Bridged metallocenes for olefin copolymerization
Abstract
The invention relates to a a soluble with a metallocene catalyst for preparing the aliphatic series solvent, specifically suitable for the solution olefin polymerization method, which can be specifically under the polymerization temperature and catalyst activity of preparing olefin copolymer by weight average. The concrete, invention relates to a method for preparing density of the polymerization method for a 0.850~0.940 ethylene copolymer, comprising in the solution polymerization conditions, the reaction temperature is 60℃ or greater than 60℃ to 250℃, wherein the ethylene and one or more of inserted into the polymerized comonomer and with a metallocene catalyst preparation steps, the metallocene catalyst preparing derived from the group consisting of assistant, wherein each ligand is a substituted or un-substituted, wherein the ligand of comprises a substitution at least one group is connected with a connecting, wherein at least one of the substitution part comprises a aryl, Wherein the aryl at least comprises a hydrocarbyl) silyl group; A B) a first promoter.
Term
No projected expiry on record.
- Priority
- Filed
- Granted
- Today
68 members in 16 offices
Priority claims3
| Document | Office | Kind | Date |
|---|---|---|---|
| 10532998 | United States of America | P | |
| 13106799 | United States of America | P | |
| 9924944 | United States of America | W |
Members68
| Document | Office | Kind | |
|---|---|---|---|
| CA2343768A1 | Canada | A1 | |
| CA2345628A1 | Canada | A1 | |
| WO0024792A1 | World Intellectual Property Organization (WIPO) | A1 | |
| WO0024793A1 | World Intellectual Property Organization (WIPO) | A1 | |
| AU1321200A | Australia | A | |
| AU1448400A | Australia | A | |
| CA2397818A1 | Canada | A1 | |
| WO0129096A1 | World Intellectual Property Organization (WIPO) | A1 | |
| BR9914738A | Brazil | A | |
| BR9914717A | Brazil | A | |
| KR20010075644A | Republic of Korea | A | |
| EP1129115A1 | European Patent Office (EPO) | A1 | |
| US6300433B1 | United States of America | B1 | |
| WO0024793A8 | World Intellectual Property Organization (WIPO) | A8 | |
| KR20010099705A | Republic of Korea | A | |
| CN1324370A | China | A | |
| CN1328580A | China | A | |
| EP1196464A1 | European Patent Office (EPO) | A1 | |
| TW486489B | Taiwan Province of China | B | |
| BR0014119A | Brazil | A | |
| KR20020040905A | Republic of Korea | A | |
| US2002086958A1 | United States of America | A1 | |
| HK1041705A1 | Hong Kong, China | A1 | |
| JP2002528463A | Japan | A | |
| JP2002528576A | Japan | A | |
| US2002137959A1 | United States of America | A1 | |
| CN1376168A | China | A | |
| MXPA02003940A | Mexico | A | |
| US2002165086A1 | United States of America | A1 | |
| US6486088B1 | United States of America | B1 | |
| EP1259553A1 | European Patent Office (EPO) | A1 | |
| US6506857B2 | United States of America | B2 | |
| AU757241B2 | Australia | B2 | |
| US6528670B1 | United States of America | B1 | |
| US6562919B2 | United States of America | B2 | |
| JP2003518146A | Japan | A | |
| AU761531B2 | Australia | B2 | |
| MXPA01003977A | Mexico | A | |
| MXPA01003978A | Mexico | A | |
| CN1125834C | China | C | |
| CN1138796C | China | C | |
| RU2228937C2 | Russian Federation | C2 | |
| RU2232766C2 | Russian Federation | C2 | |
| US6806220B2 | United States of America | B2 | |
| EP1129115B1 | European Patent Office (EPO) | B1 | |
| EP1196464B1 | European Patent Office (EPO) | B1 | |
| AT284421T | Austria | T | |
| AT284422TThis record | Austria | T | |
| ATE284421T1 | Austria | T1 | |
| ATE284422T1 | Austria | T1 | |
| EP1259553B1 | European Patent Office (EPO) | B1 | |
| DE69922536D1 | Germany | D1 | |
| DE69922548D1 | Germany | D1 | |
| AT286921T | Austria | T | |
| ATE286921T1 | Austria | T1 | |
| DE60017467D1 | Germany | D1 | |
| EP1196464B9 | European Patent Office (EPO) | B9 | |
| ES2233109T3 | Spain | T3 | |
| ES2233471T3 | Spain | T3 | |
| ES2235549T3 | Spain | T3 | |
| DE69922536T2 | Germany | T2 | |
| DE69922548T2 | Germany | T2 | |
| DE60017467T2 | Germany | T2 | |
| KR100568839B1 | Republic of Korea | B1 | |
| KR100621299B1 | Republic of Korea | B1 | |
| CA2345628C | Canada | C | |
| JP4689829B2 | Japan | B2 | |
| JP5255740B2 | Japan | B2 |
1 legal event, as the office reported them to INPADOC
Events
| Event | Code | |
|---|---|---|
| Ceased as to paragraph 5 lit. 3 law introducing patent treatiesCeasedRER | RER |
Numbers
- Application
- 99974265
Titles2
- German
- VERBRÜCKTE METALLOCENE ZUR OLEFINCOPOLYMERISATION
- English
- BROKEN METAL OENCENE FOR OLEFIN COPOLYMERIZATION
Classification
- CPC, 5
- C07F17/00
- C08F4/65908
- C08F10/02
- C08F110/02
- C08F210/16
- IPC, 8
- C07F17 00
- C08F10 02
- C08F110 02
- C08F210 00
- C08F210 02
- C08F210 16
- C08F4 645
- C08F4 659