Inert filler concentrates for use in thermoplastic products
Abstract
The invention concerns the use of high fluidity isotactic polypropylenes for preparing inert filler concentrates for use in olefin-type thermoplastic materials such as polypropylene and general: polymers used alone or in mixture, based on polymerized ethylene monomers containing 2 to 6 carbon atoms alone or in mixture. The invention also concerns inert filler concentrates or masterbatches prepared from very high fluidity isotactic propylenes. The invention further concerns filled thermoplastic material obtained by addition of selected propylenes of the invention, and industrial products made from, or containing, such thermoplastic materials. 17 claims

Term
Term ended
Expired 31 July 2022, 4.2 years ago.
- Priority
- Filed
- Granted
- Expired
- Today
17 claims: 17 independent, 0 dependent
- 168 PATENT CLAIMS ПАТЕНТНИ ПРЕТЕНЦИИ 1. Метод за получаване на изходни смеси или концентрат(и) на минерални пълнител(и), силно заредени с вещество(а) или пълтинел(и), използувани за пълнене на термопластични вещества с помоща на посочените минерални пълнители, при което се използуват полимери като свързващи средства, характеризиращ се с това, че посочените полимери или смеси от полимери:A process for the preparation of starting mixtures or mineral concentrate (s), highly charged catharsis (s) or filler (s) used to fill the thermoplastic materials by means of said mineral fillers, using polymers as binding agents, characterized in that said polymers or mixtures of polymers: - contain at least one isotactic polypropylene with very high fluidity, and - have a crystallinity percentage, commonly called an isotactic index, exceeding approximately 20%, preferably not in the range between 30% and 90%, more preferably between 50% and 85%, as measured by the DST method. - съдържат най-малкото един изотактичен полипропилен с много голям флуидитет, и - имат процент на кристалинност, наричан обикновено, индекс на изотактичност, надвишаващ приблизително 20%, за предпочитане в граници между 30% и 90%, по-предпочитано в граници между 50% и 85%, измерено по DSC метода.
- 2A process for preparing the starting materials or mineral filler concentrate (s) according to claim 1, characterized in that said polymers or mixtures of polymers present a fluidity index, also referred to as MEI, exceeding 200 g / 10 min, measured according to the modified standard NEL T 51-620 (190 ° C - 10 kD - 1.05 mm). 2. Метод за получаване на изходни смеси или концентрат(и) на минерални пълнител(и), съгласно претенция 1, характеризиращ се с това, че посочените полимери или смеси от полимери представят индекс на флуидитет, наречен също така MFI (Melting Flow Index), надвишаващ или равен на 200 д/10 минути, измерен съгласно модифицирания стандарт NF Т 51-620 (190°С - 10 kg - 1,05 mm).
- 3A method for preparing the starting materials or mineral filler concentrate (s) according to claim 2, characterized in that said polymers or mixtures of polymers present a fluid index greater than or equal to 500 g / 10 minutes as measured according to the modified standard NE T 51-620 (190 ° C - 10 kD - 1.05 mm). 69 3. Метод за получаване на изходни смеси или концентрат(и) на минерални пълнител(и), съгласно претенция 2, характеризиращ се с това, че посочените полимери или смеси от полимери представят индекс на флуидитет надвишаващ или равен на 500 д/10 минути, измерен съгласно модифицирания стандарт NF Т 51-620 (190°С - 10 kg - 1,05 mm).
- 4A process for the preparation of a mineral premix or concentrate (s) according to any one of claims 1 or 2, characterized in that the organic component of the filler concentrates, i.e. the mixture is de-polymerized, forming the binder and optionally optional additives comprise:- from 30% to 100% isotactic polypropylene with a high degree of fluidity, the MP measured according to the conforming standard NP 51-620 is greater than or equal to 20 g / 10 min (190 ° F, filler 10 kD, thread1.05 mm);- from 0 to 70% of amorphous and / or crystalline polyolefins selected from polypropylene, polyethylene and polymers or copolymers based on ethylene monomers containing 2 to 6 carbon atoms, alone or in combination;- 0 to 5% additives such as thermal stabilizing agents, antioxidants, anti-UV agents, dispersants, 4. Метод за получаване на изходни смеси или концентрат(и) на минерални пълнител(и), съгласно коя да е претенция 1 или 2, характеризиращ се с това, че органичната част на концентратите на пълнителнители, т.е., сместта от полимери, образуваща свързващото средство и, евентуално обичайните добавки, се състои от: - от 30% да 100% изотактичен полипропилен с много голям флуидитет, чийто MFI, измерен съгласно модифицирания стандарт NF Т 51-620 надвишава или е равен на 20 g/Ю минути (температура 190°С, пълнител 10 kg, нишка 1,05 mm);- от 0 до 70% аморфни и/или кристални полиолефини, избрани измежду полипропилен, полиетилен и полимерите или съполимерите на основата на етиленови мономери, съдържащи 2 до 6 въглеродни атома, самостоятелно или в смес;- от 0 до 5% добавки, като термични стабилизиращи средства, антиоксиданти, анти-UV, диспергиращи средства, омазняващи средства, оцветители, пластификатори, средства с антистатично действие, противозапалителни средства, средства за образуване на зародиши, средства за пасивиране на метали, като купропасивните средства.
- 5A process for preparing starting mixtures or concentrate (s) of mineral filler (s) according to any one of claims 1 to 4, characterized in that said polymer is an isotactic polypropylene with a high-flux. 5. Метод за получаване на изходни смеси или концентрат(и) на минерални пълнител(и), съгласно коя да е претенция от 1 до 4, характеризиращ се с това, че посоченият полимер е изотактичен полипропилен с много висок флуидитет.
- 6A process for preparing starting mixtures or concentrate (s) of mineral filler (s) according to any one of claims 1 to 4, characterized in that said polymers or mixtures of polymers are composed of at least one isotactic polypropylene with very high fl uidity and at least one other olefinic crystalline or amorphous polymer. 6. Метод за получаване на изходни смеси или концентрат(и) на минерални пълнител(и), съгласно коя да е претенция от 1 до 4, характеризиращ се с това, че посочените полимери или смеси на полимери са съставени от наймалкото един изотактичен полипропилен с много висок флуидитет и най-малкото един друг олефинен кристален или аморфен полимер.
- 7A process for the preparation of the starting mixtures or mineral concentrate (s) according to claim 6, wherein the other olefin crystalline amorphous polymer is a polyethylene. 7. Метод за получаване на изходни смеси или концентрат(и) на минерални пълнител(и), съгласно претенция 6, характеризиращ се с това, че другият олефинен кристален или аморфен полимер е един полиетилен.
- 8A process for preparing starting materials or mineral filler concentrate (s) according to claim 6, characterized in that said polymers or mixtures of polymers are composed of one high-density polyethylene isotactic polypropylene and one polyethylene. 8. Метод за получаване на изходни смеси или концентрат(и) на минерални пълнител(и), съгласно претенция 6, характеризиращ се с това, че посочените полимери или смеси на полимери са съставени от един изотактичен полипропилен с много висок флуидитет и един полиетилен.
- 9A process for the preparation of starting mixtures or concentrate (s) of mineral filler (s) according to any one of claims 1 to 3, characterized in that said polymers or polymer blends are composed of at least one isotactic polypropylene with a multi- high fl uidity and at least one other copolymer or terpolymer amorphous or affective or substantially amorphous or substantially tactile. 9. Метод за получаване на изходни смеси или концентрат(и) на минерални пълнител(и), съгласно коя да е претенция от 1 до 3, характеризиращ се с това, че посочените полимери или смеси на полимери са съставени от наймалкото един изотактичен полипропилен с много висок флуидитет и най-малкото един друг съполимер или терполимер аморфен или атактичен или по същество аморфен или по същество атактичен.
- 10Starting mixtures or concentrate (s) of a mineral compound (s) highly charged with a substance (s) or a mineral filler (s), characterized in that it has a mineral filler content exceeding 80% by weight, preferably from 83.5% to 95.0%, and more preferably from 82.5% to 93.0%, having a Fluidity Index or MP greater than 5 g / 10 min (190 ° C - 5 kD - 2.09 mm), measured 71 according to standard NP 51-620, preferably exceeding 8 g / 10 min (190 ° C - 5 kg - 2.09 mm), and comprising at least one polymer of the isotactic polyolefin type with very high fluidity, (also called indosolarity index) exceeding approximately 20%, preferably in the range between 30% and 90%, more preferably between 50% and 85%, measured by the C5 method. 10. Изходни смеси или концентрат(и) на минерални пълнител(и), силно заредени с вещество(а) или минерални пълнител(и), характеризиращ се с това, че има съдържание на минерален пълнител надвишаващо 80% тегловни, за предпочитане от 83,5% до 95,0% и по-предпочитано от 82,5% до 93,0%, че има индекс на флуидитет или MFI надвишаващ или равен на 5 д/10 минути (190°С - 5 kg - 2,09 mm), измерен съгласно стандарт NF Т 51-620, за предпочитане надвишаващ или равен на 8 д/10 минути (190°С - 5 кд - 2,09 mm), и че съдържа най-малкото един полимер от тип изотактичен полиолефин с много голям флуидитет, представящ един процент на кристалинност (наречен, също така индекс на изотактичност) надвишаващ приблизително 20%, за предпочитане в граници между 30% и 90%, по-предпочитано в граници между 50% и 85%, измерен по DSC метода.
- 11Starting compounds or mineral concentrate (s) highly charged with a substance (s) or a mineral extractor (s) according to claim 10, characterized in that the treated or untreated mineral (s) filler (s) are selected from among carbonates, such as natural calcium carbonates, among which various borates, calcites, marbles, or synthetic carbonates such as precipitated calcium carbonates at different stages of crystallization, or are also selected from mixed salts of magnesia and calcium dolomites or also magnesium zinc carbonate, lime, magnesite, barium sulfate, in particular as barium, calcium sulphate, silicon dioxide, silicomagnesium salts such as talc, vallonite, clays and other silico-aluminum salts such as kaolins, mica, oxides or hydroxides of metal or alkaline earth metal, such as magnesium hydroxide, zinc oxide, glass fiber or powder, wood fiber or dust, mineral or organic pigments or a mixture of these compounds, such as mixtures of talc and carbonates, as well as mixtures of titanium oxide and carbonates, mixtures obtained before or after the digestion of the minerals. 72 11. Изходни смеси или концентрат(и) на минерални V пълнител(и), силно заредени с вещество(а) или минерални пълнител(и), съгласно претенция 10, характеризиращ се с това, че обработеният(ите) или необработен(и) минерален(и) пълнител(и) се избират измежду карбонати, като естествени калциеви карбонати, измежду коите различни креди, калцити, мрамори или измежду синтетични карбонати, като утаените калциеви карбонати в различен стадий на кристализиране, или също така, се избират измежду смесените соли на магнезий и на калций, като доломити или също така, магнезиевия карбонат, цинковия карбонат, вар, магнезит, бариев сулфат, по-специално като барит, калциев сулфат, силициев диксид, силико-магнезиеви соли, като талк, валастонит, глини и други силико-алуминиеви соли, като каолини, слюда, оксиди или хидрооксиди на метални или алкалоземни, като магнезиев хидрооксид, железни оксиди, цинков оксид, стъклено влакно или прах, дървесно влакно или прах, минерални или органични пигменти или смес от тези съединения, като смесите на талк и на карбонати, както и смесите на титанов оксид и карбонати, смеси получени преди или след смилането на минералите.
