

CA 02256707 1998-11-26 pigments, dyes, dispersing agents, cupper deactivators, neutralizers, foaming agents, plasticizing agents, antifoaming agents, crosslinking agents, flow property improving agents, such as peroxides, etc., weld strength 5 improving agents, natural oils, synthetic oils, waxes, etc .

It is especially preferable that the polypropylene composition of the present invention contains a nucleating agent, and this nucleating agent may be the abovementioned prepolymer that is contained in the polypropylene. Also, various other known nucleating agents may be contained and both such nucleating agents and said prepolymer may be contained. By containing such nucleating agents, the crystal particles are made 15 fine and the crystallization rate is improved to enable high-speed molding.

Although various conventionally known nucleating agents can be used without restriction as the nucleating agent besides the prepolymer, nucleating agents of the following formula can be used preferably in particular.

CA 02256707 1998-11-26

<img file="CA2256707C_D0002.tif" />

(In the above formula, R¹ indicates oxygen, sulfur, or a hydrocarbon group of 1 to 10 carbon atoms, and R² and R³ may be the same as or different from each other of each indicating hydrogen or a hydrocarbon group of 1 to 10 carbon atoms. The R²'s may be bonded with each other to form a ring, the R^{3 1} s may be bonded with each other to form a ring, and R² and R³ may be bonded together to form a ring. M indicates a metal atom of valence 1 to 3 and n is an integer with a value of 1 to 3.)

Specific examples include sodium-2,2'-methylenebis(4,6-di-t-butylphenyl)phosphate, sodium-2, 2 'ethylidene-bis(4,6-di-t-butylphenyl)phosphate, lithium15 2,2'-methylene-bis-(4,6-di-t-butylphenyl)phosphate, lithium-2,2'-ethylidene-bis(4,6-di-tbutylphenyl)phosphate, sodium-2,2¹-ethylidene-bis(4-ipropyl-6-t-butylphenyDphosphate, lithium-2,2 ' methylene-bis(4-methyl-6-t-butylphenyl) phosphate, lithium-2,2'-methylene-bis{4-ethyl-6-tCA 02256707 1998-11-26 butylphenyl)phosphate, calcium-bis[2,2'-thiobis(4methyl-6-t-butylphenyl)phosphate], calcium-bis [2,2 ¹ thiobis(4-ethyl-6-t-butylphenyl)phosphate], calciumbis[2,2¹-thiobis-{4,β-di-t-butylphenyl) phosphate], magnesium-bis[2,2'-thiobis(4,6-di-tbutylphenyl)phosphate], magnesium-bis[2,2'-thiobis(4-t octylphenyl)phosphate], sodium-2,2¹-butylidene-bis(4,6 di-methylphenyl)phosphate, sodium-2,2'-butylidenebis(4,6-di-t-butylphenyl)phosphate, sodium-2,2¹-t10 octylmethylene-bis(4,6-di-methylphenyl)phosphate, sodium-2,2'-t-octylmethylene-bis(4,6-di-tbutylphenyl) phosphate, calcium-bis(2,2'-methylenebis(4,6-di-t-butylphenyl)phosphate), magnesium-bis[2,2 methylene-bis(4,6-di-t-butylphenyl)phosphate], barium15 bis[2,2’-methylene-bis(4,6-di-t-butylphenyl) phosphate] sodium-2,2'-methylene-bis(4-methyl-6-tbutylphenyl)phosphate, sodium-2,2'-methylene-bis(4ethyl-6-t-butylphenyl)phosphate, sodium (4,4'-dimethyl

5,6'-di-t-butyl-2,2'-biphenyl(phosphate, calcium20 bis[{4,4'-dimethyl-6,6¹-di-t-butyl-2,2'biphenyl)phosphate], sodium-2,2'-ethylidene-bis (4-mbutyl-6-t-butylphenyl)phosphate, sodium-2,2'-methylene bis (4,6-di-methylphenyl)phosphate, sodium-2,2 ¹ methylene-bis(4,6-di-ethylphenyl)phosphate, potassium25 2,2'-ethylidene-bis(4,6-di-t-butylphenyl) phosphate,

CA 02256707 1998-11-26 calcium-bis[2 ₁2¹-ethylidene-bis-(4,6-di-tbutylphenyl)phosphate], magnesium-bis[2,2¹-ethylidenebis [4,β-di-t-butylphenyl)phosphate], barium-bis [2,2' ethylidene-bis(4,6-di-t-butylphenyl) phosphate], aluminum-tris[2, 2¹-methylene-bis(4,6-di-tbutylphenyl) phosphate], aluminum-tris[2,2'-ethylidenebis (4,6-di-t-butylphenyl) phosphate, and mixtures of two or more of the above.

Among the above, sodium-2,2'-methylene-bis(4,6-di10 t-butylphenyl)phosphate is particularly preferable.

<img file="CA2256707C_D0003.tif" />

(In the above formula, R⁴ indicates hydrogen or a 15 hydrocarbon group of 1 to 10 carbon atoms, M indicates a metal atom of a valence of 1 to 3, and n indicates an integer of value 1 to 3.)

Specific examples include sodium-bis(4-tbutylpheny1) phosphate, sodium-bis (4-methylphenyl ) phosphate, sodium-bis(4-ethylphenyl) phosphate, sodium-bis(4-i-propylphenyl) phosphate, sodium-bis(4-t-octylphenyl)phosphate,

CA 02256707 1998-11-26 potassium-bis (4-t-butylphenyl)phosphate, calcium-bis (4-t-butylphenyl) phosphate, magnesium-bis(4-t-butylphenyl)phosphate, lithium-bis{4-t-butylphenyl)phosphate, aluminum-bis(4-t-butylphenyl)phosphate, and mixtures of two or more of the above.

Among the above, sodium-bis(4-tbutylphenyl ) phosphate is preferred.

<img file="CA2256707C_D0004.tif" />

(In the above formula, R⁵ indicates hydrogen or a hydrocarbon group of 1 to 10 carbon atoms.)

Specific examples include 1,3,2,415 dibenzylidenesorbitol,

1.3- benzylidene-2,4-p-methylbenzylidenesorbitol,

1.3- benzylidene-2,4-p-ethylbenzylidenesorbitol,

1.3- p-methylbenzylidene-2,4-benzylidenesorbitol,

1.3- p-ethylbenzylidene-2,4-benzylidenesorbitol,

1,3-p-methylbenzylidene-2,4-p-ethylbenzylidenesorbitol,

1.3- p-ethylbenzylidene-2,4-p-methylbenzylidenesorbitol,

1,3,2,4-di(p-methylbenzylidene)sorbitol,

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1.3.2.4- di(p-ethylbenzylidene)sorbitol,

1.3.2.4- di(p-n-propylbenzylidene)sorbitol,

1.3.2.4- di(p-i-propylbenzylidene)sorbitol,

1.3.2.4- di(p-n-butylbenzylidene)sorbitol,

1,3,2,4-di(p-s-butylbenzylidene)sorbitol,

1.3.2.4- di(p-t-butylbenzylidene)sorbitol,

1.3.2.4- di(2'-4'-dimethylbenzylidene)sorbitol,

1.3.2.4- di(p-methoxybenzylidene)sorbitol,

1.3.2.4- di(p-ethoxybenzylidene)sorbitol,

1,3-benzylidene-2,4-p-chlorobenzylidenesorbitol,

1.3- p-chlorobenzylidene-2,4-benzylidenesorbitol,

1.3- p-chlorobenzylidene-2,4-p-methylbenzylidenesorbitol,

1.3- p-chlorobenzylidene-2,4-p-ethylbenzylidenesorbitol,

1.3- p-methylbenzylidene-2,4-p-chlorobenzylidenesorbitol,

1,3-p-ethylbenzylidene-2,4-p-chlorobenzylidenesorbitol,

1.3.2.4- di(p-chlorobenzylidene)sorbitol, and mixtures of two or more of the above.

Among the above, 1,3,2,4-dibenzylidenesorbitol,

1.3.2.4- di(p-methylbenzylidene)sorbitol,

1,3,2, 4-di(p-ethylbenzylidene)sorbitol,

1.3- p-chlorobenzylidene-2,4-p-methylbenzylidenesorbitol, and 1,3,2,4-di(p-chlorobenzylidene)sorbitol, and mixtures of two or more of these are preferred.

The nucleating agents include metal salts of aromatic carboxylic acids and fatty carboxylic acids,

CA 02256707 1998-11-26 such as aluminum benzoate, aluminum p-t-butylbenzonate, sodium adipate, sodium thiophenecarboxylate, sodium pyrolecarboxylate, etc. Talc and other inorganic compounds mentioned below may also be used as nucleating 5 agents.

Xn preparing the polypropylene composition, it is desirable to use about 0.001 to 10 parts by weight, preferably 0.01 to 5 parts by weight, and preferably still 0.1 to 3 parts by weight of the abovementioned 10 nucleating agents based on 100 parts by weight of polypropylene.

Phenol antioxidants, sulfur antioxidants, and phosphorus antioxidants can be used as the antioxidant.

Examples of phenol antioxidants include phenols, such as 2,6-di-tert-butyl-p-cresol (3,5-di-tert-butyl-4hydroxytoluene), stearyl(3,3-dimethyl-4-hydroxybenzyl) thioglycolate, stearyl-β-(4-hydroxy-3,5-di-tertbutylphenol) propionate, distearyl-3,5-di-tert-butyl-4hydroxybenzyl phosphonate, 2,4,6-tris(3',5'-di-tert20 butyl-4'-hydroxybenzylthio)-1,3,5-triazine, distearyl (4-hydroxy-3-methyl-5-tert-butylbenzyl) malonate, 2,2'methylene-bis(4-methyl-6-tert-butylphenol), 4,4'methylene-bis(2, 6-di-tert-butylphenol), 2,2¹-methylenebis[6-(1-methylcyclohexyl)p-cresol], bis[3,5-bis[425 hydroxy-3-tert-butylphenyl) butyric acid] glycol ester,

CA 02256707 1998-11-26

4,4'-butylidene-bis(6-tert-butyl-m-cresol) , 1,1,3tris(2-methyl-4-hydroxy-5-tert-butylphenyl) butane, bis[2-tert-butyl-4-methyl-6-(2-hydroxy-3-tert-butyl-5methylbenzyl)phenyl] terephthalate, 1,3,5-tris(2,65 dimethyl-3-hydroxy-4-tert-butyl)benzyl isocyanurate,

1.3.5- tris(3,5-di-tert-butyl-4-hydroxybenzyl)-2,4,6trimethylbenzene, tetrakis[methylene-3-(3,5-di-tertbutyl-4-hydroxyphenyl)propionate]methane, 1,3,5tris(3,5-di-tert-butyl-4-hydroxybenzyl) isocyanurate, 10 1,3,5-tris [(3,5-di-tert-butyl-4hydroxyphenyl)propionyloxyethyl] isocyanurate, 2octylthio-4,6-di{4-hydroxy-3,5-di-tert-butyl)phenoxy1.3.5- triazine, 4,4'-thiobis(6-tert-butyl-m-cresol), etc.; and polyphenol oligocarbonates, such as the 15 oligocarbonate (of degree of polymerization of 2 to 10) of 4,4'-butylidene-bis( 2-tert-butyl-5-methylphenol).

Examples of sulfur antioxidants include dialkyl thiodipropionates, such as dilauryl-, dimyristyl- and distearyl-thiodipropionates, and polyalcohol (for example, glycerine, trimethylolethane, trimethylolpropane, pentaerythritol, trishydroxyethyl isocyanurate) esters of butyl-, octyl-, lauryl-, stearyl-, and other alkyl thiopropionic acid (for example, pentaerythritol tetralauryl thiopropionate).

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Examples of phosphorus antioxidants include trioctyl phosphite, trilauryl phosphite, tridecyl phosphite, octyl-diphenyl phosphite, tris(2,4-di-tertbutylphenyl) phosphite, triphenyl phosphite, tris(butoxyethyl) phosphite, tris(nonylphenyl) phosphite, distearyl pentaerythritol diphosphite, tetra(tridecyl)-1,1,3-tris(2-methyl-5-tert-butyl-4hydroxyphenyl) butane diphosphite, tetra(C12 - C15 mixed alkyl)-4,4'-isopropylidene diphenyl diphosphite, tetra(tridecyl)-4,4'-butylidene bis(3-methyl-6-tertbutylphenol) diphosphite, tris (3,5-di-tert-butyl-4hydroxyphenyl) phosphite, tris(mono-di mixed nonylphenyl) phosphite, hydrogenated-4,4¹-isopropylidene diphenol polyphosphite, bis(octylphenyl)-bis[4,4’butylidene-bis ( 3-methyl-6-tert-butylphenol) ] -1,6hexanediol diphosphite, phenyl - 4,4 *-isopropylidene diphenol-pentaerythritol diphosphite, bis(2,4-di-tertbutylphenyl) pentaerythritol diphosphite, bis(2,6-ditert-butyl-4-methylphenyl) pentaerythritol diphosphite, tris[4,4'-isopropylidene-bis (2-tert-butylphenol)] phosphite, phenyl·disodecyl phosphite, di(nonylphenyl) pentaerythritol diphosphite), tris(l,3-distearoyloxyisopropyl) phosphite, 4,4'-isopropylidenebis(2-tert-butylphenol)-di(nonylphenyl) phosphite, 9,10di-hydro-9-oxa-9-oxa-10-phosphaphenanthrene-10-oxide,

CA 02256707 1998-11-26 tetrakis(2,4-di-tert-butylphenyl)-4,4'-biphenylene diphosphonite, etc .

