Device and method for gasifying biomass
Abstract
The invention relates to a reactor (1) for gasifying biomass, in particular wood, comprising a filling shaft (7) and an ash bed arranged below the filling shaft (7). According to the invention, provision is made for a device with which biomass adhering to the filling shaft (7) can be detached and / or a heat exchanger is provided, with which a product gas produced from the biomass heats up the biomass in the hopper (7) and to an oxidizing air emits. The invention further relates to a fine filter (29) for purifying a product gas generated from biomass. According to the invention, it is provided that the filter medium contains biomass. In addition, the invention relates to a process for the gasification of biomass in a reactor (1), in particular a reactor (1) according to the invention, to a product gas. According to the invention, it is provided that biomass adhering to the filling shaft (7) is released and / or heat is released from the product gas to biomass and an oxidation air.

Term
No projected expiry on record.
- Priority and filed
- Published
- Today
23 claims: 23 independent, 0 dependent
- 1Claims Patentansprüche 1. Reactor (1) for gasifying biomass, in particular wood, comprising a filling shaft (7) and an ash bed arranged under the filling shaft (7), characterized in that a device is provided with which biomass adhering to the filling shaft (7) can be released and / or a heat exchanger is provided with which a product gas generated from the biomass gives off heat to the biomass that is tracked in the filling shaft (7) and to an oxidation air, 1. Reaktor (1) zum Vergasen von Biomasse, insbesondere Holz, aufweisend einen Füllschacht (7) und ein unter dem Füllschacht (7) angeordnetes Aschebett, dadurch gekennzeichnet, dass eine Einrichtung vorgesehen ist, mit der am Füllschacht (7) anhaftende Biomasse lösbar ist und/oder ein Wärmetauscher vorgesehen ist, mit dem ein aus der Biomasse erzeugtes Produktgas Wärme an im Füllschacht (7) nachgeführte Biomasse sowie an eine Oxidationsluft abgibt,
- 2Reactor (1) according to Claim 1, characterized in that a multiple jacket is provided, with which heat from the product gas can be transferred to the oxidation air and the biomass that is fed in. 2. Reaktor (1) nach Anspruch 1, dadurch gekennzeichnet, dass ein Mehrfachmantel vorgesehen ist, mit welchem eine Wärme des Produktgases an die Oxidationsluft und nachgeführte Biomasse übertragbar ist.
- 3Reactor (1) according to claim 1 or 2, characterized in that a vibrating device (8) is provided with which the filling shaft (7) can be set in vibration so that adhering biomass can be detached from the filling shaft (7). 3. Reaktor (1) nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass eine Rütteleinrichtung (8) vorgesehen ist, mit welcher der Füllschacht (7) in Schwingungen versetzbar ist, sodass anhaftende Biomasse vom Füllschacht (7) lösbar ist.
- 4Reaktor (1) nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass ein Keilschieber vorgesehen ist, mit dem die Biomasse dem Füllschacht (7) zuführbar ist. 4th Reactor (1) according to one of Claims 1 to 3, characterized in that a wedge slide is provided with which the biomass can be fed to the filling shaft (7).
- 5Reactor (1) according to one of Claims 1 to 4, characterized in that a sealed feed device is provided with which the biomass can be fed to the filling shaft (7) with the exclusion of oxygen. 5. Reaktor (1) nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass eine abgedichtete Zuführeinrichtung vorgesehen ist, mit welcher die Biomasse unter Ausschluss von Sauerstoff dem Füllschacht (7) zuführbar ist.
- 6Reaktor (1) nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, dass der Füllschacht (7) in einem unteren Bereich (12) konisch zulaufend ausgebildet ist, insbesondere mit einem Verhältnis eines Füllschachtquerschnittes zu einem Feuerzonenquerschnitt von 1,2 bis 10, bevorzugt 1,4 bis 3, besonders bevorzugt etwa 1,9. 6th Reactor (1) according to one of claims 1 to 5, characterized in that the filling shaft (7) is conically tapered in a lower region (12), in particular with a ratio of a filling shaft cross-section to a fire zone cross-section of 1.2 to 10, preferably 1.4 to 3, particularly preferably about 1.9.
- 7Reaktor (1) nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, dass eine Oxidationsluftzufuhr (43) über einen Zwischenbereich und einen Oxidationsluftring (15) mit Oxidationsluftdüsen (16) verbunden ist, die in eine Feuerzone (13) münden. 7th Reactor (1) according to one of claims 1 to 6, characterized in that an oxidation air supply (43) is connected via an intermediate area and an oxidation air ring (15) with oxidation air nozzles (16) which open into a fire zone (13). • * • · · · • * · · • * • · · · • * · ·
- 8Reaktor (1) nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass ein Drehrost (18) mit mindestens einem Rührstift am Aschebett vorgesehen ist, mit dem Anpackungen von Biomasse lösbar sind. 8th. Reactor (1) according to one of claims 1 to 7, characterized in that a rotating grate (18) with at least one agitator pin is provided on the ash bed, with which packings of biomass can be detached.
- 9Reactor (1) according to Claim 8, characterized in that sensors are provided with which a pressure can be measured upstream and downstream of the ash bed in order to use data obtained during a measurement to control and / or regulate the stirring pins (19). 9. Reaktor (1) nach Anspruch 8, dadurch gekennzeichnet, dass Sensoren vorgesehen sind, mit denen ein Druck vor und nach dem Aschebett messbar ist, um bei einer Messung erhaltene Daten zu einer Steuerung und/oder Regelung der Rührstifte (19) zu verwenden.