- 12Exit mixtures or concentrate (s) of a mineral compound (s) highly charged with a substance (s) or a mineral filler (s) according to claim 11, characterized in that the treated mineral filler (s) ) are selected from natural calcium carbonates, among which various borates, calcites, marbles, or intermittent carbonates, such as precipitated calcium carbonates or also from talc, magnesium hydroxide, barite, titanium dioxide, vallonite or dolomite and mixtures thereof. 12. Изходни смеси или концентрат(и) на минерални пълнител(и), силно заредени с вещество(а) или минерални пълнител(и), съгласно претенция 11, характеризиращ се с това, че обработеният(ите) или не минерален(и) пълнител(и) се избират измежду естествени калциеви карбонати, измежду които различни креди, калцити, мрамори или измежду синтетични карбонати, като утаените калциеви карбонати, или също така измежду талк, магнезиев хидрооксид, барит, титанов диоксид, валастонит или доломити и тяхни смеси.
- 13A process for the production of thermoplastic binder products by means of mineral fillers, characterized in that a mixture is obtained several times from said or indicated thermoplastic products with starting mixtures according to any one of claims 10 to 12, characterized in that said or said thermoplastic products are selected from among low density polyethylene, linear or branched chains or high density polyethylene, homopolymers or copolymers of polypropylenes, polyisobutylene and the resulting copolymers during the polymerization of at least two co-monomers, ethylene, propylene, isobutylene, polyolefin, modified by grafting, such as grafted polyolefins with maleic anhydride or by copolymerization such as halogenated polyolefins, modified polypropylenes (ethylene, propylene, 13. Метод за получаване на термопластични продукти с пълнители, с помоща на минерални пълнител(и), характеризиращи се с това, че се получава смес, наведнъж или на няколко пъти, от посочения или посочените термопластични продукти с изходни смеси, съгласно коя да е претенция от 10 до 12, характеризиращ се с това, че посоченият или посочените термопластични продукти се избират измежду полиетилени с ниска плътност, линейни или с разклонени вериги, или полиетилени с висока плътност, хомо- или съполимери на полипропилени, полиизобутилени и получените съполимери по време на полимеризирането на най-малко два съ-мономери, етиленови, пропиленови, изобутиленови, полиолефиниови, модифицирани чрез присаждане, като присадените полиолефини с малеинов анхидрид или чрез съполимеризиране, като халогенираните полиолефини, модифицираните полипропилени EPDM (етилен, пропилен, диен, мономери), модифицираните полипропилени SEBS (стирен, етилен, бутилен, стирен) или също така най-малкото два от горе-посочените полимери и съполимери, в смеси, или също каучуци или естествени или синтетични и термопластични еластомери, по-специално измежду тях каучаците SBR (каучук стирен-бутадиен) или термопластични EPDM или SEBS.
- 14Use of starting mixtures according to any one of claims 10 to 12, optionally in the form of aggregate granulates, for the production of thermoforming or injection-molded industrial articles. 14. Използуване на изходни смеси, съгласно коя да е претенция от 10 до 12, евентуално под формата на агрегати или гранулати, за получаване на индустриални артикули, изляти чрез термоформолеене или инжектиране.
- 15Use of starting mixtures according to any one of claims 10 to 12, optionally in the form of aggregate granules, for extrusion, in particular of a film, a nozzle or of a tube or of a profile, or of wires or sockets, for extrusion by blowing, extruding sheets or sheets or also extruding a coating on a paper or metal sheet. 15. Използуване на изходни смеси, съгласно коя да е претенция от 10 до 12, евентуално под формата на агрегати или гранулати, за екструдиране и по-специално на филм, на обвивка или на тръба или на профил или на жици или на кабели, за екструдиране чрез вдухване, екструдиране на ленти или на листове или също екструдиране на покривен слой върху хартия или метален лист.
Independent claims17
5 paragraphs in 4 sections, as filed
FIELD OF THE INVENTION The invention relates to the use of high-density polyethylene glycols to produce concentrated excipients which are used in thermoplastic products of the olefin type, such as polypropylene, polyethylene and in general: polymers which are used alone or in a mixture based on ethylene monomers containing 2 to 6 carbon atoms, polymerized alone or in a mixture. These high-density isotactic polypropyles are used in the invention as vectors favoring dispersion or re-dispersion of the mineral products used as inert fillers in the polyolefins. The invention also relates to concentrates of fillers or feedstocks, based polyester isotactic polypropylenes with very high fluidity. The invention furthermore relates to the thermoplastic loaded products obtained by the addition of selected polypropylenes according to the invention and the manufactured industrial products based on or containing such thermoplastic products. The invention also relates to thermoplastic filler products obtained by adding selected polypropylenes according to the invention and to the manufactured products of or containing such thermoplastic products. It is known to use liquid copolymers to prepare starting mixtures with fillers with high concentration of filler (s), i.e., to levels of approximately 90% calcium carbonate and / or talc. These copolymers are typically copolymers of ethylene, propylene and sometimes butylene. They are known in the trade network under the name VESTERIATS ™ on the company Soleidas-Neis, or REXTAS ™ by Nymplastam. Some also use stylized polypropylenes, by-products derived from the production of isotactic polypropylenes, in particular polypropylene Alphamins 8TN-1 of the company Alkarpat. Also known is the product disclosed in WO95 / 17441, which consists of amorphous polypropylene. 3 The cured polymers of the state of the art are specialized products, that is to say, made in small quantities by specific methods and therefore unprofitable, and which, among other things, lack of hardness and adhesion properties (desirable in the Kopectile liquid adhesives industry) are unfavorable for the above-mentioned application. In addition, they spoil the ultimate mechanical properties of the extruded or extruded objects, derived from feedstocks containing them. Finally, they have softening points (approximately 130-150 ° C) away from the temperature at which they are used (polypropylene 230 ° C, polyethylene 190 ° C). These temperature differences lead to undesirable effects, such as, for example, the deposition of foams, well known to those skilled in the art of extruding profiles or films. The technical problem posed is twofold: polymers should be selected which could lead to very high charge concentrations in feedstocks re-dispersible in the various polymer matrices used in the manufacture of plastics and which do not degrade the mechanical properties of the end- after re-dilution, even increase. Given that the state of the art of the prior art provides starting mixtures, made with copolymeric ethylene, propylene, and sometimes butylactic or astactic, of the amorphous polypropylenes, the invention provides the use of isotactic polypropylenes, i. e. crystalline, with very high fluidity, for the preparation of excipient concentrates which can be used in thermoplastics of the olefin type. It is now known to use polymers having a crystallinity greater than 50%, of polypropylene or other, for a single blend of feedstocks which can reach 80%, but these products are very limited in fluidity with an index Fluidity also called MP (Mellellen), less than approximately 200 g / 10 min (190 ° C - 10 kD - 1.05 mm), according to the modified NPT T 51-620 standard. According to the NP 51-1620 standard, the index of the fluids, also referred to as MP in the remainder of the application, is the amount of polymer and / or copolymer expressed in grams for 10 minutes which expire at a temperature selected within the range of the softening and transformation temperatures of a given normalized filler (2.16 kg, 5 kg , 10 kD, 21.6 kD) in a thread with a defined diameter (2.09 mm at 2.10 mm) over a measured time interval. In the present invention, the modified standard NPT 51-620 is used for polypropylene, a fiber having a diameter of 1.05 mm and a temperature of 190 ° C. Existing devices are adapted to this type of products. Also known is the product described in EP 0203 017 which provides a significant improvement. The improvement comes from a very distinctly higher fluidity that is higher than MPI with 200 g / 10 min (190 ° C -510 kD - 1.05 mm) the concentration of excipients being estimated to be approximately 80-90% in starting mixtures and a percentage of crystallinity significantly decreased by approximately 10%, i.e., one amorphous product. Also known is the product described in Patent No. WO95 / 17441, already mentioned above, which presents the disadvantage of reaching plastic products which are lacking in strength due to problems caused by the resin used which is sticky and difficult to feed . The present state of the art (EP 0 203 017, WO 95/17441) suggests to those skilled in the art that in order to substantially improve fluidity, which is obligatory for the conventional products, while retaining the characteristic, also basic, of a high concentration of filler i) in the starting mixtures, suitably to reduce the crystallinity. It is also proposed (Patent 1) 5,4455, 344) to prepare granulates comprising: a) from 60 to 80 parts by weight of a mineral filler of an average size comprised between 0.05 and 100 ppm; b) from 5 to 35 parts by weight of a crystalline olefin; 150 and 1000 μm, and 5 to 35 parts by weight of a binder having a melting point lower than at least 10 ° C of the detectable olefin. In order to reach such granulates, the prior art method consists in the preparation of the crystalline polyolefin and / or the mineral components with the aid of the binder, which forms one coating providing the adhesion of the particles therebetween. One such method does not result in the production of a composite paste mixture, i.e., of the same composition as the whole of the mixture at the production temperature, but the preparation of non-coherent agglomerates, with the most common composition next to each other, and with uneven sizes, leading later to a poor dispersion. This is probably the reason why the state of the art sells amorphous products on the market. Such entirely amorphous products are more easily obtained by resorting to co-or terpolymers, which then, as some of the preceding products have, in fact, poor crystallinity, problems of consciousness with the olefins. These resins are more melt-flowable and their granules or agglomerates stick to cold presentation and therefore make their processing and dosing significantly difficult. As will be seen from the description that follows, the invention, contrary to this, succeeds in selecting polymers of the type of isotactic polypropylenes with a high fl uidity and exceeding or equal to MEI of 200 g / 10 min, as measured against the modified standard NF T 51-620 (190 ° C - 10 kD - 1.05 mm), preferably above 500 g / 10 min, measured against the modified standard TL 51-620 (190 ° C - 10 kD - 1.05 by a percentage of crystallinity exceeding about 20%, preferably in the range of 30% to 90%, preferably between 50% and 85%, and resulting in starting mixtures with 7 characteristics that are both remarkable and surprising, i. e. , - has a filler content of 80% or greater, - has a high fluidity, i.e., an MPI exceeding 5 g / 10 min (190 ° C - 5 kD - 2.09 mm) in accordance with the NPS standard T 51-620, preferably exceeding 8 g / 10 min (190 ° C - 5 kD - 2.09 mm), and - contains at least