Other antioxidants that can be used include, 6hydroxycoumarone derivatives, such as α, β, γ, and δ tocopherols and their mixtures, the 2,5-dimethylsubstituted form, 2,5,8-trimethyl-substituted form, and

2,5,7,8-tetramethyl-substituted form of 2-(4-methylpenta-3-enyl)-6-hydroxycoumarone, 2,2,7-trimethyl-5tert-butyl-6-hydroxycoumarone, 2,2,5-trimethyl-7-tert10 butyl-6-hydroxycoumarone, 2,2,5-trimethyl-6-tert-butyl6-hydroxycoumarone, 2,2-dimethyl-5-tert-butyl-6hydroxycoumarone, etc.

Furthermore, a double compound of the general formula, M_xAl_y (OH) 2x+3y-2z (A) z · ati₂O (wherein M is Mg, Ca, or Zn, A is an anion other than the hydroxide group, x, y, and z are positive numbers, and a is 0 or a positive number), for example,

Mg₆Al₂ (OH) ₁₆CO₃ ·4H₂O,

Mg₅Al₂ (OH) 14CO3 ·4H₂O,

Mg₁₀Al₂ (OH) 22 (CO₃ ) 2 · 4H₂O,

Mg₆Al₂(OH)16HPO4·4H₂O,

Ca₆Al₂(OH)₁₆CO₃·4H₂O,

Zn₆Al₂(OH)16CO3·4H₂O,

Zn₆Al₂(OH)16SO4·4H₂O,

CA 02256707 1998-11-26

MggAl2 (OH) 16SO3 · 4H2O, etc., can be contained as the hydrochloric acid absorbent.

Examples of light stabilizers include hydroxybenzophenones, such as 2-hydroxy-45 methoxybenzophenone, 2-hydroxy-4-n-octoxybenzophenone2,2¹-di-hydroxy-4-methoxybenzophenone, 2,4dihydroxybenzophene, etc.; benzotriazoles, such as 2(2'-hydroxy-3'-tert-butyl-5'-methylphenyl)-5chlorobenzotriazole, 2-(2¹-hydroxy-3',5'-di-tert10 butylphenyl)-5-chlorobenzotriazole, 2-(2’-hydroxy-5 ¹ methylphenyl) benzotriazole, 2-(2¹-hydroxy-3' ,5'-di-tertamylphenyl) benzotriazole, etc.; benzoates, such as phenylsalicylate, p-tert-butylphenylsalicylate, 2,4-ditert-butylphenyl -3 ,5-di-tert-butyl-4-hydroxybenzoate, hexadecyl-3,5-di-tert-butyl-4-hydroxybenzoate, etc.;

nickel compounds, such as the Ni salt of 2,2'-thiobis(4tert-octylphenol), [2,2'-thiobis(4-tertoctylphenolate)]-n-butylamine Ni, Ni salt of (3,5-ditert-butyl-4-hydroxybenzyl) phosphonic acid monoethyl 20 ester, etc.; substituted acrylonitriles, such as methyl a-cyano-p-methyl-β-(p-methoxyphenyl) acrylate, etc. ;

oxalyldianilides, such as N¹-2-ethylphenyl-N-ethoxy-5tert-butylphenyloxalyldiamide, N-2-ethylphenyl-N'-2ethoxyphenyloxalyldiamide, etc.; and hindered amine 25 compounds, such as bis{2,2,6,6-tetramethyl-4-piperidine)

CA 02256707 1998-11-26 sebaceate, poly[{(6-(1,1,3,3-tetramethylbutyl)imino}1,3,5-triazine-2,4-diyl{4-(2,2,6,6tetramethylpiperidyl)iminojhexamethylene], condensate of

2-(4-hydroxy-2,2,6,6-tetramethyl-1-piperidyl) ethanol and 5 dimethyl succinate, etc.

Examples of lubricants include aliphatic hydrocarbons, such as paraffin wax, polyethylene wax and polypropylene wax; higher fatty acids, such as capric acid, lauric acid, myristic acid, palmitic acid, margaric acid, stearic acid, arachidic acid and behenic acid, and metal salts thereof (for example, lithium salt, calcium salt, sodium salt, magnesium salt, potassium salt); fatty alcohols, such as palmityl alcohol, cetyl alcohol and stearyl alcohol; fatty amides, such as capronamide, caprylamide, caprinamide, laurylamide, myristamide, palmitamide and stearamide;

fat and alcohol esters; and fluorine compounds, such as fluoroalkylcarboxylic acids and metal salts thereof, metal salts of fluoroalkylsulfonic acid, etc.

The above additives can be used at an amount of

0.0001 to 10 parts by weight per 100 parts by weight of crystalline polypropylene.

The polypropylene composition of the present invention may also contain 30wt.% or less of inorganic filler.

CA 02256707 1998-11-26

Specific examples of inorganic fillers include powder fillers, including natural silicic acids and silicates, such as fine powder talc, kaolinite, baked clay, pyrophyllite, sericite, wollastonite, etc., carbonates, such as precipitated calcium carbonate, limestone powder whiting, magnesium carbonate, etc., hydroxides, such as aluminum hydroxide, magnesium hydroxide, etc., oxides, such as zinc oxide, zinc white, magnesium oxide, etc., barium sulfate, and synthetic silicic acids and silicates, such as hydrated calcium silicate, hydrated aluminum silicate, hydrated silicic acid, silicic anhydride, etc., flake-form fillers, such as mica, fibrous fillers, such as glass fiber, basic 15 magnesium sulfate whiskers, calcium titanate whiskers, aluminum borate whiskers, sepiolite, PMF (processed mineral fiber), xonotolite, potassium titanate, ellestadite, etc., and balloon-form fillers, such as glass balloons, fly 20 ash balloons, etc.

Among the above, talc, calcium carbonate, glass fiber, potassium titanate, and barium sulfate, etc. are used preferably in the present invention, and fine powder talc having an average particle size of 0.01 to 25 lOgrn is especially preferable for use.

CA 02256707 1998-11-26

The average particle size of talc can be measured by the liquid phase sedimentation method.

The inorganic filler, in particular, the talc that is used in the present invention may be non-treated or 5 may be surface treated in advance. Specific examples of surface treatment include chemical or physical treatment using silane coupling agents, higher fatty acids, metal salts of fatty acids, unsaturated organic acids, organic titanates, resin acids, polyethylene glycol, and other 10 treatment agents. When talc provided with such surface treatment is used, a propylene polymer composition that is excellent in weld strength, coating properties, and forming properties can be obtained.

Two or more of the above types of inorganic filler may be used in combination.

Also in the present invention, organic fillers such as high styrenes, lignin and reclaimed rubber may be used along with inorganic fillers such as those men t i oned above.

Since the polypropylene composition of the present invention contains such additives, nucleating agents, rubber components, fillers, etc., a molded product can be formed that is further improved in balance of physical properties, durability, coating properties,

CA 02256707 1998-11-26 printing properties, flaw resistance, and forming properties.

The polypropylene composition may be produced by kneading the above-described propylene, additives, rubber components, inorganic filler, and other components by use of known methods.

Thermoformed Product

The above-described crystalline polypropylenes and polypropylene compositions of the present invention (shall be referred to hereinafter simply as polypropylenes) can be used widely in conventionally known polyolefin applications, and in particular, the polypropylenes may be molded and used, for example, as sheets, unstretched or stretched films, filaments, and molded products of various other shapes.

Specific examples of molded products include molded products obtained by such known thermoforming methods as extrusion molding, injection molding, inflation molding, blow molding, extrusion blow molding, injection blow molding, press molding, vacuum forming, calendering, foam molding, etc. A few examples shall be given below to describe such molded products.

When for example the moled product of the present invention is an extrusion molded product, the shape and

CA 02256707 1998-11-26 type of the product is not limited in particular, and sheets, films (unstretched), pipes, hoses, electric cable jackets, filaments, etc., can be given as examples. Especially preferred are sheets, films, and filaments.

Conventionally known extrusion devices and molding conditions can be employed in extrusion molding the polypropylene. The molten polypropylene can be extruded from a T die, etc., using, for example, a single-axis screw extruder, kneading extruder, ram extruder, gear extruder, etc., and formed into a sheet or a film (unstretched).

Stretched films can be obtained by stretching the abovementioned extruded sheet or extruded film (unstretched) by the tenter method (longitudinaltransverse stretching, transverse-longitudinal stretching), simultaneous biaxial stretching method, uniaxial method, or other known stretching method.

The draw ratio in the stretching of a sheet or 20 unstretched film is usually about 20 to 70 times in the case of biaxial stretching and usually about 2 to 10 times in the case of uniaxial stretching. It is desirable to obtain a stretched film of about 5 to 200μπι thickness by stretching.

CA 02256707 1998-11-26

As another example of formed product of film form, inflation films may also be manufactured. Drawdown is unlikely to occur in the process of inflation molding.

The above-described sheets and film molded products, obtained from the polypropylenes of the present invention, do not become charged easily, are excellent in tensile modulus and other rigidity characteristics, heat resistance, impact resistance, aging resistance, transparency, see-through properties, gloss, rigidity, moisture proof, and gas barrier properties, and can be used widely as packaging film, etc. Since these sheets and films are particularly excellent in moisture proof, they can be used preferably in press through packs, etc., that are used as packaging 15 material for drug tablets, capsules, etc.

Filament molded products can be produced for example by extruding the molten polypropylene through a spinning nozzle. A filament thus obtained can be further stretched. It is sufficient that this stretching be performed so that the molecules become oriented in at least one axial direction of the filament. It is usually desirable to perform stretching to attain a draw ratio of about 5 to 10 times.

Filaments obtained from the polypropylenes of the 25 present invention do not become charged readily and are

CA 02256707 1998-11-26 excellent in rigidity, heat resistance, and impact resistance.

Injection molded products can be produced by injection molding the polypropylene into various shapes using conventionally known injection molding equipment and employing known conditions. Injection molded products, obtained from the polypropylenes of the present invention do not become charged readily, are excellent in rigidity, heat resistance, impact 10 resistance, surface gloss, resistance against chemicals wear resistance, etc., and can be used widely as interior automotive trim material, exterior automotive trim material, housing for household electric products, various types of containers, etc.

Blow molded products can be manufactured by blow molding the polypropylene using conventionally known blow molding equipment and employing known conditions.

For example in extrusion blow molding, an abovementioned polypropylene is extruded from a die in 20 the molten condition where the resin temperature is

100°C to 300°C to form a tube-shaped parison. After then retaining the parison in a mold of the desired shape, air is blown in to make the parison fit the mold at a resin temperature of 130°C to 300°C and thereby form a hollow molded product. It is desirable that the

CA 02256707 1998-11-26 draw (blow) ratio is 1.5 to 5 times in the transverse direction.

In injection blow molding, an abovementioned polypropylene is injected into a parison-mold in the 5 molten condition where the resin temperature is 100°C to

300°C to form a parison. After then retaining the parison in a mold of the desired shape, air is blown in to make the parison fit the mold at a resin temperature of 120°C to 300°C and thereby form a hollow molded product. In obtaining the hollow molded product, it is desirable that the draw (blow) ratio is 1.1 to 1.8 times in the longitudinal direction and 1.3 to 2.5 times in the transverse direction.

Blow molded products, obtained from the polypropylenes of the present invention, are excellent in rigidity, heat resistance, impact resistance, as well as in moisture proof.

Mold stamping molded products can be given as examples of press molded products. Polypropylene of the present invention can be used for example as the base material used, in a composite integral molding (mold stamping molding) process wherein the base material and a skin material are press molded simultaneously.

Specific examples of such mold stamping molded products include door trims, rear package trims, seat back

CA 02256707 1998-11-26 garnishes, instrument panels, and other interior automotive trim materials.

Since the polypropylenes of the present invention exhibit high rigidity and, for example, exhibit 5 sufficiently high rigidity even when containing rubber components, the polypropylenes can be used in various applications that require high rigidity. In particular, the polypropylenes of the present invention can be used preferably in such applications as interior and exterior 10 automotive trim material, housing for household electric goods, and various containers.

Press molded products made of the polypropylenes of the present invention do not become charged readily and are excellent in rigidity, heat resistance, impact resistance, aging resistance, surface gloss, resistance against chemicals, wear resistance, etc.