- 10Device (2) for generating a product gas from biomass, comprising a fuel store (3) for the biomass, a reactor (1) for gasifying the biomass, at least one conveying means (4) for conveying the biomass from the fuel store (3) into the reactor (1) and at least one filter system for cleaning product gas generated from the biomass, characterized in that the reactor (1) is designed according to one of Claims 1 to 9. 10. Vorrichtung (2) zur Erzeugung eines Produktgases aus Biomasse, umfassend ein Brennstofflager (3) für die Biomasse, einen Reaktor (1) zum Vergasen der Biomasse, zumindest ein Fördermittel (4) zum Befördern der Biomasse aus dem Brennstofflager (3) in den Reaktor (1) und zumindest eine Filteranlage zum Reinigen von aus der Biomasse erzeugtem Produktgas, dadurch gekennzeichnet, dass der Reaktor (1) nach einem der Ansprüche 1 bis 9 ausgebildet ist.
- 11Device (2) according to claim 10, characterized in that at least one cyclone filter (27) is arranged downstream of the reactor (1) 11. Vorrichtung (2) nach Anspruch 10, dadurch gekennzeichnet, dass mindestens ein Zyklonfilter (27) dem Reaktor (1) nachgeschaltet angeordnet ist
- 12Vorrichtung (2) nach Anspruch 10 oder 11, dadurch gekennzeichnet, dass zumindest ein Feinfilter (29) dem Reaktor (1) nachgeschaltet ist, der Biomasse als Filtermedium beinhaltet 12th Device (2) according to claim 10 or 11, characterized in that at least one fine filter (29) is connected downstream of the reactor (1) which contains biomass as a filter medium
- 13Vorrichtung (2) nach einem der Ansprüche 10 bis 12, dadurch gekennzeichnet, dass ein Verbrennungsmotor (30) vorgesehen ist, in welchen das Produktgas leitbar ist, und der Verbrennungsmotor (30) an einen Generator (31) zur Erzeugung von elektrischer Energie gekoppelt ist. 13th Device (2) according to one of claims 10 to 12, characterized in that an internal combustion engine (30) is provided, into which the product gas can be conducted, and the internal combustion engine (30) is coupled to a generator (31) for generating electrical energy .
- 14Vorrichtung (2) nach Anspruch 13, dadurch gekennzeichnet, dass ein AbwärmeWärmetauscher (32) vorgesehen ist, mit dem eine Wärme eines Abgases des Verbrennungsmotors (30) an die Biomasse zur Vorwärmung derselben übertragbar ist 14th Device (2) according to claim 13, characterized in that a waste heat exchanger (32) is provided with which heat from an exhaust gas of the internal combustion engine (30) can be transferred to the biomass for preheating the same
- 15Feinfilter (29) zum Reinigen eines aus Biomasse erzeugten Produktgases, dadurch gekennzeichnet, dass das Filtermedium Biomasse enthält. 15th Fine filter (29) for cleaning a product gas generated from biomass, characterized in that the filter medium contains biomass. 4 · 4 4 · 4 4444 4 4444 4444 4 4444
- 16Use of a fine filter (29) according to Claim 15 for cleaning a product gas generated from biomass, in particular for separating tar. 16. Verwendung eines Feinfilters (29) nach Anspruch 15 zum Reinigen eines aus Biomasse erzeugtem Produktgases, insbesondere zur Abscheidung von Teer.
- 17Verfahren zur Vergasung von Biomasse in einem Reaktor (1), insbesondere einem Reaktor (1) nach einem der Ansprüche 1 bis 9, zu einem Produktgas, dadurch gekennzeichnet, dass am Füllschacht (7) anhaftende Biomasse gelöst und/oder vom Produktgas Wärme an Biomasse und eine Oxidationsluft abgegeben wird. 17th A method for gasifying biomass in a reactor (1), in particular a reactor (1) according to one of claims 1 to 9, to form a product gas, characterized in that biomass adhering to the filling shaft (7) is dissolved and / or from the product gas heat to biomass and an oxidizing air is discharged.
- 18Verfahren nach Anspruch 17, dadurch gekennzeichnet, dass eine 18th The method according to claim 17, characterized in that a Rütteleinrichtung (8) in bestimmten Abständen, bevorzugt in Abständen von 10 bis 30 Minuten, insbesondere 15 bis 25 Minuten, bevorzugt etwa 20 Minuten, für die Dauer von weniger als 5 Minuten, vorzugsweise weniger als eine Minute, besonders bevorzugt für etwa 5 Sekunden, aktiviert wird, um am Füllschacht (7) anhaftende Biomasse zu lösen. Vibrating device (8) at certain intervals, preferably at intervals of 10 to 30 minutes, in particular 15 to 25 minutes, preferably about 20 minutes, for a period of less than 5 minutes, preferably less than one minute, particularly preferably for about 5 seconds, is activated in order to loosen biomass adhering to the hopper (7).
- 19Verfahren nach Anspruch 17 oder 18, dadurch gekennzeichnet, dass eine Fließgeschwindigkeit der Biomasse in einem unteren Bereich (12) des Füllschachtes (7) über eine konische Ausbildung des Füllschachtes (7) in diesem Bereich etwa konstant gehalten wird. 19th Method according to Claim 17 or 18, characterized in that a flow rate of the biomass in a lower region (12) of the filling shaft (7) is kept approximately constant in this region via a conical design of the filling shaft (7).
- 20Verfahren nach einem der Ansprüche 17 bis 19, dadurch gekennzeichnet, dass in einem untersten Bereich (14) des Füllschachtes (7), insbesondere im Bereich einer Einschnürung (17), in mehr ais 50 %, insbesondere mehr als 70 %, bevorzugt mehr als 90 %, der Biomasse eine Temperatur zwischen 1000 °C und 1600 °C, insbesondere 1200 °C und 1500 °C, bevorzugt 1220 °C und 1470 °C, liegt. 20th Method according to one of Claims 17 to 19, characterized in that in a lowermost area (14) of the filling chute (7), in particular in the area of a constriction (17), in more than 50%, in particular more than 70%, preferably more than 90%, the biomass has a temperature between 1000 ° C and 1600 ° C, in particular 1200 ° C and 1500 ° C, preferably 1220 ° C and 1470 ° C.
