AT424424T

Process for the manufacture of branched polypropylene

Abstract

Process for the manufacture of a branched polypropylene having a branching index g 'of less than 1.00, wherein the process comprises the step polymerizing propylene and optionally another (s) comonomer (s) under non-supercritical conditions in a reaction vessel, characterized in that a. The pressure during the polymerization of propylene and optionally another (s) comonomer (s) in said reaction vessel is at least 45,4 bar, b. The temperature during the polymerization of propylene and optionally another (s) comonomer (s) in said reaction vessel is below 90 and c. The polymerization of propylene and optionally another (s) comonomer (s) is conducted in said reaction vessel in the presence of a catalyst system having a not greater surface area of ​​350 m 2 / g measured according to ISO 9277 and said catalyst system comprises a metallocene catalyst having zirconium as the transition metal and wherein the metallocene catalyst has the formula (I): wherein z is 0 or 1, (Cp) 2R zZrX 2 X is independently a monovalent anionic ligand, R is a bridging group linking the two Cp ligands, and the two Cp-ligands are selected independently of one another from the group consisting of cyclopentadienyl ring unsubstituted indenyl ring, unsubstituted ring tetrahydroindenyl, unsubstituted fluorenyl ring unsubstituted , substituted cyclopentadienyl ring, substituted indenyl ring, substituted tetrahydroindenyl ring, and substituted fluorenyl ring, and said Cp-ligands differ in their chemical structure.

Term

No projected expiry on record.

  1. Priority and filed
  2. Granted
  3. Today

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EP1939230A1European Patent Office (EPO)A1
WO2008080886A1World Intellectual Property Organization (WIPO)A1
EP1939230B1European Patent Office (EPO)B1
AT424424TThis recordAustriaT
ATE424424T1AustriaT1
DE602006005508D1GermanyD1
ES2322186T3SpainT3
KR20090083488ARepublic of KoreaA
EP2097461A1European Patent Office (EPO)A1
US2009264606A1United States of AmericaA1
CN101568558AChinaA
RU2009128975ARussian FederationA
US7915367B2United States of AmericaB2
RU2421476C2Russian FederationC2
CN101568558BChinaB
KR101118950B1Republic of KoreaB1
EP2097461B1European Patent Office (EPO)B1
AT552279TAustriaT
ATE552279T1AustriaT1
BRPI0720864A2BrazilA2