Effects of the Invention

The crystalline polypropylenes and polypropylene compositions of the present invention contain crystalline polypropylene components of high molecular weight and crystalline components having specific physical properties, and are therefore extremely high in rigidity. Also, the crystalline polypropylenes and polypropylene compositions of the present invention are

CA 02256707 1998-11-26 excellent in hardness, rigidity, melt tension, fluidity, and molding properties.

Such crystalline polypropylenes and polypropylene compositions of the present invention can be used in a wide variety of applications requiring high rigidity, and can be used preferably for example as materials for household electric goods such as housing, washing tubs, etc., film materials, such as uniaxially stretched films, biaxially stretched films, inflation films, etc., sheet materials made by calendering, extrusion molding, etc., container materials for bags, retort containers, interior automotive trim materials for trims, instrumental panels, column covers, etc., exterior automotive trim materials for fenders, bumpers, chenille, mud guards, mirror covers, etc., sundry goods, etc.

Exampjo

Though the present invention shall now foe described more specifically by way of examples, the present invention is not limited to these examples.

The physical properties of polypropylene or polypropylene composition, indicated in the description of the examples, were measured as follows.

CA 02256707 1998-11-26 (Intrinsic viscosity (η))

The limiting viscosity (η) was measured in decahydronaphthalene at 135°C.

(Weight-average molecular weight (Mw), z-average molecular weight (Mz))

The weight-average molecular weight (Mw) and zaverage molecular weight (Mz) were determined from gel permeation chromatography (GPC) measurements made at 10 140^QC using o-chlorobenzene as the solvent.

(Melt viscoelasticity)

The frequency dependent loss tangent of the components insoluble in 64°C decane of the polypropylene 15 was measured using RDS-11 made by Reometrix Co.

Using a disk-shaped sheet of 2mm thickness and

12.5mm radius that was press molded at 230°C, the loss tangent (tanÔo.os) ^{at a} frequency of 0.05rad/sec and the loss tangent (tan5io) ^{at a} frequency of lOrad/sec were measured at 230°C and under constant strain.

The value of the melt viscoelasticity index D was then determined using the aforementioned formula from the respective frequencies and measured loss tangent values .

CA 02256707 1998-11-26 (Flexure modulus test (FM))

Using a test piece that was injection molded under predetermined conditions, the flexure modulus was measured at a test temperature of 23°C, span interval of 5 51mm, and flexing rate of 20mm/minute in compliance with

ASTM D790.

[Melt tension (MT)]

The melt tension was measured as the tension applied to a filament when an extruded strand is pulled at a constant rate using the Melt Tension Tester (made by Toyo Seiki) and under conditions of a measurement temperature of 200°C and extrusion rate of 15mm/minute.

(Pencil hardness)

The pencil hardness was measured in compliance with

JIS K5401.

Example 1

Production of Homopolvoropvlene (PP-1) (Preparation of solid titanium catalyst component (a))

A mixture of 95.2g of anhydrous magnesium chloride,

442ml of decane, and 390.6g of 2-ethylhexyl alcohol was heated for 2 hours at 130°C to obtain a uniform solution. To the solution was added 21.3g of phthalic

CA 02256707 1998-11-26

100 anhydride, and further stirring and mixing were carried out for 1 hour at 130°C to dissolve the phthalic anhydride.

After cooling the uniform solution thus obtained to 5 23°C, 75ml of the uniform solution were dripped over 1 hour into 200ml of titanium tetrachloride kept at -20°C.

After the dripping process, the temperature of the mixed solution obtained was raised to 110°C over 4 hours.

When the temperature was reached to 110°C, 5.22g of 10 diisobutyl phthalate (DIBP) were added and the mixture was then kept at said temperature while stirring for 2 hours. The solid components were then collected by hot filtration, resuspended in 275ml of titanium tetrachloride, and then heated again for 2 hours at no°c.

After heating ended, the solid components were collected by hot filtration again and washed using decane and hexane at 110°C until titanium compounds were no longer detected in the wash liquid.

The solid titanium catalyst component (a) that was prepared in the above manner was preserved as a hexane slurry and a portion was dried to examine the catalyst composition.

CA 02256707 1998-11-26

101

The solid titanium catalyst component (a) contained

2.5wt.% of titanium, 58wt.% of chlorine, 18wt.% of magnesium, and 13.8wt.% of DIBP.

(Preparation of prepolymer catalyst)

To a 2 liter autoclave with stirrer were introduced

500ml of refined hexane, 120g of 3-methyl-l-butene, 50 millimoles of triethylaluminum, 50 millimoles of trimethylmethoxysilane, and an amount of the above10 obtained solid titanium catalyst component (a) corresponding to 5,0 millimoles in terms of titanium atom under a nitrogen atmosphere. A polymerization reaction was performed for 8 hours. The polymerization temperature was maintained at 2 0°C.

After the end of polymerization, the interior of the reactor was replaced with nitrogen, and then a washing operation, comprised of removing the supernatant and adding refined hexane, was performed three times.

The prepolymer catalyst (B)-l that was obtained was then 20 resuspended in refined hexane and the entire amount was transferred into a catalyst bottle.

A prepolymer catalyst containing 10.4g of poly(3methyl-l-butene) per lg of solid titanium catalyst component (a) was obtained.

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102 (Polymerization)

3kg of propylene were placed in an autoclave with an inner volume of 17 liter and after raising the temperature to 60°C, 7.0 millimoles of triethylaluminum, 5 7.0 millimoles of dicyclopentyldimethoxysilane, and

2.28g of the prepolymer catalyst obtained in the abovedescribed manner were added. The temperature was then raised to 70°C and kept there for 10 minutes to carry out polymerization.

Next, the vent valve was opened and the unreacted propylene was purged via an integrating flowmeter (end of first stage propylene homopolymerization).

After the end of purging, the vent valve was closed, 3kg of propylene and 0.7 liter of hydrogen were introduced, and the temperature was raised to 70°C and kept there for 5 minutes to carry out polymerization.

The vent valve was then opened and the unreacted propylene was purged via an integrating flowmeter (end of second stage propylene homopolymerization).

After the end of purging, the vent valve was closed, 3kg of propylene and 8.5 liter of hydrogen were introduced, and the temperature was raised to 70°C and kept there for 60 minutes to carry out polymerization.

After then adding a small amount of ethanol to stop the polymerization reaction, the unreacted gas in the

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103 reactor was purged via an integrating flowmeter (end of third stage propylene homopolymerization).

2780g of polypropylene were obtained by the above procedure.

This polypropylene had an intrinsic viscosity (η) of 2.1dl/g and a bulk specific gravity of 0.48g/ml. The ratio of the polymer quantities at the respective stages as calculated from the integrating flowmeter was first stage (xi)/second stage (X2)/third stage (X3) = 6/6/88.

0 The intrinsic viscosities (T]ist) &gt; (îl2nd) / and (H3rd) °f the polymers obtained in the respective stages are shown in Table 1. These intrinsic viscosities of the respective stages were determined as follows.

The intrinsic viscosity (T|i_st) ^of the polymer obtained in the first stage was measured by sampling a portion of the polymer after completion of the first stage.

The intrinsic viscosity (η2ηά) of the polymer obtained in the second stage and the intrinsic viscosity

0 (T|3rd) of the polymer obtained in the third stage were determined using equations (1) and (2) indicated below.

(r|2. Total) = Xl/(X1 + X2&gt; (Hist) ⁺ X2/(Xl ⁺ X2 ) (Ί2ηά) · (U

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104 (TlTotal) = Xl/ (*1 + *2 + *3) ( T|lst ) + *2/(*1 + *2 + *3 ) (H2nd) + X3/(X1 + *2 + *3 ) (Tl3rd) (2)

In the above, χχ, X2, and X3 are the polymer quantity ratios of the respective stages, (η₂, Total) is trie value measured upon sampling a portion of the polymer after the completion of the second stage, and (η Total) is the value measured upon sampling a

0 portion of the polymer after the completion of the third stage.

(Pelletization)

Pelletizing of the homopolypropylene was performed by blending

0.1 parts by weight of 3,5-di-t-butyl-4hydroxytoluene,

0.1 parts by weight of tetrakis[methylene-3(3,5-dit-butyl-4-hydroxyphenyl)propionate]methane,

0.1 parts by weight of calcium stearate, and

0.2 parts by weight of sodium-2,2'-methylenebis(4,6-di-t-butylphenyl) phosphate with 100 weight parts of the polypropylene (PP-1) obtained as described above and

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105 melt kneading at a resin temperature of 230°C with a double-axis extruder (made by Haake Co.).

The IS55 injection molder manufactured by Toshiba Machinery Co. Ltd. was then used to prepare a test piece under predetermined conditions from the sample thus obtained. The test results are shown in Table 2.

ExampJ.ê-2

Production of Homopolvpropvlene (PP-2)

3kg of propylene were placed in an autoclave with an inner volume of 17 liter and after raising the temperature to 60°C, 7.0 millimoles of triethylaluminum, 7.0 millimoles of dicyclopentyldimethoxysilane, and

2.28g of the prepolymer catalyst obtained in Example 1

5 were added. The temperature was kept at 60°C for 14 minutes to carry out polymerization.

Next, the vent valve was opened and the unreacted propylene was purged via an integrating flowmeter (end of first stage propylene homopolymerization).

After the end of purging, the vent valve was closed, 3kg of propylene and 0.6 liter of hydrogen were introduced, and the temperature was raised to 70°C and kept there for 6 minutes to carry out polymerization.

The vent valve was then opened and the unreacted

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106 propylene was purged via an integrating flowmeter (end of second stage propylene homopolymerization).

After the end of purging, the vent valve was closed, 3kg of propylene and 23 liter of hydrogen were introduced, and the temperature was raised to 70°C and kept there for 65 minutes to carry out polymerization.

After then adding a small amount of ethanol to stop the polymerization reaction, the unreacted gas in the reactor was purged via an integrating flowmeter (end of third stage propylene homopolymerization).

814g of polypropylene were obtained by the above procedure.

This polypropylene had an intrinsic viscosity (η) of 2.0dl/g and a bulk specific gravity of 0.48g/ml. The ratio of the polymer quantities at the respective stages as calculated from the integrating flowmeter was first stage (χχ)/second stage (X2&gt;/third stage (X3) = 8/8/84.

The intrinsic viscosities (T|ist) · (^rl2nd) &gt; and (l|3ra) the polymers obtained in the respective stages are shown in Table 1.

( Pelletization)

Example 1 was repeated except for using the homopolypropylene (PP-2) obtained in the above manner in place of PP-1, to perform pelletization.

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107

An injection molded test piece was prepared in the same manner as in Example 1. The results are shown in

Table 2.

Example 3

Production of Homopolvoroovlene (PP-3)

3kg of propylene were placed in an autoclave with an inner volume of 17 liter and after raising the temperature to 60°C, 7.0 millimoles of triethylaluminum, 10 7.0 millimoles of di-t-butyldimethoxysilane (DTBMS), and

2.28g of the prepolymer catalyst obtained in Example 1 were added. The temperature was then raised to 70°C and kept there for 9 minutes to carry out polymerization.

Next, the vent valve was opened and the unreacted propylene was purged via an integrating flowmeter (end of first stage propylene homopolymerization).

After the end of purging, the vent valve was closed, 3kg of propylene and 0.7 liter of hydrogen were introduced, and the temperature was raised to 70°C and 20 kept there for 5 minutes to carry out polymerization.

The vent valve was then opened and the unreacted propylene was purged via an integrating flowmeter (end of second stage propylene homopolymerization).

After the end of purging, the vent valve was closed, 3kg of propylene and 56 liter of hydrogen were

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108 introduced, and the temperature was raised to 70°C and kept there for 70 minutes to carry out polymerization. After then adding a small amount of ethanol to stop the polymerization reaction, the unreacted gas in the 5 reactor was purged via an integrating flowmeter (end of third stage propylene homopolymerization).

697g of polypropylene were obtained by the above procedure.

This polypropylene had an intrinsic viscosity (η) of 2.2dl/g and a bulk specific gravity of 0.47g/ml. The ratio of the polymer quantities at the respective stages as calculated from the integrating flowmeter was first stage (χχ)/second stage (X2)/third stage (X3) = 8/8/84. The intrinsic viscosities (T|ist) / (l|2nd) t ancl (T)3rd) °f

5 the polymers obtained in the respective stages are shown in Table 1.

(Pelletization)

Example 1 was repeated except for using the 20 homopolypropylene (PP-3) obtained in the above manner in place of PP-1, to perform pelletization.

An injection molded test piece was prepared in the same manner as in Example 1. The results are shown in

Table 2.

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109

Comparative Example 1

Production of Homopolvpropvlene (PPcll

3kg of propylene and 6.5 liter of hydrogen were placed in an autoclave with an inner volume of 17 liter and after raising the temperature to 6Q°C, 7.0 millimoles of triethylaluminum, 7.0 millimoles of dicyclopentyldimethoxysilane, and 2.28g of the prepolymer catalyst obtained in Example 1 were added.

The temperature was then raised to 70°C and kept there for 55 minutes to carry out polymerization.

