Nova Patents
AT282648T

Production of multimodal polyethylene

Abstract

A process for the preparation of polyethylene resins having a multimodal molecular weight distribution which comprises: (i) contacting ethylene monomer and a comonomer comprising an alpha-olefin having from 3 to 10 carbon atoms with a first catalyst system in a first reactor under first polymerisation conditions to produce a product comprising a first polyethylene having a first molecular weight and a first density and the first catalyst system comprising (a) a metallocene catalyst selected from one of components A or B and component A comprising a bis tetrahydroindenyl compound of the general formula (IndH4) 2R''MQ2 in which each Ind is the same or different and is indenyl or substituted indenyl, R'' is a bridge which comprises aC1-C20 alkylene radical, a dialkyl germanium or silicon or siloxane, or an alkyl phosphine or amine radical, which bridge is substituted orunsubstituted, M is a Group IVB transition metal or vanadium and each Q is hydrocarbyl having 1 to 20 carbon atoms or halogen andcomponent B comprising a metallocene catalyst of general formula R'' (CpRm) (Cp'R'n) MQ2, wherein Cp is a cyclopentadienyl moiety. Cp' is a substituted or unsubstituted fluorenyl ring;each R is independently hydrogen or hydrocarbyl having 1 to 20 carbon atoms in which O ≤m ≤ 4; each R' is independently hydrocarbyl having 1 to 20 carbon atoms in which O ≤n ≤8; R'', M and Q are each as defined above, the metallocene component B having a centroid-M-centroid angle in the range 105 DEG to 125 DEG ;and (b) a cocatalyst which activates the catalyst component; (ii) providing a second polyethylene having a second lower molecular weight and higher density than the first molecular weight;and (iii) mixing together the first and second polyethylenes to form a polyethylene resin having a multimodal molecular weight distribution.

Term

No projected expiry on record.

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28 members in 8 offices

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Priority claims
DocumentOfficeKindDate
98118190European Patent Office (EPO)A
98123826European Patent Office (EPO)A
9907128European Patent Office (EPO)W

Members28

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DocumentOfficeKind
EP0989140A1European Patent Office (EPO)A1
EP0989141A1European Patent Office (EPO)A1
WO0018813A1World Intellectual Property Organization (WIPO)A1
WO0018814A1World Intellectual Property Organization (WIPO)A1
JP2000103813AJapanA
AU6329399AAustraliaA
AU6329499AAustraliaA
JP2000191726AJapanA
EP1117709A1European Patent Office (EPO)A1
EP1124868A1European Patent Office (EPO)A1
US6346575B1United States of AmericaB1
US2002065368A1United States of AmericaA1
US2002099140A1United States of AmericaA1
US6479589B2United States of AmericaB2
US6566450B2United States of AmericaB2
EP1117709B1European Patent Office (EPO)B1
EP1124868B1European Patent Office (EPO)B1
AT282647TAustriaT
AT282648TThis recordAustriaT
ATE282647T1AustriaT1
ATE282648T1AustriaT1
DE69922035D1GermanyD1
DE69922040D1GermanyD1
ES2232178T3SpainT3
ES2232179T3SpainT3
DE69922040T2GermanyT2
DE69922035T2GermanyT2
JP5283292B2JapanB2