- 21Method according to one of Claims 17 to 20, characterized in that a pressure loss over an ash bed is continuously measured and, when a predetermined limit value is exceeded, a stirring device in the ash bed is activated. 21. Verfahren nach einem der Ansprüche 17 bis 20, dadurch gekennzeichnet, dass ein Druckverlust über einem Aschebett kontinuierlich gemessen und bei Überschreiten eines vorgegebenen Grenzwertes eine Rühreinrichtung im Aschebett aktiviert wird.
- 22Verfahren nach einem der Ansprüche 17 bis 21, dadurch gekennzeichnet, dass die Oxidationsluft vom Zwischenmantel übereinen Oxidationsluftring (15) zu Luftdüsen in einem unteren Bereich (12) des Füllschachtes (7) strömt, wo eine Oxidation von Biomasse hervorgerufen wird. 22nd Method according to one of Claims 17 to 21, characterized in that the oxidation air flows from the intermediate jacket via an oxidation air ring (15) to air nozzles in a lower area (12) of the filling shaft (7), where oxidation of biomass is caused. • · • ·
- 2323 Method according to one of Claims 17 to 22, characterized in that a product gas is used to drive an internal combustion engine (30) and with this a generator (31) for generating electrical energy is driven. 23. Verfahren nach einem der Ansprüche 17 bis 22, dadurch gekennzeichnet, dass ein Produktgas zum Antrieb eines Verbrennungsmotors (30) genutzt wird und mit diesem ein Generator (31) zum Erzeugen elektrischer Energie angetrieben wird. 5 24. The method according to claim 23, characterized in that a heat one 5 24. Verfahren nach Anspruch 23, dadurch gekennzeichnet, dass eine Wärme eines Abgases des Verbrennungsmotors (30) zum Vorwärmen der Biomasse genutzt wird. Exhaust gas from the internal combustion engine (30) is used to preheat the biomass.
Independent claims23
86 paragraphs, as filed
Device and method for gasifying biomass
The invention relates to a reactor for gasifying biomass, in particular wood, having a filling shaft and an ash bed arranged under the filling shaft.
The invention also relates to a fine filter for cleaning a product gas generated from biomass.
The invention also relates to a use of such a fine filter.
The invention further relates to a method for gasifying biomass in a reactor, in particular in a reactor of the type mentioned at the outset, to form a product gas.
Biomass gasifiers are known as such from the prior art. For example, from WO 2008/004070 A1 a device is known with which biomass such as wood, straw or biological waste is gasified in a reactor and a resulting gas is then passed into a gas-powered motor, where this gas is converted into mechanical energy by combustion . The motor is connected to a generator with which the mechanical energy is converted into electrical energy.
Devices of the prior art have the disadvantages that the system efficiency is only low, since on the one hand product gas exits the reactor at high temperatures, which affects the efficiency of a downstream internal combustion engine, on the other hand the consistency of the biomass often leads to sticking in the reactor, so that frequent and expensive maintenance is the result. Furthermore, the high expenditure for the disposal of filter media that are required for product gas cleaning also has a negative effect on the system efficiency.
The object of the invention is to eliminate or reduce the disadvantages of the prior art by specifying a reactor with which a more efficient process is possible.
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In addition, a fine filter is to be specified which further increases the efficiency of such a method.
The aim is also to specify a use of such a fine filter.
Furthermore, a method is to be specified which eliminates or reduces the disadvantages of the prior art.
The first object is achieved according to the invention in that a device is provided in a reactor of the type mentioned at the beginning with which biomass adhering to the filling shaft can be detached and / or a heat exchanger is provided with which a product gas generated from the biomass is fed heat to the filling shaft Releases biomass as well as to an oxidizing air.
Since the biomass has to be moved through the filling shaft from a first end to a second end at a flow rate during operation, biomass adhering to the filling shaft prevents movement and thus proper operation. An advantage of the device with which biomass adhering to the filling shaft can be removed can therefore also be seen in particular in the fact that downtimes during which the reactor has to be shut down for maintenance purposes can be significantly reduced. This increases the system efficiency for a system operator.
The heat exchanger, with which the heat of the product gas can be transferred to the biomass fed into the filling shaft as well as the oxidation air, also has the particular advantage that the energy required for pyrolysis and preheating of the oxidation air can be taken from the product gas, so that less Energy has to be taken from the biomass and a temperature of the product gas can be reduced. When the product gas is in a
Internal combustion engine is processed further directly, a lower temperature increases pure thermodynamic efficiency in the internal combustion engine. A heat transfer from the product gas to oxidizing air and biomass thus has several positive effects on the system efficiency.
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It is advantageous that a multiple jacket is provided, with which heat from the product gas can be transferred to the oxidation air and the biomass that is fed in. In addition to a mechanically load-bearing function, this multiple jacket thus also fulfills the function of the heat exchanger, which means that the reactor can be manufactured particularly inexpensively. The multiple jacket is preferably designed in such a way that it has several, approximately concentric, approximately cylindrical jackets, with product gas between a first jacket, which forms the filling chute, and a second jacket, which encloses the first jacket, in the case of a preferred vertical installation due to the thermal buoyancy can flow from the bottom to the top and a third jacket is arranged around this second jacket in such a way that that the area between the second jacket and the third jacket can be flowed through by oxidizing air. In this way, heat can be transferred from the product gas via the first jacket or to biomass in the filling shaft and via the second jacket to oxidizing air and the temperature of the product gas can be minimized until it exits the multiple jacket. The multiple jacket is preferably made of steel, the first jacket, which borders on the one hand on the biomass and on the other hand on the product gas, preferably consists of temperature and acid-resistant material, for example an austenitic chromium-nickel-molybdenum steel. The second jacket, which adjoins the oxidizing air and the product gas, is preferably made from heat-resistant steel only in a lower area and from a normal boiler plate in an upper area in order to minimize manufacturing costs. It is advantageous if an insulating layer made of a heat-insulating material is applied around the third jacket, which is preferably also made of steel, in order to prevent heat from the oxidizing air from being given off to the environment.