one polymer of the isotactic polypropylene type, representing a percentage of crystallinity , also an isotactic index) more than about 20%, preferably between 30% and 90%, most preferably between 50% and 85%, which is in fact the opposite of the state of the art. This isotactic index is a temperature exceeding 140 ° C, a blowing power of the foil between 40U / d and 138U / g, as described by Kepkakel et al. in the present application, the crystallinity or isotacticity index is defined in the present application by the introduction of a calorimetric differential method called the OZC (O) Auspüd Süüpfeu) with the aid of a device 20 on the Meier-Tolleu, which allows to measure the energy of melting of the polymeric filler and to determine the index by comparing with the value of 138 μg / g, which corresponds to an index of 100%. This method of determining crystallinity or isotactic index will be called DSD in all of the following. Moreover, these feedstocks allow to harden the hardness of the grains, so far difficult to achieve. Other features and advantages of the invention will be better understood from the following description. It is appropriate to specify that throughout the present specification, & quot; isotactic polypropylene & quot; refers to isotactic polypropylenes containing a very low percentage, unavoidable and known to those skilled in the art, a polypolymer or a portion of a contacting polymer. These isotactic polypropylenes with very high fl uidity are, moreover, (EP 0 523 717 or EP 0 600 464). It will be appreciated by those skilled in the art that such polymers subject to degradation in which one participates in a radical reaction must be regarded as equivalenttechniques. They are characterized by their fluidity or MI as measured according to the modified NPT T 51-620 standard that exceeds or is equal to 200 g / 10 min (190 ° C - 10 kD - 1.05 mm) and their percentage of crystallization exceeding approximately 30% measured by the M5Smod. One of the features of the invention is therefore also to use these isotactic polypropylenes obtained by direct polymerization. This represents an important advantage, even decisive, 9 since this technique allows to avoid the products of numbelling or by-products of polymerization which often are the cause of the degradation of the ultimate mechanical properties and the fluctuations of the hardly achievable industry qualities. Another decisive advantage is to allow the specialist in the field to design, with a very high degree of freedom, precisely the product that is needed for the exact application under consideration and / or to take into account the pre-production equipment. The capacity is provided, as will become apparent below, the possibility of retaining the advantages of the invention while at the same time specifying the degree of crystallinity and stiffness. The present invention therefore relates to a method of obtaining feedstocks or mineral concentrate concentrates which are highly mineral-filled, which are used to fill thermoplastic products with the aid of said mineral fillers, by making polymers or mixtures of polymers such as binders characterized by characterized in that said polymers or polymer blends: - contain at least one isotactic polypropylene, and - have a crystallinity percentage, generally referred to as isotactic ratio, exceeding approximately 20%, preferably in the range of 30% to 90%, more preferably between 50% and 85%, as measured by the DSD method as described above . 10 In addition, we will specify for a good understanding of the terms used, the corresponding definitions for isotacticity, for the contact and for the syndiotactic polymers. Thus, the isotacticity characterizes, in the case of the unleaded polymer, the presence of substituents only the counterion side of the carbon backbone of the molecule, while, on the contrary, an aseptic polymer has distributed substitutions on both sides in a random fashion. A syndiotactic polymer represents, from the site, repetitive sequences of substituents on each side. These concepts are well within the skill of the art but can nevertheless, to make a comparison with the Chrysanthemums of the present invention, Figure 25.1, Figure 25.1, and Figure 15.1. Reference may also be made to the general considerations in this area, namely with respect to Tg (glass transition temperature) and Tm (melting point) with the article of Lactoglucose without Nail Roller et al. CaCl3. Tetrahedron, April, 1990, and Testimonopolis, Molecular Biophysics, Aryophora, A3 320. According to a preferred embodiment, the invention is characterized in that the percent crystallinity of the polymer or of said polymer mixtures is in the range between 50 and 85%, as measured according to the OZ methadone, as described above. According to a preferred embodiment, said polar binding agent or mixture of polymers, which presents an MPI of greater than or equal to 11 g / 100 g / 10 min, measured according to the modified NPT 51-620 standard (190 ° C -10 kD-1.05 mm), presents a fluid index greater than 500 g / 10 min measured according to the modified standard NP 51-620 (190 ° C-10 kD-1.05 mm). According to another particular embodiment, the invention is characterized in that said polymer is an isotactic polypropylene. According to another particular embodiment, the invention is characterized in that a mixture of at least one isotactic polypropylene and at least one other crystalline or amorphous olefin copolymer is used. According to another particular embodiment, the invention is characterized in that a mixture of at least one isotactic polypropylene and at least one polyethylene is used. According to another particular embodiment, the invention is characterized in that a mixed isotactic polypropylene and a crystalline-olefin polymer such as polyethylene are used. According to another particular embodiment, the invention is characterized in that at least one isotactic polypropylene and at least one polymer or an amorphous olefin terpolymer or an amorphous product are used. It is to be recalled that "copolymer" also means polymers of two, three, four or more polymers, the terpolymers of which are only one particular case. By the term "amorphous in nature" are meant polymers or copolymers whose crystallinity is very low in the order of 10 or below 5%. According to another particular embodiment, the invention is characterized in that, wherein at least one isotactic polypropylene and at least one contacting olefin polymer or copolymer is applied. According to another particular embodiment, the invention is characterized in that at least one isotactic polypropylene and at least one olefinic tackifying polymer or copolymer is applied. According to one particular, non-limiting embodiment, the organic part of the filler concentrate, i.e. the blend of polymers which forms the binder and optionally the conventional additives, is composed of: - from 30% to 100% isotactic polypropylene with a high degree of fluidity, , measured according to the modified standard NP 51-620, is greater than or equal to 200 g / 10 min (temperature 190 ° C, filler 10 kD, 1.05 mm strand); - from 0 to 70% of standard amorphous and / or crystalline polyolefins, such as polypropylene, polyethylene and, in general, polymers and copolymers based on ethylene monomers containing from 2 to 6 carbon atoms, alone or in admixture; from 0 to 5% of additives such as thermostabilizing agents, antioxidants, anti-UV agents, dispersants, lubricants, colorants, plasticizers, antistatic agents, anti-inflammatory agents, well known to those skilled in the art for germination, passivation of metals, such as, for example, cuprous agents. According to a preferred embodiment of the invention, isotactic polypropylenes obtained by direct polymerization are used. The invention also relates to starting mixtures obtained by the said method. The starting mixtures, according to the invention are characterized in that they have a mineral content in excess of 80% by weight, preferably of from 89.5% to 95.0%, and more preferably from 82.0% to 93.0%, have a fluidity or MP exceeding or (190 ° C -5kg-2.09 mm), measured according to the NPT T 51-620 standard, preferably exceeding 8 g / 10 min (190 ° C -5kg-2.09 mm) , and that at least one polymer of the isotactic polypropylene type is present which represents a percentage of crystallinity (called an isotactic index) of more than about 20% Also, according to another embodiment, the invention is characterized in that, the minerals or mineral fillers are selected from intercalates such as natural calcium carbonate, in particular the different types of boron, calcites, marbles, or also 14 of the synthetic carbonates, such as the previous calcium carbonates at different stages of crystallization or the like, are selected from mixed magnesium salts and nakaltsiy such as dolomites, or also from magnezieviyakarbonat, zinc carbonate, lime, magnesium salts, barievsulfat, in particular, barite, calcium sulphate, silitsievdioksid, silicone magnesium salts such as talc, voastonite, clays and other silico-aluminum salts such as kaolins, mica, oxides or hydroxides of metals or alkaline earths such as magnesium hydroxide, iron oxides, zinc oxide, glass fiber or glass powder, wood fiber or wood dust, mineral or organic pigments or mixtures thereof, in particular mixtures of talc and carbonates or also mixtures of titanium oxide and carbonates, mixtures obtained before or after grinding of the minerals. These fillers may optionally be tretiranipredi their processed with one or more agents, in particular cetyl acid, stearic acid, behenic acid, the mixtures of said acids styahnite calcium salts, or zinc, phosphate, phosphonates, organic sulfates and sulfonates. In even more specific manner, the fillers are izbiratizmezhdu carbonates, previously treated or not, katoestestveniya calcium carbonate, among which razlichnitekredi, calcites, marbles or from sintetichnitekarbonati, such as precipitated calcium carbonate, or also from among talc, magnesium hydroxide, barite, titanievdioksid , vulcanite or dolomite or mixtures thereof. Examples of the type of filler are described in detail in, for example, EP 0 203 017, or also examples of mold and particle size are specified in, for example, patent application WO 95/17441 and are, in any case, very well substituted by those skilled in the art. The invention also relates to a method of obtaining a filler concentrate according to the invention, characterized in that a mixture is obtained, once or several times, of the mass of the filler (s) and the polymer or mixture of polymers according to the invention, and in that the concentrate may contain more than 80% by weight of filler (s), in particular from 80% to 95% and most preferably from 82% to 93%. The invention also relates to a method of obtaining thermoplastic articles with a filler, aided by a mineral filler (s) characterized in that a mixture of said thermoplastic products is obtained with starting mixtures, also referred to as concentrate fillers prepared according to the invention. These thermoplastic products obtained by means naizhodni mixtures according izobratanieto are selected izmezhdupolietileni low density, linear or branched, ilipolietileni high density polypropylene homo-copolymers, polyisobutylenes and copolymers obtained Throughout of polymerization of at least two comonomers, ethylene , propylene, isobutylene, modified polyolefins by grafting, such as maleic anhydride grafted polyolefins or by copolymerization such as, for example, the halogenated 16 polyolefins, the modified poly propylenes, EDDM (ethylene, propylene, diene, monomer), modified polypropylenes 5EB5 (styrene, ethylene, butylene, styrene) at least two of the above-cited polymers ilisapolimeri, in admixture or also rubbers iliestestvenite or synthetic, and