After then adding a small amount of ethanol to stop the polymerization reaction, the unreacted gas in the reactor was purged via an integrating flowmeter.

2755g of polypropylene were obtained by the above procedure.

This polypropylene had an intrinsic viscosity (η) of 1.7dl/g and a bulk specific gravity of Q.48g/ml.

(Pelletization)

Example 1 was repeated except for using the homopolypropylene (PPc-1) obtained in the above manner in place of PP-1, to perform pelletization.

An injection molded test piece was prepared in the same manner as in Example 1. The results are shown in

5 Table 2.

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110

Example 4

Production of Propylene Block Copolymer (PP-4)

First stage propylene homopolymerization, second 5 stage propylene homopolymerization, and third stage propylene homopolymerization were carried out in the same manner as in Example 2, and the unreacted gas after the end of the third stage propylene homopolymerization was purged without adding ethanol.

Ethylene, propylene, and hydrogen were then supplied to the polymerizer at rates of 800 liter/hour,

1200 liter/hour and 30 liter/hour, respectively, the vent opening of the polymerizer was adjusted to keep the pressure inside the polymerizer at 10kg/cm²-G, and 15 polymerization was carried out for 60 minutes at 70°C.

After then adding a small amount of ethanol to stop the polymerization reaction, the unreacted gas in the polymerizer was purged.

3141g of polypropylene were obtained in the above

0 manner.

The quantity of polymer in the rubber component comprised llwt.% of the polypropylene, the intrinsic viscosity (η) was 3.0dl/g, and the ethylene content was

40mol%.

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111 (Pelletization)

Example 1 was repeated except for using the propylene block copolymer (PP-4) obtained in the above manner in place of PP-1, to perform pelletization.

An injection molded test piece was prepared in the same manner as in Example 1. The results are shown in

Table 2.

Comparison Example 2

Production of Propylene Block Polymer (PPc2)

After performing homopolymerization of propylene in the same manner as in Comparative Example 1, the unreacted gas was purged without adding ethanol.

Ethylene, propylene, and hydrogen were then supplied to 15 the polymerizer at rates of 800 liter/hour, 1200 liter/hour and 30 liter/hour, respectively, the vent opening of the polymerizer was adjusted so that the pressure inside the polymerizer was 10kg/cm²-G, and polymerization was carried out for 60 minutes at 70°C.

After then adding a small amount of ethanol to stop the polymerization reaction, the unreacted gas in the polymerizer was purged.

3132g of polypropylene were obtained in the above manner.

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112

The quantity of polymer in the rubber component comprised 10wt.% of the polypropylene, the intrinsic viscosity (η) was 3.0dl/g, and the ethylene content was

40mol%.

(Pelletization)

Example 1 was repeated except for using the propylene block copolymer (PPc-2) obtained in the above manner in place of PP-1, to perform pelletization.

An injection molded test piece was prepared in the same manner as in Example 1. The results are shown in

Table 2.

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113

Table 1

<td colspan="2" rowspan="2"></td><td> Ex.l</td><td> Ex. 2</td><td> Ex. 3</td><td> Comp. Ex.l</td><td> Ex. 4</td><td> Comp. Ex. 2</td>

<td> PP-l</td><td> PP-2</td><td> PP-3</td><td> PPcl</td><td> PP-4</td><td> PPc2</td>

<td rowspan="2"> Propylene i First stage</td><td> □olymerization (η 1st)(di/g)</td><td> 8.8</td><td> 9.5</td><td> 12</td><td> 1.7</td><td> 9.5</td><td> 1.7</td>

<td> Polymer ratio (wt.%)</td><td> 6</td><td> 8</td><td> 8</td><td> 100</td><td> 5</td><td> 90</td>

<td rowspan="2"> Second stage</td><td> (Ί 2nd)(dl/g)</td><td> 4.3</td><td> 4.5</td><td> 6.5</td><td></td><td> 4.5</td><td></td>

<td> Polymer ratio (wt. % )</td><td> 6</td><td> 8</td><td> 8</td><td> -</td><td> 5</td><td></td>

<td rowspan="2"> Third stage</td><td> (η 3rd) (dl/g)</td><td> 1.5</td><td> 1.0</td><td> 1.0</td><td></td><td> 1.0</td><td></td>

<td> Polymer ratio (wt. %)</td><td> 88</td><td> 84</td><td> 84</td><td> -</td><td> 79</td><td> -</td>

<td rowspan="3"> Rubber com]</td><td> ponent (η) (dl/g)</td><td colspan="4" rowspan="3"></td><td> 3.0</td><td> 3.0</td>

<td> Ethylene content (mol %)</td><td> 40</td><td> 40</td>

<td> Polymer ratio (wt. % )</td><td> 11</td><td> 10</td>

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114

Table 2

<td rowspan="2"></td><td rowspan="2"> Propylene No.</td><td colspan="5"> Components insoluble in 64°C decane</td>

<td> Quantity (wt. %)</td><td> (η) (dl/g)</td><td> Mz/Mw</td><td> mmmm percentage ( % )</td><td> D value</td>

<td> Ex. 1</td><td> PP-1</td><td> 99.4</td><td> 2.1</td><td> 6.1</td><td> 99.0</td><td> 6.1</td>

<td> Ex. 2</td><td> PP-2</td><td> 99.6</td><td> 2.0</td><td> 8.0</td><td> 98.7</td><td> 6.3</td>

<td> Ex. 3</td><td> PP-3</td><td> 99.5</td><td> 2.2</td><td> 9.3</td><td> 98.4</td><td> 7.5</td>

<td> Comp . Ex. 1</td><td> PPcl</td><td> 99.5</td><td> 1.7</td><td> 3.5</td><td> 98.5</td><td> 2.1</td>

<td> Ex. 4</td><td> PP-4</td><td> 89.5</td><td> 2.0</td><td> 7.9</td><td> 98.2</td><td> 6.4</td>

<td> Comp. Ex. 2</td><td> PPc2</td><td> 89.4</td><td> 2.1</td><td> 3.2</td><td> 98.2</td><td> 2.2</td>

Table 2 (continue)

<td rowspan="2"></td><td colspan="4"> Total polypropylene</td>

<td> FM (MPa)</td><td> MT (g)</td><td> Pencil</td><td> hardness</td>

<td> Ex. 1</td><td> 2432</td><td> 2.5</td><td></td><td> HB</td>

<td> Ex. 2</td><td> 2551</td><td> 4.0</td><td></td><td> F</td>

<td> Ex. 3</td><td> 2700</td><td> 7.0</td><td></td><td> F</td>

<td> Comp. Ex. 1</td><td> 2121</td><td> 0.6</td><td></td><td> B</td>

<td> Ex. 4</td><td> 2150</td><td> 3.8</td><td></td><td> 2B</td>

<td> Comp. Ex. 2</td><td> 1844</td><td> 0.5</td><td></td><td> 3B</td>

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Production examples of the polypropylene used in the embodiments and comparison examples described below shall now be described.

Preparation Example 1

Production of Homopolvoropvlene (PP-5) (Polymerization)

135.9kg of propylene were placed in a polymerizer with an inner volume of lm³ and after raising the

0 temperature to 30°C, 250 millimoles of triethylaluminum, 250 millimoles of dicyclopentyldimethoxysilane, and 5 millimoles of the solid titanium catalyst component (a) obtained in Example 1 were added. The temperature was then maintained at 30°C and the pressure was kept at 15 5.7kg/cm²G for 45 minutes to carry out polymerization.

Next, the vent valve was opened and the unreacted propylene was purged via an integrating flowmeter (end of first stage propylene homopolymerization).

After the end of purging, the vent valve was 20 closed, 125kg of propylene and 200N liter of hydrogen were introduced, and the temperature was raised to 70°C and kept there for 2 hours and 23 minutes to carry out polymerization. The vent valve was then opened and the unreacted propylene was purged via an integrating

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116 flowmeter (end of second stage propylene homopolymerization).

91.2kg of polypropylene were obtained by the above procedure .

This polypropylene had an intrinsic viscosity (η) of 2.9dl/g and a bulk specific gravity of 0.47g/ml. The ratio of the polymer quantities at the respective stages as calculated from the integrating flowmeter was first stage (χχ)/second stage (X2) = 5/95.

The intrinsic viscosities (T|ist) and (Ή2ηά) of the polymers obtained in the respective stages and the (η) ((TlTotal)) of polypropylene (PP-5) are shown in Table 3.

These intrinsic viscosities of the respective stages were determined as follows.

The limiting viscosity (Hist) of the polymer obtained in the first stage was measured by sampling a portion of the polymer after completion of the first stage.

The limiting viscosity (H2nd) of the polymer obtained in the second stage was determined using equation (1) indicated below.

(11 Total) = Xl/(X1 + X2) (Hist) + X2/(Xl + ^x2 ) (Tl2nd) .·’·’(!)

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117

Preparation Example 2

Production of Homopolypropvlene (PP-6)

153.8kg of propylene were placed in a polymerizer with an inner volume of lm³ and after raising the 5 temperature to 30°C, 250 millimoles of triethylaluminum,

250 millimoles of dicyclopentyldimethoxysilane, and 5 millimoles of the solid titanium catalyst component (a) obtained in Example 1 were added. The temperature was then kept at 30°C and the pressure was kept at 10 5.7kg/cm²G for 50 minutes to carry out polymerization.

Next, the vent valve was opened and the unreacted propylene was purged via an integrating flowmeter (end of first stage propylene homopolymerization).

After the end of purging, the vent valve was closed, 135kg of propylene and 1580N liter of hydrogen were introduced, and the temperature was raised to 7 0°C and kept there for 4 hours and 35 minutes to carry out polymerization. The vent valve was then opened and the unreacted propylene was purged via an integrating 20 flowmeter (end of second stage propylene homopolymerization).

This polypropylene had an intrinsic (η) of 1.5dl/g and a bulk specific gravity of 0.47g/ml. The ratio of the polymer quantities at the respective stages as

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118 calculated from the integrating flowmeter was first stage (χχ)/second stage (X2) = 5/95.

The intrinsic viscosities (rçi_st) and (η2ηά) of the polymers obtained in the respective stages and the (η) ((BTotal)) of polypropylene {PP—6) are shown in Table 3.

Preparation Example 3

Production of Homopolvpropvlene (PP-7)

150.2kg of propylene were placed in a polymerizer

0 with an inner volume of lm³ and after raising the temperature to 30°C, 250 millimoles of triethylaluminum,

250 millimoles of dicyclopentyldimethoxysilane, and 5 millimoles of the solid titanium catalyst component (a) obtained in Example 1 were added. The temperature was

5 then maintained at 3 0°C and the pressure was kept at 5.7kg/cm²G for 2 hours and 15 minutes to carry out polymerization.

Next, the vent valve was opened and the unreacted propylene was purged via an integrating flowmeter (end of first stage propylene homopolymerization).

After the end of purging, the vent valve was closed, 130kg of propylene and 650N liter of hydrogen were added, and the temperature was raised to 70°C and kept there for 4 hours to carry out polymerization. The vent valve was then opened and the unreacted propylene

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119 was purged via an integrating flowmeter (end of second stage propylene homopolymerization).

84kg of polypropylene were obtained by the above procedure .

This polypropylene had an intrinsic viscosity (η) of 2.7dl/g and a bulk specific gravity of 0.47g/ml. The ratio of the polymer quantities at the respective stages as calculated from the integrating flowmeter was first stage (xi)/second stage (X2) = 12/88.

0 The limiting viscosities (T|ist:) ^and (Ή2ηά) the polymers obtained in the respective stages and the (η) of polypropylene (PP-7) are shown in Table 3.

Preparation Example 4

Production of Homopolvoroovlene (PP-8) (Polymerization)

148.7kg of propylene were placed in a polymerizer with an inner volume of lm³ and after raising the temperature to 30°C, 250 millimoles of triethylaluminum,

250 millimoles of dicyclopentyldiraethoxysilane, and 5 millimoles of the solid titanium catalyst component (a) obtained in Example 1 were added. The temperature was then maintained at 30°C and the pressure was kept at 5.7kg/cm²G for 52 minutes to carry out polymerization.

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120

Next, the vent valve was opened and the unreacted propylene was purged via an integrating flowmeter (end of first stage propylene homopolymerization).

After the end of purging, the vent valve was closed, 135kg of propylene and 280ÛN liter of hydrogen were added, and the temperature was raised to 70°C and kept there for 6 hours and 30 minutes to carry out polymerization. The vent valve was then opened and the unreacted propylene was purged via an integrating flowmeter (end of second stage propylene homopolymerization).

121kg of polypropylene were obtained by the above procedure.

This polypropylene had an intrinsic viscosity (η) of 1.2dl/g and a bulk specific gravity of 0.47g/ml. The ratio of the polymer quantities at the respective stages as calculated from the integrating flowmeter was first stage (χχ)/second stage (X2) = 5/95.

The limiting viscosities (riist) and (Ή2ηά) the 20 polymers obtained in the respective stages and the (η) of polypropylene (PP-8) are shown in Table 3.