In order to reduce maintenance times, it is particularly advantageous that a
A vibrating device is provided, with which the filling shaft can be made to vibrate, so that adhering biomass can be detached from the filling shaft. Due to the broad spectrum of possible constituents and possible consistencies of the biomass, biomass can adhere to the filling shaft during operation, which can severely impair the functionality of the reactor. In order to loosen any adhering biomass in a particularly favorable manner, the filling shaft can be made to vibrate by means of the vibrating device. The vibrating device can consist of a motor and an unbalance connected to the motor or other electromagnetic • · • · · · or mechanical devices, with vibrations from the
Vibrating device are preferably transferable to the hopper by means of shaped tubes.
These shaped tubes can form a direct connection between the vibrating device and the filling chute; However, it can also be provided that the vibrating device is indirectly connected to the filling shaft via flexible connecting elements.The connection between the vibrating device and filling shaft is preferably designed in such a way that temperature-related mechanical stresses in the entire reactor are minimized and the filling shaft is permanently sealed. The vibrating device is preferably activated at regular intervals of between 10 and 30 minutes, preferably between 15 and 25 minutes, particularly preferably of about 20 minutes for a period of a few seconds, preferably for about 5 seconds.
It has been proven that a wedge slide is provided with which the biomass can be fed to the filling shaft. In this way, the biomass can be fed to the filling shaft in a particularly simple and energy-efficient manner. The wedge slide preferably comprises a slide plate which is guided in a linearly movable manner in a groove of a frame rigidly connected to the filling chute. The wedge slide and the frame are preferably components of a sluice via which the biomass is fed to the filling shaft. The connection of the slide plate to the frame is preferably carried out in a particularly low-wear manner via one or more ball bearings. Other types of storage are also possible. Due to the acidic atmosphere in the hopper, the entire wedge slide or parts thereof are made of an acid-resistant material, preferably an acid-resistant steel.
It is advantageous that a sealed feed device is provided with which the biomass can be fed to the filling shaft with the exclusion of oxygen. This is particularly important in order not to allow any undesired gases, in particular oxygen, to enter the filling shaft in order to be able to trigger chemical reactions in the filling shaft in a targeted manner, which are dependent on a controlled or regulated air ratio.
It is preferably provided that the filling chute is designed to taper conically in a lower region, in particular with a ratio of one
Filling chute cross-section to a fire zone cross-section of 1.2 to 10, preferably 1.4 • · · * ·· ·· * ·· »·· ·· ·« «« · «* · * ·« «« ·· * · «♦ »· · To 3, particularly preferably about 1.9. In this calculation, the
Filling shaft cross-section in a cylindrical upper area of the filling shaft and the fire zone cross-section measured in a fire zone. Since the biomass changes its volume during the pyrolysis taking place in this lower area when moving through the lower area, it is advantageous if the filling shaft is adapted to a change in volume of the biomass in order to ensure a uniform flow rate of the biomass and optimal conditions for the chemical that is running off Enable processes. A cone angle between a cone axis and a lateral surface of the conically designed lower region is preferably between 20 ° and 60 °, particularly preferably between 30 ° and 50 °, in particular approximately 40 °. While the fire zone adjoining this conical area is preferably cylindrical, a lowest area further adjoining the fire zone between the fire zone and a constriction is preferably also conical in order to constructively take account of a change in volume of the biomass in this lowest area as well. A cone angle of this lowermost region is preferably between 20 ° and 60 °, particularly preferably between 30 ° and 50 °, in particular approximately 40 °. This cone angle can also correspond to the cone angle of the lower area.
It has been proven that an oxidizing air supply is connected via an intermediate area and an oxidizing air ring with oxidizing air nozzles which open into a fire zone. The oxidation air can be preheated both in the intermediate area, which is preferably thermally connected to a product gas area, and in the oxidation air ring, which is preferably thermally connected to the fire zone. Preheating of the oxidation air is thus made possible in a particularly favorable manner. Another advantage can also be seen in the fact that the oxidizing air can enter the fire zone evenly over a circumference and thus can be evenly distributed in the fire zone.
An air outlet speed at the oxidation air nozzles, which has a high influence on a chemical reaction in the fire zone, can be influenced particularly favorably via a cross section of the oxidation air nozzles and an air pressure. A higher air outlet speed results in a higher temperature in the fire zone, but the spatial expansion of a glow zone is smaller. Depending on the composition and the calorific value of the biomass, an optimal • * • «• ·» * ♦ ft · «
Change the air inlet cross-section. It has proven particularly useful that a sum of all cross-sections of the oxidation air nozzles corresponds to between 1% and 10%, preferably between 2% and 8%, in particular approximately 4%, of a constriction cross-section. The constriction cross-section is that cross-section of the filling shaft at which the biomass can escape from the filling shaft to the ash bed.
It has been proven that the oxidation air nozzles are evenly distributed over a circumference of the fire zone in such a way that there is a distance of between 2 and 30 cm, preferably between 5 and 20 cm, in particular about 10 to 12 cm, between each two oxidation air nozzles on the circumference of the fire zone . The oxidation air nozzles are preferably arranged in one plane, but an arrangement in several planes is also possible. Depending on the circumference of the fire zone, this results in a particularly favorable number of oxidation air nozzles for the chemical reaction in the fire zone and a favorable air speed.
It can be preferred that a rotating grate with at least one agitator pin is provided on the ash bed, with which packings of biomass can be detached. The rotating grate enables the biomass to burn evenly and also serves to discharge ash into an ash bin below. The rotating grate is preferably driven by means of a linear motor via a drive linkage. Other types of drive are also possible. The drive linkage is preferably sealed in a gas-tight manner by means of a stuffing box which has a temperature-resistant graphite sealing cord for creating a seal. The at least one agitator pin enables biomass gripping the rotating grate to be released in a particularly favorable manner.
It has been proven that sensors are provided with which a pressure can be measured upstream and downstream of the ash bed in order to use data obtained during a measurement to control and / or regulate the stirring pins. With this arrangement, packings of biomass on the rotating grate are particularly easy to recognize, since packings lead to an increased difference between a pressure before and a pressure after the rotating grate. In this way, the stirring pins can be activated precisely when further handling would lead to problems and wear and tear on the stirring pins can be minimized.