thermoplastic elastomers, among which in particular 5VR rubbers (rubber styrene-butadiene) or ΕΡϋΜ or 5EV5 thermoplastics. In accordance with this method, binary additives well known to the skilled artisan adapted to the final application may be incorporated. The invention ultimately refers to the use of these starting mixtures, optionally in the form of aggregates of granules, for the preparation of industrial products, in particular of poured industrial products, as well as the obtained cast products. The ways of transforming these feed blends can also be extrusion and, in particular, the stripping of a film, a microporous film, one or a single tube or profile or extrusion by extrusion, extrusion of strips or strands, or also extrusion of a coating layer on a paper or metal sheet, or may also be by thermoforming, injection, smoothing, coiling and cable making and other known methods of the expert. The scope and interest of the invention will be better understood and illustrated by the non-limiting examples which follow. EXAMPLES OF EMBODIMENT EXAMPLE 1 These examples relate to the realization of polymer populations according to the invention which allow the preparation of starting mixtures having a filler content equal to or greater than 80%, which have high fluidity, i. E. with MP greater than or equal to 5 g / 10 min (190 ° C - 5 g / 2.09 mm), measured according to NPT T 51-620 standard, and which contain at least a polypropylene isotype polypropylene type which represents a percentage of crystallinity (also called an index of indolence) of more than about 20%, preferably in the range of 30% to 90%, more preferably in the range between 50% and 85% , as measured by the 05C method as described above. For this purpose, for each of the experiments from 1 to 15, 600 excipient concentrates are prepared in a mixer with a Z-type stirrer of the type C1TTAPO ™, by stirring the selected resin with the filler and the various other additives added at the same time, the rate of stirring is 761 / min and the temperature is 180 ° C. As the starting mixtures were prepared for 45 minutes (except for Experiment n ° 1), the flufluidate was measured, i. E. measurement of the Fluidity Index (MP) in the various tests according to the NPT Standard T 51-620, to be taken into consideration by the use of a ZWLOR ™ 4105 plaster at a temperature of 190 ° C with a mass of 5 kD and a thread of 2.09 mm in diameter. 18 EXPERIMENT 1 This example illustrates the prior art of the art and produces an isotactic copolymer having a fluid composition in a composition comprising: - 80.5% by weight of chalk from the Citalopine area treated with stearic acid having a mean diameter of 2 micrometers; - 19.5% by weight non-isotactic isotactic polypropylene, cpm equal to 9.3 g / 10 min (190 ° C, 10 kD, 1.05 mm) and commercially known under the trade name 3120 MN 1 of Aparl. After 75 minutes of stirring, a non-homogeneous composition of aggregates and a powder is formed. Measurement of fluency is impossible. EXPERIMENT 2 This example illustrates the prior art of the art and produces an amorphous polymer in a single composition, comprising: - 88.0% by weight of chalk from the Citalopram area having an average diameter of 2 micrometers; - 11.2% by weight of an olefin copolymer having a molecular weight exceeding 1150 g / 10 minutes (190 ° C, 10 kg, 1.05 mm) and commercially known under the trade name "Vazolam ™ 408". - 0.8% by weight of a type of phosphorous fatty alcohol dispersant commercially known as Coallex DOPP-18 of Coallex. 19 The resulting MPI has a value of 21.0 g / 10 minutes, measured under the above conditions. EXAMPLES This example illustrates the prior art of the art and produces an amorphous polymer in a single composition comprising: - 87.5% by weight of chalk from the Craftpepe area treated with stearic acid having a mean diameter of 2 micrometers; - 12.5% by weight of the polypropylene, produced by the stripping of one isotactic polypropylene, with a magnitude of 1150 g / 10 min (190 ° C, 10 kD, 1.05 mm) and commercially known under the designation Alphabetic ™ 3HT-b of Alpurine. The resulting MP has a value in the range of 120 g / 10 minutes and 400 g / 10 minutes measured under the aforementioned conditions and in function with batches of antispot polypropylene. EXPERIMENT 4 This example illustrates the prior art of the art and produces an amorphous polymer in a single composition comprising: - 87.5% by weight of chalk from the Citalopide area treated with stearic acid having an average diameter of 2 micrometers; -12.5% by weight of amorphous polypropylene, with an MPS equal to 450 g / 10 min (190 ° C, 10 kD, 1.05 mm), known in the trade as KExLex ™ 12-125 on the Niplast ™; The resulting MP has a value of 10.0 g / 10 minutes, measured under the above conditions. EXPERIMENT 5 This example illustrates the invention to provide a composition comprising: - 87.5% by weight of chalk from the CK-tetrapepe, treated with stearic acid having a mean diameter of 2 micrometers; - 12.45% by weight of isotactic polymer having a MOP equal to 970 g / 10 minutes (190 ° C, 10 kg cartridge, 1.05 mm fiber) obtained from the peroxide degradation at 300 ° C over 15 minutes of a mixture of 24 , 8% by weight of X / ATHTCHN442H ™, by Montreal and 75.2% by weight of single-sided polypropylene with an MPS equal to 757 g / 10 min (190 ° C, 10 kg, 1.05 mm); - 0.05% by weight of the thermal stabilizer, known in the trade network, under the designation 1gadoch ™ 1010, the Chuy-Ceudu Company. The resulting MP has a value of 23.0 g / 10 minutes, the above-mentioned conditions. EXPERIMENT 6 This example illustrates the invention and provides a composition comprising: 21 - 87.5% by weight of chalk from the Cedarpe area treated with stearic acid having an average diameter of 2 micrometers; - 12.45% by weight of isotactic polymer, with a MDI equal to 1150 g / 10 minutes (190 ° C, 10 kg cartridge, 1.05 mm fiber) obtained from the peroxide degradation at 300 ° C for 15 minutes on a mixture of 50 % weight of X / ANESHN442H ™, manufactured by Mons (e11 and 50% mass of single-sided polypropylene with an MPS equal to 757 g / 10 min C (190 ° C, 10 kg, 1.05 mm) 05% by weight of a thermal stabilizer known as the grid under the name 1gadoch ™ 1010, the Sue-Seudu Company, with a value of 30.0 g / 10 minutes, the above-mentioned conditions. treated with stearic acid having an average diameter of 2 micrometers; - 12.45% by weight isotactic polymer, with a MDI of 355 g / 10 min (190 ° C, 10 kg, 1.05 mm); - 0.05% by weight of the thermal stabilizer, known in the trade network, under the designation 1gadoch ™ 1010, the Chuy-Ceudu Company. 22 The resulting MP has a value of 11.5 g / 10 minutes, the above-mentioned conditions. EXPERIMENT 8 This example illustrates the invention to provide a composition comprising: - 87.5% by weight of a chalk from the Craftpepe area treated with stearic acid having an average diameter of 2 micrometers; - 12.45% by weight isotactic polymer, with an MOP equal to 632 g / 10 min (190 ° C, 10 kg, 1.05 mm); - 0.05% by weight of a thermal stabilizer, known in the trade network under the designation 1gadoch ™ 1010, the Cuu-Oleu company. The resulting MI has a value of 16.4 g / 10 minutes, the above-mentioned conditions. EXPERIMENT 9 This example illustrates the invention to provide a composition comprising: - 87.5% by weight of chalk from the Craftpepe area treated with stearic acid having a mean diameter of 2 micrometers; - 12.45% by weight of isotactic polymer, with an MP of 757 g / 10 min (190 ° C, 10 kg, 1.05 mm); 23 - 0.05% by weight of thermal stabilizer, known in the trade network under the designation 1gadoch ™ 1010, the Chuy-Seudu company. The resulting MP has a value of 18.0 g / 10 minutes, the above mentioned conditions. EXPERIMENT 10 This example illustrates the invention to provide a composition comprising: - 87.5% by weight of chalk from the Cidrate area treated with stearic acid having a mean diameter of 2 micrometers; - 11.55% by weight isotactic polymer, with a MP fiber of 1.05 mm); - 0, 90% by weight of a type of phosphatide fatty alcohol dispersant, of the company Coallex, known under the trade name COATEX DOPP-18; - 0.05% by weight of the thermal stabilizer, known in the trade network, under the designation 1gadoch ™ 1010, the Chuy-Ceudu Company. The resulting MP has a value of 32.0 g / 10 minutes, the above-mentioned conditions. EXPERIMENT 11 This example illustrates the invention and provides a composition comprising: - 87.5% by weight of chalk from the Citalopide area treated with stearic acid having a mean diameter of 2 micrometers; 24 - 11.55% by weight of isotactic polymer, with an MP of 757 g / 10 min (190 ° C, 10 kg, 1.05 mm); - 0.45% by weight of a type of phosphatide fatty alcohol dispersant, by Coallex, known under the trade name COATEX DOPP-18; - 0.45% by weight of zinc stearate; - 0, 05% by weight of a thermal stabilizer, known in the trade network under the designation 1gadoch ™ 1010, the Chuy-Seudu Company. The resulting MP has a value of 19.0 g / 10 minutes, the above mentioned conditions. EXPERIMENT 12 This example illustrates the invention to provide a composition comprising: - 87.5% by weight of chalk from the Citalopram area treated with stearic acid having a mean diameter of 2 micrometers; - 10.0% by weight of isotactic polymer, with an MOP equal to 840 g / 10 min (190 ° C, 10 kg, 1.05 mm); - 2.45% by weight of low density polyethylene, known by Rupert Eigora, under the name Klinkel ™ MV 10; - 0.05% by weight of the thermal stabilizer, known in the trade network under the designation 1gadoch ™ 1010; 25 The resulting MP has a value of 26.2 g / 10 minutes, the above-mentioned conditions. EXPERIMENT 13 This example illustrates the invention and provides a composition comprising: - 87.5% by weight of chalk from the Citalopram area treated with stearic acid having a mean diameter of 2 micrometers; - 12.45% by weight of isotactic polymer, having a molecular weight of 295 g / 10 minutes (temperature 190 ° C, 10 kg cartridge, 1.25 mm fiber), commercially available under the name Augees 800 of the American Company; - 0.05% by weight of the thermal stabilizer, known in the trade network, under the designation 1gadoch ™ 1010, the Chuy-Ceudu Company. The resulting MP has a value of 8.4 g / 10 minutes, the above-mentioned conditions. EXPERIMENT 14 This example illustrates the invention to provide a composition comprising: - 87.5% by weight of chalk from the Craftpepe area treated with stearic acid having a mean diameter of 2 micrometers; - 12.45% by weight isotactic polymer, with an MP equal to 1038 g / 10 min (190 ° C, 10 kg cartridge, 1.05 mm); 26 - 0.05% by weight of a thermal stabilizer, known in the trade network under the designation 1gadoch ™ 1010, the Chuy-Ceudu Company. The resulting MP has a value of 25.2 g / 10 minutes, the above mentioned conditions. EXPERIMENT 15 This example illustrates the invention and provides a composition comprising: - 87.5% by weight of chalk from the Craftpepe area treated with stearic acid having an average diameter of 2 micrometers; - 12.45% by weight isotactic polymer, with an MF of 200 g / 10 minutes (190 ° C, 10 kg, 1.05 mm); - 0.05% by weight of a thermal stabilizer, known in the trade network under the designation 1gadoch ™ 1010, the Cuu-Oleu company. The resulting MP has a value of 5.0 g / 10 minutes, the above mentioned conditions. After all these experiments and measurements of fluidity have been carried out, measurement of the indices is performed according to the above-described DSC method. The individual results obtained are summarized in the following Table 1. Summary of the invention Invention state Prev. state Prev. state Prev. N / A N / A Trial 87.5 87.5 87.5 87.5 87.5 87.5 87.5 87.5 87.5 87.5 87, 5 87,5 87,5 00 00 80,5% by weight of