PreparatiQn Example 5

Production of Polypropylene (PP-9)

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121

The temperature of a slurry solution (100g/liter) of the propylene (PP-8) powder, obtained in the manner described above, in decane was kept at 124°C and stirred for 2 hours. Thereafter, the slurry solution was filtered, and the filter mass was dried to obtain polypropylene (PP-9).

The intrinsic viscosity (η) of this polypropylene was 1.4g/dl.

Preparation Example 6

Production of Polypropylene (PP-1Œ1

The temperature of a slurry solution {100g/liter) of the propylene (PP-8) powder, obtained in the manner described above, in decane was kept at 120°C and stirred 15 for 2 hours. Thereafter, the slurry solution was filtered, and the filter mass was dried to obtain polypropylene (PP-10).

The intrinsic viscosity (η) of this polypropylene was 1.3g/dl.

Comparative Preparation Example 1

Production of Homopolypropylene (PPc3)

135kg of propylene and 200N liter of hydrogen were placed in a polymerizer with an inner volume of lm³ and after raising the temperature to 70°C, 250 millimoles of

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122 triethylaluminum, 250 millimoles of dicyclopentyldimethoxysilane, and 5 millimoles of the solid titanium catalyst component (a) obtained in

Example 1 were added. The temperature was then maintained at 70°C and the pressure was kept at

5.7kg/cm²G for 4 hours to carry out polymerization. The vent valve was then opened and the unreacted propylene was purged via an integrating flowmeter.

71kg of polypropylene were obtained by the above 10 procedure.

This polypropylene had an intrinsic viscosity (η) of 2.7dl/g and a bulk specific gravity of 0.47g/ml.

Comparative Preparation Example 2

Production of Homopolvpropvlene &lt;PPc4)

135kg of propylene and 1350N liter of hydrogen were placed in a polymerizer with an inner volume of lm³ and after raising the temperature to 70°C, 250 millimoles of triethylaluminum, 250 millimoles of 20 dicyclopentyldimethoxysilane, and 5 millimoles of the solid titanium catalyst component (a) obtained in

Example 1 were added. The temperature was then maintained at 70°C and the pressure was kept at 5.7kg/cm²G for 4 hours to carry out polymerization. The

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123 vent valve was then opened and the unreacted propylene was purged via an integrating flowmeter.

78kg of polypropylene were obtained by the above procedure .

This polypropylene had an intrinsic viscosity (η) of 1.3dl/g and a bulk specific gravity of 0.47g/ml.

CQwaratîvs Preparation Exawie .3.

Production of Homopolyproovlene (PPc5)

135kg of propylene and 690N liter of hydrogen were placed in a polymerizer with an inner volume of lm³ and after raising the temperature to 70°C, 250 millimoles of triethylaluminum, 250 millimoles of dicyclopentyldimethoxysilane, and 5 millimoles of the solid titanium catalyst component (a) obtained in Example 1 were added. The temperature was then maintained at 70°C and the pressure was kept at 5.7kg/cm²G for 4 hours to carry out polymerization.

The vent valve was then opened and the unreacted propylene was purged via an integrating flowmeter (end of first stage propylene homopolymerization).

After the end of purging, the vent valve was closed, 130kg of propylene and 1950N liter of hydrogen were introduced, and the temperature was raised to 70°C and kept there for 3 hours to carry out polymerization.

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124

The vent valve was then opened and the unreacted propylene was purged via an integrating flowmeter (end of second stage propylene homopolymerization).

88kg of polypropylene were obtained by the above 5 procedure.

This polypropylene had an intrinsic viscosity (η) of 1.3dl/g and a bulk specific gravity of 0.47g/ml. The ratio of the polymer quantities at the respective stages as calculated from the integrating flowmeter was first 10 stage (xi)/second stage (X2) = 40/60.

The intrinsic viscosities (T|i_st) and (η2ηά) °f polymers obtained in the respective stages and the (η) of polypropylene (PPc5) are shown in Table 3.

Comparative preparation Example 4

Production of Homopolvpropvlene (PPc6)

135kg of propylene and 68N liter of hydrogen were placed in a polymerizer with an inner volume of lm³ and after raising the temperature to 70°C, 250 millimoles of triethylaluminum, 250 millimoles of dicyclopentyldimethoxysilane, and 5 millimoles of the solid titanium catalyst component (a) obtained in

Example 1 were added. The temperature was then maintained at 70°C and the pressure was kept at

5.7kg/cm²G for 4 hours to carry out polymerization.

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125

The vent valve was then opened and the unreacted propylene was purged via an integrating flowmeter (end of first stage propylene homopolymerization).

After the end of purging, the vent valve was 5 closed, 130kg of propylene and 850N liter of hydrogen were introduced, and the temperature was raised to 70°C and kept there for 3 hours to carry out polymerization.

The vent valve was then opened and the unreacted propylene was purged via an integrating flowmeter (end 10 of second stage propylene homopolymerization).

89kg of polypropylene were obtained by the above procedure.

This polypropylene had an intrinsic viscosity (η) of 2.6dl/g and a bulk specific gravity of 0.47g/ml. The 15 ratio of the polymer quantities at the respective stages as calculated from the integrating flowmeter was first stage (χχ)/second stage (X2) = 40/60.

The limiting viscosities (Hist) and (η2ηά) of the polymers obtained in the respective stages and the (η) of polypropylene (PPc6) are shown in Table 3.

Comparative Preparation Example 5

Production of Homopolvpropvlene (PPc7)

135kg of propylene and 1500N liter of hydrogen were 25 placed in a polymerizer with an inner volume of lm³ and

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126 after raising the temperature to 7Q°C, 250 millimoles of triethylaluminum, 250 millimoles of dicyclopentyldimethoxysilane, and 5 millimoles of the solid titanium catalyst component (a) obtained in 5 Example 1 were added. The temperature was then maintained at 70°C and the pressure was kept at 5.7kg/cm²G for 4 hours to carry out polymerization. The vent valve was then opened and the unreacted propylene was purged via an integrating flowmeter.

82kg of polypropylene were obtained by the above procedure .

This polypropylene had an intrinsic viscosity (η) of 1.2dl/g and a bulk specific gravity of 0.47g/ml.

Reference Preparation Example

Production of Homopolypropvlene (PP-11)

150.2kg of propylene were placed in a polymerizer with an inner volume of lm³ and after raising the temperature to 30°C, 250 millimoles of triethylaluminum,

250 millimoles of dicyclopentyldimethoxysilane, and 5 millimoles of the solid titanium catalyst component (a) obtained in Example 1 were added. The temperature was then maintained at 3 0°C and the pressure was kept at 5.7kg/cm²G for 2 hours and 15 minutes to carry out polymerization.

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Next, the vent valve was opened and the unreacted propylene was purged via an integrating flowmeter (end of first stage propylene homopolymerization).

After the end of purging, the vent valve was closed, 130kg of propylene and 1950N liter of hydrogen were added, and the temperature was raised to 70°C and kept there for 4 hours to carry out polymerization. The vent valve was then opened and the unreacted propylene was purged via an integrating flowmeter (end of second stage propylene homopolymerization).

90kg of polypropylene were obtained by the above procedure .

This polypropylene had an intrinsic viscosity (η) of 2.2dl/g and a bulk specific gravity of 0.47g/ml. The ratio of the polymer quantities at the respective stages as calculated from the integrating flowmeter was first stage (χχ)/second stage (X2&gt; = 15/85.

The intrinsic viscosities (TJist) and (Ή2ηά) °f the polymers obtained in the respective stages and the (η) of polypropylene (PP-11) are shown in Table 3.

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Table

128

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The evaluation methods, besides those described above, which were used to evaluate the polypropylene or polypropylene composition in Examples and Comparative

Examples are described below.

(Quantity of components insoluble in 64°C decane)

In the description of Examples and Comparative

Examples that follow, the quantity of components insoluble in 64°C decane* (wt. % ) indicated in the Tables is that of the components insoluble in 64°C decane that are contained in the components soluble in 140°C decane

Quantity of components insoluble in 64°C decane (wt.%) = (Quantity of components insoluble in 64°C decane (weight)) / (Quantity of components soluble in 15 140°C decane) X 100 (Melt flow rate (MFR))

The melt flow rate was measured at 230°C and under a load of 2.16kg in compliance with ASTM D1238.

(Flexure modulus (FM))

Using a test piece that was injection molded under predetermined conditions, the flexure modulus was measured at a test temperature of 23°C, span interval o:

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51mm, and flexing rate of 20mm/minute in compliance with

ASTM D79Q.

(Izod impact strength (IZ))

The Izod impact strength was measured in compliance with ASTM D790.

(Tensile elongation)

The tensile elongation was measured in compliance with ASTM D638.

(SR (die swell ratio))

A sample was extruded at 230°C and γ = 2600sec^-1 using a capillary rheometer (barrel diameter: 10mm, nozzle diameter (D): 1mm, nozzle length (L): 30mm). The diameter of the extruded strand was measured and this diameter was divided by the nozzle diameter (D) to obtain the SR.

(Surface hardness)

The surface hardness was measured in compliance with ASTM D685 (R scale).

(Embrittlement temperature)

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The embrittlement temperature was measured in compliance with ASTM D746.

(External appearance)

100 parts by weight of polypropylene composition was blended with two parts by weight of a carbon master batch (PPM01143 Black supplied from by Toyo Ink Co.,

Ltd.) and this was used to form an injection molded rectangular plate (length 350mm X width 100mm X thickness 3mm) . The gate was a side gate and was located 35mm from an end in the length direction. The external appearance was judged visually under the following standards.

AA : No flow marks are seen within 300mm in the length direction from the gate position.

BB: No flow marks are seen within 280mm in the length direction from the gate position.

CC: A flow mark is seen within 280mm in the length direction from the gate position.

Here, a flow mark refers to vertical, stripe-like patterns that occur in the injection path.

Examples 5 to 7

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Each of the polypropylenes (PP-5 to PP-7) obtained in Preparation Examples was pelletized by blending 100 parts by weight of the polypropylene with

0.1 parts by weight of 3,5-di-t-butyl-45 hydroxytoluene,

0.1 parts by weight of tetrakis[methylene-3(3,5-di t-butyl-4-hydroxyphenyl) propionate]methane, and

0.1 parts by weight of calcium stearate, and melt kneading at a resin temperature of 230°C with 10 a double-axis extruder (made by Haake Co.).

The results are shown in Table 4.

Example 8

Polypropylene powders obtained in Preparation

Examples 5 and 6 described above were dry-blended at a weight ratio of (PP-5)/(PP-6) = 63/37 to prepare a polypropylene mixture.

This mixture was pelletized in the same manner as in Example 5. The results are shown in Table 4.

Example 9

The polypropylene mixture obtained in Preparation

Examples 8 was pelletized by blending 100 parts by weight of the polypropylene mixture with

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0.1 parts by weight of 3,5-di-t-butyl-4hydroxytoluene,

0.1 parts by weight of tetrakis[methylene-3 (3,5-di t-butyl-4-hydroxyphenyl·)propionate]methane,

0.1 parts by weight of calcium stearate, and

0.2 parts by weight of sodium-2,2¹-methylenebis{4,6-di-t-butylphenyl) phosphate and melt kneading at a resin temperature of 230°C with a double-axis extruder {made by Haake Co.).

The results are shown in Table 4.

