Process for the manufacture of branched polypropylene
Abstract
Process for the manufacture of a branched polypropylene having a branching index g 'of less than 1.00, wherein the process comprises the step polymerizing propylene and optionally another (s) comonomer (s) under non-supercritical conditions in a reaction vessel, characterized in that a. The pressure during the polymerization of propylene and optionally another (s) comonomer (s) in said reaction vessel is at least 45,4 bar, b. The temperature during the polymerization of propylene and optionally another (s) comonomer (s) in said reaction vessel is below 90 and c. The polymerization of propylene and optionally another (s) comonomer (s) is conducted in said reaction vessel in the presence of a catalyst system having a not greater surface area of 350 m 2 / g measured according to ISO 9277 and said catalyst system comprises a metallocene catalyst having zirconium as the transition metal and wherein the metallocene catalyst has the formula (I): wherein z is 0 or 1, (Cp) 2R zZrX 2 X is independently a monovalent anionic ligand, R is a bridging group linking the two Cp ligands, and the two Cp-ligands are selected independently of one another from the group consisting of cyclopentadienyl ring unsubstituted indenyl ring, unsubstituted ring tetrahydroindenyl, unsubstituted fluorenyl ring unsubstituted , substituted cyclopentadienyl ring, substituted indenyl ring, substituted tetrahydroindenyl ring, and substituted fluorenyl ring, and said Cp-ligands differ in their chemical structure.
Term
No projected expiry on record.
- Priority and filed
- Granted
- Today
20 members in 10 offices
Members20
| Document | Office | Kind | |
|---|---|---|---|
| EP1939230A1 | European Patent Office (EPO) | A1 | |
| WO2008080886A1 | World Intellectual Property Organization (WIPO) | A1 | |
| EP1939230B1 | European Patent Office (EPO) | B1 | |
| AT424424TThis record | Austria | T | |
| ATE424424T1 | Austria | T1 | |
| DE602006005508D1 | Germany | D1 | |
| ES2322186T3 | Spain | T3 | |
| KR20090083488A | Republic of Korea | A | |
| EP2097461A1 | European Patent Office (EPO) | A1 | |
| US2009264606A1 | United States of America | A1 | |
| CN101568558A | China | A | |
| RU2009128975A | Russian Federation | A | |
| US7915367B2 | United States of America | B2 | |
| RU2421476C2 | Russian Federation | C2 | |
| CN101568558B | China | B | |
| KR101118950B1 | Republic of Korea | B1 | |
| EP2097461B1 | European Patent Office (EPO) | B1 | |
| AT552279T | Austria | T | |
| ATE552279T1 | Austria | T1 | |
| BRPI0720864A2 | Brazil | A2 |
1 legal event, as the office reported them to INPADOC
Events
| Event | Code | |
|---|---|---|
| Ceased as to paragraph 5 lit. 3 law introducing patent treatiesCeasedRER | RER |
Numbers
- Application
- 6027007
Titles2
- German
- VERFAHREN ZUR HERSTELLUNG VON VERZWEIGTEM POLYPROPYLEN
- English
- PROCESS FOR PREPARING BRANCHED POLYPROPYLENE
Classification
- CPC, 8
- C08F10/00
- C08F4/65912
- C08F4/65916
- C08F10/06
- C08F110/06
- C08F210/06
- Y02P20/544
- Y02P20/54
- IPC, 2
- C08F10 06
- C08F2 06