the excipient in starting mixtures 12,45 12,45 12,45 11,55 11,55 12,45 12,45 12,45 12,45 12,45 (19 ° / o) isotactic polypropylene (190 ° C / 10 kg / 1.05 mm) is used for the preparation of the isotactic polypropylene (20 ° C) 5.0 [25.2 00 26, 2 19.0 32.0 00 o 16.4 11.5 30.0 23.0 o 120-400 21.0 Impossible measurement MP (d / 10min) EXTERNAL mixtures (190 ° C / 5kg / 2.09 mm ) 74.2 77.4 68.5 61.6 65.0 65.0 65.0 43.5 68.2 74.6 at 11.4 ° C 53.2 Percent of crystalline indices index of the liquid isotactic polymer TABLE 1 (C o-4) The reading of Table 1 shows that the selection of isotactic polypropylene with a high fluidity and exceeding 200 g / 10 min measured according to the modified standard NP 51-620 (190 ° C - 10 kD / 1.05 mm), preferably over 500 g / 10 min, measured according to the modified NPT T 51-620 standard (190 ° C - 10 g / 1.0 5 mm) with a crystallinity percentage of approximately 20%, preferably between 30% and 90%, more preferably between 50% and 85%, allows the preparation of starting mixtures, which have high fluidity, i.e., MPs greater than or equal to 80%, which have a high fluidity, i. e., MP exceeding 5 g / 10 min (190 ° C - 5 g / 2.09 mm), measured according to standard N ° 51-620, and which contain at least one polymer of the type isotactic polypropylene, representing a percentage of crystallinity (also called a nozzle index) of more than 20%, preferably in the range of 30 % and 90%, more preferably vgranitsi between 50% and 85%, measured by AAL method as eopisan above. EXAMPLE 2 This example relates to the preparation of various mineral fillers for the preparation of starting blends having a filler content exceeding 80%, having a high fluidity, i.e., a MP greater than or equal to 5 g / 10 min ° C - 5 g / 2, 09 mm) measured according to NPT T 29 51-620 standard and which contains at least one polypropylene polypropylene polymer representing a crystallinity percentage (also called an isotactic index) greater than about 20%, preferably in the range of 30% to 90% %, more preferably in the range between 50% and 85%, as measured by the DSD method as described above. For this purpose, for each of the experiments of No. 16 to 24, 600 excipients of a filler are prepared in a mixer with a stirrer in the form of Z of the type CLUTGCO ™, by stirring the selected resin with the filler and the various other additives added at the same time, stirring is 761 / min and the temperature is 180 ° C. Since the starting mixtures are obtained in 45 minutes, the fluids are measured, i. E. measurement of the Fluidity Index (MI) of the various tests according to NPT T 51-620 standard, as it should be known using a Zwork® 4105 plasticizer at a temperature of 190 ° C, the mass of pressure being 5 kd and the thread having a diameter of 2.09 mm. EXPERIMENT 16 This example illustrates the invention and provides a composition comprising: - 41.5% by weight of chalk from the Citalopide area treated with stearic acid having an average diameter of 2 micrometers; - 41.5% by weight of talc with such granulometry that 41% of the particles have a diameter of less than 5 micrometres; 30 - 15.9% by weight isotactic polypropylene having an MP equal to 840 g / 10 min (190 ° C, 10 kg, 1.05 mm); -1.0% by weight of zinc stearate; - 0.1% by weight of a thermal stabilizer, known in the trade network under the name 1goda ™ 1010 of the Cua-Ceudu. The resulting MP has a value of 10.6 g / 10 minutes, the above mentioned conditions. EXPERIMENT 17 This example illustrates the invention to provide a composition comprising: - 64.25% by weight of chalk from the Cidradope area treated with stearic acid having a mean diameter of 2 micrometers; - 21.25% by weight of talc with such granulometry that 41% of the particles have a diameter of less than 5 micrometers; - 13.9% by weight of isotactic polypropylene having an MP equal to 840 g / 10 min (190 ° C, 10 kg, 1.05 mm); 0.50% by weight of a phosphate fatty alcohol type dispersant commercially available under the name COATEX DOPP-18 of Coallex], 0.1% by weight of a thermal stabilizer known as the commercial grid under the designation 1gadox ™ 1010 of the Cua-Ceu. 31 The resulting MP has a value of 20.7 g / 10 minutes, the above-mentioned conditions. EXPERIMENT 18 This example illustrates the invention to provide a composition comprising: - 75, 0% by weight of chalk from the Citalopine area treated with stearic acid having an average diameter of 2 micrometers; - 13.0% by weight of a commercially available magnesium hydroxide having an average diameter of 1.4-1.8 micrometres; - 8.9% by weight of isotactic polypropylene having an MP of 840 g / 10 min (190 ° C, 10 kg of filler, 1.05 mm) and 2.0% by weight of one polypropylene copolymer grade 100 manufactured by Montreal, Morline ™ EP-N 31 MA; - 1.0% by weight of wax produced by the company A1Ne1515 | dpa1 under the name PEAC6; - 0.1% by weight of a thermal stabilizer, known in the trade network under the name 1goda ™ 1010 of the Cua-Ceudu. The resulting MP has a value of 14.5 g / 10 minutes, the above-mentioned conditions. EXPERIMENT 19 This example illustrates the invention and provides a composition comprising: - 87, 0% weight calcite with a diameter of 1.8 micrometers; 32-9.9% by weight of isotactic polypropylene having an MP equal to 840 g / 10 min (190 ° C, 10 kg, 1.05 mm) and 1.5% by weight of one polypropylene copolymer grade 100 manufactured by Montechilop the name Mercury ™ EP-N 31 MA; -1.5% by weight zinc stearate; - 0.1% by weight of a thermal stabilizer, known in the trade network under the name 1goda ™ 1010 of the Cua-Ceudu. The resulting MP has a value of 10.8 g / 10 minutes, the above mentioned conditions. EXPERIMENT 20 This example illustrates the invention to provide a composition comprising: - 41.0% by weight of a chalk from the Cidradepene area treated with stearic acid having an average diameter of 2 micrometers; - 41.0% by weight of a dolomite with a mean diameter of 3 micrometres; - 17, 9% by weight isotactic polypropylene having an MP equal to 840 g / 10 min (190 ° C, 10 kg, 1.05 mm); - 0.1% by weight of a thermal stabilizer, known in the trade network under the name 1goda ™ 1010 of the Cua-Ceudu. The resulting MP has a value of 95.5 g / 10 minutes, the above mentioned conditions. 33 EXPERIMENT 21 This example illustrates the invention to provide a composition comprising: - 81.0% by weight marble with a mean diameter of 5 micrometers; - 5.0 wt.% Of a calcium carbonate available from the market under the name Pearing ™ of the company Sacchar-Kaik; - 10.6% by weight of isotactic polypropylene having an MF equal to 757 g / 10 min (190 ° C, 10 kg, 1.05 mm) and 2.0% by weight of one low density polyethylene commercially available from Roptep The name under the name Pfleepe ™ MV10; - 0, 5% sorbitan phosphate type disintegrant, manufactured by Coalch Co., under the name COATEX DOPP-18; - 0.8% by weight of zinc stearate; - 0.1% by weight of a thermal stabilizer, known in the trade network under the name 1goda ™ 1010 of the Cua-Ceudu. The MPI obtained was 48.2 g / 10 min, under the above-mentioned conditions. EXAMPLES 22 This example illustrates the invention to provide a composition comprising: 34-32.8% by weight of chalk from the CMATtrape, treated with stearic acid having an average diameter of 2 micrometers; - 60,2% by weight of barite with a mean diameter below 5 micrometers; - 4.6% by weight of isotactic polypropylene having an MP equal to 757 g / 10 min (190 ° C, 10 kg, 1.05 mm) and 0.5% by weight of a 100% polypropylene copolymer, manufactured by Montreal, the name Mupun ™ EP-N 31 MA; - 0.9% sorbitan phosphate-type dispersant, manufactured by Coalch Co., under the name COATEX DOPP-18; - 0.9% by weight of zinc stearate; - 0.1% by weight of a thermal stabilizer, known in the trade network, under the designation 10a10 of the Cua-SeuDu company. The resulting MFI has a value of 26.0 g / 10 minutes under the above-mentioned conditions. EXPERIMENT 23 This example illustrates the invention to provide a composition comprising: - 42.0% by weight of chalk from the Claytrape area treated with stearic acid having an average diameter of 2 micrometers; - 43,0% by weight of titanium dioxide (rutile), in the commercial network under the name P1_90; 35- 7.3% by weight of isotactic polypropylene having an MF equal to 757 g / 10 min (190 ° C, 10 kg, 1.05 mm) and 6, 7% by weight of one low density polyethylene produced by Root Tee Company under the name P & apos; Lite ™ MV10; - 0.9% by weight of zinc stearate; - 0.1% by weight of a thermal stabilizer, known in the trade network, under the designation 1goda ™ 1010 of the Cua-Oleu company. The resulting MP has a value of 149.0 g / 10 minutes, the above-mentioned conditions. EXPERIMENT 24 This example illustrates the invention and provides a composition comprising: - 19.2% by weight of chalk from the Citalopide area treated with stearic acid having an average diameter of 2 micrometers; - 60,5% by weight of barium with an average diameter of 5 micrometers; - 11.5% by weight of valeronite treated with an average fiber length of 90 micrometers; - 6.1% by weight of isotactic polypropylene having an MF equal to 757 g / 10 min (190 ° C, 10 kg, 1.05 mm) and 1, 7% by weight of a 100% polypropylene copolymer produced by Molexel under the name Mopel ™ EP-N 31 MA; - 0.9% by weight of zinc stearate; 36 - 0.1% by weight of thermal stabilizer, known as the commercial grid, under the name 1goda ™ 1010 of the Cua-6e1d. The resulting MP has a value of 146.0 g / 10 minutes, the above mentioned conditions. EXPERIMENTAL 25 This example illustrates the invention to provide a composition comprising: - 75.0% by weight of chalk from the Cidratope, treated with stearic acid having a mean diameter of 2 micrometers; - 12.0% dry weight of an aqueous suspension at 62.2% dry crayfish of Citalopram, untreated, free of acrylic dispersants and having a mean diameter equal to 1 micrometre; - 13.0% by weight of isotactic polypropylene having an MP equal to 840 g / 10 minutes (190 ° C, 10 kg, 1.05 mm); The resulting MP has a value of 12.0 g / 10 minutes, the above mentioned conditions. The various results obtained are summarized in the following Table 2. Inventory Invention Invented Invention Inspired Inspired Inspired Invent Inspired Inspired Inspiration 25 24 23 22 Ju 20 <0 00 "4c> Trial No. Chalk Chalk Chalk Waltoston Creta-Titanium Dioxide Chalk-Barite Marble-precipitated calcium carbonate P <Row-dolomite Calcite Chalk-Magnesium hydroxide Creta-talc Chalk-talc Type of minerals I 87,0 19,2-60,5- 11,5 42,0-43,0 32,8-60 , 2 00 o 1 O 1 O 41.0-41.0 87.5 75.0-13.0 64.25-21.25 41.5-41.5% by weight mineral filler in starting mixtures 13.0-0.0 4.6 10.6 17.9% b) 13.9.45 15.9% by weight of isotactic polypropylene in feedstocks 840 757 757 757 430 238 840 840 840 840 MH (10 min) isotactic polypropylene (190 ° C / 10 kg / 1.05 mm) 12.0 146.0 149.0 26.0 48.2 95.5 o 00 14, 5 20.7 10.6 61.6 65.0 65.0 65.0 65.0 35.0 61.6 61.6 61.6 61.6 Percentage of crystallinity indices of liquid isotactic polymer TABLES TABLES 38 Reading of Table 2 makes it possible to ascertain the production of isotactic polypropylene with high fl uidity and exceeding or equal to 200 g / 10 min, measured according to the modified standard NP 51-620 (190 ° C - 10 kg / 1.05 mm), preferably (190 ° C - 10 g / 1.05 mm), with a crystallinity percentage of approximately 20%, preferably between 30% and 90%, as measured according to the modified standard NPS T51-620 more preferably between 50% and 85%, allows the preparation of starting mixtures having a filler content equal to or greater than 80%, which have a high fluidity, i.e., a MP greater than or equal to 5g / 10min (190 ° C -5 g / 2.09 mm), as measured according to standard TN 51-620, and which contain at least one polymer isotype polypropylene copolymer exhibiting a crystallinity percentage (also called isotactic index) greater than about 20%, preferably in the range of 30% to 90%, more preferably between 50% and 85%, as measured by the DSC method as described above. Furthermore, it may be noted that the high density fluidizable polypropylene bonding with one or more of the polymers allows: - one adjustment of the fluidity of the filling concentrate in order to achieve blends with filler properties and with many different characteristics, one with respect to the other , in particular granulometry, to adapt the formula to the method, - to increase compatibility of the concentrate concentrate with the medium in which it is to be dispersed, 39 - to reach a less expensive formula, - to regulate the hardness of the concentrates. EXAMPLE 3 This example relates to the re-dispersion of starting mixtures in different polyolefins. For this purpose, for each of experiments n ° 26 to 53, a strip of 3 mm thick strips is drawn through a flat filament using a Toll screw extruder whose screw is a diameter of 25 mm long, 15 L long, while a thread of length from 16 mm and height 2.5 mm. The screw rotation speed is 50 revolutions per minute, the amount of compression is 3, and the extrusion temperature is 170 ° C with polyethylene and 210 ° C for one polypropylene copolymer homopolymer. The extrusion is carried out by successively feeding the extruder with the virgin polyolefin resuspension which serves to control and formulated mixtures of the same polyolefin and starting mixtures, according to the invention for testing so as to coincorporate 20% by weight filler over the total mass. The binocular magnifying glass magnification with an increase of 50 for each of the dispersions obtained allows to observe the 1 to 6 visual aspect of the dispersion with the value 1 when there is no variance and the value 6 when there is a very good dispersion, i.e., when there are no black points corresponding to the disintegrated polyolefin and white dots matching the contractor. The results are as follows: 40 EXPERIMENT n ° 26: This study illustrates the invention and demonstrates the preparation of the starting mixtures according to the invention No. 5 and the commercially available polypropylene homopolymer resin as manufactured by Moncelle ™ under the name Montell ™ TM 1600 K. The value 6 is attributed to the dispersion. EXPERIENCE n ° 27: This study illustrates the invention and illustrates the preparation of the starting mixtures according to the invention, et al. No. 6, and the commercially available polypropylene homopolymer resin, such as the Monitell Manufacturing under the name Montreal ™ TM 1600 K. The value 6 is attributed to the dispersion. EXPERIMENT No. 28: This study illustrates the invention and shows the preparation of the starting mixtures according to the invention, nop. 7, and the commercially available polypropylene homopolymer resin, such as the Mannell Company under the name Molex ™ TM 1600 K. The value 6 is attributed to the dispersion. EXPERIMENT No 29: This study illustrates the invention and demonstrates the preparation of the starting mixtures according to the invention, etherate n ° 8 and the commercially available polypropylene homopolymer resin, such as the production of Molexel under the name Molex ™ TM 1600 K. The value 6 is attributed to the dispersion. EXPERIMENT n ° 30: This study illustrates the invention and shows the preparation of the starting mixtures according to the invention of ketone No. 9 and the commercially available polypropylene homopolymer resin, such as the manufacture of C Molle11 under the name Montell ™ TM 1600 K. The value 6 is attributed to dispersion. EXPERIMENT No 31: This study illustrates the invention and demonstrates the preparation of starting mixtures according to the invention at No. 10 and the commercially available polypropylene homopolymer resin, such as Mannell ™ TM 1600 K. The value 6 is attributed to the dispersion. EXPERIMENT No. 32: This study illustrates the invention and shows the preparation of starting mixtures, according to the invention, melt No. 11 and the commercially available polypropylene homopolymer resin, such as the Mannell Company under the name of Molex ™ TM 1600 K. The value 6 is attributed to the dispersion. 42 EXPERIMENT n ° 33: This study illustrates the invention and demonstrates the preparation of the starting mixtures according to the invention at No. 12 and the commercially available polypropylene homopolymer resin as the manufacture of the Monheim product under the name Montal ™ TM 1600 K. The value 6 is attributed to the dispersion . EXPERIMENT n ° 34: This study illustrates the invention and shows the preparation of the starting mixtures according to the invention, et al. No. 13, and the commercially available polypropylene homopolymer resin, such as the Mannell Company under the name Molex ™ TM 1600 K. The value 6 is attributed to the dispersion. EXPERIMENT No. 35: This study illustrates the invention and demonstrates the preparation of the starting mixtures according to the invention, et. Al. 14 and the commercially available polypropylene homopolymer resin, such as Mannell ™ TM 1600 K. The value 6 is attributed to the dispersion. EXPERIMENT No 36: This study illustrates the invention and demonstrates the preparation of starting mixtures according to the invention, et al. No. 15, and the commercially available polypropylene homopolymer resin 43, manufactured by Monheim, under the designation Mochep ™ TM 1600 K. The value 6 is attributed to the dispersion . EXPERIMENT n ° 37: This study illustrates the invention and shows the preparation of the starting mixtures according to the invention, No. 16, and the commercially available polypropylene homopolymer resin, such as the production of Montelle under the name Montreal ™ TM 1600 K. The value 6 is attributed to the dispersion. EXPERIMENT No. 38: This study illustrates the invention and demonstrates the preparation of the starting mixtures according to the invention at No. 17 and the commercially available polypropylene homopolymer resin, such as Molex® under the name Molex ™ TM 1600 K. The value 6 is attributed to the dispersion. EXPERIMENT No. 39: This study illustrates the invention and demonstrates the preparation of starting mixtures according to the invention, et. Al. 18 and the commercially available polypropylene homopolymer resin, such as Molex® under the name Molex ™ TM 1600 K. The value 6 is attributed to the dispersion. 44 EXPERIMENT n ° 40: This study illustrates the invention and shows the preparation of starting mixtures, according to the invention, melt No. 19 and the commercially available polypropylene homopolymer resin, such as Molex®, manufactured under the name Montreal ™ TM 1600 K. The value 6 is attributed to the dispersion. EXPERIMENT No. 41: This study illustrates the invention and demonstrates the preparation of starting compounds according to the invention, etherified n ° 20 and the commercially available polypropylene homopolymer resin, such as Mannell ™ TM 1600 K. The value 6 is attributed to the dispersion. EXPERIMENT No. 42: This study illustrates the invention and demonstrates the preparation of the starting mixtures according to the invention, et al. No. 21, and the commercially available polypropylene homopolymer resin, such as the Monheim product under the name Montreal ™ TM 1600 K. The value 6 is attributed to the dispersion. EXPERIMENT No 43: This study illustrates the invention and demonstrates the preparation of the starting mixtures according to the invention, etherified n ° 22 and the commercially available polypropylene homopolymer resin, such as the production of Molex® under the name Montell ™ TM 1600 K. The value 6 is attributed to the dispersion . EXPERIMENT n ° 44: This study illustrates the invention and shows the preparation of the starting mixtures according to the invention, et al. No. 23 and the commercially available polypropylene homopolymer resin, such as the Mannell Company under the designation Molex ™ TM 1600 K. The value 6 is attributed to the dispersion. EXPERIMENT n ° 45: This study illustrates the invention and shows the preparation of starting mixtures according to the invention, nop. No. 24 and the commercially available polypropylene homopolymer resin, such as Monheim's Manufacturing under the name Montell ™ TM 1600 K. The value 6 is attributed to the dispersion. Test n ° 46: This test illustrates the invention and pokazvapoluchavaneto of polypropylene copolymer resin, known commercially as production nafirmata ΑρριγΙ under the name ΑρριγΙ ™ 3120 ΜΝ 1 isastav according to the invention comprising: 46-87% by weight chalk field SYatradpe treated with stearic acid having an average diameter of 2 micrometers; - 9.1% by weight of amorphous polypropylene having a molecular weight of 450 g / 10 minutes (190 ° C, 10 kg cartridge, 1.05 mesh), commercially available from Nympartop®, the name KexLex ™ 125; - 3.9% by weight of isotactic polypropylene having an MP equal to 840 g / 10 min (190 ° C, 10 kg, 1.05 mm); The value 6 is attributed to the dispersion. Test n ° 47: This test illustrates the invention and pokazvapoluchavaneto uses the master batch according to the invention otopit n ° 14 and the polypropylene copolymer resin izvestnaot commercially by the company Arrgu! Under the name Arrgu! ™ 312θ ΜΝ 1 value 6 is attributed to the dispersion . Test n ° 48: This test illustrates the invention and uses the master batch pokazvapoluchavaneto invention otopit n ° 14 and polyethylene resin, high density, known commercially as production nafirmata R1i55-81aiTeg under the name No51a1ep ™ Οϋ7225. The value 6 is attributed to the dispersion. 47 EXPERIMENT n ° 49: This study illustrates the invention and demonstrates the preparation of starting mixtures according to the invention at No. 12 and the high density polyethylene resin commercially known, such as the production of P1558-51AeTeg under the name of No81ael ™ CD7225. The value 6 is attributed to the dispersion. Test n ° 50: This test illustrates the invention and pokazvapoluchavaneto polyethylene resin, high density, known commercially as production nafirmata R1izz-81aiTeg under the name No51a1ep ™ Οϋ7225 and master batch according to the invention for the composition: - 87.0% by weight of chalk from the STAtrape region, treated with stearic acid having an average diameter of 2 micrometers; - 10.0% by weight of isotactic polypropylene with MPI equal to 840 g / 10 min (190 ° C, 10 kg cartridge, 1.05 mm fiber) and 3.0% by weight of one polypropylene copolymer grade 100 produced by Molexel under the name Morwon ™ EP-N 31 MA; The value 6 is attributed to the dispersion. EXPERIENCE n ° 51: This test illustrates the invention and pokazvapoluchavaneto polyethylene resin, high density, 48 known commercially as production nafirmata R1i55-51ai1eg under the name No51a1ep ™ Οϋ7225 and master batch according to the invention for the composition: - 86.0% by weight of chalk field SYatradpe, treated with stearic acid having an average diameter of 2 micrometers; - 7.5% by weight of isotactic polypropylene having an MP equal to 840 g / 10 min (190 ° C, 10 kg, 1.05 mm) and 6.5% by weight of one polypropylene copolymer grade 100 manufactured by Molexel under the name Morwon ™ EP-N 31 MA; The value 6 is attributed to the dispersion. EXPERIMENT n ° 52: This study illustrates the invention and demonstrates the preparation of a low density polyethylene resin, commercially known, as production nafirmata VA5R under the name 1_iro1epe ™ 2420 H isastav according to the invention containing: - 87.0% by weight of chalk field SIatradpe treated with stearic acid and with a mean diameter from 2 micrometers; - 9.1% by weight amorphous polypropylene with equal ΜΡΙ na450 g / 10 min (temperature 190 ° C, load 10 kg, nishka1,05 mm) made commercially available by the company name Nipyutappod RehLeh ™ \ L / 1_ 125; 49 - 3.9% by weight of isotactic polypropylene having an MP equal to 840 g / 10 min (temperature 190 ° C, filler 10 kg, fiber 1.05 mm); The value 6 is attributed to the dispersion. EXPERIMENT No. 53: This study illustrates the invention and demonstrates the preparation of starting mixtures according to the invention, et al. No. 14 and a low density polyethylene resin known from the trade network, such as the production of the company VAPS under the name Liropole ™ 2420 H. The value 6 is attributed to the dispersion. The reading of all of these results allows us to assume that the choice of isotactic polypropylene with high fl uidity and greater than or equal to 200 g / 10 minutes as measured above allows to achieve an excellent redispersion of any repressible resin or filler, constituent of the starting mixture. EXAMPLE 4 This example relates to the mechanical properties of the various starting materials according to the invention manufactured on an industrial scale. For this purpose, and for each of experiments n ° 54 to 65, test tubes made by injection were subjected to tests of the mechanical properties. For this purpose, normalized tubes (ISO 1873-2: 1989) were performed by means of a press. 