Production of multimodal polyethylene
Abstract
A process for the preparation of polyethylene resins having a multimodal molecular weight distribution which comprises: (i) contacting ethylene monomer and a comonomer comprising an alpha-olefin having from 3 to 10 carbon atoms with a first catalyst system in a first reactor under first polymerisation conditions to produce a product comprising a first polyethylene having a first molecular weight and a first density and the first catalyst system comprising (a) a metallocene catalyst selected from one of components A or B and component A comprising a bis tetrahydroindenyl compound of the general formula (IndH4) 2R''MQ2 in which each Ind is the same or different and is indenyl or substituted indenyl, R'' is a bridge which comprises aC1-C20 alkylene radical, a dialkyl germanium or silicon or siloxane, or an alkyl phosphine or amine radical, which bridge is substituted orunsubstituted, M is a Group IVB transition metal or vanadium and each Q is hydrocarbyl having 1 to 20 carbon atoms or halogen andcomponent B comprising a metallocene catalyst of general formula R'' (CpRm) (Cp'R'n) MQ2, wherein Cp is a cyclopentadienyl moiety. Cp' is a substituted or unsubstituted fluorenyl ring;each R is independently hydrogen or hydrocarbyl having 1 to 20 carbon atoms in which O ≤m ≤ 4; each R' is independently hydrocarbyl having 1 to 20 carbon atoms in which O ≤n ≤8; R'', M and Q are each as defined above, the metallocene component B having a centroid-M-centroid angle in the range 105 DEG to 125 DEG ;and (b) a cocatalyst which activates the catalyst component; (ii) providing a second polyethylene having a second lower molecular weight and higher density than the first molecular weight;and (iii) mixing together the first and second polyethylenes to form a polyethylene resin having a multimodal molecular weight distribution.
Term
No projected expiry on record.
- Priority
- Filed
- Granted
- Today
28 members in 8 offices
Priority claims3
| Document | Office | Kind | Date |
|---|---|---|---|
| 98118190 | European Patent Office (EPO) | A | |
| 98123826 | European Patent Office (EPO) | A | |
| 9907128 | European Patent Office (EPO) | W |
Members28
| Document | Office | Kind | |
|---|---|---|---|
| EP0989140A1 | European Patent Office (EPO) | A1 | |
| EP0989141A1 | European Patent Office (EPO) | A1 | |
| WO0018813A1 | World Intellectual Property Organization (WIPO) | A1 | |
| WO0018814A1 | World Intellectual Property Organization (WIPO) | A1 | |
| JP2000103813A | Japan | A | |
| AU6329399A | Australia | A | |
| AU6329499A | Australia | A | |
| JP2000191726A | Japan | A | |
| EP1117709A1 | European Patent Office (EPO) | A1 | |
| EP1124868A1 | European Patent Office (EPO) | A1 | |
| US6346575B1 | United States of America | B1 | |
| US2002065368A1 | United States of America | A1 | |
| US2002099140A1 | United States of America | A1 | |
| US6479589B2 | United States of America | B2 | |
| US6566450B2 | United States of America | B2 | |
| EP1117709B1 | European Patent Office (EPO) | B1 | |
| EP1124868B1 | European Patent Office (EPO) | B1 | |
| AT282647T | Austria | T | |
| AT282648TThis record | Austria | T | |
| ATE282647T1 | Austria | T1 | |
| ATE282648T1 | Austria | T1 | |
| DE69922035D1 | Germany | D1 | |
| DE69922040D1 | Germany | D1 | |
| ES2232178T3 | Spain | T3 | |
| ES2232179T3 | Spain | T3 | |
| DE69922040T2 | Germany | T2 | |
| DE69922035T2 | Germany | T2 | |
| JP5283292B2 | Japan | B2 |
1 legal event, as the office reported them to INPADOC
Events
| Event | Code | |
|---|---|---|
| Ceased as to paragraph 5 lit. 3 law introducing patent treatiesCeasedRER | RER |
Numbers
- Application
- 99950550
Titles2
- German
- HERSTELLUNG VON MULTIMODALEM POLYETHYLEN
- English
- PREPARATION OF MULTIMODAL POLYETHYLENE
Classification
- CPC, 11
- C08F210/16
- C08F4/65916
- C08F110/02
- C08L23/06
- C08L23/0815
- C08L2205/02
- C08L2205/025
- C08L2308/00
- C08L2314/02
- C08L2314/04
- C08L2314/06
- IPC, 10
- C08F10 02
- C08F110 02
- C08F210 16
- C08F4 64
- C08F4 642
- C08F4 659
- C08F4 6592
- C08L23 04
- C08L23 06
- C08L23 08