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134

<td> ΟΊ X w</td><td> &lt;0 ί r» a co 0-</td><td colspan="3"> co cn</td><td colspan="3"> m co σι</td><td> 1 2.0 I</td><td> CN m</td><td> 3.13</td><td> m m m</td><td> CO σ</td><td> 10.7 |</td><td> 98.4</td><td> ΓΊ CO N</td><td> 15.1</td><td> | 2540 |</td><td colspan="2"> rd CN</td><td> O N</td><td colspan="2"> LO O</td><td> 2.03 |</td>

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<td></td><td> i ro</td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td>

<td></td><td> Û4 LO</td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td>

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<td> r-</td><td></td><td></td><td> CN</td><td></td><td></td><td></td><td></td><td> r-</td><td> CN m</td><td> co</td><td> m LO</td><td> LO</td><td> un</td><td> N</td><td> iH</td><td> 00</td><td> o CN</td><td> Ν’</td><td></td><td> O</td><td> CN</td><td></td><td> N O</td>

<td> X ω</td><td> CL, CL</td><td></td><td> cn cn</td><td></td><td></td><td> œ σ</td><td></td><td> CN</td><td> η-</td><td> N*</td><td> CN</td><td> LO</td><td> in</td><td> CO σ</td><td> N</td><td> CN</td><td> σ CN</td><td> CO</td><td></td><td> Ρ- οο</td><td> CN</td><td></td><td> CN</td>

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<td></td><td></td><td> in</td><td> c</td><td></td><td> (Λ</td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td> -—</td><td> r i</td><td></td><td></td>

<td></td><td></td><td> jj</td><td rowspan="2"> &lt;0 f I</td><td></td><td> 4L</td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td> σ</td><td></td><td></td><td> .—«</td><td></td><td></td><td> dP</td><td> 0</td><td></td><td></td>

<td></td><td> 0</td><td> £</td><td></td><td> £</td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td> £ —</td><td></td><td></td><td> Iti</td><td></td><td></td><td> --</td><td> O</td><td></td><td></td>

<td></td><td> 2!</td><td> Φ</td><td rowspan="3"> Φ Ό</td><td></td><td> Φ</td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td> 4J dP</td><td></td><td></td><td> a</td><td></td><td></td><td></td><td> CO</td><td></td><td></td>

<td></td><td></td><td> £</td><td></td><td> £</td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td> £ ~</td><td></td><td></td><td> S</td><td> r</td><td></td><td> £</td><td> CN</td><td></td><td> —</td>

<td></td><td> jJ</td><td> C</td><td></td><td> 0</td><td rowspan="2"> Ο ο</td><td></td><td></td><td> n</td><td> in</td><td> LO</td><td></td><td></td><td> Φ</td><td></td><td> W</td><td> —</td><td> 4L</td><td></td><td> 0</td><td></td><td></td><td> U</td>

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<td></td><td> Φ</td><td> Φ</td><td> Ν’</td><td></td><td> υ</td><td></td><td></td><td></td><td></td><td></td><td></td><td> S</td><td></td><td> a</td><td> £</td><td> £</td><td></td><td> £</td><td></td><td> σ</td><td></td><td></td>

<td></td><td> £</td><td></td><td> 1</td><td></td><td></td><td> £</td><td> dP</td><td> —</td><td> X</td><td> X</td><td> X</td><td></td><td></td><td></td><td> T—1</td><td> Ή</td><td> £</td><td> 4L</td><td></td><td> £</td><td> £</td><td></td><td></td>

<td></td><td> Φ</td><td> ml</td><td></td><td></td><td> ML</td><td> •Η</td><td></td><td></td><td> •—</td><td> —«</td><td> &gt;—»</td><td> X.</td><td> N</td><td> g</td><td> fd</td><td> ε</td><td></td><td> 03</td><td rowspan="2"> S \</td><td> 0</td><td> 0</td><td></td><td> **</td>

<td></td><td></td><td> 0</td><td> £</td><td></td><td> 0</td><td></td><td> 4L</td><td></td><td></td><td></td><td></td><td></td><td> S</td><td> g</td><td> &gt;</td><td></td><td> 0</td><td></td><td> rH</td><td> •H</td><td></td><td> o</td>

<td></td><td> &gt;1</td><td></td><td> •pH</td><td></td><td></td><td> φ</td><td> 3</td><td> !=</td><td> C</td><td> 3</td><td> N</td><td> 3</td><td></td><td> g</td><td></td><td> ο</td><td> b</td><td> 4L</td><td></td><td> Φ</td><td> in</td><td></td><td> o</td>

<td></td><td> a</td><td></td><td></td><td></td><td> &gt;1</td><td> r—1</td><td></td><td></td><td> 2</td><td> S</td><td> S</td><td> S</td><td></td><td> g</td><td> Q</td><td> rH</td><td></td><td> U</td><td></td><td></td><td> c</td><td></td><td> LO</td>

<td></td><td> 0</td><td> 4L</td><td> Φ</td><td></td><td> L»</td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td> Φ</td><td> id</td><td></td><td> Φ</td><td> φ</td><td></td><td> CN</td>

<td></td><td> Li</td><td> •H</td><td> rH</td><td></td><td> •H</td><td> £</td><td> Φ</td><td> •—·</td><td></td><td></td><td></td><td></td><td> —·</td><td> -—</td><td> —-</td><td> σ</td><td> Ll</td><td> a</td><td></td><td> nH</td><td> 4L</td><td></td><td> II</td>

<td></td><td> P-</td><td> 4L</td><td> J2</td><td> dP</td><td> L&gt;</td><td> f—1</td><td> £</td><td> ί—1</td><td></td><td></td><td></td><td></td><td> CN</td><td> m</td><td> N</td><td> —</td><td> £</td><td> t</td><td> r ί</td><td> •H</td><td></td><td></td><td></td>

<td></td><td> S</td><td> £</td><td> £</td><td></td><td> £</td><td> Q</td><td> &lt;C</td><td></td><td></td><td></td><td></td><td></td><td> —'</td><td></td><td></td><td></td><td> X</td><td> •rH</td><td> o</td><td> 01</td><td> 4L</td><td></td><td></td>

<td></td><td> i—1</td><td> £</td><td> rH</td><td> 4L</td><td> £</td><td> U}</td><td> U</td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td> CL</td><td> Φ</td><td></td><td> ro</td><td> £</td><td> i-H</td><td></td><td rowspan="2"> a</td>

<td></td><td> 0</td><td> O</td><td> Ç</td><td> ?</td><td> O</td><td> £</td><td> Φ</td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td> a</td><td> rH</td><td> N</td><td> CN</td><td> Φ</td><td> Φ</td><td> σ</td>

<td></td><td> a</td><td> O</td><td> in</td><td></td><td> O</td><td> •H</td><td> TJ</td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td></td><td> s</td><td> a</td><td> H</td><td></td><td></td><td> 2</td><td></td><td> σι</td>

* Quantity of components insoluble in 64°C decane (wt.%) = (Quantity of components insoluble in 64°C decane (weight)) / (Quantity of components insoluble in 140°C decane) X 100

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Comparative examples 3 to 6

Example 5 was repeated except for using the polypropylenes PPc3 to PP-c6 obtained in Comparative preparation Examples 1 to 4 in place of polypropylene 5 PP-5, pelletizing was performed in the same manner as in

Example 5. The results are shown in Table 5.

Comparative Example 7

Polypropylene powders obtained in Comparative 10 preparation Example 4 and Reerance preparation Example were dry-blended at a weight ratio of (PPc6)/(PP-11) =

59/41 to prepare a polypropylene mixture.

Examples 5 was repeated except for using this polypropylene mixture in place of polypropylene PP-5, pelletizing was performed in the same manner as in Example 5. The results are shown in Table 5.

Comparative Example 8

The polypropylene mixture obtained in Comparative 20 Example 7 was pelletized in the same manner as in

Example 9. The results are shown in Table 5.

Referential Example 1

Example 5 was repeated except for using the polypropylene PP-11 obtained in the reference production

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Table 5

<td></td><td> Comp. Ex. 3</td><td> Comp. Ex 4</td><td> Comp. Ex. 5</td><td> Comp . Ex. 6</td>

<td> Polypropylene rot No.</td><td> PPc3</td><td> PPc4</td><td> PPc5</td><td> PPc6</td>

<td> Quantity of components soluble in 140°C decane (wt. % )</td><td> 99</td><td> 99.2</td><td> 98.8</td><td> 98.9</td>

<td> Quantity of components insoluble in 64°C decane (wt. % )</td><td> 98.5</td><td> 98.4</td><td> 98.9</td><td> 99.1</td>

<td> (1) (η) (dl/g)</td><td> 2.7</td><td> 1.3</td><td> 1.3</td><td> 2.6</td>

<td> Mn (X 10'⁴)</td><td> 10</td><td> 3.1</td><td> 2.49</td><td> 7.36</td>

<td> Mw (X IO’⁵)</td><td> 4.49</td><td> 1.7</td><td> 1.63</td><td> 4.42</td>

<td> Mz (X 10⁶)</td><td> 1.7</td><td> 0.61</td><td> 0.66</td><td> 1.84</td>

<td> Mw/Mn</td><td> 4.5</td><td> 5.5</td><td> 6.5</td><td> 6</td>

<td> (2) Mz / Mw</td><td> 3.8</td><td> 3.6</td><td> 4.1</td><td> 4.2</td>

<td> (3) mmmm percentage (%)</td><td> 98.6</td><td> 98.6</td><td> 98.9</td><td> 98.5</td>

<td> (4) D value</td><td> 3.27</td><td> &lt;2.6</td><td> 2.68</td><td> 3.68</td>

<td> MFR (g/10 minutes)</td><td> 1.9</td><td> 52</td><td> 59</td><td> 2.7</td>

<td> Flexure modulus: FM (MPa)</td><td> 1807</td><td> 1679</td><td> 1860</td><td> 1880</td>

<td> IZ impact strength (23^ÇC) (J/M)</td><td> 46</td><td> 21</td><td> 34</td><td> 22</td>

<td> Tensile elongation (%)</td><td> 330</td><td> 370</td><td> 90</td><td> 380</td>

<td> Melt tension: MT 230°C tg)</td><td> 2</td><td> Could not be measured.</td><td> 0.1</td><td> 1.9</td>

<td> SR (γ=2600, 230°C)</td><td> 1.76</td><td> 1.61</td><td> 1.71</td><td> 1.88</td>

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Table 5 (continued)

<td></td><td> Comp. Ex. 7</td><td> Comp. Ex 8</td><td> Ref . Ex. 1</td>

<td> Polypropylene rot No.</td><td colspan="2"> PPc6/PP-ll 59/41</td><td> PP-11</td>

<td> Quantity of components soluble in 140°C decane (wt. % )</td><td> 98.6</td><td> 98.2</td><td> 98.5</td>

<td> Quantity of components insoluble in 64°C decane (wt. %)</td><td> 98.7</td><td> 99.2</td><td> 99.1</td>

<td> (1) (η) (dl/g)</td><td> 1.9</td><td> 1.9</td><td> 2.2</td>

<td> Mn (X 10⁴)</td><td> 3.42</td><td> 3.43</td><td> 2.1</td>

<td> Mw (X 3.0^-5)</td><td> 2.77</td><td> 2.78</td><td> 3.87</td>

<td> Mz (X 10^-6)</td><td> 1.43</td><td> 1.45</td><td> 4.57</td>

<td> Mw/Mn</td><td> 8.1</td><td> 8.1</td><td> 18.6</td>

<td> (2) Mz / Mw</td><td> 5.2</td><td> 5.2</td><td> 11.8</td>

<td> (3) mmmm percentage (%)</td><td> 98.5</td><td> 98.3</td><td> 98.3</td>

<td> (4) D value</td><td> 3.39</td><td> 3.38</td><td> 7.64</td>

<td> MFR (g/10 minutes)</td><td> 15.6</td><td> 15.2</td><td> 45</td>

<td> Flexure modulus : FM (MPa)</td><td> 1910</td><td> 2470</td><td> 2240</td>

<td> IZ impact strength. (23°C) (J/M)</td><td> 19</td><td> 20</td><td> 21</td>

<td> Tensile elongation (%)</td><td> 310</td><td> 240</td><td> 10</td>

<td> Melt tension: MT 230°C (g)</td><td> 0.4</td><td> 0.41</td><td> 1.35</td>

<td> SR (7=2600, 230°C)</td><td> 1.85</td><td> 1.87</td><td> 3.03</td>

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In Examples 10 to 24 and Comparative Examples 9 to described below, the following rubber components and inorganic fillers were used.

(Styrene copolymer)

S-l : Hydrogenated styrene block copolymer

MFR = 7.1g/10 minutes

Styrene block unit content : 13.2wt.% (Kraton G1657; made by Shell Co.)

S-2 : Hydrogenated styrene block copolymer

MFR = l.lg/10 minutes

Styrene block unit content : 30.4wt.% (Kraton G1652; made by Shell Co.) (Ethylene/a-olefin copolymer)

E-l : Ethylene/l-butene copolymer

Density = 0.861g/cm³, MFR = 1.0g/10 minutes Ethylene unit content = 81 mole %

Ξ-2 : Ethylene/1-octene copolymer

Density = 0.885g/cm³, MFR = 4.9g/10 minutes

1-octene unit content = 11 mole %

Ξ-3 :

Propylene/ethylene copolymer

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Density = 0.858g/cm^, MFR = 2.0g/10 minutes Ethylene unit content = 41 mole %

E-4 : Propylene/ethylene copolymer 5 [η] ” 2.1dl/g, ethylene unit content = 39.8 mole % (Inorganic filler)

A-l : Talc (Miceltone, made by Hayashi Kasei Co.), average particle size = 1.4gm

0

Examples 10 to 16

The respective polypropylenes obtained in

Preparation Examples described above, the rubber components, and the inorganic filler were dry-blended at the quantities shown in Table 6 to prepare polypropylene mixtures. These polypropylene mixtures were pelletized upon adding the same type of additive as that added in

Example 1.

Kneading was performed at 200 to 230°C using a 2 0 3 Omrruj) extruder.

An injection molder made by Toshiba Machine Co.,

Ltd. was used to injection mold the obtained compositions at a cylinder temperature of 210°C and a die temperature of 40°C. The test results are shown in

5 Table 6.

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Comparative Example 9

Example 10 was repeated except for using PPc4 obtained in Comparative Preparation Example in place of 5 the polypropylene, a polypropylene composition was prepared in the same manner as in Example 10. The results are shown in Table 6.

Comparative Example 10

Example 15 was repeated except for using PPc4 obtained in Comparative Preparation Example in place of the polypropylene, a polypropylene composition was prepared in the same manner as in Example 10. The results are shown in Table 6.