170/90, 50 guided by a microprocessor with a closing force of 900 kJ, a screw diameter of 32 mm and a length / diameter ratio of 18.8. The main parameters for regulating the press are the following: - the temperature of the substance is between 200 ° C and 240 ° C, according to the dispersion polymer or copolymer it is used, - the temperature of the matrix is 40 ° C, - the air tube temperature rises between 200 ° C C and 240 ° C, according to the dispersion polymer or copolymer to be used, - the maximum injection rate is 200 m & lt; 3 & gt; / h, - the injection pressure is 100 bar, - the cycle time is approximately 62 seconds, cooling for 30 seconds, retention time The press is fed in succession only with the polymers or copolymers, controlling mixtures with the same polymers or copolymers in which the starting mixtures of the inventions obtained in the form of granules at a flow rate of 155 kg / l are added by adding different ingredients in a continuous twin screw mixer ending with a single screw extruder whose output adapts a granulator. The tests for the mechanical properties are the determination of the modulus of elasticity for 51 bending four points according to the DIN 53457 standard and the determination of a Clair stroke at 23 ° C according to DIN 53453. EXPERIMENT n ° 54 This example illustrates the prior art of the technique and the preparation of a dispersion comprising 60% by weight of high density polyethylene resin known from the commercial network, such as the production of Plast-51aireg under the designation Nozzle ™ 7225 and 40% of the starting mixes of Experiment 2 of the state of the art. The results obtained are equal to 799 N / mm2 for the modulus of elasticity for bending four points according to standard 53457 and 3,4 and / or 2 for a Clair stroke at 23 ° C, according to DIN 53453. EXPERIMENT n ° 55: This example illustrates the invention and the preparation a dispersion containing 60% by weight of a high density polyethylene resin, commercially available, as manufactured by the company P1ise-51a (ee under the name Hazel ™ 7225 and 40% starting mixtures according to the invention: 87.0% by weight of chalk from the field Stearic acid treated with stearic acid but with an average diameter of 2 microns, 52-10.0% by weight of isotactic polypropylene having an MP equal to 840 g / 10 minutes (190 ° C, filler 10 kg, fiber 1.05 mm) and 3.0% by weight of one polypropylene copolymer grade 100 manufactured by Molexel under the name Mopron ™ EP-N 31 MA; The results obtained are equal to 1363 N / mm2 of elasticity modulus for bending four points according to the DIN 53457 standard and 3,4 and / or 2 for a Clair stroke at 23 ° C according to DIN 53453 standard. illustrates the invention and the preparation of a dispersion comprising 60% by weight of a high density polyethylene resin, commercially available, as a production of the company Polysaccharide under the name Holzellen TM 7225 and 40% of the starting mixtures according to the invention with: - 87.0% by weight of chalk from the field Stearic acid treated with stearic acid - 8, 5% by weight isotactic polypropylene having an MP of 840 g / 10 min (190 ° C, 10 kg cartridge, 1.05 mm mesh) and 4.5% by weight of one polypropylene copolymer grade 100 manufactured by Mopu under the name Merup ™ EP -N 31 MA; The results obtained are equal to 1333 N / mm2 modulus of elasticity for bending four points according to 53 standards DIN 53457 and 3.6 and / or 2 for a Clair stroke at 23 ° C according to DIN 53453. EXPERIMENT n ° 57: This example illustrates the invention and the preparation of a dispersion containing 60% by weight of a high density polyethylene resin, commercially available, produced by the company Polysaccharide under the name Holzellen TM 7225 and 40% of the starting blends according to the invention with a composition of: 87.0% by weight of chalk , treated with stearic acid - 7, 0% by weight of isotactic polypropylene having a MPI equal to 840 g / 10 min (190 ° C, 10 kg, 1.05 mm) and 6.0% by weight of a 100% polypropylene copolymer manufactured by Monsley under the name Merup ™ EP -N 31 MA; The results obtained are equal to 1309 N / mm2 of elasticity modulus for bending four points according to the DIN 53457 and 3,4 and / or 2 standards for impact of CHAgru at 23 ° C according to DIN 53453. EXPERIMENT No. 58: This example illustrates one control , for which the mechanical properties are measured on a virgin resin, in particular a polypropylene homopolymer resin known in the art as a monolithic monomer known as Molex ™ TM 1600 K. The results obtained are equal to 914 Nm2 for the modulus of elasticity for bending four points according to a standard TDIN 53457 and 2.6 M / m 2 for a Clair stroke at 23 ° C, according to DIN 53453. EXPERIMENT n ° 59: This example illustrates the prior art of the technique and the preparation of a dispersion containing 60% by weight of a polypropylene homopolymer resin known in the trade network, such as Mannell's Mannell TM TM 1600 K and 40% 2 of the prior art of the art. The results obtained are equal to 1446 N / mm2 of elasticity modulus for bending four points according to DIN 53457 standard and 3.0 and / or 2 for impact of SKARGU at 23 ° C according to DIN 53453. EXPERIMENT n ° 60: This example illustrates the invention a dispersion containing 60% by weight of a commercially available polypropylene homopolymer resin as manufactured by Montreal under the name of Monolel ™ TM 1600 K and 40% of starting mixtures according to the invention with the composition: 55 - 87.0% by weight of chalk from the Citalopine area treated with stearic acid having an average diameter of 2 micrometers; - 10.0% by weight of isotactic polypropylene having an MP equal to 840 g / 10 min (190 ° C, 10 kg, 1.05 mm) and 3.0% by weight of one polypropylene copolymer grade 100, manufactured by Montreal, Morwon ™ EP-N 31 MA; The results obtained are equal to 1805 N / mm2 of elasticity modulus for bending four points according to the DIN 53457 standard and 3.0 and / or 2 for a Clair stroke at 23 ° C according to DIN 53453. EXPERIMENT No. 61: This example illustrates the invention a dispersion containing 60% by weight of polypropylene homopolymer resin commercially known as Molex® under the name Molex ™ TM 1600 K and 40% of starting mixtures according to the invention: 0% by weight of chalk from the Citalopine area treated with stearic acid having an average diameter of 2 micrometers; - 8.5% by weight of isotactic polypropylene having an MP equal to 840 g / 10 min (190 ° C, 10 kg cartridge, 1.05 mm fiber) and 4.5% by weight of one polypropylene copolymer grade 100 manufactured by MopuNupon the name Morwon ™ EP-N 31 MA; 56 The results obtained are equal to 1718 N / mm2 flexural modulus of four points according to the DIN 53457 standard and 3.2 M / m 2 for a Clair stroke at 23 ° C according to UN 53453. EXPERIMENT n ° 62: This example 5% by weight of a 100% polypropylene copolymer, manufactured by Modell Company under the name Mercury ™ EP-N 31 MA; 56 The results obtained are equal to 1718 N / mm2 flexural modulus of four points according to the DIN 53457 standard and 3.2 M / m 2 for a Clair stroke at 23 ° C according to UN 53453. EXPERIMENT n ° 62: This example 5% by weight of a 100% polypropylene copolymer, manufactured by Modell Company under the name Mercury ™ EP-N 31 MA; 56 The results obtained are equal to 1718 N / mm2 flexural modulus of four points according to the DIN 53457 standard and 3.2 M / m 2 for a Clair stroke at 23 ° C according to UN 53453. EXPERIMENT n ° 62: This exampleillustrates the invention and the preparation of a dispersion comprising 60% by weight of a commercially available polypropylene homopolymer resin as manufactured by Montreal under the name Montell TM TM 1600 K and 40% by weight of the blend according to the invention with a composition of: 87.0% by weight of a chalk from the region of C, treated with stearic acid having an average diameter of 2 micrometers; - 7.0% by weight of isotactic polypropylene having an MP equal to 840 g / 10 min (190 ° C, 10 kg, 1.05 mm) and 3.0% by weight of a 100% polypropylene copolymer manufactured by Molexel under the name Morwon ™ EP-N 31 MA; The results obtained are equal to 1754 N / mm2 modulus of elasticity for bending four points according to the DIN 53457 standard and 3.1 M / m 2 for a Sparrow impact at 23 ° C according to DIN 53453. EXPERIMENT n ° 63: This example illustrates the invention and the preparation of a dispersion containing 69% by weight of a commercially available polypropylene 57 resin, such as the manufacture of the Bodea® sub-name Bodea ™ 202E and 31% by weight of starting mixtures (corresponding to 25% by weight of mineral filler) : 80.5% by weight of talc with such granulometry that 41% of the particles have a diameter of less than 5 micrometers; - 18.5% by weight of isotactic polypropylene having an MP equal to 1038 g / 10 min (190 ° C, 10 kg, 1.05 mm); -1.0% by weight of zinc stearate. The results obtained are equal to 2212 N / mm² of elasticity modulus for bending four points according to the DIN 53457 standard and 12 m / m 2 for a Clair stroke at 23 ° C according to DIN 53453. EXPERIMENT n ° 64: This example illustrates the invention and the preparation of a dispersion , containing 69, 88% by weight of commercially available polypropylene resin, such as Boehringer® 202 E and 30.12% by weight of starting materials (corresponding to 25% by weight of mineral filler) according to the invention with a composition of 41.5% by weight of chalk the Citalopine area treated with stearic acid having an average diameter of 2 micrometers; - 41.5% by weight of talc with such granulometry that 41% of the particles have a diameter of less than 5 micrometres; 58 - 16.5% by weight isotactic polypropylene having an MP equal to 1038 g / 10 min (temperature 190 ° C, filler 10 kg, fiber 1.05 mm); - 0.5% by weight of a type of phosphorous fatty alcohol dispersant commercially known as Coallex DOPP-18 of Coallex. The results obtained are equal to 1845 N / mm2 of elasticity modulus for bending four points, according to the DIN 53457 standard and 18 mm2 for a KARarrow stroke at 23 ° C according to the standard DIN 53453. EXPERIMENT n ° 65: This example illustrates the invention and the preparation of a dispersion comprising 70.59% by weight of polypropylene homopolymer commercially available, the name Bodean ™ 202 E and 29.41% by weight of starting mixtures (corresponding to 25% by weight of the treated mineral filler) according to the invention with a composition of: - 63.75% by weight of chalk from the CKtradepe treated with stearic acid having an average diameter of 2 micrometers; - 21.25% by weight of talc with such granulometry that 41% of the particles have a diameter of less than 5 micrometers; - 14.5% by weight of isotactic polypropylene having an MP equal to 1038 g / 10 minutes (temperature 190 ° C, filler 10 kg, fiber 1.05 mm); 59 - 0.5% by weight of a type of phosphorous fatty alcohol dispersant, commercially known as Coallex DOPP-18 of Coallex. The results obtained are equal to 1670 N / mm2 modulus of elasticity for bending four points according to the DIN 53457 standard and 22 M / m 2 for impact of CMargo at 23 ° C according to DIN 53453. The various results obtained are summarized in the following Table 3 "0 ТЗ" 0 ТЗ С1 о ± 1 "О з 1 з: i3 φ