In order to produce a product gas from biomass, it is advantageous that in a device for producing a product gas from biomass, comprising a fuel store for the biomass, a reactor for gasifying the biomass, at least one conveying means for conveying the biomass from the fuel store into the reactor and at least one filter system for cleaning product gas generated from the biomass, the reactor being designed according to the invention.
This means that biomass can be transported fully automatically from a fuel store into the reactor and the product gas can then be cleaned in a filter system. In particular, due to the particularly efficient reactor, the system efficiency of the entire device is better than with devices of the prior art,
It is preferably provided that at least one cyclone filter is arranged downstream of the reactor. The product gas is freed of dust and fly ash in the cyclone filter, so that the product gas is of higher quality for further use. Three cyclone filters connected in parallel are preferably provided, with only one cyclone filter or more than three cyclone filters also being possible. Several cyclone filters can be arranged in parallel or in series so that gas can flow through them, a cyclone filter ash container being arranged such that an ash that can be separated in the at least one cyclone filter is preferably automatically passed into the cyclone filter ash container. If the cyclone filter ash container is arranged below the cyclone filter, this is particularly easy. The functionality of the cyclone filter is known and is based on a centrifugal force with which dust and fly ash in the cyclone filter are pushed outwards.
It is advantageous that at least one fine filter is connected downstream of the reactor, which contains biomass as the filter medium. This fine filter can be connected downstream of the cyclone filter, as it can also be used to remove smaller particles and tar residues.
It is advantageous that an internal combustion engine is provided in which the
Product gas can be conducted, and the internal combustion engine is coupled to a generator for generating electrical energy. As an alternative to the internal combustion engine, another internal combustion engine, for example a gas turbine, can also be provided.
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This means that biomass can be converted fully automatically into electrical energy with the device.
It is preferably provided that a waste heat heat exchanger is provided with which heat from an exhaust gas of the internal combustion engine can be transferred to the biomass for preheating the same. This further increases the efficiency of the system as a whole, since the heat from the exhaust gas from the internal combustion engine can also be reused. Of course, it is also possible to use the heat of the exhaust gas from the internal combustion engine for other purposes, for example for heating purposes.
The second object is achieved according to the invention in that a fine filter of the type mentioned at the beginning contains biomass as the filter medium. This biomass can preferably contain wood chips according to ÖNORM M7133 G50 or G30 as well as sawdust. The advantage of this design is that the filter medium can be transported to the fuel store after a long period of use and processed like biomass in the reactor, so that this filter medium can be recycled in the simplest possible way. The product gas flows through this filter medium in the fine filter, preferably from bottom to top, with impurities in the product gas, in particular tar, being deposited on the biomass. The biomass can be stored on one or more levels. A sensor can also be provided which measures a pressure loss across the filter and thus determines the optimal point in time for transferring the contaminated biomass to the fuel store and for filling the filter with new biomass. Alternatively, a time-based refilling with biomass is possible.
Instead of wood chips and sawdust, another type of solid biomass can of course also be used, with the filtration effect changing with the filter medium. It is advantageous that the filter medium lies on several levels in the filter on porous perforated bases, preferably perforated metal sheets, and the product gas can flow through it in series from bottom to top. A bottom layer has around 20% wood chips and around 80% sawdust and a top layer has around 70% wood chips and around 30% sawdust. In the intermediate layers, a proportion of wood chips lies above that of the bottom layer and rises to the top layer. It is preferred that wood chips and sawdust are made from spruce wood.
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The third object is achieved in that a filter according to the invention is used for cleaning a product gas generated from biomass, in particular for separating tar. A particularly cost-effective and environmentally friendly type of product gas cleaning can thus be achieved.
The fourth object is achieved according to the invention in that in a method of the type mentioned at the beginning, biomass adhering to the filling shaft is dissolved and / or heat is given off from the product gas to biomass and an oxidation air.
By loosening, in particular intermittently, biomass adhering to the filling shaft, contamination of the filling shaft with biomass, which would severely impair its function, can be avoided. This can reduce maintenance times and increase system efficiency. A transfer of heat from the product gas to biomass and an oxidation air can minimize the amount of energy that leaves the reactor in the form of heat in the product gas.
It is preferably provided that a vibrating device at certain intervals, preferably at intervals of 10 to 30 minutes, in particular 15 to 25 minutes, preferably about 20 minutes, for a duration of less than 5 minutes, preferably less than 1 minute, particularly preferably for about 5 seconds, is activated in order to loosen biomass adhering to the filling shaft. In this way, on the one hand, adhering impurities can be loosened particularly favorably and, on the other hand, mechanical stresses on a material due to vibrations remain minimal, so that the reactor has a long service life.
It is advantageous that a flow rate of the biomass in a lower area of the filling shaft is kept approximately constant in this area via a conical design of the filling shaft. Since the biomass in the lower region changes its volume due to chemical reactions, a conical design of the filling shaft has an effect , which leads to an even flow rate, is particularly beneficial
Framework conditions for these chemical reactions such as pressure or temperature.
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It is advantageous that in a lowermost area of the filling shaft, in particular in the area of a constriction, in more than 50%, in particular more than 70%, preferably more than 90% of the biomass, a temperature between 1000 ° C. and 1600 ° C., in particular 1200 ° C and 1500 <sup>D.</sup>C, preferably 1220 ° C and 1470 ° C. Cracking of long-chain hydrocarbons (tars) can thus be ensured and accumulation of long-chain hydrocarbons in pipelines and in any downstream internal combustion engine can be avoided or at least reduced.
It has been proven that a pressure loss over an ash bed is continuously measured and a stirring device in the ash bed is activated when a predetermined limit value is exceeded. In this way, packings of biomass on the ash bed or on a rotating grate can be recognized and detached so that the device can be guaranteed to function.