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Table 6

<td rowspan="2"> Composition</td><td colspan="2"> Ex. 10</td><td colspan="2"> Ex. 11</td><td colspan="2"> Comp. Ex. 9</td>

<td> Type</td><td> Parts by weight</td><td> Type</td><td> Parts by weight</td><td> Type</td><td> Parts by weight</td>

<td> Polypropylene</td><td> PP-6</td><td> 75</td><td> PP-6</td><td> 75</td><td> PPc4</td><td> 75</td>

<td> Styrene copolymer</td><td> S-l</td><td> 25</td><td> S-l</td><td> 5</td><td> S-l</td><td> 25</td>

<td> Ethylene/a-olefin copolymer</td><td></td><td></td><td> E-2</td><td> 20</td><td></td><td></td>

<td> Quantity of components soluble in 140°C decane (wt.%)</td><td colspan="2"> 99.8</td><td colspan="2"> 99.4</td><td colspan="2"> 98.9</td>

<td> Quantity of components insoluble in 64°C decane (wt.%)</td><td colspan="2"> 73.6</td><td colspan="2"> 74.2</td><td colspan="2"> 73.5</td>

<td> (1) (η) (dl/g)</td><td colspan="2"> 1.5</td><td colspan="2"> 1.5</td><td colspan="2"> 1.3</td>

<td> (2) Mz / Mw</td><td colspan="2"> 18.2</td><td colspan="2"> 18.1</td><td colspan="2"> 3.4</td>

<td> (3) mniran percentage (%)</td><td colspan="2"> 98.5</td><td colspan="2"> 98.5</td><td colspan="2"> 98.6</td>

<td> (4) D value</td><td colspan="2"> 9.0</td><td colspan="2"> 9.1</td><td colspan="2"> 2.4</td>

<td> MFR (g/10 minutes)</td><td colspan="2"> 31.5</td><td colspan="2"> 28.7</td><td colspan="2"> 31.1</td>

<td> Flexure modulus (MPa)</td><td colspan="2"> 1460</td><td colspan="2"> 1440</td><td colspan="2"> 1405</td>

<td> IZ impact strength (J/M)</td><td colspan="2"> 250</td><td colspan="2"> 290</td><td colspan="2"> 200</td>

<td> Surface hardness (R scale)</td><td colspan="2"> 83</td><td colspan="2"> 81</td><td colspan="2"> 85</td>

<td> Embr i 111ement temperature (°C)</td><td colspan="2"> -29</td><td colspan="2"> -31</td><td colspan="2"> -25</td>

<td> External appearance</td><td colspan="2"> AA</td><td colspan="2"> AA</td><td colspan="2"> CC</td>

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Table 6 (continued)

<td rowspan="2"> Composition</td><td colspan="2"> Ex. 12</td><td colspan="2"> Ex. 13</td><td colspan="2"> Ex. 14</td>

<td> Type</td><td> Parts by weight</td><td> Type</td><td> Parts by weight</td><td> Type</td><td> Parts by weight</td>

<td> Polypropylene</td><td> PP-6</td><td> 55</td><td> PP-6</td><td> 55</td><td> PP-10</td><td> 55</td>

<td> Styrene copolymer</td><td> S-l</td><td> 25</td><td> S-l</td><td> 5</td><td> S-l S-2</td><td> 12 13</td>

<td> Ethylene/a-olefin copolymer</td><td></td><td></td><td> E-2</td><td> 20</td><td></td><td></td>

<td> Inorganic filler</td><td> Al</td><td> 20</td><td colspan="2"> Al | 20</td><td> Al</td><td> 20</td>

<td> Quantity of components soluble in 140°C decane (wt.%)</td><td colspan="2"> 78.5</td><td colspan="2"> 79.3</td><td colspan="2"> 78.5</td>

<td> Quantity of components insoluble in 64°C decane (wt.%)</td><td colspan="2"> 66.4</td><td colspan="2"> 67.1</td><td colspan="2"> 66.3</td>

<td> (1) (η) (dl/g)</td><td colspan="2"> 1.5</td><td colspan="2"> 1.5</td><td colspan="2"> 1.3</td>

<td> (2) Mz / Mw</td><td colspan="2"> 17.9</td><td colspan="2"> 17.9</td><td colspan="2"> 18.5</td>

<td> (3) mmmm percentage (%)</td><td colspan="2"> 98.5</td><td colspan="2"> 98.5</td><td colspan="2"> 99.1</td>

<td> (4) D value</td><td colspan="2"> 9.1</td><td colspan="2"> 9.0</td><td colspan="2"> 9.4</td>

<td> MFR (g/10 minutes)</td><td colspan="2"> 26.1</td><td colspan="2"> 25.0</td><td colspan="2"> 27.9</td>

<td> Flexure modulus (MPa)</td><td colspan="2"> 2200</td><td colspan="2"> 2150</td><td colspan="2"> 2200</td>

<td> IZ impact strength (J/M)</td><td colspan="2"> 380</td><td colspan="2"> 350</td><td colspan="2"> 410</td>

<td> Surface hardness (R scale)</td><td colspan="2"> 79</td><td colspan="2"> 76</td><td colspan="2"> 81</td>

<td> Embrittlement temperature (°C)</td><td colspan="2"> -28</td><td colspan="2"> -26</td><td colspan="2"> -34</td>

<td> External appearance</td><td colspan="2"> AA</td><td colspan="2"> AA</td><td colspan="2"> AA</td>

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Table 6 (continued)

<td rowspan="2"> Composition</td><td colspan="2"> Ex. 15</td><td colspan="2"> Ex. 16</td><td colspan="2"> Comp. Ex. 10</td>

<td> Type</td><td> Parts by weight</td><td> Type</td><td> Parts by weight</td><td> Type</td><td> Parts by weight</td>

<td> Polypropylene</td><td> PP-10</td><td> 55</td><td> PP-10</td><td> 60</td><td> PPc4</td><td> 55</td>

<td> Styrene copolymer</td><td></td><td></td><td></td><td></td><td></td><td></td>

<td> Ethylene/a-olefin copolymer</td><td> E-2 E-3</td><td> 20 5</td><td> E-l E-3</td><td> 20 10</td><td> E-2 E-3</td><td> 20 5</td>

<td> Inorganic filler</td><td> Al</td><td> 20</td><td> Al</td><td> 10</td><td> Al</td><td> 20</td>

<td> Quantity of components soluble in 140°C decane (wt.%)</td><td> 79</td><td> .2</td><td colspan="2"> 86.6</td><td colspan="2"> 79.2</td>

<td> Quantity of c omponent s insoluble in 64°C decane (wt.%)</td><td colspan="2"> 66.5</td><td colspan="2"> 66.7</td><td colspan="2"> 66.4</td>

<td> (1) (η) (dl/g)</td><td colspan="2"> 1.3</td><td colspan="2"> 1.3</td><td colspan="2"> 1.3</td>

<td> (2) Mz / Mw</td><td colspan="2"> 19.9</td><td colspan="2"> 19.1</td><td colspan="2"> 3.5</td>

<td> (3) imranm percentage (%)</td><td colspan="2"> 99.1</td><td colspan="2"> 99.1</td><td colspan="2"> 98.6</td>

<td> (4) D value</td><td colspan="2"> 9.3</td><td colspan="2"> 9.4</td><td colspan="2"> 2.5</td>

<td> MFR (g/10 minutes)</td><td colspan="2"> 31.9</td><td colspan="2"> 20.4</td><td colspan="2"> 24.3</td>

<td> Flexure modulus (MPa)</td><td colspan="2"> 2120</td><td colspan="2"> 1450</td><td colspan="2"> 2060</td>

<td> IZ impact strength (J/M)</td><td colspan="2"> 330</td><td colspan="2"> Did not break &lt;&gt; 500)</td><td colspan="2"> 210</td>

<td> Surface hardness (R scale)</td><td colspan="2"> 79</td><td colspan="2"> 60</td><td colspan="2"> 77</td>

<td> Embrittlement temperature (°C)</td><td colspan="2"> -21</td><td colspan="2"> -43</td><td colspan="2"> -11</td>

<td> Externa1 appearanc e</td><td colspan="2"> AA</td><td colspan="2"> AA</td><td colspan="2"> cc</td>

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Examples 17 to 23

The respective polypropylenes obtained in

Preparation Examples described above, the rubber components, and the inorganic filler were dry-blended at 5 the quantities shown in Table 7 to prepare polypropylene mixtures. These polypropylene mixtures were pelletized in accordance with the pelletization method of Example 5 and injection molded test pieces of the obtained polypropylene compositions were prepared. The test results are shown in Table 7.

Comparative Example 11

Example 17 was repeated except for using PPc4 obtained in Comparative Preparation Example in place of 15 the polypropylene PP-9, a polypropylene composition was prepared in the same manner as in Example 17. The results are shown in Table 7.

Comparative Example 12

Example 22 was repeated except for using PPc7 obtained in Comparative Preparation Example in place of the polypropylene PP-10, a polypropylene composition was prepared in the same manner as in Example 17. The results are shown in Table 7.

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Table 7

<td rowspan="2"> Composition</td><td colspan="2"> Ex. 17</td><td colspan="2"> Ex. 18</td><td colspan="2"> Comp. Ex. 11</td>

<td> Type</td><td> Parts by weight</td><td> Type</td><td> Parts by weight</td><td> Type</td><td> Parts by weight</td>

<td> Polypropylene</td><td> PP-9</td><td> 75</td><td> PP-9</td><td> 75</td><td> PPc4</td><td> 75</td>

<td> Styrene copolymer (hydrogenated)</td><td> S-l</td><td> 25</td><td> S-l</td><td> 5</td><td> S-l</td><td> 25</td>

<td> Etylene/a-olefin copolymer</td><td></td><td></td><td> E-2</td><td> 20</td><td></td><td></td>

<td> Quantity of components soluble in 140°C decane (wt.%)</td><td colspan="2"> 99.8</td><td colspan="2"> 99.6</td><td colspan="2"> 98.7</td>

<td> Quantity of components insoluble in 64°C decane* (wt.%)</td><td colspan="2"> 74.1</td><td colspan="2"> 74.1</td><td colspan="2"> 73.6</td>

<td> (1) (η)(dl/g)</td><td colspan="2"> 1.4</td><td colspan="2"> 1.4</td><td colspan="2"> 1.3</td>

<td> Mn (X 10^-4)</td><td colspan="2"> 3.2</td><td colspan="2"> 3.1</td><td colspan="2"> 3.1</td>

<td> (2) Mz / Mw</td><td colspan="2"> 16.5</td><td colspan="2"> 17.5</td><td colspan="2"> 3 .5</td>

<td> (3) iraranm percentage (%)</td><td colspan="2"> 99.1</td><td colspan="2"> 99.1</td><td colspan="2"> 98.6</td>

<td> (4) D value</td><td colspan="2"> 9.3</td><td colspan="2"> 9.2</td><td colspan="2"> 2.4</td>

<td> Components soluble in 64°C decane Propylene content (mole %)</td><td colspan="2"></td><td colspan="2"></td><td colspan="2"> 2.8</td>

<td> Butene content (mole %)</td><td colspan="2"> 19.7</td><td colspan="2"> 4.0</td><td colspan="2"> 17.6</td>

<td> Content of comonomers of C8 or more (mole %)</td><td colspan="2"> -</td><td colspan="2"> 6.9</td><td colspan="2"> -</td>

<td> Styrene content (mole %)</td><td colspan="2"> 4.1</td><td colspan="2"> 1.2</td><td colspan="2"> 3.9</td>

<td> MFR (g/10 minutes)</td><td colspan="2"> 30.7</td><td colspan="2"> 28.5</td><td colspan="2"> 31.1</td>

<td> Flexure modulus (MPa)</td><td colspan="2"> 1480</td><td colspan="2"> 1440</td><td colspan="2"> 1405</td>

<td> IZ impact strength (J/M)</td><td colspan="2"> 260</td><td colspan="2"> 290</td><td colspan="2"> 200</td>

<td> Surface hardness (R scale)</td><td colspan="2"> 84</td><td colspan="2"> 81</td><td colspan="2"> 85</td>

<td> Embr i 111ement temperature (°C)</td><td colspan="2"> -35</td><td colspan="2"> -31</td><td colspan="2"> -28</td>

<td> External appearance</td><td colspan="2"> AA</td><td colspan="2"> AA</td><td colspan="2"> CC</td>

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Table 7 (continued)

<td rowspan="2"> Composition</td><td colspan="2"> Ex. 19</td><td colspan="2"> Ex. 20</td><td colspan="2"> Ex. 21</td>

<td> Type</td><td> Parts by. weight</td><td> Type</td><td> Parts by weight</td><td> Type</td><td> Parts by weight</td>

<td> Polypropylene</td><td> PP-9</td><td> 55</td><td> PP-9</td><td> 55</td><td> PP-10</td><td> 55</td>