(S)
I = 1 ο C Ο ΞΙ ± 1 Φ
I T3 T3
I
X ο ο 3 ο Σ: Φ σ φ = 3 ο ± 1 = 1 ο ο Σ3 Φ
I T3 AG
I σ ο φ Σο Φ
I ο φ ζ? o ο τ? 0) S3 In Invention Invention Invention Invent Invent Inventory Inventory Inventory Inventory Inventory Inventory Priority 65 °> 4 ° 03 ° o> 0 ° C> 0 ° C) 4-Z-1 PP T3 T3 T3 T3 T3 T3 PPN PPN PPN PPN PEHD PEHD PEHD PEHD Resin type 87.0 19.2-60.5-11.5 42.0-43.0 32.8-60, 2 00 o 1 ol o 4 o O 4 o o 87,5 75,0-13,0 64,25-21,25 41,5-41,5 starting mixture% filler-isotacticpolypropylene 13,0-0,4 00 4 ^ 5 »10,6 17,9 5 ° 00 00 13,9,45 15,9 Flexible elasticity modulus four feet (N / mm 2) 00 4 ° C 757 757 757 238 00 4b. 0 4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 The reading of Table 3 permits to note that the selection of isotactic polypropylene with a high fluidity and exceeding or greater than that of the polypropylene equal to 200 g / 10 minutes, as measured above, allows excellent mechanical properties to be obtained, whatever the resuspension resin or the composite of feedstocks. Good collision qualities characterize the good dispersion of the filler in the polymer matrix. EXAMPLE 5 This example relates to the determination of the hardness of the products according to the invention. For this purpose, for each of the experiments n ° 66 to 68, the feedstock mixtures according to the invention, cooled to room temperature, formed in paste form at approximately 190 ° and at a flow rate of 155 kg / s, by adding various components in a continuous twin screw mixer, a capacity of 500 kg / s and ending with a single screw extruder, a hardness measurement is carried out using a hardness tester of the type Gluc ™ and according to the NF T 51-109 standard, and immediately after the tensioning of the filler concentrate bridge also referred to as the feed mixture. EXPERIMENT n ° 66: This experiment illustrates the prior art of the art and produces a composition comprising: 62-87% by weight of chalk from the Craftard area treated with stearic acid having an average diameter of 2 micrometers; - 13% by weight of amorphous polypropylene with a melting point of 450 g / 10 min (190 ° C, 10 kg cartridge, 1.05 mm long) known commercially under the trade name Niplast ™ Peptide ™. The hardness achieved is 66. EXPERIMENT n ° 67: This experiment illustrates the invention and provides a composition comprising: - 87% by weight of chalk from the Craftpepe area treated with stearic acid having an average diameter of 2 micrometers; - 9.1% by weight of an amorphous polypropylene having an MOP equal to 450 g / 10 min (190 ° C, filler 10 kD, fiber 1.05 mm) commercially known under the trade name & quot; Peptide ™ & quot; - 3.9% by weight of isotactic polypropylene having an MP equal to 450 g / 10 min (190 ° C, 10 kg, 1.05 mm). The obtained stiffness is 73. EXPERIMENT n ° 68: This experiment illustrates the invention and provides a composition comprising: 63-87% by weight of chalk from the Citalopide area treated with stearic acid having a mean diameter of 2 micrometers; -13% isotactic polypropylene with MDI equal to 840 g / 10 min (temperature 190 ° C, filler 10 kg, fiber 1.05 mm). The achieved hardness is 76. The foregoing results show that the compositions of the invention are more rigid than those of the state of the art (76 and 73 exceed 66) and that it is possible to adjust the hardness of the starting mixtures, by changing the composition of its organic part. EXAMPLE 6 This example relates to the use of starting materials according to the invention in extrusion of films. For the preparation of films of linear polyethylene low density, also denoted as GOPE and for each of Examples 70 to 76, the LIPE resin is extruded in the presence of increasing amounts of the premix nozzle 14 according to the invention using a Naake Pekosogas ™, equipped with a twin screwdriver rotating at 30 rpm and passing through a circular filament at a temperature of 190 DEG C. and whose diameters were increased before cooling by a 40 bar pressurized injecting air. The cooling is carried out in air. After the film was obtained, its thickness was measured. 64 Experience n ° 69 corresponds to the control, i.e., the preparation of a film with a LUPE virgin resin gives a film thickness of 9 micrometers. The different amounts of the starting mixtures of Experiment n ° 14 produced according to the invention correspond to the cubic cubic centimeter to the weight of the resin as described below. EXPERIMENT n ° 70 This example, which illustrates the invention, corresponds to 5.3% chalk on the weight of HEPRE and gives a film thickness of 11 micrometers. EXPERIMENT n ° 71 This example, which illustrates the invention, corresponds to 15.2% chalk on the weight of HORE and gives a film thickness of 15 micrometers. EXPERIMENT n ° 72 This example, which illustrates the invention, corresponds to 28.7% chalk on the weight of LPEPE and gives a film thickness of 19 micrometers. EXPERIMENT n ° 73 This example, which illustrates the invention, corresponds to 29, 1% chalk on the weight of LLDPE and gives a film thickness of 22 micrometers. 65 EXPERIMENT n ° 74 This example, which illustrates the invention, corresponds to 45.6% chalk on the weight of 1.SHEP and gives a film thickness of 32 micrometers. EXPERIMENT n ° 75 This example, which illustrates the invention, corresponds to 51.7% chalk on the weight of LPEPE and gives a film thickness of 31 micrometers. EXPERIMENT n ° 76 This example, illustrating the invention, corresponds to 53.2% chalk on the weight of III / PE and gives a film thickness of 25 micrometers. Thus, when reading the results, it can be seen that it is possible to obtain an extruded film containing feedstocks according to the invention. EXAMPLE 7 This example relates to the use of feedstocks according to the invention in smoothing. For this purpose, for each of the experiments, it is prepared in mixer cylinders, a mixture of 60 wt.% virgin polymer with 40 wt.% of the composition of Experiment n ° 9 according to the invention. The mixer parameters for each of the tests are the following: - cylinder temperature equal to 170 ° C, 66 - cylinder crossing thickness equal to 11 mm, - cylinder speed of 25 L / min. The smoothing is complete when the composition visually becomes homogeneous. Then, for each of the tests, the modulus of flexural flexibility was four points according to the standard 5353 and a cut of the Clair cut at 23 ° C according to DIN 53453. EXPERIMENT No 77 This experiment illustrates the invention and produces, as a polymer, a polypropylene homopolymer known commercially available, as manufactured by Modelle under the designation Molex ™ TM 1600 K. The results obtained are equal to 1 695 N / mm2 of the elasticity modulus for bending four points, according to the DIN 53457 standard and 2.9 M / m 2 for a Clair stroke cut at 23 ° C according to DIN 53453. EXPERIMENT No 78 This experiment illustrates the invention and produces, as a polymer, a high density polyethylene, commercially known, manufactured by the company Rise-51aireg under the name Hosseel ™ CC 7260. The results obtained are equal to 1 285 N / m 2 of a modulus of elasticity for bending four points according to 67 DIN 53457 standards and 3.4 N / m 2 for a Clare cut cut at 23 ° C , according to DIN 53453. Therefore, the reading of the results allows
Contents4
52 sheets
Sheet 1 Sheet 2 Sheet 3 Sheet 4 Sheet 5 Sheet 6 Sheet 7 Sheet 8 Sheet 9 Sheet 10 Sheet 11 Sheet 12 Sheet 13 Sheet 14 Sheet 15 Sheet 16 Sheet 17 Sheet 18 Sheet 19 Sheet 20 Sheet 21 Sheet 22 Sheet 23 Sheet 24 Sheet 25 Sheet 26 Sheet 27 Sheet 28 Sheet 29 Sheet 30 Sheet 31 Sheet 32 Sheet 33 Sheet 34 Sheet 35 Sheet 36 Sheet 37 Sheet 38 Sheet 39 Sheet 40 Sheet 41 Sheet 42 Sheet 43 Sheet 44 Sheet 45 Sheet 46 Sheet 47 Sheet 48 Sheet 49 Sheet 50 Sheet 51 Sheet 52
66 members in 36 offices
Priority claims8
| Document | Office | Kind | Date |
|---|---|---|---|
| 0001788 | France | A | |
| 0001788 | France | A | |
| 0100441 | France | W | |
| 0100441 | France | W | |
| 0001788 | – | – | – |
| FR20000001788 | – | – | – |
| PCTFR0100441 | – | – | – |
| WO2001FR00441 | – | – | – |
Members66
| Document | Office | Kind | |
|---|---|---|---|
| CA2398699A1 | Canada | A1 | |
| DZ3267A1 | Algeria | A1 | |
| WO0158988A1 | World Intellectual Property Organization (WIPO) | A1 | |
| FR2804964A1 | France | A1 | |
| AU2001235679C1 | Australia | C1 | |
| AU3567901A | Australia | A | |
| NO20023827D0 | Norway | D0 | |
| NO20023827L | Norway | L | |
| KR20020081331A | Republic of Korea | A | |
| CZ20022699A3 | Czechia | A3 | |
| SK11762002A3 | Slovakia | A3 | |
| EP1268616A1 | European Patent Office (EPO) | A1 | |
| CN1400985A | China | A | |
| BR0108324A | Brazil | A | |
| US2003050378A1 | United States of America | A1 | |
| AR027415A1 | Argentina | A1 | |
| HU0204265A2 | Hungary | A2 | |
| MA25709A1 | Morocco | A1 | |
| BG106970AThis record | Bulgaria | A | |
| ZA200205293B | South Africa | B | |
| JP2003522267A | Japan | A | |
| EG22714A | Egypt | A | |
| HK1052715A1 | Hong Kong, China | A1 | |
| RU2002124619A | Russian Federation | A | |
| HRP20020550A2 | Croatia | A2 | |
| PL356367A1 | Poland | A1 | |
| MXPA02007738A | Mexico | A | |
| YU61102A | Yugoslavia, later Serbia and Montenegro (until 2006) | A | |
| US2005049346A1 | United States of America | A1 | |
| HU0204265A3 | Hungary | A3 | |
| NZ519880A | New Zealand | A | |
| US6951900B2 | United States of America | B2 | |
| AU2001235679B2 | Australia | B2 | |
| CN1781970A | China | A | |
| RU2278128C2 | Russian Federation | C2 | |
| CN1264899C | China | C | |
| AU2001235679B9 | Australia | B9 | |
| FR2804964B1 | France | B1 | |
| EP1268616B1 | European Patent Office (EPO) | B1 | |
| HK1052715B | Hong Kong, China | B | |
| AT343609T | Austria | T | |
| MY127072A | Malaysia | A | |
| DE60124082D1 | Germany | D1 | |
| EP1743914A2 | European Patent Office (EPO) | A2 | |
| TWI272283B | Taiwan Province of China | B | |
| HK1092826A1 | Hong Kong, China | A1 | |
| DK1268616T3 | Denmark | T3 | |
| PT1268616E | Portugal | E | |
| EP1743914A3 | European Patent Office (EPO) | A3 | |
| SI1268616T1 | Slovenia | T1 | |
| DE60124082T2 | Germany | T2 | |
| ES2274868T3 | Spain | T3 | |
| KR100856764B1 | Republic of Korea | B1 | |
| AR061813A2 | Argentina | A2 | |
| NO328581B1 | Norway | B1 | |
| PL205267B1 | Poland | B1 | |
| BG65919B1 | Bulgaria | B1 | |
| SK287391B6 | Slovakia | B6 | |
| RS50799B | Serbia | B | |
| BR0108324B1 | Brazil | B1 | |
| CA2398699C | Canada | C | |
| HRP20020550B1 | Croatia | B1 | |
| CZ302546B6 | Czechia | B6 | |
| CN1781970B | China | B | |
| JP5042424B2 | Japan | B2 | |
| HU230511B1 | Hungary | B1 |
Numbers
- Publication, DOCDB
- 106970
- Publication, EPODOC
- BG106970
- Application
- 106970
- Application, DOCDB
- 10697002
- Application, EPODOC
- BG20020106970
Titles2
- Bulgarian
- КОНЦЕНТРАТИ НА ИНЕРТНИ ПЪЛНИТЕЛИ ИЗПОЛЗУВАНИ В ТЕРМОПЛАСТИЧНИТЕ ПРОДУКТИ
- English
- INERT FILLER CONCENTRATES FOR USE IN THERMOPLASTIC PRODUCTS
Classification
- CPC, 3
- C08J3/226
- C08J3/22
- C08J2423/00
- IPC, 8
- B29B7 00
- B29K23 00
- B29K105 16
- C08J3 22
- C08J5 18
- C08K3 00
- C08L21 00
- C08L23 00