It is advantageous that the oxidizing air flows from an intermediate jacket via an oxidizing air ring to air nozzles in a fire zone, where the biomass is oxidized. This ensures that the oxidation air is sufficiently preheated so that higher product gas temperatures are achieved after the oxidation zone. The air can enter the fire zone evenly distributed via the oxidation air ring and the oxidation air nozzles, so that even temperatures are achieved.
It is advantageous if a product gas is used to drive an internal combustion engine and a generator for generating electrical energy is driven with this. A fully automatic conversion of chemical energy stored in biomass into electrical energy can thus be achieved in a particularly simple manner.
It is preferably provided that heat from an exhaust gas of the internal combustion engine is used to preheat the biomass. The efficiency of the method can thus be increased further, since waste heat from the internal combustion engine is fed back into the method. Alternatively, this waste heat could also be used for heating purposes or other thermal processes.
• · ··*· «« · ·♦*·· * * * «··»· « * »
4 * · · · · · · * » · ·
Further features, advantages and effects of the invention emerge from the exemplary embodiment shown below. In the drawings to which reference is made:
1 shows a schematic representation of a reactor according to the invention for gasifying biomass;
Fig. 2 is a schematic representation of a device for generating a
Product gases from biomass;
3 shows a representation of a fine filter with biomass as the filter medium.
1 shows a schematic representation of a reactor 1 for gasifying biomass, in particular wood. Via a sluice 6, the biomass can be introduced into the reactor 1 or a filling shaft 7 with a wedge slide valve at the top, which is sealed gas-tight by means of a temperature-resistant graphite sealing cord in order to be able to precisely control the oxygen content in the reactor 1. The wedge slide is designed with position sensors so that the current position of a slide plate can be recorded at any time for automatic operation. The slide plate is driven by an electric motor. Attached to the side of the reactor 1 is a vibrating device 8 with which biomass adhering to the filling shaft 7 can be detached. For this purpose, a vibrating movement can be transmitted from the vibrating device 8 to the filling chute 7 via one or more shaped tubes 9. It is also possible to transfer the vibrating movement with other structural components instead of a shaped tube 9, for example mechanically softer or stiffer components, in order to achieve an optimal vibrating result. In the reactor 1 shown in the exemplary embodiment, the vibrating device 8 is activated regularly every 20 minutes for about 5 seconds in order to loosen adhering biomass from the filling shaft 7. The choice of longer intervals between the shaking intervals and longer shaking intervals are just as possible as the choice of shorter times for these intervals. It is also possible to regulate the vibrating device 8 via a sensor which detects a volume or a mass of adhering biomass and activates the vibrating device 8 in a coordinated manner. Alternatively, it is also possible to remove adhering biomass using other mechanical methods, such as direct or indirect exposure to a solid, liquid or gaseous medium.
« ·
Mt «« 4 · • I · · · · · »• · · ·« <«·« k. 4 * · »• · * ·« * - · · ♦ ί »
The filling chute 7 is formed by a first jacket 23 in which the biomass is moved during operation from a first end in an upper region 10 to a constriction 17 by means of gravity. Chemical processes take place in the biomass during movement. Due to the chemical processes and the chemical constituents that arise in the process, the first jacket 23 is made at least in the lower region 12 from an austenitic chromium-nickel-molybdenum steel. Alternatively, other heat and acid-resistant materials can be used. The first jacket 23, which is cylindrical in the upper region 10 and a central region 11, is enclosed by a second jacket 24 lying concentrically therewith. This second jacket 24 is further enclosed by a third jacket 25 lying concentrically therewith. On an outer side of the third jacket 25, an insulating layer 26 consisting of heat insulating material is arranged, which minimizes heat emission from oxidizing air to an environment. The first jacket 23, second jacket 24 and third jacket 25, which are preferably made of steel, are essentially rotationally symmetrical, and the second jacket 24 and third jacket 25 are essentially continuously cylindrical. In the lower region 12 and a lowermost region 14 of the filling chute 7, the first casing 23 is partially conical, an angle between a cone axis and a cone casing being approximately 40 °. The conical design is interrupted by a cylindrically designed fire zone 13 and ends at a constriction 17 at which the biomass can emerge from the filling shaft 7 to an ash bed during operation. A constriction ratio of a fire zone cross section to a filling chute cross section is approximately 1: 1.9, the constriction ratio being formed with the cross section of the filling chute 7 in the cylindrical upper region 10. This constriction ratio and the angle are dependent on a composition of the biomass and can also be smaller or larger depending on the application. The constriction ratio is about 1: 1.8 for softwood as a main component of the biomass and about 1: 2 for hardwood as a main component of the biomass. However, this can change upwards or downwards depending on the biomass used or the type of wood used. Constriction ratios of 1: 4 to 1: 1.1 are also possible, depending on the application.
In the lower region 12 of the filling shaft 7, an oxidation air ring is arranged around the filling shaft 7, which ring is connected to the intermediate region via a compensator which can compensate for thermal expansions. From the oxidation air ring 15 protrude for fr • fr fr · t fr fr fr · fr fr fr fr fr fr fr fr · fr fr fr fr *
Oxidation air nozzles 16 in one plane in the fire zone 13. In the exemplary embodiment, the number of oxidation air nozzles 16 is selected such that a circumferential distance of about 10 to 12 cm remains between the centers of the oxidation air nozzles 16 over a circumference of the fire zone 13. The cross section of the oxidation air nozzles 16 is selected such that the sum of all cross sections corresponds to approximately 4% of a constriction cross section. However, the function is also given at least to a limited extent with other cross-sectional ratios, for example 1% to 20%, or distances between the oxidizing air nozzles 16, for example 1 to 30 cm. The constriction cross-section is the smallest cross-section of the feed chute 7 through which the biomass exits from the feed chute 7 to the ash bed.
Below the constriction 17 is the ash bed on which the biomass falls after it has passed through the reactor 1. The ash bed comprises a rotating grate 18, which is connected to a motor, preferably a linear motor 20, via a drive linkage and can be driven by this. A gas-tight implementation of the drive linkage from the rotating grate 18 to the motor located outside the reactor 1 is achieved via a stuffing box which is equipped with a temperature-resistant
Graphite sealing cord is sealed.