<td> Styrene copolymer (hydrogenated)</td><td> S-l</td><td> 25</td><td> S-l</td><td> 5</td><td> S-l 3-2</td><td> 12 13</td>

<td> Etylene/a-olefin copolymer</td><td></td><td></td><td> E-2</td><td> 20</td><td></td><td></td>

<td> Inorganic filler</td><td> Al</td><td> 20</td><td> Al</td><td> 20</td><td> Al</td><td> 20</td>

<td> Quantity of components soluble in 140°C decane (wt.%)</td><td colspan="2"> 78.5</td><td colspan="2"> 79.6</td><td colspan="2"> 78.6</td>

<td> Quantity of components insoluble in 64°C decane* (wt.%)</td><td colspan="2"> 66.6</td><td colspan="2"> 66.4</td><td colspan="2"> 66.3</td>

<td> (1) (η)(dl/g)</td><td colspan="2"> 1.4</td><td colspan="2"> 1.4</td><td colspan="2"> 1.3</td>

<td> Mn (X IO’⁴)</td><td colspan="2"> 3.3</td><td colspan="2"> 3.2</td><td colspan="2"> 2.9</td>

<td> (2) Mz I Mw</td><td colspan="2"> 16.8</td><td colspan="2"> 17.9</td><td colspan="2"> 18.5</td>

<td> (3) mmmm percentage (%)</td><td colspan="2"> 98.5</td><td colspan="2"> 98.5</td><td colspan="2"> 99.1</td>

<td> (4) D value</td><td colspan="2"> 9.1</td><td colspan="2"> 9.1</td><td colspan="2"> 9.4</td>

<td> Components soluble in 64°C decane Propylene content (mole %)</td><td colspan="2"></td><td colspan="2"></td><td colspan="2"></td>

<td> Butene content (mole %)</td><td colspan="2"> 19.5</td><td colspan="2"> 4.1</td><td colspan="2"> 18.1</td>

<td> Content of comonomers of C8 or more (mole %)</td><td colspan="2"> -</td><td colspan="2"> 6.6</td><td colspan="2"> -</td>

<td> Styrene content (mole %)</td><td colspan="2"> 3.9</td><td colspan="2"> 1.2</td><td colspan="2"> 5.2</td>

<td> MFR (g/10 minutes)</td><td colspan="2"> 26.1</td><td colspan="2"> 25.1</td><td colspan="2"> 27.7</td>

<td> Flexure modulus (MPa)</td><td colspan="2"> 2200</td><td colspan="2"> 2150</td><td colspan="2"> 2200</td>

<td> IZ impact strength (J/M)</td><td colspan="2"> 380</td><td colspan="2"> 350</td><td colspan="2"> 410</td>

<td> Surface hardness (R scale)</td><td colspan="2"> 79</td><td colspan="2"> 76</td><td colspan="2"> 81</td>

<td> Embrittlement temperature (°C)</td><td colspan="2"> -32</td><td colspan="2"> -26</td><td colspan="2"> -34</td>

<td> External appearance</td><td colspan="2"> AA</td><td colspan="2"> AA</td><td colspan="2"> AA</td>

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Table 7 (continued)

<td rowspan="2"> Composition</td><td colspan="2"> Ex. 22</td><td colspan="2"> Ex. 23</td><td colspan="2"> Comp. Ex. 12</td>

<td> Type</td><td> Parts by weight</td><td> Type</td><td> Parts by weight</td><td> Type</td><td> Parts by weight</td>

<td> Polypropylene</td><td> PP-10</td><td> 55</td><td> PP-10</td><td> 60</td><td> PPc7</td><td> 55</td>

<td> Styrene copolymer (hydrogenated)</td><td></td><td></td><td></td><td></td><td></td><td></td>

<td> Etylene/a-olefin</td><td> E-2</td><td> 20</td><td> E-l</td><td> 20</td><td> E-2</td><td> 20</td>

<td> copolymer</td><td> E-3</td><td> 5</td><td> E-3</td><td> 10</td><td> E-3</td><td> 5</td>

<td> Inorganic filler</td><td> Al</td><td> 20</td><td> Al</td><td> 10</td><td> Al</td><td> 20</td>

<td> Quantity of components soluble in 140°C decane (wt.%)</td><td colspan="2"> 79.1</td><td colspan="2"> 89.6</td><td colspan="2"> 79.9</td>

<td> Quantity of components insoluble in 64°C decane* (wt.%)</td><td colspan="2"> 66.1</td><td colspan="2"> 65.1</td><td colspan="2"> 65.1</td>

<td> (1) (η)(dl/g)</td><td colspan="2"> 1.3</td><td colspan="2"> 1.3</td><td colspan="2"> 1.2</td>

<td> Mn |X 10^-4)</td><td colspan="2"> 3.2</td><td colspan="2"> 2.9</td><td colspan="2"> 2.7</td>

<td> (2) Mz / Mw</td><td colspan="2"> 18.9</td><td colspan="2"> 19.1</td><td colspan="2"> 3.6</td>

<td> (3) mmmm percentage</td><td> 99.1</td><td></td><td> 99.1</td><td></td><td> 98.5</td><td></td>

<td> (%)</td><td></td><td></td><td></td><td></td><td></td><td></td>

<td> (4) D value</td><td colspan="2"> 9.3</td><td colspan="2"> 9.4</td><td colspan="2"> 2.8</td>

<td> Components soluble in 64°C decane Propylene content (mole %)</td><td colspan="2"> 11.5</td><td colspan="2"> 18.6</td><td colspan="2"> 12.9</td>

<td> Butene content (mole %)</td><td colspan="2"> -</td><td colspan="2"> 7.3</td><td colspan="2"> -</td>

<td> Content of comonomers of C8 or more (mole %)</td><td colspan="2"> 8.3</td><td colspan="2"> -</td><td colspan="2"> 8.1</td>

<td> Styrene content (mole %)</td><td colspan="2"> -</td><td colspan="2"> -</td><td colspan="2"> -</td>

<td> MFR (g/10 minutes)</td><td colspan="2"> 31.6</td><td colspan="2"> 20.1</td><td colspan="2"> 30.3</td>

<td> Flexure modulus (MPa)</td><td colspan="2"> 2120</td><td colspan="2"> 1450</td><td colspan="2"> 2060</td>

<td> IZ impact strength</td><td> 330</td><td></td><td> Did not</td><td> break</td><td> 210</td><td></td>

<td> (J/M)</td><td></td><td></td><td> (&gt; 500)</td><td></td><td></td><td></td>

<td> Surface hardness (R scale)</td><td colspan="2"> 79</td><td colspan="2"> 60</td><td colspan="2"> 77</td>

<td> Embrittlement temperature (°C)</td><td colspan="2"> -21</td><td colspan="2"> -44</td><td colspan="2"> -14</td>

<td> External appearance</td><td colspan="2"> AA</td><td colspan="2"> AA</td><td colspan="2"> CC</td>

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Example 24

The polypropylene powders PP-5 and PP-6, obtained in Preparation Examples 5 and 6 examples, and the propylene/ethylene' copolymer E-4 were dry-blended at a weight ratio of (PP-5)/(PP-6)/(E-4) = 63/37/25 to prepare a polypropylene mixture.

The obtained polypropylene mixture was pelletized in accordance with the pelletization method of Example

5. The results are shown in Table 8.

Comparative Examples 13 and 14

Example 24 was repeated except for using the polypropylene mixtures shown in Table 8 in place of the mixture used there, polypropylene compositions were 15 prepared in the same manner as in Example 24. The results are shown in Table 8.

Referential Example 2

Example 24 was repeated except for using the 20 polypropylene mixture shown in Table 8 in place of the mixture used there, a polypropylene composition was prepared in the same manner as in Example 24. The results are shown in Table 8.

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Table 8

<td> Composition</td><td> Ex. 24</td><td> Comp. Ex. 13</td><td> Comp. Ex. 14</td><td> Ref. Ex. 2</td>

<td> Polypropylene</td><td> PP-5(13)</td><td> PPc3(12)</td><td> PPc3(59)</td><td> PP-7(10)</td>

<td> (parts by weight )</td><td> PP-6(62)</td><td> PPc4(63)</td><td> PPc4(16)</td><td> PP-1K65)</td>

<td> Propylene/ethylene copolymer (parts by weight)</td><td> E-4(25)</td><td> E-4 &lt;25)</td><td> E-4(25)</td><td> E-4 (25)</td>

<td> Quantity of components soluble in 140°C decane (wt. % )</td><td> 99.2</td><td> 98.8</td><td> 98.5</td><td> 98.9</td>

<td> Quantity of components insoluble in 64°C decane* (wt.%)</td><td> 73.6</td><td> 73.4</td><td> 73.2</td><td> 73.3</td>

<td> (1) (η) (dl/g)</td><td> 1.7</td><td> 1.5</td><td> 1.6</td><td> 2.2</td>

<td> Mn (x 10⁴)</td><td> 2.85</td><td> 3.48</td><td> 2.93</td><td> 2.16</td>

<td> Mw (x 10^-5)</td><td> 2.66</td><td> 2.15</td><td> 2.26</td><td> 3.91</td>

<td> Mw (x 10⁶)</td><td> 3.69</td><td> 0.97</td><td> 1.18</td><td> 4.48</td>

<td> Mw / Mn</td><td> 9.3</td><td> 6.2</td><td> 7.7</td><td> 18.1</td>

<td> (2) Mz / Mw</td><td> 13.9</td><td> 4.5</td><td> 5.2</td><td> 11.5</td>

<td> (3) mmmm percentage (%)</td><td> 98.5</td><td> 98.5</td><td> 98.5</td><td> 98.5</td>

<td> (4) D value</td><td> 7.1</td><td> 3.5</td><td> 3.7</td><td> 6.1</td>

<td> Components soluble in 64°C decane Ethylene content (mole %)</td><td> 24.8</td><td> 24.8</td><td> 24.7</td><td> 24.8</td>

<td> (η) (dl/g)</td><td> 2</td><td> 1.9</td><td> 2.1</td><td> 2</td>

<td> MFR (g/10 minutes)</td><td> 13.4</td><td> 15.6</td><td> 14.1</td><td> 18.5</td>

<td> Flexure modulus (MPa)</td><td> 1150</td><td> 920</td><td> 960</td><td> 1000</td>

<td> IZ impact strength (23°C) (J/M)</td><td> 240</td><td> 310</td><td> 240</td><td> 180</td>

<td> Tensile elongation (%)</td><td> 340</td><td> 360</td><td> 380</td><td> 400</td>

<td> Melt tension (230°C) (g)</td><td> 0.55</td><td> 0.3</td><td> 0.35</td><td> 1.3</td>

<td> SR(230°C) (7=2600)</td><td> 1.88</td><td> 1.49</td><td> 1.61</td><td> 2.28</td>

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Example 25

A polypropylene composition was obtained by pelletizing the polypropylene mixture, that was obtained in Example 24, in accordance with the pelletizing method 5 of Example 1. The results are shown in Table 9,

Comparative Examples 15 and 16

Example 25 was repeated except for using the polypropylene mixtures shown in Table 9 in place of the mixture used there, polypropylene compositions were obtained in the same manner as in Example 25. The results are shown in Table 9.

Referential Example 3

Example 25 was repeated except for using the polypropylene mixture shown in Table 9 in place of the mixture used there, a polypropylene composition was obtained in the same manner as in Example 25. The results are shown in Table 9.

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Table 9

Composition Ex. 25 Comp. Ex. 15 Comp Ex. 16 Ref. Ex. 3 Polypropylene PP-5 &lt;13) PPc3(12) PPc3 ¢59) PP-7{10) (parts by weight) PP-6(62) PPc4(63) PPc4(16) PP-11(65) Propylene/ethylene copolymer (parts by weight) E-4¢25) E-4(25) E-4(25) E-4(25) Quantity of components soluble in 140°C decane (wt.%) 98.5 98.9 98.6 98.5 Quantity of components insoluble in 64°C decane* (wt.%) 73.8 73.6 73.4 73.5 (1) (η) (dl/g) 1.7 1.5 1.6 2.2 Mn (x IO

4

) 2.88 3.45 2.92 2.12 Mw (x IQ*

5

) 2.71 2.14 2.25 3.9 Mw (x 1CT

6

) 3.71 0.98 1.19 4.45 Mw / Mn 9.4 6.2 7.7 18.4 (2) Mz / Mw 13.7 4.6 5.3 11.4 (3) mmmm percentage (%) 98.8 98.5 98.6 98.6 (4) D value 7.2 3.6 3.6 6.2 Components soluble in 64°C decane Ethylene content (mole %) 24.7 24.6 24.5 24.5 (η) (dl/g) 2.1 2 2 1.9 MFR (g/10 minutes) 13.8 15.1 14.5 18.5 Flexure modulus (MPa) 1340 1180 1240 1300 IZ impact strength (23°C) (J/M) 350 430 360 300 Tensile elongation (%) 260 370 310 280 Melt tension (230°C) (g) 0.56 0.29 0.36 1.29 SR(230°C)(7=2600) 1.89 1.49 1.6 2.27