On the rotating grate 18 stirring pins 19 are arranged with which biomass adhering to the rotating grate 18 can be detached. Adhering biomass prevents ash from being discharged into an ash bin 21 arranged below the rotating grate 18 and, due to an increased pressure loss on the rotating grate 18, prevents the product gas from flowing out unhindered. The optimum point in time at which the agitator pins 19 are activated and biomass is released from the rotating grate 18 is determined by measuring the pressure difference. As a result, a function of the reactor 1 is also constantly monitored.
In a space between the first jacket 23 and the second jacket 24, a product gas flows from the constriction 17 upwards out of the reactor 1 during operation. In the space between the second jacket 24 and the third jacket 25, an oxidation air flows from an oxidation air supply 43 to an oxidation air ring 15. In the filling chute 7 there is biomass, which is brought into the filling chute 7 by the wedge slide and runs through it from top to bottom. The product gas gives heat via the first jacket 23 to the biomass located in the filling shaft 7 and via the second jacket 24 to the • · · ·
Oxidation air from. Biomass adhering to the filling shaft 7 is released in that the vibrating device 8 is activated for 5 seconds every 20 minutes. The biomass is dried and preheated in the upper area 10 of the filling shaft 7 by the heat of the product gas. In the middle area 11, the pyrolysis begins, during which, in the course of thermal decomposition, organic acids such as acetic acid, methyl alcohol and tar are formed. Furthermore, hemicellulose, which is contained in the biomass, if at all, decomposes in this central region 11 at a temperature of 200 ° C. to 300 ° C. With further heating, the cellulose contained in the biomass between 325 ° C and 375 ° C is broken down and carbon dioxide, methane and organic acids, especially acetic acid, are formed. If the temperature continues to rise above 375 ° C, lignin breaks into smaller chemical compounds. Hydrocarbons and tars are also obtained in this central area 11. Oxidation of the biomass begins in a lower region 12 of the filling chute 7. A continuous flow rate and a high pressure, which are achieved in this area due to a decreasing solid volume of the biomass via the conical design of the filling shaft 7, are necessary in order to ensure an optimal course of oxidation. In the fire zone 13, the biomass is supplied with the oxidizing air via the oxidizing air nozzles 16 and carbon and hydrogen burn substoichiometrically, releasing energy. The temperature is around 650 ° C to 850 ° C, with carbon dioxide, water and methane being produced. A temperature range can be controlled particularly favorably via the amount of oxidizing air supplied and the speed at which the oxidizing air penetrates. A chemical reduction takes place below the fire zone 13 in the lowermost area 14 of the hopper 7. Here the formation of flammable gas is made possible, among other things, by gasifying carbon. In this lowermost area 14, the intermediate products formed during the oxidation, such as carbon dioxide and water, are reduced at hot spots, with carbon monoxide, hydrogen and higher
Hydrocarbons are formed. Due to the special design of the reactor 1 in this lowest area 14, ideal temperatures between 1220 ° C. and 1470 ° C. are reached here, in particular also in the area of the constriction 17, which are close to the ash melting point of the biomass. A restricted function is also possible in a temperature range from 1000 ° C to 1600 ° C. Due to the conical design of the filling chute 7 in the lowermost area 14, a constant temperature can be achieved over a large part of the volume of the biomass, particularly in the area of the constriction 17, with which long-chain cracking can be achieved
Hydrocarbons (tars) are guaranteed and the accumulation of tars, especially in pipelines, is minimized. Due to the temperatures close to an ash melting point of biomass, biomass adhering to the rotating grate 18 occurs during operation and is loosened with the stirring pins 19. Since the right choice of stirring intervals or Pauses between the stirring intervals is relevant in order to achieve an optimal result of the chemical reaction in the reduction zone, the stirring pins 19 are actuated exactly to the extent necessary to loosen adhering biomass. For this purpose, a pressure difference is measured upstream and downstream of the rotating grate 18 and these values are used to regulate the stirring sticks 19. By means of a movement of the rotating grate 18, ash is discharged particularly favorably into the ash bin 21, from where it is automatically conveyed by means of an ash conveyor 22 into an ash storage container 42. This process results in a gas yield of up to 2 standard cubic meters of product gas per kilogram of biomass supplied.
FIG. 2 shows a device 2 in which the reactor 1 is embedded in order to generate a product gas from biomass. The biomass can be transported from a fuel store 3 into the reactor 1 by means of a conveying means 4 via a biomass dryer 5. A gas outlet of the reactor 1 is connected to cyclone filters 27, where the product gas can be freed from dust and fly ash. Three parallel cyclone filters 27 are provided, through which gas can flow uniformly and in parallel. In the cyclone filters 27, the product gas can be guided in a circular path at a very high speed, so that, due to a centrifugal force, dust and ash are pressed radially outward, from where they are pushed down into one
Cyclone filter ash container 28 can be discharged.
Downstream of the cyclone filter 27 is a fine filter 29 in which the product gas is cleaned by means of wood chips and sawdust. A particular advantage of the wood chips as filter material in this fine filter 29 is that the wood chips, after they are saturated with impurities, can be fed to the fuel storage room and can thus be recycled directly. There is no filter waste in this way. The fine filter 29 is preferably designed in such a way that the product gas flows through it from bottom to top during operation, and dirt and tar can accumulate on the wood chips. A pressure sensor can be provided by means of which an optimal point in time for emptying this filter can be determined. Alternatively, purely time-based emptying of the filter would also be possible.
A gas outlet of the fine filter 29 is connected to a four-cylinder Otto engine or, in general, an internal combustion engine 30, which drives a generator 31 and can thus convert the energy of the gas into electrical energy. Alternatively, it is also possible to use a gas turbine or other machines that can convert the chemical energy of a product gas into mechanical energy and then into electrical energy. Downstream of the gas engine is a waste heat exchanger 32, which uses waste heat from the gas engine to preheat the biomass and for any heating purposes. A biomass preheating line 33 can also be seen in FIG. 2, of which at least part of the residual heat of the product gas can be used for preheating biomass in the biomass dryer 5. A heat store 34 is also provided for intermediate storage of waste heat.
The method for cleaning product gas obtained from biomass as well as further processing into electrical energy works with the device 2 in such a way that the biomass is fed from the fuel store 3 by means of the conveyor 4 via the lock 6 to the filling shaft 7. The biomass is then gasified into product gas in reactor 1 as described above. After exiting reactor 1, the product gas is cleaned in cyclone filters 27 and in fine filter 29 before it is fed into internal combustion engine 30. There the chemical energy of the gas is converted into mechanical energy, which is then converted into electrical energy in a generator 31. When the product gas is burned, the gas engine is regulated to an air ratio of lambda equal to 1.15. This achieves particularly favorable pollutant values in the exhaust gas. Waste heat from the internal combustion engine 30 is given off to a heat transfer medium via the waste heat exchanger 32 and partially stored in the heat accumulator 34 for heating purposes and partly used via the biomass preheat line 33 to dry the biomass in the biomass dryer 5 before it enters the reactor 1. A high maintenance and disposal expenditure is avoided in this method in that the filling shaft 7 is regularly freed of adhering biomass by shaking and the filling shaft 7 by regular shaking
<img file="AT511684A1_D0001.tif" />
Stirring with stirring pins 19 is cleaned of packings and that contaminated wood chips in the fine filter 29 are recycled in a particularly favorable manner by being returned to the fuel store 3.
3 shows a representation of the fine filter 29 in which biomass is used as the filter material. The product gas can enter the fine filter 29 via a product gas inlet 35 at a lower end. The filter medium is distributed over four layers 38, 39, 40, 41 on perforated floors 37 through which the product gas can flow. The perforated bottoms 37 are preferably formed from metal sheets with a large number of bores, but a different type of porous bottom can also be selected, which is preferably designed to be temperature-resistant. Alternatively, it is of course also possible to use only a single layer or to use more than four layers. The product gas flows through the fine filter 29 during operation from the bottom to the top and flows in series through the individual levels until it leaves the fine filter 29 cleaned at the product gas outlet 36. When flowing through the individual layers, particles in the product gas, in particular tars, dust and impurities, are largely attached to the filter material. The filter medium in layer 38 consists of 20% wood chips and 80% sawdust, the filter medium in layer 39 consists of 30% wood chips and 70% sawdust, the filter medium in layer 40 consists of 50% wood chips and 50% from sawdust and the filter medium in layer 41 is made up of 70% wood chips and 30% sawdust. Wood chips and sawdust are preferably made from spruce wood, but the use of other types of biomass is also conceivable, the filter performance depending on the biomass used. A particular advantage of using biomass as a filter medium is that the biomass after contamination in the fine filter 29 can be fed to the fuel store 3 and can thus be recycled in the simplest possible way. An optimal point in time for replacing the filter media due to contamination can be determined by measuring the pressure difference, with a pressure loss across the fine filter 29 being measured. Alternatively, a purely time-dependent exchange of the filter media is also possible. If the filter media are replaced depending on the time, it is recommended to replace them after about 100 hours of operation.
9 sheets
Sheet 1 Sheet 2 Sheet 3 Sheet 4 Sheet 5 Sheet 6 Sheet 7 Sheet 8 Sheet 9
Every citation, both ways
| Document | Relation | Office | Cited during |
|---|---|---|---|
| JP2009242696A | Cites | Japan | Search report |
| US4583992A | Cites | United States of America | Search report |
12 members in 11 offices
Priority claims2
| Document | Office | Kind | Date |
|---|---|---|---|
| 10332011 | Austria | A | |
| AT20110001033 | – | – | – |
Members12
| Document | Office | Kind | |
|---|---|---|---|
| AT511684A1This record | Austria | A1 | |
| CA2841898A1 | Canada | A1 | |
| WO2013006877A1 | World Intellectual Property Organization (WIPO) | A1 | |
| AT511684B1 | Austria | B1 | |
| AU2012283719A1 | Australia | A1 | |
| CN103797095A | China | A | |
| EP2732011A1 | European Patent Office (EPO) | A1 | |
| US2014290593A1 | United States of America | A1 | |
| JP2014527095A | Japan | A | |
| RU2014105490A | Russian Federation | A | |
| IN256MUN2014A | India | A | |
| BR112014000781A2 | Brazil | A2 |
1 legal event, as the office reported them to INPADOC
Events
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|---|---|---|
| Lapse because of not paying annual feesLapsedMM01 | MM01 |
Numbers
- Publication
- 511684
- Publication, DOCDB
- 511684
- Publication, EPODOC
- AT511684
- Application
- 1033
- Application, DOCDB
- 10332011
- Application, EPODOC
- AT20110001033
Titles2
- English
- DEVICE AND METHOD FOR GASIZING BIOMASS
- German
- VORRICHTUNG UND VERFAHREN ZUM VERGASEN VON BIOMASSE
Classification
- CPC, 36
- C10J3/72
- C10J3/26
- B01D39/163
- B01D39/04
- B01D2239/0407
- B01D2239/1233
- B01D2239/1241
- C10J3/30
- C10J3/32
- C10J3/42
- C10J3/84
- C10J2200/15
- C10J2300/0916
- C10J2300/092
- C10J2300/0956
- C10J2300/1671
- C10J2300/1869
- C10J2300/1884
- C10K1/024
- C10K1/026
- C10K1/20
- F23G5/0276
- F23G5/14
- F23G5/26
- F23G5/28
- F23G5/46
- F23G5/50
- F23G7/105
- F23G2206/10
- F23G2206/203
- F23G2207/102
- Y02E20/12
- Y02P20/129
- Y02P20/145
- Y02T10/12
- Y02T10/16
- IPC, 1
- C10J3 74